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Home My WebLink AboutNC0003417_J15030284 Report_20150805DUE Analytical Laboratory Page 1 of43 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15030284 AB GW ASSESSMENT SOIL Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer 1677 Old Smithfield Rd Goldsboro NC 27530, Margaret Galvin -Karr Phone: 980-875-5219 �f�v1lwIA�7�pCy ma g.gomn-karr@duke- " `�"GY"' 2015.04.08 14:53:44-04100. Date: Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 4/6/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015006843 HF LEE PLANT 05-Mar-15 8:50 AM ILLEGIBLE AMW-9SB-0-2 2015006854 HF LEE PLANT 05-Mar-15 9:30 AM ILLEGIBLE AMW-9SB-5-6 2015006855 HF LEE PLANT 05-Mar-15 10:15 AM ILLEGIBLE AMW-9SB-9-10 3 Total Samples Page 2 of 43 Page 3 of 43 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report L-1 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/6/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030284 Site: AMW-9SB-0-2 Collection Date: 05-Mar-15 8:50 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 43 Sample #: 2015006843 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030284 Site: AMW-9SB-5-6 Collection Date: 05-Mar-15 9:30 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 43 Sample #: 2015006854 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030284 Site: AMW-9SB-9-10 Collection Date: 05-Mar-15 10:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 43 Sample #: 2015006855 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. %Q9'9c&� W- Suite 100 �Huntersville, INC 28078 (704)875-9092 March 25, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15030284 Pace Project No.: 92240781 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 11, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. %gig%y4fte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030284 Pace Project No.: 92240781 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification M FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. %9i99 W- Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15030284 Pace Project No.: 92240781 Lab ID Sample ID Matrix Date Collected Date Received 92240781001 2015006843 Solid 03/05/15 08:50 03/11/15 12:01 92240781002 2015006854 Solid 03/05/15 09:30 03/11/15 12:01 92240781003 2015006855 Solid 03/05/1510:15 03/11/15 12:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qy0698f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15030284 92240781 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92240781001 2015006843 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92240781002 2015006854 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92240781003 2015006855 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA7471 HEA 1 PASI-O ASTM D2974-87 RPM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�fflin�c 41" Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030284 Pace Project No.: 92240781 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92240781001 2015006843 EPA 6010 Aluminum 7100 mg/kg 6.2 03/20/15 21:26 EPA 6010 Barium 31.8 mg/kg 0.62 03/20/15 21:26 EPA 6010 Beryllium 0.31 mg/kg 0.062 03/20/15 21:26 EPA 6010 Boron 6.3 mg/kg 3.1 03/20/15 21:26 EPA 6010 Calcium 92.9 mg/kg 31.1 03/20/15 21:26 EPA 6010 Chromium 7.7 mg/kg 0.31 03/20/15 21:26 EPA 6010 Copper 3.5 mg/kg 0.31 03/20/15 21:26 EPA 6010 Iron 9500 mg/kg 2.5 03/20/15 21:26 EPA 6010 Magnesium 654 mg/kg 31.1 03/20/15 21:26 EPA 6010 Manganese 21.6 mg/kg 0.31 03/20/15 21:26 EPA 6010 Nickel 2.3 mg/kg 0.31 03/20/15 21:26 EPA 6010 Potassium 102 mg/kg 62.3 03/20/15 21:26 EPA 6010 Sodium 35.OJ mg/kg 62.3 03/20/15 21:26 EPA 6010 Strontium 2.2 mg/kg 0.62 03/20/15 21:26 EPA 6010 Zinc 7.8 mg/kg 1.2 03/20/15 21:26 EPA 6020 Cobalt 2.5J mg/kg 3.1 03/20/15 18:22 EPA 6020 Lead 7.8 mg/kg 3.1 03/20/15 18:22 EPA 6020 Vanadium 27.1 mg/kg 3.1 03/20/15 18:22 EPA 7471 Mercury 0.020 mg/kg 0.010 03/23/15 14:24 ASTM D2974-87 Percent Moisture 20.0 % 0.10 03/24/15 13:09 EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 03/17/15 15:25 EPA 9060 Total Organic Carbon 14200 mg/kg 744 03/19/15 08:25 EPA 9060 Total Organic Carbon 19800 mg/kg 746 03/19/15 08:31 EPA 9060 Total Organic Carbon 22400 mg/kg 752 03/19/15 08:37 EPA 9060 Total Organic Carbon 22200 mg/kg 749 03/19/15 08:43 EPA 9060 Mean Total Organic Carbon 19700 mg/kg 748 03/19/15 08:25 EPA 9060 RSD% 19.5 % 03/19/15 08:25 92240781002 2015006854 EPA 6010 Aluminum 5520 mg/kg 5.4 03/20/15 21:30 EPA 6010 Barium 56.4 mg/kg 0.54 03/20/15 21:30 EPA 6010 Beryllium 0.21 mg/kg 0.054 03/20/15 21:30 EPA 6010 Boron 3.1 mg/kg 2.7 03/20/15 21:30 EPA 6010 Calcium 428 mg/kg 26.9 03/20/15 21:30 EPA 6010 Chromium 8.3 mg/kg 0.27 03/20/15 21:30 EPA 6010 Copper 3.8 mg/kg 0.27 03/20/15 21:30 EPA 6010 Iron 4330 mg/kg 2.2 03/20/15 21:30 EPA 6010 Magnesium 1030 mg/kg 26.9 03/20/15 21:30 EPA 6010 Manganese 27.0 mg/kg 0.27 03/20/15 21:30 EPA 6010 Nickel 2.7 mg/kg 0.27 03/20/15 21:30 EPA 6010 Potassium 187 mg/kg 53.8 03/20/15 21:30 EPA 6010 Sodium 197 mg/kg 53.8 03/20/15 21:30 EPA 6010 Strontium 6.0 mg/kg 0.54 03/20/15 21:30 EPA 6010 Zinc 9.0 mg/kg 1.1 03/20/15 21:30 EPA 6020 Cobalt 1.8J mg/kg 2.7 03/20/15 18:25 EPA 6020 Lead 4.7 mg/kg 2.7 03/20/15 18:25 EPA 6020 Vanadium 18.9 mg/kg 2.7 03/20/15 18:25 EPA 7471 Mercury 0.013 mg/kg 0.0091 03/23/15 14:26 REPORT OF LABORATORY ANALYSIS D3 D3 D3 MO D3 D3 D3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qy0298f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030284 Pace Project No.: 92240781 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92240781002 2015006854 ASTM D2974-87 Percent Moisture 11.4 % 0.10 03/24/15 13:09 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 03/17/15 15:25 EPA 9060 Total Organic Carbon 506J mg/kg 678 03/19/15 09:35 EPA 9060 Total Organic Carbon 509J mg/kg 677 03/19/15 09:40 EPA 9060 Total Organic Carbon 521J mg/kg 672 03/19/15 09:46 EPA 9060 Total Organic Carbon 532J mg/kg 680 03/19/15 09:51 EPA 9060 Mean Total Organic Carbon 517J mg/kg 677 03/19/15 09:35 EPA 9060 RSD% 2.3 % 03/19/15 09:35 92240781003 2015006855 EPA 6010 Aluminum 1580 mg/kg 5.9 03/20/15 21:35 EPA 6010 Barium 8.7 mg/kg 0.59 03/20/15 21:35 EPA 6010 Beryllium 0.22 mg/kg 0.059 03/20/15 21:35 EPA 6010 Boron 7.5 mg/kg 2.9 03/20/15 21:35 EPA 6010 Calcium 122 mg/kg 29.5 03/20/15 21:35 EPA 6010 Chromium 28.9 mg/kg 0.29 03/20/15 21:35 EPA 6010 Copper 9.2 mg/kg 0.29 03/20/15 21:35 EPA 6010 Iron 10900 mg/kg 2.4 03/20/15 21:35 EPA 6010 Magnesium 98.5 mg/kg 29.5 03/20/15 21:35 EPA 6010 Manganese 14.5 mg/kg 0.29 03/20/15 21:35 EPA 6010 Nickel 3.9 mg/kg 0.29 03/20/15 21:35 EPA 6010 Potassium 53.2J mg/kg 59.0 03/20/15 21:35 EPA 6010 Sodium 37AJ mg/kg 59.0 03/20/15 21:35 EPA 6010 Strontium 0.89 mg/kg 0.59 03/20/15 21:35 EPA 6010 Zinc 5.6 mg/kg 1.2 03/20/15 21:35 EPA 6020 Cobalt 2.7J mg/kg 2.9 03/20/15 18:27 D3 EPA 6020 Lead 5.5 mg/kg 2.9 03/20/15 18:27 D3 EPA 6020 Vanadium 32.9 mg/kg 2.9 03/20/15 18:27 D3 ASTM D2974-87 Percent Moisture 14.3 % 0.10 03/24/15 13:09 EPA 9045 pH at 25 Degrees C 6.2 Std. Units 0.10 03/17/15 15:25 EPA 9060 Total Organic Carbon 394J mg/kg 707 03/19/15 09:57 EPA 9060 Total Organic Carbon 396J mg/kg 707 03/19/15 10:02 EPA 9060 Total Organic Carbon 394J mg/kg 706 03/19/15 10:09 EPA 9060 Total Organic Carbon 389J mg/kg 699 03/19/15 10:14 EPA 9060 Mean Total Organic Carbon 393J mg/kg 705 03/19/15 09:57 EPA 9060 RSD% 0.76 % 03/19/15 09:57 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0980S'8f4W- Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 25, 2015 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23172 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240782001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1161438) • Aluminum • Barium • Beryllium • Chromium • Copper • Iron • Magnesium • Manganese • Molybdenum • Nickel • Potassium • MSD (Lab ID: 1161439) • Aluminum • Barium • Beryllium • Chromium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098Pli4'8f4 re. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 25, 2015 QC Batch: MPRP/23172 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240782001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Copper • Iron • Magnesium • Manganese • Molybdenum • Nickel • Potassium R1: RPD value was outside control limits. • MSD (Lab ID: 1161439) • Manganese • Molybdenum Additional Comments: Analyte Comments: QC Batch: MPRP/23172 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MS (Lab ID: 1161438) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • MSD (Lab ID: 1161439) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qy0998f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 25, 2015 Analyte Comments: QC Batch: MPRP/23172 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MSD (Lab ID: 1161439) • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1161436) • Aluminum Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qy0698f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 25, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23173 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240782002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1161442) • Antimony • Arsenic • Cobalt • Lead • Selenium • Vanadium • MSD (Lab ID: 1161443) • Antimony • Arsenic • Cobalt • Lead • Selenium • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098Pii9'8f4 re. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 25, 2015 QC Batch: MPRP/23173 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240782002 R1: RPD value was outside control limits. • MSD (Lab ID: 1161443) • Cobalt Additional Comments: Analyte Comments: QC Batch: MPRP/23173 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006843 (Lab ID:92240781001) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015006854 (Lab ID:92240781002) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015006855 (Lab ID:92240781003) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MS (Lab ID: 1161442) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qy0998f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 25, 2015 Analyte Comments: QC Batch: MPRP/23173 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MS (Lab ID: 1161442) • Thallium • Vanadium • MSD (Lab ID: 1161443) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015006843 (Lab ID:92240781001) • Antimony •2015006854 (Lab ID:92240781002) • Antimony •2015006855 (Lab ID:92240781003) • Antimony • BLANK (Lab ID: 1161440) • Antimony • LCS (Lab ID: 1161441) • Antimony • MS (Lab ID: 1161442) • Antimony • MSD (Lab ID: 1161443) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qy0998f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: March 25, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5493 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35179481001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1161942) • Mercury • MSD (Lab ID: 1161943) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09899698f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: March 25, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989 9nlc&)r4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 25, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44600 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015006843 (Lab ID:92240781001) • Chloride • Sulfate •2015006854 (Lab ID:92240781002) • Chloride • Sulfate •2015006855 (Lab ID:92240781003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09899298)r4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: March 25, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015006843 (Lab ID:92240781001) •2015006854 (Lab ID:92240781002) •2015006855 (Lab ID:92240781003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09899998f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030284 Pace Project No.: 92240781 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 25, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09899498f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030284 Pace Project No.: 92240781 Sample: 2015006843 Lab ID: 92240781001 Collected: 03/05/15 08:50 Received: 03/11/15 12:01 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 7100 mg/kg 6.2 3.1 1 03/20/15 06:37 03/20/15 21:26 7429-90-5 Barium 31.8 mg/kg 0.62 0.31 1 03/20/15 06:37 03/20/15 21:26 7440-39-3 Beryllium 0.31 mg/kg 0.062 0.031 1 03/20/15 06:37 03/20/15 21:26 7440-41-7 Boron 6.3 mg/kg 3.1 1.6 1 03/20/15 06:37 03/20/15 21:26 7440-42-8 Calcium 92.9 mg/kg 31.1 15.6 1 03/20/15 06:37 03/20/15 21:26 7440-70-2 Chromium 7.7 mg/kg 0.31 0.16 1 03/20/15 06:37 03/20/15 21:26 7440-47-3 Copper 3.5 mg/kg 0.31 0.16 1 03/20/15 06:37 03/20/15 21:26 7440-50-8 Iron 9500 mg/kg 2.5 1.2 1 03/20/15 06:37 03/20/15 21:26 7439-89-6 Magnesium 654 mg/kg 31.1 15.6 1 03/20/15 06:37 03/20/15 21:26 7439-95-4 Manganese 21.6 mg/kg 0.31 0.16 1 03/20/15 06:37 03/20/15 21:26 7439-96-5 Molybdenum ND mg/kg 0.62 0.31 1 03/20/15 06:37 03/20/15 21:26 7439-98-7 Nickel 2.3 mg/kg 0.31 0.16 1 03/20/15 06:37 03/20/15 21:26 7440-02-0 Potassium 102 mg/kg 62.3 31.1 1 03/20/15 06:37 03/20/15 21:26 7440-09-7 Sodium 35.OJ mg/kg 62.3 31.1 1 03/20/15 06:37 03/20/15 21:26 7440-23-5 Strontium 2.2 mg/kg 0.62 0.31 1 03/20/15 06:37 03/20/15 21:26 7440-24-6 Zinc 7.8 mg/kg 1.2 0.62 1 03/20/15 06:37 03/20/15 21:26 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.1 1.6 50 03/20/15 06:37 03/20/15 18:22 7440-36-0 D3,N2 Arsenic ND mg/kg 3.1 1.6 50 03/20/15 06:37 03/20/15 18:22 7440-38-2 D3 Cadmium ND mg/kg 0.37 0.19 50 03/20/15 06:37 03/20/15 18:22 7440-43-9 D3 Cobalt 2.5J mg/kg 3.1 1.6 50 03/20/15 06:37 03/20/15 18:22 7440-48-4 D3 Lead 7.8 mg/kg 3.1 1.6 50 03/20/15 06:37 03/20/15 18:22 7439-92-1 D3 Selenium ND mg/kg 3.1 1.6 50 03/20/15 06:37 03/20/15 18:22 7782-49-2 D3 Thallium ND mg/kg 3.1 1.6 50 03/20/15 06:37 03/20/15 18:22 7440-28-0 D3 Vanadium 27.1 mg/kg 3.1 1.6 50 03/20/15 06:37 03/20/15 18:22 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.020 mg/kg 0.010 0.0051 1 03/20/1513:25 03/23/1514:24 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.0 % 0.10 0.10 1 03/24/15 13:09 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 0.10 1 03/17/15 15:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 310 155 5 03/18/15 03:41 16887-00-6 D3 Sulfate ND mg/kg 310 155 5 03/18/15 03:41 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.0 15.5 5 03/18/15 03:41 14797-55-8 H3 Date: 03/25/2015 09:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09899998f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030284 Pace Project No.: 92240781 Sample: 2015006843 Lab ID: 92240781001 Collected: 03/05/15 08:50 Received: 03/11/15 12:01 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 14200 mg/kg 744 372 1 03/19/15 08:25 7440-44-0 Total Organic Carbon 19800 mg/kg 746 373 1 03/19/15 08:31 7440-44-0 Total Organic Carbon 22400 mg/kg 752 376 1 03/19/15 08:37 7440-44-0 Total Organic Carbon 22200 mg/kg 749 375 1 03/19/15 08:43 7440-44-0 Mean Total Organic Carbon 19700 mg/kg 748 374 1 03/19/15 08:25 7440-44-0 MO Surrogates RSD% 19.5 % 1 03/19/15 08:25 Date: 03/25/2015 09:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09899698f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030284 Pace Project No.: 92240781 Sample: 2015006854 Lab ID: 92240781002 Collected: 03/05/15 09:30 Received: 03/11/15 12:01 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 5520 mg/kg 5.4 2.7 1 03/20/15 06:37 03/20/15 21:30 7429-90-5 Barium 56.4 mg/kg 0.54 0.27 1 03/20/15 06:37 03/20/15 21:30 7440-39-3 Beryllium 0.21 mg/kg 0.054 0.027 1 03/20/15 06:37 03/20/15 21:30 7440-41-7 Boron 3.1 mg/kg 2.7 1.3 1 03/20/15 06:37 03/20/15 21:30 7440-42-8 Calcium 428 mg/kg 26.9 13.4 1 03/20/15 06:37 03/20/15 21:30 7440-70-2 Chromium 8.3 mg/kg 0.27 0.13 1 03/20/15 06:37 03/20/15 21:30 7440-47-3 Copper 3.8 mg/kg 0.27 0.13 1 03/20/15 06:37 03/20/15 21:30 7440-50-8 Iron 4330 mg/kg 2.2 1.1 1 03/20/15 06:37 03/20/15 21:30 7439-89-6 Magnesium 1030 mg/kg 26.9 13.4 1 03/20/15 06:37 03/20/15 21:30 7439-95-4 Manganese 27.0 mg/kg 0.27 0.13 1 03/20/15 06:37 03/20/15 21:30 7439-96-5 Molybdenum ND mg/kg 0.54 0.27 1 03/20/15 06:37 03/20/15 21:30 7439-98-7 Nickel 2.7 mg/kg 0.27 0.13 1 03/20/15 06:37 03/20/15 21:30 7440-02-0 Potassium 187 mg/kg 53.8 26.9 1 03/20/15 06:37 03/20/15 21:30 7440-09-7 Sodium 197 mg/kg 53.8 26.9 1 03/20/15 06:37 03/20/15 21:30 7440-23-5 Strontium 6.0 mg/kg 0.54 0.27 1 03/20/15 06:37 03/20/15 21:30 7440-24-6 Zinc 9.0 mg/kg 1.1 0.54 1 03/20/15 06:37 03/20/15 21:30 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.7 1.3 50 03/20/15 06:37 03/20/15 18:25 7440-36-0 D3,N2 Arsenic ND mg/kg 2.7 1.3 50 03/20/15 06:37 03/20/15 18:25 7440-38-2 D3 Cadmium ND mg/kg 0.32 0.16 50 03/20/15 06:37 03/20/15 18:25 7440-43-9 D3 Cobalt 1.8J mg/kg 2.7 1.3 50 03/20/15 06:37 03/20/15 18:25 7440-48-4 D3 Lead 4.7 mg/kg 2.7 1.3 50 03/20/15 06:37 03/20/15 18:25 7439-92-1 D3 Selenium ND mg/kg 2.7 1.3 50 03/20/15 06:37 03/20/15 18:25 7782-49-2 D3 Thallium ND mg/kg 2.7 1.3 50 03/20/15 06:37 03/20/15 18:25 7440-28-0 D3 Vanadium 18.9 mg/kg 2.7 1.3 50 03/20/15 06:37 03/20/15 18:25 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.013 mg/kg 0.0091 0.0045 1 03/20/1513:25 03/23/1514:26 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.4 % 0.10 0.10 1 03/24/15 13:09 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 0.10 1 03/17/15 15:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 279 140 5 03/18/15 04:02 16887-00-6 D3 Sulfate ND mg/kg 279 140 5 03/18/15 04:02 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 27.9 14.0 5 03/18/15 04:02 14797-55-8 H3 Date: 03/25/2015 09:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989 K�i -Wfte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030284 Pace Project No.: 92240781 Sample: 2015006854 Lab ID: 92240781002 Collected: 03/05/15 09:30 Received: 03/11/15 12:01 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 506J mg/kg 678 339 1 03/19/15 09:35 7440-44-0 Total Organic Carbon 5091 mg/kg 677 338 1 03/19/15 09:40 7440-44-0 Total Organic Carbon 521J mg/kg 672 336 1 03/19/15 09:46 7440-44-0 Total Organic Carbon 532J mg/kg 680 340 1 03/19/15 09:51 7440-44-0 Mean Total Organic Carbon 517J mg/kg 677 338 1 03/19/15 09:35 7440-44-0 Surrogates RSD% 2.3 % 1 03/19/15 09:35 Date: 03/25/2015 09:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09899898f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030284 Pace Project No.: 92240781 Sample: 2015006855 Lab ID: 92240781003 Collected: 03/05/15 10:15 Received: 03/11/15 12:01 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 1580 mg/kg 5.9 2.9 1 03/20/15 06:37 03/20/15 21:35 7429-90-5 Barium 8.7 mg/kg 0.59 0.29 1 03/20/15 06:37 03/20/15 21:35 7440-39-3 Beryllium 0.22 mg/kg 0.059 0.029 1 03/20/15 06:37 03/20/15 21:35 7440-41-7 Boron 7.5 mg/kg 2.9 1.5 1 03/20/15 06:37 03/20/15 21:35 7440-42-8 Calcium 122 mg/kg 29.5 14.7 1 03/20/15 06:37 03/20/15 21:35 7440-70-2 Chromium 28.9 mg/kg 0.29 0.15 1 03/20/15 06:37 03/20/15 21:35 7440-47-3 Copper 9.2 mg/kg 0.29 0.15 1 03/20/15 06:37 03/20/15 21:35 7440-50-8 Iron 10900 mg/kg 2.4 1.2 1 03/20/15 06:37 03/20/15 21:35 7439-89-6 Magnesium 98.5 mg/kg 29.5 14.7 1 03/20/15 06:37 03/20/15 21:35 7439-95-4 Manganese 14.5 mg/kg 0.29 0.15 1 03/20/15 06:37 03/20/15 21:35 7439-96-5 Molybdenum ND mg/kg 0.59 0.29 1 03/20/15 06:37 03/20/15 21:35 7439-98-7 Nickel 3.9 mg/kg 0.29 0.15 1 03/20/15 06:37 03/20/15 21:35 7440-02-0 Potassium 53.2J mg/kg 59.0 29.5 1 03/20/15 06:37 03/20/15 21:35 7440-09-7 Sodium 37AJ mg/kg 59.0 29.5 1 03/20/15 06:37 03/20/15 21:35 7440-23-5 Strontium 0.89 mg/kg 0.59 0.29 1 03/20/15 06:37 03/20/15 21:35 7440-24-6 Zinc 5.6 mg/kg 1.2 0.59 1 03/20/15 06:37 03/20/15 21:35 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 18:27 7440-36-0 D3,N2 Arsenic ND mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 18:27 7440-38-2 D3 Cadmium ND mg/kg 0.35 0.18 50 03/20/15 06:37 03/20/15 18:27 7440-43-9 D3 Cobalt 2.7J mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 18:27 7440-48-4 D3 Lead 5.5 mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 18:27 7439-92-1 D3 Selenium ND mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 18:27 7782-49-2 D3 Thallium ND mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 18:27 7440-28-0 D3 Vanadium 32.9 mg/kg 2.9 1.5 50 03/20/15 06:37 03/20/15 18:27 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0090 0.0045 1 03/20/1513:25 03/23/1514:28 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 14.3 % 0.10 0.10 1 03/24/15 13:09 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.2 Std. Units 0.10 0.10 1 03/17/15 15:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 291 146 5 03/18/15 04:23 16887-00-6 D3 Sulfate ND mg/kg 291 146 5 03/18/15 04:23 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.1 14.6 5 03/18/15 04:23 14797-55-8 H3 Date: 03/25/2015 09:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09899998�r�re. Suite 100 �J Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030284 Pace Project No.: 92240781 Sample: 2015006855 Lab ID: 92240781003 Collected: 03/05/15 10:15 Received: 03/11/15 12:01 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 394J mg/kg 707 353 1 03/19/15 09:57 7440-44-0 Total Organic Carbon 396J mg/kg 707 354 1 03/19/15 10:02 7440-44-0 Total Organic Carbon 394J mg/kg 706 353 1 03/19/15 10:09 7440-44-0 Total Organic Carbon 389J mg/kg 699 349 1 03/19/15 10:14 7440-44-0 Mean Total Organic Carbon 393J mg/kg 705 352 1 03/19/15 09:57 7440-44-0 Surrogates RSD% 0.76 % 1 03/19/15 09:57 Date: 03/25/2015 09:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989 %-Wfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 QC Batch: MERP/5493 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92240781001, 92240781002, 92240781003 METHOD BLANK: 1161940 Matrix: Solid Associated Lab Samples: 92240781001, 92240781002, 92240781003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 03/23/1513:24 LABORATORY CONTROL SAMPLE: 1161941 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.077 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161942 1161943 MS MSD 35179481001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.38 .787 .787 0.94 0.82 72 56 80-120 14 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 24 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989K3inlcWe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 QC Batch: MPRP/23172 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92240781001, 92240781002, 92240781003 METHOD BLANK: 1161436 Matrix: Associated Lab Samples: 92240781001, 92240781002, 92240781003 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg 3AJ 4.9 03/20/1519:15 P8 Barium mg/kg ND 0.49 03/20/1519:15 Beryllium mg/kg ND 0.049 03/20/1519:15 Boron mg/kg ND 2.4 03/20/1519:15 Calcium mg/kg ND 24.3 03/20/1519:15 Chromium mg/kg ND 0.24 03/20/1519:15 Copper mg/kg ND 0.24 03/20/1519:15 Iron mg/kg ND 1.9 03/20/1519:15 Magnesium mg/kg ND 24.3 03/20/1519:15 Manganese mg/kg 0.18J 0.24 03/20/1519:15 P8 Molybdenum mg/kg ND 0.49 03/20/1519:15 Nickel mg/kg ND 0.24 03/20/1519:15 Potassium mg/kg ND 48.6 03/20/1519:15 Sodium mg/kg ND 48.6 03/20/1519:15 Strontium mg/kg ND 0.49 03/20/1519:15 Zinc mg/kg ND 0.97 03/20/1519:15 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1161437 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 126 129 103 80-120 Barium mg/kg 12.6 12.9 102 80-120 Beryllium mg/kg 1.3 1.3 101 80-120 Boron mg/kg 126 127 100 80-120 Calcium mg/kg 631 647 102 80-120 Chromium mg/kg 12.6 12.7 101 80-120 Copper mg/kg 12.6 12.5 99 80-120 Iron mg/kg 126 127 101 80-120 Magnesium mg/kg 631 647 102 80-120 Manganese mg/kg 12.6 12.7 101 80-120 Molybdenum mg/kg 12.6 12.6 100 80-120 Nickel mg/kg 12.6 13.0 103 80-120 Potassium mg/kg 631 628 100 80-120 Sodium mg/kg 631 648 103 80-120 Strontium mg/kg 12.6 12.4 99 80-120 Zinc mg/kg 63.1 64.4 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 25 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989ISQ-8f4ftre. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161438 1161439 MS MSD 92240782001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 16000 183 171 24200 22600 4440 3870 75-125 7 20 D3,M1 Barium mg/kg 488 18.3 17.1 658 620 928 771 75-125 6 20 D3,M1 Beryllium mg/kg 2.7 1.89 1.74 5.1 5.0 131 132 75-125 3 20 D3,M1 Boron mg/kg 17.OJ 183 171 173 157 85 82 75-125 10 20 D3 Calcium mg/kg 381 917 855 1340 1270 105 105 75-125 5 20 D3 Chromium mg/kg 36.8 18.3 17.1 76.5 78.2 216 242 75-125 2 20 D3,M1 Copper mg/kg 44.6 18.3 17.1 54.0 48.0 51 19 75-125 12 20 D3,M1 Iron mg/kg 26100 183 171 37000 34800 5940 5050 75-125 6 20 D3,M1 Magnesium mg/kg 9390 917 855 15400 14700 653 617 75-125 5 20 D3,M1 Manganese mg/kg 226 18.3 17.1 451 315 1230 523 75-125 35 20 D3,M1, R1 Molybdenum mg/kg ND 18.3 17.1 8.1 6.3 44 37 75-125 24 20 D3,M1, R1 Nickel mg/kg 19.5 18.3 17.1 52.6 50.7 180 182 75-125 4 20 D3,M1 Potassium mg/kg 8060 917 855 12700 11800 504 442 75-125 7 20 D3,M1 Sodium mg/kg ND 917 855 962 872 97 93 75-125 10 20 D3 Strontium mg/kg 9.6 18.3 17.1 28.5 26.7 103 100 75-125 7 20 D3 Zinc mg/kg 56.9 91.7 85.5 168 158 121 118 75-125 6 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 26 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989ISS-We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 QC Batch: MPRP/23173 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92240781001, 92240781002, 92240781003 METHOD BLANK: 1161440 Matrix: Solid Associated Lab Samples: 92240781001, 92240781002, 92240781003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.049 03/20/1517:06 N2 Arsenic mg/kg ND 0.049 03/20/1517:06 Cadmium mg/kg ND 0.0058 03/20/1517:06 Cobalt mg/kg ND 0.049 03/20/1517:06 Lead mg/kg ND 0.049 03/20/1517:06 Selenium mg/kg ND 0.049 03/20/1517:06 Thallium mg/kg ND 0.049 03/20/1517:06 Vanadium mg/kg ND 0.049 03/20/1517:06 LABORATORY CONTROL SAMPLE: Parameter 1161441 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 98 80-120 N2 Arsenic mg/kg 2.5 2.5 99 80-120 Cadmium mg/kg .25 0.24 98 80-120 Cobalt mg/kg 2.5 2.5 102 80-120 Lead mg/kg 2.5 2.4 98 80-120 Selenium mg/kg 2.5 2.4 97 80-120 Thallium mg/kg 2.5 2.5 101 80-120 Vanadium mg/kg 2.5 2.5 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161442 MS 92240782002 Spike Parameter Units Result Conc. MSD Spike Conc. 1161443 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 3.39 3.39 2.1J 2.2J 60 61 75-125 20 D3,M6, N2 Arsenic mg/kg 3.3J 3.39 3.39 4.9 5.1 47 53 75-125 4 20 D3,M6 Cadmium mg/kg ND .339 .339 0.43 0.44 112 117 75-125 3 20 D3 Cobalt mg/kg 6.9 3.39 3.39 9.3 11.7 70 142 75-125 23 20 D3,M6, R1 Lead mg/kg 17.5 3.39 3.39 19.8 22.0 67 135 75-125 11 20 D3,M6 Selenium mg/kg 4.0 3.39 3.39 5.1 5.3 31 37 75-125 4 20 D3,M6 Thallium mg/kg ND 3.39 3.39 3.5 3.5 88 89 75-125 0 20 D3 Vanadium mg/kg 20.7 3.39 3.39 21.6 25.5 27 144 75-125 17 20 D3,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 27 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989K3i498Mlre. Suite100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 QC Batch: PMST/3371 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92240781001, 92240781002, 92240781003 SAMPLE DUPLICATE: 1164316 92241061005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 25.6 21.6 17 10 D6 SAMPLE DUPLICATE: 1164317 92242149002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 32.7 21.3 42 10 D6 SAMPLE DUPLICATE: 1164318 35180582004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 28.0 21.3 27 10 D6 SAMPLE DUPLICATE: 1164319 35180582013 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 28.4 26.9 6 10 SAMPLE DUPLICATE: 1164320 35180582022 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 8.4 10.4 21 10 D6 SAMPLE DUPLICATE: 1164321 35180582031 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.2 5.0 79 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 28 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989 %-Wfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 QC Batch: WET/36257 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92240781001, 92240781002, 92240781003 SAMPLE DUPLICATE: 1412422 92240258001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.7 6.7 0 10 SAMPLE DUPLICATE: 1412423 Parameter pH at 25 Degrees C 92240781003 Dup Units Result Result Std. Units 6.2 6.1 Max RPD RPD Qualifiers 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989 %-Wfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 QC Batch: WETA/44600 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92240781001, 92240781002, 92240781003 METHOD BLANK: 1158250 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 03/18/15 00:28 Sulfate mg/kg ND 49.9 03/18/15 00:28 LABORATORY CONTROL SAMPLE: 1158251 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1158253 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1158252 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 501 501 100 80-120 501 502 100 80-120 35179663004 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers 125U 497 495 79 80-120 D3,M1 125U 497 503 90 80-120 35179663004 Dup Units Result Result mg/kg 125U ND mg/kg 125U ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989K3i -Wfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 QC Batch: WETA/44599 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92240781001, 92240781002, 92240781003 METHOD BLANK: 1158246 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 03/18/15 00:28 LABORATORY CONTROL SAMPLE: 1158247 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.1 52.5 105 80-120 MATRIX SPIKE SAMPLE: 1158249 35179663004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 12.5U 49.7 49.0 98 80-120 SAMPLE DUPLICATE: 1158248 35179663004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg 12.5U ND 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989K3igcWe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030284 Pace Project No.: 92240781 QC Batch: WETA/27622 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92240781001, 92240781002, 92240781003 METHOD BLANK: 1128812 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/19/15 07:40 LABORATORY CONTROL SAMPLE: 1128813 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 115000 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1128814 1128815 MS MSD 92240781001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 19700 7520 7490 27500 22600 104 40 50-150 19 30 MO Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 36 Pace Analytical Services, Inc aceAnalXical ® � ��tr�9c&rr�re. Suite100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15030284 Pace Project No.: 92240781 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/25/2015 09:45 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 36 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0989W698Mlre. Suite100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030284 Pace Project No.: 92240781 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92240781001 2015006843 EPA 3050 MPRP/23172 EPA 6010 92240781002 2015006854 EPA 3050 MPRP/23172 EPA 6010 92240781003 2015006855 EPA 3050 MPRP/23172 EPA 6010 92240781001 2015006843 EPA 3050 MPRP/23173 EPA 6020 92240781002 2015006854 EPA 3050 MPRP/23173 EPA 6020 92240781003 2015006855 EPA 3050 MPRP/23173 EPA 6020 92240781001 2015006843 EPA 7471 MERP/5493 EPA 7471 92240781002 2015006854 EPA 7471 MERP/5493 EPA 7471 92240781003 2015006855 EPA 7471 MERP/5493 EPA 7471 92240781001 2015006843 ASTM D2974-87 PMST/3371 92240781002 2015006854 ASTM D2974-87 PMST/3371 92240781003 2015006855 ASTM D2974-87 PMST/3371 92240781001 2015006843 EPA 9045 WET/36257 92240781002 2015006854 EPA 9045 WET/36257 92240781003 2015006855 EPA 9045 WET/36257 92240781001 2015006843 EPA 9056 WETA/44600 92240781002 2015006854 EPA 9056 WETA/44600 92240781003 2015006855 EPA 9056 WETA/44600 92240781001 2015006843 EPA 9056 WETA/44599 92240781002 2015006854 EPA 9056 WETA/44599 92240781003 2015006855 EPA 9056 WETA/44599 92240781001 2015006843 EPA 9060 WETA/27622 92240781001 2015006843 EPA 9060 WETA/27623 92240781002 2015006854 EPA 9060 WETA/27622 92240781002 2015006854 EPA 9060 WETA/27623 92240781003 2015006855 EPA 9060 WETA/27622 92240781003 2015006855 EPA 9060 WETA/27623 Date: 03/25/2015 09:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14182 ICP/14182 ICP/14182 ICPM/9448 ICPM/9448 ICPM/9448 MERC/5482 MERC/5482 MERC/5482 Page 34 of 36 document Dame: uocument Keviseci: z)epiemuut z- — ,� r�ceAltalyir'cla Sample Condition Upon Receipt (SCUR) Page 1 of Document Number: Issuing AutVSgy:41 of 43 F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Narne:- Courier: ❑Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial® FQ-0 Other + t Custody Seal on Cooler/Box Present: ❑ yes no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble VE)p D B 6� 1e Bagg ❑ None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice:e? Blue None ❑'"mp[es on ice, cooling process has begun 7cmn rnrror4inn �erfnr TIAnl Nn r ..nrronfinn Corrected Cooler Tem 1 - •C Biological Tissue is Frozen: Yes No �fiA1 p•� Date and Initialof person + Intng contents: - � Temp should be above freezing to 6°C Comments: Chain of Custody Present; nlys ONO ❑NIA 1. Chain of Custody Filled Out: Yes ONO ❑NIA 2. Chain of Custody Relinquished: ClYes ONO ❑NIA 3. Sampler Name & Signature on COC: Iflyas ONO ❑NIA 4. Samples Arrived within Hold Time: Gres ONO ❑N/A 5. Short Hold Time Analysis (a72hr): Dyes dNo ❑NIA 6. Rush Turn Around Time Requested: Dyes. 0 o ❑NIA 7. Sufficient Volume: es Elmo 0NIA 8, Correct Containers Used: �,❑ es ❑No �No CINIA 9. -Pace Containers Used: Yes El NIA. Containers Intact: 0 es ❑No ❑N!A 10, Filtered volume received for Dissolved tests ❑Yo f C]No NIA 11. Sample Labels match COC: ®es ❑No DNIA 12, �� -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. Dyes []No 13. All containers needing preservation are found to be in ❑Yes Elmo No �N!%A NIA compliance with EPA recommendation. Dyes I JNo exceptions: VOA, coliform, TOC, O&G, W-DRO (water) Samples checked for dechlorination: ❑Yes ONO ®'NIA 14, Headspace in VOA Vials >6mm): fives ❑No d A 15. Trip Blank Present: Dyes LINO '6ZIA 16, Trip Blank Custody Seals Present ❑Yes f]No Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Date/Time: Field Data Required? Y 1 N SCURF Review: W. lDate:IZE T WO# • 9224 (V 1 SRF Review: EA Date: W Note: Whenever there is a discr panty affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR I ff I II Certification Office (Le out of hold, incorrect preservative, out of temp, 92240781 incorrect containers) Page 35 of 36 - �+ Cugornermw, Comri&age 42 of 43 ®r R g ! C' a d m '� •� � � v} q�Q 5 z � g o � c s �3 � .Custumcr N., compl,•cr.ap�oroprialo columns to rlghl -. ..---_� ° a Cu 0 zQ m X FL M o 0 g Q ° p a e Vitro ^_ rn o N a r H I ss e_ (D N a a 3 x r I s v_ W G P O m` a N T I^n it I oo . - C1 Z N a. u w w lyr•'ta 3 C7 0 o g i 0 rye o 8 I .------_.-._.1 in i I Ilk m ' 8 ul ui Vl e a ,, -� ^O 4.1' i - Q �' . , rt '� < 1�' rani C. C1 O 0 o .'. iilyr. N y Q 5 �a OQ 3 I z I o W3 iBGreb Req Ire = i s r Mir- 0 [ - Total Metals , Anions, ° °Q i fn `a� a pH n 8 oz jar (PACE) 5 O l Sri oil TOC 1 - 4 oz jar (PACE) 4 a c l f71 SPLP -Total Metals and Anions 10 2 - 8 oz jars (PACE) 5 Sediment specific �t tests 2 - 8 oz jar i (ACCESS i ANALYTICAL) 5 w rye;"t- C' � I OOo rop �2 _ r o —1 -�.. !e C O z�0 y�o a uc r -1 !6o z -total a of Containers$'s `.. � ,X_ {-� Page 36 of 36 CHAIN OF CUSTODY RECORD AND ANALYSIS, REQUEST FORM ------------------ -------------------- ....... ........... k Anplocal Laboratory Services i I Anal)!�:-Anal U600* PDUKE Mail Cadle MG0M2 [BuMny 7405] vaut.: SOIL SIP_ DISTRiBunom 13339 Hpgwa Ferry Rd &6nelfill OfIgIrW1109 Fft4% N. C. ZWT8 ORIGINAL io LAo. ENERUT, L9110) 975,5245 i CL. COPY 10 CL 1E NT ----- ------- �MLJAMA?- ------------ SAMPLE P11ROGIFLAM Gmmnd WOW NPDESI Irm)"kame Al Ground,, Q`leF Assessment s_sme_nt - S01121P1*00 ft 0VW rot • REYDA.TF 2fTQMl 5 H. V LoACE GOOIar T mC1 4PFM lklim AB GW po 1142 '—fir [M : vohmn m"cWft ncouFFLing hn hmm nsthb4lsh" and ks 004 indlGatod atwoo Preservalives when used must be we neon the lollowlftfj 10 E111:114 CQWoc`! W.CuuPPIM0 In all S acnaa ilng field% aho".. pr added within, 15 Fnin utes of sample 121 pfovldm cnrrjpcj aw;c.mirriling ror Upafmtinp 1-14tic and 15o emn ID wil"thon mamx G.ollortion Information [&ak Sedim", "14 "Sam pie Des c ription or ICI 0-8 1 T— signs-wv S43 —.2- Iq IV ej S; 6 S7 L) 0 CL N' 'n LO r- C5 W fq E -0 -J (n CM V) a c < lRel —I, d- �-o a �If UR*qljodted Turnaround Poor. V-J�V-- "Wro" 40 Hr 4Wa�.narft Metals: M. Sh, As, Fla, tie, B., Cd, Ca, Cr, Co, Ckj, Fly', Pt�, Mg, Mn, , Nk IS, So, Nd, Sr, T1, V, Zil, Mercury, PH Pj Anions; Cl. Nitrate-N,!504 Sediment Sper4fic Parameters: %Solldil, CEC PaTtIeW Size DistributiDn, Redox PoftimtW1