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Home My WebLink AboutNC0003417_J15040400 Report_20150805' w, DU bf50 Analytical Laboratory "It' ENERGY, 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J15040400 Project Name: HF LEE PLANT - AB GW ASSESSMENT SOIL Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer Customer Address: 1677 Old Smithfield Rd Goldsboro NC 27530, Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) Report Authorized By: VIC, " �° 2015.06.05 11:02:18 Date: (Signature)-04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/5/2015 1 of 50 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample Wa)& Descriptions: Collection Sample ID Plant/Station Date and Time 2015011187 2015011188 2015011189 2015011190 4 Total Samples Collected By Sample Description HF LEE PLANT 14-Apr-15 11:55 AM Judd Mahan AMW-15-0.5-2 HF LEE PLANT 14-Apr-15 12:05 PM Judd Mahan AMW-15-4-5 HF LEE PLANT 14-Apr-15 1:45 PM Judd Mahan AMW-15-16-17 HF LEE PLANT 14-Apr-15 11:15 AM Judd Mahan Equipment Blank 2 of 50 3 of 50 3 of 50 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately 4 of 50 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040400 Site: AMW-15-0.5-2 Collection Date: 14-Apr-15 11:55 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 50 Sample #: 2015011187 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE 5 of 50 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040400 Site: AMW-15-4-5 Collection Date: 14-Apr-15 12:05 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 50 Sample #: 2015011188 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE 6 of 50 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040400 Site: AMW-15-16-17 Collection Date: 14-Apr-15 1:45 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 50 Sample #: 2015011189 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE 7 of 50 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040400 Site: Equipment Blank Collection Date: 14-Apr-15 11:15 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015011190 Matrix: SOIL 7 of 50 Method Analysis Date/Time Analyst Vendor Method V_PACE ac�Alyical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&�e. Suite 100 Huntersville, INC 28078 (704)875-9092 May 12, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15040400 Pace Project No.: 92246059 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 17, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 42 lacci. imlytical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinf&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040400 Pace Project No.: 92246059 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040400 Pace Project No.: 92246059 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 42 ac,Aical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�in� c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15040400 Pace Project No.: 92246059 Lab ID Sample ID Matrix Date Collected Date Received 92246059001 2015011187 Solid 04114/1511:55 04/17/1512:40 92246059002 2015011188 Solid 04/14/1512:05 04/17/1512:40 92246059003 2015011189 Solid 04/14/1513:45 04/17/1512:40 92246059004 2015011190 Water 04/14/1511:15 04/17/1512:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15040400 92246059 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92246059001 2015011187 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92246059002 2015011188 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92246059003 2015011189 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92246059004 2015011190 EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 42 ac,ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15040400 92246059 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92246059001 2015011187 EPA 6010 Aluminum 3860 mg/kg 29.0 04/29/15 08:33 M1,R1 EPA 6010 Barium 21.6 mg/kg 2.9 04/29/15 08:33 M1,R1 EPA 6010 Chromium 2.8 mg/kg 1.5 04/29/15 08:33 EPA 6010 Copper 1.0J mg/kg 1.5 04/29/15 08:33 EPA 6010 Iron 1510 mg/kg 11.6 04/29/15 08:33 M1,R1 EPA 6010 Magnesium 127J mg/kg 145 04/29/15 08:33 EPA 6010 Manganese 5.3 mg/kg 1.5 04/29/15 08:33 EPA 6010 Nickel 0.801 mg/kg 1.5 04/29/15 08:33 EPA 6020 Lead 4.1 J mg/kg 5.8 04/27/15 23:31 EPA 6020 Vanadium 6.2 mg/kg 5.8 04/27/15 23:31 M6 EPA 7471 Mercury 0.011 mg/kg 0.0093 04/26/15 19:22 ASTM D2974-87 Percent Moisture 14.3 % 0.10 04/28/15 10:30 EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 04/24/15 13:15 H3 EPA 9060 Total Organic Carbon 1530 mg/kg 700 05/11/15 19:35 EPA 9060 Total Organic Carbon 1490 mg/kg 702 05/11/15 19:42 EPA 9060 Total Organic Carbon 1520 mg/kg 701 05/11/15 19:49 EPA 9060 Total Organic Carbon 1520 mg/kg 699 05/11/15 19:55 EPA 9060 Mean Total Organic Carbon 1520 mg/kg 700 05/11/15 19:35 EPA 9060 RSD% 1.1 % 05/11/15 19:35 92246059002 2015011188 EPA 6010 Aluminum 1240 mg/kg 32.6 04/29/15 08:45 EPA 6010 Barium 13.6 mg/kg 3.3 04/29/15 08:45 EPA 6010 Chromium 1.1J mg/kg 1.6 04/29/15 08:45 EPA 6010 Copper 0.89J mg/kg 1.6 04/29/15 08:45 EPA 6010 Iron 295 mg/kg 13.0 04/29/15 08:45 EPA 6010 Manganese 2.7 mg/kg 1.6 04/29/15 08:45 ASTM D2974-87 Percent Moisture 20.5 % 0.10 04/28/15 10:30 EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 04/24/15 13:15 H3 EPA 9060 Total Organic Carbon 885 mg/kg 753 05/11/15 20:02 EPA 9060 Total Organic Carbon 639J mg/kg 748 05/11/15 20:07 EPA 9060 Total Organic Carbon 679J mg/kg 757 05/11/15 20:14 EPA 9060 Total Organic Carbon 705J mg/kg 755 05/11/15 20:20 EPA 9060 Mean Total Organic Carbon 727J mg/kg 753 05/11/15 20:02 EPA 9060 RSD% 15.0 % 05/11/15 20:02 92246059003 2015011189 EPA 6010 Aluminum 730 mg/kg 30.7 04/29/15 08:53 EPA 6010 Barium 3.7 mg/kg 3.1 04/29/15 08:53 EPA 6010 Calcium 96.7J mg/kg 153 04/29/15 08:53 EPA 6010 Chromium 1.5 mg/kg 1.5 04/29/15 08:53 EPA 6010 Copper 1.2J mg/kg 1.5 04/29/15 08:53 EPA 6010 Iron 513 mg/kg 12.3 04/29/15 08:53 EPA 6010 Manganese 3.4 mg/kg 1.5 04/29/15 08:53 ASTM D2974-87 Percent Moisture 20.8 % 0.10 04/30/15 10:27 EPA 9045 pH at 25 Degrees C 5.6 Std. Units 0.10 04/24/15 13:15 H3 EPA 9060 Total Organic Carbon 493J mg/kg 753 05/11/15 20:25 EPA 9060 Total Organic Carbon 421J mg/kg 754 05/11/15 20:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J15040400 Pace Project No.: 92246059 Lab Sample ID Client Sample ID Method Parameters Result Units 92246059003 2015011189 EPA 9060 Total Organic Carbon 528J mg/kg EPA 9060 Total Organic Carbon 449J mg/kg EPA 9060 Mean Total Organic Carbon 473J mg/kg EPA 9060 RSD% 10 % 92246059004 2015011190 EPA 6020A Aluminum 10.2 ug/L EPA 6020A Barium 0.61 ug/L EPA 6020A Calcium 66.2 ug/L EPA 6020A Chromium 0.22J ug/L EPA 6020A Copper 1.7 ug/L EPA 6020A Iron 31.9J ug/L EPA 6020A Lead 0.053J ug/L EPA 6020A Magnesium 14.6 ug/L EPA 6020A Manganese 0.74 ug/L EPA 6020A Potassium 12.5J ug/L EPA 6020A Sodium 82.0 ug/L EPA 6020A Strontium 0.51 ug/L EPA 6020A Zinc 3.5J ug/L EPA 7470A Mercury 0.030J ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 753 05/11/15 20:38 751 05/11/15 20:43 753 05/11/15 20:25 05/11/15 20:25 10.0 04/23/1519:32 0.30 04/23/1519:32 40.0 04/23/1519:32 0.50 04/23/1519:32 1.0 04/23/1519:32 50.0 04/23/1519:32 0.10 04/23/1519:32 10.0 04/23/1519:32 0.50 04/23/1519:32 50.0 04/23/1519:32 50.0 04/23/1519:32 0.50 04/23/1519:32 5.0 04/23/1519:32 0.20 04/23/15 20:55 Page 7 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 12, 2015 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23799 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246059001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1193768) • Aluminum • Barium • Boron • Iron • Molybdenum • MSD (Lab ID: 1193769) • Aluminum • Barium • Iron R1: RPD value was outside control limits. • MSD (Lab ID: 1193769) • Aluminum • Barium • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040400 Pace Project No.: 92246059 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 12, 2015 Additional Comments: PROJECT NARRATIVE REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 12, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23800 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246059001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1193774) • Antimony • Arsenic • Cadmium • Selenium • Vanadium • MSD (Lab ID: 1193775) • Antimony • Arsenic • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffiigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 12, 2015 Analyte Comments: QC Batch: MPRP/23800 N2: The lab does not hold TNI accreditation for this parameter. •2015011187 (Lab ID:92246059001) • Antimony •2015011188 (Lab ID:92246059002) • Antimony •2015011189 (Lab ID:92246059003) • Antimony • BLANK (Lab ID: 1193772) • Antimony • LCS (Lab ID: 1193773) • Antimony • MS (Lab ID: 1193774) • Antimony • MSD (Lab ID: 1193775) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 12, 2015 General Information: 1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53822 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246088001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1945457) • Aluminum • MSD (Lab ID: 1945458) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 42 acL�navical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: May 12, 2015 General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 42 acLAnavical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 12, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 12, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015011187 (Lab ID:92246059001) •2015011188 (Lab ID:92246059002) •2015011189 (Lab ID:92246059003) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 42 ac,ical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 12, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45720 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015011187 (Lab ID:92246059001) • Chloride • Sulfate •2015011188 (Lab ID:92246059002) • Chloride • Sulfate •2015011189 (Lab ID:92246059003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 42 acatical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 12, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015011187 (Lab ID:92246059001) •2015011188 (Lab ID:92246059002) •2015011189 (Lab ID:92246059003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 42 acatical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040400 Pace Project No.: 92246059 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 12, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 42 acL�navical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040400 Pace Project No.: 92246059 Sample: 2015011187 Lab ID: 92246059001 Collected: 04/14/15 11:55 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/12/2015 06:17 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 3860 mg/kg 29.0 14.5 5 04/25/15 19:00 04/29/15 08:33 7429-90-5 21.6 mg/kg 2.9 1.5 5 04/25/15 19:00 04/29/15 08:33 7440-39-3 ND mg/kg 0.29 0.15 5 04/25/15 19:00 04/29/15 08:33 7440-41-7 ND mg/kg 14.5 7.3 5 04/25/15 19:00 04/29/15 08:33 7440-42-8 ND mg/kg 145 72.5 5 04/25/15 19:00 04/29/15 08:33 7440-70-2 2.8 mg/kg 1.5 0.73 5 04/25/15 19:00 04/29/15 08:33 7440-47-3 1.0J mg/kg 1.5 0.73 5 04/25/15 19:00 04/29/15 08:33 7440-50-8 1510 mg/kg 11.6 5.8 5 04/25/15 19:00 04/29/15 08:33 7439-89-6 127J mg/kg 145 72.5 5 04/25/15 19:00 04/29/15 08:33 7439-95-4 5.3 mg/kg 1.5 0.73 5 04/25/15 19:00 04/29/15 08:33 7439-96-5 ND mg/kg 2.9 1.5 5 04/25/15 19:00 04/29/15 08:33 7439-98-7 0.80J mg/kg 1.5 0.73 5 04/25/15 19:00 04/29/15 08:33 7440-02-0 ND mg/kg 290 145 5 04/25/15 19:00 04/29/15 08:33 7440-09-7 ND mg/kg 290 145 5 04/25/15 19:00 04/29/15 08:33 7440-23-5 ND mg/kg 2.9 1.5 5 04/25/15 19:00 04/29/15 08:33 7440-24-6 ND mg/kg 5.8 2.9 5 04/25/15 19:00 04/29/15 08:33 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.8 2.9 100 04/25/15 19:00 04/27/15 23:31 7440-36-0 ND mg/kg 5.8 2.9 100 04/25/15 19:00 04/27/15 23:31 7440-38-2 ND mg/kg 0.70 0.35 100 04/25/15 19:00 04/27/15 23:31 7440-43-9 ND mg/kg 5.8 2.9 100 04/25/15 19:00 04/27/15 23:31 7440-48-4 4.1J mg/kg 5.8 2.9 100 04/25/15 19:00 04/27/15 23:31 7439-92-1 ND mg/kg 5.8 2.9 100 04/25/15 19:00 04/27/15 23:31 7782-49-2 ND mg/kg 5.8 2.9 100 04/25/15 19:00 04/27/15 23:31 7440-28-0 6.2 mg/kg 5.8 2.9 100 04/25/15 19:00 04/27/15 23:31 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.011 mg/kg 0.0093 0.0046 1 04/25/1519:20 04/26/1519:22 7439-97-6 Analytical Method: ASTM D2974-87 14.3 % 0.10 0.10 1 04/28/1510:30 Analytical Method: EPA 9045 4.7 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 287 143 5 ND mg/kg 287 143 5 Analytical Method: EPA 9056 ND mg/kg 28.7 14.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 1811WIr`N1SKAN M1,R1 M1,R1 M1 M1,R1 M1 M6, N2 M6 M6 M6 M6 I:B1 04/24/15 07:14 16887-00-6 D3 04/24/15 07:14 14808-79-8 D3 04/24/15 07:14 14797-55-8 H3 Page 19 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040400 Pace Project No.: 92246059 Sample: 2015011187 Lab ID: 92246059001 Collected: 04/14/15 11:55 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1530 mg/kg 700 350 1 05/11/15 19:35 7440-44-0 Total Organic Carbon 1490 mg/kg 702 351 1 05/11/15 19:42 7440-44-0 Total Organic Carbon 1520 mg/kg 701 350 1 05/11/15 19:49 7440-44-0 Total Organic Carbon 1520 mg/kg 699 349 1 05/11/15 19:55 7440-44-0 Mean Total Organic Carbon 1520 mg/kg 700 350 1 05/11/15 19:35 7440-44-0 Surrogates RSD% 1.1 % 1 05/11/15 19:35 Date: 05/12/2015 06:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 42 acL�navical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040400 Pace Project No.: 92246059 Sample: 2015011188 Lab ID: 92246059002 Collected: 04/14/15 12:05 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/12/2015 06:17 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 1240 mg/kg 32.6 16.3 5 04/25/15 19:00 04/29/15 08:45 7429-90-5 13.6 mg/kg 3.3 1.6 5 04/25/15 19:00 04/29/15 08:45 7440-39-3 ND mg/kg 0.33 0.16 5 04/25/15 19:00 04/29/15 08:45 7440-41-7 ND mg/kg 16.3 8.1 5 04/25/15 19:00 04/29/15 08:45 7440-42-8 ND mg/kg 163 81.4 5 04/25/15 19:00 04/29/15 08:45 7440-70-2 1.1J mg/kg 1.6 0.81 5 04/25/15 19:00 04/29/15 08:45 7440-47-3 0.891 mg/kg 1.6 0.81 5 04/25/15 19:00 04/29/15 08:45 7440-50-8 295 mg/kg 13.0 6.5 5 04/25/15 19:00 04/29/15 08:45 7439-89-6 ND mg/kg 163 81.4 5 04/25/15 19:00 04/29/15 08:45 7439-95-4 2.7 mg/kg 1.6 0.81 5 04/25/15 19:00 04/29/15 08:45 7439-96-5 ND mg/kg 3.3 1.6 5 04/25/15 19:00 04/29/15 08:45 7439-98-7 ND mg/kg 1.6 0.81 5 04/25/15 19:00 04/29/15 08:45 7440-02-0 ND mg/kg 326 163 5 04/25/15 19:00 04/29/15 08:45 7440-09-7 ND mg/kg 326 163 5 04/25/15 19:00 04/29/15 08:45 7440-23-5 ND mg/kg 3.3 1.6 5 04/25/15 19:00 04/29/15 08:45 7440-24-6 ND mg/kg 6.5 3.3 5 04/25/15 19:00 04/29/15 08:45 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.5 3.3 100 04/25/15 19:00 04/27/15 23:37 7440-36-0 ND mg/kg 6.5 3.3 100 04/25/15 19:00 04/27/15 23:37 7440-38-2 ND mg/kg 0.78 0.39 100 04/25/15 19:00 04/27/15 23:37 7440-43-9 ND mg/kg 6.5 3.3 100 04/25/15 19:00 04/27/15 23:37 7440-48-4 ND mg/kg 6.5 3.3 100 04/25/15 19:00 04/27/15 23:37 7439-92-1 ND mg/kg 6.5 3.3 100 04/25/15 19:00 04/27/15 23:37 7782-49-2 ND mg/kg 6.5 3.3 100 04/25/15 19:00 04/27/15 23:37 7440-28-0 ND mg/kg 6.5 3.3 100 04/25/15 19:00 04/27/15 23:37 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.010 0.0050 1 04/25/1519:20 04/26/1519:28 7439-97-6 Analytical Method: ASTM D2974-87 20.5 % 0.10 0.10 1 04/28/1510:30 Analytical Method: EPA 9045 4.7 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 311 156 5 ND mg/kg 311 156 5 Analytical Method: EPA 9056 ND mg/kg 31.1 15.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 1811WIr`N1SKAN N2 I:B1 04/24/15 07:35 16887-00-6 D3 04/24/15 07:35 14808-79-8 D3 04/24/15 07:35 14797-55-8 H3 Page 21 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040400 Pace Project No.: 92246059 Sample: 2015011188 Lab ID: 92246059002 Collected: 04/14/15 12:05 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 885 mg/kg 753 377 1 05/11/15 20:02 7440-44-0 Total Organic Carbon 639J mg/kg 748 374 1 05/11/15 20:07 7440-44-0 Total Organic Carbon 679J mg/kg 757 378 1 05/11/15 20:14 7440-44-0 Total Organic Carbon 705J mg/kg 755 378 1 05/11/15 20:20 7440-44-0 Mean Total Organic Carbon 727J mg/kg 753 377 1 05/11/15 20:02 7440-44-0 Surrogates RSD% 15.0 % 1 05/11/15 20:02 Date: 05/12/2015 06:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 42 acL�navical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040400 Pace Project No.: 92246059 Sample: 2015011189 Lab ID: 92246059003 Collected: 04/14/15 13:45 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/12/2015 06:17 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 730 mg/kg 30.7 15.3 5 04/25/15 19:00 04/29/15 08:53 7429-90-5 3.7 mg/kg 3.1 1.5 5 04/25/15 19:00 04/29/15 08:53 7440-39-3 ND mg/kg 0.31 0.15 5 04/25/15 19:00 04/29/15 08:53 7440-41-7 ND mg/kg 15.3 7.7 5 04/25/15 19:00 04/29/15 08:53 7440-42-8 96.7J mg/kg 153 76.7 5 04/25/15 19:00 04/29/15 08:53 7440-70-2 1.5 mg/kg 1.5 0.77 5 04/25/15 19:00 04/29/15 08:53 7440-47-3 1.2J mg/kg 1.5 0.77 5 04/25/15 19:00 04/29/15 08:53 7440-50-8 513 mg/kg 12.3 6.1 5 04/25/15 19:00 04/29/15 08:53 7439-89-6 ND mg/kg 153 76.7 5 04/25/15 19:00 04/29/15 08:53 7439-95-4 3.4 mg/kg 1.5 0.77 5 04/25/15 19:00 04/29/15 08:53 7439-96-5 ND mg/kg 3.1 1.5 5 04/25/15 19:00 04/29/15 08:53 7439-98-7 ND mg/kg 1.5 0.77 5 04/25/15 19:00 04/29/15 08:53 7440-02-0 ND mg/kg 307 153 5 04/25/15 19:00 04/29/15 08:53 7440-09-7 ND mg/kg 307 153 5 04/25/15 19:00 04/29/15 08:53 7440-23-5 ND mg/kg 3.1 1.5 5 04/25/15 19:00 04/29/15 08:53 7440-24-6 ND mg/kg 6.1 3.1 5 04/25/15 19:00 04/29/15 08:53 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.1 3.1 100 04/25/15 19:00 04/27/15 23:49 7440-36-0 ND mg/kg 6.1 3.1 100 04/25/15 19:00 04/27/15 23:49 7440-38-2 ND mg/kg 0.74 0.37 100 04/25/15 19:00 04/27/15 23:49 7440-43-9 ND mg/kg 6.1 3.1 100 04/25/15 19:00 04/27/15 23:49 7440-48-4 ND mg/kg 6.1 3.1 100 04/25/15 19:00 04/27/15 23:49 7439-92-1 ND mg/kg 6.1 3.1 100 04/25/15 19:00 04/27/15 23:49 7782-49-2 ND mg/kg 6.1 3.1 100 04/25/15 19:00 04/27/15 23:49 7440-28-0 ND mg/kg 6.1 3.1 100 04/25/15 19:00 04/27/15 23:49 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.010 0.0052 1 04/25/1519:20 04/26/1519:32 7439-97-6 Analytical Method: ASTM D2974-87 20.8 % 0.10 0.10 1 04/30/1510:27 Analytical Method: EPA 9045 5.6 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 311 156 5 ND mg/kg 311 156 5 Analytical Method: EPA 9056 ND mg/kg 31.1 15.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 1811WIr`N1SKAN N2 I:B1 04/24/15 07:56 16887-00-6 D3 04/24/15 07:56 14808-79-8 D3 04/24/15 07:56 14797-55-8 H3 Page 23 of 42 acLAnavical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�n�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040400 Pace Project No.: 92246059 Sample: 2015011189 Lab ID: 92246059003 Collected: 04/14/15 13:45 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 493J mg/kg 753 376 1 05/11/15 20:25 7440-44-0 Total Organic Carbon 421J mg/kg 754 377 1 05/11/15 20:32 7440-44-0 Total Organic Carbon 528J mg/kg 753 377 1 05/11/15 20:38 7440-44-0 Total Organic Carbon 449J mg/kg 751 375 1 05/11/15 20:43 7440-44-0 Mean Total Organic Carbon 473J mg/kg 753 376 1 05/11/15 20:25 7440-44-0 Surrogates RSD% 10 % 1 05/11/15 20:25 Date: 05/12/2015 06:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040400 Pace Project No.: 92246059 Sample: 2015011190 Lab ID: 92246059004 Collected: 04/14/15 11:15 Received: 04/17/15 12:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\��,I=11a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/12/2015 06:17 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 10.2 ug/L 10.0 3.0 1 04/22/1514:55 04/23/1519:32 7429-90-5 ND ug/L 0.50 0.15 1 04/22/1514:55 04/23/1519:32 7440-36-0 ND ug/L 0.50 0.11 1 04/22/1514:55 04/23/1519:32 7440-38-2 0.61 ug/L 0.30 0.081 1 04/22/1514:55 04/23/1519:32 7440-39-3 ND ug/L 0.20 0.067 1 04/22/1514:55 04/23/1519:32 7440-41-7 ND ug/L 5.0 1.1 1 04/22/1514:55 04/23/1519:32 7440-42-8 ND ug/L 0.080 0.024 1 04/22/1514:55 04/23/1519:32 7440-43-9 66.2 ug/L 40.0 16.0 1 04/22/1514:55 04/23/1519:32 7440-70-2 0.22J ug/L 0.50 0.17 1 04/22/1514:55 04/23/1519:32 7440-47-3 ND ug/L 0.50 0.13 1 04/22/1514:55 04/23/1519:32 7440-48-4 1.7 ug/L 1.0 0.21 1 04/22/1514:55 04/23/1519:32 7440-50-8 31.9J ug/L 50.0 13.7 1 04/22/1514:55 04/23/1519:32 7439-89-6 0.053J ug/L 0.10 0.046 1 04/22/1514:55 04/23/1519:32 7439-92-1 14.6 ug/L 10.0 3.2 1 04/22/1514:55 04/23/1519:32 7439-95-4 0.74 ug/L 0.50 0.24 1 04/22/1514:55 04/23/1519:32 7439-96-5 ND ug/L 0.50 0.094 1 04/22/1514:55 04/23/1519:32 7439-98-7 ND ug/L 0.50 0.16 1 04/22/1514:55 04/23/1519:32 7440-02-0 12.5J ug/L 50.0 11.7 1 04/22/1514:55 04/23/1519:32 7440-09-7 ND ug/L 0.50 0.20 1 04/22/1514:55 04/23/1519:32 7782-49-2 82.0 ug/L 50.0 16.3 1 04/22/1514:55 04/23/1519:32 7440-23-5 0.51 ug/L 0.50 0.13 1 04/22/1514:55 04/23/1519:32 7440-24-6 ND ug/L 0.10 0.015 1 04/22/1514:55 04/23/1519:32 7440-28-0 ND ug/L 1.0 0.28 1 04/22/1514:55 04/23/1519:32 7440-62-2 3.5J ug/L 5.0 2.4 1 04/22/1514:55 04/23/1519:32 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.030J ug/L 0.20 0.022 1 04/22/15 17:55 04/23/15 20:55 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 42 ac,ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: MERP/13313 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92246059004 METHOD BLANK: 1945566 Matrix: Water Associated Lab Samples: 92246059004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/23/15 20:16 LABORATORY CONTROL SAMPLE: 1945567 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.1 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945568 1945569 MS MSD 92246044001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.2 103 104 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 42 acatical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: MERP/5633 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92246059001, 92246059002, 92246059003 METHOD BLANK: 1193779 Matrix: Solid Associated Lab Samples: 92246059001, 92246059002, 92246059003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 04/26/1519:13 LABORATORY CONTROL SAMPLE: 1193780 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .083 0.080 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1193781 1193782 MS MSD 92246059001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.011 .0898 .091 0.097 0.10 96 99 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 42 acatical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: MPRP/23799 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92246059001, 92246059002, 92246059003 METHOD BLANK: 1193766 Matrix: Associated Lab Samples: 92246059001, 92246059002, 92246059003 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.1 04/29/15 08:25 Barium mg/kg ND 0.51 04/29/15 08:25 Beryllium mg/kg ND 0.051 04/29/15 08:25 Boron mg/kg ND 2.5 04/29/15 08:25 Calcium mg/kg ND 25.4 04/29/15 08:25 Chromium mg/kg ND 0.25 04/29/15 08:25 Copper mg/kg ND 0.25 04/29/15 08:25 Iron mg/kg ND 2.0 04/29/15 08:25 Magnesium mg/kg ND 25.4 04/29/15 08:25 Manganese mg/kg ND 0.25 04/29/15 08:25 Molybdenum mg/kg ND 0.51 04/29/15 08:25 Nickel mg/kg ND 0.25 04/29/15 08:25 Potassium mg/kg ND 50.9 04/29/15 08:25 Sodium mg/kg ND 50.9 04/29/15 08:25 Strontium mg/kg ND 0.51 04/29/15 08:25 Zinc mg/kg ND 1.0 04/29/15 08:25 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1193767 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 128 101 80-120 Barium mg/kg 12.7 12.7 100 80-120 Beryllium mg/kg 1.3 1.2 96 80-120 Boron mg/kg 127 121 95 80-120 Calcium mg/kg 635 651 103 80-120 Chromium mg/kg 12.7 11.5 90 80-120 Copper mg/kg 12.7 11.8 93 80-120 Iron mg/kg 127 128 101 80-120 Magnesium mg/kg 635 623 98 80-120 Manganese mg/kg 12.7 12.4 98 80-120 Molybdenum mg/kg 12.7 12.3 97 80-120 Nickel mg/kg 12.7 12.6 99 80-120 Potassium mg/kg 635 629 99 80-120 Sodium mg/kg 635 641 101 80-120 Strontium mg/kg 12.7 12.9 101 80-120 Zinc mg/kg 63.5 63.4 100 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 42 ac��navical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1193768 1193769 MS MSD 92246059001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Aluminum mg/kg 3860 146 140 5800 7750 1320 2770 75-125 29 20 M1,R1 Barium mg/kg 21.6 14.6 14 31.1 40.1 65 131 75-125 25 20 M1,R1 Beryllium mg/kg ND 1.52 1.4 1.2 1.4 78 92 75-125 12 20 Boron mg/kg ND 146 140 107 114 72 80 75-125 6 20 M1 Calcium mg/kg ND 731 702 665 738 84 98 75-125 10 20 Chromium mg/kg 2.8 14.6 14 13.9 16.6 76 98 75-125 17 20 Copper mg/kg 1.01 14.6 14 12.1 13.7 76 90 75-125 12 20 Iron mg/kg 1510 146 140 1760 2390 166 621 75-125 30 20 M1,R1 Magnesium mg/kg 127J 731 702 744 868 84 106 75-125 15 20 Manganese mg/kg 5.3 14.6 14 17.9 20.3 86 107 75-125 12 20 Molybdenum mg/kg ND 14.6 14 11.1 11.8 74 82 75-125 6 20 M1 Nickel mg/kg 0.80J 14.6 14 13.0 14.8 84 100 75-125 13 20 Potassium mg/kg ND 731 702 682 748 84 97 75-125 9 20 Sodium mg/kg ND 731 702 584 623 80 89 75-125 6 20 Strontium mg/kg ND 14.6 14 13.7 15.5 85 101 75-125 12 20 Zinc mg/kg ND 73.1 70.2 61.8 68.9 82 95 75-125 11 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: MPRP/23800 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92246059001, 92246059002, 92246059003 METHOD BLANK: 1193772 Matrix: Solid Associated Lab Samples: 92246059001, 92246059002, 92246059003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/27/15 23:26 N2 Arsenic mg/kg ND 0.051 04/27/15 23:26 Cadmium mg/kg ND 0.0061 04/27/15 23:26 Cobalt mg/kg ND 0.051 04/27/15 23:26 Lead mg/kg ND 0.051 04/27/15 23:26 Selenium mg/kg ND 0.051 04/27/15 23:26 Thallium mg/kg ND 0.051 04/27/15 23:26 Vanadium mg/kg ND 0.051 04/27/15 23:26 LABORATORY CONTROL SAMPLE: Parameter 1193773 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 94 80-120 N2 Arsenic mg/kg 2.5 2.4 97 80-120 Cadmium mg/kg .25 0.23 91 80-120 Cobalt mg/kg 2.5 2.4 94 80-120 Lead mg/kg 2.5 2.4 94 80-120 Selenium mg/kg 2.5 2.4 97 80-120 Thallium mg/kg 2.5 2.4 96 80-120 Vanadium mg/kg 2.5 2.4 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1193774 1193775 MS MSD 92246059001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.03 2.92 ND ND 59 58 75-125 20 M6, N2 Arsenic mg/kg ND 3.03 2.92 ND ND 73 69 75-125 20 M6 Cadmium mg/kg ND .303 .292 ND ND 66 102 75-125 20 M6 Cobalt mg/kg ND 3.03 2.92 3AJ 3AJ 98 97 75-125 20 Lead mg/kg 4.1J 3.03 2.92 7.3 7.3 105 109 75-125 1 20 Selenium mg/kg ND 3.03 2.92 ND ND 55 50 75-125 20 M6 Thallium mg/kg ND 3.03 2.92 ND ND 81 81 75-125 20 Vanadium mg/kg 6.2 3.03 2.92 11.2 11.6 168 183 75-125 3 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 42 ac��navical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: MPRP/53822 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92246059004 METHOD BLANK: 1945455 Associated Lab Samples: 92246059004 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Qualifiers Aluminum ug/L ND 10.0 04/23/1517:17 Antimony ug/L ND 0.50 04/23/1517:17 Arsenic ug/L ND 0.50 04/23/1517:17 Barium ug/L ND 0.30 04/23/1517:17 Beryllium ug/L ND 0.20 04/23/1517:17 Boron ug/L 1.6J 5.0 04/23/1517:17 Cadmium ug/L ND 0.080 04/23/1517:17 Calcium ug/L ND 40.0 04/23/1517:17 Chromium ug/L ND 0.50 04/23/1517:17 Cobalt ug/L ND 0.50 04/23/1517:17 Copper ug/L 0.46J 1.0 04/23/1517:17 Iron ug/L ND 50.0 04/23/1517:17 Lead ug/L ND 0.10 04/23/1517:17 Magnesium ug/L ND 10.0 04/23/1517:17 Manganese ug/L ND 0.50 04/23/1517:17 Molybdenum ug/L ND 0.50 04/23/1517:17 Nickel ug/L 0.38J 0.50 04/23/1517:17 Potassium ug/L ND 50.0 04/23/1517:17 Selenium ug/L ND 0.50 04/23/1517:17 Sodium ug/L ND 50.0 04/23/1517:17 Strontium ug/L ND 0.50 04/23/1517:17 Thallium ug/L 0.016J 0.10 04/23/1517:17 Vanadium ug/L ND 1.0 04/23/1517:17 Zinc ug/L ND 5.0 04/23/1517:17 LABORATORY CONTROL SAMPLE: Parameter 1945456 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 83.6 105 80-120 Antimony ug/L 80 77.2 97 80-120 Arsenic ug/L 80 77.4 97 80-120 Barium ug/L 80 77.0 96 80-120 Beryllium ug/L 80 78.9 99 80-120 Boron ug/L 80 82.3 103 80-120 Cadmium ug/L 80 77.8 97 80-120 Calcium ug/L 1000 1010 101 80-120 Chromium ug/L 80 79.6 99 80-120 Cobalt ug/L 80 77.7 97 80-120 Copper ug/L 80 81.6 102 80-120 Iron ug/L 1000 955 96 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 42 ac,�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 LABORATORY CONTROL SAMPLE: 1945456 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 80.4 101 80-120 Magnesium ug/L 1000 970 97 80-120 Manganese ug/L 80 79.4 99 80-120 Molybdenum ug/L 80 76.6 96 80-120 Nickel ug/L 80 77.9 97 80-120 Potassium ug/L 1000 974 97 80-120 Selenium ug/L 80 77.9 97 80-120 Sodium ug/L 1000 938 94 80-120 Strontium ug/L 80 76.4 95 80-120 Thallium ug/L 80 83.1 104 80-120 Vanadium ug/L 80 78.3 98 80-120 Zinc ug/L 80 80.8 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945457 1945458 MS MSD 92246088001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 36.8 80 80 146 145 137 135 75-125 1 20 M1 Antimony ug/L ND 80 80 79.6 79.2 99 99 75-125 0 20 Arsenic ug/L 0.12J 80 80 79.5 79.6 99 99 75-125 0 20 Barium ug/L 1.1 80 80 81.5 82.8 100 102 75-125 2 20 Beryllium ug/L ND 80 80 78.6 79.4 98 99 75-125 1 20 Boron ug/L ND 80 80 84.7 84.2 105 104 75-125 1 20 Cadmium ug/L ND 80 80 82.0 81.4 102 102 75-125 1 20 Calcium ug/L 138 1000 1000 1230 1250 109 111 75-125 2 20 Chromium ug/L 0.46J 80 80 84.4 85.2 105 106 75-125 1 20 Cobalt ug/L ND 80 80 81.5 82.2 102 103 75-125 1 20 Copper ug/L 0.84J 80 80 85.9 85.9 106 106 75-125 0 20 Iron ug/L 122 1000 1000 1110 1130 99 100 75-125 1 20 Lead ug/L 0.0801 80 80 83.6 85.0 104 106 75-125 2 20 Magnesium ug/L 26.8 1000 1000 1040 1070 101 104 75-125 3 20 Manganese ug/L 2.8 80 80 85.5 86.0 103 104 75-125 1 20 Molybdenum ug/L ND 80 80 79.9 80.9 100 101 75-125 1 20 Nickel ug/L 0.21J 80 80 81.6 82.7 102 103 75-125 1 20 Potassium ug/L 40.2J 1000 1000 1060 1060 102 102 75-125 1 20 Selenium ug/L ND 80 80 82.1 82.1 103 103 75-125 0 20 Sodium ug/L 53.4 1000 1000 1030 1050 98 100 75-125 2 20 Strontium ug/L 0.88 80 80 80.5 81.4 99 101 75-125 1 20 Thallium ug/L ND 80 80 88.1 89.6 110 112 75-125 2 20 Vanadium ug/L ND 80 80 82.7 82.7 103 103 75-125 0 20 Zinc ug/L 2.6J 80 80 85.0 85.8 103 104 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 42 apaid �ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: PMST/3498 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92246059001, 92246059002 SAMPLE DUPLICATE: 1196514 35184332001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 73.8 73.1 1 10 SAMPLE DUPLICATE: 1196515 92246044010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 29.9 25.3 17 10 D6 SAMPLE DUPLICATE: 1196516 92246068001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 29.8 33.6 12 10 D6 SAMPLE DUPLICATE: 1196517 92246050007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.5 18.5 0 10 SAMPLE DUPLICATE: 1196518 35184952005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 13.9 14.6 5 10 SAMPLE DUPLICATE: 1196519 92246088014 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 31.0 32.7 6 10 SAMPLE DUPLICATE: 1196520 35185526001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.0 13.0 8 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 42 apall �ical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: PMST/3514 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92246059003 SAMPLE DUPLICATE: 1199286 35184836001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 6.4 5.6 13 10 D6 SAMPLE DUPLICATE: 1199287 35185117008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 27.8 27.5 1 10 SAMPLE DUPLICATE: 1199288 35185117018 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 20.3 23.9 16 10 D6 SAMPLE DUPLICATE: 1199289 35185410022 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.1 3.0 34 10 D6 SAMPLE DUPLICATE: 1199290 35185412027 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.6 4.9 6 10 SAMPLE DUPLICATE: 1199291 35185649007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.6 6.0 7 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 42 ace��ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: WET/37029 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92246059001, 92246059002, 92246059003 SAMPLE DUPLICATE: 1441575 92246050010 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.2 5.2 0 10 H3 SAMPLE DUPLICATE: 1441576 92246050013 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.6 5.6 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 42 ace�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: WETA/45720 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92246059001, 92246059002, 92246059003 METHOD BLANK: 1192886 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.0 04/24/15 03:18 Sulfate mg/kg ND 50.0 04/24/15 03:18 LABORATORY CONTROL SAMPLE: 1192887 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1192889 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1192888 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 497 477 96 80-120 497 477 96 80-120 92246050010 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 728 677 75 80-120 M 1 ND 728 704 97 80-120 92246050010 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 42 ace��ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: WETA/45721 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92246059001, 92246059002, 92246059003 METHOD BLANK: 1192891 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/24/15 03:18 LABORATORY CONTROL SAMPLE: 1192892 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.7 48.5 98 80-120 MATRIX SPIKE SAMPLE: 1192894 92246050010 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 72.8 65.2 90 80-120 H3 SAMPLE DUPLICATE: 1192893 92246050010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 42 acat��ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040400 Pace Project No.: 92246059 QC Batch: WETA/28413 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92246059001, 92246059002, 92246059003 METHOD BLANK: 1154316 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/11/15 09:53 LABORATORY CONTROL SAMPLE: 1154317 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 118000 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1154318 1154319 MS MSD 92245627013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 175000 74100 74500 234000 263000 79 118 50-150 12 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1154320 1154321 MS MSD 92247019006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 524J 6950 6920 6130 6060 81 80 50-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 42 ace��navical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15040400 Pace Project No.: 92246059 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/12/2015 06:17 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 42 ace��ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040400 Pace Project No.: 92246059 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92246059001 2015011187 EPA 3050 MPRP/23799 EPA 6010 92246059002 2015011188 EPA 3050 MPRP/23799 EPA 6010 92246059003 2015011189 EPA 3050 MPRP/23799 EPA 6010 92246059001 2015011187 EPA 3050 MPRP/23800 EPA 6020 92246059002 2015011188 EPA 3050 MPRP/23800 EPA 6020 92246059003 2015011189 EPA 3050 MPRP/23800 EPA 6020 92246059004 2015011190 EPA 3020 MPRP/53822 EPA 6020A 92246059004 2015011190 EPA 7470A MERP/13313 EPA 7470A 92246059001 2015011187 EPA 7471 MERP/5633 EPA 7471 92246059002 2015011188 EPA 7471 MERP/5633 EPA 7471 92246059003 2015011189 EPA 7471 MERP/5633 EPA 7471 92246059001 2015011187 ASTM D2974-87 PMST/3498 92246059002 2015011188 ASTM D2974-87 PMST/3498 92246059003 2015011189 ASTM D2974-87 PMST/3514 92246059001 2015011187 EPA 9045 WET/37029 92246059002 2015011188 EPA 9045 WET/37029 92246059003 2015011189 EPA 9045 WET/37029 92246059001 2015011187 EPA 9056 WETA/45720 92246059002 2015011188 EPA 9056 WETA/45720 92246059003 2015011189 EPA 9056 WETA/45720 92246059001 2015011187 EPA 9056 WETA/45721 92246059002 2015011188 EPA 9056 WETA/45721 92246059003 2015011189 EPA 9056 WETA/45721 92246059001 2015011187 EPA 9060 WETA/28413 92246059001 2015011187 EPA 9060 WETA/28414 92246059002 2015011188 EPA 9060 WETA/28413 92246059002 2015011188 EPA 9060 WETA/28414 92246059003 2015011189 EPA 9060 WETA/28413 92246059003 2015011189 EPA 9060 WETA/28414 Date: 05/12/2015 06:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14546 ICP/14546 ICP/14546 ICPM/9675 ICPM/9675 ICPM/9675 ICPM/23912 MERC/15479 MERC/5627 MERC/5627 MERC/5627 Page 40 of 42 Document Name: Sample Condition Upon Receipt (SCUR) Document Revised: September 22, 2014 Page 1 of 2 1r�lytrcals Document Number: Issuing Authority: F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Name:r,C. rnf'JJ17 Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑��no m�rcial❑ 6 a Other Custody Seal on CoolerlBox Present: ❑ yes Seals intact: ❑ yes Packing Material: ❑ Bubble 113p F Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun 44f] Type of ice We Blue None Temn C'_nrrae4inn F;2 nr T1401 Nn Correction no Samples once. cooling process has begun Corrected Cooler Temp.: °C Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes No /A g Comments: Bate and lnitia ers n examining_ contents: {%'f Chain of Custody Present: es o ❑NIA 1. Chain of Custody Filled Out: a es No ❑NIA 2, Chain of Custody Relinquished: Yes o ❑NIA 3. Sampler Name & Signature on COC: des No ❑NIA 4. Samples Arrived within Hold Time: Ljf/es ❑No LXA 5. Short Hold Time Analysis (<72hr): Dyes Qpe,2KA 6. Rush Turn Around Time Requested: Dyes o ❑NIA 7. Sufficient Volume: 01es o ❑NIA 8. Correct Containers Used: -Pace Containers Used: es ❑Yes ONO A ❑NIA 9. Containers Intact: E14, ❑No ❑NIA 1 Filtered volume received for Dissolved tests ❑Yes o DNIIA 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: es ONO ❑NIA 12, All containers needing preservation have been checked. Ali containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, W-DRO (water) es o ❑NIA ❑Yes ONO ON1A Dyes ❑ o 13. Samples checked for dechlorination: Dyes ONO ❑ hA 4. Headspace in VOA Vials (>6mm): Dyes ❑No NI 5, Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes ❑Yes ❑No ONO NI 0N1A 16. Client Notification! Resolution: Person Contacted: Comments/ Resolution: Date/Time: SCURF Review: Date: 1-_rlr5 SRF Review: IWA lDate: IZO Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Field Data Required? Y / N WOii:92246059 1111111111111ud iiirnni Page 41 of 42 49 of 50 49 of 50 "A 77 m Ilk 733 z tj > m co 'a 0 Ob vx T ils lc*r 10 00 rh-------- > el CL 10 0 -4 .......... Uh Cr. m I \ � � � � A 1 I `+ C I ems'00 V "Comp. a `RGrab Recl Jrs fD .2c qq I 0 -5 0 I I 212Tutal # of Conlainers Page 42 of 42 cl� 50 of 50 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST 'FORM I or, al Laborallory Savlam Apaticml "buratoly Use l i ,ago I of I DUKt Mail Co" MGMA2 (EkAkfing 7406) wom 0(dw IMAD N 3339 Mager8 Ferry Rd 1)1STFJBVn0N I C;k C3 J; I HurFlemAle, M. r 2MB Oiziuwi toLAB. ENERGY. 9 J!mo) 87!5z245 SAWI E PW_'1rRAM s GOPY to 4-1 IENT NPOt ............ lip-41-1 ka"W 12tppmne Pro: Owe 000W Tem lei HCRA m-W SYNTERRAL EDD 2-R.SO, 3i* I t rimild cock - A 40 -t rlpwm-lq Lino "J)AGE wity 113. 1@pF*%aft 1b wukwuwu 'Vrw'.ff4pm1ci& WE'Duntirm) ;ia*.44wn witablished and is Prot laidiCatied awv. acceurninq "i all 5 itcotinfing fields elabove, Of IR F [Lill LAD USE OkLY I "Lob ID -.Desktop No. 1 "Samba Descriptkm or ID A oj,5� . L 7 _""CoWcbon Informa!*9 Daft T'rrw Li'Lmartriff I a 4 AA N I , 1: PACE A PO 1142081 18 ZL otl Z 1`5 I? Xr y 7 - ed By DatejTw* 2%bqueuted Turimmund 4 Days,3ZIhs 7 Days