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Home My WebLink AboutNC0003417_J15030452 Report_20150805DUE Analytical Laboratory Page 1of83 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15030452 AB GW ASSESSMENT SOIL Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer 1677 Old Smithfield Rd Goldsboro NC 27530, Margaret Galvin -Karr Phone: 980-875-5219 ne gy. omn karr@duke- Er RGY1 2015.04.2113:49:44-04'00' Date: Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 4/21 /2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Page 2 of 83 Sample Description 2015007573 HF LEE PLANT 13-Mar-15 10:11 AM ILLEGIBLE Well ABMW-15B 29-31 2015007574 HF LEE PLANT 13-Mar-15 10:20 AM ILLEGIBLE Well ABMW-15B 32-33 2015007575 HF LEE PLANT 13-Mar-15 11:50 AM ILLEGIBLE Well ABMW-15B 42-44 2015007576 HF LEE PLANT 13-Mar-15 9:07 AM ILLEGIBLE Well ABMW-15B 13-15 2015007577 HF LEE PLANT 13-Mar-15 8:30 AM ILLEGIBLE Well ABMW-15B 3-5 2015007578 HF LEE PLANT 13-Mar-15 7:56 AM ILLEGIBLE Well Equipment Blank 6 Total Samples Page 3 of 83 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/21/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030452 Site: Well ABMW-15B 29-31 Collection Date: 13-Mar-15 10:11 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 83 Sample #: 2015007573 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030452 Site: Well ABMW-15B 32-33 Collection Date: 13-Mar-15 10:20 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 83 Sample #: 2015007574 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030452 Site: Well ABMW-15B 42-44 Collection Date: 13-Mar-15 11:50 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 83 Sample #: 2015007575 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030452 Site: Well ABMW-15B 13-15 Collection Date: 13-Mar-15 9:07 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 83 Sample #: 2015007576 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030452 Site: Well ABMW-15B 3-5 Collection Date: 13-Mar-15 8:30 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 83 Sample #: 2015007577 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis Page 9 of 83 This report shall not be reproduced, except in full. Order # J15030452 Site: Well Equipment Blank Collection Date: 13-Mar-15 7:56 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015007578 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, INC 28078 (704)875-9092 April 10, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15030452 Pace Project No.: 92241508 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 17, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 73 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. oQgg inlcSf841e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030452 Pace Project No.: 92241508 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030452 Pace Project No.: 92241508 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15030452 Pace Project No.: 92241508 Lab ID Sample ID Matrix Date Collected Date Received 92241508001 2015007573 Solid 03/13/1510:11 03/17/15 13:07 92241508002 2015007574 Solid 03/13/1510:20 03/17/15 13:07 92241508003 2015007575 Solid 03113/1511:50 03/17/15 13:07 92241508004 2015007576 Solid 03/13/15 09:07 03/17/15 13:07 92241508005 2015007577 Solid 03/13/15 08:30 03/17/15 13:07 92241508006 2015007578 Water 03/13/15 07:56 03/17/15 13:07 92241508007 2015007573 SPLP Water 03/13/15 10:11 03/17/15 13:07 92241508008 2015007574 SPLP Water 03/13/15 10:20 03/17/15 13:07 92241508009 2015007575 SPLP Water 03/13/15 11:50 03/17/15 13:07 92241508010 2015007576 SPLP Water 03/13/15 09:07 03/17/15 13:07 92241508011 2015007577 SPLP Water 03/13/15 08:30 03/17/15 13:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15030452 Pace Project No.: 92241508 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92241508001 2015007573 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241508002 2015007574 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241508003 2015007575 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241508004 2015007576 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15030452 Pace Project No.: 92241508 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241508005 2015007577 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92241508006 2015007578 EPA 6020A TT3 24 PASI-M EPA 7470 JDD 1 PASI-M 92241508007 2015007573 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92241508008 2015007574 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92241508009 2015007575 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92241508010 2015007576 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92241508011 2015007577 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g li %Y84Jre. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15030452 92241508 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241508001 2015007573 EPA 6010 Aluminum 12200 mg/kg 8.9 04/01/15 09:20 EPA 6010 Barium 244 mg/kg 0.89 04/01/15 09:20 EPA 6010 Beryllium 5.0 mg/kg 0.89 04/01/1511:11 D3 EPA 6010 Boron 43.1J mg/kg 44.6 04/01/1511:11 D3 EPA 6010 Calcium 3930 mg/kg 44.6 04/01/15 09:20 EPA 6010 Chromium 36.7 mg/kg 4.5 04/01/1511:11 D3 EPA 6010 Copper 68.2 mg/kg 4.5 04/01/1511:11 D3 EPA 6010 Iron 7740 mg/kg 3.6 04/01/15 09:20 EPA 6010 Magnesium 897 mg/kg 44.6 04/01/15 09:20 EPA 6010 Manganese 63.9 mg/kg 4.5 04/01/1511:11 D3 EPA 6010 Molybdenum 1.4 mg/kg 0.89 04/01/15 09:20 EPA 6010 Nickel 25.3 mg/kg 0.45 04/01/15 09:20 EPA 6010 Potassium 1580 mg/kg 89.3 04/01/15 09:20 EPA 6010 Sodium 311 mg/kg 89.3 04/01/15 09:20 EPA 6010 Strontium 237 mg/kg 0.89 04/01/15 09:20 EPA 6010 Zinc 35.7 mg/kg 1.8 04/01/15 09:20 EPA 6020 Arsenic 48.3 mg/kg 4.5 04/02/15 11:39 D4 EPA 6020 Cadmium 0.36J mg/kg 0.54 04/02/15 11:39 D3 EPA 6020 Cobalt 17.1 mg/kg 4.5 04/02/15 11:39 D3 EPA 6020 Lead 25.5 mg/kg 4.5 04/02/15 11:39 D3 EPA 6020 Selenium 16.9 mg/kg 4.5 04/02/15 11:39 D3 EPA 6020 Vanadium 108 mg/kg 4.5 04/02/15 11:39 D4 EPA7471 Mercury 0.26 mg/kg 0.014 04/01/1512:15 ASTM D2974-87 Percent Moisture 41.4 % 0.10 03/31/15 12:14 EPA 9045 pH at 25 Degrees C 7.1 Std. Units 0.10 03/24/15 23:50 EPA300.0 Sulfate 10.5 mg/L 6.8 04/02/1510:19 B,D3 EPA353.2 Nitrogen, Nitrate 322 mg/L 17.1 03/31/1519:03 B,H1 EPA 9060 Total Organic Carbon 52600 mg/kg 6010 03/26/15 12:19 EPA 9060 Total Organic Carbon 55900 mg/kg 5820 03/26/15 12:31 EPA 9060 Total Organic Carbon 59900 mg/kg 5910 03/26/15 12:43 EPA 9060 Total Organic Carbon 62400 mg/kg 5710 03/26/15 12:49 EPA 9060 Mean Total Organic Carbon 57700 mg/kg 5860 03/26/15 12:19 EPA 9060 RSD% 7.5 % 03/26/15 12:19 92241508002 2015007574 EPA 6010 Aluminum 4440 mg/kg 5.6 04/01/15 09:37 EPA 6010 Barium 17.9 mg/kg 0.56 04/01/15 09:37 EPA 6010 Beryllium 0.21 mg/kg 0.056 04/01/15 09:37 EPA 6010 Boron 2.2J mg/kg 2.8 04/01/15 09:37 EPA 6010 Calcium 482 mg/kg 28.2 04/01/15 09:37 EPA 6010 Chromium 4.5 mg/kg 0.28 04/01/15 09:37 EPA 6010 Copper 2.3 mg/kg 0.28 04/01/15 09:37 EPA 6010 Iron 6110 mg/kg 2.3 04/01/15 09:37 EPA 6010 Magnesium 189 mg/kg 28.2 04/01/15 09:37 EPA 6010 Manganese 39.9 mg/kg 0.28 04/01/15 09:37 EPA 6010 Molybdenum 2.1 mg/kg 0.56 04/01/15 09:37 EPA 6010 Nickel 1.0 mg/kg 0.28 04/01/15 09:37 EPA 6010 Potassium 140 mg/kg 56.3 04/01/15 09:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030452 Pace Project No.: 92241508 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92241508002 2015007574 EPA 6010 Strontium 19.6 mg/kg 0.56 04/01/15 09:37 EPA 6010 Zinc 4.5 mg/kg 1.1 04/01/15 09:37 EPA 6020 Arsenic 26.8 mg/kg 2.8 04/02/15 11:41 EPA 6020 Cobalt 1.6J mg/kg 2.8 04/02/15 11:41 EPA 6020 Lead 2.5J mg/kg 2.8 04/02/15 11:41 EPA 6020 Vanadium 12.0 mg/kg 2.8 04/02/15 11:41 EPA7471 Mercury 0.013 mg/kg 0.0091 04/01/1512:17 ASTM D2974-87 Percent Moisture 14.3 % 0.10 03/31/15 12:15 EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 03/24/15 23:50 EPA300.0 Sulfate 3.4 mg/L 2.3 04/01/1516:33 EPA353.2 Nitrogen, Nitrate 51.0 mg/L 4.7 03/31/1518:14 EPA 9060 Total Organic Carbon 468J mg/kg 700 03/26/15 13:42 EPA 9060 Total Organic Carbon 448J mg/kg 697 03/26/15 13:47 EPA 9060 Total Organic Carbon 453J mg/kg 695 03/26/15 13:53 EPA 9060 Total Organic Carbon 494J mg/kg 700 03/26/15 13:59 EPA 9060 Mean Total Organic Carbon 466J mg/kg 698 03/26/15 13:42 EPA 9060 RSD% 4.5 % 03/26/15 13:42 92241508003 2015007575 EPA 6010 Aluminum 584 mg/kg 56.0 04/01/1511:15 EPA 6010 Barium 15.3 mg/kg 5.6 04/01/1511:15 EPA 6010 Calcium 270J mg/kg 280 04/01/1511:15 EPA 6010 Chromium 2.7J mg/kg 2.8 04/01/1511:15 EPA 6010 Copper 8.3 mg/kg 2.8 04/01/1511:15 EPA 6010 Iron 4050 mg/kg 22.4 04/01/1511:15 EPA 6010 Manganese 7.6 mg/kg 2.8 04/01/1511:15 EPA 6010 Nickel 3.4 mg/kg 2.8 04/01/1511:15 EPA 6010 Strontium 6.3 mg/kg 5.6 04/01/1511:15 EPA 6020 Arsenic 10.1 mg/kg 2.8 04/02/15 11:44 EPA 6020 Cobalt 7.1 mg/kg 2.8 04/02/15 11:44 EPA 6020 Lead 6.8 mg/kg 2.8 04/02/15 11:44 EPA 6020 Selenium 4.0 mg/kg 2.8 04/02/15 11:44 EPA 6020 Vanadium 11.4 mg/kg 2.8 04/02/15 11:44 ASTM D2974-87 Percent Moisture 15.5 % 0.10 03/31/15 12:15 EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 03/24/15 23:50 EPA300.0 Sulfate 7.1 mg/L 2.4 04/01/1516:47 EPA353.2 Nitrogen, Nitrate 15.4 mg/L 1.2 03/31/1518:20 EPA 9060 Total Organic Carbon 662J mg/kg 716 03/26/15 14:05 EPA 9060 Total Organic Carbon 610J mg/kg 712 03/26/15 14:12 EPA 9060 Total Organic Carbon 654J mg/kg 709 03/26/15 14:18 EPA 9060 Total Organic Carbon 492J mg/kg 714 03/26/15 14:24 EPA 9060 Mean Total Organic Carbon 605J mg/kg 713 03/26/15 14:05 EPA 9060 RSD% 13.0 % 03/26/15 14:05 92241508004 2015007576 D4 D3 D3 D3 B B.H1 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 B B.H1 EPA 6010 Aluminum 10000 mg/kg 7.5 04/01/15 09:45 EPA 6010 Barium 273 mg/kg 0.75 04/01/15 09:45 EPA 6010 Beryllium 4.7 mg/kg 0.37 04/01/1511:19 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15030452 92241508 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241508004 2015007576 EPA 6010 Boron 21.0 mg/kg 18.7 04/01/1511:19 D3 EPA 6010 Calcium 2840 mg/kg 37.4 04/01/15 09:45 EPA 6010 Chromium 35.3 mg/kg 1.9 04/01/1511:19 D3 EPA 6010 Copper 72.3 mg/kg 1.9 04/01/1511:19 D3 EPA 6010 Iron 12900 mg/kg 3.0 04/01/15 09:45 EPA 6010 Magnesium 651 mg/kg 37.4 04/01/15 09:45 EPA 6010 Manganese 46.2 mg/kg 1.9 04/01/1511:19 D3 EPA 6010 Molybdenum 1.7 mg/kg 0.75 04/01/15 09:45 EPA 6010 Nickel 27.8 mg/kg 0.37 04/01/15 09:45 EPA 6010 Potassium 1150 mg/kg 74.7 04/01/15 09:45 EPA 6010 Sodium 264 mg/kg 74.7 04/01/15 09:45 EPA 6010 Strontium 236 mg/kg 0.75 04/01/15 09:45 EPA 6010 Zinc 31.1 mg/kg 1.5 04/01/15 09:45 EPA 6020 Arsenic 47.5 mg/kg 3.7 04/02/15 11:46 D4 EPA 6020 Cadmium 0.23J mg/kg 0.45 04/02/15 11:46 D3 EPA 6020 Cobalt 14.9 mg/kg 3.7 04/02/15 11:46 D3 EPA 6020 Lead 23.7 mg/kg 3.7 04/02/15 11:46 D3 EPA 6020 Selenium 6.6 mg/kg 3.7 04/02/15 11:46 D3 EPA 6020 Vanadium 96.6 mg/kg 3.7 04/02/15 11:46 D4 EPA7471 Mercury 0.22 mg/kg 0.012 04/01/1512:21 ASTM D2974-87 Percent Moisture 32.0 % 0.10 03/31/15 12:15 EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 03/24/15 23:50 EPA300.0 Sulfate 30.8 mg/L 5.9 04/02/1510:33 B,D3 EPA353.2 Nitrogen, Nitrate 518 mg/L 29.4 03/31/1519:10 B,H1 EPA 9060 Total Organic Carbon 32300 mg/kg 3020 03/26/15 14:31 EPA 9060 Total Organic Carbon 50600 mg/kg 2980 03/26/15 14:37 EPA 9060 Total Organic Carbon 37800 mg/kg 2990 03/26/15 14:43 EPA 9060 Total Organic Carbon 40600 mg/kg 2950 03/26/15 14:49 EPA 9060 Mean Total Organic Carbon 40300 mg/kg 2980 03/26/15 14:31 EPA 9060 RSD% 19.0 % 03/26/15 14:31 92241508005 2015007577 EPA 6010 Aluminum 4740 mg/kg 6.7 04/01/15 09:49 EPA 6010 Barium 231 mg/kg 0.67 04/01/15 09:49 EPA 6010 Beryllium 1.8 mg/kg 0.067 04/01/15 09:49 EPA 6010 Boron 12.8 mg/kg 3.4 04/01/15 09:49 EPA 6010 Calcium 1250 mg/kg 33.7 04/01/15 09:49 EPA 6010 Chromium 14.9 mg/kg 0.34 04/01/15 09:49 EPA 6010 Copper 29.7 mg/kg 0.34 04/01/15 09:49 EPA 6010 Iron 10200 mg/kg 2.7 04/01/15 09:49 EPA 6010 Magnesium 321 mg/kg 33.7 04/01/15 09:49 EPA 6010 Manganese 50.2 mg/kg 0.34 04/01/15 09:49 EPA 6010 Molybdenum 3.5 mg/kg 0.67 04/01/15 09:49 EPA 6010 Nickel 21.3 mg/kg 0.34 04/01/15 09:49 EPA 6010 Potassium 641 mg/kg 67.3 04/01/15 09:49 EPA 6010 Sodium 126 mg/kg 67.3 04/01/15 09:49 EPA 6010 Strontium 66.3 mg/kg 0.67 04/01/15 09:49 EPA 6010 Zinc 22.2 mg/kg 1.3 04/01/15 09:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffii�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15030452 92241508 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92241508005 2015007577 EPA 6020 Arsenic 24.3 mg/kg 3.4 04/02/15 11:48 D3 EPA 6020 Cobalt 12.0 mg/kg 3.4 04/02/15 11:48 D3 EPA 6020 Lead 11.2 mg/kg 3.4 04/02/15 11:48 D3 EPA 6020 Selenium 12.0 mg/kg 3.4 04/02/15 11:48 D3 EPA 6020 Vanadium 44.4 mg/kg 3.4 04/02/15 11:48 D4 EPA7471 Mercury 0.20 mg/kg 0.010 04/01/1512:23 ASTM D2974-87 Percent Moisture 23.7 % 0.10 03/31/15 12:15 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 03/26/15 11:30 EPA300.0 Sulfate 56.5 mg/L 52.4 04/01/1517:41 B,D3 EPA353.2 Nitrogen, Nitrate 391 mg/L 15.7 03/31/1519:12 B,H1,M6 EPA 9056 Sulfate 567 mg/kg 328 03/25/15 22:17 EPA 9060 Total Organic Carbon 98700 mg/kg 5180 03/26/15 14:55 EPA 9060 Total Organic Carbon 94600 mg/kg 5150 03/26/15 15:01 EPA 9060 Total Organic Carbon 104000 mg/kg 5150 03/26/15 15:07 EPA 9060 Total Organic Carbon 104000 mg/kg 5110 03/26/15 15:13 EPA 9060 Mean Total Organic Carbon 100000 mg/kg 5150 03/26/15 14:55 EPA 9060 RSD% 4.7 % 03/26/15 14:55 92241508006 2015007578 EPA 6020A Aluminum 16.6 ug/L 10.0 03/25/15 14:22 EPA 6020A Barium 0.54 ug/L 0.30 03/25/15 14:22 EPA 6020A Calcium 193 ug/L 40.0 03/25/15 14:22 EPA 6020A Lead 0.16 ug/L 0.10 03/25/15 14:22 EPA 6020A Magnesium 44.4 ug/L 10.0 03/25/15 14:22 EPA 6020A Manganese 1.3 ug/L 0.50 03/25/15 14:22 EPA 6020A Sodium 222 ug/L 50.0 03/25/15 14:22 EPA 6020A Strontium 0.89 ug/L 0.50 03/25/15 14:22 EPA 6020A Zinc 53.2 ug/L 5.0 03/25/15 14:22 92241508007 2015007573 SPLP EPA 6020A Aluminum 622 ug/L 10.0 04/08/15 15:00 EPA 6020A Antimony 19.8 ug/L 0.50 04/08/15 15:00 EPA 6020A Arsenic 39.6 ug/L 0.50 04/08/15 15:00 EPA 6020A Barium 439 ug/L 0.30 04/08/15 15:00 EPA 6020A Boron 192 ug/L 25.0 04/09/15 10:27 EPA 6020A Calcium 10600 ug/L 40.0 04/08/15 15:00 EPA 6020A Chromium 2.2 ug/L 0.50 04/08/15 15:00 EPA 6020A Copper 8.5 ug/L 1.0 04/08/15 15:00 EPA 6020A Iron 59.8 ug/L 50.0 04/08/15 15:00 EPA 6020A Lead 2.6 ug/L 0.10 04/08/15 15:00 EPA 6020A Magnesium 323 ug/L 10.0 04/08/15 15:00 EPA 6020A Manganese 9.4 ug/L 0.50 04/08/15 15:00 EPA 6020A Molybdenum 16.3 ug/L 0.50 04/08/15 15:00 EPA 6020A Nickel 2.7 ug/L 0.50 04/08/15 15:00 EPA 6020A Potassium 1010 ug/L 50.0 04/08/15 15:00 EPA 6020A Selenium 71.2 ug/L 0.50 04/08/15 15:00 EPA 6020A Sodium 2440 ug/L 50.0 04/08/15 15:00 EPA 6020A Strontium 278 ug/L 0.50 04/08/15 15:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030452 Pace Project No.: 92241508 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92241508007 2015007573 SPLP EPA 6020A Thallium 0.26 ug/L 0.10 04/08/15 15:00 EPA 6020A Vanadium 119 ug/L 1.0 04/08/15 15:00 EPA 6020A Zinc 227 ug/L 5.0 04/08/15 15:00 92241508008 2015007574 SPLP EPA 6020A Aluminum 845 ug/L 10.0 04/08/15 15:04 EPA 6020A Arsenic 39.7 ug/L 0.50 04/08/15 15:04 EPA 6020A Barium 32.9 ug/L 0.30 04/08/15 15:04 EPA 6020A Boron 481 ug/L 25.0 04/09/15 10:32 EPA 6020A Calcium 5610 ug/L 40.0 04/08/15 15:04 EPA 6020A Chromium 2.1 ug/L 0.50 04/08/15 15:04 EPA 6020A Cobalt 0.60 ug/L 0.50 04/08/15 15:04 EPA 6020A Copper 1.7 ug/L 1.0 04/08/15 15:04 EPA 6020A Iron 310 ug/L 50.0 04/08/15 15:04 EPA 6020A Lead 0.63 ug/L 0.10 04/08/15 15:04 EPA 6020A Magnesium 1160 ug/L 10.0 04/08/15 15:04 EPA 6020A Manganese 74.5 ug/L 0.50 04/08/15 15:04 EPA 6020A Molybdenum 6.0 ug/L 0.50 04/08/15 15:04 EPA 6020A Nickel 0.71 ug/L 0.50 04/08/15 15:04 EPA 6020A Potassium 1140 ug/L 50.0 04/08/15 15:04 EPA 6020A Sodium 9530 ug/L 50.0 04/08/15 15:04 EPA 6020A Strontium 129 ug/L 0.50 04/08/15 15:04 EPA 6020A Vanadium 1.3 ug/L 1.0 04/08/15 15:04 EPA 6020A Zinc 18.0 ug/L 5.0 04/08/15 15:04 92241508009 2015007575 SPLP EPA 6020A Aluminum 2360 ug/L 10.0 04/08/15 15:09 EPA 6020A Arsenic 2.7 ug/L 0.50 04/08/15 15:09 EPA 6020A Barium 68.9 ug/L 0.30 04/08/15 15:09 EPA 6020A Beryllium 0.47 ug/L 0.20 04/08/15 15:09 EPA 6020A Boron 29.1 ug/L 5.0 04/09/15 10:37 EPA 6020A Calcium 1020 ug/L 40.0 04/08/15 15:09 EPA 6020A Chromium 3.6 ug/L 0.50 04/08/15 15:09 EPA 6020A Cobalt 4.4 ug/L 0.50 04/08/15 15:09 EPA 6020A Copper 11.2 ug/L 1.0 04/08/15 15:09 EPA 6020A Iron 751 ug/L 50.0 04/08/15 15:09 EPA 6020A Lead 2.2 ug/L 0.10 04/08/15 15:09 EPA 6020A Magnesium 433 ug/L 10.0 04/08/15 15:09 EPA 6020A Manganese 22.4 ug/L 0.50 04/08/15 15:09 EPA 6020A Nickel 4.0 ug/L 0.50 04/08/15 15:09 EPA 6020A Potassium 722 ug/L 50.0 04/08/15 15:09 EPA 6020A Selenium 1.6 ug/L 0.50 04/08/15 15:09 EPA 6020A Sodium 376 ug/L 50.0 04/08/15 15:09 EPA 6020A Strontium 18.5 ug/L 0.50 04/08/15 15:09 EPA 6020A Vanadium 8.3 ug/L 1.0 04/08/15 15:09 EPA 6020A Zinc 29.9 ug/L 5.0 04/08/15 15:09 92241508010 2015007576 SPLP EPA 6020A Aluminum 225 ug/L 10.0 04/08/15 15:14 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiTvele. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030452 Pace Project No.: 92241508 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92241508010 2015007576 SPLP EPA 6020A Antimony 15.3 ug/L 0.50 04/08/15 15:14 EPA 6020A Arsenic 24.1 ug/L 0.50 04/08/15 15:14 EPA 6020A Barium 469 ug/L 1.5 04/09/15 10:51 EPA 6020A Boron 236 ug/L 25.0 04/09/15 10:51 EPA 6020A Calcium 3410 ug/L 40.0 04/08/15 15:14 EPA 6020A Chromium 1.9 ug/L 0.50 04/08/15 15:14 EPA 6020A Copper 8.4 ug/L 1.0 04/08/15 15:14 EPA 6020A Lead 3.0 ug/L 0.10 04/08/15 15:14 EPA 6020A Magnesium 454 ug/L 10.0 04/08/15 15:14 EPA 6020A Manganese 3.4 ug/L 0.50 04/08/15 15:14 EPA 6020A Molybdenum 77.8 ug/L 0.50 04/08/15 15:14 EPA 6020A Nickel 1.7 ug/L 0.50 04/08/15 15:14 EPA 6020A Potassium 1260 ug/L 50.0 04/08/15 15:14 EPA 6020A Selenium 23.3 ug/L 0.50 04/08/15 15:14 EPA 6020A Sodium 2460 ug/L 50.0 04/08/15 15:14 EPA 6020A Strontium 144 ug/L 0.50 04/08/15 15:14 EPA 6020A Thallium 0.36 ug/L 0.10 04/08/15 15:14 EPA 6020A Vanadium 171 ug/L 1.0 04/08/15 15:14 EPA 6020A Zinc 243 ug/L 5.0 04/08/15 15:14 92241508011 2015007577 SPLP EPA 6020A Aluminum 119 ug/L 10.0 04/08/15 15:19 EPA 6020A Antimony 2.2 ug/L 0.50 04/08/15 15:19 EPA 6020A Arsenic 1.9 ug/L 0.50 04/08/15 15:19 EPA 6020A Barium 374 ug/L 0.30 04/08/15 15:19 EPA 6020A Boron 203 ug/L 25.0 04/09/15 10:56 EPA 6020A Calcium 9080 ug/L 40.0 04/08/15 15:19 EPA 6020A Chromium 4.5 ug/L 0.50 04/08/15 15:19 EPA 6020A Cobalt 7.7 ug/L 0.50 04/08/15 15:19 EPA 6020A Copper 2.1 ug/L 1.0 04/08/15 15:19 EPA 6020A Lead 1.3 ug/L 0.10 04/08/15 15:19 EPA 6020A Magnesium 1750 ug/L 10.0 04/08/15 15:19 EPA 6020A Manganese 7.7 ug/L 0.50 04/08/15 15:19 EPA 6020A Molybdenum 9.1 ug/L 0.50 04/08/15 15:19 EPA 6020A Nickel 9.5 ug/L 0.50 04/08/15 15:19 EPA 6020A Potassium 1440 ug/L 50.0 04/08/15 15:19 EPA 6020A Selenium 33.2 ug/L 0.50 04/08/15 15:19 EPA 6020A Sodium 2790 ug/L 50.0 04/08/15 15:19 EPA 6020A Strontium 204 ug/L 0.50 04/08/15 15:19 EPA 6020A Thallium 0.22 ug/L 0.10 04/08/15 15:19 EPA 6020A Vanadium 20.1 ug/L 1.0 04/08/15 15:19 EPA 6020A Zinc 210 ug/L 5.0 04/08/15 15:19 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiQvele. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23320 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241225001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1169006) • Aluminum • Barium • Boron • Copper • Iron • Manganese • MSD (Lab ID: 1169007) • Aluminum • Boron • Iron • Strontium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiSvele. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 10, 2015 Analyte Comments: QC Batch: MPRP/23320 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007573 (Lab ID:92241508001) • Boron • Beryllium • Chromium • Copper • Manganese •2015007575 (Lab ID:92241508003) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015007576 (Lab ID:92241508004) • Boron • Beryllium • Chromium • Copper • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g 4-8 le. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23321 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241225002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1169010) • Antimony • Arsenic • Cobalt • Vanadium • MSD (Lab ID: 1169011) • Antimony • Arsenic • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 10, 2015 Analyte Comments: QC Batch: MPRP/23321 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007573 (Lab ID:92241508001) • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015007574 (Lab ID:92241508002) • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015007575 (Lab ID:92241508003) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015007576 (Lab ID:92241508004) • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015007577 (Lab ID:92241508005) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MS (Lab ID: 1169010) • Arsenic • Cadmium • Lead REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 10, 2015 Analyte Comments: QC Batch: MPRP/23321 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MS (Lab ID: 1169010) • Antimony • Selenium • Thallium • MSD (Lab ID: 1169011) • Arsenic • Cadmium • Lead • Antimony • Selenium • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. •2015007573 (Lab ID:92241508001) • Arsenic • Vanadium •2015007574 (Lab ID:92241508002) • Arsenic •2015007576 (Lab ID:92241508004) • Arsenic • Vanadium •2015007577 (Lab ID:92241508005) • Vanadium • MS (Lab ID: 1169010) • Cobalt • Vanadium • MSD (Lab ID: 1169011) • Cobalt • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015007573 (Lab ID:92241508001) • Antimony •2015007574 (Lab ID:92241508002) • Antimony •2015007575 (Lab ID:92241508003) • Antimony •2015007576 (Lab ID:92241508004) • Antimony •2015007577 (Lab ID:92241508005) • Antimony • BLANK (Lab ID: 1169008) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gl i -wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 10, 2015 Analyte Comments: QC Batch: MPRP/23321 N2: The lab does not hold TNI accreditation for this parameter. • LCS (Lab ID: 1169009) • Antimony • MS (Lab ID: 1169010) • Antimony • MSD (Lab ID: 1169011) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 10, 2015 General Information: 6 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53156 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241965005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1924656) • Aluminum • MSD (Lab ID: 1924657) • Aluminum QC Batch: MPRP/53405 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10301430001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1932878) • Calcium • Magnesium • Manganese • Sodium • MSD (Lab ID: 1932879) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i - e. Suite 100 �J Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 10, 2015 QC Batch: MPRP/53405 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10301430001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Aluminum • Calcium • Magnesium • Manganese • Potassium • Sodium Additional Comments: Analyte Comments: QC Batch: MPRP/53405 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1932878) • Calcium • MSD (Lab ID: 1932879) • Calcium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g Isnol e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: April 10, 2015 General Information: 6 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinivele. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g Isnol e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/36394 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1417563) • pH at 25 Degrees C QC Batch: WET/36412 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1418509) • pH at 25 Degrees C • DUP (Lab ID: 1418510) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gl�vele. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22391 B: Analyte was detected in the associated method blank. • BLANK for HBN 257604 [WETA/223 (Lab ID: 1422986) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/22391 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007573 (Lab ID:92241508001) • Sulfate •2015007576 (Lab ID:92241508004) • Sulfate •2015007577 (Lab ID:92241508005) • Sulfate • BLANK (Lab ID: 1422986) • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsi4vele. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015007573 (Lab ID:92241508001) •2015007574 (Lab ID:92241508002) •2015007575 (Lab ID:92241508003) •2015007576 (Lab ID:92241508004) •2015007577 (Lab ID:92241508005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22397 B: Analyte was detected in the associated method blank. • BLANK for HBN 257672 [WETA/223 (Lab ID: 1423312) • Nitrogen, Nitrate QC Batch: WETA/22398 B: Analyte was detected in the associated method blank. • BLANK for HBN 257673 [WETA/223 (Lab ID: 1423321) • Nitrogen, Nitrate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/22397 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387006,92241387007 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1423314) • Nitrogen, Nitrate • MS (Lab ID: 1423316) • Nitrogen, Nitrate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g Isnol e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 10, 2015 QC Batch: WETA/22397 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241387006,92241387007 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MSD (Lab ID: 1423315) • Nitrogen, Nitrate • MSD (Lab ID: 1423317) • Nitrogen, Nitrate QC Batch: WETA/22398 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241508005,92242371020 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1423323) • Nitrogen, Nitrate • MS (Lab ID: 1423325) • Nitrogen, Nitrate • MSD (Lab ID: 1423324) • Nitrogen, Nitrate • MSD (Lab ID: 1423326) • Nitrogen, Nitrate Additional Comments: Analyte Comments: QC Batch: WETA/22397 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1423312) • Nitrogen, Nitrate QC Batch: WETA/22398 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1423321) • Nitrogen, Nitrate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g Ise-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/22399 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007576 (Lab ID:92241508004) • Chloride •2015007577 (Lab ID:92241508005) • Chloride REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gl�vele. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44808 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007573 (Lab ID:92241508001) • Chloride • Sulfate •2015007574 (Lab ID:92241508002) • Chloride • Sulfate •2015007575 (Lab ID:92241508003) • Chloride • Sulfate •2015007576 (Lab ID:92241508004) • Chloride • Sulfate •2015007577 (Lab ID:92241508005) • Chloride REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g Ise-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015007573 (Lab ID:92241508001) •2015007574 (Lab ID:92241508002) •2015007575 (Lab ID:92241508003) •2015007576 (Lab ID:92241508004) •2015007577 (Lab ID:92241508005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44807 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015007573 (Lab ID:92241508001) • Nitrate as N •2015007574 (Lab ID:92241508002) • Nitrate as N •2015007575 (Lab ID:92241508003) • Nitrate as N •2015007576 (Lab ID:92241508004) • Nitrate as N •2015007577 (Lab ID:92241508005) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g Isnol e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030452 Pace Project No.: 92241508 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 10, 2015 General Information: 5 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wnml e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007573 Lab ID: 92241508001 Collected: 03/13/15 10:11 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/10/2015 07:25 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 12200 mg/kg 8.9 4.5 1 03/29/15 16:04 04/01/15 09:20 7429-90-5 244 mg/kg 0.89 0.45 1 03/29/15 16:04 04/01/15 09:20 7440-39-3 5.0 mg/kg 0.89 0.45 10 03/29/15 16:04 04/01/15 11:11 7440-41-7 D3 43.1J mg/kg 44.6 22.3 10 03/29/15 16:04 04/01/15 11:11 7440-42-8 D3 3930 mg/kg 44.6 22.3 1 03/29/15 16:04 04/01/15 09:20 7440-70-2 36.7 mg/kg 4.5 2.2 10 03/29/15 16:04 04/01/15 11:11 7440-47-3 D3 68.2 mg/kg 4.5 2.2 10 03/29/15 16:04 04/01/15 11:11 7440-50-8 D3 7740 mg/kg 3.6 1.8 1 03/29/15 16:04 04/01/15 09:20 7439-89-6 897 mg/kg 44.6 22.3 1 03/29/15 16:04 04/01/15 09:20 7439-95-4 63.9 mg/kg 4.5 2.2 10 03/29/15 16:04 04/01/15 11:11 7439-96-5 D3 1.4 mg/kg 0.89 0.45 1 03/29/15 16:04 04/01/15 09:20 7439-98-7 25.3 mg/kg 0.45 0.22 1 03/29/15 16:04 04/01/15 09:20 7440-02-0 1580 mg/kg 89.3 44.6 1 03/29/15 16:04 04/01/15 09:20 7440-09-7 311 mg/kg 89.3 44.6 1 03/29/15 16:04 04/01/15 09:20 7440-23-5 237 mg/kg 0.89 0.45 1 03/29/15 16:04 04/01/15 09:20 7440-24-6 35.7 mg/kg 1.8 0.89 1 03/29/15 16:04 04/01/15 09:20 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 4.5 2.2 50 03/29/15 16:04 04/02/1511:39 7440-36-0 D3,N2 48.3 mg/kg 4.5 2.2 50 03/29/15 16:04 04/02/1511:39 7440-38-2 D4 0.36J mg/kg 0.54 0.27 50 03/29/15 16:04 04/02/1511:39 7440-43-9 D3 17.1 mg/kg 4.5 2.2 50 03/29/15 16:04 04/02/1511:39 7440-48-4 D3 25.5 mg/kg 4.5 2.2 50 03/29/15 16:04 04/02/1511:39 7439-92-1 D3 16.9 mg/kg 4.5 2.2 50 03/29/15 16:04 04/02/1511:39 7782-49-2 D3 ND mg/kg 4.5 2.2 50 03/29/15 16:04 04/02/1511:39 7440-28-0 D3 108 mg/kg 4.5 2.2 50 03/29/15 16:04 04/02/1511:39 7440-62-2 D4 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.26 mg/kg 0.014 0.0070 1 03/31/1510:20 04/01/1512:15 7439-97-6 Analytical Method: ASTM D2974-87 41.4 % 0.10 0.10 1 03/31/1512:14 Analytical Method: EPA 9045 7.1 Std. Units 0.10 0.10 1 03/24/15 23:50 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/24/15 16:15 10.5 mg/L 6.8 3.4 2 04/02/1510:19 14808-79-8 B,D3 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/24/15 16:15 322 mg/L 17.1 17.1 50 03/31/1519:03 B,H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/24/15 16:15 ND mg/L 8.5 4.3 1 03/28/15 04:00 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwiyvele. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007573 Lab ID: 92241508001 Collected: 03/13/15 10:11 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 424 212 5 03/25/15 20:08 16887-00-6 D3 Sulfate ND mg/kg 424 212 5 03/25/15 20:08 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 42.4 21.2 5 03/25/15 20:08 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 52600 mg/kg 6010 3010 1 03/26/15 12:19 7440-44-0 Total Organic Carbon 55900 mg/kg 5820 2910 1 03/26/15 12:31 7440-44-0 Total Organic Carbon 59900 mg/kg 5910 2960 1 03/26/15 12:43 7440-44-0 Total Organic Carbon 62400 mg/kg 5710 2860 1 03/26/15 12:49 7440-44-0 Mean Total Organic Carbon 57700 mg/kg 5860 2930 1 03/26/15 12:19 7440-44-0 Surrogates RSD% 7.5 % 1 03/26/15 12:19 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wnml e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007574 Lab ID: 92241508002 Collected: 03/13/15 10:20 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/10/2015 07:25 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 4440 mg/kg 5.6 2.8 1 03/29/15 16:04 04/01/15 09:37 7429-90-5 17.9 mg/kg 0.56 0.28 1 03/29/15 16:04 04/01/15 09:37 7440-39-3 0.21 mg/kg 0.056 0.028 1 03/29/15 16:04 04/01/15 09:37 7440-41-7 2.2J mg/kg 2.8 1.4 1 03/29/15 16:04 04/01/15 09:37 7440-42-8 482 mg/kg 28.2 14.1 1 03/29/15 16:04 04/01/15 09:37 7440-70-2 4.5 mg/kg 0.28 0.14 1 03/29/15 16:04 04/01/15 09:37 7440-47-3 2.3 mg/kg 0.28 0.14 1 03/29/15 16:04 04/01/15 09:37 7440-50-8 6110 mg/kg 2.3 1.1 1 03/29/15 16:04 04/01/15 09:37 7439-89-6 189 mg/kg 28.2 14.1 1 03/29/15 16:04 04/01/15 09:37 7439-95-4 39.9 mg/kg 0.28 0.14 1 03/29/15 16:04 04/01/15 09:37 7439-96-5 2.1 mg/kg 0.56 0.28 1 03/29/15 16:04 04/01/15 09:37 7439-98-7 1.0 mg/kg 0.28 0.14 1 03/29/15 16:04 04/01/15 09:37 7440-02-0 140 mg/kg 56.3 28.2 1 03/29/15 16:04 04/01/15 09:37 7440-09-7 ND mg/kg 56.3 28.2 1 03/29/15 16:04 04/01/15 09:37 7440-23-5 19.6 mg/kg 0.56 0.28 1 03/29/15 16:04 04/01/15 09:37 7440-24-6 4.5 mg/kg 1.1 0.56 1 03/29/15 16:04 04/01/15 09:37 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:41 7440-36-0 D3,N2 26.8 mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:41 7440-38-2 D4 ND mg/kg 0.34 0.17 50 03/29/15 16:04 04/02/1511:41 7440-43-9 D3 1.6J mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:41 7440-48-4 D3 2.5J mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:41 7439-92-1 D3 ND mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:41 7782-49-2 D3 ND mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:41 7440-28-0 D3 12.0 mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:41 7440-62-2 D3 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.013 mg/kg 0.0091 0.0045 1 03/31/1510:20 04/01/1512:17 7439-97-6 Analytical Method: ASTM D2974-87 14.3 % 0.10 0.10 1 03/31/1512:15 Analytical Method: EPA 9045 7.2 Std. Units 0.10 0.10 1 03/24/15 23:50 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/24/15 16:15 3.4 mg/L 2.3 1.2 1 04/01/15 16:33 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/24/15 16:15 51.0 mg/L 4.7 4.7 20 03/31/1518:14 B,H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/24/15 16:15 ND mg/L 5.8 2.9 1 03/27/15 04:42 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wnml e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007574 Lab ID: 92241508002 Collected: 03/13/15 10:20 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 291 145 5 03/25/15 21:12 16887-00-6 D3 Sulfate ND mg/kg 291 145 5 03/25/15 21:12 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.1 14.5 5 03/25/15 21:12 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 468J mg/kg 700 350 1 03/26/15 13:42 7440-44-0 Total Organic Carbon 448J mg/kg 697 348 1 03/26/15 13:47 7440-44-0 Total Organic Carbon 453J mg/kg 695 347 1 03/26/15 13:53 7440-44-0 Total Organic Carbon 494J mg/kg 700 350 1 03/26/15 13:59 7440-44-0 Mean Total Organic Carbon 466J mg/kg 698 349 1 03/26/15 13:42 7440-44-0 Surrogates RSD% 4.5 % 1 03/26/15 13:42 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007575 Lab ID: 92241508003 Collected: 03/13/15 11:50 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/10/2015 07:25 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 584 mg/kg 56.0 28.0 10 03/29/15 16:04 04/01 /15 11:15 7429-90-5 D3 15.3 mg/kg 5.6 2.8 10 03/29/15 16:04 04/01/1511:15 7440-39-3 D3 ND mg/kg 0.56 0.28 10 03/29/15 16:04 04/01/1511:15 7440-41-7 D3 ND mg/kg 28.0 14.0 10 03/29/15 16:04 04/01/1511:15 7440-42-8 D3 270J mg/kg 280 140 10 03/29/15 16:04 04/01/1511:15 7440-70-2 D3 2.7J mg/kg 2.8 1.4 10 03/29/15 16:04 04/01/1511:15 7440-47-3 D3 8.3 mg/kg 2.8 1.4 10 03/29/15 16:04 04/01 /15 11:15 7440-50-8 D3 4050 mg/kg 22.4 11.2 10 03/29/15 16:04 04/01/1511:15 7439-89-6 D3 ND mg/kg 280 140 10 03/29/15 16:04 04/01/1511:15 7439-95-4 D3 7.6 mg/kg 2.8 1.4 10 03/29/15 16:04 04/01 /15 11:15 7439-96-5 D3 ND mg/kg 5.6 2.8 10 03/29/15 16:04 04/01/1511:15 7439-98-7 D3 3.4 mg/kg 2.8 1.4 10 03/29/15 16:04 04/01 /15 11:15 7440-02-0 D3 ND mg/kg 560 280 10 03/29/15 16:04 04/01/1511:15 7440-09-7 D3 ND mg/kg 560 280 10 03/29/15 16:04 04/01/1511:15 7440-23-5 D3 6.3 mg/kg 5.6 2.8 10 03/29/15 16:04 04/01 /15 11:15 7440-24-6 D3 ND mg/kg 11.2 5.6 10 03/29/15 16:04 04/01/1511:15 7440-66-6 D3 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:44 7440-36-0 D3,N2 10.1 mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:44 7440-38-2 D3 ND mg/kg 0.34 0.17 50 03/29/15 16:04 04/02/1511:44 7440-43-9 D3 7.1 mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:44 7440-48-4 D3 6.8 mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:44 7439-92-1 D3 4.0 mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:44 7782-49-2 D3 ND mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:44 7440-28-0 D3 11.4 mg/kg 2.8 1.4 50 03/29/15 16:04 04/02/1511:44 7440-62-2 D3 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0096 0.0048 1 03/31/1510:20 04/01/1512:19 7439-97-6 Analytical Method: ASTM D2974-87 15.5 % 0.10 0.10 1 03/31/1512:15 Analytical Method: EPA 9045 4.7 Std. Units 0.10 0.10 1 03/24/15 23:50 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/26/15 00:00 7.1 mg/L 2.4 1.2 1 04/01 /15 16:47 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/26/15 00:00 15.4 mg/L 1.2 1.2 5 03/31/1518:20 B,H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/26/15 00:00 ND mg/L 5.9 3.0 1 03/31/1515:24 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wnml e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007575 Lab ID: 92241508003 Collected: 03/13/15 11:50 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 296 148 5 03/25/15 21:34 16887-00-6 D3 Sulfate ND mg/kg 296 148 5 03/25/15 21:34 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.6 14.8 5 03/25/15 21:34 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 662J mg/kg 716 358 1 03/26/15 14:05 7440-44-0 Total Organic Carbon 610J mg/kg 712 356 1 03/26/15 14:12 7440-44-0 Total Organic Carbon 654J mg/kg 709 354 1 03/26/15 14:18 7440-44-0 Total Organic Carbon 492J mg/kg 714 357 1 03/26/15 14:24 7440-44-0 Mean Total Organic Carbon 605J mg/kg 713 356 1 03/26/15 14:05 7440-44-0 Surrogates RSD% 13.0 % 1 03/26/15 14:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g we-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007576 Lab ID: 92241508004 Collected: 03/13/15 09:07 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 04/10/2015 07:25 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 10000 mg/kg 7.5 3.7 1 03/29/15 16:04 04/01/15 09:45 7429-90-5 273 mg/kg 0.75 0.37 1 03/29/15 16:04 04/01/15 09:45 7440-39-3 4.7 mg/kg 0.37 0.19 5 03/29/15 16:04 04/01/15 11:19 7440-41-7 D3 21.0 mg/kg 18.7 9.3 5 03/29/15 16:04 04/01/15 11:19 7440-42-8 D3 2840 mg/kg 37.4 18.7 1 03/29/15 16:04 04/01/15 09:45 7440-70-2 35.3 mg/kg 1.9 0.93 5 03/29/15 16:04 04/01/15 11:19 7440-47-3 D3 72.3 mg/kg 1.9 0.93 5 03/29/15 16:04 04/01/15 11:19 7440-50-8 D3 12900 mg/kg 3.0 1.5 1 03/29/15 16:04 04/01/15 09:45 7439-89-6 651 mg/kg 37.4 18.7 1 03/29/15 16:04 04/01/15 09:45 7439-95-4 46.2 mg/kg 1.9 0.93 5 03/29/15 16:04 04/01/15 11:19 7439-96-5 D3 1.7 mg/kg 0.75 0.37 1 03/29/15 16:04 04/01/15 09:45 7439-98-7 27.8 mg/kg 0.37 0.19 1 03/29/15 16:04 04/01/15 09:45 7440-02-0 1150 mg/kg 74.7 37.4 1 03/29/15 16:04 04/01/15 09:45 7440-09-7 264 mg/kg 74.7 37.4 1 03/29/15 16:04 04/01/15 09:45 7440-23-5 236 mg/kg 0.75 0.37 1 03/29/15 16:04 04/01/15 09:45 7440-24-6 31.1 mg/kg 1.5 0.75 1 03/29/15 16:04 04/01/15 09:45 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 3.7 1.9 50 03/29/15 16:04 04/02/1511:46 7440-36-0 D3,N2 47.5 mg/kg 3.7 1.9 50 03/29/15 16:04 04/02/1511:46 7440-38-2 D4 0.23J mg/kg 0.45 0.22 50 03/29/15 16:04 04/02/1511:46 7440-43-9 D3 14.9 mg/kg 3.7 1.9 50 03/29/15 16:04 04/02/1511:46 7440-48-4 D3 23.7 mg/kg 3.7 1.9 50 03/29/15 16:04 04/02/1511:46 7439-92-1 D3 6.6 mg/kg 3.7 1.9 50 03/29/15 16:04 04/02/1511:46 7782-49-2 D3 ND mg/kg 3.7 1.9 50 03/29/15 16:04 04/02/1511:46 7440-28-0 D3 96.6 mg/kg 3.7 1.9 50 03/29/15 16:04 04/02/1511:46 7440-62-2 D4 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.22 mg/kg 0.012 0.0060 1 03/31/1510:20 04/01/1512:21 7439-97-6 Analytical Method: ASTM D2974-87 32.0 % 0.10 0.10 1 03/31/1512:15 Analytical Method: EPA 9045 6.8 Std. Units 0.10 0.10 1 03/24/15 23:50 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/26/15 00:00 30.8 mg/L 5.9 2.9 2 04/02/1510:33 14808-79-8 B,D3 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/26/15 00:00 518 mg/L 29.4 29.4 100 03/31/1519:10 B,H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/26/15 00:00 ND mg/L 36.7 18.4 5 03/31/1515:41 16887-00-6 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWi�vele. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007576 Lab ID: 92241508004 Collected: 03/13/15 09:07 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 367 184 5 03/25/15 21:55 16887-00-6 D3 Sulfate ND mg/kg 367 184 5 03/25/15 21:55 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 36.7 18.4 5 03/25/15 21:55 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 32300 mg/kg 3020 1510 1 03/26/15 14:31 7440-44-0 Total Organic Carbon 50600 mg/kg 2980 1490 1 03/26/15 14:37 7440-44-0 Total Organic Carbon 37800 mg/kg 2990 1490 1 03/26/15 14:43 7440-44-0 Total Organic Carbon 40600 mg/kg 2950 1480 1 03/26/15 14:49 7440-44-0 Mean Total Organic Carbon 40300 mg/kg 2980 1490 1 03/26/15 14:31 7440-44-0 Surrogates RSD% 19.0 % 1 03/26/15 14:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g we-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007577 Lab ID: 92241508005 Collected: 03/13/15 08:30 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 4740 mg/kg 6.7 3.4 1 03/29/15 16:04 04/01/15 09:49 7429-90-5 Barium 231 mg/kg 0.67 0.34 1 03/29/15 16:04 04/01/15 09:49 7440-39-3 Beryllium 1.8 mg/kg 0.067 0.034 1 03/29/15 16:04 04/01/15 09:49 7440-41-7 Boron 12.8 mg/kg 3.4 1.7 1 03/29/15 16:04 04/01/15 09:49 7440-42-8 Calcium 1250 mg/kg 33.7 16.8 1 03/29/15 16:04 04/01/15 09:49 7440-70-2 Chromium 14.9 mg/kg 0.34 0.17 1 03/29/15 16:04 04/01/15 09:49 7440-47-3 Copper 29.7 mg/kg 0.34 0.17 1 03/29/15 16:04 04/01/15 09:49 7440-50-8 Iron 10200 mg/kg 2.7 1.3 1 03/29/15 16:04 04/01/15 09:49 7439-89-6 Magnesium 321 mg/kg 33.7 16.8 1 03/29/15 16:04 04/01/15 09:49 7439-95-4 Manganese 50.2 mg/kg 0.34 0.17 1 03/29/15 16:04 04/01/15 09:49 7439-96-5 Molybdenum 3.5 mg/kg 0.67 0.34 1 03/29/15 16:04 04/01/15 09:49 7439-98-7 Nickel 21.3 mg/kg 0.34 0.17 1 03/29/15 16:04 04/01/15 09:49 7440-02-0 Potassium 641 mg/kg 67.3 33.7 1 03/29/15 16:04 04/01/15 09:49 7440-09-7 Sodium 126 mg/kg 67.3 33.7 1 03/29/15 16:04 04/01/15 09:49 7440-23-5 Strontium 66.3 mg/kg 0.67 0.34 1 03/29/15 16:04 04/01/15 09:49 7440-24-6 Zinc 22.2 mg/kg 1.3 0.67 1 03/29/15 16:04 04/01/15 09:49 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.4 1.7 50 03/29/15 16:04 04/02/1511:48 7440-36-0 D3,N2 Arsenic 24.3 mg/kg 3.4 1.7 50 03/29/15 16:04 04/02/1511:48 7440-38-2 D3 Cadmium ND mg/kg 0.40 0.20 50 03/29/15 16:04 04/02/1511:48 7440-43-9 D3 Cobalt 12.0 mg/kg 3.4 1.7 50 03/29/15 16:04 04/02/1511:48 7440-48-4 D3 Lead 11.2 mg/kg 3.4 1.7 50 03/29/15 16:04 04/02/1511:48 7439-92-1 D3 Selenium 12.0 mg/kg 3.4 1.7 50 03/29/15 16:04 04/02/1511:48 7782-49-2 D3 Thallium ND mg/kg 3.4 1.7 50 03/29/15 16:04 04/02/1511:48 7440-28-0 D3 Vanadium 44.4 mg/kg 3.4 1.7 50 03/29/15 16:04 04/02/1511:48 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.20 mg/kg 0.010 0.0052 1 03/31/1510:20 04/01/1512:23 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 23.7 % 0.10 0.10 1 03/31/15 12:15 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 03/26/15 11:30 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/26/15 00:00 Sulfate 56.5 mg/L 52.4 26.2 20 04/01/1517:41 14808-79-8 B,D3 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/26/15 00:00 Nitrogen, Nitrate 391 mg/L 15.7 15.7 60 03/31/15 19:12 B,H1, M6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wnml e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007577 Lab ID: 92241508005 Collected: 03/13/15 08:30 Received: 03/17/15 13:07 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Mean Total Organic Carbon Surrogates RSD% Date: 04/10/2015 07:25 AM Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/26/15 00:00 ND mg/L 32.8 16.4 5 03/31/1515:44 16887-00-6 D3 Analytical Method: EPA 9056 ND mg/kg 328 164 5 03/25/15 22:17 16887-00-6 D3 567 mg/kg 328 164 5 03/25/15 22:17 14808-79-8 Analytical Method: EPA 9056 ND mg/kg 32.8 16.4 5 03/25/15 22:17 14797-55-8 D3,H3 Analytical Method: EPA 9060 98700 mg/kg 5180 2590 1 03/26/1514:55 7440-44-0 94600 mg/kg 5150 2570 1 03/26/1515:01 7440-44-0 104000 mg/kg 5150 2580 1 03/26/1515:07 7440-44-0 104000 mg/kg 5110 2550 1 03/26/1515:13 7440-44-0 100000 mg/kg 5150 2570 1 03/26/1514:55 7440-44-0 4.7 % 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 03/26/15 14:55 Page 40 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007578 Lab ID: 92241508006 Collected: 03/13/15 07:56 Received: 03/17/15 13:07 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/10/2015 07:25 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 16.6 ug/L 10.0 1.2 1 03/25/15 05:54 03/25/15 14:22 7429-90-5 ND ug/L 0.50 0.25 1 03/25/15 05:54 03/25/15 14:22 7440-36-0 ND ug/L 0.50 0.25 1 03/25/15 05:54 03/25/15 14:22 7440-38-2 0.54 ug/L 0.30 0.14 1 03/25/15 05:54 03/25/15 14:22 7440-39-3 ND ug/L 0.20 0.066 1 03/25/15 05:54 03/25/15 14:22 7440-41-7 ND ug/L 5.0 1.0 1 03/25/15 05:54 03/25/15 14:22 7440-42-8 ND ug/L 0.080 0.033 1 03/25/15 05:54 03/25/15 14:22 7440-43-9 193 ug/L 40.0 8.4 1 03/25/15 05:54 03/25/15 14:22 7440-70-2 ND ug/L 0.50 0.22 1 03/25/15 05:54 03/25/15 14:22 7440-47-3 ND ug/L 0.50 0.25 1 03/25/15 05:54 03/25/15 14:22 7440-48-4 ND ug/L 1.0 0.22 1 03/25/15 05:54 03/25/15 14:22 7440-50-8 ND ug/L 50.0 8.0 1 03/25/15 05:54 03/25/15 14:22 7439-89-6 0.16 ug/L 0.10 0.046 1 03/25/15 05:54 03/25/15 14:22 7439-92-1 44.4 ug/L 10.0 2.8 1 03/25/15 05:54 03/25/15 14:22 7439-95-4 1.3 ug/L 0.50 0.14 1 03/25/15 05:54 03/25/15 14:22 7439-96-5 ND ug/L 0.50 0.24 1 03/25/15 05:54 03/25/15 14:22 7439-98-7 ND ug/L 0.50 0.23 1 03/25/15 05:54 03/25/15 14:22 7440-02-0 ND ug/L 50.0 8.3 1 03/25/15 05:54 03/25/15 14:22 7440-09-7 ND ug/L 0.50 0.25 1 03/25/15 05:54 03/25/15 14:22 7782-49-2 222 ug/L 50.0 18.2 1 03/25/15 05:54 03/25/15 14:22 7440-23-5 0.89 ug/L 0.50 0.057 1 03/25/15 05:54 03/25/15 14:22 7440-24-6 ND ug/L 0.10 0.025 1 03/25/15 05:54 03/25/15 14:22 7440-28-0 ND ug/L 1.0 0.21 1 03/25/15 05:54 03/25/15 14:22 7440-62-2 53.2 ug/L 5.0 2.5 1 03/25/15 05:54 03/25/15 14:22 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/24/15 19:35 03/25/15 20:21 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g inlvele. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007573 SPLP Lab ID: 92241508007 Collected: 03/13/15 10:11 Received: 03/17/15 13:07 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/10/2015 07:25 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 622 ug/L 10.0 3.0 1 04/05/15 20:48 04/08/15 15:00 7429-90-5 19.8 ug/L 0.50 0.15 1 04/05/15 20:48 04/08/15 15:00 7440-36-0 39.6 ug/L 0.50 0.11 1 04/05/15 20:48 04/08/15 15:00 7440-38-2 439 ug/L 0.30 0.081 1 04/05/15 20:48 04/08/15 15:00 7440-39-3 ND ug/L 0.20 0.067 1 04/05/15 20:48 04/08/15 15:00 7440-41-7 192 ug/L 25.0 5.6 5 04/05/15 20:48 04/09/15 10:27 7440-42-8 ND ug/L 0.080 0.024 1 04/05/15 20:48 04/08/15 15:00 7440-43-9 10600 ug/L 40.0 16.0 1 04/05/15 20:48 04/08/15 15:00 7440-70-2 2.2 ug/L 0.50 0.17 1 04/05/15 20:48 04/08/15 15:00 7440-47-3 ND ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:00 7440-48-4 8.5 ug/L 1.0 0.21 1 04/05/15 20:48 04/08/15 15:00 7440-50-8 59.8 ug/L 50.0 13.7 1 04/05/15 20:48 04/08/15 15:00 7439-89-6 2.6 ug/L 0.10 0.046 1 04/05/15 20:48 04/08/15 15:00 7439-92-1 323 ug/L 10.0 3.2 1 04/05/15 20:48 04/08/15 15:00 7439-95-4 9.4 ug/L 0.50 0.24 1 04/05/15 20:48 04/08/15 15:00 7439-96-5 16.3 ug/L 0.50 0.094 1 04/05/15 20:48 04/08/15 15:00 7439-98-7 2.7 ug/L 0.50 0.16 1 04/05/15 20:48 04/08/15 15:00 7440-02-0 1010 ug/L 50.0 11.7 1 04/05/15 20:48 04/08/15 15:00 7440-09-7 71.2 ug/L 0.50 0.20 1 04/05/15 20:48 04/08/15 15:00 7782-49-2 2440 ug/L 50.0 16.3 1 04/05/15 20:48 04/08/15 15:00 7440-23-5 278 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:00 7440-24-6 0.26 ug/L 0.10 0.015 1 04/05/15 20:48 04/08/15 15:00 7440-28-0 119 ug/L 1.0 0.28 1 04/05/15 20:48 04/08/15 15:00 7440-62-2 227 ug/L 5.0 2.4 1 04/05/15 20:48 04/08/15 15:00 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1518:47 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g iQvele. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007574 SPLP Lab ID: 92241508008 Collected: 03/13/15 10:20 Received: 03/17/15 13:07 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/10/2015 07:25 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 845 ug/L 10.0 3.0 1 04/05/15 20:48 04/08/15 15:04 7429-90-5 ND ug/L 0.50 0.15 1 04/05/15 20:48 04/08/15 15:04 7440-36-0 39.7 ug/L 0.50 0.11 1 04/05/15 20:48 04/08/15 15:04 7440-38-2 32.9 ug/L 0.30 0.081 1 04/05/15 20:48 04/08/15 15:04 7440-39-3 ND ug/L 0.20 0.067 1 04/05/15 20:48 04/08/15 15:04 7440-41-7 481 ug/L 25.0 5.6 5 04/05/15 20:48 04/09/15 10:32 7440-42-8 ND ug/L 0.080 0.024 1 04/05/15 20:48 04/08/15 15:04 7440-43-9 5610 ug/L 40.0 16.0 1 04/05/15 20:48 04/08/15 15:04 7440-70-2 2.1 ug/L 0.50 0.17 1 04/05/15 20:48 04/08/15 15:04 7440-47-3 0.60 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:04 7440-48-4 1.7 ug/L 1.0 0.21 1 04/05/15 20:48 04/08/15 15:04 7440-50-8 310 ug/L 50.0 13.7 1 04/05/15 20:48 04/08/15 15:04 7439-89-6 0.63 ug/L 0.10 0.046 1 04/05/15 20:48 04/08/15 15:04 7439-92-1 1160 ug/L 10.0 3.2 1 04/05/15 20:48 04/08/15 15:04 7439-95-4 74.5 ug/L 0.50 0.24 1 04/05/15 20:48 04/08/15 15:04 7439-96-5 6.0 ug/L 0.50 0.094 1 04/05/15 20:48 04/08/15 15:04 7439-98-7 0.71 ug/L 0.50 0.16 1 04/05/15 20:48 04/08/15 15:04 7440-02-0 1140 ug/L 50.0 11.7 1 04/05/15 20:48 04/08/15 15:04 7440-09-7 ND ug/L 0.50 0.20 1 04/05/15 20:48 04/08/15 15:04 7782-49-2 9530 ug/L 50.0 16.3 1 04/05/15 20:48 04/08/15 15:04 7440-23-5 129 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:04 7440-24-6 ND ug/L 0.10 0.015 1 04/05/15 20:48 04/08/15 15:04 7440-28-0 1.3 ug/L 1.0 0.28 1 04/05/15 20:48 04/08/15 15:04 7440-62-2 18.0 ug/L 5.0 2.4 1 04/05/15 20:48 04/08/15 15:04 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1518:55 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 43 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g inml e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007575 SPLP Lab ID: 92241508009 Collected: 03/13/15 11:50 Received: 03/17/15 13:07 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/10/2015 07:25 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 2360 ug/L 10.0 3.0 1 04/05/15 20:48 04/08/15 15:09 7429-90-5 ND ug/L 0.50 0.15 1 04/05/15 20:48 04/08/15 15:09 7440-36-0 2.7 ug/L 0.50 0.11 1 04/05/15 20:48 04/08/15 15:09 7440-38-2 68.9 ug/L 0.30 0.081 1 04/05/15 20:48 04/08/15 15:09 7440-39-3 0.47 ug/L 0.20 0.067 1 04/05/15 20:48 04/08/15 15:09 7440-41-7 29.1 ug/L 5.0 1.1 1 04/05/15 20:48 04/09/15 10:37 7440-42-8 ND ug/L 0.080 0.024 1 04/05/15 20:48 04/08/15 15:09 7440-43-9 1020 ug/L 40.0 16.0 1 04/05/15 20:48 04/08/15 15:09 7440-70-2 3.6 ug/L 0.50 0.17 1 04/05/15 20:48 04/08/15 15:09 7440-47-3 4.4 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:09 7440-48-4 11.2 ug/L 1.0 0.21 1 04/05/15 20:48 04/08/15 15:09 7440-50-8 751 ug/L 50.0 13.7 1 04/05/15 20:48 04/08/15 15:09 7439-89-6 2.2 ug/L 0.10 0.046 1 04/05/15 20:48 04/08/15 15:09 7439-92-1 433 ug/L 10.0 3.2 1 04/05/15 20:48 04/08/15 15:09 7439-95-4 22.4 ug/L 0.50 0.24 1 04/05/15 20:48 04/08/15 15:09 7439-96-5 ND ug/L 0.50 0.094 1 04/05/15 20:48 04/08/15 15:09 7439-98-7 4.0 ug/L 0.50 0.16 1 04/05/15 20:48 04/08/15 15:09 7440-02-0 722 ug/L 50.0 11.7 1 04/05/15 20:48 04/08/15 15:09 7440-09-7 1.6 ug/L 0.50 0.20 1 04/05/15 20:48 04/08/15 15:09 7782-49-2 376 ug/L 50.0 16.3 1 04/05/15 20:48 04/08/15 15:09 7440-23-5 18.5 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:09 7440-24-6 ND ug/L 0.10 0.015 1 04/05/15 20:48 04/08/15 15:09 7440-28-0 8.3 ug/L 1.0 0.28 1 04/05/15 20:48 04/08/15 15:09 7440-62-2 29.9 ug/L 5.0 2.4 1 04/05/15 20:48 04/08/15 15:09 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1518:57 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 44 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007576 SPLP Lab ID: 92241508010 Collected: 03/13/15 09:07 Received: 03/17/15 13:07 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/10/2015 07:25 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 225 ug/L 10.0 3.0 1 04/05/15 20:48 04/08/15 15:14 7429-90-5 15.3 ug/L 0.50 0.15 1 04/05/15 20:48 04/08/15 15:14 7440-36-0 24.1 ug/L 0.50 0.11 1 04/05/15 20:48 04/08/15 15:14 7440-38-2 469 ug/L 1.5 0.40 5 04/05/15 20:48 04/09/15 10:51 7440-39-3 ND ug/L 0.20 0.067 1 04/05/15 20:48 04/08/15 15:14 7440-41-7 236 ug/L 25.0 5.6 5 04/05/15 20:48 04/09/15 10:51 7440-42-8 ND ug/L 0.080 0.024 1 04/05/15 20:48 04/08/15 15:14 7440-43-9 3410 ug/L 40.0 16.0 1 04/05/15 20:48 04/08/15 15:14 7440-70-2 1.9 ug/L 0.50 0.17 1 04/05/15 20:48 04/08/15 15:14 7440-47-3 ND ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:14 7440-48-4 8.4 ug/L 1.0 0.21 1 04/05/15 20:48 04/08/15 15:14 7440-50-8 ND ug/L 50.0 13.7 1 04/05/15 20:48 04/08/15 15:14 7439-89-6 3.0 ug/L 0.10 0.046 1 04/05/15 20:48 04/08/15 15:14 7439-92-1 454 ug/L 10.0 3.2 1 04/05/15 20:48 04/08/15 15:14 7439-95-4 3.4 ug/L 0.50 0.24 1 04/05/15 20:48 04/08/15 15:14 7439-96-5 77.8 ug/L 0.50 0.094 1 04/05/15 20:48 04/08/15 15:14 7439-98-7 1.7 ug/L 0.50 0.16 1 04/05/15 20:48 04/08/15 15:14 7440-02-0 1260 ug/L 50.0 11.7 1 04/05/15 20:48 04/08/15 15:14 7440-09-7 23.3 ug/L 0.50 0.20 1 04/05/15 20:48 04/08/15 15:14 7782-49-2 2460 ug/L 50.0 16.3 1 04/05/15 20:48 04/08/15 15:14 7440-23-5 144 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:14 7440-24-6 0.36 ug/L 0.10 0.015 1 04/05/15 20:48 04/08/15 15:14 7440-28-0 171 ug/L 1.0 0.28 1 04/05/15 20:48 04/08/15 15:14 7440-62-2 243 ug/L 5.0 2.4 1 04/05/15 20:48 04/08/15 15:14 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1519:00 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 45 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030452 Pace Project No.: 92241508 Sample: 2015007577 SPLP Lab ID: 92241508011 Collected: 03/13/15 08:30 Received: 03/17/15 13:07 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\��il=11 a r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/10/2015 07:25 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 119 ug/L 10.0 3.0 1 04/05/15 20:48 04/08/15 15:19 7429-90-5 2.2 ug/L 0.50 0.15 1 04/05/15 20:48 04/08/15 15:19 7440-36-0 1.9 ug/L 0.50 0.11 1 04/05/15 20:48 04/08/15 15:19 7440-38-2 374 ug/L 0.30 0.081 1 04/05/15 20:48 04/08/15 15:19 7440-39-3 ND ug/L 0.20 0.067 1 04/05/15 20:48 04/08/15 15:19 7440-41-7 203 ug/L 25.0 5.6 5 04/05/15 20:48 04/09/15 10:56 7440-42-8 ND ug/L 0.080 0.024 1 04/05/15 20:48 04/08/15 15:19 7440-43-9 9080 ug/L 40.0 16.0 1 04/05/15 20:48 04/08/15 15:19 7440-70-2 4.5 ug/L 0.50 0.17 1 04/05/15 20:48 04/08/15 15:19 7440-47-3 7.7 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:19 7440-48-4 2.1 ug/L 1.0 0.21 1 04/05/15 20:48 04/08/15 15:19 7440-50-8 ND ug/L 50.0 13.7 1 04/05/15 20:48 04/08/15 15:19 7439-89-6 1.3 ug/L 0.10 0.046 1 04/05/15 20:48 04/08/15 15:19 7439-92-1 1750 ug/L 10.0 3.2 1 04/05/15 20:48 04/08/15 15:19 7439-95-4 7.7 ug/L 0.50 0.24 1 04/05/15 20:48 04/08/15 15:19 7439-96-5 9.1 ug/L 0.50 0.094 1 04/05/15 20:48 04/08/15 15:19 7439-98-7 9.5 ug/L 0.50 0.16 1 04/05/15 20:48 04/08/15 15:19 7440-02-0 1440 ug/L 50.0 11.7 1 04/05/15 20:48 04/08/15 15:19 7440-09-7 33.2 ug/L 0.50 0.20 1 04/05/15 20:48 04/08/15 15:19 7782-49-2 2790 ug/L 50.0 16.3 1 04/05/15 20:48 04/08/15 15:19 7440-23-5 204 ug/L 0.50 0.13 1 04/05/15 20:48 04/08/15 15:19 7440-24-6 0.22 ug/L 0.10 0.015 1 04/05/15 20:48 04/08/15 15:19 7440-28-0 20.1 ug/L 1.0 0.28 1 04/05/15 20:48 04/08/15 15:19 7440-62-2 210 ug/L 5.0 2.4 1 04/05/15 20:48 04/08/15 15:19 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1519:02 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 46 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g uvele. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: MERP/13047 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92241508006 METHOD BLANK: 1924347 Matrix: Water Associated Lab Samples: 92241508006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/25/1519:52 LABORATORY CONTROL SAMPLE: 1924348 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1924438 1924439 MS MSD 92241961004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 5.0 99 100 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g "-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: MERP/13139 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92241508007, 92241508008, 92241508009, 92241508010, 92241508011 METHOD BLANK: 1932636 Matrix: Water Associated Lab Samples: 92241508007, 92241508008, 92241508009, 92241508010, 92241508011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/06/1518:28 LABORATORY CONTROL SAMPLE: 1932637 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.8 116 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1932638 1932639 MS MSD 92239540007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 15 15 16.1 16.0 107 106 75-125 1 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: MERP/5527 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 METHOD BLANK: 1169331 Matrix: Solid Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 03/31/1516:38 LABORATORY CONTROL SAMPLE: 1169332 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.093 116 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1169333 1169334 MS MSD 92241225001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.18 .124 .124 0.32 0.31 111 102 80-120 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: MPRP/23320 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 METHOD BLANK: 1169004 Matrix: Solid Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.1 03/31/1515:47 Barium mg/kg ND 0.51 03/31/1515:47 Beryllium mg/kg ND 0.051 03/31/1515:47 Boron mg/kg ND 2.5 03/31/1515:47 Calcium mg/kg ND 25.4 03/31/1515:47 Chromium mg/kg ND 0.25 03/31/1515:47 Copper mg/kg ND 0.25 03/31/1515:47 Iron mg/kg ND 2.0 03/31/1515:47 Magnesium mg/kg ND 25.4 03/31/1515:47 Manganese mg/kg ND 0.25 03/31/1515:47 Molybdenum mg/kg ND 0.51 03/31/1515:47 Nickel mg/kg ND 0.25 03/31/1515:47 Potassium mg/kg ND 50.9 03/31/1515:47 Sodium mg/kg ND 50.9 03/31/1515:47 Strontium mg/kg ND 0.51 03/31/1515:47 Zinc mg/kg ND 1.0 03/31/1515:47 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1169005 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 133 105 80-120 Barium mg/kg 12.7 13.5 107 80-120 Beryllium mg/kg 1.3 1.3 103 80-120 Boron mg/kg 127 129 101 80-120 Calcium mg/kg 634 666 105 80-120 Chromium mg/kg 12.7 12.8 101 80-120 Copper mg/kg 12.7 12.4 98 80-120 Iron mg/kg 127 133 105 80-120 Magnesium mg/kg 634 663 104 80-120 Manganese mg/kg 12.7 13.0 103 80-120 Molybdenum mg/kg 12.7 12.7 100 80-120 Nickel mg/kg 12.7 13.2 104 80-120 Potassium mg/kg 634 684 108 80-120 Sodium mg/kg 634 706 111 80-120 Strontium mg/kg 12.7 13.1 104 80-120 Zinc mg/kg 63.4 65.8 104 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1169006 1169007 MS MSD 92241225001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 10600 192 198 14300 14000 1930 1700 75-125 2 20 M1 Barium mg/kg 206 19.2 19.8 213 230 36 122 75-125 8 20 M1 Beryllium mg/kg 1.9 1.96 1.96 3.4 3.6 77 85 75-125 6 20 Boron mg/kg 12.2 192 198 149 155 71 72 75-125 4 20 M1 Calcium mg/kg 1660 958 990 2600 2660 98 101 75-125 2 20 Chromium mg/kg 18.8 19.2 19.8 37.2 35.3 96 84 75-125 5 20 Copper mg/kg 30.6 19.2 19.8 43.0 47.2 65 84 75-125 9 20 M1 Iron mg/kg 11500 192 198 13500 13400 1050 977 75-125 1 20 M1 Magnesium mg/kg 2500 958 990 3610 3700 116 122 75-125 3 20 Manganese mg/kg 139 19.2 19.8 150 154 57 76 75-125 3 20 M1 Molybdenum mg/kg 7.1 19.2 19.8 23.3 23.9 84 85 75-125 3 20 Nickel mg/kg 16.4 19.2 19.8 33.8 34.5 91 92 75-125 2 20 Potassium mg/kg 1930 958 990 3020 3150 114 123 75-125 4 20 Sodium mg/kg 205 958 990 1120 1140 96 95 75-125 2 20 Strontium mg/kg 97.4 19.2 19.8 118 123 106 130 75-125 5 20 M1 Zinc mg/kg 34.3 95.8 99 117 123 87 89 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gI inlvele. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: MPRP/23321 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 METHOD BLANK: 1169008 Matrix: Solid Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/02/1510:23 N2 Arsenic mg/kg ND 0.051 04/02/1510:23 Cadmium mg/kg ND 0.0062 04/02/1510:23 Cobalt mg/kg ND 0.051 04/02/1510:23 Lead mg/kg ND 0.051 04/02/1510:23 Selenium mg/kg ND 0.051 04/02/1510:23 Thallium mg/kg ND 0.051 04/02/1510:23 Vanadium mg/kg ND 0.051 04/02/1510:23 LABORATORY CONTROL SAMPLE: Parameter 1169009 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.6 2.5 98 80-120 N2 Arsenic mg/kg 2.6 2.6 100 80-120 Cadmium mg/kg .26 0.26 102 80-120 Cobalt mg/kg 2.6 2.6 100 80-120 Lead mg/kg 2.6 2.5 97 80-120 Selenium mg/kg 2.6 2.7 105 80-120 Thallium mg/kg 2.6 2.6 99 80-120 Vanadium mg/kg 2.6 2.6 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1169010 MS 92241225002 Spike Parameter Units Result Conc. MSD Spike Conc. 1169011 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 3.04 2.92 2.2J 1.91 59 51 75-125 20 D3,M6, N2 Arsenic mg/kg 8.0 3.04 2.92 14.5 12.7 213 160 75-125 13 20 D3,M6 Cadmium mg/kg ND .304 .292 0.40 0.43 98 109 75-125 6 20 D3 Cobalt mg/kg 20.9 3.04 2.92 25.0 24.3 133 114 75-125 3 20 D4,M6 Lead mg/kg 5.1 3.04 2.92 7.8 7.8 88 91 75-125 0 20 D3 Selenium mg/kg 5.4 3.04 2.92 8.4 7.4 100 69 75-125 13 20 D3,M6 Thallium mg/kg ND 3.04 2.92 3.8 3.1 111 93 75-125 19 20 D3 Vanadium mg/kg 59.5 3.04 2.92 64.0 67.5 150 272 75-125 5 20 D4,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gI iQvele. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: MPRP/53156 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92241508006 METHOD BLANK: 1924642 Associated Lab Samples: 92241508006 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/25/1510:50 ND 0.50 03/25/1510:50 ND 0.50 03/25/1510:50 ND 0.30 03/25/1510:50 ND 0.20 03/25/1510:50 ND 5.0 03/25/1510:50 ND 0.080 03/25/1510:50 ND 40.0 03/25/1510:50 ND 0.50 03/25/1510:50 ND 0.50 03/25/1510:50 ND 1.0 03/25/1510:50 ND 50.0 03/25/1510:50 ND 0.10 03/25/1510:50 ND 10.0 03/25/1510:50 ND 0.50 03/25/1510:50 ND 0.50 03/25/1510:50 ND 0.50 03/25/1510:50 ND 50.0 03/25/1510:50 ND 0.50 03/25/1510:50 ND 50.0 03/25/1510:50 ND 0.50 03/25/1510:50 ND 0.10 03/25/1510:50 ND 1.0 03/25/1510:50 ND 5.0 03/25/1510:50 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1924643 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 83.7 105 80-120 Antimony ug/L 80 80.4 101 80-120 Arsenic ug/L 80 80.8 101 80-120 Barium ug/L 80 78.0 98 80-120 Beryllium ug/L 80 84.5 106 80-120 Boron ug/L 80 79.5 99 80-120 Cadmium ug/L 80 84.3 105 80-120 Calcium ug/L 1000 1090 109 80-120 Chromium ug/L 80 84.5 106 80-120 Cobalt ug/L 80 83.3 104 80-120 Copper ug/L 80 88.3 110 80-120 Iron ug/L 1000 1070 107 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 53 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qgl�i - e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 LABORATORY CONTROL SAMPLE: 1924643 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 78.4 98 80-120 Magnesium ug/L 1000 1040 104 80-120 Manganese ug/L 80 84.7 106 80-120 Molybdenum ug/L 80 81.6 102 80-120 Nickel ug/L 80 86.1 108 80-120 Potassium ug/L 1000 1030 103 80-120 Selenium ug/L 80 80.7 101 80-120 Sodium ug/L 1000 1040 104 80-120 Strontium ug/L 80 81.0 101 80-120 Thallium ug/L 80 84.5 106 80-120 Vanadium ug/L 80 82.4 103 80-120 Zinc ug/L 80 83.4 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1924656 1924657 MS MSD 92241965005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 53.2 80 80 167 170 142 146 75-125 2 20 M1 Antimony ug/L ND 80 80 80.4 79.2 100 99 75-125 1 20 Arsenic ug/L ND 80 80 81.4 80.6 102 101 75-125 1 20 Barium ug/L 1.4 80 80 81.6 81.1 100 100 75-125 1 20 Beryllium ug/L ND 80 80 86.0 87.1 108 109 75-125 1 20 Boron ug/L ND 80 80 80.6 84.9 99 104 75-125 5 20 Cadmium ug/L ND 80 80 85.5 86.2 107 108 75-125 1 20 Calcium ug/L 68.6 1000 1000 1210 1160 114 109 75-125 4 20 Chromium ug/L ND 80 80 85.5 84.9 107 106 75-125 1 20 Cobalt ug/L ND 80 80 85.7 85.5 107 107 75-125 0 20 Copper ug/L ND 80 80 90.1 90.3 112 113 75-125 0 20 Iron ug/L ND 1000 1000 1140 1120 109 107 75-125 2 20 Lead ug/L ND 80 80 79.4 79.3 99 99 75-125 0 20 Magnesium ug/L 11.5 1000 1000 1060 1040 105 103 75-125 2 20 Manganese ug/L 0.92 80 80 86.2 85.2 107 105 75-125 1 20 Molybdenum ug/L ND 80 80 82.9 82.4 103 103 75-125 1 20 Nickel ug/L ND 80 80 87.7 87.3 109 109 75-125 0 20 Potassium ug/L ND 1000 1000 1060 1050 103 102 75-125 1 20 Selenium ug/L ND 80 80 82.0 81.4 102 102 75-125 1 20 Sodium ug/L 94.3 1000 1000 1100 1080 100 98 75-125 2 20 Strontium ug/L 0.74 80 80 83.1 82.5 103 102 75-125 1 20 Thallium ug/L ND 80 80 83.8 83.8 105 105 75-125 0 20 Vanadium ug/L ND 80 80 82.5 81.3 103 102 75-125 1 20 Zinc ug/L ND 80 80 85.6 84.5 106 105 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 54 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gt 4-8 le. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: MPRP/53405 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92241508007, 92241508008, 92241508009, 92241508010, 92241508011 METHOD BLANK: 1932876 Matrix: Water Associated Lab Samples: 92241508007, 92241508008, 92241508009, 92241508010, 92241508011 Blank Reporting Parameter Units Result Limit Analyzed Aluminum ug/L ND 10.0 04/08/1514:02 Antimony ug/L ND 0.50 04/08/1514:02 Arsenic ug/L ND 0.50 04/08/1514:02 Barium ug/L ND 0.30 04/08/1514:02 Beryllium ug/L ND 0.20 04/08/1514:02 Boron ug/L ND 5.0 04/09/15 09:54 Cadmium ug/L ND 0.080 04/08/1514:02 Calcium ug/L ND 40.0 04/08/1514:02 Chromium ug/L ND 0.50 04/08/1514:02 Cobalt ug/L ND 0.50 04/08/1514:02 Copper ug/L ND 1.0 04/08/1514:02 Iron ug/L ND 50.0 04/08/1514:02 Lead ug/L ND 0.10 04/08/1514:02 Magnesium ug/L ND 10.0 04/08/1514:02 Manganese ug/L ND 0.50 04/08/1514:02 Molybdenum ug/L ND 0.50 04/08/1514:02 Nickel ug/L ND 0.50 04/08/1514:02 Potassium ug/L ND 50.0 04/08/1514:02 Selenium ug/L ND 0.50 04/08/1514:02 Sodium ug/L ND 50.0 04/08/1514:02 Strontium ug/L ND 0.50 04/08/1514:02 Thallium ug/L ND 0.10 04/08/1514:02 Vanadium ug/L ND 1.0 04/08/1514:02 Zinc ug/L ND 5.0 04/08/1514:02 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1932877 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 75.9 95 80-120 Antimony ug/L 80 79.8 100 80-120 Arsenic ug/L 80 78.7 98 80-120 Barium ug/L 80 77.9 97 80-120 Beryllium ug/L 80 75.6 94 80-120 Boron ug/L 80 76.2 95 80-120 Cadmium ug/L 80 77.5 97 80-120 Calcium ug/L 1000 890 89 80-120 Chromium ug/L 80 76.8 96 80-120 Cobalt ug/L 80 74.9 94 80-120 Copper ug/L 80 74.9 94 80-120 Iron ug/L 1000 967 97 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 55 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 LABORATORY CONTROL SAMPLE: 1932877 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 78.3 98 80-120 Magnesium ug/L 1000 956 96 80-120 Manganese ug/L 80 77.7 97 80-120 Molybdenum ug/L 80 75.1 94 80-120 Nickel ug/L 80 78.1 98 80-120 Potassium ug/L 1000 975 98 80-120 Selenium ug/L 80 79.6 99 80-120 Sodium ug/L 1000 943 94 80-120 Strontium ug/L 80 75.4 94 80-120 Thallium ug/L 80 76.6 96 80-120 Vanadium ug/L 80 79.3 99 80-120 Zinc ug/L 80 79.0 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1932878 1932879 MS MSD 10301430001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 80 80 100 119 121 144 75-125 17 20 M1 Antimony ug/L ND 80 80 80.2 80.2 100 100 75-125 0 20 Arsenic ug/L 183 80 80 262 263 99 100 75-125 0 20 Barium ug/L 113 80 80 188 192 94 98 75-125 2 20 Beryllium ug/L ND 80 80 68.2 72.9 85 91 75-125 7 20 Boron ug/L 500 80 80 589 596 111 119 75-125 1 20 Cadmium ug/L ND 80 80 77.5 77.4 97 97 75-125 0 20 Calcium ug/L 94300 1000 1000 91600 92700 -262 -158 75-125 1 20 E,M1 Chromium ug/L 0.53 80 80 76.8 78.0 95 97 75-125 1 20 Cobalt ug/L ND 80 80 74.7 74.6 93 93 75-125 0 20 Copper ug/L 1.1 80 80 75.0 75.9 92 93 75-125 1 20 Iron ug/L 9490 1000 1000 10500 10600 99 115 75-125 1 20 Lead ug/L ND 80 80 77.3 78.1 96 98 75-125 1 20 Magnesium ug/L 46700 1000 1000 45800 46000 -92 -72 75-125 0 20 M1 Manganese ug/L 1500 80 80 1520 1540 30 48 75-125 1 20 M1 Molybdenum ug/L 0.91 80 80 77.0 77.6 95 96 75-125 1 20 Nickel ug/L 1.2 80 80 78.4 77.1 96 95 75-125 2 20 Potassium ug/L 9940 1000 1000 11100 11200 116 128 75-125 1 20 M1 Selenium ug/L ND 80 80 81.8 80.3 102 100 75-125 2 20 Sodium ug/L 78700 1000 1000 76500 76800 -222 -190 75-125 0 20 M1 Strontium ug/L 604 80 80 669 677 81 91 75-125 1 20 Thallium ug/L ND 80 80 78.9 80.2 99 100 75-125 2 20 Vanadium ug/L ND 80 80 79.4 79.2 99 98 75-125 0 20 Zinc ug/L 5.7 80 80 86.5 89.1 101 104 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 56 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wvele. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: PMST/3398 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 SAMPLE DUPLICATE: 1170238 92241225001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 33.8 31.0 9 10 SAMPLE DUPLICATE: 1170239 92241230005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 16.0 15.2 5 10 SAMPLE DUPLICATE: 1170240 92242742002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 3.3 4.1 22 10 D6 SAMPLE DUPLICATE: 1170241 92243187006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.0 18.9 5 10 SAMPLE DUPLICATE: 1170242 35181515009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.5 2.2 14 10 D6 SAMPLE DUPLICATE: 1170243 35181515018 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 3.3 3.3 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 57 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g "-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WET/36394 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004 SAMPLE DUPLICATE: 1417563 92240692001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 5.8 10 10 D6 SAMPLE DUPLICATE: 1417564 92241508004 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.8 6.8 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 58 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WET/36412 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92241508005 SAMPLE DUPLICATE: 1418509 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 1418510 Parameter pH at 25 Degrees C 92242504025 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 5.9 5.7 3 10 D6 92241963004 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 5.4 5.5 2 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 59 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/22391 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 METHOD BLANK: 1422986 Matrix: Water Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 4.9 4.0 04/02/1511:41 D3 LABORATORY CONTROL SAMPLE: 1422987 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.3 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1422988 1422989 MS MSD 92241061007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 8.5 24.8 24.8 32.9 33.2 98 99 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1422990 1422991 MS MSD 92241965003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 45.8 29.5 29.5 42.6 47.5 -11 6 11 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 60 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g 6-8 le. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/22397 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004 METHOD BLANK: 1423312 Matrix: Water Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 148 1.0 03/31/15 18:55 P8 LABORATORY CONTROL SAMPLE: 1423313 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.3 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423314 1423315 MS MSD 92241387006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 467 2.8 2.8 478 480 418 490 90-110 0 10 H1,M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423316 1423317 MS MSD 92241387007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 317 3.3 3.3 316 317 -34 -16 90-110 0 10 H1,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 61 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g inlvele. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/22398 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92241508005 METHOD BLANK: 1423321 Matrix: Water Associated Lab Samples: 92241508005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 355 2.0 03/31/15 19:29 P8 LABORATORY CONTROL SAMPLE: 1423322 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423323 1423324 MS MSD 92241508005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 391 3.3 3.3 387 389 -104 -65 90-110 0 10 H1,M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423325 1423326 MS MSD 92242371020 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 371 3.1 3.1 370 368 -55 -95 90-110 0 10 H1,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 62 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g iQvele. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/22349 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92241508002 METHOD BLANK: 1420866 Matrix: Water Associated Lab Samples: 92241508002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/27/15 04:28 LABORATORY CONTROL SAMPLE: 1420867 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.1 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1420868 1420869 MS MSD 92241061007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 24.8 24.8 25.6 25.5 101 100 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1420870 1420871 MS MSD 92241225003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 29.6 29.6 32.4 32.3 104 104 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 63 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g "-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/22369 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92241508001 METHOD BLANK: 1421891 Matrix: Water Associated Lab Samples: 92241508001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/28/15 03:59 LABORATORY CONTROL SAMPLE: 1421892 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.4 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1421893 1421894 MS MSD 92241508001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 34.1 34.1 35.8 35.8 105 105 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 64 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/22399 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92241508003, 92241508004, 92241508005 METHOD BLANK: 1423399 Matrix: Water Associated Lab Samples: 92241508003, 92241508004, 92241508005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/31/1515:20 LABORATORY CONTROL SAMPLE: 1423400 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423401 1423402 MS MSD 92241965003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 29.5 29.5 32.1 32.2 105 105 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423403 1423404 MS MSD 92242381003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 27.6 27.6 29.6 29.1 107 105 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 65 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g inml e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/44808 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 METHOD BLANK: 1165183 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.7 03/25/1519:25 Sulfate mg/kg ND 49.7 03/25/1519:25 LABORATORY CONTROL SAMPLE: 1165184 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1165186 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1165185 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 496 473 95 80-120 496 475 96 80-120 92241508001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 848 842 80 80-120 ND 848 851 87 80-120 92241508001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 66 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g vwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/44807 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 METHOD BLANK: 1165175 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 03/25/15 19:25 LABORATORY CONTROL SAMPLE: 1165176 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.6 49.6 100 80-120 MATRIX SPIKE SAMPLE: 1165178 92241508001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 84.8 83.5 98 80-120 H3 SAMPLE DUPLICATE: 1165177 92241508001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 67 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g "-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030452 Pace Project No.: 92241508 QC Batch: WETA/27714 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92241508001, 92241508002, 92241508003, 92241508004, 92241508005 METHOD BLANK: 1131411 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/26/15 07:20 LABORATORY CONTROL SAMPLE: 1131412 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 111000 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1131413 1131414 MS MSD 92241230001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 177000 71200 71000 237000 238000 84 86 50-150 1 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1131415 1131416 MS MSD 92241508001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 57700 58700 58800 118000 115000 103 97 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 68 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15030452 Pace Project No.: 92241508 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. E Analyte concentration exceeded the calibration range. The reported result is estimated. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 69 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-wAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030452 Pace Project No.: 92241508 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92241508001 2015007573 EPA 3050 MPRP/23320 EPA 6010 ICP/14263 92241508002 2015007574 EPA 3050 MPRP/23320 EPA 6010 ICP/14263 92241508003 2015007575 EPA 3050 MPRP/23320 EPA 6010 ICP/14263 92241508004 2015007576 EPA 3050 MPRP/23320 EPA 6010 ICP/14263 92241508005 2015007577 EPA 3050 MPRP/23320 EPA 6010 ICP/14263 92241508001 2015007573 EPA 3050 MPRP/23321 EPA 6020 ICPM/9502 92241508002 2015007574 EPA 3050 MPRP/23321 EPA 6020 ICPM/9502 92241508003 2015007575 EPA 3050 MPRP/23321 EPA 6020 ICPM/9502 92241508004 2015007576 EPA 3050 MPRP/23321 EPA 6020 ICPM/9502 92241508005 2015007577 EPA 3050 MPRP/23321 EPA 6020 ICPM/9502 92241508006 2015007578 EPA 3020 MPRP/53156 EPA 6020A ICPM/23546 92241508007 2015007573 SPLP EPA 3020 MPRP/53405 EPA 6020A ICPM/23667 92241508008 2015007574 SPLP EPA 3020 MPRP/53405 EPA 6020A ICPM/23667 92241508009 2015007575 SPLP EPA 3020 MPRP/53405 EPA 6020A ICPM/23667 92241508010 2015007576SPLP EPA 3020 MPRP/53405 EPA 6020A ICPM/23667 92241508011 2015007577 SPLP EPA 3020 MPRP/53405 EPA 6020A ICPM/23667 92241508006 2015007578 EPA 7470 MERP/13047 EPA 7470 MERC/15148 92241508007 2015007573 SPLP EPA 7470 MERP/13139 EPA 7470 MERC/15254 92241508008 2015007574 SPLP EPA 7470 MERP/13139 EPA 7470 MERC/15254 92241508009 2015007575 SPLP EPA 7470 MERP/13139 EPA 7470 MERC/15254 92241508010 2015007576 SPLP EPA 7470 MERP/13139 EPA 7470 MERC/15254 92241508011 2015007577 SPLP EPA 7470 MERP/13139 EPA 7470 MERC/15254 92241508001 2015007573 EPA 7471 MERP/5527 EPA 7471 MERC/5518 92241508002 2015007574 EPA 7471 MERP/5527 EPA 7471 MERC/5518 92241508003 2015007575 EPA 7471 MERP/5527 EPA 7471 MERC/5518 92241508004 2015007576 EPA 7471 MERP/5527 EPA 7471 MERC/5518 92241508005 2015007577 EPA 7471 MERP/5527 EPA 7471 MERC/5518 92241508001 2015007573 ASTM D2974-87 PMST/3398 92241508002 2015007574 ASTM D2974-87 PMST/3398 92241508003 2015007575 ASTM D2974-87 PMST/3398 92241508004 2015007576 ASTM D2974-87 PMST/3398 92241508005 2015007577 ASTM D2974-87 PMST/3398 92241508001 2015007573 EPA 9045 WET/36394 92241508002 2015007574 EPA 9045 WET/36394 92241508003 2015007575 EPA 9045 WET/36394 92241508004 2015007576 EPA 9045 WET/36394 92241508005 2015007577 EPA 9045 WET/36412 92241508001 2015007573 EPA 300.0 WETA/22391 92241508002 2015007574 EPA 300.0 WETA/22391 92241508003 2015007575 EPA 300.0 WETA/22391 92241508004 2015007576 EPA 300.0 WETA/22391 92241508005 2015007577 EPA 300.0 WETA/22391 92241508001 2015007573 EPA 353.2 WETA/22397 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/10/2015 07:25 AM without the written consent of Pace Analytical Services, Inc.. Page 70 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g wwAl e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030452 Pace Project No.: 92241508 Lab ID Sample ID QC Batch Method QC Batch 92241508002 2015007574 EPA 353.2 WETA/22397 92241508003 2015007575 EPA 353.2 WETA/22397 92241508004 2015007576 EPA 353.2 WETA/22397 92241508005 2015007577 EPA 353.2 WETA/22398 92241508001 2015007573 SM 4500-CI-E WETA/22369 92241508002 2015007574 SM 4500-CI-E WETA/22349 92241508003 2015007575 SM 4500-CI-E WETA/22399 92241508004 2015007576 SM 4500-CI-E WETA/22399 92241508005 2015007577 SM 4500-CI-E WETA/22399 92241508001 2015007573 EPA 9056 WETA/44808 92241508002 2015007574 EPA 9056 WETA/44808 92241508003 2015007575 EPA 9056 WETA/44808 92241508004 2015007576 EPA 9056 WETA/44808 92241508005 2015007577 EPA 9056 WETA/44808 92241508001 2015007573 EPA 9056 WETA/44807 92241508002 2015007574 EPA 9056 WETA/44807 92241508003 2015007575 EPA 9056 WETA/44807 92241508004 2015007576 EPA 9056 WETA/44807 92241508005 2015007577 EPA 9056 WETA/44807 92241508001 2015007573 EPA 9060 WETA/27714 92241508001 2015007573 EPA 9060 WETA/27716 92241508002 2015007574 EPA 9060 WETA/27714 92241508002 2015007574 EPA 9060 WETA/27716 92241508003 2015007575 EPA 9060 WETA/27714 92241508003 2015007575 EPA 9060 WETA/27716 92241508004 2015007576 EPA 9060 WETA/27714 92241508004 2015007576 EPA 9060 WETA/27716 92241508005 2015007577 EPA 9060 WETA/27714 92241508005 2015007577 EPA 9060 WETA/27716 Date: 04/10/2015 07:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 71 of 73 Document Name: Document Revised: September 22. 2U14 ceAn<?! fc�lSample Condition Upon Receipt (SCUR Page I of 2 Document Number: Issuing Auth6W 81 of 83 F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Name: K c, I` r u f Courier: ❑ Fed Ex ❑ UPS[] USPS❑ Client❑ mmercial❑ P' c�Other fill 1 ti° 3 Custody Seal on Cooler/Box Present: ❑ yes no Seals intact: ❑ yes ❑ noy Packing Material: ❑ Bubble VE)p Bubble Bags C] None ❑ Other Thermometer Used: IR Gun 414 Type of Ice: et~ lue None Samples on ice, cooling process has begun `i-mm- Cnrrnr4inn C—fnr TUni Nn rnrraetinn j Corrected Cooler Temp.: I 'C Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes No A) g Comments: ate and Initials of erson exar�Inin contents: / j r Z Chain of Custody Present: Yes No ❑NIA 1, Chain of Custody Filled Out: Yes o ❑NIA 2, Chain of Custody Relinquished: es No ONIA 3. Sampler Name & Signature on COC: Yes DN, ❑N/A 4, Samples Arrived within Hold Time: es ONo NIA 5. Short Hold Time Analysis (<72hr): []Yes 0411 ❑ A 6. Rush Turn Around Time Requested: Byes ❑NIA 7. Sufficient Volume: es f o NIA 8. Correct Containers Used: f -Pace Containers Used: es .t o ❑ ❑NIA 9. Containers Intact: es ❑No ❑NIA 1 Filtered volume received for Dissolved tests ❑Yes ❑No N1A 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: ❑ /es ❑No ❑NIA 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, 0&G, VA-DRO (water) es ❑Yes ❑Yes ❑ ❑No FINo N 9 I 1 Samples checked for dechlorination: ❑Yes ❑No Ell IA 4. Headspace in VOA Vials( >6mm): ❑Yes ❑No NIA Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes []Yes ❑No E]No D141rA ❑NIA 6. Client Notification/ Resolution: Field Data Required? Y I N Person Contacted:. Comments/ Resolution: Date/Time: SCURF Review: („{,; Date: 13 [ rS_ SRF Review: 1 Date: 3 I Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92241506 111111111111111111111111111111111 92241508 Page 72 of 73 �eulryvua � I*ial m o� o 0 o m m o 0 0 0 0 o ro o o p z LLP r N �10 s peAlosGla 0. 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