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NC0025534_Renewal (Application)_20150630
CITY COUNCIL:G.VOLK NC : CITY OF H EN D ERSONVI LLE JOHN F.OFFICERS: BARBARA Mayor The City of Four Seasons City Manager RON STEPHENS SAMUEL H. FRITSCHNER Mayor Pro Tern City Attorney STEVE CARAKER WATER AND SEWER DEPARTMENT TAMMIE K. DRAKE JERRY A.SMITH,JR. Lee Smith, Utilities Director City Clerk JEFF MILLER June 17, 2015 North Carolina Department of Environment RECEIVEDIDENRIDWR And Natural Resources, Division of Water Resources, JUN 3 0 2015 Water Quality Permitting Section—NPDES 1617 Mail Service Center Water Quality Raleigh, NC 27699-1617 Permitting Section SUBJECT: Permit Renewal City of Hendersonville Permit No. NC0025534 Henderson County Dear Sirs, Attached please find the renewal application for permit number NC0025534 as required by 15A NCAC 2H .0105(e). The subject permit Expires on December 31, 2015. The existing Permit contains a quarterly monitoring of bis(2-ethylhexyl)phthalate. We would like to remove this requirement from the requirements since all tests have been non-detect at the 5.0 ug/1 detection limit. If any further information is needed feel free to contact me at (828) 233-3211. Thanks in advance for you help in this matter. Sincerely, Lee Smit Utilities Director City of Hendersonville, NC Attachments 305 Williams St. (smith@cityofhendersonville.org Phone: 828.697.3063 Hendersonville, NC 28792-4461 www.cityofhendersonville.org Fax: 828.697.3089 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP. NC0025534 Renewal French Broad FORM 2A NPDES FORM 2A APPLICATION OVERVIEW NPDES APPLICATION OVERVIEW Form 2A has been developed in a modular format and consists of a "Basic Application Information" packet and a "Supplemental Application Information" packet. The Basic Application Information packet is divided into two parts. All applicants must complete Parts A and C. Applicants with a design flow greater than or equal to 0.1 mgd must also complete Part B. Some applicants must also complete the Supplemental Application Information packet. The following items explain which parts of Form 2A you must complete. BASIC APPLICATION INFORMATION: A. Basic Application Information for all Applicants. All applicants must complete questions A.1 through A.8. A treatment works that discharges effluent to surface waters of the United States must also answer questions A.9 through A.12. B. Additional Application Information for Applicants with a Design Flow z 0.1 mgd. All treatment works that have design flows greater than or equal to 0.1 million gallons per day must complete questions B.1 through DECEIVED/DENR/DWR C. Certification. All applicants must complete Part C(Certification). JUN 3 0 2015 SUPPLEMENTAL APPLICATION INFORMATION: Water Quality Permitting Section D. Expanded Effluent Testing Data. A treatment works that discharges effluent to surface waters of the United States and meets one or more of the following criteria must complete Part D(Expanded Effluent Testing Data): 1. Has a design flow rate greater than or equal to lmgd, 2. Is required to have a pretreatment program(or has one in place), or 3. Is otherwise required by the permitting authority to provide the information. E. Toxicity Testing Data. A treatment works that meets one or more of the following criteria must complete Part E (Toxicity Testing Data): 1. Has a design flow rate greater than or equal to 1 mgd, 2. Is required to have a pretreatment program(or has one in place), or 3. Is otherwise required by the permitting authority to submit results of toxicity testing. F. Industrial User Discharges and RCRA/CERCLA Wastes. A treatment works that accepts process wastewater from any significant industrial users(SIUs)or receives RCRA or CERCLA wastes must complete Part F(Industrial User Discharges and RCRA/CERCLA Wastes). SIUs are defined as: 1. All industrial users subject to Categorical Pretreatment Standards under 40 Code of Federal Regulations(CFR)403.6 and 40 CFR Chapter I, Subchapter N (see instructions); and 2. Any other industrial user that: a. Discharges an average of 25,000 gallons per day or more of process wastewater to the treatment works(with certain exclusions); or b. Contributes a process wastestream that makes up 5 percent or more of the average dry weather hydraulic or organic capacity of the treatment plant; or c. Is designated as an SIU by the control authority. G. Combined Sewer Systems. A treatment works that has a combined sewer system must complete Part G(Combined Sewer Systems). ALL APPLICANTS MUST COMPLETE PART C (CERTIFICATION) EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 1 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville VVWTP , NC0025534 Renewal French Broad BASIC APPLICATION INFORMATION PART A.BASIC APPLICATION INFORMATION FOR ALL APPLICANTS: All treatment works must complete questions A.1 through A.8 of this Basic Application Information Packet. A.1. Facility Information. Facility Name City of Hendersonville WWTP Mailing Address 305 Williams Street Hendersonville.NC 28792 RECEIVED/DENR/DWR Contact Person Vincent Edwards Title Plant Superintendent JUN . 0 2015 Telephone Number ( 8281 897-3057 Water Otiosity Permitting Section Facility Address 99 Belford Road (not P.O.Box) Hendersonville.NC A.2. Applicant informatIon. If the applicant is different from the above,provide the following: Applicant Name City of Hendersonville Mailing Address 305 Williams Street Hendersonville.NC 28792 Contact Person Lee Smith Title Water and Sewer Utilities Director Telephone Number 08281233-3211 Is the applicant the owner or operator(or both)of the treatment works? [x] owner [x] operator Indicate whether correspondence regarding this permit should be directed to the facility or the applicant. 0 facility [x] applicant A.3. Existing Environmental Permits. Provide the permit number of any existing environmental permits that have been issued to the treatment works (Include state-issued permits). NPDES NC0025534 PSD UIC Other W00011381 RCRA ___ Other WQ0034350 A.4. Collection System Information. Provide information on municipalities and areas served by the facility. Provide the name and population of each entity and,If known,provide information on the type of collection system(combined vs.separate)and its ownership(municipal,private,etc.). Name Population Served Type of Collection System Ownership Hendersonville 18.000 Separate Municipal Laurel Park 1.800 Separate Municipal Total population served 19.800 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6 8 7550-22. Page 2 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad A.5. Indian Country. a. Is the treatment works located in Indian Country? ❑ Yes [x]No b. Does the treatment works discharge to a receiving water that is either in Indian Country or that is upstream from(and eventually flows through)Indian Country? ❑ Yes [x] No A.B. Flow. Indicate the design flow rate of the treatment plant(i.e.,the wastewater flow rate that the plant was built to handle). Also provide the average daily flow rate and maximum daily flow rate for each of the last three years. Each year's data must be based on a 12-month time period with the 12th month of"this year"occurring no more than three months prior to this application submittal. a. Design flow rate 4.8 mgd 0_12 2013 zQ]4 b. Annual average daily flow rate 3.535 3.572 3.137 c. Maximum daily flow rate 7.669 8.085 8.026 A.7. Collection System. Indicate the type(s)of collection system(s)used by the treatment plant. Check all that apply. Also estimate the percent contribution(by miles)of each. [x] Separate sanitary sewer 100 % 0 Combined storm and sanitary sewer °k A.8. Discharges and Other Disposal Methods. a. Does the treatment works discharge effluent to waters of the U.S.? [x]Yes 0 No If yes,list how many of each of the following types of discharge points the treatment works uses: i. Discharges of treated effluent 1 ii. Discharges of untreated or partially treated effluent 0 iii. Combined sewer overflow points 0 iv. Constructed emergency overflows(prior to the headworks) 0 v. Other 0 b. Does the treatment works discharge effluent to basins,ponds,or other surface impoundments that do not have outlets for discharge to waters of the U.S.? 0 Yes [x] No If yes,provide the following for each surface impoundment: Location: Annual average daily volume discharge to surface impoundment(s) mgd Is discharge 0 continuous or 0 intermittent? c. Does the treatment works land-apply treated wastewater? 0 Yes [x] No If yes,provide the following for each land aoolication site: Location: Number of acres: Annual average daily volume applied to site: mgd Is land application 0 continuous or 0 intermittent? d. Does the treatment works discharge or transport treated or untreated wastewater to another treatment works? 0 Yes [x] No EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 3 of 22 FACIUTY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville V V TP , NC0025534 Renewal French Broad If yes,describe the mean(s)by which the wastewater from the treatment works is discharged or transported to the other treatment works (e.g.,tank truck,pipe). If transport is by a party other than the applicant,provide: Transporter Name Mailing Address Contact Person Title Telephone Number ( For each treatment works that receives this discharoe,provide the following: Name Mailing Address Contact Person Title Telephone Number j 1 If known,provide the NPDES permit number of the treatment works that receives this discharge Provide the average daily flow rate from the treatment works into the receiving facility. mgd e. Does the treatment works discharge or dispose of its wastewater in a manner not included in A.S.through A.8.d above(e.g.,underground percolation,well injection): 0 Yes [x] No If yes,provide the following for each disposal method: Description of method(including location and size of site(s)if applicable): Bulk Reclaim Water Permit number W0003435 Annual daily volume disposed by this method: Small amounts trucked off Is disposal through this method 0 continuous or [x]intermittent? EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-8&7550-22. Page 4 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WVVrP , NC0025534 Renewal French Broad WASTEWATER DISCHARGES: H you answered"Yes"to auestlon A.8.a,complete auestlons A.9 throuah A.1Z once for each outfall(including bypass points)through which effluent Is discharged. Do not include Information on combined sewer overflows in this section. If you answered"No"to auestlon Ma,go to Part B,"Additional Application Information for Applicants with a Design Flow Greater than or Equal to 0.1 mgd." A.B. Description of Outfall. a. Outfall number 001 b. Location Hendersonville 28792 (City or town.if applicable) (Zip Code) Henderson 28792 (County) (State) 35.21.11 82.27.52 (Latitude) (Longitude) c. Distance from shore(if applicable) N/A ft. d. Depth below surface(if applicable) N/A ft. e. Average daily flow rate mgd f. Does this outfall have either an intermittent or a periodic discharge? 0 Yes [x] No (go to A.9.g.) If yes,provide the following information: Number f times per year discharge occurs: Average duration of each discharge: Average flow per discharge: mgd Months in which discharge occurs: g. Is outfall equipped with a diffuser? 0 Yes [x] No A.10. Description of Receiving Waters. a. Name of receiving water Mud Creek b. Name of watershed(if known) Lower Mud Creek United States Soil Conservation Service 14-digit watershed code(if known): 06010105030030 c. Name of State Management/River Basin(if known):French Broad United States Geological Survey 8-digit hydrologic cataloging unit code(if known): 06010105 d. Critical low flow of receiving stream(rf applicable) acute cfs chronic 34.9 cfs e. Total hardness of receiving stream at critical low flow(if applicable): mg/I of CaCO3 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 5 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad A.11. Description of Treatment a. What level of treatment are provided? Check all that apply. ❑ Primary ❑ Secondary [x] Advanced ❑ Other. Describe: b. Indicate the following removal rates(as applicable): Design BOD5 removal or Design CBOD5 removal 96 cyo Design SS removal 96 Design P removal % Design N removal % Other % c. What type of disinfection is used for the effluent from this outfall? If disinfection varies by season,please describe: Ultraviolet If disinfection is by chlorination is dechlorination used for this outfall? 0 Yes 0 No Does the treatment plant have post aeration? [X] Yes 0 No A.12. Effluent Testing Information. All Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a minimum,effluent testing data must be based on at least three samples and must be no more than four and one-half years apart. Outfall number: 001 MAXIMUM DAILY VALUE AVERAGE DAILY VALUE PARAMETER Value Units Value Units Number of Samples pH(Minimum) .1 s.u. 7 •� ///�//////%%� /,/ pH(Maximum) 7.3 s.u. Flow Rate 8.0 MGD 3.357 MGD 365 Temperature(Winter) 22.1 Deg C 14.3 Deg C 125 Temperature(Summer) 24.4 Deg C 20.7 Deg C 125 For pH please report a minimum and a maximum daily value MAXIMUM DAILY AVERAGE DAILY DISCHARGE POLLUTANT DISCHARGE ANALYTICAL MUMDL Number of METHOD Conc. Units Conc. Units Samples CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS BIOCHEMICAL OXYGEN BOD5 15.2 mg/I 3.9 mg/I 253 SM5210B 2 mg/I DEMAND(Report one) CBOD5 N/A FECAL COLIFORM >512 #/100 9.5 #/100 250 SM9222D 1/100 TOTAL SUSPENDED SOLIDS(TSS) 7.2 mg/I 3.150 mg/I 253 SM2540D 5 mg/I END OF PART A. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 6 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville VVVVTP , NC0025534 Renewal French Broad BASIC APPLICATION INFORMATION PART B. ADDITIONAL APPLICATION INFORMATION FOR APPLICANTS WITH A DESIGN FLOW GREATER THAN OR EQUAL TO 0.1 MGD(100,000 gallons per day). All applicants with a design flow rate 2 0.1 mgd must answer questions B.1 through B.6. All others go to Part C(Certification). B.1. Inflow and Infiltration. Estimate the average number of gallons per day that flow into the treatment works from inflow and/or infiltration. 1.01 million gpd Briefly explain any steps underway or planned to minimize inflow and infiltration. Budaeted line and manhole replacement program.new Dositons being added to look for leaks and infiltration B.2. Topographic Map. Attach to this application a topographic map of the area extending at least one mile beyond facility property boundaries. This map must show the outline of the facility and the following information. (You may submit more than one map if one map does not show the entire area.) a. The area surrounding the treatment plant,including all unit processes. b. The major pipes or other structures through which wastewater enters the treatment works and the pipes or other structures through which treated wastewater is discharged from the treatment plant. Include outfalls from bypass piping,if applicable. c. Each well where wastewater from the treatment plant is injected underground. d. Wells,springs,other surface water bodies,and drinking water wells that are: 1)within Y.mile of the property boundaries of the treatment works,and 2)listed in public record or otherwise known to the applicant. e. Any areas where the sewage sludge produced by the treatment works is stored,treated,or disposed. f. If the treatment works receives waste that is classified as hazardous under the Resource Conservation and Recovery Act(RCRA)by truck,rail, or special pipe,show on the map where the hazardous waste enters the treatment works and where it is treated,stored,and/or disposed. B.3. Process Flow Diagram or Schematic. Provide a diagram showing the processes of the treatment plant,including all bypass piping and all backup power sources or redundancy in the system. Also provide a water balance showing all treatment units,including disinfection(e.g., chlorination and dechlorination). The water balance must show daily average flow rates at influent and discharge points and approximate daily flow rates between treatment units. Include a brief narrative description of the diagram. B.4. Operation/Maintenance Performed by Contractor(s). Are any operational or maintenance aspects(related to wastewater treatment and effluent quality)of the treatment works the responsibility of a contractor? 0 Yes [x] No If yes,list the name,address,telephone number,and status of each contractor and describe the contractors responsibilities(attach additional pages if necessary). Name: Mailing Address: Telephone Number: ( l Responsibilities of Contractor: B.5. Scheduled improvements and Schedules of implementation. Provide information on any uncompleted implementation schedule or uncompleted plans for improvements that will affect the wastewater treatment,effluent quality,or design capacity of the treatment works. If the treatment works has several different implementation schedules or is planning several improvements,submit separate responses to question B.5 for each. (If none,go to question B.6.) a. List the outfall number(assigned in question A.9)for each outfall that is covered by this implementation schedule. b. Indicate whether the planned improvements or implementation schedule are required by local,State,or Federal agencies. 0 Yes [x] No EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 7 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad c. If the answer to B.5.b is"Yes,"briefly describe,including new maximum daily inflow rate(if applicable). d. Provide dates imposed by any compliance schedule or any actual dates of completion for the implementation steps listed below,as applicable. For improvements planned independently of local,State,or Federal agencies,indicate planned or actual completion dates,as applicable. Indicate dates as accurately as possible. Schedule Actual Completion Implementation Stage MM/DD/YYYY MM/DD/YYYY -Begin Construction / / / / -End Construction / / / / -Begin Discharge / / / / -Attain Operational Level / / / / e. Have appropriate permits/clearances concerning other Federal/State requirements been obtained? 0 Yes 0 No Describe briefly: B.B. EFFLUENT TESTING DATA(GREATER THAN 0.1 MGD ONLY). Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not include information on combine sewer overflows In this section. All Information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a minimum effluent testing data must be based on at least three pollutant scans and must be no more than four and on-half years old. Outfall Number: 001 MAXIMUM DAILY AVERAGE DAILY DISCHARGE DISCHARGE ANALYTICAL POLLUTANT METHOD MIJMDL Conc. Units Conc. Units Number of Samples CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS AMMONIA(as N) 6.9 mg/I .52 mg/I 253 SM4500-NH3D 0.5 CHLORINE(TOTAL N/A mg/I mg/I RESIDUAL,TRC) DISSOLVED OXYGEN 9.8 mg/I 7.5 mg/I 250 SM15000G 0.10 TOTAL KJELDAHL 1.1 mg/I 1.1 mg/I 1 EPA351.2 0.50 NITROGEN(rKN) NITRATE PLUS NITRITE 11.3 mg/I 11.3 mg/I 1 EPA353.2 0.10 NITROGEN OIL and GREASE ND mg/I ND mg/I 1 EPA1664A 5.0 PHOSPHORUS(Total) 3.8 mg/I 3.06 mg/I 8 EPA365.2 0.10 TOTAL DISSOLVED SOLIDS 155 mg/I 155 mg/l 1 EPA160.1 20 (TDS) OTHER 1 END OF PART B. REFER TO THE APPLICATION OVERVIEW(PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 8 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad BASIC APPLICATION INFORMATION PART C. CERTIFICATION All applicants must complete the Certification Section. Refer to instructions to determine who is an officer for the purposes of this certification. All applicants must complete all applicable sections of Form 2A,as explained in the Application Overview. Indicate below which parts of Form 2A you have completed and are submitting. By signing this certification statement,applicants confirm that they have reviewed Form 2A and have completed all sections that apply to the facility for which this application is submitted. Indicate which parts of Form 2A you have completed and are submitting: [x] Basic Application Information packet Supplemental Application Information packet: [x] Part D(Expanded Effluent Testing Data) [x] Part E(Toxicity Testing: Biomonitoring Data) [x] Part F(Industrial User Discharges and RCRA/CERCLA Wastes) 0 Part G(Combined Sewer Systems) ALL APPLICANTS MUST COMPLETE THE FOLLOWING CERTIFICATION. I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information,the information is,to the best of my knowledge and belief,true. accurate,and complete. I am aware that there are significant penalties for submitting false information.including the possibility of fine and imprisonment for knowing violations. Name and official title Lee Smith/Utilities Director Signature Telephone number (828)233-3211 Date signed G /� Upon request of the permitting authority,you mu t submit any other information necessary to assure wastewater treatment practices at the treatment works or identify appropriate permitting requirements. SEND COMPLETED FORMS TO: NCDENR/ DWQ Attn: NPDES Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 9 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville VVV TP , NC0025534 Renewal French Broad SUPPLEMENTAL APPLICATION INFORMATION PART D. EXPANDED EFFLUENT TESTING DATA Refer to the directions on the cover page to determine whether this section applies to the treatment works. Effluent Testing: 1.0 mgd and Pretreatment Works. If the treatment works has a design flow greater than or equal to 1.0 mgd or it has(or is required to have)a pretreatment program,or is otherwise required by the permitting authority to provide the data,then provide effluent testing data for the following pollutants. Provide the indicated effluent testing information and any other information required by the permitting authority for each outfall through which effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected through analyses conducted using 40 CFR Part 136 methods. In addition,these data must comply with QNQC requirements of 40 CFR Part 136 and other appropriate QNQC requirements for standard methods for analytes not addressed by 40 CFR Part 136. Indicate in the blank rows provided below any data you may have on pollutants not specifically listed in this form. At a minimum,effluent testing data must be based on at least three pollutant scans and must be no more than four and one-half years old. Outfall number. 001 (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT Number ANALYTICAL MUMDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples METALS(TOTAL RECOVERABLE),CYANIDE,PHENOLS,AND HARDNESS. ANTIMONY ND ugh ND ugh 3 EPA-200.7 5.0 ARSENIC ND ugh ND ugh 3 EPA-200.7 10 BERYLLIUM ND ugh ND ugh 3 EPA-200.7 1.0 CADMIUM ND ug/I ND ugh 3 EPA-200.7 1.0 CHROMIUM ND ugh ND WA 3 EPA-200.7 5.0 COPPER 18.5 ugh 16 ugh 3 EPA-200.7 5.0 LEAD ND ugh ND 3 EPA-200.7 5.0 MERCURY 1.55 ng/I 1.24 ngh 3 EPA-1631 0.5 NICKEL 13.6 ugh 7,9 than 3 EPA-200.7 5.0 SELENIUM ND ugh ND ugh 3 EPA-200.7 10.0 SILVER ND ugh ND ugh 3 EPA-200.7 5.0 THALLIUM ND ugh ND IVA 3 EPA-200.7 10.0 ZINC 68 ug/I 61 ugh 3 EPA-200.7 10.0 CYANIDE .0065 ug/I <.01 u9n 3 EPA-335-2 .0050 TOTAL PHENOLIC092 <.04 3 EPA 420.4 .01, COMPOUNDS 0.005,.015 HARDNESS(as CaCO3) 33.3 mg/I 34,1 3 SM2340B .66 Use this space(or a separate sheet)to provide information on other metals requested by the permit writer EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-8&7550-22. Page 10 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville VWVTP , NC0025534 Renewal French Broad Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT Number ANALYTICAL MLIMDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples VOLATILE ORGANIC COMPOUNDS ACROLEIN ND ugh ND ugh 3 EPA 624 5,100,5 ACRYLONITRILE ND ugh ND ugll 3 1 EPA 624 50 BENZENE ND ugh ND ugh 3 EPA 824 2.0 i BROMOFORM ND ugh ND ugh 3 EPA 624 2.0 CARBON ND u ND3 EPA 624 2.0 TETRACHLORIDE � ugh CHLOROBENZENE ND ugh ND ugn 3 EPA 624 2.0 CHLORODIBROMO- METHANE ND ugh ND ug/I 3 EPA 624 2.0 CHLOROETHANE ND ugh ND ug/I 3 EPA 624 2.0 2-CHLOROETHYLVINYL ETHER ND ugh ND ug/1 3 EPA 624 5.0 CHLOROFORM ND ugh ND ugII 3 EPA 624 2.0 DICHLOROBROMO- METHANE ND ugh ND ugII 3 EPA 624 2.0 1,1-DICHLOROETHANE ND ugh ND ug/I 3 EPA 624 2.0 1,2-DICHLOROETHANE ND ugh ND ugh 3 EPA 824 2.0 TRANS-I,2-DICHLORO ETHYLENE ND ugh ND ugn 3 EPA 624 2.0 1-DICHLORO• ETHYLENE u� �ND ND 3 EPA 624 2.0 E 1,2-DICHLOROPROPANE ND ugh ND ug/I 3 EPA 624 2.0 1,3-DICHLORO PROPYLENE ND ugh ND ugn 3 EPA 624 2.0 ETHYLBENZENE ND ugh ND ugh 3 EPA 624 2.0 METHYL BROMIDE ND ugh ND ug/I 3 EPA 624 2.0 METHYL CHLORIDE ND ugh ND ugl 3 EPA 624 2.0 METHYLENE CHLORIDE ND ugh ND ugII 3 EPA 624 2.0 1,1,2,2-TETRA- CHLOROETHANE ND ugh ND ug/I 3 EPA 624 2.0 TETRACHLORO- ETHYLENE ND ug/I ND ugn 3 EPA 624 2.0 TOLUENE ND ugII ND ug/I 3 EPA 624 2.0 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 11 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville VWVTP , NC0025534 Renewal French Broad Outfall number. 001 (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT Number ANALYTICAL MLIMDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples 11,1- �ugh! u ND l ND l 3 EPA624 2,5,2 TRICHLOROETHANE 1,1,2- TRICHLOROETHANE � �ND u ND I 3 EPA624 2,5,2 TRICHLOROETHYLENE ND ugn ND ug/I 3 EPA624 2,5,2 VINYL CHLORIDE ND ug/I ND ug/I 3 EPA624 2,5,2 Use this space(or a separate sheet)to provide information on other volatile organic compounds requested by the permit writer ACID-EXTRACTABLE COMPOUNDS P-CHLORO-M-CRESOL ND ug/I ND ug/I 3 EPA 625 10 2-CHLOROPHENOL ND ug/I ND ug/I 3 EPA 625 5.0 2,4-DICHLOROPHENOL ND ugh ND ug/I 3 EPA 625 5.0 2,4-DIMETHYLPHENOL ND ug/I ND ug/I 3 EPA 625 10 4,6-DINITRO-O-CRESOL ND ugh ND ugh 3 EPA 625 20 2,4-DINITROPHENOL ND ug/I ND ug/I 3 EPA 625 50 2-NITROPHENOL ND ug/I ND ug/1 3 EPA 625 5 4-NITROPHENOL ND ug/I ND ug/1 3 EPA 625 50 PENTACHLOROPHENOL ND ug/I ND ugh 3 EPA 625 10 PHENOL ND ug/l ND ugh 3 EPA 625 5 I TRICCHLOROPHENOL � I u ND uI ND 3 EPA 625 10 TR � Use this space(or a separate sheet)to provide information on other acid-extractable compounds requested by the permit writer BASE-NEUTRAL COMPOUNDS ACENAPHTHENE ND ug/I ND ugh 3 5 ACENAPHTHYLENE ND ug/I ND ug/I 3 5 ANTHRACENE ND ug/1 ND ugn 3 5 BENZIDINE ND ugh ND ugh! 3 50 BENZO(A)ANTHRACENE ND ugh ND ug/I 3 5 • BENZO(A)PYRENE ND ugh ND ugh 31 5 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 12 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad Outfall number. 001 (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT Number ANALYTICAL MLANDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples 3,4 BENZO- ND ugh ND ugll 3 EPA 625 5 FLUORANTHENE BENZO(GHI)PERYLENE ND ugh ND uglI 3 EPA 625 5 BENZO(K) ND ugh ND ugh 3 EPA 625 5 FLUORANTHENE BIS(2-CHLOROETHOXY) METHANE ND ugh ND ugh 3 EPA 625 10 BIS(2 CHLOROETHYL)- ND ug/1 ND ugll 3 EPA 625 5 ETHER BIS(2-CHLOROISO- PROPYL)ETHER ND ug/1 ND ugugh3 EPA 625 5 BIS(2-ETHYLHEXYL) PHTHALATE ND ugh ND ug/l 3 EPA 625 5 4-BROMOPHENYL PHENYL ETHER ND ugll ND ug/l 3 EPA 625 5 BUTYL BENE PHTHALATE �1 ND u ND ugh 3 EPA 625 5 RO- 2NAPHOTHALENE ND ug/1 ND ugll 3 EPA 625 5 4-CHLORPHENYL PHENYL ETHER ND ugh ND ugh 3 EPA 625 5 CHRYSENE ND ugh ND ug/I 3 EPA 625 5 DI-N-BUTYL PHTHALATE ND ugll ND ugll 3 EPA 825 5 DI-N-OCTYL PHTHALATE ND ugh ND ugh 3 EPA 625 5 DIBENZO(A,H) ANTHRACENE ND ugh ND ugh 3 EPA 625 5 1,2-DICHLOROBENZENE ND ugll ND ugh 3 EPA 625 5 1,3-DICHLOROBENZENE ND ugh ND ugh 3 EPA 625 5 1,4-DICHLOROBENZENE ND ugll ND ugh 3 EPA 625 5 3,3-DICHLORO- BENZIDINE ND Kin ND ugh 3 EPA 625 25 DIETHYL PHTHALATE ND ugh ND ugh 3 EPA 825 5 DIMETHYL PHTHALATE ND ugll ND ugh 3 EPA 625 5 2,4-DINITROTOLUENE ND ugh ND ugh 3 EPA 625 5 2,6-DINITROTOLUENE ND ugll ND ugll 3 EPA 625 5 1,2-DIPHENYL- HYDRAZINE ND ugh ND ugh 3 EPA 625 5 EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550.6&7550-22. Page 13 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville V V TP , NC0025534 Renewal French Broad Outfall number. QQi (Complete once for each outfall discharging effluent to waters of the United States.) MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE POLLUTANT Number ANALYTICAL MLIMDL Conc. Units Mass Units Conc. Units Mass Units of METHOD Samples FLUORANTHENE ND ug/I ND ugh 3 EPA 625 5 FLUORENE ND ugh ND ug/1 3 EPA 625 5 HEXACHLOROBENZENE ND ug/I ND ug/I 3 EPA 625 5 BUTADND ug/I ND ug/I 3 EPA 625 5 BUTADIENEIENE HEXACHLOROCYCLO- PENTADIENE ND ug/1 ND ugh 3 EPA 625 10 HEXACHLOROETHANE ND ug/I ND ugh 3 EPA 625 5 INDEN0(1,2,3-CD) PYRENE ND ugh ND ug/I 3 EPA 625 5 ISOPHORONE ND ug/I ND ug/I 3 EPA 625 10 NAPHTHALENE ND ug/1 ND ugh 3 EPA 625 5 NITROBENZENE ND ugh ND ugh 3 EPA 625 6 N-NITPROP AMINE ND ug/I ND ugh 3 EPA 625 5 PROPYLAMINE N-NI MET YLAMIN- ND ug/I ND ugh 3 EPA 625 5 METHYLAMINE PHENYLAMIN ND I ND ugh 3 EPA 625 10 PHENYLAMINE � PHENANTHRENE ND ugh ND ugh 3 EPA 625 5 PYRENE ND ugh ND ugh 3 EPA 625 6 1,2,TRI ND ug/I ND ugh3 EPA 625 6 RICHLOROBENZENE Use this space(or a separate sheet)to provide information on other base-neutral compounds requested by the permit write r Use this space(or a separate sheet)to provide information on other pollutants(e.g.,pesticides)requested by the permit writer END OF PART D. REFER TO THE APPLICATION OVERVIEW(PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 14 of 22 FACIUTY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WVVfP , NC0025534 Renewal French Broad SUPPLEMENTAL APPLICATION INFORMATION PART E. TOXICITY TESTING DATA POTWs meeting one or more of the following criteria must provide the results of whole effluent toxicity tests for acute or chronic toxicity for each of the facility's discharge points: 1)POTWs with a design flow rate greater than or equal to 1.0 mgd;2)POTWs with a pretreatment program(or those that are required to have one under 40 CFR Part 403);or 3)POTWs required by the permitting authority to submit data for these parameters. • At a minimum,these results must include quarterly testing for a 12-month period within the past 1 year using multiple species(minimum of two species),or the results from four tests performed at least annually in the four and one-half years prior to the application,provided the results show no appreciable toxicity,and testing for acute and/or chronic toxicity,depending on the range of receiving water dilution. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. • In addition,submit the results of any other whole effluent toxicity tests from the past four and one-half years. If a whole effluent toxicity test conducted during the past four and one-half years revealed toxicity,provide any information on the cause of the toxicity or any results of a toxicity reduction evaluation,if one was conducted. • If you have already submitted any of the information requested in Part E,you need not submit it again. Rather,provide the information requested in question E.4 for previously submitted information. If EPA methods were not used,report the reasons for using alternate methods. If test summaries are available that contain all of the information requested below,they may be submitted in place of Part E. If no biomonitoring data is required,do not complete Part E. Refer to the N/A E.1. Required Tests. Indicate the number of whole effluent toxicity tests conducted in the past four and one-half years. [x]chronic 0 acute E.2. Individual Test Data. Complete the following chart for each whole effluent toxicity test conducted in the last four and one-half years. Allow one column per test(where each species constitutes a test). Copy this page if more than three tests are being reported. Test number. Test number. Test number. a. Test information. SEE ATTACHMENTS Test Species&test method number Age at initiation of test Outfall number Dates sample collected Date test started Duration b. Give toxicity test methods followed. Manual title Edition number and year of publication Page number(s) c. Give the sample collection method(s)used. For multiple grab samples,indicate the number of grab samples used. 24-Hour composite Grab d. Indicate where the sample was taken in relation to disinfection. (Check all that apply for each. Before disinfection After disinfection After dechlorination EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 15 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville VVWTP , NC0025534 Renewal French Broad Test number: Test number: Test number: e. Describe the point in the treatment process at which the sample was collected. Sample was collected: f. For each test,include whether the test was intended to assess chronic toxicity,acute toxicity,or both Chronic toxicity Acute toxicity g. Provide the type of test performed. Static Static-renewal Flow-through h. Source of dilution water. If laboratory water,specify type;if receiving water,specify source. Laboratory water Receiving water i. Type of dilution water. If salt water,specify"natural"or type of artificial sea salts or brine used. Fresh water Salt water j. Give the percentage effluent used for all concentrations in the test series. k. Parameters measured during the test. (State whether parameter meets test method specifications) pH Salinity Temperature Ammonia Dissolved oxygen I. Test Results. Acute: Percent survival in 100% effluent LC50 95%C.I. Control percent survival Other(describe) EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 16 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad Chronic: NOEC IC25 Control percent survival • Other(describe) m. Quality ControUQuality Assurance. Is reference toxicant data available? Was reference toxicant test within acceptable bounds? What date was reference toxicant test run(MM/DD/YYYY)? Other(describe) E.3. Toxicity Reduction Evaluation. Is the treatment works involved in a Toxicity Reduction Evaluation? ❑ Yes ❑ No If yes,describe: E.4. Summary of Submitted Blomonitoring Test Information. If you have submitted biomonitoring test information,or information regarding the cause of toxicity,within the past four and one-half years,provide the dates the information was submitted to the permitting authority and a summary of the results. Date submitted: / / (MM/DD/YYYY) Summary of results: (see instructions) See Attachments END OF PART E. REFER TO THE APPLICATION OVERVIEW(PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE. EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 17 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad SUPPLEMENTAL APPLICATION INFORMATION PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA,or other remedial wastes must complete part F. GENERAL INFORMATION: F.1. Pretreatment program. Does the treatment works have,or is subject ot,an approved pretreatment program? [x] Yes ❑ No F.2. Number of Significant Industrial Users(Sills)and Categorical Industrial Users(CIOs). Provide the number of each of the following types of industrial users that discharge to the treatment works. a. Number of non-categorical SIUs. 1 b. Number of CIUs. 2 SIGNIFICANT INDUSTRIAL USER INFORMATION: Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and provide the information requested for each SIU. F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages as necessary. Name: General Electric Lighting Mailing Address: 3010 Spartanburg Hwy. Hendersonville,NC 28739 F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge. Metal Finishing,cleaning,coating,painting F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's discharge. Principal product(s): Component Parts for outdoor lighting fixtures, Raw material(s): Steel, aluminum,copper, acids, Bases, Soaps, Speciality chemicals. F.6. Flow Rate. a. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 92,900 gpd (x continuous or intermittent) b. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 5,100 gpd (x continuous or intermittent) F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following: a. Local limits [x] Yes ❑ No b. Categorical pretreatment standards [x] Yes ❑ No If subject to categorical pretreatment standards,which category and subcategory? 433.15 EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 18 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WVVTP , NC0025534 Renewal French Broad F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g., upsets,interference)at the treatment works in the past three years? O Yes [x]No If yes,describe each episode. RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE: F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck,rail or dedicated pipe? ❑ Yes [x]No(go to F.12) F.10. Waste transport. Method by which RCRA waste is received(check all that apply): ❑ Truck ❑ Rail ❑ Dedicated Pipe F.11. Waste Description. Give EPA hazardous waste number and amount(volume or mass,specify units). EPA Hazardous Waste Number Amount Units CERCLA(SUPERFUND)WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION WASTEWATER,AND OTHER REMEDIAL ACTIVITY WASTEWATER: F.12. Remediation Waste. Does the treatment works currently(or has it been notified that it will)receive waste from remedial activities? ❑ Yes(complete F.13 through F.15.) [x]No F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates(or is excepted to origniate in the next five years). F.14. Pollutants. List the hazardous constituents that are received(or are expected to be received). Include data on volume and concentration,if known. (Attach additional sheets if necessary.) F.15. Waste Treatment. a. Is this waste treated(or will be treated)prior to entering the treatment works? ❑ Yes ❑ No If yes,describe the treatment(provide information about the removal efficiency): b. Is the discharge(or will the discharge be)continuous or intermittent? ❑ Continuous 0 Intermittent If intermittent,describe discharge schedule. END OF PART F. REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 19 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad SUPPLEMENTAL APPLICATION INFORMATION PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA,or other remedial wastes must complete part F. GENERAL INFORMATION: F.1. Pretreatment program. Does the treatment works have,or is subject ot,an approved pretreatment program? [x] Yes 0 No F.2. Number of Significant Industrial Users(SIUs)and Categorical Industrial Users(CIOs). Provide the number of each of the following types of industrial users that discharge to the treatment works. c. Number of non-categorical SIUs. 1 d. Number of CIUs. 2 SIGNIFICANT INDUSTRIAL USER INFORMATION: Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and provide the information requested for each SIU. F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages as necessary. Name: Kimberly-Clark Corporation Mailing Address: 32 Smyth Avenue Hendersonville,NC 28792 F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge. Manufacture of non-woven goods F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's discharge. Principal product(s): Non woven Rolls Raw material(s): Polyprophylene,polyethelene, achovel,glucopon, surfactants,pigments,flouropolymer F.6. Flow Rate. c. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 10.820 gpd ( X continuous or intermittent) d. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 16,230 gpd ( X continuous or intermittent) F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following: a. Local limits [x] Yes 0 No b. Categorical pretreatment standards [ ] Yes [x] No If subject to categorical pretreatment standards,which category and subcategory? N/A EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 20 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g., upsets,interference)at the treatment works in the past three years'? ❑ Yes [x]No If yes,describe each episode. RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE: F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck,rail or dedicated pipe? ❑ Yes [x]No(go to F.12) F.10. Waste transport. Method by which RCRA waste is received(check all that apply): 0 Truck ❑ Rail 0 Dedicated Pipe F.11. Waste Description. Give EPA hazardous waste number and amount(volume or mass,specify units). EPA Hazardous Waste Number Amount Units CERCLA(SUPERFUND)WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION WASTEWATER,AND OTHER REMEDIAL ACTIVITY WASTEWATER: F.12. Remediation Waste. Does the treatment works currently(or has it been notified that it will)receive waste from remedial activities'? 0 Yes(complete F.13 through F.15.) [x]No F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates(or is excepted to origniate in the next five years). F.14. Pollutants. List the hazardous constituents that are received(or are expected to be received). Include data on volume and concentration,if known. (Attach additional sheets if necessary.) F.15. Waste Treatment. c. Is this waste treated(or will be treated)prior to entering the treatment works? ❑ Yes ❑ No If yes,describe the treatment(provide information about the removal efficiency): d. Is the discharge(or will the discharge be)continuous or intermittent? ❑ Continuous ❑ Intermittent If intermittent,describe discharge schedule. EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 21 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad SUPPLEMENTAL APPLICATION INFORMATION PART F.INDUSTRIAL USER DISCHARGES AND RCRAICERCLA WASTES All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA,or other remedial wastes must complete part F. GENERAL INFORMATION: F.1. Pretreatment program. Does the treatment works have,or is subject ot,an approved pretreatment program? [x] Yes ❑ No F.2. Number of Significant Industrial Users(Sills)and Categorical Industrial Users(CIUs). Provide the number of each of the following types of industrial users that discharge to the treatment works. e. Number of non-categorical SIUs. 1 f. Number of CIUs. 2 SIGNIFICANT INDUSTRIAL USER INFORMATION: Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and provide the information requested for each SIU. F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages as necessary. Name: Coats North America Mailing Address: P.O.Box 130 Hendersonville,NC 28739 F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge. Manufacture of industrial sewing threads.dental floss and modified nylon resin F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's discharge. Principal product(s): Industrial sewing threads,dental floss Raw material(s): Nylon and polyester yarns, dyes, bonds and finishes F.6. Flow Rate. e. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 3281 gpd (x continuous or intermittent) f. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system in gallons per day(gpd)and whether the discharge is continuous or intermittent. 929 gpd (x continuous or intermittent) F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following: a. Local limits [x] Yes ❑ No b. Categorical pretreatment standards [x] Yes ❑ No If subject to categorical pretreatment standards,which category and subcategory? 40 CFR 414.55 EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 22 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g., upsets,interference)at the treatment works in the past three years? ❑ Yes [x]No If yes,describe each episode. RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE: F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck,rail or dedicated pipe? ❑ Yes [x]No(go to F.12) F.10. Waste transport. Method by which RCRA waste is received(check all that apply): D Truck ❑ Rail ❑ Dedicated Pipe F.11. Waste Description. Give EPA hazardous waste number and amount(volume or mass,specify units). EPA Hazardous Waste Number Amount Units CERCLA(SUPERFUND)WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER: F.12. Remediation Waste. Does the treatment works currently(or has it been notified that it will)receive waste from remedial activities? ❑ Yes(complete F.13 through F.15.) [x]No F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates(or is excepted to origniate in the next five years). F.14. Pollutants. List the hazardous constituents that are received(or are expected to be received). Include data on volume and concentration,if known. (Attach additional sheets if necessary.) F.15. Waste Treatment. e. Is this waste treated(or will be treated)prior to entering the treatment works? ❑ Yes ❑ No If yes,describe the treatment(provide information about the removal efficiency): f. Is the discharge(or will the discharge be)continuous or intermittent? ❑ Continuous 0 Intermittent If intermittent,describe discharge schedule. EPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 23 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville WWTP , NC0025534 Renewal French Broad SUPPLEMENTAL APPLICATION INFORMATION PART G. COMBINED SEWER SYSTEMS If the treatment works has a combined sewer system,complete Part G. G.1. System Map. Provide a map indicating the following: (may be included with Basic Application Information) a. All CSO discharge points. b. Sensitive use areas potentially affected by CSOs(e.g.,beaches,drinking water supplies,shellfish beds,sensitive aquatic ecosystems,and outstanding natural resource waters). c. Waters that support threatened and endangered species potentially affected by CSOs. G.2. System Diagram. Provide a diagram,either in the map provided in G.1 or on a separate drawing,of the combined sewer collection system that includes the following information. a. Location of major sewer trunk lines,both combined and separate sanitary. b. Locations of points where separate sanitary sewers feed into the combined sewer system. c. Locations of in-line and off-line storage structures. d. Locations of flow-regulating devices. e. Locations of pump stations. CSO OUTFALLS: Complete questions G.3 through G.6 once for each CSO discharge point. G.3. Description of Outfall. a. Outfall number N/A b. Location (City or town,if applicable) (Zip Code) (County) (State) (Latitude) (Longitude) c. Distance from shore(if applicable) ft. d. Depth below surface(if applicable) ft. e. Which of the following were monitored during the last year for this CSO? ❑ Rainfall ❑ CSO pollutant concentrations 0 CSO frequency 0 CSO flow volume 0 Receiving water quality f. How many storm events were monitored during the last year? G.4. CSO Events. a. Give the number of CSO events in the last year. events (0 actual or 0 approx.) b. Give the average duration per CSO event. hours (0 actual or 0 approx.) EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 24 of 22 FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN: City of Hendersonville VVVVTP , NC0025534 Renewal French Broad c. Give the average volume per CSO event. million gallons(0 actual or 0 approx.) d. Give the minimum rainfall that caused a CSO event in the last year Inches of rainfall G.8. Description of Receiving Waters. a. Name of receiving water: b. Name of watershed/river/stream system: United State Soil Conservation Service 14-digit watershed code(if known): c. Name of State Management/River Basin: United States Geological Survey 8-digit hydrologic cataloging unit code(if known): G.8. CSO Operations. Describe any known water quality impacts on the receiving water caused by this CSO(e.g.,permanent or intermittent beach closings,permanent or intermittent shell fish bed closings,fish kills,fish advisories,other recreational loss,or violation of any applicable State water quality standard). END OF PART G. REFER TO THE APPLICATION OVERVIEW(PAGE 1)TO DETERMINE WHICH OTHER PARTS OF FORM 2A YOU MUST COMPLETE. EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 25 of 22 vizi _ CITY OF HENDERSONVILLE X i •��`' M HENDERSONVILLE �'. `r /4-1g , �o '` - M VVWTP � � =- y ' 44'` NPDES PERMIT NC00025534 ' -�',. f a il.' r , • 1 4 i• -.-.t. '•, .ak' .i..off` + r,. �..,. �}4, •'• I - _ :{ at - .-._ +tet', :i!cr v i 1 • ,.• t �`, - Mi t• • .7,/,,,, '. r`„ fir` .. J , • < ,'. , ti, °�,• %-�,,• _; J� -,- �,y 11 - ,ice _ !:N. J`R 'r "04 DTP sir+ "-. , f�L `.' .� ' _I I 's1r # k,+j� •• ,�`• " l c _ •4. It � •X••---• • ..� zr • i r'',�i `moi �,i' r k • i ' ;� t s.� } .r ,)'" I r, "a; �p? :., 7 tir • � ¢. yet �` ` •• r 1.:G! €' ';•',. �•" ! �y r r• v./�.. , ` ,' s' J —�. .so"_ld . •. ; • • 'n R 4. Ott • .. I •llti , .,. ' r + •` ' -, '• .!. r; , . •gin' ' ` . . p, i " . r } .. , ` 'P., . , ., - e, . f :. l'. ..." ‘... '7; - ••. , ...,100 ....OW 0 r ••, ..).)>1,4, .... : . 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' ;►4a4 . •./i/4 '",*►fit f : 41..„,4c--010, ` . • r +i }• '` .,;'•�e t !t1. ._ 'r 11 WWTP Property ' c d• • ! "' , Street Centerline , - o� f F • To_ �� • _.. Major Road Latitude: 35° 21' 11" ,, "F Parcel Longitude: 82° 27' 52" ' • - ,,': :; s ,:' x r .A _ Quad: F9SW/ Hendersonville City Limits Sub-Basin: 04-03-02 ''i . °X Stream Class: C •,, "` .,c `tr t ` . - •A' 0 1,000 2,000 Receiving Stream: Mud Creek , - . • i, Feet Permitted Flow: Phased 4.8 and 6.0 MGD C\ii `, • , ' 1nch=1,000 feet RrCHT-OF-RAT %Imo,— n - 3� ELECTRIC i /,ii \ .- 230• • 1 CwTE �• SEE (] I L 1!7.06' �•' ` \ O- 1 Y I I . . NorE�iii1 % t r+eoo /' L "I 141.68. l —_==x--_1"------ a� f "—i�ari—aGi 1111111 1�� : , xLR- 6e s2'I I �� TI t lJ I�: + TAE3tc[�O ir • '� �I 1 II , \ •n7O0 .� R :.�• / I if II 1 121 TA • j i I • 600 . •• STRUCTURE LOCATION COME ((ID w / I I •0. 6) CONCRETE % \ ,' STRUCTUR .o.Jr LOCATION PLANT wu0 COOR. -'kr. APRON0 ' ,( • N sLu0CE � PAC N 50• Rn500 P NICKENVII • Nw CORNEA 6il2.00 1016.001 I % ( • 1 - • \ . 0 EI05TtNG LT PRESS ANO BWILDINGi • 6 E1 sntaG&BELT PRESS BWIDwG 6�N%.0S1G 1 • SO R■' . T SEPTAC1 NECE6444 STA 1'♦ I , i 20.R „� O % ' ' I t I j • )2 N400 \ ��� J * 1 . I FENCE CORNER LOCATION SCsEDULE ! I I i 1 i ' CORNER PLANT +0 0008, 1 N300 'N• 647.00 i 690.00 , I / 'Cl. • 664700 , 1122.00 •, 1 % NOTES. - ,1 I I i ' I 1. ALL CURB RAOWS SHALL BE 25 FT , ` � \ I �� UNLESS OTNERw1SE SIONN. I 1\\ X`�_X�—_. .h,..,,,...,„ __ ''� alat , / `.200 2 All SrS wKKS SNAIL BE ♦ R w1OE , ;\ ki 1 J/`7 / I / UNLESS OTNERNrSE!SHOWN. II 3. 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I UUMISEMINURS 1CITY Of HENDERSONVILLE PROCESS PIPING PLAN ,,00,13.., ,loal G WASTEWATER FACIUTIES 1....cw .MI PROCESS NARRATIVE Process units located on site include influent pumping station with bar screens designed to handle all raw sewage delivered by 42 inch gravity sewer, all septage received at WWTP for treatment, and waste streams from solids handling facility, consisting of gravity thickener supernatant overflow and belt press filtrates. Additional facilities include headworks consisting of mechanical screening and aerated grit removal; biological treatment using an activated sludge process utilizing fine bubble aeration with single stage nitrification;circular clarifiers; recycle pumping station; effluent polishing using low head filters;disinfection by ultraviolet light; and cascade aeration of final effluent prior to surface discharge to Mud Creek. Design for sludge residuals are treated as prescribed by State and Federal requirements to Class A solid, intended for land application. Residuals are currently disposed of in class D landfill. Capability for re-use of treated wastewater has been incorporated into plant design. S _ \ „----. J c 0 t\ • ..„....\\ ..... . • ,.. , ri A . . . '. \ G N , \ J .,.._ ) ) • `... t . ' • NI 70\. "-N, \ • / f\. , , . 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'7"4"1,--- s. • \ ,:,, , ___________, / / •_„:____-7,6: .„, 21+c) (. \ ..„ 100 ,'''' 000/ ,...- E2__ ----1:100- 1 °E;s1VIA) jE6(t0-,----sr'', ?pp,„\ '''''\'‘ iE1100 ---,'(MO---....-- 1000:\,-•-tc\NI100\\, „SI 2po r I •ci•loct-11\'--•,.,.._gloo Elmo f-v . 0 CA* 4t •' /4 I ii UAL 5 z 1T1 ..... ..... . • 0 CITY OF HENDERSONVILLE '1,0 OW aa/ am" emomo./. 1'.I IAIMSENGINEERS I WASTEWATER FACILITIES GRADING PLAN G-4 - ..... ,,,0 •oGuS1 094 • • Pace Aaalytleat Services,Inc. aeAnalytical. 2225 Flvere ds Dr. Asheville.NC 28804 reef oo P (828)254-7178 ANALYTICAL RESULTS Project VWVTP EFF PPA 5/11-12 Pace Project No.: 92249625 Sample: WWTP EFF PPA Lab ID: 92249825001 Collected: 05/11/15 09:55 Received: 05/13/15 13:30 Matrbc Vtliler Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM,Oil and Grease Analytical Method:EPA 166448 ON and Grease ND mg/I 5.0 1 05/22/1510:12 624 Voltlle Organics Analytical Method:EPA 624 Ac olein ND ug/L 5.0 1 05/17/15 21:55 107-02-8 L3 Acrylonitrile ND u911 50.0 1 05/17/15 21:55 107-13-1 Benzene ND ughL 2.0 1 05/17/15 21:55 71-43-2 Bromodichloromethane ND u9h- 2.0 1 05/17/1521:55 75-27-4 Bromofonn ND WA- 2.0 1 05/17/1521:55 75-25-2 Bromomethane ND ugh 2.0 1 05/17/15 21:55 74-83-9 Carbon tetradrloride ND ugh 2.0 1 05/17/15 21:55 56-23-5 Chlorobenzene ND u9/L 2.0 1 05/17/1521:55 106-90-7 Chioroethene ND u911- 2.0 1 05/17/1521:55 75-00-3 2-Chloroethylvinyi ether ND ugA- 5.0 1 05/17/15 21:55 110-75-8 Chloroform ND ugh 2.0 1 05/17/15 21:55 87-88-3 Chloromethane ND ugh 2.0 1 05/17/15 21:55 74-87-3 Dibromochloromeniane ND ugh- 2.0 1 05/17/15 21:55 124-48-1 1,1-Dichoroethane ND ugh- 2.0 1 05/17/15 21:55 75-34-3 1,2-Dichloroetlans ND ugh 2.0 1 05/17/15 21:55 107-06-2 1,1-DIchbroethene ND ug/t. 2.0 1 05/17/15 21:55 75-35-4 trans-1,2-Dichloroet ene ND ugh 2.0 1 05/17/15 21:55 158-00.5 1,2-0idrloropropene ND ugh 2.0 1 05/17/15 21:55 78-87-5 ds-1,3-Diddoropropene ND ugA- 2.0 1 05/17/15 21:55 10061-01-5 trans-1,3-DidNoroprapene ND ugA. 2.0 1 05/17/1521:55 10061-02-6 Ethylbenzene ND ugh- 2.0 1 05/17/1521:55 100.41-4 Methylene Chloride ND ugh 2.0 1 05/17/15 21:55 75-09-2 1,1,22-Tetrachloroethane ND ug/L 2.0 1 05/17/15 21:55 79-34-5 Tetrachioroalhene ND WA- 2.0 1 05/17/1521:55 127-18-4 Toluene ND ugh- 2.0 1 05/17/15 21:55 108-88-3 1,1,1-TrklNoroethane ND ugh 2.0 1 05/17/15 21:55 71-55-8 1,12-Trkidoroethane ND ugh 2.0 1 05/17/15 21:55 79-00-5 Trichloroethene ND ugA- 2.0 1 05117/15 21:55 79-01-0 Vinyl chloride ND Ain- 2.0 1 05/17/15 21:55 75-01-4 Summates (S) 91 % 70-130 1 05/17/15 21:55 480-00-4 Toluene-d8(S) 97 % 70-130 1 05/17/15 21:55 2037-26-5 1.2-Didioroethane-d4(S) 98 % 70-130 1 05/17/15 21:55 17060-07-0 420.4 Phenolics.Total Analytical Method:EPA 420.4 Phenol ND mg/L 0.010 1 05/20/1516:25 108-95-2 4SOOCNE Cyanide.Total Analytical Method:SM 4500.CN-E Cyanide ND mg/I. 0.0080 1 0524/151129 57-12-0 REPORT OF LABORATORY ANALYSIS This report shell not be reproduced,except In Tut, Date:05/292015 08:08 AM without the written consent of Pace Analytical Services,Inc_ Page 4 of 32 Pace Sending. c. cedn'� ,,,,/s 2225 Riverside Dr. ry rwJ�/�l AshMM.NC 28804 (828)254-7178 ANALYTICAL RESULTS Project WNTP EFF PPA 5/11-12 Pace Project No.: 92249825 Sample: Field 81k WWTP EFF PPA Lab ID: 92249425002 Collected: 05111/1513:46 Received: 06/13/15 13:30 Matrbc Vatter Parameters Results Units Report limit DF Prepared Analyzed CAS No. Dual 1431E Nercury.Low Level Analylical Method:EPA 1831E Preparation Method:EPA 1831E Mercury ND nplL 0.50 1 05/13/15 16:00 05/19/15 15:40 7439-97-8 REPORT OF LABORATORY ANALYSIS This report ehd not be reproduced,swept in full. Date:05/2912015 08:08 AM without the wdaen consent d Pace Analytical Sarvlas,inc.. Page 5of32 Pace Analytical 9aerbe8.Nrc. • 2225 Riverside Dr.c/ nl/rIfcQ/ ANlarlla.NC 28804 •warpeoeYbe oom (828)254-7176 ANALYTICAL RESULTS Project V W VTP EFF PPA 5111-12 Pace Project No.: 92249825 Sample: WWTP EFF PPA LLHO Lab ID: 92249625003 Collected: 05/11/15 13:48 Received: 05/13/15 13:30 Matrix:Water Parameters Results Units Report limit DF Prepared Analyzed CAS No. Qual 1831E Msrcury.Low Level Analytical Method:EPA 1831E Preparation Method:EPA 1831E Mercury 1.22 np!L 0.50 1 05/13/15 18:00 05/1W15 15:47 7439-97-0 REPORT OF LABORATORY ANALYSIS This report shill not be reproduced,wept in full, Date:05/29/2015 08:08 AM without the written consent d Pace Ansy6cal Services,Inc. Pape 8of32 Pace Analytical Services,Inc. ?"1 aceAnalytical b 2225 Riverside Dr. Asheville,NC 28804 *Mew pacelabs.corn (828)254-7176 ANALYTICAL RESULTS Project: WWTP EFF PPA 5/11-12 Pace Project No.: 92249625 Sample: WWTP EFF PPA Lab ID: 92249625004 Collected: 05/12/15 10:16 Received: 05/13/15 13:30 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7 Antimony ND ug/L 5.0 1 05/15/15 16:30 05/18/15 22:37 7440-36-0 Arsenic ND ug/L 10.0 1 05/15/15 16:30 05/18/15 22:37 7440-38-2 Beryllium ND ug/L 1.0 1 05/15/15 16:30 05/18/15 22:37 7440-41-7 Cadmium ND ug/L 1.0 1 05/15/15 16:30 05/18/15 22:37 7440-43-9 --Calcium-- 9820 ug/L 100 1 05/15/15 16:30 05/19/15 15:03 7440-70-2 Chromium ND ug/L 5.0 1 05/15/15 16:30 05/18/15 22:37 7440-47-3 Copper 13.9 ug/L 5.0 1 05/15/15 16:30 05/18/15 22:37 7440-50-8 Lead ND ug/L 5.0 1 05/15/15 16:30 05/18/15 22:37 7439-92-1 AAagneSlUr 2200 ug/L 100 1 05/15/15 16:30 05/18/15 22:37 7439-95-4 Nickel 13.6 ug/L 5.0 1 05/15/15 16:30 05/18/15 22:37 7440-02-0 Selenium ND ug/L 10.0 1 05/15/15 16:30 05/18/15 22:37 7782-49-2 Silver ND ug/L 5.0 1 05/15/15 16:30 05/18/15 22:37 7440-22-4 Thallium ND ug/L 10.0 1 05/15/15 16:30 05/18/15 22:37 7440-28-0 Hardness,Total(SM 2340B) 33600 ug/L 662 1 05/15/15 16:30 05/19/15 15:03 Zinc 68.4 ug/L 10.0 1 05/15/15 16:30 05/18/15 22:37 7440-66-6 245.1 Mercury Analytical Method:EPA 245.1 Preparation Method:EPA 245.1 Mercury ND ug/L 0.20 1 05/20/15 16:30 05/21/15 14:25 7439-97-6 625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625 Acenaphthene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 83-32-9 Acenaphthylene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 208-96-8 Anthracene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 120-12-7 Benzidine ND ug/L 50.0 1 05/19/15 09:10 05/20/15 21:49 92-87-5 L2 Benzo(a)anthracene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 50-32-8 Benzo(b)fluoranthene ND ugAL 5.0 1 05/19/15 09:10 05/20/15 21:49 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 85-68-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 05/19/15 09:10 05/20/15 21:49 111-91-1 bis(2-Chloroethyl)ether ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 111-44-4 bis(2-Chloroisopropyt)ether ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 108-60-1 2-Chloronaphthalene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 91-58-7 2-Chlorophenol ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 7005-72-3 Chrysene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 53-70-3 1,2-Dichlorobenzene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 1066-7 3,3'-Dichlorobenzidine ND ug/L 25.0 1 05/19/15 09:10 0520/15 21:49 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 120-83-2 Diethylphthalate ND ug/L 5.0 1 05/19/15 09:10 0520/15 21:49 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 05/19/15 09:10 05/20/15 21:49 105-67-9 L3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced.except in full, Date:05292015 08:08 AM without the written consent of Pace Analytical Services,Inc.. Page 7 of 32 Paco Analytical Services,Inc. a dn�ti ,,,,/a 2225 Riverside Dr. /v IiUJ�uGUI Asheville,NC 28804 trirspacdabacam (82854-7178 ANALYTICAL RESULTS Project WWTP EFF PPA 5/11-12 Pace Project No.: 92249825 Sample: WWTP EFF PPA Lab ID: 92249625004 Collected: 05/12/15 10:16 Received: 05/13/1513:30 Matrbc Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method:EPA 825 Preparation Method:EPA 625 Dimethylphthalate ND uglL 5.0 1 05/19/15 09:10 05/20/15 21:49 131-11-3 Din-butylphthalate ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 84-74-2 4.6-Dinil o-2-methylphenoI ND ug/L 20.0 1 05/19/15 09:10 05/20/15 21:49 534-52-1 2,4-Dlnitrophenol ND ug/L 50.0 1 05/19/15 09:10 05/20/15 21:49 51-28-5 2,4 Dinitrotoluene ND ugA- 5.0 1 05/19/15 09:10 05/20/15 21:49 121-14-2 2,6-Dina rotoluene ND uglL 5.0 1 05/19/15 09:10 05/20/15 21:49 606-20-2 Dl-n-octylphlhalate ND ughL 5.0 1 05/19/15 09:10 05/20/15 21:49 117-84-0 1,2-Diphenylhydrazine ND ugh 5.0 1 05/19/15 09:10 05/20/15 21:49 122-66-7 bis(2-Ethylhexyl)phthalatee ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 117-81-7 Fluoranthene ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 206-44-0 Fluorene ND ugh 5.0 1 05/19/15 09:10 05/20/15 21:49 86-73-7 Hexachloro-1,3-butadiene ND ugh 5.0 1 05/19/15 09:10 05/20/15 21:49 87-68-3 Hexachlorobenzene ND ugh 5.0 1 05/19/15 09:10 05/20/15 21:49 118-74-1 Hexachlorocydopentadiene ND ugA- 10.0 1 05/19/15 09:10 05/20/15 21:49 77-47-4 Hexachioroethane ND MA- 5.0 1 05/19/15 09:10 05/20/15 21:49 67-72-1 Indeno(1,2,3-od)pyrene ND ug/L 5.0 1 05/19/15 09:10 0520/15 21:49 193-39-5 Isophorone ND ug/L 10.0 1 05/19/15 09:10 0520/15 21:49 78-59-1 334-Met ylphenol(m&p Cresol) ND uglL 10.0 1 05/19/15 09:10 0520/15 21:49 Naphthalene ND uglL 5.0 1 05/19115 09:10 0520/15 21:49 91-20-3 Nitrobenzene ND ug&L 5.0 1 05/19/15 09:10 0520/15 21:49 98-95-3 2-Nltrophenol ND ug/L 5.0 1 05/19/15 09:10 0520/15 21:49 88-75.5 4-Nitrophenol ND uglL 50.0 1 05/19/15 09:10 0520/15 21:49 100-02-7 N-Nltrosodlmethylamine ND ug/L 5.0 1 05/19/15 09:10 05/20/15 21:49 62-75-9 N-NND ugh. 5.0 1 05/19/15 09:10 0520/15 21:49 621-64-7 ND uglL 10.0 1 05/19/15 09:10 0520/15 21:49 8630-6 Pentachlorophenol ND uglL 10.0 1 05/19/15 09:10 05/20/15 21:49 87.86-5 PhenaMhene ND ugA- 5.0 1 05/19/15 09:10 0520/15 21:49 85-01-8 Phenol ND MA- 5.0 1 05/19/15 09:10 0520/15 21:49 108-95-2 Pyrene ND IgA- 5.0 1 05/19/15 09:10 0520/15 21:49 129-00-0 1,2,4-TriGdorobenzene ND uglL 5.0 1 05/19/15 09:10 0520/15 21:49 120-82-1 2,4,6-Trichlorophenol ND Kin- 10.0 1 05/19/15 09:10 0520/15 21:49 88-06-2 Surrogates Nitrobenzene-d5(S) 48 % 10-120 1 05/19/15 09:10 05/20/15 21:49 4165-60-0 2-Fiuorobiphenyi(S) 34 % 15-120 1 05/19/15 09:10 0520/15 21:49 321-60-8 Terphenyl-d14(S) 89 % 11-131 1 051111509:10 0520/1521:49 1718-51-0 Phenol-d6(S) 11 % 10-120 1 05/19/15 09:10 0520/15 21:49 13127-88-3 2-Fluorophenol(S) 18 % 10-120 1 05/19/15 09:10 0520/15 21:49 367-12-4 2,4,6-Tribromophenol(S) 68 % 10-137 1 05/19/15 09:10 0520/15 21:49 118-79-6 2540C Total Dissolved Solids Analytical Method:SM 2540C Total Dissolved Solids 187 mg/L 25.0 1 05/15/15 14:44 350.1 Ammonia Analytical Method:EPA 350.1 Nitrogen,Ammonia ND mgIL 0.10 1 05/15/1513:46 7664-41-7 REPORT OF LABORATORY ANALYSIS This report shell not be reproduced,accept In full, Date:05/29/2015 08:08 AM without the written consent of Pace Analytical Services,Inc.. Page 8 of 32 • Analytical Sabss,he ii;„9 ceAn,�f� 2715 Riverside Dr. �WJu • Pace Asheville.roc 28804 r.r�pecbl�dsaan (828)254-7178 ANALYTICAL RESULTS Project W WTP EFF PPA 5111-12 Pace Project No.: 92249825 Sample: WWTP EFF PPA Lab ID: 52249825004 Collected: 05/12/1510:16 Received: 05/13/15 13:30 Matrbc Water Parameters Results Units Report Lima DF Prepared Analyzed CAS No. Qual 351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 Nitrogen,Kjeldahl.Total 1.2 mg/L 0.50 1 05/21/15 19:42 7727-37-9 353.2 Nitrogen,NO2M03 pros. Analytical Method:EPA 353.2 Nitrogen,NO2 plus NO3 8.1 mg/L 0.080 3 05/28/151928 365.1 Phosphorus,Total Analytical Method:EPA 365.1 Phosphorus 3.2 mg/L 0.050 1 05/20/15 15:03 7723-14-0 REPORT OF LABORATORY ANALYSIS TN.report shall not be reproduced,=apt h rt. Date:05/29/2015 08:08 AM without the wrlasn consent d Pace Analytical&Moss,Inc.. Page 9 d 32 • • &;eAllalYticale Pace Analytical Services,Inc. 2225 Firee Dir. Asherire. sid NC 28804 wissoscsirbaeam (828)254-7176 QUAUFIERS Project WWTP EFF PPA 5111-12 Pace Project No.: 92249825 DEFINITIONS DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot. ND-Not Detected at or above adjusted reporting limit J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL-Practical Quantitation Limit. RL-Reporting LYnlL S-Surrogate I,2-Diphenythydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is a combined concentration. Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values. LCS(D)-Laboratory Control Sample(Duplicate) MS(D)-Matrix Spice(Duplicate) DUP-Sample Duplicate RPD-Relative Percent Diference NC-Not Calculable. SG-Slice Gel-Clean-Up U-Indicates the compound was analyzed for,but not detected. Acid preservation may not be appropriate for 2 Chbroethylvkryl ether,Styrene,and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW848 Chapter 4 for the analysis of Acrolein and Acrylonitrie by EPA Method 8280. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes. TNI-The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services-Asheville PASI-C Pace Analytical Services-Charlotte ANALYTE QUALIFIERS E Analyte concentration exceeded the calibration range.The reported result is estimated. LO Analyte recovery in the laboratory control sample(LCS)was outside QC knits. L2 Analyte recovery in the laboratory control sample(LCS)was below QC limits. Results for this analyte in associated samples may be biased low. L3 Analyte recovery in the laboratory control sample(LCS)exceeded QC limits.Analyte presence below reporting limits in associated samples. Results unaffected by high bias. M1 Matrix spike recovery exceeded QC knits. Batch accepted based on laboratory control sample(LCS)recovery. M8 Matrix spice and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. R1 RPD value was outside control lints. SO Surrogate recovery outside laboratory control knits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in fur. Date:05/282015 08:08 AM without the written consent of Pace Anslytxal Services,Inc.. Page 29 of 32 •ClN COUNCIL: r." y? 4 BARBARA G.VOLT: CiTu OF j :J ! L'' .� .:z _k�.?. �t rOFFICERS: L' ""�' JOHN F.CONNET Mayor The City _ecso s CityManager STEPHENS SAMUEL H.FRITSCHNER Mayor Pro Tern City Attorney STEVE CARAKER WATER AND SFiiWERZ DEPARTMENT TAMMIE K.DRAKE JERRY A.SMITH,JR. Lee Smith, Utilities Director City Clerk JEFF MILLER August 6, 1.2014 e Division of Water Quality �4%,.a� Surface Water Protection Section 1617 Mail Service Center44:% 3 Raleigh,N.C. 27699-1617 Dear Sir or Madam, Please find enclosed the Pollutant Scan results from the City of Hendersonville's WWTP Effluent(NC0025534)sampled on June 16,2014 . If you have any questions,please feel free to call me at(828)697-3077. Sincerely, Scott Chovan Laboratory Supervisor 305 Williams St. Ismith@cityofhendersonvule.org Phone: 828.697.3063 Hendersonville, NC 28792-4461 www.cityofhendersonville.org Fax: 828.697.3089 "mr' anual Monitoring and Pollutant Scan�' ' Permit No.//Gaa`JS537 Month i u!y' Outfall Ce/ Year aloi. ...__... _- Facility Name_Hendersonville WWTP ORC_Vince Edwards Date of Sampling 6/16/2014 Phone _(828) 697-3077 Pace Analytical Services, Inc. Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples_ Ammonia(as N) Composite EPA 350.1 0.10 <0.10 mg/L 1 Dissolved oxygen Grab SM4500-0 0 0.1 7.0 mg/L 1 Nitrate/Nitrite Composite EPA 353.2 0.10 11.3 mg/L 1 Total Kjeldahl nitrogen Composite EPA 351.2 0.50 1.1 mg/L 1 Total Phosphorus Composite EPA 365.1 0.050 3.2 mg/L 1 Total dissolved solids Composite SM 2540C 25.0 155 mg/L 1 Hardness Composite SM 2340B 0.66 34.1 mg/L 1 Chlorine(total residual,TRC) Grab N/A N/A N/A N/A 0 Oil and grease Grab EPA1664A 5.0 <5.0 __ mg/L 1 Metals(total recoverable),cyanide and total phenols Antimony Composite EPA 200.7 5.0 <5.0 ug/L 1 Arsenic Composite EPA 200.7 10.0 <10.0 ug/L 1 Beryllium Composite EPA 200.7 1.0 <1.0 ug/L 1 Cadmium Composite EPA 200.7 1.0 <1.0 ug/L 1 Chromium Composite EPA 200.7 5.0 <5.0 ug/L 1 Copper Composite EPA 200.7 5.0 16.5 ug/L 1 Lead Composite EPA 200.7 5.0 <5.0 ug/L 1 Mercury Composite EPA 1631E 0.50 1.55 ng/L 1 Nickel Composite EPA 200.7 5.0 9.4 ug/L 1 Selenium Composite EPA 200.7 10.0 <10.0 ug/L 1 Silver Composite EPA 200.7 5.0 <5.0 ug/L 1 Thallium Composite EPA 200.7 10.0 <10.0 ug/L 1 Zinc Composite EPA 200.7 10.0 60.0 ug/L 1 Cyanide Grab SM4500CN 0.0050 <0.0050 mg/L 1 Total phenolic compounds Grab EPA 420.4 0.015 0.092 mg/L 1 Volatile organic compounds Acrolein Grab EPA 624 5.0 <5.0 ug/L 1 Acrylonitrile Grab EPA 624 50.0 <50.0 ug/L 1 Benzene Grab EPA 624 2.0 <2.0 ug/L 1 Bromoform Grab EPA 624 2.0 <2.0 ug/L 1 Carbon tetrachloride Grab EPA 624 2.0 <2.0 ug/L 1 Chlorobenzene Grab EPA 624 2.0 <2.0 ug/L 1 Chlorodibromomethane Grab EPA 624 2.0 <2.0 ug/L 1 Chloroethane Grab EPA 624 2.0 <2.0 ug/L 1 2-chloroethylvinyl ether Grab EPA 624 5.0 <5.0 ug/L 1 Chloroform Grab EPA 624 2.0 <2.0 ug/L 1 Dichlorobromomethane Grab EPA 624 2.0 <2.0 ug/L 1 1,1-dichloroethane Grab EPA 624 2.0 <2.0 ug/L 1 1,2-dichloroethane Grab EPA 624 2.0 <2.0 ug/L 1 Trans-1,2-dichloroethylene Grab EPA 624 2.0 <2.0 ug/L 1 Sample Analytical Quantitation Sample ' Units of Number of Parameter Type Method Level Result Measurement samples Volatile organic compounds(Cont.) 1,1-dichloroethylene Grab EPA 624 2.0 <2.0 ug/1 1 1,2-dichloropropane Grab EPA 624 2.0 <2.0 _ ug/I 1 1,3-dichioropropylene Grab EPA 624 2.0 <2.0 ug/1 1 Ethylbenzene Grab EPA 624 2.0 <2.0 ug/1 1 Methyl bromide. PPA-1 Grab EPA 624 2.0 <2.0 _ ug/1 �1� 1111 - annual Monitoring and Pollutant Scan`r f . • Permit No. /W 00,25531/ Month •J Uly Outfall , Year AO/d/ Methyl chloride Grab EPA 624 2.0 <2.0 ug/1 1 Methylene chloride Grab EPA 624 2.0 <2.0 ug/1 1 1,1,2,2-tetrachloroethane Grab EPA 624 2.0 <2.0 ug/1 1 Tetrachloroethylene Grab EPA 624 2.0 <2.0 ug/1 1 Toluene Grab EPA 624 2.0 ' • <2.0 ug/1 1 1,1,1-trichloroethane Grab EPA 624 2.0 <2.0 ug/1 1 1,1,2-trichloroethane Grab EPA 624 2.0 <2.0 ug/1 1 Trichloroethylene Grab EPA 624 2.0 <2.0 ug/1 1 Vinyl chloride Grab EPA 624 2.0 <2.0 ug/1 1 Acid-extractable compounds P-chloro-m-creso Grab EPA 625 10.0 <10.0 ug/1 1 2-chlorophenol Grab EPA 625 5.0 <5.0 ug/1 1 2,4-dichlorophenol Grab EPA 625 5.0 <5.0 ug/1 1 2,4-dimethylphenol Grab EPA 625 10.0 <10.0 ug/1 1 4,6-dinitro-o-cresol Grab EPA 625 20.0 <20.0 ug/1 1 2,4-dinitrophenol Grab EPA 625 50.0 <50.0 ug/1 1 2-nitrophenol Grab EPA 625 5.0 <5.0 ug/1 1 4-nitrophenol Grab EPA 625 50.0 <50.0 ug/1 1 Pentachlorophenol Grab EPA 625 10.0 <10.0 ug/1 1 Phenol Grab EPA 625 5.0 <5.0 ug/1 1 2,4,6-trichlorophenol Grab EPA 625 10.0 <10.0 ug/1 1 Base-neutral compounds Acenaphthene Grab EPA 625 5.0 <5.0 ug/1 1 Acenaphthylene Grab EPA 625 5.0 <5.0 ug/l 1 Anthracene Grab EPA 625 5.0 <5.0 ug/1 1 Benzidine Grab EPA 625 50.0 <50.0 ug/1 1 Benzo(a)anthracene Grab EPA 625 5.0 <5.0 ug/1 I Benzo(a)pyrene Grab EPA 625 5.0 <5.0 ug/1 1 3,4 benzofluoranthene Grab EPA 625 5.0 <5.0 , ug/1 1 Benzo(ghi)perylene Grab EPA 625 5.0 <5.0 ug/1 1 Benzo(k)fluoranthene Grab EPA 625 5.0 <5.0 ug/1 1 Bis(2-chloroethoxy)methane Grab EPA 625 10.0 <10.0 • ug/1 1 Bis(2-chloroethyl) ether Grab EPA 625 5.0 <5.0 ug/1 1 Bis(2-chloroisopropyl)ether Grab EPA 625 5.0 <5.0 ug/1 1 Bis (2-ethylhexyl)phthalate Grab EPA 625 5.0 <5.0 ug/I 1 4-bromophenyl phenyl ether Grab EPA 625 5.0 <5.0 ug/1 1 Butyl benzyl phthalate Grab EPA 625 5.0 <5.0 ug/1 1 2-chloronaphthalene Grab EPA 625 5.0 <5.0 ug/1 1 4-chlorophenyl phenyl ether Grab EPA 625 5.0 <5.0 ug/1 1 Sample Analytical Quantitation Sample Units of Number of Parameter Type Method Level Result Measurement samples Base-neutral compounds(cont.) Chrysene Grab EPA 625 5.0 <5.0 ug/1 1 Di-n-butyl phthalate Grab EPA 625 5.0 <5.0 ug/1 1 Di-n-octyl phthalate Grab EPA 625 5.0 <5.0 ug/l 1 Dibenzo(a,h)anthracene Grab EPA 625 5.0 <5.0 ughl 1 1,2-dichlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 1,3-dichlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 1,4-dichlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 3,3-dichlorobenzidine Grab EPA 625 25.0 <25.0 ug/1 1 Diethyl phthalate Grab EPA 625 5.0 <5.0 ug/1 1 Dimethyl phthalate Grab EPA 625 5.0 <5.0 ug/1 1 2,4-dinitrotoluene Grab EPA 625 5.0 <5.0 ug/1 1 2,6-dinitrotoluene Grab EPA 625 5.0 <5.0 ug/1 1 1,2-dipini- 1y��A-1 Grab EPA 625 5.0 <5.0 u/l mini 1ll� c Il'innual Monitoring and Pollutant Scam te • Permit No.��o 6-,s 4/ Month l-rC//), Outfall . (.)O/ Year..2Q/ f - Fluoranthene Grab EPA 625 5.0 <5.0 ug/1 1 Fluorene Grab EPA 625 5.0 <5.0 ug/1 1 Hexachlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 Hexachlorobutadiene Grab EPA 625 5.0 <5.0 ug/1 1 Hexachlorocyclo-pentadiene Grab EPA 625 10.0 <10.0 ug/1 1 Hexachloroethane Grab EPA 625 5.0 <5.0 ug/1 1 Indeno(1,2,3-cd)pyrene Grab EPA 625 5.0 <5.0 ug/1 1 Isophorone Grab EPA 625 10.0 <10.0 ug/1 1 Naphthalene Grab EPA 625 5.0 <5.0 ug/1 1 Nitrobenzene Grab EPA 625 5.0 <5.0 ug/1 1 N-nitrosodi-n-propylamine Grab EPA 625 5.0 <5.0 ug/1 1 N-nitrosodimethylamine ' Grab EPA 625 5.0 <5.0 ug/1 1 N-nitrosodiphenylamine Grab EPA 625 10.0 <10.0 us/1 1 Phenanthrene Grab EPA 625 5.0 <5.0 ug/1 1 Pyrene Grab EPA 625 5.0 <5.0 ug/1 1 1,2,4,-trichlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified peri personnel gather and evaluate the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsib]sible for gathering the information information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. 9 --/- ` _ . .: Authorized Represen*bte.name • i.. Signature , e ,4 .e ' Gi ' .-1 Date Form- DMR- PPA-1 Page 3 • �' - .. /Ralf *11110r Pate Analytical service.,Ina. erside Dr. / / . PaceAnalytical As. 2225p`'NC 21, a,w p.csIabacom (825)254-7176 ANALYTICAL RESULTS Project Wastewater 6/16 Pace Project No.: 92205859 Sample: W WTP EFF PPA GRAB Lab ID: 92208859001 Collected: 06//18/1410:19 Received: 08/1811412:00 Matrix:Water Parameters Results Units Report limit DF Prepared Analyzed CAS No. Qua! HEM,OH and Grease Analytical Method:EPA 168848 011 and Grease ND mg/I.. 5.0 1 06/19/14 12:00 824 Volatile Organics Analytical Method:EPA 624 Acrolsin ND ugh 5.0 1 08/30/14 14:57 107-02-8 Acrylonitrile ND ug/L 50.0 1 06/30/14 14:57 107-13-1 Benzene ND ugh 2.0 1 06(30/1414:57 7143-2 Bromodichloromethane ND ugh 2.0 1 06/30/14 14:57 75-274 Bromoform ND ug/L 2.0 1 08/30/14 14:57 75-25-2 Bromomethane ND ug/L 2.0 1 06/30/14 14:57 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 06//30/1414:57 58-23-5 Chlorobenzene ND ugh 2.0 1 08/30/14 14:57 108-90-7 Chloroethane NO ug/L 2.0 1 06/30/14 14:57 75-00-3 2-Chloroethylvinyl ether ND ugh 5.0 1 06/30/14 14:57 110-75-8 Chloroform ND ugh 2.0 1 06/30/14 14:57 67-66-3 Chloromethane ND ug/L 2.0 1 06/30/14 14:57 74-87-3 Dibromochloromethane ND ug/L 2.0 1 06/30/14 14:57 124-48-1 1,1-Dlchloroethane ND ugh. 2.0 1 06/30/1414:57 75-34-3 1.2-Dichloroethane ND ug/L 2.0 1 08/30/14 14:57 107-06-2 1,1-Diddoroethene ND ugh 2.0 1 06/30/14 14:57 75-35-4 trans-1,2-Dlchloroethene ND ug/L 2.0 1 06//30/1414:57 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 06/30/1414:57 78-87-5 ds-1,3-Dichloropropene ND ug/L 2.0 1 06/30/14 14:57 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 06/30/14 14:57 10081-02-6 Ethylbenzene ND ug/L 2.0 1 06/30/14 14:57 10041.4 Methylene Chloride ND ug/L 2.0 1 06/30/14 14:57 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 06/30/14 14:57 79-34-5 Tetrachloroethene ND ugh 2.0 1 06/30/14 14:57 127-18-4 Toluene ND ug/L 2.0 1 06/30/14 14:57 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 06/30/14 14:57 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 06130/14 14:57 79-00-5 Trichloroethene ND ugh 2.0 1 06/30/14 14:57 79.01-8 Vinyl chloride ND ugh 2.0 1 06/30/14 14:57 75-01-4 Surrogate 4-Bromofluorobenzens(5) 90 % 70-130 1 08/30/14 14:57 480-00-4 Toluene-d8(S) 99 % 70-130 1 06/30/14 14:57 2037-26-5 1,2-Dlchloroethane-d4(S) 100 % 70-130 1 08/30/14 14:57 17060-07-0 420.4 Phenolics,Total Analytical Method:EPA 420.4 Phenol 0.092 mg/L 0.015 3 07/02/14 21:46 108-95-2 M1 4600CNE Cyanide,Total Analytical Method:SM 4500-CN-E Cyanide ND mg/L 0.0050 1 06/22/1412:12 57-12-5 REPORT OF LABORATORY ANALYSIS TNI report.hail not be reproduced,accept In tut, Date:07/03/2014 07:19 AM without the written consent of Pace Analytical Services.Inc.. Page 4 of 31 G. Nur for Pace Analytical Services.Inc. laceAnalytical' Ad2225 arevenid.o.' (828)254-7176 ANALYTICAL RESULTS Project Wastewater 6/16 Pace Project No.: 92205859 Sample: YVINTP EFF PPA GRAB Lab ID: 02205859002 Collected: 06/18/14 15:06 Received: 06/18/14 12:00 Matrix:Water LLHG Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1631E M.rcury,Low Level Analytical Method:EPA 1831E Preparation Method:EPA 1631E Mercury 1.56 ng/L 0.50 1 06/25/1415:00 07/02/14 14:54 7439-97.6 REPORT OF LABORATORY ANALYSIS This moon shall not be reproduced.except In full, Date:07/03/2014 07:19 AM without the written consent of Pace Analytical Services,Inc.. Page 5 of 31 / 1d' NNW Pace Analytical Services,talc. • ..PaceAnalytica! 2225 Riverside Dr. 8804 wwwpec iabscam Asheville,NC (929)254-71711-7176 ANALYTICAL RESULTS Project: Wastewater 6/16 Pace Project No.: 92205859 Sample: FIELD ELK WVKTP EFF Lab ID: 92206869003 Collected: 08/18/1415:06 Received: 06118/14 12:00 Matrix:Water LLHG Parameters Results Units Report lJmIt DF Prepared Analyzed CAS No. Qual 1831E Mercury,Low Level Analytical Method:EPA 1831E Preparation Method:EPA 1831E Mercury ND ng/L 0.50 1 08/25/14 15:00 07/02/14 15:02 7439-97.8 • REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in fit, Date:07/03/2014 07:19 AM without the written consent of Pace Analytical Services,Ino.. Page 6 of 31 /�' `I Paco Aeaytkal Services,Inc. . ` .PaceAnalyfical, 2225 Riverside a Asheville,NC 28804 wenvonceicccoen (828)284-7178 ANALYTICAL RESULTS Project: Wastewater 8/18 Pace Project No.: 92205859 Sample: WWTP EFF PPA COMP Lab ID: 82205859004 Collected: 06/16/14 09:20 Received: 06/18/14 12:00 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7 Antimony ND ug/L 5.0 1 08/19/14 12:40 06/20/14 19:26 7440-36-0 Arsenic ND ug/L 10.0 1 08/19/14 12:40 06/20/14 19:28 7440-38-2 Beryllium ND ug/L 1.0 1 08/19/14 12:40 08/20/14 19:28 7440-41-7 Cadmium ND ug/L 1.0 1 06/19/14 12:40 06/20/14 19:28 7440-43-9 Calcium 10200 ug/L 100 1 08/19/14 12:40 06/20/14 19:26 7440-70-2 Chromium ND ug/L 5.0 1 08/19/14 12:40 06/20/14 19:28 7440-47-3 Copper 18.5 ug/L 5.0 1 08/19/14 12:40 08/20/141926 7440-50-8 Lead ND ugh 5.0 1 00/19/14 12:40 06/20/14 19:26 7439-92-1 Magnesium 2110 ugh 100 1 08/19/14 12:40 08120/14 19:26 7439-95-4 Nickel 9.4 ug/L 5.0 1 06/19/14 12:40 06/20/14 19:28 7440-02-0 Selenium ND ugh 10.0 1 08/19/1412:40 08/20/1419:26 778249-2 Silver ND ugh 8.0 1 06/19/14 12:40 06/20/14 19:28 7440-22-4 Thallium ND ugh 10.0 1 08/19/14 12:40 08/20/1419:26 7440-28-0 Hardness,Total(SM 23408) 34100 ug/L 682 1 08/19/14 12:40 06/20/14 19:26 Zinc 60.0 ug/L 10.0 1 08119/1412:40 06/20/14 19:28 7440.66-6 625 MSSV Analytical Method:EPA 825 Preparation Method:EPA 625 Acenaphthene ND ug/L 5.0 1 06/23/14 08:25 06/25/14 06:58 83-32-9 Acenaphthylene ND ugh 5.0 1 08/23/14 08:25 06/25/14 08:56 208-98-8 Anthracene ND ugh 5.0 1 06/23/14 08:25 06/25/14 08:58 120-12-7 Benzidine ND ugh 50.0 1 08/23/14 0825 06/25/14 08:56 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 06/23/14 08:25 06/25/14 06:56 58-55-3 Benzo(a)pyrene ND ugh 5.0 1 06/23/14 08:25 06/25/14 06:56 5032-8 Benzo(b)fluoranthene ND ugh 5.0 1 08/23/14 08:25 08/26/14 06:56 205-99-2 Benzo(0,1)perylene ND ugh 5.0 1 08/23/14 08:25 08/25/14 08:56 191-24-2 Benzo(k)fluoranthene ND ugh 5.0 1 06/23/14 08:25 06125/14 08:58 207-08-9 4-Bromaphenylphenyt ether ND ug/L 5.0 1 08/23/14 08:25 06/25/14 06:56 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 06/23/14 08:25 06/25/14 06:56 85-68-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 06/23/14 08:25 06/25/14 08:56 111-91-1 bis(2-Chloroethy1)ether ND ug/L 5.0 1 06/23/14 08:28 06/25/14 06:58 11144.4 bls(2-Chloroisopropyl)ether ND ug/L 5.0 1 08/23/14 08:25 0825/14 08:56 108.80-1 2-Chloranaphthalene ND ug/L 5.0 1 08/23/1408:25 08/25/14 06:56 91-58-7 2-Chlorophenol ND ugh 5.0 1 08/23/14 08:25 08/25/14 08:56 95-57-8 4-Chlorophenylphenyl ether ND ugh 5.0 1 06/23/14 08:25 06/25/14 08:56 7005-72-3 Chrysene ND ugh. 5.0 1 08/23/14 0825 06/25/14 08:58 218-01-9 Dibenz(a,h)anthracene ND ugh 5.0 1 08/23/14 08:25 0825/14 08:56 53-70-3 1,2-Dlchiorobenzena ND ug/L 5.0 1 06/23/14 08:25 06/25/14 06:56 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 1 06/23/14 08:25 06/28/14 06:58 541-73-1 1.4-Dichlorobenzene ND ug/L 5.0 1 0823/14 08:25 08/25/14 06:58 106-48-7 3,3'-Dichlorobenzld ne ND ugh 25.0 1 0623/14 08:25 08/25/14 06:58 91-94-1 2.4-Oichiorophenol ND ugh 5.0 1 06/23/14 0825 06/25/14 08:58 120-83-2 Dletltylphthalate ND ugh 5.0 1 06/23/14 08:25 08/25/1406:56 84-68-2 2,4-Dimethylphenol ND ug/L 10.0 1 08/23/14 08:25 08/25/1408:58 105-87-9 Dimetylphihsute ND ug/L 5.0 1 08/23/14 08:25 06/26/14 08:58 131-11-3 DM-butyiphthalate ND ug/L 5.0 1 08/23/14 08:25 06/25/14 06:58 84-74-2 4,6-Dinitro-2-methylphenol ND Ug/L 20.0 1 08/23/14 0825 06/25/1406:58 534-52-1 2,4-Dinitrophenol ND ugh 50.0 1 0823/14 08:25 0825/14 06:88 51-28-5 REPORT OF LABORATORY ANALYSIS Thu report shell not be reproduced,except In full, Date:07/03/2014 07:19 AM without the mitten consent of Pace Analytical Sargon,Inc.. Page 7 of 31 lytical Services.Mc- Riverside aceAnal kale r.. IMAM5 � bny,, cont Asheville,NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: wastewater 6/16 Pace Protect No.: 92205859 Sample: W WTP EFF PPA COMP Lab ID: 92205869004 Collected: 06/18/14 09:20 Received: 08/18/14 12:00 Matrix:Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 825 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625 2,4-Dinitrotoiuene ND ug/L 5.0 1 06/23/14 08:25 06/25/14 06:58 121-14-2 2,8-Dinitrotokiene ND ug/L 5.0 1 0623/14 08:25 06/25/14 06:66 608-20-2 Dl-n-octyiphthalate ND ug/L 5.0 1 06/23/14 08:25 0825/14 08:56 117-84-0 12-Diphenyihydrazine ND ugh 5.0 1 08/23/14 08:25 06/25/14 08:58 122.88-7 bis(2-Ethylhexyl)phthaiate ND ug/L 5.0 1 0623/14 08:25 06/25/14 06:58 117-81-7 Fluoranthene ND ug/L 5.0 1 0823/14 08:26 0625/14 06:58 206.44-0 Fluorene ND ugh 5.0 1 0823/14 08:25 06/25/1406:56 86-73-7 Hexachioro-1.3-butadlene ND ug/L 5.0 1 08/23/14 08:25 0825/14 06:58 87-68-3 Hexachlorobenzene ND ugh 5.0 1 08/23/14 08:25 0625/14 08:56 118-74-1 Hexachlorocyciopentadiene ND ug/L 10.0 1 06/23/14 05:25 06/25/14 06:58 77-47-4 Hexachioroethane ND ug/L 5.0 1 08/23/14 08:25 08/25/14 06:58 87.72.1 Indeno(1,2,3-cd)pyrene • ND ug/L 5.0 1 0823/14 08:25 06/25/14 06:58 193-39-5 Isophorone ND ug/L 10.0 1 06/23/14 08:25 06/25/14 06:58 78-59-1 364-Methyiphenof(m&p Cresol) ND ugh 10.0 1 06/23/14 08:25 0625/14 06:56 Naphthalene ND ugh 5.0 1 06/23/14 08:25 06/25/14 08:56 91-20-3 Nitrobenzene ND ug/L 5.0 1 08/23/1408:25 0625/14 06:56 98-95-3 2-Nltrophenol ND ugh 5.0 1 0823/14 08:25 0825/14 08:58 88-75-5 4-Nitrophenol ND ug/L 9 50.0 1 06/23/14 08:25 06/25/14 06:56 100-02-7 N-Nitrosodlmethylamine ND ugh 5.0 1 06/23/14 06:25 08/25/14 06:56 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 06/23/14 08:25 06/25/14 06:56 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 08/23/14 08:25 0625/14 06:56 86-30-6 Pentachlorophenol ND ug/L 10.0 1 06/23/14 08:25 06/25/14 06:56 67-86-5 Phenanthrene ND ugh 5.0 1 06/23/14 08:25 06/25/14 06:58 85-01-8 Phenol ND ugh 5.0 1 06/23/14 08:25 0825/14 06:56 108-95-2 ane ND ug/L 5.0 1 08/23/14 08:25 06/25/14 06:56 129-00-0 1,2,4-Trichlorobenzene ND ugh 5.0 1 06/23/14 08:25 08/25/14 06:58 120-82-1 2,4,6-Trichlorophenol 4.6-T�rophenol ND ugh 10.0 1 0623/14 08:25 06/25/14 08:58 88-06-2 Nitrobenzene-d5(S) 25 % 10-120 1 06/23/14 08:25 06/25/14 06:56 4165-80-0 2-Fluorobiphenyl(S) 24 % 15-120 1 0823/14 08:25 06/25/14 08:58 321.80-8 Terphenyi-d14(S) 57% 11-131 1 0823/1408:26 06/25/1408:56 1716-51-0 Phenol-d8(S) 10 % 10-120 1 06/23/14 08:25 0625/14 06:56 13127-88-3 2-Fluorophenol(S) 14 % 10-120 1 0623/14 08:25 06/25/14 06:56 387-12-4 2,4,8-Tribromophenol(S) 19 % 10-137 1 0623/14 08:26 06/25/14 06:58 118-79-6 2540C Total Dissolved Solids Analytical Method:SM 2540C Total Dissolved Solids 155 mg/L 25.0 1 06/23/14 14:39 350.1 Ammonia Analytical Method:EPA 350.1 Nitrogen,Ammonia ND mg/L 0.10 1 06/18/1416:58 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 Nitrogen,Kjeldahl,Total 1.1 mg/L 0.50 1 08f19/1416:26 7727-37-9 363.2 Nitrogen,NO2/NO3 pros. Analytical Method:EPA 353.2 Nitrogen,NO2 plus NO3 11.3 mg/L 0.10 5 08/27/1418:44 REPORT OF LABORATORY ANALYSIS THe report shell not be reproduced,except In run, Date:07/03/2014 07:19 AM without the wduen consent or Pace Anslytlal Services,Inc.. Page 8 of 31 'lurer' rPace An. Sep/Ices,Inc. dCB�lal Cc?I NEIyuw2225 a Asheville,NC 28804 Nwmpaceiehs.cam (828)254-7178 ANALYTICAL RESULTS Project: Wastewater 6/16 Pace Project No.: 92205859 Sample: W WTP EFF PPA COMP Lab ID: 92206859004 Collected: 06/18/14 09:20 Received: 06/18/14 12:00 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Dual 365.1 Phosphorus,Total Analytical Method:EPA 365.1 Phosphorus 3.2 mg/L 0.050 1 08/24/14 16:45 7723-14-0 REPORT OF LABORATORY ANALYSIS This report shill not be reproduced.except In full, Date:07/03/2014 07:19 AM wtthout the written consent of pace Anolytlgl Sates,Inc.. Pape 9 of 31 • ter' Pace Analytical Services,Inc. Pace Analytics! 2225 Riverside Dr. M+mcaebr.wa A�ravifle,NC 28804 (828)254.7176 QUALIFIERS Project: Wastewater 8/18 Pace Project No.: 92205859 DEFINITIONS DF-Dilution Factor,if reported,represents the factor applied to the reported data due to changes in sample preparation,dilution of the sample aliquot,or moisture content ND-Not Detected at or above adjusted reporting limit. .1-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL-Practical Quantitation Limit. RL-Reporting Limit. S-Surrogate 1,2-Diphenylhydrazine(8270 listed analyte)decomposes toAzobenzene. Consistent with EPA guidelines,unrounded date are displayed and have been used to calculate%recovery and RPD values. LCS(D)-Laboratory Control Sample(Duplicate) MS(D)-Matrix Spike(Duplicate) DUP-Sample Duplicate RPD-Relative Percent Difference NC-Not Calculable. SG-Silica Gel-Clean-Up U-Indicates the compound was analyzed for,but not detected. eodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for anaiyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether,Styrene,and Vinyl chloride. LOD-Limit of Detection. LOQ-Limit of Quantitation. Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes. TNI-The NELAC institute. LABORATORIES PAST-A Pace Analytical Services-Asheville PAS1-C Pace Analytical Services-Charlotte ANALYTE QUALIFIERS D6 The relative percent difference(RPD)between the sample and sample duplicate exceeded laboratory control limits. L2 Analyte recovery in the laboratory control sample(LCS)was below QC limits. Results for this analyte In associated samples may be biased low. MO . Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution, R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS Date:07f03l2014 07:19 AMThis report shell not be reproduced,except In full, without the written consent of Pace Analytical Services,Inc.. Page 28 of 31 CHAIN-OF-CUSTODY/Analytical Request Document aceAnalytical- The Chain-of-Custody Is a LEGAL DOCUMENT At relevant fields must be completed accurately. c� 77( w .Pamlabs.cam O wv Cr) Section A Section B Required Client Information. Section C Pte: of N Required Project Infonnatlorc pr Company: Invoice Information: Q a. e .4B.Vel t rd,-vi•-// 4fJIV/Y Report To. ...• y.� Attention: //� 1 3 9 6 8?5 Address: p /T"U U/r g� Copy To: O7 C./.4.0r... �CCo VcO�/G-a/v' s'C•to ompanYName. p314ATOR ..AGENCY P Address: 9Q 4X'l A :E Email To: - /l Q(/!. R� NPDES ;- GROUND WATER r DRINKING WATER Purchase Order No.: Pace Quote Pnone�I�.yO Fax:/ - �dNe Reference: Si UST (- RCRA r- OTHER r 7 77 I 6 j��Q�03 Project Name: Pam Protect Requested Due DatOITAT: Project Number. Manager. Site STAT : T Pace Prone F: S TATE: /.141, ... Section 0 _ .Requested Analysis Filtered(YIN) - Matrix Codes Required Caws Inlomrae, COOS MATRIX r i o COLLECTED Preservatives .7i. . a I� Drinking Water OW a z• /� Water WT U 0 Waste Water WW COHFSSfrE COAPOSNE R Product P 9 Q ST/Rr ENOCg.Aa , _ SOIVSofid Si ¢ SAMPLE ID on Si ! g it 4 t. (A-Z,0-9/,) e AW m ?JrAir qw R < z 11 Sample IDs MUST BE UNIQUE Tissue TS O n a. 'g :g N [` L Other OT O I Z* 2 0< 1 H 1 < DATE TIME DATE TIME CO lb D 2 i 2 Z A O 3 v l Cr �t''e t N / 1 4fer4,� �� CPPA �] v IX Pace Pro ea No./Lab I.D. ,� ��- rD r .. i O i �II. - �l kX Y 5 r y . X X kX X 1C ..,..21, c s.54 C:ii y s., s• T- T Q I , 1 • Y. I lilt 1 , HI 11 I 1; AO.. .•AL.CO. - RELINQUISHED BYIAFFWATION DATE TIME ACC D B`!/AFFl •TION DATE 'hue SAMPLE CONDITIONS ,l i/"J- 9l ! 7# � AZ � �so6 . ORIGINAL . . . R 00.*l***,:. ... _ P U `0 ts FRIT NNamof SAMPLER• //�/ J' SIGNATURE of SAMPLER J _ �,r�`0� DATE Signed e tj Z' 'Mportard Note By 090mg this lam you are accepting Pace's NET 311 day payment terms and apreeNr9 m late charges of 1,5%per month fn¢en-G y-bwroicos not peld!sAthin 30 days._ (walDD/rv): ��f y w F-ALL-0-020rev.07,15-May-2007 yaw w • OFFICERS: . CRY COUNCIL: JOHN F.CONNET BARBARA G.VOLK G p OF HEiERSONVftL Mayor The City of Four seasons City Manager JEFF COWS SAMUEL.H.FRrrsCHNER Mayor Pro Tem City Attorney STEVE CARAi:ER WATER.AND SEWER TAMMLE K.DRAKE JERRY A.SMITH.JR. Lee Smith, Utilities Director city Clerk RON STEPHENS October 17,2013 Division of Water Quality Surface Water Protection Section 1617 Mail Service Center Raleigh,N.C.27699-1617 Dear Sir or Madam, Please find enclosed the Pollutant Scan results from the City of Hendersonville's WWTP Effluent(NC0025534)sampled on September 19,2013 . If you have any questions, please feel free to call me at(828)697-3077. Sincerely, Scott Chovan,Laboratory Supervisor 305 Williams St. • ismith@cityofhendersonvllle.org Phone: 828.697.3073 Hendersonville, NC 28792-4461 www.cityofhendersonvflle.org Fax: 828.697.3089 ual Monitoring and Pollutant Sean �' Permit No.M.:00...-25...-3" Month '/G.ZN: Outfall 62/ Year . O Facility Name_Hendersonville WWTP ORC_Vince Edwards Date of Sampling 9/19/2013 Phone _(828) 697-3077 Pace Analytical Services, Inc. Sample Analytical Quantitation Sample Units of Number of Parameter 'lopeMethod Level Result Measurement samples _ Ammonia(as N) Composite EPA 350.1 _ 0.10 <0.10 mg/L 1 Dissolved oxygen Grab SM4500-0 G 0.1 6.9 mg/L 1 Nitrate/Nitrite . Composite EPA 353.2 0.10 13.3 mg/L 1 Total Kjeldahl nitrogen Composite EPA 351.2 0.50 1.1 mg/L 1 Total Phosphorus Composite EPA 365.1 0.050 2.9 mg/L 1 Total dissolved solids Composite SM 2540C 25.0 211 mg/L 1 Hardness Composite SM 2340B 0.66 32.2 mg/L 1 Chlorine(total residual,TRC) Grab N/A N/A N/A N/A 0 Oil and grease Grab EPA1664A 5.0 <5.0 mg/L 1 Metals(total recoverable),cyanide and total phenols Antimony Composite EPA 200.7 5.0 <5.0 ug/L 1 Arsenic Composite EPA 200.7 10.0 <10.0 ug/L 1 Beryllium Composite EPA 200.7 1.0 <1.0 ug/L 1 Cadmium Composite EPA 200.7 1.0 <1.0 ug/L 1 Chromium Composite EPA 200.7 5.0 <5.0 ug/L 1 Copper Composite EPA 200.7 5.0 15.3 ug/L 1 Lead Composite EPA 200.7 5.0 <5.0 ug/L 1 Mercury Composite EPA 1631E 0.50 0.955 ng/L 1 Nickel Composite EPA 200.7 5.0 7.3 ug/L 1 Selenium Composite EPA 200.7 10.0 <10.0 ug/L 1 Silver Composite EPA 200.7 5.0 <5.0 ug/L 1 Thallium Composite EPA 200.7 10.0 <10.0 ug/L 1 Zinc Composite EPA 200.7 10.0 53.5 ug/L 1 Cyanide Grab SM4500CN 0.0050 0.0065 mg/L 1 Total phenolic compounds Grab EPA 420.4 0.0050 0.0084 mg/L 1 Volatile organic compounds Acrolein Grab EPA 624 100 <100 ug/L 1 Acrylonitrile Grab EPA 624 50.0 <50.0 ug/L 1 Benzene Grab EPA 624 5.0 <5.0 ug/L 1 Bromoform Grab EPA 624 5.0 <5.0 ug/L 1 Carbon tetrachloride Grab EPA 624 5.0 <5.0 ug/L 1 Chlorobenzene Grab EPA 624 5.0 <5.0 ug/L 1 Chlorodibromomethane Grab EPA 624 5.0 <5.0 ug/L 1 Chloroethane Grab EPA 624 10 <10, ug/L 1 2-chloroethylvinyl ether Grab EPA 624 10 <10 1 ug/L 1 Chloroform Grab EPA 624 5.0 <5.0 ug/L 1 Dichiorobromomethane Grab EPA 624 5.0 <5.0 ug/L 1 1,1-dichloroethane Grab EPA 624 5.0 <5.0 ug/L 1 1,2-dichloroethane Grab EPA 624 5.0 <5.0 ug/L 1 Trans-l,2-dichloroethylene _ Grab EPA 624 _ 5.0 <5.0 ug/L 1 Parameter Sample -Analytical Quantitation' Sample Units of Number of TYPe Method Level Result Measurement samples Volatile organic compounds(Cont.) 1,1-dichloroethylene Grab EPA 624 5.0 <5.0 ug/1 1 1,2-dichloropropane Grab EPA 624 5.0 <5.0 ug/1 1 1,3-dichloropropylene Grab EPA 624 5.0 <5.0 ug/1 1 Ethylbenzene Grab EPA 624 5.0 <5.0 ug/1 1 Methrubromj R-PPA-1 Grab EPA 624 5.0 <5.0 ug/1 , D P'agv 11 ` nual Monitoring and Pollutant Scan �' L Permit No./It 4C��.5�.S.�yiMonth T6P Outfall OW Year D/. Methyl chloride Grab EPA 624 5.0 <5.0 ug/1 1 Methylene chloride Grab EPA 624 5.0 - <5.0 ug/1 1 1,1,2,2-tetrachloroethane - Grab EPA 624 5.0 <5.0 ug/1 1 Tetrachloroethylene Grab EPA 624 5.0 <5.0 ug/1 1 Toluene Grab EPA 624 5.0 <5.0 ug/1 1 1,1,1-trichloroethane Grab EPA 624 5.0 <5.0 ug/1 1 1,1,2-trichloroethane Grab EPA 624 5.0 <5.0 ug/1 1 Trichloroethylene Grab EPA 624 _ 5.0 <5.0 ug/1 1 Vinyl chloride Grab EPA 624 5.0 <5.0 ug/1 1 Acid-extractable compounds P-chloro-m-creno Grab EPA 625 10.0 <10.0 ug/1 1 2-chlorophenol Grab EPA 625 5.0 <5.0 ug/1 1 2,4-dichlorophenol Grab EPA 625 5.0 <5.0 ug/1 1 2,4-dimethylphenol Grab EPA 625 10.0 <10.0 ug/1 1 4,6-dinitro-o-cresol Grab EPA 625 20.0 <20.0 ug/1 1 2,4-dinitrophenol Grab EPA 625 50.0 <50.0 ug/1 1 2-nitrophenol Grab EPA 625 5.0 <5.0 ug/1 1 4-nitrophenol Grab EPA 625 50.0 <50.0 ug/1 1 Pentachlorophenol Grab EPA 625 10.0 <10.0 ugh! 1 Phenol Grab EPA 625 5.0 <5.0 ug/1 1 2,4,6-trichlorophenol Grab EPA 625 10.0 <10.0 ug/1 1 Base-neutral compounds Acenaphthene Grab EPA 625 5.0 <5.0 ugh 1 Acenaphthylene Grab EPA 625 5.0 <5.0 ug/1 _ 1 Anthracene Grab EPA 625 5.0 <5.0 ug/1 1 Benzidine Grab EPA 625 50.0 <50.0 ug/1 1 Benzo(a)anthracene Grab EPA 625 5.0 <5.0 ug/l 1 Benzo(a)pyrene Grab EPA 625 _ 5.0 _ <5.0 ug/1 1 3,4 benzofluoranthene Grab EPAEPA 625 5.0 <5.0. ug/1 1 Benzo(ghi)perylene Grab A 625 r 5.0 <5.0 ug/1 1 Benzo(k)fluoranthene Grab EPA 625 5.0 <5.0 ug/1 1 Bis(2-chloroethoxy)methane Grab EPA 625 10.0 <10.0 ug/1 1 Bis(2-chloroethyl)ether Grab EPA 625 5.0 <5.0 ug/1 1 _ Bis(2-chloroisopropyl)ether Grab EPA 625 5.0 <5.0 ug/1 1 - Bis(2-ethylhexyl)phthalate Grab EPA 625 5.0 <5.0 ug/1 1 4-bromophenyl phenyl ether Grab EPA 625 5.0 <5.0 ug/1 I Butyl benzyl phthalate Grab EPA 625 _ 5.0 <5.0 ug/1 1 2-chloronaphthalene Grab EPA 625 5.0 <5.0 ug/1 1 4-chlorophenyl phenyl ether _ Grab EPA 625 5.0 <5.0 ug/1 1 Sample Analytical Quantitation Sample Unita of Number of Parameter Type Method Level Result Measurement samples Base-neutral compounds(cony Chrysene Grab EPA 625 5.0 <5.0 ug/1 1 Di-n-butyl phthalate Grab EPA 625 5.0 <5.0 ug/1 1 Di-n-octyl phthalate Grab EPA 625 5.0 <5.0 ug/1 1 Dibenzo(a,h)anthracene Grab EPA 625 5.0 <5.0 ug/1 1 1,2-dichlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 1,3-dichlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 1,4-dichlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 3,3-dichlorobenzidine Grab EPA 625 25.0 <25.0 ug/1 1 Diethyl phthalate Grab EPA 625 5.0 <5.0 ug/1 1 Dimethyl phthalate Grab EPA 625 5.0 <5.0 ug/1 1 2,4-dinitrotoluene Grab EPA 625 5.0 <5.0 ug/1 1 2,6-dinitrotoluene Grab EPA 625 5.0 <5.0 ug/1 1 1,2-itheglli+izi�gyA-1 Grab EPA 625 5.0 <5.0 ug/112 i `!!banal Monitoring and Pollutant seas Now. Permit No.//C Oon/$S.5y /� Outfall 00/ Month .6C,l.6ert Year old/3 Fluoranthene Grab EPA 625 5.0 <5.0 ug/1 1 Fluorene Grab EPA 625 5.0 _ <5.0 ug/1 1 Hexachlorobenzene Grab `EPA 625 5.0 <5.0 ug/1 1 Hexachlorobutadiene Grab EPA 625 5.0 <5.0 ug/1 1 Hexachlorocyclo-pentadiene Grab EPA 625 10.0 <10.0 ug/1 1 Hexachloroethane Grab EPA 625 5.0 <5.0 ug/1 1 Indeno(1,2,3-cd)pyrene Grab EPA 625 5.0 - <5.0 ug/1 1 Isophorone Grab EPA 625 10.0 <10.0 ug/1 1 Naphthalene Grab EPA 625 5.0 <5.0 Nitrobenzene Grab EPA 625 - ug/l 1 5.0 <5.0 ug/1 1 N-nitrosodi-n-propylamine Grab EPA 625 5.0 <5.0 ug/1 1 N-nitrosodimethylamine Grab EPA 625 5.0 <5.0 ug/1 1 N-nitrosodiphenylamine Grab EPA 625 10.0 <10.0 ug/1 1 Phenanthrene Grab EPA 625 5.0 <5.0 Pyrene Grab EPA 625 5.0 <5.0 ug/1 1 ,1,2,41-trichlorobenzene Grab EPA 625 5.0 <5.0 ug/1 1 ug/1 1 I certify under penalty of law that this document and all attachments were prepared under my direction and supervision in accordance with a system to design to assure that qualified pert personnel gather and evaluate the information submitted. Based on my inquiry of the person or persons that manage the system, or those persons directly responsibl sible forgathering information submitted is , to the best of my knowledge the information and belief, true,accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. k' + _thuth�r ,zed RepreseatiVe name `Signature_.. - ) '.')/1�•''', -.T � Date I r Forza - DMR- PPA-1 Page 3 Pace Analytical Services,Inc. • ZAna&4iCaI• 2225 Riverside Dr. yaw Asheville,NC 28804 www.psoNs6s.cam (828)254-7178 Page 1 of 1 Laboratory Report Mr. Scott Chovan Report Date: 11/26/2014 City of Hendersonville VVVVTP Date Received: 11/18/2014 99 Balfour Road Hendersonville, NC 28792 Project: Bioassay NC0025534 Pace Project No.:92226067 Sample: Pipe 001 Lab ID: 92226067001 Collected: 11/18/14 09:16 Matrix: Water Parameters Results Units Report Limit Analyzed Qualifiers C.dubia Pass/Fail C PASS 11/19/14 00:00 Reviewed by: Pam Cotten pam.cotten©pacelabs.corn Raleigh Certification IDs 6701 Conference Drive,Raleigh,NC 27607 North Carolina Bioassay Certification#: 16 North Carolina Wastewater Certification#:67 North Carolina Drinking Water Certification#:37731 RECEIVED DEC 0 2 2014 (Po uJ 4m, low Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 11/26/14 Facility: CITY OF HENDERSONVILLE WWTP NPDES#: NC0025534 Pipe#: 001 County: HENDERSON Laboratory Performing Test: PACE ANALYTICAL Comments: X Sig ur o orator in Responsible Charge X Signature o aboratory Supervisor * PASSED: 12.28% Reduction * Work Order: 9222-6067 Environmental Sciences Branch MAIL ORIGINAL TO: Div. of Water Quality N.C. DENR 1621 Mail Service Center Raleigh, North Carolina 27699-1621 North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results Calculated t = Tabular t = CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = 12.28 % Mortality Avg.Reprod. # Young Produced 20 24 20 30 27 28 20 21 26 21 27 21 0.00 23.75 Control Control Adult (L)ive (D)ead L L L L L L L L L L L L 8.33 20.83 Treatment 2 Treatment 2 Effluent t: 18% - - TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV 15.457% PASS FAIL # Young Produced 3 23 24 25 22 22 19 25 25 20 20 22 % control orgs X producing 3rd brood Check One Adult (L)ive (D)ead D L L L L L L L L L L L 100% lst sample 1st sample 2nd sample Complete This For Either Test pH Test Start Date: 11/19/14 Control 7.61 7.87 7.87 7.80 7.71 7.64 Collection (Start) Date Sample 1: 11/17/14 Sample 2: 11/19/14 Treatment 2 7.53 7.46 7.62 7.74 7.63 7.78 Sample Type/Duration 2nd 1st P/F s s s Grab Comp. Duration D t e t e t e I S S a n a n a n Sample 1 X 23 hrs L A A ✓ d r d r d U M M t t t Sample 2 X 24 hrs T P P let sample 1st sample 2nd sample D.O. Hardness(mg/1) 38 Control 7.36 7.60 8.23 7.74 7.78 7.70 Spec. Cond. (µmhos) 105 291.5 301.0 Treatment 2 7.92 7.54 8.08 7.65 7.43 7.53 Chlorine(mg/1) <0.1 <0.1 LC50/Acute Toxicity Test Sample temp. at receipt(°C) 0.4 0.5 (Mortality expressed as %, combining replicates) I Note: Please % % % % % % % I I I Concentration Complete This Section Also % % % I I I I I I I Mortality start/end start/end LC50 - I Method of Determination Control 95% Confidence Limits Moving Average -- Probit I -- I Spearman Barber _ Other - High Conc. pH D.O. Organism Tested: Ceriodaphnia dubia Duration(hrs) : Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41) Effluent Toxicity Statistical Results - Chronic Pass/Fail Date: 11/26/14 Facility: CITY OF HENDERSONVILLE WWTP NPDES#: NC0025534 Pipe#: 001 County:HENDERSON Laboratory Performing Test: PACE ANALYTICAL Reduction: 12.28% CONTROL 18% Effluent # Replicates 12 12 Female Live 12 11 Adult Male 0 0 Adult Dead 0 1 Adult Mortality 0.00% 8.33% # Neonates 285 250 • Mean # Neonates 23.750 20.833 Standard Deviation 3.671 5.982 Coefficient of Variation 15.457% Fisher's Exact Test A = 12 B = 12 a = 12 b = 11 a/A = 1.00 b/B = 0.92 Success is: survival Critical b value = 8 11 > 8 The test concludes that the proportion of survival is not significantly different for the control and the effluent groups. Test Passes! SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA • ORDERED OBSERVATIONS i Group Neonates Centered i Group Neonates Centered 1 E 3 -17.8333 13 E 22 1.1667 2 C 20 -3.7500 14 E 22 1.1667 3 C 20 -3.7500 15 E 23 2.1667 4 C 20 -3.7500 16 C 26 2.2500 5 C 21 -2.7500 17 E 24 3.1667 6 C 21 -2.7500 18 C 27 3.2500 7 C 21 -2.7500 19 C 27 3.2500 8 E 19 -1.8333 20 E 25 4.1667 9 E 20 -0.8333 21 E 25 4.1667 10 E 20 -0.8333 22 E 25 4.1667 11 C 24 0.2500 23 C 28 4.2500 12 5 22 1.1667 24 C 30 6.2500 SHAPIRO-WIVIS TEST FOR NORMAL DISTRIBUTIONW DATA (cont.) COEFFICIENTS AND DIFFERENCES i x(n-i-1) x(i) a(i) x(n-i-1) - x(i) 1 6.2500 -17.8333 0.4493 24.0833 2 4.2500 -3.7500 0.3098 8.0000 3 4.1667 -3.7500 0.2554 7.9167 4 4.1667 -3.7500 0.2145 7.9167 5 4.1667 -2.7500 0.1807 6.9167 6 3.2500 -2.7500 0.1512 6.0000 7 3.2500 -2.7500 0.1245 6.0000 8 3.1667 -1.8333 0.0997 5.0000 9 2.2500 -0.8333 0.0764 3.0833 10 2.1667 -0.8333 0.0539 3.0000 11 1.1667 0.2500 0.0321 0.9167 12 1.1667 1.1667 0.0107 0.0000 1 W = X 434.6525 541.9167 Calculated W = 0.802 Critical W = 0.884 • 0.802 < 0.884 The reproduction data is not normally distributed evaluated at a 99% confidence interval Test Failed! Wilcoxon Rank Sum Test Rank Sum - Effluent Group(treatment) : 133 Control Group: 168 Mann-Whitney U = 54.5 nl(treatment) = 12 n2(control) = 12 The critical value from TABLE A.15 (0.01 Level of T) for the above n values: Critical T = 109 133 > 109 The Sum of the Ranks of the effluent group is greater than the significant value from the table. Therefore there is no significant difference between the means of the effluent and control groups and the test passes. TEST PASSES Chronic Test PASSES The reduction was less then 20% Ceriodaphnia dubia Chronic Pass/Fail Toxicity Test Client: ?YN., "S1.4.�\\ 1NO-CeDays Fed ByTime NPDES#: NC C�L?<�5 531 Culture ransfer(Date/Time): 013114 /S:=p Organism Born(Date/Time): 1(It%)t4 / 3'-46fi,,, -g'• ,,, Day 0 rix. 1--25 Age of Organism: (hf s --S‘{nw..N Time Fed(Culture): G$le-, Organism source: OetDay 1 "Z,_ 6 /-04„) Dilution Water atch: IA 4 Temp Dilution Water: 2`k%% Temp tock solution 2`k.1- Day 2 Start Date: 'i 4 Time:.L_,_,4,..47F;, Analyst: (' - Randomized: Incubator: AAA Day 3 Nw ID:s-a 1S`Transfer Date: t t Lt1 N Time: 1'%,�,., Analyst: e-N-. 2°d Transfer Date: 11,`2�1t`t Time: (9( L4' Analyst: v�:� Day 4 � l) <<5-9 Ending Date: tkI24)1‘4 Time: 0$ 5 Analyst: 4 a*-- Reviewed by: 'P' `---- Day 5 fr-5,_ c,. 2..- _____ ---- ----------------------------------------------------------- ---------- L 2' ------- - ---- -- Day 6D3 DS1 c7Control Day 2 1 2 3 4 5 6 7 8 9 10 11 12 Collection (Start)Date #Young Produced © O v .C> 1st Sample: 11 Il�j 2nd Sample: ‘1)9)1(-1 { Adult: Live, Dead tr 4-- L - L- -`_ \— L- \.. Sample Type/Duration Grab Composite Duration Day 5 1 2 3 4 5 6 7 8 9 10 11 12 ls` Sample #Young Produced 10. tit 8 .31'c to11a I11 �R sl$ �(e3 dt ti�- 51to 2nd L•/' r3 3 Adult: Live, Dead L- L L t_ 'k-_ L L- �` Sample ✓ N2'� Day 7 1 2 3 4 5 6 7 8 9 10 11 12 Control 11 S` Sample 2°d Sample #Young Produced C1 9, 11 H 11 ) a 1i It., 't-) 11 Hardness Adult: Live, Dead L L L. L- L L. L >r (m:11-) 38•t{ Conductivity 1 2 3 4 5 6 7 8 9 10 11 12 (µS/cm) I&S 12-' r.� 361 #Total Produced 170I-`r l 9--t3 11C'l D-.4 I DS 101-� 19\ I av l-)1 I ?3 I Di 1 Chlorine (mgt-) D;l <e•1 Effluent % Sample Temp la (°C) ©,LI O•s" Day 1 2 3 4 5 6 7 8 9 10 11 12 #Young Produced d U c_..) Q O U a a o j pH 100% 7 • Z7 2e') CJ Adult: Live,Dead L L L t✓ L- L- i✓ t,.- t✓ L- 1. ! pH Start End Start End Start End Day S 1 2 3 4 5 6 7 8 9 10 11 12 Control -�.(,l -7•$-/ 1r g,"7 /,'30 Z'1 { '�[,t.y #Young Produced n � s 51ta so 4)Io '{I8 '3 (..cm ii 30() ( 'PS ,, Treatment Adult: Live,Dead D ` L L L._ L L_ t_ L 7,53 5 --7,q(, 7` ,� —1,11-1 1-14,3D.O. Start End Start End Start End Day 7 1 2 3 4 5 6 7 8 9 10 11 12 Control #Young Produced y C 7 7•(FO -23 �(. 7 7B Adult: Live,Dead ti $ �v I�0 11 $ 13 11 '� (� Treatment w -- L L L �. t_ L L L- L_ L �- C tZ ?5`i �$ ��4 3 5-S Temp. Start End I Start 1 End Start End 1 2 3 4 5 6 7 8 9 10 11 12I - #Total Produced ,n I��l, � I? "7 0 I --kI 1`� I��'i i i � t, �C iaaI Control L� � Z`i `7 iZ.{ 2•{. 2��� �- t — -- - - - - - - - - Treatment �5 .t 24_gz5-0z_54.-7 2S-z (;),--,z., Pace Analytical Services,Inc. • J 2225 Riverside Dr. aceAnalytical `r `w Asheville,NC 28804 00m (828)254-7176 RECEIVED AUG 2 6 nu Page 1 of 1 Po TIC) Laboratory Report Mr. Scott Chovan Report Date: 08/21/2014 City of Hendersonville WWTP Date Received: 08/12/2014 99 Balfour Road Hendersonville, NC 28792 Project: Bioassay NC0025534 Pace Project No.:92212998 Sample: Pipe 001 Lab ID: 92212998001 Collected: 08/12/14 10:12 Matrix: Water Parameters Results Units Report Limit Analyzed Qualifiers C.dubla Pass/Fail•ic PASS 08/13/14 00:00 I - • Reviewed by: t Pam Cotten pam.cotten@pacelabs.com Raleigh Certification IDs 6701 Conference Drive Raleigh, NC 27607 North Carolina Bioassay Certification#: 16 North Carolina Wastewater Certification#:67 North Carolina Drinking Water Certification#:37731 New Now Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 09/21/14 Facility: CITY OF HENDERSONVILLE WWTP NPDES#: NC0025534 Pipe#: 001 County: HENDERSON Laboratory Performing Test: PACE ANALYTICAL r x Comments:tle.c pyx„yr C.i.4S t q A-* II Si-414e o erator in Responsible Charge -ft;;fic1 6.):7k: ry tc4,r.� • - L3 ` X { Signature o Zaboratory Supervisor * PASSED: -1.12% Reduction * Work Order: 9221-2998 Environmental Sciences Branch MAIL ORIGINAL TO: Div. of Water Quality N.C. DENR 1621 Mail Service Center Raleigh, North Carolina 27699-1621 North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results Calculated t = -0.113 Tabular t = 2.528 CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = -1.12 # Young Produced 22 29 27 26 15 22 28 24 15 29 14 16 Mortality Avg.Reprod. 0.00 22.25 Control Control Adult (L)ive (D)ead L L L L L L L L L L L L 0.00 22.50 Treatment 2 Treatment 2 Effluent %: 18% ._ TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV 26.285% PASS FAIL # Young Produced 16 23 23 M 28 27 16 23 26 23 M 20 % control orgs X producing 3rd brood Check One Adult (L)ive (D)ead L L L L L L L L L L L L 83.3* 1st sample 1st sample 2nd sample Complete This For Either Test pH Test Start Date: 08/13/14 Control 7.65 7.70 7.69 7.67 7.59 7.58 Collection (Start) Date Sample 1: 08/11/14 Sample 2: 08/13/14 Treatment 2 7.56 7.88 7.64 7.97 7.71 7.97 Sample Type/Duration 2nd 1st P/F s s s Grab Comp. Duration D t e t e t e I S S a n a n a n Sample 1 X 24.3 hrs L A A r d r d r d U M M t t t Sample 2 X 23.6 hrs T P P lst sample let sample 2nd sample D.O. Hardness(mg/1) 40 Control 7.59 7.78 7.70 7.66 7.58 7.72 Spec. Cond. (µmhos) 146 315 474 Treatment 2 7.97 7.58 7.96 7.85 7.98 7.57 Chlorine(mg/1) <0.1 <0.1 LC50/Acute Toxicity Test Sample temp. at receipt(°C) 1.3 0.7 (Mortality expressed as %, combining replicates) ) Note: Please % % % % % % % % % 4 Concentration Complete This % % % % % % % % % % Mortality Section Also start/end start/end LC50 = % Method of Determination Control 1-, 95% Confidence Limits Moving Average Probit V -- % Spearman Karber _ Other -- High Conc. pH D.O. Organism Tested: Ceriodaphnia dubia Duration(hrs) : Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41) NNW Torr Effluent Toxicity Statistical Results - Chronic Pass/Fail Date: 09/21/14 Facility: CITY OF HENDERSONVILLE WWTP NPDES#: NC0025534 Pipe#: 001 County:HENDERSON Laboratory Performing Test: PACE ANALYTICAL Reduction: -1.12% CONTROL 18% Effluent # Replicates 12 10 Female Live 12 10 Adult Male 0 2 Adult Dead 0 0 Adult Mortality 0.00% 0.00% # Neonates 267 225 Mean # Neonates 22.250 22.500 Standard Deviation 5.848 4.143 Coefficient of Variation 26.285% Fisher's Exact Test A = 12 B = 12 a = 12 b = 12 a/A = 1.00 b/B = 1.00 Success is: survival Critical b value = 8 12 > 8 The test concludes that the proportion of survival is not significantly different for the control and the effluent groups. Test Passes: SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA ORDERED OBSERVATIONS i Group Neonates Centered i Group Neonates Centered 1 C 14 -8.2500 12 E 23 0.5000 2 C 15 -7.2500 13 E 23 0.5000 3 C 15 -7.2500 14 C 24 1.7500 4 E 16 -6.5000 15 B 26 3.5000 5 E 16 -6.5000 16 C 26 3.7500 6 C 16 -6.2500 17 E 27 4.5000 7 5 20 -2.5000 18 C 27 4.7500 8 C 22 -0.2500 19 E 28 5.5000 9 C 22 -0.2500 20 C 28 5.7500 10 5 23 0.5000 21 C 29 6.7500 11 E 23 0.5000 22 C 29 6.7500 I SHAPIRO-WILT S TEST FOR NORMAL DISTRIBUTION Y DATA (cont.) COEFFICIENTS AND DIFFERENCES i x(n-i-1) x(i) a(i) x(n-i-1) - x(i) 1 6.7500 -8.2500 0.4590 15.0000 2 6.7500 -7.2500 0.3156 14.0000 3 5.7500 -7.2500 0.2571 13.0000 4 5.5000 -6.5000 0.2131 12.0000 5 4.7500 -6.5000 0.1764 11.2500 6 4.5000 -6.2500 0.1443 10.7500 7 3.7500 -2.5000 0.1150 6.2500 8 3.5000 -0.2500 0.0878 3.7500 9 1.7500 -0.2500 0.0618 2.0000 10 0.5000 0.5000 0.0368 0.0000 11 0.5000 0.5000 0.0122 0.0000 1 • W = X 480.0580 530.7500 Calculated W = 0.904 Critical W = 0.878 0.904 s 0.878 The reproduction data is normally distributed evaluated at a 99% confidence interval. Test Passes! F test for Homogeneity of variance Control variance 34.2045 F = = = 1.99 Effluent variance 17.1667 Numerator degrees of freedom: 11 Denominator degrees of freedom: 9 Critical F = 6.32 1.99 s 6.32 =► The Test PASSES, the variances of the two groups are significantly the same, homogeneous. • ► 400 EQUAL VARIANCE t TEST • 22.3 - 22.5 t = _ -0.113 2.206 . Degrees of' freedom.= 20 Critical t =• 2.528 • • -0.113 < 2.52$ • Test: passed. There is not a significant d4ffe p►nce in reproduction between the Control and the effluentevaluated. at a 99t confence interval. . • Chronic Teat PASSES , • • • • • .I • • • • • • • • • Ceriodaphnia dubia Chronic Pass/Fail Toxicity Test Client: l-ZISC.,1J.jVL k)-:.:4-)."--14) NPDES#: NC au ass34 Days Fed By Time Culture Transfer(Date/Time): 13112-1H /Cl•Z'R,,r Organism Born(Date/1'ime : F 12(i-7 / IV,"- 3:--ist, Day 0 NI v) i 11 i{ Age of Organism: '2 - h-3c- .-t Time Fed(Culture): (� 2Organism source: %t7c\ Day' 1 ��v i 0:10 Dilution Water Batch: .;r3 Temp Dilution Water: ":)`1.°i Temp stock solution :9Li.r Day 2 e4,L Ir./?-i,,., Start Date: • ' Time: i1:17- Analyst: NW Randomized: Incubator: / 1St Transfer Date: I Time: Il'(icr ' Analyst: 9? (--- Day 3 ( 1 L�/( 2°d Transfer Date: l�? Time: 3 Analyst: /°3 n� Day 4 pc• / Y �(j Ending Date: `Z.c'lI1 Time: C ice% Analyst: '': _ Day5 y j" Reviewed by: ��L �'�3`� Control - - - - Day 6 Nv,) t :7-1 Day 2 1 2 3 4 5 6 7 8 9 10 11 12 Collection(Start)Dat It Young Produced 151 Sample: P41i U 1-f 2"d Sample: <i115//`-i l`) C 0 C:; C`i ca C) 0 C c r� c Adult: Live, Dead C` 1 t_ C.— L.. ! t✓ L L L- L Sample Type/Duration Grab Composite Duration Day 5 1 2 3 4 5 6 7 8 9 10 11 12 #Young Produced _ _ 151 Sample ✓ N a 4, 15- (4\3 „;ir:k c\tk 5�LV 24 `1i S `-1I c1 /Itl' �t..i— (c -5�S -52nd Adult: Live, Dead t_. t--- L- t t L C, 'L 1_ L (-- ! 2 Sample .�3 Day 7 1 2 3 4 5 6 7 8 9 10 11 12 Control 15f Sample 2nd Sample #Young Produced tc= 15 11 l} --/ lb �• - 1,``=i tt(5)1:5 `----; ,} Hardness Adult: Live, Dead l.. L. L, L. �_, G ‘...5'- L. L, L_ (m./L) D. Conductivity 1 2 3 4 5 6 7 8 9 10 11 12 (ISS/cm) 1't!9<3 a 1.4 i 4 #Total Produced I,9:z I .4i I ri I D(,..I 't- - I )) I ID`-‘ 115.1 i I )-j I ti 4- I Chlorine (mom-) Z..'C%, i 40A Effluent % Sample Temp 1S cc) 1 3 0._4 Day 1 2 3 4 5 6 7 8 9 10 11 12 pH 100% 1 ,DS '1, i C 4 #Young Produced C C t Gc1 C_') Ci c-•, �, Adult: Live,Dead C. 4,_ L. (. ( L_ L L ` C L� _ pH Start End Start End Start End Day 1 2 3 4 5 6 7 8 9 10 11 12 . c #Young Produced Control -7 ( 1.1 G ,;, 7.(a 1 1.51 1 r d 3 11�` a t, (0Slla qie 31 C; 3/6 Treatment -7, -7-`s 7.1-14 -7.-C� ) 7i 1.`"1- Adult: Live, Dead i... C i". (- t_ , c. t - L- D.O. Start End Start End Start End Day 7 1 2 3 4 5 6 7 8 9 10 11 12 Control #Young Produced � t � ,Z , 1,5q •-(-1`� -Tic �7.4,1G 1•'j�S C.,1� Adult: Live,Dead i t it L L k-- tl(,- Treatment iq7 1 `Z C J -.l Temp. Start End Start End Start End 1 2 3 4 5 6 7 8 9 10 11 12 #Total Produced 'a 7I'31 .-1,,, 1 '; 1--) -1\� 12-.I)kb lrxim I/.0 Control �� 2 z 2_4.9� z=✓i I , I'a.. -------- - --- ---- - - - Treatment zG' Z 0 2e..L 2A9 ,c ZS 0 Pace Analytical Services,Inc. ♦ (le°112 Dr. CeAnaca • .. 2225 eR,NC 28804e Vii �� Asheville,NC (828)254-7178 Page 1 of 1 Laboratory Report RECEivrnn MAY ? ' 114 Mr. Scott Chovan Report Date: 05/15/2014 City of Hendersonville WWTP Date Received: 05/06/2014 99 Balfour Road Hendersonville, NC 28792 Project: Hend.WWTP NC0025534 5/6/2014 Pace Project No.:92200058 Sample: Hend WWTP Pipe 001 Lab ID: 92200058001 Collected: 05/06/14 09:40 Matrix: Water Parameters Results Units Report Limit Analyzed Qualifiers C.dubia Pass/Fail nic • PASS 05/07/14 00:00 Reviewed by: _"" Pam Cotten pam.cotten@pacelabs.com Raleigh Certification IDs 6701 Conference Drive Raleigh,NC 27607 North Carolina Bioassay Certification#: 16 North Carolina Wastewater Certification#:67 North Carolina Drinking Water Certification#:37731 NEI NW Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 05/15/14 Facility: CITY OF HENDERSONVILLE WWTP NPDES#: NC0025534 Pipe#: 001 County: HENDERSON Laboratory Performing Test: PACE ANALYTICAL Comments: X Signatu of er for in Responsible Charge Signature of Laboratory Supervisor * PASSED: -6.29% Reduction * Work Order: 9220-0058 Environmental Sciences Branch MAIL ORIGINAL TO: Div. of Water Quality N.C. DENR 1621 Mail Service Center Raleigh, North Carolina 27699-1621 North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results Calculated t = -1.344 Tabular t = 2.508 CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction - -6.29 # Young Produced 25 25 28 33 25, 24 30 31 30 36 30 33 Mortality Avg.Reprod. 0.00 29.17 Control Control Adult (L)ive (D)ead L L L L L L L L L L L L 0.00 31.00 Treatment 2 Treatment 2 Effluent %: 18% TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV 13.144% PASS FAIL # Young Produced 32 30 33 32 32 33 29 30 24 32 30 35 I control orgs X r--- ood producing 3rd Adult (L)ive (D)ead L L L L L L L L L L L L �r 100% Check One 1st sample 1st sample 2nd sample Complete This For Either Test pH Test Start Date: 05/07/14 Control 7.45 7.66 7.67 7.75 7.51 7.79 Collection (Start) Date Treatment 2 7.41 7.61 7.43 7.75 7.45 7.64 Sample 1: 05/05/14 Sample 2: 05/07/14 ample Type/Duration 2nd 1st P/F s s s Grab Comp. Duration D t e t e t e I S S a n a n a n Sample 1 X 24 hrs L A A r d r d r d U M M t t t Sample 2 X 24.5 hrs T P P 1st sample 1st sample 2nd sample D.O. Hardness(mg/1) 42 Control 8.33 7.83 8.09 7.98 8.09 7.70 Spec. Cond. (Amhos) 129 284.9 313 Treatment 2 8.13 8.03 7.64 7.82 7.56 7.49 Chlorine(mg/1) <0.1 <0.1 LC50/Acute Toxicity Test Sample temp. at receipt(°C) 1.8 1.6 (Mortality expressed as I, combining replicates) I Note: Please I I I I I I I I I I Concentration Complete This Section Also I I I I % I I it % I Mortality start/end start/end LC50 = I Method of Determination Control 95% Confidence Limits Moving Average - Probit I -- I Spearman Kerber Other High Conc. pH D.O. Organism Tested: Ceriodaphnia dubia Duration(hrs) : Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41) • Effluent Toxicity Statistical Results - Chronic Pass/Fail Date: 05/15/14 Facility: CITY OF HENDERSONVILLE WWTP NPDES#: NC0025534 Pipe#: 001 County:HENDERSON Laboratory Performing Test: PACE ANALYTICAL Reduction: -6.29% CONTROL 18% Effluent # Replicates 12 12 Female Live 12 12 Adult Male 0 0 Adult Dead 0 0 Adult Mortality 0.00% 0.00% # Neonates 350 372 Mean # Neonates 29.167 31.000 Standard Deviation 3.834 2.763 Coefficient of Variation 13.144% Fisher's Exact Test A = 12 B = 12 a = 12 b = 12 a/A = 1.00 b/B = 1.00 Success is: survival Critical b value = 8 12 > 8 The test concludes that the proportion of survival is not significantly different for the control and the effluent groups. Test Passes! SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA ORDERED OBSERVATIONS i Group Neonates Centered i Group Neonates Centered 1 E 24 -7.0000 13 C 30 0.8333 2 C 24 -5.1667 14 E 32 1.0000 3 C 25 -4.1667 15 E 32 1.0000 4 C 25 -4.1667 16 E 32 1.0000 5 C 25 -4.1667 17 E 32 1.0000 6 E 29 -2.0000 18 C 31 1.8333 7 C 28 -1.1667 19 E 33 2.0000 8 E 30 -1.0000 20 E 33 2.0000 9 E 30 -1.0000 21 C 33 3.8333 10 E 30 -1.0000 22 C 33 3.8333 11 C 30 0.8333 23 E 35 4.0000 12 C 30 0.8333 24 C 36 6.8333 SHAPIRO-WIGS TEST FOR NORMAL DISTRIBUTION W DATA (cont.) COEFFICIENTS AND DIFFERENCES i x(n-i-1) x(i) a(i) x(n-i-1) - x(i) 1 6.8333 -7.0000 0.4493 13.8333 2 4.0000 -5.1667 0.3098 9.1667 3 3.8333 -4.1667 0.2554 8.0000 4 3.8333 -4.1667 0.2145 8.0000 5 2.0000 -4.1667 0.1807 6.1667 6 2.0000 -2.0000 0.1512 4.0000 7 1.8333 -1.1667 0.1245 3.0000 8 1.0000 -1.0000 0.0997 2.0000 9 1.0000 -1.0000 0.0764 2.0000 10 1.0000 -1.0000 0.0539 2.0000 11 1.0000 0.8333 0.0321 0.1667 12 0.8333 0.8333 0.0107 0.0000 1 W = X 236.3082 245.6667 Calculated W = 0.962 Critical W = 0.884 0.962 x 0.884 The reproduction data is normally distributed evaluated at a 99% confidence interval. Test Passes! F test for Homogeneity of Variance Control variance 14.6970 F = _ = 1.92 Effluent variance 7.6364 Numerator degrees of freedom: 11 Denominator degrees of freedom: 11 Critical F = 5.32 1.92 s 5.32 =► The Test PASSES, the variances of the two groups are significantly the same, homogeneous. v 400 EQUAL VARIANCE t TEST • 29.2 - 31.0 t • . -1.344 1.364 Degrees of freedom • 22 • Critical t = 2.508 -1.344 c 2.508 • Test passed. There is not a significant difference in reproduction • between the Control and theeffluent evaluated at 'a 998 confidence intervhl. • Chronic Test PASSES • • • • • • • . ... Ceriodaphnia dubia Chronic Pass/Fail Toxicity Test Client: \tarthVe..-6",v1kL GOL^'1 NPDES#: NC - �S Days Fed By Time Culture Transfer(Date/Time): Si(�}j4 /t)- `~ Organism Born(Date/Time): _ U ]y / 11 '32cw,„;- ti:4ji+,,.) Day 0 ,13,_ 11•Win-, Age of Organism: i;� - t_'3✓,%` Time Fed(Culture): S'-'551'.0-0 Organism source: )4>S-A tic.'Co Day I /P-;c_ :3,ct.. r9 Dilution Water Batch: 3;Stv Temp Dilution Water: 2'1 ? Temp stock solution 2-'-i:5 Day 2 N W 13".2. - Start Date: .511 VI Time: \I•Z t,n Analyst: P3,- Randomized: V/ \Incubator: M Day 3 G 1stTransfer Date: tAcll,1yi Time: 13.45 Analyst: N W - 1 " r 2nd Transfer Date- 5112-1H Time: t e:.:-t`1 Analyst: �.' Day 4 �?L 1`x ;p F, Ending Date: 5t13114i Time: Kq'-Z')yyr Analyst: Pj Reviewed by: P6 C_- Day 5 (73c )6•, e„h Control - - - - - - - - - -- -; Day 6 NVV i0'2 7 Day 2 1 2 3 4 5 6 7 8 9 10 11 12 Collection (Start) Date. #Young Produced 1St Sample: 5/4)y 2nd Sample: .$I?'f/'l Adult: Live, Dead i,-- L- i_- i._ l.__ i✓ I-_- ` i- t- L-. Sample Type/Duration Grab Composite Duration Day 5 1 ,2 3 4 5 6 7 8 9 10 11 12 #Young Produced 4g 511t, tti g it 5j:?- ` cl .(,Ola. (h S1 (/(3 .Sp 1�'(L 15`Sample v n; t-1 Adult: Live, Dead I-, C- c- (_ L, L- L 2nd Sample L/ "I.;(.21' .� Day 7 1 2 3 4 5 6 7 8 9 10 11 12 Control ls` Sample rd Sample #Young Produced ! Hardness MI to kb li . 0- )9 1) fJ lc l(, li 14, )-C- Adult: Live, Dead i- L. L- L L L L t, i 1, j (m_/1-L) Conductivity 1 2 3 4 5 6 7 8 9 10 11 12 (itS/cm) (Dem( 28 ',9 313 #Total Produced 15-1D-7133175 1 )51 `i 13'=13 1 132, 17E I '3°133 I Chlorine 0'1 CCDr Sample Temp Effluent % (°C) l Day 1 2 3 4 5 6 7 8 9 10 11 12 pH 100% #Young Produced 0 -e` .e% 7��3 t 3 `Adult: Live, Dead L- L 1s I_ L- L— l.- zr it L_ I---. V pH Start End Start End Start End Day 5 1 2 3 4 5 6 7 8 9 10 11 12 #Young Produced I Control -� ,,LS 1- , .7,„(e...7 -Li.5. -7.51 7,�ci 51 h _apt It (0112._bill 611! 03 (s= u )-1)7_ ' 510513 (o))2_ Treatment Adult: Live, Dead L. '- L t_ \-, L. L ` L C. _ 1 �.(o( "T,4t3 .7,7;3- Z'-(� �.4<u D.O. Start End Start End Start End Day 7 1 2 3 4 5 6 7 8 9 10 11 12 #Young Produced Control g,33 irs 3 g,09 -)ng $,0, 7,70 1� l3 _I J 17_ lS IL( la, is 10 17- I?' I R' L4-- � Treatment x,13 �,o Adult: Live, Dead 1. 1., L. 1. . L L c . 4-- 3 7. 4 /,%-2- -7.5k, /,0 Temp. Start End Start End Start End ., 1 2 3 4 5 6 7 8 9 10 11 12 #Total Produced 132[30123 13-12_ I33 I Z`i 12c I2y 132- I?o L3si Control 2_ -,s L14,, 20.9 ak,�2.4.01 -0 --= Treatment 2,5.1 04-,,8 0.i,, . .,-) ail 2,4,i Pace Analytical Services,Inc. /�,,,, ,,,,/e ..... 2225 Riverside Dr. �+1'7IIQ [iQ! Asheville,NC 28804 (828)254-7178 Page 1 of 1 Laboratory Report Mr. Scott Chovan RECEIVED FEB 2 g 2014 Report Date: 02/14/2014 City of Hendersonville VVVVTP Date Received: 02/04/2014 99 Balfour Road Ark/ Hendersonville, NC 28792 Project: Bioassay 2/4/2014 Pace Project No.:92188483 Sample: Hendersonville WWTP Bioassay Lab ID: 92188483001 Collected: 02/04/14 09:18 Matrix: Water Parameters Results Units Report Limit Analyzed Qualifiers C.dubia Pass/Fail nic PASS 02/05/14 00:00 Reviewed by: Pam Cotten pam.cotten©pa cela bs.com Raleigh Certification IDs 6701 Conference Drive Raleigh, NC 27607 North Carolina Bioassay Certification#: 16 North Carolina Wastewater Certification#:67 North Carolina Drinking Water Certification#:37731 Nor Imr Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 02/14/14 Facility: CITY OF HENDERSONVILLE WWTP NPDES#: NC0025534 Pipe#: 001 County: HENDERSON Laboratory Performing Test: PACE ANALYTICAL Comments: X Signatitio of •aerator in Responsible Charge X I ,, jlb Signature of - •oratory Supervisor * PASSED: 6.881 Reduction * Work Order: 92188483 Environmental Sciences Branch MAIL ORIGINAL TO: Div. of Water Quality N.C. DENR 1621 Mail Service Center Raleigh, North Carolina 27699-1621 North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results Calculated t = Tabular t = CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 1 Reduction = 6.88 # Young Produced 26 31 32 32 33 33 32 28 37 32 32 30 1 Mortality Avg.Reprod. 0.00 31.50 Adult (L)ive (D)ead L L L L L L L L L L L L Control Control 8.33 ' 29.33 Effluent 1: 181 Treatment 2 Treatment 2 TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV 8.6151 PASS FAIL # Young Produced 16 32 34 31 33 28 31 35 32 27 29 24 1 control orgs X producing 3rd I Adult (L)ive (D)ead D L L L L L L L L L L L brood 1001 Check One 1st sample 1st sample 2nd sample Complete This For Either Test pH Test Start Date: 02/05/14 Control 8.10 7.73 7.64 7.70 7.83 7.68 Collection (Start) Date Sle Treatment 2 7.19 7.60 7.27 7.68 7.52 7.62 Sale 1: 02/03/14 Sample 2: 02/05/14 .Sample Type/Duration 2nd 1st P/F s s s Grab Comp. Duration D t e t e t e I S S a n a n a n Sample 1 X 23.5 hrs L A A r d r d r d U M M t t t Sample 2 X 24.2 hrs T P p let sample let sample 2nd sample D.o. Hardness(mg/1) 40 Control 7.73 7.27 8.60 7.66 7.50 7.06 Treatment 2 8.31 7.35 7.78 7.46 . 7.97 7.78 Spec. Cond. (µmhos) 158 370 360 Chlorine(mg/1) <0.1 <0.1 LC50/Acute Toxicity Test Sample temp. at receipt(°C) 0.7 0.8 (Mortality expressed as 1, combining replicates) I Note: 1 1 1 1 1 1 1 1 1 1 Concentration Completeease This I I 1 1 1 1 1 1 1 1 Mortality Section Also start/end start/end LC50 = 1 Method of Determination Control-----,-- 95% Confidence Limits Moving Average -- Probit 1 -- t Spearman Karber _ Other - High Conc. PH D.O. IOrganism Tested: Ceriodaphnia dubia Duration(hrs) : Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41) 4400 . Vim, Effluent Toxicity Statistical Results - Chronic Pass/Fail Date: 02/14/14 Facility: CITY OF HENDERSONVILLE WWTP NPDES#: NC0025534 Pipe#: 001 COunty:HENDERSOI Laboratory Performing Test: PACE ANALYTICAL Reduction: 6.88% CONTROL 18% Effluent # Replicates ' 12 12 Female Live 12 11 Adult Male 0 0 Adult Dead 0 1 Adult Mortality 0.00k 8.33% # Neonates 378 352 Mean # Neonates 31.500 29.333 Standard Deviation 2.714 5.228 Coefficient of Variation 8.615% Fisher's Exact Test A = 12 B = 12 a = 12 b = 11 a/A = 1.00 b/B = 0.92 Success is: survival Critical b value = 8 11 > 8 The test concludes that the proportion of survival is not significantly different for the control and the effluent groups. Test Passes! SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA ORDERED OBSERVATIONS i Group Neonates Centered i Group Neonates Centered 1 E 16 -13.3333 13 C 32 0.5000 2 C 26 -5.5000 14 C 32 0.5000 3 E 24 -5.3333 15 C 33 1.5000 4 C 28 -3.5000 16 C 33 1.5000 5 E 27 -2.3333 17 E 31 1.6667 6 C 30 -1.5000 18 E 31 1.6667 7 E 28 -1.3333 19 E 32 2.6667 8 C 31 -0.5000 20 E 32 2.6667 9 E 29 -0.3333 21 E 33 3.6667 10 C 32 0.5000 22 E 34 4.6667 11 C 32 0.5000 23 C 37 5.5000 12 C 32 0.5000 24 E 35 5.6667 `r %OW SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA (cont.) COEFFICIENTS AND DIFFERENCES i x(n-i-1) x(i) a(i) x(n-i-1) - x(i) 1 5.6667 -13.3333 0.4493 19.0000 2 5.5000 -5.5000 0.3098 11.0000 3 4.6667 -5.3333 0.2554 10.0000 4 3.6667 -3.5000 0.2145 7.1667 5 2.6667 -2.3333 0.1807 5.0000 6 2.6667 -1.5000 0.1512 4.1667 7 1.6667 -1.3333 0.1245 3.0000 8 1.6667 -0.5000 0.0997 2..1667 9 1.5000 -0.3333 0.0764 1.8333 10 1.5000 0.5000 0.0539 1.0000 11 0.5000 0.5000 0.0321 0.0000 12 0.5000 0.5000 0.0107 0.0000 1 W = X 336.8233 381.6667 Calculated W = 0.883 Critical W = 0.884 0.883 < 0.884 The reproduction data is not normally distributed evaluated at a 99% confidence interval Test Failed! Wilcoxon Rank Sum Test Rank Sum - Effluent Group(treatment) : 135 Control Group: 166 Mann-Whitney U = 56.5 nl(treatment) = 12 n2 (control) = 12 The critical value from TABLE A.15 (0.01 Level of T) for the above n values: Critical T = 109 135 > 109 The Sum of the Ranks of the effluent group is greater than the significant value from the table. Therefore there is no significant difference between the means of the effluent and control groups and the test passes. TEST PASSES Chronic Test PASSES The reduction was less then 20% Ceriodapnia dubia Chronic Pass/Fail Toxicity Test Q-✓1 �J` Client: 4_ t),.. U-.\,tl' NPDES#: NC COD575-3`) Days Fed By Time Culture Transfer(Date/Time): 2 Litt- / qt"2c Organism Born(Date/Time): *4)19 / ,S tOorn- 11'27-pK) Day 0 #3r_ i a'43Qr Age of Organism: 1 V\i` -t 344;,,, Time Fed(Culture): `1--�s Organism source: O"Zci-c)3l Day I e 1)'i pg Dilution Water Batch: \1 2`'11 Temp Dilution Water: 21-ig _ Temp stock solution 2.t• Day 2 �('.2c/ . Start Date: 2 51l'-( Time: 11 4, Analyst:°3�- Randomized: (.7" Incubator: / ADay 3 (/fez( 151 Transfer Date: FJ 4 Time: 11' 3JQ ) Analyst: 2nd Transfer Date: 2 Lc 'k Time: `ic--25-x'1 Analyst: P'` -- Day 4 �� lit Ending Date: 13-‘ Time: +ck) c.-, Analyst:,060 Reviewed by: P3<-- Day 5 lq7L r S.Sc�►, Control -------------------------------------------- ---------------------------------------------------------i Day 6 f, 0712,5 Day 2 1 2 3 4, 5 6 7 8 9 10 11 12 Collection (Start) Date � 1s Sample: a'311`- 1 2od Sample: '451 lc{ #Young Produced 0 G C cJ p c., U c-D q C, c:, Adult:Live,Dead L L L_ (4.- L L- L L L (- c-- ; Sample Type/Duration Grab Composite Duration Days 1 2 3 41 5 6 7 8 9 10 11 12 #Young Produced ` C 15`Sample a 3, 5 \k 1,Q)13 icblio if 0i2,sll3 S,Akb(GA4 toil oi, 2nd Sample Adult:Live,Dead L L L. L. tr, L L, t✓ L, L- (- Day j P 2y.Z' Control lst Sample 2nd Sample Day? 1 2 3 4 5 6 7 8 9 10 11 12 ', P P #Young ProducedHardness Ilin. 10 12- 1'1 1 1-; I5 Iti 13 I-7 14 01 1Y Adult:Live,Dead L L L L L i_- l- L L- L.- L t_ ! (m./L) Conductivity 1 2 3 4 5 6 7 8 9 10 11 12 (µS/cm) I 5E;2- j-3-0 . D 360 .O Chlorine #Total Produced 2,L "; ( " `r 3 23 33 i- 23 . -- 3- 71- ",. ., (mom ) to.,l Lo - L leEffluent % I�SSarn(°C)emp Y Day 1 2 3 4i 5 6 7 8 9 10 11 12 pH 100% b. 61 ,i.16 #Young Produced I /; Adult:Live,Dead L L- L c- L L- L L- ( - pg Start End Start End Start End Day 5 1 2 3 41 5 6 7 8 9 - 10 11 12 ' Control #Young Produced 3 1II 1 i I 603�11� ) ,IU 3 _7.t`i �c� t� 7. � 11 _ 1 1� (a 1�-- 115 �11� 1P�13 5��05� 7 4117- Ilk Adult:Live, Dead L l_ (-.. 1, L t-- L <.- L l✓ V I 1q 1- 60 7,9,1-fT V( 7 S^_ -7.12 U.O. Start End Start End Start End Day 7 1 2 3 4 5 6 7 8 9 10 11 12 Control #Young Produced �, � .-7.9'7.- g-bU 7'14' ,14 - ,5L) -7,U.(, U f3 _ l y l31 1Z q 12, 13 1.3 /3, 9_, i's � Treatment , . Adult:Live,Dead p i_ L L L L L L L, L L ; % '' I - _- .77 96 },Tt 7q-E Temp. Start End Start End Start End 1 2 3 41 5 6 7 8 9 10 11 12 Control #Total Produced hL;I ii 3-?-I'-\13 133 3 I'21 f 31 13.s' I 32- h.R-I i l I Treatment ,-I.�S (5, 0 3,s. 3 RS 0 a1 1 „:x (-) . ------_____-- - - 9\9, `l 5 0 )5. 1 aS t as- a LI el • A NCDENR North Carolina Department of Environment and Natural Resources Pat McCrory Donald R. van der Vaart Governor Secretary June 2,2015 Lee Smith,Utilities Director City of Hendersonville WWTP 305 Williams Street Hendersonville,NC 28792 Subject: Acknowledgement of Permit Renewal Permit NC0025534 Henderson County Dear Permittee: The NPDES Unit received your permit renewal application on June 30, 2015. A member of the NPDES Unit will review your application. They will contact you if additional information is required to complete your permit renewal. You should expect to receive a draft permit approximately 30-45 days before your existing permit expires. If you have any additional questions concerning renewal of the subject permit, please contact Tom Belnick at(919) 807-6390. Sincerely, W frees Tl i,eo(fo-rd• Wren Thedford Wastewater Branch cc: Central Files Asheville Regional Office NPDES Unit 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 Location:512 N.Salisbury St.Raleigh,North Carolina 27604 Phone:919-807-63001 Fax:919-807-6492/Customer Service:1-877-623-6748 Internet::www.ncwater.orq An Equal OpportunitylAfrmative Action Employer