Aberdeen Pesticide_Dye Test_20120601

NCDNR
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Beverly Eaves Perdue
Governor
Harold Moats
Syngenta Crop Protection, LLC
P.O. Box 18300
Greensboro, NC 27419-8300
Charles Wakild, P. E.
Director
June 1, 2012
RE: Approval of Injection Well Dye Tracer Test
Aberdeen Pesticide Dumps Site — McIver Superfund Site
Dear Mr. Moats:
Dee Freeman
Secretary
The subject proposal for injection of Rhodamine dye, received on May 22, 2012, has been reviewed.
The proposed injection project as presented meets relevant state regulatory requirements (15A NCAC
2C.0200) for construction and operation of injection wells. Due to the site's coverage under the
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), the state's
administrative permitting requirements have been waived. for this project. If you have any questions
regarding this letter or the UIC Program, please contact me at [e-mail] or 919-807-
6412.
Best Regards,
J
Thomas Slusser, L.G.
UIC Program Manager
cc: . Doug'Rumford, DWM Superfund Section
qui er Protectton Section— - ;M 7 ill e Regions Odic
UIC files DGNR-FRO
JUN 0.5 2012
_ . WQ
AQUIFER PROTECTION SECTION
1636 Mail Service Center, Raleigh, North Carolina 27699-1617
Location: 512 N. Salisbury St. Raleigh, North Carolina 27604
Phone: [phone] FAX: [phone] one,
Internet: www.ncwaterpuality.orglweblwolaps NorthCarolina

NCDENR
North Carolina Department of Environment and Natural Resources
Division of Waste Management
Beverly Eaves Perdue Dexter R. Matthews
Governor Director
May 23, 2012
Mr. Thomas Slusser
UIC Program Manager
Aquifer Protection Program
1636 Mail Service Center
Raleigh, NC 27699-1636
Dee Freeman
Secretary
Reference: Dye Tracer Study, Aberdeen Pesticide Dumps Site- McIver Dump.Area, Aberdeen, NC,
CERCLA Verification
Dear Mr. Slusser:
This letter is to certify that the Remedial Action being conducted. at Aberdeeri.Pesticide Dumps Site- McIver
Dump Area is being conducted under the CERCLA program. The proposed work is being performed in
accordance with the June 4; 1999 Record of Decision between the United States Environmental Protection
Agency, North Carolina Department of Environment and Natural Resources, and Syngenta Crop Protection,
LLC. Per N.C.G.S. 130A.310 -(e), "For any removal. or remedial. action conducted entirely on -site under this
Part, to the extent that a permit would .not be required under 42 U.S.C. § 9621(e) for a removal or remedial
action conducted entirely on -site under CERCLA/SARA, the Secretary may grant a waiver from any State law
or rule that requires that an environmental permit be obtained from the Department." Per this statute, Syngenta
Crop Protection, LLC would like to obtain a Letter of Consent to Inject for this pilot study/clean-up rather than
a Class 5I UIC Permit. I concur with_this request. The Class 5I UIC Permit application has been mailed to your
office and should be in your possession.
If you have any questions or need any additional information contact me at [phone].
'Sincerely,
Doug R ford
Hydrogeologist
NCDENR-Superfiind Section
cc: Tom Mama-SynTerra Corp..
1646 Mail Service Center, Raleigh, North Carolina 27699-1646
PhoneTax: 919-707-82001 Internet httpJlportal.ncdenr.orgitaebhvml
An Equal OpporlunllyAAffim aliveAction Employot
NorthCarol:irla
awtaa I

f
sue _r
Terra � ".
May 18, 2012
Mr. Thomas Slusser
NCDENR, Division of Water Quality .
Aquifer Protection, Underground Injectiot-Control Program
1636 Mail Service Center
r Raleigh, North Carolina 27699-1636
RE: bye "Tracer Test -UIC Permit Application
Aberdeen Pesticide Dumps Site .McIver Site .
Aberdeen, North Carolina
Dear Mr. Slusser:
i
On behalf -of_ Syngenta Crop- Protection, L:LC.;- please find .enclosed- a completed UIC
Permit ,application, to conduct= a';dye "tracer: test .at the McIver Site of the. Aberdeen =
Pesticide Dumps Site. Included: with .the permit, application are "required figures, an
attached write up that details. the history,:'hydrogeology, composition of the injection
_ fluid, injection rationale, injection procedure; _and injection equipment, as, well as the
material safety data sheet (MSDS) of the dye that-WM be used.
If you have any.questions, please contact me at (864).527-4637. -
Sincerely,
r SynTerra Corporation:. .
Ted Volskay
RECEIVENDENR/M
Li Attachments:
Permit application figures; MAY 2 2 2012,
i Permit application McIver Site description;, and
1417
- MSDS — FWT RedTM 25 Liquid (Bright DyesTM)
Aquifer Protection.Section
INNOVATE 148 River Street, Suite 220 Greenville; SC 29601 (864) 421=9999 : Fax [phone] www.synterracorp.com
l

Dye Tracer Test — UIC Permit Application
Aberdeen Pesticide Dumps Site — McIver Site
March 28, 2012
Page Two
Electronic cc: - -
Luis Flores — USEPA
Doug Rumford - NCDENR
George Crouse - Syngenta
Howard Grubbs, Esq. - WCS&R
Tom Mann — SynTerra . '
INNOVATE 148 River Street, Suite 220 Greenville, SC 29601 [phone] Fax [phone] www.synterracorp.com

State of North Carolina
L � l Department of Environment and Natural Resources
Division of Water Quality
L JI APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
_ _Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells —Tracer Injection
• Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject the treated groundwater,,
• -Submit TWO copies of the completed application and all attachments to the address on the last page of this form.
qqa Any changes made to this form will result in the application. package being returned,
Application Number (to be completed by DWQ):
I. GENERAL INFORMATION:
1. Applicant's Name (generally the responsible party. S;geniaCwap 1?rofc etion, LLC
2. Signing Official's Name*.: Harold Moats . Title: Corporate Remediation Manager
*:Signing Official must be in accordance with instructions in part VI on page 7.
3. Mailing address of applicant: Syngerita Crop- Protection, LLC
41 Q Sumg itoad P.O 13ox I:831)Q'
City - - ....... Greensboro.... _ w. _ . State: NC Zip, 2741.9 8360
--_
Telephone number, (336).632-7714 ..Fax number 4336) 632-2192
4. Property Owner's Name (if different from. Applicant): Joseph Monroe
5. Property Owner's mailing address:, ..... P.O.-Box 261 _....
f1 Cityt Aberdeen „State: NC Zip. 28315
6. Name and address of contact person who can answer questions about the proposed .injection project:
Email Address: [e-mail]
II. PERMIT INFORMATION:;
1. Project is: (X) New ( Modification of existing permit ( Renewal of existing permit without modification
j( Renewal of existing permit with modification
2. If this application is being submitted for renewal or,modification to an existing permit, provide:
( i existing permit number ..and the issuance date
1 1 For renewal without modifications, fill out sections I & II only, sign the certification on the last page of this
IJ form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner).
For all renewals, submit a status report including monitoring results'of all injection activities to date.
RECEIVEDIDENRIM
Revised 6/09 UiC-SI/ST Page 1 of 9
MAY 2 2 2012
Ani iifer Protection Section

i
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
JType 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
III. INCIDENT, & FACILITY DATA
A. FACILITY.INFORMATION..
1. Facility name: Aberdeen Pesticide Dumps Site —McI)g& perfund.Site
2. Complete physical address of the 11h0 : - :. Coordinates:_ .35°..07' 57.3T' N 7.90 27' 27.67" W ...
Road
City: Aberdeen,.. County. Moore State: NC Zip: 28315
B , INCIDENT DESCRT....
1. Describe the source of the contamination:.. The .McIver Sup.erf 6d Site..is a former_dump site that received:
pesticide ormulatlon haste tt duets froze a.l ical esticide forrnulatltan/dis Ibuto"r fasili'ty TFit Mcluei: Site r�ras:
discovered by N:CDENR In I984 and spas }laced on the NI' m t g, .l:l c Melyel'ltemedta) lltvesti�ation,was.
iriitlated in 1.9..anil eonlpletecl',m .1997._Contatnnatcd Nfclvel:,S'itesciilswere eeavatcl and tiilen tcan off$Ite'
loeatiori to be Cleated U51 fli&iih 1 Ci4'SOrptlbil Tleated'SOIIS W IC rSlerlto bPrGl "' c1]1Cl 1' ar,6� Dh, iEdxtO t &.
McIver site as clean fill in 1997. The McIver Site Feasibility Study was completed in 1998 and the Record of:
1)ecislonwas s►.gged on'fune 4' 1999.I he sel'ected:relnedy;,periodlc groundwater monifioringltytoremedlatidti
.and area ree6nnaissance,..is_on oin
2. List all contaminants present in soils or groundwater at the site (contaminants maybe listed in groups, e.g.,
gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides; etc);i
-NIcIv r_S`ctc so17s have: hee remecfia ecl and eontmn no contamination. ___ iVlc.Ivel.Slte.groundwater coii6ijr s.
_..
,isomers..of.._benzenehexachloi:i ie� C .delta 13H.0 an6.'6inJn BHC wlii6h:. s a pesticide
3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)?
Yes If yes, list maximum measured separate phase thickness
( X) No If no, list maximum concentration of total VOCs obser d at site:. No VOC contamination ppb
4. Agency managing the contamination incident:
( UST Section (X) Superfund Section (including REC Program_ and DSCA sites)
(DWQ Aquifer Protection Section ( Solid Waste Section
j ( Hazardous Waste Section
5., Incident managers name I�U and phone number ... E564 H_�_
r—
6. Incident number or other site number assigned by the agency managing the contamination incident:
�! EPA ID # NCD 9808433.46 ._OUS McIver Area
Revised 6/09
UIC-5I/5T
Page 2 of 9
0

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells —In Situ Groundwater Remediatibn / Type 5T Wells —Tracer Injection
C. PERMITS
List -all permits or construction approvals that have been issued for the facility or incident, including those not
directly related to the proposed injection operation:
1. Hazardous Waste Management program permits under RCRA: Not -Applicable
2. DWQ Non -Discharge or NPDES permits: Not Applicable
3. County or DEH subsurface wastewater disposal permits: Not Applicable
4. Other environmental permits required by state or federal lave! Not Applicable:
Revised 6/09 UIC-5I/5T Page 3 of 9

Ll
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
' IV. INJECTION DATA
A: .INJECTION FLUID DATA
l . List all proposed injectants.
NOTE: Any substance to be injected as a tracer. or to promote in situ remediation must be reviewed by the
Occupational and Environmental Epidemiology Section (GEES) of the Division of Public Health, Department of
Health and Human Services. Review the list of approved injectants or contact the UIC Program to determine if
the injectants you are proposing have been reviewed by GEES
Injectant: Bright Dyes FWT Red 25 (Liquid) (also known as Rhodamine WTI
...:..::... .
Concentration at point of injection: -:
Percent if in a mixture with other injectants: Not.a.:mixture
Injectatt:. _.:::. .....
Concentration at point of injection _
_ ..... _._.....
Percent if in a mixture with:other injectants:,
Injectant: .
Concentration at point of injection:
__.
Percent if in a mixture with other injectants: ...._- ._. _...._ ........
Injectant;
Concentration at point of injection _.,_
Percent if in a mixture with other injectants::._
2. Source of fluids used to dilute or chase the injectants listed above:
(X) None
( Municipal water supply
( Groundwater from private well or any well within A mile of injection site
( Air
( Other:
3. If any well -within '/a mile of injection site, a private well, or surface water is to be used as the fluid source, supply
the following information:
a. Location/ID number ofs9wce:; N:ot.AmAicable
b. Depth of source:
c. Formation:
d. Rock/Sediment type:
e. In Attachment C, provide a current, complete chemical analysis of the water from the source well, including
analyses for all contaminants suspected or historically recognized in soil or groundwater on the site.
NOTE: If contaminated groundwater is to be used as the dilution or chase fluid, this is not the proper permit
applicationform. You must apply for a closed -loop gr bundwater remediation permit using application form
GWRS.
Revised 6/09 UIC-5I/5T Page 4 of 9

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells --In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
B. PROPOSED OPERATING PARAMETERS
rl
1. Duration of Injection: <1 day
a. Maximum number of separate injection .events: - 1
_I b. Expected duration of each injection event: 5 minutes
c. Expected duration between events (if more than one event): Not Applicable
2. Injection rate per well: <0.2 gpm (or 500 m lmin) gallons per minute (gpm)
f
L�J 3. Total Injection volume: gallons per day (gpd); 0.13 gal (or 500 ml) gallons per event (if separate
events)
1 4. Injection pressure: 0 (gravity feed at atmospheric pressure) pounds/square inch (psi)
lv i
5. Temperature at point of injection:- Ambient outdoor temperature OF
6. Briefly describe how the above parameters will be measured and controlled: A polyethylene tube attached to
a funnel will be extended into the injection well and below the water table. One 500 ml bottle of Rhodamine WT
(- tracer dye will be poured into the well.
7.
Estimated hydraulic capacity of the well: > 500 ml/min gpm
I'
L�
C.
INJECTION WELL CONSTRUCTION DATA
1.
Injection will be via:
(X) Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the
best of your knowledge.
t- J
( Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as
proposed construction specifications.
H2.
Well Drilling Contractor's Name: Not Applicable
NC Well Contractor Certification number:
3.
Date to be constructed: Existing well (PT-9) Number of borings:
`
Approximate depth of each boring (feet):
�J�
4.
Screened interval/Injection interval of injection wells:
Depth: 10 to 15 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth).
LJ
5.
Well casing (N/A if injection is through direct push rods):
Type: (X) PVC ( Stainless steel( Other:
Casing depth: 0 to 15 ft.
6. Grout (N/A if injection is through direct push rods):
Type: ( Cement ( Bentonite (X) Other:_Grout (Cement) 0 ft. to 2 ft. and Bentonite 2 ft. to 9 ft.
Grout depth: 0 to 2 ft.
Revised 6/09 UIC-5I/5T i Page 5 of 9
0

f
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
V. ATTACHMENTS
Provide the following items as separate attachments with the given headings:
A. SITE HISTORY
Provide a brief description of the site history including:
(1) site usage historically and present,
(2) - origin of the contamination,
(3) previous -remedial action(s).
NOTE; G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the
public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under their
direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work prepared or approved
by a licensed geologist; or a subordinate under their direction, be signed and sealed by the licensed geologist.
r_.
B. HYDROGEOLO.GIC DESCRIPTION'
Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth.that includes the
known or projected depth, of contamination. The hydrogeologic description. shall include:.
(1) the regional geologic setting;
(2) significant changes'in lithology;
(3) the hydraulic.conductivity, transmis"sivity, and specific yield of the aquifer to be used for injection, including a
description of the tests) used to determine these parameters; and
(4) the depth to the mean seasonal high water table.
C.; tINJEG7'CON'FLUID OC)1yIl O:SITIO:N
Describe the chemical, physical, biological and radiological characteristics. of each injectant. Attach the Material Safety
Data Sheet (MSDS) for each injectant. If a private well or a well within 'A mile of the injection site is used as the source
well, include chemical analysis of source fluid here.
Dr INJECTION RATIONALE
Attach a brief description of the rationale for selecting the -injectants and concentrations proposed for injection, including:
(1) goals of the injection project;
(2) explanation and/or calculations of how the proposed injectant volume and concentration were determined;
(3) a description of the reactions between the injectants and the contaminants present including specific breakdown
products or intermediate compounds that may be formed by the injection; and
(4) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change
(biological, chemical or physical) in the subsurface.
E. iNJECTION.PROCI:I? I:T:ZL AND,EQUI:PMEN:I
Provide a detailed description of all planned activities related to the proposed injection including but not limited to:
(1) construction plans and materials;
(2) operation procedures;
(3) a detailed diagram of the surface and subsurface portions of the system; and
(4) a planned injection schedule.
Revised 6/09
UIC-51/5T
Page 6 of 9

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells -.In Situ Groundwater Remediation / Type ST Wells - Tracer Injection
F. MONITORING PLAN
Provide a plan for monitoring the results of the injection, including:
(1) a list of existing and proposed monitoring wells to be used;
(2) a list of monitoring parameters and analytical methods to be used; and
(3) a schedule for sampling. to monitor the proposed injection.
NOTE: The selected monitoring wells must be- located so as to detect any movement of injection fluids, process by-
products, or formation ,fluids outside the injection area or zone. The monitoring parameters should include the target
contaminants as well as secondary or intermediate contaminants which may result from the injection and other
parameters which; may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved oxygen, and
other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated
reactions and rate of transport of the injectants and contaminants.
G. WELL DATA
Provide a tabulation of data on all existing or abandoned wells within '/a mile of the- injection well(s) which penetrate the
proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells.
Such data shall include a description of each well's use (water supply, monitoring; etc), total depth, screened or open
borehole depth interval, and well construction -or abandonment record, if available.
H. MAPS _.
- ,j Attach the following scaled, site -specific maps;
(1)
Area map based on the most recent USGS 7.5' topographic_ map of the area,. at a scale of 1:24,000.and
t
showing the location of the proposed injection site.
}
(2)
Site map including:
j
a. all property boundaries;
b. all buildings within the property boundary;
c. existing and proposed injection wells or well field(s)
d any existing sources of potential or known groundwater contamination, including waste storage,
treatment or disposal systems within"/4 mile of the injection well or well system;
e, all surface water bodies within'/ mile of the injection well or well system; and
f. all existing or abandoned wells within'/a mile of the injection well(s) which penetrate the proposed
injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection
wells.
l
(3)
Potentiometric surface map(s) including:
a. direction of groundwater movement
b. existing and proposed monitoring wells
(4)
c. existing and proposed injection wells
Contaminant plume map(s) including:
a. the horizontal extent of the contaminant plume, including isoconcentration lines
_
b. existing and proposed monitoring wells
c. existing and proposed injection wells
(5)
Cross-section(s) to the known or projected depth of contamination, including:
a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines
b. major changes in lithology
! I
c. existing and proposed monitoring wells
d. existing and proposed injection wells
Revised 6/09
UIC-51/5T
Page 7 of 9
L�

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells —In Situ Groundwater Remediation % Type 5T Wells — Tracer Injection
IF
0
Revised 6/09
UIC-5I/5T
Page 8 of 9
0

VI.
VII.
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells —In Situ Groundwater Remediation / Type 5T.Wells — Tracer Injection
CERTIFICATION (to be signed as required below or by that person's authorized agent)
NCAC 15A 2C .0211(b) requires that all permit applications shall be signed as follows:
1. for a corporation: by a responsible corporate officer
2. for a partnership or sole proprietorship: by a general partner or the proprietor, respectively
3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or
ranking publicly elected official
4. for all others: by the well owner.
If an authorized agent is signing on behalf of the applicant, then supply a letter signed by the applicant that
names and authorizes their agent.
I hereby -certify under penalty of law that I have personally examined and 'am familiar with the information
submitted in this document and all attachments therein, and that, based on my inquiry of those individuals
immediately responsible for obtaining said information, I believe that the information iss true, accurate, and
complete.. I am aware that there are penalties, including the possibility offines and imprisonment, -for submitting
false information. I agree to construct, operate, maintain, repair-, and if applicable, abandon the -injection well(s)
and all related appurtenances in accordance with the approved. specifications and conditions of the Permit.
Printed Name and
. Re
CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant)
P
("Owner" means any person who holds the fee or other property rights in .the. well being constructed. A well is
real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of
contrary agreement in writing.)
As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to
allow the applicant to construct each injection well as outlined in this application and agree that it shall be the
responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards
(Title 15A NCAC 2C .0200).
Printed Name and Title:
Signature:..._..... _.._. Date:
Submit TWO copies of the completed application package, including all attachments, to:.
UIC Program
Aquifer Protection Section
North Carolina DENR-DWQ
1636 Mail Service Center RECEIVED/DEN
Raleigh, NC 27699-1636 R/D�Q
Telephone [phone] MAY 2 2 2012
Revised 6/09 UIC-SI/ST Aquifer Protection Secti4age 9 of 9

VI.
VII.
APPLICATION FOR. PERMIT TO CONSTRUCT AND/OR USE A WELLS) FOR INJECTION
Type 5I Wells - In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
CERTIFICATION (to be signed as required below or by that person's authorized agent)
NCAC 15A 2C .021l(b) requires that all permit applications shall be signed as follows:
1. for a corporation: by a responsible corporate officer
2. for a partnership or sole proprietorship,• by a. general partner or the proprietor, respectively
3. for a municipality or a state, federal, or other public agency: by either -a principal executive officer or
ranking publicly elected official
4: for all others: by the well owner.
If an authorized agent is signing on behalf of the applicant, then supply a letter signed by the applicant that
names and authorizes their agent.
I hereby certify under penalty . of law that I have personally examined and am familiar with the information
submitted in this document and all attachments therein; and that; based on my inquiry of those individuals
immediately responsible for obtaining said information, I believe that the information is true, accurate, and
complete. I am aware that there are penalties; including the possibility of fines and imprisonment, for submitting
false 'information. I agree to construct; operate; maintain, repair, and if applicable, abandon the injection well(s)
and all related appurtenances in accordance with the approved specifications and conditions of the Permit.
Printed Name and Title:
Signature,: Date._,..... r. . ........:.. ...........
CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant)
("Owner ". means any person who holds thefee or other property rights in the wellbeing constructed. A well is
real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of
contrary agreement in writing.)
As owner of the property on which the injection well(s)-are to be constructed and operated, I hereby consent to
allow the applicant to construct each injection well as outlined in this application and agree that it shall be the
responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards
(Title 15A NCAC 2C .0200).
Printed
Date:..,',° 1�--
Submit TWO copies of the completed application package, including all attachments, to:
UIC Program
Aquifer Protection Section
North Carolina DENR-DWQ
1636 Mail Service Center
Raleigh, NC 27699-1636 RECEIVED/DENRIDWQ
Telephone [phone]
MAY 2 2 2012
Revised 6/09 UIC-51/5T Aquifer Protection SectioPan �e 9 of 9

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Source: Moore County GIS (2012)
FIGURE 1
http:/lwww.co.moore.nc.uslndex.p*ed/data-download
USES TOPOGRAPHIC MAP
This map is a productof SynTerra.. Reasonable efforts have been made to
ensure the accuracy of this map. SyhTerra expressly disclaims
any responsibility or []ability with regard to the use of this map, and promotes
MCIVER DUMP AREA
and recommends the independent verification of any data contained on:this
map by the user of this map product.
s)
Created: 7/1612012 try: R: Berber
e1 ,.W ■ ■
ABERDEEN PESTICIDE DUMPS SITE
MOORE COUNTY, NORTH-CAROLINA

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4t1 { i t} I LEGEND
df d� tr :'tL } s ♦ — Site Property Boundary
d is
74.
; • > ' - _ ,,i Street (Moore County 2012)
Surface Water (Patterson.Branch)
Parcel Boundaries (Moore County 2012)
� Y�`— Ier i y- V O Structures (Moore County 2012)
i fa a �•r; a d + t 4 :� Monitoring Well
Piezometer Well
di I
AM
I j �lC FIGURE 2
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SITE MAP
MP MOVER D
y� �'' �''< ; � ; � 't It •+�: �� , .: s - � : ,,, ,� U AREA
ABERDEEN PESTICIDE DUMPS SITE
MOORE COUNTY, NORTH CAROLINA
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fP.r-10
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yTn�+. r- �r'c����i���f 04'MW=02. •4t.� `�'� n. � j` i rr� � s t. � . k;!'p'�•.k:
"GiZsRl�fJ-�1'+O •,371.07 '�' r. `,l`t ry �. {; .. ' ®. ,r' . r r.f '',f,.° w1 _c '_ pL4';-•
•N { s'Y 372 F �t� � �--' . - - ... _-�,r`sa'^'li � ' .. +/ t r �'M6 MWA5 �w .4�
• _ (/!r' - .:'t - i ,., _tyr MC-MW 10 x ,f
66.85
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ae
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t1 P
; ��� , �`,u ,` , `;•y tL '11 ' ,' OTENTIOMETRIC MAP
1r`ti i1 10
MCIVER DUMP AREA
ABERDEEN PESTICIDE DUMPS SITE
MOORE COUNTY, NORTH CAROLINA
r. to Monitoring Well
synTena
4.
• Piezometer s-5ft<aarroy—fi.1dmoa,°-1.
" r�r "r - _ �'•� Groundwater T1tl°map"•R0°'"'°'synTaro.a<a°a,aon<ronanmab..madam I4j
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Y arty pwwaTH EaN'Ry w2AragaIOb un usa of Ws m<p ah pmmm6a
t �� by W=pmw,
Surface Water (Patterson Branch) "oN°apon°° `"°"Hono1any°°°`"" 8°°" "'°
J� '' " •` 371.81 Groundwater Elevation Measured P:,<r�•d,oan„d.dao.vm�•�nacw,mmno_,_wku.o�°,Zm me
f n on March 2012. o 70 140
Feet,
_ ailkt.,.

031 Y Patterson Branch '
Kw-:
MC-MW-11
PT-
alpha-BHC 0.093
ij beta-
0.530
U--IJZ� 77
a
(l ;: —
r j['yqu)tu,ff
12! 1
4 .L
q--'A'. •Mc
W.
alpha-BHC <0.00061
MC-MW-09 PT� 9 MC.MW-10 beta-BHC 0.00110
W-03
alpha-BHC 0.0023 a1ph(uL0Q050
alpha-BHC -50.00057 beta-BHC 0.0017 i a-'jMHC—<0.001T
�i`; beta.BHC 0.035000 r, 4
beta.BHC <0.00065 0.0040 i 0.035590
<0.01112
ffAki.,
LA
M
N L
Z.
04-PZ-01
alpha-I3HC<0.00057 "IL
pel.a BHC <0 00055
may, y
0.00112 -W j
r alpha-BHC 0.00
beta-BHC 0
0.0070 FIGURE 4
% -_
TOTAL ALPHA AND BETA
Ct ISOCONCENTRATION MAP
%
McIVER DUMP AREA
ABERDEEN PESTICIDE DUMPS SITE
MOORE COUNTY, NORTH CAROLINA
synTpna
N
.—aeqy eft" map�SpT.ps �—fy da�J.I.
Legend Fpepp�WAY I UNIAV WM W9.0 tO 010 UW W M map,yy5prompla
4 md�mmwdsfthdepew�wff�oonof,,YdaWwntamdmW,
map by the sor of the map pmdzt
Monitoring Well
A Piezorneter 0
70 140 Ma
Feet

"LITTV "IT T
Bcaver mclmw
Pond
"v-
17,
-02
_P,T,03
Ins.
L 0
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/
mtfmvv-09, M 1� 4
u_ _A,
�.emc-mw-lo
Proposed Injection Well
(PT-nq)
All
-!4
06
%
J,
V%> FIGURE 5
CROSS-SECTION MAP
•
NA.: McIVER DUMP AREA
ABERDEEN PESTICIDE DUMPS SITE
q MOORE COUNTY, NORTH CAROLINA
J, 4V
synTena
:Sll­Wawftldmwwn­
TNj map V a pmWd d SynTma. R—bWOW. h— Coen matlP to N
Legend —1 flo �NAIY —,i mo '5 g, .1 ml le I I mll lo If 6 � d
Y.e­P""' o'ws _Pmd,cl
MonitofinWell
Piezometer 0 70 140
Feet
A.* all: _j

A A'
380
370
360
d
d,.
u..
350
0
M
a�
W
340
330
320
MC-MW-04 MC-MW-04D PT-01 MC-MW-11 MC-MW-05D
MC-MW-05
VADOSE ZONE
SOIL
L AQUIFER
NIS
�141y�
'
F'z" tH�sf S �' I n^ ' a Rkryr4"" A `
CONFrIxNED �AQ,UI�FER � r� f
�2b7'
A.'iC�s"�i,
� �
n 4T t'M'^��w.t '"„it 9 �' c pr,„f# cc r'b Rr,v�G kk�•�y �5+ �r, S �_
380
370
360
350
340
330
32-0
Note: Approximate horizontal scale
March 2012 October 2011 FIGURE SA
Water Table Elevation Total alpha- and beta-BHC
(Surficial Aquifer) 0 concentrations (>0.01 ug/L) GEOLOGIC CROSS SECTION A -A'
Water Table Elevation Total alpha- and beta-BHC tip MCIVER DUMP SITE
(Confined Aquifer) concentrations (>0.1 ug/L)
Source: Water Level Source: McIver Dump Site, Aberdeen ! ABEFtDEEN PESTICIDE DUMPS SITE
Measurement March 2012 Pesticide Dumps, 2011 Annual Report M OO RE COUNTY, NORTH CARO LI NA .

B
400
390'
B'
400
390
380 1
370.
360
350
3.40
330
March 2612 October 2011• FIGURE 5B
Water Table Elevation Total alpha- and. beta-BHC. , •
_.
® GEOLOGIC CROSS. B=B
(Surficial Aquifer) concentrations (>0.01•ug/L)
Total alpha- and beta-BHC MCIVER DUMP SITE
concentrations .(>0:1,ug%L) Source: Water Level Source: McIver Dump Site, Aberdeen
synTerra. ABERDEEN PESTICIDE. DUMPS SITE.
Measurement March 2012. Pesticide Dumps, 2011 Annual Report MOO RE COUNTY; NORTH CAROLINA

f
UIC Permit Application Attachment
Dye Tracer Study
Aberdeen Pesticide Dumps Site - McIver Site
March 28, 2012
Site History
The McIver Site received material from a pesticide formulation plant.that was once located in Aberdeen.
The material contained pesticides and pesticide constituents. The McIver Site was discovered by
NCDENR in 1984 and was placed on the National Priorities List (NPL) on March 31, 1989. 'On June 30,
1987, the EPA initiated a Remedial Investigation and Feasibility Study (RI/FS) for the site. The initial RI
for the McIver Site was completed on April 12, 1991. During this time, the EPA determined that the
surface water, sediments, and groundwater required further investigation. A subsequent RI was
initiated in 1994 and completed in 1997. Pesticide contamination in soils was delineated, contaminated
soils were: excavated, and the soils were treated using thermal desorption at an offsite location in 1997.
The treated soils were returned to the McIver Site as clean fill. The McIver Site FS was completed in
1998 and the Record of Decision (ROD) was signed ,on June 4:, 1999. The selected remedy, periodic
groundwater monitoring, phytoremediation, and area reconnaissance isongoing.
Hydroeeoloeic Description
Relevant to the proposed McIver Site dye tracer study.are the Upper portion of the Lower Black Creek
(ULBC) Aquifer and the Lower portion of the Lower Black Creek (LLBC) Aquifer. The dye tracer study will
be conducted only in the ULBC Aquifer, which is under unconfined conditions at the McIver Site.
Underlying the ULBC Aquifer is a relatively thin -but continuous clay layer that serves as a local confining
unit that separates the Lower Black Creek Aquifer into "upper" and "lower" portions. The LLBC Aquifer
is under confined conditions at the McIver Site.
There is a difference in the potentiometric surface levels between the ULBC and LLBC Aquifers. The
potentiometric surface in the LLBC Aquifer is higher than the potentiometric surface in the ULBC
Aquifer. Wells MC-MW-4/MC-MW-5 and MC-MW-4D/MC-MW-5D are screened in the ULBC and LLBC
Aquifers, respectively. Both well pairs have upward vertical gradients. In October 2011, the
potentiometric surface of MC-MW-4D was 1.85 ft.,higher than well MC-MW-4 and the potentiometric
surface of MC-MW-5D was 1.75 ft. higher than well MC-MW-5.
In general, the groundwater flow direction in the ULBC Aquifer in the vicinity of.the McIver Site is to the
north-northeast and perpendicular to Patterson Branch'. However, the beaver dam constructed
between McIver Areas B and C has resulted in the creation of a pond directly across from Area B. The
beaver pond has decreased the hydraulic gradient across Area B but has little, if any, effect on
groundwater flow in Area C.

According to the Record of Decision (ROD), the average hydraulic gradient in the ULBC Aquifer is 0.02
ft./ft. and the hydraulic conductivity ranges between 2.73 x 10-2 cm/sec to 3.44 x 10-3 cm/sec.
Consequently, the theoretical groundwater velocity in the ULBC Aquifer is 325 ft. per year. If this
groundwater flow velocity is accurate, the dye from well PT-9 should reach well PT-1 in 4 to 6 months.
Iniection Fluid Composition -
The injection fluid will be a -red fluorescent dye called "FWR, T edTm 25 Liquid" that is manufactured by
Kingscoat Chemicals and marketed under the name of Bright DyesTM. The material safety data sheet
(MSDS) for the FWT Red TM 25 Liquid indicates that the dye material is in the "xanthenes dye form"
chemical family and that it contains 0.375% trimellitic acid (CAS# 528-44-9). No other ingrediants are
specified in the MSDS. The MSDS is attached.
Infection Rationale
The FWT RedTm 25 Liquid will be introduced into the groundwater at well PT-9 per the Injection
Procedure._ Based upon potentiometric data, it appears that wells'PT-8, PT-7, PT-6, PT-5,,PT-4, PT-3; PT-
2, PT-1, and MC-MW41, are directly downgradient relative to the injection well (PT-9): Consequently, it
is anticipated that the dye will eventually be detected at each of these wells as it migrates from the
injection well.
liniection"Procedure And Equipment
Injection equipment:
• 1 bottle of FWT RedTm 25 Liquid(1 pint);
• 20 feet of new 1/2-inch clear poly tubing; !
• Powder free nitrile gloves;
• Funnel;
• Bailer and rope or peristaltic pump and tubing;
• Bottleware for each downgradient well (<500 ml); and
• Fluorometer.
Injection Procedure:
Step 1: Personnel will don powder free nitrite gloves.
Step 2: Open the PT-9 protective casing and lower the clear poly tubing to the bottom of well.
Step 3: Attach the funnel to the end of the poly tubing.'
Step 4: Pour 1 pint of the FWT RedTm 25 Liquid into the funnel/poly tubing.
Step 5: When all of the dye has been received by the well, withdraw the poly tubing and secure the
well.

Step 6: Periodically (approximately monthly) collect a small sample of groundwater from each of the
downgradient groundwater wells.
Step 7: Using a fluorometer capable of detecting and quantifying fluoroesence from Rhodamine WT,
measure and record the amount of fluoroesence in the samples collected: from each
downgradient well.
Step 8: Based upon time and distance, calculate the time of travel (groundwater flow velocity) after the
dye has reached the most downgradient well.
A
i

BRIGHT DYESS' MATERIAL SAFETY DATA SHEET
FWT RED" 25 LIQUID
PAGE I OF 3
.. ... . .....
.. .. ............... .
MSDS PREPARATION INFORMATION
.. . ..... .....
PREPARED BY: T. P. MULDOON EMERGENCY RESPONSE; TNFOTRAC
[phone] USA/cANADA/MLXICO:' [phone]
DATE PREPARED; 11/9/11 INTERNATIONAL: [phone]
. ... ... ... ..
PRODUCT INFORMATION
.... ... ...
MAUNFACTURED BY:: KINGSCOTE CHEMICALS
3334 S. TECH BLVD.
MIAMISBURG, OHIO 45342
TRIMELLITIC ACID NONE 5.2844-9
LD150, SPECIES LC150, SPECIES.
ORAL (MOUSE)
2500 MG/KG NONE AVAILABLE
DERMAL,(RABBIT)
........ .... .... ... . . .......
NOT AVAILABLE NOT AVAILABLE
. ... ...... . ..
. . ....... .
..... . ...
PHYSICAL DATA
... .........
PHYSICAL STATE
....... LIQUID
ODOR AND
------- DARK RED LIQUID WITH MILD ODOR
SPECIFIC GRAVITY......
—1.03
VAPOR DENSITY (mm Hg-@ 25 C).__'o"-, NOT APPLICABLE
VAPOR DENSITY (AIR =1) ...
NOT APPLICABLE
EVAPORATION RATE (Butyl Acetate —
-
1). PPLICA5LE
BOILING POINT,
—100 degr.�qs. C (212. degrees. F)
--------- --- FREEZING POINT,
0 degrees"C (32 degrees F)
TO 8.8
SOLUBILITY IN WATER,
VERY SOLUBLE
FIRE HAZARD
CONDITION OF FLAMMABILITY NON-FLAMABLE
-------------------
MEANS OF EXTINCTION._ WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, WEAR
.............
SCBA
FLASH POINT AND METHOD NOT APPLICABLE
--------- --
UPPER FLAMABLE LIMIT; •-NOT APPLICABLE
LOWER FLAMABLE LIMIT APPLICABLE
AUTO -IGNITION TEMPERATURE .NOT APPLICABLE
HAZARDOUS COMBUSTION PRODUCTS BURNING MAY PRODUCE OXIDES OF CARBON & NITROGEN
UNUSUAL FIRE HAZARD,,..,- NOT APPLICABLE

BRIGHT DYES"m MATERIAL SAFETY DATA SHEET
FWT RED"" 25 LIQUID
PAGE 2 OF 3
.EXPLOSION HAZARD
SENSITIVITY TO STATIC DISCHARGE,,,: _ •,. ,, ._„_,,._,:. _..NOT APPLICABLE
SENSITIVITY TO MECHANICAL IMPACT,, -.----.NOT APPLICABLE
REACTIVITY DATA
SYMPTOMS OF OVER EXPOSURE FOR EACH POTENTIAL ROUTE OF ENTRY.;
INHALLATION ACUTE y . TRIMELLTTIC ACID MAY CAUSE IRRITATION
INHALATION; CHRONIC
y
.. „ , rNOT KNOWN
SKIN CONTACT
BE IRRITATING TO THE SKIN. WILL CAUSE
_..
_ ,. ,.MAY
TEMPORARY STAINING OF THE SKIN ON CONTACT..
EYE CONTACT
MAY CAUSE IRRITATION
INGESTION
,_:..,URINE MAY BE A RED COLOR UNTIL THE DYE HAS BEEN
WASHED THROUGH THE SYSTEM.
EFFECTS OF ACUTE EXPOSURE �
. ._., ., DIRECT CONTACT MAY CAUSE IRRITATION TO THE EYES,
SKIN, AND RESPIRATORY TRACT.
EFFECTS OF CHRONIC EXPOSURE.,,,.,_
NOT KNOWN
THRESHOLD OF LIMIT VALUE
NOT APPLICABLE
CARCINOGENICITY
_ : NOT LISTED AS A KINOWN OR SUSPECTED CARCINOGEN BY
IARC, NTP OR OSHA.
TERATOGENICITY ,.___ �.
NONE KNOWN
MUTAGENICITY
_ _,__, _, CONFLICTING EVIDENCE AS TO MUTAGENICITY OF THE
DYE CONTAINED IN THIS PRODUCT,
TOXICOLOGY SYNERGISTIC NONEKNOWN
REGULATORY INFORMATION
SARA SECTION 303________NONE FOUND
______________________________,____.:,, _;___
SARA (311, 312) HAZARD CLASS________________ ,_ ____: IMIviEDIATE HEALTH HAZARD
SARA (313) REPORTABLE CHEMICAL (%):a__„ ,- -----:NONE
METAL CONTENT __________________________________________-___,__,__ ,__THIS PRODUCTJS NOT A METALLIZED DYE
TSCS INVENTORY STATUS____ ALL COIv'� ONE`ITS ARE INCLUDED ON TSCA SECTION 8
CALIFORNIA PROPOSITION 65 CHEMICALS: ........ NONE
TSCA SECTION 12 (B) EXPORT REGULATIONS:,.______,,, --- NOT SUBJECT TO TSCA 12 (b) EXPORT REGULATION
ECOLOGICAL INFORMATION
U
ECOTOXICOLOGICAL INFORMATION:__ LC50: >320 mg/L RAINBOW TROUT (96 Hour)
LC50: 170 mg/L DAPHINA MAGNA
NO DEVELOPMENTAL ABNORMALITIES OR TOXICITY TO OYSTER LARVAE AT 100 mg/L

I.
r
F-11
BRIGHT DYES'" MATERIAL SAFETY DATA SHEET
f FWT RED'" 25 LIQUID
PAGE 3 OF 3
PREVENTATIVE MEASURES
PERSONAL PROTECTIVE`EQUIPMENT
GLOVES ;
RUBBER
RESPIRATORY
_,,- ......NONE REQUIRED UNDER NORMAL -CONDITIONS
EYE PROTECTION
. GOGGLES
-
CLOTHING-,,----, ._
�_ :_:>_.:.... PROTECTIVE CLOTHING SHOULD BE WORN WHERE
CONTACT IS UNAVOIDABLE.
ACCESS TO EMERGENCY EYEWASH.
ENGINEERING CONTROLS
________ r ;,; ,_:NOT.NECESSARY UNDER NORMAL CONDITIONS USE LOCAL
VENTILATION IF DUSTY CONDITIONS EXIST.
SPILL OR LEAK RESPONSE
.,::..;...... ;,CONTAIN AND CLEAN UP SPILL IMMEDIATELY, PREVENT
FROM ENTERING FLOOR DRAINS. SWEEP POWDERS AND
PLACE IN WASTE DISPOSAL CONTAINER, FLUSH AFFECTED
AREA WITH WATER.
WASTE DISPOSAL
:._f ::.INCINERATE OR REMOVE TO A SUITABLE SOLID WASTE
DISPOSAL SITE, DISPOSE OF ALL WASTES IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
HANDELING PROCEDURES AND EQUIPMENT .............. NO SPECIAL REQUIREMENTS:
STORAGE REQUIREMENTS _______________
„_, "_. STORE AT ROOM TEMPERATURE BUT ABOVE THE FREEZING
POINT OF WATER
SHIPPING INFORMATION ..:_
<-.;- <,...:..: FROM FREEZING
________________________KEEP
FIRST AID MEASURES
FIRST AID EMERGENGY PROCEDURES
EYE CONTACT.,---.-- _
FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT
. . =.-.•..::-..-<--:-• _-_:>-:- WASH SKIN THOROUGHLY WITH SOAP AND WATER, GET
MEDICAL ATTENTION IF IRRITATION DEVELOPS.
INHALATION".__ ------ ,_
_:;_ _�;_„___________IF DUST IS INHALED, MOVE TO FRESH AIR. IF BREATHING IS
DIFFICULT GIVE OXYGEN AND GET IMMEDIATE MEDICAL
ATTENTION.
INGESTION ____________ _,_ __ _
DRINK PLENTY OF WATER AND INDUCE VOMITING. GET
..
MEDICAL ATTENTION IF LARGE QUANTITIES WERE
INGESTED OR IF NAUSEA OCCURS. NEVER GIVE FLUIDS OR
INDUCE VOMITING IF THE PERSON IS UNCONSCIOUS OR
HAS CONVULSIONS.
SPECIAL NOTICE
ALL INFORMATION, RECOMMENDATIONS AND SUGGESTIONS APPEARING HEREIN CONCERNING THIS PRODUCT ARE BASED UPON DATA
OBTAINED FROM MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES; HOWEVER, KINGSCOTE CHEMICALS MAKES NO
WARRANTY, REPRESENTATION OR GUARANTEE AS TO THE ACCURACY, SUFFICIENCY OR COMPLETENESS OF THE MATERIAL SET FORTH
_ HEREIN. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TdXICITY,'AND SUITABILITY OF HIS OWN USE, HANDLING, AND
DISPOSAL OF THE PRODUCT. ADDITIONAL PRODUCT LITERATURE MAY BE AVAILABLE UPON REQUEST. SINCE ACTUAL USE BY OTHERS IS
BEYOND OUR CONTROL, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE BY kfNGSCOTE CHEMICALS AS TO THE EFFECTS OF SUCH USE, THE
RESULTS TO BE OBTAINED OR THE SAFETY AND TOXICITY OF THE PRODUCT, NOR DOES KINGSCOTE CHEMICALS ASSUME ANY LIABILITY
ARISING OUT OF USE BY OTHERS OF THE PRODUCT REFERRED TO HEREIN. THE DATA IN THE MSDS RELATES ONLY TO SPECIFIC MATERIAL
DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS.
END OF MATERIAL SAFETY DATA SHEET