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HomeMy WebLinkAboutNC0003417_J15040045 Report_20150805+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J15040045 Project Name: HF LEE PLANT - AB GW ASSESSMENT SOIL Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer Customer Address: 1677 Old Smithfield Rd Goldsboro NC 27530, Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 � MXG4644(101161) Report Authorized By: 2015.05.28 09:11:26 Date: (Signature) "►RGY-04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/26/2015 ilii[im Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2 of 102 2015009361 HF LEE PLANT 31-Mar-15 11:45 AM ILLEGIBLE Well LLMW-1-2-3 2015009362 HF LEE PLANT 31-Mar-15 1:05 PM ILLEGIBLE Well LLMW-2-1.5-2.5 2015009363 HF LEE PLANT 30-Mar-15 1:27 PM ILLEGIBLE Well IABMW-1-3-4 2015009364 HF LEE PLANT 30-Mar-15 2:09 PM ILLEGIBLE Well IABMW-1-8-10 2015009365 HF LEE PLANT 30-Mar-15 3:18 PM ILLEGIBLE Well IABMW-1-12-13 2015009366 HF LEE PLANT 30-Mar-15 3:30 PM ILLEGIBLE Well IABMW-1-18-20 2015009367 HF LEE PLANT 01-Apr-15 10:05 AM ILLEGIBLE Well LLMW-2-8-9 2015009368 HF LEE PLANT 01-Apr-15 10:27 AM ILLEGIBLE Well LLMW-2-11-12 2015009369 HF LEE PLANT 01-Apr-15 7:20 AM ILLEGIBLE Well Equipment Blank 2015009370 HF LEE PLANT 31-Mar-15 10:12 AM ILLEGIBLE Well Equipment Blank 10 Total Samples Oni 511M Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well LLMW-1-2-3 Collection Date: 31-Mar-15 11:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 102 Sample #: 2015009361 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well LLMW-2-1.5-2.5 Collection Date: 31-Mar-15 1:05 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 102 Sample #: 2015009362 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well IABMW-1-3-4 Collection Date: 30-Mar-15 1:27 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 102 Sample #: 2015009363 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well IABMW-1-8-10 Collection Date: 30-Mar-15 2:09 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 102 Sample #: 2015009364 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well IABMW-1-12-13 Collection Date: 30-Mar-15 3:18 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 8 of 102 Sample #: 2015009365 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well IABMW-1-18-20 Collection Date: 30-Mar-15 3:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 9 of 102 Sample #: 2015009366 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well LLMW-2-8-9 Collection Date: 01-Apr-15 10:05 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015009367 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well LLMW-2-11-12 Collection Date: 01-Apr-15 10:27 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 11 of 102 Sample #: 2015009368 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis 12 of 102 This report shall not be reproduced, except in full. Order # J15040045 Site: Well Equipment Blank Collection Date: 01-Apr-15 7:20 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015009369 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040045 Site: Well Equipment Blank Collection Date: 31-Mar-15 10:12 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015009370 Matrix: SOIL 13 of 102 Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980011,ir6fy011je. Suite 100 Huntersville, INC 28078 (704)875-9092 May 13, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15040045 Pace Project No.: 92243920 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 02, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 88 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 980011� y6r. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98001�yo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98001�yo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15040045 Pace Project No.: 92243920 Lab ID Sample ID Matrix Date Collected Date Received 92243920001 2015009361 Solid 03131/1511:45 04/02/15 15:30 92243920002 2015009362 Solid 03/31/1513:05 04/02/15 15:30 92243920003 2015009363 Solid 03/30/1513:27 04/02/15 15:30 92243920004 2015009364 Solid 03/30/1514:09 04/02/15 15:30 92243920005 2015009365 Solid 03/30/1515:18 04/02/15 15:30 92243920006 2015009366 Solid 03/30/15 15:30 04/02/15 15:30 92243920007 2015009367 Solid 04/01/1510:05 04/02/15 15:30 92243920008 2015009368 Solid 04/01/1510:27 04/02/15 15:30 92243920009 2015009369 Water 04/01/15 07:20 04/02/15 15:30 92243920010 2015009370 Water 03/31/1510:12 04/02/15 15:30 92243920011 2015009361 SPLP Water 03/31/15 11:45 04/02/15 15:30 92243920012 2015009362 SPLP Water 03/31/15 13:05 04/02/15 15:30 92243920013 2015009363 SPLP Water 03/30/15 13:27 04/02/15 15:30 92243920014 2015009364 SPLP Water 03/30/15 14:09 04/02/15 15:30 92243920015 2015009365 SPLP Water 03/30/15 15:18 04/02/15 15:30 92243920016 2015009366 SPLP Water 03/30/15 15:30 04/02/15 15:30 92243920017 2015009367 SPLP Water 04/01/15 10:05 04/02/15 15:30 92243920018 2015009368 SPLP Water 04/01/15 10:27 04/02/15 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98001�yo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15040045 Pace Project No.: 92243920 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92243920001 2015009361 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243920002 2015009362 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243920003 2015009363 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243920004 2015009364 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT, DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980019,6fYo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15040045 Pace Project No.: 92243920 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243920005 2015009365 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243920006 2015009366 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243920007 2015009367 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800�8rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15040045 92243920 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243920008 2015009368 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243920009 2015009369 EPA 6020A RJS 24 PASI-M EPA 7470 DM 1 PASI-M 92243920010 2015009370 EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92243920011 2015009361 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92243920012 2015009362 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92243920013 2015009363 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92243920014 2015009364 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92243920015 2015009365 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92243920016 2015009366 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92243920017 2015009367 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92243920018 2015009368 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980c�)irpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92243920001 2015009361 EPA 6010 Aluminum 17400 mg/kg 50.0 04/13/15 00:56 D3 EPA 6010 Barium 806 mg/kg 5.0 04/13/15 00:56 D3 EPA 6010 Beryllium 6.9 mg/kg 0.50 04/13/15 00:56 D3 EPA 6010 Boron 22AJ mg/kg 25.0 04/13/15 00:56 D3 EPA 6010 Calcium 5750 mg/kg 250 04/13/15 00:56 D3 EPA 6010 Chromium 31.9 mg/kg 2.5 04/13/15 00:56 D3 EPA 6010 Copper 61.7 mg/kg 2.5 04/13/15 00:56 D3 EPA 6010 Iron 12000 mg/kg 20.0 04/13/15 00:56 D3 EPA 6010 Magnesium 1890 mg/kg 250 04/13/15 00:56 D3 EPA 6010 Manganese 161 mg/kg 2.5 04/13/15 00:56 D3 EPA 6010 Nickel 28.8 mg/kg 2.5 04/13/15 00:56 D3 EPA 6010 Potassium 2250 mg/kg 500 04/13/15 00:56 D3 EPA 6010 Sodium 429J mg/kg 500 04/13/15 00:56 D3 EPA 6010 Strontium 479 mg/kg 5.0 04/13/15 00:56 D3 EPA 6010 Zinc 25.2 mg/kg 10 04/13/15 00:56 D3 EPA 6020 Arsenic 105 mg/kg 5.0 04/16/15 20:36 D3 EPA 6020 Cobalt 15.4 mg/kg 5.0 04/16/15 20:36 D3 EPA 6020 Lead 18.7 mg/kg 5.0 04/16/15 20:36 D3 EPA 6020 Selenium 8.4 mg/kg 5.0 04/16/15 20:36 D3 EPA 6020 Vanadium 63.6 mg/kg 5.0 04/16/15 20:36 D3 EPA 7471 Mercury 0.081 mg/kg 0.016 04/13/15 18:15 ASTM D2974-87 Percent Moisture 47.6 % 0.10 04/10/15 14:16 EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 04/10/15 12:45 EPA 300.0 Sulfate 8.8 mg/L 3.8 04/15/15 17:10 B EPA 9060 Total Organic Carbon 66400 mg/kg 5610 04/22/15 10:18 EPA 9060 Total Organic Carbon 84900 mg/kg 5690 04/22/15 10:25 EPA 9060 Total Organic Carbon 117000 mg/kg 5610 04/22/15 10:30 EPA 9060 Total Organic Carbon 75900 mg/kg 5540 04/22/15 10:36 EPA 9060 Mean Total Organic Carbon 86000 mg/kg 5610 04/22/15 10:18 EPA 9060 RSD% 25.5 % 04/22/15 10:18 92243920002 2015009362 EPA 6010 Aluminum 6330 mg/kg 48.8 04/13/15 01:00 D3 EPA 6010 Barium 1140 mg/kg 4.9 04/13/15 01:00 D3 EPA 6010 Beryllium 1.9 mg/kg 0.49 04/13/15 01:00 D3 EPA 6010 Boron 17.5J mg/kg 24.4 04/13/15 01:00 D3 EPA 6010 Calcium 2940 mg/kg 244 04/13/15 01:00 D3 EPA 6010 Chromium 13.6 mg/kg 2.4 04/13/15 01:00 D3 EPA 6010 Copper 32.2 mg/kg 2.4 04/13/15 01:00 D3 EPA 6010 Iron 12600 mg/kg 19.5 04/13/15 01:00 D3 EPA 6010 Magnesium 595 mg/kg 244 04/13/15 01:00 D3 EPA 6010 Manganese 77.4 mg/kg 2.4 04/13/15 01:00 D3 EPA 6010 Nickel 13.1 mg/kg 2.4 04/13/15 01:00 D3 EPA 6010 Potassium 786 mg/kg 488 04/13/15 01:00 D3 EPA 6010 Strontium 189 mg/kg 4.9 04/13/15 01:00 D3 EPA 6010 Zinc 7.8J mg/kg 9.8 04/13/15 01:00 D3 EPA 6020 Arsenic 45.4 mg/kg 4.9 04/16/15 20:38 D3 EPA 6020 Cobalt 5.0 mg/kg 4.9 04/16/15 20:38 D3 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800�qrpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92243920002 2015009362 EPA 6020 Lead 5.1 mg/kg 4.9 04/16/15 20:38 EPA 6020 Selenium 2.5J mg/kg 4.9 04/16/15 20:38 EPA 6020 Vanadium 34.2 mg/kg 4.9 04/16/15 20:38 EPA 7471 Mercury 0.072 mg/kg 0.015 04/13/15 18:17 ASTM D2974-87 Percent Moisture 46.8 % 0.10 04/10/15 14:17 EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 04/10/15 12:45 EPA 300.0 Sulfate 8.4 mg/L 3.8 04/15/15 17:24 EPA 9060 Total Organic Carbon 62400 mg/kg 5410 04/22/15 12:28 EPA 9060 Total Organic Carbon 88100 mg/kg 5430 04/22/15 12:34 EPA 9060 Total Organic Carbon 99300 mg/kg 5480 04/22/15 12:40 EPA 9060 Total Organic Carbon 79200 mg/kg 5470 04/22/15 12:47 EPA 9060 Mean Total Organic Carbon 82300 mg/kg 5450 04/22/15 12:28 EPA 9060 RSD% 18.9 % 04/22/15 12:28 92243920003 2015009363 EPA 6010 Aluminum 12700 mg/kg 53.4 04/13/15 01:05 EPA 6010 Barium 900 mg/kg 5.3 04/13/15 01:05 EPA 6010 Beryllium 4.3 mg/kg 0.53 04/13/15 01:05 EPA 6010 Boron 35.2 mg/kg 26.7 04/13/15 01:05 EPA 6010 Calcium 5200 mg/kg 267 04/13/15 01:05 EPA 6010 Chromium 28.2 mg/kg 2.7 04/13/15 01:05 EPA 6010 Copper 44.8 mg/kg 2.7 04/13/15 01:05 EPA 6010 Iron 20900 mg/kg 21.3 04/13/15 01:05 EPA 6010 Magnesium 1100 mg/kg 267 04/13/15 01:05 EPA 6010 Manganese 126 mg/kg 2.7 04/13/15 01:05 EPA 6010 Nickel 25.2 mg/kg 2.7 04/13/15 01:05 EPA 6010 Potassium 1250 mg/kg 534 04/13/15 01:05 EPA 6010 Strontium 357 mg/kg 5.3 04/13/15 01:05 EPA 6010 Zinc 18.0 mg/kg 10.7 04/13/15 01:05 EPA 6020 Arsenic 53.5 mg/kg 5.3 04/16/15 20:40 EPA 6020 Cobalt 10.3 mg/kg 5.3 04/16/15 20:40 EPA 6020 Lead 12.4 mg/kg 10.7 04/20/15 09:55 EPA 6020 Selenium 4.3J mg/kg 5.3 04/16/15 20:40 EPA 6020 Vanadium 56.5 mg/kg 5.3 04/16/15 20:40 EPA 7471 Mercury 0.086 mg/kg 0.017 04/13/15 18:19 ASTM D2974-87 Percent Moisture 53.6 % 0.10 04/10/15 14:18 EPA 9045 pH at 25 Degrees C 6.6 Std. Units 0.10 04/10/15 12:45 EPA 300.0 Sulfate 12.7 mg/L 4.3 04/15/15 17:37 EPA 9060 Total Organic Carbon 95300 mg/kg 5510 04/22/15 12:53 EPA 9060 Total Organic Carbon 128000 mg/kg 5480 04/22/15 13:00 EPA 9060 Total Organic Carbon 129000 mg/kg 5460 04/22/15 13:06 EPA 9060 Total Organic Carbon 135000 mg/kg 5520 04/22/15 13:12 EPA 9060 Mean Total Organic Carbon 122000 mg/kg 5490 04/22/15 12:53 EPA 9060 RSD% 14.8 % 04/22/15 12:53 92243920004 2015009364 D3 D3 D3 B D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 B EPA 6010 Aluminum 12100 mg/kg 44.7 04/13/15 01:09 D3 EPA 6010 Barium 502 mg/kg 4.5 04/13/15 01:09 D3 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800�Srpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92243920004 2015009364 EPA 6010 Beryllium 4.7 mg/kg 0.45 04/13/15 01:09 D3 EPA 6010 Boron 20.OJ mg/kg 22.4 04/13/15 01:09 D3 EPA 6010 Calcium 8760 mg/kg 224 04/13/15 01:09 D3 EPA 6010 Chromium 27.6 mg/kg 2.2 04/13/15 01:09 D3 EPA 6010 Copper 40.6 mg/kg 2.2 04/13/15 01:09 D3 EPA 6010 Iron 7130 mg/kg 17.9 04/13/15 01:09 D3 EPA 6010 Magnesium 1240 mg/kg 224 04/13/15 01:09 D3 EPA 6010 Manganese 86.4 mg/kg 2.2 04/13/15 01:09 D3 EPA 6010 Nickel 21.9 mg/kg 2.2 04/13/15 01:09 D3 EPA 6010 Potassium 962 mg/kg 447 04/13/15 01:09 D3 EPA 6010 Sodium 299J mg/kg 447 04/13/15 01:09 D3 EPA 6010 Strontium 448 mg/kg 4.5 04/13/15 01:09 D3 EPA 6010 Zinc 16.5 mg/kg 8.9 04/13/15 01:09 D3 EPA 6020 Arsenic 22.7 mg/kg 4.5 04/16/15 20:43 D3 EPA 6020 Cobalt 10.1 mg/kg 4.5 04/16/15 20:43 D3 EPA 6020 Lead 12.9 mg/kg 8.9 04/21/1511:09 D3 EPA 6020 Selenium 5.6 mg/kg 4.5 04/16/15 20:43 D3 EPA 6020 Vanadium 61.0 mg/kg 4.5 04/16/15 20:43 D3 EPA 7471 Mercury 0.090 mg/kg 0.013 04/13/15 18:22 ASTM D2974-87 Percent Moisture 41.7 % 0.10 04/10/15 14:18 EPA 9045 pH at 25 Degrees C 7.0 Std. Units 0.10 04/10/15 12:45 EPA 300.0 Sulfate 9.7 mg/L 3.4 04/15/15 17:51 B EPA 9060 Total Organic Carbon 164000 mg/kg 7680 04/22/15 13:31 EPA 9060 Total Organic Carbon 134000 mg/kg 7500 04/22/15 13:38 EPA 9060 Total Organic Carbon 133000 mg/kg 7800 04/22/15 13:44 EPA 9060 Total Organic Carbon 147000 mg/kg 7390 04/22/15 13:52 EPA 9060 Mean Total Organic Carbon 144000 mg/kg 7590 04/22/15 13:31 EPA 9060 RSD% 10.2 % 04/22/15 13:31 92243920005 2015009365 EPA 6010 Aluminum 10800 mg/kg 33.0 04/13/15 01:13 D3 EPA 6010 Barium 101 mg/kg 3.3 04/13/15 01:13 D3 EPA 6010 Beryllium 0.79 mg/kg 0.33 04/13/15 01:13 D3 EPA 6010 Boron 24.3 mg/kg 16.5 04/13/15 01:13 D3 EPA 6010 Calcium 725 mg/kg 165 04/13/15 01:13 D3 EPA 6010 Chromium 14.9 mg/kg 1.7 04/13/15 01:13 D3 EPA 6010 Copper 16.0 mg/kg 1.7 04/13/15 01:13 D3 EPA 6010 Iron 25100 mg/kg 13.2 04/13/15 01:13 D3 EPA 6010 Magnesium 1270 mg/kg 165 04/13/15 01:13 D3 EPA 6010 Manganese 68.4 mg/kg 1.7 04/13/15 01:13 D3 EPA 6010 Nickel 9.1 mg/kg 1.7 04/13/15 01:13 D3 EPA 6010 Strontium 13.6 mg/kg 3.3 04/13/15 01:13 D3 EPA 6010 Zinc 20.8 mg/kg 6.6 04/13/15 01:13 D3 EPA 6020 Cobalt 11.8 mg/kg 3.3 04/16/15 20:45 D3 EPA 6020 Lead 13.2 mg/kg 3.3 04/16/15 20:45 D3 EPA 6020 Vanadium 48.5 mg/kg 3.3 04/16/15 20:45 D3 EPA 7471 Mercury 0.012 mg/kg 0.010 04/13/15 18:24 ASTM D2974-87 Percent Moisture 23.6 % 0.10 04/10/15 14:19 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800Airpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92243920005 2015009365 EPA 9045 pH at 25 Degrees C 5.4 Std. Units 0.10 04/10/15 12:45 EPA 300.0 Sulfate 5.3 mg/L 2.6 04/15/15 18:04 EPA 353.2 Nitrogen, Nitrate 0.28 mg/L 0.26 04/15/15 17:29 EPA 9060 Total Organic Carbon 1710 mg/kg 779 04/22/15 13:58 EPA 9060 Total Organic Carbon 1780 mg/kg 785 04/22/15 14:03 EPA 9060 Total Organic Carbon 1700 mg/kg 785 04/22/15 14:09 EPA 9060 Total Organic Carbon 1590 mg/kg 786 04/22/15 14:15 EPA 9060 Mean Total Organic Carbon 1700 mg/kg 784 04/22/15 13:58 EPA 9060 RSD% 4.5 % 04/22/15 13:58 92243920006 2015009366 EPA 6010 Aluminum 430 mg/kg 31.2 04/13/15 01:17 EPA 6010 Barium 7.7 mg/kg 3.1 04/13/15 01:17 EPA 6010 Beryllium 0.42 mg/kg 0.31 04/13/15 01:17 EPA 6010 Boron 28.4 mg/kg 15.6 04/13/15 01:17 EPA 6010 Calcium 253 mg/kg 156 04/13/15 01:17 EPA 6010 Chromium 8.0 mg/kg 1.6 04/13/15 01:17 EPA 6010 Copper 196 mg/kg 1.6 04/13/15 01:17 EPA 6010 Iron 25400 mg/kg 12.5 04/13/15 01:17 EPA 6010 Manganese 199 mg/kg 1.6 04/13/15 01:17 EPA 6010 Nickel 17.3 mg/kg 1.6 04/13/15 01:17 EPA 6010 Strontium 2.9J mg/kg 3.1 04/13/15 01:17 EPA 6010 Zinc 17.9 mg/kg 6.2 04/13/15 01:17 EPA 6020 Cobalt 14.5 mg/kg 6.2 04/20/15 09:57 EPA 6020 Vanadium 17.7 mg/kg 6.2 04/20/15 09:57 EPA 7471 Mercury 0.017 mg/kg 0.010 04/13/15 18:26 ASTM D2974-87 Percent Moisture 20.1 % 0.10 04/10/15 14:21 EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 04/10/15 12:45 EPA 300.0 Sulfate 6.2 mg/L 2.5 04/15/15 18:45 EPA 9060 Total Organic Carbon 1440 mg/kg 754 04/22/15 14:21 EPA 9060 Total Organic Carbon 789 mg/kg 758 04/22/15 14:28 EPA 9060 Total Organic Carbon 500J mg/kg 751 04/22/15 14:33 EPA 9060 Total Organic Carbon 1430 mg/kg 749 04/22/15 14:39 EPA 9060 Mean Total Organic Carbon 1040 mg/kg 753 04/22/15 14:21 EPA 9060 RSD% 45.4 % 04/22/15 14:21 92243920007 2015009367 EPA 6010 Aluminum 12400 mg/kg 30.2 04/14/15 10:07 EPA 6010 Barium 230 mg/kg 3.0 04/14/15 10:07 EPA 6010 Beryllium 1.3 mg/kg 0.30 04/14/15 10:07 EPA 6010 Calcium 888 mg/kg 151 04/14/15 10:07 EPA 6010 Chromium 20.5 mg/kg 1.5 04/14/15 10:07 EPA 6010 Copper 14.3 mg/kg 1.5 04/14/15 10:07 EPA 6010 Iron 29200 mg/kg 12.1 04/14/15 10:07 EPA 6010 Magnesium 2130 mg/kg 151 04/14/15 10:07 EPA 6010 Manganese 898 mg/kg 1.5 04/14/15 10:07 EPA 6010 Nickel 7.3 mg/kg 1.5 04/14/15 10:07 EPA 6010 Potassium 584 mg/kg 302 04/14/15 10:07 REPORT OF LABORATORY ANALYSIS B H1 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 B 1g This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800Airpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92243920007 2015009367 EPA 6010 Strontium 32.0 mg/kg 3.0 04/14/15 10:07 EPA 6010 Zinc 27.4 mg/kg 6.0 04/14/15 10:07 EPA 6020 Arsenic 4.3J mg/kg 6.0 04/20/15 09:59 EPA 6020 Cobalt 13.8 mg/kg 6.0 04/20/15 09:59 EPA 6020 Lead 12.3 mg/kg 3.0 04/16/15 20:49 EPA 6020 Vanadium 55.3 mg/kg 6.0 04/20/15 09:59 EPA 7471 Mercury 0.048 mg/kg 0.0096 04/13/15 18:28 ASTM D2974-87 Percent Moisture 20.3 % 0.10 04/10/15 14:22 EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 04/10/15 12:45 EPA 300.0 Sulfate 3.5 mg/L 2.5 04/15/15 18:59 EPA 353.2 Nitrogen, Nitrate 0.26 mg/L 0.25 04/15/15 17:31 EPA 9060 Total Organic Carbon 1940 mg/kg 750 04/22/15 14:45 EPA 9060 Total Organic Carbon 2270 mg/kg 758 04/22/15 14:52 EPA 9060 Total Organic Carbon 1900 mg/kg 758 04/22/15 14:57 EPA 9060 Total Organic Carbon 1700 mg/kg 756 04/22/15 15:04 EPA 9060 Mean Total Organic Carbon 1950 mg/kg 755 04/22/15 14:45 EPA 9060 RSD% 12.1 % 04/22/15 14:45 92243920008 2015009368 EPA 6010 Aluminum 11800 mg/kg 32.1 04/14/15 10:11 EPA 6010 Barium 164 mg/kg 3.2 04/14/15 10:11 EPA 6010 Beryllium 0.93 mg/kg 0.32 04/14/15 10:11 EPA 6010 Calcium 906 mg/kg 161 04/14/15 10:11 EPA 6010 Chromium 24.1 mg/kg 1.6 04/14/15 10:11 EPA 6010 Copper 14.1 mg/kg 1.6 04/14/15 10:11 EPA 6010 Iron 20100 mg/kg 12.9 04/14/15 10:11 EPA 6010 Magnesium 2440 mg/kg 161 04/14/15 10:11 EPA 6010 Manganese 199 mg/kg 1.6 04/14/15 10:11 EPA 6010 Nickel 7.3 mg/kg 1.6 04/14/15 10:11 EPA 6010 Potassium 619 mg/kg 321 04/14/15 10:11 EPA 6010 Strontium 18.9 mg/kg 3.2 04/14/15 10:11 EPA 6010 Zinc 30.9 mg/kg 6.4 04/14/15 10:11 EPA 6020 Cobalt 3.9J mg/kg 6.4 04/20/15 10:01 EPA 6020 Lead 9.0 mg/kg 3.2 04/16/15 20:52 EPA 6020 Vanadium 55.7 mg/kg 6.4 04/20/15 10:01 EPA 7471 Mercury 0.031 mg/kg 0.010 04/13/15 18:46 ASTM D2974-87 Percent Moisture 20.1 % 0.10 04/10/15 14:23 EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 04/10/15 12:45 EPA 300.0 Sulfate 4.8 mg/L 2.5 04/15/15 19:12 EPA 353.2 Nitrogen, Nitrate 0.32 mg/L 0.25 04/15/15 17:32 EPA 9060 Total Organic Carbon 1710 mg/kg 753 04/22/15 15:10 EPA 9060 Total Organic Carbon 1620 mg/kg 755 04/22/15 15:15 EPA 9060 Total Organic Carbon 1860 mg/kg 751 04/22/15 15:21 EPA 9060 Total Organic Carbon 1660 mg/kg 747 04/22/15 15:27 EPA 9060 Mean Total Organic Carbon 1710 mg/kg 752 04/22/15 15:10 EPA 9060 RSD% 6.2 % 04/22/15 15:10 REPORT OF LABORATORY ANALYSIS D3 B H1 D3 B H1 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800z1 ,pyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92243920009 2015009369 EPA 6020A Chromium 23.6 ug/L 0.50 04/13/15 12:11 EPA 6020A Cobalt 0.58 ug/L 0.50 04/13/15 12:11 EPA 6020A Iron 154 ug/L 50.0 04/13/15 12:11 EPA 6020A Manganese 2.4 ug/L 0.50 04/13/15 12:11 EPA 6020A Nickel 16.9 ug/L 0.50 04/13/15 12:11 92243920010 2015009370 EPA 6020A Barium 1.0 ug/L 0.30 04/13/15 12:16 EPA 6020A Magnesium 11.3 ug/L 10.0 04/13/15 12:16 92243920011 2015009361 SPLP EPA 6020A Aluminum 640 ug/L 50.0 04/30/15 12:06 EPA 6020A Antimony 0.83J ug/L 2.5 04/30/15 12:06 EPA 6020A Arsenic 16.5 ug/L 2.5 04/30/15 12:06 EPA 6020A Barium 277 ug/L 1.5 04/30/15 12:06 EPA 6020A Boron 90.6 ug/L 25.0 04/30/15 12:06 EPA 6020A Calcium 2130 ug/L 200 04/30/15 12:06 EPA 6020A Chromium 6.7 ug/L 2.5 04/30/15 12:06 EPA 6020A Copper 5.8 ug/L 5.0 04/30/15 12:06 EPA 6020A Iron 522 ug/L 250 04/30/15 12:06 EPA 6020A Lead 0.92 ug/L 0.50 04/30/15 12:06 EPA 6020A Magnesium 445 ug/L 50.0 04/30/15 12:06 EPA 6020A Manganese 9.9 ug/L 2.5 04/30/15 12:06 EPA 6020A Molybdenum 1.2J ug/L 2.5 04/30/15 12:06 EPA 6020A Nickel 1.3J ug/L 2.5 04/30/15 12:06 EPA 6020A Potassium 351 ug/L 250 04/30/15 12:06 EPA 6020A Selenium 1.91 ug/L 2.5 04/30/15 12:06 EPA 6020A Sodium 2040 ug/L 250 04/30/15 12:06 EPA 6020A Strontium 76.7 ug/L 2.5 04/30/15 12:06 EPA 6020A Vanadium 17.7 ug/L 5.0 04/30/15 12:06 EPA 6020A Zinc 80.0 ug/L 25.0 04/30/15 12:06 92243920012 2015009362 SPLP EPA 6020A Aluminum 594 ug/L 10.0 04/30/15 11:58 EPA 6020A Antimony 0.84 ug/L 0.50 04/30/15 11:58 EPA 6020A Arsenic 28.4 ug/L 0.50 04/30/15 11:58 EPA 6020A Barium 240 ug/L 0.30 04/30/15 11:58 EPA 6020A Beryllium 0.16J ug/L 0.20 04/30/15 11:58 EPA 6020A Boron 35.5 ug/L 5.0 04/30/15 11:58 EPA 6020A Cadmium 0.053J ug/L 0.080 04/30/15 11:58 EPA 6020A Calcium 2050 ug/L 40.0 04/30/15 11:58 EPA 6020A Chromium 4.5 ug/L 0.50 04/30/15 11:58 EPA 6020A Cobalt 0.58 ug/L 0.50 04/30/15 11:58 EPA 6020A Copper 3.8 ug/L 1.0 04/30/15 11:58 EPA 6020A Iron 480 ug/L 50.0 04/30/15 11:58 EPA 6020A Lead 1.2 ug/L 0.10 04/30/15 11:58 EPA 6020A Magnesium 524 ug/L 10.0 04/30/15 11:58 EPA 6020A Manganese 27.0 ug/L 0.50 04/30/15 11:58 EPA 6020A Molybdenum 1.3 ug/L 0.50 04/30/15 11:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800&pyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92243920012 2015009362 SPLP EPA 6020A Nickel 1.9 ug/L 0.50 04/30/15 11:58 EPA 6020A Potassium 363 ug/L 50.0 04/30/15 11:58 EPA 6020A Selenium 1.1 ug/L 0.50 04/30/15 11:58 EPA 6020A Sodium 1900 ug/L 50.0 04/30/15 11:58 EPA 6020A Strontium 105 ug/L 0.50 04/30/15 11:58 EPA 6020A Thallium 0.14 ug/L 0.10 04/30/15 11:58 EPA 6020A Vanadium 25.3 ug/L 1.0 04/30/15 11:58 EPA 6020A Zinc 33.1 ug/L 5.0 04/30/15 11:58 92243920013 2015009363 SPLP EPA 6020A Aluminum 572 ug/L 10.0 04/30/15 12:01 EPA 6020A Antimony 0.93 ug/L 0.50 04/30/15 12:01 EPA 6020A Arsenic 21.5 ug/L 0.50 04/30/15 12:01 EPA 6020A Barium 177 ug/L 0.30 04/30/15 12:01 EPA 6020A Beryllium 0.20 ug/L 0.20 04/30/15 12:01 EPA 6020A Boron 56.9 ug/L 5.0 04/30/15 12:01 EPA 6020A Cadmium 0.035J ug/L 0.080 04/30/15 12:01 EPA 6020A Calcium 3150 ug/L 40.0 04/30/15 12:01 EPA 6020A Chromium 4.0 ug/L 0.50 04/30/15 12:01 EPA 6020A Cobalt 0.45J ug/L 0.50 04/30/15 12:01 EPA 6020A Copper 3.7 ug/L 1.0 04/30/15 12:01 EPA 6020A Iron 372 ug/L 50.0 04/30/15 12:01 EPA 6020A Lead 0.84 ug/L 0.10 04/30/15 12:01 EPA 6020A Magnesium 560 ug/L 10.0 04/30/15 12:01 EPA 6020A Manganese 5.4 ug/L 0.50 04/30/15 12:01 EPA 6020A Molybdenum 2.3 ug/L 0.50 04/30/15 12:01 EPA 6020A Nickel 1.3 ug/L 0.50 04/30/15 12:01 EPA 6020A Potassium 1130 ug/L 50.0 04/30/15 12:01 EPA 6020A Selenium 1.8 ug/L 0.50 04/30/15 12:01 EPA 6020A Sodium 1490 ug/L 50.0 04/30/15 12:01 EPA 6020A Strontium 118 ug/L 0.50 04/30/15 12:01 EPA 6020A Thallium 0.058J ug/L 0.10 04/30/15 12:01 EPA 6020A Vanadium 35.1 ug/L 1.0 04/30/15 12:01 EPA 6020A Zinc 32.1 ug/L 5.0 04/30/15 12:01 92243920014 2015009364 SPLP EPA 6020A Aluminum 204 ug/L 10.0 04/30/15 12:04 EPA 6020A Antimony 3.5 ug/L 0.50 04/30/15 12:04 EPA 6020A Arsenic 13.6 ug/L 0.50 04/30/15 12:04 EPA 6020A Barium 244 ug/L 0.30 04/30/15 12:04 EPA 6020A Boron 62.8 ug/L 5.0 04/30/15 12:04 EPA 6020A Cadmium 0.027J ug/L 0.080 04/30/15 12:04 EPA 6020A Calcium 14000 ug/L 40.0 04/30/15 12:04 EPA 6020A Chromium 2.5 ug/L 0.50 04/30/15 12:04 EPA 6020A Copper 0.49J ug/L 1.0 04/30/15 12:04 EPA 6020A Iron 17.7J ug/L 50.0 04/30/15 12:04 EPA 6020A Lead 0.070J ug/L 0.10 04/30/15 12:04 EPA 6020A Magnesium 484 ug/L 10.0 04/30/15 12:04 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800Airpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92243920014 2015009364 SPLP EPA 6020A Manganese 4.3 ug/L 0.50 04/30/15 12:04 EPA 6020A Molybdenum 10 ug/L 0.50 04/30/15 12:04 EPA 6020A Nickel 0.49J ug/L 0.50 04/30/15 12:04 EPA 6020A Potassium 129 ug/L 50.0 04/30/15 12:04 EPA 6020A Selenium 12.7 ug/L 0.50 04/30/15 12:04 EPA 6020A Sodium 1390 ug/L 50.0 04/30/15 12:04 EPA 6020A Strontium 548 ug/L 2.5 05/01/1511:00 EPA 6020A Vanadium 100 ug/L 1.0 04/30/15 12:04 EPA 6020A Zinc 31.1 ug/L 5.0 04/30/15 12:04 92243920015 2015009365 SPLP EPA 6020A Aluminum 11300 ug/L 50.0 04/30/15 12:28 EPA 6020A Arsenic 3.0 ug/L 2.5 04/30/15 12:28 EPA 6020A Barium 557 ug/L 1.5 04/30/15 12:28 EPA 6020A Beryllium 2.1 ug/L 1.0 04/30/15 12:28 EPA 6020A Boron 156 ug/L 25.0 04/30/15 12:28 EPA 6020A Calcium 3040 ug/L 200 04/30/15 12:28 EPA 6020A Chromium 11.8 ug/L 2.5 04/30/15 12:28 EPA 6020A Cobalt 6.2 ug/L 2.5 04/30/15 12:28 EPA 6020A Copper 27.0 ug/L 5.0 04/30/15 12:28 EPA 6020A Iron 21900 ug/L 250 04/30/15 12:28 EPA 6020A Lead 33.5 ug/L 0.50 04/30/15 12:28 EPA 6020A Magnesium 2280 ug/L 50.0 04/30/15 12:28 EPA 6020A Manganese 70.4 ug/L 2.5 04/30/15 12:28 EPA 6020A Nickel 5.9 ug/L 2.5 04/30/15 12:28 EPA 6020A Potassium 545 ug/L 250 04/30/15 12:28 EPA 6020A Sodium 3400 ug/L 250 04/30/15 12:28 EPA 6020A Strontium 52.3 ug/L 2.5 04/30/15 12:28 EPA 6020A Thallium 0.14J ug/L 0.50 04/30/15 12:28 EPA 6020A Vanadium 57.7 ug/L 5.0 04/30/15 12:28 EPA 6020A Zinc 172 ug/L 25.0 04/30/15 12:28 92243920016 2015009366 SPLP EPA 6020A Aluminum 13.3 ug/L 10.0 04/30/15 12:30 EPA 6020A Barium 109 ug/L 0.30 04/30/15 12:30 EPA 6020A Boron 41.6 ug/L 5.0 04/30/15 12:30 EPA 6020A Cadmium 0.038J ug/L 0.080 04/30/15 12:30 EPA 6020A Calcium 916 ug/L 40.0 04/30/15 12:30 EPA 6020A Chromium 0.22J ug/L 0.50 04/30/15 12:30 EPA 6020A Cobalt 6.6 ug/L 0.50 04/30/15 12:30 EPA 6020A Copper 0.48J ug/L 1.0 04/30/15 12:30 EPA 6020A Iron 20.1J ug/L 50.0 04/30/15 12:30 EPA 6020A Magnesium 293 ug/L 10.0 04/30/15 12:30 EPA 6020A Manganese 103 ug/L 0.50 04/30/15 12:30 EPA 6020A Nickel 4.3 ug/L 0.50 04/30/15 12:30 EPA 6020A Potassium 137 ug/L 50.0 04/30/15 12:30 EPA 6020A Sodium 2310 ug/L 50.0 04/30/15 12:30 EPA 6020A Strontium 9.0 ug/L 0.50 04/30/15 12:30 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800hrpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040045 Pace Project No.: 92243920 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92243920016 2015009366 SPLP EPA 6020A Zinc 31.3 ug/L 5.0 04/30/15 12:30 92243920017 2015009367 SPLP EPA 6020A Aluminum 9340 ug/L 10.0 04/30/15 12:33 EPA 6020A Arsenic 1.4 ug/L 0.50 04/30/15 12:33 EPA 6020A Barium 358 ug/L 0.30 04/30/15 12:33 EPA 6020A Beryllium 1.5 ug/L 0.20 04/30/15 12:33 EPA 6020A Boron 52.0 ug/L 5.0 04/30/15 12:33 EPA 6020A Calcium 2990 ug/L 40.0 04/30/15 12:33 EPA 6020A Chromium 5.8 ug/L 0.50 04/30/15 12:33 EPA 6020A Cobalt 36.5 ug/L 0.50 04/30/15 12:33 EPA 6020A Copper 23.7 ug/L 1.0 04/30/15 12:33 EPA 6020A Iron 8950 ug/L 50.0 04/30/15 12:33 EPA 6020A Lead 18.8 ug/L 0.10 04/30/15 12:33 EPA 6020A Magnesium 2170 ug/L 10.0 04/30/15 12:33 EPA 6020A Manganese 1680 ug/L 5.0 04/30/15 12:52 EPA 6020A Nickel 5.3 ug/L 0.50 04/30/15 12:33 EPA 6020A Potassium 461 ug/L 50.0 04/30/15 12:33 EPA 6020A Selenium 0.40J ug/L 0.50 04/30/15 12:33 EPA 6020A Sodium 2550 ug/L 50.0 04/30/15 12:33 EPA 6020A Strontium 119 ug/L 0.50 04/30/15 12:33 EPA 6020A Thallium 0.23 ug/L 0.10 04/30/15 12:33 EPA 6020A Vanadium 24.3 ug/L 1.0 04/30/15 12:33 EPA 6020A Zinc 58.0 ug/L 5.0 04/30/15 12:33 92243920018 2015009368 SPLP EPA 6020A Aluminum 15800 ug/L 10.0 04/30/15 12:36 EPA 6020A Arsenic 1.9 ug/L 0.50 04/30/15 12:36 EPA 6020A Barium 1220 ug/L 1.5 05/01/1511:03 EPA 6020A Beryllium 2.8 ug/L 1.0 05/01/1511:03 EPA 6020A Boron 41.0 ug/L 25.0 05/01/1511:03 EPA 6020A Calcium 7040 ug/L 40.0 04/30/15 12:36 EPA 6020A Chromium 12.9 ug/L 0.50 04/30/15 12:36 EPA 6020A Cobalt 11.7 ug/L 0.50 04/30/15 12:36 EPA 6020A Copper 39.2 ug/L 1.0 04/30/15 12:36 EPA 6020A Iron 8550 ug/L 50.0 04/30/15 12:36 EPA 6020A Lead 12.9 ug/L 0.10 04/30/15 12:36 EPA 6020A Magnesium 11500 ug/L 10.0 04/30/15 12:36 EPA 6020A Manganese 283 ug/L 0.50 04/30/15 12:36 EPA 6020A Nickel 11.4 ug/L 0.50 04/30/15 12:36 EPA 6020A Potassium 560 ug/L 50.0 04/30/15 12:36 EPA 6020A Selenium 0.86 ug/L 0.50 04/30/15 12:36 EPA 6020A Sodium 2100 ug/L 50.0 04/30/15 12:36 EPA 6020A Strontium 156 ug/L 0.50 04/30/15 12:36 EPA 6020A Thallium 0.11 ug/L 0.10 04/30/15 12:36 EPA 6020A Vanadium 26.5 ug/L 1.0 04/30/15 12:36 EPA 6020A Zinc 128 ug/L 5.0 04/30/15 12:36 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980aq8r6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23533 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243914005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1180942) • Aluminum • Barium • Beryllium • Calcium • Copper • Iron • Magnesium • Manganese • Nickel • Strontium • Zinc • MSD (Lab ID: 1180943) • Aluminum • Barium • Beryllium • Calcium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980mirpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 13, 2015 QC Batch: MPRP/23533 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243914005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Copper • Iron • Magnesium • Manganese • Nickel • Strontium R1: RPD value was outside control limits. • MSD (Lab ID: 1180943) • Barium • Manganese • Strontium Additional Comments: Analyte Comments: QC Batch: MPRP/23533 D3: D3 •2015009365 (Lab ID:92243920005) • Aluminum D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009361 (Lab ID:92243920001) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015009362 (Lab ID:92243920002) • Aluminum • Boron • Barium • Beryllium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980agir6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 13, 2015 Analyte Comments: QC Batch: MPRP/23533 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009362 (Lab ID:92243920002) • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015009363 (Lab ID:92243920003) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015009364 (Lab ID:92243920004) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980agir6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 13, 2015 Analyte Comments: QC Batch: MPRP/23533 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009364 (Lab ID:92243920004) • Sodium • Nickel • Strontium • Zinc •2015009365 (Lab ID:92243920005) • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015009366 (Lab ID:92243920006) • Aluminum • Boron • Barium • Calcium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800Airpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23534 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243914006 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1180946) • Antimony • Arsenic • Cadmium • Cobalt • Vanadium • MSD (Lab ID: 1180947) • Antimony • Arsenic • Cobalt • Vanadium R1: RPD value was outside control limits. • MSD (Lab ID: 1180947) • Arsenic REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980agir6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 13, 2015 Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9581 Analyte Comments: QC Batch: MPRP/23534 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009361 (Lab ID:92243920001) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015009362 (Lab ID:92243920002) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Vanadium •2015009363 (Lab ID:92243920003) • Arsenic • Cadmium • Cobalt • Antimony • Selenium • Vanadium •2015009364 (Lab ID:92243920004) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015009365 (Lab ID:92243920005) • Arsenic • Cadmium • Cobalt REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980aq8r6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 13, 2015 Analyte Comments: QC Batch: MPRP/23534 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009365 (Lab ID:92243920005) • Lead • Antimony • Selenium • Thallium • Vanadium •2015009366 (Lab ID:92243920006) • Cadmium • Lead • Antimony • Thallium •2015009367 (Lab ID:92243920007) • Cadmium • Lead • Antimony • Thallium •2015009368 (Lab ID:92243920008) • Cadmium • Lead • Antimony • Thallium • MS (Lab ID: 1180946) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MSD (Lab ID: 1180947) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015009361 (Lab ID:92243920001) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800*rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 13, 2015 Analyte Comments: QC Batch: MPRP/23534 N2: The lab does not hold TNI accreditation for this parameter. •2015009362 (Lab ID:92243920002) • Antimony •2015009363 (Lab ID:92243920003) • Antimony •2015009364 (Lab ID:92243920004) • Antimony •2015009365 (Lab ID:92243920005) • Antimony •2015009366 (Lab ID:92243920006) • Antimony •2015009367 (Lab ID:92243920007) • Antimony •2015009368 (Lab ID:92243920008) • Antimony • BLANK (Lab ID: 1180944) • Antimony • LCS (Lab ID: 1180945) • Antimony • MS (Lab ID: 1180946) • Antimony • MSD (Lab ID: 1180947) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980a�grpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 13, 2015 General Information: 10 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53458 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243916007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1934335) • Aluminum • MSD (Lab ID: 1934336) • Aluminum QC Batch: MPRP/53957 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243920011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1949391) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980agir6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004tbirWY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004irWY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5583 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243914005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1180938) • Mercury • MSD (Lab ID: 1180939) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004K WeYdle. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004WeY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22570 B: Analyte was detected in the associated method blank. • BLANK for HBN 259622 [WETA/225 (Lab ID: 1434821) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004t�ir6fY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015009361 (Lab ID:92243920001) •2015009362 (Lab ID:92243920002) •2015009363 (Lab ID:92243920003) •2015009364 (Lab ID:92243920004) •2015009365 (Lab ID:92243920005) •2015009366 (Lab ID:92243920006) •2015009367 (Lab ID:92243920007) •2015009368 (Lab ID:92243920008) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980041 WeY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004t WeY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45210 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009361 (Lab ID:92243920001) • Chloride • Sulfate •2015009362 (Lab ID:92243920002) • Chloride • Sulfate •2015009363 (Lab ID:92243920003) • Chloride • Sulfate •2015009364 (Lab ID:92243920004) • Chloride • Sulfate •2015009365 (Lab ID:92243920005) • Chloride • Sulfate •2015009366 (Lab ID:92243920006) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004t WeY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 13, 2015 Analyte Comments: QC Batch: WETA/45210 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009367 (Lab ID:92243920007) • Chloride • Sulfate •2015009368 (Lab ID:92243920008) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004t WeY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015009361 (Lab ID:92243920001) •2015009362 (Lab ID:92243920002) •2015009363 (Lab ID:92243920003) •2015009364 (Lab ID:92243920004) •2015009365 (Lab ID:92243920005) •2015009366 (Lab ID:92243920006) •2015009367 (Lab ID:92243920007) •2015009368 (Lab ID:92243920008) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004t WeY051e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040045 Pace Project No.: 92243920 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 13, 2015 General Information: 8 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/28128 1g: % RSD > 40 •2015009366 (Lab ID:92243920006) • RSD% This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98005k8r6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009361 Lab ID: 92243920001 Collected: 03/31/15 11:45 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:46 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 17400 mg/kg 50.0 25.0 5 04/12/15 15:00 04/13/15 00:56 7429-90-5 D3 806 mg/kg 5.0 2.5 5 04/12/15 15:00 04/13/15 00:56 7440-39-3 D3 6.9 mg/kg 0.50 0.25 5 04/12/15 15:00 04/13/15 00:56 7440-41-7 D3 22AJ mg/kg 25.0 12.5 5 04/12/15 15:00 04/13/15 00:56 7440-42-8 D3 5750 mg/kg 250 125 5 04/12/15 15:00 04/13/15 00:56 7440-70-2 D3 31.9 mg/kg 2.5 1.2 5 04/12/15 15:00 04/13/15 00:56 7440-47-3 D3 61.7 mg/kg 2.5 1.2 5 04/12/15 15:00 04/13/15 00:56 7440-50-8 D3 12000 mg/kg 20.0 10 5 04/12/15 15:00 04/13/15 00:56 7439-89-6 D3 1890 mg/kg 250 125 5 04/12/15 15:00 04/13/15 00:56 7439-95-4 D3 161 mg/kg 2.5 1.2 5 04/12/15 15:00 04/13/15 00:56 7439-96-5 D3 ND mg/kg 5.0 2.5 5 04/12/15 15:00 04/13/15 00:56 7439-98-7 D3 28.8 mg/kg 2.5 1.2 5 04/12/15 15:00 04/13/15 00:56 7440-02-0 D3 2250 mg/kg 500 250 5 04/12/15 15:00 04/13/15 00:56 7440-09-7 D3 429J mg/kg 500 250 5 04/12/15 15:00 04/13/15 00:56 7440-23-5 D3 479 mg/kg 5.0 2.5 5 04/12/15 15:00 04/13/15 00:56 7440-24-6 D3 25.2 mg/kg 10 5.0 5 04/12/15 15:00 04/13/15 00:56 7440-66-6 D3 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.0 2.5 50 04/12/15 15:00 04/16/15 20:36 7440-36-0 D3,N2 105 mg/kg 5.0 2.5 50 04/12/15 15:00 04/16/15 20:36 7440-38-2 D3 ND mg/kg 0.60 0.30 50 04/12/15 15:00 04/16/15 20:36 7440-43-9 D3 15.4 mg/kg 5.0 2.5 50 04/12/15 15:00 04/16/15 20:36 7440-48-4 D3 18.7 mg/kg 5.0 2.5 50 04/12/15 15:00 04/16/15 20:36 7439-92-1 D3 8.4 mg/kg 5.0 2.5 50 04/12/15 15:00 04/16/15 20:36 7782-49-2 D3 ND mg/kg 5.0 2.5 50 04/12/15 15:00 04/16/15 20:36 7440-28-0 D3 63.6 mg/kg 5.0 2.5 50 04/12/15 15:00 04/16/15 20:36 7440-62-2 D3 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.081 mg/kg 0.016 0.0078 1 04/13/1510:27 04/13/1518:15 7439-97-6 Analytical Method: ASTM D2974-87 47.6 % 0.10 0.10 1 04/10/1514:16 Analytical Method: EPA 9045 6.8 Std. Units 0.10 0.10 1 04/10/15 12:45 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20 8.8 mg/L 3.8 1.9 1 04/15/1517:10 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 0.38 0.38 1 04/15/1517:22 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 9.5 4.8 1 04/15/15 04:20 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800q�irpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009361 Lab ID: 92243920001 Collected: 03/31/15 11:45 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 475 238 5 04/08/15 20:34 16887-00-6 D3 Sulfate ND mg/kg 475 238 5 04/08/15 20:34 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 47.5 23.8 5 04/08/15 20:34 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 66400 mg/kg 5610 2800 1 04/22/15 10:18 7440-44-0 Total Organic Carbon 84900 mg/kg 5690 2850 1 04/22/15 10:25 7440-44-0 Total Organic Carbon 117000 mg/kg 5610 2800 1 04/22/15 10:30 7440-44-0 Total Organic Carbon 75900 mg/kg 5540 2770 1 04/22/15 10:36 7440-44-0 Mean Total Organic Carbon 86000 mg/kg 5610 2810 1 04/22/15 10:18 7440-44-0 Surrogates RSD% 25.5 % 1 04/22/15 10:18 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98005kf pyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009362 Lab ID: 92243920002 Collected: 03/31/15 13:05 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:46 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6330 mg/kg 48.8 24.4 5 04/12/15 15:00 04/13/15 01:00 7429-90-5 D3 1140 mg/kg 4.9 2.4 5 04/12/15 15:00 04/13/15 01:00 7440-39-3 D3 1.9 mg/kg 0.49 0.24 5 04/12/15 15:00 04/13/15 01:00 7440-41-7 D3 17.5J mg/kg 24.4 12.2 5 04/12/15 15:00 04/13/15 01:00 7440-42-8 D3 2940 mg/kg 244 122 5 04/12/15 15:00 04/13/15 01:00 7440-70-2 D3 13.6 mg/kg 2.4 1.2 5 04/12/15 15:00 04/13/15 01:00 7440-47-3 D3 32.2 mg/kg 2.4 1.2 5 04/12/15 15:00 04/13/15 01:00 7440-50-8 D3 12600 mg/kg 19.5 9.8 5 04/12/15 15:00 04/13/15 01:00 7439-89-6 D3 595 mg/kg 244 122 5 04/12/15 15:00 04/13/15 01:00 7439-95-4 D3 77.4 mg/kg 2.4 1.2 5 04/12/15 15:00 04/13/15 01:00 7439-96-5 D3 ND mg/kg 4.9 2.4 5 04/12/15 15:00 04/13/15 01:00 7439-98-7 D3 13.1 mg/kg 2.4 1.2 5 04/12/15 15:00 04/13/15 01:00 7440-02-0 D3 786 mg/kg 488 244 5 04/12/15 15:00 04/13/15 01:00 7440-09-7 D3 ND mg/kg 488 244 5 04/12/15 15:00 04/13/15 01:00 7440-23-5 D3 189 mg/kg 4.9 2.4 5 04/12/15 15:00 04/13/15 01:00 7440-24-6 D3 7.8J mg/kg 9.8 4.9 5 04/12/15 15:00 04/13/15 01:00 7440-66-6 D3 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 4.9 2.4 50 04/12/15 15:00 04/16/15 20:38 7440-36-0 D3,N2 45.4 mg/kg 4.9 2.4 50 04/12/15 15:00 04/16/15 20:38 7440-38-2 D3 ND mg/kg 0.58 0.29 50 04/12/15 15:00 04/16/15 20:38 7440-43-9 D3 5.0 mg/kg 4.9 2.4 50 04/12/15 15:00 04/16/15 20:38 7440-48-4 D3 5.1 mg/kg 4.9 2.4 50 04/12/15 15:00 04/16/15 20:38 7439-92-1 D3 2.5.11 mg/kg 4.9 2.4 50 04/12/15 15:00 04/16/15 20:38 7782-49-2 D3 ND mg/kg 9.7 4.9 100 04/12/15 15:00 04/20/15 09:53 7440-28-0 34.2 mg/kg 4.9 2.4 50 04/12/15 15:00 04/16/15 20:38 7440-62-2 D3 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.072 mg/kg 0.015 0.0074 1 04/13/1510:27 04/13/1518:17 7439-97-6 Analytical Method: ASTM D2974-87 46.8 % 0.10 0.10 1 04/10/1514:17 Analytical Method: EPA 9045 6.7 Std. Units 0.10 0.10 1 04/10/15 12:45 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20 8.4 mg/L 3.8 1.9 1 04/15/1517:24 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 0.38 0.38 1 04/15/1517:23 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 9.4 4.7 1 04/15/15 04:21 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98005kf pyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009362 Lab ID: 92243920002 Collected: 03/31/15 13:05 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 472 236 5 04/08/15 20:55 16887-00-6 D3 Sulfate ND mg/kg 472 236 5 04/08/15 20:55 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 47.2 23.6 5 04/08/15 20:55 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 62400 mg/kg 5410 2700 1 04/22/15 12:28 7440-44-0 Total Organic Carbon 88100 mg/kg 5430 2720 1 04/22/15 12:34 7440-44-0 Total Organic Carbon 99300 mg/kg 5480 2740 1 04/22/15 12:40 7440-44-0 Total Organic Carbon 79200 mg/kg 5470 2740 1 04/22/15 12:47 7440-44-0 Mean Total Organic Carbon 82300 mg/kg 5450 2720 1 04/22/15 12:28 7440-44-0 Surrogates RSD% 18.9 % 1 04/22/15 12:28 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800�ir6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009363 Lab ID: 92243920003 Collected: 03/30/15 13:27 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:46 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 12700 mg/kg 53.4 26.7 5 04/12/15 15:00 04/13/15 01:05 7429-90-5 D3 900 mg/kg 5.3 2.7 5 04/12/15 15:00 04/13/15 01:05 7440-39-3 D3 4.3 mg/kg 0.53 0.27 5 04/12/15 15:00 04/13/15 01:05 7440-41-7 D3 35.2 mg/kg 26.7 13.3 5 04/12/15 15:00 04/13/15 01:05 7440-42-8 D3 5200 mg/kg 267 133 5 04/12/15 15:00 04/13/15 01:05 7440-70-2 D3 28.2 mg/kg 2.7 1.3 5 04/12/15 15:00 04/13/15 01:05 7440-47-3 D3 44.8 mg/kg 2.7 1.3 5 04/12/15 15:00 04/13/15 01:05 7440-50-8 D3 20900 mg/kg 21.3 10.7 5 04/12/15 15:00 04/13/15 01:05 7439-89-6 D3 1100 mg/kg 267 133 5 04/12/15 15:00 04/13/15 01:05 7439-95-4 D3 126 mg/kg 2.7 1.3 5 04/12/15 15:00 04/13/15 01:05 7439-96-5 D3 ND mg/kg 5.3 2.7 5 04/12/15 15:00 04/13/15 01:05 7439-98-7 D3 25.2 mg/kg 2.7 1.3 5 04/12/15 15:00 04/13/15 01:05 7440-02-0 D3 1250 mg/kg 534 267 5 04/12/15 15:00 04/13/15 01:05 7440-09-7 D3 ND mg/kg 534 267 5 04/12/15 15:00 04/13/15 01:05 7440-23-5 D3 357 mg/kg 5.3 2.7 5 04/12/15 15:00 04/13/15 01:05 7440-24-6 D3 18.0 mg/kg 10.7 5.3 5 04/12/15 15:00 04/13/15 01:05 7440-66-6 D3 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.3 2.7 50 04/12/15 15:00 04/16/15 20:40 7440-36-0 D3,N2 53.5 mg/kg 5.3 2.7 50 04/12/15 15:00 04/16/15 20:40 7440-38-2 D3 ND mg/kg 0.64 0.32 50 04/12/15 15:00 04/16/15 20:40 7440-43-9 D3 10.3 mg/kg 5.3 2.7 50 04/12/15 15:00 04/16/15 20:40 7440-48-4 D3 12.4 mg/kg 10.7 5.3 100 04/12/15 15:00 04/20/15 09:55 7439-92-1 4.3J mg/kg 5.3 2.7 50 04/12/15 15:00 04/16/15 20:40 7782-49-2 D3 ND mg/kg 10.7 5.3 100 04/12/15 15:00 04/20/15 09:55 7440-28-0 56.5 mg/kg 5.3 2.7 50 04/12/15 15:00 04/16/15 20:40 7440-62-2 D3 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.086 mg/kg 0.017 0.0087 1 04/13/1510:27 04/13/1518:19 7439-97-6 Analytical Method: ASTM D2974-87 53.6 % 0.10 0.10 1 04/10/1514:18 Analytical Method: EPA 9045 6.6 Std. Units 0.10 0.10 1 04/10/15 12:45 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20 12.7 mg/L 4.3 2.2 1 04/15/1517:37 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 0.43 0.43 1 04/15/1517:24 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 10.8 5.4 1 04/15/15 04:22 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%ppyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009363 Lab ID: 92243920003 Collected: 03/30/15 13:27 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 546 273 5 04/08/15 21:17 16887-00-6 D3 Sulfate ND mg/kg 546 273 5 04/08/15 21:17 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 54.6 27.3 5 04/08/15 21:17 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 95300 mg/kg 5510 2760 1 04/22/15 12:53 7440-44-0 Total Organic Carbon 128000 mg/kg 5480 2740 1 04/22/15 13:00 7440-44-0 Total Organic Carbon 129000 mg/kg 5460 2730 1 04/22/15 13:06 7440-44-0 Total Organic Carbon 135000 mg/kg 5520 2760 1 04/22/15 13:12 7440-44-0 Mean Total Organic Carbon 122000 mg/kg 5490 2750 1 04/22/15 12:53 7440-44-0 Surrogates RSD% 14.8 % 1 04/22/15 12:53 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%ppyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009364 Lab ID: 92243920004 Collected: 03/30/15 14:09 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:46 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 12100 mg/kg 44.7 22.4 5 04/12/15 15:00 04/13/15 01:09 7429-90-5 D3 502 mg/kg 4.5 2.2 5 04/12/15 15:00 04/13/15 01:09 7440-39-3 D3 4.7 mg/kg 0.45 0.22 5 04/12/15 15:00 04/13/15 01:09 7440-41-7 D3 20.OJ mg/kg 22.4 11.2 5 04/12/15 15:00 04/13/15 01:09 7440-42-8 D3 8760 mg/kg 224 112 5 04/12/15 15:00 04/13/15 01:09 7440-70-2 D3 27.6 mg/kg 2.2 1.1 5 04/12/15 15:00 04/13/15 01:09 7440-47-3 D3 40.6 mg/kg 2.2 1.1 5 04/12/15 15:00 04/13/15 01:09 7440-50-8 D3 7130 mg/kg 17.9 8.9 5 04/12/15 15:00 04/13/15 01:09 7439-89-6 D3 1240 mg/kg 224 112 5 04/12/15 15:00 04/13/15 01:09 7439-95-4 D3 86.4 mg/kg 2.2 1.1 5 04/12/15 15:00 04/13/15 01:09 7439-96-5 D3 ND mg/kg 4.5 2.2 5 04/12/15 15:00 04/13/15 01:09 7439-98-7 D3 21.9 mg/kg 2.2 1.1 5 04/12/15 15:00 04/13/15 01:09 7440-02-0 D3 962 mg/kg 447 224 5 04/12/15 15:00 04/13/15 01:09 7440-09-7 D3 299J mg/kg 447 224 5 04/12/15 15:00 04/13/15 01:09 7440-23-5 D3 448 mg/kg 4.5 2.2 5 04/12/15 15:00 04/13/15 01:09 7440-24-6 D3 16.5 mg/kg 8.9 4.5 5 04/12/15 15:00 04/13/15 01:09 7440-66-6 D3 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 4.5 2.2 50 04/12/15 15:00 04/16/15 20:43 7440-36-0 D3,N2 22.7 mg/kg 4.5 2.2 50 04/12/15 15:00 04/16/15 20:43 7440-38-2 D3 ND mg/kg 0.54 0.27 50 04/12/15 15:00 04/16/15 20:43 7440-43-9 D3 10.1 mg/kg 4.5 2.2 50 04/12/15 15:00 04/16/15 20:43 7440-48-4 D3 12.9 mg/kg 8.9 4.5 100 04/12/15 15:00 04/21/1511:09 7439-92-1 D3 5.6 mg/kg 4.5 2.2 50 04/12/15 15:00 04/16/15 20:43 7782-49-2 D3 ND mg/kg 8.9 4.5 100 04/12/15 15:00 04/21/1511:09 7440-28-0 D3 61.0 mg/kg 4.5 2.2 50 04/12/15 15:00 04/16/15 20:43 7440-62-2 D3 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.090 mg/kg 0.013 0.0067 1 04/13/1510:27 04/13/1518:22 7439-97-6 Analytical Method: ASTM D2974-87 41.7 % 0.10 0.10 1 04/10/1514:18 Analytical Method: EPA 9045 7.0 Std. Units 0.10 0.10 1 04/10/15 12:45 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20 9.7 mg/L 3.4 1.7 1 04/15/1517:51 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 0.34 0.34 1 04/15/1517:28 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 8.6 4.3 1 04/15/15 04:22 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 43 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980vrpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009364 Lab ID: 92243920004 Collected: 03/30/15 14:09 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 427 214 5 04/08/15 21:38 16887-00-6 D3 Sulfate ND mg/kg 427 214 5 04/08/15 21:38 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 42.7 21.4 5 04/08/15 21:38 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 164000 mg/kg 7680 3840 1 04/22/15 13:31 7440-44-0 Total Organic Carbon 134000 mg/kg 7500 3750 1 04/22/15 13:38 7440-44-0 Total Organic Carbon 133000 mg/kg 7800 3900 1 04/22/15 13:44 7440-44-0 Total Organic Carbon 147000 mg/kg 7390 3700 1 04/22/15 13:52 7440-44-0 Mean Total Organic Carbon 144000 mg/kg 7590 3800 1 04/22/15 13:31 7440-44-0 Surrogates RSD% 10.2 % 1 04/22/15 13:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%5 rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009365 Lab ID: 92243920005 Collected: 03/30/15 15:18 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:46 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 10800 mg/kg 33.0 16.5 5 04/12/15 15:00 04/13/15 01:13 7429-90-5 D3 101 mg/kg 3.3 1.7 5 04/12/15 15:00 04/13/15 01:13 7440-39-3 D3 0.79 mg/kg 0.33 0.17 5 04/12/15 15:00 04/13/15 01:13 7440-41-7 D3 24.3 mg/kg 16.5 8.3 5 04/12/15 15:00 04/13/15 01:13 7440-42-8 D3 725 mg/kg 165 82.5 5 04/12/15 15:00 04/13/15 01:13 7440-70-2 D3 14.9 mg/kg 1.7 0.83 5 04/12/15 15:00 04/13/15 01:13 7440-47-3 D3 16.0 mg/kg 1.7 0.83 5 04/12/15 15:00 04/13/15 01:13 7440-50-8 D3 25100 mg/kg 13.2 6.6 5 04/12/15 15:00 04/13/15 01:13 7439-89-6 D3 1270 mg/kg 165 82.5 5 04/12/15 15:00 04/13/15 01:13 7439-95-4 D3 68.4 mg/kg 1.7 0.83 5 04/12/15 15:00 04/13/15 01:13 7439-96-5 D3 ND mg/kg 3.3 1.7 5 04/12/15 15:00 04/13/15 01:13 7439-98-7 D3 9.1 mg/kg 1.7 0.83 5 04/12/15 15:00 04/13/15 01:13 7440-02-0 D3 ND mg/kg 330 165 5 04/12/15 15:00 04/13/15 01:13 7440-09-7 D3 ND mg/kg 330 165 5 04/12/15 15:00 04/13/15 01:13 7440-23-5 D3 13.6 mg/kg 3.3 1.7 5 04/12/15 15:00 04/13/15 01:13 7440-24-6 D3 20.8 mg/kg 6.6 3.3 5 04/12/15 15:00 04/13/15 01:13 7440-66-6 D3 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.3 1.7 50 04/12/15 15:00 04/16/15 20:45 7440-36-0 D3,N2 ND mg/kg 3.3 1.7 50 04/12/15 15:00 04/16/15 20:45 7440-38-2 D3 ND mg/kg 0.40 0.20 50 04/12/15 15:00 04/16/15 20:45 7440-43-9 D3 11.8 mg/kg 3.3 1.7 50 04/12/15 15:00 04/16/15 20:45 7440-48-4 D3 13.2 mg/kg 3.3 1.7 50 04/12/15 15:00 04/16/15 20:45 7439-92-1 D3 ND mg/kg 3.3 1.7 50 04/12/15 15:00 04/16/15 20:45 7782-49-2 D3 ND mg/kg 3.3 1.7 50 04/12/15 15:00 04/16/15 20:45 7440-28-0 D3 48.5 mg/kg 3.3 1.7 50 04/12/15 15:00 04/16/15 20:45 7440-62-2 D3 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.012 mg/kg 0.010 0.0050 1 04/13/1510:27 04/13/1518:24 7439-97-6 Analytical Method: ASTM D2974-87 23.6 % 0.10 0.10 1 04/10/1514:19 Analytical Method: EPA 9045 5.4 Std. Units 0.10 0.10 1 04/10/15 12:45 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20 5.3 mg/L 2.6 1.3 1 04/15/1518:04 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20 0.28 mg/L 0.26 0.26 1 04/15/1517:29 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 6.5 3.3 1 04/15/15 04:23 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 45 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%�rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009365 Lab ID: 92243920005 Collected: 03/30/15 15:18 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 326 163 5 04/08/15 22:00 16887-00-6 D3 Sulfate ND mg/kg 326 163 5 04/08/15 22:00 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 32.6 16.3 5 04/08/15 22:00 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1710 mg/kg 779 390 1 04/22/15 13:58 7440-44-0 Total Organic Carbon 1780 mg/kg 785 392 1 04/22/15 14:03 7440-44-0 Total Organic Carbon 1700 mg/kg 785 392 1 04/22/15 14:09 7440-44-0 Total Organic Carbon 1590 mg/kg 786 393 1 04/22/15 14:15 7440-44-0 Mean Total Organic Carbon 1700 mg/kg 784 392 1 04/22/15 13:58 7440-44-0 Surrogates RSD% 4.5 % 1 04/22/15 13:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%48r6fYo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009366 Lab ID: 92243920006 Collected: 03/30/15 15:30 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:46 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 430 mg/kg 31.2 15.6 5 04/12/15 15:00 04/13/15 01:17 7429-90-5 D3 7.7 mg/kg 3.1 1.6 5 04/12/15 15:00 04/13/15 01:17 7440-39-3 D3 0.42 mg/kg 0.31 0.16 5 04/12/15 15:00 04/13/15 01:17 7440-41-7 28.4 mg/kg 15.6 7.8 5 04/12/15 15:00 04/13/15 01:17 7440-42-8 D3 253 mg/kg 156 78.0 5 04/12/15 15:00 04/13/15 01:17 7440-70-2 D3 8.0 mg/kg 1.6 0.78 5 04/12/15 15:00 04/13/15 01:17 7440-47-3 196 mg/kg 1.6 0.78 5 04/12/15 15:00 04/13/15 01:17 7440-50-8 D3 25400 mg/kg 12.5 6.2 5 04/12/15 15:00 04/13/15 01:17 7439-89-6 D3 ND mg/kg 156 78.0 5 04/12/15 15:00 04/13/15 01:17 7439-95-4 D3 199 mg/kg 1.6 0.78 5 04/12/15 15:00 04/13/15 01:17 7439-96-5 D3 ND mg/kg 3.1 1.6 5 04/12/15 15:00 04/13/15 01:17 7439-98-7 D3 17.3 mg/kg 1.6 0.78 5 04/12/15 15:00 04/13/15 01:17 7440-02-0 D3 ND mg/kg 312 156 5 04/12/15 15:00 04/13/15 01:17 7440-09-7 D3 ND mg/kg 312 156 5 04/12/15 15:00 04/13/15 01:17 7440-23-5 D3 2.9J mg/kg 3.1 1.6 5 04/12/15 15:00 04/13/15 01:17 7440-24-6 D3 17.9 mg/kg 6.2 3.1 5 04/12/15 15:00 04/13/15 01:17 7440-66-6 D3 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.1 1.6 50 04/12/15 15:00 04/16/15 20:47 7440-36-0 D3,N2 ND mg/kg 6.2 3.1 100 04/12/15 15:00 04/20/15 09:57 7440-38-2 ND mg/kg 0.37 0.19 50 04/12/15 15:00 04/16/15 20:47 7440-43-9 D3 14.5 mg/kg 6.2 3.1 100 04/12/15 15:00 04/20/15 09:57 7440-48-4 ND mg/kg 3.1 1.6 50 04/12/15 15:00 04/16/15 20:47 7439-92-1 D3 ND mg/kg 6.2 3.1 100 04/12/15 15:00 04/20/15 09:57 7782-49-2 ND mg/kg 3.1 1.6 50 04/12/15 15:00 04/16/15 20:47 7440-28-0 D3 17.7 mg/kg 6.2 3.1 100 04/12/15 15:00 04/20/15 09:57 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.017 mg/kg 0.010 0.0052 1 04/13/1510:27 04/13/1518:26 7439-97-6 Analytical Method: ASTM D2974-87 20.1 % 0.10 0.10 1 04/10/1514:21 Analytical Method: EPA 9045 5.0 Std. Units 0.10 0.10 1 04/10/15 12:45 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20 6.2 mg/L 2.5 1.3 1 04/15/1518:45 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 0.25 0.25 1 04/15/1517:30 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 6.3 3.1 1 04/15/15 04:27 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 47 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%-)ir6fYo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009366 Lab ID: 92243920006 Collected: 03/30/15 15:30 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 315 157 5 04/08/15 22:21 16887-00-6 D3 Sulfate ND mg/kg 315 157 5 04/08/15 22:21 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.5 15.7 5 04/08/15 22:21 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1440 mg/kg 754 377 1 04/22/15 14:21 7440-44-0 Total Organic Carbon 789 mg/kg 758 379 1 04/22/15 14:28 7440-44-0 Total Organic Carbon 5001 mg/kg 751 375 1 04/22/15 14:33 7440-44-0 Total Organic Carbon 1430 mg/kg 749 375 1 04/22/15 14:39 7440-44-0 Mean Total Organic Carbon 1040 mg/kg 753 377 1 04/22/15 14:21 7440-44-0 Surrogates RSD% 45.4 % 1 04/22/15 14:21 1g REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98006Jf pyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009367 Lab ID: 92243920007 Collected: 04/01/15 10:05 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:46 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 12400 mg/kg 30.2 15.1 5 04/12/15 15:00 04/14/1510:07 7429-90-5 230 mg/kg 3.0 1.5 5 04/12/15 15:00 04/14/1510:07 7440-39-3 1.3 mg/kg 0.30 0.15 5 04/12/15 15:00 04/14/1510:07 7440-41-7 ND mg/kg 15.1 7.5 5 04/12/15 15:00 04/14/1510:07 7440-42-8 888 mg/kg 151 75.4 5 04/12/15 15:00 04/14/1510:07 7440-70-2 20.5 mg/kg 1.5 0.75 5 04/12/15 15:00 04/14/1510:07 7440-47-3 14.3 mg/kg 1.5 0.75 5 04/12/15 15:00 04/14/1510:07 7440-50-8 29200 mg/kg 12.1 6.0 5 04/12/15 15:00 04/14/1510:07 7439-89-6 2130 mg/kg 151 75.4 5 04/12/15 15:00 04/14/1510:07 7439-95-4 898 mg/kg 1.5 0.75 5 04/12/15 15:00 04/14/1510:07 7439-96-5 ND mg/kg 3.0 1.5 5 04/12/15 15:00 04/14/1510:07 7439-98-7 7.3 mg/kg 1.5 0.75 5 04/12/15 15:00 04/14/1510:07 7440-02-0 584 mg/kg 302 151 5 04/12/15 15:00 04/14/1510:07 7440-09-7 ND mg/kg 302 151 5 04/12/15 15:00 04/14/1510:07 7440-23-5 32.0 mg/kg 3.0 1.5 5 04/12/15 15:00 04/14/1510:07 7440-24-6 27.4 mg/kg 6.0 3.0 5 04/12/15 15:00 04/14/1510:07 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.0 1.5 50 04/12/15 15:00 04/16/15 20:49 7440-36-0 4.3J mg/kg 6.0 3.0 100 04/12/15 15:00 04/20/15 09:59 7440-38-2 ND mg/kg 0.36 0.18 50 04/12/15 15:00 04/16/15 20:49 7440-43-9 13.8 mg/kg 6.0 3.0 100 04/12/15 15:00 04/20/15 09:59 7440-48-4 12.3 mg/kg 3.0 1.5 50 04/12/15 15:00 04/16/15 20:49 7439-92-1 ND mg/kg 6.0 3.0 100 04/12/15 15:00 04/20/15 09:59 7782-49-2 ND mg/kg 3.0 1.5 50 04/12/15 15:00 04/16/15 20:49 7440-28-0 55.3 mg/kg 6.0 3.0 100 04/12/15 15:00 04/20/15 09:59 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.048 mg/kg 0.0096 0.0048 1 04/13/1510:27 04/13/1518:28 7439-97-6 Analytical Method: ASTM D2974-87 20.3 % 0.10 0.10 1 04/10/1514:22 Analytical Method: EPA 9045 6.8 Std. Units 0.10 0.10 1 04/10/15 12:45 D3,N2 D3 D3 D3 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20 3.5 mg/L 2.5 1.3 1 04/15/1518:59 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20 0.26 mg/L 0.25 0.25 1 04/15/1517:31 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 6.3 3.1 1 04/15/15 04:27 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 49 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%4sr6fYo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009367 Lab ID: 92243920007 Collected: 04/01/15 10:05 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 308 154 5 04/08/15 22:42 16887-00-6 D3 Sulfate ND mg/kg 308 154 5 04/08/15 22:42 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.8 15.4 5 04/08/15 22:42 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1940 mg/kg 750 375 1 04/22/15 14:45 7440-44-0 Total Organic Carbon 2270 mg/kg 758 379 1 04/22/15 14:52 7440-44-0 Total Organic Carbon 1900 mg/kg 758 379 1 04/22/15 14:57 7440-44-0 Total Organic Carbon 1700 mg/kg 756 378 1 04/22/15 15:04 7440-44-0 Mean Total Organic Carbon 1950 mg/kg 755 378 1 04/22/15 14:45 7440-44-0 Surrogates RSD% 12.1 % 1 04/22/15 14:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98006}�irpYo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009368 Lab ID: 92243920008 Collected: 04/01/15 10:27 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:46 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 11800 mg/kg 32.1 16.1 5 04/12/15 15:00 04/14/1510:11 7429-90-5 164 mg/kg 3.2 1.6 5 04/12/15 15:00 04/14/1510:11 7440-39-3 0.93 mg/kg 0.32 0.16 5 04/12/15 15:00 04/14/1510:11 7440-41-7 ND mg/kg 16.1 8.0 5 04/12/15 15:00 04/14/1510:11 7440-42-8 906 mg/kg 161 80.3 5 04/12/15 15:00 04/14/1510:11 7440-70-2 24.1 mg/kg 1.6 0.80 5 04/12/15 15:00 04/14/1510:11 7440-47-3 14.1 mg/kg 1.6 0.80 5 04/12/15 15:00 04/14/1510:11 7440-50-8 20100 mg/kg 12.9 6.4 5 04/12/15 15:00 04/14/1510:11 7439-89-6 2440 mg/kg 161 80.3 5 04/12/15 15:00 04/14/1510:11 7439-95-4 199 mg/kg 1.6 0.80 5 04/12/15 15:00 04/14/1510:11 7439-96-5 ND mg/kg 3.2 1.6 5 04/12/15 15:00 04/14/1510:11 7439-98-7 7.3 mg/kg 1.6 0.80 5 04/12/15 15:00 04/14/1510:11 7440-02-0 619 mg/kg 321 161 5 04/12/15 15:00 04/14/1510:11 7440-09-7 ND mg/kg 321 161 5 04/12/15 15:00 04/14/1510:11 7440-23-5 18.9 mg/kg 3.2 1.6 5 04/12/15 15:00 04/14/1510:11 7440-24-6 30.9 mg/kg 6.4 3.2 5 04/12/15 15:00 04/14/1510:11 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.2 1.6 50 04/12/15 15:00 04/16/15 20:52 7440-36-0 ND mg/kg 6.4 3.2 100 04/12/15 15:00 04/20/1510:01 7440-38-2 ND mg/kg 0.39 0.19 50 04/12/15 15:00 04/16/15 20:52 7440-43-9 3.9J mg/kg 6.4 3.2 100 04/12/15 15:00 04/20/1510:01 7440-48-4 9.0 mg/kg 3.2 1.6 50 04/12/15 15:00 04/16/15 20:52 7439-92-1 ND mg/kg 6.4 3.2 100 04/12/15 15:00 04/20/1510:01 7782-49-2 ND mg/kg 3.2 1.6 50 04/12/15 15:00 04/16/15 20:52 7440-28-0 55.7 mg/kg 6.4 3.2 100 04/12/15 15:00 04/20/1510:01 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.031 mg/kg 0.010 0.0051 1 04/13/1510:27 04/13/1518:46 7439-97-6 Analytical Method: ASTM D2974-87 20.1 % 0.10 0.10 1 04/10/1514:23 Analytical Method: EPA 9045 6.8 Std. Units 0.10 0.10 1 04/10/15 12:45 D3,N2 D3 D3 D3 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20 4.8 mg/L 2.5 1.3 1 04/15/1519:12 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20 0.32 mg/L 0.25 0.25 1 04/15/1517:32 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/10/15 17:20 ND mg/L 6.3 3.1 1 04/15/15 04:28 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 51 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%48r6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009368 Lab ID: 92243920008 Collected: 04/01/15 10:27 Received: 04/02/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 311 156 5 04/08/15 23:04 16887-00-6 D3 Sulfate ND mg/kg 311 156 5 04/08/15 23:04 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.1 15.6 5 04/08/15 23:04 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1710 mg/kg 753 376 1 04/22/15 15:10 7440-44-0 Total Organic Carbon 1620 mg/kg 755 378 1 04/22/15 15:15 7440-44-0 Total Organic Carbon 1860 mg/kg 751 376 1 04/22/15 15:21 7440-44-0 Total Organic Carbon 1660 mg/kg 747 374 1 04/22/15 15:27 7440-44-0 Mean Total Organic Carbon 1710 mg/kg 752 376 1 04/22/15 15:10 7440-44-0 Surrogates RSD% 6.2 % 1 04/22/15 15:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%48r6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009369 Lab ID: 92243920009 Collected: 04/01/15 07:20 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\ri,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 ND ug/L 10.0 3.0 1 04/09/15 08:55 04/13/15 12:11 7429-90-5 ND ug/L 0.50 0.15 1 04/09/15 08:55 04/13/15 12:11 7440-36-0 ND ug/L 0.50 0.11 1 04/09/15 08:55 04/13/15 12:11 7440-38-2 ND ug/L 0.30 0.081 1 04/09/15 08:55 04/13/15 12:11 7440-39-3 ND ug/L 0.20 0.067 1 04/09/15 08:55 04/13/15 12:11 7440-41-7 ND ug/L 5.0 1.1 1 04/09/15 08:55 04/13/15 12:11 7440-42-8 ND ug/L 0.080 0.024 1 04/09/15 08:55 04/13/15 12:11 7440-43-9 ND ug/L 40.0 16.0 1 04/09/15 08:55 04/13/15 12:11 7440-70-2 23.6 ug/L 0.50 0.17 1 04/09/15 08:55 04/13/15 12:11 7440-47-3 0.58 ug/L 0.50 0.13 1 04/09/15 08:55 04/13/15 12:11 7440-48-4 ND ug/L 1.0 0.21 1 04/09/15 08:55 04/13/15 12:11 7440-50-8 154 ug/L 50.0 13.7 1 04/09/15 08:55 04/13/15 12:11 7439-89-6 ND ug/L 0.10 0.046 1 04/09/15 08:55 04/13/15 12:11 7439-92-1 ND ug/L 10.0 3.2 1 04/09/15 08:55 04/13/15 12:11 7439-95-4 2.4 ug/L 0.50 0.24 1 04/09/15 08:55 04/13/15 12:11 7439-96-5 ND ug/L 0.50 0.094 1 04/09/15 08:55 04/13/15 12:11 7439-98-7 16.9 ug/L 0.50 0.16 1 04/09/15 08:55 04/13/15 12:11 7440-02-0 ND ug/L 50.0 11.7 1 04/09/15 08:55 04/13/15 12:11 7440-09-7 ND ug/L 0.50 0.20 1 04/09/15 08:55 04/13/15 12:11 7782-49-2 ND ug/L 50.0 16.3 1 04/09/15 08:55 04/13/15 12:11 7440-23-5 ND ug/L 0.50 0.13 1 04/09/15 08:55 04/13/15 12:11 7440-24-6 ND ug/L 0.10 0.015 1 04/09/15 08:55 04/13/15 12:11 7440-28-0 ND ug/L 1.0 0.28 1 04/09/15 08:55 04/13/15 12:11 7440-62-2 ND ug/L 5.0 2.4 1 04/09/15 08:55 04/13/15 12:11 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/12/1519:00 04/13/1511:40 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 53 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%4?r6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009370 Lab ID: 92243920010 Collected: 03/31/15 10:12 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\ri,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 ND ug/L 10.0 3.0 1 04/09/15 08:55 04/13/15 12:16 7429-90-5 ND ug/L 0.50 0.15 1 04/09/15 08:55 04/13/15 12:16 7440-36-0 ND ug/L 0.50 0.11 1 04/09/15 08:55 04/13/15 12:16 7440-38-2 1.0 ug/L 0.30 0.081 1 04/09/15 08:55 04/13/15 12:16 7440-39-3 ND ug/L 0.20 0.067 1 04/09/15 08:55 04/13/15 12:16 7440-41-7 ND ug/L 5.0 1.1 1 04/09/15 08:55 04/13/15 12:16 7440-42-8 ND ug/L 0.080 0.024 1 04/09/15 08:55 04/13/15 12:16 7440-43-9 ND ug/L 40.0 16.0 1 04/09/15 08:55 04/13/15 12:16 7440-70-2 ND ug/L 0.50 0.17 1 04/09/15 08:55 04/13/15 12:16 7440-47-3 ND ug/L 0.50 0.13 1 04/09/15 08:55 04/13/15 12:16 7440-48-4 ND ug/L 1.0 0.21 1 04/09/15 08:55 04/13/15 12:16 7440-50-8 ND ug/L 50.0 13.7 1 04/09/15 08:55 04/13/15 12:16 7439-89-6 ND ug/L 0.10 0.046 1 04/09/15 08:55 04/13/15 12:16 7439-92-1 11.3 ug/L 10.0 3.2 1 04/09/15 08:55 04/13/15 12:16 7439-95-4 ND ug/L 0.50 0.24 1 04/09/15 08:55 04/13/15 12:16 7439-96-5 ND ug/L 0.50 0.094 1 04/09/15 08:55 04/13/15 12:16 7439-98-7 ND ug/L 0.50 0.16 1 04/09/15 08:55 04/13/15 12:16 7440-02-0 ND ug/L 50.0 11.7 1 04/09/15 08:55 04/13/15 12:16 7440-09-7 ND ug/L 0.50 0.20 1 04/09/15 08:55 04/13/15 12:16 7782-49-2 ND ug/L 50.0 16.3 1 04/09/15 08:55 04/13/15 12:16 7440-23-5 ND ug/L 0.50 0.13 1 04/09/15 08:55 04/13/15 12:16 7440-24-6 ND ug/L 0.10 0.015 1 04/09/15 08:55 04/13/15 12:16 7440-28-0 ND ug/L 1.0 0.28 1 04/09/15 08:55 04/13/15 12:16 7440-62-2 ND ug/L 5.0 2.4 1 04/09/15 08:55 04/13/15 12:16 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/14/1510:50 04/14/1516:41 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 54 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980ygrpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009361 SPLP Lab ID: 92243920011 Collected: 03/31/15 11:45 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 640 ug/L 50.0 14.9 1 04/27/15 22:45 04/30/15 12:06 7429-90-5 0.83J ug/L 2.5 0.74 1 04/27/15 22:45 04/30/15 12:06 7440-36-0 16.5 ug/L 2.5 0.56 1 04/27/15 22:45 04/30/15 12:06 7440-38-2 277 ug/L 1.5 0.40 1 04/27/15 22:45 04/30/15 12:06 7440-39-3 ND ug/L 1.0 0.34 1 04/27/15 22:45 04/30/15 12:06 7440-41-7 90.6 ug/L 25.0 5.6 1 04/27/15 22:45 04/30/15 12:06 7440-42-8 ND ug/L 0.40 0.12 1 04/27/15 22:45 04/30/15 12:06 7440-43-9 2130 ug/L 200 80.0 1 04/27/15 22:45 04/30/15 12:06 7440-70-2 6.7 ug/L 2.5 0.84 1 04/27/15 22:45 04/30/15 12:06 7440-47-3 ND ug/L 2.5 0.63 1 04/27/15 22:45 04/30/15 12:06 7440-48-4 5.8 ug/L 5.0 1.1 1 04/27/15 22:45 04/30/15 12:06 7440-50-8 522 ug/L 250 68.5 1 04/27/15 22:45 04/30/15 12:06 7439-89-6 0.92 ug/L 0.50 0.23 1 04/27/15 22:45 04/30/15 12:06 7439-92-1 445 ug/L 50.0 15.8 1 04/27/15 22:45 04/30/15 12:06 7439-95-4 9.9 ug/L 2.5 1.2 1 04/27/15 22:45 04/30/15 12:06 7439-96-5 1.2J ug/L 2.5 0.47 1 04/27/15 22:45 04/30/15 12:06 7439-98-7 1.3J ug/L 2.5 0.81 1 04/27/15 22:45 04/30/15 12:06 7440-02-0 351 ug/L 250 58.7 1 04/27/15 22:45 04/30/15 12:06 7440-09-7 1.91 ug/L 2.5 1.0 1 04/27/15 22:45 04/30/15 12:06 7782-49-2 2040 ug/L 250 81.5 1 04/27/15 22:45 04/30/15 12:06 7440-23-5 76.7 ug/L 2.5 0.66 1 04/27/15 22:45 04/30/15 12:06 7440-24-6 ND ug/L 0.50 0.077 1 04/27/15 22:45 04/30/15 12:06 7440-28-0 17.7 ug/L 5.0 1.4 1 04/27/15 22:45 04/30/15 12:06 7440-62-2 80.0 ug/L 25.0 12.0 1 04/27/15 22:45 04/30/15 12:06 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/27/15 20:20 04/30/15 18:23 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 55 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98006rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009362 SPLP Lab ID: 92243920012 Collected: 03/31/15 13:05 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 594 ug/L 10.0 3.0 1 04/27/15 22:45 04/30/15 11:58 7429-90-5 0.84 ug/L 0.50 0.15 1 04/27/15 22:45 04/30/15 11:58 7440-36-0 28.4 ug/L 0.50 0.11 1 04/27/15 22:45 04/30/15 11:58 7440-38-2 240 ug/L 0.30 0.081 1 04/27/15 22:45 04/30/15 11:58 7440-39-3 0.16J ug/L 0.20 0.067 1 04/27/15 22:45 04/30/15 11:58 7440-41-7 35.5 ug/L 5.0 1.1 1 04/27/15 22:45 04/30/15 11:58 7440-42-8 0.053J ug/L 0.080 0.024 1 04/27/15 22:45 04/30/15 11:58 7440-43-9 2050 ug/L 40.0 16.0 1 04/27/15 22:45 04/30/15 11:58 7440-70-2 4.5 ug/L 0.50 0.17 1 04/27/15 22:45 04/30/15 11:58 7440-47-3 0.58 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 11:58 7440-48-4 3.8 ug/L 1.0 0.21 1 04/27/15 22:45 04/30/15 11:58 7440-50-8 480 ug/L 50.0 13.7 1 04/27/15 22:45 04/30/15 11:58 7439-89-6 1.2 ug/L 0.10 0.046 1 04/27/15 22:45 04/30/15 11:58 7439-92-1 524 ug/L 10.0 3.2 1 04/27/15 22:45 04/30/15 11:58 7439-95-4 27.0 ug/L 0.50 0.24 1 04/27/15 22:45 04/30/15 11:58 7439-96-5 1.3 ug/L 0.50 0.094 1 04/27/15 22:45 04/30/15 11:58 7439-98-7 1.9 ug/L 0.50 0.16 1 04/27/15 22:45 04/30/15 11:58 7440-02-0 363 ug/L 50.0 11.7 1 04/27/15 22:45 04/30/15 11:58 7440-09-7 1.1 ug/L 0.50 0.20 1 04/27/15 22:45 04/30/15 11:58 7782-49-2 1900 ug/L 50.0 16.3 1 04/27/15 22:45 04/30/15 11:58 7440-23-5 105 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 11:58 7440-24-6 0.14 ug/L 0.10 0.015 1 04/27/15 22:45 04/30/15 11:58 7440-28-0 25.3 ug/L 1.0 0.28 1 04/27/15 22:45 04/30/15 11:58 7440-62-2 33.1 ug/L 5.0 2.4 1 04/27/15 22:45 04/30/15 11:58 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/27/15 20:20 04/30/15 18:25 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 56 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98007tbirpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009363 SPLP Lab ID: 92243920013 Collected: 03/30/15 13:27 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 572 ug/L 10.0 3.0 1 04/27/15 22:45 04/30/15 12:01 7429-90-5 0.93 ug/L 0.50 0.15 1 04/27/15 22:45 04/30/15 12:01 7440-36-0 21.5 ug/L 0.50 0.11 1 04/27/15 22:45 04/30/15 12:01 7440-38-2 177 ug/L 0.30 0.081 1 04/27/15 22:45 04/30/15 12:01 7440-39-3 0.20 ug/L 0.20 0.067 1 04/27/15 22:45 04/30/15 12:01 7440-41-7 56.9 ug/L 5.0 1.1 1 04/27/15 22:45 04/30/15 12:01 7440-42-8 0.035J ug/L 0.080 0.024 1 04/27/15 22:45 04/30/15 12:01 7440-43-9 3150 ug/L 40.0 16.0 1 04/27/15 22:45 04/30/15 12:01 7440-70-2 4.0 ug/L 0.50 0.17 1 04/27/15 22:45 04/30/15 12:01 7440-47-3 0.45J ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:01 7440-48-4 3.7 ug/L 1.0 0.21 1 04/27/15 22:45 04/30/15 12:01 7440-50-8 372 ug/L 50.0 13.7 1 04/27/15 22:45 04/30/15 12:01 7439-89-6 0.84 ug/L 0.10 0.046 1 04/27/15 22:45 04/30/15 12:01 7439-92-1 560 ug/L 10.0 3.2 1 04/27/15 22:45 04/30/15 12:01 7439-95-4 5.4 ug/L 0.50 0.24 1 04/27/15 22:45 04/30/15 12:01 7439-96-5 2.3 ug/L 0.50 0.094 1 04/27/15 22:45 04/30/15 12:01 7439-98-7 1.3 ug/L 0.50 0.16 1 04/27/15 22:45 04/30/15 12:01 7440-02-0 1130 ug/L 50.0 11.7 1 04/27/15 22:45 04/30/15 12:01 7440-09-7 1.8 ug/L 0.50 0.20 1 04/27/15 22:45 04/30/15 12:01 7782-49-2 1490 ug/L 50.0 16.3 1 04/27/15 22:45 04/30/15 12:01 7440-23-5 118 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:01 7440-24-6 0.058J ug/L 0.10 0.015 1 04/27/15 22:45 04/30/15 12:01 7440-28-0 35.1 ug/L 1.0 0.28 1 04/27/15 22:45 04/30/15 12:01 7440-62-2 32.1 ug/L 5.0 2.4 1 04/27/15 22:45 04/30/15 12:01 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.60 0.065 1 04/27/15 20:20 04/30/15 18:27 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 57 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800Airpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009364 SPLP Lab ID: 92243920014 Collected: 03/30/15 14:09 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 204 ug/L 10.0 3.0 1 04/27/15 22:45 04/30/15 12:04 7429-90-5 3.5 ug/L 0.50 0.15 1 04/27/15 22:45 04/30/15 12:04 7440-36-0 13.6 ug/L 0.50 0.11 1 04/27/15 22:45 04/30/15 12:04 7440-38-2 244 ug/L 0.30 0.081 1 04/27/15 22:45 04/30/15 12:04 7440-39-3 ND ug/L 0.20 0.067 1 04/27/15 22:45 04/30/15 12:04 7440-41-7 62.8 ug/L 5.0 1.1 1 04/27/15 22:45 04/30/15 12:04 7440-42-8 0.027J ug/L 0.080 0.024 1 04/27/15 22:45 04/30/15 12:04 7440-43-9 14000 ug/L 40.0 16.0 1 04/27/15 22:45 04/30/15 12:04 7440-70-2 2.5 ug/L 0.50 0.17 1 04/27/15 22:45 04/30/15 12:04 7440-47-3 ND ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:04 7440-48-4 0.49J ug/L 1.0 0.21 1 04/27/15 22:45 04/30/15 12:04 7440-50-8 17.7J ug/L 50.0 13.7 1 04/27/15 22:45 04/30/15 12:04 7439-89-6 0.070J ug/L 0.10 0.046 1 04/27/15 22:45 04/30/15 12:04 7439-92-1 484 ug/L 10.0 3.2 1 04/27/15 22:45 04/30/15 12:04 7439-95-4 4.3 ug/L 0.50 0.24 1 04/27/15 22:45 04/30/15 12:04 7439-96-5 10 ug/L 0.50 0.094 1 04/27/15 22:45 04/30/15 12:04 7439-98-7 0.49J ug/L 0.50 0.16 1 04/27/15 22:45 04/30/15 12:04 7440-02-0 129 ug/L 50.0 11.7 1 04/27/15 22:45 04/30/15 12:04 7440-09-7 12.7 ug/L 0.50 0.20 1 04/27/15 22:45 04/30/15 12:04 7782-49-2 1390 ug/L 50.0 16.3 1 04/27/15 22:45 04/30/15 12:04 7440-23-5 548 ug/L 2.5 0.66 5 04/27/15 22:45 05/01/15 11:00 7440-24-6 ND ug/L 0.10 0.015 1 04/27/15 22:45 04/30/15 12:04 7440-28-0 100 ug/L 1.0 0.28 1 04/27/15 22:45 04/30/15 12:04 7440-62-2 31.1 ug/L 5.0 2.4 1 04/27/15 22:45 04/30/15 12:04 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/27/15 20:20 04/30/15 18:33 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 58 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800hirpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009365 SPLP Lab ID: 92243920015 Collected: 03/30/15 15:18 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 11300 ug/L 50.0 14.9 1 04/27/15 22:45 04/30/15 12:28 7429-90-5 ND ug/L 2.5 0.74 1 04/27/15 22:45 04/30/15 12:28 7440-36-0 3.0 ug/L 2.5 0.56 1 04/27/15 22:45 04/30/15 12:28 7440-38-2 557 ug/L 1.5 0.40 1 04/27/15 22:45 04/30/15 12:28 7440-39-3 2.1 ug/L 1.0 0.34 1 04/27/15 22:45 04/30/15 12:28 7440-41-7 156 ug/L 25.0 5.6 1 04/27/15 22:45 04/30/15 12:28 7440-42-8 ND ug/L 0.40 0.12 1 04/27/15 22:45 04/30/15 12:28 7440-43-9 3040 ug/L 200 80.0 1 04/27/15 22:45 04/30/15 12:28 7440-70-2 11.8 ug/L 2.5 0.84 1 04/27/15 22:45 04/30/15 12:28 7440-47-3 6.2 ug/L 2.5 0.63 1 04/27/15 22:45 04/30/15 12:28 7440-48-4 27.0 ug/L 5.0 1.1 1 04/27/15 22:45 04/30/15 12:28 7440-50-8 21900 ug/L 250 68.5 1 04/27/15 22:45 04/30/15 12:28 7439-89-6 33.5 ug/L 0.50 0.23 1 04/27/15 22:45 04/30/15 12:28 7439-92-1 2280 ug/L 50.0 15.8 1 04/27/15 22:45 04/30/15 12:28 7439-95-4 70.4 ug/L 2.5 1.2 1 04/27/15 22:45 04/30/15 12:28 7439-96-5 ND ug/L 2.5 0.47 1 04/27/15 22:45 04/30/15 12:28 7439-98-7 5.9 ug/L 2.5 0.81 1 04/27/15 22:45 04/30/15 12:28 7440-02-0 545 ug/L 250 58.7 1 04/27/15 22:45 04/30/15 12:28 7440-09-7 ND ug/L 2.5 1.0 1 04/27/15 22:45 04/30/15 12:28 7782-49-2 3400 ug/L 250 81.5 1 04/27/15 22:45 04/30/15 12:28 7440-23-5 52.3 ug/L 2.5 0.66 1 04/27/15 22:45 04/30/15 12:28 7440-24-6 0.14J ug/L 0.50 0.077 1 04/27/15 22:45 04/30/15 12:28 7440-28-0 57.7 ug/L 5.0 1.4 1 04/27/15 22:45 04/30/15 12:28 7440-62-2 172 ug/L 25.0 12.0 1 04/27/15 22:45 04/30/15 12:28 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.60 0.065 1 04/27/15 20:20 04/30/15 18:35 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 59 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800h,pyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009366 SPLP Lab ID: 92243920016 Collected: 03/30/15 15:30 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\��il=11 a � 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 13.3 ug/L 10.0 3.0 1 04/27/15 22:45 04/30/15 12:30 7429-90-5 ND ug/L 0.50 0.15 1 04/27/15 22:45 04/30/15 12:30 7440-36-0 ND ug/L 0.50 0.11 1 04/27/15 22:45 04/30/15 12:30 7440-38-2 109 ug/L 0.30 0.081 1 04/27/15 22:45 04/30/15 12:30 7440-39-3 ND ug/L 0.20 0.067 1 04/27/15 22:45 04/30/15 12:30 7440-41-7 41.6 ug/L 5.0 1.1 1 04/27/15 22:45 04/30/15 12:30 7440-42-8 0.038J ug/L 0.080 0.024 1 04/27/15 22:45 04/30/15 12:30 7440-43-9 916 ug/L 40.0 16.0 1 04/27/15 22:45 04/30/15 12:30 7440-70-2 0.22J ug/L 0.50 0.17 1 04/27/15 22:45 04/30/15 12:30 7440-47-3 6.6 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:30 7440-48-4 0.48J ug/L 1.0 0.21 1 04/27/15 22:45 04/30/15 12:30 7440-50-8 20.1J ug/L 50.0 13.7 1 04/27/15 22:45 04/30/15 12:30 7439-89-6 ND ug/L 0.10 0.046 1 04/27/15 22:45 04/30/15 12:30 7439-92-1 293 ug/L 10.0 3.2 1 04/27/15 22:45 04/30/15 12:30 7439-95-4 103 ug/L 0.50 0.24 1 04/27/15 22:45 04/30/15 12:30 7439-96-5 ND ug/L 0.50 0.094 1 04/27/15 22:45 04/30/15 12:30 7439-98-7 4.3 ug/L 0.50 0.16 1 04/27/15 22:45 04/30/15 12:30 7440-02-0 137 ug/L 50.0 11.7 1 04/27/15 22:45 04/30/15 12:30 7440-09-7 ND ug/L 0.50 0.20 1 04/27/15 22:45 04/30/15 12:30 7782-49-2 2310 ug/L 50.0 16.3 1 04/27/15 22:45 04/30/15 12:30 7440-23-5 9.0 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:30 7440-24-6 ND ug/L 0.10 0.015 1 04/27/15 22:45 04/30/15 12:30 7440-28-0 ND ug/L 1.0 0.28 1 04/27/15 22:45 04/30/15 12:30 7440-62-2 31.3 ug/L 5.0 2.4 1 04/27/15 22:45 04/30/15 12:30 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/27/15 20:20 04/30/15 18:37 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 60 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98007VWYO"�-. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009367 SPLP Lab ID: 92243920017 Collected: 04/01/15 10:05 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 9340 ug/L 10.0 3.0 1 04/27/15 22:45 04/30/15 12:33 7429-90-5 ND ug/L 0.50 0.15 1 04/27/15 22:45 04/30/15 12:33 7440-36-0 1.4 ug/L 0.50 0.11 1 04/27/15 22:45 04/30/15 12:33 7440-38-2 358 ug/L 0.30 0.081 1 04/27/15 22:45 04/30/15 12:33 7440-39-3 1.5 ug/L 0.20 0.067 1 04/27/15 22:45 04/30/15 12:33 7440-41-7 52.0 ug/L 5.0 1.1 1 04/27/15 22:45 04/30/15 12:33 7440-42-8 ND ug/L 0.080 0.024 1 04/27/15 22:45 04/30/15 12:33 7440-43-9 2990 ug/L 40.0 16.0 1 04/27/15 22:45 04/30/15 12:33 7440-70-2 5.8 ug/L 0.50 0.17 1 04/27/15 22:45 04/30/15 12:33 7440-47-3 36.5 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:33 7440-48-4 23.7 ug/L 1.0 0.21 1 04/27/15 22:45 04/30/15 12:33 7440-50-8 8950 ug/L 50.0 13.7 1 04/27/15 22:45 04/30/15 12:33 7439-89-6 18.8 ug/L 0.10 0.046 1 04/27/15 22:45 04/30/15 12:33 7439-92-1 2170 ug/L 10.0 3.2 1 04/27/15 22:45 04/30/15 12:33 7439-95-4 1680 ug/L 5.0 2.4 10 04/27/15 22:45 04/30/15 12:52 7439-96-5 ND ug/L 0.50 0.094 1 04/27/15 22:45 04/30/15 12:33 7439-98-7 5.3 ug/L 0.50 0.16 1 04/27/15 22:45 04/30/15 12:33 7440-02-0 461 ug/L 50.0 11.7 1 04/27/15 22:45 04/30/15 12:33 7440-09-7 0.40J ug/L 0.50 0.20 1 04/27/15 22:45 04/30/15 12:33 7782-49-2 2550 ug/L 50.0 16.3 1 04/27/15 22:45 04/30/15 12:33 7440-23-5 119 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:33 7440-24-6 0.23 ug/L 0.10 0.015 1 04/27/15 22:45 04/30/15 12:33 7440-28-0 24.3 ug/L 1.0 0.28 1 04/27/15 22:45 04/30/15 12:33 7440-62-2 58.0 ug/L 5.0 2.4 1 04/27/15 22:45 04/30/15 12:33 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/27/15 20:20 04/30/15 18:43 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 61 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98008rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040045 Pace Project No.: 92243920 Sample: 2015009368 SPLP Lab ID: 92243920018 Collected: 04/01/15 10:27 Received: 04/02/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:46 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 15800 ug/L 10.0 3.0 1 04/27/15 22:45 04/30/15 12:36 7429-90-5 ND ug/L 0.50 0.15 1 04/27/15 22:45 04/30/15 12:36 7440-36-0 1.9 ug/L 0.50 0.11 1 04/27/15 22:45 04/30/15 12:36 7440-38-2 1220 ug/L 1.5 0.40 5 04/27/15 22:45 05/01/15 11:03 7440-39-3 2.8 ug/L 1.0 0.34 5 04/27/15 22:45 05/01/15 11:03 7440-41-7 41.0 ug/L 25.0 5.6 5 04/27/15 22:45 05/01/15 11:03 7440-42-8 ND ug/L 0.080 0.024 1 04/27/15 22:45 04/30/15 12:36 7440-43-9 7040 ug/L 40.0 16.0 1 04/27/15 22:45 04/30/15 12:36 7440-70-2 12.9 ug/L 0.50 0.17 1 04/27/15 22:45 04/30/15 12:36 7440-47-3 11.7 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:36 7440-48-4 39.2 ug/L 1.0 0.21 1 04/27/15 22:45 04/30/15 12:36 7440-50-8 8550 ug/L 50.0 13.7 1 04/27/15 22:45 04/30/15 12:36 7439-89-6 12.9 ug/L 0.10 0.046 1 04/27/15 22:45 04/30/15 12:36 7439-92-1 11500 ug/L 10.0 3.2 1 04/27/15 22:45 04/30/15 12:36 7439-95-4 283 ug/L 0.50 0.24 1 04/27/15 22:45 04/30/15 12:36 7439-96-5 ND ug/L 0.50 0.094 1 04/27/15 22:45 04/30/15 12:36 7439-98-7 11.4 ug/L 0.50 0.16 1 04/27/15 22:45 04/30/15 12:36 7440-02-0 560 ug/L 50.0 11.7 1 04/27/15 22:45 04/30/15 12:36 7440-09-7 0.86 ug/L 0.50 0.20 1 04/27/15 22:45 04/30/15 12:36 7782-49-2 2100 ug/L 50.0 16.3 1 04/27/15 22:45 04/30/15 12:36 7440-23-5 156 ug/L 0.50 0.13 1 04/27/15 22:45 04/30/15 12:36 7440-24-6 0.11 ug/L 0.10 0.015 1 04/27/15 22:45 04/30/15 12:36 7440-28-0 26.5 ug/L 1.0 0.28 1 04/27/15 22:45 04/30/15 12:36 7440-62-2 128 ug/L 5.0 2.4 1 04/27/15 22:45 04/30/15 12:36 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/27/15 20:20 04/30/15 18:45 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 62 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800M,pyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: MERP/13175 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92243920009 METHOD BLANK: 1935443 Matrix: Water Associated Lab Samples: 92243920009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/13/1510:36 LABORATORY CONTROL SAMPLE: 1935444 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.2 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1935445 1935446 MS MSD 10301355001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L <0.20 5 5 5.2 4.7 104 94 75-125 9 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 63 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800firpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: MERP/13216 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92243920010 METHOD BLANK: 1938141 Matrix: Water Associated Lab Samples: 92243920010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/14/1516:36 LABORATORY CONTROL SAMPLE: 1938142 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.4 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1938475 1938476 MS MSD 10302456001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.3 105 106 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 64 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800&6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: MERP/13366 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92243920011,92243920012,92243920013,92243920014,92243920015,92243920016,92243920017, 92243920018 METHOD BLANK: 1949398 Matrix: Water Associated Lab Samples: 92243920011,92243920012,92243920013,92243920014,92243920015,92243920016,92243920017, 92243920018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/30/1518:19 LABORATORY CONTROL SAMPLE: 1949399 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.4 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1949400 1949401 MS MSD 92243920013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Mercury ug/L ND 15 15 15.7 15.9 104 106 80-120 1 20 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 65 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980079,6fyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: MERP/5583 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1180936 Matrix: Solid Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 04/13/1517:21 LABORATORY CONTROL SAMPLE: 1180937 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.074 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1180938 1180939 MS MSD 92243914005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Mercury mg/kg 0.019 .111 .114 0.11 0.11 79 77 80-120 1 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 66 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980Vrpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: MPRP/23533 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1180940 Matrix: Solid Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 Parameter Units Blank Result Reporting Limit Aluminum mg/kg ND 4.9 Barium mg/kg 0.28J 0.49 Beryllium mg/kg ND 0.049 Boron mg/kg ND 2.5 Calcium mg/kg ND 24.6 Chromium mg/kg ND 0.25 Copper mg/kg ND 0.25 Iron mg/kg ND 2.0 Magnesium mg/kg ND 24.6 Manganese mg/kg ND 0.25 Molybdenum mg/kg ND 0.49 Nickel mg/kg ND 0.25 Potassium mg/kg ND 49.1 Sodium mg/kg ND 49.1 Strontium mg/kg ND 0.49 Zinc mg/kg ND 0.98 Analyzed Qualifiers 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 04/13/15 00:09 LABORATORY CONTROL SAMPLE: Parameter 1180941 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 134 106 80-120 Barium mg/kg 12.7 13.3 105 80-120 Beryllium mg/kg 1.3 1.3 106 80-120 Boron mg/kg 127 132 104 80-120 Calcium mg/kg 634 672 106 80-120 Chromium mg/kg 12.7 13.0 103 80-120 Copper mg/kg 12.7 13.0 103 80-120 Iron mg/kg 127 124 98 80-120 Magnesium mg/kg 634 648 102 80-120 Manganese mg/kg 12.7 13.6 107 80-120 Molybdenum mg/kg 12.7 12.2 96 80-120 Nickel mg/kg 12.7 13.0 103 80-120 Potassium mg/kg 634 629 99 80-120 Sodium mg/kg 634 681 107 80-120 Strontium mg/kg 12.7 13.9 109 80-120 Zinc mg/kg 63.4 61.8 97 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 67 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980mirpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1180942 1180943 MS MSD 92243914005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Aluminum mg/kg 28600 173 176 25100 26800 -2040 -1030 75-125 7 20 M1 Barium mg/kg 810 17.3 17.6 370 580 -2550 -1320 75-125 44 20 M1,R1 Beryllium mg/kg 2.0 1.68 1.68 2.7 3.0 42 58 75-125 10 20 M1 Boron mg/kg 44.2 173 176 184 185 81 81 75-125 1 20 Calcium mg/kg 2940 863 875 4860 4510 222 180 75-125 7 20 M1 Chromium mg/kg 29.2 17.3 17.6 47.1 47.0 104 102 75-125 0 20 Copper mg/kg 69.8 17.3 17.6 64.6 71.8 -30 12 75-125 11 20 M1 Iron mg/kg 43900 173 176 34800 39000 -5240 -2770 75-125 11 20 M1 Magnesium mg/kg 7890 863 875 10600 10100 319 248 75-125 6 20 M1 Manganese mg/kg 946 17.3 17.6 719 893 -1310 -302 75-125 22 20 M1,R1 Molybdenum mg/kg 2.2J 17.3 17.6 16.9 17.4 85 87 75-125 3 20 Nickel mg/kg 36.7 17.3 17.6 45.9 49.1 54 71 75-125 7 20 M1 Potassium mg/kg 2450 863 875 3210 3300 87 97 75-125 3 20 Sodium mg/kg ND 863 875 997 1010 107 106 75-125 1 20 Strontium mg/kg 267 17.3 17.6 153 207 -659 -339 75-125 30 20 M1,R1 Zinc mg/kg 123 86.3 87.5 179 195 65 83 75-125 9 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 68 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%ypyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: MPRP/23534 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1180944 Matrix: Solid Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.049 04/16/15 20:06 N2 Arsenic mg/kg ND 0.049 04/16/15 20:06 Cadmium mg/kg ND 0.0059 04/16/15 20:06 Cobalt mg/kg ND 0.049 04/16/15 20:06 Lead mg/kg ND 0.049 04/16/15 20:06 Selenium mg/kg ND 0.049 04/16/15 20:06 Thallium mg/kg ND 0.049 04/16/15 20:06 Vanadium mg/kg ND 0.049 04/16/15 20:06 LABORATORY CONTROL SAMPLE: Parameter 1180945 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.4 2.3 96 80-120 N2 Arsenic mg/kg 2.4 2.4 99 80-120 Cadmium mg/kg .24 0.25 104 80-120 Cobalt mg/kg 2.4 2.4 99 80-120 Lead mg/kg 2.4 2.3 94 80-120 Selenium mg/kg 2.4 2.5 102 80-120 Thallium mg/kg 2.4 2.4 98 80-120 Vanadium mg/kg 2.4 2.4 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1180946 MS 92243914006 Spike Parameter Units Result Conc. MSD Spike Conc. 1180947 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 4.41 4.59 ND ND 45 44 75-125 20 D3,M6, N2 Arsenic mg/kg 17.8 4.41 4.59 39.4 26.2 497 185 75-125 40 20 D3,M6, R1 Cadmium mg/kg ND .441 .459 0.72 0.64 143 120 75-125 12 20 D3,M6 Cobalt mg/kg 5.1 4.41 4.59 11.6 11.8 148 147 75-125 2 20 D3,M6 Lead mg/kg 7.7J 4.41 4.59 13.3 13.0 129 118 75-125 2 20 D3 Selenium mg/kg 6.3 4.41 4.59 11.8 10.0 125 81 75-125 16 20 D3 Thallium mg/kg ND 4.41 4.59 ND ND 39 41 75-125 20 D3 Vanadium mg/kg 25.4 4.41 4.59 36.7 36.6 259 248 75-125 0 20 D3,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 69 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800Air6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: MPRP/53458 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92243920009, 92243920010 METHOD BLANK: 1934333 Associated Lab Samples: 92243920009, 92243920010 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 04/13/1511:04 ND 0.50 04/13/1511:04 ND 0.50 04/13/1511:04 ND 0.30 04/13/1511:04 ND 0.20 04/13/1511:04 ND 5.0 04/13/1511:04 ND 0.080 04/13/1511:04 ND 40.0 04/13/1511:04 ND 0.50 04/13/1511:04 ND 0.50 04/13/1511:04 ND 1.0 04/13/1511:04 ND 50.0 04/13/1511:04 ND 0.10 04/13/1511:04 ND 10.0 04/13/1511:04 ND 0.50 04/13/1511:04 ND 0.50 04/13/1511:04 ND 0.50 04/13/1511:04 ND 50.0 04/13/1511:04 ND 0.50 04/13/1511:04 ND 50.0 04/13/1511:04 ND 0.50 04/13/1511:04 ND 0.10 04/13/1511:04 ND 1.0 04/13/1511:04 ND 5.0 04/13/1511:04 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1934334 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 79.5 99 80-120 Antimony ug/L 80 81.2 102 80-120 Arsenic ug/L 80 81.7 102 80-120 Barium ug/L 80 78.5 98 80-120 Beryllium ug/L 80 79.3 99 80-120 Boron ug/L 80 77.1 96 80-120 Cadmium ug/L 80 82.2 103 80-120 Calcium ug/L 1000 978 98 80-120 Chromium ug/L 80 79.8 100 80-120 Cobalt ug/L 80 81.0 101 80-120 Copper ug/L 80 79.5 99 80-120 Iron ug/L 1000 1000 100 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 70 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800Airpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 LABORATORY CONTROL SAMPLE: 1934334 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 80.4 100 80-120 Magnesium ug/L 1000 1010 101 80-120 Manganese ug/L 80 81.0 101 80-120 Molybdenum ug/L 80 81.0 101 80-120 Nickel ug/L 80 83.9 105 80-120 Potassium ug/L 1000 1010 101 80-120 Selenium ug/L 80 80.7 101 80-120 Sodium ug/L 1000 999 100 80-120 Strontium ug/L 80 80.0 100 80-120 Thallium ug/L 80 75.4 94 80-120 Vanadium ug/L 80 81.2 101 80-120 Zinc ug/L 80 83.1 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1934335 1934336 MS MSD 92243916007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 200 80 80 456 471 320 338 75-125 3 20 M1 Antimony ug/L ND 80 80 80.8 81.1 101 101 75-125 0 20 Arsenic ug/L ND 80 80 81.3 82.0 101 102 75-125 1 20 Barium ug/L 3.6 80 80 83.6 84.4 100 101 75-125 1 20 Beryllium ug/L ND 80 80 76.6 76.7 96 96 75-125 0 20 Boron ug/L ND 80 80 75.5 80.1 93 99 75-125 6 20 Cadmium ug/L ND 80 80 83.0 82.8 104 103 75-125 0 20 Calcium ug/L 78.0 1000 1000 1170 1120 110 104 75-125 5 20 Chromium ug/L 0.92 80 80 82.0 81.8 101 101 75-125 0 20 Cobalt ug/L ND 80 80 82.6 82.6 103 103 75-125 0 20 Copper ug/L ND 80 80 83.1 82.0 103 101 75-125 1 20 Iron ug/L 308 1000 1000 1350 1370 105 106 75-125 1 20 Lead ug/L 0.30 80 80 81.4 81.4 101 101 75-125 0 20 Magnesium ug/L 29.8 1000 1000 1070 1050 104 102 75-125 2 20 Manganese ug/L 4.7 80 80 86.6 86.0 102 102 75-125 1 20 Molybdenum ug/L ND 80 80 81.6 81.8 101 102 75-125 0 20 Nickel ug/L 0.53 80 80 85.9 86.4 107 107 75-125 1 20 Potassium ug/L 89.2 1000 1000 1140 1130 105 104 75-125 1 20 Selenium ug/L ND 80 80 82.4 80.9 103 101 75-125 2 20 Sodium ug/L 84.6 1000 1000 1120 1100 103 101 75-125 2 20 Strontium ug/L 3.0 80 80 83.2 83.9 100 101 75-125 1 20 Thallium ug/L ND 80 80 79.2 79.0 99 99 75-125 0 20 Vanadium ug/L ND 80 80 83.1 82.9 103 103 75-125 0 20 Zinc ug/L ND 80 80 89.3 89.4 106 107 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 71 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980%�rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: MPRP/53957 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92243920011,92243920012,92243920013,92243920014,92243920015,92243920016,92243920017, 92243920018 METHOD BLANK: 1949388 Matrix: Water Associated Lab Samples: 92243920011,92243920012,92243920013,92243920014,92243920015,92243920016,92243920017, 92243920018 Parameter Units Blank Result Reporting Limit Analyzed Qualifiers Aluminum ug/L ND 10.0 04/30/1511:53 Antimony ug/L ND 0.50 04/30/1511:53 Arsenic ug/L ND 0.50 04/30/1511:53 Barium ug/L ND 0.30 04/30/15 22:38 Beryllium ug/L ND 0.20 04/30/1511:53 Boron ug/L ND 5.0 04/30/1511:53 Cadmium ug/L ND 0.080 04/30/1511:53 Calcium ug/L ND 40.0 04/30/1511:53 Chromium ug/L ND 0.50 04/30/1511:53 Cobalt ug/L ND 0.50 04/30/1511:53 Copper ug/L ND 1.0 04/30/1511:53 Iron ug/L ND 50.0 04/30/1511:53 Lead ug/L ND 0.10 04/30/1511:53 Magnesium ug/L 4.3J 10.0 04/30/1511:53 Manganese ug/L ND 0.50 04/30/1511:53 Molybdenum ug/L ND 0.50 04/30/1511:53 Nickel ug/L ND 0.50 04/30/1511:53 Potassium ug/L ND 50.0 04/30/1511:53 Selenium ug/L ND 0.50 04/30/1511:53 Sodium ug/L ND 50.0 04/30/1511:53 Strontium ug/L ND 0.50 04/30/1511:53 Thallium ug/L ND 0.10 04/30/1511:53 Vanadium ug/L ND 1.0 04/30/1511:53 Zinc ug/L ND 5.0 04/30/1511:53 LABORATORY CONTROL SAMPLE: 1949389 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum ug/L 80 80.3 100 80-120 Antimony ug/L 80 79.1 99 80-120 Arsenic ug/L 80 82.3 103 80-120 Barium ug/L 80 84.2 105 80-120 Beryllium ug/L 80 80.2 100 80-120 Boron ug/L 80 79.0 99 80-120 Cadmium ug/L 80 79.7 100 80-120 Calcium ug/L 1000 1010 101 80-120 Chromium ug/L 80 85.1 106 80-120 Cobalt ug/L 80 87.0 109 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 72 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980vrpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 LABORATORY CONTROL SAMPLE: 1949389 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper ug/L 80 86.3 108 80-120 Iron ug/L 1000 1080 108 80-120 Lead ug/L 80 84.7 106 80-120 Magnesium ug/L 1000 1100 110 80-120 Manganese ug/L 80 81.0 101 80-120 Molybdenum ug/L 80 80.7 101 80-120 Nickel ug/L 80 83.7 105 80-120 Potassium ug/L 1000 1100 110 80-120 Selenium ug/L 80 82.0 102 80-120 Sodium ug/L 1000 1100 110 80-120 Strontium ug/L 80 74.9 94 80-120 Thallium ug/L 80 89.5 112 80-120 Vanadium ug/L 80 83.8 105 80-120 Zinc ug/L 80 79.8 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1949390 1949391 MS MSD 92243920011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 640 400 400 1140 1170 125 131 75-125 2 20 M1 Antimony ug/L 0.83J 400 400 394 407 98 102 75-125 3 20 Arsenic ug/L 16.5 400 400 427 439 102 106 75-125 3 20 Barium ug/L 277 400 400 670 707 98 107 75-125 5 20 Beryllium ug/L ND 400 400 409 412 102 103 75-125 1 20 Boron ug/L 90.6 400 400 513 507 106 104 75-125 1 20 Cadmium ug/L ND 400 400 398 410 99 103 75-125 3 20 Calcium ug/L 2130 5000 5000 7090 7480 99 107 75-125 5 20 Chromium ug/L 6.7 400 400 410 418 101 103 75-125 2 20 Cobalt ug/L ND 400 400 406 416 101 104 75-125 3 20 Copper ug/L 5.8 400 400 403 412 99 102 75-125 2 20 Iron ug/L 522 5000 5000 5990 6230 109 114 75-125 4 20 Lead ug/L 0.92 400 400 408 422 102 105 75-125 3 20 Magnesium ug/L 445 5000 5000 5510 5680 101 105 75-125 3 20 Manganese ug/L 9.9 400 400 413 416 101 102 75-125 1 20 Molybdenum ug/L 1.2J 400 400 404 411 101 103 75-125 2 20 Nickel ug/L 1.3J 400 400 418 433 104 108 75-125 3 20 Potassium ug/L 351 5000 5000 5230 5400 98 101 75-125 3 20 Selenium ug/L 1.91 400 400 418 421 104 105 75-125 1 20 Sodium ug/L 2040 5000 5000 7230 7540 104 110 75-125 4 20 Strontium ug/L 76.7 400 400 455 468 95 98 75-125 3 20 Thallium ug/L ND 400 400 440 457 110 114 75-125 4 20 Vanadium ug/L 17.7 400 400 423 426 101 102 75-125 1 20 Zinc ug/L 80.0 400 400 472 490 98 103 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 73 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ,pyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: PMST/3429 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 SAMPLE DUPLICATE: 1179867 35182431001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 15.7 14.8 6 10 SAMPLE DUPLICATE: 1179868 92243926008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 33.1 33.8 2 10 SAMPLE DUPLICATE: 1179869 92243926015 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 29.4 31.8 8 10 SAMPLE DUPLICATE: 1179870 92243920002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 46.8 48.2 3 10 SAMPLE DUPLICATE: 1179871 35182950006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.7 12.8 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 74 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800�rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: WET/36721 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 SAMPLE DUPLICATE: 1430245 92243926006 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.1 7.1 0 10 SAMPLE DUPLICATE: 1430246 92243926010 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.5 7.5 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 75 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98006r6fyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: WETA/22570 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1434821 Matrix: Water Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 2.8 2.0 04/15/1514:27 LABORATORY CONTROL SAMPLE: 1434822 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1434823 1434824 MS MSD 92243757005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfate mg/L 4.0 33.3 33.3 33.9 34.0 90 90 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1434825 1434826 MS MSD 92243920005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Sulfate mg/L 5.3 26.2 26.2 28.7 28.9 89 90 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 76 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980Vrpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: WETA/22576 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1435291 Matrix: Water Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.16 0.020 04/15/15 17:00 Z2 LABORATORY CONTROL SAMPLE: 1435292 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1435293 1435294 MS MSD 92243757005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Nitrogen, Nitrate mg/L ND 4.2 4.2 4.0 4.1 91 92 90-110 1 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1435295 1435296 MS MSD 92243759001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.3 3.3 3.3 3.3 95 95 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 77 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980mirpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: WETA/22563 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1434670 Matrix: Water Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 04/15/15 04:12 LABORATORY CONTROL SAMPLE: 1434671 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.3 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1434672 1434673 MS MSD 92243757005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Chloride mg/L ND 33.3 33.3 36.4 36.0 104 103 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1434674 1434675 MS MSD 92243920005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Chloride mg/L ND 26.2 26.2 28.2 28.0 103 102 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 78 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980cbypyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: WETA/45210 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1177213 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.4 04/08/1514:51 Sulfate mg/kg ND 49.4 04/08/1514:51 LABORATORY CONTROL SAMPLE: 1177214 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1177216 Parameter Units Chloride mg/kg Sulfate mg/kg Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 502 474 94 80-120 502 473 94 80-120 92243914001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 706 618 70 80-120 M 1 ND 706 640 78 80-120 M 1 SAMPLE DUPLICATE: 1177215 92243914001 Dup Parameter Units Result Result Chloride mg/kg ND ND Sulfate mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 79 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98006rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: WETA/45211 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1177217 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 04/08/15 14:51 LABORATORY CONTROL SAMPLE: 1177218 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.2 48.2 96 80-120 MATRIX SPIKE SAMPLE: 1177221 92243914001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 70.6 62.3 88 80-120 H3 SAMPLE DUPLICATE: 1177220 92243914001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 80 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 980C�ir6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040045 Pace Project No.: 92243920 QC Batch: WETA/28128 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92243920001, 92243920002, 92243920003, 92243920004, 92243920005, 92243920006, 92243920007, 92243920008 METHOD BLANK: 1144490 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 04/22/15 08:24 LABORATORY CONTROL SAMPLE: 1144491 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 119000 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1144492 1144493 MS MSD 92243926010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 20900 50100 50300 68100 67500 94 93 50-150 1 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1144494 1144495 MS MSD 92243920001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 86000 56100 55500 128000 131000 74 80 50-150 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 81 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 98004rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15040045 Pace Project No.: 92243920 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/9581 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS 1g %RSD>40 B Analyte was detected in the associated method blank. D3 D3 D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. H1 Analysis conducted outside the EPA method holding time. H1 Analysis conducted outside the recognized method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 82 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800Airpyo"Je. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15040045 Pace Project No.: 92243920 ANALYTE QUALIFIERS M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 83 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800*rpyo"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040045 Pace Project No.: 92243920 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92243920001 2015009361 EPA 3050 MPRP/23533 EPA 6010 ICP/14399 92243920002 2015009362 EPA 3050 MPRP/23533 EPA 6010 ICP/14399 92243920003 2015009363 EPA 3050 MPRP/23533 EPA 6010 ICP/14399 92243920004 2015009364 EPA 3050 MPRP/23533 EPA 6010 ICP/14399 92243920005 2015009365 EPA 3050 MPRP/23533 EPA 6010 ICP/14399 92243920006 2015009366 EPA 3050 MPRP/23533 EPA6010 ICP/14399 92243920007 2015009367 EPA 3050 MPRP/23533 EPA 6010 ICP/14399 92243920008 2015009368 EPA 3050 MPRP/23533 EPA 6010 ICP/14399 92243920001 2015009361 EPA 3050 MPRP/23534 EPA 6020 ICPM/9581 92243920002 2015009362 EPA 3050 MPRP/23534 EPA 6020 ICPM/9581 92243920003 2015009363 EPA 3050 MPRP/23534 EPA 6020 ICPM/9581 92243920004 2015009364 EPA 3050 MPRP/23534 EPA 6020 ICPM/9581 92243920005 2015009365 EPA 3050 MPRP/23534 EPA 6020 ICPM/9581 92243920006 2015009366 EPA 3050 MPRP/23534 EPA 6020 ICPM/9581 92243920007 2015009367 EPA 3050 MPRP/23534 EPA 6020 ICPM/9581 92243920008 2015009368 EPA 3050 MPRP/23534 EPA 6020 ICPM/9581 92243920009 2015009369 EPA 3020 MPRP/53458 EPA 6020A ICPM/23725 92243920010 2015009370 EPA 3020 MPRP/53458 EPA 6020A ICPM/23725 92243920011 2015009361 SPLP EPA 3020 MPRP/53957 EPA 6020A ICPM/24002 92243920012 2015009362 SPLP EPA 3020 MPRP/53957 EPA 6020A ICPM/24002 92243920013 2015009363 SPLP EPA 3020 MPRP/53957 EPA 6020A ICPM/24002 92243920014 2015009364 SPLP EPA 3020 MPRP/53957 EPA 6020A ICPM/24002 92243920015 2015009365 SPLP EPA 3020 MPRP/53957 EPA 6020A ICPM/24002 92243920016 2015009366 SPLP EPA 3020 MPRP/53957 EPA 6020A ICPM/24002 92243920017 2015009367 SPLP EPA 3020 MPRP/53957 EPA 6020A ICPM/24002 92243920018 2015009368 SPLP EPA 3020 MPRP/53957 EPA 6020A ICPM/24002 92243920009 2015009369 EPA 7470 MERP/13175 EPA 7470 MERC/15344 92243920010 2015009370 EPA 7470 MERP/13216 EPA 7470 MERC/15367 92243920011 2015009361 SPLP EPA 7470A MERP/13366 EPA 7470A MERC/15539 92243920012 2015009362 SPLP EPA 7470A MERP/13366 EPA 7470A MERC/15539 92243920013 2015009363 SPLP EPA 7470A MERP/13366 EPA 7470A MERC/15539 92243920014 2015009364 SPLP EPA 7470A MERP/13366 EPA 7470A MERC/15539 92243920015 2015009365 SPLP EPA 7470A MERP/13366 EPA 7470A MERC/15539 92243920016 2015009366 SPLP EPA 7470A MERP/13366 EPA 7470A MERC/15539 92243920017 2015009367 SPLP EPA 7470A MERP/13366 EPA 7470A MERC/15539 92243920018 2015009368 SPLP EPA 7470A MERP/13366 EPA 7470A MERC/15539 92243920001 2015009361 EPA 7471 MERP/5583 EPA 7471 MERC/5570 92243920002 2015009362 EPA 7471 MERP/5583 EPA 7471 MERC/5570 92243920003 2015009363 EPA 7471 MERP/5583 EPA 7471 MERC/5570 92243920004 2015009364 EPA 7471 MERP/5583 EPA 7471 MERC/5570 92243920005 2015009365 EPA 7471 MERP/5583 EPA 7471 MERC/5570 92243920006 2015009366 EPA 7471 MERP/5583 EPA 7471 MERC/5570 92243920007 2015009367 EPA 7471 MERP/5583 EPA 7471 MERC/5570 92243920008 2015009368 EPA 7471 MERP/5583 EPA 7471 MERC/5570 92243920001 2015009361 ASTM D2974-87 PMST/3429 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 84 of 88 acmnalytical www.pacelabs.com Pace Analytical Services, Inc. 980098raeybe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040045 Pace Project No.: 92243920 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92243920002 2015009362 ASTM D2974-87 PMST/3429 92243920003 2015009363 ASTM D2974-87 PMST/3429 92243920004 2015009364 ASTM D2974-87 PMST/3429 92243920005 2015009365 ASTM D2974-87 PMST/3429 92243920006 2015009366 ASTM D2974-87 PMST/3429 92243920007 2015009367 ASTM D2974-87 PMST/3429 92243920008 2015009368 ASTM D2974-87 PMST/3429 92243920001 2015009361 EPA 9045 WET/36721 92243920002 2015009362 EPA 9045 WET/36721 92243920003 2015009363 EPA 9045 WET/36721 92243920004 2015009364 EPA 9045 WET/36721 92243920005 2015009365 EPA 9045 WET/36721 92243920006 2015009366 EPA 9045 WET/36721 92243920007 2015009367 EPA 9045 WET/36721 92243920008 2015009368 EPA 9045 WET/36721 92243920001 2015009361 EPA 300.0 WETA/22570 92243920002 2015009362 EPA 300.0 WETA/22570 92243920003 2015009363 EPA 300.0 WETA/22570 92243920004 2015009364 EPA 300.0 WETA/22570 92243920005 2015009365 EPA 300.0 WETA/22570 92243920006 2015009366 EPA 300.0 WETA/22570 92243920007 2015009367 EPA 300.0 WETA/22570 92243920008 2015009368 EPA 300.0 WETA/22570 92243920001 2015009361 EPA 353.2 WETA/22576 92243920002 2015009362 EPA 353.2 WETA/22576 92243920003 2015009363 EPA 353.2 WETA/22576 92243920004 2015009364 EPA 353.2 WETA/22576 92243920005 2015009365 EPA 353.2 WETA/22576 92243920006 2015009366 EPA 353.2 WETA/22576 92243920007 2015009367 EPA 353.2 WETA/22576 92243920008 2015009368 EPA 353.2 WETA/22576 92243920001 2015009361 SM 4500-CI-E WETA/22563 92243920002 2015009362 SM 4500-CI-E WETA/22563 92243920003 2015009363 SM 4500-CI-E WETA/22563 92243920004 2015009364 SM 4500-CI-E WETA/22563 92243920005 2015009365 SM 4500-CI-E WETA/22563 92243920006 2015009366 SM 4500-CI-E WETA/22563 92243920007 2015009367 SM 4500-CI-E WETA/22563 92243920008 2015009368 SM 4500-CI-E WETA/22563 92243920001 2015009361 EPA 9056 WETA/45210 92243920002 2015009362 EPA 9056 WETA/45210 92243920003 2015009363 EPA 9056 WETA/45210 92243920004 2015009364 EPA 9056 WETA/45210 92243920005 2015009365 EPA 9056 WETA/45210 92243920006 2015009366 EPA 9056 WETA/45210 92243920007 2015009367 EPA 9056 WETA/45210 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:46 AM without the written consent of Pace Analytical Services, Inc.. Page 85 of 88 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800q6r6fy0"Je. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040045 Pace Project No.: 92243920 Lab ID Sample ID QC Batch Method QC Batch 92243920008 2015009368 EPA 9056 WETA/45210 92243920001 2015009361 EPA 9056 WETA/45211 92243920002 2015009362 EPA 9056 WETA/45211 92243920003 2015009363 EPA 9056 WETA/45211 92243920004 2015009364 EPA 9056 WETA/45211 92243920005 2015009365 EPA 9056 WETA/45211 92243920006 2015009366 EPA 9056 WETA/45211 92243920007 2015009367 EPA 9056 WETA/45211 92243920008 2015009368 EPA 9056 WETA/45211 92243920001 2015009361 EPA 9060 WETA/28128 92243920001 2015009361 EPA 9060 WETA/28129 92243920002 2015009362 EPA 9060 WETA/28128 92243920002 2015009362 EPA 9060 WETA/28129 92243920003 2015009363 EPA 9060 WETA/28128 92243920003 2015009363 EPA 9060 WETA/28129 92243920004 2015009364 EPA 9060 WETA/28128 92243920004 2015009364 EPA 9060 WETA/28129 92243920005 2015009365 EPA 9060 WETA/28128 92243920005 2015009365 EPA 9060 WETA/28129 92243920006 2015009366 EPA 9060 WETA/28128 92243920006 2015009366 EPA 9060 WETA/28129 92243920007 2015009367 EPA 9060 WETA/28128 92243920007 2015009367 EPA 9060 WETA/28129 92243920008 2015009368 EPA 9060 WETA/28128 92243920008 2015009368 EPA 9060 WETA/28129 Date: 05/13/2015 07:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 86 of 88 (�21COAnalytkal' L/Murritirit 114ame: vut+u11i'11% IN v'-Q . Condition Upon Receipt (S2YEL Pagel of 2 Document Number: Issuing Authority�(: F-CHR-CS-003-rev.15 Pace Huntersville Qualit° Client Name: Courier: ❑ Fed Ex ❑ UPS❑ ' USPS❑ Client❑ Commercial Pace Other Custody Seal on Cooler/Box Present: ❑ yes ❑/ no Seals intact: ❑ yes [] no Packing Material: ❑ Bubble VDp ❑ Bubble Bags © None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: OW t Blue None mples on ice, cooling process has begun Tomn f:nrrorfinn trarinr T114fil Idn rnrrpction Biological Tissue is Frozen: Yes No NIA Date a �la s f arson examining Corrected Cooler Temp.: 'C c01 tent9: Temp should be above freezing to 6°C Comments: Chain of Custody Present: D4. ❑No ONIA 1, Chain of Custody Filled Out: CJYes ONO ❑NIA 2. Chain of Custody Relinquished: E Yes ONO ❑NIA 3, Sampler Name & Signature on COC:[a1es ONO ❑NIA 4. Samples Arrived within Hold Time: ElYes ONO ❑NIA 5. Short Hold Time Analysis ({72hr): ❑Yes❑f//o ❑NIA 6. Rush Turn Around Time Requested: ❑Yes l(No ❑NIA 7, Sufficient Volume: Gres [:]No ❑NIA 8, Correct Containers Used: Zyes ❑No ❑NIA 9. -Pace Containers Used: "CIYes ❑No ❑NIA Containers Intact: IlYes ONO ❑NI 10. Filtered volume received for Dissolved tests ❑Yes ❑No NIA 11. Sample Labels match COC: f2res ONO '❑NIA 12. -includes dateltimellD/Analysis Matrix: All containers needing preservation have been checked. ❑WS ONO !A 1� All containers needing preservation are found to be in [a s ONO A compliance with EPA recommendation. exceptions: VOA, colirorm, T00, O&G, W-DRO (water) ❑Yes ONO Samples checked for dechlorination: Oyes ONO E115A 14. Headspace in VOA Vials (>6mm): ❑Yes ONO IINIA 15. Trip Blank Present: ❑Yes ❑No [!� 16. Trip Blank Custody Seals Present ❑Yes ONO. ❑NIA Pace Trip Blank Lot # (if purchased): Client Notification! Resolution: hy Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: (. c,i%t; Date: 12y f SRF Review: Date: Ljkdf� Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( 1.e out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92243920 1111111111111111111111 92243920 Page 87 of 88 101 of 102 i ar ro rlv�,wnjrlydrr �Jrprgl,ri:gSG �nLut n: ar} r?gi,t' ,rDr7pr 1 rr AA i ' I z 3 ! � �� yD1 t56 SO ri G A Ci 0 EiK'wA ct: f Tl TD 0 � "d 'ty 170 9 /ryn a 0a02 u� fD ! W I f iii ------------- Z "O X N n o $ v a �} 00 "An 5 `;i ri s� � ' -= \= `_- -�--{---..-•.�,_i... ._..�.. I _ ..._...�_ "GrabI � _. r i- 6 05 J � e t _..__....__„_.._S V r �t �n `Total # Of Containers Page 88 of 88 l7 Q •L ... '9. _ .. __ .__ , _.. -- ''�. -- o �"Q. � �.' Rif r% 00 M t- 4-.? T r !7 -7 t -? rt. CUSTODY REC'"W) 18AINIDANAL""I" I"'# "" "' M Analytical Laboratory Services i ------------- Analytical Laboratory Use Only i I 102 of 102 DUKE i Mail Code MG03A2 tBuilding 7405) . - Work O"W Mawr ! I isanvIes NO— I I Sc Page I Qfi XP'v ENER 13339 Hagers reny Rd Huntersville, N. C. 28078 1 0 Li By Date T10" .0f4614;1tq -j DISTRIBUTION ORIGINAL to LAB. LG`Y, it (980) $76-R245 i jLgqd 1 SAMPLE PROGRAM 1 i C� �10 V'JatC' COPY to CLIENT gj9RqIjkj. I 1p"ni"t Name r---4 ............. - --------- 12)Phone No: I 1 0 I "1 Other 1 PACE C ooler Temi, (C) RA Vusto 4)FOR No: isery.: 1FibiI, PO 1142081 '4�l ire Mail Ck. P WA* 81 dPerating unit 9 cfivity ID 7QjProcess ID SYNTERRA EDD Nftxen spetific accounting has beer. established and is not indicated above we neec Ime iovow.": i) enter correct accounting m idii 5 4ccounfing fteids above. Of provide ,,onrecta.- 'collection Information I --------------- ! 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