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Home My WebLink AboutNC0003417_J15040238 Report_20150805DUE Analytical Laboratory Page 1of61 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15040238 HF LEE PLANT - AB GW ASSESSMENT SOIL Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer 1677 Old Smithfield Rd Goldsboro NC 27530, Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) y 2015.05.1810:43:12 Date: -04'00' Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/6/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015010244 HF LEE PLANT 07-Apr-15 1:52 PM Synterra LLMW-1 (8.5-9.5) 2015010245 HF LEE PLANT 07-Apr-15 4:45 PM Synterra LLMW-1 (16-18) 2015010246 HF LEE PLANT 07-Apr-15 11:20 AM Synterra Equipment Blank 3 Total Samples Page 2 of 61 Page 3 of 61 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 5/6/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040238 Site: LLMW-1 (8.5-9.5) Collection Date: 07-Apr-15 1:52 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 61 Sample #: 2015010244 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040238 Site: LLMW-1 (16-18) Collection Date: 07-Apr-15 4:45 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 61 Sample #: 2015010245 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040238 Site: Equipment Blank Collection Date: 07-Apr-15 11:20 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015010246 Matrix: SOIL Page 6 of 61 Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. qpgQ. ,C 8y ft.. Suite 100 �Huntersville, INC 28078 (704)875-9092 April 27, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15040238 Pace Project No.: 92245087 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 10, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 54 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. GORRigwifte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040238 Pace Project No.: 92245087 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. qP2Q.�C§'8y fte. Suite 100 �Huntersville, NC 28078 (704)875-9092 Project: J15040238 Pace Project No.: 92245087 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0g8pli6'8y fte. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15040238 Pace Project No.: 92245087 Lab ID Sample ID Matrix Date Collected Date Received 92245087001 2015010244 Solid 04/07/1513:52 04/10/15 16:35 92245087002 2015010245 Solid 04/07/1516:45 04/10/15 16:35 92245087003 2015010244 SPLP Water 04/07/15 13:52 04/10/15 16:35 92245087004 2015010245 SPLP Water 04/07/15 16:45 04/10/15 16:35 92245087005 2015010246 Water 04107/1511:20 04/10/15 16:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflinlc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15040238 Pace Project No.: 92245087 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92245087001 2015010244 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245087002 2015010245 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245087003 2015010244 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A LMW 1 PASI-M 92245087004 2015010245 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A LMW 1 PASI-M 92245087005 2015010246 EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040238 Pace Project No.: 92245087 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245087001 2015010244 EPA 6010 Aluminum 15200 mg/kg 32.3 04/25/15 16:50 EPA 6010 Barium 71.2 mg/kg 3.2 04/25/15 16:50 EPA 6010 Beryllium 1.0 mg/kg 0.32 04/25/15 16:50 EPA 6010 Calcium 435 mg/kg 162 04/25/15 16:50 EPA 6010 Chromium 16.8 mg/kg 1.6 04/25/15 16:50 EPA 6010 Copper 9.6 mg/kg 1.6 04/25/15 16:50 EPA 6010 Iron 16400 mg/kg 12.9 04/25/15 16:50 EPA 6010 Magnesium 997 mg/kg 162 04/25/15 16:50 EPA 6010 Manganese 49.5 mg/kg 1.6 04/25/15 16:50 EPA 6010 Nickel 6.3 mg/kg 1.6 04/25/15 16:50 EPA 6010 Potassium 325 mg/kg 323 04/25/15 16:50 EPA 6010 Strontium 19.6 mg/kg 3.2 04/25/15 16:50 EPA 6010 Zinc 19.7 mg/kg 6.5 04/25/15 16:50 EPA 6020 Cobalt 10.1 mg/kg 6.5 04/21/15 23:38 EPA 6020 Lead 10.6 mg/kg 6.5 04/21/15 23:38 EPA 6020 Vanadium 48.3 mg/kg 6.5 04/21/15 23:38 EPA 7471 Mercury 0.016 mg/kg 0.010 04/17/15 12:41 ASTM D2974-87 Percent Moisture 24.8 % 0.10 04/16/15 15:54 EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 04/14/15 15:10 EPA 300.0 Sulfate 4.0 mg/L 2.7 04/19/15 15:52 B EPA 9060 Total Organic Carbon 2950 mg/kg 800 04/24/15 11:39 EPA 9060 Total Organic Carbon 2500 mg/kg 799 04/24/15 11:45 EPA 9060 Total Organic Carbon 2450 mg/kg 799 04/24/15 11:50 EPA 9060 Total Organic Carbon 2350 mg/kg 795 04/24/15 11:56 EPA 9060 Mean Total Organic Carbon 2560 mg/kg 798 04/24/15 11:39 EPA 9060 RSD% 10.5 % 04/24/15 11:39 92245087002 2015010245 EPA 6010 Aluminum 7310 mg/kg 34.2 04/25/15 16:54 EPA 6010 Barium 28.9 mg/kg 3.4 04/25/15 16:54 EPA 6010 Beryllium 0.62 mg/kg 0.34 04/25/15 16:54 EPA 6010 Calcium 634 mg/kg 171 04/25/15 16:54 EPA 6010 Chromium 10.7 mg/kg 1.7 04/25/15 16:54 EPA 6010 Copper 5.8 mg/kg 1.7 04/25/15 16:54 EPA 6010 Iron 18500 mg/kg 13.7 04/25/15 16:54 EPA 6010 Magnesium 849 mg/kg 171 04/25/15 16:54 EPA 6010 Manganese 69.5 mg/kg 1.7 04/25/15 16:54 EPA 6010 Nickel 2.4 mg/kg 1.7 04/25/15 16:54 EPA 6010 Potassium 327J mg/kg 342 04/25/15 16:54 EPA 6010 Strontium 10.9 mg/kg 3.4 04/25/15 16:54 EPA 6010 Zinc 15.3 mg/kg 6.8 04/25/15 16:54 EPA 6020 Cobalt 5.OJ mg/kg 6.8 04/21/15 23:41 EPA 6020 Lead 5.5J mg/kg 6.8 04/21/15 23:41 EPA 6020 Vanadium 26.7 mg/kg 6.8 04/21/15 23:41 EPA 7471 Mercury 0.0079J mg/kg 0.011 04/17/15 12:44 ASTM D2974-87 Percent Moisture 25.5 % 0.10 04/16/15 15:55 EPA 9045 pH at 25 Degrees C 6.5 Std. Units 0.10 04/14/15 15:10 EPA 300.0 Sulfate 4.8 mg/L 2.7 04/19/15 16:33 B REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040238 Pace Project No.: 92245087 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245087002 2015010245 EPA353.2 Nitrogen, Nitrate 0.30 mg/L 0.27 04/22/1517:41 H1 EPA 9060 Total Organic Carbon 620J mg/kg 808 04/24/15 12:02 EPA 9060 Total Organic Carbon 5551 mg/kg 813 04/24/15 12:08 EPA 9060 Total Organic Carbon 554J mg/kg 803 04/24/15 12:14 EPA 9060 Total Organic Carbon 593J mg/kg 811 04/24/15 12:21 EPA 9060 Mean Total Organic Carbon 5811 mg/kg 809 04/24/15 12:02 EPA 9060 RSD% 5.5 % 04/24/15 12:02 92245087003 2015010244 SPLP EPA 6020A Aluminum 5400 ug/L 10.0 04/23/15 14:30 EPA 6020A Arsenic 0.90 ug/L 0.50 04/23/15 14:30 EPA 6020A Barium 278 ug/L 0.30 04/23/15 14:30 EPA 6020A Beryllium 0.81 ug/L 0.20 04/23/15 14:30 EPA 6020A Boron 145 ug/L 5.0 04/23/15 14:30 EPA 6020A Calcium 694 ug/L 40.0 04/23/15 14:30 EPA 6020A Chromium 7.1 ug/L 0.50 04/23/15 14:30 EPA 6020A Cobalt 2.8 ug/L 0.50 04/23/15 14:30 EPA 6020A Copper 9.0 ug/L 1.0 04/23/15 14:30 EPA 6020A Iron 9600 ug/L 50.0 04/23/15 14:30 EPA 6020A Lead 9.3 ug/L 0.10 04/23/15 14:30 EPA 6020A Magnesium 353 ug/L 10.0 04/23/15 14:30 EPA 6020A Manganese 20.2 ug/L 0.50 04/23/15 14:30 EPA 6020A Nickel 2.3 ug/L 0.50 04/23/15 14:30 EPA 6020A Potassium 433 ug/L 50.0 04/23/15 14:30 EPA 6020A Selenium 0.23J ug/L 0.50 04/23/15 14:30 EPA 6020A Sodium 1950 ug/L 50.0 04/23/15 14:30 EPA 6020A Strontium 31.0 ug/L 0.50 04/23/15 14:30 EPA 6020A Thallium 0.074J ug/L 0.10 04/23/15 14:30 EPA 6020A Vanadium 24.4 ug/L 1.0 04/23/15 14:30 EPA 6020A Zinc 137 ug/L 5.0 04/23/15 14:30 EPA 7470A Mercury 0.070J ug/L 0.20 04/23/15 19:53 92245087004 2015010245 SPLP EPA 6020A Aluminum 3220 ug/L 10.0 04/23/15 14:33 EPA 6020A Arsenic 0.51 ug/L 0.50 04/23/15 14:33 EPA 6020A Barium 266 ug/L 0.30 04/23/15 14:33 EPA 6020A Beryllium 0.65 ug/L 0.20 04/23/15 14:33 EPA 6020A Boron 86.7 ug/L 5.0 04/23/15 14:33 EPA 6020A Calcium 2090 ug/L 40.0 04/23/15 14:33 EPA 6020A Chromium 3.5 ug/L 0.50 04/23/15 14:33 EPA 6020A Cobalt 2.7 ug/L 0.50 04/23/15 14:33 EPA 6020A Copper 4.6 ug/L 1.0 04/23/15 14:33 EPA 6020A Iron 2510 ug/L 50.0 04/23/15 14:33 EPA 6020A Lead 3.6 ug/L 0.10 04/23/15 14:33 EPA 6020A Magnesium 944 ug/L 10.0 04/23/15 14:33 EPA 6020A Manganese 61.9 ug/L 0.50 04/23/15 14:33 EPA 6020A Nickel 1.2 ug/L 0.50 04/23/15 14:33 EPA 6020A Potassium 409 ug/L 50.0 04/23/15 14:33 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J15040238 Pace Project No.: 92245087 Lab Sample ID Client Sample ID Method Parameters Result Units 92245087004 2015010245 SPLP EPA 6020A Sodium 2090 ug/L EPA 6020A Strontium 32.2 ug/L EPA 6020A Thallium 0.025J ug/L EPA 6020A Vanadium 9.4 ug/L EPA 6020A Zinc 88.6 ug/L EPA 7470A Mercury 0.070J ug/L 92245087005 2015010246 EPA 6020A Calcium 66.3 ug/L EPA 6020A Chromium 0.50 ug/L EPA 6020A Magnesium 11.0 ug/L EPA 6020A Manganese 0.78 ug/L EPA 6020A Nickel 1.1 ug/L EPA 6020A Sodium 56.3 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 50.0 04/23/1514:33 0.50 04/23/1514:33 0.10 04/23/1514:33 1.0 04/23/1514:33 5.0 04/23/1514:33 0.20 04/23/1519:55 40.0 04/20/1515:56 0.50 04/17/1518:22 10.0 04/17/1518:22 0.50 04/17/1518:22 0.50 04/17/1518:22 50.0 04/17/1518:22 Page 8 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&)e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23656 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245143001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1186029) • Aluminum • Barium • Copper • Iron • Manganese • MSD (Lab ID: 1186030) • Aluminum • Barium • Copper • Iron • Magnesium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 Batch Comments: Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference, unless otherwise flagged. • QC Batch: ICP / 14455 Analyte Comments: QC Batch: MPRP/23656 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1186027) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflic&)e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23657 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245143002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1186035) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1186036) • Antimony • Arsenic • Cadmium • Cobalt REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�igc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 QC Batch: MPRP/23657 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245143002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Lead • Selenium • Thallium • Vanadium R1: RPD value was outside control limits. • MSD (Lab ID: 1186036) • Cobalt • Vanadium Additional Comments: Batch Comments: Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9617 Analyte Comments: QC Batch: MPRP/23657 N2: The lab does not hold TNI accreditation for this parameter. •2015010244 (Lab ID:92245087001) • Antimony •2015010245 (Lab ID:92245087002) • Antimony • BLANK (Lab ID: 1186033) • Antimony • LCS (Lab ID: 1186034) • Antimony • MS (Lab ID: 1186035) • Antimony • MSD (Lab ID: 1186036) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&)e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 27, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53815 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10303182004 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1945266) • Boron • Calcium • Magnesium • Potassium • Sodium • Strontium • MSD (Lab ID: 1945267) • Boron • Calcium • Magnesium • Potassium • Sodium • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 27, 2015 QC Batch: MPRP/53815 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10303182004 R1: RPD value was outside control limits. • MSD (Lab ID: 1945267) • Selenium Additional Comments: Analyte Comments: QC Batch: MPRP/53815 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1945266) • Sodium • MSD (Lab ID: 1945267) • Sodium P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1945264) • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: April 27, 2015 General Information: 1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gK4-8y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22607 B: Analyte was detected in the associated method blank. • BLANK for HBN 260035 [WETA/226 (Lab ID: 1437291) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015010244 (Lab ID:92245087001) •2015010245 (Lab ID:92245087002) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45407 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010244 (Lab ID:92245087001) • Chloride • Sulfate •2015010245 (Lab ID:92245087002) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vfte. Suite 100 �J Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015010244 (Lab ID:92245087001) •2015010245 (Lab ID:92245087002) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040238 Pace Project No.: 92245087 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 27, 2015 General Information: 2 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninvfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040238 Pace Project No.: 92245087 Sample: 2015010244 Lab ID: 92245087001 Collected: 04/07/15 13:52 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/27/2015 03:26 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 15200 mg/kg 32.3 16.2 5 04/16/15 21:15 04/25/15 16:50 7429-90-5 71.2 mg/kg 3.2 1.6 5 04/16/15 21:15 04/25/15 16:50 7440-39-3 1.0 mg/kg 0.32 0.16 5 04/16/15 21:15 04/25/15 16:50 7440-41-7 ND mg/kg 16.2 8.1 5 04/16/15 21:15 04/25/15 16:50 7440-42-8 435 mg/kg 162 80.8 5 04/16/15 21:15 04/25/15 16:50 7440-70-2 16.8 mg/kg 1.6 0.81 5 04/16/15 21:15 04/25/15 16:50 7440-47-3 9.6 mg/kg 1.6 0.81 5 04/16/15 21:15 04/25/15 16:50 7440-50-8 16400 mg/kg 12.9 6.5 5 04/16/15 21:15 04/25/15 16:50 7439-89-6 997 mg/kg 162 80.8 5 04/16/15 21:15 04/25/15 16:50 7439-95-4 49.5 mg/kg 1.6 0.81 5 04/16/15 21:15 04/25/15 16:50 7439-96-5 ND mg/kg 3.2 1.6 5 04/16/15 21:15 04/25/15 16:50 7439-98-7 6.3 mg/kg 1.6 0.81 5 04/16/15 21:15 04/25/15 16:50 7440-02-0 325 mg/kg 323 162 5 04/16/15 21:15 04/25/15 16:50 7440-09-7 ND mg/kg 323 162 5 04/16/15 21:15 04/25/15 16:50 7440-23-5 19.6 mg/kg 3.2 1.6 5 04/16/15 21:15 04/25/15 16:50 7440-24-6 19.7 mg/kg 6.5 3.2 5 04/16/15 21:15 04/25/15 16:50 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.5 3.2 100 04/16/15 21:15 04/21/15 23:38 7440-36-0 ND mg/kg 6.5 3.2 100 04/16/15 21:15 04/21/15 23:38 7440-38-2 ND mg/kg 0.78 0.39 100 04/16/15 21:15 04/21/15 23:38 7440-43-9 10.1 mg/kg 6.5 3.2 100 04/16/15 21:15 04/21/15 23:38 7440-48-4 10.6 mg/kg 6.5 3.2 100 04/16/15 21:15 04/21/15 23:38 7439-92-1 ND mg/kg 6.5 3.2 100 04/16/15 21:15 04/21/15 23:38 7782-49-2 ND mg/kg 6.5 3.2 100 04/16/15 21:15 04/21/15 23:38 7440-28-0 48.3 mg/kg 6.5 3.2 100 04/16/15 21:15 04/21/15 23:38 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.016 mg/kg 0.010 0.0052 1 04/16/15 22:25 04/17/15 12:41 7439-97-6 Analytical Method: ASTM D2974-87 24.8 % 0.10 0.10 1 04/16/1515:54 Analytical Method: EPA 9045 6.0 Std. Units 0.10 0.10 1 04/14/15 15:10 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55 4.0 mg/L 2.7 1.3 1 04/19/1515:52 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55 ND mg/L 0.27 0.27 1 04/22/1517:39 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55 ND mg/L 6.6 3.3 1 04/17/15 05:40 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040238 Pace Project No.: 92245087 Sample: 2015010244 Lab ID: 92245087001 Collected: 04/07/15 13:52 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 338 169 5 04/15/15 02:43 16887-00-6 D3,M1 Sulfate ND mg/kg 338 169 5 04/15/15 02:43 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.8 16.9 5 04/15/15 02:43 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2950 mg/kg 800 400 1 04/24/15 11:39 7440-44-0 Total Organic Carbon 2500 mg/kg 799 399 1 04/24/15 11:45 7440-44-0 Total Organic Carbon 2450 mg/kg 799 400 1 04/24/15 11:50 7440-44-0 Total Organic Carbon 2350 mg/kg 795 398 1 04/24/15 11:56 7440-44-0 Mean Total Organic Carbon 2560 mg/kg 798 399 1 04/24/15 11:39 7440-44-0 Surrogates RSD% 10.5 % 1 04/24/15 11:39 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040238 Pace Project No.: 92245087 Sample: 2015010245 Lab ID: 92245087002 Collected: 04/07/15 16:45 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/27/2015 03:26 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 7310 mg/kg 34.2 17.1 5 04/16/15 21:15 04/25/15 16:54 7429-90-5 28.9 mg/kg 3.4 1.7 5 04/16/15 21:15 04/25/15 16:54 7440-39-3 0.62 mg/kg 0.34 0.17 5 04/16/15 21:15 04/25/15 16:54 7440-41-7 ND mg/kg 17.1 8.5 5 04/16/15 21:15 04/25/15 16:54 7440-42-8 634 mg/kg 171 85.4 5 04/16/15 21:15 04/25/15 16:54 7440-70-2 10.7 mg/kg 1.7 0.85 5 04/16/15 21:15 04/25/15 16:54 7440-47-3 5.8 mg/kg 1.7 0.85 5 04/16/15 21:15 04/25/15 16:54 7440-50-8 18500 mg/kg 13.7 6.8 5 04/16/15 21:15 04/25/15 16:54 7439-89-6 849 mg/kg 171 85.4 5 04/16/15 21:15 04/25/15 16:54 7439-95-4 69.5 mg/kg 1.7 0.85 5 04/16/15 21:15 04/25/15 16:54 7439-96-5 ND mg/kg 3.4 1.7 5 04/16/15 21:15 04/25/15 16:54 7439-98-7 2.4 mg/kg 1.7 0.85 5 04/16/15 21:15 04/25/15 16:54 7440-02-0 327J mg/kg 342 171 5 04/16/15 21:15 04/25/15 16:54 7440-09-7 ND mg/kg 342 171 5 04/16/15 21:15 04/25/15 16:54 7440-23-5 10.9 mg/kg 3.4 1.7 5 04/16/15 21:15 04/25/15 16:54 7440-24-6 15.3 mg/kg 6.8 3.4 5 04/16/15 21:15 04/25/15 16:54 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.8 3.4 100 04/16/15 21:15 04/21/15 23:41 7440-36-0 ND mg/kg 6.8 3.4 100 04/16/15 21:15 04/21/15 23:41 7440-38-2 ND mg/kg 0.82 0.41 100 04/16/15 21:15 04/21/15 23:41 7440-43-9 5.OJ mg/kg 6.8 3.4 100 04/16/15 21:15 04/21/15 23:41 7440-48-4 5.5J mg/kg 6.8 3.4 100 04/16/15 21:15 04/21/15 23:41 7439-92-1 ND mg/kg 6.8 3.4 100 04/16/15 21:15 04/21/15 23:41 7782-49-2 ND mg/kg 6.8 3.4 100 04/16/15 21:15 04/21/15 23:41 7440-28-0 26.7 mg/kg 6.8 3.4 100 04/16/15 21:15 04/21/15 23:41 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.0079J mg/kg 0.011 0.0056 1 04/16/15 22:25 04/17/15 12:44 7439-97-6 Analytical Method: ASTM D2974-87 25.5 % 0.10 0.10 1 04/16/1515:55 Analytical Method: EPA 9045 6.5 Std. Units 0.10 0.10 1 04/14/15 15:10 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55 4.8 mg/L 2.7 1.3 1 04/19/1516:33 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55 0.30 mg/L 0.27 0.27 1 04/22/1517:41 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55 ND mg/L 6.7 3.4 1 04/17/15 05:41 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040238 Pace Project No.: 92245087 Sample: 2015010245 Lab ID: 92245087002 Collected: 04/07/15 16:45 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 332 166 5 04/15/15 03:47 16887-00-6 D3 Sulfate ND mg/kg 332 166 5 04/15/15 03:47 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.2 16.6 5 04/15/15 03:47 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 620J mg/kg 808 404 1 04/24/15 12:02 7440-44-0 Total Organic Carbon 555J mg/kg 813 406 1 04/24/15 12:08 7440-44-0 Total Organic Carbon 554J mg/kg 803 401 1 04/24/15 12:14 7440-44-0 Total Organic Carbon 593J mg/kg 811 406 1 04/24/15 12:21 7440-44-0 Mean Total Organic Carbon 581J mg/kg 809 404 1 04/24/15 12:02 7440-44-0 Surrogates RSD% 5.5 % 1 04/24/15 12:02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040238 Pace Project No.: 92245087 Sample: 2015010244 SPLP Lab ID: 92245087003 Collected: 04/07/15 13:52 Received: 04/10/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 04/27/2015 03:26 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 5400 ug/L 10.0 3.0 1 04/22/1514:54 04/23/1514:30 7429-90-5 ND ug/L 0.50 0.15 1 04/22/1514:54 04/23/1514:30 7440-36-0 0.90 ug/L 0.50 0.11 1 04/22/1514:54 04/23/1514:30 7440-38-2 278 ug/L 0.30 0.081 1 04/22/1514:54 04/23/1514:30 7440-39-3 0.81 ug/L 0.20 0.067 1 04/22/1514:54 04/23/1514:30 7440-41-7 145 ug/L 5.0 1.1 1 04/22/1514:54 04/23/1514:30 7440-42-8 ND ug/L 0.080 0.024 1 04/22/1514:54 04/23/1514:30 7440-43-9 694 ug/L 40.0 16.0 1 04/22/1514:54 04/23/1514:30 7440-70-2 7.1 ug/L 0.50 0.17 1 04/22/1514:54 04/23/1514:30 7440-47-3 2.8 ug/L 0.50 0.13 1 04/22/1514:54 04/23/1514:30 7440-48-4 9.0 ug/L 1.0 0.21 1 04/22/1514:54 04/23/1514:30 7440-50-8 9600 ug/L 50.0 13.7 1 04/22/1514:54 04/23/1514:30 7439-89-6 9.3 ug/L 0.10 0.046 1 04/22/1514:54 04/23/1514:30 7439-92-1 353 ug/L 10.0 3.2 1 04/22/1514:54 04/23/1514:30 7439-95-4 20.2 ug/L 0.50 0.24 1 04/22/1514:54 04/23/1514:30 7439-96-5 ND ug/L 0.50 0.094 1 04/22/1514:54 04/23/1514:30 7439-98-7 2.3 ug/L 0.50 0.16 1 04/22/1514:54 04/23/1514:30 7440-02-0 433 ug/L 50.0 11.7 1 04/22/1514:54 04/23/1514:30 7440-09-7 0.23J ug/L 0.50 0.20 1 04/22/1514:54 04/23/1514:30 7782-49-2 1950 ug/L 50.0 16.3 1 04/22/1514:54 04/23/1514:30 7440-23-5 31.0 ug/L 0.50 0.13 1 04/22/1514:54 04/23/1514:30 7440-24-6 0.074J ug/L 0.10 0.015 1 04/22/1514:54 04/23/1514:30 7440-28-0 24.4 ug/L 1.0 0.28 1 04/22/1514:54 04/23/1514:30 7440-62-2 137 ug/L 5.0 2.4 1 04/22/1514:54 04/23/1514:30 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.070J ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:53 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040238 Pace Project No.: 92245087 Sample: 2015010245 SPLP Lab ID: 92245087004 Collected: 04/07/15 16:45 Received: 04/10/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 04/27/2015 03:26 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 3220 ug/L 10.0 3.0 1 04/22/1514:54 04/23/1514:33 7429-90-5 ND ug/L 0.50 0.15 1 04/22/1514:54 04/23/1514:33 7440-36-0 0.51 ug/L 0.50 0.11 1 04/22/1514:54 04/23/1514:33 7440-38-2 266 ug/L 0.30 0.081 1 04/22/1514:54 04/23/1514:33 7440-39-3 0.65 ug/L 0.20 0.067 1 04/22/1514:54 04/23/1514:33 7440-41-7 86.7 ug/L 5.0 1.1 1 04/22/1514:54 04/23/1514:33 7440-42-8 ND ug/L 0.080 0.024 1 04/22/1514:54 04/23/1514:33 7440-43-9 2090 ug/L 40.0 16.0 1 04/22/1514:54 04/23/1514:33 7440-70-2 3.5 ug/L 0.50 0.17 1 04/22/1514:54 04/23/1514:33 7440-47-3 2.7 ug/L 0.50 0.13 1 04/22/1514:54 04/23/1514:33 7440-48-4 4.6 ug/L 1.0 0.21 1 04/22/1514:54 04/23/1514:33 7440-50-8 2510 ug/L 50.0 13.7 1 04/22/1514:54 04/23/1514:33 7439-89-6 3.6 ug/L 0.10 0.046 1 04/22/1514:54 04/23/1514:33 7439-92-1 944 ug/L 10.0 3.2 1 04/22/1514:54 04/23/1514:33 7439-95-4 61.9 ug/L 0.50 0.24 1 04/22/1514:54 04/23/1514:33 7439-96-5 ND ug/L 0.50 0.094 1 04/22/1514:54 04/23/1514:33 7439-98-7 1.2 ug/L 0.50 0.16 1 04/22/1514:54 04/23/1514:33 7440-02-0 409 ug/L 50.0 11.7 1 04/22/1514:54 04/23/1514:33 7440-09-7 ND ug/L 0.50 0.20 1 04/22/1514:54 04/23/1514:33 7782-49-2 2090 ug/L 50.0 16.3 1 04/22/1514:54 04/23/1514:33 7440-23-5 32.2 ug/L 0.50 0.13 1 04/22/1514:54 04/23/1514:33 7440-24-6 0.025J ug/L 0.10 0.015 1 04/22/1514:54 04/23/1514:33 7440-28-0 9.4 ug/L 1.0 0.28 1 04/22/1514:54 04/23/1514:33 7440-62-2 88.6 ug/L 5.0 2.4 1 04/22/1514:54 04/23/1514:33 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.070J ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:55 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i vfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040238 Pace Project No.: 92245087 Sample: 2015010246 Lab ID: 92245087005 Collected: 04/07/15 11:20 Received: 04/10/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:26 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 ND ug/L 10.0 3.0 1 04/15/15 22:19 04/17/15 18:22 7429-90-5 ND ug/L 0.50 0.15 1 04/15/15 22:19 04/17/15 18:22 7440-36-0 ND ug/L 0.50 0.11 1 04/15/15 22:19 04/17/15 18:22 7440-38-2 ND ug/L 0.30 0.081 1 04/15/15 22:19 04/17/15 18:22 7440-39-3 ND ug/L 0.20 0.067 1 04/15/15 22:19 04/17/15 18:22 7440-41-7 ND ug/L 5.0 1.1 1 04/15/15 22:19 04/17/15 18:22 7440-42-8 ND ug/L 0.080 0.024 1 04/15/15 22:19 04/17/15 18:22 7440-43-9 66.3 ug/L 40.0 16.0 1 04/15/15 22:19 04/20/15 15:56 7440-70-2 0.50 ug/L 0.50 0.17 1 04/15/15 22:19 04/17/15 18:22 7440-47-3 ND ug/L 0.50 0.13 1 04/15/15 22:19 04/17/15 18:22 7440-48-4 ND ug/L 1.0 0.21 1 04/15/15 22:19 04/17/15 18:22 7440-50-8 ND ug/L 50.0 13.7 1 04/15/15 22:19 04/17/15 18:22 7439-89-6 ND ug/L 0.10 0.046 1 04/15/15 22:19 04/17/15 18:22 7439-92-1 11.0 ug/L 10.0 3.2 1 04/15/15 22:19 04/17/15 18:22 7439-95-4 0.78 ug/L 0.50 0.24 1 04/15/15 22:19 04/17/15 18:22 7439-96-5 ND ug/L 0.50 0.094 1 04/15/15 22:19 04/17/15 18:22 7439-98-7 1.1 ug/L 0.50 0.16 1 04/15/15 22:19 04/17/15 18:22 7440-02-0 ND ug/L 50.0 11.7 1 04/15/15 22:19 04/17/15 18:22 7440-09-7 ND ug/L 0.50 0.20 1 04/15/15 22:19 04/17/15 18:22 7782-49-2 56.3 ug/L 50.0 16.3 1 04/15/15 22:19 04/17/15 18:22 7440-23-5 ND ug/L 0.50 0.13 1 04/15/15 22:19 04/17/15 18:22 7440-24-6 ND ug/L 0.10 0.015 1 04/15/15 22:19 04/17/15 18:22 7440-28-0 ND ug/L 1.0 0.28 1 04/15/15 22:19 04/20/15 15:56 7440-62-2 ND ug/L 5.0 2.4 1 04/15/15 22:19 04/17/15 18:22 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/16/15 08:58 04/16/15 19:38 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: MERP/13232 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92245087005 METHOD BLANK: 1939457 Matrix: Water Associated Lab Samples: 92245087005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/16/1519:16 LABORATORY CONTROL SAMPLE: 1939458 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.7 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1939459 1939460 MS MSD 92245092001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.7 4.8 95 96 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: MERP/13312 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92245087003, 92245087004 METHOD BLANK: 1945562 Matrix: Water Associated Lab Samples: 92245087003, 92245087004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/23/1519:26 LABORATORY CONTROL SAMPLE: 1945563 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.2 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945564 1945565 MS MSD 92246088001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.0 5.1 100 102 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: MERP/5597 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1186051 Matrix: Solid Associated Lab Samples: 92245087001, 92245087002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 04/17/1512:20 LABORATORY CONTROL SAMPLE: 1186052 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .083 0.081 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1186053 1186054 MS MSD 92245143001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.011 .0868 .0914 0.083 0.088 83 84 80-120 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWinlc8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: MPRP/23656 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1186027 Associated Lab Samples: 92245087001, 92245087002 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 5.2 04/25/1516:01 ND 0.52 04/25/1516:01 ND 0.052 04/25/1516:01 ND 2.6 04/25/1516:01 ND 26.2 04/25/1516:01 ND 0.26 04/25/1516:01 ND 0.26 04/25/1516:01 2.1 2.1 04/25/15 16:01 ND 26.2 04/25/1516:01 ND 0.26 04/25/1516:01 ND 0.52 04/25/1516:01 ND 0.26 04/25/1516:01 ND 52.3 04/25/1516:01 ND 52.3 04/25/1516:01 ND 0.52 04/25/1516:01 ND 1.0 04/25/1516:01 P8 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1186028 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 130 134 103 80-120 Barium mg/kg 13 13.4 102 80-120 Beryllium mg/kg 1.3 1.3 101 80-120 Boron mg/kg 130 127 97 80-120 Calcium mg/kg 652 681 104 80-120 Chromium mg/kg 13 12.6 96 80-120 Copper mg/kg 13 12.6 97 80-120 Iron mg/kg 130 134 102 80-120 Magnesium mg/kg 652 661 101 80-120 Manganese mg/kg 13 13.0 99 80-120 Molybdenum mg/kg 13 12.8 98 80-120 Nickel mg/kg 13 13.3 102 80-120 Potassium mg/kg 652 659 101 80-120 Sodium mg/kg 652 685 105 80-120 Strontium mg/kg 13 13.3 102 80-120 Zinc mg/kg 65.2 66.4 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gW2.8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1186029 1186030 MS MSD 92245143001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 13100 139 143 15700 16800 1880 2580 75-125 7 20 M1 Barium mg/kg 43.3 13.9 14.3 62.2 64.3 137 146 75-125 3 20 M1 Beryllium mg/kg ND 1.35 1.47 1.5 1.6 100 101 75-125 4 20 Boron mg/kg ND 139 143 128 132 93 92 75-125 3 20 Calcium mg/kg 356 693 717 1050 1080 100 101 75-125 3 20 Chromium mg/kg 4.7 13.9 14.3 16.4 17.8 85 92 75-125 8 20 Copper mg/kg 33.0 13.9 14.3 35.7 37.0 19 28 75-125 4 20 M1 Iron mg/kg 13800 139 143 12500 13000 -956 -556 75-125 4 20 M1 Magnesium mg/kg 2010 693 717 2820 3010 116 139 75-125 7 20 M1 Manganese mg/kg 70.1 13.9 14.3 78.6 88.0 61 125 75-125 11 20 M1 Molybdenum mg/kg ND 13.9 14.3 12.9 12.8 90 87 75-125 0 20 Nickel mg/kg 1.3J 13.9 14.3 15.4 15.9 102 101 75-125 3 20 Potassium mg/kg 995 693 717 1810 1890 118 125 75-125 4 20 Sodium mg/kg 184J 693 717 1000 956 118 108 75-125 5 20 Strontium mg/kg 6.0 13.9 14.3 21.2 21.0 110 105 75-125 1 20 Zinc mg/kg 16.5 69.3 71.7 87.7 90.7 103 104 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: MPRP/23657 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1186033 Matrix: Solid Associated Lab Samples: 92245087001, 92245087002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.052 04/21/15 23:09 N2 Arsenic mg/kg ND 0.052 04/21/15 23:09 Cadmium mg/kg ND 0.0062 04/21/15 23:09 Cobalt mg/kg ND 0.052 04/21/15 23:09 Lead mg/kg ND 0.052 04/21/15 23:09 Selenium mg/kg ND 0.052 04/21/15 23:09 Thallium mg/kg ND 0.052 04/21/15 23:09 Vanadium mg/kg ND 0.052 04/21/15 23:09 LABORATORY CONTROL SAMPLE: Parameter 1186034 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.6 2.7 104 80-120 N2 Arsenic mg/kg 2.6 2.7 105 80-120 Cadmium mg/kg .26 0.27 106 80-120 Cobalt mg/kg 2.6 2.7 105 80-120 Lead mg/kg 2.6 2.6 102 80-120 Selenium mg/kg 2.6 2.6 103 80-120 Thallium mg/kg 2.6 2.7 105 80-120 Vanadium mg/kg 2.6 2.7 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1186035 1186036 MS MSD 92245143002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.98 2.87 ND ND -5 -64 75-125 20 M6, N2 Arsenic mg/kg 3.9J 2.98 2.87 3.8J ND -3 -113 75-125 20 M6 Cadmium mg/kg ND .298 .287 ND ND 39 -64 75-125 20 M6 Cobalt mg/kg 27.7 2.98 2.87 51.3 26.2 787 -55 75-125 65 20 M6,R1 Lead mg/kg 3.9J 2.98 2.87 3.8J ND -2 -102 75-125 20 M6 Selenium mg/kg 5.2J 2.98 2.87 ND ND -79 -161 75-125 20 M6 Thallium mg/kg 3.9J 2.98 2.87 3.3J ND -21 -127 75-125 20 M6 Vanadium mg/kg 87.3 2.98 2.87 103 78.7 539 -299 75-125 27 20 M6, RI Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: MPRP/53628 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92245087005 METHOD BLANK: 1939436 Associated Lab Samples: 92245087005 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 04/17/1517:03 ND 0.50 04/17/1517:03 ND 0.50 04/17/1517:03 ND 0.30 04/17/1517:03 ND 0.20 04/17/1517:03 ND 5.0 04/17/1517:03 ND 0.080 04/17/1517:03 ND 40.0 04/20/1514:02 ND 0.50 04/17/1517:03 ND 0.50 04/17/1517:03 ND 1.0 04/17/1517:03 ND 50.0 04/17/1517:03 ND 0.10 04/17/1517:03 ND 10.0 04/17/1517:03 ND 0.50 04/17/1517:03 ND 0.50 04/17/1517:03 ND 0.50 04/17/1517:03 ND 50.0 04/17/1517:03 ND 0.50 04/17/1517:03 ND 50.0 04/17/1517:03 ND 0.50 04/17/1517:03 ND 0.10 04/17/1517:03 ND 1.0 04/17/1517:03 ND 5.0 04/17/1517:03 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1939437 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 78.0 98 80-120 Antimony ug/L 80 76.9 96 80-120 Arsenic ug/L 80 78.2 98 80-120 Barium ug/L 80 76.5 96 80-120 Beryllium ug/L 80 68.9 86 80-120 Boron ug/L 80 79.4 99 80-120 Cadmium ug/L 80 76.6 96 80-120 Calcium ug/L 1000 1060 106 80-120 Chromium ug/L 80 77.1 96 80-120 Cobalt ug/L 80 77.9 97 80-120 Copper ug/L 80 80.4 101 80-120 Iron ug/L 1000 977 98 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 LABORATORY CONTROL SAMPLE: 1939437 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 76.9 96 80-120 Magnesium ug/L 1000 951 95 80-120 Manganese ug/L 80 77.1 96 80-120 Molybdenum ug/L 80 77.8 97 80-120 Nickel ug/L 80 80.1 100 80-120 Potassium ug/L 1000 991 99 80-120 Selenium ug/L 80 79.4 99 80-120 Sodium ug/L 1000 951 95 80-120 Strontium ug/L 80 77.1 96 80-120 Thallium ug/L 80 77.3 97 80-120 Vanadium ug/L 80 81.3 102 80-120 Zinc ug/L 80 79.2 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1939446 1939447 MS MSD 92245087005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 80 80 98.4 83.9 120 102 75-125 16 20 Antimony ug/L ND 80 80 76.9 77.7 96 97 75-125 1 20 Arsenic ug/L ND 80 80 77.2 78.0 97 97 75-125 1 20 Barium ug/L ND 80 80 76.5 77.2 95 96 75-125 1 20 Beryllium ug/L ND 80 80 68.0 68.6 85 86 75-125 1 20 Boron ug/L ND 80 80 79.4 78.5 97 95 75-125 1 20 Cadmium ug/L ND 80 80 75.6 77.2 94 97 75-125 2 20 Calcium ug/L 66.3 1000 1000 1130 1070 106 100 75-125 5 20 Chromium ug/L 0.50 80 80 78.2 79.8 97 99 75-125 2 20 Cobalt ug/L ND 80 80 76.9 78.1 96 98 75-125 2 20 Copper ug/L ND 80 80 80.2 80.9 100 101 75-125 1 20 Iron ug/L ND 1000 1000 993 1010 98 99 75-125 1 20 Lead ug/L ND 80 80 76.7 78.3 96 98 75-125 2 20 Magnesium ug/L 11.0 1000 1000 961 983 95 97 75-125 2 20 Manganese ug/L 0.78 80 80 77.4 78.5 96 97 75-125 1 20 Molybdenum ug/L ND 80 80 76.8 77.4 96 97 75-125 1 20 Nickel ug/L 1.1 80 80 80.8 82.4 100 102 75-125 2 20 Potassium ug/L ND 1000 1000 984 994 97 98 75-125 1 20 Selenium ug/L ND 80 80 78.8 79.4 98 99 75-125 1 20 Sodium ug/L 56.3 1000 1000 999 985 94 93 75-125 1 20 Strontium ug/L ND 80 80 76.8 78.4 96 98 75-125 2 20 Thallium ug/L ND 80 80 79.6 80.8 99 101 75-125 2 20 Vanadium ug/L ND 80 80 81.2 80.8 101 101 75-125 0 20 Zinc ug/L ND 80 80 80.7 81.6 96 97 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: MPRP/53815 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92245087003, 92245087004 METHOD BLANK: 1945264 Associated Lab Samples: 92245087003, 92245087004 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed 4.7J 10.0 04/24/1511:23 ND 0.50 04/24/1511:23 ND 0.50 04/24/1511:23 ND 0.30 04/24/1511:23 ND 0.20 04/24/1511:23 ND 5.0 04/24/1511:23 ND 0.080 04/24/1511:23 ND 40.0 04/24/1511:23 ND 0.50 04/24/1511:23 ND 0.50 04/24/1511:23 ND 1.0 04/24/1511:23 ND 50.0 04/24/1511:23 ND 0.10 04/24/1511:23 4.2J 10.0 04/24/1511:23 0.67 0.50 04/24/1511:23 ND 0.50 04/24/1511:23 ND 0.50 04/24/1511:23 ND 50.0 04/24/1511:23 ND 0.50 04/24/1511:23 ND 50.0 04/24/1511:23 ND 0.50 04/24/1511:23 ND 0.10 04/24/1511:23 ND 1.0 04/24/1511:23 ND 5.0 04/24/1511:23 P8 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1945265 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 89.9 112 80-120 Antimony ug/L 80 82.0 102 80-120 Arsenic ug/L 80 80.0 100 80-120 Barium ug/L 80 82.2 103 80-120 Beryllium ug/L 80 81.5 102 80-120 Boron ug/L 80 84.7 106 80-120 Cadmium ug/L 80 82.4 103 80-120 Calcium ug/L 1000 991 99 80-120 Chromium ug/L 80 81.7 102 80-120 Cobalt ug/L 80 83.5 104 80-120 Copper ug/L 80 82.1 103 80-120 Iron ug/L 1000 1030 103 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 LABORATORY CONTROL SAMPLE: Parameter 1945265 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Lead ug/L 80 78.2 98 80-120 Magnesium ug/L 1000 1010 101 80-120 Manganese ug/L 80 81.5 102 80-120 Molybdenum ug/L 80 80.0 100 80-120 Nickel ug/L 80 84.3 105 80-120 Potassium ug/L 1000 1010 101 80-120 Selenium ug/L 80 80.3 100 80-120 Sodium ug/L 1000 1050 105 80-120 Strontium ug/L 80 78.4 98 80-120 Thallium ug/L 80 83.3 104 80-120 Vanadium ug/L 80 79.6 100 80-120 Zinc ug/L 80 82.9 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945266 1945267 Qualifiers MS MSD 10303182004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L <59.6 80 80 ND ND 108 86 75-125 20 Antimony ug/L <2.9 80 80 85.8 74.4 107 93 75-125 14 20 Arsenic ug/L <2.3 80 80 82.5 72.6 101 89 75-125 13 20 Barium ug/L 7.8 80 80 93.2 79.4 107 90 75-125 16 20 Beryllium ug/L <1.3 80 80 84.0 70.8 105 89 75-125 17 20 Boron ug/L 2730 80 80 3340 2940 760 267 75-125 13 20 M6 Cadmium ug/L <0.49 80 80 75.0 65.4 94 82 75-125 14 20 Calcium ug/L 300000 1000 1000 316000 273000 1520 -2740 75-125 14 20 M6 Chromium ug/L <0.0034 80 80 85.4 74.1 105 90 75-125 14 20 mg/L Cobalt ug/L 3.5J 80 80 87.8 76.6 105 91 75-125 14 20 Copper ug/L 0.0053J 80 80 84.4 72.0 99 83 75-125 16 20 mg/L Iron ug/L 0.63J 1000 1000 1700J 1480J 107 85 75-125 20 mg/L Lead ug/L <0.00092 80 80 72.2 63.2 90 79 75-125 13 20 mg/L Magnesium ug/L 793000 1000 1000 978000 856000 18500 6270 75-125 13 20 M6 Manganese ug/L 54.4 80 80 139 120 106 81 75-125 15 20 Molybdenum ug/L 10.5 80 80 95.9 80.6 107 88 75-125 17 20 Nickel ug/L 0.020 80 80 106 88.6 107 86 75-125 18 20 mg/L Potassium ug/L 289000 1000 1000 300000 264000 1070 -2520 75-125 13 20 M6 Selenium ug/L <4.0 80 80 85.8 68.9 106 85 75-125 22 20 R1 Sodium ug/L 6790000 1000 1000 8250000 7260000 145000 46300 75-125 13 20 E,M6 Strontium ug/L 4640 80 80 5540 4860 1120 278 75-125 13 20 M6 Thallium ug/L <0.31 80 80 79.9 68.4 100 85 75-125 16 20 Vanadium ug/L <5.6 80 80 90.0 81.5 110 99 75-125 10 20 Zinc ug/L <0.048 80 80 ND ND 92 76 75-125 20 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: PMST/3452 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92245087001, 92245087002 SAMPLE DUPLICATE: 1185592 35183639002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 13.8 14.2 3 10 SAMPLE DUPLICATE: 1185593 92245092006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 15.8 16.1 2 10 SAMPLE DUPLICATE: 1185594 92245094007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 34.6 35.1 1 10 SAMPLE DUPLICATE: 1185595 92245118003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 38.1 38.1 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098m.8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: WET/36811 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92245087001, 92245087002 SAMPLE DUPLICATE: 1433694 92245086007 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.3 7.3 0 10 SAMPLE DUPLICATE: 1433695 92245087002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.5 6.5 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: WETA/22607 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1437291 Matrix: Water Associated Lab Samples: 92245087001, 92245087002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.1 2.0 04/19/1512:14 LABORATORY CONTROL SAMPLE: 1437292 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 18.9 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437293 1437294 MS MSD 92244130003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 275 22.7 22.7 294 295 83 85 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437295 1437296 MS MSD 92245087001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 4.0 26.6 26.6 26.5 26.2 85 83 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onlc8foe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: WETA/22655 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1440999 Matrix: Water Associated Lab Samples: 92245087001, 92245087002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.16 0.020 04/22/15 17:09 Z2 LABORATORY CONTROL SAMPLE: 1441000 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441001 1441002 MS MSD 92244130003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.8 2.8 3.1 3.1 104 104 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441003 1441004 MS MSD 92244130004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.9 2.9 3.1 3.1 100 100 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: WETA/22603 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1437036 Matrix: Water Associated Lab Samples: 92245087001, 92245087002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 04/17/15 05:27 LABORATORY CONTROL SAMPLE: 1437037 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.3 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437038 1437039 MS MSD 92244130003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 22.7 22.7 23.0 23.4 101 102 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437040 1437041 MS MSD 92244130004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.2 23.2 23.9 23.5 103 101 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: WETA/45407 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1183130 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.2 04/15/15 02:00 Sulfate mg/kg ND 49.2 04/15/15 02:00 LABORATORY CONTROL SAMPLE: 1183131 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1183133 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1183132 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 501 483 96 80-120 501 481 96 80-120 92245087001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 675 623 75 80-120 M 1 ND 675 638 94 80-120 92245087001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: WETA/45406 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1183126 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 04/15/15 02:00 LABORATORY CONTROL SAMPLE: 1183127 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.1 49.7 99 80-120 MATRIX SPIKE SAMPLE: 1183129 92245087001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 67.5 62.4 92 80-120 H3 SAMPLE DUPLICATE: 1183128 92245087001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040238 Pace Project No.: 92245087 QC Batch: WETA/28164 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92245087001, 92245087002 METHOD BLANK: 1145576 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 04/24/15 05:56 LABORATORY CONTROL SAMPLE: 1145577 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 120000 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1145578 1145579 MS MSD 92244458001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 54700 110000 109000 160000 178000 96 114 50-150 11 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1145580 1145581 MS MSD 92244973001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 6840 6900 6770 7070 94 98 50-150 4 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15040238 Pace Project No.: 92245087 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/9617 Ill Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICP/14455 III Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference, unless otherwise flagged. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. E Analyte concentration exceeded the calibration range. The reported result is estimated. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 54 Pace Analytical Services, Inc aceAnalXical ® � ��t��c&rrfte. Suite100 Huntersville, INC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15040238 Pace Project No.: 92245087 ANALYTE QUALIFIERS M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:26 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 54 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040238 Pace Project No.: 92245087 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92245087001 2015010244 EPA 3050 MPRP/23656 EPA 6010 92245087002 2015010245 EPA 3050 MPRP/23656 EPA 6010 92245087001 2015010244 EPA 3050 MPRP/23657 EPA 6020 92245087002 2015010245 EPA 3050 MPRP/23657 EPA 6020 92245087003 2015010244 SPLP EPA 3020 MPRP/53815 EPA 6020A 92245087004 2015010245 SPLP EPA 3020 MPRP/53815 EPA 6020A 92245087005 2015010246 EPA 3020 MPRP/53628 EPA 6020A 92245087005 2015010246 EPA 7470 MERP/13232 EPA 7470 92245087003 2015010244 SPLP EPA 7470A MERP/13312 EPA 7470A 92245087004 2015010245 SPLP EPA 7470A MERP/13312 EPA 7470A 92245087001 2015010244 EPA 7471 MERP/5597 EPA 7471 92245087002 2015010245 EPA 7471 MERP/5597 EPA 7471 92245087001 2015010244 ASTM D2974-87 PMST/3452 92245087002 2015010245 ASTM D2974-87 PMST/3452 92245087001 2015010244 EPA 9045 WET/36811 92245087002 2015010245 EPA 9045 WET/36811 92245087001 2015010244 EPA 300.0 WETA/22607 92245087002 2015010245 EPA 300.0 WETA/22607 92245087001 2015010244 EPA 353.2 WETA/22655 92245087002 2015010245 EPA 353.2 WETA/22655 92245087001 2015010244 SM 4500-CI-E WETA/22603 92245087002 2015010245 SM 4500-CI-E WETA/22603 92245087001 2015010244 EPA 9056 WETA/45407 92245087002 2015010245 EPA 9056 WETA/45407 92245087001 2015010244 EPA 9056 WETA/45406 92245087002 2015010245 EPA 9056 WETA/45406 92245087001 2015010244 EPA 9060 WETA/28164 92245087001 2015010244 EPA 9060 WETA/28165 92245087002 2015010245 EPA 9060 WETA/28164 92245087002 2015010245 EPA 9060 WETA/28165 Date: 04/27/2015 03:26 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14455 ICP/14455 ICPM/9617 ICPM/9617 ICPM/23916 ICPM/23916 ICPM/23839 MERC/15387 MERC/15482 MERC/15482 MERC/5585 MERC/5585 Page 52 of 54 �ICOAwfyfibal' Document Name: Condition Upon Receii Document Number: F-CHR-CS-003-rev.15 Document Revised: September 22. ZU14 Passe 1 of 2 _ Issuing At.lflaoW of 61 Pace Huntersville Quality Office Client dame: Dt1t R- r A er y Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ C ercial❑ �ther, Custody Seal on Cooler/Box Present: ❑ yes no Seals intact: El yes El no Packing Material: ❑ Bubble'Dp Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun 14 Type of Ice: Blue None amples on ice, cooling process has begun Temp Correction Factor T1401 No Correction G .0 Biological Tissue is Frozen: Yes No Date and Initia of,tt��erson examinir� Corrected Cooler Temp.: contents: d' Temp should be above freezing to 6°C -I-,' Comments: Chain of Custody Present: Eff"'S'JUM ❑NIA 1. Chain of Custody Filled Out: es ❑ ❑NrA 2. Chain of Custody Relinquished: ❑ o ❑NrA 3. Sampler Name & Signature on COC: 111Ye, ,5-10N/A 4• Samples Arrived within Hold Time: EY,, El No ❑ 5. Short Hold Time Analysis (<72hr): ❑Yes o ❑ IA 6. Rush Turn Around Time Requested: ❑Yes o ❑NIA 7. Sufficient Volume: es o ❑N/A 8. Correct Containers Used: es IA g.-Pace Containers Used: ❑Yes �INA Containers Intact; es ❑No ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes N*o- EINK 11. Sample Labels match COC: Yes El No ❑NIA 12. -Includes date/time/ID/Analysis Matrix: Ali containers needing preservation have been checked. ❑Yes ❑N ❑N!A 13. All containers needing preservation are found to be in yes ❑No ❑ A compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, Vll-DRO (water) []Yes No Samples checked for dechlorination: ❑Yes []No P<A 1 . Headspace in VOA Vials ( >6mm): ❑Yes ❑No I 5. Trip Blank Present: ❑Yes ❑No NIA Trip Blank Custody Seals Present ❑Yes ❑No NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: YL+t Date: SRF Review: 1 %i,; Date: WO# • 9�22460'817 Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR 1111111111111111111111 Certification Office ( Le out of hold, incorrect preservative, out of temp, 92245087 incorrect containers) Page 53 of 54 Page 60 of 61 t i G y_ c inr s� CusromET to COMPlele upproprialc columns to right �. 3 .16 MOI m ry2 AC Tm PID tzae o d a T1 1 f[ C O a ii ' N n M 0 1 1 $ oa { ° �m C—tenw muss Y m lu CL Q am , w m h N Q w I 'w y T a 0 m idGrob Ft 2111111 Total Metals , Anions, PM 1 -8 oz jar (PACE). C 1 - 4 oz jar 5 PLP - Total Metals and pions 2-8 it jars (PACE) 5 Sediment specific tests i! - 8 oz jar (ACCESS WALYTICAL) 7°ToW # of Containers 5 Z a M a ern O c C 7< Q � CD T I l r Drn I I i IT w m d r a i �3 ; N op, .yr s di7 ffiC13— >4 I� �i I a .ill i I N ; 4 h � ry s lW M i p NJ �] G M 00 gO {� • IQ s f I � r !D b I ❑ �b m d cn F yr , fn 0i RiM c i to z 2iC o Cim IF ®! Gn I w o nib �! F. !0 I 0 3 i� o i a i I � i n I Il !!_o Inrn n I � 3 i �1 O x 0 � r M of Q•' .> I? rrt Page !8 of 54 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM ------ SYNTERRA EDD ------------ ----------------------- "cal Labo all Laborato Use Only 4 P�� I {Sr I N.. ------------ wtwr;'�w��j ....... Mqll Code MG03A2 [EWIdoing 7405) 1 DUKE mivirix: SOIL r C. i DISTRIBUTION 1.1339 Flagem FeFry Rd Ur I f%%f ; Ji'55oq J-1 — — G'I M; INAL iri LAE!. jr,tom4mr.. N.C. noys iLiiwd "! k ENERUT. it ki9H�p ass -seal i - TEL le, CL, ENT i L SAMPLE PROORAAS G*UTA Ifflow -------------- I 1AS Gtouredwatef Assessment - Soll r4" D - (41i REV DA-11 731V201 5 HIF LEE I PACE CoolWer TfL UP PO 11420111 'P' Aft GW 2Air' 4;10— st-wbhe LP k � -------------- — .. I I Ilimgmrtaild. w;ei. specific accountlifig hfts tmi4il v61.01.shvi anil ks OW lffmgubod Mbwo wn jborij Itm In a4l _ -iccoupAling Was MDOWD. Or PF850TVfffi"* WhOn L]"d musl be "004 with Itl 15 MIA.1tes of sample collectk1w, IntGrmatk3n 1] atp. circa: sloriatury L 4 LAS L-02 ONLY ..L,40 i IS-i, &�bn*M. A2h) "Sampk- Description or ID yy r 13 ------------- uj 0 0 '7� r- M N 0 0. E E No ou CL C 0 CL 0 2411: WATEER EQIIJTMENT KANK (1 PER DAY) I'S AL &btl I es M4AAY-- _jb ('ww o Y '000p,tLlel7im. AcsrDAVTu MoUls: Al. S b. As, Ba. 50, la, Cd, Ca, Cr, Cc, Cu, Fe. Pb, mg, Mn, mo. Ni. K. Se. Na, SF, 1I. V, Zn, W-Trury, PH Aniurm. Cl. NAnpit4�-N-504 S&djmv"t Spocific PdF1Af1`bffte73: %SMids, CEC. Pjirtirle Size mstribubon, Redox Pcytonlial - AWI 94 uR"-uested Turnaround 64 -Oq-- 14 oovs ----x 1,;3 -48 Hr