WQ0005910_Monitoring - 07-2023_20230824 (3)

Monitoring Report Submittal
...................................................
Permit Number#* WQ0005910
Name of Facility:* Avoca LLC
Month: * July
Report Information
Type *
G W-59
Confirmation Email Address: *
Name of Submitter: *
Signature:
Date of submittal:
Initial Review
Year:* 2023
Upload Document*
Avoca LLC July 2023 GW-59 Forms.pdf 4.12MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
[e-mail]
Brian M. Conner
Reviewer: Wanda.Gerald
8/24/2023
This will be filled in automatically

Is the project number correct?* WQ0005910
Is the monitoring report accepted?* Yes No
Regional Office* Washington
Reviewer: _anonymous
Review Date: 9/6/2023

GW-59A COMPLIANCE REPORT FORM Permit # WQ0005910
(.Submit one each monitoring period with GIV-59 jarms.)
j
Enter date monitoring results were due. (0
QVILL2L2,J Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GNV-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? 11the answer is "Yes", contact the Regional Office for guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is 'NO'; skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
/
i�1m•+nON. c. - IMv4 1 % - % --t`b
V/
Mv0 S- SS d
fv.w 11 - to 00 0
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
VES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is 'NO'; skip to section 8.
if the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection date for each occ rrence (for the last two years).
►aw►� ram►......; w Mw 11 ZDS MWS -COS
31aa123 -1.�4 313a122- 1%-S 31:0013-VIO 311o1-1z-610 311012 -SZ0 ;13a11'>;- 5Q0
�ti71'e117.- lO.bN 1�111i{21^ 9.slo ►�12�122^-1'�O �1{��11-51.0 1�111i{11-5�0
-1120111- t1.9(p '111t,111^i.0.b-llzol'22^1zo -t11o1z1^Sg0-l1lVlZl-SRO
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES'; describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation maV be
required to determine the impact the waste disposal system is havinq at the review and compliance
boundaries surrounding this facility. Failure to do so ►nay subject the permittee to a Notice of Violation,
fines, and/or penalties.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
C)1 VI —A DI23 7,o23
Signature of Permittee (or Auth rized•Agent) Date
GN1'-59A 12/8/2003

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 1O d2
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: q>L�i pivocc&rw,
TYPE OF PERMITTED OPERATION BEING MONITORED
(Street) 2"11qIsl County Bertie
❑ Lagoon ❑ Remediation: Infiltration Gallery
(CRY) (State) (zip)
0 Spray Field El Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): lv`W '
Date sample collected: —] 1 Sl- 125
FIELD ANALYSES:
If WELL
WAS
Well Depth: 2-1.1ft.
Well Diameter: Z in.
pH 00400: y.S`i units Temp. 00010: Z.L1. I °C
DRY at
Depth to Water Level 62546: %,1 ft. below measuring point
Screened Interval: IS ft.
to Z2
ft. Spec. Cond. 000sa: µMhos
time ofsampling,
Measuring Point is 2 ft. above land surface
Relative M.P. Elevation:
ft.
Odor 000m: Nov\.e.
check
Volume of water pumped/bailed before sampling: JC—
gallons
Appearance C—kC*r .
here:❑
Samples for metals were collected unfiltered: 2YES ❑
NO and field acidified: Ly'1'ES ❑
NO
LABORATORY INFORMATION
Date sample analyzed: Z I :t — i 14b,)L 3
`
Laboratory Name: W Qy 90 ".,k 'Puna. N� eel Certification No.
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead oio51 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 L p y
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 L Q .O y
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 Mjsfl mg/L
Al - Aluminum o11o5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 3.S(o mg/L
Ca - Calcium 00916 2$,Oo
mg/L
Chloride 00940 25b mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #; ,ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? [Yes (1) ❑ No (0)
Specific Conductance 00095 uMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo6lo mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
i i v, A T 1 l (f ..
Permittee (or Authorized Agent) Nanie and Title - Please print or type a
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
•
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC27699-1617 Phone, 919-807-6306
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: p '3� zorti
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: 19gI Livoccr_
TYPE OF PERMITTED OPERATION BEING MONITORED
t lr � '.%.x (Street) Ii ` IL'l gS-1 County Bertie
❑ Lagoon ❑Remediation: Infiltration Gallery
(city) (State) (rip)
N Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL ID NUMBER (from Permit):
Date sample collected: -1 I 11 `2,3
FIELD ANALYSES:
If WELL
WAS
Well Depth: �'aft.
Well Diameter: 2 in.
pH o0400:4.41units Temp. 0001o:Zl0•4 °C
DRY at
Depth to Water Level 82546: tO .'I ft. below measuring point
Screened Interval: 3 ft. to
2)
ft. Spec. Cond. 00094: µ
time ofMhos sampling,
Measuring Point is 2 ft. above land surface
Relative M.P. Elevation: ft.
Odor o0085: hl pnC.
check
Volume of water pumped/bailed before sampling:
gallons
Appearance C.ICaw-
here:❑
Samples for metals were collected unfiltered: ES El
�/
NO and field acidified: I�,YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11-4 " (1��2'�
Laboratory Name: Wa• ?'D"' {�►wc��y};��
Certification No. to
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N oo615
mg/L Pb - Lead oio51 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 2.LA 0 mg/L
Al - Aluminum o11o5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 mg/L
Ca - Calcium 00916 H. 0 Co'Z
mg/L
Chloride oo94o 2.2 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
_#./ATTACH
Lab Report Attached? L�f Yes (1) ❑ No (0)
pecific Conductance 0o095 µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia 00610 O • S o mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese o1o55
ug/L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name land TiUe - Please print or type
GW-59 Rev.3-1-2016
Signature of Perrnittee (or
(Date)

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
161T MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 3l 20'Zy
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: Ob%Al 44oc. cv,,. PA
•
TYPE OF PERMITTED OPERATION BEING MONITORED
(Street) t—
2'1 Q S'7 County Bartle
❑ Lagoon ❑ Remediation: Infiltration Gallery
(C ) (State)
(Zip)
0 Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:AVOca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): MW "'
Date sample collected: 7 ( t%I23
FIELD ANALYSES:
If WELL
WAS
Well Depth: 12) ft.
Well Diameter: 2 in.
pH 004001-411 units Temp. 00010:2n• oC
DRY at
Depth to Water Level 82546: 10 •S ft. below measuring point
Screened Interval:ft. to 1 Q> ft.
Spec. Cond. 00094: µMhos
time ofsampling,
Measuring Point is 2 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: jJ onG
check
Volume of water pumped/bailed before sampling:
5
gallons
Appearance Cledy-
here:❑
Samples for metals were collected unfiltered: ES ❑
NO and field acidified: &?"'YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 'L 1\2 — -11 tlbl 23
LaboratoryName: (tea,., po,^A
And13heei( Certification No.
PARAMETERS NOTE: Values should reflect
dissolved and
colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620 .�j2
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P 00665 2. • 1 �I
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 4 S D
mg/L
Al - Aluminum oilo5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 . 2
mg/L
Ca - Calcium 00916 S� . l07
mg/L
Chloride 00940 l
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils o0552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. !#TTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? S2' Yes (1) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia oo6lo 4).79
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese oio55
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
(Date)
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
•
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 10 si 29'2
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: 00'—k1 0-"OG.c" e�./w, Q06A
TYPE OF PERMITTED OPERATION BEING MONITORED
�-k. \ 1 (Street) C.r 27 `i S? County Bertie
[I Lagoon ❑Remediation: Infiltration Gallery
(city) (State) (Zip)
0 Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): MW—
Date sample collected: —1 1 X%las
FIELD ANALYSES:
If WELL
WAS
Well Depth: Zft.
Well Diameter: 2 in.
pH ooaoo:5.44 units Temp. 0001o:27.R °C
DRY at
Depth to Water Level 82546: % .q ft. below measuring point Screened Interval: to
23 ft.
Spec. Cond. 000sa: µMhos
time of
Measuring Point is 2 ft. above land surface
_eft.
Relative M.P. Elevation: ft.
Odor oo085: None,
sampling,
check
Volume of water pumped/bailed before sampling: 5'
gallons
Appearance C.lCAW-
here:❑
Samples for metals were collected unfiltered: NrYES
❑ NO and field acidified: &KYES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: "( �1'Z �I�1$12,3
Laboratory Name: Wg4 gos^+ AY\a�W+1
II
IL661 Certification No.0
PARAMETERS NOTE: Values should reflect dissolved
and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 S. VA
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 Q , Q—j
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 23 mg/L
AI - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 S mg/L
Ca - Calcium 00916 ly (o .LiS 3
mg/L
Chloride oo94o Z mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total m34
ug/L
Grease and Oils 00552 mg/L
Cu - Copper o1042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method�TTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia o0610 DA mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH38s N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
OWN
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: to13112,0214
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: 'ONAI pt'jorux r-uw,-► RoaCX
TYPE OF PERMITTED OPERATION BEING MONITORED
mtyym K'. % (street) iJ L -Z-19
? County Bertie
❑ Lagoon ❑ Remediation: Infiltration Gallery
(at (state) (zip)
X Spray Field ❑ Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): M` W — I 0
Date sample collected: —1l %\�i.3
FIELD ANALYSES:
If WELL
WAS
Well Depth: 20 ft.
Well Diameter: 2- in.
pH 00400:3,(oS units Temp. 000io: Z(v •3 °C
DRY at
Depth to Water Level 82546: ft. below measuring point
Screened Interval: ft. to 20 ft.
Spec. Cond. 0009a: µ Mhos
time of
sampling,
Measuring Point is 2. ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: Nor,le—
check
Volume of water pumped/bailed before sampling: 5
gallons
Appearance C-lt4✓
here:❑
Samples for metals were collected unfiltered: 2 YES ❑
NO and field acidified: S YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: �[�\Z ^ \� 1a-�
Laboratory Name: {�ay �p �"C�
,/�
t"�'y
tt
\M i Call Certification No.
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead olo51 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 -"� ,�{2.
mg/L
Zn -Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 L 0 .01A
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 Lk20 mg/L
AI - Aluminum oilo5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 •Cj —L mg/L
Ca - Calcium 00916 23 •yg 5
mg/L
Chloride 00940 Sq mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug1L
Grease and Oils oo552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron o1045
ug/L
(Specify test and method #.ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? 9 Yes (1) ❑ No (0)
pecific Conductance 00095 µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia 00610 0 AS mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen: NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Aqent) Nanie and Title - Please print or type
GW-59 Rev.3-1-2016
Siqnature of Permittee

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:[phone]
FACILITY INFORMATION Please P6nt Clearly or Type
PERMIT Number: Expiration Date: l0 3
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: '0% A"Np c4 1Favm Oac]
TYPE OF PERMITTED OPERATION BEING MONITORED
i 1(Street; Z'Tq 5-7 County Bertie
❑ Lagoon ❑Remediation: Infiltration Gallery
(CRY) (S;_-fci (zip)
X Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone* 252-482-2133
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): (�—
Date sample collected: r1��� 123
FIELD ANALYSES:
WAS
Well Depth: 2 Oft.
Well Diameter: Z, in.
pH 00400:(0-`` units Temp. 000lo: 2. 2, °C
DRY at
Depth to Water Level 82546: ft. below measuring
p �_ g point
Screened Interval: 3 ft. to ?—oft.
Spec. Cond. 0oosa: µ Mhos
time of
Measuring Point is 2 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: N O h e.
sampling,
check
Volume of water pumped/bailed before sampling: S
gallons
Appearance [Lett'-
here:
Samples for metals were collected unfiltered: YES ❑
_/
NO and field acidified:LK YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: "L�t�—�[l�$���
Laboratory Name: WeA�,^+
Ar41y
� }'*Ca Certification No.
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead o1051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 p -2tD
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 Q �'�
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 (psay © mg/L
Al - Aluminum o1105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 mg/L
Ca- Calcium oo916 1 S . S b S
mg/L
Chloride oo94o 2`-1 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total o1o34
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #./ATTACH LAB REPORT.)
Sulfate oo945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? S� Yes (1) ❑ No (0)
pecific Conductance o0095 µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia 00610 1 O -Tmg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH38s N; Ammonia Nitrogen, Total)
Mn - Manganese o1o55
ug/L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug1L
method #
For Remediation Systems Only • • •
I certify that, to the best of my knowledge and belief. the information submitted in this report is true. accurate. and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information. including the possibility of fines and imprisonment for knowing violations.
Permittee (or Authorized Agent) Naine and Title - Please print or type Signature of Permittee (or Authori. ed Agent)
GW-59 Rev.3-1-2016

AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. Box 129
MERRY HILL, NC 27957
Effluent Well #5
PARAMETERS
BOD, mg/I
1640
Total Suspended Residue, mg1l
224
Ammonia Nitrogen as N, mg/I
0.42
0.42
Total 1geldald Nitrogen as N,mg/l
73.10
Nitrate+Nitrite as N, mg/I (cite)
<0.04
Nitrate Nitrogen as N, nngtl
<0.04
<0.04
Nitrite Nitrogen as N, tug/l
<0.02
Total Phosphorus as P, mgll
7.70
<0.04
Total Organic Carbon, mg/l
3.56
Bromide, mg/l
TESTED
TESTED
Chloride, mg/l
69
28
Total Dissolved Residue, mg/l
2000
550
Calcium, ug/l
10666
28854
Magnesium, ugA
2311
Sodium, ug/l
178970
Sodium Adsorption Ratio (calc)
13.0
Total Nitrogen, mgA (calc)
73.10
Drinking Water IDi 37715
Wantetfater XD, 10
PHONE [phone]
FAX [phone]
ID#: 132
DATE COLLECTED: 07/11/23
DATE REPORTED : 08/11/23
REVIEWED BY:
Well #7
Well #8
Well #9
Analysis
Method
Date
Analyst Cade
07111/23
BNC 5210E-16
07/12/23
KJH 2540D-I5
0.50
0.79
0.48
07/12/23
AMC 350A 112-93
07/18/23
TRJ 351.2 112-93
353.2 R2-93
1.45
0.72
3,24
07112/23
TRJ 353.2 112-93
07/12/23
TRJ 353.2 112-93
0.11
2.17
0.07
07/18/23
TRJ 365.4-74
4,51
19.20
1.15
07/17/23
HM�Yf 531OC-14
TESTED
TESTED
TESTED
22
17
21
07/17/23
ADR 4500CLB-ll
240
450
230
07/13/23
JMS D5907-13
4062
8667
46433
07/14/23
MTM EPA200.7
07/14/23
MTM EPA200.7
07/14/23
i4lTYt EPA200.7
td0 [ E Any result listed ahove os "ThS ITD" was sub -contracted to another lahoratory flre corresponding resins are attached

Waypointw
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NO 27858
AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, MC 27957
Drinking Water lot 37115
Wastewater IDi 10
PHONE [phone]
FAX [phone]
ID$: 132
DATE COLLECTED: 07/11/23
DATE REPORTED : 08/11/23
REVIEWED BY:
Well N10
Well Nil
Analysis
Method
PARAMETERS
Date Analyst
Cade
Ammonia Nitrogen as N, mg/I
0,43
10.78
OVUM
AMC
350.1 112-93
Nitrate Nitrogen as N, mg/l
7.42
0.20
07/12/23
TRJ
353.2 R2-93
Total Phosphorus as P, mg1l
<0.04
0.17
07/18/23
TRJ
365.4-74
Total Organic Carbon, mgA
1,54
11.80
07/17/23
HA-1M
531OC-14
Bromide, mg11
TESTED
TESTED
Chloride, mg/I
59
24
07/17/23
ADR
4500CL13-11
Total Dissolved Residue, mg/i
420
680
07/13/23
JMS
D5907-13
Calcium, ag/l
23495
15565
07114123
NITM
EPA200.7
NOTE: Any result Iistcd above is "TCSTEJ)" NNns sub -contracted to another taborntory. I he corresponding results me attached

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Y
PARAMETERS/TESTS
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® I Laboratories LLC
a member of The GEL Group i•::
July 14, 2023
Andrea Brownfield
Waypoint Analytical, LLC
2790 Whitten Road
Memphis, Tennessee 38133
Re: Routine Analysis
Work Order: 629087
Dear Andrea Brownfield:
PO Box 5rt712 ( I %2NI I
2040233a apeRold l.ianr>::n SC29-107
P M 556.e171
i M766.1178
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 13, 2023. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Test results for NELAP or ISO 17025 accredited tests are verified to meet the requirements of those standards,
with any exceptions noted. The results reported relate only to the items tested and to the sample as received by
the laboratory. These results may not be reproduced except as full reports without approval by the laboratory.
Copies of GEL's accreditations and certifications can be found on our website at www.gel.com.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 1614.
Sincerely,
Jordan Melton for
Delaney Stone
Project Manager
Purchase Order: GELP22-0230
Enclosures
gel.com
problem solved

Table of Contents
Case Narrative..................................1
Chain of Custody and Supporting Documentation.4
Laboratory Certifications ......................7
General Chem Analysis ..........................9
Case Narrative .............................10
Sample Data Summary ........................13
Quality Control Summary...................21
Instrument QC Data Summary................24
Ion Chromatography Raw Data...............26

Case Narrative
Page 1 of 62 SDG: 629087

Receipt Narr ative
for
Waypoint Analytical
SDG: 629087
July 14, 2023
Laboratory Identification:
GEL Laboratories LLC
2040 Savage Road
Charleston, South Caiohna 29407
[phone]
Summary:
Sample receipt: The samples airived at GEL Laboiatones LLC, Charleston, South Catolina on July 13, 2023 for
analysis The samples were delivered with piopei chain of custody documentation and signatures All sample
containers anived without any visible signs of tampering of breakage. There wete no collect times on the
containeisieceived
Sample Identification: The laboratory received the following samples.
Laboratory iD Client ID
629087001
Effluent
629087002
Well #5
629087003
Well #7
629087004
Well #8
629087005
Well 49
629087006
Well #10
629087007
Well #11
Case Nari ative:
Sample analyses were conducted using methodology as outlined in GEL's Standard Operating Pioceduics Any
technical of admijustiative problems dining analysts, data review, and reduction are contained in the analytical
case narratives in the enclosed data package.
Page 2 of 62 SDG: 629087

The enclosed data package contains the following sections- Case Narrative, Chant of Custody, Cooler Receipt
Checklist, Data Package Qualifier Definitions and data fiom the fol[owmg fractions- General Chemistry
Jordan Melton foe
Delaney Stone
PtoJect Managet
I
Page 3 of 62 SDG: 629087

Chain of Custody and
Supporting
Documentation
Page 4 of 62 SDU: 629087

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Laboril0fies uc
SAMPLE RECEIPT & REVIEW DORM
CIIcnS:
SDC/ARICO(:A1b kUrder.
Hcct•ived Ilv: VFi
Dale Itecclve
Gr. prii. u.
FedExExpress FedEx Ground UPS 'eldSerices Courier 011ier
C:u i ier and Tracking \Umber
S,nIrted llaranl lnfonmrlkn
y
•If\et Counts >Mclinjon samples not mekedcontact the RxliAion Safety Group for futlxr imestiynim.
Lard Class Shipped: UNII:
A)Shi . •d as a DOT Ilazrrdws?
If UN-1910,1s the Radioactive S)dptrenl Survey Cornpliam? Yes_ No_
R) Did the clientdesipnaleIre saniplesamtobe
10,
CDC ootatkinorranlioardveslickers meootaluersequal dientdeslpinition.
received as Wdttmcilve?
CPJI/nR/r
erved, H
OaeimirnNet CouObss):
C)DiddneRSOdsssifythesvrrpluas
_
(lacdRed as: Rad 1 Rad 2 Had 3
-
radiokdve?
upratioo or bazard labels an containers equal client desdVedmi.
D) Did the client ticsipuic sainples arc huardous?
If D or E is )rs, select Hazards below.
PCR's Fl.vnmible Foreign Soil RCRA Asbestos Ber)Ilium Other.
Gl Did the lt50 idenif flbk hazards?
Sample Receipt Criteria
Z
Commencs/Qualificls (Regldred rorNon•Conforming Items)
Shipping containers received Intact and
(
CinleApplca(k: Stahbrokm DamazeJcvnLjer LeabriSconlainett Odrer(descnbc)
1
scaled?
V
CtuinofaatodydocurrienuIncluded
CirdeApplkatk: (lienc*nueteJ=JprmiJedCOC COC createJupmreceipt
Z
with shipirent?
, ., ---7)
Pmseratiou,Nled : Vet Ice I Packs Dryke None Other. \1
3
Samples requiring cold preservation
v
-all temperature are recer Celsius TEMP:
within (O q 6 do C)7 e
Daily check perforned and passed on IR
TempemtireDevice Serial 9: tR2-11
4
temperature gun?
Secondary Temperature Device Serial I (1f Applicable):
Circle Aptikatir Seatstrokm Dama6Ncmuner L: atinz contain:r Oiheridt nter
S
Sample containers intact and sealed?
Samples requiring chemical preservation
S:unpklD'sand Cmr.iners Attu w
6
y Proper PH?
If Presenatim oJ,ld I.as:
If es, are Dicores or Sod Kits present for solidi? Yes_ No_ NA_(1(5es, lake to VOA Freezell
Do any samples require Volatile
liquid VIJA vials etraail acid preservation? Yes_ Nu_ NA_(If unbwun, select No)
Are liquid VOA vials free of heath n Yes No NA_
7
AM1II)YIS?
Sample ID's and emuintrs affected:
1 D's and tests affected
8
Samples received within holding time?
Sample ID's on COC notch ID's on
ID's and containers affected:
9
boules?
.10.
Date_&-liaron00C ltuldldalc&linn_
—
nrcleApplicable: Nodioom times Nosn ners CDC inbAing info Other dmb ese
on bottles?
Number of containers received malch
Circle Applicable: No mnuiner count on COC Othertdeserih )
I I
number indicated on COC?
12
Art sauplt containersidcnlifiahlc as
GEL provided by use of Gf.I. labels? ?
C04C form is properly sigrzel in
Circle Applicable: Not relinquished (Mier ide. mbe)
13
relin)tdsixtUreceitY(I eCclions?
C%)Iwmns (Use Con tiutllion Form if needed):
?J
PM (tar P\L1) rceicn- IniriaLs __J ll Date 1 �I �-=C SPagc L or
GL-CHL-SR-001 Rey
Page 6 of 62 SEIG: 629087

Laboratory
Certifications
Page 7 of 62 SDG: 629087

List of current GEL Cei tifications as of 14 July 2023
State Cm tiflcation
Alabamd
--Alaska --
- Alaska Drinking \Nate€- ----
Arkansas
42200
17-018 -
SC00012 — -
88-0651
_ 42D0904046
2940
CLFA
Cahfoinia
Colorado _
Connecticut
SC00012
PH-0169
Dol) I'I,AP/ ISO17025 A2LA
256701
Florida NELAP
E87156
Foietgn So€ls Pe_nnit_
P330-15-00283, P330-15-00253
Georgia _ T
SC_ OOO12
967
_ _ SC00012
SC00012
Georgia SDWA
Hawaii -
Idalio
_
Illinois NELAP
200029
C-SC-OI
Indiana
Kansas NELAP
E-10332
90129
Kentucky SDWA
_
Kentucky Wastewater
90129
Louisiana Drinking Water
_ Louisiana NELAP
Maine -
Maryland
Massachusetts
Massachusetts PFAS Approv
Michigan
Mississippi
Nebraska
- - _ Nevada - New Hampshire NELAP__
New Jersey NELAP
New Mexico
--- New Yoi k NELAP
North Carolina
North Carolina SDWA _
North Dakota
LA024 -
03__046 (A13390.4)_
2019020
- 270
Nf-SCOl2
Letter
9976
SC00012
NE-OS-26-13 _
SC000122023-4
- 2054
SC002
SC00012
11501
- --- _ 233 - --
45709
R-158
-- 2022-160
Pennsylvania NELAP -
68-00485
Puerto Rico
SC00012
_
S Carolina Radlocheln
10120002
Sanitation Districts of L
_
9255651
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
_
T104704235-22-20
Utah NELAP
SC000122022-37
Vetmont VT87156
Virginia NELAP 460202 --
Washington -- -- C780
Page 8 of 62 SDG: 629087

General Chem Analysis
Page 9 of 62 SDG: 629087

Case Narrative
..O of "S-2' 6 0 8

General Chemistry
Technical Case Narrative
Waypoint Analytical
SDG #: 029087
Product: Ion Chronnatogiaphy
Analytical Method: SW846 9056
Analytical Procedure: GL-GC-E-086 REV# 32
Analytical Batch: 2458814
The following samples were analyzed using the above methods and analytical piocedute(s)
GEL Sample a ID#
Client Sample Identification
629087001
Effluent
629087002
Well #5
629087003
Well #7
629087004
Well #8
629087005
Well #9
629087006
Well #10
629087007
Well 411
1205457779
Method Blank (MB)
1205457780
Labotatory Control Sample (LCS)
1205457781
629044008(NonSDG) Sample Duplicate (DUP)
1205457782
629044008(NoiiSDG) Post Spike (PS)
The samples in this SDG wete analyzed on an "as ieceived" basis
Data ummar
All sample data piovided in this tepoit met the acceptance criteria specified in the analytical methods and
piocedutes foi initial calibiation, continuing calibiation, instrument contiols and ptocess contiols where
applicable, with the following exceptions.
Technical Information
Saniple Dilutions
The following samples 1205457781 (Non SDG 629044008DUP), 1205457782 (Note SDG 629044008PS),
629087001 (Effluent), 629087002 (Well #5), 629087003 (Well 417), 629087004 (Well #8) and 629087007 (Well
#11) were diluted because taiget analyte concentrations exceeded the calibiation range. Samples 629087001
(Effluent), 629087002 (Well #5), 629087003 (Well #7), 629087004 (Well #8) and 629087007 (Well 911) weie
drhited based oil historical data. Dilutions may be iequited foi many reasons, including to minimize matrix
interferences of to biirig overiainge taiget analyte concentrations into tine lineat calibiation iange.
629087
Analyse
001
1
002
1
003
004
007
Bromide
20X
20X
20X
20X
20X
Co tification Statement
Wheie the analytical method has been peifonned under NELAP ceitifieation, the analysis has met all of the
requneinents of the NELAC standard unless otherwise noted in the analytical case naitative.
Page 11 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www gel corn
Qualifier Definition Report
for
WAYP001 Waypoint Analytical
Client SDG. 629087 GEL Wotk Order- 629087
The Qualifiers in this report ai a defined as follows:
* A quality contiof analyte iecoveiy is outside of specified acceptance criteria
U Analyte was analyzed foi, but not detected above the MDL, MDA, MDC of LOD.
Review/Validation
GEL iequues all analytical data to be verified by a quahfied data ieviewet. In addition, all CLP-like deliverables
iecetve a thud level ieview of the fiactional data package
The following data validatoi verified the information presented i❑ this data lepoit
Signature: #�A� Name: Aubrey Kingsbury
Date: 09 AUG 2023 Title: Analyst II/Data Validator/Te,
Page 12 of 62 SDG: 629087

Sample Data Summary
Page 13 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www gel corn
Cert flcate of Al aCysls
Company:
Waypoint Analytical, LLC
Address :
2790 Whitten Road
Memphis, Tennessee 38133
Contact
Andrea Biownfield
Ptoaeet•
Routine Analysis
Client Sample ID Effluent
Sample ID.
629087001
Matt Ix.
Giound Water
Collect Date
I I-JUL-23 10 00
Receive Date
13-JUL-23
C011ectoi.
Client
Paianieter Qualifier Result DL RL
Ion Cbiomatogiaphy
SW846 9056 Bromide, Liquid "As Received"
Report Date August 9, 2023
Project WAYP00122
Client ID• WAYP001
Units PF DF Analyst Date Time Batch Method
Bromide 780 134 400 mg1L 20 1LD1 07/13/23 1912 2458814
The following Analytical Methods were petformed:
Method _ _- _ Desciiption _ Analyst Comments _ _
I SW846 9056
Notes:
Column treaders are deftnecl as follows
DF. Dilution Factoi Le/LC. Cittical Level
DL Detection Limit PF Prep Factot
MDA Minimum Detectable Activity RL Repoitmg Limit
MDC Minimum Detectable Concentration SQL Sample Quantitation Limit
Page 14 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www gel corn
Certificate of Analysis
Company
Waypoint Analytical, LLC
Address:
2790 Whitten Road
Memphis, 'Tennessee 38133
Contact
Andiea Biownfteld
Project•
Routine Analysis
Client Sample ID:
Well #5
Sample ID•
629087002
Matiix•
Giound Watei
Collect Date
l l-JUI. 23 10.10
Receive Date
13-JUL-23
Collectoi.
Client
Palametei QuahBei Result
DL RL
Ion Chiomatogiaphy
SW846 9056 Btomide, Liquid "As Received"
Bromide 5 14
1 34 400
The following Analytical Methods were peifoinied
Method _ Desci iption
-
1 SW946 9036
Notes:
Column headers are cleJhied as follows
DF• Dilution Factor
Lc/LC, Critical Level
DL Detection Linut
PF Ptep Factoi
MDA Minimum Detectable Activity
RL• Repoititig Limit
MDC• Minimum Detectable Conceiihatron
SQL, Sample Quantitation Limit
Repoi t Date August 9, 2023
Pio}ect• WAYP00122
Client ID: WAYP001
Units PF DF Analyst Date Time Batch Method
m9/L 20 JLDI 07/13/23 1943 2458814 1
Analyst Comments
Page 15 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www gel corn
Certificate of Analysis
Report Date. August 9, 2023
Company
Waypomt Analytical, LLC
Addiess
2790 Whitten Road
Memphis, Tennessee 38133
Contact,
Andiea Biownfield
Pioject
Routine Analysis
Client Sample ID
Well #7 Project WAYP00122
Sample ID
629087003 Client 113• WAYP001
Mati ix
Gi ound Watet
Collect Date:
I I-JUL-23 11.25
Receive Date
13-JUL-23
Collector
Client
Paiametei Qualifier Result
_ DL RL
Ion Chromatography
SW846 9056 Biomide, Liquid "As Received"
Bromide 137
134 400
The following Analytical Methods were performed_
Method- Descii tio_n_ _
I SW846 9056
Notes:
Colunui hewless are defined as follows
DF• Dilution Factor
Lc/LC- Ctttical Level
DL• Detection Limit
PF. Prep Factor
MDA Murnnum Detectable Activity
RL. Reporting Limit
MDC. Minimum Detectable Concentiatton
SQL. Sample Quantitation Limit
Units PF DF Analyst Date Time Batch Method
mg/L 20 JLDI 07/13/23 2014 2458914
Angst Comments _
Page 16 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www gel corn
Certificate of'Analysis
Company.
Waypoint Analytical, LLC
Addiess
2790 Whitten Road
Memphis, Tennessee 38133
Contact
Andiea Biownfield
Project:
Routine Analysis
Client Sample ID
Well #8 1110ject.
Sample ID
629087004 Client ID
Matrix.
Giound Watet
Collect Date-
11-JUL-23 11.10
Receive Date-
13-JUL-23
Collector
Client
Paiameter Qualifiei Result
lon Chi omatogi aphy
SW846 9056 Biomide, Liquid "As Received"
Bromide 459
The following Analytical Methods were pei foi need:
Method Desw iption
t Sw846 9056
Notes:
Column heaclei s aie defined as lollows
DL RL
1 34 400
DF Dilution Factoi Lc/LC. Ciitical Level
DL• Detection Limit PF Piep Factoi
MDA• Minimum Detectable Activity RL Repotting Limit
MDC. Minimum Detectable Concentiation SQL Sample Quantitation Lnmit
Report Date- August 9, 2023
WAYP00122
WAYP001
Units PF DF Analyst Date Time Batch Method
mg/L 20 JLD I 07/ 13/23 2046 2458,914 t
Analyst Comm sits
Page 17 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www gel cam
Certificate of Analysis
Company
Waypoint Analytical, LLC
Addiess
2790 Whitten Road
Memphis, Tennessee 38133
Contact'
Andrea Biownfteld
Pioject
Routine Analysis
Client Sample ID
Well #9
Sample ID
629087005
Matt ix
Ground Watei
Collect Date:
I I-JUL-23 10 55
Receive Date-
13-JUL-23
Collecto€
Client
Paiametei _ Qualifiei Result
Ion Chiomatogiaphy
SW846 9056 Biomide, Liquid "As Received"
Bromide U ND
The following Analytical Methods were pet formed:
MethodDesciiption
1 SW846 9056
Notes:
Column headers ai e defined as follows
Repot Date August 9, 2023
11110Ject• WAYP00122
Client ID. WAYP001
DL RL Units TPF DF Analyst Date Time Batch Method
00670 0200 mg/L
DF• Dilution Facto€ Lc/LC. Cittical Level
DL• Detection Limit PF Prep Facto€
MDA. Minimum Detectable Activity RI, Repoiting Limit
MDC. Minimum Detectable Concentration SQL Sample Quantitation Limit
1 JLDI 07/13/23 2117 2458814 1
Analyst Comments _
Page 18 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www gel com
Cel t1fiCRIe oJ Al alysls
Company .
Waypoint Analytical, LLC
Address.
2790 Whitten Road
Memphis, Tennessee 38133
Contact
Andrea 13townfield
Project.
Routine Analysts
Client Sample ID
Well #10 Project
Sample ID.
629087006 Client ID:
Matrix.
Ground Water
Collect Date,
11-JUL-23 1120
Receive Date-
13-JUL-23
Collectot
Client
Parameter Qualifiei Result
Ion Chromatography
SW846 9056 Bromide, Liquid "As Received"
13ronude 0 229
The following Analytical Methods were pe►foimed-
Method Description
l SW846 9056
Notes:
Column headers me defined as follows
DL RL
00670 0200
DF• Dilution Factoi Lc/LC- Ctitical Level
DL• Detection Limit PF. Piep Factor
MDA- Minimum Detectable Activity RL Reporting Limit
MDC. Mrnrmum Detectable Concenttation SQL Sample Quantitatron Limit
Repoit Date: August 9, 2023
WAYP00122
WAYP001
uUnits PF DF Analyst Date Time Batch Method
mg/L I JLD1 07/13/23 2251 2458814 1
Analyst Comments
Page 19 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www gel com
Certl f carte o f'Analysis
Company Waypomt Analytical, LLC
Address • 2790 Whitten Road
Memphis, Tennessee 38133
Contact. Andrea Bromfield
Piojeet Routine Analysis
Sample ID
629087007
Matrix-
Ground Water
Collect Date.
I I-JUL-23 09 50
Receive Date
13-JUL-23
Collector
Client
Parameter Qualifier Result
DL _RL
Ion Chromatography
SW846 9056 Bromide, Liquid "As Received"
Bromide 9 18
134 400
The following Analytical Methods were per formed
_
Method _ Descii tioin
- - -- - -----
1 SW846 9056
Notes:
Column headets are dgfined as rollowT
DF Dilution Factor
Lc/LC: Critical Level
DL Detection Limit
PF. Prep Factoi
MDA Minimum Detectable Activity
RI. Reporting Lit -nit
MDC• Minimum Detectable Concentiation
SQL Sample Quantitation Limit
Report Date. August 9, 2023
Project. WAYPOO122
Client ID WAYPOOI
Units PF DF Analyst Date Time Batch Method
nig/L 20 JLD1 07/13/23 2323 2458814 1
Analyst Comments
Page 20 of 62 SDG: 629087

Quality Control
Page 21 of 62 SDG: 629087

GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www gel com
QC ,Slll)?lt?Clly
Waypoint Analytical, LLC ReDor t hate: August 9, 2023 2
2790 Whitten Road Page 1 or
Memphis, 'Tennessee
Contact: Andrea Brownfield
Workordet: 629087
Parninanie _ --- - _ NOM Sample QuaI _QC Units RPD% REC% Range _ Anlst Date Time^
lon Chm oinatogi aphy
Batch 2458814 --- - — - — — -
QC1205457781 629044008 DUP
Bromide U ND tJ NIA nig/I, N/A JLDI 07/13/23 18 09
QC1205457780 LCS
Bromide 125 1 27 nig/L 102 (90%-110%) 07/14/23 00 25
QC1205457779 MB
Bromide U ND mg/L 07/13/23 23 54
QC1205457782 629044008 PS
Bromide 125 U ND 129 mg/L 103 (90%-1 10%) 07/13/23 18 40
Notes:
The Qualifiers in this report are defined as follows
U Analyte was analyzed for, but not detected above the IvIDL, MDA, MDC or LOD.
J Value is estimated
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Ii Analytical holding time was exceeded
< Result is less than value repotted
> Result is greater than value repotted
h Pieparation or preseivation holding time was exceeded
R Sample results ate rejected
Z Paint Filter Test --Particulates passed through the 61tei, however no free liquids were observed
d 5-day BOD--The 2 l depletion requirement was not met for this sample
^ RPD of sample and duplicate evaluated using 1/-RL Concentrations are <5X the RI, Qualifier Not Applicable for Radmocliemtsity
N/A RPD or %Recovery limits do not apply
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Nanative, Data Summary package, or Project Matiager concerning this qualifier
E General Chemistry --Concentration of the target analyte exceeds the instrument calibtatton range
Q One or more quality control criteria have not been met Refer to the applicable narrative or DER
NI See case narrative
Page 22 of 62 SDG: 629087

Wot koi der: 629087
Pat mname
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www gel com
QC S11111111aly
Page 2 of 2
NOM _.Sample Qiial -YQC Units R1'D% RRC% ___ Ran a Anlst_ _Date Time
R Per section 9 3 4 1 of Method 1664 Revision B, due to inatux spike recovery issues, this result may not be reported or used foi tegulatory compliance
pin poses
B The target analyte was detected in the associated blank
e 5-day BOD--Test replicates show more than 30% difference between high and low values The data is qualified per the method and can be used foi
reporting purposes
J Sec case narrative for an explanation
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone by a factor of 4 or more of %RPD not applicable
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract requited detection limit (RL) In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result
* Indicates that a Quality Control parameter was not within specifications
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations
Where the analytical method has been peiforined tmdei NELAP ceitification, the analysts has met all of the
requtiements of the NELAC standaid unless qualified on the QC Summary
Page 23 of 62 SDG: 629087

Instrument QC Data
Summary
Page 24 of 62 SDG: 629087

INITIAL AND CONTINUING CALIBRATION VERIFICATION
Report Run Ow 09-AUG-2023 15 16
GEL Laboratories LLC
Contract: WAYP00122
SDG #: 629087
Ion Chromatography
Method: SW846 9056
Instrument: DIONEX ICS-1600 Ion Chromatograph (1C9)
Parmname• Bromide Concentration Units:mg/L
Sample Type
Run Date
Data File
Result
Nominal
Recovery
Limits
Within Limits
ICV
13-JUL-2023 08:22:00
13-JUL-2023 15.32 00
230713
230713
1.3428
1.25
107
(90%.110%)
Yes
CCV
19068
1.2574
1,9379
1.876
1.25
102
101
1(90%-110%)
(90°k-110%)
Yes
CCV
CCV
13-JUL-2023 21.48 00
2307i3
Yes
14-JUL-2023 03 02,00
230713
1 876
103
(90%-110%)
Yes
Sample Type Run Date Data File Result Limits Within Limits
ICB 13-JUL-202308:53:00 230713 l 0 02 Yes
CCB 13-JUL-2023 16-03.00 230713 0 02 Yes
CCB 13-JUL-2023 22.20 00 230713 -- 0 02 Yes
CCB 14-JUL-2023 03.34 00 230713 0 02 Yes
Page 25 of 62 SDG: 629087

Ion Chromatography
Raw Data
Page 26 of 62 SDG: 629087

This is runlog
for Sequence 230509.seq for IC9
Sample ID
Run Time
Batch
Dilution
Dataset
Analyst
BLK
05/09/23
09:50
1
230509
JLDI
ICAL-06
05/09/23
10:20
1
230509
JLDI
ICAL-05
05/09/23
10:50
1
230509
JLDI
ICAL-04
05/09/23
11 19
1
230509
JLD1
TCAL-03
05/09/23
11:49
1
230509
JLD1
ICAL-02
05/09/23
12:19
1
230509
JLD1
ICAL-01
05/09/23
12:49
1
230509
JLD1
ICAL-06
05/09/23
10 2.0
1
230509
JLDI
ICAL 05
05/09/23
10:50
1
230509
JLD1
ICAL-04
05/09/23
11:19
1
230509
JLD1
ICAL-03
05/09/23
11 49
1
230509
JLDI
ICAL-02
05/09/23
12:19
1
230509
JLDI
ICAL-01
05/09/23
12:49
1
230509
JLDI
ICV
05/09/23
13:19
1
230509
JLDI
ICB
05/09/23
33 49
1
230509
JLDI
1205399388
05/09/23
14:53
2426073
1
230509
JLD1
1205399389
05/09/23
15:23
2426073
1
230509
JLD1
620226001
05/09/23
15:53
2426073
1
230509
JLDI
620226009
05/09/23
16.22
2426073
1
230509
JLD1
1205399390
05/09/23
16.52
2426073
1
230509
JLDI
1205399391
05/09/23
17:22
2426073
1
230509
JLDI
620226027
05/09/23
17:52
2426073
1
230509
JLDI
620226028
05/09/23
18:22
2426073
1
230509
JLDI
620226001
05/09/23
18 52
2426073
20
230509
JLDI
620226009
05/09/23
19:22
2426073
10
230509
JLDI
CVH
05/09/23
19-52
1
230509
JLD1
CCB
05/09/23
20:21
1
230509
JLDI
1205399390
05/09/23
20.51
2426073
10
230509
JLDI
Page 27 of 62
SDG: 629087

1205399391
05/09/23
21 21
2426073
10
230509
620374076
05/09/23
21:51
2426460
100
230509
blk
05/09/23
22:21
1
230509
1205399986
05/09/23
22:51
2426460
1
230509
1205299987
05/09/23
23:21
2426460
1
230509
620909005
05/09/23
23:51
2426460
1
230509
JLDI
JLDI
JLD1
JLDI
JLD1
JLDI
Page 28 of 62 SDG: 629087

Operator n a. Timebase.'IC9 Sequence:230509
Page 10-19
5/9/2023 2.35 PM
8 AUTOCAL6
Sample Name.
AUTOCAL6
Injection Volume
1.0
Vial Number,
2
Channel.
ECD_1
Sample Type:
Calibration Standard
Dilution Factor.-
1.0000
Control Program.
AS23
Sample Weight'
1.0000
Quantif. Method'
230509an
Sample Amount.
1.0000
Recording Time:
51912023 10:20
Analyst'
JLD1
Run Time (min)'
27.00
Column:
AS23-001528;GLGCE086;300;9056
30 0 g 230509 #8
AUTOCAL6
ECD_1
PS
25.0
20 0
I�
15.0
a
oI
y
10 A
Iqy
`0.
5.0
ra
cc`�e
ra�Q
00
Mill
-3.0
0.0
50
100
150
20.0
2 0 20 27.0
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
mall-
m 1L
S*min
%
1
4.51
Fluoride
5.0000
50179
240184
11.35
2
787
Chloride
10.0000
100256
382377
18.07
3
10.23
Nitrite-N
5.0000
5.0070
3.87478
18.31
4
12.96
Bromide
3.0000
29922
0.43232
2.04
5
1528
Nitrate-N
50000
5.0097
4,54406
2147
6
22.75
O-Phosphate-P
3.0000
2.9611
0.86161
4.07
7
25.57
Sulfate
200000
20.0283
5.22665
2469
T tall
51.0419
0.000 21 165
100.00
GEL Report RT-Dev/Integration
Page 29 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10.23925

Operator.n.a Timebase:IC9 Sequence•230509
Page 11-19
5/9/2023 2.35 PM
9 AUTOCAL.5
Sample Name:
AUTOCAL5
injection Volume.
1.0
Vial Number.
3
Channel
ECD_1
Sample Type-
Calibration Standard
Dilution Factor,
1.0000
Control Program:
AS23
Sample Weight,
1.0000
Quantif Method.
230509an
Sample Amount.
1.0000
Recording Time,
5/9/2023 10:50
Analyst:
JLD1
Run Time (rein).
27.00
Column:
AS23-001528;GLGCE086;300;9056
30.0 1230509 #9
AUTOCAL6
EC6_1
PS
25.0
20 0
15.0
10.0
�A1 hA1
�
11
�.a�
'k°
i� �°�*
Rip
i0
5��
i
DO
msn
-3.0
0.0
to
10.0
16 4
20.0
250 27.0
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m 1L
m IL
S*min
%
1
450
Fluoride
1.0000
08869
042976
8.98
2
7.85
Chloride
2.0000
18628
0.68243
14.25
3
1020
Nitrite-N
1.0000
0.9680
0.73667
15.39
4
1296
Bromide
2.5000
2.5079
0.36236
7.57
5
15.33
Nitrate-N
1.0000
0.9481
0.83912
1753
6
22.77
O-Phosphate-P
2.5000
2.5421
0.74214
15.50
7
25.57
Sulfate
4.0000
3.8525
0.99541
20.79
ITotall
135683
0.000 4 788
100.00
GEL Report RT-Dev/Integration
Page 30 of 62 SDC: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10,23925

Operator n a. Tlmebase:IC9 Sequence:230509
Page 12-19
5/912023 2.35 PM
10 AUTOCAL4
Sample Name
AUTOCAL4
Injection Volume.
1.0
Vial Number.
4
Channel:
ECD 1
Sample Type:
Calibration Standard
Dilution Factor,
1.0000
Control Program
AS23
Sample Weight
1.0000
Quantif Method-
230509an
Sample Amount
1.0000
Recording Time.
5/912023 11:19
Analysi•
JLD1
Run Time (ruin)-
27.00
Column:
AS23-001528;GLGCE086;300;9056
30 0 1230609 #10
AUTOCAL4
ECD_1
PS
25.0
20 0
15.0
100
00
5.0
p Ao�
e' +•0
Igo
'`�
�Q
tia°� 10� :erg
a�w¢ e4 a6
QoD
�aNKb
I�a
I
0.0
1F
v
uin
r
-3 0
0 0
5.0
10.0
190
20.0
25.0 27 0
No.
Re#.Time
Peak Name
Concentration
Amount
Modit"ied? Area
Rel.Area
min
m 1L
m 1L
S*min
%
1
4.50
Fluoride
0.5000
05090
0.24935
1090
2
7 84
Chloride
1.0000
0.9568
0.33379
14 59
3
10.19
Nitnte-N
0.5000
0.4704
035008
15.30
4
12.96
Bromide
1.0000
10004
0.14458
6.32
5
15.33
Nitrate-N
05000
0.4796
041184
18.00
S
22.80
O-Phosphale-P
1.0000
10192
030787
13.46
7
25.57
Sulfate
2.0000
1.9206
049007
21.42
TotWIT-
6.3561
0.000 2.288
10000
GEL Report RT-Dev/Integration
Page 31 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2 10 23925

Operator•n a. Timebase:IC9 Sequence:230509
Page 13-19
5/9/2023 2:35 PM
11 AUTOCAU
Sample Name-
AUTOCAL3
Injection Volume
1.0
Vial Number:
5
Channel-
ECD_1
Sample Type.
Calibration Standard
Dilution Factor:
1.0000
Control Program•
AS23
Sample Weight:
1.0000
Quantif Method:
230509an
Sample Amount:
1.0000
Recording Time-
5/9/2023 11:49
Analyst:
JLD1
Run Time (min):
27.00
Column:
A823-001528;GLGCE086;300;9056
230509 411
30.0
AUTOCAL3
ECD 1
PS
25 0
20.0
15.0
10.0
50
Jq r
�j OTC+
$6
0.0
I
I
I
Irvin
-3 0
00
50
10.0
150
26.0
250 270
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rei.Area
min
m IL
m /L
S*min
%
1
4.50
Fluoride
0.2500
0.3208
015952
11.91
2
7.84
Chloride
0.5000
0.6006
019670
14.68
3
1019
Nitrile-N
0.2500
0.2937
0.21276
15.88
4
1296
Bromide
05000
0.5110
0.07389
5.52
5
15.34
Nitrate-N
0.2500
02980
0.24616
18.38
6
2281
O-Phosphate-P
0.5000
0.4884
0,15650
11.68
7
25.57
Sulfate
1.0000
1.1711
0.29402
21.95
Totall
3.6837
0.000 1.340
100.00
GEL Report RT-Dev/Integration
Page 32 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10 23925

Operator.n.a Timebase.IC9 Secluence:230509
Page 14-19
5/9/2023 2.35 PM
12 AUTOCAL2
Sample Name:
AUTOCAL2
Injection Volume.
1.0
Via] Number.-
6
Channel.
ECD_1
Sample Type-
Calibration Standard
Dilution Factor.
1.0000
Control Program:
AS23
Sample Weight-
1.0000
Quantrf. Method
230509an
Sample Amount:
1.0000
Recording Time,
5/9/2023 12:19
Analyst-
JLD1
Run Time (rain).
27.00
Column: AS23-001528;GLGCE086;300;9056
30.0 1 230509 #12
AUTOCAL2
EOD -1
PS
25 0
20.0
150
10.0
�ti
0�a@,
IGror�
21����
I
I
I
0.0
rein
-3 0 11
00
5.0
10.0
190
20.0
25.0 27 0
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m /L
m 1L
S*min
%
1
4.49
Fluoride
0 1000
0.1154
006144
13.01
2
7.84
Chloride
0.2000
02541
0.06337
1342
3
10.19
Nitrite-N
01000
0.1110
0.07079
14.99
4
1296
Bromide
0.2000
0 1885
002729
5,78
5
15.34
Nitrate-N
0.1000
0.1146
0.07883
16.69
6
22.82
O-Phosphate-P
02000
0.1891
007114
15.06
7
25.56
Sulfate
0.4000
0.4275
0.09951
21.07
To all
1.4001
0.000 0.472
10000
GEL Reporl RT- Devlin tegrati on
Page 33 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10.23925

Operator•n a. Timebase:IC9 Sequence.230509
Page 15-19
5/9/2023 2:35 PM
13 AUTOCALI
Sample Name-
AUTOCAi_1
Injection Volume,
1.0
Vial Number:
7
Channel-
ECD_1
Sample Type:
Calibration Standard
Dilution Factor,
1.0000
Control Program •
AS23
Sample Weight:
1.0000
Quantif Method.
230509an
Sample Amount:
1.0000
Recording Time,
51912023 12:49
Analyst.
JLD1
Run Time {min):
27.00
Column AS23-001528;GLGCE086;300;9056
30 0 1230509 #13
AUTOCAL1
ECD 1
PS
2 5.0
20 0
15.0
100
5.0
00
min
-3 0
00
50
10.0 150
200
250 270
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
Rel.Area
min
m /L m IL
S*min
%
no
ma,
Fluoride
0 0000 n.a.
no n.a.
n.a.
no
n.a.
Chloride
0.0000 n.a.
no n.a.
no
n.a.
n a.
Nitrite-N
0.0000 n a.
n.a. no
n.a.
n a.
n.a.
Bromide
0 0000 n.a.
n a. n.a.
n.a
n.a.
n.a,
Nitrate-N
0.0000 n a
n.a. n.a.
n.a.
n.a.
no
O-Phosphate-P
0 0000 n a.
n.a. n a.
n.a.
n.a.
n.a,
Sulfate
0.0000 n.a
n.a. no
n.a.
Total;
0.0000
0.000 0.000
000
GEL Report RT-Dev/Integration
Page 34 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10 23925

Operator.n.a Timebase.IC9 Sequence.230509
Page 17-19
5/9/2023 2:35 PM
No.
Ret.Time
Peak Name
Cal.Type
Coeff.Det.
Offset
Slope
Curve
min
%
n a.
n.a
Fluoride
n, WilhOffs+
99.8912
0.0064
0.4774
0.0000
n.a.
n.a
Chloride
n, WithOffsj
999492
-0.0344
0.3848
00000
n a
n.a.
Nitrite-N
n, WilhOifs,
99.9765
-0.0154
0.7770
00000
n.a
n.a
Bromide
n, WiIhOffsi
99.9939
0.0001
01445
0.0000
n.a
n a.
Nitrate-N
n, WithOffs,
99.9662
-0 0257
0.9122
0,0000
n a
Ma.
O-Phosphate-P
n, WithOffsi
99,9367
0.0172
02852
0.0000
n.a.
Ina
Sulfate
n, WithOffsi
999783
-0.0123
0.2616
00000
Average:
999560
-0.0092
0.4632
00000
GEL Report RT-Dev/Calibrati on (Batch)
Chromeleon (c) Dionex 1996-2006
Version 7 2 10.23925
Page 35 of 62 SDG: 629087

Operator.n.a Timebase:IC9 Sequence•230509
Page 16-19
5/9/2023 2 35 PM
13 AUTOGAU
Sample Name,
AUTOCALI
Injection Volume.
1.0
Vial Number.
7
Channel.
ECD_1
Sample Type-
Calibration Standard
Dilution Factor.
1.0000
Control Program:
AS23
Sample Weight
1.0000
Quant)f. Method.
230509an
Sample Amount-
1.0000
Recording Time,
5/91202312:49
Analyst-
JLD1
Run Time (min)
27.00 Column. n.a.
3 00 Fluoride External ECD_1
p8'min
2.00
1 d10
mg1L
QAO
0 00 2.00 4.00 6 00
4 50 Nitrite-N External ECD_1
u S"min
3.75
2 56
125
mg1L
0 00
0.00 200 4.00 6.00
5.00 Nitrate-N External ECD_1
{P S`min
4,00
2 00
mglL
0 00
000 2.00 4.00 6.00
GEL Report RT-Dev/Calibration(Batch)
Page 36 of 62 SDG: 629087
4,50 Chloride External ECD_1
ps*min
3 75
2.50
1 25
m
0.00 g/L
0!0 5.0 160 12 0
0 500 Bromide External ECD_1
tjS"min
0 400
0 200
mg/L
0.000
0.00 125 2 50 3 50
Chromeleon (c) Dionex 1996-2006
Version 7.2.10.23925

This is runlog
for Sequence 230713.seq for IC9
Sample ID
Run Time
Batch
Dilution
Dataset
Analyst
BLK
07/13/23
07.51
1
230713
JLDI
ICV
07/13/23
08:22
1
230713
JLD1
ICB
07/13/23
08:53
1
230713
JLD1
1205456105
07/13/23
10:18
2457720
1
230713
JLDI
1205456106
07/13/23
10:49
2457720
1
230713
JLDI
628442006
07/13/2.3
11:21
2457720
1
230713
JLDI
628442010
07/13/23
11:52
2457720
1
230713
JLDI
628442014
07/13/23
12 24
2457720
1
230713
JLDI
628442001
07/13/23
12:55
2457720
1
230713
JLDI
1205456107
07/13/23
13:26
2457720
1
230713
JLDI
1205456108
07/23/23
13 58
2457720
1
230713
JLDI
628442001
07/13/23
14:29
2457720
10
230713
JLD1
1205456107
07/13/23
15:00
245772G
10
230713
JLDI
CVH
07/13/23
15.32
1
230713
JLDI
CCB
07/13/23
16.03
1
230713
JLD1
1205456108
07/13/23
16:35
2457720
10
230713
JLDI
629090001
07/13/23
17:06
2458814
2
230713
JLDI
629044008
07/13/23
17 37
2458814
1
230713
JLD1
1205457781
07/13/23
18:09
2458814
1
230713
JLD1
1205457782
07/13/23
18:40
2458814
1
230713
JLDI
629087001
07/13/23
19:12
2458814
20
230713
JLDI
629087002
07/13/23
19:43
2458814
20
230713
JLDI
629087003
07/13/23
20:14
2458814
20
230713
JLDI
629087004
07/13/23
20 46
2458814
20
230713
JLDI
629087005
07/13/23
21:17
2458814
1
230713
JLDI
CCV
07/13/23
21.48
1
230713
JLDI
CCB
07/13/23
22:20
1
230713
JLD1
629087006
07/13/23
22:51
2458814
1
230713
JLD1
Page 37 of 62
SDG: 629087

629087007 07/13/23 23 23 2458814 20 230713 JLD1
1205457779 07/13/23 23 54 2458814 1 230713 JIM
Page 38 of 62 SDG: 629087

Operator.n.a Timebase:IC9 Sequence:230713
Page 1-2
7/14/2023 8.10 AM
15 WIC230713-021CV
Sample Name:
VOC230713-021CV
Injection Volume:
1.0
Vial Number
2
Channel.
ECD_1
Sample Type-
Unknown
Dilution Factor.
1.0000
Control Program:
AS23
Sample Weight,
1.0000
Quanhf Method
230509an
Sample Amount:
1.0000
Recording Time:
711312023 8:22
Analyst,
JLD1
Run Time (min).
28.50
Column:
AS23-001528;GLGCE086;300;9056
30.0 1, 230713 #15
WIC230713-021CV
ECD_1
PS
25 0
20.0
15.0
ya
tit
10-0
r`o�
ho
obi
c
'b
5 0
k
awe✓
r
1O`o�tae
0����
0.0-1A
min
00
50
100 150
20.0 250
285
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m lL
m lL
S*min
%
1
4.49
Fluoride
n.a.
25538
1 22552
11.60
2
7.75
Chloride
n.a.
4.9750
1.88013
17.79
3
10 04
Nitrite-N
n a.
2.5924
1.99876
18.91
4
1269
Bromide
n a.
1.3428
0 19404
1.84
5
14.97
Nitrate-N
n.a
2.4807
2.23718
2117
6
2202
O-Phosphate-P
n.a.
12478
0.37305
353
7
24.78
Sulfate
n a
10.2130
2,65918
25 16
Total:
25.4055
0.000 10.568
100.00
GEL Report RT-DeOniegraiion
Page 39 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2 10 23925

Operatorm a Timebase:IC9 Sequence.230713
Page 2-2
7/14/2023 8A0 AM
16 [GB
Sample Name•
ICB
Injection Volume:
1.0
Vial Number:
3
Channel:
ECD 1
Sample Type.
Unknown
Dilution Factor•
1.0000
Control Program
AS23
Sample Weight.
1.0000
Quantif Method.,
230509an
Sample Amount
1.0000
Recording Time•
7/13/2023 8:53
Analyst
JLD1
Run Time (min):
28.50
Column:
AS23-001528;GLGCE086;300;9056
230713 #16
30.0
ICB
ECD_ _1
PS
2 5.0
20.0
15.0
10.0
5
o.n
-3.0
ET31(1
Q0
50
100
150
200 250
285
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
ReLArea
min
m 1L
m IL
S*min
%
n.a.
n a
Fluoride
n a.
n a
n.a. n a.
n a
n.a.
n.a.
Chloride
n a.
n a
n.a n.a.
n a,
n.a.
n.a.
Nitrite-N
n.a
n.a.
n.a. n.a
n.a.
n.a.
n a
Bromide
n.a
n.a
n.a. n.a.
n.a
n a
n.a.
Nitrate-N
n.a.
n.a.
n a. n.a.
n.a.
n.a.
n a
O-Phosphate-P
n.a
n.a
n.a. n a
n.a,
n a
n.a.
Sulfate
n.a.
ma.
n.a. n.a.
n.a.
Total:
0.0000
0.000 0.000
0.00
GEL Report RT-Dev/integration
Page 40 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2 10 23925

Operator -ma Timebase.IC9 Sequence 230713
Page 11-12
7/14/2023 8:09 AM
28 WIC230713-02CVH
Sample Name-
VOC230713-02CVH
Injection Volume:
1.0
Vial Number.
15
Channel-
ECD_1
Sample Type.
Unknown
Dilution Factor
1.0000
Control Program-
AS23
Sample Weight:
1.0000
Quantif Method.
230509an
Sample Amount
1.0000
Recording Time•
7/1312023 15:32
Analyst:
JLD1
Run Time (min).
28.50
Column
AS23-001528;GLGCE086;300;9056
30.0 1230713 #28
WIC230713-02CVH
ECD_1
P5
2 5.0
20.0
o'
0
15.0%�
0�1
10 0
�h
5.0
aL
�o
00
0
-3
00
60 160 150
200 250
285
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
MAIL
m 1L
S*min
%
1
4.49
Fluoride
n.a
3.9342
1.88449
11.73
2
7.75
Chloride
n a
76504
290971
18.11
3
1004
Nitrite-N
n.a.
3.9370
3.04344
18.94
4
12.68
Bromide
n a
1.9068
0.27553
1.71
5
14.94
Nitrate-N
n.a.
3.7639
3.40767
21.21
6
21 97
O-Phosphate-P
n.a.
1.7744
0.52322
326
7
24 73
Sulfate
n.a.
154237
4.02218
25.04
Total:
38.3905
0 000 16.066
100.00
GEL Report RT-Dev/Integration
Page 41 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2 10.23925

Operator n.a Timebase:IC9 Sequence:230713
Page 12-12
7/14/2023 8:09 AM
29 CCB
Sample Name,
CCB
Injection Volume:
1.0
Vial Number.
16
Channel
ECD_1
Sample Type:
Unknown
Dilution Factor.
1.0000
Control Program.
AS23
Sample Weight-
1.0000
Quantif. Method,
230509an
Sample Amount.
1.0000
Recording Time,
7113/2023 16:03
Analyst:
JLD1
Run Time (min),
28.50
Column.
AS23-001528;GLGCE086;300;9056
300 1230713 #29
GCB
ECD_1
PS
25.0
20 0
15.0
100
5.0
0.0
-3 0
min
00
50
160
160
20.0 25 0
28.5
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
Rel.Area
min
m /L
m 1L
S*min
%
n.a
n.a.
Fluoride
n a
n.a.
n a. n.a.
n.a
n.a.
n.a.
Chloride
n.a.
n.a
n.a. n.a
n.a.
n a
n.a.
Nitne-N
n.a
n.a.
n a n.a.
n.a
n a
n.a.
Bromide
n a
n.a
n.a. n.a.
n a.
n.a.
n a
Nitrate-N
n.a.
n.a.
n.a n a.
n.a.
n a
n.a.
O-Phosphate-P
n.a
n.a.
n a n.a.
n a
n.a.
Ina
Sulfate
n.a.
n a.
n.a n a.
n.a.
Total:
00000
O.000 0 000
0.00
GEL Report RT-Dev/Integration
Page 42 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2 10.23925

Operator.n.a. Timebase'iC9 Seyuence:230713
Page 3-12
7/14/2023 8:09 AM
32 629044008/245881411111
Sample Name:
629044008/245881411ill
Injection Volume•
1.0
Vial Number.
19
Channel
ECD_1
Sample Type,
Unknown
Dilution Factor.
1.0000
Control Program:
A823
Sample Weight-
1.0000
Quantif. Method
230509an
Sample Amount:
1.0000
Recording Time:
7/1312023 17:37
Analyst:
JL01
Run Time (rain)
28.50
Column:
AS23-001528;GLGCE086;300;9056
30.0 230713 #32
629044008/245881411/11
ECD_1
p S
�01
'l
ae•
250
r10
20.0
15 0
�6.
�JE
5
10.0
1
'
5 0
p1b
A•
o`ti�
4
�o
�wm
ra
0
1,
�Q+•
�r
p'
0.0
�
gy
min
-3.0
0.0
50
100
150
260 250
285
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
Rei.Area
min
m IL
m /L
S*min
%
1
447
Fluoride
n a
02639
0.13233
029
2
7 91
Chlonde
n.a.
983897
3782920
83.94
3
10.02
Nitrite-N
n a
0.0508
0.02409
0.05
n.a.
n a
Bromide
n a.
n.a
n a. n.a.
n.a
4
15.16
Nitrate-N
n.a
0.8018
070572
1.57
6
22,07
O-Phosphate-P
n.a
0.1892
0.07118
016
7
24.77
Sulfate
n.a.
23.9344
6.24838
13.86
Tota1:
1236298
0.000 45.011
9988
GEL Report RT-Dev/lntegration
Page 43 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2 10 23925

Operator n.a. Timebase•IC9 Sequence.230713
Page 4-12
7/14/2023 8.09 AM
33 12054577811245881411111DU P
Sample Name:
12054577811245881411111DUP
Injection Volume:
1.0
Vial Number.
20
Channel,
ECD 1
Sample Type:
Unknown
Dilution Factor•
1.0000
Control Program:
AS23
Sample Weight:
1.0000
Quantif. Method-
230509an
Sample Amount
1.0000
Recording Time.
7/1312023 18:09
Analyst.
JLD1
Run Time (rain):
28.50
Column.
A823.001528;GLGCE086;300;9056
30 0 1230713 #33
120545778112458814/1111DUP
ECD_1
PS
25.0
20 0
w�
klp
5J
100
�4
o�
5.0
��
`��
*y.
1v
4
0.4
min
-3 0
00
50
10.0
150
260 25.0
285
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
Rel.Area
min
m lL
m IL
S*min
%
1
4.47
Fluoride
n a.
0.2733
0.13681
030
2
7.90
Chloride
n a
98.4544
37.85410
8399
3
10.02
Nitrite-N
n.a.
0.0503
0.02365
0.05
n a
n.a.
Bromide
n.a
n.a.
n.a. n.a.
n.a.
4
1516
Nitrate-N
n.a.
08037
070742
1.57
6
22.07
O-Phosphate-P
n.a.
0.1786
0.06815
0.15
7
24.77
Sulfate
n.a.
238449
622496
13.81
Total•
123.6051
0.000 45.015
99.87
GEL Report RT-Devllntegrabon
Page 44 of 62 SDG: 629087
Chromeieon (c) Dionex 1996-2006
Version 7.2.10.23925

Operator.n.a. Timebase:IC9 Sequence:230713
Page 5-12
7/14/2023 8:09 AM
34 12054577821245881411 /1 /PS
Sample Name:
12054577821245881411111PS
Injection Volume.
1.0
Vial Number.-
21
Channel:
ECD_1
Sample Type-
Unknown
Dilution Factor.
1.0000
Control Program:
A823
Sample Weight.
1.0000
Quantif. Method-
230509an
Sample Amount-
1.0000
Recording Time:
7/1312023 18:40
Analysi:
JLD1
Run Time (min)
28.50
Column:
AS23.001528;GLGCE086;300;9056
30.0 " 230713 #34
1205457782/2458814/1/l/PS
ECD 1
NS^�
1•
25.0
r�o
20.0
5v
t
15.0
10 0
No.
OrytK
Q
5.0
•
0
bm
�Q�
0.0
min
0.0
50
10.0 150
20.0 250
286
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
MAIL
m 1L
S*min
%
1
448
Fluoride
n.a.
26943
1.29261
2.31
2
7.91
Chloride
n.a.
104.3837
40.13587
7168
3
10.04
Nitrite-N
n.a.
24981
1 92550
3.44
4
1272
Bromide
n.a.
1.2928
0.18682
0.33
5
15.13
Nitrate-N
n.a
3,1603
2.85711
5.10
7
22.02
O-Phosphale-P
n.a.
1.2832
038313
0.68
8
24.79
Sulfate
n a
35.0623
9.15918
16.36
Total:
150.3746
0.000 55.940
99.90
GEL Report RT-Dev/lniegralion
Page 45 of 62 SDG: 629087
Chromeleon (G) Dionex 1996-2006
Version 7.2 10 23925

Operator.n.a. Timebase•IC9 Sequence•230713
Page 6-12
7/14/2023 8.09 AM
35 62908700112458814120111
Sample Name.
62908700112458814/20111
Injection Volume.
1.0
Vial Number:
22
Channel-
ECD_1
Sample Type:
Unknown
Dilution Factor.•
1.0000
Control Program.
A823
Sample Weight.
1.0000
Quantif. Method,
230509an
Sample Amount:
1.0000
Recording Time.
711312023 19:12
Analyst.
JLD1
Run Time (min),
28.50
Column:
AS23.001528;GLGCE086;300;9056
30 0 1230713 #35
6290870011246881412011!
EC©_1
PS
25.0
20 4
150
10.0
�o
Oyu rGr
5.0
I� 1
1
�
�.OQ1
r
r
Rio
rnQ
00
rein
-3.0
0.0
.50
10 0 150
20.0 290
2$ 5
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m 1L
m A.
S*rain
%
1
4.48
Fluoride
n.a.
00478
0.02917
1 01
3
7.74
Chloride
n.a.
3.3103
1.23950
4280
n.a
n.a.
Nitrite-N
n a
n.a.
n a. n.a.
n.a.
4
12.68
Bromide
n a.
03901
0.05642
1.95
n.a,
n a
Nitrate-N
n.a
n.a.
n a n.a.
n a.
5
22.01
O-Phosphate-P
n a
00131
002097
0.72
n.a,
n a.
Sulfate
n.a
n.a.
n a n.a.
n a.
Totall
37614
0.000 1.346
4648
GEL Report RT-DeOntegralion
Page 46 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10.23925

Operator.n.a. Tlmebase.IC9 Seyuence:230713
Page 7-12
7/14/2023 8:09 AM
35 629087002/2458814/20111
Sample Name:
62908700212458814120111
Injection Volume-
1.0
Vial Number'
23
Channel
ECD_1
Sample Type-
Unknown
Dilution Factor.
1.0000
Control P►ogram:
AS23
Sample Weight.,
1.0000
Quantif. Method
230509an
Sample Amount:
1.0000
Recording Time:
7/1312023 19:43
Analyst:
JL01
Run Time (min).
28.50
Column:
AS23-001528;GLGCE086;300;9056
30.0 1 230713 #136
629087002/2458814/20/1/
ECD_1
PS
25 0
20.0
150
10.0
�a
t
A41
yJ
I
1'
5 0
a0
b0b
a�
�i
0.0
Irn n
-3.0
0.0
50 100 150
200 250
285
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m 1L
m IL
S*min
%
n.a.
n a.
Fluoride
n.a.
n.a
n a. n.a.
n a
1
773
Chloride
n.a.
1.1572
0.41090
8.94
n a.
n.a.
Nitnte-N
n a
n.a.
n.a n.a.
n a
2
1268
Bromide
n a.
02570
003719
0.81
n.a
n.a.
Nitrate-N
n.a.
n.a.
n.a n.a.
n.a.
n a
n.a.
O-Phosphate-P
n a
n.a
n a n.a.
n.a
3
24.75
Sulfate
n.a
15.8996
4.14666
9025
ITotall
173138
0.000 4 595
100.00
GEL Report RT-Dev/Integration
Page 47 of 62 SDG: 629087
Chromeleon (c) Dlonex 1996-2006
Version 7 2 10 23925

Operator -ma Timebase:IC9 Sequence.230713
Page 8-12
7/14/2023 8.09 AM
37 629087003124588141201'il
Sample Name:
6290870031245881412011)
Infection Volume:
1.0
Vial Number.
24
Channel:
ECD_1
Sample Type.
Unknown
Dilution Factor
1.0000
Control Program
AS23
Sample Weight.
1.0000
Quantif Method:
230509an
Sample Amount-
1.0000
Recording Time-
7/13/2023 20:14
Analysi.
JLD1
Run Time (min):
28.50
Column
AS23-001528;GLGCE086;300;9056
30 0 230713 #37
62908700312458814120/1/
ECD_1
PS
25.0
20 0
1 �.o
10.0
� •
tie.•
�.o
��'� ��
�ti. ,�b.
o`�aa
9�m•
0.0
min
-3.0J
0.0
50 10.0 150 200 250
285
No.
Ret.Time
Peak Name
Concentration
Amount Modified? Area
Re{.Area
min
m 1L.
m /L S*min
%
n a
n a.
Fluoride
n.a
n.a. n.a. n a.
n.a.
1
7.73
Chloride
n.a
1.0040 0.35195
20.34
n.a,
n.a
Nitrite-N
n.a.
n.a. n.a. n a
n.a.
2
12.68
Bromide
n a.
0.6841 0.09890
572
3
14 98
Nitrate-N
n.a.
00973 006309
3.65
n.a.
n a.
O-Phosphate-P
n.a.
n a. n.a. n a
n.a.
4
24 75
Sulfate
n.a.
46965 1 21617
70.29
Total:
6.4819 0.000 1.730
100.00
GEL Reporl RT-DeOniegration
Page 48 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10 23925

Operator n a Timebase•IC9 Sequence•230713
Page 9-12
7/14/2023 8.09 AM
38 629087004/2458814/20/11
Sample Name,
62908700412458814120/11
injection Volume.
1.0
Vial Number:
25
Channel-
ECD_1
Sample Type.
Unknown
Dilution Factor-
1.0000
Control Program•
AS23
Sample Weight.
1.0000
Quantif. Method.
230509an
Sample Amount•
1.0000
Recording Time-
7/13/2023 20:46
Analyst:
JLD1
Run Time (min):
28.50
Column.
AS23-001528;GLGCE086;300;9056
30.0 1230713 #3B
629087004/2458814120/l/
ECD_1
PS
25,0
20.0
15.0
100
5 0
0
4
0
r,'Y ��''
��o
ryp,•
0.0
min
-3 0
0.0
50
10.0 150
260 250
285
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m /L
m /L
S*min
%
n a.
n.a
Fluoride
n.a.
n.a.
n a n a
n a.
1
7.73
Chloride
n.a.
0.5035
0.15933
22.01
n a.
n.a
Nitrite-N
n a.
n a
n a n a
n a
2
12.68
Bromide
n.a.
0.2294
0.03321
4.59
3
14.99
Nitrate-N
n a.
0,0584
0.02763
3.82
4
2205
O-Phosphate-P
n.a.
0.0684
0.03673
5.07
5
24.75
Sulfate
n a.
1,8324
0.46700
64.51
Totall
2.6921
0.000 0 724
100.00
GEL Report RT-Dev/integration
Page 49 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2.10.23925

Operator n a Tlmebase•IC9 Sequence 230713
Page 10-12
7/14/2023 8.09 AM
39 6290870051245881411 /it
Sample Name-
629087005124588141111/
Injection Volume:
1.0
Vial Number.
26
Channel.
ECD 1
Sample Type.
Unknown
Dilution Factor
1.0000
Control Program•
AS23
Sample Weight:
1.0000
Quantif. Method:
230509an
Sample Amount.
1.0000
Recording Time,
7M312023 21:17
Analyst:
JLD1
Run Time {min):
28.50
Column-
AS23.001528;GLGCE086;300;9056
30.0 230713 #39
620087005/2458814/1 /1 /
ECD_1
PS
�a�
�v
25 0
20.0
150
10 0�.
^h0
I
50
0.0
i
mill
-3.0
00
60
10.0
15 0
20.0 25.0
28.5
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
Rel.Area
min
m lL
m IL
S*min
%
1
4.68
Fluoride
n.a.
0.0796
0.04436 0.10
2
7.80
Chloride
n a
27.5331
10.56124 22.74
n.a
n a
Nitrite-N
n.a.
n.a.
n.a. n.a.
n.a.
n.a.
n.a.
Bromide
n.a.
n.a.
n.a. n.a.
n.a.
3
15.09
Nitrate-N
n.a.
3.2717
2.95864 637
n.a
n.a
O-Phosphate-P
n.a.
n.a.
n.a. n.a.
n.a.
5
24.89
Sulfate
n a.
1256124
32.84505 7071
Total:
156,4968
0.000 46.409 99.91
GEL Report RT-Dev/integrairon
Page 50 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2 10 23925

Operator.n.a. Timebase:IC9 Sequence:230713
Page 11-12
7/14/2023 8.09 AM
40 WIC230713-02CCV
Sample Name.
MC230713.02CCV
Injection Volume,
1.0
Vial Number,
27
Channel
ECD_1
Sample Type:
Unknown
Dilution Factor
1.0000
Control Program.
A823
Sample Weight-
1.0000
Quantif. Method.,
230509an
Sample Amount:
1.0000
Recording Time:
7/13/2023 21:48
Analyst:
JLD1
Run Time (min)'
28.50
Column:
AS23-001528;GLGCE086;300;9056
30.0 230713 #40
WIC230713-02CCV
ECD_1
PS
25.0
20.0
15.0
10.0.
Gr`o�
+
��b•
�agya
`' t•
a
5.0
to
0.0
min
-3.0
0.0
60 10 0 150
260 25.0
28.5
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m /L
m IL
S*min
%
1
4.48
Fluoride
n.a
2.5692
1.23286
11.96
2
7.75
Chloride
n a.
48732
1 84092
17.85
3
1003
Nitne-N
n.a
2.5111
1.93561
1877
4
12.68
Bromide
n a.
1.2574
0.18170
1.76
5
14 95
Nitrate-N
n.a.
2.4103
2.17297
21.07
6
22.00
O-Phosphate-P
n.a
1.1570
0.34716
3 37
7
24.76
Sulfate
n.a.
9.9856
2.59970
25.21
Total:
24.7638
0.000 10.311
100.00
GEL Report RT-DeOntegration
Page 51 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2 10.23925

Operator.n.a. Timebase:IC9 Sequence•230713
Page 12-12
7/14/2023 8.09 AM
41 CCB
Sample Name.
CCB
Injection Volume-
1.0
Vial Number-
28
Channel:
ECD_1
Sample Type:
Unknown
Dilution Factor.-
1.0000
Control Program.
A823
Sample Weight.
1.0000
Quanta. Method-
230509an
Sample Amount.
1.0000
Recording Time.
7/13/2023 22:20
Analyst:
JLD1
Run Time (min):
28.50
Column.
AS23-001528;GLGCE086;300;9056
30.0 j, 230713 #41
GCB
ECD 1
PS
25 0
2 0.0
15.0
100
b.0
0.0
-3.0
min
0 0
6 0
10 0
160
20.0 25.0
28.5
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
Rel.Area
min
m IL
m IL
S*min
%
n.a.
n.a.
Fluoride
n.a
n.a.
n.a. n.a.
n.a.
n.a
n a
Chloride
n.a.
n.a.
n.a. n.a.
n.a
n.a.
n.a.
Nitrite-N
n a.
n.a
n a. n.a
n.a.
n.a.
n.a.
Bromide
n.a.
n.a.
n.a. n.a.
n.a.
n.a
n.a.
Nitrate-N
n.a
n a
n a. n.a
n.a
n.a.
ma.
O-Phosphate-P
n a
n a.
n a. n.a
Mal
n a.
n a.
Sulfate
n.a
n a.
n a n a
n a
ITotall
0.0000
0.000 0.000
0.00
GEL Report RT-DeOntegration
Page 52 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2.10.23925

Operatorm.a. Timebase-IC9 Sequence.230713
42 6290870061245881411111
Sample Name:
6290870061245881411/11
injection Volume.
Oai Number-
29
Channel:
Sample Type,
Unknown
Dilution Factor:
Control Program:
AS23
Sample Weight.
Quantif Method-
230509an
Sample Amount:
Recording Time:
7/1312023 22:51
Analyst:
Run Time (min)
28.50 Column:
A823-001528;GL.GCE086;300;9056
30.0 230713 ##42 629087006/2458814/111/
25,0
2 0.0
15.0
100.
5.0.
Page 1-10
7/14/2023 8.10 AM
1.0
ECD 1
1.0000
1,0000
1.0000
JLD1
ECD 1
PS
���
9AN
as
tie
D�
0
i
h
mtn
00�
0.0
No. I Ret.Time
50 10.0 150 200 2.50 28.5
Peak Name Concentration Amount Modified? Area Rel.Area
1
450
Fluoride
n.a.
0.1394
007291
0.07
2
790
Chloride
n.a.
872460
3354074
31.15
n.a.
n.a.
Nitnie-N
n a.
n.a. n.a.
n.a.
n.a
3
12.71
Bromide
n.a.
0.2289
003313
0.03
4
15.04
Nitrate-N
n a
9.3441
8.49778
7.89
n.a.
n.a.
O-Phosphate-P
n.a.
n.a. n.a.
n.a.
n.a
6
24.97
Sulfate
n.a
250.3924
65.48466
60.81
Chromeleon (c) Dionex 1996-2006
GEL. Report RT-Dev/Integration Version 7 2.10 23925
Page 53 of 62 SDG: 629087

Operator:n.a. Timebase.IC9 Sequence.230713
Page 2-10
7/14/2023 8.10 AM
43 62908700712458814120111
Sample Name:
62908700712458814120/11
Injection Volume.
1.0
Vial Number,
30
Channel.
ECD_1
Sample Type:
Unknown
Dilution Factor-
1.0000
Control Program:
AS23
Sample Weight,
1.0000
Quantif Method
230509an
Sample Amount-
1.0000
Recording Time:
7/13/2023 23:23
Analyst:
JLD1
Run Time (min)
28.50
Column-
AS23-001528;GLGCE086;300;9056
300 1230713 #43
6290870071245W4120/1/
ECD_1
PS
2 5.0
20 0
16.0
10.0
5.0
rya.
�`a
'
c°
0.0
mm
-3.0
00
50
1p.0 150
200 250
296
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m /L
m IL
S"min
%
n.a
n.a
Fluoride
n a,
n.a.
n.a. n.a.
n a.
1
7 74
Chloride
n a
1.0152
0.35623
19.38
n.a.
n.a.
Nitrite-N
n.a.
n.a.
n a. n a
n a
2
12 69
Bromide
n a
0.4588
0.06634
3 61
n.a.
n.a.
Nitrate-N
n.a.
n.a
n a. n a
n.a.
n.a.
n.a.
O-Phosphate-P
n.a.
n.a.
n.a. n a
n a
3
24.77
Sulfate
n.a.
54596
141580
77.01
otal:
6.9335
0.000 1.838
10000
GEL Report RT-Dev/lntegration
Page 54 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10.23925

Operator•n a Timebase•IC9 Seguence•230713
Page 3-10
7/14/2023 8:10 AM
44 12054577791245889 41'1111MB
Sample Name:
12054577791245881411/11MB
Injection Volume:
1.0
Vial Number:
31
Channel,
ECD_1
Sample Type.
Unknown
Dilution Factor-
1.0000
Control Program:
AS23
Sample Weight:
1.0000
Quantif Method.
230509an
Sample Amount•
1.0000
Recording Time-
7/13/2023 23:54
Analyst:
JLD1
Run Time (min).
28.50
Column:
AS23-001528;GLGCE086;300;9056
30.0 1230713 #44
1205457779/2458814/1/1/MB
ECD_1
P8
25.0
20 a
15.0
100
5.0
00
-3.0
m
in
00
50
10.0
150
200 250
285
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
Rel.Area
min
m 1L
m /L
S*min
%
n a
n a
Fluoride
n.a.
n.a.
n.a n.a
n a
n.a.
n.a.
Chloride
n.a.
n.a.
n.a. n.a.
n.a.
n a.
n a
Nitrite-N
n a
n.a
n a n a
n.n.
n a
n a
Bromide
n.a.
n.a
n a. n.a.
n a
n.a.
n.a.
Nitrate-N
n a
n.a.
n.a. n.a.
n.a.
n.a
n a
O-Phosphate-P
n a
n.a
n a n.a
n a.
n.a.
Sulfate
n a.
n.a.
n.a. n.a.
n.a.
[n.a.
otal:
0.0000
0.000 0.000
000
GEL Report RT-Dev/Integration
Page 55 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10,23925

This is runlog for Sequence 230713.seq for IC9
Sample TD
Run Time
Batch
Dilution
Dataset
Analyst
1205457780
07/14/23
00:25
2458814
1
230713
JLD1
629044008
07/14/23
00:57
2458814
25
2.30713
JLD1
1205457781
07/14/23
01:28
2458814
25
230713
JLD1
1205457782
07/14/23
02:00
2458814
25
230713
JLD1
629090001
07/14/23
02:31
Buse 1X
?
230733
JLD1
CVH
07/14/23
03:02
1
230713
JLD1
CCB
07/14/23
03:34
1
230713
JLD1
Page 56 of 62 SDG: 629087

Operator:n.a. Timebase.IC9 Sequence.230713
Page 4-10
7/14/2023 8.10 AM
45 1205457780I245881411 I11LCS
Sample Name.
1205457780124588141111ILCS
Injection Volume.
1.0
Vial Number-
32
Channel
ECD_1
Sample Type-
Unknown
Dilution Factor-
1.0000
Control Program.
AS23
Sample Weight.
1.0000
Quantif. Method,
230509an
Sample Amount:
1.0000
Recording Time.
711412023 0:25
Analyst:
JLD1
Run Time (min)-
28.50
Column:
AS23.001528;GLGCE086;300;9056
30.0 1, 230713 #45
1205457780/245881411/1/LCS
ECD_1
PS
25.0
20.0
15.0
10 0
tk
5.0
ra��Ayo
00
min
30
00
50
10.0 150
260 250
285
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m lL
m IL
S*min
%
1
4.49
Fluoride
n.a.
2.5946
1 24502
1203
2
7.75
Chlonde
n.a.
4.8946
1 84916
1787
3
10.04
Nitrite-N
n.a
25070
1 93239
18.68
4
12.69
Bromide
n.a.
1.2705
018361
177
5
14 96
Nitrate-N
n.a
24071
2.16998
20.97
6
22.00
O-Phosphate-P
ma
1 2253
036663
3.54
7
24 78
Sulfate
n.a
99886
2.60048
25.13
ITotall
24,8877
0.000 10 347
10000
GEL Report RT-DeOntegration
Page 57 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10.23925

Operatorn a Timebase:IC9 Sequence:230713
Page 5-10
7/14/2023 8:10 AM
46 62904400812458814125/21
Sample Name:
629044008/2458814/25121
Injection Volume:
1.0
Vial Number.
33
Channel.
ECD_1
Sample Type.
Unknown
Dilution Factor
1.0000
Control Program:
AS23
Sample Weight:
1.0000
Quantif. Method.
230509an
Sample Amount
1.0000
Recording Tome-
7/1412023 0:57
Analyst:
JLD1
Run Time {min).
28.50
Column
AS23-001528;GLGCE086;300;9056
230713 #46
30.0
629044008/2458814125/2/
ECD_1
PS
25.0
20.0
15.0
10.0
AAA
a�
G�
5.0
00
min
-3 0
00
50
10.0
150 200 250
285
No.
Ret.Time
Peak Name
Concentration Amount Modified? Area
Rel.Area
min
m 1L
m lL S*min
%
n a
n a
Fluoride
n.a.
n.a. n.a. n a
n a
1
7 75
Chloride
n a
2.8201 1.05086
80.83
n.a.
n.a.
Nitrite-N
n.a.
n a. n a n a
n a.
n a
n a.
Bromide
n.a.
n.a. n.a. n a
n a
2
14.99
Nitrate-N
n a.
00548 0.02427
1.87
n.a.
n.a.
O-Phosphate-P
n.a.
n a. n a n a
n.a.
3
24.78
Sulfate
n.a.
09070 0.22493
17.30
Total:1
3.7819 0.000 1.300
10000
GEL Report RT-Dev/lntegration
Page 58 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10.23925

Operator.n.a. Timebase:IC9 Sequence-230713
Page 6-10
7/14/2023 8:10 AM
47 12054577811245881412512/DUP
Sample Name:
120545778112458814125121DUP
Injection Volume-
1.0
Vial Number•
34
Channel:
ECD_1
Sample Type:
Unknown
dilution Factor.
1.0000
Control Program.
AS23
Sample Weight,
1.0000
Quantif Method,
230509an
Sample Amount.
1.0000
Recording Time.
711412023 1:28
Analyst:
JLD1
Run Time (min):
28.50
Column:
A823-001528;GLGCE086;300;9056
30 0 230713 #47
1205457781/2458814/2512/DUP
ECD_1
PS
25.0
20.0
15.0
10.0
a@
G
5.0
,`
��
,�a•
,tia.
i
5
0.0
min
0.0
5 0
160
150 20.0 25.0
28 5
No.
Ret.Time
Peak Name
Concentration Amount Modified? Area
Rel.Area
min
m IL
m 1L S*min
%
n.a.
n.a.
Fluoride
n a
n.a. n.a. n.a.
n.a.
1
7.75
Chloride
n.a.
2 8148 1.04881
80.93
n a
n a.
Nitrite-N
n a
n.a. n.a. n.a.
n a
n.a.
n.a.
Bromide
n a
n.a n.a. n.a.
n a
2
14 98
Nitrate-N
n.a.
0.0553 002475
1.91
n a
n.a
O-Phosphate-P
n a
n.a. n.a. n.a.
n a
3
24 78
Sulfate
n.a.
0.8973 022241
17.16
Total:
3.7674 0.000 1.296
100.00
GEL Report RT-DeOntegration
Page 59 of 62 SDG: 629087
Chromeleon (c) DEonex 1996-2006
Version 7.2.10.23925

Operatorm a. Timebase:IC9 Sequence•230713
Page 7-10
7114/2023 8.10 AM
48 120545778212458814/25121PS
Sample Name-
120545778212458814125121PS
injection Volume.
1.0
Vial Number.
35
Channel
ECLI_1
Sample Type.
Unknown
Dilution Factor-
1.0000
Control Program:
AS23
Sample Weight
1.0000
Quantif. Method
230509an
Sample Amount:
1.0000
Recording Time-
711412023 2:00
Analyst.
JLD1
Run Time (min).
28.50
Column.
AS23-001528;GLGCE086;300;9056
30.0 230713 #48
1206457782/2468814/25/21PS
ECD_1
PS
25 0
20.0
1^6�
t�
150
letio'
10.0
toPilo
5 0
ro
uF,�e`
4'c�yQr
�i
t0
0.0
in
m
-3 0
--28.5
00
50
100 150
200 2 0
No.
Ret.Ttme
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m 1L
m IL
S*min
%
1
4.49
Fluoride
n.a
2.3837
1.14431
1027
2
7.76
Chloride
n.a.
7.7238
2.93794
26.36
3
10.03
Nitrite-N
n.a
2.3646
1.82181
1635
4
1269
Bromide
n.a
1.1956
0.17278
1.55
5
14.96
Nilrate-N
n.a.
23007
2.07297
18 60
6
2200
O-Phosphate-P
n a
1.1245
0.33789
3 03
7
24.78
Sulfate
n.a.
102005
2.65590
23.83
Total:
27.2934
0.000 11.144
100.00
GEL Report RT-Dev/Integration
Page 60 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7.2.10.23925

Operator.n.a. Timebase:IC9 Sequence•230713
Page 9-10
7/14/2023 8.10 AM
50 WIC23O713-02CVH
Sample Name
WIC230713.02CVH
Injection Volume,
1.0
Vial Number,
37
Channel-
ECD_1
Sample Type:
Unknown
Dilution Factor:
1.0000
Control Progiam•
AS23
Sample Weight,
1.0000
Quantrf Method.
230509an
Sample Amount.
1.0000
Recording Time:
711412023 3:02
Analyst:
JLD1
Run Time (min):
28.50
Column,
AS23-001528;GLGCE086;300;9056
30 0 1230713 #60
WIC230713-02CVH
EGD_1
PS
25.0
200-
as`
r
0
gaP`
hp
b Ug
10 0
Z,am
v
kp
10.
0.0
rain
-3 0
00
50 100 150
20.0 250
285
No.
Ret.Time
Peak Name
Concentration
Amount
Modified? Area
Rel.Area
min
m IL
m IL
S*min
%
1
449
Fluoride
n.a.
3.9083
1.87215
11.68
2
7.76
Chloride
n a.
7.6277
2.90094
18.11
3
10 04
Nitrite-N
n.a
3 9049
3,01857
18.84
4
12.68
Bromide
n.a.
1.9379
028001
1.75
5
14.94
Nitrate-N
n a.
3.7575
3.40185
21.23
6
21.98
O-Phosphate-P
n.a
1.8453
0.54343
3 39
7
24.78
Sulfate
n.a
15.3611
4.00579
25.00
ITOtall
38.3427
0 000 16 023
10000
GEL Report RT-Dev/Integration
Page 61 of 62 SDG: 629087
Chromeleon (c) Dsonex 1996-2006
Version 7.2,10.23925

Operator•n a. Timebase•IC9 Sequence:230713
Page 10-10
7/14/2023 8:10 AM
51 CCB
Sample Name
CCB
Injection Volume:
1.0
Vial Number-
38
Channel.
ECD_1
Sample Type:
Unknown
Dilution Factor.
1.0000
Control Program•
AS23
Sample Weight-
1.0000
Quantif. Method:
230509an
Sample Amount.
1.0000
Recording Time:
7114/2023 3:34
Analyst:
JLD1
Run Time (min):
28.60
Column:
AS23.001528;GLGCE086;300;9056
30 0 1, 230713 #61
CCI3
ECD_1
PS
2 5.0
20 0
15.0
10.0
6.0
00
min
-3 b
0.0
5 0
10 0
150
26.0 25.0
28.5
No.
Ret.Time
Peak Name
Concentration Amount
Modified? Area
Rei.Area
min
rn lL
m /L
S*min
%
n.a,
n a.
Fluoride
n.a.
n.a.
n a. n.a.
n.a.
n.a
n.a
Chloride
n a.
n.a.
n.a n.a.
n a.
n.a.
n a.
Nitrite-N
n.a.
n.a
n.a. n.a
n.a
n.a.
n a.
Bromide
n.a.
n.a.
n a. n.a
n.a.
n.a
n.a.
Nitrate-N
n a
no
n.a. n.a.
n.a
n.a.
n.a.
O-Phosphate-P
n.a.
no
n a. n.a
n.a
n.a
n.a.
Sulfate
n.a
n a.
n.a. n.a.
n a.
Total:
0.0000
0.000 0.000
0.00
GEL Report RT-Devllnlegration
Page 62 of 62 SDG: 629087
Chromeleon (c) Dionex 1996-2006
Version 7 2 10.23925