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Home My WebLink AboutNC0003417_J15020344 Report_20150805DUKE ENERGY Revision 1 - April 2, 2015 Analytical Laboratory Page 1of52 Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15020344 AB GW ASSESSMENT SOIL Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer 1677 Old Smithfield Rd Goldsboro NC 27530, Margaret Galvin -Karr Phone: 980-875-5219 Date: 4/2/2015 Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Revision 1 - April 2, 2015 Sample ID's & Descriptions: Page 2 of 52 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015003909 HF LEE PLANT 10-Feb-15 5:00 PM ILLEGIBLE AMW 11-4-6 2015003910 HF LEE PLANT 10-Feb-15 5:30 PM ILLEGIBLE AMW 11-9-11 2015003911 HF LEE PLANT 10-Feb-15 4:00 PM ILLEGIBLE AMW-11SIB 0-2 2015003912 HF LEE PLANT 10-Feb-15 5:35 PM ILLEGIBLE AMW 11SB-12-13 2015004028 HF LEE PLANT 10-Feb-15 2:43 PM ILLEGIBLE EB-1 5 Total Samples Revision 1 - April 2, 2015 Page 3 of 52 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 3/10/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020344 Site: AMW 11-4-6 Collection Date: 10-Feb-15 5:00 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Revision 1 - April 2, 2015 Page 4 of 52 Sample #: 2015003909 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020344 Site: AMW 11-9-11 Collection Date: 10-Feb-15 5:30 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Revision 1 - April 2, 2015 Page 5 of 52 Sample #: 2015003910 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020344 Site: AMW-11 SB 0-2 Collection Date: 10-Feb-15 4:00 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Revision 1 - April 2, 2015 Page 6 of 52 Sample #: 2015003911 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020344 Site: AMW 11 SB-12-13 Collection Date: 10-Feb-15 5:35 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Revision 1 - April 2, 2015 Page 7 of 52 Sample #: 2015003912 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE 15 Certificate of Laborator Anal sis Revision 1 -April y y Page 8 8 oof f 52 This report shall not be reproduced, except in full. Order # J15020344 Site: EB-1 Collection Date: 10-Feb-15 2:43 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015004028 Matrix: OTHER Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1-�pvig,8y&�e. Suite 100 Huntersville, INC 28078 (704)875-9092 March 04, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15020344 Pace Project No.: 92237739 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 13, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n OgQlgffii6g8y&�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020344 Pace Project No.: 92237739 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Arizona Certification #: AZ0735 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity New York Certification #: 11888 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n �Q�ff�in�c&fie. Suite100 y Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15020344 Pace Project No.: 92237739 Lab ID Sample ID Matrix Date Collected Date Received 92237739001 2015003909 Solid 02/10/1517:00 02/13/1513:38 92237739002 2015003910 Solid 02/10/1517:30 02/13/1513:38 92237739003 2015003911 Solid 02/10/1516:00 02/13/1513:38 92237739004 2015003912 Solid 02/10/1517:35 02/13/1513:38 92237739005 2015004028 Water 02/10/1514:43 02/13/1513:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- A n �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15020344 92237739 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92237739001 2015003909 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237739002 2015003910 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237739003 2015003911 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237739004 2015003912 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237739005 2015004028 EPA 6010 TAP 15 PASI-0 EPA 6020 DRS 9 PASI-O EPA 245.1 TAP 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020344 Pace Project No.: 92237739 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92237739001 2015003909 EPA6010 Aluminum 2760 mg/kg 5.1 02/21/1515:50 EPA6010 Barium 6.0 mg/kg 0.51 02/21/1515:50 EPA6010 Boron 3.5 mg/kg 2.6 02/21/1515:50 EPA6010 Calcium 19.01 mg/kg 25.6 02/21/1515:50 EPA6010 Chromium 3.4 mg/kg 0.26 02/21/1515:50 EPA6010 Copper 1.9 mg/kg 0.26 02/21/1515:50 EPA6010 Iron 3470 mg/kg 2.0 02/21/1515:50 EPA6010 Magnesium 106 mg/kg 25.6 02/21/1515:50 EPA6010 Manganese 22.7 mg/kg 0.26 02/21/1515:50 EPA6010 Nickel 1.0 mg/kg 0.26 02/21/1515:50 EPA6010 Potassium 62.3 mg/kg 51.1 02/21/1515:50 EPA6010 Strontium 0.52 mg/kg 0.51 02/21/1515:50 EPA6010 Zinc 2.8 mg/kg 1.0 02/21/1515:50 EPA 6020 Beryllium 0.17J mg/kg 0.31 02/20/15 10:49 EPA 6020 Cobalt 1.4J mg/kg 2.6 02/20/15 10:49 EPA 6020 Lead 3.4 mg/kg 2.6 02/20/15 10:49 EPA 6020 Vanadium 8.4 mg/kg 2.6 02/20/15 10:49 ASTM D2974-87 Percent Moisture 5.9 % 0.10 03/04/15 13:20 EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 02/17/15 11:50 EPA 9060 RSD% 7.9 % 02/26/15 15:38 92237739002 2015003910 EPA6010 Aluminum 983 mg/kg 5.3 02/21/1516:20 EPA6010 Barium 4.4 mg/kg 0.53 02/21/1516:20 EPA6010 Boron 2.3J mg/kg 2.7 02/21/1516:20 EPA6010 Calcium 17AJ mg/kg 26.7 02/21/1516:20 EPA6010 Chromium 2.6 mg/kg 0.27 02/21/1516:20 EPA6010 Copper 1.2 mg/kg 0.27 02/21/1516:20 EPA6010 Iron 1970 mg/kg 2.1 02/21/1516:20 EPA6010 Magnesium 36.6 mg/kg 26.7 02/21/1516:20 EPA6010 Manganese 16.1 mg/kg 0.27 02/21/1516:20 EPA6010 Nickel 0.66 mg/kg 0.27 02/21/1516:20 EPA6010 Potassium 104 mg/kg 53.4 02/21/1516:20 EPA6010 Strontium 0.57 mg/kg 0.53 02/21/1516:20 EPA6010 Zinc 1.4 mg/kg 1.1 02/21/1516:20 EPA 6020 Vanadium 3.1 mg/kg 2.7 02/20/15 11:07 ASTM D2974-87 Percent Moisture 7.2 % 0.10 03/04/15 13:20 EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 02/17/15 11:50 EPA 9060 RSD% 14.0 % 02/26/15 16:02 92237739003 2015003911 EPA6010 Aluminum 3290 mg/kg 5.4 02/21/1516:28 EPA6010 Barium 15.0 mg/kg 0.54 02/21/1516:28 EPA6010 Boron 3.8 mg/kg 2.7 02/21/1516:28 EPA6010 Calcium 62.2 mg/kg 26.8 02/21/1516:28 EPA6010 Chromium 4.1 mg/kg 0.27 02/21/1516:28 EPA6010 Copper 2.3 mg/kg 0.27 02/21/1516:28 EPA6010 Iron 3780 mg/kg 2.1 02/21/1516:28 REPORT OF LABORATORY ANALYSIS M1 M1 D3 D3 D3 D3 D3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n �Q�ffiic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020344 Pace Project No.: 92237739 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92237739003 2015003911 EPA 6010 Magnesium 223 mg/kg 26.8 02/21/1516:28 EPA 6010 Manganese 19.9 mg/kg 0.27 02/21/1516:28 EPA 6010 Nickel 1.4 mg/kg 0.27 02/21/1516:28 EPA 6010 Potassium 106 mg/kg 53.7 02/21/1516:28 EPA 6010 Strontium 0.93 mg/kg 0.54 02/21/1516:28 EPA 6010 Zinc 5.7 mg/kg 1.1 02/21/1516:28 EPA 6020 Beryllium 0.191 mg/kg 0.32 02/20/15 11:20 EPA 6020 Lead 3.7 mg/kg 2.7 02/20/15 11:20 EPA 6020 Vanadium 10.6 mg/kg 2.7 02/20/15 11:20 EPA 7471 Mercury 0.0045J mg/kg 0.0089 02/22/15 09:55 ASTM D2974-87 Percent Moisture 9.1 % 0.10 03/04/15 13:21 EPA 9045 pH at 25 Degrees C 4.8 Std. Units 0.10 02/17/15 11:50 EPA 9060 Total Organic Carbon 3090 mg/kg 605 02/26/15 16:34 EPA 9060 Total Organic Carbon 1520 mg/kg 604 02/26/15 16:40 EPA 9060 Total Organic Carbon 1570 mg/kg 605 02/26/15 16:46 EPA 9060 Total Organic Carbon 1840 mg/kg 596 02/26/15 16:52 EPA 9060 Mean Total Organic Carbon 2000 mg/kg 603 02/26/15 16:34 EPA 9060 RSD% 36.8 % 02/26/15 16:34 92237739004 2015003912 EPA 6010 Aluminum 1440 mg/kg 5.2 02/21/1516:46 EPA 6010 Barium 4.6 mg/kg 0.52 02/21/1516:46 EPA 6010 Boron 4.1 mg/kg 2.6 02/21/1516:46 EPA 6010 Calcium 29.6 mg/kg 26.0 02/21/1516:46 EPA 6010 Chromium 7.2 mg/kg 0.26 02/21/1516:46 EPA 6010 Copper 5.1 mg/kg 0.26 02/21/1516:46 EPA 6010 Iron 4380 mg/kg 2.1 02/21/1516:46 EPA 6010 Magnesium 67.7 mg/kg 26.0 02/21/1516:46 EPA 6010 Manganese 54.8 mg/kg 0.26 02/21/1516:46 EPA 6010 Nickel 1.9 mg/kg 0.26 02/21/1516:46 EPA 6010 Potassium 51.9J mg/kg 51.9 02/21/1516:46 EPA 6010 Strontium 0.48J mg/kg 0.52 02/21/1516:46 EPA 6010 Zinc 4.4 mg/kg 1.0 02/21/1516:46 EPA 6020 Beryllium 0.18J mg/kg 0.31 02/20/15 11:23 EPA 6020 Cobalt 4.6 mg/kg 2.6 02/20/15 11:23 EPA 6020 Lead 1 AJ mg/kg 2.6 02/20/15 11:23 EPA 6020 Vanadium 10.3 mg/kg 2.6 02/20/15 11:23 ASTM D2974-87 Percent Moisture 7.7 % 0.10 03/04/15 13:21 EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 02/17/15 11:50 EPA 9060 RSD% 5.5 % 02/26/15 16:58 92237739005 2015004028 EPA 6010 Aluminum 183 ug/L 100 02/20/15 05:56 EPA 6010 Calcium 1290 ug/L 500 02/20/15 05:56 EPA 6010 Chromium 5.1 ug/L 5.0 02/20/15 05:56 EPA 6010 Iron 1610 ug/L 40.0 02/20/15 05:56 EPA 6010 Manganese 37.3 ug/L 5.0 02/20/15 05:56 EPA 6020 Cobalt 6.1 ug/L 1.0 02/24/15 20:19 REPORT OF LABORATORY ANALYSIS D3 D3 D3 D3 D3 D3 D3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 04, 2015 General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22706 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35175467001 Ml: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1132791) • Aluminum • Calcium • Iron • MSD (Lab ID: 1132792) • Aluminum • Calcium • Iron QC Batch: MPRP/22732 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 Ml: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1134160) • Aluminum • Iron • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 04, 2015 QC Batch: MPRP/22732 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 Ml: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1134161) • Aluminum • Iron • Manganese Additional Comments: Analyte Comments: QC Batch: MPRP/22706 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1132791) • Zinc • MSD (Lab ID: 1132792) • Zinc REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 04, 2015 General Information: 5 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. The samples were prepared in accordance with EPA 3010 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22733 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1134164) • Antimony • Cadmium • Selenium • MSD (Lab ID: 1134165) • Antimony Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n �Q�ffligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 04, 2015 Analyte Comments: QC Batch: MPRP/22733 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003909 (Lab ID:92237739001) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015003910 (Lab ID:92237739002) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015003911 (Lab ID:92237739003) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015003912 (Lab ID:92237739004) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MS (Lab ID: 1134164) • Arsenic • Beryllium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 04, 2015 Analyte Comments: QC Batch: MPRP/22733 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MS (Lab ID: 1134164) • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MSD (Lab ID: 1134165) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015003909 (Lab ID:92237739001) • Antimony •2015003910 (Lab ID:92237739002) • Antimony •2015003911 (Lab ID:92237739003) • Antimony •2015003912 (Lab ID:92237739004) • Antimony • BLANK (Lab ID: 1134162) • Antimony • LCS (Lab ID: 1134163) • Antimony • MS (Lab ID: 1134164) • Antimony • MSD (Lab ID: 1134165) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - Apn 1995`9699y�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 245.1 Description: 245.1 Mercury Client: Duke Energy Date: March 04, 2015 General Information: 1 sample was analyzed for EPA 245.1. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 245.1 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5391 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35174974003,92237369003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1135128) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 1995`9inic&)r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: March 04, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - Apn 199519299y�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: March 04, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 1995`9isc&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 04, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/43647 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003909 (Lab ID:92237739001) • Chloride • Sulfate •2015003910 (Lab ID:92237739002) • Chloride • Sulfate •2015003911 (Lab ID:92237739003) • Chloride • Sulfate •2015003912 (Lab ID:92237739004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - Apn 1995`9499y�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: March 04, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015003909 (Lab ID:92237739001) •2015003910 (Lab ID:92237739002) •2015003911 (Lab ID:92237739003) •2015003912 (Lab ID:92237739004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - Apn 199519999y�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020344 Pace Project No.: 92237739 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 04, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apn 199519699y�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015003909 Lab ID: 92237739001 Collected: 02/10/15 17:00 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Beryllium Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 03/04/2015 05:11 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 2760 mg/kg 5.1 2.6 1 02/18/1515:48 02/21/1515:50 7429-90-5 6.0 mg/kg 0.51 0.26 1 02/18/1515:48 02/21/1515:50 7440-39-3 3.5 mg/kg 2.6 1.3 1 02/18/1515:48 02/21/1515:50 7440-42-8 19.01 mg/kg 25.6 12.8 1 02/18/1515:48 02/21/1515:50 7440-70-2 3.4 mg/kg 0.26 0.13 1 02/18/1515:48 02/21/1515:50 7440-47-3 1.9 mg/kg 0.26 0.13 1 02/18/1515:48 02/21/1515:50 7440-50-8 3470 mg/kg 2.0 1.0 1 02/18/1515:48 02/21/1515:50 7439-89-6 106 mg/kg 25.6 12.8 1 02/18/1515:48 02/21/1515:50 7439-95-4 22.7 mg/kg 0.26 0.13 1 02/18/1515:48 02/21/1515:50 7439-96-5 ND mg/kg 0.51 0.26 1 02/18/1515:48 02/21/1515:50 7439-98-7 1.0 mg/kg 0.26 0.13 1 02/18/1515:48 02/21/1515:50 7440-02-0 62.3 mg/kg 51.1 25.6 1 02/18/1515:48 02/21/1515:50 7440-09-7 ND mg/kg 51.1 25.6 1 02/18/1515:48 02/21/1515:50 7440-23-5 0.52 mg/kg 0.51 0.26 1 02/18/1515:48 02/21/1515:50 7440-24-6 2.8 mg/kg 1.0 0.51 1 02/18/1515:48 02/21/1515:50 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1510:49 7440-36-0 ND mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1510:49 7440-38-2 0.17J mg/kg 0.31 0.15 50 02/18/1515:48 02/20/1510:49 7440-41-7 ND mg/kg 0.31 0.15 50 02/18/1515:48 02/20/1510:49 7440-43-9 II AJ mg/kg 2.6 1.3 50 02/18/15 15:48 02/20/15 10:49 7440-48-4 3.4 mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1510:49 7439-92-1 ND mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1510:49 7782-49-2 ND mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1510:49 7440-28-0 8.4 mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1510:49 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0086 0.0043 1 02/18/15 17:58 02/22/15 09:44 7439-97-6 Analytical Method: ASTM D2974-87 5.9 % 0.10 0.10 1 03/04/1513:20 Analytical Method: EPA 9045 4.7 Std. Units 0.10 0.10 1 02/17/15 11:50 Analytical Method: EPA 9056 M1 D3,M6, N2 D3 D3 D3,M6 D3 D3 D3,M6 D3 D3 ND mg/kg 264 132 5 02/15/15 20:49 16887-00-6 D3 ND mg/kg 264 132 5 02/15/15 20:49 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 26.4 13.2 5 02/15/15 20:49 14797-55-8 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apn IYRQItf� 99y�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015003909 Lab ID: 92237739001 Collected: 02/10/15 17:00 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 605 303 1 02/26/15 15:38 7440-44-0 Total Organic Carbon ND mg/kg 604 302 1 02/26/15 15:45 7440-44-0 Total Organic Carbon ND mg/kg 598 299 1 02/26/15 15:51 7440-44-0 Total Organic Carbon ND mg/kg 597 298 1 02/26/15 15:56 7440-44-0 Mean Total Organic Carbon ND mg/kg 601 300 1 02/26/15 15:38 7440-44-0 Surrogates RSD% 7.9 % 1 02/26/15 15:38 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apn 199519899y�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015003910 Lab ID: 92237739002 Collected: 02/10/15 17:30 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 983 mg/kg 5.3 2.7 1 02/18/1515:48 02/21/1516:20 7429-90-5 Barium 4.4 mg/kg 0.53 0.27 1 02/18/1515:48 02/21/1516:20 7440-39-3 Boron 2.3J mg/kg 2.7 1.3 1 02/18/1515:48 02/21/1516:20 7440-42-8 Calcium 17AJ mg/kg 26.7 13.3 1 02/18/1515:48 02/21/1516:20 7440-70-2 Chromium 2.6 mg/kg 0.27 0.13 1 02/18/1515:48 02/21/1516:20 7440-47-3 Copper 1.2 mg/kg 0.27 0.13 1 02/18/1515:48 02/21/1516:20 7440-50-8 Iron 1970 mg/kg 2.1 1.1 1 02/18/1515:48 02/21/1516:20 7439-89-6 Magnesium 36.6 mg/kg 26.7 13.3 1 02/18/1515:48 02/21/1516:20 7439-95-4 Manganese 16.1 mg/kg 0.27 0.13 1 02/18/1515:48 02/21/1516:20 7439-96-5 Molybdenum ND mg/kg 0.53 0.27 1 02/18/1515:48 02/21/1516:20 7439-98-7 Nickel 0.66 mg/kg 0.27 0.13 1 02/18/1515:48 02/21/1516:20 7440-02-0 Potassium 104 mg/kg 53.4 26.7 1 02/18/1515:48 02/21/1516:20 7440-09-7 Sodium ND mg/kg 53.4 26.7 1 02/18/1515:48 02/21/1516:20 7440-23-5 Strontium 0.57 mg/kg 0.53 0.27 1 02/18/1515:48 02/21/1516:20 7440-24-6 Zinc 1.4 mg/kg 1.1 0.53 1 02/18/1515:48 02/21/1516:20 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:07 7440-36-0 D3,N2 Arsenic ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:07 7440-38-2 D3 Beryllium ND mg/kg 0.32 0.16 50 02/18/1515:48 02/20/1511:07 7440-41-7 D3 Cadmium ND mg/kg 0.32 0.16 50 02/18/1515:48 02/20/1511:07 7440-43-9 D3 Cobalt ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:07 7440-48-4 D3 Lead ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:07 7439-92-1 D3 Selenium ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:07 7782-49-2 D3 Thallium ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:07 7440-28-0 D3 Vanadium 3.1 mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:07 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0088 0.0044 1 02/18/15 17:58 02/22/15 09:53 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.2 % 0.10 0.10 1 03/04/15 13:20 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 0.10 1 02/17/15 11:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 269 135 5 02/15/15 21:11 16887-00-6 D3 Sulfate ND mg/kg 269 135 5 02/15/15 21:11 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.9 13.5 5 02/15/15 21:11 14797-55-8 H3 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apn 199519999y�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015003910 Lab ID: 92237739002 Collected: 02/10/15 17:30 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 605 303 1 02/26/15 16:02 7440-44-0 Total Organic Carbon ND mg/kg 606 303 1 02/26/15 16:07 7440-44-0 Total Organic Carbon ND mg/kg 597 299 1 02/26/15 16:12 7440-44-0 Total Organic Carbon ND mg/kg 602 301 1 02/26/15 16:18 7440-44-0 Mean Total Organic Carbon ND mg/kg 603 301 1 02/26/15 16:02 7440-44-0 Surrogates RSD% 14.0 % 1 02/26/15 16:02 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 A n 469&y,,�e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015003911 Lab ID: 92237739003 Collected: 02/10/15 16:00 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 3290 mg/kg 5.4 2.7 1 02/18/1515:48 02/21/1516:28 7429-90-5 Barium 15.0 mg/kg 0.54 0.27 1 02/18/1515:48 02/21/1516:28 7440-39-3 Boron 3.8 mg/kg 2.7 1.3 1 02/18/1515:48 02/21/1516:28 7440-42-8 Calcium 62.2 mg/kg 26.8 13.4 1 02/18/1515:48 02/21/1516:28 7440-70-2 Chromium 4.1 mg/kg 0.27 0.13 1 02/18/1515:48 02/21/1516:28 7440-47-3 Copper 2.3 mg/kg 0.27 0.13 1 02/18/1515:48 02/21/1516:28 7440-50-8 Iron 3780 mg/kg 2.1 1.1 1 02/18/1515:48 02/21/1516:28 7439-89-6 Magnesium 223 mg/kg 26.8 13.4 1 02/18/1515:48 02/21/1516:28 7439-95-4 Manganese 19.9 mg/kg 0.27 0.13 1 02/18/1515:48 02/21/1516:28 7439-96-5 Molybdenum ND mg/kg 0.54 0.27 1 02/18/1515:48 02/21/1516:28 7439-98-7 Nickel 1.4 mg/kg 0.27 0.13 1 02/18/1515:48 02/21/1516:28 7440-02-0 Potassium 106 mg/kg 53.7 26.8 1 02/18/1515:48 02/21/1516:28 7440-09-7 Sodium ND mg/kg 53.7 26.8 1 02/18/1515:48 02/21/1516:28 7440-23-5 Strontium 0.93 mg/kg 0.54 0.27 1 02/18/1515:48 02/21/1516:28 7440-24-6 Zinc 5.7 mg/kg 1.1 0.54 1 02/18/1515:48 02/21/1516:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:20 7440-36-0 D3,N2 Arsenic ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:20 7440-38-2 D3 Beryllium 0.191 mg/kg 0.32 0.16 50 02/18/1515:48 02/20/1511:20 7440-41-7 D3 Cadmium ND mg/kg 0.32 0.16 50 02/18/1515:48 02/20/1511:20 7440-43-9 D3 Cobalt ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:20 7440-48-4 D3 Lead 3.7 mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:20 7439-92-1 D3 Selenium ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:20 7782-49-2 D3 Thallium ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:20 7440-28-0 D3 Vanadium 10.6 mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:20 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0045J mg/kg 0.0089 0.0045 1 02/18/15 17:58 02/22/15 09:55 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 9.1 % 0.10 0.10 1 03/04/15 13:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.8 Std. Units 0.10 0.10 1 02/17/15 11:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 274 137 5 02/15/15 21:32 16887-00-6 D3 Sulfate ND mg/kg 274 137 5 02/15/15 21:32 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 27.4 13.7 5 02/15/15 21:32 14797-55-8 H3 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- A n Opuniycffl,�e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015003911 Lab ID: 92237739003 Collected: 02/10/15 16:00 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 3090 mg/kg 605 303 1 02/26/15 16:34 7440-44-0 Total Organic Carbon 1520 mg/kg 604 302 1 02/26/15 16:40 7440-44-0 Total Organic Carbon 1570 mg/kg 605 303 1 02/26/15 16:46 7440-44-0 Total Organic Carbon 1840 mg/kg 596 298 1 02/26/15 16:52 7440-44-0 Mean Total Organic Carbon 2000 mg/kg 603 301 1 02/26/15 16:34 7440-44-0 Surrogates RSD% 36.8 % 1 02/26/15 16:34 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 A n 429&y,,�e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015003912 Lab ID: 92237739004 Collected: 02/10/15 17:35 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 1440 mg/kg 5.2 2.6 1 02/18/1515:48 02/21/1516:46 7429-90-5 Barium 4.6 mg/kg 0.52 0.26 1 02/18/1515:48 02/21/1516:46 7440-39-3 Boron 4.1 mg/kg 2.6 1.3 1 02/18/1515:48 02/21/1516:46 7440-42-8 Calcium 29.6 mg/kg 26.0 13.0 1 02/18/1515:48 02/21/1516:46 7440-70-2 Chromium 7.2 mg/kg 0.26 0.13 1 02/18/1515:48 02/21/1516:46 7440-47-3 Copper 5.1 mg/kg 0.26 0.13 1 02/18/1515:48 02/21/1516:46 7440-50-8 Iron 4380 mg/kg 2.1 1.0 1 02/18/1515:48 02/21/1516:46 7439-89-6 Magnesium 67.7 mg/kg 26.0 13.0 1 02/18/1515:48 02/21/1516:46 7439-95-4 Manganese 54.8 mg/kg 0.26 0.13 1 02/18/1515:48 02/21/1516:46 7439-96-5 Molybdenum ND mg/kg 0.52 0.26 1 02/18/1515:48 02/21/1516:46 7439-98-7 Nickel 1.9 mg/kg 0.26 0.13 1 02/18/1515:48 02/21/1516:46 7440-02-0 Potassium 51.9J mg/kg 51.9 26.0 1 02/18/1515:48 02/21/1516:46 7440-09-7 Sodium ND mg/kg 51.9 26.0 1 02/18/1515:48 02/21/1516:46 7440-23-5 Strontium 0.48J mg/kg 0.52 0.26 1 02/18/1515:48 02/21/1516:46 7440-24-6 Zinc 4.4 mg/kg 1.0 0.52 1 02/18/1515:48 02/21/1516:46 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1511:23 7440-36-0 D3,N2 Arsenic ND mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1511:23 7440-38-2 D3 Beryllium 0.181 mg/kg 0.31 0.16 50 02/18/1515:48 02/20/1511:23 7440-41-7 D3 Cadmium ND mg/kg 0.31 0.16 50 02/18/1515:48 02/20/1511:23 7440-43-9 D3 Cobalt 4.6 mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1511:23 7440-48-4 D3 Lead 1 AJ mg/kg 2.6 1.3 50 02/18/15 15:48 02/20/15 11:23 7439-92-1 D3 Selenium ND mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1511:23 7782-49-2 D3 Thallium ND mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1511:23 7440-28-0 D3 Vanadium 10.3 mg/kg 2.6 1.3 50 02/18/1515:48 02/20/1511:23 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0085 0.0042 1 02/18/15 17:58 02/22/15 09:57 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.7 % 0.10 0.10 1 03/04/15 13:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 0.10 1 02/17/15 11:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 271 135 5 02/15/15 21:54 16887-00-6 D3 Sulfate ND mg/kg 271 135 5 02/15/15 21:54 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 27.1 13.5 5 02/15/15 21:54 14797-55-8 H3 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- A n Opuninyl,e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015003912 Lab ID: 92237739004 Collected: 02/10/15 17:35 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 595 298 1 02/26/15 16:58 7440-44-0 Total Organic Carbon ND mg/kg 605 303 1 02/26/15 17:03 7440-44-0 Total Organic Carbon ND mg/kg 602 301 1 02/26/15 17:10 7440-44-0 Total Organic Carbon ND mg/kg 606 303 1 02/26/15 17:17 7440-44-0 Mean Total Organic Carbon ND mg/kg 602 301 1 02/26/15 16:58 7440-44-0 Surrogates RSD% 5.5 % 1 02/26/15 16:58 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 A n 449&y',�e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020344 Pace Project No.: 92237739 Sample: 2015004028 Lab ID: 92237739005 Collected: 02/10/15 14:43 Received: 02/13/15 13:38 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Aluminum 183 ug/L 100 50.0 1 02/17/15 09:10 02/20/15 05:56 7429-90-5 Barium ND ug/L 10.0 5.0 1 02/17/15 09:10 02/20/15 05:56 7440-39-3 Boron ND ug/L 50.0 25.0 1 02/17/15 09:10 02/20/15 05:56 7440-42-8 Calcium 1290 ug/L 500 250 1 02/17/15 09:10 02/20/15 05:56 7440-70-2 Chromium 5.1 ug/L 5.0 2.5 1 02/17/15 09:10 02/20/15 05:56 7440-47-3 Copper ND ug/L 5.0 2.5 1 02/17/15 09:10 02/20/15 05:56 7440-50-8 Iron 1610 ug/L 40.0 20.0 1 02/17/15 09:10 02/20/15 05:56 7439-89-6 Magnesium ND ug/L 500 250 1 02/17/15 09:10 02/20/15 05:56 7439-95-4 Manganese 37.3 ug/L 5.0 2.5 1 02/17/15 09:10 02/20/15 05:56 7439-96-5 Molybdenum ND ug/L 10.0 5.0 1 02/17/15 09:10 02/20/15 05:56 7439-98-7 Nickel ND ug/L 5.0 2.5 1 02/17/15 09:10 02/20/15 05:56 7440-02-0 Potassium ND ug/L 1000 500 1 02/17/15 09:10 02/20/15 05:56 7440-09-7 Sodium ND ug/L 1000 500 1 02/17/15 09:10 02/20/15 05:56 7440-23-5 Strontium ND ug/L 10.0 5.0 1 02/17/15 09:10 02/20/15 05:56 7440-24-6 Zinc ND ug/L 20.0 10.0 1 02/17/15 09:10 02/20/15 05:56 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Antimony ND ug/L 1.0 0.50 1 02/17/15 09:10 02/24/15 20:19 7440-36-0 Arsenic ND ug/L 1.0 0.50 1 02/17/15 09:10 02/24/15 20:19 7440-38-2 Beryllium ND ug/L 0.10 0.050 1 02/17/15 09:10 02/23/15 16:28 7440-41-7 Cadmium ND ug/L 0.10 0.050 1 02/17/15 09:10 02/24/15 20:19 7440-43-9 Cobalt 6.1 ug/L 1.0 0.50 1 02/17/15 09:10 02/24/15 20:19 7440-48-4 Lead ND ug/L 1.0 0.50 1 02/17/15 09:10 02/23/15 16:28 7439-92-1 Selenium ND ug/L 1.0 0.50 1 02/17/15 09:10 02/24/15 20:19 7782-49-2 Thallium ND ug/L 1.0 0.50 1 02/17/15 09:10 02/23/15 16:28 7440-28-0 Vanadium ND ug/L 1.0 0.50 1 02/17/15 09:10 02/24/15 20:19 7440-62-2 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 Mercury ND ug/L 0.20 0.10 1 02/19/1510:40 02/20/1513:34 7439-97-6 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 A n 499&y,,�e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: MERP/5391 Analysis Method: EPA 245.1 QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury Associated Lab Samples: 92237739005 METHOD BLANK: 1135125 Matrix: Water Associated Lab Samples: 92237739005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 02/20/1512:47 LABORATORY CONTROL SAMPLE: 1135126 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2 1.8 90 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1135127 1135128 MS MSD 35174974003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L 0.00024 2 2 1.7 1.6 72 66 70-130 9 20 M1 mg/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1135129 1135130 MS MSD 92237369003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2 2 2.0 2.1 102 103 70-130 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n Opuniffyl,�e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: MERP/5386 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 METHOD BLANK: 1134154 Matrix: Solid Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 02/22/15 09:33 LABORATORY CONTROL SAMPLE: 1134155 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.082 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134156 1134157 MS MSD 92237650015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.036 .126 .132 0.16 0.16 98 92 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 410K A n c&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: MPRP/22732 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 METHOD BLANK: 1134158 Matrix: Solid Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.0 02/21/1515:20 Barium mg/kg ND 0.50 02/21/1515:20 Boron mg/kg ND 2.5 02/21/1515:20 Calcium mg/kg ND 25.2 02/21/1515:20 Chromium mg/kg ND 0.25 02/21/1515:20 Copper mg/kg ND 0.25 02/21/1515:20 Iron mg/kg ND 2.0 02/21/1515:20 Magnesium mg/kg ND 25.2 02/21/1515:20 Manganese mg/kg ND 0.25 02/21/1515:20 Molybdenum mg/kg ND 0.50 02/21/1515:20 Nickel mg/kg ND 0.25 02/21/1515:20 Potassium mg/kg ND 50.4 02/21/1515:20 Sodium mg/kg ND 50.4 02/21/1515:20 Strontium mg/kg ND 0.50 02/21/1515:20 Zinc mg/kg ND 1.0 02/21/1515:20 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1134159 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 124 124 100 80-120 Barium mg/kg 12.4 12.5 101 80-120 Boron mg/kg 124 126 102 80-120 Calcium mg/kg 619 612 99 80-120 Chromium mg/kg 12.4 12.2 98 80-120 Copper mg/kg 12.4 12.2 99 80-120 Iron mg/kg 124 118 96 80-120 Magnesium mg/kg 619 623 101 80-120 Manganese mg/kg 12.4 12.5 101 80-120 Molybdenum mg/kg 12.4 12.6 102 80-120 Nickel mg/kg 12.4 12.6 102 80-120 Potassium mg/kg 619 608 98 80-120 Sodium mg/kg 619 612 99 80-120 Strontium mg/kg 12.4 12.7 103 80-120 Zinc mg/kg 61.9 63.3 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 A n 489&y',�e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134160 1134161 MS MSD 92237739001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 2760 129 135 5310 5320 1990 1900 75-125 0 20 M1 Barium mg/kg 6.0 12.9 13.5 21.0 21.0 117 112 75-125 0 20 Boron mg/kg 3.5 129 135 120 119 91 86 75-125 1 20 Calcium mg/kg 19.01 642 673 664 651 100 94 75-125 2 20 Chromium mg/kg 3.4 12.9 13.5 15.8 16.2 97 95 75-125 2 20 Copper mg/kg 1.9 12.9 13.5 14.9 14.9 101 97 75-125 0 20 Iron mg/kg 3470 129 135 4040 4100 440 464 75-125 1 20 M1 Magnesium mg/kg 106 642 673 822 809 112 104 75-125 2 20 Manganese mg/kg 22.7 12.9 13.5 31.6 30.8 69 60 75-125 3 20 M1 Molybdenum mg/kg ND 12.9 13.5 10.8 11.5 84 85 75-125 6 20 Nickel mg/kg 1.0 12.9 13.5 14.2 15.0 103 104 75-125 5 20 Potassium mg/kg 62.3 642 673 702 725 100 99 75-125 3 20 Sodium mg/kg ND 642 673 647 646 100 95 75-125 0 20 Strontium mg/kg 0.52 12.9 13.5 13.4 14.2 100 102 75-125 6 20 Zinc mg/kg 2.8 64.2 67.3 67.6 69.7 101 100 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 A n 499&y,,�e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: MPRP/22706 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 92237739005 METHOD BLANK: 1132789 Associated Lab Samples: 92237739005 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Aluminum ug/L ND 100 02/20/15 04:35 Barium ug/L ND 10.0 02/20/15 04:35 Boron ug/L ND 50.0 02/20/15 04:35 Calcium ug/L ND 500 02/20/15 04:35 Chromium ug/L ND 5.0 02/20/15 04:35 Copper ug/L ND 5.0 02/20/15 04:35 Iron ug/L ND 40.0 02/20/15 04:35 Magnesium ug/L ND 500 02/20/15 04:35 Manganese ug/L ND 5.0 02/20/15 04:35 Molybdenum ug/L ND 10.0 02/20/15 04:35 Nickel ug/L ND 5.0 02/20/15 04:35 Potassium ug/L ND 1000 02/20/15 04:35 Sodium ug/L ND 1000 02/20/15 04:35 Strontium ug/L ND 10.0 02/20/15 04:35 Zinc ug/L ND 20.0 02/20/15 04:35 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1132790 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 2500 2520 101 80-120 Barium ug/L 250 252 101 80-120 Boron ug/L 2500 2590 104 80-120 Calcium ug/L 12500 12900 103 80-120 Chromium ug/L 250 251 100 80-120 Copper ug/L 250 253 101 80-120 Iron ug/L 2500 2470 99 80-120 Magnesium ug/L 12500 12700 102 80-120 Manganese ug/L 250 258 103 80-120 Molybdenum ug/L 250 251 100 80-120 Nickel ug/L 250 254 102 80-120 Potassium ug/L 12500 12100 96 80-120 Sodium ug/L 12500 12500 100 80-120 Strontium ug/L 250 249 100 80-120 Zinc ug/L 1250 1280 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 4101i A n 6c&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 MATRIX SPIKE & MATRIX Parameter SPIKE DUPLICATE: 1132791 35175467001 Units Result MS Spike Conc. MSD Spike Conc. 1132792 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Aluminum ug/L 15400 2500 2500 22500 22600 285 290 75-125 1 20 M1 Barium ug/L 433 250 250 712 700 111 107 75-125 2 20 Boron ug/L 99.8 2500 2500 2630 2590 101 100 75-125 1 20 Calcium ug/L 403000 12500 12500 427000 423000 197 164 75-125 1 20 M1 Chromium ug/L 75.4 250 250 320 320 98 98 75-125 0 20 Copper ug/L 252 250 250 513 509 104 103 75-125 1 20 Iron ug/L 52700 2500 2500 58200 59300 219 263 75-125 2 20 M1 Magnesium ug/L 6070 12500 12500 18800 18400 102 98 75-125 2 20 Manganese ug/L 868 250 250 1160 1150 116 112 75-125 1 20 Molybdenum ug/L 24.9 250 250 267 265 97 96 75-125 1 20 Nickel ug/L 65.9 250 250 309 308 97 97 75-125 0 20 Potassium ug/L 1870 12500 12500 14800 14400 104 100 75-125 3 20 Sodium ug/L 1260 12500 12500 14700 14400 108 105 75-125 2 20 Strontium ug/L 573 250 250 854 842 112 108 75-125 1 20 Zinc ug/L 5810 1250 1250 6920 6870 89 85 75-125 1 20 E Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n Opuolinlcffl,�e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: MPRP/22733 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 METHOD BLANK: 1134162 Matrix: Solid Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 02/20/1510:43 N2 Arsenic mg/kg ND 0.051 02/20/1510:43 Beryllium mg/kg ND 0.0061 02/20/1510:43 Cadmium mg/kg ND 0.0061 02/20/1510:43 Cobalt mg/kg ND 0.051 02/20/1510:43 Lead mg/kg ND 0.051 02/20/1510:43 Selenium mg/kg ND 0.051 02/20/1510:43 Thallium mg/kg ND 0.051 02/20/1510:43 Vanadium mg/kg ND 0.051 02/20/1510:43 LABORATORY CONTROL SAMPLE: Parameter 1134163 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 94 80-120 N2 Arsenic mg/kg 2.5 2.5 100 80-120 Beryllium mg/kg .25 0.25 100 80-120 Cadmium mg/kg .25 0.25 98 80-120 Cobalt mg/kg 2.5 2.6 103 80-120 Lead mg/kg 2.5 2.6 102 80-120 Selenium mg/kg 2.5 2.5 98 80-120 Thallium mg/kg 2.5 2.5 100 80-120 Vanadium mg/kg 2.5 2.5 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134164 MS 92237739001 Spike Parameter Units Result Conc. MSD Spike Conc. 1134165 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 2.66 2.66 1.5J 1.7J 56 64 75-125 20 D3,M6, N2 Arsenic mg/kg ND 2.66 2.66 3.1 3.0 92 89 75-125 4 20 D3 Beryllium mg/kg 0.17J .266 .266 0.40 0.43 87 100 75-125 7 20 D3 Cadmium mg/kg ND .266 .266 0.34 0.23J 127 89 75-125 20 D3,M6 Cobalt mg/kg 1.4J 2.66 2.66 4.1 4.0 103 99 75-125 5 20 D3 Lead mg/kg 3.4 2.66 2.66 6.3 6.1 109 104 75-125 3 20 D3 Selenium mg/kg ND 2.66 2.66 2.5J 2.7 68 79 75-125 20 D3,M6 Thallium mg/kg ND 2.66 2.66 2.7 2.5J 87 81 75-125 20 D3 Vanadium mg/kg 8.4 2.66 2.66 11.6 11.1 117 102 75-125 4 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 4101i A n 2c&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: MPRP/22707 Analysis Method: EPA 6020 QC Batch Method: EPA 3010 Analysis Description: 6020 MET Associated Lab Samples: 92237739005 METHOD BLANK: 1132799 Matrix: Water Associated Lab Samples: 92237739005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony ug/L ND 1.0 02/23/1515:55 Arsenic ug/L ND 1.0 02/23/1515:55 Beryllium ug/L ND 0.10 02/23/1515:55 Cadmium ug/L ND 0.10 02/23/1515:55 Cobalt ug/L ND 1.0 02/23/1515:55 Lead ug/L ND 1.0 02/23/1515:55 Selenium ug/L ND 1.0 02/23/1515:55 Thallium ug/L ND 1.0 02/23/1515:55 Vanadium ug/L ND 1.0 02/23/1515:55 LABORATORY CONTROL SAMPLE: 1132800 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 50 46.4 93 80-120 Arsenic ug/L 50 49.2 98 80-120 Beryllium ug/L 5 5.0 101 80-120 Cadmium ug/L 5 4.6 92 80-120 Cobalt ug/L 50 48.8 98 80-120 Lead ug/L 50 48.9 98 80-120 Selenium ug/L 50 51.6 103 80-120 Thallium ug/L 50 49.8 100 80-120 Vanadium ug/L 50 48.8 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1132801 1132802 MS MSD 92237244001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 50 50 50.2 50.3 99 99 75-125 0 20 Arsenic ug/L 2.3 50 50 50.0 49.3 95 94 75-125 1 20 Beryllium ug/L ND 5 5 5.2 5.1 103 102 75-125 0 20 Cadmium ug/L 0.10 5 5 5.1 5.2 99 102 75-125 3 20 Cobalt ug/L ND 50 50 48.2 47.3 96 94 75-125 2 20 Lead ug/L 1.3 50 50 44.1 43.8 86 85 75-125 1 20 Selenium ug/L ND 50 50 48.6 48.0 96 95 75-125 1 20 Thallium ug/L ND 50 50 44.8 44.4 89 89 75-125 1 20 Vanadium ug/L 1.4 50 50 50.3 49.6 98 96 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 4101i A n 9c&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: PMST/3302 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 SAMPLE DUPLICATE: 1146078 92237650001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 9.8 9.4 4 10 SAMPLE DUPLICATE: 1146084 92237650011 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.0 3.9 25 10 D6 SAMPLE DUPLICATE: 1146085 92237760002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.0 1.9 10 10 SAMPLE DUPLICATE: 1146086 35177074004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.9 24.4 2 10 SAMPLE DUPLICATE: 1146087 92238666008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 40.9 43.8 7 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 4101i A n 4c&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: WET/35731 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 SAMPLE DUPLICATE: 1392421 92237760001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.0 4.9 1 10 SAMPLE DUPLICATE: 1392422 92237650009 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.0 5.1 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 4101i A n 9c&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: WETA/43647 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 METHOD BLANK: 1131948 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.1 02/15/1513:20 Sulfate mg/kg ND 50.1 02/15/1513:20 LABORATORY CONTROL SAMPLE: 1131949 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1131951 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1131950 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 485 97 80-120 500 489 98 80-120 92237650001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 555 519 93 80-120 185J 555 901 129 80-120 M1 92237650001 Dup Units Result Result mg/kg ND ND mg/kg 185J 187J Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 4101i A n 6c&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: WETA/43648 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 METHOD BLANK: 1131952 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 02/15/15 13:20 LABORATORY CONTROL SAMPLE: 1131953 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50 49.9 100 80-120 MATRIX SPIKE SAMPLE: 1131955 92237650001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 55.5 53.9 97 80-120 H3 SAMPLE DUPLICATE: 1131954 92237650001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 43 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 4101i A n 99y',�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020344 Pace Project No.: 92237739 QC Batch: WETA/27341 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92237739001, 92237739002, 92237739003, 92237739004 METHOD BLANK: 1120596 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 02/25/15 07:40 LABORATORY CONTROL SAMPLE: 1120597 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 113000 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1120598 1120599 MS MSD 92237746005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 668 6010 5980 5860 6170 86 92 50-150 5 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1120600 1120601 MS MSD 92237746006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 6020 6000 6040 6030 95 95 50-150 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 43 Pac Anr�timll�ervices, Inc. Revision 1 - A n aceAnalyical ��igc&fie. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15020344 Pace Project No.: 92237739 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. E Analyte concentration exceeded the calibration range. The reported result is estimated. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/04/2015 05:11 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 43 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - 4101i A n 9c&�r�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15020344 Pace Project No.: 92237739 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92237739001 2015003909 EPA 3050 MPRP/22732 EPA 6010 92237739002 2015003910 EPA 3050 MPRP/22732 EPA 6010 92237739003 2015003911 EPA 3050 MPRP/22732 EPA 6010 92237739004 2015003912 EPA 3050 MPRP/22732 EPA 6010 92237739005 2015004028 EPA 3010 MPRP/22706 EPA 6010 92237739001 2015003909 EPA 3050 MPRP/22733 EPA 6020 92237739002 2015003910 EPA 3050 MPRP/22733 EPA 6020 92237739003 2015003911 EPA 3050 MPRP/22733 EPA 6020 92237739004 2015003912 EPA 3050 MPRP/22733 EPA 6020 92237739005 2015004028 EPA 3010 MPRP/22707 EPA 6020 92237739005 2015004028 EPA 245.1 MERP/5391 EPA 245.1 92237739001 2015003909 EPA 7471 MERP/5386 EPA 7471 92237739002 2015003910 EPA 7471 MERP/5386 EPA 7471 92237739003 2015003911 EPA 7471 MERP/5386 EPA 7471 92237739004 2015003912 EPA 7471 MERP/5386 EPA 7471 92237739001 2015003909 ASTM D2974-87 PMST/3302 92237739002 2015003910 ASTM D2974-87 PMST/3302 92237739003 2015003911 ASTM D2974-87 PMST/3302 92237739004 2015003912 ASTM D2974-87 PMST/3302 92237739001 2015003909 EPA 9045 WET/35731 92237739002 2015003910 EPA 9045 WET/35731 92237739003 2015003911 EPA 9045 WET/35731 92237739004 2015003912 EPA 9045 WET/35731 92237739001 2015003909 EPA 9056 WETA/43647 92237739002 2015003910 EPA 9056 WETA/43647 92237739003 2015003911 EPA 9056 WETA/43647 92237739004 2015003912 EPA 9056 WETA/43647 92237739001 2015003909 EPA 9056 WETA/43648 92237739002 2015003910 EPA 9056 WETA/43648 92237739003 2015003911 EPA 9056 WETA/43648 92237739004 2015003912 EPA 9056 WETA/43648 92237739001 2015003909 EPA 9060 WETA/27341 92237739001 2015003909 EPA 9060 WETA/27342 92237739002 2015003910 EPA 9060 WETA/27341 92237739002 2015003910 EPA 9060 WETA/27342 92237739003 2015003911 EPA 9060 WETA/27341 92237739003 2015003911 EPA 9060 WETA/27342 92237739004 2015003912 EPA 9060 WETA/27341 92237739004 2015003912 EPA 9060 WETA/27342 Date: 03/04/2015 05:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/13910 ICP/13910 ICP/13910 ICP/13910 ICP/13898 ICPM/9278 ICPM/9278 ICPM/9278 ICPM/9278 ICPM/9273 MERC/5381 MERC/5380 MERC/5380 MERC/5380 MERC/5380 Page 41 of 43 r---114`70napical' Condition Upon Receit Document Nulrib'er: F-CHR-CS-003-rev.' 5 P,age_1 of,2 Issuing AMON& 56 of 52 Pace Huntersville Quality Office Client Name: �)I} Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑_, �C mmercial❑ Other Custody Seal on Cooler/Box Present: El yes F] no Seals intact: ❑ yes ❑ no 1 Packing Material: ❑ Bubble V❑rp ❑ �t a s ❑ None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: 6-111 Blue None El -Samples on ice, cooling process has begun TA AAA K1- !'nrrnn4inn Corrected Cooler Temp.: •C Biological Tissue is Frozen: Yes No Date and Initia s of ers nhxarpmlng contents: r Temp should be above freezing to 6°C Comments: Chain of Custody Present: D41 ©No ❑NIA 1. Chain of Custody Filled Out: o 0No ❑NIA 2. Chain of Custody Relinquished: ❑No ❑NIA 3. Sampler Name & Signature on COC: Ye ❑No ❑NIA 4. Samples Arrived within Hold Time: Yes ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): lives ® ❑NIA 6. Rush Turn Around Time Requested: CIY No ❑NIA 7. Sufficient Volume: s ❑No ❑NIA S. Correct Containers Used: Yes ❑NIA 9, -Pace Containers Used: .lye 7N, ❑NIA Containers Intact: es ONo []NIL 10. Filtered volume received for Dissolved tests Dyes LINO NIA 11. Sample Labels match COC: es ❑No ❑NIA 12. _ ' q- W -Includes dateltimellDlAnalysis Matrix: ,SL All containers needing preservation have been checked. All needing are found to be in es Vy" ❑No ❑NIA 13. containers preservation ❑ NIA compliance with EPA recommendation. No exceptions: VOA, colirorm, TOC, O&G, VVI-DRO (water) ❑Yes No Samples checked for dechlorination: ❑Yes ❑No Q(h 14. Headspace in VOA Vials >6mm): ❑Yes ❑No 15. Trip Blank Present: ❑Yes ❑No N 16. Trip Blank Custody Seals Present [--]yes ❑No NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: DatelTime: Comments/ Resolution: Field Data Required? Y 1 N SCURF Review. IM iDate: �tm `-�� ; 92237739 SRF Review: Date: W Note: Whenever there is a discrepancy affecting North Carolina compliance 1111111111111111111111 samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, 92237739 incorrect containers) Page 42 of 43 Revision 1 - April 2, 2015 Page 51 of 52 p 3 3 rq A ,c � a co S� a w w co W r a y o o a o a e F li O 0 I m t ro Q -'_ 3 " n � y .. 5, A L) Z A? �v iv � y A m � a � 0 b c N N y L N a 3 I-V ,, 1 1!I1s; III y Customer to complolo approprlato columns to right Ca At 61- r l la N 9 �1 d � w � c • 3 'A 'a A S RICU a �Z: m o` a 5 m y a R a 3 Q 3•� m?� y c$ '. M • S � l M r9 N o 'C O 'D G n a 'a j m 3 V v n N m N y a a O O N 0 °c a ry _' � d CL Z x A a p 8 a d � o � � Page 43 of 43 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST -M-al FORM t(--ja-O cJA�L'2`�;: "3-rwcw ArlalyfiGaal L-a-bb-orat-ory DUKE tmb;l 1wC'u7t e- Building @anly I 74&5� mmum: Sm 133W Hayes r-an-V Rid 'r 11 cyF 1 00) Flunt�svilla, N C. 20078 ENERGY, i schNZ-J�- LIPSTRiBUTION A ORJGINAP, to LAB. r1ompki tv balm A (5F.L0j.97S,&24& I SAMPLE FROaRAM Grbuad WWnr i COPY to CLIENT AB Groundwafer Assessmerd - Sol PACE ' Psiort F Leis RCRA x *N*r Tarr Ml F "M i709 r. Duke PO 1142081 HeaMor SmM. Syntarra Mark micnad*. synterra 7--- --------------- 4-ICO OkNmm U'j ACLLE1402 Lr) kn Ln 'J. ra LEOO Is 'cr 0 -L ff W c NCcpspm tp 13 0 v H-algm� .1 Z M imaRaw: men mmffic mccountnia has bman ffifftabilshod and in no Inoc44ed —mb IL own P reslervafives W11-en used MUS1 J)e ki 0 L" m;V accoun&V jtj ddl !; 0 F :6 1`0110wiflo: I%-,fihGr19m1dm obf,,, or a(Me(I withi-n 15 ml n t1tes of sample correct ai-cummi.ric Mr Irl. 0 — — < Uj 4n f1L collection CL I-- .2 U cc iq we USE ONLY MWIX 4COillectioll Information C CL dx E %*bW 15041. Swrll�nt, AmhF a "Sample DescripLion or io P 11�- 'A" Dmv 11 Thim 'E v x rL CL U) lu C. Y-1 6 MOD �- ZnD Jk Zn 14% 4 jr r v BV -L "- WIAW Al, 3b, As. Hot, ft. S. C4 IS" - 44 -0:4 Cr, tk� (At Fe, Ph, No, mtmfrNF1-X1S0., N' T"e WfCU — y PH ly 'Aiilcns:Cl Nfiva 3q. 22 Requested 14 LWr, '; barya -48 Ift