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Home My WebLink AboutNC0003417_J15040280 Report_20150805+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J15040280 Project Name: HF LEE PLANT - AB GW ASSESSMENT SOIL Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer Customer Address: 1677 Old Smithfield Rd Goldsboro NC 27530, Lab Contact: Margaret �(Galvin-Karr Phone: 980-875-5219 Report Authorized By: q �Gu MXG4644(101161) (Signature) R Y- 2015.05.271125:08-04'00' Date: Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/22/2015 1 of 54 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 54 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015010461 HF LEE PLANT 10-Apr-15 9:15 AM Judd Mahan Well AMW-45B 1-2 2015010462 HF LEE PLANT 10-Apr-15 9:30 AM Judd Mahan Well AMW-45B 4-5 2015010463 HF LEE PLANT 10-Apr-15 10:11 AM Judd Mahan Well AMW-45B 8-9 2015010464 HF LEE PLANT 10-Apr-15 10:30 AM Judd Mahan Well AMW-45B 10-11 2015010465 HF LEE PLANT 10-Apr-15 8:45 AM Judd Mahan Well EQUIPMENT BLANK 5 Total Samples 3 of 54 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040280 Site: Well AMW-45B 1-2 Collection Date: 10-Apr-15 9:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 54 Sample #: 2015010461 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040280 Site: Well AMW-45B 4-5 Collection Date: 10-Apr-15 9:30 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 54 Sample #: 2015010462 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040280 Site: Well AMW-45B 8-9 Collection Date: 10-Apr-15 10:11 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 54 Sample #: 2015010463 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040280 Site: Well AMW-45B 10-11 Collection Date: 10-Apr-15 10:30 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 54 Sample #: 2015010464 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis 8 of 54 This report shall not be reproduced, except in full. Order # J15040280 Site: Well EQUIPMENT BLANK Collection Date: 10-Apr-15 8:45 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015010465 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kig%fir&We. Suite 100 Huntersville, INC 28078 (704)875-9092 May 05, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15040280 Pace Project No.: 92245409 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 14, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 45 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kiiacsf.e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040280 Pace Project No.: 92245409 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f inlc&ygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040280 Pace Project No.: 92245409 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f iQ'8ygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15040280 Pace Project No.: 92245409 Lab ID Sample ID Matrix Date Collected Date Received 92245409001 2015010461 Solid 04/10/15 09:15 04/14/15 15:00 92245409002 2015010462 Solid 04/10/15 09:30 04/14/15 15:00 92245409003 2015010463 Solid 04110/1510:11 04/14/15 15:00 92245409004 2015010464 Solid 04/10/1510:30 04/14/15 15:00 92245409005 2015010465 Water 04/10/15 08:45 04/14/15 15:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f ig'8ygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15040280 92245409 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92245409001 2015010461 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245409002 2015010462 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245409003 2015010463 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245409004 2015010464 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245409005 2015010465 EPA 6020A TT3 24 PASI-M EPA 7470 LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040280 Pace Project No.: 92245409 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245409001 2015010461 EPA 6010 Aluminum 7530 mg/kg 6.4 04/20/15 18:48 EPA 6010 Barium 70.7 mg/kg 0.64 04/20/15 18:48 EPA 6010 Beryllium 0.62 mg/kg 0.064 04/20/15 18:48 EPA 6010 Calcium 135 mg/kg 31.9 04/20/15 18:48 EPA 6010 Chromium 10.8 mg/kg 0.32 04/20/15 18:48 EPA 6010 Copper 5.6 mg/kg 0.32 04/20/15 18:48 EPA 6010 Iron 13300 mg/kg 2.6 04/20/15 18:48 EPA 6010 Magnesium 1330 mg/kg 31.9 04/20/15 18:48 EPA 6010 Manganese 513 mg/kg 0.32 04/20/15 18:48 EPA 6010 Nickel 3.4 mg/kg 0.32 04/20/15 18:48 EPA 6010 Potassium 97.8 mg/kg 63.8 04/20/15 18:48 EPA 6010 Strontium 3.1 mg/kg 0.64 04/20/15 18:48 EPA 6010 Zinc 24.8 mg/kg 1.3 04/20/15 18:48 EPA 6020 Cobalt 21.2 mg/kg 6.4 04/26/15 09:51 EPA 6020 Lead 12.3 mg/kg 6.4 04/26/15 09:51 EPA 6020 Vanadium 35.9 mg/kg 6.4 04/26/15 09:51 EPA 7471 Mercury 0.034 mg/kg 0.0099 04/22/15 10:35 ASTM D2974-87 Percent Moisture 22.3 % 0.10 04/21/15 15:54 EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 04/20/15 15:50 EPA 9060 Total Organic Carbon 2300 mg/kg 777 05/04/15 07:55 EPA 9060 Total Organic Carbon 2940 mg/kg 776 05/04/15 08:01 EPA 9060 Total Organic Carbon 2690 mg/kg 773 05/04/15 08:07 EPA 9060 Total Organic Carbon 2600 mg/kg 772 05/04/15 08:13 EPA 9060 Mean Total Organic Carbon 2630 mg/kg 774 05/04/15 07:55 EPA 9060 RSD% 10 % 05/04/15 07:55 92245409002 2015010462 EPA 6010 Aluminum 7650 mg/kg 6.8 04/20/15 18:53 EPA 6010 Barium 59.3 mg/kg 0.68 04/20/15 18:53 EPA 6010 Beryllium 0.77 mg/kg 0.34 04/21/1510:06 EPA 6010 Calcium 80.1 mg/kg 34.1 04/20/15 18:53 EPA 6010 Chromium 14.1 mg/kg 1.7 04/21/1510:06 EPA 6010 Copper 7.2 mg/kg 1.7 04/21/1510:06 EPA 6010 Iron 14300 mg/kg 2.7 04/20/15 18:53 EPA 6010 Magnesium 1610 mg/kg 34.1 04/20/15 18:53 EPA 6010 Manganese 505 mg/kg 1.7 04/21/1510:06 EPA 6010 Nickel 3.8 mg/kg 0.34 04/20/15 18:53 EPA 6010 Potassium 155 mg/kg 68.1 04/20/15 18:53 EPA 6010 Strontium 3.0 mg/kg 0.68 04/20/15 18:53 EPA 6010 Zinc 20.5 mg/kg 1.4 04/20/15 18:53 EPA 6020 Cobalt 12.1 mg/kg 6.8 04/26/15 09:53 EPA 6020 Lead 10 mg/kg 6.8 04/26/15 09:53 EPA 6020 Vanadium 40.9 mg/kg 6.8 04/26/15 09:53 EPA 7471 Mercury 0.015 mg/kg 0.011 04/22/15 10:37 ASTM D2974-87 Percent Moisture 25.8 % 0.10 04/21/15 15:54 EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 04/20/15 15:50 EPA 9060 Total Organic Carbon 1340 mg/kg 808 05/04/15 09:08 EPA 9060 Total Organic Carbon 1520 mg/kg 805 05/04/15 09:13 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f ig'8ygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040280 Pace Project No.: 92245409 Lab Sample ID Method Client Sample ID Parameters 92245409002 2015010462 EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% 92245409003 2015010463 EPA 6010 Aluminum EPA 6010 Barium EPA 6010 Beryllium EPA 6010 Calcium EPA 6010 Chromium EPA 6010 Copper EPA 6010 Iron EPA 6010 Magnesium EPA 6010 Manganese EPA 6010 Nickel EPA 6010 Potassium EPA 6010 Sodium EPA 6010 Strontium EPA 6010 Zinc EPA 6020 Cobalt EPA 6020 Lead EPA 6020 Vanadium EPA 7471 Mercury ASTM D2974-87 Percent Moisture EPA 9045 pH at 25 Degrees C EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 1490 mg/kg 804 05/04/15 09:20 1450 mg/kg 811 05/04/15 09:26 1450 mg/kg 807 05/04/15 09:08 5.4 % 05/04/15 09:08 6000 mg/kg 6.2 04/20/1518:57 44.5 mg/kg 0.62 04/20/1518:57 0.62 mg/kg 0.31 04/21/1510:10 55.0 mg/kg 30.9 04/20/1518:57 11.9 mg/kg 1.5 04/21/1510:10 6.3 mg/kg 1.5 04/21/1510:10 11400 mg/kg 2.5 04/20/1518:57 1370 mg/kg 30.9 04/20/1518:57 455 mg/kg 1.5 04/21/1510:10 3.2 mg/kg 0.31 04/20/1518:57 171 mg/kg 61.8 04/20/1518:57 34AJ mg/kg 61.8 04/20/1518:57 2.1 mg/kg 0.62 04/20/1518:57 16.2 mg/kg 1.2 04/20/1518:57 15.2 mg/kg 6.2 04/26/15 09:55 9.3 mg/kg 6.2 04/26/15 09:55 32.5 mg/kg 6.2 04/26/15 09:55 0.026 mg/kg 0.0097 04/22/1510:39 21.1 % 0.10 04/21/1515:56 5.8 Std. Units 0.10 04/17/15 10:50 H3 855 mg/kg 758 05/04/15 09:33 843 mg/kg 759 05/04/15 09:38 915 mg/kg 763 05/04/15 09:44 817 mg/kg 753 05/04/15 09:50 857 mg/kg 758 05/04/15 09:33 4.8 % 05/04/15 09:33 92245409004 2015010464 EPA 6010 Aluminum 4900 mg/kg 6.5 04/20/15 19:01 EPA 6010 Barium 43.5 mg/kg 0.65 04/20/15 19:01 EPA 6010 Beryllium 0.49 mg/kg 0.065 04/20/15 19:01 EPA 6010 Calcium 139 mg/kg 32.6 04/20/15 19:01 EPA 6010 Chromium 10.3 mg/kg 0.33 04/20/15 19:01 EPA 6010 Copper 4.9 mg/kg 0.33 04/20/15 19:01 EPA 6010 Iron 11200 mg/kg 2.6 04/20/15 19:01 EPA 6010 Magnesium 1180 mg/kg 32.6 04/20/15 19:01 EPA 6010 Manganese 325 mg/kg 0.33 04/20/15 19:01 EPA 6010 Nickel 2.6 mg/kg 0.33 04/20/15 19:01 EPA 6010 Potassium 172 mg/kg 65.1 04/20/15 19:01 EPA 6010 Sodium 63.8J mg/kg 65.1 04/20/15 19:01 EPA 6010 Strontium 2.6 mg/kg 0.65 04/20/15 19:01 EPA 6010 Zinc 12.6 mg/kg 1.3 04/20/15 19:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15040280 92245409 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92245409004 2015010464 EPA 6020 Cobalt 10.5 mg/kg 6.5 04/26/15 09:58 EPA 6020 Lead 13.5 mg/kg 6.5 04/26/15 09:58 EPA 6020 Vanadium 26.4 mg/kg 6.5 04/26/15 09:58 EPA 7471 Mercury 0.025 mg/kg 0.0098 04/22/15 10:45 ASTM D2974-87 Percent Moisture 19.4 % 0.10 04/21/15 15:56 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 04/17/15 10:50 H3 EPA 9060 Total Organic Carbon 1280 mg/kg 752 05/04/15 09:55 EPA 9060 Total Organic Carbon 1220 mg/kg 744 05/04/15 10:01 EPA 9060 Total Organic Carbon 1690 mg/kg 743 05/04/15 10:07 EPA 9060 Total Organic Carbon 1190 mg/kg 749 05/04/15 10:13 EPA 9060 Mean Total Organic Carbon 1350 mg/kg 747 05/04/15 09:55 EPA 9060 RSD% 17.3 % 05/04/15 09:55 92245409005 2015010465 EPA 6020A Aluminum 6.OJ ug/L 10.0 04/17/15 14:47 EPA 6020A Barium 1.6 ug/L 0.30 04/17/15 14:47 EPA 6020A Calcium 213 ug/L 40.0 04/17/15 14:47 EPA 6020A Chromium 10.7 ug/L 0.50 04/17/15 14:47 EPA 6020A Cobalt 0.191 ug/L 0.50 04/17/15 14:47 EPA 6020A Copper 0.74J ug/L 1.0 04/17/15 14:47 EPA 6020A Iron 76.3 ug/L 50.0 04/17/15 14:47 EPA 6020A Magnesium 67.6 ug/L 10.0 04/17/15 14:47 EPA 6020A Manganese 24.4 ug/L 0.50 04/17/15 14:47 EPA 6020A Molybdenum 0.15J ug/L 0.50 04/17/15 14:47 EPA 6020A Nickel 5.7 ug/L 0.50 04/17/15 14:47 EPA 6020A Potassium 675 ug/L 50.0 04/17/15 14:47 EPA 6020A Sodium 115 ug/L 50.0 04/17/15 14:47 EPA 6020A Strontium 1.6 ug/L 0.50 04/17/15 14:47 EPA 6020A Zinc 3.5J ug/L 5.0 04/17/15 14:47 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 yf ,,i&)rgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 05, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245086014 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188105) • Aluminum • Barium • Boron • Chromium • Iron • Manganese • Molybdenum • MSD (Lab ID: 1188106) • Aluminum • Barium • Boron • Iron • Manganese • Molybdenum R1: RPD value was outside control limits. • MSD (Lab ID: 1188106) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 05, 2015 QC Batch: MPRP/23700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245086014 R1: RPD value was outside control limits. • Manganese Additional Comments: Batch Comments: Samples on this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14486 Analyte Comments: QC Batch: MPRP/23700 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1188105) • Iron • MSD (Lab ID: 1188106) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 05, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23701 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244601001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188109) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Thallium • Vanadium • MSD (Lab ID: 1188110) • Antimony • Arsenic • Cadmium • Cobalt • Lead REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 05, 2015 QC Batch: MPRP/23701 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244601001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Selenium • Thallium • Vanadium Additional Comments: Analyte Comments: QC Batch: MPRP/23701 N2: The lab does not hold TNI accreditation for this parameter. •2015010461 (Lab ID:92245409001) • Antimony •2015010462 (Lab ID:92245409002) • Antimony •2015010463 (Lab ID:92245409003) • Antimony •2015010464 (Lab ID:92245409004) • Antimony • BLANK (Lab ID: 1188107) • Antimony • LCS (Lab ID: 1188108) • Antimony • MS (Lab ID: 1188109) • Antimony • MSD (Lab ID: 1188110) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf�nic&)rgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 05, 2015 General Information: 1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K2'8ygw.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: May 05, 2015 General Information: 1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KS'8ygw.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 05, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4'8ygw.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 05, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015010463 (Lab ID:92245409003) •2015010464 (Lab ID:92245409004) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 05, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45547 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010461 (Lab ID:92245409001) • Chloride • Sulfate •2015010462 (Lab ID:92245409002) • Chloride • Sulfate •2015010463 (Lab ID:92245409003) • Chloride • Sulfate •2015010464 (Lab ID:92245409004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 05, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015010461 (Lab ID:92245409001) •2015010462 (Lab ID:92245409002) •2015010463 (Lab ID:92245409003) •2015010464 (Lab ID:92245409004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 if '8ygw.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040280 Pace Project No.: 92245409 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 05, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010461 Lab ID: 92245409001 Collected: 04/10/15 09:15 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 7530 mg/kg 6.4 3.2 1 04/20/15 03:50 04/20/15 18:48 7429-90-5 Barium 70.7 mg/kg 0.64 0.32 1 04/20/15 03:50 04/20/15 18:48 7440-39-3 Beryllium 0.62 mg/kg 0.064 0.032 1 04/20/15 03:50 04/20/15 18:48 7440-41-7 Boron ND mg/kg 3.2 1.6 1 04/20/15 03:50 04/20/15 18:48 7440-42-8 Calcium 135 mg/kg 31.9 16.0 1 04/20/15 03:50 04/20/15 18:48 7440-70-2 Chromium 10.8 mg/kg 0.32 0.16 1 04/20/15 03:50 04/20/15 18:48 7440-47-3 Copper 5.6 mg/kg 0.32 0.16 1 04/20/15 03:50 04/20/15 18:48 7440-50-8 Iron 13300 mg/kg 2.6 1.3 1 04/20/15 03:50 04/20/15 18:48 7439-89-6 Magnesium 1330 mg/kg 31.9 16.0 1 04/20/15 03:50 04/20/15 18:48 7439-95-4 Manganese 513 mg/kg 0.32 0.16 1 04/20/15 03:50 04/20/15 18:48 7439-96-5 Molybdenum ND mg/kg 0.64 0.32 1 04/20/15 03:50 04/20/15 18:48 7439-98-7 Nickel 3.4 mg/kg 0.32 0.16 1 04/20/15 03:50 04/20/15 18:48 7440-02-0 Potassium 97.8 mg/kg 63.8 31.9 1 04/20/15 03:50 04/20/15 18:48 7440-09-7 Sodium ND mg/kg 63.8 31.9 1 04/20/15 03:50 04/20/15 18:48 7440-23-5 Strontium 3.1 mg/kg 0.64 0.32 1 04/20/15 03:50 04/20/15 18:48 7440-24-6 Zinc 24.8 mg/kg 1.3 0.64 1 04/20/15 03:50 04/20/15 18:48 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.4 3.2 100 04/20/15 03:50 04/26/15 09:51 7440-36-0 N2 Arsenic ND mg/kg 6.4 3.2 100 04/20/15 03:50 04/26/15 09:51 7440-38-2 Cadmium ND mg/kg 0.77 0.38 100 04/20/15 03:50 04/26/15 09:51 7440-43-9 Cobalt 21.2 mg/kg 6.4 3.2 100 04/20/15 03:50 04/26/15 09:51 7440-48-4 Lead 12.3 mg/kg 6.4 3.2 100 04/20/15 03:50 04/26/15 09:51 7439-92-1 Selenium ND mg/kg 6.4 3.2 100 04/20/15 03:50 04/26/15 09:51 7782-49-2 Thallium ND mg/kg 6.4 3.2 100 04/20/15 03:50 04/26/15 09:51 7440-28-0 Vanadium 35.9 mg/kg 6.4 3.2 100 04/20/15 03:50 04/26/15 09:51 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.034 mg/kg 0.0099 0.0050 1 04/21/1514:55 04/22/1510:35 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 22.3 % 0.10 0.10 1 04/21/15 15:54 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 0.10 1 04/20/15 15:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 320 160 5 04/18/1518:22 16887-00-6 D3 Sulfate ND mg/kg 320 160 5 04/18/1518:22 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 32.0 16.0 5 04/18/15 18:22 14797-55-8 H3 Date: 05/05/2015 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010461 Lab ID: 92245409001 Collected: 04/10/15 09:15 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2300 mg/kg 777 388 1 05/04/15 07:55 7440-44-0 Total Organic Carbon 2940 mg/kg 776 388 1 05/04/15 08:01 7440-44-0 Total Organic Carbon 2690 mg/kg 773 386 1 05/04/15 08:07 7440-44-0 Total Organic Carbon 2600 mg/kg 772 386 1 05/04/15 08:13 7440-44-0 Mean Total Organic Carbon 2630 mg/kg 774 387 1 05/04/15 07:55 7440-44-0 Surrogates RSD% 10 % 1 05/04/15 07:55 Date: 05/05/2015 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010462 Lab ID: 92245409002 Collected: 04/10/15 09:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 7650 mg/kg 6.8 3.4 1 04/20/15 03:50 04/20/15 18:53 7429-90-5 Barium 59.3 mg/kg 0.68 0.34 1 04/20/15 03:50 04/20/15 18:53 7440-39-3 Beryllium 0.77 mg/kg 0.34 0.17 5 04/20/15 03:50 04/21/15 10:06 7440-41-7 Boron ND mg/kg 17.0 8.5 5 04/20/15 03:50 04/21/15 10:06 7440-42-8 Calcium 80.1 mg/kg 34.1 17.0 1 04/20/15 03:50 04/20/15 18:53 7440-70-2 Chromium 14.1 mg/kg 1.7 0.85 5 04/20/15 03:50 04/21/15 10:06 7440-47-3 Copper 7.2 mg/kg 1.7 0.85 5 04/20/15 03:50 04/21/15 10:06 7440-50-8 Iron 14300 mg/kg 2.7 1.4 1 04/20/15 03:50 04/20/15 18:53 7439-89-6 Magnesium 1610 mg/kg 34.1 17.0 1 04/20/15 03:50 04/20/15 18:53 7439-95-4 Manganese 505 mg/kg 1.7 0.85 5 04/20/15 03:50 04/21/15 10:06 7439-96-5 Molybdenum ND mg/kg 0.68 0.34 1 04/20/15 03:50 04/20/15 18:53 7439-98-7 Nickel 3.8 mg/kg 0.34 0.17 1 04/20/15 03:50 04/20/15 18:53 7440-02-0 Potassium 155 mg/kg 68.1 34.1 1 04/20/15 03:50 04/20/15 18:53 7440-09-7 Sodium ND mg/kg 68.1 34.1 1 04/20/15 03:50 04/20/15 18:53 7440-23-5 Strontium 3.0 mg/kg 0.68 0.34 1 04/20/15 03:50 04/20/15 18:53 7440-24-6 Zinc 20.5 mg/kg 1.4 0.68 1 04/20/15 03:50 04/20/15 18:53 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.8 3.4 100 04/20/15 03:50 04/26/15 09:53 7440-36-0 N2 Arsenic ND mg/kg 6.8 3.4 100 04/20/15 03:50 04/26/15 09:53 7440-38-2 Cadmium ND mg/kg 0.82 0.41 100 04/20/15 03:50 04/26/15 09:53 7440-43-9 Cobalt 12.1 mg/kg 6.8 3.4 100 04/20/15 03:50 04/26/15 09:53 7440-48-4 Lead 10 mg/kg 6.8 3.4 100 04/20/15 03:50 04/26/15 09:53 7439-92-1 Selenium ND mg/kg 6.8 3.4 100 04/20/15 03:50 04/26/15 09:53 7782-49-2 Thallium ND mg/kg 6.8 3.4 100 04/20/15 03:50 04/26/15 09:53 7440-28-0 Vanadium 40.9 mg/kg 6.8 3.4 100 04/20/15 03:50 04/26/15 09:53 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.015 mg/kg 0.011 0.0054 1 04/21/1514:55 04/22/1510:37 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 25.8 % 0.10 0.10 1 04/21/15 15:54 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 0.10 1 04/20/15 15:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 331 165 5 04/18/1518:44 16887-00-6 D3 Sulfate ND mg/kg 331 165 5 04/18/1518:44 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.1 16.5 5 04/18/15 18:44 14797-55-8 H3 Date: 05/05/2015 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �nic&ygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010462 Lab ID: 92245409002 Collected: 04/10/15 09:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1340 mg/kg 808 404 1 05/04/15 09:08 7440-44-0 Total Organic Carbon 1520 mg/kg 805 402 1 05/04/15 09:13 7440-44-0 Total Organic Carbon 1490 mg/kg 804 402 1 05/04/15 09:20 7440-44-0 Total Organic Carbon 1450 mg/kg 811 406 1 05/04/15 09:26 7440-44-0 Mean Total Organic Carbon 1450 mg/kg 807 404 1 05/04/15 09:08 7440-44-0 Surrogates RSD% 5.4 % 1 05/04/15 09:08 Date: 05/05/2015 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010463 Lab ID: 92245409003 Collected: 04/10/15 10:11 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/05/2015 11:50 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6000 mg/kg 6.2 3.1 1 04/20/15 03:50 04/20/15 18:57 7429-90-5 44.5 mg/kg 0.62 0.31 1 04/20/15 03:50 04/20/15 18:57 7440-39-3 0.62 mg/kg 0.31 0.15 5 04/20/15 03:50 04/21/15 10:10 7440-41-7 ND mg/kg 15.4 7.7 5 04/20/15 03:50 04/21/15 10:10 7440-42-8 55.0 mg/kg 30.9 15.4 1 04/20/15 03:50 04/20/15 18:57 7440-70-2 11.9 mg/kg 1.5 0.77 5 04/20/15 03:50 04/21/15 10:10 7440-47-3 6.3 mg/kg 1.5 0.77 5 04/20/15 03:50 04/21/15 10:10 7440-50-8 11400 mg/kg 2.5 1.2 1 04/20/15 03:50 04/20/15 18:57 7439-89-6 1370 mg/kg 30.9 15.4 1 04/20/15 03:50 04/20/15 18:57 7439-95-4 455 mg/kg 1.5 0.77 5 04/20/15 03:50 04/21/15 10:10 7439-96-5 ND mg/kg 0.62 0.31 1 04/20/15 03:50 04/20/15 18:57 7439-98-7 3.2 mg/kg 0.31 0.15 1 04/20/15 03:50 04/20/15 18:57 7440-02-0 171 mg/kg 61.8 30.9 1 04/20/15 03:50 04/20/15 18:57 7440-09-7 34AJ mg/kg 61.8 30.9 1 04/20/15 03:50 04/20/15 18:57 7440-23-5 2.1 mg/kg 0.62 0.31 1 04/20/15 03:50 04/20/15 18:57 7440-24-6 16.2 mg/kg 1.2 0.62 1 04/20/15 03:50 04/20/15 18:57 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.2 3.1 100 04/20/15 03:50 04/26/15 09:55 7440-36-0 ND mg/kg 6.2 3.1 100 04/20/15 03:50 04/26/15 09:55 7440-38-2 ND mg/kg 0.74 0.37 100 04/20/15 03:50 04/26/15 09:55 7440-43-9 15.2 mg/kg 6.2 3.1 100 04/20/15 03:50 04/26/15 09:55 7440-48-4 9.3 mg/kg 6.2 3.1 100 04/20/15 03:50 04/26/15 09:55 7439-92-1 ND mg/kg 6.2 3.1 100 04/20/15 03:50 04/26/15 09:55 7782-49-2 ND mg/kg 6.2 3.1 100 04/20/15 03:50 04/26/15 09:55 7440-28-0 32.5 mg/kg 6.2 3.1 100 04/20/15 03:50 04/26/15 09:55 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.026 mg/kg 0.0097 0.0049 1 04/21/1514:55 04/22/1510:39 7439-97-6 Analytical Method: ASTM D2974-87 21.1 % 0.10 0.10 1 04/21/1515:56 Analytical Method: EPA 9045 5.8 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 318 159 5 ND mg/kg 318 159 5 Analytical Method: EPA 9056 ND mg/kg 31.8 15.9 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [8Llfrif6illito .7t, N2 04/18/1519:05 16887-00-6 D3 04/18/1519:05 14808-79-8 D3 04/18/1519:05 14797-55-8 H3 Page 24 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t S,8ygw.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010463 Lab ID: 92245409003 Collected: 04/10/15 10:11 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 855 mg/kg 758 379 1 05/04/15 09:33 7440-44-0 Total Organic Carbon 843 mg/kg 759 379 1 05/04/15 09:38 7440-44-0 Total Organic Carbon 915 mg/kg 763 381 1 05/04/15 09:44 7440-44-0 Total Organic Carbon 817 mg/kg 753 376 1 05/04/15 09:50 7440-44-0 Mean Total Organic Carbon 857 mg/kg 758 379 1 05/04/15 09:33 7440-44-0 Surrogates RSD% 4.8 % 1 05/04/15 09:33 Date: 05/05/2015 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4,8ygw.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010464 Lab ID: 92245409004 Collected: 04/10/15 10:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/05/2015 11:50 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 4900 mg/kg 6.5 3.3 1 04/20/15 03:50 04/20/15 19:01 7429-90-5 43.5 mg/kg 0.65 0.33 1 04/20/15 03:50 04/20/15 19:01 7440-39-3 0.49 mg/kg 0.065 0.033 1 04/20/15 03:50 04/20/15 19:01 7440-41-7 ND mg/kg 3.3 1.6 1 04/20/15 03:50 04/20/15 19:01 7440-42-8 139 mg/kg 32.6 16.3 1 04/20/15 03:50 04/20/15 19:01 7440-70-2 10.3 mg/kg 0.33 0.16 1 04/20/15 03:50 04/20/15 19:01 7440-47-3 4.9 mg/kg 0.33 0.16 1 04/20/15 03:50 04/20/15 19:01 7440-50-8 11200 mg/kg 2.6 1.3 1 04/20/15 03:50 04/20/15 19:01 7439-89-6 1180 mg/kg 32.6 16.3 1 04/20/15 03:50 04/20/15 19:01 7439-95-4 325 mg/kg 0.33 0.16 1 04/20/15 03:50 04/20/15 19:01 7439-96-5 ND mg/kg 0.65 0.33 1 04/20/15 03:50 04/20/15 19:01 7439-98-7 2.6 mg/kg 0.33 0.16 1 04/20/15 03:50 04/20/15 19:01 7440-02-0 172 mg/kg 65.1 32.6 1 04/20/15 03:50 04/20/15 19:01 7440-09-7 63.8J mg/kg 65.1 32.6 1 04/20/15 03:50 04/20/15 19:01 7440-23-5 2.6 mg/kg 0.65 0.33 1 04/20/15 03:50 04/20/15 19:01 7440-24-6 12.6 mg/kg 1.3 0.65 1 04/20/15 03:50 04/20/15 19:01 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:58 7440-36-0 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:58 7440-38-2 ND mg/kg 0.78 0.39 100 04/20/15 03:50 04/26/15 09:58 7440-43-9 10.5 mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:58 7440-48-4 13.5 mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:58 7439-92-1 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:58 7782-49-2 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:58 7440-28-0 26.4 mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:58 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.025 mg/kg 0.0098 0.0049 1 04/21/1514:55 04/22/1510:45 7439-97-6 Analytical Method: ASTM D2974-87 19.4 % 0.10 0.10 1 04/21/1515:56 Analytical Method: EPA 9045 4.9 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 312 156 5 ND mg/kg 312 156 5 Analytical Method: EPA 9056 ND mg/kg 31.2 15.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [8Llfrif6illito .7t, N2 04/18/1519:27 16887-00-6 D3 04/18/1519:27 14808-79-8 D3 04/18/1519:27 14797-55-8 H3 Page 26 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010464 Lab ID: 92245409004 Collected: 04/10/15 10:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1280 mg/kg 752 376 1 05/04/15 09:55 7440-44-0 Total Organic Carbon 1220 mg/kg 744 372 1 05/04/15 10:01 7440-44-0 Total Organic Carbon 1690 mg/kg 743 372 1 05/04/15 10:07 7440-44-0 Total Organic Carbon 1190 mg/kg 749 374 1 05/04/15 10:13 7440-44-0 Mean Total Organic Carbon 1350 mg/kg 747 373 1 05/04/15 09:55 7440-44-0 Surrogates RSD% 17.3 % 1 05/04/15 09:55 Date: 05/05/2015 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040280 Pace Project No.: 92245409 Sample: 2015010465 Lab ID: 92245409005 Collected: 04/10/15 08:45 Received: 04/14/15 15:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 05/05/2015 11:50 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 6.OJ ug/L 10.0 3.0 1 04/17/15 08:56 04/17/15 14:47 7429-90-5 ND ug/L 0.50 0.15 1 04/17/15 08:56 04/17/15 14:47 7440-36-0 ND ug/L 0.50 0.11 1 04/17/15 08:56 04/17/15 14:47 7440-38-2 1.6 ug/L 0.30 0.081 1 04/17/15 08:56 04/17/15 14:47 7440-39-3 ND ug/L 0.20 0.067 1 04/17/15 08:56 04/17/15 14:47 7440-41-7 ND ug/L 5.0 1.1 1 04/17/15 08:56 04/17/15 14:47 7440-42-8 ND ug/L 0.080 0.024 1 04/17/15 08:56 04/17/15 14:47 7440-43-9 213 ug/L 40.0 16.0 1 04/17/15 08:56 04/17/15 14:47 7440-70-2 10.7 ug/L 0.50 0.17 1 04/17/15 08:56 04/17/15 14:47 7440-47-3 0.191 ug/L 0.50 0.13 1 04/17/15 08:56 04/17/15 14:47 7440-48-4 0.74J ug/L 1.0 0.21 1 04/17/15 08:56 04/17/15 14:47 7440-50-8 76.3 ug/L 50.0 13.7 1 04/17/15 08:56 04/17/15 14:47 7439-89-6 ND ug/L 0.10 0.046 1 04/17/15 08:56 04/17/15 14:47 7439-92-1 67.6 ug/L 10.0 3.2 1 04/17/15 08:56 04/17/15 14:47 7439-95-4 24.4 ug/L 0.50 0.24 1 04/17/15 08:56 04/17/15 14:47 7439-96-5 0.15J ug/L 0.50 0.094 1 04/17/15 08:56 04/17/15 14:47 7439-98-7 5.7 ug/L 0.50 0.16 1 04/17/15 08:56 04/17/15 14:47 7440-02-0 675 ug/L 50.0 11.7 1 04/17/15 08:56 04/17/15 14:47 7440-09-7 ND ug/L 0.50 0.20 1 04/17/15 08:56 04/17/15 14:47 7782-49-2 115 ug/L 50.0 16.3 1 04/17/15 08:56 04/17/15 14:47 7440-23-5 1.6 ug/L 0.50 0.13 1 04/17/15 08:56 04/17/15 14:47 7440-24-6 ND ug/L 0.10 0.015 1 04/17/15 08:56 04/17/15 14:47 7440-28-0 ND ug/L 1.0 0.28 1 04/17/15 08:56 04/17/15 14:47 7440-62-2 3.5J ug/L 5.0 2.4 1 04/17/15 08:56 04/17/15 14:47 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/17/1513:50 04/19/1517:59 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: MERP/13262 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92245409005 METHOD BLANK: 1941653 Matrix: Water Associated Lab Samples: 92245409005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/19/1517:25 LABORATORY CONTROL SAMPLE: 1941654 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1941655 1941656 MS MSD 10302585001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 4.8 98 96 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: MERP/5609 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 METHOD BLANK: 1189243 Matrix: Solid Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0084 04/22/1510:13 LABORATORY CONTROL SAMPLE: 1189244 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.076 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1189389 1189390 MS MSD 92245417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.029 .108 .111 0.11 0.12 80 80 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: MPRP/23700 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 METHOD BLANK: 1188103 Matrix: Solid Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.0 04/20/1515:03 Barium mg/kg ND 0.50 04/20/1515:03 Beryllium mg/kg ND 0.050 04/20/1515:03 Boron mg/kg ND 2.5 04/20/1515:03 Calcium mg/kg ND 25.1 04/20/1515:03 Chromium mg/kg ND 0.25 04/20/1515:03 Copper mg/kg ND 0.25 04/20/1515:03 Iron mg/kg ND 2.0 04/20/1515:03 Magnesium mg/kg ND 25.1 04/20/1515:03 Manganese mg/kg ND 0.25 04/20/1515:03 Molybdenum mg/kg ND 0.50 04/20/1515:03 Nickel mg/kg ND 0.25 04/20/1515:03 Potassium mg/kg ND 50.2 04/20/1515:03 Sodium mg/kg ND 50.2 04/20/1515:03 Strontium mg/kg ND 0.50 04/20/1515:03 Zinc mg/kg ND 1.0 04/20/1515:03 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1188104 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 123 128 104 80-120 Barium mg/kg 12.3 12.8 104 80-120 Beryllium mg/kg 1.2 1.3 103 80-120 Boron mg/kg 123 124 101 80-120 Calcium mg/kg 616 653 106 80-120 Chromium mg/kg 12.3 12.5 102 80-120 Copper mg/kg 12.3 12.2 99 80-120 Iron mg/kg 123 128 104 80-120 Magnesium mg/kg 616 641 104 80-120 Manganese mg/kg 12.3 12.7 103 80-120 Molybdenum mg/kg 12.3 12.4 100 80-120 Nickel mg/kg 12.3 12.8 104 80-120 Potassium mg/kg 616 634 103 80-120 Sodium mg/kg 616 661 107 80-120 Strontium mg/kg 12.3 12.6 102 80-120 Zinc mg/kg 61.6 63.8 104 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188105 1188106 MS MSD 92245086014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 9620 168 177 12500 13300 1720 2080 75-125 6 20 M1 Barium mg/kg 33.7 16.8 17.7 62.3 61.8 170 159 75-125 1 20 M1 Beryllium mg/kg 0.21 1.65 1.79 1.6 1.7 85 84 75-125 3 20 Boron mg/kg ND 168 177 113 115 67 65 75-125 2 20 M1 Calcium mg/kg 102 841 885 842 898 88 90 75-125 6 20 Chromium mg/kg 24.2 16.8 17.7 33.4 40.3 55 91 75-125 19 20 M1 Copper mg/kg 15.4 16.8 17.7 30.8 32.9 92 99 75-125 7 20 Iron mg/kg 43500 168 177 29000 33400 -8640 -5690 75-125 14 20 E,M1 Magnesium mg/kg 1120 841 885 2110 2080 118 109 75-125 1 20 Manganese mg/kg 203 16.8 17.7 254 320 302 662 75-125 23 20 M1,R1 Molybdenum mg/kg ND 16.8 17.7 10.2 9.9 60 55 75-125 4 20 M1 Nickel mg/kg 2.3 16.8 17.7 18.2 18.8 95 93 75-125 3 20 Potassium mg/kg 793 841 885 1820 1820 122 116 75-125 0 20 Sodium mg/kg ND 841 885 796 843 95 95 75-125 6 20 Strontium mg/kg 2.2 16.8 17.7 17.3 18.1 90 90 75-125 5 20 Zinc mg/kg 11.6 84.1 88.5 87.8 92.4 91 91 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: MPRP/23701 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 METHOD BLANK: 1188107 Matrix: Solid Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/26/15 09:21 N2 Arsenic mg/kg ND 0.051 04/26/15 09:21 Cadmium mg/kg ND 0.0061 04/26/15 09:21 Cobalt mg/kg ND 0.051 04/26/15 09:21 Lead mg/kg ND 0.051 04/26/15 09:21 Selenium mg/kg ND 0.051 04/26/15 09:21 Thallium mg/kg ND 0.051 04/26/15 09:21 Vanadium mg/kg ND 0.051 04/26/15 09:21 LABORATORY CONTROL SAMPLE: 1188108 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 101 80-120 N2 Arsenic mg/kg 2.5 2.6 104 80-120 Cadmium mg/kg .25 0.25 100 80-120 Cobalt mg/kg 2.5 2.7 106 80-120 Lead mg/kg 2.5 2.6 103 80-120 Selenium mg/kg 2.5 2.7 107 80-120 Thallium mg/kg 2.5 2.6 103 80-120 Vanadium mg/kg 2.5 2.7 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188109 1188110 MS MSD 92244601001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.4 2.5 4.6J 4.6J 176 174 75-125 20 M6, N2 Arsenic mg/kg ND 2.4 2.5 5.6 4.3J 212 157 75-125 20 M6 Cadmium mg/kg ND .24 .25 0.97 1.1 359 390 75-125 10 20 M6 Cobalt mg/kg ND 2.4 2.5 15.5 16.6 600 626 75-125 6 20 M6 Lead mg/kg ND 2.4 2.5 17.8 18.4 536 547 75-125 3 20 M6 Selenium mg/kg ND 2.4 2.5 3.OJ ND 113 59 75-125 20 M6 Thallium mg/kg ND 2.4 2.5 12.8 12.9 504 492 75-125 0 20 M6 Vanadium mg/kg ND 2.4 2.5 72.9 80.0 2980 3190 75-125 9 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: MPRP/53693 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92245409005 METHOD BLANK: 1941663 Associated Lab Samples: 92245409005 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.30 04/17/1513:59 ND 0.20 04/17/1513:59 ND 5.0 04/17/1513:59 ND 0.080 04/17/1513:59 ND 40.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.50 04/17/1513:59 ND 1.0 04/17/1513:59 ND 50.0 04/17/1513:59 ND 0.10 04/17/1513:59 ND 10.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.50 04/17/1513:59 ND 50.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 50.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.10 04/17/1513:59 ND 1.0 04/17/1513:59 ND 5.0 04/17/1513:59 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1941664 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 82.3 103 80-120 Antimony ug/L 80 80.8 101 80-120 Arsenic ug/L 80 81.2 102 80-120 Barium ug/L 80 80.2 100 80-120 Beryllium ug/L 80 86.2 108 80-120 Boron ug/L 80 87.1 109 80-120 Cadmium ug/L 80 84.6 106 80-120 Calcium ug/L 1000 1010 101 80-120 Chromium ug/L 80 85.1 106 80-120 Cobalt ug/L 80 84.6 106 80-120 Copper ug/L 80 79.7 100 80-120 Iron ug/L 1000 1050 105 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 LABORATORY CONTROL SAMPLE: 1941664 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 84.2 105 80-120 Magnesium ug/L 1000 1020 102 80-120 Manganese ug/L 80 85.3 107 80-120 Molybdenum ug/L 80 80.9 101 80-120 Nickel ug/L 80 85.0 106 80-120 Potassium ug/L 1000 1020 102 80-120 Selenium ug/L 80 82.6 103 80-120 Sodium ug/L 1000 1010 101 80-120 Strontium ug/L 80 81.1 101 80-120 Thallium ug/L 80 85.2 107 80-120 Vanadium ug/L 80 83.9 105 80-120 Zinc ug/L 80 84.8 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1941683 1941684 MS MSD 92245394017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 12.3 80 80 101 101 111 110 75-125 0 20 Antimony ug/L ND 80 80 82.3 81.2 103 101 75-125 1 20 Arsenic ug/L ND 80 80 82.8 81.7 104 102 75-125 1 20 Barium ug/L 0.23J 80 80 82.5 82.6 103 103 75-125 0 20 Beryllium ug/L ND 80 80 88.3 88.6 110 111 75-125 0 20 Boron ug/L ND 80 80 88.6 88.7 111 111 75-125 0 20 Cadmium ug/L ND 80 80 85.8 84.8 107 106 75-125 1 20 Calcium ug/L 169 1000 1000 1200 1180 103 101 75-125 2 20 Chromium ug/L ND 80 80 87.7 86.6 109 108 75-125 1 20 Cobalt ug/L ND 80 80 86.6 85.9 108 107 75-125 1 20 Copper ug/L 0.41J 80 80 81.7 80.6 102 100 75-125 1 20 Iron ug/L 37.9J 1000 1000 1110 1100 107 106 75-125 1 20 Lead ug/L ND 80 80 88.0 86.6 110 108 75-125 2 20 Magnesium ug/L 9.91 1000 1000 1080 1070 107 106 75-125 1 20 Manganese ug/L 0.38J 80 80 88.4 87.4 110 109 75-125 1 20 Molybdenum ug/L 0.30J 80 80 82.7 80.8 103 101 75-125 2 20 Nickel ug/L ND 80 80 87.3 86.2 109 108 75-125 1 20 Potassium ug/L 23.6J 1000 1000 1080 1060 105 103 75-125 2 20 Selenium ug/L ND 80 80 86.0 84.5 108 106 75-125 2 20 Sodium ug/L 30.6J 1000 1000 1090 1070 106 104 75-125 2 20 Strontium ug/L 0.36J 80 80 83.9 82.2 104 102 75-125 2 20 Thallium ug/L ND 80 80 87.7 86.0 110 107 75-125 2 20 Vanadium ug/L ND 80 80 86.2 85.3 108 107 75-125 1 20 Zinc ug/L ND 80 80 87.6 86.4 107 106 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: PMST/3462 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 SAMPLE DUPLICATE: 1189700 92245417001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 26.2 26.1 0 10 SAMPLE DUPLICATE: 1189701 92245394003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 24.2 24.7 2 10 SAMPLE DUPLICATE: 1189702 92245394012 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.9 18.8 1 10 SAMPLE DUPLICATE: 1189703 35184627020 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 10.2 9.3 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: WET/36871 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92245409001, 92245409002 SAMPLE DUPLICATE: 1436225 92245394004 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.5 5.5 1 10 SAMPLE DUPLICATE: 1436226 92245394011 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.0 5.1 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: WET/36878 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92245409003, 92245409004 SAMPLE DUPLICATE: 1436453 92245618009 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.0 4.9 1 10 H3 SAMPLE DUPLICATE: 1436454 92245612008 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.7 5.8 2 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: WETA/45547 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 METHOD BLANK: 1187883 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.4 04/18/1510:53 Sulfate mg/kg ND 49.4 04/18/1510:53 LABORATORY CONTROL SAMPLE: 1187884 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1187886 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1187885 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 493 469 95 80-120 493 469 95 80-120 92245394002 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 587 576 80 80-120 ND 587 646 90 80-120 92245394002 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: WETA/45546 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 METHOD BLANK: 1187879 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 04/18/15 10:53 LABORATORY CONTROL SAMPLE: 1187880 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.3 47.9 97 80-120 MATRIX SPIKE SAMPLE: 1187882 92245394002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 58.7 60.2 103 80-120 H3 SAMPLE DUPLICATE: 1187881 92245394002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040280 Pace Project No.: 92245409 QC Batch: WETA/28295 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92245409001, 92245409002, 92245409003, 92245409004 METHOD BLANK: 1150532 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/04/15 07:11 LABORATORY CONTROL SAMPLE: 1150533 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 114000 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1150534 1150535 MS MSD 92245409001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 2630 7720 7710 11800 10400 118 101 50-150 12 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1150536 1150537 MS MSD 92245612009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 4910 12700 12700 18600 23200 108 145 50-150 22 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 41 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15040280 Pace Project No.: 92245409 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14486 Ill Samples on this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. E Analyte concentration exceeded the calibration range. The reported result is estimated. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/05/2015 11:50 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 45 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98001jinlc&ygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040280 Pace Project No.: 92245409 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92245409001 2015010461 EPA 3050 MPRP/23700 EPA 6010 92245409002 2015010462 EPA 3050 MPRP/23700 EPA 6010 92245409003 2015010463 EPA 3050 MPRP/23700 EPA 6010 92245409004 2015010464 EPA 3050 MPRP/23700 EPA 6010 92245409001 2015010461 EPA 3050 MPRP/23701 EPA 6020 92245409002 2015010462 EPA 3050 MPRP/23701 EPA 6020 92245409003 2015010463 EPA 3050 MPRP/23701 EPA 6020 92245409004 2015010464 EPA 3050 MPRP/23701 EPA 6020 92245409005 2015010465 EPA 3020 MPRP/53693 EPA 6020A 92245409005 2015010465 EPA 7470 MERP/13262 EPA 7470 92245409001 2015010461 EPA 7471 MERP/5609 EPA 7471 92245409002 2015010462 EPA 7471 MERP/5609 EPA 7471 92245409003 2015010463 EPA 7471 MERP/5609 EPA 7471 92245409004 2015010464 EPA 7471 MERP/5609 EPA 7471 92245409001 2015010461 ASTM D2974-87 PMST/3462 92245409002 2015010462 ASTM D2974-87 PMST/3462 92245409003 2015010463 ASTM D2974-87 PMST/3462 92245409004 2015010464 ASTM D2974-87 PMST/3462 92245409001 2015010461 EPA 9045 WET/36871 92245409002 2015010462 EPA 9045 WET/36871 92245409003 2015010463 EPA 9045 WET/36878 92245409004 2015010464 EPA 9045 WET/36878 92245409001 2015010461 EPA 9056 WETA/45547 92245409002 2015010462 EPA 9056 WETA/45547 92245409003 2015010463 EPA 9056 WETA/45547 92245409004 2015010464 EPA 9056 WETA/45547 92245409001 2015010461 EPA 9056 WETA/45546 92245409002 2015010462 EPA 9056 WETA/45546 92245409003 2015010463 EPA 9056 WETA/45546 92245409004 2015010464 EPA 9056 WETA/45546 92245409001 2015010461 EPA 9060 WETA/28295 92245409001 2015010461 EPA 9060 WETA/28296 92245409002 2015010462 EPA 9060 WETA/28295 92245409002 2015010462 EPA 9060 WETA/28296 92245409003 2015010463 EPA 9060 WETA/28295 92245409003 2015010463 EPA 9060 WETA/28296 92245409004 2015010464 EPA 9060 WETA/28295 92245409004 2015010464 EPA 9060 WETA/28296 Date: 05/05/2015 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14486 ICP/14486 ICP/14486 ICP/14486 ICPM/9634 ICPM/9634 ICPM/9634 ICPM/9634 ICPM/23840 MERC/15414 MERC/5599 MERC/5599 MERC/5599 MERC/5599 Page 43 of 45 Document Name: Document Revised: September LZ. 2-U14 Sample Condition Upon Receipt SCUR Pa e 1 of 2 -r` acehi lyflcaf Document Number; Issuing Authorif?. of 54 iI F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Name:, Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial❑ Pace Other Custody Seal on Cooler/Box Present: ❑ yes ©' no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble VDp ❑ Nubble Bags ❑ None ❑ Other Thermometer Used: 1R Gun T1401 Type of Ice: ke) Blue None D,Sra nples on ice, coaling process has begun Temp Correction Factor T1401 No Correction .0 co Biological Tissue is Frozen: Yes No NIA Date Corrected Cooler Temp.: Temp should be above freezing to 6°C Comments: Chain of Custody Present: ,ErYes ONO ❑NIA 1. Chain of Custody Filled Out: .2res ONO ❑NIA 12. Chain of Custody Relinquished: lutes ONO ❑NIA 3, Sampler Name & Signature on COC: Rles ONO ❑NIA 4. Samples Arrived within Hold Time: fires ❑No ❑NIA 6. Short hold Time Analysis (<72hr): Dyes Woo ❑NIA 6. Rush Turn Around Time Requested: Dyes Dt o ❑NIA 7. Sufficient Volume: dyes ONO ❑NIA & Correct Containers Used: ElYes ❑No ❑NIA 9. -Pace Containers Used: Dyes Of(. ❑NIA Containers Intact: l4es ONO ❑NtA 10. Filtered volume received for Dissolved tests Dyes ONO ❑NIA 11. Sample Labels match COC: s6Yes ONO ❑NIA 12. -Includes dateltime/ID/Analysis Matrix: A9 containers needing preservation have been checked. Dyes ONO l2f A 13, All containers needing preservation are found to be in Dyes ❑No 1;jNfA compliance with EPA recommendation. exceptions: VOA, coliform, TOG, O&G, wl-oRo (water) Dyes ❑No Samples checked for dechlorination: Dyes ONO ❑NIA Headspace in VOA Vials ( >6mm): Dyes ONO ❑NIA 15. ❑ ❑N ❑N!A 16 person examining Trip Blank Present: Yes o Trip Blank Custody Seals Present Dyes ONO ❑NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: 'Field Data Required? Y I N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: ! Date: t �l III~- SRF Review:rt✓I�t Date: ( [S / Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the Noah Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92Y45409 I1111111114091111111111111 Page 44 of 45 53 of 54 35 LO C 0 � • �— _ . �. _ .. J.'� . _ .. �` � � s. "' v� � � fit"! ��p .—A w; i �i r to r,:, f m z 3 Ic fj Ifl >i z Iql 4 '3 sr I Ll TT L 7)N ;? e co V) I M A R Uv'l41 ..... .... ... X 0 tj Mt Ell ro wil -Z L4 0 > 46 Ll I. Scu 01 j its ran At, "Grab ira i—T 8 (A MS • 0 z ti Q C 20rotal # of Containers th —4 LO z C� CPPage 45 of 45 I CHAIN OFGU`., - �DY RECORD AND ANALYSIS RE(- ------------------- An �sz onit al La mues ! I I PW I Of A I Ww $ DUKL Maip Cnde MC.OW;Z lfluddinU 7405� p DISTMUTHM i m3a Halpivs Fei ry Rd ji-I SZ q OZ -t amulmAL to LAS. il-awed BW s,,,,- wo� copy tq mAIENT (91MI 97"245 (.fpWW UVAt-4 Hurg'ar&Yme, h� C �%079 ENERGY* 1, -4 i V i To" Mi ee Pft -Z Np- - So" �MTSCe T jF4 � �FV. Urfa Ina -fimmc.�ll 1 UOK!15i ?)Njffi Code: L IP Opriole ---4, c -.1-b End lsfr t Mdlcbtmi. ibreas- t%W r p"*c, AEC 1pluft,lg an all 5 acrouMng fmirft xlx,r OF 7cowction infcwmation L L" Um MLY 1. Chem I "Sample DescriOon or ID nate7 -r-40 NpAuft -QmKtop l4o� 4rl 3W --H -5 416 19 F - Ei+ V,4� DatrtlTlarrE Ac IV. 3 J a S4 elk - �Lxk, UOIA—i 24pf'—"t-nt5 T Ci zsRe"esteff Tprinaround 14 Dav 41 ' Flay., -:14 Hr