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Home My WebLink AboutNC0003417_J15030758 Report_20150805DUE Analytical Laboratory Page 1 of 109 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15030758 HF LEE PLANT - AB GW ASSESSMENT SOIL Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer 1677 Old Smithfield Rd Goldsboro NC 27530, Margaret Galvin -Karr Phone: 980-875-5219 _'�,,,,, MXG4644(101161) RGY,: 2015.05.1809:37:03-04'00' Date: Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 4/30/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Page 2 of 109 Sample Description 2015009008 HF LEE PLANT 28-Mar-15 9:30 AM ILLEGIBLE Well IABMW-2-2.5-3.5 2015009009 HF LEE PLANT 28-Mar-15 10:26 AM ILLEGIBLE Well IABMW-2-6-7 2015009010 HF LEE PLANT 28-Mar-15 10:57 AM ILLEGIBLE Well IABMW-2-12-14 2015009011 HF LEE PLANT 25-Mar-15 12:55 PM ILLEGIBLE Well IMW-2SB-7-8 2015009012 HF LEE PLANT 25-Mar-15 10:36 AM ILLEGIBLE Well IMW-2SB-0-2 2015009013 HF LEE PLANT 25-Mar-15 10:46 AM ILLEGIBLE Well IMW-2SB-4-5 2015009014 HF LEE PLANT 29-Mar-15 8:45 AM ILLEGIBLE Well IABMW-3-3-5 2015009015 HF LEE PLANT 29-Mar-15 10:41 AM ILLEGIBLE Well IABMW-3-14-15 2015009016 HF LEE PLANT 29-Mar-15 10:21 AM ILLEGIBLE Well IABMW-3-7-8 2015009017 HF LEE PLANT 29-Mar-15 8:20 AM ILLEGIBLE Well Equipment Blank 2015009018 HF LEE PLANT 28-Mar-15 11:30 AM ILLEGIBLE Well Equipment Blank 2015009019 HF LEE PLANT 25-Mar-15 3:05 PM ILLEGIBLE Well Equipment Blank 12 Total Samples Page 3 of 109 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/30/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IABMW-2-2.5-3.5 Collection Date: 28-Mar-15 9:30 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 109 Sample #: 2015009008 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IABMW-2-6-7 Collection Date: 28-Mar-15 10:26 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 109 Sample #: 2015009009 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IABMW-2-12-14 Collection Date: 28-Mar-15 10:57 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 109 Sample #: 2015009010 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IMW-2SB-7-8 Collection Date: 25-Mar-15 12:55 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 109 Sample #: 2015009011 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IMW-2SB-0-2 Collection Date: 25-Mar-15 10:36 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 109 Sample #: 2015009012 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IMW-2SB-4-5 Collection Date: 25-Mar-15 10:46 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 9 of 109 Sample #: 2015009013 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IABMW-3-3-5 Collection Date: 29-Mar-15 8:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 10 of 109 Sample #: 2015009014 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IABMW-3-14-15 Collection Date: 29-Mar-15 10:41 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 11 of 109 Sample #: 2015009015 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well IABMW-3-7-8 Collection Date: 29-Mar-15 10:21 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 12 of 109 Sample #: 2015009016 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis Page 13 of 109 This report shall not be reproduced, except in full. Order # J15030758 Site: Well Equipment Blank Collection Date: 29-Mar-15 8:20 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015009017 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030758 Site: Well Equipment Blank Collection Date: 28-Mar-15 11:30 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 14 of 109 Sample #: 2015009018 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis Page 15 of 109 This report shall not be reproduced, except in full. Order # J15030758 Site: Well Equipment Blank Collection Date: 25-Mar-15 3:05 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015009019 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3Syyg01t weyNe. Suite 100 Huntersville, INC 28078 (704)875-9092 April 27, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15030758 Pace Project No.: 92243393 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 31, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 93 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. P089g01yr6fy&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. Pggoi weyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36g01qrwyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15030758 Pace Project No.: 92243393 Lab ID Sample ID Matrix Date Collected Date Received 92243393001 2015009008 Solid 03/28/15 09:30 03/31/15 14:35 92243393002 2015009009 Solid 03/28/1510:26 03/31/15 14:35 92243393003 2015009010 Solid 03/28/1510:57 03/31/15 14:35 92243393004 2015009014 Solid 03/29/15 08:45 03/31/15 14:35 92243393005 2015009015 Solid 03/29/1510:41 03/31/15 14:35 92243393006 2015009016 Solid 03/29/1510:21 03/31/15 14:35 92243393007 2015009011 Solid 03/25/1512:55 03/31/15 14:35 92243393008 2015009012 Solid 03/25/1510:36 03/31/15 14:35 92243393009 2015009013 Solid 03/25/1510:46 03/31/15 14:35 92243393010 2015009008 SPLP Water 03/28/15 09:30 03/31/15 14:35 92243393011 2015009009 SPLP Water 03/28/15 10:26 03/31/15 14:35 92243393012 2015009010 SPLP Water 03/28/15 10:57 03/31/15 14:35 92243393013 2015009014 SPLP Water 03/29/15 08:45 03/31/15 14:35 92243393014 2015009015 SPLP Water 03/29/15 10:41 03/31/15 14:35 92243393015 2015009016 SPLP Water 03/29/15 10:21 03/31/15 14:35 92243393016 2015009017 Water 03/29/15 08:20 03/31/15 14:35 92243393017 2015009018 Water 03128/1511:30 03/31/15 14:35 92243393018 2015009019 Water 03/25/1515:05 03/31/15 14:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P360816fyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15030758 Pace Project No.: 92243393 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92243393001 2015009008 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243393002 2015009009 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243393003 2015009010 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243393004 2015009014 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. Pggc0 SirpyN.. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15030758 Pace Project No.: 92243393 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243393005 2015009015 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243393006 2015009016 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243393007 2015009011 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P360916fyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15030758 92243393 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92243393008 2015009012 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243393009 2015009013 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92243393010 2015009008 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 BT 1 PASI-M 92243393011 2015009009 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 BT 1 PASI-M 92243393012 2015009010 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 BT 1 PASI-M 92243393013 2015009014 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 BT 1 PASI-M 92243393014 2015009015 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 BT 1 PASI-M 92243393015 2015009016 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 BT 1 PASI-M 92243393016 2015009017 EPA 6020A RJS 24 PASI-M EPA 7470 DM 1 PASI-M 92243393017 2015009018 EPA 6020A RJS 24 PASI-M EPA 7470 DM 1 PASI-M 92243393018 2015009019 EPA 6020A RJS 24 PASI-M EPA 7470 DM 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3S�OzslWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92243393001 2015009008 EPA 6010 Aluminum 11100 mg/kg 49.1 04/09/15 08:12 EPA 6010 Barium 548 mg/kg 4.9 04/09/15 08:12 EPA 6010 Beryllium 3.9 mg/kg 0.49 04/09/15 08:12 EPA 6010 Boron 12.5J mg/kg 24.6 04/09/15 08:12 EPA 6010 Calcium 3690 mg/kg 246 04/09/15 08:12 EPA 6010 Chromium 22.8 mg/kg 2.5 04/09/15 08:12 EPA 6010 Copper 43.9 mg/kg 2.5 04/09/15 08:12 EPA 6010 Iron 6450 mg/kg 19.7 04/09/15 08:12 EPA 6010 Magnesium 818 mg/kg 246 04/09/15 08:12 EPA 6010 Manganese 97.5 mg/kg 2.5 04/09/15 08:12 EPA 6010 Nickel 18.4 mg/kg 2.5 04/09/15 08:12 EPA 6010 Potassium 1010 mg/kg 491 04/09/15 08:12 EPA 6010 Strontium 340 mg/kg 4.9 04/09/15 08:12 EPA 6010 Zinc 13.1 mg/kg 9.8 04/09/15 08:12 EPA 6020 Arsenic 25.8 mg/kg 4.9 04/07/15 13:33 EPA 6020 Cobalt 10.0 mg/kg 4.9 04/07/15 13:33 EPA 6020 Lead 15.0 mg/kg 4.9 04/07/15 13:33 EPA 6020 Vanadium 55.5 mg/kg 4.9 04/07/15 13:33 EPA 7471 Mercury 0.088 mg/kg 0.015 04/09/15 09:45 ASTM D2974-87 Percent Moisture 47.2 % 0.10 04/09/15 14:36 EPA 9045 pH at 25 Degrees C 6.2 Std. Units 0.10 04/07/15 14:15 EPA 300.0 Sulfate 11.3 mg/L 3.8 04/09/15 20:19 B EPA 353.2 Nitrogen, Nitrate 0.44 mg/L 0.38 04/09/15 20:09 H1 EPA 9060 Total Organic Carbon 141000 mg/kg 10900 04/17/15 11:51 EPA 9060 Total Organic Carbon 104000 mg/kg 10800 04/17/15 11:58 EPA 9060 Total Organic Carbon 109000 mg/kg 10500 04/17/15 12:04 EPA 9060 Total Organic Carbon 93200 mg/kg 10900 04/17/15 12:14 EPA 9060 Mean Total Organic Carbon 112000 mg/kg 10800 04/17/15 11:51 EPA 9060 RSD% 18.3 % 04/17/15 11:51 92243393002 2015009009 EPA 6010 Aluminum 11000 mg/kg 30.7 04/09/15 08:16 EPA 6010 Barium 38.0 mg/kg 3.1 04/09/15 08:16 EPA 6010 Beryllium 0.53 mg/kg 0.31 04/09/15 08:16 EPA 6010 Boron 19.7 mg/kg 15.4 04/09/15 08:16 EPA 6010 Calcium 698 mg/kg 154 04/09/15 08:16 EPA 6010 Chromium 14.9 mg/kg 1.5 04/09/15 08:16 EPA 6010 Copper 10.3 mg/kg 1.5 04/09/15 08:16 EPA 6010 Iron 16700 mg/kg 12.3 04/09/15 08:16 EPA 6010 Magnesium 1400 mg/kg 154 04/09/15 08:16 EPA 6010 Manganese 61.6 mg/kg 1.5 04/09/15 08:16 EPA 6010 Nickel 5.0 mg/kg 1.5 04/09/15 08:16 EPA 6010 Potassium 462 mg/kg 307 04/09/15 08:16 EPA 6010 Strontium 17.0 mg/kg 3.1 04/09/15 08:16 EPA 6010 Zinc 20.6 mg/kg 6.1 04/09/15 08:16 EPA 6020 Arsenic 1.91 mg/kg 3.1 04/07/15 13:35 EPA 6020 Cobalt 3.8 mg/kg 3.1 04/07/15 13:35 EPA 6020 Lead 9.0 mg/kg 3.1 04/07/15 13:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGAIirWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92243393002 2015009009 EPA 6020 Vanadium 36.0 mg/kg 3.1 04/07/15 13:35 EPA 7471 Mercury 0.037 mg/kg 0.0096 04/09/15 09:47 ASTM D2974-87 Percent Moisture 18.8 % 0.10 04/09/15 14:37 EPA 9045 pH at 25 Degrees C 5.3 Std. Units 0.10 04/07/15 14:15 EPA 300.0 Sulfate 9.4 mg/L 2.5 04/09/15 21:00 EPA 9056 Sulfate 169J mg/kg 306 04/05/15 01:31 EPA 9060 Total Organic Carbon 1280 mg/kg 737 04/17/15 12:20 EPA 9060 Total Organic Carbon 1960 mg/kg 743 04/17/15 12:26 EPA 9060 Total Organic Carbon 1250 mg/kg 739 04/17/15 12:31 EPA 9060 Total Organic Carbon 1180 mg/kg 745 04/17/15 12:37 EPA 9060 Mean Total Organic Carbon 1420 mg/kg 741 04/17/15 12:20 EPA 9060 RSD% 25.6 % 04/17/15 12:20 92243393003 2015009010 EPA 6010 Aluminum 7710 mg/kg 32.2 04/09/15 08:20 EPA 6010 Barium 49.3 mg/kg 3.2 04/09/15 08:20 EPA 6010 Beryllium 0.62 mg/kg 0.32 04/09/15 08:20 EPA 6010 Boron 14AJ mg/kg 16.1 04/09/15 08:20 EPA 6010 Calcium 737 mg/kg 161 04/09/15 08:20 EPA 6010 Chromium 10.2 mg/kg 1.6 04/09/15 08:20 EPA 6010 Copper 9.2 mg/kg 1.6 04/09/15 08:20 EPA 6010 Iron 13100 mg/kg 12.9 04/09/15 08:20 EPA 6010 Magnesium 1620 mg/kg 161 04/09/15 08:20 EPA 6010 Manganese 150 mg/kg 1.6 04/09/15 08:20 EPA 6010 Nickel 5.4 mg/kg 1.6 04/09/15 08:20 EPA 6010 Potassium 438 mg/kg 322 04/09/15 08:20 EPA 6010 Strontium 23.0 mg/kg 3.2 04/09/15 08:20 EPA 6010 Zinc 18.2 mg/kg 6.4 04/09/15 08:20 EPA 6020 Arsenic 2.8J mg/kg 3.2 04/07/15 13:38 EPA 6020 Cobalt 6.8 mg/kg 3.2 04/07/15 13:38 EPA 6020 Lead 7.1 mg/kg 3.2 04/07/15 13:38 EPA 6020 Vanadium 29.4 mg/kg 3.2 04/07/15 13:38 EPA 7471 Mercury 0.0076J mg/kg 0.010 04/09/15 09:49 ASTM D2974-87 Percent Moisture 19.5 % 0.10 04/09/15 14:38 EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 04/07/15 14:15 EPA 300.0 Sulfate 6.2 mg/L 2.5 04/09/15 21:14 EPA 353.2 Nitrogen, Nitrate 0.29 mg/L 0.25 04/09/15 20:15 EPA 9060 Total Organic Carbon 1180 mg/kg 750 04/17/15 12:43 EPA 9060 Total Organic Carbon 908 mg/kg 748 04/17/15 12:48 EPA 9060 Total Organic Carbon 1020 mg/kg 743 04/17/15 12:54 EPA 9060 Total Organic Carbon 1350 mg/kg 745 04/17/15 12:59 EPA 9060 Mean Total Organic Carbon 1110 mg/kg 747 04/17/15 12:43 EPA 9060 RSD% 17.3 % 04/17/15 12:43 92243393004 2015009014 EPA 6010 Aluminum 12600 mg/kg 38.8 04/09/15 08:25 EPA 6010 Barium 631 mg/kg 3.9 04/09/15 08:25 EPA 6010 Beryllium 3.0 mg/kg 0.39 04/09/15 08:25 REPORT OF LABORATORY ANALYSIS B D3 B H1 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92243393004 2015009014 EPA 6010 Boron 21.1 mg/kg 19.4 04/09/15 08:25 EPA 6010 Calcium 1620 mg/kg 194 04/09/15 08:25 EPA 6010 Chromium 19.9 mg/kg 1.9 04/09/15 08:25 EPA 6010 Copper 31.4 mg/kg 1.9 04/09/15 08:25 EPA 6010 Iron 7550 mg/kg 15.5 04/09/15 08:25 EPA 6010 Magnesium 951 mg/kg 194 04/09/15 08:25 EPA 6010 Manganese 53.0 mg/kg 1.9 04/09/15 08:25 EPA 6010 Nickel 14.3 mg/kg 1.9 04/09/15 08:25 EPA 6010 Potassium 2240 mg/kg 388 04/09/15 08:25 EPA 6010 Sodium 203J mg/kg 388 04/09/15 08:25 EPA 6010 Strontium 170 mg/kg 3.9 04/09/15 08:25 EPA 6010 Zinc 21.4 mg/kg 7.8 04/09/15 08:25 EPA 6020 Arsenic 76.3 mg/kg 3.9 04/07/15 13:40 EPA 6020 Cobalt 8.4 mg/kg 3.9 04/07/15 13:40 EPA 6020 Lead 14.3 mg/kg 3.9 04/07/15 13:40 EPA 6020 Selenium 6.6 mg/kg 3.9 04/07/15 13:40 EPA 6020 Vanadium 50.2 mg/kg 3.9 04/07/15 13:40 EPA 7471 Mercury 0.20 mg/kg 0.012 04/09/15 09:51 ASTM D2974-87 Percent Moisture 35.1 % 0.10 04/09/15 14:39 EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 04/07/15 14:15 EPA 300.0 Sulfate 21.6 mg/L 3.1 04/09/15 21:27 B SM 4500-CI-E Chloride 4.7J mg/L 7.7 04/09/15 05:10 EPA 9060 Total Organic Carbon 36900 mg/kg 8200 04/17/15 13:06 EPA 9060 Total Organic Carbon 40300 mg/kg 8720 04/17/15 13:12 EPA 9060 Total Organic Carbon 55300 mg/kg 8690 04/17/15 13:18 EPA 9060 Total Organic Carbon 53600 mg/kg 8390 04/17/15 13:25 EPA 9060 Mean Total Organic Carbon 46500 mg/kg 8500 04/17/15 13:06 EPA 9060 RSD% 19.9 % 04/17/15 13:06 92243393005 2015009015 EPA 6010 Aluminum 9210 mg/kg 29.6 04/09/15 08:42 EPA 6010 Barium 83.8 mg/kg 3.0 04/09/15 08:42 EPA 6010 Beryllium 0.74 mg/kg 0.30 04/09/15 08:42 EPA 6010 Calcium 692 mg/kg 148 04/09/15 08:42 EPA 6010 Chromium 13.1 mg/kg 1.5 04/09/15 08:42 EPA 6010 Copper 12.6 mg/kg 1.5 04/09/15 08:42 EPA 6010 Iron 6760 mg/kg 11.8 04/09/15 08:42 EPA 6010 Magnesium 883 mg/kg 148 04/09/15 08:42 EPA 6010 Manganese 15.9 mg/kg 1.5 04/09/15 08:42 EPA 6010 Nickel 4.4 mg/kg 1.5 04/09/15 08:42 EPA 6010 Potassium 154J mg/kg 296 04/09/15 08:42 EPA 6010 Strontium 22.9 mg/kg 3.0 04/09/15 08:42 EPA 6010 Zinc 12.2 mg/kg 5.9 04/09/15 08:42 EPA 6020 Arsenic 2.3J mg/kg 3.0 04/07/15 13:43 EPA 6020 Cobalt 4.2 mg/kg 3.0 04/07/15 13:43 EPA 6020 Lead 7.5 mg/kg 3.0 04/07/15 13:43 EPA 6020 Vanadium 43.7 mg/kg 3.0 04/07/15 13:43 EPA 7471 Mercury 0.028 mg/kg 0.0095 04/09/15 10:17 M1 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92243393005 2015009015 ASTM D2974-87 Percent Moisture 17.1 % 0.10 04/09/15 14:39 EPA 9045 pH at 25 Degrees C 5.4 Std. Units 0.10 04/07/15 14:15 EPA 300.0 Sulfate 5.7 mg/L 2.4 04/09/15 22:08 B SM 4500-CI-E Chloride 11.5 mg/L 6.0 04/09/15 05:11 EPA 9060 Total Organic Carbon 1440 mg/kg 721 04/17/15 13:32 EPA 9060 Total Organic Carbon 2080 mg/kg 724 04/17/15 13:37 EPA 9060 Total Organic Carbon 2470 mg/kg 719 04/17/15 13:43 EPA 9060 Total Organic Carbon 1340 mg/kg 723 04/17/15 13:49 EPA 9060 Mean Total Organic Carbon 1830 mg/kg 722 04/17/15 13:32 EPA 9060 RSD% 29.2 % 04/17/15 13:32 92243393006 2015009016 EPA 6010 Aluminum 10700 mg/kg 32.7 04/09/15 08:46 EPA 6010 Barium 94.7 mg/kg 3.3 04/09/15 08:46 EPA 6010 Beryllium 0.55 mg/kg 0.33 04/09/15 08:46 EPA 6010 Boron 25.2 mg/kg 16.4 04/09/15 08:46 EPA 6010 Calcium 589 mg/kg 164 04/09/15 08:46 EPA 6010 Chromium 12.9 mg/kg 1.6 04/09/15 08:46 EPA 6010 Copper 12.6 mg/kg 1.6 04/09/15 08:46 EPA 6010 Iron 23700 mg/kg 13.1 04/09/15 08:46 EPA 6010 Magnesium 657 mg/kg 164 04/09/15 08:46 EPA 6010 Manganese 16.4 mg/kg 1.6 04/09/15 08:46 EPA 6010 Nickel 3.3 mg/kg 1.6 04/09/15 08:46 EPA 6010 Strontium 13.6 mg/kg 3.3 04/09/15 08:46 EPA 6010 Zinc 12.4 mg/kg 6.5 04/09/15 08:46 EPA 6020 Cobalt 2.7J mg/kg 3.3 04/07/15 13:45 EPA 6020 Lead 12.1 mg/kg 3.3 04/07/15 13:45 EPA 6020 Vanadium 41.7 mg/kg 3.3 04/07/15 13:45 EPA 7471 Mercury 0.043 mg/kg 0.010 04/09/15 10:23 ASTM D2974-87 Percent Moisture 23.4 % 0.10 04/09/15 14:39 EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 04/07/15 14:15 EPA 300.0 Sulfate 12.3 mg/L 2.6 04/09/15 22:22 B EPA 353.2 Nitrogen, Nitrate 0.28 mg/L 0.26 04/09/15 20:18 H1 SM 4500-CI-E Chloride 7.6 mg/L 6.5 04/09/15 05:11 EPA 9060 Total Organic Carbon 4720 mg/kg 785 04/17/15 14:07 EPA 9060 Total Organic Carbon 4840 mg/kg 780 04/17/15 14:12 EPA 9060 Total Organic Carbon 4700 mg/kg 780 04/17/15 14:18 EPA 9060 Total Organic Carbon 4330 mg/kg 779 04/17/15 14:25 EPA 9060 Mean Total Organic Carbon 4650 mg/kg 781 04/17/15 14:07 EPA 9060 RSD% 4.7 % 04/17/15 14:07 92243393007 2015009011 EPA 6010 Aluminum 1270 mg/kg 32.2 04/11/1521:25 D3,M1 EPA 6010 Barium 6.8 mg/kg 3.2 04/11 /15 21:25 D3 EPA 6010 Chromium 2.4 mg/kg 1.6 04/11/15 21:25 D3 EPA 6010 Copper 1.6 mg/kg 1.6 04/11 /15 21:25 D3 EPA 6010 Iron 829 mg/kg 12.9 04/11/1521:25 D3,M1 EPA 6010 Manganese 5.0 mg/kg 1.6 04/11 /15 21:25 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW1*r6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92243393007 2015009011 EPA 6010 Nickel 1.0J mg/kg 1.6 04/11/15 21:25 D3 EPA 6010 Zinc 3.5J mg/kg 6.4 04/11/15 21:25 D3 EPA 6020 Vanadium 4.2 mg/kg 3.2 04/10/15 14:32 ASTM D2974-87 Percent Moisture 22.8 % 0.10 04/09/15 14:40 EPA 9045 pH at 25 Degrees C 4.1 Std. Units 0.10 04/06/15 13:30 EPA 9060 Total Organic Carbon 493J mg/kg 780 04/17/15 14:31 EPA 9060 Total Organic Carbon 479J mg/kg 769 04/17/15 14:36 EPA 9060 Total Organic Carbon 471J mg/kg 772 04/17/15 14:41 EPA 9060 Total Organic Carbon 531J mg/kg 770 04/17/15 14:48 EPA 9060 Mean Total Organic Carbon 493J mg/kg 773 04/17/15 14:31 EPA 9060 RSD% 5.4 % 04/17/15 14:31 92243393008 2015009012 EPA 6010 Aluminum 5170 mg/kg 31.5 04/11/15 21:37 D3 EPA 6010 Barium 17.0 mg/kg 3.2 04/11/15 21:37 D3 EPA 6010 Beryllium 0.191 mg/kg 0.32 04/11/15 21:37 D3 EPA 6010 Chromium 5.6 mg/kg 1.6 04/11/15 21:37 D3 EPA 6010 Copper 3.2 mg/kg 1.6 04/11/15 21:37 D3 EPA 6010 Iron 5150 mg/kg 12.6 04/11/15 21:37 D3 EPA 6010 Magnesium 262 mg/kg 158 04/11/15 21:37 D3 EPA 6010 Manganese 11.7 mg/kg 1.6 04/11/15 21:37 D3 EPA 6010 Nickel 1.0J mg/kg 1.6 04/11/15 21:37 D3 EPA 6010 Zinc 6.8 mg/kg 6.3 04/11/15 21:37 D3 EPA 6020 Lead 5.5 mg/kg 3.2 04/10/15 14:41 M6 EPA 6020 Vanadium 16.1 mg/kg 3.2 04/10/15 14:41 M6 EPA 7471 Mercury 0.0087J mg/kg 0.010 04/09/15 10:34 ASTM D2974-87 Percent Moisture 20.6 % 0.10 04/09/15 14:42 EPA 9045 pH at 25 Degrees C 4.3 Std. Units 0.10 04/06/15 13:30 EPA 9060 Total Organic Carbon 2780 mg/kg 757 04/17/15 14:55 EPA 9060 Total Organic Carbon 2680 mg/kg 756 04/17/15 15:01 EPA 9060 Total Organic Carbon 2740 mg/kg 752 04/17/15 15:08 EPA 9060 Total Organic Carbon 2560 mg/kg 758 04/17/15 15:13 EPA 9060 Mean Total Organic Carbon 2690 mg/kg 756 04/17/15 14:55 EPA 9060 RSD% 3.5 % 04/17/15 14:55 92243393009 2015009013 EPA 6010 Aluminum 3840 mg/kg 28.9 04/11/15 21:58 D3 EPA 6010 Barium 15.6 mg/kg 2.9 04/11/15 21:58 D3 EPA 6010 Beryllium 0.15J mg/kg 0.29 04/11/15 21:58 D3 EPA 6010 Chromium 3.6 mg/kg 1.4 04/11/15 21:58 D3 EPA 6010 Copper 2.1 mg/kg 1.4 04/11/15 21:58 D3 EPA 6010 Iron 1580 mg/kg 11.5 04/11/15 21:58 D3 EPA 6010 Magnesium 146 mg/kg 144 04/11/15 21:58 D3 EPA 6010 Manganese 5.6 mg/kg 1.4 04/11/15 21:58 D3 EPA 6010 Nickel 0.78J mg/kg 1.4 04/11/15 21:58 D3 EPA 6010 Zinc 3AJ mg/kg 5.8 04/11/15 21:58 D3 EPA 6020 Lead 3.9 mg/kg 2.9 04/10/15 14:55 EPA 6020 Vanadium 5.1 mg/kg 2.9 04/10/15 14:55 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROzl IWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92243393009 2015009013 EPA 7471 Mercury 0.0083J mg/kg 0.0092 04/09/15 10:36 ASTM D2974-87 Percent Moisture 10.9 % 0.10 04/09/15 14:43 EPA 9045 pH at 25 Degrees C 4.6 Std. Units 0.10 04/06/15 13:30 EPA 9060 Total Organic Carbon 455J mg/kg 669 04/17/15 15:20 EPA 9060 Total Organic Carbon 455J mg/kg 674 04/17/15 15:26 EPA 9060 Total Organic Carbon 453J mg/kg 677 04/17/15 15:33 EPA 9060 Total Organic Carbon 457J mg/kg 668 04/17/15 15:40 EPA 9060 Mean Total Organic Carbon 455J mg/kg 672 04/17/15 15:20 EPA 9060 RSD% 0.36 % 04/17/15 15:20 92243393010 2015009008 SPLP EPA 6020A Aluminum 615 ug/L 10.0 04/17/15 14:52 EPA 6020A Antimony 0.78 ug/L 0.50 04/17/15 14:52 EPA 6020A Arsenic 5.1 ug/L 0.50 04/17/15 14:52 EPA 6020A Barium 171 ug/L 0.30 04/17/15 14:52 EPA 6020A Boron 48.8 ug/L 5.0 04/20/15 12:12 EPA 6020A Calcium 1790 ug/L 40.0 04/17/15 14:52 EPA 6020A Chromium 3.8 ug/L 0.50 04/17/15 14:52 EPA 6020A Cobalt 0.63 ug/L 0.50 04/17/15 14:52 EPA 6020A Copper 3.2 ug/L 1.0 04/17/15 14:52 EPA 6020A Iron 277 ug/L 50.0 04/17/15 14:52 EPA 6020A Lead 0.80 ug/L 0.10 04/17/15 14:52 EPA 6020A Magnesium 341 ug/L 10.0 04/17/15 14:52 EPA 6020A Manganese 23.4 ug/L 0.50 04/17/15 14:52 EPA 6020A Molybdenum 2.4 ug/L 0.50 04/17/15 14:52 EPA 6020A Nickel 2.4 ug/L 0.50 04/17/15 14:52 EPA 6020A Potassium 913 ug/L 50.0 04/17/15 14:52 EPA 6020A Selenium 1.2 ug/L 0.50 04/17/15 14:52 EPA 6020A Sodium 1320 ug/L 50.0 04/17/15 14:52 EPA 6020A Strontium 90.1 ug/L 0.50 04/17/15 14:52 EPA 6020A Vanadium 24.6 ug/L 1.0 04/17/15 14:52 EPA 6020A Zinc 29.0 ug/L 5.0 04/17/15 14:52 92243393011 2015009009 SPLP EPA 6020A Barium 103 ug/L 0.30 04/17/15 15:15 EPA 6020A Boron 74.9 ug/L 5.0 04/17/15 15:15 EPA 6020A Calcium 1440 ug/L 40.0 04/17/15 15:15 EPA 6020A Magnesium 365 ug/L 10.0 04/17/15 15:15 EPA 6020A Manganese 9.2 ug/L 0.50 04/17/15 15:15 EPA 6020A Potassium 484 ug/L 50.0 04/17/15 15:15 EPA 6020A Selenium 2.4 ug/L 0.50 04/17/15 15:15 EPA 6020A Sodium 1770 ug/L 50.0 04/17/15 15:15 EPA 6020A Strontium 29.9 ug/L 0.50 04/17/15 15:15 EPA 6020A Zinc 24.4 ug/L 5.0 04/17/15 15:15 92243393012 2015009010 SPLP EPA 6020A Aluminum 28.5 ug/L 10.0 04/17/15 15:20 EPA 6020A Barium 119 ug/L 0.30 04/17/15 15:20 EPA 6020A Boron 63.6 ug/L 5.0 04/17/15 15:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92243393012 2015009010 SPLP EPA 6020A Calcium 1150 ug/L 40.0 04/17/15 15:20 EPA 6020A Magnesium 897 ug/L 10.0 04/17/15 15:20 EPA 6020A Manganese 41.9 ug/L 0.50 04/17/15 15:20 EPA 6020A Sodium 1530 ug/L 50.0 04/17/15 15:20 EPA 6020A Strontium 20.7 ug/L 0.50 04/17/15 15:20 EPA 6020A Zinc 11.5 ug/L 5.0 04/17/15 15:20 92243393013 2015009014 SPLP EPA 6020A Aluminum 780 ug/L 10.0 04/17/15 15:24 EPA 6020A Antimony 10.3 ug/L 0.50 04/17/15 15:24 EPA 6020A Arsenic 24.7 ug/L 0.50 04/17/15 15:24 EPA 6020A Barium 450 ug/L 1.5 04/20/15 12:17 EPA 6020A Beryllium 0.24 ug/L 0.20 04/17/15 15:24 EPA 6020A Boron 116 ug/L 5.0 04/17/15 15:24 EPA 6020A Cadmium 0.081 ug/L 0.080 04/17/15 15:24 EPA 6020A Calcium 4220 ug/L 40.0 04/17/15 15:24 EPA 6020A Chromium 18.2 ug/L 0.50 04/17/15 15:24 EPA 6020A Cobalt 8.1 ug/L 0.50 04/17/15 15:24 EPA 6020A Copper 11.8 ug/L 1.0 04/17/15 15:24 EPA 6020A Iron 404 ug/L 50.0 04/17/15 15:24 EPA 6020A Lead 25.3 ug/L 0.10 04/17/15 15:24 EPA 6020A Magnesium 458 ug/L 10.0 04/17/15 15:24 EPA 6020A Manganese 8.5 ug/L 0.50 04/17/15 15:24 EPA 6020A Molybdenum 10.4 ug/L 0.50 04/17/15 15:24 EPA 6020A Nickel 19.4 ug/L 0.50 04/17/15 15:24 EPA 6020A Potassium 2770 ug/L 50.0 04/17/15 15:24 EPA 6020A Selenium 5.4 ug/L 0.50 04/17/15 15:24 EPA 6020A Sodium 48700 ug/L 250 04/20/15 12:17 EPA 6020A Strontium 224 ug/L 0.50 04/17/15 15:24 EPA 6020A Thallium 0.22 ug/L 0.10 04/17/15 15:24 EPA 6020A Vanadium 25.2 ug/L 1.0 04/17/15 15:24 EPA 6020A Zinc 109 ug/L 5.0 04/17/15 15:24 92243393014 2015009015 SPLP EPA 6020A Aluminum 9210 ug/L 10.0 04/17/15 15:29 EPA 6020A Arsenic 5.9 ug/L 0.50 04/17/15 15:29 EPA 6020A Barium 1100 ug/L 1.5 04/20/15 12:26 EPA 6020A Beryllium 4.3 ug/L 0.20 04/17/15 15:29 EPA 6020A Boron 118 ug/L 5.0 04/17/15 15:29 EPA 6020A Calcium 7270 ug/L 40.0 04/17/15 15:29 EPA 6020A Chromium 10.4 ug/L 0.50 04/17/15 15:29 EPA 6020A Cobalt 30.2 ug/L 0.50 04/17/15 15:29 EPA 6020A Copper 45.6 ug/L 1.0 04/17/15 15:29 EPA 6020A Iron 10800 ug/L 50.0 04/17/15 15:29 EPA 6020A Lead 30.4 ug/L 0.50 04/20/15 12:26 EPA 6020A Magnesium 6870 ug/L 10.0 04/17/15 15:29 EPA 6020A Manganese 31.0 ug/L 0.50 04/17/15 15:29 EPA 6020A Nickel 23.9 ug/L 0.50 04/17/15 15:29 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PWIb fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92243393014 2015009015 SPLP EPA 6020A Potassium 545 ug/L 50.0 04/17/15 15:29 EPA 6020A Selenium 7.6 ug/L 0.50 04/17/15 15:29 EPA 6020A Sodium 4180 ug/L 50.0 04/17/15 15:29 EPA 6020A Strontium 245 ug/L 0.50 04/17/15 15:29 EPA 6020A Vanadium 37.9 ug/L 1.0 04/17/15 15:29 EPA 6020A Zinc 231 ug/L 5.0 04/17/15 15:29 EPA 7470 Mercury 0.20 ug/L 0.20 04/17/15 07:21 92243393015 2015009016 SPLP EPA 6020A Aluminum 15900 ug/L 10.0 04/17/15 15:34 EPA 6020A Arsenic 9.4 ug/L 0.50 04/17/15 15:34 EPA 6020A Barium 2090 ug/L 1.5 04/20/15 13:09 EPA 6020A Beryllium 5.4 ug/L 1.0 04/20/15 13:09 EPA 6020A Boron 138 ug/L 25.0 04/20/15 13:09 EPA 6020A Calcium 6630 ug/L 40.0 04/17/15 15:34 EPA 6020A Chromium 25.7 ug/L 0.50 04/17/15 15:34 EPA 6020A Cobalt 12.6 ug/L 0.50 04/17/15 15:34 EPA 6020A Copper 108 ug/L 1.0 04/17/15 15:34 EPA 6020A Iron 56100 ug/L 250 04/20/15 13:09 EPA 6020A Lead 102 ug/L 0.50 04/20/15 13:09 EPA 6020A Magnesium 5460 ug/L 10.0 04/17/15 15:34 EPA 6020A Manganese 16.8 ug/L 0.50 04/17/15 15:34 EPA 6020A Nickel 20.7 ug/L 0.50 04/17/15 15:34 EPA 6020A Potassium 729 ug/L 50.0 04/17/15 15:34 EPA 6020A Selenium 12.1 ug/L 0.50 04/17/15 15:34 EPA 6020A Sodium 5130 ug/L 50.0 04/17/15 15:34 EPA 6020A Strontium 235 ug/L 0.50 04/17/15 15:34 EPA 6020A Vanadium 182 ug/L 1.0 04/17/15 15:34 EPA 6020A Zinc 294 ug/L 5.0 04/17/15 15:34 EPA 7470 Mercury 0.47 ug/L 0.20 04/17/15 07:24 92243393016 2015009017 EPA 6020A Aluminum 13.1 ug/L 10.0 04/08/15 16:06 EPA 6020A Barium 0.54 ug/L 0.30 04/08/15 16:06 EPA 6020A Calcium 75.6 ug/L 40.0 04/08/15 16:06 EPA 6020A Chromium 6.6 ug/L 0.50 04/08/15 16:06 EPA 6020A Magnesium 19.0 ug/L 10.0 04/08/15 16:06 EPA 6020A Manganese 0.96 ug/L 0.50 04/08/15 16:06 EPA 6020A Nickel 4.2 ug/L 0.50 04/08/15 16:06 EPA 6020A Sodium 91.6 ug/L 50.0 04/08/15 16:06 EPA 6020A Strontium 0.53 ug/L 0.50 04/08/15 16:06 92243393017 2015009018 EPA 6020A Aluminum 26.7 ug/L 10.0 04/08/15 16:11 EPA 6020A Antimony 0.52 ug/L 0.50 04/08/15 16:11 EPA 6020A Barium 0.31 ug/L 0.30 04/08/15 16:11 EPA 6020A Calcium 78.8 ug/L 40.0 04/08/15 16:11 EPA 6020A Chromium 2.2 ug/L 0.50 04/08/15 16:11 EPA 6020A Magnesium 18.5 ug/L 10.0 04/08/15 16:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36gmirpYN.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030758 Pace Project No.: 92243393 Lab Sample ID Method 92243393017 EPA 6020A EPA 6020A EPA 6020A 92243393018 EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A Client Sample ID Parameters 2015009018 Manganese Nickel Sodium 2015009019 Barium Calcium Chromium Iron Magnesium Manganese Nickel Sodium Strontium Zinc SUMMARY OF DETECTION Result UnitE 1.1 ug/L 1.8 ug/L 65.3 ug/L 0.82 ug/L 332 ug/L 5.2 ug/L 125 ug/L 38.2 ug/L 3.4 ug/L 7.7 ug/L 179 ug/L 0.87 ug/L 6.8 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 0.50 04/08/1516:11 0.50 04/08/1516:11 50.0 04/08/1516:11 0.30 04/08/1516:16 40.0 04/08/1516:16 0.50 04/08/1516:16 50.0 04/08/1516:16 10.0 04/08/1516:16 0.50 04/08/1516:16 0.50 04/08/1516:16 50.0 04/08/1516:16 0.50 04/08/1516:16 5.0 04/08/1516:16 Page 16 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW1*r6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23429 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242920018 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1174971) • Aluminum • Barium • Chromium • Copper • Iron • Manganese • Strontium • MSD (Lab ID: 1174972) • Aluminum • Barium • Iron • Magnesium • Manganese • Potassium • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36911rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 QC Batch: MPRP/23429 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242920018 R1: RPD value was outside control limits. • MSD (Lab ID: 1174972) • Barium • Beryllium • Potassium • Strontium QC Batch: MPRP/23485 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243393007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1176764) • Aluminum • Iron • MSD (Lab ID: 1176765) • Aluminum • Iron Additional Comments: Analyte Comments: QC Batch: MPRP/23485 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009011 (Lab ID:92243393007) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015009012 (Lab ID:92243393008) • Aluminum • Boron • Barium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROAirWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: MPRP/23485 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009012 (Lab ID:92243393008) • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015009013 (Lab ID:92243393009) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • MS (Lab ID: 1176764) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARIArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: MPRP/23485 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MS (Lab ID: 1176764) • Molybdenum • Sodium • Nickel • Strontium • Zinc • MSD (Lab ID: 1176765) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1176762) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23430 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242920019 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1174975) • Antimony • Arsenic • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1174976) • Antimony • Arsenic • Selenium • Thallium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. POQ WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 QC Batch: MPRP/23486 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243393008 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1176768) • Antimony • Vanadium • MSD (Lab ID: 1176769) • Antimony • Lead • Selenium • Vanadium Additional Comments: Analyte Comments: QC Batch: MPRP/23430 N2: The lab does not hold TNI accreditation for this parameter. •2015009008 (Lab ID:92243393001) • Antimony •2015009009 (Lab ID:92243393002) • Antimony •2015009010 (Lab ID:92243393003) • Antimony •2015009014 (Lab ID:92243393004) • Antimony •2015009015 (Lab ID:92243393005) • Antimony •2015009016 (Lab ID:92243393006) • Antimony • BLANK (Lab ID: 1174973) • Antimony • LCS (Lab ID: 1174974) • Antimony • MS (Lab ID: 1174975) • Antimony • MSD (Lab ID: 1174976) • Antimony QC Batch: MPRP/23486 N2: The lab does not hold TNI accreditation for this parameter. •2015009011 (Lab ID:92243393007) • Antimony •2015009012 (Lab ID:92243393008) • Antimony •2015009013 (Lab ID:92243393009) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARGArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: MPRP/23486 N2: The lab does not hold TNI accreditation for this parameter. • BLANK (Lab ID: 1176766) • Antimony • LCS (Lab ID: 1176767) • Antimony • MS (Lab ID: 1176768) • Antimony • MSD (Lab ID: 1176769) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARIArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53405 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10301430001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1932878) • Calcium • Magnesium • Manganese • Sodium • MSD (Lab ID: 1932879) • Aluminum • Calcium • Magnesium • Manganese • Potassium • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904!8r6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 27, 2015 QC Batch: MPRP/53629 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245086001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1939444) • Aluminum • MSD (Lab ID: 1939445) • Aluminum Additional Comments: Analyte Comments: QC Batch: MPRP/53405 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1932878) • Calcium • MSD (Lab ID: 1932879) • Calcium QC Batch: MPRP/53629 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • 2015009015 SPLP (Lab ID: 92243393014) • Thallium • 2015009016 SPLP (Lab ID: 92243393015) • Thallium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904irWYN" Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904K W%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5566 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243393005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1178140) • Mercury • MSD (Lab ID: 1178141) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904WeY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/36610 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1426089) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904r6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: April 27, 2015 General Information: 6 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22495 B: Analyte was detected in the associated method blank. • BLANK for HBN 258853 [WETA/224 (Lab ID: 1430392) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690AW%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 27, 2015 General Information: 6 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015009008 (Lab ID:92243393001) •2015009009 (Lab ID:92243393002) •2015009010 (Lab ID:92243393003) •2015009014 (Lab ID:92243393004) •2015009015 (Lab ID:92243393005) •2015009016 (Lab ID:92243393006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369041 WeY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: April 27, 2015 General Information: 6 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/22491 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243096002,92243393001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1430200) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904f WeYNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45120 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009008 (Lab ID:92243393001) • Chloride • Sulfate •2015009009 (Lab ID:92243393002) • Chloride • Sulfate •2015009010 (Lab ID:92243393003) • Chloride • Sulfate •2015009014 (Lab ID:92243393004) • Chloride • Sulfate QC Batch: WETA/45122 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009011 (Lab ID:92243393007) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904 W%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: WETA/45122 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009012 (Lab ID:92243393008) • Chloride • Sulfate •2015009013 (Lab ID:92243393009) • Chloride • Sulfate •2015009015 (Lab ID:92243393005) • Chloride • Sulfate •2015009016 (Lab ID:92243393006) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36904f WeY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015009008 (Lab ID:92243393001) •2015009009 (Lab ID:92243393002) •2015009010 (Lab ID:92243393003) •2015009011 (Lab ID:92243393007) •2015009012 (Lab ID:92243393008) •2015009013 (Lab ID:92243393009) •2015009014 (Lab ID:92243393004) •2015009015 (Lab ID:92243393005) •2015009016 (Lab ID:92243393006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PO05k WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030758 Pace Project No.: 92243393 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 27, 2015 General Information: 9 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PggcO )irpyN.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009008 Lab ID: 92243393001 Collected: 03/28/15 09:30 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/27/2015 03:25 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 11100 mg/kg 49.1 24.6 5 04/04/15 18:37 04/09/15 08:12 7429-90-5 548 mg/kg 4.9 2.5 5 04/04/15 18:37 04/09/15 08:12 7440-39-3 3.9 mg/kg 0.49 0.25 5 04/04/15 18:37 04/09/15 08:12 7440-41-7 12.5J mg/kg 24.6 12.3 5 04/04/15 18:37 04/09/15 08:12 7440-42-8 3690 mg/kg 246 123 5 04/04/15 18:37 04/09/15 08:12 7440-70-2 22.8 mg/kg 2.5 1.2 5 04/04/15 18:37 04/09/15 08:12 7440-47-3 43.9 mg/kg 2.5 1.2 5 04/04/15 18:37 04/09/15 08:12 7440-50-8 6450 mg/kg 19.7 9.8 5 04/04/15 18:37 04/09/15 08:12 7439-89-6 818 mg/kg 246 123 5 04/04/15 18:37 04/09/15 08:12 7439-95-4 97.5 mg/kg 2.5 1.2 5 04/04/15 18:37 04/09/15 08:12 7439-96-5 ND mg/kg 4.9 2.5 5 04/04/15 18:37 04/09/15 08:12 7439-98-7 18.4 mg/kg 2.5 1.2 5 04/04/15 18:37 04/09/15 08:12 7440-02-0 1010 mg/kg 491 246 5 04/04/15 18:37 04/09/15 08:12 7440-09-7 ND mg/kg 491 246 5 04/04/15 18:37 04/09/15 08:12 7440-23-5 340 mg/kg 4.9 2.5 5 04/04/15 18:37 04/09/15 08:12 7440-24-6 13.1 mg/kg 9.8 4.9 5 04/04/15 18:37 04/09/15 08:12 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 4.9 2.5 50 04/04/15 18:37 04/07/1513:33 7440-36-0 25.8 mg/kg 4.9 2.5 50 04/04/15 18:37 04/07/1513:33 7440-38-2 ND mg/kg 0.59 0.29 50 04/04/15 18:37 04/07/1513:33 7440-43-9 10.0 mg/kg 4.9 2.5 50 04/04/15 18:37 04/07/1513:33 7440-48-4 15.0 mg/kg 4.9 2.5 50 04/04/15 18:37 04/07/1513:33 7439-92-1 ND mg/kg 4.9 2.5 50 04/04/15 18:37 04/07/1513:33 7782-49-2 ND mg/kg 4.9 2.5 50 04/04/15 18:37 04/07/1513:33 7440-28-0 55.5 mg/kg 4.9 2.5 50 04/04/15 18:37 04/07/1513:33 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.088 mg/kg 0.015 0.0076 1 04/08/15 20:18 04/09/15 09:45 7439-97-6 Analytical Method: ASTM D2974-87 47.2 % 0.10 0.10 1 04/09/1514:36 Analytical Method: EPA 9045 6.2 Std. Units 0.10 0.10 1 04/07/15 14:15 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30 11.3 mg/L 3.8 1.9 1 04/09/15 20:19 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30 0.44 mg/L 0.38 0.38 1 04/09/15 20:09 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30 ND mg/L 9.5 4.7 1 04/09/15 05:05 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PO05kf WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009008 Lab ID: 92243393001 Collected: 03/28/15 09:30 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 468 234 5 04/05/15 01:09 16887-00-6 D3 Sulfate ND mg/kg 468 234 5 04/05/15 01:09 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 46.8 23.4 5 04/05/15 01:09 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 141000 mg/kg 10900 5460 1 04/17/15 11:51 7440-44-0 Total Organic Carbon 104000 mg/kg 10800 5420 1 04/17/15 11:58 7440-44-0 Total Organic Carbon 109000 mg/kg 10500 5260 1 04/17/15 12:04 7440-44-0 Total Organic Carbon 93200 mg/kg 10900 5470 1 04/17/15 12:14 7440-44-0 Mean Total Organic Carbon 112000 mg/kg 10800 5400 1 04/17/15 11:51 7440-44-0 Surrogates RSD% 18.3 % 1 04/17/15 11:51 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PO05kf WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009009 Lab ID: 92243393002 Collected: 03/28/15 10:26 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/27/2015 03:25 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 11000 mg/kg 30.7 15.4 5 04/04/15 18:37 04/09/15 08:16 7429-90-5 38.0 mg/kg 3.1 1.5 5 04/04/15 18:37 04/09/15 08:16 7440-39-3 0.53 mg/kg 0.31 0.15 5 04/04/15 18:37 04/09/15 08:16 7440-41-7 19.7 mg/kg 15.4 7.7 5 04/04/15 18:37 04/09/15 08:16 7440-42-8 698 mg/kg 154 76.8 5 04/04/15 18:37 04/09/15 08:16 7440-70-2 14.9 mg/kg 1.5 0.77 5 04/04/15 18:37 04/09/15 08:16 7440-47-3 10.3 mg/kg 1.5 0.77 5 04/04/15 18:37 04/09/15 08:16 7440-50-8 16700 mg/kg 12.3 6.1 5 04/04/15 18:37 04/09/15 08:16 7439-89-6 1400 mg/kg 154 76.8 5 04/04/15 18:37 04/09/15 08:16 7439-95-4 61.6 mg/kg 1.5 0.77 5 04/04/15 18:37 04/09/15 08:16 7439-96-5 ND mg/kg 3.1 1.5 5 04/04/15 18:37 04/09/15 08:16 7439-98-7 5.0 mg/kg 1.5 0.77 5 04/04/15 18:37 04/09/15 08:16 7440-02-0 462 mg/kg 307 154 5 04/04/15 18:37 04/09/15 08:16 7440-09-7 ND mg/kg 307 154 5 04/04/15 18:37 04/09/15 08:16 7440-23-5 17.0 mg/kg 3.1 1.5 5 04/04/15 18:37 04/09/15 08:16 7440-24-6 20.6 mg/kg 6.1 3.1 5 04/04/15 18:37 04/09/15 08:16 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.1 1.5 50 04/04/15 18:37 04/07/1513:35 7440-36-0 1.91 mg/kg 3.1 1.5 50 04/04/15 18:37 04/07/1513:35 7440-38-2 ND mg/kg 0.37 0.18 50 04/04/15 18:37 04/07/1513:35 7440-43-9 3.8 mg/kg 3.1 1.5 50 04/04/15 18:37 04/07/1513:35 7440-48-4 9.0 mg/kg 3.1 1.5 50 04/04/15 18:37 04/07/1513:35 7439-92-1 ND mg/kg 3.1 1.5 50 04/04/15 18:37 04/07/1513:35 7782-49-2 ND mg/kg 3.1 1.5 50 04/04/15 18:37 04/07/1513:35 7440-28-0 36.0 mg/kg 3.1 1.5 50 04/04/15 18:37 04/07/1513:35 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.037 mg/kg 0.0096 0.0048 1 04/08/15 20:18 04/09/15 09:47 7439-97-6 Analytical Method: ASTM D2974-87 18.8 % 0.10 0.10 1 04/09/1514:37 Analytical Method: EPA 9045 5.3 Std. Units 0.10 0.10 1 04/07/15 14:15 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30 9.4 mg/L 2.5 1.2 1 04/09/15 21:00 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30 ND mg/L 0.25 0.25 1 04/09/15 20:14 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30 ND mg/L 6.2 3.1 1 04/09/15 05:09 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAMIirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009009 Lab ID: 92243393002 Collected: 03/28/15 10:26 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 306 153 5 04/05/15 01:31 16887-00-6 D3 Sulfate 169J mg/kg 306 153 5 04/05/15 01:31 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.6 15.3 5 04/05/15 01:31 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1280 mg/kg 737 368 1 04/17/15 12:20 7440-44-0 Total Organic Carbon 1960 mg/kg 743 372 1 04/17/15 12:26 7440-44-0 Total Organic Carbon 1250 mg/kg 739 370 1 04/17/15 12:31 7440-44-0 Total Organic Carbon 1180 mg/kg 745 372 1 04/17/15 12:37 7440-44-0 Mean Total Organic Carbon 1420 mg/kg 741 371 1 04/17/15 12:20 7440-44-0 Surrogates RSD% 25.6 % 1 04/17/15 12:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROAlWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009010 Lab ID: 92243393003 Collected: 03/28/15 10:57 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/27/2015 03:25 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 7710 mg/kg 32.2 16.1 5 04/04/15 18:37 04/09/15 08:20 7429-90-5 49.3 mg/kg 3.2 1.6 5 04/04/15 18:37 04/09/15 08:20 7440-39-3 0.62 mg/kg 0.32 0.16 5 04/04/15 18:37 04/09/15 08:20 7440-41-7 14AJ mg/kg 16.1 8.0 5 04/04/15 18:37 04/09/15 08:20 7440-42-8 737 mg/kg 161 80.5 5 04/04/15 18:37 04/09/15 08:20 7440-70-2 10.2 mg/kg 1.6 0.80 5 04/04/15 18:37 04/09/15 08:20 7440-47-3 9.2 mg/kg 1.6 0.80 5 04/04/15 18:37 04/09/15 08:20 7440-50-8 13100 mg/kg 12.9 6.4 5 04/04/15 18:37 04/09/15 08:20 7439-89-6 1620 mg/kg 161 80.5 5 04/04/15 18:37 04/09/15 08:20 7439-95-4 150 mg/kg 1.6 0.80 5 04/04/15 18:37 04/09/15 08:20 7439-96-5 ND mg/kg 3.2 1.6 5 04/04/15 18:37 04/09/15 08:20 7439-98-7 5.4 mg/kg 1.6 0.80 5 04/04/15 18:37 04/09/15 08:20 7440-02-0 438 mg/kg 322 161 5 04/04/15 18:37 04/09/15 08:20 7440-09-7 ND mg/kg 322 161 5 04/04/15 18:37 04/09/15 08:20 7440-23-5 23.0 mg/kg 3.2 1.6 5 04/04/15 18:37 04/09/15 08:20 7440-24-6 18.2 mg/kg 6.4 3.2 5 04/04/15 18:37 04/09/15 08:20 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.2 1.6 50 04/04/15 18:37 04/07/1513:38 7440-36-0 2.8J mg/kg 3.2 1.6 50 04/04/15 18:37 04/07/1513:38 7440-38-2 ND mg/kg 0.39 0.19 50 04/04/15 18:37 04/07/1513:38 7440-43-9 6.8 mg/kg 3.2 1.6 50 04/04/15 18:37 04/07/1513:38 7440-48-4 7.1 mg/kg 3.2 1.6 50 04/04/15 18:37 04/07/1513:38 7439-92-1 ND mg/kg 3.2 1.6 50 04/04/15 18:37 04/07/1513:38 7782-49-2 ND mg/kg 3.2 1.6 50 04/04/15 18:37 04/07/1513:38 7440-28-0 29.4 mg/kg 3.2 1.6 50 04/04/15 18:37 04/07/1513:38 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.0076J mg/kg 0.010 0.0050 1 04/08/15 20:18 04/09/15 09:49 7439-97-6 Analytical Method: ASTM D2974-87 19.5 % 0.10 0.10 1 04/09/1514:38 Analytical Method: EPA 9045 6.7 Std. Units 0.10 0.10 1 04/07/15 14:15 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30 6.2 mg/L 2.5 1.2 1 04/09/15 21:14 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30 0.29 mg/L 0.25 0.25 1 04/09/15 20:15 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30 ND mg/L 6.2 3.1 1 04/09/15 05:09 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 40 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009010 Lab ID: 92243393003 Collected: 03/28/15 10:57 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 308 154 5 04/05/15 01:52 16887-00-6 D3 Sulfate ND mg/kg 308 154 5 04/05/15 01:52 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.8 15.4 5 04/05/15 01:52 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1180 mg/kg 750 375 1 04/17/15 12:43 7440-44-0 Total Organic Carbon 908 mg/kg 748 374 1 04/17/15 12:48 7440-44-0 Total Organic Carbon 1020 mg/kg 743 372 1 04/17/15 12:54 7440-44-0 Total Organic Carbon 1350 mg/kg 745 373 1 04/17/15 12:59 7440-44-0 Mean Total Organic Carbon 1110 mg/kg 747 373 1 04/17/15 12:43 7440-44-0 Surrogates RSD% 17.3 % 1 04/17/15 12:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690*rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009014 Lab ID: 92243393004 Collected: 03/29/15 08:45 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/27/2015 03:25 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 12600 mg/kg 38.8 19.4 5 04/04/15 18:37 04/09/15 08:25 7429-90-5 631 mg/kg 3.9 1.9 5 04/04/15 18:37 04/09/15 08:25 7440-39-3 3.0 mg/kg 0.39 0.19 5 04/04/15 18:37 04/09/15 08:25 7440-41-7 21.1 mg/kg 19.4 9.7 5 04/04/15 18:37 04/09/15 08:25 7440-42-8 1620 mg/kg 194 97.1 5 04/04/15 18:37 04/09/15 08:25 7440-70-2 19.9 mg/kg 1.9 0.97 5 04/04/15 18:37 04/09/15 08:25 7440-47-3 31.4 mg/kg 1.9 0.97 5 04/04/15 18:37 04/09/15 08:25 7440-50-8 7550 mg/kg 15.5 7.8 5 04/04/15 18:37 04/09/15 08:25 7439-89-6 951 mg/kg 194 97.1 5 04/04/15 18:37 04/09/15 08:25 7439-95-4 53.0 mg/kg 1.9 0.97 5 04/04/15 18:37 04/09/15 08:25 7439-96-5 ND mg/kg 3.9 1.9 5 04/04/15 18:37 04/09/15 08:25 7439-98-7 14.3 mg/kg 1.9 0.97 5 04/04/15 18:37 04/09/15 08:25 7440-02-0 2240 mg/kg 388 194 5 04/04/15 18:37 04/09/15 08:25 7440-09-7 203J mg/kg 388 194 5 04/04/15 18:37 04/09/15 08:25 7440-23-5 170 mg/kg 3.9 1.9 5 04/04/15 18:37 04/09/15 08:25 7440-24-6 21.4 mg/kg 7.8 3.9 5 04/04/15 18:37 04/09/15 08:25 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.9 1.9 50 04/04/15 18:37 04/07/1513:40 7440-36-0 76.3 mg/kg 3.9 1.9 50 04/04/15 18:37 04/07/1513:40 7440-38-2 ND mg/kg 0.47 0.23 50 04/04/15 18:37 04/07/1513:40 7440-43-9 8.4 mg/kg 3.9 1.9 50 04/04/15 18:37 04/07/1513:40 7440-48-4 14.3 mg/kg 3.9 1.9 50 04/04/15 18:37 04/07/1513:40 7439-92-1 6.6 mg/kg 3.9 1.9 50 04/04/15 18:37 04/07/1513:40 7782-49-2 ND mg/kg 3.9 1.9 50 04/04/15 18:37 04/07/1513:40 7440-28-0 50.2 mg/kg 3.9 1.9 50 04/04/15 18:37 04/07/1513:40 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.20 mg/kg 0.012 0.0060 1 04/08/15 20:18 04/09/15 09:51 7439-97-6 Analytical Method: ASTM D2974-87 35.1 % 0.10 0.10 1 04/09/1514:39 Analytical Method: EPA 9045 6.1 Std. Units 0.10 0.10 1 04/07/15 14:15 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30 21.6 mg/L 3.1 1.5 1 04/09/15 21:27 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30 ND mg/L 0.31 0.31 1 04/09/15 20:16 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30 4.7J mg/L 7.7 3.9 1 04/09/15 05:10 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROAirWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009014 Lab ID: 92243393004 Collected: 03/29/15 08:45 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 386 193 5 04/05/15 03:13 16887-00-6 D3 Sulfate ND mg/kg 386 193 5 04/05/15 03:13 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 38.6 19.3 5 04/05/15 03:13 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 36900 mg/kg 8200 4100 1 04/17/15 13:06 7440-44-0 Total Organic Carbon 40300 mg/kg 8720 4360 1 04/17/15 13:12 7440-44-0 Total Organic Carbon 55300 mg/kg 8690 4340 1 04/17/15 13:18 7440-44-0 Total Organic Carbon 53600 mg/kg 8390 4190 1 04/17/15 13:25 7440-44-0 Mean Total Organic Carbon 46500 mg/kg 8500 4250 1 04/17/15 13:06 7440-44-0 Surrogates RSD% 19.9 % 1 04/17/15 13:06 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009015 Lab ID: 92243393005 Collected: 03/29/15 10:41 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/27/2015 03:25 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 9210 mg/kg 29.6 14.8 5 04/04/15 18:37 04/09/15 08:42 7429-90-5 83.8 mg/kg 3.0 1.5 5 04/04/15 18:37 04/09/15 08:42 7440-39-3 0.74 mg/kg 0.30 0.15 5 04/04/15 18:37 04/09/15 08:42 7440-41-7 ND mg/kg 14.8 7.4 5 04/04/15 18:37 04/09/15 08:42 7440-42-8 692 mg/kg 148 74.0 5 04/04/15 18:37 04/09/15 08:42 7440-70-2 13.1 mg/kg 1.5 0.74 5 04/04/15 18:37 04/09/15 08:42 7440-47-3 12.6 mg/kg 1.5 0.74 5 04/04/15 18:37 04/09/15 08:42 7440-50-8 6760 mg/kg 11.8 5.9 5 04/04/15 18:37 04/09/15 08:42 7439-89-6 883 mg/kg 148 74.0 5 04/04/15 18:37 04/09/15 08:42 7439-95-4 15.9 mg/kg 1.5 0.74 5 04/04/15 18:37 04/09/15 08:42 7439-96-5 ND mg/kg 3.0 1.5 5 04/04/15 18:37 04/09/15 08:42 7439-98-7 4.4 mg/kg 1.5 0.74 5 04/04/15 18:37 04/09/15 08:42 7440-02-0 154J mg/kg 296 148 5 04/04/15 18:37 04/09/15 08:42 7440-09-7 ND mg/kg 296 148 5 04/04/15 18:37 04/09/15 08:42 7440-23-5 22.9 mg/kg 3.0 1.5 5 04/04/15 18:37 04/09/15 08:42 7440-24-6 12.2 mg/kg 5.9 3.0 5 04/04/15 18:37 04/09/15 08:42 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.0 1.5 50 04/04/15 18:37 04/07/1513:43 7440-36-0 N2 2.3J mg/kg 3.0 1.5 50 04/04/15 18:37 04/07/1513:43 7440-38-2 ND mg/kg 0.36 0.18 50 04/04/15 18:37 04/07/1513:43 7440-43-9 4.2 mg/kg 3.0 1.5 50 04/04/15 18:37 04/07/1513:43 7440-48-4 7.5 mg/kg 3.0 1.5 50 04/04/15 18:37 04/07/1513:43 7439-92-1 ND mg/kg 3.0 1.5 50 04/04/15 18:37 04/07/1513:43 7782-49-2 ND mg/kg 3.0 1.5 50 04/04/15 18:37 04/07/1513:43 7440-28-0 43.7 mg/kg 3.0 1.5 50 04/04/15 18:37 04/07/1513:43 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.028 mg/kg 0.0095 0.0047 1 04/08/15 20:18 04/09/15 10:17 7439-97-6 M1 Analytical Method: ASTM D2974-87 17.1 % 0.10 0.10 1 04/09/1514:39 Analytical Method: EPA 9045 5.4 Std. Units 0.10 0.10 1 181108 /f61SEER Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30 5.7 mg/L 2.4 1.2 1 04/09/15 22:08 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30 ND mg/L 0.24 0.24 1 04/09/15 20:17 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30 11.5 mg/L 6.0 3.0 1 04/09/15 05:11 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 44 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369%1bir6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009015 Lab ID: 92243393005 Collected: 03/29/15 10:41 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 1200 598 20 04/05/15 04:18 16887-00-6 D3,M6 Sulfate ND mg/kg 1200 598 20 04/05/15 04:18 14808-79-8 D3,M6 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 120 59.8 20 04/05/15 04:18 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1440 mg/kg 721 360 1 04/17/15 13:32 7440-44-0 Total Organic Carbon 2080 mg/kg 724 362 1 04/17/15 13:37 7440-44-0 Total Organic Carbon 2470 mg/kg 719 360 1 04/17/15 13:43 7440-44-0 Total Organic Carbon 1340 mg/kg 723 362 1 04/17/15 13:49 7440-44-0 Mean Total Organic Carbon 1830 mg/kg 722 361 1 04/17/15 13:32 7440-44-0 Surrogates RSD% 29.2 % 1 04/17/15 13:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PggmirpYN.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009016 Lab ID: 92243393006 Collected: 03/29/15 10:21 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/27/2015 03:25 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 10700 mg/kg 32.7 16.4 5 04/04/15 18:37 04/09/15 08:46 7429-90-5 94.7 mg/kg 3.3 1.6 5 04/04/15 18:37 04/09/15 08:46 7440-39-3 0.55 mg/kg 0.33 0.16 5 04/04/15 18:37 04/09/15 08:46 7440-41-7 25.2 mg/kg 16.4 8.2 5 04/04/15 18:37 04/09/15 08:46 7440-42-8 589 mg/kg 164 81.9 5 04/04/15 18:37 04/09/15 08:46 7440-70-2 12.9 mg/kg 1.6 0.82 5 04/04/15 18:37 04/09/15 08:46 7440-47-3 12.6 mg/kg 1.6 0.82 5 04/04/15 18:37 04/09/15 08:46 7440-50-8 23700 mg/kg 13.1 6.5 5 04/04/15 18:37 04/09/15 08:46 7439-89-6 657 mg/kg 164 81.9 5 04/04/15 18:37 04/09/15 08:46 7439-95-4 16.4 mg/kg 1.6 0.82 5 04/04/15 18:37 04/09/15 08:46 7439-96-5 ND mg/kg 3.3 1.6 5 04/04/15 18:37 04/09/15 08:46 7439-98-7 3.3 mg/kg 1.6 0.82 5 04/04/15 18:37 04/09/15 08:46 7440-02-0 ND mg/kg 327 164 5 04/04/15 18:37 04/09/15 08:46 7440-09-7 ND mg/kg 327 164 5 04/04/15 18:37 04/09/15 08:46 7440-23-5 13.6 mg/kg 3.3 1.6 5 04/04/15 18:37 04/09/15 08:46 7440-24-6 12.4 mg/kg 6.5 3.3 5 04/04/15 18:37 04/09/15 08:46 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.3 1.6 50 04/04/15 18:37 04/07/1513:45 7440-36-0 ND mg/kg 3.3 1.6 50 04/04/15 18:37 04/07/1513:45 7440-38-2 ND mg/kg 0.39 0.20 50 04/04/15 18:37 04/07/1513:45 7440-43-9 2.7J mg/kg 3.3 1.6 50 04/04/15 18:37 04/07/1513:45 7440-48-4 12.1 mg/kg 3.3 1.6 50 04/04/15 18:37 04/07/1513:45 7439-92-1 ND mg/kg 3.3 1.6 50 04/04/15 18:37 04/07/1513:45 7782-49-2 ND mg/kg 3.3 1.6 50 04/04/15 18:37 04/07/1513:45 7440-28-0 41.7 mg/kg 3.3 1.6 50 04/04/15 18:37 04/07/1513:45 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.043 mg/kg 0.010 0.0051 1 04/08/15 20:18 04/09/15 10:23 7439-97-6 Analytical Method: ASTM D2974-87 23.4 % 0.10 0.10 1 04/09/1514:39 Analytical Method: EPA 9045 6.1 Std. Units 0.10 0.10 1 04/07/15 14:15 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30 12.3 mg/L 2.6 1.3 1 04/09/15 22:22 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30 0.28 mg/L 0.26 0.26 1 04/09/15 20:18 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30 7.6 mg/L 6.5 3.3 1 04/09/15 05:11 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 46 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P�S�06Jf WyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009016 Lab ID: 92243393006 Collected: 03/29/15 10:21 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 1280 642 20 04/05/15 05:22 16887-00-6 D3 Sulfate ND mg/kg 1280 642 20 04/05/15 05:22 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 128 64.2 20 04/05/15 05:22 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 4720 mg/kg 785 392 1 04/17/15 14:07 7440-44-0 Total Organic Carbon 4840 mg/kg 780 390 1 04/17/15 14:12 7440-44-0 Total Organic Carbon 4700 mg/kg 780 390 1 04/17/15 14:18 7440-44-0 Total Organic Carbon 4330 mg/kg 779 389 1 04/17/15 14:25 7440-44-0 Mean Total Organic Carbon 4650 mg/kg 781 390 1 04/17/15 14:07 7440-44-0 Surrogates RSD% 4.7 % 1 04/17/15 14:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW%1Sr6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009011 Lab ID: 92243393007 Collected: 03/25/15 12:55 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 1270 mg/kg 32.2 16.1 5 04/09/15 05:30 04/11/15 21:25 7429-90-5 D3,M1 Barium 6.8 mg/kg 3.2 1.6 5 04/09/15 05:30 04/11/15 21:25 7440-39-3 D3 Beryllium ND mg/kg 0.32 0.16 5 04/09/15 05:30 04/11/15 21:25 7440-41-7 D3 Boron ND mg/kg 16.1 8.0 5 04/09/15 05:30 04/11/15 21:25 7440-42-8 D3 Calcium ND mg/kg 161 80.4 5 04/09/15 05:30 04/11/15 21:25 7440-70-2 D3 Chromium 2.4 mg/kg 1.6 0.80 5 04/09/15 05:30 04/11/15 21:25 7440-47-3 D3 Copper 1.6 mg/kg 1.6 0.80 5 04/09/15 05:30 04/11/15 21:25 7440-50-8 D3 Iron 829 mg/kg 12.9 6.4 5 04/09/15 05:30 04/11/15 21:25 7439-89-6 D3,M1 Magnesium ND mg/kg 161 80.4 5 04/09/15 05:30 04/11/15 21:25 7439-95-4 D3 Manganese 5.0 mg/kg 1.6 0.80 5 04/09/15 05:30 04/11/15 21:25 7439-96-5 D3 Molybdenum ND mg/kg 3.2 1.6 5 04/09/15 05:30 04/11/15 21:25 7439-98-7 D3 Nickel 1.0J mg/kg 1.6 0.80 5 04/09/15 05:30 04/11/15 21:25 7440-02-0 D3 Potassium ND mg/kg 322 161 5 04/09/15 05:30 04/11/15 21:25 7440-09-7 D3 Sodium ND mg/kg 322 161 5 04/09/15 05:30 04/11/15 21:25 7440-23-5 D3 Strontium ND mg/kg 3.2 1.6 5 04/09/15 05:30 04/11/15 21:25 7440-24-6 D3 Zinc 3.5J mg/kg 6.4 3.2 5 04/09/15 05:30 04/11/15 21:25 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:32 7440-36-0 N2 Arsenic ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:32 7440-38-2 Cadmium ND mg/kg 0.39 0.19 50 04/09/15 05:30 04/10/15 14:32 7440-43-9 Cobalt ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:32 7440-48-4 Lead ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:32 7439-92-1 Selenium ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:32 7782-49-2 Thallium ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:32 7440-28-0 Vanadium 4.2 mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:32 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.011 0.0054 1 04/08/15 20:18 04/09/15 10:32 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 22.8 % 0.10 0.10 1 04/09/15 14:40 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.1 Std. Units 0.10 0.10 1 04/06/15 13:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 319 159 5 04/05/15 05:43 16887-00-6 D3 Sulfate ND mg/kg 319 159 5 04/05/15 05:43 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.9 15.9 5 04/05/15 05:43 14797-55-8 H3 Date: 04/27/2015 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 48 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369%1�irwy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009011 Lab ID: 92243393007 Collected: 03/25/15 12:55 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 493J mg/kg 780 390 1 04/17/15 14:31 7440-44-0 Total Organic Carbon 479J mg/kg 769 385 1 04/17/15 14:36 7440-44-0 Total Organic Carbon 471J mg/kg 772 386 1 04/17/15 14:41 7440-44-0 Total Organic Carbon 531J mg/kg 770 385 1 04/17/15 14:48 7440-44-0 Mean Total Organic Carbon 493J mg/kg 773 386 1 04/17/15 14:31 7440-44-0 Surrogates RSD% 5.4 % 1 04/17/15 14:31 Date: 04/27/2015 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 49 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAR18rWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009012 Lab ID: 92243393008 Collected: 03/25/15 10:36 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 5170 mg/kg 31.5 15.8 5 04/09/15 05:30 04/11/15 21:37 7429-90-5 D3 Barium 17.0 mg/kg 3.2 1.6 5 04/09/15 05:30 04/11/15 21:37 7440-39-3 D3 Beryllium 0.191 mg/kg 0.32 0.16 5 04/09/15 05:30 04/11/15 21:37 7440-41-7 D3 Boron ND mg/kg 15.8 7.9 5 04/09/15 05:30 04/11/15 21:37 7440-42-8 D3 Calcium ND mg/kg 158 78.9 5 04/09/15 05:30 04/11/15 21:37 7440-70-2 D3 Chromium 5.6 mg/kg 1.6 0.79 5 04/09/15 05:30 04/11/15 21:37 7440-47-3 D3 Copper 3.2 mg/kg 1.6 0.79 5 04/09/15 05:30 04/11/15 21:37 7440-50-8 D3 Iron 5150 mg/kg 12.6 6.3 5 04/09/15 05:30 04/11/15 21:37 7439-89-6 D3 Magnesium 262 mg/kg 158 78.9 5 04/09/15 05:30 04/11/15 21:37 7439-95-4 D3 Manganese 11.7 mg/kg 1.6 0.79 5 04/09/15 05:30 04/11/15 21:37 7439-96-5 D3 Molybdenum ND mg/kg 3.2 1.6 5 04/09/15 05:30 04/11/15 21:37 7439-98-7 D3 Nickel 1.0J mg/kg 1.6 0.79 5 04/09/15 05:30 04/11/15 21:37 7440-02-0 D3 Potassium ND mg/kg 315 158 5 04/09/15 05:30 04/11/15 21:37 7440-09-7 D3 Sodium ND mg/kg 315 158 5 04/09/15 05:30 04/11/15 21:37 7440-23-5 D3 Strontium ND mg/kg 3.2 1.6 5 04/09/15 05:30 04/11/15 21:37 7440-24-6 D3 Zinc 6.8 mg/kg 6.3 3.2 5 04/09/15 05:30 04/11/15 21:37 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:41 7440-36-0 M6,N2 Arsenic ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:41 7440-38-2 Cadmium ND mg/kg 0.39 0.19 50 04/09/15 05:30 04/10/15 14:41 7440-43-9 Cobalt ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:41 7440-48-4 Lead 5.5 mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:41 7439-92-1 M6 Selenium ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:41 7782-49-2 M6 Thallium ND mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:41 7440-28-0 Vanadium 16.1 mg/kg 3.2 1.6 50 04/09/15 05:30 04/10/15 14:41 7440-62-2 M6 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0087J mg/kg 0.010 0.0051 1 04/08/15 20:18 04/09/15 10:34 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.6 % 0.10 0.10 1 04/09/15 14:42 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.3 Std. Units 0.10 0.10 1 04/06/15 13:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 311 155 5 04/05/15 06:05 16887-00-6 D3 Sulfate ND mg/kg 311 155 5 04/05/15 06:05 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.1 15.5 5 04/05/15 06:05 14797-55-8 H3 Date: 04/27/2015 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 50 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARWrWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009012 Lab ID: 92243393008 Collected: 03/25/15 10:36 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2780 mg/kg 757 378 1 04/17/15 14:55 7440-44-0 Total Organic Carbon 2680 mg/kg 756 378 1 04/17/15 15:01 7440-44-0 Total Organic Carbon 2740 mg/kg 752 376 1 04/17/15 15:08 7440-44-0 Total Organic Carbon 2560 mg/kg 758 379 1 04/17/15 15:13 7440-44-0 Mean Total Organic Carbon 2690 mg/kg 756 378 1 04/17/15 14:55 7440-44-0 Surrogates RSD% 3.5 % 1 04/17/15 14:55 Date: 04/27/2015 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 51 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARVr6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009013 Lab ID: 92243393009 Collected: 03/25/15 10:46 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 3840 mg/kg 28.9 14.4 5 04/09/15 05:30 04/11/15 21:58 7429-90-5 D3 Barium 15.6 mg/kg 2.9 1.4 5 04/09/15 05:30 04/11/15 21:58 7440-39-3 D3 Beryllium 0.151 mg/kg 0.29 0.14 5 04/09/15 05:30 04/11/15 21:58 7440-41-7 D3 Boron ND mg/kg 14.4 7.2 5 04/09/15 05:30 04/11/15 21:58 7440-42-8 D3 Calcium ND mg/kg 144 72.2 5 04/09/15 05:30 04/11/15 21:58 7440-70-2 D3 Chromium 3.6 mg/kg 1.4 0.72 5 04/09/15 05:30 04/11/15 21:58 7440-47-3 D3 Copper 2.1 mg/kg 1.4 0.72 5 04/09/15 05:30 04/11/15 21:58 7440-50-8 D3 Iron 1580 mg/kg 11.5 5.8 5 04/09/15 05:30 04/11/15 21:58 7439-89-6 D3 Magnesium 146 mg/kg 144 72.2 5 04/09/15 05:30 04/11/15 21:58 7439-95-4 D3 Manganese 5.6 mg/kg 1.4 0.72 5 04/09/15 05:30 04/11/15 21:58 7439-96-5 D3 Molybdenum ND mg/kg 2.9 1.4 5 04/09/15 05:30 04/11/15 21:58 7439-98-7 D3 Nickel 0.78J mg/kg 1.4 0.72 5 04/09/15 05:30 04/11/15 21:58 7440-02-0 D3 Potassium ND mg/kg 289 144 5 04/09/15 05:30 04/11/15 21:58 7440-09-7 D3 Sodium ND mg/kg 289 144 5 04/09/15 05:30 04/11/15 21:58 7440-23-5 D3 Strontium ND mg/kg 2.9 1.4 5 04/09/15 05:30 04/11/15 21:58 7440-24-6 D3 Zinc 3.4J mg/kg 5.8 2.9 5 04/09/15 05:30 04/11/15 21:58 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.9 1.4 50 04/09/15 05:30 04/10/15 14:55 7440-36-0 N2 Arsenic ND mg/kg 2.9 1.4 50 04/09/15 05:30 04/10/15 14:55 7440-38-2 Cadmium ND mg/kg 0.35 0.17 50 04/09/15 05:30 04/10/15 14:55 7440-43-9 Cobalt ND mg/kg 2.9 1.4 50 04/09/15 05:30 04/10/15 14:55 7440-48-4 Lead 3.9 mg/kg 2.9 1.4 50 04/09/15 05:30 04/10/15 14:55 7439-92-1 Selenium ND mg/kg 2.9 1.4 50 04/09/15 05:30 04/10/15 14:55 7782-49-2 Thallium ND mg/kg 2.9 1.4 50 04/09/15 05:30 04/10/15 14:55 7440-28-0 Vanadium 5.1 mg/kg 2.9 1.4 50 04/09/15 05:30 04/10/15 14:55 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0083J mg/kg 0.0092 0.0046 1 04/08/15 20:18 04/09/15 10:36 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.9 % 0.10 0.10 1 04/09/15 14:43 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.6 Std. Units 0.10 0.10 1 04/06/15 13:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 279 140 5 04/05/15 06:26 16887-00-6 D3 Sulfate ND mg/kg 279 140 5 04/05/15 06:26 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 27.9 14.0 5 04/05/15 06:26 14797-55-8 H3 Date: 04/27/2015 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 52 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PW%18r6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009013 Lab ID: 92243393009 Collected: 03/25/15 10:46 Received: 03/31/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 455J mg/kg 669 335 1 04/17/15 15:20 7440-44-0 Total Organic Carbon 455J mg/kg 674 337 1 04/17/15 15:26 7440-44-0 Total Organic Carbon 453J mg/kg 677 339 1 04/17/15 15:33 7440-44-0 Total Organic Carbon 457J mg/kg 668 334 1 04/17/15 15:40 7440-44-0 Mean Total Organic Carbon 455J mg/kg 672 336 1 04/17/15 15:20 7440-44-0 Surrogates RSD% 0.36 % 1 04/17/15 15:20 Date: 04/27/2015 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 53 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PA9%16r6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009008 SPLP Lab ID: 92243393010 Collected: 03/28/15 09:30 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 615 ug/L 10.0 3.0 1 04/15/15 22:22 04/17/15 14:52 7429-90-5 0.78 ug/L 0.50 0.15 1 04/15/15 22:22 04/17/15 14:52 7440-36-0 5.1 ug/L 0.50 0.11 1 04/15/15 22:22 04/17/15 14:52 7440-38-2 171 ug/L 0.30 0.081 1 04/15/15 22:22 04/17/15 14:52 7440-39-3 ND ug/L 0.20 0.067 1 04/15/15 22:22 04/17/15 14:52 7440-41-7 48.8 ug/L 5.0 1.1 1 04/15/15 22:22 04/20/15 12:12 7440-42-8 ND ug/L 0.080 0.024 1 04/15/15 22:22 04/17/15 14:52 7440-43-9 1790 ug/L 40.0 16.0 1 04/15/15 22:22 04/17/15 14:52 7440-70-2 3.8 ug/L 0.50 0.17 1 04/15/15 22:22 04/17/15 14:52 7440-47-3 0.63 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 14:52 7440-48-4 3.2 ug/L 1.0 0.21 1 04/15/15 22:22 04/17/15 14:52 7440-50-8 277 ug/L 50.0 13.7 1 04/15/15 22:22 04/17/15 14:52 7439-89-6 0.80 ug/L 0.10 0.046 1 04/15/15 22:22 04/17/15 14:52 7439-92-1 341 ug/L 10.0 3.2 1 04/15/15 22:22 04/17/15 14:52 7439-95-4 23.4 ug/L 0.50 0.24 1 04/15/15 22:22 04/17/15 14:52 7439-96-5 2.4 ug/L 0.50 0.094 1 04/15/15 22:22 04/17/15 14:52 7439-98-7 2.4 ug/L 0.50 0.16 1 04/15/15 22:22 04/17/15 14:52 7440-02-0 913 ug/L 50.0 11.7 1 04/15/15 22:22 04/17/15 14:52 7440-09-7 1.2 ug/L 0.50 0.20 1 04/15/15 22:22 04/17/15 14:52 7782-49-2 1320 ug/L 50.0 16.3 1 04/15/15 22:22 04/17/15 14:52 7440-23-5 90.1 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 14:52 7440-24-6 ND ug/L 0.10 0.015 1 04/15/15 22:22 04/17/15 14:52 7440-28-0 24.6 ug/L 1.0 0.28 1 04/15/15 22:22 04/17/15 14:52 7440-62-2 29.0 ug/L 5.0 2.4 1 04/15/15 22:22 04/17/15 14:52 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/16/15 08:58 04/17/15 07:07 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 54 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36907blWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009009 SPLP Lab ID: 92243393011 Collected: 03/28/15 10:26 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 ND ug/L 10.0 3.0 1 04/15/15 22:22 04/17/15 15:15 7429-90-5 ND ug/L 0.50 0.15 1 04/15/15 22:22 04/17/15 15:15 7440-36-0 ND ug/L 0.50 0.11 1 04/15/15 22:22 04/17/15 15:15 7440-38-2 103 ug/L 0.30 0.081 1 04/15/15 22:22 04/17/15 15:15 7440-39-3 ND ug/L 0.20 0.067 1 04/15/15 22:22 04/17/15 15:15 7440-41-7 74.9 ug/L 5.0 1.1 1 04/15/15 22:22 04/17/15 15:15 7440-42-8 ND ug/L 0.080 0.024 1 04/15/15 22:22 04/17/15 15:15 7440-43-9 1440 ug/L 40.0 16.0 1 04/15/15 22:22 04/17/15 15:15 7440-70-2 ND ug/L 0.50 0.17 1 04/15/15 22:22 04/17/15 15:15 7440-47-3 ND ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:15 7440-48-4 ND ug/L 1.0 0.21 1 04/15/15 22:22 04/17/15 15:15 7440-50-8 ND ug/L 50.0 13.7 1 04/15/15 22:22 04/17/15 15:15 7439-89-6 ND ug/L 0.10 0.046 1 04/15/15 22:22 04/17/15 15:15 7439-92-1 365 ug/L 10.0 3.2 1 04/15/15 22:22 04/17/15 15:15 7439-95-4 9.2 ug/L 0.50 0.24 1 04/15/15 22:22 04/17/15 15:15 7439-96-5 ND ug/L 0.50 0.094 1 04/15/15 22:22 04/17/15 15:15 7439-98-7 ND ug/L 0.50 0.16 1 04/15/15 22:22 04/17/15 15:15 7440-02-0 484 ug/L 50.0 11.7 1 04/15/15 22:22 04/17/15 15:15 7440-09-7 2.4 ug/L 0.50 0.20 1 04/15/15 22:22 04/17/15 15:15 7782-49-2 1770 ug/L 50.0 16.3 1 04/15/15 22:22 04/17/15 15:15 7440-23-5 29.9 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:15 7440-24-6 ND ug/L 0.10 0.015 1 04/15/15 22:22 04/17/15 15:15 7440-28-0 ND ug/L 1.0 0.28 1 04/15/15 22:22 04/17/15 15:15 7440-62-2 24.4 ug/L 5.0 2.4 1 04/15/15 22:22 04/17/15 15:15 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/16/15 08:58 04/17/15 07:14 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 55 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PgRoAirpyN.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009010 SPLP Lab ID: 92243393012 Collected: 03/28/15 10:57 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 28.5 ug/L 10.0 3.0 1 04/15/15 22:22 04/17/15 15:20 7429-90-5 ND ug/L 0.50 0.15 1 04/15/15 22:22 04/17/15 15:20 7440-36-0 ND ug/L 0.50 0.11 1 04/15/15 22:22 04/17/15 15:20 7440-38-2 119 ug/L 0.30 0.081 1 04/15/15 22:22 04/17/15 15:20 7440-39-3 ND ug/L 0.20 0.067 1 04/15/15 22:22 04/17/15 15:20 7440-41-7 63.6 ug/L 5.0 1.1 1 04/15/15 22:22 04/17/15 15:20 7440-42-8 ND ug/L 0.080 0.024 1 04/15/15 22:22 04/17/15 15:20 7440-43-9 1150 ug/L 40.0 16.0 1 04/15/15 22:22 04/17/15 15:20 7440-70-2 ND ug/L 0.50 0.17 1 04/15/15 22:22 04/17/15 15:20 7440-47-3 ND ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:20 7440-48-4 ND ug/L 1.0 0.21 1 04/15/15 22:22 04/17/15 15:20 7440-50-8 ND ug/L 50.0 13.7 1 04/15/15 22:22 04/17/15 15:20 7439-89-6 ND ug/L 0.10 0.046 1 04/15/15 22:22 04/17/15 15:20 7439-92-1 897 ug/L 10.0 3.2 1 04/15/15 22:22 04/17/15 15:20 7439-95-4 41.9 ug/L 0.50 0.24 1 04/15/15 22:22 04/17/15 15:20 7439-96-5 ND ug/L 0.50 0.094 1 04/15/15 22:22 04/17/15 15:20 7439-98-7 ND ug/L 0.50 0.16 1 04/15/15 22:22 04/17/15 15:20 7440-02-0 ND ug/L 50.0 11.7 1 04/15/15 22:22 04/17/15 15:20 7440-09-7 ND ug/L 0.50 0.20 1 04/15/15 22:22 04/17/15 15:20 7782-49-2 1530 ug/L 50.0 16.3 1 04/15/15 22:22 04/17/15 15:20 7440-23-5 20.7 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:20 7440-24-6 ND ug/L 0.10 0.015 1 04/15/15 22:22 04/17/15 15:20 7440-28-0 ND ug/L 1.0 0.28 1 04/15/15 22:22 04/17/15 15:20 7440-62-2 11.5 ug/L 5.0 2.4 1 04/15/15 22:22 04/17/15 15:20 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/16/15 08:58 04/17/15 07:17 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 56 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P369ohlWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009014 SPLP Lab ID: 92243393013 Collected: 03/29/15 08:45 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 780 ug/L 10.0 3.0 1 04/15/15 22:22 04/17/15 15:24 7429-90-5 10.3 ug/L 0.50 0.15 1 04/15/15 22:22 04/17/15 15:24 7440-36-0 24.7 ug/L 0.50 0.11 1 04/15/15 22:22 04/17/15 15:24 7440-38-2 450 ug/L 1.5 0.40 5 04/15/15 22:22 04/20/15 12:17 7440-39-3 0.24 ug/L 0.20 0.067 1 04/15/15 22:22 04/17/15 15:24 7440-41-7 116 ug/L 5.0 1.1 1 04/15/15 22:22 04/17/15 15:24 7440-42-8 0.081 ug/L 0.080 0.024 1 04/15/15 22:22 04/17/15 15:24 7440-43-9 4220 ug/L 40.0 16.0 1 04/15/15 22:22 04/17/15 15:24 7440-70-2 18.2 ug/L 0.50 0.17 1 04/15/15 22:22 04/17/15 15:24 7440-47-3 8.1 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:24 7440-48-4 11.8 ug/L 1.0 0.21 1 04/15/15 22:22 04/17/15 15:24 7440-50-8 404 ug/L 50.0 13.7 1 04/15/15 22:22 04/17/15 15:24 7439-89-6 25.3 ug/L 0.10 0.046 1 04/15/15 22:22 04/17/15 15:24 7439-92-1 458 ug/L 10.0 3.2 1 04/15/15 22:22 04/17/15 15:24 7439-95-4 8.5 ug/L 0.50 0.24 1 04/15/15 22:22 04/17/15 15:24 7439-96-5 10.4 ug/L 0.50 0.094 1 04/15/15 22:22 04/17/15 15:24 7439-98-7 19.4 ug/L 0.50 0.16 1 04/15/15 22:22 04/17/15 15:24 7440-02-0 2770 ug/L 50.0 11.7 1 04/15/15 22:22 04/17/15 15:24 7440-09-7 5.4 ug/L 0.50 0.20 1 04/15/15 22:22 04/17/15 15:24 7782-49-2 48700 ug/L 250 81.5 5 04/15/15 22:22 04/20/15 12:17 7440-23-5 224 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:24 7440-24-6 0.22 ug/L 0.10 0.015 1 04/15/15 22:22 04/17/15 15:24 7440-28-0 25.2 ug/L 1.0 0.28 1 04/15/15 22:22 04/17/15 15:24 7440-62-2 109 ug/L 5.0 2.4 1 04/15/15 22:22 04/17/15 15:24 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/16/15 08:58 04/17/15 07:19 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 57 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690 3irWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009015 SPLP Lab ID: 92243393014 Collected: 03/29/15 10:41 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 9210 ug/L 10.0 3.0 1 04/15/15 22:22 04/17/15 15:29 7429-90-5 ND ug/L 0.50 0.15 1 04/15/15 22:22 04/17/15 15:29 7440-36-0 5.9 ug/L 0.50 0.11 1 04/15/15 22:22 04/17/15 15:29 7440-38-2 1100 ug/L 1.5 0.40 5 04/15/15 22:22 04/20/15 12:26 7440-39-3 4.3 ug/L 0.20 0.067 1 04/15/15 22:22 04/17/15 15:29 7440-41-7 118 ug/L 5.0 1.1 1 04/15/15 22:22 04/17/15 15:29 7440-42-8 ND ug/L 0.080 0.024 1 04/15/15 22:22 04/17/15 15:29 7440-43-9 7270 ug/L 40.0 16.0 1 04/15/15 22:22 04/17/15 15:29 7440-70-2 10.4 ug/L 0.50 0.17 1 04/15/15 22:22 04/17/15 15:29 7440-47-3 30.2 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:29 7440-48-4 45.6 ug/L 1.0 0.21 1 04/15/15 22:22 04/17/15 15:29 7440-50-8 10800 ug/L 50.0 13.7 1 04/15/15 22:22 04/17/15 15:29 7439-89-6 30.4 ug/L 0.50 0.23 5 04/15/15 22:22 04/20/15 12:26 7439-92-1 6870 ug/L 10.0 3.2 1 04/15/15 22:22 04/17/15 15:29 7439-95-4 31.0 ug/L 0.50 0.24 1 04/15/15 22:22 04/17/15 15:29 7439-96-5 ND ug/L 0.50 0.094 1 04/15/15 22:22 04/17/15 15:29 7439-98-7 23.9 ug/L 0.50 0.16 1 04/15/15 22:22 04/17/15 15:29 7440-02-0 545 ug/L 50.0 11.7 1 04/15/15 22:22 04/17/15 15:29 7440-09-7 7.6 ug/L 0.50 0.20 1 04/15/15 22:22 04/17/15 15:29 7782-49-2 4180 ug/L 50.0 16.3 1 04/15/15 22:22 04/17/15 15:29 7440-23-5 245 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:29 7440-24-6 ND ug/L 0.50 0.077 5 04/15/15 22:22 04/20/15 12:26 7440-28-0 37.9 ug/L 1.0 0.28 1 04/15/15 22:22 04/17/15 15:29 7440-62-2 231 ug/L 5.0 2.4 1 04/15/15 22:22 04/17/15 15:29 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 0.20 ug/L 0.20 0.022 1 04/16/15 08:58 04/17/15 07:21 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 Page 58 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36907ir6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009016 SPLP Lab ID: 92243393015 Collected: 03/29/15 10:21 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\riil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 15900 ug/L 10.0 3.0 1 04/15/15 22:22 04/17/15 15:34 7429-90-5 ND ug/L 0.50 0.15 1 04/15/15 22:22 04/17/15 15:34 7440-36-0 9.4 ug/L 0.50 0.11 1 04/15/15 22:22 04/17/15 15:34 7440-38-2 2090 ug/L 1.5 0.40 5 04/15/15 22:22 04/20/15 13:09 7440-39-3 5.4 ug/L 1.0 0.34 5 04/15/15 22:22 04/20/15 13:09 7440-41-7 138 ug/L 25.0 5.6 5 04/15/15 22:22 04/20/15 13:09 7440-42-8 ND ug/L 0.080 0.024 1 04/15/15 22:22 04/17/15 15:34 7440-43-9 6630 ug/L 40.0 16.0 1 04/15/15 22:22 04/17/15 15:34 7440-70-2 25.7 ug/L 0.50 0.17 1 04/15/15 22:22 04/17/15 15:34 7440-47-3 12.6 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:34 7440-48-4 108 ug/L 1.0 0.21 1 04/15/15 22:22 04/17/15 15:34 7440-50-8 56100 ug/L 250 68.5 5 04/15/15 22:22 04/20/15 13:09 7439-89-6 102 ug/L 0.50 0.23 5 04/15/15 22:22 04/20/15 13:09 7439-92-1 5460 ug/L 10.0 3.2 1 04/15/15 22:22 04/17/15 15:34 7439-95-4 16.8 ug/L 0.50 0.24 1 04/15/15 22:22 04/17/15 15:34 7439-96-5 ND ug/L 0.50 0.094 1 04/15/15 22:22 04/17/15 15:34 7439-98-7 20.7 ug/L 0.50 0.16 1 04/15/15 22:22 04/17/15 15:34 7440-02-0 729 ug/L 50.0 11.7 1 04/15/15 22:22 04/17/15 15:34 7440-09-7 12.1 ug/L 0.50 0.20 1 04/15/15 22:22 04/17/15 15:34 7782-49-2 5130 ug/L 50.0 16.3 1 04/15/15 22:22 04/17/15 15:34 7440-23-5 235 ug/L 0.50 0.13 1 04/15/15 22:22 04/17/15 15:34 7440-24-6 ND ug/L 0.50 0.077 5 04/15/15 22:22 04/20/15 13:09 7440-28-0 182 ug/L 1.0 0.28 1 04/15/15 22:22 04/17/15 15:34 7440-62-2 294 ug/L 5.0 2.4 1 04/15/15 22:22 04/17/15 15:34 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 0.47 ug/L 0.20 0.022 1 04/16/15 08:58 04/17/15 07:24 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 Page 59 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690816fyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009017 Lab ID: 92243393016 Collected: 03/29/15 08:20 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\��,I=11a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 13.1 ug/L 10.0 3.0 1 04/05/15 20:48 04/08/15 16:06 7429-90-5 ND ug/L 0.50 0.15 1 04/05/15 20:48 04/08/15 16:06 7440-36-0 ND ug/L 0.50 0.11 1 04/05/15 20:48 04/08/15 16:06 7440-38-2 0.54 ug/L 0.30 0.081 1 04/05/15 20:48 04/08/15 16:06 7440-39-3 ND ug/L 0.20 0.067 1 04/05/15 20:48 04/08/15 16:06 7440-41-7 ND ug/L 5.0 1.1 1 04/05/15 20:48 04/08/15 16:06 7440-42-8 ND ug/L 0.080 0.024 1 04/05/15 20:48 04/08/15 16:06 7440-43-9 75.6 ug/L 40.0 16.0 1 04/05/15 20:48 04/08/15 16:06 7440-70-2 6.6 ug/L 0.50 0.17 1 04/05/15 20:48 04/08/15 16:06 7440-47-3 ND ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 16:06 7440-48-4 ND ug/L 1.0 0.21 1 04/05/15 20:48 04/08/15 16:06 7440-50-8 ND ug/L 50.0 13.7 1 04/05/15 20:48 04/08/15 16:06 7439-89-6 ND ug/L 0.10 0.046 1 04/05/15 20:48 04/08/15 16:06 7439-92-1 19.0 ug/L 10.0 3.2 1 04/05/15 20:48 04/08/15 16:06 7439-95-4 0.96 ug/L 0.50 0.24 1 04/05/15 20:48 04/08/15 16:06 7439-96-5 ND ug/L 0.50 0.094 1 04/05/15 20:48 04/08/15 16:06 7439-98-7 4.2 ug/L 0.50 0.16 1 04/05/15 20:48 04/08/15 16:06 7440-02-0 ND ug/L 50.0 11.7 1 04/05/15 20:48 04/08/15 16:06 7440-09-7 ND ug/L 0.50 0.20 1 04/05/15 20:48 04/08/15 16:06 7782-49-2 91.6 ug/L 50.0 16.3 1 04/05/15 20:48 04/08/15 16:06 7440-23-5 0.53 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 16:06 7440-24-6 ND ug/L 0.10 0.015 1 04/05/15 20:48 04/08/15 16:06 7440-28-0 ND ug/L 1.0 0.28 1 04/05/15 20:48 04/08/15 16:06 7440-62-2 ND ug/L 5.0 2.4 1 04/05/15 20:48 04/08/15 16:06 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/09/1512:23 04/10/1513:03 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 60 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690mrWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009018 Lab ID: 92243393017 Collected: 03/28/15 11:30 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\ri,I=11a 99�r6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 26.7 ug/L 10.0 3.0 1 04/05/15 20:48 04/08/15 16:11 7429-90-5 0.52 ug/L 0.50 0.15 1 04/05/15 20:48 04/08/15 16:11 7440-36-0 ND ug/L 0.50 0.11 1 04/05/15 20:48 04/08/15 16:11 7440-38-2 0.31 ug/L 0.30 0.081 1 04/05/15 20:48 04/08/15 16:11 7440-39-3 ND ug/L 0.20 0.067 1 04/05/15 20:48 04/08/15 16:11 7440-41-7 ND ug/L 5.0 1.1 1 04/05/15 20:48 04/08/15 16:11 7440-42-8 ND ug/L 0.080 0.024 1 04/05/15 20:48 04/08/15 16:11 7440-43-9 78.8 ug/L 40.0 16.0 1 04/05/15 20:48 04/08/15 16:11 7440-70-2 2.2 ug/L 0.50 0.17 1 04/05/15 20:48 04/08/15 16:11 7440-47-3 ND ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 16:11 7440-48-4 ND ug/L 1.0 0.21 1 04/05/15 20:48 04/08/15 16:11 7440-50-8 ND ug/L 50.0 13.7 1 04/05/15 20:48 04/08/15 16:11 7439-89-6 ND ug/L 0.10 0.046 1 04/05/15 20:48 04/08/15 16:11 7439-92-1 18.5 ug/L 10.0 3.2 1 04/05/15 20:48 04/08/15 16:11 7439-95-4 1.1 ug/L 0.50 0.24 1 04/05/15 20:48 04/08/15 16:11 7439-96-5 ND ug/L 0.50 0.094 1 04/05/15 20:48 04/08/15 16:11 7439-98-7 1.8 ug/L 0.50 0.16 1 04/05/15 20:48 04/08/15 16:11 7440-02-0 ND ug/L 50.0 11.7 1 04/05/15 20:48 04/08/15 16:11 7440-09-7 ND ug/L 0.50 0.20 1 04/05/15 20:48 04/08/15 16:11 7782-49-2 65.3 ug/L 50.0 16.3 1 04/05/15 20:48 04/08/15 16:11 7440-23-5 ND ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 16:11 7440-24-6 ND ug/L 0.10 0.015 1 04/05/15 20:48 04/08/15 16:11 7440-28-0 ND ug/L 1.0 0.28 1 04/05/15 20:48 04/08/15 16:11 7440-62-2 ND ug/L 5.0 2.4 1 04/05/15 20:48 04/08/15 16:11 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/09/1512:23 04/10/1513:05 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 61 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARO&WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030758 Pace Project No.: 92243393 Sample: 2015009019 Lab ID: 92243393018 Collected: 03/25/15 15:05 Received: 03/31/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11a 99�r6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/27/2015 03:25 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 ND ug/L 10.0 3.0 1 04/05/15 20:48 04/08/15 16:16 7429-90-5 ND ug/L 0.50 0.15 1 04/05/15 20:48 04/08/15 16:16 7440-36-0 ND ug/L 0.50 0.11 1 04/05/15 20:48 04/08/15 16:16 7440-38-2 0.82 ug/L 0.30 0.081 1 04/05/15 20:48 04/08/15 16:16 7440-39-3 ND ug/L 0.20 0.067 1 04/05/15 20:48 04/08/15 16:16 7440-41-7 ND ug/L 5.0 1.1 1 04/05/15 20:48 04/08/15 16:16 7440-42-8 ND ug/L 0.080 0.024 1 04/05/15 20:48 04/08/15 16:16 7440-43-9 332 ug/L 40.0 16.0 1 04/05/15 20:48 04/08/15 16:16 7440-70-2 5.2 ug/L 0.50 0.17 1 04/05/15 20:48 04/08/15 16:16 7440-47-3 ND ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 16:16 7440-48-4 ND ug/L 1.0 0.21 1 04/05/15 20:48 04/08/15 16:16 7440-50-8 125 ug/L 50.0 13.7 1 04/05/15 20:48 04/08/15 16:16 7439-89-6 ND ug/L 0.10 0.046 1 04/05/15 20:48 04/08/15 16:16 7439-92-1 38.2 ug/L 10.0 3.2 1 04/05/15 20:48 04/08/15 16:16 7439-95-4 3.4 ug/L 0.50 0.24 1 04/05/15 20:48 04/08/15 16:16 7439-96-5 ND ug/L 0.50 0.094 1 04/05/15 20:48 04/08/15 16:16 7439-98-7 7.7 ug/L 0.50 0.16 1 04/05/15 20:48 04/08/15 16:16 7440-02-0 ND ug/L 50.0 11.7 1 04/05/15 20:48 04/08/15 16:16 7440-09-7 ND ug/L 0.50 0.20 1 04/05/15 20:48 04/08/15 16:16 7782-49-2 179 ug/L 50.0 16.3 1 04/05/15 20:48 04/08/15 16:16 7440-23-5 0.87 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 16:16 7440-24-6 ND ug/L 0.10 0.015 1 04/05/15 20:48 04/08/15 16:16 7440-28-0 ND ug/L 1.0 0.28 1 04/05/15 20:48 04/08/15 16:16 7440-62-2 6.8 ug/L 5.0 2.4 1 04/05/15 20:48 04/08/15 16:16 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/09/1512:23 04/10/1513:08 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 62 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690mrWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MERP/13171 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92243393016, 92243393017, 92243393018 METHOD BLANK: 1934785 Matrix: Water Associated Lab Samples: 92243393016, 92243393017, 92243393018 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/10/1511:49 LABORATORY CONTROL SAMPLE: 1934786 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.4 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1935455 1935456 MS MSD 92243388026 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.3 104 105 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690hrWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MERP/13233 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92243393010, 92243393011, 92243393012, 92243393013, 92243393014, 92243393015 METHOD BLANK: 1939461 Matrix: Water Associated Lab Samples: 92243393010, 92243393011, 92243393012, 92243393013, 92243393014, 92243393015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/17/15 06:43 LABORATORY CONTROL SAMPLE: 1939462 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1939463 1939464 MS MSD 92245086002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.1 5.1 102 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MERP/5565 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004 METHOD BLANK: 1178132 Matrix: Solid Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 04/09/15 09:06 LABORATORY CONTROL SAMPLE: 1178133 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .078 0.079 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1178134 1178135 MS MSD 35181255003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.040U .8 .73 0.65 0.64 82 88 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 65 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36R08 6fyN.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MERP/5566 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92243393005, 92243393006, 92243393007, 92243393008, 92243393009 METHOD BLANK: 1178138 Matrix: Solid Associated Lab Samples: 92243393005, 92243393006, 92243393007, 92243393008, 92243393009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 04/09/1510:13 LABORATORY CONTROL SAMPLE: 1178139 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.086 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1178140 1178141 MS MSD 92243393005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.028 .0929 .0989 0.096 0.10 73 77 80-120 7 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 66 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARYWYNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MPRP/23429 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 METHOD BLANK: 1174969 Matrix: Solid Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg ND 5.1 04/09/15 06:25 Barium mg/kg ND 0.51 04/09/15 06:25 Beryllium mg/kg ND 0.051 04/09/15 06:25 Boron mg/kg ND 2.6 04/09/15 06:25 Calcium mg/kg ND 25.7 04/09/15 06:25 Chromium mg/kg ND 0.26 04/09/15 06:25 Copper mg/kg ND 0.26 04/09/15 06:25 Iron mg/kg ND 2.1 04/09/15 06:25 Magnesium mg/kg ND 25.7 04/09/15 06:25 Manganese mg/kg ND 0.26 04/09/15 06:25 Molybdenum mg/kg ND 0.51 04/09/15 06:25 Nickel mg/kg ND 0.26 04/09/15 06:25 Potassium mg/kg ND 51.4 04/09/15 06:25 Sodium mg/kg ND 51.4 04/09/15 06:25 Strontium mg/kg ND 0.51 04/09/15 06:25 Zinc mg/kg ND 1.0 04/09/15 06:25 LABORATORY CONTROL SAMPLE: Parameter 1174970 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 126 123 98 80-120 Barium mg/kg 12.6 12.5 99 80-120 Beryllium mg/kg 1.3 1.2 98 80-120 Boron mg/kg 126 123 98 80-120 Calcium mg/kg 629 621 99 80-120 Chromium mg/kg 12.6 12.3 98 80-120 Copper mg/kg 12.6 12.2 97 80-120 Iron mg/kg 126 120 96 80-120 Magnesium mg/kg 629 612 97 80-120 Manganese mg/kg 12.6 12.4 98 80-120 Molybdenum mg/kg 12.6 11.9 95 80-120 Nickel mg/kg 12.6 12.2 97 80-120 Potassium mg/kg 629 603 96 80-120 Sodium mg/kg 629 626 100 80-120 Strontium mg/kg 12.6 12.3 98 80-120 Zinc mg/kg 62.9 61.9 98 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 67 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARYWYNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1174971 1174972 MS MSD 92242920018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Aluminum mg/kg 8060 166 183 10800 12100 1660 2220 75-125 11 20 M1 Barium mg/kg 833 16.6 18.3 723 904 -660 388 75-125 22 20 M1,R1 Beryllium mg/kg 1.5 1.7 1.84 2.9 3.8 84 125 75-125 26 20 R1 Boron mg/kg 14.7J 166 183 176 193 97 98 75-125 9 20 Calcium mg/kg 1340 829 913 2070 2440 88 120 75-125 16 20 Chromium mg/kg 10.6 16.6 18.3 32.0 30.5 129 109 75-125 5 20 M1 Copper mg/kg 28.0 16.6 18.3 40.3 46.5 74 101 75-125 14 20 M1 Iron mg/kg 9380 166 183 11100 11400 1030 1120 75-125 3 20 M1 Magnesium mg/kg 918 829 913 1840 2170 111 138 75-125 17 20 M1 Manganese mg/kg 40.4 16.6 18.3 61.9 64.8 129 133 75-125 5 20 M1 Molybdenum mg/kg ND 16.6 18.3 15.9 17.5 88 89 75-125 10 20 Nickel mg/kg 8.6 16.6 18.3 26.1 29.5 105 114 75-125 12 20 Potassium mg/kg 1870 829 913 2720 3750 102 207 75-125 32 20 M1,R1 Sodium mg/kg 251J 829 913 1120 1290 105 114 75-125 14 20 Strontium mg/kg 77.1 16.6 18.3 81.2 117 24 218 75-125 36 20 M1,R1 Zinc mg/kg 12.3 82.9 91.3 94.9 106 100 103 75-125 11 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 68 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAMIirWyNe. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MPRP/23485 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92243393007, 92243393008, 92243393009 METHOD BLANK: 1176762 Matrix: Associated Lab Samples: 92243393007, 92243393008, 92243393009 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.0 04/11/15 21:17 Barium mg/kg ND 0.50 04/11/15 21:17 Beryllium mg/kg ND 0.050 04/11/15 21:17 Boron mg/kg ND 2.5 04/11/15 21:17 Calcium mg/kg ND 25.0 04/11/15 21:17 Chromium mg/kg ND 0.25 04/11/15 21:17 Copper mg/kg ND 0.25 04/11/15 21:17 Iron mg/kg 1.11 2.0 04/11/15 21:17 P8 Magnesium mg/kg ND 25.0 04/11/15 21:17 Manganese mg/kg ND 0.25 04/11/15 21:17 Molybdenum mg/kg ND 0.50 04/11/15 21:17 Nickel mg/kg ND 0.25 04/11/15 21:17 Potassium mg/kg ND 49.9 04/11/15 21:17 Sodium mg/kg ND 49.9 04/11/15 21:17 Strontium mg/kg ND 0.50 04/11/15 21:17 Zinc mg/kg ND 1.0 04/11/15 21:17 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1176763 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 123 125 101 80-120 Barium mg/kg 12.3 12.9 105 80-120 Beryllium mg/kg 1.2 1.2 101 80-120 Boron mg/kg 123 123 100 80-120 Calcium mg/kg 615 626 102 80-120 Chromium mg/kg 12.3 12.2 100 80-120 Copper mg/kg 12.3 12.1 99 80-120 Iron mg/kg 123 119 97 80-120 Magnesium mg/kg 615 608 99 80-120 Manganese mg/kg 12.3 12.4 101 80-120 Molybdenum mg/kg 12.3 12.1 98 80-120 Nickel mg/kg 12.3 12.5 102 80-120 Potassium mg/kg 615 655 107 80-120 Sodium mg/kg 615 670 109 80-120 Strontium mg/kg 12.3 12.5 102 80-120 Zinc mg/kg 61.5 63.0 103 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 69 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1176764 1176765 MS MSD 92243393007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Aluminum mg/kg 1270 163 170 3970 3550 1650 1330 75-125 11 20 D3,M1 Barium mg/kg 6.8 16.3 17 25.8 25.2 116 108 75-125 2 20 D3 Beryllium mg/kg ND 1.68 1.68 1.8 1.8 103 100 75-125 1 20 D3 Boron mg/kg ND 163 170 160 164 97 95 75-125 3 20 D3 Calcium mg/kg ND 815 851 891 918 104 102 75-125 3 20 D3 Chromium mg/kg 2.4 16.3 17 19.7 20.0 106 103 75-125 1 20 D3 Copper mg/kg 1.6 16.3 17 17.8 18.0 100 96 75-125 1 20 D3 Iron mg/kg 829 163 170 1280 1310 276 280 75-125 2 20 D3,M1 Magnesium mg/kg ND 815 851 942 948 108 104 75-125 1 20 D3 Manganese mg/kg 5.0 16.3 17 22.6 22.1 108 100 75-125 2 20 D3 Molybdenum mg/kg ND 16.3 17 15.3 15.5 92 89 75-125 2 20 D3 Nickel mg/kg 1.01 16.3 17 18.5 19.1 107 106 75-125 3 20 D3 Potassium mg/kg ND 815 851 965 965 111 106 75-125 0 20 D3 Sodium mg/kg ND 815 851 907 948 110 110 75-125 4 20 D3 Strontium mg/kg ND 16.3 17 17.9 18.2 105 103 75-125 2 20 D3 Zinc mg/kg 3.5J 81.5 85.1 89.0 91.3 105 103 75-125 3 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 70 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARVr6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MPRP/23430 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 METHOD BLANK: 1174973 Matrix: Solid Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.052 04/07/1512:23 N2 Arsenic mg/kg ND 0.052 04/07/1512:23 Cadmium mg/kg ND 0.0063 04/07/1512:23 Cobalt mg/kg ND 0.052 04/07/1512:23 Lead mg/kg ND 0.052 04/07/1512:23 Selenium mg/kg ND 0.052 04/07/1512:23 Thallium mg/kg ND 0.052 04/07/1512:23 Vanadium mg/kg ND 0.052 04/07/1512:23 LABORATORY CONTROL SAMPLE: Parameter 1174974 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.6 2.5 96 80-120 N2 Arsenic mg/kg 2.6 2.7 106 80-120 Cadmium mg/kg .26 0.27 104 80-120 Cobalt mg/kg 2.6 2.7 106 80-120 Lead mg/kg 2.6 2.6 100 80-120 Selenium mg/kg 2.6 2.7 103 80-120 Thallium mg/kg 2.6 2.6 99 80-120 Vanadium mg/kg 2.6 2.7 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1174975 1174976 MS MSD 92242920019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.38 3.52 2.8J 2.6J 49 44 75-125 20 M6, N2 Arsenic mg/kg 74.5 3.38 3.52 71.3 81.3 -97 197 75-125 13 20 M6 Cadmium mg/kg 0.24J .338 .352 0.61 0.52 110 82 75-125 15 20 Cobalt mg/kg 5.6 3.38 3.52 9.2 9.5 107 111 75-125 2 20 Lead mg/kg 11.7 3.38 3.52 16.4 14.6 141 85 75-125 12 20 M6 Selenium mg/kg 3.9 3.38 3.52 5.9 5.9 60 57 75-125 1 20 M6 Thallium mg/kg ND 3.38 3.52 3.6 3.6 74 72 75-125 0 20 M6 Vanadium mg/kg 39.4 3.38 3.52 50.4 43.3 327 112 75-125 15 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 71 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARVr6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MPRP/23486 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92243393007, 92243393008, 92243393009 METHOD BLANK: 1176766 Matrix: Solid Associated Lab Samples: 92243393007, 92243393008, 92243393009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/10/1514:28 N2 Arsenic mg/kg ND 0.051 04/10/1514:28 Cadmium mg/kg ND 0.0061 04/10/1514:28 Cobalt mg/kg ND 0.051 04/10/1514:28 Lead mg/kg ND 0.051 04/10/1514:28 Selenium mg/kg ND 0.051 04/10/1514:28 Thallium mg/kg ND 0.051 04/10/1514:28 Vanadium mg/kg ND 0.051 04/10/1514:28 LABORATORY CONTROL SAMPLE: Parameter 1176767 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 105 80-120 N2 Arsenic mg/kg 2.5 2.6 106 80-120 Cadmium mg/kg .25 0.25 100 80-120 Cobalt mg/kg 2.5 2.6 107 80-120 Lead mg/kg 2.5 2.6 107 80-120 Selenium mg/kg 2.5 2.7 110 80-120 Thallium mg/kg 2.5 2.4 98 80-120 Vanadium mg/kg 2.5 2.7 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1176768 1176769 MS MSD 92243393008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.27 3.15 2.6J 2AJ 71 70 75-125 20 M6, N2 Arsenic mg/kg ND 3.27 3.15 3.9 3.9 86 91 75-125 1 20 Cadmium mg/kg ND .327 .315 0.33J 0.27J 101 87 75-125 20 Cobalt mg/kg ND 3.27 3.15 4.5 4.6 112 122 75-125 4 20 Lead mg/kg 5.5 3.27 3.15 9.3 9.9 116 141 75-125 6 20 M6 Selenium mg/kg ND 3.27 3.15 2.7J 2.6J 75 74 75-125 20 M6 Thallium mg/kg ND 3.27 3.15 3.1J 3.2 90 97 75-125 20 Vanadium mg/kg 16.1 3.27 3.15 20.4 23.4 133 238 75-125 14 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 72 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARI&WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MPRP/53405 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92243393016, 92243393017, 92243393018 METHOD BLANK: 1932876 Matrix: Associated Lab Samples: 92243393016, 92243393017, 92243393018 Blank Parameter Units Result Water Reporting Limit Analyzed Aluminum ug/L ND 10.0 04/08/1514:02 Antimony ug/L ND 0.50 04/08/1514:02 Arsenic ug/L ND 0.50 04/08/1514:02 Barium ug/L ND 0.30 04/08/1514:02 Beryllium ug/L ND 0.20 04/08/1514:02 Boron ug/L ND 5.0 04/09/15 09:54 Cadmium ug/L ND 0.080 04/08/1514:02 Calcium ug/L ND 40.0 04/08/1514:02 Chromium ug/L ND 0.50 04/08/1514:02 Cobalt ug/L ND 0.50 04/08/1514:02 Copper ug/L ND 1.0 04/08/1514:02 Iron ug/L ND 50.0 04/08/1514:02 Lead ug/L ND 0.10 04/08/1514:02 Magnesium ug/L ND 10.0 04/08/1514:02 Manganese ug/L ND 0.50 04/08/1514:02 Molybdenum ug/L ND 0.50 04/08/1514:02 Nickel ug/L ND 0.50 04/08/1514:02 Potassium ug/L ND 50.0 04/08/1514:02 Selenium ug/L ND 0.50 04/08/1514:02 Sodium ug/L ND 50.0 04/08/1514:02 Strontium ug/L ND 0.50 04/08/1514:02 Thallium ug/L ND 0.10 04/08/1514:02 Vanadium ug/L ND 1.0 04/08/1514:02 Zinc ug/L ND 5.0 04/08/1514:02 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1932877 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 75.9 95 80-120 Antimony ug/L 80 79.8 100 80-120 Arsenic ug/L 80 78.7 98 80-120 Barium ug/L 80 77.9 97 80-120 Beryllium ug/L 80 75.6 94 80-120 Boron ug/L 80 76.2 95 80-120 Cadmium ug/L 80 77.5 97 80-120 Calcium ug/L 1000 890 89 80-120 Chromium ug/L 80 76.8 96 80-120 Cobalt ug/L 80 74.9 94 80-120 Copper ug/L 80 74.9 94 80-120 Iron ug/L 1000 967 97 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 73 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. POO WyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 LABORATORY CONTROL SAMPLE: 1932877 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 78.3 98 80-120 Magnesium ug/L 1000 956 96 80-120 Manganese ug/L 80 77.7 97 80-120 Molybdenum ug/L 80 75.1 94 80-120 Nickel ug/L 80 78.1 98 80-120 Potassium ug/L 1000 975 98 80-120 Selenium ug/L 80 79.6 99 80-120 Sodium ug/L 1000 943 94 80-120 Strontium ug/L 80 75.4 94 80-120 Thallium ug/L 80 76.6 96 80-120 Vanadium ug/L 80 79.3 99 80-120 Zinc ug/L 80 79.0 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1932878 1932879 MS MSD 10301430001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 80 80 100 119 121 144 75-125 17 20 M1 Antimony ug/L ND 80 80 80.2 80.2 100 100 75-125 0 20 Arsenic ug/L 183 80 80 262 263 99 100 75-125 0 20 Barium ug/L 113 80 80 188 192 94 98 75-125 2 20 Beryllium ug/L ND 80 80 68.2 72.9 85 91 75-125 7 20 Boron ug/L 500 80 80 589 596 111 119 75-125 1 20 Cadmium ug/L ND 80 80 77.5 77.4 97 97 75-125 0 20 Calcium ug/L 94300 1000 1000 91600 92700 -262 -158 75-125 1 20 E,M1 Chromium ug/L 0.53 80 80 76.8 78.0 95 97 75-125 1 20 Cobalt ug/L ND 80 80 74.7 74.6 93 93 75-125 0 20 Copper ug/L 1.1 80 80 75.0 75.9 92 93 75-125 1 20 Iron ug/L 9490 1000 1000 10500 10600 99 115 75-125 1 20 Lead ug/L ND 80 80 77.3 78.1 96 98 75-125 1 20 Magnesium ug/L 46700 1000 1000 45800 46000 -92 -72 75-125 0 20 M1 Manganese ug/L 1500 80 80 1520 1540 30 48 75-125 1 20 M1 Molybdenum ug/L 0.91 80 80 77.0 77.6 95 96 75-125 1 20 Nickel ug/L 1.2 80 80 78.4 77.1 96 95 75-125 2 20 Potassium ug/L 9940 1000 1000 11100 11200 116 128 75-125 1 20 M1 Selenium ug/L ND 80 80 81.8 80.3 102 100 75-125 2 20 Sodium ug/L 78700 1000 1000 76500 76800 -222 -190 75-125 0 20 M1 Strontium ug/L 604 80 80 669 677 81 91 75-125 1 20 Thallium ug/L ND 80 80 78.9 80.2 99 100 75-125 2 20 Vanadium ug/L ND 80 80 79.4 79.2 99 98 75-125 0 20 Zinc ug/L 5.7 80 80 86.5 89.1 101 104 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 74 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARVrwY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: MPRP/53629 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92243393010, 92243393011, 92243393012, 92243393013, 92243393014, 92243393015 METHOD BLANK: 1939440 Matrix: Water Associated Lab Samples: 92243393010, 92243393011, 92243393012, 92243393013, 92243393014, 92243393015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum ug/L ND 10.0 04/17/1514:19 Antimony ug/L ND 0.50 04/17/1514:19 Arsenic ug/L ND 0.50 04/17/1514:19 Barium ug/L ND 0.30 04/17/1514:19 Beryllium ug/L ND 0.20 04/17/1514:19 Boron ug/L ND 5.0 04/17/1514:19 Cadmium ug/L ND 0.080 04/17/1514:19 Calcium ug/L ND 40.0 04/17/1514:19 Chromium ug/L ND 0.50 04/17/1514:19 Cobalt ug/L ND 0.50 04/17/1514:19 Copper ug/L ND 1.0 04/17/1514:19 Iron ug/L ND 50.0 04/17/1514:19 Lead ug/L ND 0.10 04/17/1514:19 Magnesium ug/L ND 10.0 04/17/1514:19 Manganese ug/L ND 0.50 04/17/1514:19 Molybdenum ug/L ND 0.50 04/17/1514:19 Nickel ug/L ND 0.50 04/17/1514:19 Potassium ug/L ND 50.0 04/17/1514:19 Selenium ug/L ND 0.50 04/17/1514:19 Sodium ug/L ND 50.0 04/17/1514:19 Strontium ug/L ND 0.50 04/17/1514:19 Thallium ug/L ND 0.10 04/17/1514:19 Vanadium ug/L ND 1.0 04/17/1514:19 Zinc ug/L ND 5.0 04/17/1514:19 LABORATORY CONTROL SAMPLE: Parameter 1939441 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 80.5 101 80-120 Antimony ug/L 80 78.6 98 80-120 Arsenic ug/L 80 78.2 98 80-120 Barium ug/L 80 78.9 99 80-120 Beryllium ug/L 80 69.6 87 80-120 Boron ug/L 80 73.9 92 80-120 Cadmium ug/L 80 78.2 98 80-120 Calcium ug/L 1000 958 96 80-120 Chromium ug/L 80 78.7 98 80-120 Cobalt ug/L 80 78.3 98 80-120 Copper ug/L 80 80.9 101 80-120 Iron ug/L 1000 1010 101 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 75 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36gmirpYN.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 LABORATORY CONTROL SAMPLE: 1939441 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 78.9 99 80-120 Magnesium ug/L 1000 980 98 80-120 Manganese ug/L 80 78.6 98 80-120 Molybdenum ug/L 80 79.2 99 80-120 Nickel ug/L 80 80.6 101 80-120 Potassium ug/L 1000 1000 100 80-120 Selenium ug/L 80 78.8 99 80-120 Sodium ug/L 1000 970 97 80-120 Strontium ug/L 80 78.5 98 80-120 Thallium ug/L 80 79.5 99 80-120 Vanadium ug/L 80 82.4 103 80-120 Zinc ug/L 80 78.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1939444 1939445 MS MSD 92245086001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 45.6 80 80 157 178 139 165 75-125 13 20 M1 Antimony ug/L ND 80 80 78.2 77.2 98 96 75-125 1 20 Arsenic ug/L ND 80 80 78.6 78.4 98 98 75-125 0 20 Barium ug/L 1.1 80 80 78.2 79.0 96 97 75-125 1 20 Beryllium ug/L ND 80 80 67.9 66.3 85 83 75-125 2 20 Boron ug/L ND 80 80 83.0 81.1 102 100 75-125 2 20 Cadmium ug/L ND 80 80 77.8 78.1 97 98 75-125 0 20 Calcium ug/L 129 1000 1000 1080 1120 95 99 75-125 3 20 Chromium ug/L ND 80 80 78.2 78.6 98 98 75-125 1 20 Cobalt ug/L ND 80 80 79.0 78.3 99 98 75-125 1 20 Copper ug/L ND 80 80 81.6 81.4 102 101 75-125 0 20 Iron ug/L 60.0 1000 1000 1090 1090 103 103 75-125 0 20 Lead ug/L ND 80 80 78.2 77.7 98 97 75-125 1 20 Magnesium ug/L 30.0 1000 1000 990 1000 96 97 75-125 1 20 Manganese ug/L 3.5 80 80 82.8 81.7 99 98 75-125 1 20 Molybdenum ug/L ND 80 80 77.9 78.6 97 98 75-125 1 20 Nickel ug/L ND 80 80 81.4 80.6 102 101 75-125 1 20 Potassium ug/L ND 1000 1000 1060 1060 102 101 75-125 0 20 Selenium ug/L ND 80 80 80.5 80.3 101 100 75-125 0 20 Sodium ug/L 50.2 1000 1000 1020 1020 97 97 75-125 1 20 Strontium ug/L 0.89 80 80 78.6 78.3 97 97 75-125 0 20 Thallium ug/L ND 80 80 80.8 80.5 101 101 75-125 0 20 Vanadium ug/L ND 80 80 81.8 80.8 102 101 75-125 1 20 Zinc ug/L ND 80 80 80.2 81.6 98 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 76 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36906rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: PMST/3426 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006, 92243393007, 92243393008,92243393009 SAMPLE DUPLICATE: 1178869 92243757001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 21.7 22.3 3 10 SAMPLE DUPLICATE: 1178870 92243393002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.8 17.4 8 10 SAMPLE DUPLICATE: 1178871 92243388023 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 33.3 31.5 6 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 77 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36906rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WET/36610 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92243393007, 92243393008, 92243393009 SAMPLE DUPLICATE: 1426089 92243388008 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.0 6.1 2 10 D6 SAMPLE DUPLICATE: 1426090 92243393009 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.6 4.6 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 78 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WET/36662 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 SAMPLE DUPLICATE: 1427924 92243391001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.2 5.1 1 10 SAMPLE DUPLICATE: 1427925 92243391016 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.6 5.6 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 79 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROArWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WETA/22495 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 METHOD BLANK: 1430392 Matrix: Water Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.4 2.0 04/09/1516:42 LABORATORY CONTROL SAMPLE: 1430393 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.3 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1430394 1430395 MS MSD 92243096002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.9 20.6 20.6 22.4 22.3 90 89 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1430396 1430397 MS MSD 92243393001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 11.3 37.9 37.9 46.4 46.7 93 94 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 80 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PAROAlWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WETA/22501 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 METHOD BLANK: 1431026 Matrix: Water Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.16 0.020 04/09/15 19:46 Z2 LABORATORY CONTROL SAMPLE: 1431027 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1431028 1431029 MS MSD 92243245004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.7 2.7 102 102 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1431030 1431031 MS MSD 92243245005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.5 2.5 92 92 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 81 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P3690orwyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WETA/22491 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 METHOD BLANK: 1430197 Matrix: Water Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 04/09/15 04:54 LABORATORY CONTROL SAMPLE: 1430198 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.2 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1430199 1430200 MS MSD 92243096002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 3.9J 20.6 20.6 26.6 26.7 110 111 90-110 1 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1430201 1430202 MS MSD 92243393001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 37.9 37.9 40.2 39.6 102 101 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 82 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PARVr6fY(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WETA/45120 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004 METHOD BLANK: 1174921 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.4 04/04/1516:35 Sulfate mg/kg ND 49.4 04/04/1516:35 LABORATORY CONTROL SAMPLE: 1174922 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1174924 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1174923 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 501 489 98 80-120 501 490 98 80-120 92243391001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 560 558 81 80-120 ND 560 554 99 80-120 92243391001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 D3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 83 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. P36906rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WETA/45122 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92243393005, 92243393006, 92243393007, 92243393008, 92243393009 METHOD BLANK: 1174929 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.4 04/05/15 03:35 Sulfate mg/kg ND 49.4 04/05/15 03:35 LABORATORY CONTROL SAMPLE: 1174930 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1174932 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1174931 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 496 469 94 80-120 496 469 94 80-120 92243393005 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 602 855J 73 80-120 M6 ND 602 781J 130 80-120 M6 92243393005 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 D3 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 84 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. Pa89QMr6fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WETA/45119 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004 METHOD BLANK: 1174917 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 04/04/15 16:35 LABORATORY CONTROL SAMPLE: 1174918 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.1 51.3 102 80-120 MATRIX SPIKE SAMPLE: 1174920 92243391001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 56 57.3 102 80-120 H3 SAMPLE DUPLICATE: 1174919 92243391001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 85 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. Padg"lirpyN.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WETA/45121 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92243393005, 92243393006, 92243393007, 92243393008, 92243393009 METHOD BLANK: 1174925 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 04/05/15 03:35 LABORATORY CONTROL SAMPLE: 1174926 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.6 48.9 99 80-120 MATRIX SPIKE SAMPLE: 1174928 92243393005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 60.2 ND 96 80-120 H3 SAMPLE DUPLICATE: 1174927 92243393005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 86 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. Padg"rWyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030758 Pace Project No.: 92243393 QC Batch: WETA/28037 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92243393001, 92243393002, 92243393003, 92243393004, 92243393005, 92243393006, 92243393007, 92243393008,92243393009 METHOD BLANK: 1141398 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 04/17/15 05:46 LABORATORY CONTROL SAMPLE: 1141399 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 114000 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1141400 1141401 MS MSD 92243245001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 91000 114000 113000 193000 205000 89 101 50-150 6 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1141402 1141403 MS MSD 92243090001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 334J 6640 6650 6910 6120 99 87 50-150 12 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 87 of 93 Pace Analytical Services, Inc aceAnalXical ® pa�� ?(vfe. Suite100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15030758 Pace Project No.: 92243393 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. E Analyte concentration exceeded the calibration range. The reported result is estimated. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 88 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. PaWffl�116fyNe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: J15030758 92243393 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92243393001 2015009008 EPA 3050 MPRP/23429 EPA 6010 ICP/14330 92243393002 2015009009 EPA 3050 MPRP/23429 EPA 6010 ICP/14330 92243393003 2015009010 EPA 3050 MPRP/23429 EPA 6010 ICP/14330 92243393004 2015009014 EPA 3050 MPRP/23429 EPA 6010 ICP/14330 92243393005 2015009015 EPA 3050 MPRP/23429 EPA 6010 ICP/14330 92243393006 2015009016 EPA 3050 MPRP/23429 EPA6010 ICP/14330 92243393007 2015009011 EPA 3050 MPRP/23485 EPA 6010 ICP/14364 92243393008 2015009012 EPA 3050 MPRP/23485 EPA6010 ICP/14364 92243393009 2015009013 EPA 3050 MPRP/23485 EPA6010 ICP/14364 92243393001 2015009008 EPA 3050 MPRP/23430 EPA 6020 ICPM/9541 92243393002 2015009009 EPA 3050 MPRP/23430 EPA 6020 ICPM/9541 92243393003 2015009010 EPA 3050 MPRP/23430 EPA 6020 ICPM/9541 92243393004 2015009014 EPA 3050 MPRP/23430 EPA 6020 ICPM/9541 92243393005 2015009015 EPA 3050 MPRP/23430 EPA 6020 ICPM/9541 92243393006 2015009016 EPA 3050 MPRP/23430 EPA 6020 ICPM/9541 92243393007 2015009011 EPA 3050 MPRP/23486 EPA 6020 ICPM/9568 92243393008 2015009012 EPA 3050 MPRP/23486 EPA 6020 ICPM/9568 92243393009 2015009013 EPA 3050 MPRP/23486 EPA 6020 ICPM/9568 92243393010 2015009008 SPLP EPA 3020 MPRP/53629 EPA 6020A ICPM/23811 92243393011 2015009009 SPLP EPA 3020 MPRP/53629 EPA 6020A ICPM/23811 92243393012 2015009010 SPLP EPA 3020 MPRP/53629 EPA 6020A ICPM/23811 92243393013 2015009014 SPLP EPA 3020 MPRP/53629 EPA 6020A ICPM/23811 92243393014 2015009015 SPLP EPA 3020 MPRP/53629 EPA 6020A ICPM/23811 92243393015 2015009016 SPLP EPA 3020 MPRP/53629 EPA 6020A ICPM/23811 92243393016 2015009017 EPA 3020 MPRP/53405 EPA 6020A ICPM/23667 92243393017 2015009018 EPA 3020 MPRP/53405 EPA 6020A ICPM/23667 92243393018 2015009019 EPA 3020 MPRP/53405 EPA 6020A ICPM/23667 92243393010 2015009008 SPLP EPA 7470 MERP/13233 EPA 7470 MERC/15388 92243393011 2015009009 SPLP EPA 7470 MERP/13233 EPA 7470 MERC/15388 92243393012 2015009010 SPLP EPA 7470 MERP/13233 EPA 7470 MERC/15388 92243393013 2015009014 SPLP EPA 7470 MERP/13233 EPA 7470 MERC/15388 92243393014 2015009015 SPLP EPA 7470 MERP/13233 EPA 7470 MERC/15388 92243393015 2015009016 SPLP EPA 7470 MERP/13233 EPA 7470 MERC/15388 92243393016 2015009017 EPA 7470 MERP/13171 EPA 7470 MERC/15316 92243393017 2015009018 EPA 7470 MERP/13171 EPA 7470 MERC/15316 92243393018 2015009019 EPA 7470 MERP/13171 EPA 7470 MERC/15316 92243393001 2015009008 EPA 7471 MERP/5565 EPA 7471 MERC/5553 92243393002 2015009009 EPA 7471 MERP/5565 EPA 7471 MERC/5553 92243393003 2015009010 EPA 7471 MERP/5565 EPA 7471 MERC/5553 92243393004 2015009014 EPA 7471 MERP/5565 EPA 7471 MERC/5553 92243393005 2015009015 EPA 7471 MERP/5566 EPA 7471 MERC/5554 92243393006 2015009016 EPA 7471 MERP/5566 EPA 7471 MERC/5554 92243393007 2015009011 EPA 7471 MERP/5566 EPA 7471 MERC/5554 92243393008 2015009012 EPA 7471 MERP/5566 EPA 7471 MERC/5554 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Page 89 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. Pa89QM16fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030758 Pace Project No.: 92243393 Lab ID Sample ID QC Batch Method QC Batch 92243393009 2015009013 EPA 7471 M ERP/5566 92243393001 2015009008 ASTM D2974-87 PMST/3426 92243393002 2015009009 ASTM D2974-87 PMST/3426 92243393003 2015009010 ASTM D2974-87 PMST/3426 92243393004 2015009014 ASTM D2974-87 PMST/3426 92243393005 2015009015 ASTM D2974-87 PMST/3426 92243393006 2015009016 ASTM D2974-87 PMST/3426 92243393007 2015009011 ASTM D2974-87 PMST/3426 92243393008 2015009012 ASTM D2974-87 PMST/3426 92243393009 2015009013 ASTM D2974-87 PMST/3426 92243393001 2015009008 EPA 9045 WET/36662 92243393002 2015009009 EPA 9045 WET/36662 92243393003 2015009010 EPA 9045 WET/36662 92243393004 2015009014 EPA 9045 WET/36662 92243393005 2015009015 EPA 9045 WET/36662 92243393006 2015009016 EPA 9045 WET/36662 92243393007 2015009011 EPA 9045 WET/36610 92243393008 2015009012 EPA 9045 WET/36610 92243393009 2015009013 EPA 9045 WET/36610 92243393001 2015009008 EPA 300.0 WETA/22495 92243393002 2015009009 EPA 300.0 WETA/22495 92243393003 2015009010 EPA 300.0 WETA/22495 92243393004 2015009014 EPA 300.0 WETA/22495 92243393005 2015009015 EPA 300.0 WETA/22495 92243393006 2015009016 EPA 300.0 WETA/22495 92243393001 2015009008 EPA 353.2 WETA/22501 92243393002 2015009009 EPA 353.2 WETA/22501 92243393003 2015009010 EPA 353.2 WETA/22501 92243393004 2015009014 EPA 353.2 WETA/22501 92243393005 2015009015 EPA 353.2 WETA/22501 92243393006 2015009016 EPA 353.2 WETA/22501 92243393001 2015009008 SM 4500-CI-E WETA/22491 92243393002 2015009009 SM 4500-CI-E WETA/22491 92243393003 2015009010 SM 4500-CI-E WETA/22491 92243393004 2015009014 SM 4500-CI-E WETA/22491 92243393005 2015009015 SM 4500-CI-E WETA/22491 92243393006 2015009016 SM 4500-CI-E WETA/22491 92243393001 2015009008 EPA 9056 WETA/45120 92243393002 2015009009 EPA 9056 WETA/45120 92243393003 2015009010 EPA 9056 WETA/45120 92243393004 2015009014 EPA 9056 WETA/45120 92243393005 2015009015 EPA 9056 WETA/45122 92243393006 2015009016 EPA 9056 WETA/45122 92243393007 2015009011 EPA 9056 WETA/45122 92243393008 2015009012 EPA 9056 WETA/45122 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 03:25 PM without the written consent of Pace Analytical Services, Inc.. Analytical Method EPA 7471 Analytical Batch MERC/5554 Page 90 of 93 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. Pa89Qft16fy(%e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030758 Pace Project No.: 92243393 Lab ID Sample ID QC Batch Method QC Batch 92243393009 2015009013 EPA 9056 WETA/45122 92243393001 2015009008 EPA 9056 WETA/45119 92243393002 2015009009 EPA 9056 WETA/45119 92243393003 2015009010 EPA 9056 WETA/45119 92243393004 2015009014 EPA 9056 WETA/45119 92243393005 2015009015 EPA 9056 WETA/45121 92243393006 2015009016 EPA 9056 WETA/45121 92243393007 2015009011 EPA 9056 WETA/45121 92243393008 2015009012 EPA 9056 WETA/45121 92243393009 2015009013 EPA 9056 WETA/45121 92243393001 2015009008 EPA 9060 WETA/28037 92243393001 2015009008 EPA 9060 WETA/28038 92243393002 2015009009 EPA 9060 WETA/28037 92243393002 2015009009 EPA 9060 WETA/28038 92243393003 2015009010 EPA 9060 WETA/28037 92243393003 2015009010 EPA 9060 WETA/28038 92243393004 2015009014 EPA 9060 WETA/28037 92243393004 2015009014 EPA 9060 WETA/28038 92243393005 2015009015 EPA 9060 WETA/28037 92243393005 2015009015 EPA 9060 WETA/28038 92243393006 2015009016 EPA 9060 WETA/28037 92243393006 2015009016 EPA 9060 WETA/28038 92243393007 2015009011 EPA 9060 WETA/28037 92243393007 2015009011 EPA 9060 WETA/28038 92243393008 2015009012 EPA 9060 WETA/28037 92243393008 2015009012 EPA 9060 WETA/28038 92243393009 2015009013 EPA 9060 WETA/28037 92243393009 2015009013 EPA 9060 WETA/28038 Date: 04/27/2015 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 91 of 93 ace�trll�lytr`cfu Sample Condition Upon Receipt (SCUR) Page 1 of 2 Document Number: Issuing Authorit F-CHR-CS-003-rev.15 Pace HuntersvillePml ®� Client Name: D 14 K9- t;h e- LO-1 Courier: ❑ Fed Ex ❑ UPS❑ LISPS❑ Client❑ Commercial❑ Pa Other Custody Seal on Cooler/Box Present: ❑ yes V no Seals intact: ❑ yes L/J no Packing Material: ❑ Bubble V❑tp [] uGble Ba EV None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: et Blue None Samples on ice, cooling process has begun Temn Correction Factor T1401 No Correction Corrected Cooler Temp.: C • Biological Tissue is Frozen: Yes No N! Date and Ini Is f p ca I rig contents ] Temp should be above freezing to 6°C Comments: Chain of Custody Present: yes ❑No ❑NIA '1. Chain of Custody Filled Out: yes ONO ❑NIA 2. Chain of Custody Relinquished: 14yes ONO ❑NIA 3. Sampler Name & Signature on COC: ❑Yes No ❑NIA 4. Samples Arrived within Hold Time: Yes ONO ❑NIA 5. Short Hold Time Analysis (E72hr): Dyes ANo El NIA 6. Rush Turn Around Time Requested: Dyes IdNo ❑NIA 7. Sufficient Volume: Yes ONO El NIA $• Correct Containers Used: Yes ❑No ❑NIA 9. -Pace Containers Used: ayes ONO ❑NIA Containers Intact: Yes QNo ❑NIA 10. Filtered volume received for Dissolved tests [Dyes ONO IVNIA 11. Sample Labels match COC: Yes ONO ❑NIA 12. g -Includes dateltime/iD/Analysis Matrix• All containers needing preservation have been checked. es ❑No ❑N!A 13. All containers needing preservation are found to be in ury's ONO ❑NIA compliance with EPA recommendation. 1No exceptions: VOA, coliform, TOG, ORG, WI-DRO (water) ❑Yes Samples checked for dechlorination: Dyes ONo 1A 14, Headspace in VOA Vials (>6mm): Dyes ONO - UNIA 15. Trip Blank Present: ❑Yes ONO ZNIA 16. Trip Blank Custody Seals Present Dyes ONO NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Date[Time: Comments/ Resolution: SCURF RevIew:1 ICA Bate: 3 1 SRF Review: t Date: I d 1 l Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92243393 111111111111111111111111111 92243393 Page 92 of 93 Page 108 of 109 2 C C Q C, p o 04 W a GCX a o - ._.. ..- ._.._.. CU9tOMOr to carnplete appropriate calenms to rttlhi .._.._.._ 4 I Tr 0 b aQ C a ? w w (7 w w o O C 3 Q AP M 1 /f u C N tR O v vJ 13 0 t E y i A 'a. 0a M n C a c c a� y yo m Si fat N ri} 1"' > c d_ m y N CL » A Y N o n I 0, i R a n c � i F v o � I i i 11 Vi n(� ro 04 0 9 0 > a f I to Lr f -� -k t, w r, w rn z if1 m (i � 'f 00 D w m o r n p t 3 8 ! i> irCa f p. IOA lys g 2 I i D 11 a 1 16Grab Raq Ire w Total Metals , Anions, N W;� W O d ; U? pH oz jar (PACE) o y �{ P 1' TQC 1 -4 oz jar (PACE) 4 n Q 0 V X SPLP - Total Metals and r Anions 2. ' r o' - I i 8 0 oz jars (PACE) A r ; yyy111 ; J Sediment specific tests _ . 2.8 oz jar (ACCESS ANALYTICAL) of S 5 i i I I i rm1n� 002 0. 6 m o D N 0 r C s z 5� p s 29Total # of Containers N -4 So Page 93 of 93 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM --------- Analytical Lahoralory service ' s ---Ana- nai Leborato Use Onlwnrw Omer —"- DUKE FAm, 1uft *GGIAa '111iaii1d,nq 140-11 EC_ 133,39i "avers r�my Rd -Z'n -I SOIL t-10V Dow& yk� Runfeim-wille- N c. 2SD73 ENERUT V paq 8?5 5245 I e 9a�75 4141 L ct� *A Pi-F PROGRAM rmuro ------- DNPDE,' PMMI AS Groiundwcder Assess nnent S011 w HF 11H w Te f 3KIlan 3iFaPFEF AD GW i SYNTERRA EDD he Tmmoozw. 40 PACE PO 1142081 uj R 0 < CL 0 WW�n 2PGMFIC DMPUPT1109 has WWI 9S`tmbhi%Md &Ila is not Wolcxmd Abnwi, NO — I— nned Me nQ 1, Enter il wi; cc-uffmhbq lik all s qccaunling R61114 i4b6m Of odda'd within IS minuW* Of I&EMPIR V < �.mjjojj Uriji Awl Pmi:c%,i ID. OF P4 ---------- I'd cc LPi' me oui-v *4C01%w'0*n '2 a `tlMAW... 25 m r a] Z j I! S alliple Description or ID "Laic i C"11. '.'T��' : j7- A— 3- -.4 C -7- 1Yt- 0 13 L4 B ni'v- 3 - 3- S 3 -jw- Ze!j%Lq - 14 -15 All Va Lt D. 1. br WA-r�enL j F�L� UWALTFR E NT BLANK M PER DAYI T Metjjj. _AjSb, As, Rj;, i3*. 6. Cd, Ca, Cr, CO3 Cu, To, Pb, Mg, Mn- Mu, m- Anions: (-,I. Nitil`,71dr N. SO4 Siaddraent!SpECifilt PaFarnOlvm: %S'Dfidl , Ti, V, 7fl. MWOUeY. PH to Size Dj0ri1l!ikF1i0fb. R1!d0X fttentWl pwo I of I DISTROLMM ORICMAL to LAB, CI)VY to CLIF14T kFv DATE 2el 1107.01-1, .qqLmat&d Turnwowd 3�7 48 1-V