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Home My WebLink AboutNC0003417_J15050103 Report_20150805+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J15050103 Project Name: HF LEE PLANT - AB GW ASSESSMENT SOIL Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer Customer Address: 1677 Old Smithfield Rd Goldsboro NC 27530, Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) Report Authorized By: VIC, 2015.06.2408:05:46 Date: (Signature)-04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/24/2015 1 of 69 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By 2 of 69 Sample Description 2015013473 HF LEE PLANT 29-Apr-15 12:16 PM ILLEGIBLE Well AMW-6R-0.5-2.0 2015013474 HF LEE PLANT 29-Apr-15 1:00 PM ILLEGIBLE Well AMW-6R-5.5-6.5 2015013475 HF LEE PLANT 29-Apr-15 1:40 PM ILLEGIBLE Well AMW-6R-18.5-19 2015013476 HF LEE PLANT 03-May-15 1:20 PM ILLEGIBLE Well IMW-1-0.5-2 2015013477 HF LEE PLANT 03-May-15 1:30 PM ILLEGIBLE Well IMW-1-4-5 2015013478 HF LEE PLANT 03-May-15 2:15 PM ILLEGIBLE Well IMW-1-14-15 2015013486 HF LEE PLANT 29-Apr-15 11:30 AM ILLEGIBLE Well Equipment Blank 2015013487 HF LEE PLANT 03-May-15 11:31 AM ILLEGIBLE Well Equipment Blank 8 Total Samples 3 of 69 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 6/24/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050103 Site: Well AMW-6R-0.5-2.0 Collection Date: 29-Apr-15 12:16 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 69 Sample #: 2015013473 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050103 Site: Well AMW-6R-5.5-6.5 Collection Date: 29-Apr-15 1:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 69 Sample #: 2015013474 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050103 Site: Well AMW-6R-18.5-19 Collection Date: 29-Apr-15 1:40 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 69 Sample #: 2015013475 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050103 Site: Well IMW-1-0.5-2 Collection Date: 03-Mav-15 1:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 69 Sample #: 2015013476 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050103 Site: Well IMW-1-4-5 Collection Date: 03-May-15 1:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 8 of 69 Sample #: 2015013477 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050103 Site: Well IMW-1-14-15 Collection Date: 03-May-15 2:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 9 of 69 Sample #: 2015013478 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050103 Site: Well Equipment Blank Collection Date: 29-Apr-15 11:30 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015013486 Matrix: SOIL 10 of 69 Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050103 Site: Well Equipment Blank Collection Date: 03-May-15 11:31 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015013487 Matrix: SOIL 11 of 69 Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 June 23, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15050103 Pace Project No.: 92248767 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 06, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 57 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kiinf&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050103 Pace Project No.: 92248767 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Page 2 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�ic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050103 Pace Project No.: 92248767 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f igc&y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15050103 Pace Project No.: 92248767 Lab ID Sample ID Matrix Date Collected Date Received 92248767001 2015013473 Solid 04/29/1512:16 05/06/1517:10 92248767002 2015013474 Solid 04/29/1513:00 05/06/1517:10 92248767003 2015013475 Solid 04/29/1513:40 05/06/1517:10 92248767004 2015013476 Solid 05/03/1513:20 05/06/1517:10 92248767005 2015013477 Solid 05/03/1513:30 05/06/1517:10 92248767006 2015013478 Solid 05/03/1514:15 05/06/1517:10 92248767007 2015013486 Water 04129/1511:30 05/06/1517:10 92248767008 2015013487 Water 05/03/1511:31 05/06/1517:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli '8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15050103 92248767 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92248767001 2015013473 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92248767002 2015013474 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92248767003 2015013475 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92248767004 2015013476 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92248767005 2015013477 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15050103 92248767 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92248767006 2015013478 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92248767007 2015013486 EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92248767008 2015013487 EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050103 Pace Project No.: 92248767 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92248767001 2015013473 EPA 6010 Aluminum 5240 mg/kg 30.2 05/17/15 06:02 EPA 6010 Barium 24.1 mg/kg 3.0 05/17/15 06:02 EPA 6010 Calcium 274 mg/kg 151 05/17/15 06:02 EPA 6010 Chromium 5.2 mg/kg 1.5 05/17/15 06:02 EPA 6010 Copper 2.5 mg/kg 1.5 05/17/15 06:02 EPA 6010 Iron 1850 mg/kg 12.1 05/17/15 06:02 EPA 6010 Magnesium 279 mg/kg 151 05/17/15 06:02 EPA 6010 Manganese 12.5 mg/kg 1.5 05/17/15 06:02 EPA 6010 Nickel 2.5 mg/kg 1.5 05/17/15 06:02 EPA 6010 Strontium 4.7 mg/kg 3.0 05/17/15 06:02 EPA 6010 Zinc 4.8J mg/kg 6.0 05/17/15 06:02 EPA 6020 Lead 4AJ mg/kg 6.0 05/16/1516:54 EPA 6020 Vanadium 15.4 mg/kg 6.0 05/16/15 16:54 EPA 7471 Mercury 0.0087J mg/kg 0.0097 05/15/15 17:17 ASTM D2974-87 Percent Moisture 17.1 % 0.10 05/20/15 10:34 EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 05/11/15 11:20 EPA 9060 Total Organic Carbon 2630 mg/kg 728 06/18/15 17:20 EPA 9060 Total Organic Carbon 1660 mg/kg 719 06/18/15 17:25 EPA 9060 Total Organic Carbon 2160 mg/kg 721 06/18/15 17:32 EPA 9060 Total Organic Carbon 1610 mg/kg 725 06/18/15 17:38 EPA 9060 Mean Total Organic Carbon 2020 mg/kg 723 06/18/15 17:20 EPA 9060 RSD% 23.9 % 06/18/15 17:20 92248767002 2015013474 EPA 6010 Aluminum 1490 mg/kg 30.6 05/17/15 06:19 EPA 6010 Barium 16.6 mg/kg 3.1 05/17/15 06:19 EPA 6010 Chromium 1.5J mg/kg 1.5 05/17/15 06:19 EPA 6010 Copper 2.1 mg/kg 1.5 05/17/15 06:19 EPA 6010 Iron 326 mg/kg 12.2 05/17/15 06:19 EPA 6010 Magnesium 91.91 mg/kg 153 05/17/15 06:19 EPA 6010 Manganese 3.7 mg/kg 1.5 05/17/15 06:19 EPA 6010 Nickel 1.2J mg/kg 1.5 05/17/15 06:19 EPA 6020 Vanadium 7.9 mg/kg 6.1 05/16/15 16:56 ASTM D2974-87 Percent Moisture 20.6 % 0.10 05/20/15 10:34 EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 05/11/15 11:20 EPA 9060 Total Organic Carbon 1010 mg/kg 753 05/27/15 19:01 EPA 9060 Total Organic Carbon 1080 mg/kg 762 05/27/15 19:08 EPA 9060 Total Organic Carbon 1040 mg/kg 760 05/27/15 19:14 EPA 9060 Total Organic Carbon 1040 mg/kg 751 05/27/15 19:20 EPA 9060 Mean Total Organic Carbon 1050 mg/kg 757 05/27/15 19:01 EPA 9060 RSD% 2.7 % 05/27/15 19:01 92248767003 2015013475 EPA 6010 Aluminum 4040 mg/kg 30.6 05/17/15 06:24 EPA 6010 Barium 21.7 mg/kg 3.1 05/17/15 06:24 EPA 6010 Beryllium 0.70 mg/kg 0.31 05/17/15 06:24 EPA 6010 Calcium 853 mg/kg 153 05/17/15 06:24 EPA 6010 Chromium 4.3 mg/kg 1.5 05/17/15 06:24 REPORT OF LABORATORY ANALYSIS H3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050103 Pace Project No.: 92248767 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92248767003 2015013475 EPA 6010 Copper 10.9 mg/kg 1.5 05/17/15 06:24 EPA 6010 Iron 3550 mg/kg 12.3 05/17/15 06:24 EPA 6010 Magnesium 1060 mg/kg 153 05/17/15 06:24 EPA 6010 Manganese 35.1 mg/kg 1.5 05/17/15 06:24 EPA 6010 Nickel 11.6 mg/kg 1.5 05/17/15 06:24 EPA 6010 Potassium 691 mg/kg 306 05/17/15 06:24 EPA 6010 Strontium 7.2 mg/kg 3.1 05/17/15 06:24 EPA 6010 Zinc 14.9 mg/kg 6.1 05/17/15 06:24 EPA 6020 Arsenic 4AJ mg/kg 6.1 05/16/15 16:59 EPA 6020 Cobalt 20.3 mg/kg 6.1 05/16/15 16:59 EPA 6020 Lead 11.5 mg/kg 6.1 05/16/15 16:59 EPA 6020 Selenium 4.2J mg/kg 6.1 05/16/15 16:59 EPA 6020 Vanadium 20.0 mg/kg 6.1 05/16/15 16:59 EPA 7471 Mercury 0.0062J mg/kg 0.0096 05/15/15 17:21 ASTM D2974-87 Percent Moisture 16.5 % 0.10 05/20/15 10:34 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 05/20/15 16:06 EPA 9060 Total Organic Carbon 1260 mg/kg 719 06/18/15 17:55 EPA 9060 Total Organic Carbon 1300 mg/kg 721 06/18/15 18:02 EPA 9060 Total Organic Carbon 1400 mg/kg 721 06/18/15 18:08 EPA 9060 Total Organic Carbon 1530 mg/kg 725 06/18/15 18:13 EPA 9060 Mean Total Organic Carbon 1370 mg/kg 722 06/18/15 17:55 EPA 9060 RSD% 8.6 % 06/18/15 17:55 92248767004 2015013476 EPA 6010 Aluminum 6710 mg/kg 39.7 05/17/15 06:28 EPA 6010 Barium 56.0 mg/kg 4.0 05/17/15 06:28 EPA 6010 Beryllium 0.43 mg/kg 0.40 05/17/15 06:28 EPA 6010 Chromium 7.1 mg/kg 2.0 05/17/15 06:28 EPA 6010 Copper 2.1 mg/kg 2.0 05/17/15 06:28 EPA 6010 Iron 3360 mg/kg 15.9 05/17/15 06:28 EPA 6010 Magnesium 257 mg/kg 199 05/17/15 06:28 EPA 6010 Manganese 7.5 mg/kg 2.0 05/17/15 06:28 EPA 6010 Nickel 1.6J mg/kg 2.0 05/17/15 06:28 EPA 6010 Strontium 3.OJ mg/kg 4.0 05/17/15 06:28 EPA 6010 Zinc 4AJ mg/kg 7.9 05/17/15 06:28 EPA 6020 Lead 10.6 mg/kg 7.9 05/16/15 17:02 EPA 6020 Vanadium 30.7 mg/kg 7.9 05/16/15 17:02 EPA 7471 Mercury 0.015 mg/kg 0.013 05/15/15 17:24 ASTM D2974-87 Percent Moisture 36.0 % 0.10 05/20/15 10:34 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 05/20/15 16:06 EPA 9060 Total Organic Carbon 8590 mg/kg 935 06/18/15 18:19 EPA 9060 Total Organic Carbon 8100 mg/kg 937 06/18/15 18:24 EPA 9060 Total Organic Carbon 9370 mg/kg 941 06/18/15 18:30 EPA 9060 Total Organic Carbon 7420 mg/kg 940 06/18/15 18:36 EPA 9060 Mean Total Organic Carbon 8370 mg/kg 938 06/18/15 18:19 EPA 9060 RSD% 9.8 % 06/18/15 18:19 REPORT OF LABORATORY ANALYSIS H6 H3 H6 H3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050103 Pace Project No.: 92248767 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92248767005 2015013477 EPA 6010 Aluminum 5080 mg/kg 34.9 05/17/15 06:32 EPA 6010 Barium 41.8 mg/kg 3.5 05/17/15 06:32 EPA 6010 Beryllium 0.30J mg/kg 0.35 05/17/15 06:32 EPA 6010 Calcium 106J mg/kg 174 05/17/15 06:32 EPA 6010 Chromium 5.8 mg/kg 1.7 05/17/15 06:32 EPA 6010 Copper 2.3 mg/kg 1.7 05/17/15 06:32 EPA 6010 Iron 1820 mg/kg 13.9 05/17/15 06:32 EPA 6010 Magnesium 216 mg/kg 174 05/17/15 06:32 EPA 6010 Manganese 4.9 mg/kg 1.7 05/17/15 06:32 EPA 6010 Nickel 1 AJ mg/kg 1.7 05/17/15 06:32 EPA 6010 Strontium 3.5 mg/kg 3.5 05/17/15 06:32 EPA 6020 Lead 6.2J mg/kg 7.0 05/16/15 17:13 EPA 6020 Vanadium 21.8 mg/kg 7.0 05/16/15 17:13 EPA 7471 Mercury 0.020 mg/kg 0.011 05/15/15 17:26 ASTM D2974-87 Percent Moisture 30.6 % 0.10 05/20/15 10:34 EPA 9045 pH at 25 Degrees C 4.8 Std. Units 0.10 05/12/15 10:30 EPA 9060 Total Organic Carbon 4820 mg/kg 870 06/18/15 18:42 EPA 9060 Total Organic Carbon 3480 mg/kg 867 06/18/15 18:48 EPA 9060 Total Organic Carbon 3750 mg/kg 865 06/18/15 18:54 EPA 9060 Total Organic Carbon 4320 mg/kg 859 06/18/15 18:59 EPA 9060 Mean Total Organic Carbon 4090 mg/kg 865 06/18/15 18:42 EPA 9060 RSD% 14.7 % 06/18/15 18:42 92248767006 2015013478 EPA 6010 Aluminum 817 mg/kg 30.0 05/17/15 06:36 EPA 6010 Barium 7.0 mg/kg 3.0 05/17/15 06:36 EPA 6010 Beryllium 0.49 mg/kg 0.30 05/17/15 06:36 EPA 6010 Boron 28.2 mg/kg 15.0 05/17/15 06:36 EPA 6010 Calcium 555 mg/kg 150 05/17/15 06:36 EPA 6010 Chromium 5.1 mg/kg 1.5 05/17/15 06:36 EPA 6010 Copper 215 mg/kg 1.5 05/17/15 06:36 EPA 6010 Iron 30600 mg/kg 12.0 05/17/15 06:36 EPA 6010 Magnesium 462 mg/kg 150 05/17/15 06:36 EPA 6010 Manganese 260 mg/kg 1.5 05/17/15 06:36 EPA 6010 Nickel 14.1 mg/kg 1.5 05/17/15 06:36 EPA 6010 Strontium 2.2J mg/kg 3.0 05/17/15 06:36 EPA 6010 Zinc 566 mg/kg 6.0 05/17/15 06:36 EPA 6020 Arsenic 8.5 mg/kg 6.0 05/16/15 17:15 EPA 6020 Cadmium 1.2 mg/kg 0.72 05/16/15 17:15 EPA 6020 Cobalt 47.9 mg/kg 6.0 05/16/15 17:15 EPA 6020 Lead 7.6 mg/kg 6.0 05/16/15 17:15 EPA 6020 Vanadium 32.8 mg/kg 6.0 05/16/15 17:15 EPA 7471 Mercury 0.054 mg/kg 0.0096 05/15/15 17:28 ASTM D2974-87 Percent Moisture 16.8 % 0.10 05/20/15 10:34 EPA 9045 pH at 25 Degrees C 3.8 Std. Units 0.10 05/12/15 10:30 EPA 9060 Total Organic Carbon 716J mg/kg 721 05/29/15 09:57 EPA 9060 Total Organic Carbon 726 mg/kg 716 05/29/15 10:03 EPA 9060 Total Organic Carbon 736 mg/kg 715 05/29/15 10:09 REPORT OF LABORATORY ANALYSIS H3 H3 H3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�n�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15050103 92248767 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92248767006 2015013478 EPA 9060 Total Organic Carbon 771 mg/kg 722 05/29/15 10:15 EPA 9060 Mean Total Organic Carbon 737 mg/kg 719 05/29/15 09:57 EPA 9060 RSD% 3.2 % 05/29/15 09:57 92248767007 2015013486 EPA 6020A Aluminum 4.3J ug/L 10.0 05/14/15 14:33 EPA 6020A Antimony 0.16J ug/L 0.50 05/14/15 14:33 EPA 6020A Barium 0.21J ug/L 0.30 05/14/15 14:33 EPA 6020A Calcium 68.0 ug/L 40.0 05/14/15 14:33 EPA 6020A Magnesium 16.1 ug/L 10.0 05/14/15 14:33 EPA 6020A Manganese 0.44J ug/L 0.50 05/14/15 14:33 EPA 6020A Nickel 0.191 ug/L 0.50 05/14/15 14:33 EPA 6020A Potassium 18.6J ug/L 50.0 05/14/15 14:33 EPA 6020A Sodium 87.0 ug/L 50.0 05/14/15 14:33 EPA 6020A Strontium 0.32J ug/L 0.50 05/14/15 14:33 EPA 7470A Mercury 0.024J ug/L 0.20 05/12/15 19:59 92248767008 2015013487 EPA 6020A Aluminum 7.3J ug/L 10.0 05/14/15 14:36 EPA 6020A Barium 0.11 J ug/L 0.30 05/14/15 14:36 EPA 6020A Calcium 43.4 ug/L 40.0 05/14/15 14:36 EPA 6020A Magnesium 12.2 ug/L 10.0 05/14/15 14:36 EPA 6020A Manganese 0.42J ug/L 0.50 05/14/15 14:36 EPA 6020A Potassium 12.9J ug/L 50.0 05/14/15 14:36 EPA 6020A Sodium 51.5 ug/L 50.0 05/14/15 14:36 EPA 6020A Strontium 0.21J ug/L 0.50 05/14/15 14:36 EPA 7470A Mercury 0.037J ug/L 0.20 05/12/15 20:02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KQcigy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 23, 2015 General Information: 6 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24119 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92248729001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1212835) • Aluminum • Barium • Calcium • Copper • Iron • Magnesium • Potassium • MSD (Lab ID: 1212836) • Aluminum • Barium • Calcium • Copper • Iron • Magnesium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 23, 2015 Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14775 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 23, 2015 General Information: 6 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24120 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92248729001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1212839) • Cobalt • Selenium • Vanadium • MSD (Lab ID: 1212840) • Antimony • Cobalt • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 23, 2015 Analyte Comments: QC Batch: MPRP/24120 N2: The lab does not hold TNI accreditation for this parameter. •2015013473 (Lab ID:92248767001) • Antimony •2015013474 (Lab ID:92248767002) • Antimony •2015013475 (Lab ID:92248767003) • Antimony •2015013476 (Lab ID:92248767004) • Antimony •2015013477 (Lab ID:92248767005) • Antimony •2015013478 (Lab ID:92248767006) • Antimony • BLANK (Lab ID: 1212837) • Antimony • LCS (Lab ID: 1212838) • Antimony • MS (Lab ID: 1212839) • Antimony • MSD (Lab ID: 1212840) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 23, 2015 General Information: 2 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: June 23, 2015 General Information: 2 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %cagy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 23, 2015 General Information: 6 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 23, 2015 General Information: 6 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015013477 (Lab ID:92248767005) •2015013478 (Lab ID:92248767006) H6: Analysis initiated outside of the 15 minute EPA recommended holding time. •2015013475 (Lab ID:92248767003) •2015013476 (Lab ID:92248767004) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37363 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1455163) • pH at 25 Degrees C • DUP (Lab ID: 1455164) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 23, 2015 General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �nlc&)r&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 23, 2015 General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015013473 (Lab ID:92248767001) •2015013474 (Lab ID:92248767002) •2015013475 (Lab ID:92248767003) •2015013476 (Lab ID:92248767004) •2015013477 (Lab ID:92248767005) •2015013478 (Lab ID:92248767006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46253 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015013473 (Lab ID:92248767001) • Nitrate as N •2015013474 (Lab ID:92248767002) • Nitrate as N •2015013475 (Lab ID:92248767003) • Nitrate as N •2015013476 (Lab ID:92248767004) • Nitrate as N •2015013477 (Lab ID:92248767005) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 23, 2015 Analyte Comments: QC Batch: WETA/46253 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015013478 (Lab ID:92248767006) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050103 Pace Project No.: 92248767 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: June 23, 2015 General Information: 6 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015013473 (Lab ID:92248767001) •2015013475 (Lab ID:92248767003) •2015013476 (Lab ID:92248767004) •2015013477 (Lab ID:92248767005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013473 Lab ID: 92248767001 Collected: 04/29/15 12:16 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 5240 mg/kg 30.2 15.1 5 05/15/15 10:58 05/17/15 06:02 7429-90-5 Barium 24.1 mg/kg 3.0 1.5 5 05/15/15 10:58 05/17/15 06:02 7440-39-3 Beryllium ND mg/kg 0.30 0.15 5 05/15/15 10:58 05/17/15 06:02 7440-41-7 Boron ND mg/kg 15.1 7.6 5 05/15/15 10:58 05/17/15 06:02 7440-42-8 Calcium 274 mg/kg 151 75.5 5 05/15/15 10:58 05/17/15 06:02 7440-70-2 Chromium 5.2 mg/kg 1.5 0.76 5 05/15/15 10:58 05/17/15 06:02 7440-47-3 Copper 2.5 mg/kg 1.5 0.76 5 05/15/15 10:58 05/17/15 06:02 7440-50-8 Iron 1850 mg/kg 12.1 6.0 5 05/15/15 10:58 05/17/15 06:02 7439-89-6 Magnesium 279 mg/kg 151 75.5 5 05/15/15 10:58 05/17/15 06:02 7439-95-4 Manganese 12.5 mg/kg 1.5 0.76 5 05/15/15 10:58 05/17/15 06:02 7439-96-5 Molybdenum ND mg/kg 3.0 1.5 5 05/15/15 10:58 05/17/15 06:02 7439-98-7 Nickel 2.5 mg/kg 1.5 0.76 5 05/15/15 10:58 05/17/15 06:02 7440-02-0 Potassium ND mg/kg 302 151 5 05/15/15 10:58 05/17/15 06:02 7440-09-7 Sodium ND mg/kg 302 151 5 05/15/15 10:58 05/17/15 06:02 7440-23-5 Strontium 4.7 mg/kg 3.0 1.5 5 05/15/15 10:58 05/17/15 06:02 7440-24-6 Zinc 4.8J mg/kg 6.0 3.0 5 05/15/15 10:58 05/17/15 06:02 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1516:54 7440-36-0 N2 Arsenic ND mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1516:54 7440-38-2 Cadmium ND mg/kg 0.72 0.36 100 05/15/15 10:58 05/16/1516:54 7440-43-9 Cobalt ND mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1516:54 7440-48-4 Lead 4.1J mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1516:54 7439-92-1 Selenium ND mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1516:54 7782-49-2 Thallium ND mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1516:54 7440-28-0 Vanadium 15.4 mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1516:54 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0087J mg/kg 0.0097 0.0048 1 05/15/1511:16 05/15/1517:17 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 17.1 % 0.10 0.10 1 05/20/15 10:34 D6 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 0.10 1 05/11/15 11:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 297 148 5 05/10/1519:48 16887-00-6 Sulfate ND mg/kg 297 148 5 05/10/1519:48 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.7 14.8 5 05/10/15 19:48 14797-55-8 D3,H3 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013473 Lab ID: 92248767001 Collected: 04/29/15 12:16 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2630 mg/kg 728 364 1 06/18/15 17:20 7440-44-0 Total Organic Carbon 1660 mg/kg 719 359 1 06/18/15 17:25 7440-44-0 Total Organic Carbon 2160 mg/kg 721 360 1 06/18/15 17:32 7440-44-0 Total Organic Carbon 1610 mg/kg 725 362 1 06/18/15 17:38 7440-44-0 Mean Total Organic Carbon 2020 mg/kg 723 362 1 06/18/15 17:20 7440-44-0 H3 Surrogates RSD% 23.9 % 1 06/18/15 17:20 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013474 Lab ID: 92248767002 Collected: 04/29/15 13:00 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 1490 mg/kg 30.6 15.3 5 05/15/15 10:58 05/17/15 06:19 7429-90-5 Barium 16.6 mg/kg 3.1 1.5 5 05/15/15 10:58 05/17/15 06:19 7440-39-3 Beryllium ND mg/kg 0.31 0.15 5 05/15/15 10:58 05/17/15 06:19 7440-41-7 Boron ND mg/kg 15.3 7.6 5 05/15/15 10:58 05/17/15 06:19 7440-42-8 Calcium ND mg/kg 153 76.4 5 05/15/15 10:58 05/17/15 06:19 7440-70-2 Chromium 1.51 mg/kg 1.5 0.76 5 05/15/15 10:58 05/17/15 06:19 7440-47-3 Copper 2.1 mg/kg 1.5 0.76 5 05/15/15 10:58 05/17/15 06:19 7440-50-8 Iron 326 mg/kg 12.2 6.1 5 05/15/15 10:58 05/17/15 06:19 7439-89-6 Magnesium 91.91 mg/kg 153 76.4 5 05/15/15 10:58 05/17/15 06:19 7439-95-4 Manganese 3.7 mg/kg 1.5 0.76 5 05/15/15 10:58 05/17/15 06:19 7439-96-5 Molybdenum ND mg/kg 3.1 1.5 5 05/15/15 10:58 05/17/15 06:19 7439-98-7 Nickel 1.2J mg/kg 1.5 0.76 5 05/15/15 10:58 05/17/15 06:19 7440-02-0 Potassium ND mg/kg 306 153 5 05/15/15 10:58 05/17/15 06:19 7440-09-7 Sodium ND mg/kg 306 153 5 05/15/15 10:58 05/17/15 06:19 7440-23-5 Strontium ND mg/kg 3.1 1.5 5 05/15/15 10:58 05/17/15 06:19 7440-24-6 Zinc ND mg/kg 6.1 3.1 5 05/15/15 10:58 05/17/15 06:19 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:56 7440-36-0 N2 Arsenic ND mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:56 7440-38-2 Cadmium ND mg/kg 0.73 0.37 100 05/15/15 10:58 05/16/1516:56 7440-43-9 Cobalt ND mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:56 7440-48-4 Lead ND mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:56 7439-92-1 Selenium ND mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:56 7782-49-2 Thallium ND mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:56 7440-28-0 Vanadium 7.9 mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:56 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0096 0.0048 1 05/15/1511:16 05/15/1517:19 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.6 % 0.10 0.10 1 05/20/15 10:34 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 0.10 1 05/11/15 11:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 312 156 5 05/10/15 20:09 16887-00-6 Sulfate ND mg/kg 312 156 5 05/10/15 20:09 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.2 15.6 5 05/10/15 20:09 14797-55-8 D3,H3 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013474 Lab ID: 92248767002 Collected: 04/29/15 13:00 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1010 mg/kg 753 376 1 05/27/15 19:01 7440-44-0 Total Organic Carbon 1080 mg/kg 762 381 1 05/27/15 19:08 7440-44-0 Total Organic Carbon 1040 mg/kg 760 380 1 05/27/15 19:14 7440-44-0 Total Organic Carbon 1040 mg/kg 751 376 1 05/27/15 19:20 7440-44-0 Mean Total Organic Carbon 1050 mg/kg 757 378 1 05/27/15 19:01 7440-44-0 Surrogates RSD% 2.7 % 1 05/27/15 19:01 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013475 Lab ID: 92248767003 Collected: 04/29/15 13:40 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/23/2015 02:03 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 4040 mg/kg 30.6 15.3 5 05/15/15 10:58 05/17/15 06:24 7429-90-5 21.7 mg/kg 3.1 1.5 5 05/15/15 10:58 05/17/15 06:24 7440-39-3 0.70 mg/kg 0.31 0.15 5 05/15/15 10:58 05/17/15 06:24 7440-41-7 ND mg/kg 15.3 7.7 5 05/15/15 10:58 05/17/15 06:24 7440-42-8 853 mg/kg 153 76.6 5 05/15/15 10:58 05/17/15 06:24 7440-70-2 4.3 mg/kg 1.5 0.77 5 05/15/15 10:58 05/17/15 06:24 7440-47-3 10.9 mg/kg 1.5 0.77 5 05/15/15 10:58 05/17/15 06:24 7440-50-8 3550 mg/kg 12.3 6.1 5 05/15/15 10:58 05/17/15 06:24 7439-89-6 1060 mg/kg 153 76.6 5 05/15/15 10:58 05/17/15 06:24 7439-95-4 35.1 mg/kg 1.5 0.77 5 05/15/15 10:58 05/17/15 06:24 7439-96-5 ND mg/kg 3.1 1.5 5 05/15/15 10:58 05/17/15 06:24 7439-98-7 11.6 mg/kg 1.5 0.77 5 05/15/15 10:58 05/17/15 06:24 7440-02-0 691 mg/kg 306 153 5 05/15/15 10:58 05/17/15 06:24 7440-09-7 ND mg/kg 306 153 5 05/15/15 10:58 05/17/15 06:24 7440-23-5 7.2 mg/kg 3.1 1.5 5 05/15/15 10:58 05/17/15 06:24 7440-24-6 14.9 mg/kg 6.1 3.1 5 05/15/15 10:58 05/17/15 06:24 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:59 7440-36-0 4AJ mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:59 7440-38-2 ND mg/kg 0.74 0.37 100 05/15/15 10:58 05/16/1516:59 7440-43-9 20.3 mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:59 7440-48-4 11.5 mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:59 7439-92-1 4.2J mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:59 7782-49-2 ND mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:59 7440-28-0 20.0 mg/kg 6.1 3.1 100 05/15/15 10:58 05/16/1516:59 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.0062J mg/kg 0.0096 0.0048 1 05/15/1511:16 05/15/1517:21 7439-97-6 Analytical Method: ASTM D2974-87 16.5 % 0.10 0.10 1 05/20/1510:34 Analytical Method: EPA 9045 4.9 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 293 146 5 ND mg/kg 293 146 5 Analytical Method: EPA 9056 ND mg/kg 29.3 14.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 05/10/15 20:31 16887-00-6 05/10/15 20:31 14808-79-8 N2 05/10/15 20:31 14797-55-8 D3,H3 Page 27 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013475 Lab ID: 92248767003 Collected: 04/29/15 13:40 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1260 mg/kg 719 360 1 06/18/15 17:55 7440-44-0 Total Organic Carbon 1300 mg/kg 721 361 1 06/18/15 18:02 7440-44-0 Total Organic Carbon 1400 mg/kg 721 360 1 06/18/15 18:08 7440-44-0 Total Organic Carbon 1530 mg/kg 725 363 1 06/18/15 18:13 7440-44-0 Mean Total Organic Carbon 1370 mg/kg 722 361 1 06/18/15 17:55 7440-44-0 H3 Surrogates RSD% 8.6 % 1 06/18/15 17:55 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013476 Lab ID: 92248767004 Collected: 05/03/15 13:20 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/23/2015 02:03 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6710 mg/kg 39.7 19.9 5 05/15/15 10:58 05/17/15 06:28 7429-90-5 56.0 mg/kg 4.0 2.0 5 05/15/15 10:58 05/17/15 06:28 7440-39-3 0.43 mg/kg 0.40 0.20 5 05/15/15 10:58 05/17/15 06:28 7440-41-7 ND mg/kg 19.9 9.9 5 05/15/15 10:58 05/17/15 06:28 7440-42-8 ND mg/kg 199 99.3 5 05/15/15 10:58 05/17/15 06:28 7440-70-2 7.1 mg/kg 2.0 0.99 5 05/15/15 10:58 05/17/15 06:28 7440-47-3 2.1 mg/kg 2.0 0.99 5 05/15/15 10:58 05/17/15 06:28 7440-50-8 3360 mg/kg 15.9 7.9 5 05/15/15 10:58 05/17/15 06:28 7439-89-6 257 mg/kg 199 99.3 5 05/15/15 10:58 05/17/15 06:28 7439-95-4 7.5 mg/kg 2.0 0.99 5 05/15/15 10:58 05/17/15 06:28 7439-96-5 ND mg/kg 4.0 2.0 5 05/15/15 10:58 05/17/15 06:28 7439-98-7 1.6J mg/kg 2.0 0.99 5 05/15/15 10:58 05/17/15 06:28 7440-02-0 ND mg/kg 397 199 5 05/15/15 10:58 05/17/15 06:28 7440-09-7 ND mg/kg 397 199 5 05/15/15 10:58 05/17/15 06:28 7440-23-5 3.OJ mg/kg 4.0 2.0 5 05/15/15 10:58 05/17/15 06:28 7440-24-6 4AJ mg/kg 7.9 4.0 5 05/15/15 10:58 05/17/15 06:28 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 7.9 4.0 100 05/15/15 10:58 05/16/1517:02 7440-36-0 ND mg/kg 7.9 4.0 100 05/15/15 10:58 05/16/1517:02 7440-38-2 ND mg/kg 0.95 0.48 100 05/15/15 10:58 05/16/1517:02 7440-43-9 ND mg/kg 7.9 4.0 100 05/15/15 10:58 05/16/1517:02 7440-48-4 10.6 mg/kg 7.9 4.0 100 05/15/15 10:58 05/16/1517:02 7439-92-1 ND mg/kg 7.9 4.0 100 05/15/15 10:58 05/16/1517:02 7782-49-2 ND mg/kg 7.9 4.0 100 05/15/15 10:58 05/16/1517:02 7440-28-0 30.7 mg/kg 7.9 4.0 100 05/15/15 10:58 05/16/1517:02 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.015 mg/kg 0.013 0.0065 1 05/15/1511:16 05/15/1517:24 7439-97-6 Analytical Method: ASTM D2974-87 36.0 % 0.10 0.10 1 05/20/1510:34 Analytical Method: EPA 9045 4.9 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 385 193 5 ND mg/kg 385 193 5 Analytical Method: EPA 9056 ND mg/kg 38.5 19.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 05/10/15 20:52 16887-00-6 05/10/15 20:52 14808-79-8 N2 05/10/15 20:52 14797-55-8 D3,H3 Page 29 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1in�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013476 Lab ID: 92248767004 Collected: 05/03/15 13:20 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 8590 mg/kg 935 468 1 06/18/15 18:19 7440-44-0 Total Organic Carbon 8100 mg/kg 937 469 1 06/18/15 18:24 7440-44-0 Total Organic Carbon 9370 mg/kg 941 470 1 06/18/15 18:30 7440-44-0 Total Organic Carbon 7420 mg/kg 940 470 1 06/18/15 18:36 7440-44-0 Mean Total Organic Carbon 8370 mg/kg 938 469 1 06/18/15 18:19 7440-44-0 H3 Surrogates RSD% 9.8 % 1 06/18/15 18:19 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013477 Lab ID: 92248767005 Collected: 05/03/15 13:30 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/23/2015 02:03 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 5080 mg/kg 34.9 17.4 5 05/15/15 10:58 05/17/15 06:32 7429-90-5 41.8 mg/kg 3.5 1.7 5 05/15/15 10:58 05/17/15 06:32 7440-39-3 0.30J mg/kg 0.35 0.17 5 05/15/15 10:58 05/17/15 06:32 7440-41-7 ND mg/kg 17.4 8.7 5 05/15/15 10:58 05/17/15 06:32 7440-42-8 106J mg/kg 174 87.2 5 05/15/15 10:58 05/17/15 06:32 7440-70-2 5.8 mg/kg 1.7 0.87 5 05/15/15 10:58 05/17/15 06:32 7440-47-3 2.3 mg/kg 1.7 0.87 5 05/15/15 10:58 05/17/15 06:32 7440-50-8 1820 mg/kg 13.9 7.0 5 05/15/15 10:58 05/17/15 06:32 7439-89-6 216 mg/kg 174 87.2 5 05/15/15 10:58 05/17/15 06:32 7439-95-4 4.9 mg/kg 1.7 0.87 5 05/15/15 10:58 05/17/15 06:32 7439-96-5 ND mg/kg 3.5 1.7 5 05/15/15 10:58 05/17/15 06:32 7439-98-7 1.4J mg/kg 1.7 0.87 5 05/15/15 10:58 05/17/15 06:32 7440-02-0 ND mg/kg 349 174 5 05/15/15 10:58 05/17/15 06:32 7440-09-7 ND mg/kg 349 174 5 05/15/15 10:58 05/17/15 06:32 7440-23-5 3.5 mg/kg 3.5 1.7 5 05/15/15 10:58 05/17/15 06:32 7440-24-6 ND mg/kg 7.0 3.5 5 05/15/15 10:58 05/17/15 06:32 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 7.0 3.5 100 05/15/15 10:58 05/16/1517:13 7440-36-0 ND mg/kg 7.0 3.5 100 05/15/15 10:58 05/16/1517:13 7440-38-2 ND mg/kg 0.84 0.42 100 05/15/15 10:58 05/16/1517:13 7440-43-9 ND mg/kg 7.0 3.5 100 05/15/15 10:58 05/16/1517:13 7440-48-4 6.2J mg/kg 7.0 3.5 100 05/15/15 10:58 05/16/1517:13 7439-92-1 ND mg/kg 7.0 3.5 100 05/15/15 10:58 05/16/1517:13 7782-49-2 ND mg/kg 7.0 3.5 100 05/15/15 10:58 05/16/1517:13 7440-28-0 21.8 mg/kg 7.0 3.5 100 05/15/15 10:58 05/16/1517:13 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.020 mg/kg 0.011 0.0056 1 05/15/1511:16 05/15/1517:26 7439-97-6 Analytical Method: ASTM D2974-87 30.6 % 0.10 0.10 1 05/20/1510:34 Analytical Method: EPA 9045 4.8 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 356 178 5 ND mg/kg 356 178 5 Analytical Method: EPA 9056 ND mg/kg 35.6 17.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [t'1.' 11 f oaf 6' i D191f, 05/10/15 21:13 16887-00-6 05/10/15 21:13 14808-79-8 N2 05/10/15 21:13 14797-55-8 D3,H3 Page 31 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%Y6.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013477 Lab ID: 92248767005 Collected: 05/03/15 13:30 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 4820 mg/kg 870 435 1 06/18/15 18:42 7440-44-0 Total Organic Carbon 3480 mg/kg 867 434 1 06/18/15 18:48 7440-44-0 Total Organic Carbon 3750 mg/kg 865 432 1 06/18/15 18:54 7440-44-0 Total Organic Carbon 4320 mg/kg 859 429 1 06/18/15 18:59 7440-44-0 Mean Total Organic Carbon 4090 mg/kg 865 433 1 06/18/15 18:42 7440-44-0 H3 Surrogates RSD% 14.7 % 1 06/18/15 18:42 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013478 Lab ID: 92248767006 Collected: 05/03/15 14:15 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/23/2015 02:03 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 817 mg/kg 30.0 15.0 5 05/15/15 10:58 05/17/15 06:36 7429-90-5 7.0 mg/kg 3.0 1.5 5 05/15/15 10:58 05/17/15 06:36 7440-39-3 0.49 mg/kg 0.30 0.15 5 05/15/15 10:58 05/17/15 06:36 7440-41-7 28.2 mg/kg 15.0 7.5 5 05/15/15 10:58 05/17/15 06:36 7440-42-8 555 mg/kg 150 75.0 5 05/15/15 10:58 05/17/15 06:36 7440-70-2 5.1 mg/kg 1.5 0.75 5 05/15/15 10:58 05/17/15 06:36 7440-47-3 215 mg/kg 1.5 0.75 5 05/15/15 10:58 05/17/15 06:36 7440-50-8 30600 mg/kg 12.0 6.0 5 05/15/15 10:58 05/17/15 06:36 7439-89-6 462 mg/kg 150 75.0 5 05/15/15 10:58 05/17/15 06:36 7439-95-4 260 mg/kg 1.5 0.75 5 05/15/15 10:58 05/17/15 06:36 7439-96-5 ND mg/kg 3.0 1.5 5 05/15/15 10:58 05/17/15 06:36 7439-98-7 14.1 mg/kg 1.5 0.75 5 05/15/15 10:58 05/17/15 06:36 7440-02-0 ND mg/kg 300 150 5 05/15/15 10:58 05/17/15 06:36 7440-09-7 ND mg/kg 300 150 5 05/15/15 10:58 05/17/15 06:36 7440-23-5 2.2J mg/kg 3.0 1.5 5 05/15/15 10:58 05/17/15 06:36 7440-24-6 566 mg/kg 6.0 3.0 5 05/15/15 10:58 05/17/15 06:36 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1517:15 7440-36-0 8.5 mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1517:15 7440-38-2 1.2 mg/kg 0.72 0.36 100 05/15/15 10:58 05/16/1517:15 7440-43-9 47.9 mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1517:15 7440-48-4 7.6 mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1517:15 7439-92-1 ND mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1517:15 7782-49-2 ND mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1517:15 7440-28-0 32.8 mg/kg 6.0 3.0 100 05/15/15 10:58 05/16/1517:15 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.054 mg/kg 0.0096 0.0048 1 05/15/1511:16 05/15/1517:28 7439-97-6 Analytical Method: ASTM D2974-87 16.8 % 0.10 0.10 1 05/20/1510:34 Analytical Method: EPA 9045 3.8 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 295 147 5 ND mg/kg 295 147 5 Analytical Method: EPA 9056 ND mg/kg 29.5 14.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [t'1.' 11 f oaf 6' i D191f, 05/10/15 21:35 16887-00-6 05/10/15 21:35 14808-79-8 N2 05/10/15 21:35 14797-55-8 D3,H3 Page 33 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013478 Lab ID: 92248767006 Collected: 05/03/15 14:15 Received: 05/06/15 17:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 716J mg/kg 721 360 1 05/29/15 09:57 7440-44-0 Total Organic Carbon 726 mg/kg 716 358 1 05/29/15 10:03 7440-44-0 Total Organic Carbon 736 mg/kg 715 358 1 05/29/15 10:09 7440-44-0 Total Organic Carbon 771 mg/kg 722 361 1 05/29/15 10:15 7440-44-0 Mean Total Organic Carbon 737 mg/kg 719 359 1 05/29/15 09:57 7440-44-0 Surrogates RSD% 3.2 % 1 05/29/15 09:57 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013486 Lab ID: 92248767007 Collected: 04/29/15 11:30 Received: 05/06/15 17:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/23/2015 02:03 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 4.3J ug/L 10.0 3.0 1 05/14/1510:57 05/14/1514:33 7429-90-5 0.16J ug/L 0.50 0.15 1 05/14/1510:57 05/14/1514:33 7440-36-0 ND ug/L 0.50 0.11 1 05/14/1510:57 05/14/1514:33 7440-38-2 0.21J ug/L 0.30 0.081 1 05/14/1510:57 05/14/1514:33 7440-39-3 ND ug/L 0.20 0.067 1 05/14/1510:57 05/14/1514:33 7440-41-7 ND ug/L 5.0 1.1 1 05/14/1510:57 05/14/1514:33 7440-42-8 ND ug/L 0.080 0.024 1 05/14/1510:57 05/14/1514:33 7440-43-9 68.0 ug/L 40.0 16.0 1 05/14/1510:57 05/14/1514:33 7440-70-2 ND ug/L 0.50 0.17 1 05/14/1510:57 05/14/1514:33 7440-47-3 ND ug/L 0.50 0.13 1 05/14/1510:57 05/14/1514:33 7440-48-4 ND ug/L 1.0 0.21 1 05/14/1510:57 05/14/1514:33 7440-50-8 ND ug/L 50.0 13.7 1 05/14/1510:57 05/14/1514:33 7439-89-6 ND ug/L 0.10 0.046 1 05/14/1510:57 05/14/1514:33 7439-92-1 16.1 ug/L 10.0 3.2 1 05/14/1510:57 05/14/1514:33 7439-95-4 0.44J ug/L 0.50 0.24 1 05/14/1510:57 05/14/1514:33 7439-96-5 ND ug/L 0.50 0.094 1 05/14/1510:57 05/14/1514:33 7439-98-7 0.191 ug/L 0.50 0.16 1 05/14/1510:57 05/14/1514:33 7440-02-0 18.6J ug/L 50.0 11.7 1 05/14/1510:57 05/14/1514:33 7440-09-7 ND ug/L 0.50 0.20 1 05/14/1510:57 05/14/1514:33 7782-49-2 87.0 ug/L 50.0 16.3 1 05/14/1510:57 05/14/1514:33 7440-23-5 0.32J ug/L 0.50 0.13 1 05/14/1510:57 05/14/1514:33 7440-24-6 ND ug/L 0.10 0.015 1 05/14/1510:57 05/14/1514:33 7440-28-0 ND ug/L 1.0 0.28 1 05/14/1510:57 05/14/1514:33 7440-62-2 ND ug/L 5.0 2.4 1 05/14/1510:57 05/14/1514:33 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.024J ug/L 0.20 0.022 1 05/11/1512:15 05/12/1519:59 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050103 Pace Project No.: 92248767 Sample: 2015013487 Lab ID: 92248767008 Collected: 05/03/15 11:31 Received: 05/06/15 17:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/23/2015 02:03 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 7.3J ug/L 10.0 3.0 1 05/14/1510:57 05/14/1514:36 7429-90-5 ND ug/L 0.50 0.15 1 05/14/1510:57 05/14/1514:36 7440-36-0 ND ug/L 0.50 0.11 1 05/14/1510:57 05/14/1514:36 7440-38-2 0.11J ug/L 0.30 0.081 1 05/14/1510:57 05/14/1514:36 7440-39-3 ND ug/L 0.20 0.067 1 05/14/1510:57 05/14/1514:36 7440-41-7 ND ug/L 5.0 1.1 1 05/14/1510:57 05/14/1514:36 7440-42-8 ND ug/L 0.080 0.024 1 05/14/1510:57 05/14/1514:36 7440-43-9 43.4 ug/L 40.0 16.0 1 05/14/1510:57 05/14/1514:36 7440-70-2 ND ug/L 0.50 0.17 1 05/14/1510:57 05/14/1514:36 7440-47-3 ND ug/L 0.50 0.13 1 05/14/1510:57 05/14/1514:36 7440-48-4 ND ug/L 1.0 0.21 1 05/14/1510:57 05/14/1514:36 7440-50-8 ND ug/L 50.0 13.7 1 05/14/1510:57 05/14/1514:36 7439-89-6 ND ug/L 0.10 0.046 1 05/14/1510:57 05/14/1514:36 7439-92-1 12.2 ug/L 10.0 3.2 1 05/14/1510:57 05/14/1514:36 7439-95-4 0.42J ug/L 0.50 0.24 1 05/14/1510:57 05/14/1514:36 7439-96-5 ND ug/L 0.50 0.094 1 05/14/1510:57 05/14/1514:36 7439-98-7 ND ug/L 0.50 0.16 1 05/14/1510:57 05/14/1514:36 7440-02-0 12.9J ug/L 50.0 11.7 1 05/14/1510:57 05/14/1514:36 7440-09-7 ND ug/L 0.50 0.20 1 05/14/1510:57 05/14/1514:36 7782-49-2 51.5 ug/L 50.0 16.3 1 05/14/1510:57 05/14/1514:36 7440-23-5 0.21J ug/L 0.50 0.13 1 05/14/1510:57 05/14/1514:36 7440-24-6 ND ug/L 0.10 0.015 1 05/14/1510:57 05/14/1514:36 7440-28-0 ND ug/L 1.0 0.28 1 05/14/1510:57 05/14/1514:36 7440-62-2 ND ug/L 5.0 2.4 1 05/14/1510:57 05/14/1514:36 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.037J ug/L 0.20 0.022 1 05/11/15 12:15 05/12/15 20:02 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: MERP/13477 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92248767007, 92248767008 METHOD BLANK: 1960289 Matrix: Water Associated Lab Samples: 92248767007, 92248767008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/12/1519:55 LABORATORY CONTROL SAMPLE: 1960290 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.5 110 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1961286 1961287 MS MSD 92248767008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L 0.037J 5 5 5.6 5.3 112 106 80-120 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8Y6e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: MERP/5713 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 METHOD BLANK: 1212857 Matrix: Solid Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 05/15/1516:49 LABORATORY CONTROL SAMPLE: 1212858 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.077 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1212859 1212860 MS MSD 92248729001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .078 .081 0.073 0.077 95 96 80-120 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iji g8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: MPRP/24119 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 METHOD BLANK: 1212833 Matrix: Solid Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg ND 5.1 05/17/15 04:53 Barium mg/kg ND 0.51 05/17/15 04:53 Beryllium mg/kg ND 0.051 05/17/15 04:53 Boron mg/kg ND 2.6 05/17/15 04:53 Calcium mg/kg ND 25.6 05/17/15 04:53 Chromium mg/kg ND 0.26 05/17/15 04:53 Copper mg/kg ND 0.26 05/17/15 04:53 Iron mg/kg ND 2.0 05/17/15 04:53 Magnesium mg/kg ND 25.6 05/17/15 04:53 Manganese mg/kg ND 0.26 05/17/15 04:53 Molybdenum mg/kg ND 0.51 05/17/15 04:53 Nickel mg/kg ND 0.26 05/17/15 04:53 Potassium mg/kg ND 51.2 05/17/15 04:53 Sodium mg/kg ND 51.2 05/17/15 04:53 Strontium mg/kg ND 0.51 05/17/15 04:53 Zinc mg/kg ND 1.0 05/17/15 04:53 LABORATORY CONTROL SAMPLE: Parameter 1212834 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 128 126 98 80-120 Barium mg/kg 12.8 13.3 104 80-120 Beryllium mg/kg 1.3 1.3 100 80-120 Boron mg/kg 128 125 98 80-120 Calcium mg/kg 638 632 99 80-120 Chromium mg/kg 12.8 13.0 102 80-120 Copper mg/kg 12.8 12.3 96 80-120 Iron mg/kg 128 118 92 80-120 Magnesium mg/kg 638 626 98 80-120 Manganese mg/kg 12.8 12.5 98 80-120 Molybdenum mg/kg 12.8 13.0 102 80-120 Nickel mg/kg 12.8 13.2 104 80-120 Potassium mg/kg 638 607 95 80-120 Sodium mg/kg 638 639 100 80-120 Strontium mg/kg 12.8 12.6 99 80-120 Zinc mg/kg 63.8 64.9 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j n� c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1212835 1212836 MS MSD 92248729001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 5670 125 124 5210 5760 -368 72 75-125 10 20 M1 Barium mg/kg 82.8 12.5 12.4 73.1 78.8 -78 -33 75-125 7 20 M1 Beryllium mg/kg ND 1.2 1.2 1.4 1.3 110 102 75-125 7 20 Boron mg/kg 9.7J 125 124 141 132 106 98 75-125 7 20 Calcium mg/kg 3920 624 620 5060 5590 182 269 75-125 10 20 M1 Chromium mg/kg ND 12.5 12.4 13.4 12.5 106 99 75-125 7 20 Copper mg/kg 32.6 12.5 12.4 35.1 36.3 20 30 75-125 3 20 M1 Iron mg/kg 10600 125 124 10000 11100 -487 401 75-125 10 20 M1 Magnesium mg/kg 4060 624 620 4130 4490 10 69 75-125 8 20 M1 Manganese mg/kg 68.1 12.5 12.4 82.5 77.5 115 76 75-125 6 20 Molybdenum mg/kg ND 12.5 12.4 12.6 11.9 101 96 75-125 6 20 Nickel mg/kg 2.1 12.5 12.4 14.9 14.2 103 98 75-125 5 20 Potassium mg/kg 2090 624 620 2430 2670 55 94 75-125 9 20 M1 Sodium mg/kg ND 624 620 740 698 106 100 75-125 6 20 Strontium mg/kg 12.6 12.5 12.4 24.8 24.9 98 99 75-125 0 20 Zinc mg/kg 21.0 62.4 62 84.1 81.0 101 97 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I Qgigy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: MPRP/24120 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 METHOD BLANK: 1212837 Matrix: Solid Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 05/16/1516:16 N2 Arsenic mg/kg ND 0.051 05/16/1516:16 Cadmium mg/kg ND 0.0061 05/16/1516:16 Cobalt mg/kg ND 0.051 05/16/1516:16 Lead mg/kg ND 0.051 05/16/1516:16 Selenium mg/kg ND 0.051 05/16/1516:16 Thallium mg/kg ND 0.051 05/16/1516:16 Vanadium mg/kg ND 0.051 05/16/1516:16 LABORATORY CONTROL SAMPLE: 1212838 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.6 2.7 103 80-120 N2 Arsenic mg/kg 2.6 2.7 102 80-120 Cadmium mg/kg .26 0.25 95 80-120 Cobalt mg/kg 2.6 2.7 103 80-120 Lead mg/kg 2.6 2.6 100 80-120 Selenium mg/kg 2.6 2.6 98 80-120 Thallium mg/kg 2.6 2.6 101 80-120 Vanadium mg/kg 2.6 2.6 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1212839 1212840 MS MSD 92248729001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.4 2.6 ND ND 80 66 75-125 20 M6, N2 Arsenic mg/kg ND 2.4 2.6 3.5J 3.6J 87 85 75-125 20 Cadmium mg/kg ND .24 .26 0.31J ND 105 87 75-125 20 Cobalt mg/kg 6.9 2.4 2.6 12.5 10.7 230 144 75-125 15 20 M6 Lead mg/kg ND 2.4 2.6 3.OJ 3.3J 88 93 75-125 20 Selenium mg/kg ND 2.4 2.6 2.7J 3.2J 63 78 75-125 20 M6 Thallium mg/kg ND 2.4 2.6 2.7J 2.7J 92 88 75-125 20 Vanadium mg/kg 31.3 2.4 2.6 37.8 35.0 269 144 75-125 7 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I Sgigy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: MPRP/54390 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92248767007, 92248767008 METHOD BLANK: 1965247 Associated Lab Samples: 92248767007, 92248767008 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.30 05/14/1514:25 ND 0.20 05/14/1514:25 ND 5.0 05/14/1514:25 ND 0.080 05/14/1514:25 ND 40.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.50 05/14/1514:25 ND 1.0 05/14/1514:25 ND 50.0 05/14/1514:25 ND 0.10 05/14/1514:25 ND 10.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.50 05/14/1514:25 ND 50.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 50.0 05/14/1514:25 ND 0.50 05/14/1514:25 ND 0.10 05/14/1514:25 ND 1.0 05/14/1514:25 ND 5.0 05/14/1514:25 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1965248 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 81.3 102 80-120 Antimony ug/L 80 76.5 96 80-120 Arsenic ug/L 80 81.4 102 80-120 Barium ug/L 80 87.9 110 80-120 Beryllium ug/L 80 80.9 101 80-120 Boron ug/L 80 83.6 105 80-120 Cadmium ug/L 80 84.3 105 80-120 Calcium ug/L 1000 1010 101 80-120 Chromium ug/L 80 83.1 104 80-120 Cobalt ug/L 80 87.0 109 80-120 Copper ug/L 80 85.1 106 80-120 Iron ug/L 1000 1100 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 LABORATORY CONTROL SAMPLE: 1965248 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 89.3 112 80-120 Magnesium ug/L 1000 986 99 80-120 Manganese ug/L 80 81.3 102 80-120 Molybdenum ug/L 80 82.6 103 80-120 Nickel ug/L 80 82.1 103 80-120 Potassium ug/L 1000 974 97 80-120 Selenium ug/L 80 85.6 107 80-120 Sodium ug/L 1000 1060 106 80-120 Strontium ug/L 80 79.7 100 80-120 Thallium ug/L 80 89.2 112 80-120 Vanadium ug/L 80 80.3 100 80-120 Zinc ug/L 80 85.3 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1965451 1965452 MS MSD 92248767008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 7.3J 80 80 91.5 85.4 105 98 75-125 7 20 Antimony ug/L ND 80 80 77.2 77.8 96 97 75-125 1 20 Arsenic ug/L ND 80 80 83.0 83.5 104 104 75-125 1 20 Barium ug/L 0.111 80 80 81.0 81.7 101 102 75-125 1 20 Beryllium ug/L ND 80 80 82.2 82.2 103 103 75-125 0 20 Boron ug/L ND 80 80 85.2 85.1 106 106 75-125 0 20 Cadmium ug/L ND 80 80 87.2 86.7 109 108 75-125 1 20 Calcium ug/L 43.4 1000 1000 1030 1020 99 98 75-125 1 20 Chromium ug/L ND 80 80 82.0 80.1 102 100 75-125 2 20 Cobalt ug/L ND 80 80 80.5 79.7 101 100 75-125 1 20 Copper ug/L ND 80 80 85.2 85.0 106 106 75-125 0 20 Iron ug/L ND 1000 1000 1110 1070 110 106 75-125 4 20 Lead ug/L ND 80 80 87.3 86.2 109 108 75-125 1 20 Magnesium ug/L 12.2 1000 1000 994 978 98 97 75-125 2 20 Manganese ug/L 0.42J 80 80 79.4 77.4 99 96 75-125 2 20 Molybdenum ug/L ND 80 80 84.5 85.8 106 107 75-125 2 20 Nickel ug/L ND 80 80 82.7 81.6 103 102 75-125 1 20 Potassium ug/L 12.9J 1000 1000 944 922 93 91 75-125 2 20 Selenium ug/L ND 80 80 85.7 83.9 107 105 75-125 2 20 Sodium ug/L 51.5 1000 1000 1030 1000 97 95 75-125 2 20 Strontium ug/L 0.21J 80 80 82.3 84.0 103 105 75-125 2 20 Thallium ug/L ND 80 80 89.9 89.6 112 112 75-125 0 20 Vanadium ug/L ND 80 80 79.4 78.8 99 98 75-125 1 20 Zinc ug/L ND 80 80 85.2 85.4 105 105 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: PMST/3581 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 SAMPLE DUPLICATE: 1218747 92248767001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 17.1 19.4 12 10 D6 SAMPLE DUPLICATE: 1218748 92249477001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 10.9 10.5 4 10 SAMPLE DUPLICATE: 1218749 92249077002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 25.4 24.9 2 10 SAMPLE DUPLICATE: 1218750 92249681005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 31.1 30.5 2 10 SAMPLE DUPLICATE: 1218751 92249710007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 29.6 28.1 5 10 SAMPLE DUPLICATE: 1218752 92249710016 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.3 4.8 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijigc&y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: WET/30928 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92248767003, 92248767004 SAMPLE DUPLICATE: 1218793 35188827002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.5 6.5 0 20 H6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iji g8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: WET/37363 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92248767001, 92248767002 SAMPLE DUPLICATE: 1455163 92248424010 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 6.6 2 10 D6 SAMPLE DUPLICATE: 1455164 92248773005 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.5 4.9 8 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iji g8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: WET/37381 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92248767005, 92248767006 SAMPLE DUPLICATE: 1455884 92248424014 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.7 6.7 0 10 H3 SAMPLE DUPLICATE: 1455885 Parameter pH at 25 Degrees C 92248767006 Dup Units Result Result Std. Units 3.8 3.8 Max RPD RPD Qualifiers 0 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iji g8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: WETA/46254 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 METHOD BLANK: 1209278 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.0 05/10/1513:44 Sulfate mg/kg ND 50.0 05/10/1513:44 LABORATORY CONTROL SAMPLE: 1209279 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1209281 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1209280 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 495 481 97 80-120 495 477 96 80-120 92248731001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 594 547 73 80-120 M 1 ND 594 610 82 80-120 92248731001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 D3 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: WETA/46253 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92248767001, 92248767002, 92248767003, 92248767004, 92248767005, 92248767006 METHOD BLANK: 1209274 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 05/10/15 13:44 LABORATORY CONTROL SAMPLE: 1209275 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.5 48.1 97 80-120 MATRIX SPIKE SAMPLE: 1209277 92248731001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 59.4 52.3 87 80-120 H3 SAMPLE DUPLICATE: 1209276 92248731001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1�nlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: WETA/28615 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92248767002 METHOD BLANK: 1161523 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/27/15 09:26 LABORATORY CONTROL SAMPLE: 1161524 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 113000 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1163039 1163040 MS MSD 92248416006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 538J 7990 7950 7880 8620 92 102 50-150 9 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1163043 1163044 MS MSD 92247835018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 475J 7280 7290 7100 7080 91 91 50-150 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: WETA/28618 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92248767006 METHOD BLANK: 1161557 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/29/15 07:56 LABORATORY CONTROL SAMPLE: 1161558 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 112000 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161559 1161560 MS MSD 92248735001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 710J 7440 7430 7310 7350 89 89 50-150 0 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161561 1161562 MS MSD 92248767006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 737 7210 7220 7870 7480 99 93 50-150 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050103 Pace Project No.: 92248767 QC Batch: WETA/29062 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92248767001, 92248767003, 92248767004, 92248767005 METHOD BLANK: 1176770 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/18/15 09:06 LABORATORY CONTROL SAMPLE: 1176771 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 110000 91 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1176772 1176773 MS MSD 92248773001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 8860 8830 7560 8130 82 89 50-150 7 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1176774 1176775 MS MSD 92248773002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 7840 7780 6710 7490 83 93 50-150 11 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15050103 Pace Project No.: 92248767 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14775 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: J15050103 92248767 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92248767001 2015013473 EPA 3050 MPRP/24119 EPA 6010 ICP/14775 92248767002 2015013474 EPA 3050 MPRP/24119 EPA 6010 ICP/14775 92248767003 2015013475 EPA 3050 MPRP/24119 EPA 6010 ICP/14775 92248767004 2015013476 EPA 3050 MPRP/24119 EPA 6010 ICP/14775 92248767005 2015013477 EPA 3050 MPRP/24119 EPA 6010 ICP/14775 92248767006 2015013478 EPA 3050 MPRP/24119 EPA6010 ICP/14775 92248767001 2015013473 EPA 3050 MPRP/24120 EPA 6020 ICPM/9797 92248767002 2015013474 EPA 3050 MPRP/24120 EPA 6020 ICPM/9797 92248767003 2015013475 EPA 3050 MPRP/24120 EPA 6020 ICPM/9797 92248767004 2015013476 EPA 3050 MPRP/24120 EPA 6020 ICPM/9797 92248767005 2015013477 EPA 3050 MPRP/24120 EPA 6020 ICPM/9797 92248767006 2015013478 EPA 3050 MPRP/24120 EPA 6020 ICPM/9797 92248767007 2015013486 EPA3020 MPRP/54390 EPA6020A ICPM/24266 92248767008 2015013487 EPA 3020 MPRP/54390 EPA 6020A ICPM/24266 92248767007 2015013486 EPA 7470A MERP/13477 EPA 7470A MERC/15658 92248767008 2015013487 EPA 7470A MERP/13477 EPA 7470A MERC/15658 92248767001 2015013473 EPA 7471 MERP/5713 EPA 7471 MERC/5707 92248767002 2015013474 EPA 7471 MERP/5713 EPA 7471 MERC/5707 92248767003 2015013475 EPA 7471 MERP/5713 EPA 7471 MERC/5707 92248767004 2015013476 EPA 7471 MERP/5713 EPA 7471 MERC/5707 92248767005 2015013477 EPA 7471 MERP/5713 EPA 7471 MERC/5707 92248767006 2015013478 EPA 7471 MERP/5713 EPA 7471 MERC/5707 92248767001 2015013473 ASTM D2974-87 PMST/3581 92248767002 2015013474 ASTM D2974-87 PMST/3581 92248767003 2015013475 ASTM D2974-87 PMST/3581 92248767004 2015013476 ASTM D2974-87 PMST/3581 92248767005 2015013477 ASTM D2974-87 PMST/3581 92248767006 2015013478 ASTM D2974-87 PMST/3581 92248767001 2015013473 EPA 9045 WET/37363 92248767002 2015013474 EPA 9045 WET/37363 92248767003 2015013475 EPA 9045 WET/30928 92248767004 2015013476 EPA 9045 WET/30928 92248767005 2015013477 EPA 9045 WET/37381 92248767006 2015013478 EPA 9045 WET/37381 92248767001 2015013473 EPA 9056 WETA/46254 92248767002 2015013474 EPA 9056 WETA/46254 92248767003 2015013475 EPA 9056 WETA/46254 92248767004 2015013476 EPA 9056 WETA/46254 92248767005 2015013477 EPA 9056 WETA/46254 92248767006 2015013478 EPA 9056 WETA/46254 92248767001 2015013473 EPA 9056 WETA/46253 92248767002 2015013474 EPA 9056 WETA/46253 92248767003 2015013475 EPA 9056 WETA/46253 92248767004 2015013476 EPA 9056 WETA/46253 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/23/2015 02:03 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15050103 Pace Project No.: 92248767 Lab ID Sample ID QC Batch Method QC Batch 92248767005 2015013477 EPA 9056 WETA/46253 92248767006 2015013478 EPA 9056 WETA/46253 92248767001 2015013473 EPA 9060 WETA/29062 92248767001 2015013473 EPA 9060 WETA/29063 92248767002 2015013474 EPA 9060 WETA/28615 92248767002 2015013474 EPA 9060 WETA/28616 92248767003 2015013475 EPA 9060 WETA/29062 92248767003 2015013475 EPA 9060 WETA/29063 92248767004 2015013476 EPA 9060 WETA/29062 92248767004 2015013476 EPA 9060 WETA/29063 92248767005 2015013477 EPA 9060 WETA/29062 92248767005 2015013477 EPA 9060 WETA/29063 92248767006 2015013478 EPA 9060 WETA/28618 92248767006 2015013478 EPA 9060 WETA/28721 Date: 06/23/2015 02:03 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 55 of 57 uocument Name: uocument Kevisea: z3eptemuai «. 4v 9t aeeAl7<?!ytlCal' 'Sam le Condition Upon Recei t SCUR Page 1 of 2 Document Number: Issuing Authority: F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Name: 0 Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ C mmercial❑ Pac Other r(}17t1kr 3 �` tt ' �1 Custody Seal on CoolerlBox Present: [❑ yes no Seals intact: ❑ yes ❑ noiifile IMIN ,-3 Packing Material: ❑ Bubble VDp ❑ Bubble Bags L+ None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: Ot Blue None Samples on ice, cooling process has begun Tmmn rnrrar-4inn Fartnr T1401 No Correction ' " •C Biological Tissue is Frozen: Yes No NIAFD- ateand lnii Is fpCorrected Cooler Temp.; 4� contents: Temp should be above freezing to VC Comments: Chain of Custody Present: es ❑No ❑NIA 1. Chain of Custody Filled Out: es EVJO ❑NIA 2. Chain of Custody Relinquished: EIX s ONo ❑NIA 3. Sampler Name & Signature on COC: es ❑No ❑NIA 4. Samples Arrived within Hold Time: es ONo ❑NIA 5. Short Hold Time Analysis (<72hr): OYes 4o El NIA 6. Rush Turn Around Time Requested: Oyes o ❑NIA 7. Sufficient Volume: Wes ❑No 0NlA 8. Correct Containers Used: ❑ es No ❑NIA 9. -Pace Containers Used: Oyes iY1No ❑NIA Containers Intact: es ONo L1NrA 10. Filtered volume received for Dissolved tests Oyes ❑NOIli4 11. Sample Labels match COC: Vey ❑AWL DNIA 12. -Includes dateltimelID1Analysis Matrix; ®>E All containers needing preservation have been checked. es ❑No ❑NiA 13, All containers needing preservation are found to be in es ©No ONIA compliance with EPA recommendation. exceptions: VOA, colifonn, TOC, O&G, VVI-DRO (water) ©Yes ONo Samples checked for dechlorination. Goes ONo ©NIA 14• Headspace in VOA Vials ( >6mm): Oyes ONo ANIA 16. Trip Blank Present: ❑Yes ONo NIA 116. Trip Blank Custody Seals Present Oyes ❑No c iIA Pace Trip Blank Lot # (if purchased): _ Client Notification! Resolution: Field Data Required? Y 1 N Person Contacted: DatelTime: Comments/ Resolution: SCURF Review: f_� date: 5- ( t� SRF Review: Date: ylr Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92248767 68 of 69 a 2 1 3 A 01 � 6 cy K 0 y 3 yin zW ,off➢ i � N aro W 0 r rD 0 3 :1 n C n � Nob n n x Z n N A to Oa m ' cr A o. 0T�6 a a a h n 3 3 ti � � N A m N C C v C Q C 4. � I Customer to Complete appropriate columns to right Customer must Complete + N z C � n 3 a A z o p 55 � Wo t P 0 y m n C ©o c a 3 O m N c C tD N ra 3 O _ N cL m W a n w m n n N p n m a 2. c p N Y7 3 v V N A C1 G z a N n N O d rJ o O a 4 or O � m M 0 k Page 57 of 57 CHAIN CUSTODY I ECORD AND ANALYSIS REQUEST FORM _ _ _ _F Alaalytical Laholl ti rry Servi"s - -i _._,_._.y._._,_,_,. , .-------Anal cal l.,abora�I - Use Only - - - 4i- ®�v4YL SYNTERFA EDD Mull Coda hlGd #A2 iBulPding F4al5l Hagan Fer►y -warty tMear i i ((�h rr�Y h � � J �Y 1] 6 1 Nsorix: SOIL -,- I AT 1 ��— ! DISTRIBUTION �— GYw&13MS Bufflwsvllle, N_ C. ZW73 M I i i �Lopgasl eY GaM 1 Tl SgWlss Prl&,EphG Ffirall i 7 C}F21iI hlRd. t[S LAB, (9001 875.52" 1 � � COPY is CLIENT ier: Y9PJYLRTJe.IidlC � � I +i SAMPLE PROGRAM �03 d Watar NPMS' I1Pridaer Nm■ -- A.li Groundwater Assessment - Sail slPnarraruu: H F Los - � gamut _ JIFas No:�_ AB {'iW E _ IlWusYrsss Milt — - spruisar 10. 71Mall Coda: E pTrpr sli. j Chit YilL[IIVIt?'®: 10INOCO W I L - - has bd and Is nail 4nd'Id;aled Jtiuue ! : 1VAkNi. up*dfle Accou 1itin0 ean o ial wig w uead tl)k PoNowing; t I Enler cwraLA uCC 3U111IY10 1n s 1 . r r 1-1 T,'K' fields pbnv,7. (Dr .21 PI'cwkde GOrraet accounting for a?&Wi • Unit RW 1•'' i LAR USE aNI-Y I _ i "Lab 1 Y 190rl,546fri.1L1,+�Mi ' Sample Desarl ton of IID i Ak k3ill - &0- &W - 0.T—'A' 0 •� - -.v -_ _ 1 L I�� C I0- A Oiv1L4 1 I l I _ 1 i Cwlur Tear f C PO 1142081 1°Prumerv.A-HIZ;_4-` A=Ica 6-FianoF 'C� �.t 4'1 47 4•'A.CtiRA — m aoexarsrlatrr oram, ae 4 ti tB a, < rn Preaermoves when used must he , a d CIL added Wf hin IS lnlnutee Of sample eo i011ecU411M -."iColloCtldrt as .A Lij Illfa•fnt2.tior7 ,i a � c. � 0 Data T1mr. si llatafs r C � �'- flJ' N z (n+°.+ . Ip3 ! 5 Y ' 7 ffir� l 1 1 WATER �QU P"f BLANK (I PER DAY) ��-1 )i 3 H 01wariquishcl by - nsbfffti wr 5: i t� -5 1 , a I k I � -� g ii., rrlslr+lO By _ .-RoWnrsr ...ACe ►i (Arh LallrtyuElha Mlcuimr.'[s Metals: Al. Sb, As, Ba. Be- 13, � ,Anions: CI_ Nitrate-k 504 0o, Cv, Fe, Ph, Mg. Mn, M0, M. K. Be, Na, Sr, fiI, V, nt SBBetFic Palambbars. °}:SUIkiS, CEt., Radicle Size -1115 69 z rr IAsml7lma Uri, arculy, PH huliun_ RQdcx. Putentiial r. 1 REVV HATE ,AVM it*415 —J I -1 - I I I -T- "Requested Tumaround 14 rays -7 Days - 48 w