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HomeMy WebLinkAbout20080868 Ver 2_Appendix F - Metals 2014_20150717APPENDIX F 2014 Sediment and Water Column Metals (Data only on CD) Table F -1. Minimum and maximum 2014 values for each metal and the creek sediment in which it occurred. Control creeks are indicated with an asterisk ( *). Minimums shown with < represent the LOQ /CL (reporting limit/control limit). Metal AI ( %) As (Ng/g) Mo (Ng /g) Cd (pg/g) Cr (Ng/g) Cu (Ng /g) Fe ( %) Se (ug/g) Zn (pg/g) Min Max Min Max Min Max Min Max Min Max Min Max Min Max Min Max Min Max Range 0.03 2.98 0.08 5.04 <1.04 6.73 0.01 0.88 0.44 30.5 0.14 11.90 0.02 2.69 0.06 2.04 2.5 102 Creek HC DkW HC JcB HC D11 HC JC HC DkW HC JC HC JC HC D11 HC JC HC = Huddles Cut DkW = Drinkwater JcB = Jacobs D11 = DCUT11 JC = Jacks Table F -2. Values of sediment metals in 2014 in the PCS creeks study. Creeks are listed with most upstream creek on South Creek first (Jacks Creek) and proceed downstream by creek to Hickory Point and Muddy Creek, then upriver along the Pamlico to the most western creeks (DCUT11 and DCUT19). Control creeks are indicated with an asterisk ( "). Entries with < were undetected and value shown is LOQ /CL (reporting limit and control limit.) Ag As Cd Cr Cu Fe Mo Se Zn ( %) (Ng/g NgIg) (ug/g) (Ng/g) (pg/g) (%) Ng /g) (Ng /g) (Ng /g) Creek Jacks 2.90 <0.380 4.68 0.88 29.50 11.90 2.69 <3.68 1.87 102.0 Little* 0.27 <0.140 1.40 0.15 6.53 2.18 0.19 <1.40 0.48 10.2 Jacobs 2.20 <0.314 5.04 0.53 23.20 9.49 2.26 <3.20 1.70 72.9 PA2* 0.10 <0.221 1.84 0.16 10.00 2.89 0.09 <2.13 0.60 29.1 Drinkwater 2.98 <0.351 4.92 0.55 30.50 9.99 2.51 <3.27 1.62 77.3 Long* 2.55 <0.265 4.10 0.44 18.50 6.89 2.32 <2.75 1.18 81.9 Tooley 1.94 <0.254 3.65 0.51 22.90 6.39 1.87 <2.32 1.03 64.8 Muddy* 1.55 <0.189 1.99 0.20 11.30 3.76 1.28 <2.08 0.60 40.6 Huddles Cut 0.03 <0.112 0.08 0.01 0.44 0.14 0.02 <1.04 0.06 2.5 Duck* 0.05 <0.117 0.17 <0.117 0.46 0.48 0.06 <1.26 0.11 3.8 Porter 0.28 <0.133 0.55 0.06 3.20 0.99 0.28 <1.36 0.16 9.8 DCUT11 2.27 <0.766 4.55 0.58 17.80 8.66 2.55 <6.73 2.04 72.6 DCUT19* 1.01 <0.232 1.73 0.24 6.71 2.71 1.52 <2.11 0.54 36.7 All mean 1.39 NA 2.67 0.36 13.93 5.11 1.36 NA 0.92 46.5 Control* mean 0.92 NA 1.87 0.24 8.92 3.15 0.91 NA 0.58 33.7 Other mean 1.80 NA 3.35 0.41 16.61 6.22 1.55 NA 1.21 51.5 Table F -3. Values for physical parameters of 2014 sediment samples from PCS study creeks. Control creeks are shown with an asterisk ( *). Bulk Water Water Dry Sediment %Soil -solid Total Creek Density Content Content Density as Dry Porosity Organic (g /cm3) (% by (% by (g /cm) Weight Carbon Weight) Volume) (g /kg) Jacks Creek 0.29 75.06 89.00 0.00 22.70 0.89 77.70 Little Creek* 1.20 31.25 55.00 0.01 62.50 0.55 12.30 Jacobs Creek 0.37 70.06 87.00 0.00 28.40 0.86 53.30 PA2* 0.65 53.55 75.00 0.01 43.50 0.76 19.20 Drinkwater Creek 0.32 73.46 88.00 0.00 25.50 0.88 58.40 Long Creek* 0.47 63.61 83.00 0.00 33.10 0.82 34.90 Tooley Creek 0.50 61.99 82.00 0.01 37.20 0.81 33.60 Muddy Creek* 0.74 49.32 73.00 0.01 48.00 0.72 15.50 Huddles Cut 1.20 26.72 44.00 0.01 81.50 0.55 0.35 Duck Creek* 1.30 19.58 32.00 0.01 77.60 0.51 1.59 Porter Creek 1.25 30.51 55.00 0.01 70.90 0.53 5.46 DCUT11 0.14 86.56 94.00 0.00 12.80 0.95 114.00 DCUT19* 0.73 49.36 71.00 0.01 43.10 0.73 32.80 0.70 45.14 0.74 35.32 Mean all (SD) (0.41) 53.16 (21.07) 71.38 (19.24) 0.007 (0.004) (21.95) (0.15) (33.28) 0.85 51.30 0.68 19.38 Mean control (SD) (0.33) 44.44 (16.06) 64.83 (18.51) 0.009 (0.003) (16.05) (0.12) (12.67) 0.58 39.86 0.78 48.97 Mean other (SD) (0.45) 60.62 (23.07) 77.00 (19.37) 0.006 (0.005) (26.04) (0.17) (40.12) Table F -4. Values of total recoverable metals in the 2014 PCS study creek water samples. Creeks are listed with most upstream creek on South Creek first (Jacks Creek) and proceed downstream by creek to Hickory Point and Muddy Creek, then upriver along the Pamlico to the most western creeks (DCUT11 and DCUT19). Entries with < were undetected and value shown is LOQ /CL. Control creeks are indicated with an asterisk ( *). 2014 Water Column Metals Results Creek Ag As Cd Cr Cu Fe Mo Se Zn (Ng/L) (Ng/L) (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) (Ng /L) Jacks <2.5 <2.5 <2.5 10.8 1.45 707 <10 <2.5 10.2 Little* <2.5 <2.5 <2.5 9.8 1.3 674 <10 <2.5 9.96 Jacobs <2.5 <2.5 <2.5 9.2 1.95 630 <10 10.6 8.26 PA2* <2.5 5.4 <2.5 8.9 2.8 590 <10 9.05 7.99 Drinkwater <2.5 <2.5 <2.5 9.4 1.65 503 <10 11.9 7.5 Long* <2.5 <2.5 <2.5 9.6 1.75 568 2.38 11.2 6.69 Tooley <2.5 <2.5 <2.5 9.4 1.85 557 <10 13.4 6.28 Muddy* <2.5 6.9 <2.5 8.6 1.8 602 <10 17.6 4.57 Huddles Cut <2.5 <5 <2.5 7.3 1.7 583 <10 13.6 5.97 Duck* <2.5 <1.0 <2.5 5.4 1.66 448 <10 7.12 8.47 Porter <2.5 <1.0 <2.5 7.02 1.28 815 <10 5.46 7.31 DCUT11 <1.0 <1.0 0.12 5.98 0.92 1220 <10 2.54 8.77 DCUT19* <2.5 <1.0 <2.5 6.62 1.6 614 <10 7.94 6.23