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NC0003417_J15040615 Report_20150805
+ DUKE Analytical Laboratory 1 of49 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15040615 HF LEE PLANT - AB GW ASSESSMENT SOIL Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer 1677 Old Smithfield Rd Goldsboro NC 27530, Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) u �f2015.06.01 08:38:52 Date: RG 04'00' Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/28/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time 2015011984 2015011985 2015011986 2015011987 4 Total Samples Collected By Sample Description HF LEE PLANT 21-Apr-15 10:01 AM Judd Mahan Well AMW-14-0.5-2.0 HF LEE PLANT 21-Apr-15 10:59 AM Judd Mahan Well AMW-14-4-5 HF LEE PLANT 21-Apr-15 11:15 AM Judd Mahan Well AMW-14-21.5-22.5 HF LEE PLANT 21-Apr-15 9:55 AM Judd Mahan Well Equipment Blank 2 of 49 3 of 49 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040615 Site: Well AMW-14-0.5-2.0 Collection Date: 21-Apr-15 10:01 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 49 Sample #: 2015011984 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040615 Site: Well AMW-14-4-5 Collection Date: 21-Apr-15 10:59 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 49 Sample #: 2015011985 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040615 Site: Well AMW-14-21.5-22.5 Collection Date: 21-Apr-15 11:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 49 Sample #: 2015011986 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis 7of49 This report shall not be reproduced, except in full. Order # J15040615 Site: Well Equipment Blank Collection Date: 21-Apr-15 9:55 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015011987 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&yhe. Suite 100 Huntersville, INC 28078 (704)875-9092 May 15, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15040615 Pace Project No.: 92247054 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 24, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 41 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinfhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040615 Pace Project No.: 92247054 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f i6'8yhe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040615 Pace Project No.: 92247054 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�in� c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15040615 Pace Project No.: 92247054 Lab ID Sample ID Matrix Date Collected Date Received 92247054001 2015011984 Solid 04/21/1510:01 04/24/1512:54 92247054002 2015011985 Solid 04/21/1510:59 04/24/1512:54 92247054003 2015011986 Solid 04121/1511:15 04/24/1512:54 92247054004 2015011987 Water 04/21/15 09:55 04/24/1512:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f iQ'8yhe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15040615 92247054 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92247054001 2015011984 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247054002 2015011985 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247054003 2015011986 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247054004 2015011987 EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J15040615 Pace Project No.: 92247054 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92247054001 2015011984 EPA 6010 Aluminum 2870 mg/kg 25.2 05/05/15 13:56 M1,R1 EPA 6010 Barium 9.2 mg/kg 2.5 05/05/15 13:56 EPA 6010 Beryllium 0.13J mg/kg 0.25 05/05/15 13:56 EPA 6010 Chromium 1.9 mg/kg 1.3 05/05/15 13:56 EPA 6010 Iron 343 mg/kg 10.1 05/05/15 13:56 M1 EPA 6010 Manganese 2.1 mg/kg 1.3 05/05/15 13:56 EPA 6020 Vanadium 4AJ mg/kg 6.3 05/05/15 09:16 M6 ASTM D2974-87 Percent Moisture 23.2 % 0.10 05/05/15 10:23 D6 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 04/28/15 17:30 EPA 9060 Total Organic Carbon 4390 mg/kg 779 05/14/15 10:05 EPA 9060 Total Organic Carbon 6640 mg/kg 780 05/14/15 10:12 EPA 9060 Total Organic Carbon 8620 mg/kg 781 05/14/15 10:18 EPA 9060 Total Organic Carbon 2750 mg/kg 778 05/14/15 10:24 EPA 9060 Mean Total Organic Carbon 5600 mg/kg 780 05/14/15 10:05 EPA 9060 RSD% 45.9 % 05/14/15 10:05 1g 92247054002 2015011985 EPA 6010 Aluminum 1210 mg/kg 27.2 05/05/15 14:08 EPA 6010 Barium 3.5 mg/kg 2.7 05/05/15 14:08 EPA 6010 Chromium 1.2J mg/kg 1.4 05/05/15 14:08 EPA 6010 Iron 269 mg/kg 10.9 05/05/15 14:08 EPA 6010 Manganese 1.5 mg/kg 1.4 05/05/15 14:08 ASTM D2974-87 Percent Moisture 9.2 % 0.10 05/05/15 10:23 EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 04/28/15 17:30 EPA 9060 Total Organic Carbon 1530 mg/kg 655 05/14/15 10:29 EPA 9060 Total Organic Carbon 2130 mg/kg 663 05/14/15 10:35 EPA 9060 Total Organic Carbon 2680 mg/kg 655 05/14/15 10:41 EPA 9060 Total Organic Carbon 1960 mg/kg 661 05/14/15 10:48 EPA 9060 Mean Total Organic Carbon 2080 mg/kg 659 05/14/15 10:29 EPA 9060 RSD% 22.8 % 05/14/15 10:29 92247054003 2015011986 EPA 6010 Aluminum 86.7 mg/kg 32.0 05/05/15 14:37 EPA 6010 Iron 2570 mg/kg 12.8 05/05/15 14:37 EPA 6010 Manganese 1.51 mg/kg 1.6 05/05/15 14:37 EPA 6010 Nickel 1.5J mg/kg 1.6 05/05/15 14:37 EPA 6010 Zinc 12.9 mg/kg 6.4 05/05/15 14:37 EPA 6020 Cobalt 3.3J mg/kg 6.4 05/05/15 09:36 ASTM D2974-87 Percent Moisture 20.6 % 0.10 05/05/15 10:23 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 04/28/15 17:30 EPA 9060 Total Organic Carbon 396J mg/kg 761 05/14/15 11:01 EPA 9060 Total Organic Carbon 443J mg/kg 751 05/14/15 11:06 EPA 9060 Mean Total Organic Carbon 394J mg/kg 754 05/14/15 10:54 EPA 9060 RSD% 8.8 % 05/14/15 10:54 92247054004 2015011987 EPA 6020A Barium 0.54 ug/L 0.30 04/30/15 11:20 EPA 6020A Boron 1.2J ug/L 5.0 04/30/15 11:20 EPA 6020A Calcium 197 ug/L 40.0 04/30/15 11:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040615 Pace Project No.: 92247054 Lab Sample ID Method 92247054004 EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A Client Sample ID Parameters 2015011987 Cobalt Iron Magnesium Manganese Nickel Potassium Sodium Strontium SUMMARY OF DETECTION Result Unit: 0.20J ug/L 38.6J ug/L 54.3 ug/L 2.8 ug/L 0.23J ug/L 35.7J ug/L 345 ug/L 1.0 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 0.50 04/30/1511:20 50.0 04/30/1511:20 10.0 04/30/1511:20 0.50 04/30/1511:20 0.50 04/30/1511:20 50.0 04/30/1511:20 50.0 04/30/1511:20 0.50 04/30/1511:20 Page 7 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 15, 2015 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23928 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247054001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1202030) • Aluminum • Iron • MSD (Lab ID: 1202031) • Aluminum • Iron R1: RPD value was outside control limits. • MSD (Lab ID: 1202031) • Aluminum Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14625 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 15, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23929 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247054001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1202034) • Lead • Selenium • Vanadium • MSD (Lab ID: 1202035) • Cadmium • Lead • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffiic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 15, 2015 Analyte Comments: QC Batch: MPRP/23929 N2: The lab does not hold TNI accreditation for this parameter. •2015011984 (Lab ID:92247054001) • Antimony •2015011985 (Lab ID:92247054002) • Antimony •2015011986 (Lab ID:92247054003) • Antimony • BLANK (Lab ID: 1202032) • Antimony • LCS (Lab ID: 1202033) • Antimony • MS (Lab ID: 1202034) • Antimony • MSD (Lab ID: 1202035) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflig%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 15, 2015 General Information: 1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53983 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247052008 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1950243) • Aluminum • MSD (Lab ID: 1950244) • Aluminum R1: RPD value was outside control limits. • MSD (Lab ID: 1950244) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli ,8yhe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: May 15, 2015 General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 15, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �ni%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 15, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPiQ%yhe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 15, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45962 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015011984 (Lab ID:92247054001) • Chloride • Sulfate •2015011985 (Lab ID:92247054002) • Chloride • Sulfate •2015011986 (Lab ID:92247054003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPiS%yhe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 15, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015011984 (Lab ID:92247054001) •2015011985 (Lab ID:92247054002) •2015011986 (Lab ID:92247054003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45963 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015011984 (Lab ID:92247054001) • Nitrate as N •2015011985 (Lab ID:92247054002) • Nitrate as N •2015011986 (Lab ID:92247054003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4'8yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040615 Pace Project No.: 92247054 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 15, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/28457 1g: % RSD > 40 •2015011984 (Lab ID:92247054001) • RSD% This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040615 Pace Project No.: 92247054 Sample: 2015011984 Lab ID: 92247054001 Collected: 04/21/15 10:01 Received: 04/24/15 12:54 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 2870 mg/kg 25.2 12.6 5 05/04/15 04:15 05/05/15 13:56 7429-90-5 M1,R1 Barium 9.2 mg/kg 2.5 1.3 5 05/04/15 04:15 05/05/15 13:56 7440-39-3 Beryllium 0.13J mg/kg 0.25 0.13 5 05/04/15 04:15 05/05/15 13:56 7440-41-7 Boron ND mg/kg 12.6 6.3 5 05/04/15 04:15 05/05/15 13:56 7440-42-8 Calcium ND mg/kg 126 63.0 5 05/04/15 04:15 05/05/15 13:56 7440-70-2 Chromium 1.9 mg/kg 1.3 0.63 5 05/04/15 04:15 05/05/15 13:56 7440-47-3 Copper ND mg/kg 1.3 0.63 5 05/04/15 04:15 05/05/15 13:56 7440-50-8 Iron 343 mg/kg 10.1 5.0 5 05/04/15 04:15 05/05/15 13:56 7439-89-6 M1 Magnesium ND mg/kg 126 63.0 5 05/04/15 04:15 05/05/15 13:56 7439-95-4 Manganese 2.1 mg/kg 1.3 0.63 5 05/04/15 04:15 05/05/15 13:56 7439-96-5 Molybdenum ND mg/kg 2.5 1.3 5 05/04/15 04:15 05/05/15 13:56 7439-98-7 Nickel ND mg/kg 1.3 0.63 5 05/04/15 04:15 05/05/15 13:56 7440-02-0 Potassium ND mg/kg 252 126 5 05/04/15 04:15 05/05/15 13:56 7440-09-7 Sodium ND mg/kg 252 126 5 05/04/15 04:15 05/05/15 13:56 7440-23-5 Strontium ND mg/kg 2.5 1.3 5 05/04/15 04:15 05/05/15 13:56 7440-24-6 Zinc ND mg/kg 5.0 2.5 5 05/04/15 04:15 05/05/15 13:56 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.3 3.2 100 05/04/15 04:15 05/05/15 09:16 7440-36-0 N2 Arsenic ND mg/kg 6.3 3.2 100 05/04/15 04:15 05/05/15 09:16 7440-38-2 Cadmium ND mg/kg 0.76 0.38 100 05/04/15 04:15 05/05/15 09:16 7440-43-9 M6 Cobalt ND mg/kg 6.3 3.2 100 05/04/15 04:15 05/05/15 09:16 7440-48-4 Lead ND mg/kg 6.3 3.2 100 05/04/15 04:15 05/05/15 09:16 7439-92-1 M6 Selenium ND mg/kg 6.3 3.2 100 05/04/15 04:15 05/05/15 09:16 7782-49-2 M6 Thallium ND mg/kg 6.3 3.2 100 05/04/15 04:15 05/05/15 09:16 7440-28-0 Vanadium 4AJ mg/kg 6.3 3.2 100 05/04/15 04:15 05/05/15 09:16 7440-62-2 M6 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.011 0.0053 1 05/04/15 05:06 05/04/15 15:21 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 23.2 % 0.10 0.10 1 05/05/15 10:23 D6 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 0.10 1 04/28/15 17:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 324 162 5 04/30/15 20:26 16887-00-6 D3 Sulfate ND mg/kg 324 162 5 04/30/15 20:26 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 32.4 16.2 5 04/30/15 20:26 14797-55-8 D3,H3 Date: 05/15/2015 04:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040615 Pace Project No.: 92247054 Sample: 2015011984 Lab ID: 92247054001 Collected: 04/21/15 10:01 Received: 04/24/15 12:54 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 4390 mg/kg 779 390 1 05/14/15 10:05 7440-44-0 Total Organic Carbon 6640 mg/kg 780 390 1 05/14/15 10:12 7440-44-0 Total Organic Carbon 8620 mg/kg 781 391 1 05/14/15 10:18 7440-44-0 Total Organic Carbon 2750 mg/kg 778 389 1 05/14/15 10:24 7440-44-0 Mean Total Organic Carbon 5600 mg/kg 780 390 1 05/14/15 10:05 7440-44-0 Surrogates RSD% 45.9 % 1 05/14/15 10:05 1g Date: 05/15/2015 04:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040615 Pace Project No.: 92247054 Sample: 2015011985 Lab ID: 92247054002 Collected: 04/21/15 10:59 Received: 04/24/15 12:54 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 1210 mg/kg 27.2 13.6 5 05/04/15 04:15 05/05/15 14:08 7429-90-5 Barium 3.5 mg/kg 2.7 1.4 5 05/04/15 04:15 05/05/15 14:08 7440-39-3 Beryllium ND mg/kg 0.27 0.14 5 05/04/15 04:15 05/05/15 14:08 7440-41-7 Boron ND mg/kg 13.6 6.8 5 05/04/15 04:15 05/05/15 14:08 7440-42-8 Calcium ND mg/kg 136 68.1 5 05/04/15 04:15 05/05/15 14:08 7440-70-2 Chromium 1.2J mg/kg 1.4 0.68 5 05/04/15 04:15 05/05/15 14:08 7440-47-3 Copper ND mg/kg 1.4 0.68 5 05/04/15 04:15 05/05/15 14:08 7440-50-8 Iron 269 mg/kg 10.9 5.4 5 05/04/15 04:15 05/05/15 14:08 7439-89-6 Magnesium ND mg/kg 136 68.1 5 05/04/15 04:15 05/05/15 14:08 7439-95-4 Manganese 1.5 mg/kg 1.4 0.68 5 05/04/15 04:15 05/05/15 14:08 7439-96-5 Molybdenum ND mg/kg 2.7 1.4 5 05/04/15 04:15 05/05/15 14:08 7439-98-7 Nickel ND mg/kg 1.4 0.68 5 05/04/15 04:15 05/05/15 14:08 7440-02-0 Potassium ND mg/kg 272 136 5 05/04/15 04:15 05/05/15 14:08 7440-09-7 Sodium ND mg/kg 272 136 5 05/04/15 04:15 05/05/15 14:08 7440-23-5 Strontium ND mg/kg 2.7 1.4 5 05/04/15 04:15 05/05/15 14:08 7440-24-6 Zinc ND mg/kg 5.4 2.7 5 05/04/15 04:15 05/05/15 14:08 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.4 2.7 100 05/04/15 04:15 05/05/15 09:31 7440-36-0 N2 Arsenic ND mg/kg 5.4 2.7 100 05/04/15 04:15 05/05/15 09:31 7440-38-2 Cadmium ND mg/kg 0.65 0.33 100 05/04/15 04:15 05/05/15 09:31 7440-43-9 Cobalt ND mg/kg 5.4 2.7 100 05/04/15 04:15 05/05/15 09:31 7440-48-4 Lead ND mg/kg 5.4 2.7 100 05/04/15 04:15 05/05/15 09:31 7439-92-1 Selenium ND mg/kg 5.4 2.7 100 05/04/15 04:15 05/05/15 09:31 7782-49-2 Thallium ND mg/kg 5.4 2.7 100 05/04/15 04:15 05/05/15 09:31 7440-28-0 Vanadium ND mg/kg 5.4 2.7 100 05/04/15 04:15 05/05/15 09:31 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0089 0.0045 1 05/04/15 05:06 05/04/15 15:28 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 9.2 % 0.10 0.10 1 05/05/15 10:23 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 0.10 1 04/28/15 17:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 280 140 5 04/30/15 21:30 16887-00-6 D3 Sulfate ND mg/kg 280 140 5 04/30/15 21:30 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.0 14.0 5 04/30/15 21:30 14797-55-8 D3,H3 Date: 05/15/2015 04:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPig%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040615 Pace Project No.: 92247054 Sample: 2015011985 Lab ID: 92247054002 Collected: 04/21/15 10:59 Received: 04/24/15 12:54 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1530 mg/kg 655 327 1 05/14/15 10:29 7440-44-0 Total Organic Carbon 2130 mg/kg 663 332 1 05/14/15 10:35 7440-44-0 Total Organic Carbon 2680 mg/kg 655 328 1 05/14/15 10:41 7440-44-0 Total Organic Carbon 1960 mg/kg 661 330 1 05/14/15 10:48 7440-44-0 Mean Total Organic Carbon 2080 mg/kg 659 329 1 05/14/15 10:29 7440-44-0 Surrogates RSD% 22.8 % 1 05/14/15 10:29 Date: 05/15/2015 04:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040615 Pace Project No.: 92247054 Sample: 2015011986 Lab ID: 92247054003 Collected: 04/21/15 11:15 Received: 04/24/15 12:54 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 86.7 mg/kg 32.0 16.0 5 05/04/15 04:15 05/05/15 14:37 7429-90-5 Barium ND mg/kg 3.2 1.6 5 05/04/15 04:15 05/05/15 14:37 7440-39-3 Beryllium ND mg/kg 0.32 0.16 5 05/04/15 04:15 05/05/15 14:37 7440-41-7 Boron ND mg/kg 16.0 8.0 5 05/04/15 04:15 05/05/15 14:37 7440-42-8 Calcium ND mg/kg 160 80.0 5 05/04/15 04:15 05/05/15 14:37 7440-70-2 Chromium ND mg/kg 1.6 0.80 5 05/04/15 04:15 05/05/15 14:37 7440-47-3 Copper ND mg/kg 1.6 0.80 5 05/04/15 04:15 05/05/15 14:37 7440-50-8 Iron 2570 mg/kg 12.8 6.4 5 05/04/15 04:15 05/05/15 14:37 7439-89-6 Magnesium ND mg/kg 160 80.0 5 05/04/15 04:15 05/05/15 14:37 7439-95-4 Manganese 1.51 mg/kg 1.6 0.80 5 05/04/15 04:15 05/05/15 14:37 7439-96-5 Molybdenum ND mg/kg 3.2 1.6 5 05/04/15 04:15 05/05/15 14:37 7439-98-7 Nickel 1.51 mg/kg 1.6 0.80 5 05/04/15 04:15 05/05/15 14:37 7440-02-0 Potassium ND mg/kg 320 160 5 05/04/15 04:15 05/05/15 14:37 7440-09-7 Sodium ND mg/kg 320 160 5 05/04/15 04:15 05/05/15 14:37 7440-23-5 CU Strontium ND mg/kg 3.2 1.6 5 05/04/15 04:15 05/05/15 14:37 7440-24-6 Zinc 12.9 mg/kg 6.4 3.2 5 05/04/15 04:15 05/05/15 14:37 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.4 3.2 100 05/04/15 04:15 05/05/15 09:36 7440-36-0 N2 Arsenic ND mg/kg 6.4 3.2 100 05/04/15 04:15 05/05/15 09:36 7440-38-2 Cadmium ND mg/kg 0.77 0.38 100 05/04/15 04:15 05/05/15 09:36 7440-43-9 Cobalt 3.3J mg/kg 6.4 3.2 100 05/04/15 04:15 05/05/15 09:36 7440-48-4 Lead ND mg/kg 6.4 3.2 100 05/04/15 04:15 05/05/15 09:36 7439-92-1 Selenium ND mg/kg 6.4 3.2 100 05/04/15 04:15 05/05/15 09:36 7782-49-2 Thallium ND mg/kg 6.4 3.2 100 05/04/15 04:15 05/05/15 09:36 7440-28-0 Vanadium ND mg/kg 6.4 3.2 100 05/04/15 04:15 05/05/15 09:36 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.010 0.0050 1 05/04/15 05:06 05/04/15 15:32 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.6 % 0.10 0.10 1 05/05/15 10:23 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 0.10 1 04/28/15 17:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 312 156 5 04/30/15 21:51 16887-00-6 D3 Sulfate ND mg/kg 312 156 5 04/30/15 21:51 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.2 15.6 5 04/30/15 21:51 14797-55-8 D3,H3 Date: 05/15/2015 04:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040615 Pace Project No.: 92247054 Sample: 2015011986 Lab ID: 92247054003 Collected: 04/21/15 11:15 Received: 04/24/15 12:54 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 753 376 1 05/14/15 10:54 7440-44-0 Total Organic Carbon 396J mg/kg 761 380 1 05/14/15 11:01 7440-44-0 Total Organic Carbon 443J mg/kg 751 375 1 05/14/15 11:06 7440-44-0 Total Organic Carbon ND mg/kg 752 376 1 05/14/15 11:13 7440-44-0 Mean Total Organic Carbon 394J mg/kg 754 377 1 05/14/15 10:54 7440-44-0 Surrogates RSD% 8.8 % 1 05/14/15 10:54 Date: 05/15/2015 04:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3inl%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040615 Pace Project No.: 92247054 Sample: 2015011987 Lab ID: 92247054004 Collected: 04/21/15 09:55 Received: 04/24/15 12:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/15/2015 04:05 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 ND ug/L 10.0 3.0 1 04/28/15 20:17 04/30/15 11:20 7429-90-5 ND ug/L 0.50 0.15 1 04/28/15 20:17 04/30/15 11:20 7440-36-0 ND ug/L 0.50 0.11 1 04/28/15 20:17 04/30/15 11:20 7440-38-2 0.54 ug/L 0.30 0.081 1 04/28/15 20:17 04/30/15 11:20 7440-39-3 ND ug/L 0.20 0.067 1 04/28/15 20:17 04/30/15 11:20 7440-41-7 1.2J ug/L 5.0 1.1 1 04/28/15 20:17 04/30/15 11:20 7440-42-8 ND ug/L 0.080 0.024 1 04/28/15 20:17 04/30/15 11:20 7440-43-9 197 ug/L 40.0 16.0 1 04/28/15 20:17 04/30/15 11:20 7440-70-2 ND ug/L 0.50 0.17 1 04/28/15 20:17 04/30/15 11:20 7440-47-3 0.20J ug/L 0.50 0.13 1 04/28/15 20:17 04/30/15 11:20 7440-48-4 ND ug/L 1.0 0.21 1 04/28/15 20:17 04/30/15 11:20 7440-50-8 38.6J ug/L 50.0 13.7 1 04/28/15 20:17 04/30/15 11:20 7439-89-6 ND ug/L 0.10 0.046 1 04/28/15 20:17 04/30/15 11:20 7439-92-1 54.3 ug/L 10.0 3.2 1 04/28/15 20:17 04/30/15 11:20 7439-95-4 2.8 ug/L 0.50 0.24 1 04/28/15 20:17 04/30/15 11:20 7439-96-5 ND ug/L 0.50 0.094 1 04/28/15 20:17 04/30/15 11:20 7439-98-7 0.23J ug/L 0.50 0.16 1 04/28/15 20:17 04/30/15 11:20 7440-02-0 35.7J ug/L 50.0 11.7 1 04/28/15 20:17 04/30/15 11:20 7440-09-7 ND ug/L 0.50 0.20 1 04/28/15 20:17 04/30/15 11:20 7782-49-2 345 ug/L 50.0 16.3 1 04/28/15 20:17 04/30/15 11:20 7440-23-5 1.0 ug/L 0.50 0.13 1 04/28/15 20:17 04/30/15 11:20 7440-24-6 ND ug/L 0.10 0.015 1 04/28/15 20:17 04/30/15 11:20 7440-28-0 ND ug/L 1.0 0.28 1 04/28/15 20:17 04/30/15 11:20 7440-62-2 ND ug/L 5.0 2.4 1 04/28/15 20:17 04/30/15 11:20 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/28/15 20:40 04/30/15 18:01 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �Q%yhe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: MERP/13380 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92247054004 METHOD BLANK: 1950361 Matrix: Water Associated Lab Samples: 92247054004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/30/1517:44 LABORATORY CONTROL SAMPLE: 1950362 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.2 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1950363 1950364 MS MSD 92247052009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.4 5.6 107 111 80-120 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 25 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: MERP/5669 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92247054001, 92247054002, 92247054003 METHOD BLANK: 1202036 Matrix: Solid Associated Lab Samples: 92247054001, 92247054002, 92247054003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0077 05/04/1515:17 LABORATORY CONTROL SAMPLE: 1202037 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.079 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1202038 1202039 MS MSD 92247054001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .107 .107 0.11 0.12 103 106 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t 4,8yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: MPRP/23928 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92247054001, 92247054002, 92247054003 METHOD BLANK: 1202028 Matrix: Associated Lab Samples: 92247054001, 92247054002, 92247054003 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 4.9 05/05/1513:40 Barium mg/kg ND 0.49 05/05/1513:40 Beryllium mg/kg ND 0.049 05/05/1513:40 Boron mg/kg ND 2.4 05/05/1513:40 Calcium mg/kg ND 24.5 05/05/1513:40 Chromium mg/kg ND 0.24 05/05/1513:40 Copper mg/kg ND 0.24 05/05/1513:40 Iron mg/kg ND 2.0 05/05/1513:40 Magnesium mg/kg ND 24.5 05/05/1513:40 Manganese mg/kg ND 0.24 05/05/1513:40 Molybdenum mg/kg ND 0.49 05/05/1513:40 Nickel mg/kg ND 0.24 05/05/1513:40 Potassium mg/kg ND 49.0 05/05/1513:40 Sodium mg/kg ND 49.0 05/05/1513:40 Strontium mg/kg ND 0.49 05/05/1513:40 Zinc mg/kg ND 0.98 05/05/1513:40 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1202029 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 134 106 80-120 Barium mg/kg 12.7 13.5 106 80-120 Beryllium mg/kg 1.3 1.3 103 80-120 Boron mg/kg 127 127 100 80-120 Calcium mg/kg 635 685 108 80-120 Chromium mg/kg 12.7 12.5 99 80-120 Copper mg/kg 12.7 12.5 98 80-120 Iron mg/kg 127 133 104 80-120 Magnesium mg/kg 635 655 103 80-120 Manganese mg/kg 12.7 12.9 101 80-120 Molybdenum mg/kg 12.7 13.0 102 80-120 Nickel mg/kg 12.7 13.2 104 80-120 Potassium mg/kg 635 675 106 80-120 Sodium mg/kg 635 707 111 80-120 Strontium mg/kg 12.7 13.5 106 80-120 Zinc mg/kg 63.5 67.2 106 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1202030 1202031 MS MSD 92247054001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 2870 167 167 4750 3780 1130 550 75-125 23 20 M1,R1 Barium mg/kg 9.2 16.7 16.7 26.7 25.7 105 99 75-125 4 20 Beryllium mg/kg 0.13J 1.69 1.69 1.8 1.9 101 105 75-125 3 20 Boron mg/kg ND 167 167 154 166 92 99 75-125 7 20 Calcium mg/kg ND 833 832 893 949 106 113 75-125 6 20 Chromium mg/kg 1.9 16.7 16.7 18.4 18.7 99 101 75-125 2 20 Copper mg/kg ND 16.7 16.7 16.4 17.2 96 100 75-125 4 20 Iron mg/kg 343 167 167 748 629 243 172 75-125 17 20 M1 Magnesium mg/kg ND 833 832 961 991 108 112 75-125 3 20 Manganese mg/kg 2.1 16.7 16.7 19.9 20.0 107 108 75-125 1 20 Molybdenum mg/kg ND 16.7 16.7 15.7 16.7 94 100 75-125 6 20 Nickel mg/kg ND 16.7 16.7 18.2 19.0 107 111 75-125 4 20 Potassium mg/kg ND 833 832 915 963 104 110 75-125 5 20 Sodium mg/kg ND 833 832 887 889 107 107 75-125 0 20 Strontium mg/kg ND 16.7 16.7 18.2 19.2 108 114 75-125 5 20 Zinc mg/kg ND 83.3 83.2 87.9 91.7 105 109 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: MPRP/23929 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92247054001, 92247054002, 92247054003 METHOD BLANK: 1202032 Matrix: Solid Associated Lab Samples: 92247054001, 92247054002, 92247054003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.048 05/05/15 09:11 N2 Arsenic mg/kg ND 0.048 05/05/15 09:11 Cadmium mg/kg ND 0.0058 05/05/15 09:11 Cobalt mg/kg ND 0.048 05/05/15 09:11 Lead mg/kg ND 0.048 05/05/15 09:11 Selenium mg/kg ND 0.048 05/05/15 09:11 Thallium mg/kg ND 0.048 05/05/15 09:11 Vanadium mg/kg ND 0.048 05/05/15 09:11 LABORATORY CONTROL SAMPLE: Parameter 1202033 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.5 100 80-120 N2 Arsenic mg/kg 2.5 2.7 109 80-120 Cadmium mg/kg .25 0.26 103 80-120 Cobalt mg/kg 2.5 2.7 107 80-120 Lead mg/kg 2.5 2.5 102 80-120 Selenium mg/kg 2.5 2.6 104 80-120 Thallium mg/kg 2.5 2.5 101 80-120 Vanadium mg/kg 2.5 2.6 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1202034 1202035 MS MSD 92247054001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.12 3.25 ND ND 75 82 75-125 20 N2 Arsenic mg/kg ND 3.12 3.25 3.6J 3.8J 83 86 75-125 20 Cadmium mg/kg ND .312 .325 ND 0.45J 106 140 75-125 20 M6 Cobalt mg/kg ND 3.12 3.25 3.5J 3.8J 102 109 75-125 20 Lead mg/kg ND 3.12 3.25 4.5J 5.OJ 54 68 75-125 20 M6 Selenium mg/kg ND 3.12 3.25 3.6J 3.8J 66 69 75-125 20 M6 Thallium mg/kg ND 3.12 3.25 3.3J 3.3J 78 77 75-125 20 Vanadium mg/kg 4AJ 3.12 3.25 6.6 6.3J 70 60 75-125 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: MPRP/53983 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92247054004 METHOD BLANK: 1950241 Associated Lab Samples: 92247054004 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 04/30/1510:39 ND 0.50 04/30/1510:39 ND 0.50 04/30/1510:39 ND 0.30 04/30/1510:39 ND 0.20 04/30/1510:39 ND 5.0 04/30/1510:39 ND 0.080 04/30/1510:39 ND 40.0 04/30/1510:39 ND 0.50 04/30/1510:39 ND 0.50 04/30/1510:39 ND 1.0 04/30/1510:39 ND 50.0 04/30/1510:39 ND 0.10 04/30/1510:39 ND 10.0 04/30/1510:39 ND 0.50 04/30/1510:39 ND 0.50 04/30/1510:39 ND 0.50 04/30/1510:39 ND 50.0 04/30/1510:39 ND 0.50 04/30/1510:39 ND 50.0 04/30/1510:39 ND 0.50 04/30/1510:39 ND 0.10 04/30/1510:39 ND 1.0 04/30/1510:39 ND 5.0 04/30/1510:39 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1950242 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 80.2 100 80-120 Antimony ug/L 80 82.7 103 80-120 Arsenic ug/L 80 84.7 106 80-120 Barium ug/L 80 87.4 109 80-120 Beryllium ug/L 80 83.0 104 80-120 Boron ug/L 80 82.5 103 80-120 Cadmium ug/L 80 82.1 103 80-120 Calcium ug/L 1000 1060 106 80-120 Chromium ug/L 80 89.0 111 80-120 Cobalt ug/L 80 88.8 111 80-120 Copper ug/L 80 88.2 110 80-120 Iron ug/L 1000 1110 111 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 LABORATORY CONTROL SAMPLE: 1950242 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 86.5 108 80-120 Magnesium ug/L 1000 1100 110 80-120 Manganese ug/L 80 83.9 105 80-120 Molybdenum ug/L 80 84.2 105 80-120 Nickel ug/L 80 86.1 108 80-120 Potassium ug/L 1000 1140 114 80-120 Selenium ug/L 80 86.1 108 80-120 Sodium ug/L 1000 1140 114 80-120 Strontium ug/L 80 77.7 97 80-120 Thallium ug/L 80 91.5 114 80-120 Vanadium ug/L 80 91.6 114 80-120 Zinc ug/L 80 81.7 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1950243 1950244 MS MSD 92247052008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 31.1 80 80 142 186 138 193 75-125 27 20 M1,R1 Antimony ug/L ND 80 80 89.2 82.2 111 103 75-125 8 20 Arsenic ug/L ND 80 80 92.1 86.2 115 108 75-125 7 20 Barium ug/L 0.79 80 80 90.1 84.5 112 105 75-125 6 20 Beryllium ug/L ND 80 80 83.0 83.4 104 104 75-125 0 20 Boron ug/L ND 80 80 86.1 87.2 106 108 75-125 1 20 Cadmium ug/L ND 80 80 90.3 84.8 113 106 75-125 6 20 Calcium ug/L 40.5 1000 1000 1180 1100 114 106 75-125 7 20 Chromium ug/L 0.73 80 80 89.4 83.8 111 104 75-125 6 20 Cobalt ug/L 0.191 80 80 90.5 84.9 113 106 75-125 6 20 Copper ug/L 0.56J 80 80 89.2 83.9 111 104 75-125 6 20 Iron ug/L 169 1000 1000 1410 1380 124 121 75-125 3 20 Lead ug/L ND 80 80 91.0 84.7 114 106 75-125 7 20 Magnesium ug/L 12.8 1000 1000 1130 1060 112 105 75-125 6 20 Manganese ug/L 10.3 80 80 102 95.0 115 106 75-125 7 20 Molybdenum ug/L ND 80 80 90.8 84.8 113 106 75-125 7 20 Nickel ug/L 0.25J 80 80 93.7 88.2 117 110 75-125 6 20 Potassium ug/L 20.5J 1000 1000 1110 1040 109 102 75-125 7 20 Selenium ug/L ND 80 80 86.0 85.8 108 107 75-125 0 20 Sodium ug/L 20.OJ 1000 1000 1170 1080 115 106 75-125 8 20 Strontium ug/L 0.24J 80 80 85.3 79.3 106 99 75-125 7 20 Thallium ug/L ND 80 80 99.1 91.1 124 114 75-125 8 20 Vanadium ug/L ND 80 80 90.7 85.3 113 106 75-125 6 20 Zinc ug/L ND 80 80 85.7 79.6 107 99 75-125 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: PMST/3532 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92247054001, 92247054002, 92247054003 SAMPLE DUPLICATE: 1203207 35185354001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 87.2 78.3 11 10 D6 SAMPLE DUPLICATE: 1203208 35185835006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.3 2.4 5 10 SAMPLE DUPLICATE: 1203209 35185835016 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.9 4.8 2 10 SAMPLE DUPLICATE: 1203210 92247054001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.2 20.7 11 10 D6 SAMPLE DUPLICATE: 1203211 92247080003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 13.0 12.3 6 10 SAMPLE DUPLICATE: 1203212 92247052006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 28.0 27.5 2 10 SAMPLE DUPLICATE: 1203213 92247091008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 11.1 12.3 11 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: WET/37101 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92247054001, 92247054002, 92247054003 SAMPLE DUPLICATE: 1444704 92247019016 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.6 6.6 0 10 SAMPLE DUPLICATE: 1444705 92247019001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.2 4.2 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98001 inic&fi e. Suit.100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: WETA/45962 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92247054001, 92247054002, 92247054003 METHOD BLANK: 1199898 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 04/30/1515:47 Sulfate mg/kg 117 49.8 04/30/1515:47 LABORATORY CONTROL SAMPLE: 1199899 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1199901 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1199900 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 467 93 80-120 500 470 94 80-120 92247052001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 685 592 69 80-120 M 1 ND 685 611 89 80-120 92247052001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: WETA/45963 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92247054001, 92247054002, 92247054003 METHOD BLANK: 1199903 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/30/15 15:47 LABORATORY CONTROL SAMPLE: 1199904 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50 47.9 96 80-120 MATRIX SPIKE SAMPLE: 1199906 92247052001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 68.5 61.0 87 80-120 H3 SAMPLE DUPLICATE: 1199905 92247052001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040615 Pace Project No.: 92247054 QC Batch: WETA/28457 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92247054001, 92247054002, 92247054003 METHOD BLANK: 1155940 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/14/15 07:20 LABORATORY CONTROL SAMPLE: 1155941 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 118000 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1155942 1155943 MS MSD 92247068001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 8580 8510 8380 7830 94 89 50-150 7 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1155944 1155945 MS MSD 92247080001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 932 6990 6960 7150 7530 89 95 50-150 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15040615 Pace Project No.: 92247054 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14625 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS 1g %RSD>40 CU The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15040615 Pace Project No.: 92247054 ANALYTE QUALIFIERS R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/15/2015 04:05 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 41 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %%yh.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040615 Pace Project No.: 92247054 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92247054001 2015011984 EPA 3050 MPRP/23928 EPA 6010 92247054002 2015011985 EPA 3050 MPRP/23928 EPA 6010 92247054003 2015011986 EPA 3050 MPRP/23928 EPA 6010 92247054001 2015011984 EPA 3050 MPRP/23929 EPA 6020 92247054002 2015011985 EPA 3050 MPRP/23929 EPA 6020 92247054003 2015011986 EPA 3050 MPRP/23929 EPA 6020 92247054004 2015011987 EPA 3020 MPRP/53983 EPA 6020A 92247054004 2015011987 EPA 7470A MERP/13380 EPA 7470A 92247054001 2015011984 EPA 7471 MERP/5669 EPA 7471 92247054002 2015011985 EPA 7471 MERP/5669 EPA 7471 92247054003 2015011986 EPA 7471 MERP/5669 EPA 7471 92247054001 2015011984 ASTM D2974-87 PMST/3532 92247054002 2015011985 ASTM D2974-87 PMST/3532 92247054003 2015011986 ASTM D2974-87 PMST/3532 92247054001 2015011984 EPA 9045 WET/37101 92247054002 2015011985 EPA 9045 WET/37101 92247054003 2015011986 EPA 9045 WET/37101 92247054001 2015011984 EPA 9056 WETA/45962 92247054002 2015011985 EPA 9056 WETA/45962 92247054003 2015011986 EPA 9056 WETA/45962 92247054001 2015011984 EPA 9056 WETA/45963 92247054002 2015011985 EPA 9056 WETA/45963 92247054003 2015011986 EPA 9056 WETA/45963 92247054001 2015011984 EPA 9060 WETA/28457 92247054001 2015011984 EPA 9060 WETA/28458 92247054002 2015011985 EPA 9060 WETA/28457 92247054002 2015011985 EPA 9060 WETA/28458 92247054003 2015011986 EPA 9060 WETA/28457 92247054003 2015011986 EPA 9060 WETA/28458 Date: 05/15/2015 04:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14625 ICP/14625 ICP/14625 ICPM/9721 ICPM/9721 ICPM/9721 ICPM/24001 MERC/15555 MERC/5659 MERC/5659 MERC/5659 Page 39 of 41 Sample Condition Upon Recel celin��ly#r`c>?f� Document Number: F-CHR-CS-003-rey.15 1 of 2 Issuing Authority: Pace Huntersville Quality Office 47 49 ient Name:_ n f'z ,/u 1 ;i trier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client[] mercial❑ ac Other Y ;tod Seal on CoolerlBox Present: El yes no Seals intact: ❑ yes ❑ no king Material: ❑ Bubble VDP Bubble Bags ❑ None ❑ Other rmometer Used: IR Gun 40 Type of lee: llfej' Blue None Samples on ice, cooling process has begun ip Correction Factor T1401 No Correction Date and initials o p o exa m[09 rected Cooler Temp.: °C Biological Tissue is Frozen: Yes No r contents: r < ! ip should be above freezing to 6°C Comments: tin of Custody Present: tin of Custody Filled Out: tin of Custody Relinquished: npler Name & Signature on CO nples Arrived within Hold Time: art Hold Time Analysis (<72hi sh. Turn Around Time Reques ficient Volume: rrect Containers Used: -Pace Containers Used: ntainers Intact: ered .volume received for mple Labels match COC: -Includes dateltimeliD/Ar des No ❑NIA 1. es QNr ❑NIA 2. es ❑ o ❑ NIA 3. Q es or ❑ NIA 4. es ❑No ❑ A 5, ❑Yes []No PWA 6. ❑Yes 'o ❑NIA 7. - es o ❑N/IA 8. Olies ❑No NIA 9. Oyes Dissolved tests Oyes preservation containers needing preservation are found to be in npliance with EPA recommendation. O&G. W-DRO ❑ o�L NIA ONO ❑NIA 1 © ❑ A 11. ONO ❑NIA 12. ❑des o ❑NIA 13. Yp es :No N' NIA Oyes l ples-shsokp+oTAP_chlodnation' ❑Yes ❑No ❑ A l mclspace in VOA Vials { >6mm): ❑Yes ONO ❑91A 16. ip 'Blank Present: Oyes ONO ❑ IA 16. ip Blank Custody Seals Present ❑Yes ONO 9N A sce Trip Blank Lot # (if purchased): lient Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: DatefTime: Comments/ Resolution: ,CURF Review: Date: WO# : 92247054 SRF Review: Date: 2 r� Note: Whenever there is a discrepancy affecting North Carolina compliance II ��' III `� III IIII III samples, a copy of this form will be sent to the North Carolina DEHNR 922470g4 I Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) Page 40 of 41 1. .V\10 n e , � •- -.I� W,..i � N v a b CL W n a m o O �° o Customer to complete appropriate calumns to right rni v a e a y -4 3 =; d n M3 o o .CI n O13 O n n 3 0 10 Tn 'D CL Mo f/1 v m N a ft7 w CL 3 I l Q n O O 7 c a Z-C e ►max 9 lI -1 3 w 3 0 � � � 4 rs P 0w Q0 P D z or a l � n < N f c ro + o ? I ,D IL x$ T. A ( o 3 + m 67� v `l 48 of 49 C-10mer —Sl Camplala _ z m W p ne P C - a M C7 Zc W M 7C (V_ ✓7 C 7 G � D s°I n 3 a) 1 _ c M - + + N 7 + N 3 I z '0 I M I � w CL I d = a O d m u,zis N i0a' V 6 p 7 tJ�A�9 m a r o iS I 1 tQ ( i + m �!0 I l0 I C .._._._._._._.i I:n I t O R� r b a CIL . N CL n o tx <s m Ce 0 �r N :t 3 ro ?: we o 3�C a w a 1Ly a H r 3 r m x "Grab Req Total Metals, Anjo PH 1 - 8 oz jar (PACE) 5,51 I`crCS TOC 4 - 4 oz jar (PACE) SPLP - Total Metals and Anions 2 - 8 oz jars (PACE) Sediment specific tests 2 - 8 oz jar (ACCESS ANALYTICAL) ''`Total # of Containers O H T ! a I� PQ M.I-A O !M O v (� ID j N 3 i D i ILA 1 I z j v O j > ® u ry n "n m i z u o N 3 njfy 2 Cl ! o 5 Q `� N SIC 4 13 a u C I M m i Cn Q a! 5 j a� m j 5 i i i z �k e m to m 00 w < '0 A n { T, o t m z �" --IPTPage41 of41 CHAIN OF �CUSTODY RECORD AND ANALYSIS REQUEST FORM - - - - - -------46...... - � SYNTERRA EDO .......... I ` `, F t14 N ENERGY., - ---.--_._.._._.6 Ana lytieal La4grakc>+ryl Services i Veil Coda MG43A3 IBullding 7405I ' 19]34 Figgers Fanyr Rd i Huntd:rsville N. G. �plY7fl i {"O) A75 5a45 Fix: Ir'AI&0 875--0 d-Iql i Any Isl Laisor�t Use On .. .. ..... e NCex �0 7 of 1 `I's F [)I�TRI6LITIQNi QH_ I ORIGINAL to LAB. I COPY tci CLIFNT NPDE3' wfmm SCJI----------------- Work Ortlar i P� L[ 0 � L — —_ I I-u49a 0' Pllilf i iMn� ; ire ~ P - Jr Sarnptirs 4nglnailluQ From SAMPLE PROGRAM Grains WAt er _ #) ups—g unt J4Dpw&�A ID Vil. and is nut irrdiCad1UU ebUvr _, .xf.d fhoTalf•- ., ! ,1 ,nu'.rr'n n At `, vpLounllegl lleMs at a -Q. [ir g PrnwiAn rtarre — IR i IuaE+3tttY I Mx rr4nld l4 i ISnit, 6adrmarrt, Aahl -- I_ I !w a m I llrq iI WATER .j.Q.—I'- I CSIMer . Isla It i RAMC E a.� � i i PO 1142081 i +:Iar,I�r tsi c4®rllats ail aaroo Waalasrna=.. PrasarvaUvas whin used must added wiUlif71 15 minutes of sam G[?IICCtl891 -lc 5=Nnnn di •d dri li7 p w J ha a yi � d D t w U i'nrl 1°Colleftion Infprmfabon a m I� 40 r Chi y IL C {y Dese.ription+y€ar 11) Gatr Time Si natarr. 6 m � � � r � ��y� co IL w SV -E -j � � < � 21. -- 1 r I Ie > - EQUIPMENT BLANK q'I PER DAY) r 27!Ir6eliii.�iirrdypljy t � .�_. ?� r]annfTIIMIY q7-S 1 r. R®Ilnqulahad aY r�etaPTlnna rle r,I�F +. .� P7Aff�IVM� �Requ gad TkimarP1und 14 Days y.- gMcapewd Batlrilma AGG � Irr 1 @alinqul - "� '7 Mao Q SrraWWL�ckeQBY LIZ 4Q Hr 2Cjl:ammrnts meuls, A4 Sta, M, Fla, I3e, 8. Cd, �Ce, CF. Cn, Cu, Fa, Pt, Mg. Mn, Mo. MI, K, So, Na, Sr, Tl. V. Zn, mercury, PH AdYS(3nS: CI tJi6raW,N,SO4 Sediments p(;lflCPfl FFleteW %SOHds CEC Par#V••claSlibDiRirlt�ldilinrf.I i�cioxP�steltil;dl