Loading...
HomeMy WebLinkAboutNC0003417_J15030051 Report_20150805DUE Analytical Laboratory Page 1of94 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15030051 AB GW ASSESSMENT SOIL Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer 1677 Old Smithfield Rd Goldsboro NC 27530, Margaret Galvin -Karr Phone: 980-875-5219 ma rge.galvi n-karr@du ke- energy.com ' kRGY% 2015.04.2313:37:17-04'00 Date: Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 4/22/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015005889 HF LEE PLANT 18-Feb-15 2:18 PM ILLEGIBLE AMW-12-0-2 2015005890 HF LEE PLANT 19-Feb-15 5:00 PM ILLEGIBLE AMW-12SB-5-6 2015005891 HF LEE PLANT 19-Feb-15 5:20 PM ILLEGIBLE AMW-12SB-11-13 2015005892 HF LEE PLANT 23-Feb-15 1:29 PM ILLEGIBLE AMW-13SB-0-2 2015005893 HF LEE PLANT 23-Feb-15 5:09 PM ILLEGIBLE AMW-13SB-6-8 2015005894 HF LEE PLANT 23-Feb-15 5:00 PM ILLEGIBLE AMW-13SB-12-13 2015005901 HF LEE PLANT 23-Feb-15 10:52 AM ILLEGIBLE EB-1 7 Total Samples Page 2 of 94 Page 3 of 94 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/22/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030051 Site: AMW-12-0-2 Collection Date: 18-Feb-15 2:18 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 94 Sample #: 2015005889 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030051 Site: AMW-12SB-5-6 Collection Date: 19-Feb-15 5:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 94 Sample #: 2015005890 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030051 Site: AMW-12SB-11-13 Collection Date: 19-Feb-15 5:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 94 Sample #: 2015005891 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030051 Site: AMW-13SB-0-2 Collection Date: 23-Feb-15 1:29 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 94 Sample #: 2015005892 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030051 Site: AMW-13SB-6-8 Collection Date: 23-Feb-15 5:09 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 94 Sample #: 2015005893 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030051 Site: AMW-13SB-12-13 Collection Date: 23-Feb-15 5:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 9 of 94 Sample #: 2015005894 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030051 Site: EB-1 Collection Date: 23-Feb-15 10:52 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015005901 Matrix: OTHER Page 10 of 94 Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�in�c&fie. Suite 100 y Huntersville, INC 28078 (704)875-9092 April 21, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15030051 Pace Project No.: 92239540 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 03, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 67 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. oQgg i2cgfoe. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030051 Pace Project No.: 92239540 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030051 Pace Project No.: 92239540 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�ic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15030051 Pace Project No.: 92239540 Lab ID Sample ID Matrix Date Collected Date Received 92239540001 2015005889 Solid 02/18/1514:18 03/03/15 17:00 92239540002 2015005890 Solid 02/19/15 17:00 03/03/15 17:00 92239540003 2015005891 Solid 02/19/1517:20 03/03/15 17:00 92239540004 2015005892 Solid 02/23/1513:29 03/03/15 17:00 92239540005 2015005893 Solid 02/23/1517:09 03/03/15 17:00 92239540006 2015005894 Solid 02/23/1517:00 03/03/15 17:00 92239540007 2015005889 SPLP Water 02/18/15 14:18 03/03/15 17:00 92239540008 2015005890 SPLP Water 02/19/15 17:00 03/03/15 17:00 92239540009 2015005891 SPLP Water 02/19/15 17:20 03/03/15 17:00 92239540010 2015005901 Water 02/23/1510:52 03/03/15 17:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15030051 Pace Project No.: 92239540 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92239540001 2015005889 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 KEW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E DMN 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92239540002 2015005890 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 KEW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E DMN 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92239540003 2015005891 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 KEW 1 PASI-G EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E DMN 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92239540004 2015005892 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15030051 92239540 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O 92239540005 2015005893 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O 92239540006 2015005894 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O 92239540007 2015005889 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92239540008 2015005890 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92239540009 2015005891 SPLP EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92239540010 2015005901 EPA 6020A TT3 24 PASI-M EPA 7470 DM 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffiic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15030051 92239540 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92239540001 2015005889 EPA 6010 Aluminum 1720 mg/kg 6.1 03/17/15 08:24 M1,R1 EPA 6010 Barium 6.1 mg/kg 0.61 03/17/15 08:24 EPA 6010 Beryllium 0.039J mg/kg 0.061 03/17/15 08:24 EPA 6010 Boron 1.8J mg/kg 3.0 03/17/15 08:24 EPA 6010 Calcium 42.4 mg/kg 30.4 03/17/15 08:24 EPA 6010 Chromium 2.4 mg/kg 0.30 03/17/15 08:24 EPA 6010 Copper 1.2 mg/kg 0.30 03/17/15 08:24 EPA 6010 Iron 2350 mg/kg 2.4 03/17/15 08:24 M1 EPA 6010 Magnesium 52.0 mg/kg 30.4 03/17/15 08:24 EPA 6010 Manganese 2.7 mg/kg 0.30 03/17/15 08:24 EPA 6010 Nickel 0.84 mg/kg 0.30 03/17/15 08:24 EPA 6010 Potassium 40AJ mg/kg 60.9 03/17/15 08:24 EPA 6010 Strontium 0.35J mg/kg 0.61 03/17/15 08:24 EPA 6010 Zinc 4.3 mg/kg 1.2 03/17/15 08:24 EPA 6020 Arsenic 1.4 mg/kg 1.2 03/17/15 11:10 D3 EPA 6020 Cobalt 9.9 mg/kg 1.2 03/17/15 11:10 D3 EPA 6020 Lead 4.8 mg/kg 1.2 03/17/15 11:10 D3 EPA 6020 Selenium 0.891 mg/kg 1.2 03/17/15 11:10 D3 EPA 6020 Thallium 0.66J mg/kg 1.2 03/17/15 11:10 D3 EPA 6020 Vanadium 37.6 mg/kg 1.2 03/17/15 11:10 D4 EPA 7471 Mercury 0.011 mg/kg 0.0096 03/17/15 12:50 ASTM D2974-87 Percent Moisture 16.7 % 0.10 03/18/15 14:29 EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 03/06/15 15:45 EPA 300.0 Sulfate 3.5 mg/L 2.4 03/19/15 18:49 EPA353.2 Nitrogen, Nitrate 0.41 mg/L 0.24 03/18/1516:23 B,H1 EPA 9060 Total Organic Carbon 2590 mg/kg 719 03/12/15 09:52 EPA 9060 Total Organic Carbon 2510 mg/kg 720 03/12/15 09:58 EPA 9060 Total Organic Carbon 2220 mg/kg 717 03/12/15 10:04 EPA 9060 Total Organic Carbon 2290 mg/kg 722 03/12/15 10:09 EPA 9060 Mean Total Organic Carbon 2400 mg/kg 719 03/12/15 09:52 EPA 9060 RSD% 7.3 % 03/12/15 09:52 92239540002 2015005890 EPA 6010 Aluminum 2400 mg/kg 5.8 03/17/15 08:36 EPA 6010 Barium 8.1 mg/kg 0.58 03/17/15 08:36 EPA 6010 Beryllium 0.058J mg/kg 0.058 03/17/15 08:36 EPA 6010 Boron 4.8 mg/kg 2.9 03/17/15 08:36 EPA 6010 Calcium 74.8 mg/kg 29.0 03/17/15 08:36 EPA 6010 Chromium 4.4 mg/kg 0.29 03/17/15 08:36 EPA 6010 Copper 2.7 mg/kg 0.29 03/17/15 08:36 EPA 6010 Iron 5850 mg/kg 2.3 03/17/15 08:36 EPA 6010 Magnesium 55.3 mg/kg 29.0 03/17/15 08:36 EPA 6010 Manganese 3.0 mg/kg 0.29 03/17/15 08:36 EPA 6010 Nickel 0.57 mg/kg 0.29 03/17/15 08:36 EPA 6010 Potassium 44AJ mg/kg 58.1 03/17/15 08:36 EPA 6010 Strontium 0.69 mg/kg 0.58 03/17/15 08:36 EPA 6010 Zinc 4.8 mg/kg 1.2 03/17/15 08:36 EPA 6020 Arsenic 4.5 mg/kg 1.2 03/17/1511:12 D3,M6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15030051 92239540 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92239540002 2015005890 EPA 6020 Cadmium 0.082J mg/kg 0.14 03/17/15 11:12 D3 EPA 6020 Cobalt 11.3 mg/kg 1.2 03/17/15 11:12 D3,M6 EPA 6020 Lead 3.5 mg/kg 1.2 03/17/15 11:12 D3 EPA 6020 Selenium 0.96J mg/kg 1.2 03/17/15 11:12 D3 EPA 6020 Thallium 0.73J mg/kg 1.2 03/17/15 11:12 D3 EPA 6020 Vanadium 37.2 mg/kg 1.2 03/17/15 11:12 D4,M6 EPA 7471 Mercury 0.0044J mg/kg 0.0088 03/17/15 12:59 ASTM D2974-87 Percent Moisture 13.4 % 0.10 03/18/15 14:29 EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 03/06/15 15:45 EPA 300.0 Sulfate 3.8 mg/L 2.3 03/19/15 19:30 EPA353.2 Nitrogen, Nitrate 0.33 mg/L 0.23 03/18/1516:29 B,H1 EPA 9060 Total Organic Carbon 1110 mg/kg 694 03/12/15 11:13 EPA 9060 Total Organic Carbon 977 mg/kg 692 03/12/15 11:18 EPA 9060 Total Organic Carbon 1160 mg/kg 694 03/12/15 11:24 EPA 9060 Total Organic Carbon 1120 mg/kg 693 03/12/15 11:29 EPA 9060 Mean Total Organic Carbon 1090 mg/kg 693 03/12/15 11:13 EPA 9060 RSD% 7.5 % 03/12/15 11:13 92239540003 2015005891 EPA 6010 Aluminum 775 mg/kg 5.8 03/17/15 09:06 EPA 6010 Barium 2.5 mg/kg 0.58 03/17/15 09:06 EPA 6010 Beryllium 0.11 mg/kg 0.058 03/17/15 09:06 EPA 6010 Boron 4.5 mg/kg 2.9 03/17/15 09:06 EPA 6010 Chromium 18.3 mg/kg 0.29 03/17/15 09:06 EPA 6010 Copper 7.3 mg/kg 0.29 03/17/15 09:06 EPA 6010 Iron 5240 mg/kg 2.3 03/17/15 09:06 EPA 6010 Manganese 19.1 mg/kg 0.29 03/17/15 09:06 EPA 6010 Nickel 7.8 mg/kg 0.29 03/17/15 09:06 EPA 6010 Potassium 35.3J mg/kg 58.4 03/17/15 09:06 EPA 6010 Sodium 32.9J mg/kg 58.4 03/17/15 09:06 EPA 6010 Strontium 0.36J mg/kg 0.58 03/17/15 09:06 EPA 6010 Zinc 7.2 mg/kg 1.2 03/17/15 09:06 EPA 6020 Arsenic 1.5 mg/kg 1.2 03/17/15 11:19 D3 EPA 6020 Cobalt 16.5 mg/kg 1.2 03/17/15 11:19 D3 EPA 6020 Lead 6.4 mg/kg 1.2 03/17/15 11:19 D3 EPA 6020 Selenium 1.4 mg/kg 1.2 03/17/15 11:19 D3 EPA 6020 Thallium 0.62J mg/kg 1.2 03/17/15 11:19 D3 EPA 6020 Vanadium 55.9 mg/kg 1.2 03/17/15 11:19 D4 ASTM D2974-87 Percent Moisture 16.2 % 0.10 03/18/15 14:29 EPA 9045 pH at 25 Degrees C 5.8 Std. Units 0.10 03/06/15 15:45 EPA 300.0 Sulfate 2.8 mg/L 2.4 03/19/15 19:43 EPA353.2 Nitrogen, Nitrate 0.41 mg/L 0.24 03/18/1516:37 B,H1 EPA 9060 RSD% 5.7 % 03/12/15 11:36 92239540004 2015005892 EPA 6010 Aluminum 9510 mg/kg 6.5 03/17/15 09:10 EPA 6010 Barium 58.3 mg/kg 0.65 03/17/15 09:10 EPA 6010 Beryllium 0.94 mg/kg 0.33 03/17/15 13:19 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15030051 Pace Project No.: 92239540 Lab Sample ID Client Sample ID Method Parameters 92239540004 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6020 EPA 6020 EPA 6020 EPA 6020 EPA 6020 EPA 6020 EPA 7471 ASTM D2974-87 EPA 9045 92239540005 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6020 EPA 6020 EPA 6020 EPA 6020 EPA 6020 EPA 7471 ASTM D2974-87 EPA 9045 92239540006 EPA 6010 EPA 6010 2015005892 Boron Calcium Chromium Copper Iron Magnesium Manganese Nickel Potassium Strontium Zinc Arsenic Cobalt Lead Selenium Thallium Vanadium Mercury Percent Moisture pH at 25 Degrees C 2015005893 Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Nickel Potassium Strontium Zinc Arsenic Cobalt Lead Selenium Vanadium Mercury Percent Moisture pH at 25 Degrees C 2015005894 Aluminum Barium SUMMARY OF DETECTION Result Units Report Limit Analyzed 15.5J mg/kg 16.3 03/17/1513:19 130 mg/kg 32.6 03/17/15 09:10 14.0 mg/kg 1.6 03/17/1513:19 13.8 mg/kg 1.6 03/17/1513:19 16100 mg/kg 2.6 03/17/15 09:10 1830 mg/kg 32.6 03/17/15 09:10 377 mg/kg 1.6 03/17/1513:19 5.1 mg/kg 0.33 03/17/15 09:10 722 mg/kg 65.3 03/17/15 09:10 3.3 mg/kg 0.65 03/17/15 09:10 27.9 mg/kg 1.3 03/17/15 09:10 1.8 mg/kg 1.3 03/17/1511:21 17.5 mg/kg 1.3 03/17/1511:21 8.0 mg/kg 1.3 03/17/1511:21 1.4 mg/kg 1.3 03/17/1511:21 0.84J mg/kg 1.3 03/17/1511:21 94.8 mg/kg 1.3 03/17/1511:21 0.050 mg/kg 0.010 03/17/1513:03 20.0 % 0.10 03/16/1515:18 4.5 Std. Units 0.10 04/13/15 14:30 4890 mg/kg 6.0 03/17/15 09:15 34.9 mg/kg 0.60 03/17/15 09:15 0.45 mg/kg 0.060 03/17/15 09:15 7.2 mg/kg 3.0 03/17/15 09:15 159 mg/kg 30.2 03/17/15 09:15 8.3 mg/kg 0.30 03/17/15 09:15 5.9 mg/kg 0.30 03/17/15 09:15 9530 mg/kg 2.4 03/17/15 09:15 1130 mg/kg 30.2 03/17/15 09:15 251 mg/kg 0.30 03/17/15 09:15 3.0 mg/kg 0.30 03/17/15 09:15 280 mg/kg 60.5 03/17/15 09:15 4.2 mg/kg 0.60 03/17/15 09:15 12.2 mg/kg 1.2 03/17/15 09:15 1.1J mg/kg 1.2 03/17/1511:37 7.6 mg/kg 1.2 03/17/1511:37 6.5 mg/kg 1.2 03/17/1511:37 0.901 mg/kg 1.2 03/17/1511:37 21.7 mg/kg 1.2 03/17/1511:37 0.010 mg/kg 0.0099 03/17/1513:10 15.8 % 0.10 03/16/1515:19 5.3 Std. Units 0.10 04/13/15 14:30 542 6.8 mg/kg mg/kg REPORT OF LABORATORY ANALYSIS 5.7 03/17/15 09:19 0.57 03/17/15 09:19 D3 D3 D3 D3 D3 D3 D3 D3 D3 D4 M1 H6 D3 D3 D3 D3 D3 H6 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030051 Pace Project No.: 92239540 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92239540006 2015005894 EPA 6010 Beryllium 0.18 mg/kg 0.057 03/17/15 09:19 EPA 6010 Boron 1.8J mg/kg 2.8 03/17/15 09:19 EPA 6010 Calcium 61.0 mg/kg 28.3 03/17/15 09:19 EPA 6010 Chromium 5.5 mg/kg 0.28 03/17/15 09:19 EPA 6010 Copper 7.1 mg/kg 0.28 03/17/15 09:19 EPA 6010 Iron 2450 mg/kg 2.3 03/17/15 09:19 EPA 6010 Magnesium 52.0 mg/kg 28.3 03/17/15 09:19 EPA 6010 Manganese 14.1 mg/kg 0.28 03/17/15 09:19 EPA 6010 Nickel 3.1 mg/kg 0.28 03/17/15 09:19 EPA 6010 Potassium 41 AJ mg/kg 56.6 03/17/15 09:19 EPA 6010 Strontium 0.73 mg/kg 0.57 03/17/15 09:19 EPA 6010 Zinc 9.7 mg/kg 1.1 03/17/15 09:19 EPA 6020 Cobalt 1.8 mg/kg 1.1 03/17/15 11:40 EPA 6020 Lead 1.3 mg/kg 1.1 03/17/15 11:40 EPA 6020 Vanadium 10.3 mg/kg 1.1 03/17/15 11:40 ASTM D2974-87 Percent Moisture 7.7 % 0.10 03/16/15 15:20 EPA 9045 pH at 25 Degrees C 5.8 Std. Units 0.10 04/13/15 14:30 92239540007 2015005889 SPLP EPA 6020A Aluminum 6550 ug/L 10.0 04/06/15 11:00 EPA 6020A Arsenic 1.1 ug/L 0.50 04/06/15 11:00 EPA 6020A Barium 22.5 ug/L 0.30 04/06/15 11:00 EPA 6020A Boron 24.9 ug/L 5.0 04/06/15 11:00 EPA 6020A Cadmium 0.28 ug/L 0.080 04/06/15 11:00 EPA 6020A Calcium 808 ug/L 40.0 04/06/15 11:00 EPA 6020A Chromium 7.7 ug/L 0.50 04/06/15 11:00 EPA 6020A Cobalt 0.77 ug/L 0.50 04/06/15 11:00 EPA 6020A Copper 3.1 ug/L 1.0 04/06/15 11:00 EPA 6020A Iron 4030 ug/L 50.0 04/06/15 11:00 EPA 6020A Lead 4.8 ug/L 0.10 04/06/15 11:00 EPA 6020A Magnesium 486 ug/L 10.0 04/06/15 11:00 EPA 6020A Manganese 11.5 ug/L 0.50 04/06/15 11:00 EPA 6020A Nickel 6.4 ug/L 0.50 04/06/15 11:00 EPA 6020A Potassium 617 ug/L 50.0 04/06/15 11:00 EPA 6020A Sodium 620 ug/L 50.0 04/06/15 11:00 EPA 6020A Strontium 2.9 ug/L 0.50 04/06/15 11:00 EPA 6020A Vanadium 13.2 ug/L 1.0 04/06/15 11:00 EPA 6020A Zinc 72.2 ug/L 5.0 04/06/15 11:00 92239540008 2015005890 SPLP EPA 6020A Aluminum 404 ug/L 10.0 04/06/15 11:05 EPA 6020A Barium 13.6 ug/L 0.30 04/06/15 11:05 EPA 6020A Boron 18.0 ug/L 5.0 04/06/15 11:05 EPA 6020A Calcium 824 ug/L 40.0 04/06/15 11:05 EPA 6020A Chromium 1.1 ug/L 0.50 04/06/15 11:05 EPA 6020A Iron 295 ug/L 50.0 04/06/15 11:05 EPA 6020A Lead 0.28 ug/L 0.10 04/06/15 11:05 EPA 6020A Magnesium 266 ug/L 10.0 04/06/15 11:05 REPORT OF LABORATORY ANALYSIS D3 D3 D3 H6 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinvq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15030051 Pace Project No.: 92239540 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92239540008 2015005890 SPLP EPA 6020A Manganese 11.9 ug/L 0.50 04/06/15 11:05 EPA 6020A Nickel 1.1 ug/L 0.50 04/06/15 11:05 EPA 6020A Potassium 398 ug/L 50.0 04/06/15 11:05 EPA 6020A Sodium 558 ug/L 50.0 04/06/15 11:05 EPA 6020A Strontium 4.2 ug/L 0.50 04/06/15 11:05 EPA 6020A Vanadium 1.3 ug/L 1.0 04/06/15 11:05 EPA 6020A Zinc 12.4 ug/L 5.0 04/06/15 11:05 92239540009 2015005891 SPLP EPA 6020A Aluminum 14.9 ug/L 10.0 04/06/15 10:16 EPA 6020A Barium 0.66 ug/L 0.30 04/06/15 10:16 EPA 6020A Boron 60.5 ug/L 5.0 04/06/15 10:16 EPA 6020A Calcium 118 ug/L 40.0 04/06/15 10:16 EPA 6020A Chromium 0.63 ug/L 0.50 04/06/15 10:16 EPA 6020A Iron 67.6 ug/L 50.0 04/06/15 10:16 EPA 6020A Magnesium 64.4 ug/L 10.0 04/06/15 10:16 EPA 6020A Manganese 8.5 ug/L 0.50 04/06/15 10:16 EPA 6020A Nickel 0.51 ug/L 0.50 04/06/15 10:16 EPA 6020A Potassium 752 ug/L 50.0 04/06/15 10:16 EPA 6020A Sodium 2720 ug/L 50.0 04/06/15 10:16 EPA 6020A Strontium 0.50 ug/L 0.50 04/06/15 10:16 EPA 6020A Zinc 5.2 ug/L 5.0 04/06/15 10:16 92239540010 2015005901 EPA 6020A Aluminum 44.7 ug/L 10.0 03/12/15 15:38 M1 EPA 6020A Barium 3.8 ug/L 0.30 03/12/15 15:38 EPA 6020A Calcium 3900 ug/L 40.0 03/12/15 15:38 EPA 6020A Chromium 4.2 ug/L 0.50 03/12/15 15:38 EPA 6020A Copper 2.0 ug/L 1.0 03/12/15 15:38 EPA 6020A Iron 404 ug/L 50.0 03/12/15 15:38 EPA 6020A Lead 0.47 ug/L 0.10 03/12/15 15:38 EPA 6020A Magnesium 229 ug/L 10.0 03/12/15 15:38 EPA 6020A Manganese 8.0 ug/L 0.50 03/12/15 15:38 EPA 6020A Molybdenum 1.5 ug/L 0.50 03/12/15 15:38 EPA 6020A Potassium 1290 ug/L 50.0 03/12/15 15:38 EPA 6020A Sodium 3180 ug/L 50.0 03/12/15 15:38 EPA 6020A Strontium 21.4 ug/L 0.50 03/12/15 15:38 EPA 6020A Vanadium 1.8 ug/L 1.0 03/12/15 15:38 EPA 6020A Zinc 5.1 ug/L 5.0 03/12/15 15:38 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g KiQvq'w e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 21, 2015 General Information: 6 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23094 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1157067) • Aluminum • Iron • MSD (Lab ID: 1157068) • Aluminum • Iron R1: RPD value was outside control limits. • MSD (Lab ID: 1157068) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g KiSvq'w e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 21, 2015 Analyte Comments: QC Batch: MPRP/23094 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005892 (Lab ID:92239540004) • Boron • Beryllium • Chromium • Copper • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g K4-8yq'w e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 21, 2015 General Information: 6 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23095 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1157071) • Antimony • Arsenic • Cobalt • Vanadium • MSD (Lab ID: 1157072) • Antimony • Arsenic • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 21, 2015 Analyte Comments: QC Batch: MPRP/23095 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005889 (Lab ID:92239540001) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015005890 (Lab ID:92239540002) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015005891 (Lab ID:92239540003) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015005892 (Lab ID:92239540004) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015005893 (Lab ID:92239540005) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015005894 (Lab ID:92239540006) • Arsenic REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g %-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 21, 2015 Analyte Comments: QC Batch: MPRP/23095 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005894 (Lab ID:92239540006) • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MS (Lab ID: 1157071) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MSD (Lab ID: 1157072) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. •2015005889 (Lab ID:92239540001) • Vanadium •2015005890 (Lab ID:92239540002) • Vanadium •2015005891 (Lab ID:92239540003) • Vanadium •2015005892 (Lab ID:92239540004) • Vanadium • MS (Lab ID: 1157071) • Vanadium • MSD (Lab ID: 1157072) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015005889 (Lab ID:92239540001) • Antimony •2015005890 (Lab ID:92239540002) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gl i vq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 21, 2015 Analyte Comments: QC Batch: MPRP/23095 N2: The lab does not hold TNI accreditation for this parameter. •2015005891 (Lab ID:92239540003) • Antimony •2015005892 (Lab ID:92239540004) • Antimony •2015005893 (Lab ID:92239540005) • Antimony •2015005894 (Lab ID:92239540006) • Antimony • BLANK (Lab ID: 1157069) • Antimony • LCS (Lab ID: 1157070) • Antimony • MS (Lab ID: 1157071) • Antimony • MSD (Lab ID: 1157072) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 21, 2015 General Information: 4 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52897 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540010 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1916666) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qgtr�-8Y9,We. Suite 100 �yJ Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: April 21, 2015 General Information: 4 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. • 2015005889 SPLP (Lab ID: 92239540007) • 2015005890 SPLP (Lab ID: 92239540008) • 2015005891 SPLP (Lab ID: 92239540009) Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gIsinyq'We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 21, 2015 General Information: 6 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5474 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540004 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1157679) • Mercury • MSD (Lab ID: 1157680) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinic8y9'We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 21, 2015 General Information: 6 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-16: Analysis initiated outside of the 15 minute EPA recommended holding time. •2015005892 (Lab ID:92239540004) •2015005893 (Lab ID:92239540005) •2015005894 (Lab ID:92239540006) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gIsinyq'We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: April 21, 2015 General Information: 3 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gIsisc8)r9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 21, 2015 General Information: 3 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015005889 (Lab ID:92239540001) •2015005890 (Lab ID:92239540002) •2015005891 (Lab ID:92239540003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22256 B: Analyte was detected in the associated method blank. • BLANK for HBN 256042 [WETA/222 (Lab ID: 1413768) • Nitrogen, Nitrate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gts4-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: April 21, 2015 General Information: 3 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gIsinyq'We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 21, 2015 General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44508 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005889 (Lab ID:92239540001) • Chloride • Sulfate •2015005890 (Lab ID:92239540002) • Chloride • Sulfate •2015005891 (Lab ID:92239540003) • Chloride • Sulfate •2015005892 (Lab ID:92239540004) • Chloride • Sulfate •2015005893 (Lab ID:92239540005) • Chloride • Sulfate •2015005894 (Lab ID:92239540006) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gIse- We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 21, 2015 General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1­13: Sample was received or analysis requested beyond the recognized method holding time. •2015005889 (Lab ID:92239540001) •2015005890 (Lab ID:92239540002) •2015005891 (Lab ID:92239540003) •2015005892 (Lab ID:92239540004) •2015005893 (Lab ID:92239540005) •2015005894 (Lab ID:92239540006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44509 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005889 (Lab ID:92239540001) • Nitrate as N •2015005890 (Lab ID:92239540002) • Nitrate as N •2015005891 (Lab ID:92239540003) • Nitrate as N •2015005892 (Lab ID:92239540004) • Nitrate as N •2015005893 (Lab ID:92239540005) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gl i vq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 21, 2015 Analyte Comments: QC Batch: WETA/44509 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005894 (Lab ID:92239540006) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g igcw'We. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239540 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 21, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gIsinygWe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005889 Lab ID: 92239540001 Collected: 02/18/15 14:18 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 1720 mg/kg 6.1 3.0 1 03/16/15 12:27 03/17/15 08:24 7429-90-5 M1,R1 Barium 6.1 mg/kg 0.61 0.30 1 03/16/15 12:27 03/17/15 08:24 7440-39-3 Beryllium 0.039J mg/kg 0.061 0.030 1 03/16/15 12:27 03/17/15 08:24 7440-41-7 Boron 1.8J mg/kg 3.0 1.5 1 03/16/15 12:27 03/17/15 08:24 7440-42-8 Calcium 42.4 mg/kg 30.4 15.2 1 03/16/15 12:27 03/17/15 08:24 7440-70-2 Chromium 2.4 mg/kg 0.30 0.15 1 03/16/15 12:27 03/17/15 08:24 7440-47-3 Copper 1.2 mg/kg 0.30 0.15 1 03/16/15 12:27 03/17/15 08:24 7440-50-8 Iron 2350 mg/kg 2.4 1.2 1 03/16/15 12:27 03/17/15 08:24 7439-89-6 M1 Magnesium 52.0 mg/kg 30.4 15.2 1 03/16/15 12:27 03/17/15 08:24 7439-95-4 Manganese 2.7 mg/kg 0.30 0.15 1 03/16/15 12:27 03/17/15 08:24 7439-96-5 Molybdenum ND mg/kg 0.61 0.30 1 03/16/15 12:27 03/17/15 08:24 7439-98-7 Nickel 0.84 mg/kg 0.30 0.15 1 03/16/15 12:27 03/17/15 08:24 7440-02-0 Potassium 40AJ mg/kg 60.9 30.4 1 03/16/15 12:27 03/17/15 08:24 7440-09-7 Sodium ND mg/kg 60.9 30.4 1 03/16/15 12:27 03/17/15 08:24 7440-23-5 Strontium 0.35J mg/kg 0.61 0.30 1 03/16/15 12:27 03/17/15 08:24 7440-24-6 Zinc 4.3 mg/kg 1.2 0.61 1 03/16/15 12:27 03/17/15 08:24 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.2 0.61 20 03/16/15 12:27 03/17/1511:10 7440-36-0 D3,N2 Arsenic 1.4 mg/kg 1.2 0.61 20 03/16/15 12:27 03/17/1511:10 7440-38-2 D3 Cadmium ND mg/kg 0.15 0.073 20 03/16/15 12:27 03/17/1511:10 7440-43-9 D3 Cobalt 9.9 mg/kg 1.2 0.61 20 03/16/15 12:27 03/17/1511:10 7440-48-4 D3 Lead 4.8 mg/kg 1.2 0.61 20 03/16/15 12:27 03/17/1511:10 7439-92-1 D3 Selenium 0.891 mg/kg 1.2 0.61 20 03/16/15 12:27 03/17/1511:10 7782-49-2 D3 Thallium 0.66J mg/kg 1.2 0.61 20 03/16/15 12:27 03/17/1511:10 7440-28-0 D3 Vanadium 37.6 mg/kg 1.2 0.61 20 03/16/15 12:27 03/17/1511:10 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.011 mg/kg 0.0096 0.0048 1 03/17/15 06:13 03/17/15 12:50 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.7 % 0.10 0.10 1 03/18/15 14:29 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 0.10 1 03/06/15 15:45 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 3.5 mg/L 2.4 1.2 1 03/19/1518:49 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate 0.41 mg/L 0.24 0.24 1 03/18/15 16:23 B,H1 4500 Chloride, SPLP Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride ND mg/L 6.0 3.0 1 03/19/15 20:59 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005889 Lab ID: 92239540001 Collected: 02/18/15 14:18 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 297 149 5 03/13/1513:40 16887-00-6 D3,M1 Sulfate ND mg/kg 297 149 5 03/13/1513:40 14808-79-8 D3,M1 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.7 14.9 5 03/13/15 13:40 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2590 mg/kg 719 359 1 03/12/15 09:52 7440-44-0 Total Organic Carbon 2510 mg/kg 720 360 1 03/12/15 09:58 7440-44-0 Total Organic Carbon 2220 mg/kg 717 359 1 03/12/15 10:04 7440-44-0 Total Organic Carbon 2290 mg/kg 722 361 1 03/12/15 10:09 7440-44-0 Mean Total Organic Carbon 2400 mg/kg 719 360 1 03/12/15 09:52 7440-44-0 Surrogates RSD% 7.3 % 1 03/12/15 09:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWinic8yqWe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005890 Lab ID: 92239540002 Collected: 02/19/15 17:00 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 2400 mg/kg 5.8 2.9 1 03/16/15 12:27 03/17/15 08:36 7429-90-5 Barium 8.1 mg/kg 0.58 0.29 1 03/16/15 12:27 03/17/15 08:36 7440-39-3 Beryllium 0.058J mg/kg 0.058 0.029 1 03/16/15 12:27 03/17/15 08:36 7440-41-7 Boron 4.8 mg/kg 2.9 1.5 1 03/16/15 12:27 03/17/15 08:36 7440-42-8 Calcium 74.8 mg/kg 29.0 14.5 1 03/16/15 12:27 03/17/15 08:36 7440-70-2 Chromium 4.4 mg/kg 0.29 0.15 1 03/16/15 12:27 03/17/15 08:36 7440-47-3 Copper 2.7 mg/kg 0.29 0.15 1 03/16/15 12:27 03/17/15 08:36 7440-50-8 Iron 5850 mg/kg 2.3 1.2 1 03/16/15 12:27 03/17/15 08:36 7439-89-6 Magnesium 55.3 mg/kg 29.0 14.5 1 03/16/15 12:27 03/17/15 08:36 7439-95-4 Manganese 3.0 mg/kg 0.29 0.15 1 03/16/15 12:27 03/17/15 08:36 7439-96-5 Molybdenum ND mg/kg 0.58 0.29 1 03/16/15 12:27 03/17/15 08:36 7439-98-7 Nickel 0.57 mg/kg 0.29 0.15 1 03/16/15 12:27 03/17/15 08:36 7440-02-0 Potassium 44AJ mg/kg 58.1 29.0 1 03/16/15 12:27 03/17/15 08:36 7440-09-7 Sodium ND mg/kg 58.1 29.0 1 03/16/15 12:27 03/17/15 08:36 7440-23-5 Strontium 0.69 mg/kg 0.58 0.29 1 03/16/15 12:27 03/17/15 08:36 7440-24-6 Zinc 4.8 mg/kg 1.2 0.58 1 03/16/15 12:27 03/17/15 08:36 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:12 7440-36-0 D3,M6, N2 Arsenic 4.5 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:12 7440-38-2 D3,M6 Cadmium 0.082J mg/kg 0.14 0.070 20 03/16/15 12:27 03/17/1511:12 7440-43-9 D3 Cobalt 11.3 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:12 7440-48-4 D3,M6 Lead 3.5 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:12 7439-92-1 D3 Selenium 0.96J mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:12 7782-49-2 D3 Thallium 0.73J mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:12 7440-28-0 D3 Vanadium 37.2 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:12 7440-62-2 D4,M6 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0044J mg/kg 0.0088 0.0044 1 03/17/15 06:13 03/17/15 12:59 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.4 % 0.10 0.10 1 03/18/15 14:29 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 0.10 1 03/06/15 15:45 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 3.8 mg/L 2.3 1.2 1 03/19/1519:30 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate 0.33 mg/L 0.23 0.23 1 03/18/15 16:29 B,H1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005890 Lab ID: 92239540002 Collected: 02/19/15 17:00 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Quad Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Mean Total Organic Carbon Surrogates RSD% Date: 04/21 /2015 10:56 AM Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/16/15 14:15 ND mg/L 5.8 2.9 1 03/19/15 20:59 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 289 145 5 03/13/1514:47 16887-00-6 D3 ND mg/kg 289 145 5 03/13/1514:47 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 28.9 14.5 5 03/13/1514:47 14797-55-8 D3,H3 Analytical Method: EPA 9060 1110 mg/kg 694 347 1 03/12/1511:13 7440-44-0 977 mg/kg 692 346 1 03/12/1511:18 7440-44-0 1160 mg/kg 694 347 1 03/12/1511:24 7440-44-0 1120 mg/kg 693 347 1 03/12/1511:29 7440-44-0 1090 mg/kg 693 347 1 03/12/1511:13 7440-44-0 7.5 % 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. isBliplil.'iigRi Page 32 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005891 Lab ID: 92239540003 Collected: 02/19/15 17:20 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 775 mg/kg 5.8 2.9 1 03/16/15 12:27 03/17/15 09:06 7429-90-5 Barium 2.5 mg/kg 0.58 0.29 1 03/16/15 12:27 03/17/15 09:06 7440-39-3 Beryllium 0.11 mg/kg 0.058 0.029 1 03/16/15 12:27 03/17/15 09:06 7440-41-7 Boron 4.5 mg/kg 2.9 1.5 1 03/16/15 12:27 03/17/15 09:06 7440-42-8 Calcium ND mg/kg 29.2 14.6 1 03/16/15 12:27 03/17/15 09:06 7440-70-2 Chromium 18.3 mg/kg 0.29 0.15 1 03/16/15 12:27 03/17/15 09:06 7440-47-3 Copper 7.3 mg/kg 0.29 0.15 1 03/16/15 12:27 03/17/15 09:06 7440-50-8 Iron 5240 mg/kg 2.3 1.2 1 03/16/15 12:27 03/17/15 09:06 7439-89-6 Magnesium ND mg/kg 29.2 14.6 1 03/16/15 12:27 03/17/15 09:06 7439-95-4 Manganese 19.1 mg/kg 0.29 0.15 1 03/16/15 12:27 03/17/15 09:06 7439-96-5 Molybdenum ND mg/kg 0.58 0.29 1 03/16/15 12:27 03/17/15 09:06 7439-98-7 Nickel 7.8 mg/kg 0.29 0.15 1 03/16/15 12:27 03/17/15 09:06 7440-02-0 Potassium 35.3J mg/kg 58.4 29.2 1 03/16/15 12:27 03/17/15 09:06 7440-09-7 Sodium 32.9J mg/kg 58.4 29.2 1 03/16/15 12:27 03/17/15 09:06 7440-23-5 Strontium 0.36J mg/kg 0.58 0.29 1 03/16/15 12:27 03/17/15 09:06 7440-24-6 Zinc 7.2 mg/kg 1.2 0.58 1 03/16/15 12:27 03/17/15 09:06 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:19 7440-36-0 D3,N2 Arsenic 1.5 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:19 7440-38-2 D3 Cadmium ND mg/kg 0.14 0.070 20 03/16/15 12:27 03/17/1511:19 7440-43-9 D3 Cobalt 16.5 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:19 7440-48-4 D3 Lead 6.4 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:19 7439-92-1 D3 Selenium 1.4 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:19 7782-49-2 D3 Thallium 0.62J mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:19 7440-28-0 D3 Vanadium 55.9 mg/kg 1.2 0.58 20 03/16/15 12:27 03/17/1511:19 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0096 0.0048 1 03/17/15 06:13 03/17/15 13:01 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.2 % 0.10 0.10 1 03/18/15 14:29 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.8 Std. Units 0.10 0.10 1 03/06/15 15:45 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Sulfate 2.8 mg/L 2.4 1.2 1 03/19/1519:43 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15 Nitrogen, Nitrate 0.41 mg/L 0.24 0.24 1 03/18/15 16:37 B,H1 4500 Chloride, SPLP Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/16/15 14:15 Chloride ND mg/L 6.0 3.0 1 03/19/15 21:00 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g W4.8Y9,W e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005891 Lab ID: 92239540003 Collected: 02/19/15 17:20 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 297 149 5 03/13/1515:09 16887-00-6 D3 Sulfate ND mg/kg 297 149 5 03/13/1515:09 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.7 14.9 5 03/13/15 15:09 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 720 360 1 03/12/15 11:36 7440-44-0 Total Organic Carbon ND mg/kg 712 356 1 03/12/15 11:41 7440-44-0 Total Organic Carbon ND mg/kg 721 360 1 03/12/15 11:48 7440-44-0 Total Organic Carbon ND mg/kg 713 356 1 03/12/15 11:53 7440-44-0 Mean Total Organic Carbon ND mg/kg 716 358 1 03/12/15 11:36 7440-44-0 Surrogates RSD% 5.7 % 1 03/12/15 11:36 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005892 Lab ID: 92239540004 Collected: 02/23/15 13:29 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 04/21 /2015 10:56 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 9510 mg/kg 6.5 3.3 1 03/16/15 12:27 03/17/15 09:10 7429-90-5 58.3 mg/kg 0.65 0.33 1 03/16/15 12:27 03/17/15 09:10 7440-39-3 0.94 mg/kg 0.33 0.16 5 03/16/15 12:27 03/17/1513:19 7440-41-7 D3 15.5J mg/kg 16.3 8.2 5 03/16/15 12:27 03/17/1513:19 7440-42-8 D3 130 mg/kg 32.6 16.3 1 03/16/15 12:27 03/17/15 09:10 7440-70-2 14.0 mg/kg 1.6 0.82 5 03/16/15 12:27 03/17/1513:19 7440-47-3 D3 13.8 mg/kg 1.6 0.82 5 03/16/15 12:27 03/17/1513:19 7440-50-8 D3 16100 mg/kg 2.6 1.3 1 03/16/15 12:27 03/17/15 09:10 7439-89-6 1830 mg/kg 32.6 16.3 1 03/16/15 12:27 03/17/15 09:10 7439-95-4 377 mg/kg 1.6 0.82 5 03/16/15 12:27 03/17/1513:19 7439-96-5 D3 ND mg/kg 0.65 0.33 1 03/16/15 12:27 03/17/15 09:10 7439-98-7 5.1 mg/kg 0.33 0.16 1 03/16/15 12:27 03/17/15 09:10 7440-02-0 722 mg/kg 65.3 32.6 1 03/16/15 12:27 03/17/15 09:10 7440-09-7 ND mg/kg 65.3 32.6 1 03/16/15 12:27 03/17/15 09:10 7440-23-5 3.3 mg/kg 0.65 0.33 1 03/16/15 12:27 03/17/15 09:10 7440-24-6 27.9 mg/kg 1.3 0.65 1 03/16/15 12:27 03/17/15 09:10 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 1.3 0.65 20 03/16/15 12:27 03/17/1511:21 7440-36-0 D3,N2 1.8 mg/kg 1.3 0.65 20 03/16/15 12:27 03/17/1511:21 7440-38-2 D3 ND mg/kg 0.16 0.078 20 03/16/15 12:27 03/17/1511:21 7440-43-9 D3 17.5 mg/kg 1.3 0.65 20 03/16/15 12:27 03/17/1511:21 7440-48-4 D3 8.0 mg/kg 1.3 0.65 20 03/16/15 12:27 03/17/1511:21 7439-92-1 D3 1.4 mg/kg 1.3 0.65 20 03/16/15 12:27 03/17/1511:21 7782-49-2 D3 0.84J mg/kg 1.3 0.65 20 03/16/15 12:27 03/17/1511:21 7440-28-0 D3 94.8 mg/kg 1.3 0.65 20 03/16/15 12:27 03/17/1511:21 7440-62-2 D4 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.050 mg/kg 0.010 0.0051 1 03/17/15 06:13 03/17/15 13:03 7439-97-6 M1 Analytical Method: ASTM D2974-87 20.0 % 0.10 0.10 1 03/16/1515:18 Analytical Method: EPA 9045 4.5 Std. Units 0.10 0.10 1 04/13/15 14:30 H6 Analytical Method: EPA 9056 ND mg/kg 312 156 5 ND mg/kg 312 156 5 Analytical Method: EPA 9056 ND mg/kg 31.2 15.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 03/13/1515:31 16887-00-6 D3 03/13/1515:31 14808-79-8 D3 03/13/1515:31 14797-55-8 D3,H3 Page 35 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwievgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005893 Lab ID: 92239540005 Collected: 02/23/15 17:09 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 04/21 /2015 10:56 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 4890 mg/kg 6.0 3.0 1 03/16/15 12:27 03/17/15 09:15 7429-90-5 34.9 mg/kg 0.60 0.30 1 03/16/15 12:27 03/17/15 09:15 7440-39-3 0.45 mg/kg 0.060 0.030 1 03/16/15 12:27 03/17/15 09:15 7440-41-7 7.2 mg/kg 3.0 1.5 1 03/16/15 12:27 03/17/15 09:15 7440-42-8 159 mg/kg 30.2 15.1 1 03/16/15 12:27 03/17/15 09:15 7440-70-2 8.3 mg/kg 0.30 0.15 1 03/16/15 12:27 03/17/15 09:15 7440-47-3 5.9 mg/kg 0.30 0.15 1 03/16/15 12:27 03/17/15 09:15 7440-50-8 9530 mg/kg 2.4 1.2 1 03/16/15 12:27 03/17/15 09:15 7439-89-6 1130 mg/kg 30.2 15.1 1 03/16/15 12:27 03/17/15 09:15 7439-95-4 251 mg/kg 0.30 0.15 1 03/16/15 12:27 03/17/15 09:15 7439-96-5 ND mg/kg 0.60 0.30 1 03/16/15 12:27 03/17/15 09:15 7439-98-7 3.0 mg/kg 0.30 0.15 1 03/16/15 12:27 03/17/15 09:15 7440-02-0 280 mg/kg 60.5 30.2 1 03/16/15 12:27 03/17/15 09:15 7440-09-7 ND mg/kg 60.5 30.2 1 03/16/15 12:27 03/17/15 09:15 7440-23-5 4.2 mg/kg 0.60 0.30 1 03/16/15 12:27 03/17/15 09:15 7440-24-6 12.2 mg/kg 1.2 0.60 1 03/16/15 12:27 03/17/15 09:15 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 1.2 0.60 20 03/16/15 12:27 03/17/1511:37 7440-36-0 1.1J mg/kg 1.2 0.60 20 03/16/15 12:27 03/17/1511:37 7440-38-2 ND mg/kg 0.15 0.073 20 03/16/15 12:27 03/17/1511:37 7440-43-9 7.6 mg/kg 1.2 0.60 20 03/16/15 12:27 03/17/1511:37 7440-48-4 6.5 mg/kg 1.2 0.60 20 03/16/15 12:27 03/17/1511:37 7439-92-1 0.901 mg/kg 1.2 0.60 20 03/16/15 12:27 03/17/1511:37 7782-49-2 ND mg/kg 1.2 0.60 20 03/16/15 12:27 03/17/1511:37 7440-28-0 21.7 mg/kg 1.2 0.60 20 03/16/15 12:27 03/17/1511:37 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.010 mg/kg 0.0099 0.0049 1 03/17/15 06:13 03/17/15 13:10 7439-97-6 Analytical Method: ASTM D2974-87 15.8 % 0.10 0.10 1 03/16/1515:19 Analytical Method: EPA 9045 5.3 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 300 150 5 ND mg/kg 300 150 5 Analytical Method: EPA 9056 ND mg/kg 30.0 15.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [�LliKlf6'iClKi�; D3,N2 D3 D3 D3 D3 D3 D3 D3 03/13/1515:53 16887-00-6 D3 03/13/1515:53 14808-79-8 D3 03/13/1515:53 14797-55-8 D3,H3 Page 36 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinygwe. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005894 Lab ID: 92239540006 Collected: 02/23/15 17:00 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 04/21 /2015 10:56 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 542 mg/kg 5.7 2.8 1 03/16/15 12:27 03/17/15 09:19 7429-90-5 6.8 mg/kg 0.57 0.28 1 03/16/15 12:27 03/17/15 09:19 7440-39-3 0.18 mg/kg 0.057 0.028 1 03/16/15 12:27 03/17/15 09:19 7440-41-7 1.8J mg/kg 2.8 1.4 1 03/16/15 12:27 03/17/15 09:19 7440-42-8 61.0 mg/kg 28.3 14.2 1 03/16/15 12:27 03/17/15 09:19 7440-70-2 5.5 mg/kg 0.28 0.14 1 03/16/15 12:27 03/17/15 09:19 7440-47-3 7.1 mg/kg 0.28 0.14 1 03/16/15 12:27 03/17/15 09:19 7440-50-8 2450 mg/kg 2.3 1.1 1 03/16/15 12:27 03/17/15 09:19 7439-89-6 52.0 mg/kg 28.3 14.2 1 03/16/15 12:27 03/17/15 09:19 7439-95-4 14.1 mg/kg 0.28 0.14 1 03/16/15 12:27 03/17/15 09:19 7439-96-5 ND mg/kg 0.57 0.28 1 03/16/15 12:27 03/17/15 09:19 7439-98-7 3.1 mg/kg 0.28 0.14 1 03/16/15 12:27 03/17/15 09:19 7440-02-0 41 AJ mg/kg 56.6 28.3 1 03/16/15 12:27 03/17/15 09:19 7440-09-7 ND mg/kg 56.6 28.3 1 03/16/15 12:27 03/17/15 09:19 7440-23-5 0.73 mg/kg 0.57 0.28 1 03/16/15 12:27 03/17/15 09:19 7440-24-6 9.7 mg/kg 1.1 0.57 1 03/16/15 12:27 03/17/15 09:19 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 1.1 0.57 20 03/16/15 12:27 03/17/1511:40 7440-36-0 ND mg/kg 1.1 0.57 20 03/16/15 12:27 03/17/1511:40 7440-38-2 ND mg/kg 0.14 0.068 20 03/16/15 12:27 03/17/1511:40 7440-43-9 1.8 mg/kg 1.1 0.57 20 03/16/15 12:27 03/17/1511:40 7440-48-4 1.3 mg/kg 1.1 0.57 20 03/16/15 12:27 03/17/1511:40 7439-92-1 ND mg/kg 1.1 0.57 20 03/16/15 12:27 03/17/1511:40 7782-49-2 ND mg/kg 1.1 0.57 20 03/16/15 12:27 03/17/1511:40 7440-28-0 10.3 mg/kg 1.1 0.57 20 03/16/15 12:27 03/17/1511:40 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0087 0.0044 1 03/17/1510:00 03/17/1516:45 7439-97-6 Analytical Method: ASTM D2974-87 7.7 % 0.10 0.10 1 03/16/1515:20 Analytical Method: EPA 9045 5.8 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 269 135 5 ND mg/kg 269 135 5 Analytical Method: EPA 9056 ND mg/kg 26.9 13.5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [�LliKlf6'iClKi�; D3,N2 D3 D3 D3 D3 D3 D3 D3 03/13/1516:16 16887-00-6 D3 03/13/1516:16 14808-79-8 D3 03/13/1516:16 14797-55-8 D3,H3 Page 37 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWievq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005889 SPLP Lab ID: 92239540007 Collected: 02/18/15 14:18 Received: 03/03/15 17:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/21 /2015 10:56 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 6550 ug/L 10.0 3.0 1 04/03/1512:52 04/06/1511:00 7429-90-5 ND ug/L 0.50 0.15 1 04/03/1512:52 04/06/1511:00 7440-36-0 1.1 ug/L 0.50 0.11 1 04/03/1512:52 04/06/1511:00 7440-38-2 22.5 ug/L 0.30 0.081 1 04/03/1512:52 04/06/1511:00 7440-39-3 ND ug/L 0.20 0.067 1 04/03/1512:52 04/06/1511:00 7440-41-7 24.9 ug/L 5.0 1.1 1 04/03/1512:52 04/06/1511:00 7440-42-8 0.28 ug/L 0.080 0.024 1 04/03/1512:52 04/06/1511:00 7440-43-9 808 ug/L 40.0 16.0 1 04/03/1512:52 04/06/1511:00 7440-70-2 7.7 ug/L 0.50 0.17 1 04/03/1512:52 04/06/1511:00 7440-47-3 0.77 ug/L 0.50 0.13 1 04/03/1512:52 04/06/1511:00 7440-48-4 3.1 ug/L 1.0 0.21 1 04/03/1512:52 04/06/1511:00 7440-50-8 4030 ug/L 50.0 13.7 1 04/03/1512:52 04/06/1511:00 7439-89-6 4.8 ug/L 0.10 0.046 1 04/03/1512:52 04/06/1511:00 7439-92-1 486 ug/L 10.0 3.2 1 04/03/1512:52 04/06/1511:00 7439-95-4 11.5 ug/L 0.50 0.24 1 04/03/1512:52 04/06/1511:00 7439-96-5 ND ug/L 0.50 0.094 1 04/03/1512:52 04/06/1511:00 7439-98-7 6.4 ug/L 0.50 0.16 1 04/03/1512:52 04/06/1511:00 7440-02-0 617 ug/L 50.0 11.7 1 04/03/1512:52 04/06/1511:00 7440-09-7 ND ug/L 0.50 0.20 1 04/03/1512:52 04/06/1511:00 7782-49-2 620 ug/L 50.0 16.3 1 04/03/1512:52 04/06/1511:00 7440-23-5 2.9 ug/L 0.50 0.13 1 04/03/1512:52 04/06/1511:00 7440-24-6 ND ug/L 0.10 0.015 1 04/03/1512:52 04/06/1511:00 7440-28-0 13.2 ug/L 1.0 0.28 1 04/03/1512:52 04/06/1511:00 7440-62-2 72.2 ug/L 5.0 2.4 1 04/03/1512:52 04/06/1511:00 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.60 0.065 1 04/04/1517:20 04/06/1518:33 7439-97-6 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinyq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005890 SPLP Lab ID: 92239540008 Collected: 02/19/15 17:00 Received: 03/03/15 17:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/21 /2015 10:56 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 404 ug/L 10.0 3.0 1 04/03/1512:52 04/06/1511:05 7429-90-5 ND ug/L 0.50 0.15 1 04/03/1512:52 04/06/1511:05 7440-36-0 ND ug/L 0.50 0.11 1 04/03/1512:52 04/06/1511:05 7440-38-2 13.6 ug/L 0.30 0.081 1 04/03/1512:52 04/06/1511:05 7440-39-3 ND ug/L 0.20 0.067 1 04/03/1512:52 04/06/1511:05 7440-41-7 18.0 ug/L 5.0 1.1 1 04/03/1512:52 04/06/1511:05 7440-42-8 ND ug/L 0.080 0.024 1 04/03/1512:52 04/06/1511:05 7440-43-9 824 ug/L 40.0 16.0 1 04/03/1512:52 04/06/1511:05 7440-70-2 1.1 ug/L 0.50 0.17 1 04/03/1512:52 04/06/1511:05 7440-47-3 ND ug/L 0.50 0.13 1 04/03/1512:52 04/06/1511:05 7440-48-4 ND ug/L 1.0 0.21 1 04/03/1512:52 04/06/1511:05 7440-50-8 295 ug/L 50.0 13.7 1 04/03/1512:52 04/06/1511:05 7439-89-6 0.28 ug/L 0.10 0.046 1 04/03/1512:52 04/06/1511:05 7439-92-1 266 ug/L 10.0 3.2 1 04/03/1512:52 04/06/1511:05 7439-95-4 11.9 ug/L 0.50 0.24 1 04/03/1512:52 04/06/1511:05 7439-96-5 ND ug/L 0.50 0.094 1 04/03/1512:52 04/06/1511:05 7439-98-7 1.1 ug/L 0.50 0.16 1 04/03/1512:52 04/06/1511:05 7440-02-0 398 ug/L 50.0 11.7 1 04/03/1512:52 04/06/1511:05 7440-09-7 ND ug/L 0.50 0.20 1 04/03/1512:52 04/06/1511:05 7782-49-2 558 ug/L 50.0 16.3 1 04/03/1512:52 04/06/1511:05 7440-23-5 4.2 ug/L 0.50 0.13 1 04/03/1512:52 04/06/1511:05 7440-24-6 ND ug/L 0.10 0.015 1 04/03/1512:52 04/06/1511:05 7440-28-0 1.3 ug/L 1.0 0.28 1 04/03/1512:52 04/06/1511:05 7440-62-2 12.4 ug/L 5.0 2.4 1 04/03/1512:52 04/06/1511:05 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1518:40 7439-97-6 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005891 SPLP Lab ID: 92239540009 Collected: 02/19/15 17:20 Received: 03/03/15 17:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/21 /2015 10:56 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 14.9 ug/L 10.0 3.0 1 04/03/1512:52 04/06/1510:16 7429-90-5 ND ug/L 0.50 0.15 1 04/03/1512:52 04/06/1510:16 7440-36-0 ND ug/L 0.50 0.11 1 04/03/1512:52 04/06/1510:16 7440-38-2 0.66 ug/L 0.30 0.081 1 04/03/1512:52 04/06/1510:16 7440-39-3 ND ug/L 0.20 0.067 1 04/03/1512:52 04/06/1510:16 7440-41-7 60.5 ug/L 5.0 1.1 1 04/03/1512:52 04/06/1510:16 7440-42-8 ND ug/L 0.080 0.024 1 04/03/1512:52 04/06/1510:16 7440-43-9 118 ug/L 40.0 16.0 1 04/03/1512:52 04/06/1510:16 7440-70-2 0.63 ug/L 0.50 0.17 1 04/03/1512:52 04/06/1510:16 7440-47-3 ND ug/L 0.50 0.13 1 04/03/1512:52 04/06/1510:16 7440-48-4 ND ug/L 1.0 0.21 1 04/03/1512:52 04/06/1510:16 7440-50-8 67.6 ug/L 50.0 13.7 1 04/03/1512:52 04/06/1510:16 7439-89-6 ND ug/L 0.10 0.046 1 04/03/1512:52 04/06/1510:16 7439-92-1 64.4 ug/L 10.0 3.2 1 04/03/1512:52 04/06/1510:16 7439-95-4 8.5 ug/L 0.50 0.24 1 04/03/1512:52 04/06/1510:16 7439-96-5 ND ug/L 0.50 0.094 1 04/03/1512:52 04/06/1510:16 7439-98-7 0.51 ug/L 0.50 0.16 1 04/03/1512:52 04/06/1510:16 7440-02-0 752 ug/L 50.0 11.7 1 04/03/1512:52 04/06/1510:16 7440-09-7 ND ug/L 0.50 0.20 1 04/03/1512:52 04/06/1510:16 7782-49-2 2720 ug/L 50.0 16.3 1 04/03/1512:52 04/06/1510:16 7440-23-5 0.50 ug/L 0.50 0.13 1 04/03/1512:52 04/06/1510:16 7440-24-6 ND ug/L 0.10 0.015 1 04/03/1512:52 04/06/1510:16 7440-28-0 ND ug/L 1.0 0.28 1 04/03/1512:52 04/06/1510:16 7440-62-2 5.2 ug/L 5.0 2.4 1 04/03/1512:52 04/06/1510:16 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1518:42 7439-97-6 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 40 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g invq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239540 Sample: 2015005901 Lab ID: 92239540010 Collected: 02/23/15 10:52 Received: 03/03/15 17:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/21 /2015 10:56 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 44.7 ug/L 10.0 1.2 1 03/12/1510:12 03/12/1515:38 7429-90-5 M1 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:38 7440-36-0 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:38 7440-38-2 3.8 ug/L 0.30 0.14 1 03/12/1510:12 03/12/1515:38 7440-39-3 ND ug/L 0.20 0.066 1 03/12/1510:12 03/12/1515:38 7440-41-7 ND ug/L 5.0 1.0 1 03/12/1510:12 03/12/1515:38 7440-42-8 ND ug/L 0.080 0.033 1 03/12/1510:12 03/12/1515:38 7440-43-9 3900 ug/L 40.0 8.4 1 03/12/1510:12 03/12/1515:38 7440-70-2 4.2 ug/L 0.50 0.22 1 03/12/1510:12 03/12/1515:38 7440-47-3 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:38 7440-48-4 2.0 ug/L 1.0 0.22 1 03/12/1510:12 03/12/1515:38 7440-50-8 404 ug/L 50.0 8.0 1 03/12/1510:12 03/12/1515:38 7439-89-6 0.47 ug/L 0.10 0.046 1 03/12/1510:12 03/12/1515:38 7439-92-1 229 ug/L 10.0 2.8 1 03/12/1510:12 03/12/1515:38 7439-95-4 8.0 ug/L 0.50 0.14 1 03/12/1510:12 03/12/1515:38 7439-96-5 1.5 ug/L 0.50 0.24 1 03/12/1510:12 03/12/1515:38 7439-98-7 ND ug/L 0.50 0.23 1 03/12/1510:12 03/12/1515:38 7440-02-0 1290 ug/L 50.0 8.3 1 03/12/1510:12 03/12/1515:38 7440-09-7 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:38 7782-49-2 3180 ug/L 50.0 18.2 1 03/12/1510:12 03/12/1515:38 7440-23-5 21.4 ug/L 0.50 0.057 1 03/12/1510:12 03/12/1515:38 7440-24-6 ND ug/L 0.10 0.025 1 03/12/1510:12 03/12/1515:38 7440-28-0 1.8 ug/L 1.0 0.21 1 03/12/1510:12 03/12/1515:38 7440-62-2 5.1 ug/L 5.0 2.5 1 03/12/1510:12 03/12/1515:38 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.026 1 03/12/1511:18 03/12/1514:57 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g iQvgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: MERP/12953 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92239540010 METHOD BLANK: 1916588 Matrix: Water Associated Lab Samples: 92239540010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/12/1514:47 LABORATORY CONTROL SAMPLE: 1916589 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1916590 1916591 MS MSD 92239540010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 4.8 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g iSvgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: MERP/13139 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92239540007, 92239540008, 92239540009 METHOD BLANK: 1932636 Matrix: Water Associated Lab Samples: 92239540007, 92239540008, 92239540009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/06/1518:28 LABORATORY CONTROL SAMPLE: 1932637 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.8 116 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1932638 1932639 MS MSD 92239540007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 15 15 16.1 16.0 107 106 75-125 1 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g 4-8yqwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: MERP/5474 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92239540001, 92239540002, 92239540003, 92239540004, 92239540005 METHOD BLANK: 1157677 Matrix: Solid Associated Lab Samples: 92239540001, 92239540002, 92239540003, 92239540004, 92239540005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0084 03/17/1512:46 LABORATORY CONTROL SAMPLE: 1157678 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .079 0.081 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1157679 1157680 MS MSD 92239540004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.050 .0988 .0963 0.13 0.12 77 74 80-120 4 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: MERP/5478 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92239540006 METHOD BLANK: 1158296 Matrix: Solid Associated Lab Samples: 92239540006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 03/17/1516:40 LABORATORY CONTROL SAMPLE: 1158297 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.079 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1158298 1158299 MS MSD 92239540006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .0888 .0877 0.087 0.089 99 102 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: MPRP/23094 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92239540001, 92239540002, 92239540003, 92239540004, 92239540005, 92239540006 METHOD BLANK: 1157065 Matrix: Solid Associated Lab Samples: 92239540001, 92239540002, 92239540003, 92239540004, 92239540005, 92239540006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg ND 5.0 03/17/15 08:02 Barium mg/kg ND 0.50 03/17/15 08:02 Beryllium mg/kg ND 0.050 03/17/15 08:02 Boron mg/kg ND 2.5 03/17/15 08:02 Calcium mg/kg ND 25.1 03/17/15 08:02 Chromium mg/kg ND 0.25 03/17/15 08:02 Copper mg/kg ND 0.25 03/17/15 08:02 Iron mg/kg ND 2.0 03/17/15 08:02 Magnesium mg/kg ND 25.1 03/17/15 08:02 Manganese mg/kg ND 0.25 03/17/15 08:02 Molybdenum mg/kg ND 0.50 03/17/15 08:02 Nickel mg/kg ND 0.25 03/17/15 08:02 Potassium mg/kg ND 50.1 03/17/15 08:02 Sodium mg/kg ND 50.1 03/17/15 08:02 Strontium mg/kg ND 0.50 03/17/15 08:02 Zinc mg/kg ND 1.0 03/17/15 08:02 LABORATORY CONTROL SAMPLE: Parameter 1157066 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 127 132 103 80-120 Barium mg/kg 12.7 13.1 103 80-120 Beryllium mg/kg 1.3 1.2 98 80-120 Boron mg/kg 127 123 97 80-120 Calcium mg/kg 637 646 101 80-120 Chromium mg/kg 12.7 12.8 101 80-120 Copper mg/kg 12.7 12.6 99 80-120 Iron mg/kg 127 124 98 80-120 Magnesium mg/kg 637 648 102 80-120 Manganese mg/kg 12.7 12.4 97 80-120 Molybdenum mg/kg 12.7 12.3 96 80-120 Nickel mg/kg 12.7 12.7 99 80-120 Potassium mg/kg 637 614 96 80-120 Sodium mg/kg 637 651 102 80-120 Strontium mg/kg 12.7 12.4 98 80-120 Zinc mg/kg 63.7 63.3 99 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1157067 1157068 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 1720 157 149 3580 2850 1180 756 75-125 23 20 M1,R1 Barium mg/kg 6.1 15.7 14.9 24.6 22.2 117 108 75-125 10 20 Beryllium mg/kg 0.039J 1.56 1.44 1.5 1.5 93 96 75-125 2 20 Boron mg/kg 1.8J 157 149 142 140 89 93 75-125 1 20 Calcium mg/kg 42.4 789 747 827 802 100 102 75-125 3 20 Chromium mg/kg 2.4 15.7 14.9 18.2 17.4 101 101 75-125 5 20 Copper mg/kg 1.2 15.7 14.9 16.5 15.9 98 99 75-125 4 20 Iron mg/kg 2350 157 149 2790 2350 278 -2 75-125 17 20 M1 Magnesium mg/kg 52.0 789 747 892 853 107 107 75-125 5 20 Manganese mg/kg 2.7 15.7 14.9 18.5 17.1 101 97 75-125 8 20 Molybdenum mg/kg ND 15.7 14.9 13.4 13.1 85 88 75-125 2 20 Nickel mg/kg 0.84 15.7 14.9 17.1 15.7 103 100 75-125 8 20 Potassium mg/kg 40AJ 789 747 803 774 97 98 75-125 4 20 Sodium mg/kg ND 789 747 790 763 99 101 75-125 3 20 Strontium mg/kg 0.35J 15.7 14.9 15.7 15.1 97 99 75-125 4 20 Zinc mg/kg 4.3 78.9 74.7 81.5 77.0 98 97 75-125 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g igcw'We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: MPRP/23095 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92239540001, 92239540002, 92239540003, 92239540004, 92239540005, 92239540006 METHOD BLANK: 1157069 Matrix: Solid Associated Lab Samples: 92239540001, 92239540002, 92239540003, 92239540004, 92239540005, 92239540006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.050 03/17/1511:05 N2 Arsenic mg/kg ND 0.050 03/17/1511:05 Cadmium mg/kg ND 0.0060 03/17/1511:05 Cobalt mg/kg ND 0.050 03/17/1511:05 Lead mg/kg ND 0.050 03/17/1511:05 Selenium mg/kg ND 0.050 03/17/1511:05 Thallium mg/kg ND 0.050 03/17/1511:05 Vanadium mg/kg ND 0.050 03/17/1511:05 LABORATORY CONTROL SAMPLE: Parameter 1157070 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.5 99 80-120 N2 Arsenic mg/kg 2.5 2.7 106 80-120 Cadmium mg/kg .25 0.25 99 80-120 Cobalt mg/kg 2.5 2.7 106 80-120 Lead mg/kg 2.5 2.5 101 80-120 Selenium mg/kg 2.5 2.7 108 80-120 Thallium mg/kg 2.5 2.5 99 80-120 Vanadium mg/kg 2.5 2.6 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1157071 92239540002 Parameter Units Result MS Spike Conc. MSD Spike Conc. 1157072 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 2.89 2.89 1.1 1.01 38 34 75-125 20 D3,M6, N2 Arsenic mg/kg 4.5 2.89 2.89 6.4 6.6 67 73 75-125 3 20 D3,M6 Cadmium mg/kg 0.082J .289 .289 0.38 0.38 103 102 75-125 0 20 D3 Cobalt mg/kg 11.3 2.89 2.89 12.9 14.8 57 123 75-125 14 20 D3,M6 Lead mg/kg 3.5 2.89 2.89 5.9 6.5 85 105 75-125 10 20 D3 Selenium mg/kg 0.96J 2.89 2.89 3.8 3.8 98 100 75-125 2 20 D3 Thallium mg/kg 0.73J 2.89 2.89 3.4 3.5 94 96 75-125 3 20 D3 Vanadium mg/kg 37.2 2.89 2.89 34.8 42.3 -84 177 75-125 19 20 D4,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: MPRP/52897 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92239540010 METHOD BLANK: 1916229 Associated Lab Samples: 92239540010 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.30 03/12/1515:35 ND 0.20 03/12/1515:35 ND 5.0 03/12/1515:35 ND 0.080 03/12/1515:35 ND 40.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 1.0 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.10 03/12/1515:35 ND 10.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.10 03/12/1515:35 ND 1.0 03/12/1515:35 ND 5.0 03/12/1515:35 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1916230 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 79.2 99 80-120 Antimony ug/L 80 82.0 103 80-120 Arsenic ug/L 80 82.2 103 80-120 Barium ug/L 80 83.3 104 80-120 Beryllium ug/L 80 79.7 100 80-120 Boron ug/L 80 82.0 102 80-120 Cadmium ug/L 80 84.3 105 80-120 Calcium ug/L 1000 1070 107 80-120 Chromium ug/L 80 84.2 105 80-120 Cobalt ug/L 80 87.8 110 80-120 Copper ug/L 80 84.1 105 80-120 Iron ug/L 1000 1060 106 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 LABORATORY CONTROL SAMPLE: 1916230 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 85.1 106 80-120 Magnesium ug/L 1000 1020 102 80-120 Manganese ug/L 80 88.5 111 80-120 Molybdenum ug/L 80 88.3 110 80-120 Nickel ug/L 80 88.3 110 80-120 Potassium ug/L 1000 1040 104 80-120 Selenium ug/L 80 84.6 106 80-120 Sodium ug/L 1000 1040 104 80-120 Strontium ug/L 80 82.6 103 80-120 Thallium ug/L 80 91.4 114 80-120 Vanadium ug/L 80 87.4 109 80-120 Zinc ug/L 80 80.3 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1916665 1916666 MS MSD 92239540010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 44.7 80 80 142 147 121 128 75-125 4 20 M1 Antimony ug/L ND 80 80 83.1 82.4 104 103 75-125 1 20 Arsenic ug/L ND 80 80 81.0 81.8 101 102 75-125 1 20 Barium ug/L 3.8 80 80 84.2 85.7 100 102 75-125 2 20 Beryllium ug/L ND 80 80 81.0 78.8 101 98 75-125 3 20 Boron ug/L ND 80 80 93.8 87.2 112 103 75-125 7 20 Cadmium ug/L ND 80 80 84.8 85.2 106 107 75-125 0 20 Calcium ug/L 3900 1000 1000 5040 5150 114 125 75-125 2 20 Chromium ug/L 4.2 80 80 87.0 87.7 103 104 75-125 1 20 Cobalt ug/L ND 80 80 84.3 85.0 105 106 75-125 1 20 Copper ug/L 2.0 80 80 84.9 86.0 104 105 75-125 1 20 Iron ug/L 404 1000 1000 1470 1500 107 110 75-125 2 20 Lead ug/L 0.47 80 80 85.4 85.8 106 107 75-125 1 20 Magnesium ug/L 229 1000 1000 1240 1280 101 105 75-125 3 20 Manganese ug/L 8.0 80 80 96.7 98.5 111 113 75-125 2 20 Molybdenum ug/L 1.5 80 80 87.8 88.9 108 109 75-125 1 20 Nickel ug/L ND 80 80 88.0 89.1 109 111 75-125 1 20 Potassium ug/L 1290 1000 1000 2370 2400 108 111 75-125 1 20 Selenium ug/L ND 80 80 85.3 83.7 106 104 75-125 2 20 Sodium ug/L 3180 1000 1000 4250 4390 108 121 75-125 3 20 Strontium ug/L 21.4 80 80 103 104 102 104 75-125 2 20 Thallium ug/L ND 80 80 87.8 87.5 110 109 75-125 0 20 Vanadium ug/L 1.8 80 80 88.9 90.1 109 110 75-125 1 20 Zinc ug/L 5.1 80 80 84.9 85.8 100 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gI invgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: MPRP/53349 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92239540007, 92239540008, 92239540009 METHOD BLANK: 1931408 Matrix: Associated Lab Samples: 92239540007, 92239540008, 92239540009 Blank Parameter Units Result Water Reporting Limit Analyzed Aluminum ug/L ND 10.0 04/06/15 07:50 Antimony ug/L ND 0.50 04/06/15 07:50 Arsenic ug/L ND 0.50 04/06/15 07:50 Barium ug/L ND 0.30 04/06/15 07:50 Beryllium ug/L ND 0.20 04/06/15 07:50 Boron ug/L ND 5.0 04/06/15 07:50 Cadmium ug/L ND 0.080 04/06/15 07:50 Calcium ug/L ND 40.0 04/06/15 07:50 Chromium ug/L ND 0.50 04/06/15 07:50 Cobalt ug/L ND 0.50 04/06/15 07:50 Copper ug/L ND 1.0 04/06/15 07:50 Iron ug/L ND 50.0 04/06/15 07:50 Lead ug/L ND 0.10 04/06/15 07:50 Magnesium ug/L ND 10.0 04/06/15 07:50 Manganese ug/L ND 0.50 04/06/15 07:50 Molybdenum ug/L ND 0.50 04/06/15 07:50 Nickel ug/L ND 0.50 04/06/15 07:50 Potassium ug/L ND 50.0 04/06/15 07:50 Selenium ug/L ND 0.50 04/06/15 07:50 Sodium ug/L ND 50.0 04/06/15 07:50 Strontium ug/L ND 0.50 04/06/15 07:50 Thallium ug/L ND 0.10 04/06/15 07:50 Vanadium ug/L ND 1.0 04/06/15 07:50 Zinc ug/L ND 5.0 04/06/15 07:50 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1931409 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 85.5 107 80-120 Antimony ug/L 80 80.1 100 80-120 Arsenic ug/L 80 80.5 101 80-120 Barium ug/L 80 80.4 101 80-120 Beryllium ug/L 80 80.5 101 80-120 Boron ug/L 80 82.6 103 80-120 Cadmium ug/L 80 81.6 102 80-120 Calcium ug/L 1000 955 96 80-120 Chromium ug/L 80 82.7 103 80-120 Cobalt ug/L 80 79.7 100 80-120 Copper ug/L 80 78.7 98 80-120 Iron ug/L 1000 1040 104 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gI iQvgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 LABORATORY CONTROL SAMPLE: 1931409 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 82.2 103 80-120 Magnesium ug/L 1000 978 98 80-120 Manganese ug/L 80 81.3 102 80-120 Molybdenum ug/L 80 79.2 99 80-120 Nickel ug/L 80 80.2 100 80-120 Potassium ug/L 1000 1020 102 80-120 Selenium ug/L 80 80.1 100 80-120 Sodium ug/L 1000 1000 100 80-120 Strontium ug/L 80 79.9 100 80-120 Thallium ug/L 80 80.4 101 80-120 Vanadium ug/L 80 80.0 100 80-120 Zinc ug/L 80 84.4 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1931410 1931411 MS MSD 92243088001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 80 80 94.2 90.2 113 108 75-125 4 20 Antimony ug/L ND 80 80 78.6 81.2 98 101 75-125 3 20 Arsenic ug/L ND 80 80 80.0 82.5 100 103 75-125 3 20 Barium ug/L ND 80 80 79.8 80.3 100 100 75-125 1 20 Beryllium ug/L ND 80 80 82.4 80.6 103 101 75-125 2 20 Boron ug/L ND 80 80 83.9 81.0 104 100 75-125 4 20 Cadmium ug/L ND 80 80 81.0 81.3 101 102 75-125 0 20 Calcium ug/L ND 1000 1000 882 953 88 95 75-125 8 20 Chromium ug/L ND 80 80 81.8 82.8 102 104 75-125 1 20 Cobalt ug/L ND 80 80 79.9 79.6 100 99 75-125 0 20 Copper ug/L ND 80 80 79.3 79.0 99 99 75-125 0 20 Iron ug/L ND 1000 1000 1030 1040 103 104 75-125 1 20 Lead ug/L ND 80 80 81.4 82.8 102 103 75-125 2 20 Magnesium ug/L ND 1000 1000 959 978 96 98 75-125 2 20 Manganese ug/L ND 80 80 81.1 82.1 101 103 75-125 1 20 Molybdenum ug/L ND 80 80 79.0 78.9 99 99 75-125 0 20 Nickel ug/L ND 80 80 80.5 79.6 101 100 75-125 1 20 Potassium ug/L ND 1000 1000 1030 1030 103 103 75-125 0 20 Selenium ug/L ND 80 80 81.5 80.8 102 101 75-125 1 20 Sodium ug/L ND 1000 1000 1010 1000 101 100 75-125 1 20 Strontium ug/L ND 80 80 79.9 79.8 100 100 75-125 0 20 Thallium ug/L ND 80 80 82.6 83.8 103 105 75-125 2 20 Vanadium ug/L ND 80 80 79.7 80.0 100 100 75-125 0 20 Zinc ug/L ND 80 80 85.3 84.7 105 104 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gI iSvgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: PMST/3347 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92239540004, 92239540005, 92239540006 SAMPLE DUPLICATE: 1157598 35178663001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.9 23.3 2 10 SAMPLE DUPLICATE: 1157600 92240158001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 35.5 35.2 1 10 SAMPLE DUPLICATE: 1157619 92239540004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 20.0 19.1 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 53 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gI 4-8yqwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: PMST/10975 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92239540001, 92239540002, 92239540003 SAMPLE DUPLICATE: 1129216 40111815001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 8.0 7.7 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 54 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: WET/30215 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92239540004, 92239540005, 92239540006 SAMPLE DUPLICATE: 1181977 92239540004 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.5 4.5 0 20 H6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 55 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i - We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: WET/36041 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92239540001, 92239540002, 92239540003 SAMPLE DUPLICATE: 1403559 92239540001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.1 5.1 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 56 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: WETA/22270 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92239540001, 92239540002, 92239540003 METHOD BLANK: 1415171 Matrix: Water Associated Lab Samples: 92239540001, 92239540002, 92239540003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 2.0 03/19/1518:22 LABORATORY CONTROL SAMPLE: 1415172 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 18.7 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415173 1415174 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.5 24 24 25.8 25.8 93 93 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415175 1415176 MS MSD 92240158010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.0 25.5 25.5 26.8 26.8 93 93 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 57 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g igcw'We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: WETA/22256 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92239540001, 92239540002, 92239540003 METHOD BLANK: 1413768 Matrix: Water Associated Lab Samples: 92239540001, 92239540002, 92239540003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.22 0.020 03/18/15 16:20 B LABORATORY CONTROL SAMPLE: 1413769 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1413770 1413771 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.41 3 3 3.3 3.3 95 95 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1413772 1413773 MS MSD 92239540002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.33 2.9 2.9 3.2 3.2 98 98 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 58 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: WETA/22273 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92239540001, 92239540002, 92239540003 METHOD BLANK: 1415463 Matrix: Water Associated Lab Samples: 92239540001, 92239540002, 92239540003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/19/15 20:57 LABORATORY CONTROL SAMPLE: 1415464 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.4 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415465 1415466 MS MSD 92239540003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.7 24.6 101 101 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1415467 1415468 MS MSD 92239543006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 5.7J 24.7 24.7 31.0 30.7 102 101 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 59 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g 6-8yqwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: WETA/44508 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92239540001, 92239540002, 92239540003, 92239540004, 92239540005, 92239540006 METHOD BLANK: 1155640 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.6 03/13/1512:56 Sulfate mg/kg ND 50.6 03/13/1512:56 LABORATORY CONTROL SAMPLE: 1155641 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1155643 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1155642 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 504 471 94 80-120 504 466 92 80-120 92239540001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 600 507 69 80-120 M 1 ND 600 550 78 80-120 M 1 92239540001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 60 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g invgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: WETA/44509 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92239540001, 92239540002, 92239540003, 92239540004, 92239540005, 92239540006 METHOD BLANK: 1155644 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.1 03/13/15 12:56 LABORATORY CONTROL SAMPLE: 1155645 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.4 47.9 95 80-120 MATRIX SPIKE SAMPLE: 1155647 92239540001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 60 52.6 85 80-120 H3 SAMPLE DUPLICATE: 1155646 92239540001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 61 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g iQvgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239540 QC Batch: WETA/27532 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92239540001, 92239540002, 92239540003 METHOD BLANK: 1125810 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/12/15 07:13 LABORATORY CONTROL SAMPLE: 1125811 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 121000 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1125812 1125813 MS MSD 92239539001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 4370 7510 7510 10200 9980 77 75 50-150 2 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1125814 1125815 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 2400 7210 7210 8470 8760 84 88 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 62 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i vq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15030051 Pace Project No.: 92239540 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 63 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030051 Pace Project No.: 92239540 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92239540001 2015005889 EPA 3050 MPRP/23094 EPA 6010 ICP/14133 92239540002 2015005890 EPA 3050 MPRP/23094 EPA 6010 ICP/14133 92239540003 2015005891 EPA 3050 MPRP/23094 EPA 6010 ICP/14133 92239540004 2015005892 EPA 3050 MPRP/23094 EPA 6010 ICP/14133 92239540005 2015005893 EPA 3050 MPRP/23094 EPA 6010 ICP/14133 92239540006 2015005894 EPA 3050 MPRP/23094 EPA6010 ICP/14133 92239540001 2015005889 EPA 3050 MPRP/23095 EPA 6020 ICPM/9420 92239540002 2015005890 EPA 3050 MPRP/23095 EPA 6020 ICPM/9420 92239540003 2015005891 EPA 3050 MPRP/23095 EPA 6020 ICPM/9420 92239540004 2015005892 EPA 3050 MPRP/23095 EPA 6020 ICPM/9420 92239540005 2015005893 EPA 3050 MPRP/23095 EPA 6020 ICPM/9420 92239540006 2015005894 EPA 3050 MPRP/23095 EPA 6020 ICPM/9420 92239540007 2015005889 SPLP EPA 3020 MPRP/53349 EPA 6020A ICPM/23672 92239540008 2015005890 SPLP EPA 3020 MPRP/53349 EPA 6020A ICPM/23672 92239540009 2015005891 SPLP EPA 3020 MPRP/53349 EPA 6020A ICPM/23672 92239540010 2015005901 EPA 3020 MPRP/52897 EPA 6020A ICPM/23451 92239540007 2015005889 SPLP EPA 7470 MERP/13139 EPA 7470 MERC/15254 92239540008 2015005890 SPLP EPA 7470 MERP/13139 EPA 7470 MERC/15254 92239540009 2015005891 SPLP EPA 7470 MERP/13139 EPA 7470 MERC/15254 92239540010 2015005901 EPA 7470 MERP/12953 EPA 7470 MERC/15027 92239540001 2015005889 EPA 7471 MERP/5474 EPA 7471 MERC/5464 92239540002 2015005890 EPA 7471 MERP/5474 EPA 7471 MERC/5464 92239540003 2015005891 EPA 7471 MERP/5474 EPA 7471 MERC/5464 92239540004 2015005892 EPA 7471 MERP/5474 EPA 7471 MERC/5464 92239540005 2015005893 EPA 7471 MERP/5474 EPA 7471 MERC/5464 92239540006 2015005894 EPA 7471 MERP/5478 EPA 7471 MERC/5467 92239540001 2015005889 ASTM D2974-87 PMST/10975 92239540002 2015005890 ASTM D2974-87 PMST/10975 92239540003 2015005891 ASTM D2974-87 PMST/10975 92239540004 2015005892 ASTM D2974-87 PMST/3347 92239540005 2015005893 ASTM D2974-87 PMST/3347 92239540006 2015005894 ASTM D2974-87 PMST/3347 92239540001 2015005889 EPA 9045 WET/36041 92239540002 2015005890 EPA 9045 WET/36041 92239540003 2015005891 EPA 9045 WET/36041 92239540004 2015005892 EPA 9045 WET/30215 92239540005 2015005893 EPA 9045 WET/30215 92239540006 2015005894 EPA 9045 WET/30215 92239540001 2015005889 EPA 300.0 WETA/22270 92239540002 2015005890 EPA 300.0 WETA/22270 92239540003 2015005891 EPA 300.0 WETA/22270 92239540001 2015005889 EPA 353.2 WETA/22256 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/21 /2015 10:56 AM without the written consent of Pace Analytical Services, Inc.. Page 64 of 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g inyq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030051 Pace Project No.: 92239540 Lab ID Sample ID QC Batch Method QC Batch 92239540002 2015005890 EPA 353.2 WETA/22256 92239540003 2015005891 EPA 353.2 WETA/22256 92239540001 2015005889 SM 4500-CI-E WETA/22273 92239540002 2015005890 SM 4500-CI-E WETA/22273 92239540003 2015005891 SM 4500-CI-E WETA/22273 92239540001 2015005889 EPA 9056 WETA/44508 92239540002 2015005890 EPA 9056 WETA/44508 92239540003 2015005891 EPA 9056 WETA/44508 92239540004 2015005892 EPA 9056 WETA/44508 92239540005 2015005893 EPA 9056 WETA/44508 92239540006 2015005894 EPA 9056 WETA/44508 92239540001 2015005889 EPA 9056 WETA/44509 92239540002 2015005890 EPA 9056 WETA/44509 92239540003 2015005891 EPA 9056 WETA/44509 92239540004 2015005892 EPA 9056 WETA/44509 92239540005 2015005893 EPA 9056 WETA/44509 92239540006 2015005894 EPA 9056 WETA/44509 92239540001 2015005889 EPA 9060 WETA/27532 92239540001 2015005889 EPA 9060 WETA/27533 92239540002 2015005890 EPA 9060 WETA/27532 92239540002 2015005890 EPA 9060 WETA/27533 92239540003 2015005891 EPA 9060 WETA/27532 92239540003 2015005891 EPA 9060 WETA/27533 Date: 04/21 /2015 10:56 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 65 of 67 Page 76 of 94 ObSB£ZZ6 (sJauleluoo laaJJooul dwal;o lno 'anlleAJasaJd loamoul 'ploy;o lno a•l ) aolJJo uolleollllJao 4I II Il i �NHga eullae0 WON ayl 01 lugs aq IIIM wJo; siyl;o r(doo a '991dwes �M*� aouelldwoo eulloJea WON bulloa�e RouedaJoslp a sl aJayl JBAGU94M :aloN OtF96EZZVy/�+ ' O1 f 7 :a;ell 7`Y1 :MGIAaM JZiS aaa4 lagel aaeld C 1 c? :a;ea !:IV►alAaU ddfo5 :uopnlosad /sluawwoo :awlllalep :pal0e1u00 uosJad N / A Lpambad elea plaid wognloseN /uolleO MON 1u0113 '96 2�4 ONE]saA❑ oN❑ saAQ pasepind #1} #;off pelg dul aoed luasaJd sleaS ApolsnC) xuelg dlJl :luasaJd Nuelg dlJl '94 tN ON El saAE) :(ww9<) WMA VOA ul aaedspeOH 171 /fn ON[] saAE] :uolleupolpap Jo} pa�np saldweS Tl VIN❑ V//N /— 01�17 saAE) iJ ON[] s0,k0 ONE]❑ SOA (J91eM)O'dG-IM'E)VO'001'WJOJI.IOD VOA mondeoxe -uollepuauJUJooaJ Vd9 yIIM aouelldwoo ul aq of puno) eiv uopmasaJd 6ulpaau sieuleluoo litf •parloayo uaaq aney uollenJasaJd 6ulpaau sJauleluoa lit! 'Zb VIN❑ ONl 1 SeA :XppiN slsFleuy/Ql/auall/alep sopnloul- :000 golew slogej aldweS t Vi El ON❑ saA❑ S}Sal paAIOSSIQ JO) POAIG09J 9wn10A paJallld 06 VINU oNC] SOA :loelul SJOUIelU00 -6 VINE] VINE) oNp( saAp ON[] Tasn MUMIU03 Gaud- :pasn siaulelu00 l3aJJOD '9 V/N❑ ON[] saA :ewnloA lualoLpS I VIN❑ O ❑ saA❑ :pa;sanbajl ow11 punoJV uanl ysnN •9 VINE) 0Nl SaA❑ :(J49L>) slsAleuV owl1. PIOH V01I6 9 VIN❑ ONN❑] sa, 1 :ewll P10H ulyl!M paAlJJy saldweS •t, V/N❑ o ❑ SOA❑ :C)0O uo aJnleubiS 19 aweN JaldweS E VIN❑ ON❑ sa :pagstnbuilallllpolsnoloule43 'Z V/N❑ ON[] s jp Ono Pallid Apolsno;o u1e40 G V/N❑ ON[] S! p :lUaSaJd ApolsnC) jo ule40 }5 4 e? :S;ua;uoo Bululwex uosJad;d's lllul Pug a;ea :sluauaw0D f ON se k :uezoad Sl ansslll IeoiSoloig 0.9 of 6ulzaa 1 anoge aq pinoys dwal ,r :'dwo.L Jaloo3 palaaaJoa 3• 0,1 u01109JJOD ON WVU JOIOed u0llaa"00 auJal un6aq sey ssaooJd 6ullooa'aol uo saldweS ❑ auON enlg <,:f6 �:aol;o adAjL (6-iD unE>-al :past} Ja;awowlet.}l / J9410 ❑ auoN ❑ s6,s9 a ggnt ❑ d(:IA alggng ❑ :Ie1J01eW FiMM'd ou ❑ s9A ❑ :loelul sins OV ` Safi ❑ :;uasaJd xoepalooC) uo leas Apo;sno 10410 (a9e 01e10Jawwo3 ❑lu9113 ❑Sdsfl ❑Sdfl ❑ xg pad ❑ :JalJnoo ao1_4p Algeno apiASJajunH aced q�'Aaa-£00-SO-UH3-A :Al!joglnV 6uinssl :JagwnN juawnoop Z 10 1, a 13d 05s !aoau uo f uoij1puoC) aiwaS :GweN 1UG110 s 18q' jrf ji*,"V 9 DL'�' - f Page 66 9JWUILI4U .� )f i 3i I�,Q _, z W . p Z — - W .OF cCC LO t O O a I 5U I 1•- U oz _.. Sh ;: S lVOIIAIVNV " SIMOV) F • } jer zo g 'L alsel ai;,-ads juounpeS I I 4 ii -- - { (337d) sjef zo g z i suoltiv Poe J SlelelN WWI - d-lds } i © j (D )Vd) . i it JO v G col �1)i 00 R i S� (33Vd) Je[ zo g - 4' i % ! F I.0 p I,.,� E Hd SUOILI See tf ' 1 l V1l 1e3o1 I — F r — -- r--i-- —� " m, °x°• u 95 1$1110',jil ,ee ❑, I (1 W q" NIk e.�1rI ry v � _— ur y. A I u p K q C O r: E N � j V [' C "J 4 ,^ V 4 S m � � a Q • Ia R � � IL' YI 5, f, �, G01 e ✓Y f.� C. ..� � I— t > z, d 0 f n y o f 67 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098onyq,we. Suite 100 Huntersville, INC 28078 (704)875-9092 March 13, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15030051 Pace Project No.: 92239539 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 03, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: J15030051 Pace Project No.: 92239539 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 North Dakota Certification #: R-150 Florida/NELAP Certification #: E87948 South Carolina Certification #: 83006001 Illinois Certification #: 200050 Texas Certification #: T104704529-14-1 Kentucky Certification #: 82 US Dept of Agriculture #: S-76505 Louisiana Certification #: 04168 Wisconsin Certification #: 405132750 Minnesota Certification #: 055-999-334 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15030051 Pace Project No.: 92239539 Lab ID Sample ID Matrix Date Collected Date Received 92239539001 2015005892 Solid 02/23/1513:29 03/03/1517:00 92239539002 2015005893 Solid 02/23/1517:09 03/03/1517:00 92239539003 2015005894 Solid 02/23/1517:00 03/03/1517:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gI invq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15030051 92239539 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92239539001 2015005892 ASTM D2974-87 RMS 1 PASI-G EPA 9060 TJJ 6 PASI-G 92239539002 2015005893 ASTM D2974-87 RMS 1 PASI-G EPA 9060 TJJ 6 PASI-G 92239539003 2015005894 ASTM D2974-87 RMS 1 PASI-G EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gI iQvq'we. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: J15030051 92239539 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92239539001 2015005892 ASTM D2974-87 Percent Moisture 20.0 % 0.10 03/09/15 15:38 EPA 9060 Total Organic Carbon 7010 mg/kg 748 03/12/15 15:38 EPA 9060 Total Organic Carbon 3570 mg/kg 746 03/12/15 15:43 EPA 9060 Total Organic Carbon 3290 mg/kg 748 03/12/15 15:49 EPA 9060 Total Organic Carbon 3600 mg/kg 754 03/12/15 15:55 EPA 9060 Mean Total Organic Carbon 4370 mg/kg 749 03/12/15 15:38 EPA 9060 RSD% 40.4 % 03/12/15 15:38 1g 92239539002 2015005893 ASTM D2974-87 Percent Moisture 12.3 % 0.10 03/09/15 15:38 EPA 9060 Total Organic Carbon 618J mg/kg 679 03/12/15 09:06 EPA 9060 Total Organic Carbon 567J mg/kg 689 03/12/15 09:13 EPA 9060 Total Organic Carbon 578J mg/kg 686 03/12/15 09:18 EPA 9060 Total Organic Carbon 534J mg/kg 684 03/12/15 09:24 EPA 9060 Mean Total Organic Carbon 574J mg/kg 685 03/12/15 09:06 EPA 9060 RSD% 6.0 % 03/12/15 09:06 92239539003 2015005894 ASTM D2974-87 Percent Moisture 11.7 % 0.10 03/09/15 15:38 EPA 9060 Total Organic Carbon 596J mg/kg 679 03/12/15 09:30 EPA 9060 Total Organic Carbon 675 mg/kg 674 03/12/15 09:36 EPA 9060 Total Organic Carbon 516J mg/kg 683 03/12/15 09:41 EPA 9060 Total Organic Carbon 585J mg/kg 683 03/12/15 09:47 EPA 9060 Mean Total Organic Carbon 593J mg/kg 680 03/12/15 09:30 EPA 9060 RSD% 11.0 % 03/12/15 09:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'we. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15030051 Pace Project No.: 92239539 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 13, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/27532 1g: % RSD > 40. •2015005892 (Lab ID:92239539001) • RSD% This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i-8Y9,We. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239539 Sample: 2015005892 Lab ID: 92239539001 Collected: 02/23/15 13:29 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.0 % 0.10 0.10 1 03/09/15 15:38 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 7010 mg/kg 748 374 1 03/12/15 15:38 7440-44-0 Total Organic Carbon 3570 mg/kg 746 373 1 03/12/15 15:43 7440-44-0 Total Organic Carbon 3290 mg/kg 748 374 1 03/12/15 15:49 7440-44-0 Total Organic Carbon 3600 mg/kg 754 377 1 03/12/15 15:55 7440-44-0 Mean Total Organic Carbon 4370 mg/kg 749 375 1 03/12/15 15:38 7440-44-0 Surrogates RSD% 40.4 % 1 03/12/15 15:38 1g REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/13/2015 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239539 Sample: 2015005893 Lab ID: 92239539002 Collected: 02/23/15 17:09 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.3 % 0.10 0.10 1 03/09/15 15:38 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 618J mg/kg 679 339 1 03/12/15 09:06 7440-44-0 Total Organic Carbon 567J mg/kg 689 344 1 03/12/15 09:13 7440-44-0 Total Organic Carbon 578J mg/kg 686 343 1 03/12/15 09:18 7440-44-0 Total Organic Carbon 534J mg/kg 684 342 1 03/12/15 09:24 7440-44-0 Mean Total Organic Carbon 574J mg/kg 685 342 1 03/12/15 09:06 7440-44-0 Surrogates RSD% 6.0 % 1 03/12/15 09:06 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/13/2015 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 8 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'We. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15030051 Pace Project No.: 92239539 Sample: 2015005894 Lab ID: 92239539003 Collected: 02/23/15 17:00 Received: 03/03/15 17:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.7 % 0.10 0.10 1 03/09/15 15:38 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 596J mg/kg 679 340 1 03/12/15 09:30 7440-44-0 Total Organic Carbon 675 mg/kg 674 337 1 03/12/15 09:36 7440-44-0 Total Organic Carbon 516J mg/kg 683 341 1 03/12/15 09:41 7440-44-0 Total Organic Carbon 585J mg/kg 683 342 1 03/12/15 09:47 7440-44-0 Mean Total Organic Carbon 593J mg/kg 680 340 1 03/12/15 09:30 7440-44-0 Surrogates RSD% 11.0 % 1 03/12/15 09:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/13/2015 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g i .8fgwe. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239539 QC Batch: PMST/10951 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92239539001, 92239539002, 92239539003 SAMPLE DUPLICATE: 1125151 40111309001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 19.0 18.4 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/13/2015 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g igcw'We. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15030051 Pace Project No.: 92239539 QC Batch: WETA/27532 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92239539001, 92239539002, 92239539003 METHOD BLANK: 1125810 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/12/15 07:13 LABORATORY CONTROL SAMPLE: 1125811 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 121000 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1125812 1125813 MS MSD 92239539001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 4370 7510 7510 10200 9980 77 75 50-150 2 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1125814 1125815 MS MSD 92239540001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 2000 6010 6010 7060 7300 84 88 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/13/2015 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 11 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g ww'we. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15030051 Pace Project No.: 92239539 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-G Pace Analytical Services - Green Bay ANALYTE QUALIFIERS 1g %RSD>40. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/13/2015 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 12 of 15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g 96-8Y9,W e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15030051 Pace Project No.: 92239539 Lab ID Sample ID QC Batch Method QC Batch 92239539001 2015005892 ASTM D2974-87 PMST/10951 92239539002 2015005893 ASTM D2974-87 PMST/10951 92239539003 2015005894 ASTM D2974-87 PMST/10951 92239539001 2015005892 EPA 9060 WETA/27532 92239539001 2015005892 EPA 9060 WETA/27533 92239539002 2015005893 EPA 9060 WETA/27532 92239539002 2015005893 EPA 9060 WETA/27533 92239539003 2015005894 EPA 9060 WETA/27532 92239539003 2015005894 EPA 9060 WETA/27533 Date: 03/13/2015 04:00 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 13 of 15 6£56£ZZ6:#OM away lapel Gould (s)auleluoo l°aJaooul Page 91 of 94 'dwal;o lno 'aAllemmid loanooul 'plog to lno a•l ) GOL40 u01leolP90 NNH90 eu110Je0 00N ayl of lugs ag lllnn wJOI sly} Jo Rdoo a 'saldwes oouepdwoo eullono WON bulloa.4e Aouedonslp a sl aJayl Janauay,M, :a;oN e J j l 4. .owa � . :M01AOH =1 _SI s f;• :a;<ea - �` :MaiAa�}, d23ilOS :uognlos98 /sluawwo0 :awl�ale0 :paloeluo0 uosaad N 1 A LpaJlnb98 elea plalj :uolanlosoN luogeogIRON aue'13 •gy V�E vl�R ON[] °N❑ saAl) sOA❑ :(pasegoJnd 11) # lo7 Iniq dui aced luasaad sleaS Apolsn0 Nue18 dpi :luasWd �uele dlJi '9y V10 oN❑ SOAO :(wing¢ ) s1e1A VOA ul aoedspeGH 'J7y V/ / oN❑ saA❑ :ual)euiJolyaap Jo) poNoaga saldwes r� L?i .,UAIJ VIN❑ VIN❑ oYQ sa,k❑ ON® SaAu ONE] so peleM) oaa-IM'3'aa `OO1'wJOJ!IOo 'VOA :suo!ldeoxa •uolepuawwoaaJ VC13 gl!m aouei!dwoo ul aq of puno; ale. uolleruoseid Bulpaau siauleluoa IIV 'pa�oayo uaaq aAeq uopmosaJd Bulpaou sJauleluoo 1!V ' = ' _ ICL�r lL}2 ±; lC� ��� r,?II 2?} 'Z6 V/N❑ Or -� :xlaleW slsAluuyl(jllawlllalep sapnloul- soA❑ :000 yolew sloquq oldweS y y 7ff) ONE] SOA❑ sisal paAlossla Jo; POA1809J awnloA paJalll� 'M V/N❑ ON❑ sa :)Oulu] sJaulelu00 '6 "VIN❑ VINE] oN ONE] sa .. So" elf l :past SJeu!elu00 aoed- 1 :pasn sJaulelu0c) loanoo '9 VINE)ONE] SeAAl :awnloA lualol4ns 'L V/N❑ !yd saAD :pa}senboU awll punoay uanl usnN 9 VJN❑ o�,B saAp :(JuZt>) slslsleua awll pIOH #J04S •9 VIN❑ °N❑ S!M :awls P10H ulyllM paAIJJV saldweS 'tr VIN❑ /m saA❑ :000 uo amleubiS 19 awed JaldweS VIN❑ ONE] :pagslnbullaU Apol9n0l,o uie40 'Z VIN❑ ONE] sap :1n0 p9ill3 APolsnC) jo un3g0 y VIN❑ ONE] S;? JJ 4u8s9Jd Apolsn0 jo uley0 :slualuoo fululmez ubs ed;o slelllul pue ale(3 :s;uawwa0 Isv ON so),:uazoJ3 sl anssll leol6olols3 0.9 of 6u1709Jl anoge aq pinogs dwal 0• -) :'dwalJalooO palaaJJoO U01109JJOO ON LOW. 1013e,d u0130aA03 awal unBeq sey ssaooJd Builoo° 'ool uo saidwesr.:j auoN enlg �- :aal;o edA.L 4DV4j un0 ,dl :pasn Jaiewomagl J0410 ❑ auoN ❑ s6eg 91q d(3A GlggnB ❑ :18MO ew BuNOLd I , M, ou ❑ W ❑ :laulul sleeS tou - E] sal( ❑ :IuasGJd xog1Ja1000 uo leas dpo;sn0 Al Jaglo 9(@j ❑1e1oJaww00 ❑1u9110 ❑Sdsn ❑Sdn ❑ x3 pa3 ❑ :JaIJnoC) ,��' :auaeN u9110 eoWo A;Ilsnn a{jiAsJajunH coed :AjlJogjnV Buinssl Z do 4 9158d q 4'A0J-£00-S3-UH3-d :JagwnN juawnool] 103OU uo u0)j1pu03 pf �JJjlifL'�83�',� jam` "- f Page 14 iN Pag .` 9 f 94 Cuwlomrr ib com Iem a r�ur ,rls Ir, n� Cr ra �rpaopraat J II ' � to 1 hr.. e^ � .•r[�r i D I i tp 3 r rnVS [o }3 I I r o tW N �c 9 ° '$ m I w is A_ i I 7 ) � C - C7 9 ' � W � � �I vi t7 I _ ffi N � � 0 1 , •0 r? - � i I 1 �. V • .� a � I� O 4.n �i1. i". P1 I ,'ram' (S ID rs°� _ •� � i I i t E�' - • '� D I � Q ' I N X mi m`t'11 I I 1J k� tl C-Lu� ` g ri i ! cry, ' I o o; i, tiCr "comb IeAf{111 5 u? g 5 A a �I1 _ �— —l__� Grab Req�iiro� 97r� n� ..\--rZ- ro ,j t Q , Total Metals , Anloiis pH 8 �+ 1 •8 oz jar (PACE) 0 1 1 TOC 7 •4 ox jar 1a P ---j ! �1—I—�— —I— . — --- -- - p :0 7 -€� { .1t` � � � i I SPI_.P •Total Metals A u and Anions " 2 - 8 oz jars (PACE) 5 g I Sediment specific tests 2- 8 oz jar f g (ACCESS , I -" ANALYTICAL.) i i I � Total t or Conlainers _ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM `Analytical DUKE }` EI ,E ��SE M Laboratory Services -� Mail Code MG03A2 (Building 74Q5) ! rater Hagers Feny Rd i Huntersville, N. C. 2a07s i J98 _ _ Faxa aqJ 75_4349 _ _ _ _ _ _; - _._._._._._._._._._._._ ; - _. ._Analytical Laboratory Use Only __._._._._.-.-.---.-._._._._._._.i NC x_ a &337bf 94 I DISTRIBUTION — 1 ORIGINAL to LAB, COPY to CLIENT NPDES! ; Odi 01i1ef ��`� 1 matrix: SOIL Samples Ori inetin From iloeoad By wu s ram. ' -, . S , �S 1 i +�� SAMPLE PROGRAM Ground Water E u E E E G C 'IPPoJeCi°'n1e AB Groundwater Assessment -Soil 2)Phone No: H. F. Lee 3)Cllent 4IKax No: AB GW 5)Business Unit: 5)Project ID: 7)Matl Code: 5) Operating Unit: elAc" ID: t0)Proceas ID lmporta : When specific accountlng has been established and is not indicated above we need the following: 1) Enter correct accounting In all 5 accounting fields above, or 2 Provide correct accountinq for Operating Unit and Process ID 1 LAB USE ONLY I 1 I "Lab ID i � aju io °I- Matrix ISoII, Sediment, Ash) A- - {,- n1 3 i e E_ J a .q I Im C i in E i ig I IN Ir---mot CS �-1 1 i 1 1 1 I: PACE PACE Cooler Tem C PO 1142081 „Pr serv.:1=H Other _ Plant _ I ; REV DATE 2/1W 015 2=H S0i 3=H '._.._.._.._.._.._.._.._.._.._ 4=lce = One rn LO u3 QQK... 7 to ai __43-.IgZ. nF:r LCI GOI4tD.leie 8i1 �y •- O m -c w 4 tg cs ?_ a a !� a �_ Z o Preservatives when used must be a Iw d N 14 J U added within 15 minutes of sample ` In LA a) Q collection 6i to , O 0 M .� N d7 CM U) 14Collection Information s -2 o D- a s rn U 13Sample Description or ID Date Tir W—l� —b-.7;" iYrS i'F� wV— ! 256— S— TAf_C,LS -rly l3 Z r r r., W- f :5 S a,sz Il 7. i 17< WATER EQUIPMENT BLANK (1 PER JDAY) � BY ` Syar�rLL N a wtelilma q � ^ �i "� S td�- Jai ACCePtltl� F' By ' OatalTime Accepted y3y. - - Uiie/ Oatemme Cam Sealad1Lcek Openad By - Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V,'n, Me Anions: Cl, Nitrate-N, SO4 Sediment Specific Parameters: %Solids. CEC. Particle Size Distrit ra L7 0 :r: 0- Cam' W H V Z o H dr a U) t16N UiasQex pH ox Potential IWtoo 2211equested Turnaround 14 Days x, -7 Days .48 Hr S E E E C 1)Projem Name AS Groundwater Assessment - Soil H. F. Lee ZlPhone No: 3)Cllent AB GW 4)Fax No: 75lBusimasit: Sproject ID: 7)Mall Code: nit: 8)Activity ID: 1e)Proceaa ID IIR l2QcW t: when specific accounting has been established and is not indicated above we need the following. 1) Enter correct accounting in all 5 accounting fields above.. Or 2) Provide correct accounting for Operating Unit and Process ID. I LAB USE ONLY 1 Matrix F I "Caro ID i � (Sail, Sediment, Ash) Sat - i7�t5rx 5�, 2i. -t e LI c { i0 Y I It 1 1 ' igg I 1u :a 1 I IV 1 1 1 I I f f� I 1 1 I i WATER 21)Relinquished By Relinquished By Relinquished By 73Sample Description or ID ,1- rr►zy U31 , — 06 -- EQUIPMENT BLANK (1 PER DA _ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM vim Order frj���� - -Analytical Laboratory Services - _i i -----------------------------------Analytical Laborato Use Only- - - - - - - - - - Mail Cade MG03A2 ('Building 7405) i f V"ENERGY. 13339Hagers Ferry Rd �5_()� �C�j M1 Matrix: SOIi_ Huntentvil66, H. C. 26075 Sam les Orl Inatin From M (9e0) eTN. C. 5 Logped HY Date a Time lI ` Fax: 980 e75A349 } 3` SAMPLE PROGRAM Ground water Other_ PACE Cooler Tama IC ` PO 1142081� "'r l $erv.:1=H 2=H SO4 3=H _ ..__._.._.._.._.._.._.._. _ 4=Ice =one 4A LOC. th Customer to camnlete all w ' a in y O o- Np J Preservatives when used must be added within 15 minutes of sample ig L ` 0 woo U collection d m eft 00 0 0 fa ,� N J� co E N UJ 'a � U Q 14Callection Information . _... - 0_ , 0 CL r 1 N Q Z Q Date Si nature '!?. r F� .�. N c8 N ar —13 Time t J. oe -A3 U 7:1'4 _ Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Anions: Cl. Nitrate-N. SO4 Sediment Specific Parameters: %So led By: wljF JJ No, Sr, TI, V, Zn, Mercury, pH Particle Size Distribution, Redox Potential P��Of 94 Nc x_ sc_ i DISTRIBUTION OH_ ORIGINAL to LAB, i COPY to CLIENT NPDESi Plant l l REV DATE 211012015 4- �zRequested Turnaround 14 pays x '7 Days - 48 Hr