WQ0012404_2022 Land Application Program Annual_20230201

Prepared for:
CF Industries, Inc.
4 Parkway North, Suite 400
Deerfield, IL 60015
2022 LAND APPLICATION
PROGRAM ANNUAL REPORT
NON -DISCHARGE INJECTION PERMIT
WQ0012404
CF NITROGEN SITE
HERTFORD COUNTY, NORTH CAROLINA
Prepared by:
GeosyntecO'
consultants
Geosyntec Consultants of NC, P.C.
Geosyntec Consultants of NC, P.C.
1300 S Mint Street, Suite 300
Charlotte, North Carolina 28203
Project Number: GN7566
February 2023

2022 Annual Report —Permit No. WQ0012404
CF Nitrogen Site Land Application Program
TABLE OF CONTENTS
1.0 INTRODUCTION................................................................................................... I
2.0 LAND APPLICATION SUMMARY.................................................................... 2
3.0 ANNUAL GROUNDWATER MONITORING...................................................4
4.0 REFERENCES........................................................................................................5
List of Figures
Figure 1
Site Location Map
Figure 2
Site Layout
Figure 3A
Potentiometric Surface Map (January 2022)
Figure 3B
Potentiometric Surface Map (April 2022)
Figure 3C
Potentiometric Surface Map (July 2022)
Figure 3D
Potentiometric Surface Map (October 2022)
Figure 4A
Elevation Cross Sections (January 2022)
Figure 4B
Elevation Cross Sections (April 2022)
Figure 4C
Elevation Cross Sections (July 2022)
Figure 4D
Elevation Cross Sections (October 2022)
Figure 5
Monthly Rainfall
List of Tables
Table 1 Groundwater Elevation Data
Table 2 Monthly Rainfall 2022
Table 3 Annual Residuals Sampling Summary Form
List of Appendices
Appendix A Annual Land Application Certification Form
Appendix B 2022 Application Summary and Field Loading Rate Reports
Appendix C Field Application Summaries
Appendix D Approved Land Application Sites
Appendix E Landowner Agreement Attachments and Lessee Agreement Attachments
Appendix F Residuals Sampling Analytical Reports
CAR230219 i February 2023

2022 Annual Report —Permit No. WQ0012404
CF Nitrogen Site Land Application Program
1.0 INTRODUCTION
This 2022 Land Application Program Annual Report has been prepared by Geosyntec
Consultants of NC, P.C. (Geosyntec) on behalf of CF Industries (CFI) for the Former CF
Nitrogen Ahoskie Site (Site) located at 100 Farmers Chemical Road, Hertford County, North
Carolina. The Site includes 157 acres of a 1,105-acre property and is located along the south
bank of the Chowan River, as shown in Figure 1.
The Site operated as a fertilizer manufacturing plant from 1969 through 1982 and
groundwater impacts in the form of nitrogen compounds have been documented. In 1976, a
slurry wall was constructed along the perimeter of the Site facility as shown on Figure 2. In
1998, CFI began a program of groundwater extraction into a holding lagoon followed by
trucking of extracted water to area farms for land application in accordance with Non -
Discharge Injection Permit (Permit No. WQ0012404) from the North Carolina Department
of Environmental Quality (NCDEQ), Division of Water Resources (DWR).
This report has been prepared to document land application activities conducted in Hertford,
Bertie, and Northampton counties during the 2022 compliance year under the Non -
Discharge Injection Permit. The Annual Land Application Certification Form is included in
Appendix A. As specified in Attachment A of Permit No. WQ0012404, analyses to
demonstrate that residuals are non -hazardous are only required once per permit cycle and
pathogen and vector monitoring is not applicable. Therefore, Toxicity Characteristic
Leaching Procedure (TCLP), pathogen and vector monitoring, and soil analysis are not
addressed in this annual report.
CAR230019 1 February 2023

2022 Annual Report —Permit No. WQ0012404
CF Nitrogen Site Land Application Program
2.0 LAND APPLICATION SUMMARY
This section summarizes land application activities of recovered nitrogen -enriched
groundwater. Quarterly flow during 2022 was calculated based on Transfer Pump Station # 1
flow meter readings. The extraction system recovered approximately 10,976,400 gallons of
groundwater into the holding lagoon during calendar year 2022, as summarized in the table
below:
1 st Quarter (January — March 2022)
2,166,100 gallons
2nd Quarter (April — June 2022)
3,834,500 gallons
3rd Quarter (July — September 2022)
4,071,800 gallons
4th Quarter (October — December 2022)
904,000 gallons
Total Groundwater Recovery for 2022
10,976,400 gallons
A second flow meter is in Transfer Pump Station #2 recorded that approximately 9,979,000
gallons of extracted groundwater were pumped from the holding lagoon into trucks for land
application. Nitrogen -enriched groundwater was applied to 26 fescue, soybean, wheat, corn,
and bermuda planted fields at 6 sites, as summarized in Appendix B which includes an
overall land application summary and field loading rate reports. Land application of
nitrogen -enriched groundwater occurred on 134 days in 2022. Daily application summarizes
are provided in Appendix C. The quarterly land application volumes are summarized in the
table below:
1 st Quarter (January — March 2022)
2,146,000 gallons
2nd Quarter (April — June 2022)
2,587,000 gallons
3rd Quarter (July — September 2022)
4,750,000 gallons
4th Quarter (October — December 2022)
496,000 gallons
Total Groundwater Recovery for 2022
9,979,000 gallons
Maximum agronomic rates were calculated based on analytical data from the holding lagoon,
field crop type, and field soil series. As shown in the field loading rate reports in Appendix
B, these maximum agronomic rates were not exceeded during application of the nitrogen -
enriched groundwater in 2022. The list of land application sites approved under this permit
is included in Appendix D and one new site (Site 35) including seven new fields was added
this year. Information for these new sites including landowner agreements, buffer maps, and
soil maps is included in Appendix E but groundwater was not applied to these sites in 2022.
Contact information for WQ0012404 permit holder (CFI) and the Operator in Responsible
Charge (Granville Farms) is included below:
CAR230019 2 February 2023

2022 Annual Report —Permit No. WQ0012404
CF Nitrogen Site Land Application Program
CF Nitrogen, Inc.
Mr. Kelvin Roth
4 Parkway North, Suite 400
Deerfield, IL 60015-2590
847-405-2738
Granville Farms, Inc.
Mr. Jay Bryant
8229 Highway 96 North/P.O. Box 1396
Oxford, North Carolina 27565
252-358-2129 (direct)
919-690-8000 (office)
CAR230019 3 February 2023

2022 Annual Report —Permit No. WQ0012404
CF Nitrogen Site Land Application Program
3.0 ANNUAL GROUNDWATER MONITORING
Depth to groundwater is measured quarterly in 44 wells and piezometers across the Site.
Groundwater elevations from these quarterly monitoring events are summarized in Table 1
and potentiometric maps of interpreted groundwater elevation contours inside and outside
of the slurry wall are included as Figures 3A, 3B, 3C, and 3D for January, April, July, and
October 2022, respectively.
Cross -sectional depictions of quarterly groundwater elevations are shown across two
transects of the Site in Figures 4A, 4B, 4C, and 4D. Historical water level trends dating back
to the onset of groundwater recovery in 1998 are included in prior annual reports (S&ME,
2022). The cross -sections depict current groundwater elevation conditions in comparison to
the slurry wall and show that groundwater elevations within the wall remain below the slurry
wall with the exception of some internal pockets, demonstrating that the slurry wall and
extraction program are effectively containing the nitrogen -enriched groundwater.
A rainfall gauge is located at the Site and checked on a weekly basis. The total annual
recorded rainfall at the Site in 2022 was 39.47 inches, compared with the annual average of
46 inches for the area. Monthly recorded precipitation totals are compared to average rainfall
totals for the area (from www.usa.com as reported by S&ME [S&ME, 2022]) and presented
in Table 2 and the past three years of Site data are shown in Figure 5. In 2022, monthly
precipitation was at or below average for most of the year, with a particular exception in
July. Groundwater pumping for land application efforts for 2022, on average, maintained
the groundwater elevation within the slurry wall below 30 feet mean sea level (ft-msl). There
were transitory exceptions early in the year followed by improved groundwater elevations.
Samples of the nitrogen -enriched groundwater were collected in February, April, July, and
October 2022. Samples were analyzed for nitrogen as ammonia, nitrate and nitrite, and total
Kjeldahl nitrogen (TKN), aluminum, calcium, phosphorus, magnesium, potassium, sodium
and pH. A summary of laboratory results is provided in Table 3. The analytical laboratory
data reports are provided in Appendix F.
CAR230019 4 February 2023

2022 Annual Report —Permit No. WQ0012404
CF Nitrogen Site Land Application Program
4.0 REFERENCES
S&ME. 2022. 2021 Annual Report Land Application Program, CF Nitrogen, Inc., Permit
No. WQ0012404.
CAR230019 5 February 2023

FIGURES

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Groundwater Piezometers
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Recovery Wells
Q1 2022
Cross Section Profile Groundwater Elevation Contours
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3. Service Layer Credits: Source: Esri, Maxar, Earthstar
Geographi cs, and the G I S User Community
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Groundwater Recovery Wells ; Piezometers
Cross Section Profile Groundwater Elevation Contours
Approximate Slurry Wall Inside Wall
Groundwater Monitoring Wells _ Groundwater Elevatior Canto urs
Q�J Groundwater Wells Not Gauged Outside Wall
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2. Wells used to create the potentiometric surfaces are labeled
with the water elevation.
3. Service Layer Credits: Source. Esri, Maxar, Earthstar
Geographi cs, and the G I S User Community
Legend
Groundwater Recovery Wells ; Piezometers
Cross Section Profile Groundwater Elevation Contours
Approximate Slurry Wall Inside Wall
Groundwater Monitoring Wells _ Groundwater Elevatior Canto urs
Q�J Groundwater Wells Not Gauged Outside Wall
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Notes:
1- Well, piezometer, and slurry wall boundary locations are
approximate and were obtained from figures prepared by S&ME
in April 1996 and in August 2011.
2. Wells used to create the potentiometric surfaces are labeled
with the water elevation.
3. Service Layer Credits: Source: Esri, Maxar, Earthstar
Geographi cs, and the G I S User Community
Legend
Groundwater Recovery Wells ; Piezometers
Cross Section Profile Groundwater Elevation Contours
Approximate Slurry Wall Inside Wall
Groundwater Monitoring Wells _ Groundwater Elevation Contours
Q�J Groundwater Wells Not Gauged Outside Wall
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R4 2022
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Legend
Land Surface Elevation
Groundwater Elevation
Slurry Wall
I Monitoring Well
400
800
MWI-9
Elevation Cross Section A - A'
1,200
1,600
Distance (Feet)
Elevation Cross Section B-B'
Distance (Feet)
MWI-7
2,000
C-33
C-32
2,400 2,800
PO-236
Mo
Notes:
1. Land Surface Elevation from NCOneMap 20 foot resolution Light Detection and
Ranging (LiDAR) digital elevation model.
2. Groundwater Elevations from January 2022 monioring well measurement event.
3 Well, piezometer, and slurry wall boundary locations and elevations are
approximate and were obtained from reports prepared by S&ME in April 1996 and in
August 2011.
4. Vertical exaggeration approximately 10x.
B'
A
Elevation Cross Sections
January 2022
Former CF Industries Ahoskie Site
100 Farmers Chemical Road
Hertford County, North Carolina
BI
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35
30
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45
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Legend
Land Surface Elevation
Groundwater Elevation
Slurry Wall
I Monitoring Well
400
800
MWI-9
Elevation Cross Section A - A'
1,200
1,600
Distance (Feet)
Elevation Cross Section B-B'
Distance (Feet)
MWI-7
2,000
2,400
C-33
C-32
2,800
Notes:
1. Land Surface Elevation from NCOneMap 20 foot resolution Light Detection and
Ranging (LiDAR) digital elevation model.
2. Groundwater Elevations from April 2022 monioring well measurement event.
3 Well, piezometer, and slurry wall boundary locations and elevations are
approximate and were obtained from reports prepared by S&ME in April 1996 and in
August 2011.
4. Vertical exaggeration approximately 10x.
B'
A
Elevation Cross Sections
April 2022
Former CF Industries Ahoskie Site
100 Farmers Chemical Road
Hertford County, North Carolina
Geosynteca �Q,Y1 ktl'Cl04l - i14iLII ,OfXG, R( _ Figure
consultants T1C limnsc Nu: C-3500 and C : )!-
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50
45
40
35
30
a,
25
c
20
15
10 PI-13R
5 MWO-8
0
0
50
45
40
35
30
v
25
0 20
v 15
w 10
5
0
Legend
Land Surface Elevation
Groundwater Elevation
Slurry Wall
I Monitoring Well
400
800
MWI-9
Elevation Cross Section A - A'
1,200
1,600
Distance (Feet)
Elevation Cross Section B-B'
Distance (Feet)
MWI-7
2,000
2,400
C-33
C-32
2,800
Notes:
1. Land Surface Elevation from NCOneMap 20 foot resolution Light Detection and
Ranging (LiDAR) digital elevation model.
2. Groundwater Elevations from July 2022 monioring well measurement event.
3 Well, piezometer, and slurry wall boundary locations and elevations are
approximate and were obtained from reports prepared by S&ME in April 1996 and in
August 2011.
4. Vertical exaggeration approximately 10x.
B'
A
Elevation Cross Sections
July 2022
Former CF Industries Ahoskie Site
100 Farmers Chemical Road
Hertford County, North Carolina
BI
Geosynteca �Q,Y1 ktl'Cl04l - i14iLII ,OfXG, R( _ Figure
consultants T1C limnsc Nu: G-3500 and C : )!-
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50
45
40
t35
0
25
n
° 20
115
w 10 PI-13R
s \MWO-8
0
0
50
Legend
Land Surface Elevation
Groundwater Elevation
Slurry Wall
I Monitoring Well
400
800
MWI-9
Elevation Cross Section A - A'
1,200
1,600
Distance (Feet)
Elevation Cross Section B-B'
MWI-7
2,000
2,400
C-33
C-32
2,800
Notes:
1. Land Surface Elevation from NCOneMap 20 foot resolution Light Detection and
Ranging (LiDAR) digital elevation model.
2. Groundwater Elevations from October 2022 monioring well measurement event.
3 Well, piezometer, and slurry wall boundary locations and elevations are
approximate and were obtained from reports prepared by S&ME in April 1996 and in
August 2011.
4. Vertical exaggeration approximately 10x.
B'
A
BI
Elevation Cross Sections
October 2022
Former CF Industries Ahoskie Site
100 Farmers Chemical Road
Hertford County, North Carolina
Geosynteca �Q,Y1 ktl'Cl04l-i14iLII OfXG,R(_ Figure
consultants T1C liwnsc Nu: G-3500 and C : )!-
4d
Raleigh, NC February 2023
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Table 1
Groundwater Elevations
CF Nitrogen - Ahoskie Facility
Hertford County, North Carolina
Well ID
Top of Casing
Elevation
(ft MSL)
1/25/2022
Depth to Groundwater
Water Elevation
ft BTOC ft MSL
4/29/2022
Depth to Groundwater
Water Elevation
ft BTOC ft MSL
7/6/2022
Depth to Groundwater
Water Elevation
ft BTOC ft MSL
10/10/2022
Depth to Groundwater
Water Elevation
ft BTOC ft MSL
C-22
39.65
23.60
16.05
23.96
15.69
24.32
15.33
25.20
14.45
C-23*
40.48
11.02
29.46
10.92
29.56
12.40
28.08
12.12
28.36
C-28*
39.01
29.70
9.31
29.50
9.51
30.00
9.01
30.20
8.81
C-29
43.14
17.42
25.72
16.00
27.14
17.60
25.54
18.00
25.14
C-32
36.85
26.34
10.51
26.14
10.71
26.70
10.15
26.98
9.87
C-33
39.40
12.54
26.86
11.84
27.56
13.38
26.02
14.34
25.06
C-4
42.88
13.80
29.08
13.50
29.38
14.72
28.16
16.68
26.20
MWI-1
1 45.09
14.44
30.65
14.38
30.71
15.90
29.19
15.66
29.43
MWI-2
44.64
14.72
29.92
14.42
30.22
15.20
29.44
15.28
29.36
MWI-3
44.93
15.68
29.25
14.88
30.05
15.70
29.23
15.92
29.01
MWI-4
42.03
11.82
30.21
10.76
31.27
13.00
29.03
11.80
30.23
MWO-5
41.32
17.28
24.04
17.02
24.30
17.34
23.98
17.80
23.52
MWI-6*
46.31
16.78
29.53
16.28
30.03
17.38
28.93
17.46
28.85
MWI-7
44.24
16.82
27.42
16.00
28.24
17.30
26.94
14.70
29.54
MWO-8
42.93
16.72
26.21
16.72
26.21
17.14
25.79
17.84
25.09
PI-1
42.41
12.68
29.73
12.62
29.79
13.70
28.71
13.50
28.91
PI-2
42.60
13.50
29.10
12.98
29.62
14.38
28.22
14.00
28.60
PO-3
42.05
22.48
19.57
23.00
19.05
23.20
18.85
23.28
18.77
PI-4
42.43
13.18
29.25
12.48
29.95
13.48
28.95
13.54
28.89
PI-5
43.05
13.68
29.37
13.40
29.65
14.60
28.45
14.38
28.67
PO-6
43.38
20.32
23.06
20.04
23.34
20.58
22.80
20.78
22.60
PI-7
43.60
14.22
29.38
13.50
30.10
14.62
28.98
14.70
28.90
PI-8
43.16
16.04
27.12
15.00
28.16
16.58
26.58
16.98
26.18
PI-9
43.19
13.88
29.31
12.98
30.21
13.88
29.31
13.72
29.47
PI-10
44.52
15.05
29.47
14.22
30.30
14.98
29.54
15.50
29.02
PI-11
42.57
15.30
27.27
14.52
28.05
15.72
26.85
16.32
26.25
PO-12
39.20
22.92
16.28
22.90
16.30
22.84
16.36
22.74
16.46
PI-13R*
43.25
13.60
29.65
13.00
30.25
14.00
29.25
14.34
28.91
PI-14
43.86
15.40
28.46
14.80
29.06
16.48
27.38
16.42
27.44
PO-15
42.28
18.44
23.84
18.40
23.88
18.60
23.68
18.90
23.38
PO-16
42.41
15.72
26.69
15.50
26.91
15.88
26.53
16.30
26.11
PI-17
42.90
11.92
30.98
13.04
29.86
14.94
27.96
14.70
28.20
PI-18
42.57
13.48
29.09
12.88
29.69
14.04
28.53
13.48
29.09
PI-19
41.31
12.98
28.33
12.68
28.63
14.79
26.52
13.50
27.81
PI-20
42.48
13.02
29.46
12.78
29.70
13.80
28.68
13.48
29.00
PI-21
42.33
12.70
29.63
12.78
29.55
13.78
28.55
13.50
28.83
PI-22
43.13
13.68
29.45
12.60
30.53
13.70
29.43
14.28
28.85
PI-23
42.96
11.90
31.06
12.58
30.38
13.90
29.06
13.30
29.66
PI-24
43.97
14.58
29.39
14.00
29.97
15.22
28.75
15.70
28.27
PO-25
38.85
14.68
24.17
14.24
24.61
14.80
24.05
15.00
23.85
PO-26
42.31
15.80
26.51
15.32
26.99
16.00
26.31
16.40
25.91
PO-235
44.35
27.80
16.55
28.74
15.61
29.18
15.17
29.00
15.35
PO-236
1 43.62
1 29.48
1 14.14
1 29.32
1 14.30
1 29.96
1 13.66
1 30.50
13.12
PO-237
1 44.63
1 17.60
1 27.03
1 17.62
1 27.01
1 17.90
1 26.73
1 18.50
26.13
Notes:
* indicates well has been replaced or repaired
ft MSL - feet mean sea level
ft BTOC - feet below top of casing
CAR230019 Page 1 of 1 February 2023

Table 2
Monthly Rainfall 2022
CF Nitrogen - Ahoskie Facility
Hertford County, North Carolina
Month
2022 Site Recorded
Rainfall (inches)
Average Rainfall for
Cofield (inches)
January
3.99
3.6
February
1.95
3.1
March
2.82
4.1
April
1.87
3.5
May
4.63
3.8
June
1.75
4.1
July
6.54
4.8
August
3.59
4.8
September
5.44
4.6
October
0.64
3.2
November
3.53
3.1
December
2.72
3.3
Annual Total
39.47
46
Monthly Average
3.29
3.83
Notes:
Site rainfall from on -Site rain gauge
Average rainfall for Cofield, NC from www.usa.com as reported by S&ME
CAR230019 Page 1 of 1 February 2023

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0012404
Laboratory: 1)
Pace Analytical (Feb, Apr)
Facility Name: CF Nitrogen, Inc.
2) Waypoint Analytical (Jul, Oct)
Residual Source
3)
NA
NPDES # or WQ#:
4)
WWTP Name: Nitrogen -Enriched Groundwater Re co er. System
5)
Residual Analvsis Data
Sample or Composite Date
Parameter
(mg/-) 2/3/2022 4/28/22
7/27/22
10/19/22
TKN 268 267
216
205
Ammonia -Nitrogen 241 250
40.9
30.8
Nitrate -Nitrite 256 238
243
230
Total Phosphorus 3.5 2.3
3.09
3.00
Aluminum 1.24 0.38
0.831
0.660
Calcium 42.6 54.0
47.9
50.3
Magnesium 12.6 16.1
14.2
13.3
Potassium 38.0 37.3
33.0
33.4
PH 6.5 7.0
6.9
7.0
Sodium 31.2 34.3
27.4
27.5
"I certify, under penalty of law, that this document was prepared under my
direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are
significant penalties for submitting false information, including the possibility
_ A
of fines and imprisonment
for knowing violations."
761
of Preparer of Summary Form
212�1 zc�z�
Date
DENR FORM RSSF - B (12/2006)

APPENDICES

APPENDIX A
Annual Land Application Certification
Form

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0012404 County:
Facility Name (as shown on permit):
Land Application Operator:
Hertford
Granville Farms, Inc.
Year: 2022
CF Nitrogen, Inc.
Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
® Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit:
402
Total number of fields utilized for land application during the year:
27
Total amount of dry tons applied during the year for all application sites:
N/A Groundwater Recovery System
Total number of acres utilizes for land application during the year:
1 584.3
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. 0 Yes 0 No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading
Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified
in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"i certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting fals1i infornWift including the possibility
of fines and imp ' on ent for knowing violations."
4jj,�et
`10XI --�
en ittee Name and Titl (type or print) $i t o e e ate
24 Feb 2023
zAfrl z
Signature of Preparcr*
Date
of Land Applier
Eric Howard, Geosyntec Consultants of NC, P.C, Jay Bryant, Granville Farms, Inc.
Date

APPENDIX B
2022 Application Summary and Field
Loading Rate Reports

2022 Nitrogen Enriched Groundwater Summary
CF Nitrogen - Ahoskie Facility
Hertford County, North Carolina
Farm Name
Field
Number
Application
Date
Acres Utilized
Total
Gallons
Gallons
per Acre
Inches
per Acre
PAN (lbs/ac)
C.F. Nitrogen
Site 11
1
Q2-2022
40.4
124,000
3,069
0.11
9.85
2
Q1-2022
67.2
89,000
1,324
0.05
4.25
Q2-2022
246,000
3,661
0.13
11.75
3
Q1-2022
41.4
183,000
4,420
0.16
14.19
Q2-2022
360,000
8,696
0.32
27.55
Chester Powell
Site 24
4
Q3-2022
10.8
245,000
22,685
0.84
69.69
5
Q3-2022
13
183,000
14,077
0.52
43.24
6
Q3-2022
13.5
465,000
34,444
1.27
105.81
Steven Burgess
Site 27
71
Q1-2022
61.8
683,000
11,052
0.41
35.47
73
Q1-2022
74.9
1,191,000
15,901
0.59
49.29
Walter Perry
Site 28
1
Q3-2022
17.6
504,000
28,636
1.05
87.97
2
Q3-2022
17.5
410,000
23,429
0.86
71.97
3
Q3-2022
25.1
720,000
28,685
1.06
78.82
7
Q2-2022
16
300,000
18,750
0.69
57.6
8
Q2-2022
9.2
206,000
22,391
0.82
68.78
9
Q2-2022
9.9
73,000
7,374
0.27
22.65
11
Q2-2022
3.7
93,000
25,135
0.93
77.21
12
Q2-2022
3.6
95,000
26,389
0.97
81.06
13
Q3-2022
8.7
433,000
49,770
1.83
131.25
14
Q3-2022
7
412,000
58,857
2.17
155.21
15
Q3-2022
17.4
634,000
36,437
1.34
96.09
16
Q3-2022
18.9
744,000
39,365
1.45
103.81
Kendred Williams
Site 30
9
Q4-2022
16.4
350,000
21,341
0.79
56.28
18
Q4-2022
20.9
146,000
6,986
0.26
18.42
William Ward
Site 33
2
Q2-2022
11.9
205,000
17,227
0.63
52.92
3
Q2-2022
15.1
292,000
19,338
0.71
61.1
4
Q2-2022
13.6
255,000
18,750
0.69
57.6
5
Q2-2022
14.2
168,000
11,831
0.44
36.34
6
Q2-2022
14.6
170,000
11,644
0.43
35.77
Acronyms:
PAN - Plant Available Nitrogen
lbs/ac - pounds per acre
Land Applications 2022
First Quarter
2,146,000
Second Quarter
2,587,000
Third Quarter
4,750,000
Fourth Quarter
496,000
Total Gallons Applied = 1 9,979,000
Groundwater Recovered 2022 to Holding Lagoon
First Quarter
2,166,100
Second Quarter
3,834,500
Third Quarter
4,071,800
Fourth Quarter
904,000
Total Gallons Recovered= 1 10,976,400

CF Nitrogen, Inc. - Coficld, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Pe molt # WQ01i 12404
OWNER: CF Nitrogen, Inc.
OPERATOR: Granville Farms, Inc.
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Pp rmittprl AerP%! A0.A Cron: Fescue Predominant Sail: Craven - CrA
FIELD _
DATE
ACRES
UriLVED
TOTAL
GALwNS
GALLONS
PER ACRE
Acre
inlay
Nutrients (lhslac)
PAN
P
K
!
2-2
40.4
124.000
3,069
0.11
9.85
0.09
0,97
Site No.
I
Annual Totals
124.000
3.069
1l. I !
9.X;
0.09
0,97
147 RYELimit
fibs./acre/year)
Z Z Z3
(5ignuturc of Land Appliet) Date
"i certify, under penalty of law, that this dorumont was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. i am aware that theme are
significant penalties for submitting false information, including the passibility of fines and imprisonment for knowingvinlations."

CF Nitrogen, Inc. - Colield, North Carolina
Field loading Rate Report - Nit-mgen Enriched Groundwater
Pe rmit # WQOO12404
OWNER: CF NitrolZen, Inc.
OPERATOR: Granville Farms, Inc.
RESIDUAL SOURCE: Nitrogen Enriched Groundv►^ater
Permitted Acres: 67.2 Crop: Fescue Predominant Soil: Craven - CrA
FIELD
I DATE
ACRES
UTILIZED
TOTAL
GALJ ONS
GALLONS
PER ACRE
Acre
in/Re
Nutrients (lhslac)
PAN
p
K
2
122
67,2
89,000
1,324
0.05
4.25
0.114
(].42
Site No.
11
02-22
67.2
246,000
3,661
O7 13
11 .75
0.1 1
1.16
Annual Totals
335M0
4,985
0.18
16M
11.1
I.5K
147 RYE I unit
(lbs.lacre/vear)
cs� zso!:�- Z t- Z
( Si c of Land Applier) slate
I certify, wider penalty of law. that this document was prepared under my direetian ar supervision in accordance with a syuem
desisted to assure that qualified person net properly gathered and evaluated the information submitted. i am aware that there are
significant penalties for submitting false information, including the passibility of fines and imprisonment for knowing violations."

CF Nitrogen, Inc. - Corield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Pernnit 4 WQOO 12404
OWNER: CF Nitrogen, Inc.
OPERATOR: Granville Farms, Inc.
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres:41.4
Crop: Fescue
Predominant Soil: Craven - CrA
FIFI D
DATE
ACRES
TOTAI.
GAIXONS
Acre
Nutrients {lltslac)
IfFILLUD
GALLONS
PER AC RE.
inlac
PAN
P
K
3
1-22
41.4
193,000
4,420
0.16
14.19
0.13
1.40
Site No.
11
Q2-22
41 A
360,000
8,696
0.3-2
'7.55
0.23
2.74
Annual Tatalsl 543M0
13.116 , 0.49 , 41.73 0.36 1 4.14
147 RVELirnit
{lbs Jacrely ear}
lure of Land AppIierj Date
"I cettify, under penalty of law, chat this document was prepared under my direction or supervision in accordance. with a system
designed to assure that qualified personnel properly pthered and evaluated the infarmation submitted. 1 am awure that there are
si&miCcant penalties for submitting false information, including the possibility of Fines and imprisonment for knowing violations."

CF Nitrogen, Inc, - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Perynit # WQ0012404
OWN ER: Chester Powell
OPERATOR:
RESIDUAL SOURCE:
Permitted Acres: 10.8
Nitrogen Enriched Groundwater
Crop: Soybeans Predominant Soil: Goldsboro - GoA
F'iELD
DATE
ACRES
UTRIZED
TOTAL
GALLONS
GALLONS
PER ACRE
Acre
inlac
Nutrients lac)
PAN
r
K
4
2-22
10.8
245 000
27,685
0.84
69.69
0.44
7.06
Site No.
-74
Annual Totals
245.000
22,685
0.94
69A(19
044
7.06
200 RYELamit
(fbs.lacrelyear)
<�� -z-/z-!L2-3
(Si e of Lane! Applier) Dale
"l certify, wider penalty of law that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."

CF Nitrogen, Inc. - CoField, North Carolina
Field Laading Hate Report - Nitrogen Enriched Croundwater
Pernl<it # WQ0012404
O"ER: Chester Powell
OPERATOR:
RESMUAI, SOURCE:
Pemdtted Acres: 13
F®A DA'Th ACRES
UTILIZED
5 !22-22 13
Site No.
24
Nitrogen Enriched Groundwater
Crop: no beans Predominant Soil. Bonneau - BoB
TOTAL GALLONS Acre Nutrients [lhslac)
GALLONS PER ACRE inlac PAIN P
183.000 14,077 0.5? 43?4 i�.?7 4.38
Annua! Totalsi 183.000
14.077 0,52 43.24 1 0.27 1 4.38
2()(1 R1E Limit
llbs.lacrel ear)
[Sid c of Laud Applier) Date
" 1 rerl ify, unider penalty or law, that this dOCument wa.5 prepared under my direction or supervision in accordance with a system
desisted I assure that qualified personnel properly pthered and evaluated the infonnation submitted. I am aware that there are
sip ificant penalties for submitting raise infin rmation. including the possibility affin es And imprisonment for knowing vialations.

CF Nitrogen, Inc. - Cofieid, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQOO12404
OWNER: Chester Powell
OPERATOR:
RESIDUAL SOURCE;
Permitted Acres:13.5
FW.LD DATE ACRES
UTILUEU
6 02-22 13,5
Site No
24
Annual Totals
Nitrogen Enriched Groundwater
Cr ; So beaus Predominant Soil: Craven - CrA
TOTAL GALLONS Acre Nutrients (Ihslac)
GALMNS PER ACRE inlac PAN P K
465.000 34,444 1.27 1 t15.81 1 061,
465.000 1 34-444 1 1.27 1 105.81 1 0.66 1 10.72
No RYIE I[ Mt
[l Jacre/year)
(Sim ure of Land Appiier) Date
"I ccrt iry, twder penalty or law, that this document was prepared under my direction or sup erN ision in accordance with a system
designed to assure that qualified personnel properly ytthered and evaluated the information submitted. [ ain aware that there are
sign ilicanI penalties For submitting false inform atioo, including the possibility of fines and imprisonment for knowing violations."

CT Nitrogen, Inc. - Cofeld, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQ]U12404
OWNER: William E. Davis
OPERATOR:
RESIDUAL SOURCE:
Permitted Acres: 61.8
Nitrogen Enriched Groundwater
Crop: Wheat PrednminantSoil: Benneau - BoB
YIELD
DATE
ACRES
UTILIZED
'TOTAL
GALLONS
GALIANS
PER ACRE
Acre
inlac
Nutrients libslacl
PAN
P
K
71
i 22
61.8
683,000
11,052
0,41
35.47
0.32
3.50
Site No.
27
Annual Totals
1 683.000
t 1.052
041
:5.47
0.32
� it
102 RYELimit
(1hs.lacrelyear)
[Si ure of [.and Applierj Date
"1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted_ l am aware that there are
significant penalties for submitting False information, including the possibility of Fines and imprisonment for knowing violations."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Pe rrnit # WQ0012404
OWNER: William E. Davis
OPERATOR:
RESIDUAL SOURCE:
Pe rmitte d Acre s : 74.9
F1E11]
73
Site No_
?7
Nitrogen Enriched Groundwater
Crop: Wheat Preela ninant 4ni1• Vnrrn11z _ Vn A
HATE
11-2'
ACRES
UTJ I,IZED
74.9
TOTAL.
GALLONS
1 191.000
GAid,ONS
PER ACRE
15 901
Acre
inlac
0.59
Nutrients (Ihslac' w
PAN
49_29
P
0.41
K
4.46
:annual Totals
1.1 L 1.000
1 �.901
0.59
49?9
0.41
4.46
125 RYE Limit
(lbs Jacrc/year)
(&VaaAxc of Land Applier) Date
"I certify, under penalty of law. that this document Ms prepared under my direction or vipervision in accordance with a systcm
designed to assure that qualitiedpersonnel properly gathered and evaIuatedthe intor nation submitted 1 am aware that [here are
significant penalties for submitting€aIse information, including the passibility of fines and imprisonment for knowing violations."

CF Nitrogen, lne. - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Perndt # WQ4U12404
OWNER: Judith, Allison, and Walter Perry
OPERATOR:
RESIDUAL SOURCE:
Nitrogen
Enriched Groundwater
Permitted Acres: 17.6
Crop: Corn
Predominant Soil: Norfolk - NoA
FIFTH
DATE
ACRFtR
TOTAL
GAII,QNS
Acre
Nutrients lbs/at:)
UTELIZ D
GALLONS
PER ACRF,'
inlay
PAN
P
K
17.6
504,000
28.636
t.05
87.97
0.55
8.91
Site No.
28
Annual Totals 504.000 j 28.636 1 1,t}; 1 9 7 i 0.55 1 4.91
131 RYELindt
(lhs Jacrelyear)
iSignature of Land Applierj Date
"i certify, under penalty of law, that tit is document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the in rormation submitted. I atn aware that there are
significant penalties lnr submitting ralse information, ineIuding the possibility ❑f tines and imprisonment for knowingvioIatinns."

CF Nitrogen, Inc. - Cotield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQ0012404
OWNER: Judith, Allison, and Walter Perry
OPERATOR:
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 17.5 Crop: Corn Predontinant Soil: Norfolk - NoA
FIELD
2
Site No.
28
DATE
3-22
ACRES
UTILIZED
17.5
TOTAL
GALLONS
410,000
GALLONS
PER AC RE
23,429
Acre
inlac
0.86
Nutrients Zbslac)
PAN
71.97
P
0.45
K
729
Annual Totals
410.000
23.429
!1_Rf,
? l )?
(),4i
729
131 111F Li snit
Obs dacrelyear}
C5� &A
z >< 3
t e of Land Applicrj (late
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified persermel properly gathered and evaluated tha intormation submitted. I am aware that there are
significant penalties for submitting raise information, including the possibility of lines and imprisonment for knowing violations."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report - Nitrongen Enriched Grountlwater
Permit # WQD412404
OWNER: Judith, Allison, and Walter Perry
OPERATOR:
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 25.1 Crap: Corn Predominant Soil: Norfolk - NoA
FIELD
DATE
ACRES
UTII.l7EU
TOTAL
GALLONS
GALLONS
PER ACRE
Acre
inlac
Nutrients (lWac)
PAN
P
K
3
3-22
25.1
720,000
28,685
1.06
78.82
0.69
8.16
Site No.
28
Annual Totals
720•000
28,685
1.06
78.82
0.69
S.1 el
131 RYE Limit
(lbs ./acre/year)
z z�s z3
(Sl'gna are of Land Applier) Datr
I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designedto assure that qualified personnel properly gathered and evuluaredthe information submitted. 1 ant aware that there are
sipiticant penalties for submitting false infiormat inn, including the possibility of fines and imprisonment for knowing, violations.'

CF Nitrogen, Inc. - Coheld, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Pe unit # WQ0012404
OWNER: Judith, Allison, and Walter Perry
OPERATOR:
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 16 Crop: Soybeans Predominant Soil: Norfolk - NoA
FIELD
DATE
ACRES
UTILIM11)
TOTAL.
GALLONS
GALLONS
PER ACRE
Acre
inlac
Nutrients (bslae
PAN
P
K
7
2-22
16
300,000
1 K750
Q.69
57.64
0.36
5.84
Site No.
28
Annual Totals
300000
18.7511
0.69
57.60
0.36
5.84
200 IRWILinift
(lbs.lacrelyear)
(signature of Land Applier) Date
"I certify, under penalty of law, that this document was prepared under my direction or suprrvisinn in accordance with a system
desgmed to assure [hat qualified personnel properly gathered and evaluated the information submitted- I am aware that there are
significant penalties for suInnitting false information, including the possibility of fines and imprisonment for knowing violations."

CF Nitrogen, Inc. - Cofie ld, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQ0012404
OWNER: Judith, Allison, and Walter Perry
OPERATOR:
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 9.2 CroF Soybeans Predominant Soil: Goldsboro - GoA
FIRI.n
DATE
ACRES
UTILIZED
TOTAL
GAIADNS
GALLDNS
PERACRE
Acre
inlac
Nutrients (1Wac
PAN
P
K
S
2-22
9.2
206,000
22,391
0.82
68.78
0.43
6.97
Site No.
28
Annual Totals
206,000
22,391
,;?
r,ti_78
0.43
6.97
21ltl RYELiimit
(lbs Jarrelyear)
Z zY z-5
{ - atu • i Lamd Apphvr) Date
"l certify, under penalty ofIaw, that this document was prepared mider my direction or supervision in accordance with a system
designad to assure that qua Iitied personnel prupenIy gathered and evaluated the information submitled. I am aware that there are
significant penalties for submitting false information, including t he possibility of fines and imprisonment far knowing violations."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Peradt #'WQl012404
OWNER: Judith, Allison, and Walter Perry
OPERATOR:
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres' 9.9 Crop: Soybeans Pret[ominant Soil: Goldsboro - Go A
FIELD Dr+1TE ACRFS TOTAL GAfd[7l�l5 Arrc Nutrients (lhslacy
UTYLIZFD GALLONS PER AC RE inlac PAN P K
��-22 �.� 73,ova 7.37 0.27 22.65 n.j 2.3rj
Site No.
28
Annual Totals 7: 0(10 1 374 f 0.27 122.65 1 0.14 1 2.30
100 RYE Lintit
[lUs ./acre/yew)
[ e of Land AppIierj hate
"1 certify, tntder pen aIty of law that this document was prepared udder my direction or sup ervison in accordance with a system
designed to ass-tue that qualified personnel properly gathered and evaluated the 'information submitted. 1 am aware that there are
significant penalties for submitting false information, incltiding the possibility of fines and imprisonment for knowing violations."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Pemdt # WQ0012404
OWNER: Judith, Allison, and Walter Perry
OPERATOR:
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres:3.7 Crop: Sv beans Predominant Sail: Craxen - Crn
FIE!
11
Site No.
28
DATE
2-22
ACRES
UTIUZED
3.7
TOTAL
GALLONS
93,000
GAI LONS
PF.RAC1iE
25,135
Acne
inlac
O] 93
Nutrients (lbslac
PTN7
7T21
P
0.48
IK
T82
:annual Totals
43,OD0
2 �. �;
c�-
7" 1 ' l
it
7.82
200 �RYEU"t
[ Ihs Jacre/year)
C�� '1� z �Y �3
i 5i L,Cl-and Applied Date
"i certify, under penalty of law, that this document was prepared under my direction or supervision in accmdanc-e with a system
designed tD ussure that qualified personnel properly gathered and evaluated the information submitted. l am aware that there are
significant penalties for submitting false infurmation, inelutling the possibility of fines and imprisonment for knowing violations."

CF Nitrogen, Inc. - Cofeld, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Peanut # WQ0012404
OWNER: Judith, Allison, and Walter Perry
OPERATOR:
RESIDUAL SOURCE:
Nitrogen
Enriched Groundwater
Permitted Acres:3.6
Crop: Soybeans
Predominant Soil: Craven - CrB
FOLD
DATE.
ACRES
TOTAL
GALLUNS
Acre
Nutrients [lbslac)
MrILIZED
GALLONS
PER ACRE
inlac
PAN
p
h
12
2-22
3.6
95,000
26.389
0.97
81.06
0.51
9.21
Site No.
,R
Annual-Fotalsj 95,000 1 26,389 1 0.97 1 8 L06 1 0.51 1 8.21.
200 RYELimit
Obs /acrc/year}
<7
-- z
(5i_ of LandApplier) Daze
"I certify, under penalty of law that this document was pre -pared Linder my direction or siipervision in accordance woh a system
designed to assure that qualified personnel properly gathered and evaluated the information s'uhmitted. I am avvarc that there are
sigriifieanL penalties for submiLlingfalse information, including the possibiIity of fines and imprisonment f'or knowing violations."

CF Nitrogen, Inc. - Colield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Pe IT& # WQQh 12404
OWNER: John Lock Mitchell
OPERATOR: Walter Perry
RESIDUAL SOURCE,.
Permitted Acres:8.7
FlH D ❑ATE, ACRES
UTILIZED
13 3-22 8.7
Site No,
2g
Nitrogen Enriched Groundwater
TOTAL
GALLONS
Annual Totalsl 433,000
ip beam Predominant Soil: Bonneau - So8
GALLONS 're Nutrients (lbslac]
PER ACRE, in/He Pray P ti
49,770 1.83 131 25 LP2 13.7 !
4077o 1.83 131.251 1.'h I 13.7t
2[10 RVELimit
{ ibs Jacrelyear}
z-Fr z.3
[ ' of Land Applier] Da# to
"f certify, under penalty of law�, that this document was prepared under my direction or supervision is= accordance mt h a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted, I am aware that there are
significant genalt ies for submitting false information, incioding the passibility of fines and imprisonment for knowing violations."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQ0012404
OWNER: John Luck Mitchell
OPERATOR: Walter Perry
RESIDUAL SOURCE:
Permitted Acres• 7
Nitrogen EnrichedGroundwater
Crop Soybeans Predominant Soil: Bonneau - BoB
1~'IF.ID
DATE
ACRES
UPr[LI]%D
TOTAI,
GALLONS
GALLONS
PER ACRE
Acre
in/He
Nutrients (Iwac)
PAN
I P
K
14
3-22
7
412,000
58,857
2.17
155.211
1.52
l fi.21
Site No.
28
Annual Totals
412,000
58,857
1. ] ?
15i.71
f 57
16.21
200 RYEU wt
{lbs ./acre/year}
c5T, -,a� 1/2-!A �
[Si c of Land Applier] Date
"I certify, under penalty of law, that this document was prepared snider my direction or supervision in accordance with a system
designed tat assure that qualified personnel properly gathered and evalualed the information submitted. 1 am aware that there are
sipiiicent penalties for submitting false information, including the possihility of lines and imprisonment for knowing violations."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report- Nitrogen Enriched Groundwater
Permit # WQ00I2404
OWNER: Berry Perry, John Mitchell, Eleanor Lane, Penny
OPERATOR: Walter Perry
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 17.4 Crop: Soybeans Predominant S oil: Cravcn - CrA
FIELD
DATE
ACRES
UTLMED
TOTAL
GALLONS
GALLONS
PER ACRE
Acre
i nlac
Nutrients (Ihslac)
PAN
P
K
is
3-22
17.4
634 000
36 437
1.34
96.09
D.94
10.03
Site No.
-'s
Annual `Totals
634.000
36.437
1.34
96.09
0.94
10.03
00 RYE Limit
(lb-Oacrely ear)
{S c ul Land Applierl flare
"I certify, under penalty of law: that (his document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the into rmation submitted. I am aware that there are
SiLMiticHDI penalties for sulxnitIing false information, including the possibility of fines and imprisonment far knowing violations."

C'F Nitrogen, Inc. - CoFeld, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQ0012404
OWNER: John Mitchell, Eleanor Lane, Penny Beasley, Ken
OPERATOR: Walter Perry
RESIDUAL SOURCE:
Permitted Acres:18.9
HEIR DATE ACRES
"I[ 1ZED
16 Q3-?2 18.9
Site No,
28
Nitrogen Enriched Groundwater
TOTAL,
GALLONS
Annual Totals 1 744.000
ioyheans Predominant Soil: Conetoe - CoB
GAI-LONS Acre Nutrients (lbslac)
PER ACRE i nlac PAN p K
34,365 1.45 103.81 1.02 10-84
1103.81 1 1.02 1 10.84
200 RYLLimit
(lbs ./acre/year)
(9TnMjUre of Land Applier) Date
"1 certify, under penalty of law that this documcni was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted, 1 am aware that [here are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing Vjolatiuns."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQ0412404
OWNER: Kendred C. Williams, Jr.
OPERATOR:
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres:16.4 Crop: Bermuda Predominant Soil: Norfolk- NoA
FIELD
DATE
ACRES
UTILIZED
'TOTAL
GALLO N S
GALL-ONS
PER ACRE
Acre
i nlac
Nutrients (Ihslae)
PAN
P
K
9
4-22
I6A
350,000
21341
M9
56.28
0.55
5.88
Site No.
30
Annual Totals
350.000
?1.341
0.55
5.88
ni RYE Litn
(lbs.
{ of Land Applier] Date
"I certify, under penalty of law. that this docwnmI was prepared under my direction or supervision in accordance with a system
de!;igned to assure that gwIified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibiIit y of fines and imprisonment for knowing violations."

CF Nitrogen, Inc. - CofieK North Carolina
Field Loading Rate Report - Nitrogen Enriched Grotmdwater
Pe rmit # WQOO 12404
OWNER: Kendred C. Williams, Jr.
OPERATOR:
RESIDUAL SOURCE:
Nitrogen
Enriched Groundwater
Pe rmitted Acres: 2o.9
Crop: Bermuda
Predowi pant Soil: Craven - CrA
FIMD
DATA;
ACRES
TOTAL
GAIJ AMS
Acre
Nutrients (lbslac)
UT]LUED
GALLONS
PERACHE
inlac
PAN
P
K
1$
Q4-22
70.9
146000
6,986
1$.42
0.15
1.92
Site No.
30
Annual Totals 146.000 1 6,986 1 0,26 1 18.42 I 0.1 1,92
168 IRYELidt
(ibs.lacrelyear)
e of Land Appiierl Date
"I certify, tutder penalty of law. that IItis do rum ent was prepared under my direction or supervision in %Qcordance with a system
designed to assure that qualified personnel properly gathered and eva[vat ed the information submitted t am aware that there are
significant pen allies for submitting False information, including the possibility of fines and imprisonment For knowing viotat ions."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQ0012404
OWNER: William W. and Nellie Ward
OPERATOR: William Ward
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: I1.9 Crop: Corn Predominant Soil: Craven - CrC2
FIELD
2
Site. No.
;;
DATE
-22
ACRES
UTILIZED
11.9
TOTAL
GALLONS
205.000
GAIMNS
PER AC RE
17,227
Acre
i nlae
0.63
Nutrients Qhslae)
PAN
52.92
P
033
K
5.36
Annual Totals
?45.[iQ
17 ?27
0.�3
,� )�
[).33
5.35
115 HYE Limit
(lhs./acre/year)
C5, ; - - �-2zs- z!�
( e ol'Land Apptier) pate
"I certify, under penally of law, that this document was prepared under my direction ❑r supervision in accordance Wtli a system
designed to assure that qualified personnel properly gat liered and evaluated the information suhmitted. I am aware that there are
significant penalties for submitting false in form at inn, ineIudingthe possibility of fines and imprisonment For knowing via tat inns."

CF Nitrogen, Inc, - Cofeld, North Carolina
Field Loading Rate Report -• Nitrogen Enriched Groundwater
Permit # WQ0012404
OWNER: William W. and Nellie Ward
OPERATOR: William Ward
RESIDUAL SOURCE:
Nitrogen
Enriched Groundwater
Perntitted Acres:15.1
Crop: Corn
Predominant Soil: Norfolk - NoB
HELD
DA'tTE
ACRES
TOTAL
GALLONS
Acre
Nutrients ibslae]
lfl IHZE.D
GAUU.ON S
PER ACRE
i nlac
PAN
P
K
3
22
15.1
292,000
19,338
0.71
6l A I1
0.49
6.09
Site No.
33
Annual Totals 1 292.000 1 19,338 1 0.71 1 6 i .1 tl I 0.49 1 6.09
128 RYE Li mit
(ibs.lac rclyearj
15i a of Land Applicvj hate
"I cerlify, under penalty of law., that this document was prepared under my direction or supervision in accordanu: with a systcm
designed to assure that Elm] ifiedpersonnel properly gat heredand evaluated tlic intomtation submitted. l tun aware that there are
significant penalties for sulmtilling False information, including the possibility of lines and imprisonment for knowing violations."

CF Nitrogen, Inc, - Cofield, North Carolina
Field. Loading Rate Report - Nitrogen Enriched Groundwater
Permit ## WQ0012404
OWNER: William W. and Nellie Ward
OPERATOR: William Ward
RESIDUAL SOURCE.
Nitrogen
Enriched Groundwater*
Permitted Acres: 13.6
Crop. Corn
Predominant Soil; Norfolk - NoB
FIELD
DATE
ACRES
TOTAL
GA1J DNS
Acre
Nutrients (lhslae)
UrULIZED
GALLONS
PERACRE
Wac
PAN
r
K
7-22
116
255,000
18,750
0.69
57,60
0.36
M4
Site No.
33
Annual Totalsl 255.000 1 M750 1 0.69 1 57.60 1 0.36 1 5.84
I28 RYELirnit
(fbs Jacrelycar)
`� ZY Z 3
{ e of Land Applierj Date
"I certify_ under penalty of law, that this document was prepared Linden my direction ur supervision in 3CCVMan cc with a system
designed to assure that qualified personnel properly pihered and evaluated the intormation submitted, I am aware that there are -
sign ifican t penalties l'or submitting false in tormation, including the possibility of fines and imprisonment for knowing; violations."

CF Nitrogen, Inc. - Cofield, North Carolina
Field Loading Rate Report - Nitrogen Enriched Groundwater
Permit # WQOO12404
OWNER: William W. and Nellie Ward
OPERATOR: William Ward
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 14.2 Crop. Soybeans Predominant Soil • Tarhnrn - Ta B
FIELD
5
Site No.
33
DATE
ACRES
UTII.1Z:D
14,2
TOTAL
GALLONS
168,000
GALLONS
PER ACRE
11,831
:acre
i n/ac
0_44
Nutrients (It,.clac)
PAN
36.34
P
0.23
K
3.68
knnual'Fotalsl
168,000
1 1,811
0.44
36.34
0.2,
100 RYE Limit
tlhs Jacrelyear}
(Signa ure of Land Applied Date
"f certify. under penalty of law, that this doctmtent was prepared Linder my direction or supers ision in accordance with a system
designed to assure that qualified personnel properly brathered and evaluated the intornntit) n submitted. l am aware that there are
significant penalties for submitting false information. including the possibility of fines and imprisonment for knowing vinlal ions."

CF ;Nitrogen, Inc. - Colield, North Carolina
Field Loading Rate Report- Nitrogen Enriched Groundwater
Pe rruit # WQOO12404
OWN FR: William W. and Nellie Ward
OPERATOR: William Ward
RESIDUAL SOURCE; Nitrogen Enriched Groundwater
Permitted Acres: I4.6 Crop: Soybeans Pr•edaminant sail: Norfolk - NoB
FIELD DATE ACRES TOTAL GALLONS Acre Nutrients (Ihslael
UTRJZF-D GALLONS PER ACRE inlay PAN P IC
2-22 14.6 t70OOO 11 644 0.43
35.77 D.Z2
:. 3.6?
Site No.
33
Annual Totals 17D.Crt?0 f 11.644 0 43 j 0L2
(Ibs .lacrelyear)
2 Z Z Zj
I ure of I.andAppiicrl Datc
"I certify, under penalty of law, that this document ryas prepared under my direct inn or supervision in accordance with a system
designed to assure that qualified pcmonne! properly 01hered and evaluated the information submitted. t am aware that there are
significant pen allies for submitting False information, including the possibility offines and imprisonment for knowing violations."

APPENDIX C
Field Application Summaries

2022 Field Application Summary
CF Nitrogen, Inc.
Permit #WQ0012404
Site ID: 11 Application Method: Surface
Site Name: C.F. Nitrogen Total Application: 1,002,000
Site Acres: 149
Field
1
2
3
Acres
40.4
67.2
41.4
Crop
Fescue
Fescue
Fescue
3/28/2022
-
-
32,000
3/29/2022
-
-
78,000
3/30/2022
-
-
73,000
3/31/2022
-
89,000
-
4/4/2022
-
86,000
-
4/5/2022
-
94,000
-
4/6/2022
90,000
-
-
4/7/2022
34,000
-
-
4/11/2022
-
-
96,000
4/12/2022
-
-
75,000
4/13/2022
-
-
80,000
4/27/2022
-
66,000
-
5/9/2022
-
-
109,000
Quarter 1
-
89,000
183,000
Quarter 2
124,000
246,000
360,000
Quarter 3
-
-
-
Quarter 4
-
-
-
Field Totals
124,000
335,000
543,000

2022 Field Application Summary
CF Nitrogen, Inc.
Permit #WQ0012404
Site ID: 24 Application Method: Surface
Site Name: Chester Powell Total Application: 893,000
Site Acres: 37.3
Field
4
5
6
Acres
10.8
13.0
13.5
Crop
Soybeans
Soybeans
Soybeans
6/1/2022
93,000
-
-
6/2/2022
94,000
-
-
6/3/2022
58,000
-
-
6/6/2022
94,000
-
6/7/2022
89,000
-
6/8/2022
-
-
87,000
6/9/2022
-
-
93,000
6/10/2022
-
-
94,000
6/13/2022
-
-
95,000
6/14/2022
-
-
96,000
Quarter 1
-
-
-
Quarter 2
-
-
-
Quarter 3
245,000
183,000
465,000
Quarter 4
-
-
-
Field Totals
245,0001
183,000
465,000

2022 Field Application Summary
CF Nitrogen, Inc.
Permit #WQ0012404
Site ID: 27 Application Method: Surface
Site Name: Steven Burgess Total Application: 1,874,000
Site Acres: 136.7
Field
71
73
Acres
61.8
74.9
Crop
Wheat
Wheat
1/12/2022
-
108,000
1/13/2022
-
121,000
1/14/2022
-
132,000
1/18/2022
-
121,000
1 / 19/2022
-
102,000
1/20/2022
-
45,000
1/27/2022
-
110,000
1 /28/2022
-
98,000
1/31/2022
-
71,000
2/1/2022
-
106,000
2/2/2022
-
100,000
2/3/2022
-
38,000
2/4/2022
-
39,000
2/10/2022
77,000
-
2/11 /2022
66,000
-
2/14/2022
38,000
-
2/15/2022
75,000
-
2/16/2022
76,000
-
2/17/2022
76,000
-
2/21/2022
43,000
-
2/22/2022
37,000
-
2/23/2022
13,000
-
2/24/2022
32,000
-
3/1/2022
74,000
-
3/2/2022
76,000
-
Quarter 1
683,000
1,191,000
Quarter 2
-
-
Quarter 3
-
-
Quarter 4
-
-
Field Totals
683,000
1,191,000

2022 Field Application Summary
CF Nitrogen, Inc.
Permit #WQ0012404
Site ID: 28
Site Name: Walter Perry
Site Acres: 153.9
Application Method: Surface
Total Application: 4,624,000
1
111
1 1
��
111
• 111
• 1
����������
111
111
• -
���
11 111
1. 111
111
• 111
• 111����
•
1' 111
' 1 111
1 111
�����
111
' 111
• ' 111
- • •
1' 111
1 111
1 111
11 111
1. 111
111
• 111
' 111
111
111
111
" 111

2022 Field Application Summary
CF Nitrogen, Inc.
Permit #WQ0012404
Site ID: 30
Site Name: Kendred C. Williams
Site Acres: 37.3
Application Method: Surface
Total Application: 496,000
Field
9
18
Acres
16.4
20.9
Crop
Bermuda
Bermuda
10/10/2022
116,000
-
10/11/2022
118,000
-
10/12/2022
116,000
-
10/13/2022
-
27,000
10/17/2022
-
119,000
Quarter 1
-
-
Quarter 2
-
-
Quarter 3
-
-
Quarter 4
350,000
119,000
Field Totals
350,0001
146,000

2022 Field Application Summary
CF Nitrogen, Inc.
Permit #WQ0012404
Site ID: 33
Site Name: William Ward Jr.
Site Acres: 69.4
Application Method: Surface
Total Application: 1,090,000
Field
2
3
4
5
6
Acres
11.9
15.1
13.6
14.2
14.6
Crop
Corn
Corn
Corn
Soybeans
Soybeans
4/15/2022
-
16,000
-
-
-
4/20/2022
-
29,000
-
-
-
4/21/2022
-
43,000
-
-
-
4/22/2022
-
36,000
-
-
-
4/25/2022
-
35,000
-
-
-
4/26/2022
-
27,000
-
-
-
4/28/2022
-
40,000
-
-
-
4/29/2022
-
66,000
-
-
-
5/2/2022
41,000
-
-
-
-
5/3/2022
41,000
-
-
-
-
5/4/2022
40,000
-
-
-
-
5/6/2022
41,000
-
-
-
-
5/10/2022
42,000
-
-
-
-
5/11/2022
-
-
41,000
-
-
5/12/2022
-
-
35,000
-
-
5/13/2022
-
-
21,000
-
-
5/16/2022
-
-
41,000
-
-
5/17/2022
-
-
42,000
-
-
5/18/2022
-
-
75,000
-
-
5/19/2022
-
-
-
99,000
-
5/20/2022
-
-
-
69,000
-
5/23/2022
-
-
-
-
81,000
5/31/2022
-
-
-
-
89,000
Quarter 1
-
-
-
-
-
Quarter 2
205,000
292,000
255,000
168,000
170,000
Quarter 3
-
-
-
-
-
Quarter 4
-
-
-
-
-
Field Totals
1 205,0001
292,0001
255,0001
168,0001
170,000

APPENDIX D
Approved Land Application Sites

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
29-1
Ronald Byrd
Berrie
36°09'30"
-76°57'54"
6.7
Leaf—Lf
29-2
Ronald Byrd
Berrie
36°09'31"
-76°58'02"
2.4
Leaf— Lf
29-3
Ronald Byrd
Bertie
36°09'31"
-76°58'09"
6
Exum — ExA
29-4
Ronald Byrd
Berrie
36°09'27"
-76°58'09"
9.8
Exum — ExA
29-5
Ronald Byrd
Bertie
36°09'27"
-76°58'20"
11.1
Exum—ExA
29-6
Ronald Byrd
Berrie
36°09'25"
-76°58'34"
3.1
Leaf— Lf
29-7
Ronald Byrd
Bertie
36°09'24"
-76°58'10"
4.6
Granthum G
29-8
Ronald Byrd
Berrie
36°09'21"
-76°58'05"
10
Granthum Gt
29-9
Ronald Byrd
Bertie
36°09'24"
-76°58'00"
0.5
Exum — ExA
29-10
Ronald Byrd
Bertie
36°09'24"
-76°57'56"
4.0
Exum — ExB
30-1
Kendred C. Williams, Jr.
Bettie
36°08'15"
-76°57'12"
15.4
Exum—ExA
30-2
Kendred C. Williams, Jr.
Berrie
36°08'22"
-76°57'13"
6.1
Exum— ExA
30-3
Kendred C. Williams, Jr.
Bertie
36°12'47"
-76°56'35"
1.3
Craven — CrA
30-4
Kendred C. Williams, Jr.
Berrie
36°12'45"
-76°56'22"
26.3
Norfo k NoB
30-5
Kendred C. Williams, Jr.
Bertie
36°12'43"
-76°56'07"
32.4
Craven — CrB
30-6
Kendred C. Williams, Jr.
Berrie
36°12'31"
-76°56'09"
9.0
Craven CrB
30-7
Kendred C. Williams, Jr.
Bertie
36°12'38"
-76°56'25"
12.9
Craven CrB
30-8
Kendred C. Williams, Jr.
Berrie
36°12'40"
-76°56'34"
6.5
Craven — CrB
30-9
Kendred C. Williams, Jr.
Bettie
36°12'41"
-76°56'49"
16.4
Norfolk —NoA
30-10
Kendred C. Williams, Jr.
Berrie
36°12'45"
-76°56'47"
3.7
Norfolk—NoA
30-11
Kendred C. Williams, Jr.
Bettie
36°12'48"
-76°56'45"
1.4
Norfolk —NoB
30-12
Kendred C. Williams, Jr.
Berrie
36°12'48"
-76°56'39"
1.5
Norfolk —NoA
30-13
Kendred C. Williams, Jr.
Berrie
36°12'51"
-76°56'41"
5.1
Lenoir —Ln
WQ0012404 Version: 3.0 Attachment B Page 1 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
30-14
Kendred C. Williams, Jr.
Bcrtic
36°12'56"
-76°56'38"
0.5
Lenoir—Ln
30-15
Kendred C. Williams, Jr.
Bertie
36°13'03"
-76°56'36"
8.9
Leaf—Lf
30-16
Kendred C. Williams, Jr.
Bettie
36°13'09"
-76°56'31"
4.5
Craven— CrA
30-17
Kendred C. Williams, Jr.
Berrie
36°13'06"
-76°57'03"
28.1
Craven—CrA
30-18
Kendred C. Williams, Jr.
Bettie
36°12'55"
-76°57'00"
20.9
Craven—CrA
30-19
Kendred C. Williams, Jr.
Bettie
36°12'54"
-76°5648"
9.3
Goldsboro - GoA
30-20
Kendred C. Williams, Jr.
Bettie
36°12'13"
-76°56'51"
10.7
Craven—CrA
30-21
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'23"
-76°5648"
7.0
Lenoir — Ln
30-22
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'16"
-76°56'53"
7.5
Craven—CrA
30-23
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'16"
-76°56'59"
9.2
Craven—CrA
30-24
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'18"
-76°57'02"
4
Craven—CrA
30-25
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'19"
-76°57'05"
1.5
Craven—CrA
30-26
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'26"
-76°57'12"
4.3
Craven— CrA
30-27
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'16"
-76°57'08"
4.0
Craven—CrA
30-28
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'13"
-76°57'09"
5.1
Craven— CrA
30-29
C.S. Hollomon, Jr.
Kendred C. Williams, Jr.
Bettie
36°12'08"
-76°57'07"
13.3
Craven—CrA
30-30
Kendred C. Williams, Jr.
Bettie
36°10'35"
-76°57'25"
4.5
Nahunta - Na
30-31
Kendred C. Williams, Jr.
Bettie
36°10'28"
-76°5724"
20.8
Exam — ExA
30-32
Kendred C. Williams, Jr.
Bettie
36°10'24"
-76°57'15"
7.5
Goldsboro —GoA
30-33
Kendred C. Williams, Jr.
Bettie
36°10'18"
-76°57'19"
17.8
Goldsboro —GoA
30-34
Kendred C. Williams, Jr.
Bettie
36°10'18"
-76°57'18"
24.1
Goldsboro —GoA
30-35
Kendred C. Williams, Jr.
Bettie
36°10'20"
-76°57'37"
0.9
Exum—ExA
30-36
David C. Powell
Kendred C. Williams, Jr.
Bettie
36°13'13"
-76°54'33"
19.9
Exum— ExA
30-37
E.M. Powell & Sons, Inc.
Kendred C. Williams, Jr.
Bettie
36°13'07"
-76°54'26"
21.2
Exum — ExA
30-38
E.M. Powell & Sons, Inc.
Kendred C. Williams, Jr.
Bettie
36°12'49"
-76°54'30"
23.4
Exam — ExA
WQ0012404 Version: 3.0 Attachment B Page 2 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
30-39
E.M. Powell & Sons, Inc.
Kendred C. Williams, Jr.
Bettie
36°12'42"
-76°54'24"
25.4
Exum—ExA
30-40
T.E. Ruffin
Kendred C. Williams, Jr.
Bettie
36°09'22"
-76°57'24"
19.9
Exum — ExA
30-41
T.E. Ruffin
Kendred C. Williams, Jr.
Bettie
36°09'23"
-76°57'37"
7.0
Exum — ExA
30-42
T.E. Ruffin
Kendred C. Williams, Jr.
Bettie
36°09'26"
-76°57'43"
4.7
Exum — ExA
30-43
T.E. Ruffin
Kendred C. Williams, Jr.
Bettie
36°09'23"
-76°57'46"
7.0
Exum — ExA
30-44
James C. Askew
Kendred C. Williams. Jr.
Bettie
36°11'18"
-76°57'21"
3
Exum—ExB
30-45
James C. Askew
Kendred C. Williams, Jr.
Bettie
36°11'18"
-76°57'17"
6.3
Exam —ExB
30-46
James C. Askew
Kendred C. Williams, Jr.
Bettie
36°11'17"
-76°57'10"
12.0
Gritney— Gt
30-47
Oliver B. Balance
Kendred C. Williams, Jr.
Bettie
36°11'12"
-76°57'08"
11.6
Exum—ExA
33-17
Leonard L. Godwin
William Ward
Bettie
36°13'38"
-77°00'05"
11.2
Norfolk —NoA
33-18
Leonard L. Godwin
William Ward
Bettie
36°13'31"
-76°59'55"
11.2
Goldsboro—GoA
33-19
Ola Sanders
William Ward
Bettie
36°12'15"
-76°56'09"
16.8
Goldsboro—GoA
33-20
Ruth H. Metcalf
William Ward
Bettie
36°14'16"
-76°54'30"
3.3
Exum—ExA
33-21
Ruth H. Metcalf, et al
William Ward
Bettie
36°14'02"
-76°54'24"
12.9
Exum — ExA
33-22
Mildred Harris
William Ward
Bettie
36°13'53"
-76°54'12"
17.0
Exum—ExA
33-23
Agnes 0. Moore, et al
William Ward
Bettie
36°13'42"
-76°54'09"
10
Goldsboro — GoA
County Total
Bertie
653.6
3-1
Wiley B. Gillam III
Hertford
36°19'51"
-76°50'39"
19.6
Lynchburg - Ly
3-2
Wiley B. Gillam III
Hertford
36° 19'44"
-76°50'43"
37.2
Lynchburg - Ly
3-3
Wiley B. Gillam III
Hertford
36° 19'45"
-76°50'28"
19.9
Norfolk —NoA
3-4
Wiley B. Gillam III
Hertford
36°19'27"
-76°48'06"
18.6
Wickham — WkB
3-5
Wiley B. Gillam III
Hertford
36° 19'02"
-76°48'02"
31.9
Tarboro — TaB
6-1
Stuart Pierce Farms, Inc.
Hertford
36° 16'06"
-76°56'20"
17.0
Craven — CrA
6-2
Stuart Pierce Farms, Inc.
Hertford
36°16'18"
-76°56'20"
67.4
Caroline — CaA
6-3
Stuart Pierce Farms, Inc.
Hertford
36°16'09"
-76°55'58"
7.9
Caroline — CaA
WQ0012404 Version: 3.0 Attachment B Page 3 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
6-4
Stuart Pierce Farms, Inc.
Hertford
36°15'54"
-76°56' 16"
10.9
Caroline — CaA
6-5
Stuart Pierce Farms, Inc.
Hertford
36°15'47"
-76°56'56"
54.0
Caroline — CaA
6-6
Stuart Pierce Farms, Inc.
Hertford
36°15'36"
-76°56'34"
23.3
Craven— CrB
6-7
Stuart Pierce Farms, Inc.
Hertford
36°15'27"
-76'56'11"
42.2
Craven—CrB
6-9
Stuart Pierce Farms, Inc.
Hertford
36°16'01"
-76°57'17"
38.9
Craven — CrA
6-10
Stuart Pierce Farms, Inc.
Hertford
36°16'43"
-76°55'34"
107.0
Caroline — CaA
6-11A
Stuart Pierce Farms, Inc.
Hertford
36°15'52"
-77°00'07"
41.0
Craven — CrB
6-11B
Stuart Pierce Farms, Inc.
Hertford
36°15'41"
-76°59'53"
72.2
Craven — CrB
6-1 IC
Stuart Pierce Farms, Inc.
Hertford
36°15'37"
-76°59'40"
29.4
Craven—CrB
6-1 ID
Stuart Pierce Farms, Inc.
Hertford
36°15'24"
-76°59'45"
41.2
Craven--CrB
6-11E
Stuart Pierce Farms, Inc.
Hertford
36°15'36"
-76°59'37"
47.7
Craven — CrA
6-12
Stuart Pierce Farms, Inc.
Hertford
36°18'30"
-77'01'47"
40.4
Caroline — CaA
6-13
Stuart Pierce Farms, Inc.
Hertford
36°18'27"
-76°54'52"
41.4
Craven — CrA
6-14
Stuart Pierce Farms, Inc.
Hertford
36°18'10"
-76°54'59"
30.9
Craven — CrA
6-15
Stuart Pierce Farms, Inc.
Hertford
36°18'14"
-76°55'18"
48.8
Craven—CrB
6-16
Stuart Pierce Farms, Inc.
Hertford
36°16'51"
-76°45'06"
46.1
Bonneau—BoB
6-17
Stuart Pierce Farms, Inc.
Hertford
36°16'44"
-76°45'38"
41.9
Bonneau—BoB
6-18
Stuart Pierce Farms, Inc.
Hertford
36°17'04"
-76°45'33"
21.0
Bonneau—BoB
6-19
Stuart Pierce Farms, Inc.
Hertford
36°16'33"
-76 43'56"
46.3
Goldsboro — GoA
6-20
Stuart Pierce Farms, Inc.
Hertford
36° 16'06"
-76°44' 18"
21.4
Goldsboro — GoA
6-21
Stuart Pierce Farms, Inc.
Hertford
36° 17'50"
-76°43' 10"
70.8
Bonneau — BoB
6-22
Stuart Pierce Farms, Inc.
Hertford
36°16'19"
-77°02'38"
56.4
Craven — CrA
6-23
Stuart Pierce Farms, Inc.
Hertford
36°16'32"
-77°02'41"
94.9
Craven — CrA
6-24
Stuart Pierce Farms, Inc.
Hertford
36°16'20"
-77°02'23"
41.6
Lenoir — Ln
WQ0012404 Version: 3.0 Attachment B Page 4 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net
Acreage
Dominant Soil Series
Footnotes
9-2
Gray Pierce, et al
Hertford
36°18'20"
-76°51'10"
18.5
Norfolk —NoA
9-3
Gray Pierce
Hertford
36°18'14"
-76°51'20"
8.5
Norfolk —NoA
9-5
Carlyle Archer, et al
Gray Pierce
Hertford
36°18'13"
-76°51'37"
22.8
Norfolk —NoA
9-6
Gray Pierce
Hertford
36°18'15"
-76°51'46"
4.5
Goldsboro GoA
9-7
Gray Pierce
Hertford
36°18'07"
-76°51'28"
16.2
Norfolk—NoA
9-8
Gray Pierce
Hertford
36°18'03"
-76°51'36"
11.6
Norfolk —NoA
9-9
Gray Pierce
Hertford
36°17'15"
-76°51'30"
18.1
Craven — CrB
9-10
Gray Pierce
Hertford
36°17'59"
-76°51'30"
5.6
Craven—CrB
9-11
Gray Pierce
Hertford
36°17'45"
-76°51'19"
10.6
Craven—CrB
9-12
Gray Pierce
Hertford
36°17'48"
-76°51'05"
8.6
Conetoe—CoB
9-14
Gray Pierce
Hertford
36°17'50"
-76°50'58"
6.7
Tarboro—TaB
9-15
Gray Pierce
Hertford
36°17'58"
-76°50'50"
7.7
Tarboro—TaB
9-16
Gray Pierce
Hertford
36°17'58"
-76°51'22"
1.5
Craven — CrB
9-17
Gray Pierce
Hertford
36°18'01"
-76°51'21"
3.6
Craven — CrB
9-18
Gray Pierce
Hertford
36°17'50"
-76°51'25"
14.6
Wickham — WkA
9-19
Gray Pierce
Hertford
36°17'59"
-76°51'10"
3.7
Tarboro—TaB
9-20
Gray Pierce
Hertford
36°18'06"
-76°51'13"
3.9
Bonneau—BoB
9-21
Gray Pierce
Hertford
36°17'38"
-76°51'49"
6.0
Craven—CrA
9-22
Gray Pierce
Hertford
36°17'45"
-76°51'49"
9.6
Lenoir —Ln
9-24
Gray Pierce
Hertford
36°17'47"
-76°51'43"
13.5
Craven —CrA
9-26
Gray Pierce
Hertford
36°18'34"
-76°51'45"
27.0
Craven — CrA
9-27
Gray Pierce
Hertford
36°19'12"
-76°51'48"
24.9
Tarboro — TaB
9-28
Gray Pierce
Hertford
36°18'51"
-76°52'0I"
15.0
Wickham — WkA
9-29
Gray Pierce
Hertford
36°18'47"
-76°51'57"
5.7
Wickham — WkA
9-30
Gray Pierce
Hertford
36°1844"
-76°51'53"
11.9
Wickham — WkA
WQ0012404 Version: 3.0 Attachment B Page 5 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
9-31
Gray Pierce, Merle Jones
Gray Pierce
Hertford
36° 17'48"
-76°5245"
11.4
Craven — CrA
9-32
Merle Jones
Gray Pierce
Hertford
36°17'34"
-76°52'36"
176
Lenoir —Ln
9-33
Gray Pierce
Hertford
36°17'37"
-76°52'10"
16.7
Craven—CrA
9-34
Gray Pierce
Hertford
36°17'52"
-76°53'00"
8
Craven—CrA
9-35
Gray Pierce
Hertford
36°17'58"
-76°52'55"
13
Craven—CrA
9-37
R.C. Kennington
Gray Pierce
Hertford
36°18'33"
-76°5245"
16
Craven — CrB
9-38
R.C. Kennington
Gray Pierce
Hertford
36°18'27"
-76°52'32"
8
Craven — CrB
9-40
Gray Pierce
Hertford
36°19'21"
-76°53'33"
11.2
Wickham — WkB
9-41
Gray Pierce
Hertford
36°19'33"
-76°5328"
12.4
Wickham — WkA
9-42
Gray Pierce
Hertford
36° 19'23"
-77'01'20"
26.4
Caroline — CaA
9-43
Gray Pierce
Hertford
36°19'16"
-7700'38"
39.4
Caroline — CaA
9-45
Gray Pierce
Hertford
36°19'11"
-7706'56"
73.7
Craven—CrA
9-46A
Gray Pierce
Hertford
36°19'19"
-770749"
36.7
Craven—CrA
9-46B
Gray Pierce
Hertford
36°19'15"
-7707'27"
42.5
Craven—CrA
9-47
Gray Pierce
Hertford
36°19'33"
-7708'09"
18.8
Craven—CrA
9-48
Gray Pierce
Hertford
36°18 32'
-770631"
45.1
Craven CrA
9-50
Gray Pierce
Hertford
36°18'53"
-7706'43"
63.8
Craven CrA
9-52
Gray Pierce
Hertford
36°18'57"
-7707'03"
27.4
Craven CrA
9-53
Gray Pierce
Hertford
36°19'06"
-7707'13"
26.7
Craven — CrB
10-1
J.H. Drewry, III
Hertford
36°32'36"
-7709'O1"
7.8
Tarboro —TaB
10-2
J.H. Drewry, III
Hertford
36°32'30"
-7708'36"
34.1
Wickham — WkA
10-3
J.H. Drewry, III
Hertford
36°32'17"
-7708'33"
67.7
Autryville—AuB
10-4
J.H. Drewry, III
Hertford
36°32'35"
-7708'16"
6.9
Lynchburg — Ly
10-5
J.H. Drewry, III
Hertford
36°32'58"
-7708'17"
20.0
Norfolk —NoA
10-6
J.H. Drewry, III
Hertford
36°5221"
-7707'56"
35.0
Craven—CrA
WQ0012404 Version: 3.0 Attachment B Page 6 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
10-7
J.H. Drewry, III
Hertford
36°32'17"
-77°08'07"
35.4
Norfolk—NoA
10-8
J.H. Drewry, III
Hertford
36°32'15"
-77°08'18"
42.3
Norfolk—NoA
10-9
J.H. Drewry, III
Hertford
36°32'24"
-77°07'46"
12.3
Autryville — AuB
10-10
J.H. Drewry, III
Hertford
36°32'27"
-77°07'41"
26.3
Bonneau — BoB
10-11
J.H. Drewry, III
Hertford
36°32'O1"
-77°07'07"
4.9
Norfolk—NoA
11-1
CF Industries, Inc.
Granville Farms, Inc.
Hertford
36°22'19"
-76°52'10"
40.4
Craven CrA
11-2
CF Industries, Inc.
Granville Farms, Inc.
Hertford
36°22'17"
-76°51'47"
67.2
Craven—CrA
11-3
CF Industries, Inc.
Granville Farms, Inc.
Hertford
36°22'01"
-76°5l'54"
41.4
Craven — CrA
12-1
Douglas R. White
Tuscarora Greens
Hertford
36°23'03"
-76°54'59"
8.3
Lenoir — La
12-2
Douglas R. White
Tuscarora Greens
Hertford
36°22'57"
-76'55'11"
8.8
Lenoir —Ln
12-3
Douglas R. White
Tuscarora Greens
Hertford
36°22'40"
-76°54'57"
6.3
Craven — CrB
12-4
Douglas R. White
Tuscarora Greens
Hertford
36°2243"
-76°54'46"
30.0
Craven — CrA
12-5
Douglas R. White
Tuscarora Greens
Hertford
36°22'33"
-76°54'51"
5.0
Craven — CrA
12-6
Douglas R. White
Tuscarora Greens
Hertford
36°22'55
-76°54'52"
18.0
Craven—CrA
23-1
Johnny Powell
Hertford
36°17'01"
-76°44'02"
24.9
Norfolk NoA
23-2
Johnny Powell
Hertford
36°16'42"
-76°45'12"
13.1
Norfolk —NoA
23-3
Thaddeus F. Scott
Johnny Powell
Hertford
36°17'46"
-76°45'44"
39.1
Norfolk NoA
23-4
Thaddeus F. Scott
Johnny Powell
Hertford
36°17'55"
-76°45'44"
22.0
Norfolk—NoA
23-5
Johnny Powell
Hertford
36°18'19"
-76°47'17"
27.7
Norfolk —NoB
23-6
Johnny Powell
Hertford
36°18'02"
-76°50'25"
19.9
Conetoe— CoB
23-7A
Johnny Powell
Hertford
36° 17'42"
-76°49'32"
33.5
Craven — CrA
23-713
Johnny Powell
Hertford
36°18'03"
-76'49'10"
13.2
Bonneau — BoB
23-8
Johnny Powell
Hertford
36°17'12"
-76°53'00"
29.8
Caroline — CaA
23-9
Johnny Powell
Hertford
36°19'50"
-76°51'05"
19.8
Craven—CrA
23-10
Johnny Powell
Hertford
36°20'26"
-76°49'47"
15.8
Craven — CrA
WQ0012404 Version: 3.0 Attachment B Page 7 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
23-12
Johnny Powell
Hertford
36°22'27"
-76°54'50"
26.3
Craven — CrA
23-13
Johnny Powell
Hertford
36°21'38"
-76°54'02"
20.5
Craven — CrA
23-14
Johnny Powell
Hertford
36°21'46"
-76°5423"
11.7
Craven—CrA
23-15
Johnny Powell
Hertford
36°22'38"
-76°56'02"
19.0
Norfolk—NoA
23-16
Johnny Powell
Hertford
36°18'35"
-76°5542"
45.0
Craven — CrB
24-2
Chester Powell
Hertford
36°19'15"
-76°50'40"
14.6
Norfolk —NoA
24-3
Chester Powell
Hertford
36°19'28"
-76°50'34"
11.6
Wickham - WkB
24-4
Chester Powell
Hertford
369 8'56"
-76°48'52"
10.8
Goldsboro — GoA
24-5
Chester Powell
Hertford
36°18'43"
-76°48'52"
13.0
Bonneau—BoB
24-6
Chester Powell
Hertford
36°20'24"
-76°51'54"
13.5
Craven — CrA
24-7
Chester Powell
Hertford
36°20'17"
-76°51'46"
3.6
Craven—CrA
24-8
Chester Powell
Hertford
36°15'50"
-76°56'33"
6.3
Lenoir— Ln
24-9
Chester Powell
Hertford
36°15'50"
-76°53'54"
12.7
Craven—CrA
24-10
Shirley Deramus
Chester Powell
Hertford
36° 18'04"
-76°43'20"
6.1
Bonneau — BoB
24-11
Shirley Deramus
Chester Powell
Hertford
36°18'09"
-76°43'13"
10.5
Goldsboro — GoA
24-13
Chester Powell
Hertford
36°15'23"
-76°49'06"
14.8
Craven—CrA
25-1
Tommy Castelow
Hertford
36°2F58"
-76°53'54"
39.8
Caroline — CaA
25-2
Tommy Castelow
Hertford
36°19'46"
-76°49'06"
9.3
Norfolk —NoA
25-3
Tommy Castelow
Hertford
36°20'02"
-76°49'03"
32.2
Norfolk — NoA
25-4
Tommy Castelow
Hertford
36°20'17"
-76°49'02"
30.2
Craven — CrA
25-5
Tommy Castelow
Hertford
36°20'09"
-76°4842"
25.6
Craven — CrA
25-6
Tommy Castelow
Hertford
36°20'00"
-76°47'36"
27.2
Craven — CrA
25-7
Tommy Castelow
Hertford
36°21'16"
-76°47'38"
12.3
Craven—CrA
25-8
Tommy Castelow
Hertford
36°20'43"
-76°54'05"
16.6
Craven — CrA
25-9
Tommy Castelow
Hertford
36°20'37"
-76°54'O1"
34.7
Craven—CrA
WQ0012404 Version: 3.0 Attachment B Page 8 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
25-10
Tommy Castelow
Hertford
36°20'26"
-76°54'07"
11.3
Craven — CrA
25-11
Tommy Castelow
Hertford
36°20'25"
-76°54'13"
4.8
Craven—CrA
25-12
Tommy Castelow
Hertford
36°20'O1"
-76°54'28"
32.0
Craven—CrA
26-1
Beechwood Country Club
Hertford
36°2F58"
-77°00'38"
7.9
Caroline — CaA
26-2
Beechwood Country Club
Hertford
36°2 F53"
-77°00'47"
10.5
Craven — CrB
26-3
Beechwood Country Club
Hertford
36°21'37"
-77°00'37"
8.3
Craven — CrB
26-4
Beechwood Country Club
Hertford
36°21'43"
-77°00'O1"
18.2
Caroline — CaB
27-52
Lori S. Burgess
Steven Burgess
Hertford
36°25'02"
-77°06'01"
44.7
Norfolk —NoA
27-53
Lori S. Burgess
Steven Burgess
Hertford
36°2442"
-77°05'55"
10.0
Norfolk—NoA
27-54
Steven Burgess
Hertford
36°24'36"
-77°06'06"
42.7
Norfolk—NoA
27-55
Steven Burgess
Hertford
36°21'l8"
-77°07'40"
6.6
Craven—CrA
27-56
Steven Burgess
Hertford
36°21'19"
-77°07'31"
9.8
Craven—CrA
27-57
Steven Burgess
Hertford
36°21'22"
-77°07'21"
12
Craven — CrA
27-58
Steven Burgess
Hertford
36°21'11"
-77°07'17"
4.5
Lenoir—Ln
27-59
Steven Burgess
Hertford
36°21'08"
-77°07'23"
9.0
Lenoir — Ln
27-60
Steven Burgess
Hertford
36°21'03"
-77°07'07"
2
Lenoir — Ln
27-61
Steven Burgess
Hertford
36°21'04"
-77°06'59"
14.9
Craven — CrA
27-62
Steven Burgess
Hertford
36°20'55"
-77°07'02"
3.1
Craven — CrA
27-63
Adam & Wendy Burgess
Steven Burgess
Hertford
36°21'14"
-77°06'55"
14.7
Craven — CrA
27-64
Adam & Wendy Burgess
Steven Burgess
Hertford
36°21'24"
-77°06'50"
29.5
Craven — CrA
28-1
Judith, Allison, & Walter Perry
Hertford
36°19'31"
-77°50'15"
17.6
Norfolk—NoA
28-2
Judith, Allison, & Walter Perry
Hertford
36°19'27"
-76°50'05"
17.5
Norfolk —NoA
28-3
Judith, Allison, & Walter Perry
Hertford
36°19'48"
-76°50'10"
25.1
Norfolk —NoA
28-4
Judith, Allison, & Walter Perry
Hertford
36°19'21"
-76°49'51"
10.8
Wickham — WkA
28-5
Judith, Allison, & Walter Perry
Hertford
36°19'10"
-76°49'34"
9.4
Conetoe — CoB
WQ0012404 Version: 3.0 Attachment B Page 9 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
28-6
Judith, Allison, & Walter Perry
Hertford
36°19'24"
-76°50'24"
20.4
Norfolk—NoA
28-7
Judith, Allison, & Walter Perry
Hertford
36°19'50"
-76°5l'03"
16.0
Norfolk —NoA
28-8
Judith, Allison, & Walter Perry
Hertford
36°19'42"
-76°51'06"
9.2
Goldsboro—GoA
28-9
Judith, Allison, & Walter Perry
Hertford
36°19'42"
-76°5P13"
9.9
Goldsboro —GoA
28-10
Judith, Allison, & Walter Perry
Hertford
36°19'44"
-76°51'18"
1.7
Goldsboro —GoA
28-11
Judith, Allison, & Walter Perry
Hertford
36°19'48"
-76°51'15"
3.7
Craven — CrB
28-12
Judith, Allison, & Walter Perry
Hertford
36°19'47"
-76°51'l1"
3.6
Craven—CrB
28-13
John Lock Mitchell
Walter Perry
Hertford
36° 17'42"
-76°49'37"
8.7
Bonneau — BoB
28-14
John Lock Mitchell
Walter Perry
Hertford
36°17'36"
-76°49'45"
7.0
Bonneau — BoB
28-15
Betty Perry, John Mitchell, Eleanor Lane, Penny
Beasley, & Ken Mitchell
Walter Perry
Hertford
36°17'19"
-76'50'11"
17.4
Craven — CrA
28-16
John Mitchell, Eleanor Lane, Penny Beasley, Ken
Mitchell, & Wiccacon Properties, LLC
Walter Perry
Hertford
36°18'02"
-76°50'23"
18.9
Conetoe — CoB
28-17
Margaret Hall
Walter Perry
Hertford
36°23'01"
-76°56'51"
16.9
Craven — CrA
28-18
Betty Everette Perry
Walter Perry
Hertford
36°17'30"
-76°49'53"
7.4
Craven — CrA
31-1
Ray & Linda Chamblee
Hertford
36°20'42"
-76°55'26"
8.8
Craven — CrA
31-2
Jackie Chamblee
Ray Chamblee
Hertford
36°20'40"
-76°55'20"
9.6
Craven— CrB
31-3
Jackie Chamblee
Ray Chamblee
Hertford
36°20'47"
-76°55'13"
15.9
Craven — CrA
31-4
Ray & Linda Chamblee
Hertford
36°20'43"
-76°55'04"
8.8
Craven — CrA
31-5
Ray & Linda Chamblee
Hertford
36°17'31"
-76°55'16"
5.9
Goldsboro—GoA
32-1
Janice Simmons Sessoms
William H. Sessoms
Hertford
36°17'55"
-76°48'53"
7.0
Wakulla - WaB
32-2
William H. Sessoms
Hertford
36°17'55"
-76°48'42"
30.6
Lynchburg — Ly
32-3
William H. Sessoms
Hertford
36°17'27"
-76°48'38"
5.0
Craven — CrB
32-4
Joyce Ann Sessoms
William H. Sessoms
Hertford
36°18'07"
-76°48'45"
5.0
Bonneau — BoB
32-5
Joyce Ann Sessoms
William H. Sessoms
Hertford
36°17'43"
-76°49'16"
5.5
Lynchburg — Ly
32-6
William H. Sessoms
Hertford
36°17'42"
-76°49'27"
2.7
Lynchburg — Ly
WQ0012404 Version: 3.0 Attachment B Page 10 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
32-7
William H. & Joyce Ann Sessoms
Hertford
36°17'24"
-76°47'58"
28.9
Goldsboro - Go
32-8
William H. & Delores Sessoms
Hertford
36°17'33"
-76°47'23"
23.2
Norfolk —NoB
32-9
William H. & Delores Sessoms
Hertford
36°17'36"
-76°47'36"
13.3
Norfolk—NoB
32-10
William H. & Delores Sessoms
Hertford
36°17'42"
-76°47'34"
7.3
Norfolk NoB
32-11
Wiccacon Properties, LLC
William H. Sessoms
Hertford
36°l7'47"
-76°49'32"
4.3
Craven — CrA
32-12
Ernest Chamblee
William H. Sessoms
Hertford
36°15'23"
-76°49'08"
14.0
Craven — CrA
33-1
William W & Nellie Ward
William Ward
Hertford
36°14'36"
-76°56'23"
3.0
Caroline — CaB
33-2
William W & Nellie Ward
William Ward
Hertford
36°14'51"
-76°5623"
11.9
Craven — CrC2
33-3
William W & Nellie Ward
William Ward
Hertford
36°14'47"
-76°56'21"
15.1
Norfolk—NoB
33-4
William W & Nellie Ward
William Ward
Hertford
36°1448"
-76°56'12"
13.6
Norfolk —NoB
33-5
William W & Nellie Ward
William Ward
Hertford
36°15'10"
-76°56'08"
14.2
Tarboro —TaB
33-6
William W & Nellie Ward
William Ward
Hertford
36°14'43"
-76°56'10"
14.6
Norfolk —NoB
33-7
William W &Nellie Ward
William Ward
Hertford
36°l4'37"
-76°56'08"
5.9
Craven—CrB
33-8
William W & Nellie Ward
William Ward
Hertford
36°14'35"
-76°56'14"
3.0
Craven—CrB
33-9
Michael A. & Deborah Spalding
William Ward
Hertford
36°l4'23"
-76°58'28"
14.2
Craven — CrA
33-10
Michael A. & Deborah Spalding
William Ward
Hertford
36°14'28"
-76°58'27"
8.0
Craven — CrB
33-11
Michael A. & Deborah Spalding
William Ward
Hertford
36°14'26"
-76°58'17"
3.7
Craven - CrB
33-12
Michael A. & Deborah Spalding
William Ward
Hertford
36°1421"
-76°58'17"
2.4
Craven — CrA
33-13
Rosa H. Sessoms
William Ward Hertford
Hertford
36°15'09"
-77°00'47"
25.0
Craven—CrA
33-14
Rosa H. Sessoms
William Ward Hertford
Hertford
36°15'12"
-77°00'36"
6.3
Leaf —Lf
33-15
Rosa H. Sessoms
William Ward
Hertford
36°15'15"
-77°00'29"
2.8
Craven—CrA
33-16
Rosa H. Sessoms
William Ward
Hertford
36°15'20"
-76°00'31"
4.2
Craven — CrA
County Total
Hertford
4,212.3
34-1
Nellie B. Brown
Martin
35°59'36"
-77°20'10"
26.5
Goldsboro — GoA
34-2
Nellie B. Brown
Martin
35°59'30"
-77°20'17"
19.1
Goldsboro — GoA
WQ0012404 Version: 3.0 Attachment B Page 11 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
34-3
Nellie B Brown
Martin
35°59'26"
-77120-17"
3.8
Lynchburg— Ly
34-4
Nellie B Brown
Martin
35°59'20"
-772016"
27.1
Lynchburg— Ly
County Total
Martin
76.5
15-1
J. Elliot Stephenson
Northampton
36°2842"
-772606"
19.2
Lynchburg— Ly
15-2
J. Elliot Stephenson
Northampton
36128'31"
-7712543"
27.3
Craven — CrA
15-3
J. Elliot Stephenson
Northampton
36°28'19"
-772606"
38.0
Caroline — CrB
15-4
J. Elliot Stephenson
Northampton
3612547"
-77125-26"
41.3
Norfolk - NoA
15-5
J. Elliot Stephenson
Northampton
36°26'06"
-772540"
71.3
Gritney— GxB
15-6
J. Elliot Stephenson
Northampton
36°26'17"
-77°2544"
37.1
Gritney—GxB
15-7
J. Elliot Stephenson
Northampton
36°26'12"
-77°2448'
13.1
Norfolk - NoA
15-8
J. Elliot Stephenson
Northampton
36°26'19"
-77°28'39"
35.6
Goldsboro — GoA
15-9
J. Elliot Stephenson
Northampton
36°2649"
-772639"
15.1
Gritney— GxB
15-10
J. Bentley Stephenson
J. Elliot Stephenson
Northampton
36°5121"
-77°26'21"
14.2
Gritney— GxB
15-11
J. Bentley Stephenson
J. Elliot Stephenson
Northampton
36°2644"
-772625"
14.5
Gritney— GxB
15-12
J. Elliot Stephenson
Northampton
36°26'09"
-77°26'36"
9.2
Gritney— GxB
15-13
J. Elliot Stephenson
Northampton
36°26'03"
-772625"
17.2
Gritney— GxB
15-14
J. Elliot Stephenson
Northampton
36°26'21"
-77°26'07"
19.9
Gritney—GxB
15-15
J. Elliot Stephenson
Northampton
36°28'18"
-77°25'54"
24.3
Bonneau—BoB
15-16
J. Elliot Stephenson
Northampton
36°28'24"
-77°2541"
22.8
Bonneau—BoB
15-17
J. Elliot Stephenson
Northampton
36°28'09"
-77°25'52"
33.7
Craven —CrA
18-1
Thomas Williams
Northampton
36°2941"
-77°07'55"
12.0
Craven —CrB
18-2
Thomas Williams
Northampton
36°29'52"
-7708'03"
15.0
Craven —CrA
19-1W
C.C. Woodard
Northampton
36°30'46"
-77°20'27"
31.7
Norfolk NoB
19-2W
C.C. Woodard
Northampton
36°40'47"
-772048"
21.4
Norfolk NoB
r19-3W
C.C. Woodard
Northampton
36°30'36"
-77°20'56"
69.7
Norfolk —NoB
WQ0012404 Version: 3.0 Attachment B Page 12 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
194W
C.C. Woodard
Northampton
36130'27"
-77120-45"
76.7
Norfolk—NoB
19-5W
Cecil Whitehead
C.C. Woodard
Northampton
36°30'18"
-7720'50"
12.8
Norfolk—NoB
19-6W
Amanda Cooke, et al
Cecil Whitehead
Northampton
36°30'32"
-77°20'33"
18.6
Norfolk—NoB
19-7W
C.C. Woodard
Northampton
36°30'18"
-772010"
85.6
Norfolk NoA
19-8W
C.C. Woodard
Northampton
36°30'15"
-77°20'29"
10.9
Norfolk NoB
19-9W
C.C. Woodard
Northampton
36°3O'35"
-772021"
15.7
Norfolk—NoB
19-IOW
C.C. Woodard
Northampton
36°31'25"
-77°20'54"
3.9
Bonneau - BoB
19-11 W
C.C. Woodard
Northampton
36°3l'28"
-77°20'44"
29.5
Bonneau - BoB
19-12W
C.C. Woodard
Northampton
36°3l'43"
-77°20'25"
4.6
Bonneau - BoB
19-13W
C.C. Woodard
Northampton
36°3l'12"
-77°20'10"
7.9
Norfolk NoB
19-14W
C.C. Woodard
Northampton
36°3l'19"
-77°20'10"
9.3
Norfolk—NoB
19-15W
C.C. Woodard
Northampton
36°3l'26"
-7720'10"
11
Norfolk NoB
19-1G
C.C. Woodard
Northampton
36°32'09"
-77°21'07"
48.6
Altavista - AtA
19-2G
C.C. Woodard
Northampton
36°32'17"
-77°2l'22"
13.6
Tarboro - TaB
19-3G
C.C. Woodard
Northampton
36°3226"
-77°21'03"
36.2
Altavista - AtA
194G
C.C. Woodard
Northampton
36°3243"
-7720'57"
42.5
Wickham - WkA
19-5G
C.C. Woodard
Northampton
36°32'39"
-77°21'13"
20.7
Roanoke - Ro
21-1
C.G. Perry
Northampton
36°2548"
-77°20'07"
19.6
Norfolk NoB
21-2
C.G. Perry
Northampton
36°25'39"
-77°20'45"
29.2
Caroline - CaB
21-3
C.G. Perry
Northampton
36°25'38"
-77°20'17"
11.2
Caroline - CaB
21-4
C.G. Perry
Northampton
36°2529"
-77°20'34"
3.3
Norfolk -NoA
21-5
C.G. Perry
Northampton
36°25'31"
-7720'37"
9.3
Norfolk NoB
21-6
C.G. Perry
Northampton
36°2526"
-77°20'31"
4.0
Norfolk NoB
21-7
C.G. Perry
Northampton
36°2525"
-772025"
6.2
Norfolk—NoB
21-8
Robert Jones
Robert Jones
Northampton
36°25'12"
-772028"
50.4
Norfolk —NoA
WQ0012404 Version: 3.0 Attachment B Page 13 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
CertiDcation Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
21-10
C.G. Perry
Northampton
36°2341"
-77°24'16"
44.3
Norfolk NoB
21-11
C.G. Perry
Northampton
36°27'57"
-77°25'57"
33.7
Craven - CrA
21-13
C.G. Perry
Northampton
36°27'40"
-77°25'35"
15.4
Norfolk - NoA
21-14A
C.G. Perry
Northampton
36°2728"
-77°25'40"
13.8
Goldsboro - GoA
21-14B
C.G. Perry
Northampton
36°27'34"
-77°25'39"
18.0
Goldsboro - GoA
21-15
C.G. Perry
Northampton
36°27'34"
-77°25'16"
17.5
Goldsboro - GoA
21-16
C.G. Perry
Northampton
36°2728"
-77°25'16"
5.7
Goldsboro - GoA
21-17
C.G. Perry
Northampton
36°25'40"
-77°2l'08"
4.5
Norfolk - NoA
21-18
Robert Jones
Robert Jones
Northampton
36°2528"
-77°2l'13"
6.7
Norfolk-NoA
21-20
Robert Jones
Robert Jones
Northampton
36°2523"
-77°2l'12"
3.7
Norfolk - NoA
21-21
Robert Jones
Robert Jones
Northampton
36°25'34"
-77°2l'02"
31.4
Norfolk - NoA
21-22
Robert Jones
Robert Jones
Northampton
36°2525"
-77°2l'02"
5.7
Goldsboro - GoA
22-1
Charles J. Stephenson
Northampton
36°2724"
-77°24'58"
23.7
Goldsboro - GoA
22-2
Charles J. Stephenson
Northampton
36°2721"
-77°2449"
19.6
Goldsboro - GoA
22-3
Charles J. Stephenson
Northampton
36°27'17"
-77°24'38"
11.4
Goldsboro - GoA
22-4
Charles L Stephenson
Northampton
36°26'56"
-77°24'31"
9.8
Goldsboro - GoA
22-5
Charles J. Stephenson
Northampton
36°2544"
-77°23'58"
6.9
Goldsboro - GoA
27-1
Neil Burgess
Stephen Burgess
Northampton
W20'00"
-77°12'50"
47.8
Norfolk—NoA
27-2
Neil Burgess
Stephen Burgess
Northampton
36°26'00"
-77°12'36"
56.4
Norfolk—NoA
27-3
Neil Burgess
Stephen Burgess
Northampton
36°25'54"
-77° 12'27"
25.5
Rains — Ra
27-4
Neil Burgess
Stephen Burgess
Northampton
36°2541"
-77°1241"
27.5
Norfolk—NoA
27-5
Neil Burgess
Stephen Burgess
Northampton
36°25'18"
-77°12'39"
16.0
Norfolk-NoA
27-6
Stephen Burgess
Stephen Burgess
Northampton
36°26'07"
-77°11'22"
53.4
Bonneau - BoB
27-7
Judi B. Burgess
Stephen Burgess
Northampton
36°24'20"
-77°13'28"
13.9
Craven - CrA
27-8
Judi B. Burgess
Stephen Burgess
Northampton
36°23'59"
-77°14'10"
17.7
Norfolk—NoB
WQ0012404 Version: 3.0 Attachment B Page 14 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 19, 2021
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
27-9
Lori S. Burgess
Northampton
36°23'56"
-77°13'57"
18.6
Caroline - CaA
27-10
Stephen Burgess
Northampton
36°23'52"
-77°13'51"
20.3
Craven - CrA
27-11
Stephen Burgess
Northampton
36°2342"
-77°13'50"
23.4
Craven - CrA
27-12
Stephen Burgess
Northampton
36°23'39"
-77°13'40"
16.7
Craven- CrA
27-13
Stephen Burgess
Northampton
36°23'34"
-771313"
5.2
Craven - CrA
27-14
Lori S. Burgess
Stephen Burgess
Northampton
36°24'34"
-77°16'04"
14.7
Goldsboro - GoA
27-15
Stephen Burgess
Northampton
36°26'31"
-771710"
6.5
Norfolk NoB
27-16
Stephen Burgess
Northampton
36°2627"
-77°17'02"
5.1
Norfolk NoB
27-17
Stephen Burgess
Northampton
36°26'32"
-771652"
21.9
Norfolk—NoB
27-18
Lori S. Burgess
Northampton
36°26'10"
-77°14'39"
11.1
Goldsboro - GoA
27-19
Lori S. Burgess
Northampton
36°26'18"
-771424"
18.4
Goldsboro - GoA
27-20
Eloise T. Ward
Stephen Burgess
Northampton
36°26'20"
-77°14'17"
12.9
Goldsboro - GoA
27-21
Eloise T. Ward
Stephen Burgess
Northampton
36°26'19"
-771413"
3.8
Goldsboro - GoA
27-22
Eloise T. Ward
Stephen Burgess
Northampton
36°26'34"
-77°14'15"
6.7
Goldsboro - GoA
27-23
Eloise T. Ward
Stephen Burgess
Northampton
36°2749"
-77° 15'27"
32.5
Bonneau - BoB
27-24
Eloise T. Ward
Stephen Burgess
Northampton
36°28'07"
-7715'16"
21.5
Bonneau - BoB
27-25
Eloise T. Ward
Stephen Burgess
Northampton
36°28'04"
-771445"
35.2
Bonneau - BoB
27-26
Eloise T. Ward
Stephen Burgess
Northampton
36°27'53"
-77°1441"
11.5
Norfolk - NoB
27-27
Eloise T. Ward
Stephen Burgess
Northampton
36°28'02"
-77°14'34"
14.4
Norfolk —NoB
27-28
Eloise T. Ward
Stephen Burgess
Northampton
36°27'52"
-77°14'25"
25.3
Norfolk —NoB
27-29
Eloise T. Ward
Stephen Burgess
Northampton
36°2745"
-771417"
60.5
Norfolk —NoB
27-30
Eloise T. Ward
Stephen Burgess
Northampton
36°28'11"
-77°14'51"
5.7
Autryville - AuA
27-31
Eloise T. Ward
Stephen Burgess
Northampton
36°28'16"
-77°14'52"
10.5
Norfolk—NoA
27-32
Eloise T. Ward
Stephen Burgess
Northampton
36°28'21"
-77°14'52"
26.0
Bonneau — BoB
27-33
Eloise T. Ward
Stephen Burgess
Northampton
36°2821"
-77°14'42"
9.9
Norfolk —NoA
WQ0012404 Version: 3.0 Attachment B Page 15 of 16

ATTACHMENT B - Approved Land Application Sites
CF Nitrogen, Inc.
Certification Date: February 18, 2022
Permit Number: WQ0012404 Version: 3.0
Site/
Field
Owner
Lessee
County
Latitude
Longitude
Net Acreage
Dominant Soil Series
Footnotes
27-34
Eloise T. Ward
Stephen Burgess
Northampton
36°28'26"
-77° 14'30"
17.6
Bonneau BoB
27-35
Eloise T. Ward
Stephen Burgess
Northampton
36°28'30"
-77°14'18"
9.1
Goldsboro —GoA
27-36
Eloise T. Ward
Stephen Burgess
Northampton
36°28'24"
-77° 13'S7"
9.3
Autryville AuA
27-37
Eloise T. Ward
Stephen Burgess
Northampton
36°28'23"
-77°14'12"
17.2
Autryville—AuA
27-38
Eloise T. Ward
Stephen Burgess
Northampton
36°28'10"
-77°14'09"
3.0
Norfolk - NoA
27-39
Kevin B. Burgess
Stephen Burgess
Northampton
36°26'40"
-77° 12'40"
20.6
Norfolk - NoB
27-40
Kevin B. Burgess
Stephen Burgess
Northampton
36°26'33"
-77°12'35"
21.0
Norfolk -NoB
27-41
Stephen Burgess
Northampton
36°27'33"
-77°11'45"
9.8
Norfolk-NoB
27-42
Stephen Burgess
Northampton
36°27'43"
-77°11'32"
93.5
Bonneau—BoB
27-43
Stephen Burgess
Northampton
36°27'35"
-77°1F21"
17.7
Norfolk—NoB
27-44
Stephen Burgess
Northampton
36°27'43"
-77°11'l1"
29
Bonneau—BoB
27-45
Stephen Burgess
Northampton
36°27'49"
-77°11'04"
18
Norfolk—NoB
27-46
Stephen Burgess
Northampton
36°27'27"
-77°11'18"
13.9
Bonneau—BoB
27-47
Stephen Burgess
Northampton
36°27'36"
-77°11'06"
20.8
Bonneau - BoB
27-48
Kevin B. Burgess
Stephen Burgess
Northampton
36°27'31"
-77°10'15"
14.8
State— StA
27-49
Kevin B. Burgess
Stephen Burgess
Northampton
36°27'27"
-77°]0'07"
6.1
Tarboro —TaB
27-50
Kevin B. Burgess
Stephen Burgess
Northampton
36°27'38"
-77°09'59"
17.9
Altavista— AtA
27-51
Kevin B. Burgess
Stephen Burgess
Northampton
36°27'38"
-7709'40"
52.7
Tarboro—TaB
27-65
Bobby Bridges
Neil Bridges
Northampton
36°25'50"
-77°15'01"
67.3
Bonneau BoB
27-66
Neil & Donna B. Burgess
Northampton
36°24'50"
-77° 15'10"
18.1
Norfolk - NoB
27-67
Fannie Bryant (Maria R. Jones Trustee)
Stephen Burgess
Northampton
36°27'46"
77° 10'47"
33.7
Bonneau - BoB
27-68
Martha Pearlman
Northampton
36°30'5"
77°11'l4"
58.0
Goldsboro - GoA
27-69
Ronald Woodard
Northampton
36°29'56"
771l'l8"
42.2
Gritney -GXB
27-70
Ronald Woodard
Northampton
36°28'54"
77°12'25"
85.4
Lynchburg - Ly
27-71
Stephen Burgess
Northampton
36°27'29"
77°15'27"
61.8
Bonneau — BoB
27-72
Stephen Burgess
Northampton
36°27'28"
77°15'5"
39.7
Bonneau—BoB
27-73
Stephen Burgess
Northampton
36°27'11"
779514"
74.9
Norfolk -NoA
County Total
Northampton
3,026.2
Permit Total
7,968.6
WQ0012404 Version: 3.0 Attachment B Page 16 of 16

APPENDIX E
Landowner Agreement Attachments and
Lessee Agreement Attachments

13. Within the units of the Division's nitrogen enriched- ground water land application programs permit, the
Permittee will deterinine nitrogen enriched ground water application rates and schedules based on crop
patterns and the predominant soil series of each respective field. In no case shall more Nitrogen Enriched
Groundwater be applied than was requested by the landowner, his representative, or by the lessee.
14. Specific nitrogen enriched ground water land application area boundaries sltaiI be clearly marked on the land
application sites) by the Permittee and/or his representative prior to and during a nitrogen enriched ground
water land application event.
IS. The Permittee shall provide an annual summary of the application activities ZO tine owner each year, In the
event there is no activity an a site during a given year, the annual summary document is not required to be
provided to the owner -
It. ALTERNATIVES FOR WATER SUPPLY WELLS INSIDE THE COMPLIANCE BOUNDARY:
I5A NCAC 02pl. 0107(d) prohibits water supply wells within the compliance boundary ofany site . However,
I iA NCAC 42"f .4145(h) allows the compliance boundary to be placed closer to tite waste disposal area, such
that the water supply well is situated outside of the compliance boundary provided the groundwater standards can
he rile[ at tine newly -established compliance boundary. Please mark one of the fallowing;
❑ A rc-defined compliance boundary is needed far field(s) ID:
(Please include the rationale for the requested re -location of the compliance boundary and attach a map
showing the newly proposed compliance boundary to the application package)
❑ A re -defined compliance boundary is approved as part of this agreement.
Landowner's Certification:
❑ I certify that l am a deeded landowner o f t h c above -referenced I a n d application sites) all am authorized to make
decisions regarding the use of the Iand application sites) on behalf of other deeded landowners OR that T am
otherwise authorized, through a power of attorney or other legal delegation, to make decisions regarding the use
of the land application site(s) on behalf of the deeded landowners. I certify that I have rear] this Agreement,
understand the stipulation~, alternatives for water supply wells inside the compliance boundary, and restrictions,
and do hereby grant permission to the Permittee to land apply nitrogen enriched ground water to the land
application site(s) as specified herein. 'T'his document shall be used in conjunction with the Lessee Agreement
Attachment form (FORM. LAA 01072016), which describes the responsibilities and obligations of the leasing
pasty(s).
Landowner name: &
Landowner address: J�� - _�C4-
—
City: —C7r—
Ilume/business phone: 25 Z 't5 -Cell phone: _
Signature:
Date:
Permittee's Certification:
❑ 1 certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as
specified herein.
Sighing official ntune;
Signature: --
* * * END OF FORM: LOAA "�*
Date:
FORM: CF industries LOAA 01072016 Page 3 of 3
Attachment i)

13. Within the limits of the Division's nitrogen enriched. ground water land application program permit, the
Permittee will determine nitrogen enriches} ground water application rates and schedules based on crop
patterns and the predominant soil series of each respective field. in no case shall more Nitrogen Enriched
Groundwater be applied tltatl was requested by the landowner, his representative, or by the lessee.
14. Specific iitrogen cm- icIted ground water land application area boundaries sltaiI be clearly marked on the land
application site(s) by the Permittee and/or his representative prior To and during a nitrogen enriched ground
water land application event.
l5- The Permittee shall provide an annual summary of the application activities to the owner each year. In the
event there is no activity on a site during a given year, the annual summary document is not required to be
provided to the owner.
ti. ALTERNATiVES FOR WATER SUPPLY WELLS INSIDE T11E COMPLIANCE i30UNDARV:
1.5A NCAC 02pi- .0107(d) prohibits water supply wells within the compliance boundary of'any site . 110wever,
15A NCAC 02T .0105(h) allows the compliance boundary to be placed closer to the waste disposal area, such
that the water supply well is situated outside of'the compliance boundary provided the groundwater standards can
be inet at the newly -established compliance boundary. Please mark one of the following;
❑ A re -defined compliance boundary is needed For field(s) I1):
(Pleas: include the rationale for the requested re -location of the compliance boundary and attach a map
showing the newly proposed compliance boundary to the application package)
❑ A re -defined compliance boundary is approved as part of this agreement.
Landowner's Certifieation:
❑ I certify that I am a deeded landowner of the: above -referenced land application site(s) and ant authorized to make
decisions regarding the use of the land application sitc(s) on behalf of other deeded landowners OR that I am
otherwise authorized, through it power ofattorney or other legal delegation, to make decisions regarding the use
of the land application sites) on behalf of the deeded landowners. I certify that I have read this Agreement,
understand the stipulations, alternatives for water supply wells inside the compliance boundary, and restrictions,
and d❑ hereby grant permission to the Perrnittee to land apply nitrogen enriched ground water to the land
application site(s) as specified herein. This document shall he used in conjunction with the Lessee Agreement
Attachment [form (FORM. LA 01072016), which describes the responsibilities and obligations of the leasing
pasty(s).
Landowner name: Ken 1! van5
Landowner address. 4o z-
city:
llome/business phnTie:
— - State: _ N C_ - - yip: _ 2. F<_ _qV
Cell phone:, ZS 7- - x o e.t, Ltd
Signature: Date: /9,61, )r
Permittee's Certification:
❑ i certify that l have read this Agreement and do hereby agree to abide by the stipulations and restrictions as
specified herein.
Signing official narm
Signature:
"** E.iI) OF FORM. LOAA ***
Date:
1=OPM: CF Industries I,OAA 0I072015 Page 3 of 3 Attachment D

13. Within the limits of the Division's nitrogen enriched- ground water land application program permit, the
Pennittee will determine nitrogen enriched ground water application rates and schedules based on crop
patterns and the predominant soil series of each respective field. in no case shall more Nitrogen Enriched
Groundwater be applied than was requested by the landowner, his representative, or by the lessee.
14. Specific nitrogen enriched ground water land application area boundaries shall be clearly marked on the land
application site(s) by the Pennittee andJor his representative prior to and during a nitrogen enriched ground
water land application event.
15- 3'he Pennittee shall provide an annual summary of'the application activities to the owner each year. In the
event there is no activity on a site during a given year, the annual summary document is not required to be
provided to the owner.
If. ALTERNATIVISS FOR WATER SUPPLY WELLS INSIDE TIME COMPLIANCE BOUNDARY:
l5A NCAC 02p1..0107(d) prohibits water supply wells within the compiiance boundary of any site . However,
I5A NCAC. 02T .0t05(h) allows the compliance boundary to be placer! closer to the waste disposal area, such
that the water supply well is situated outside of the compliance boundary provided the groundwater standards can
be met at the newly -established compiiance boundary. Please mark one of the following -,
❑ A re -defined compliance boundary is needed l'or freld(s) ID:
(Please include the rationale for the requested re -location of the compliance boundary and attach a trap
showing the newly proposed compliance boundary to the application package)
❑ A re -defined compliance boundary is approved as part of this agreement.
Landowner's Ccrtifieation:
❑ I certify that I am a deeded landowner of the above -re fe ren cc d land application sites) and am authorsa_ed to make
decisions regarding the use of the land application sitc(s) on behalf of other deeded landowners OR that I am
otherwise authorized, tirrough a power of'attorney or other legat delegation, to make decisions regarding the use
of the land application sites) on behalf of fire deeded landowners. 1 certify that l have read this Agreement,
understand the stipulations, alternatives for water supply weiis inside the compliance boundary, and restrictions,
and do hereby grant permission to the Perinittec to land apply nitrogen enriched ground water to tite land
application site(%) as specified herein. `i'his document shall be used in conjunction with the Lessee Agreement
Attachment tbrm (l"ORM: LAA 01072016), which describes the responsibilities and obligations of the leasing
party(s).
Landowner name: �+� '}P�
Landowner address:
s: C_ (/1.l
City: _.� '1— State: IVC zip:
ilome/business phone: — �.��`��'� � _ Cell phone:_
Date: 3 zZ
Signature. -
permittee's Certification:
❑ 1 certify that. l have read this Agrcement and do hereby agree to abide by the stipulations and restrictions as
specified herein.
Signing official name;
Signature:
*** Eli❑ OF FORM: LOAA °**
Date:
FORM: CF industries LOAA 41072016 Page 3 of 3 Attachment I)

N
W E
S
I FA
�aY
Legend
House
A Structure
Well
Ditch
1
Buffer .
❑ Field Boundary
., FIELD NET AC. SOIL
❑ Property Boundary �' 4 17.63 Craven (CrA)
Scale: 1 inch = 400 feet SITE 35 - LEE BRITT Figure
Drawn by: DM SOIL PLUS Field 4 Buffer Map
Reviewed by: JB Harrellsville, North Carolina
Date: August 2022 Soil Plus Project # 202207-CF

N
W E
S
I low'"
1
Legend
❑ Field Boundary
Property Boundary
FIELD NET AC.
SOIL
Soil Boundary
4 17.63
Craven (CrA)
Scale: 1 inch = 400 feet
SITE 35 - LEE BRITT
Figure
Drawn by: DM
SOIL PL Us
Field 4 Soil Map
Reviewed by: JB
Harrellsville, North Carolina
Date: August 2022
Soil Plus Project # 202207-CF

APPENDIX F
Laboratory Analytical Reports

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 11, 2022
Ed Henriques
S&ME, Inc.
8646 West Market Street
Suite 105
Greensboro, NC 27409
RE: Project: CIF NITROGEN
Pace Project No.: 92586310
Dear Ed Henriques:
Enclosed are the analytical results for sample(s) received by the laboratory on February 04, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
a*a-
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
cc: Diane Diks, CF Industries
REPORT OF LABORATORY ANALYSIS
r
e
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CF NITROGEN
Pace Project No.: 92586310
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: CF NITROGEN
Pace Project No.: 92586310
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92586310001 112634
EPA 350.1 Rev 2.0 1993
SRS
1
PASI-E
EPA 6010D
IDS
5
PASI-A
EPA 9040C
YEG
1
PASI-A
TKN+NO3+NO2 Calculation
EWS
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
SMT
1
PASI-A
EPA 365.1 Rev 2.0 1993
KDF1
1
PASI-A
PASI-A = Pace Analytical Services -Asheville
PASI-E = Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: CF NITROGEN
Pace Project No.: 92586310
Sample: 112634 Lab ID: 92586310001 Collected: 02/03/22 11:56 Received: 02/04/22 10:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia EDN
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Eden
Nitrogen, Ammonia
241 mg/L 2.5
25
02/09/22 15:51
7664-41-7
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method:
EPA 3010A
Pace Analytical Services -Asheville
Aluminum
1240 ug/L 100
1 02/09/22 01:01
02/09/22 11:23
7429-90-5
Calcium
42600 ug/L 100
1 02/09/22 01:01
02/09/22 11:23
7440-70-2
Magnesium
12600 ug/L 100
1 02/09/22 01:01
02/09/22 11:23
7439-95-4
Potassium
38000 ug/L 5000
1 02/09/22 01:01
02/09/22 11:23
7440-09-7
Sodium
31200 ug/L 5000
1 02/09/22 01:01
02/09/22 11:23
7440-23-5
9040 pH
Analytical Method: EPA 9040C
Pace Analytical Services -Asheville
pH at 25 Degrees C
6.5 Std. Units 0.10
1
02/07/22 14:08
H3
Total Nitrogen Calculation
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services -Asheville
Total Nitrogen
525 mg/L 0.52
1
02/11/22 12:01
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Kjeldahl, Total
268 mg/L 25.0
50 02/09/22 18:41
02/10/22 06:42
7727-37-9
353.2 Nitrogen, NO2/NO3 pres.
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
256 mg/L 4.0
100
02/07/22 15:59
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
3.5 mg/L 0.050
1 02/09/22 23:33
02/10/22 12:10
7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CF NITROGEN
Pace Project No.: 92586310
QC Batch: 677047 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92586310001
METHOD BLANK: 3543314
Associated Lab Samples: 92586310001
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 3543315
Parameter Units
Nitrogen, Ammonia mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 02/09/22 14:28
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 4.9 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3543316 3543317
MS MSD
92586037001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.11 5 5 6.1 6.1 120 119 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3543318 3543319
MS MSD
92586037002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 6.0 6.0 120 120 90-110 0 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 5 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CF NITROGEN
Pace Project No.: 92586310
QC Batch: 676917 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92586310001
METHOD BLANK: 3542975
Matrix:
Water
Associated Lab Samples: 92586310001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Aluminum
ug/L
ND
100
02/09/2210:51
Calcium
ug/L
ND
100
02/09/22 22:18
Magnesium
ug/L
ND
100
02/09/2210:51
Potassium
ug/L
ND
5000
02/09/2210:51
Sodium
ug/L
ND
5000
02/09/2210:51
LABORATORY CONTROL SAMPLE:
3542976
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Aluminum
ug/L
5000
4490
90
80-120
Calcium
ug/L
5000
5040
101
80-120
Magnesium
ug/L
5000
4370
87
80-120
Potassium
ug/L
5000
4880J
98
80-120
Sodium
ug/L
5000
5050
101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3542977
3542978
MS
MSD
92586178001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
ug/L
19100
5000
5000
25100
28500
120
188
75-125
13 M1
Calcium
ug/L
20700
5000
5000
25000
26300
85
111
75-125
5 E
Magnesium
ug/L
13800
5000
5000
18100
19500
86
115
75-125
7
Potassium
ug/L
8190
5000
5000
13400
15200
103
141
75-125
13 M1
Sodium
ug/L
6880
5000
5000
12100
12800
105
119
75-125
6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 6 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CF NITROGEN
Pace Project No.: 92586310
QC Batch: 676404 Analysis Method: EPA 9040C
QC Batch Method: EPA 9040C Analysis Description: 9040 pH
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92586310001
SAMPLE DUPLICATE: 3540342
92585725001
Dup
Parameter
Units
Result
Result RPD Qualifiers
pH at 25 Degrees C
Std. Units
6.9
6.9 0 H3
SAMPLE DUPLICATE: 3540343
92585984002
Dup
Parameter
Units
Result
Result RPD Qualifiers
pH at 25 Degrees C
Std. Units
6.8
7.2 4 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CF NITROGEN
Pace Project No.: 92586310
QC Batch: 677054 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92586310001
METHOD BLANK: 3543369
Associated Lab Samples: 92586310001
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
LABORATORY CONTROL SAMPLE: 3543370
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.50 02/10/22 05:09
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
10 10.0 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3544476 3544477
MS MSD
92585622001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 0.68 10 10 8.1 8.2 74 75 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3544478 3544479
MS MSD
92585627001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 38.1 10 10 53.8 57.3 158 192 90-110 6 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CF NITROGEN
Pace Project No.: 92586310
QC Batch: 676357 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92586310001
METHOD BLANK: 3540146
Associated Lab Samples: 92586310001
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
LABORATORY CONTROL SAMPLE: 3540147
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.040 02/07/22 15:17
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 2.4 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3540148 3540149
MS MSD
92585653001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.85 2.5 2.5 2.9 3.0 82 85 90-110 2 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3540150 3540151
MS MSD
92585656001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L ND 2.5 2.5 2.4 2.4 95 95 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CF NITROGEN
Pace Project No.: 92586310
QC Batch: 677188 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92586310001
METHOD BLANK: 3544399
Associated Lab Samples: 92586310001
Parameter Units
Phosphorus mg/L
LABORATORY CONTROL SAMPLE: 3544400
Parameter Units
Phosphorus mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.050 02/10/2211:51
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 2.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3544401 3544402
MS MSD
92585145001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.5 2.6 100 101 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3544403 3544404
MS MSD
92585145002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.5 2.5 102 101 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 15

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALIFIERS
Project: CF NITROGEN
Pace Project No.: 92586310
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CF NITROGEN
Pace Project No.: 92586310
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92586310001
112634
EPA 350.1 Rev 2.0 1993
677047
92586310001
112634
EPA 3010A
676917
EPA 6010D
676936
92586310001
112634
EPA 9040C
676404
92586310001
112634
TKN+NO3+NO2
677699
Calculation
92586310001
112634
EPA 351.2 Rev 2.0 1993
677054
EPA 351.2 Rev 2.0 1993
677250
92586310001
112634
EPA 353.2 Rev 2.0 1993
676357
92586310001
112634
EPA 365.1 Rev 2.0 1993
677188
EPA 365.1 Rev 2.0 1993
677279
Date: 02/11/2022 12:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 15

n
Analytical'
Document Name:
Sample Condition Upon Receipt (SCUR)
Document Revised: November 15, 2021
Page 1 of 2
Document No,:
F-CAR-CS-033-Rev.09
Issuing Authority:
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Huntersville ❑ Raleigh❑ Mecharticsville❑ Atlanta❑ Kernersville❑
Courier:
❑ Commercial
Custody Seal Present?
Client Name: Project q: W41t : 925V631O
❑Fed Ex ❑UPS ❑USPs []Client 11111111❑Pace III I 1111111111
❑Other:
92588;310
❑Yes [:]No Seals Intact? []Yes ❑No
Date/InitlalsPerson Examining Contents:
• c: � E i
Packing Material: ❑Bubble Wrap ❑bubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: []Yes[--]No❑N/A
0 IR Gun TD: �Z [ �(�•�� ❑wet [:]Blue []None
Type of ice:
Correction Factor:
Cooler Temp: --L-L Add/Subtract (°C) Temp should be above freezing to VC
❑Samples out of temp criteria. Samples on ice, cooling process
CoolerTemp-Corrected I'C1: ? . :: - itsNgon
USDA Regulated Sall (❑ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source {internationally,
Ilyes FIND in,1 ,4inoW.-1i d o, . o,. n I-`I� - r-t'i
Comments/Dlserepancy: y
Chain of Custody Present?
❑Yes
❑No
[I NIA
1.
Samples Arrived within Hold Time?
❑Yes
[]NO
N/A
2.
Short Hold Time Analysis (02 hr.)?
MYeS
No
N/A
3.
Rush Turn Around Time Requested?
❑Yes
ON
N/A
4,
Sufficient Volume?
Des
❑No
El N/A
S.
Correct Containers Used?
-Pace Containers Used?
[]Yes
Des
❑No
❑No
[I N/A
N/A
5,
Containers Intact?
- yes
No
N/A
7.
Dissolved analysis: Samples Field Filtered?
Yes
❑No
[]N/A
a.
Sample Labels Match COO
-includes Date/Time/ID/Analysis Matrix:
[lies
❑No
[-]N/A
9.
Headspace In VbA Vials (>5.6mm)?
[_-]Yes
❑No
_. NIA
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
uYes
❑No
No
❑N/A
N A
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Lot ID of split containers;
Date:
Date:
Field Data Required? ❑Yes [:]NO
Page 13 of 15

Document Name:
Document Revised: November 15, 2021
_ aceAnalytical
Sample Condition Upon Receipt {SCUR)
Page 2 of 2
Document No.:
Issuing Authority:
F-CAR-05.033-13ev.48
Pace Carolinas Quality Office
*Check mark top half of box If pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHS
"Bottom half of box is to list number of bottles
Project W01t ` 92',5863 1 0
PM: A11B Due Date: 02/11/22
CLIEN•I' : 92—SBME Gbor
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
Amount of Preservative
Lot k
adjusted
added
Nate: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Cerlificatlon Office (I.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 14 of 15

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SAMPLETYPE (G-GRAB C-COMP)
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Page 15 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
May 16, 2022
Ed Henriques
S&ME, Inc.
8646 West Market Street
Suite 105
Greensboro, NC 27409
RE: Project: CIF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
Dear Ed Henriques:
Enclosed are the analytical results for sample(s) received by the laboratory on April 28, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
a*a.
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
cc: Diane Diks, CF Industries
REPORT OF LABORATORY ANALYSIS
r
e
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: CF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: CF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92601766001 114466
EPA 350.1 Rev 2.0 1993
AMI
1
PASI-E
EPA 601 OD
SBW
5
PASI-A
EPA 9040C
SMS
1
PASI-A
TKN+NO3+NO2 Calculation
DMN
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-E = Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: CF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
Sample: 114466 Lab ID: 92601766001 Collected: 04/28/22 11:16 Received: 04/28/22 16:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia EDN
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Eden
Nitrogen, Ammonia
250 mg/L 5.0
50
05/04/22 13:48
7664-41-7
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method:
EPA 3010A
Pace Analytical Services -Asheville
Aluminum
380 ug/L 100
1 05/06/22 13:58
05/11/22 21:15
7429-90-5
Calcium
54000 ug/L 100
1 05/06/22 13:58
05/11/22 21:15
7440-70-2
M1
Magnesium
16100 ug/L 100
1 05/06/22 13:58
05/11/22 21:15
7439-95-4
M1
Potassium
37300 ug/L 5000
1 05/06/22 13:58
05/11/22 21:15
7440-09-7
M1
Sodium
34300 ug/L 5000
1 05/06/22 13:58
05/11/22 21:15
7440-23-5
M1
9040 pH
Analytical Method: EPA 9040C
Pace Analytical Services -Asheville
pH at 25 Degrees C
7.0 Std. Units 0.10
1
05/02/22 13:48
H3
Total Nitrogen Calculation
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services -Asheville
Total Nitrogen
506 mg/L 0.040
1
05/05/22 15:50
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Kjeldahl, Total
267 mg/L 25.0
50 05/04/22 05:36
05/05/22 03:44
7727-37-9
353.2 Nitrogen, NO2/NO3 pres.
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
238 mg/L 2.0
50
05/04/22 11:49
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
2.3 mg/L 0.050
1 05/04/22 17:41
05/04/22 21:40
7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 11:45 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CIF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
QC Batch: 695694 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92601766001
METHOD BLANK: 3633520
Associated Lab Samples: 92601766001
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 3633521
Parameter Units
Nitrogen, Ammonia mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 05/04/22 09:43
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 5.0 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3633522 3633523
MS MSD
92601660002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.12 5 5 5.0 5.0 98 98 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3633524 3633525
MS MSD
92601660006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.15 5 5 5.1 5.1 99 99 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 11:45 AM without the written consent of Pace Analytical Services, LLC.
Page 5 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CIF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
QC Batch: 696502 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92601766001
METHOD BLANK: 3637332
Matrix:
Water
Associated Lab Samples: 92601766001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Aluminum
ug/L
ND
100
05/11/2219:53
Calcium
ug/L
ND
100
05/11/2219:53
Magnesium
ug/L
ND
100
05/11/2219:53
Potassium
ug/L
ND
5000
05/11/2219:53
Sodium
ug/L
ND
5000
05/11/2219:53
LABORATORY CONTROL SAMPLE:
3637333
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Aluminum
ug/L
5000
4940
99
80-120
Calcium
ug/L
5000
5030
101
80-120
Magnesium
ug/L
5000
4960
99
80-120
Potassium
ug/L
5000
4910J
98
80-120
Sodium
ug/L
5000
5040
101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3637334
3637335
MS
MSD
92601766001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
ug/L
380
5000
5000
5460
4920
102
91
75-125
10
Calcium
ug/L
54000
5000
5000
56800
55400
57
30
75-125
2 M1
Magnesium
ug/L
16100
5000
5000
20500
19800
88
73
75-125
4 M1
Potassium
ug/L
37300
5000
5000
41500
40300
85
60
75-125
3 M1
Sodium
ug/L
34300
5000
5000
38100
36900
76
50
75-125
3 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 11:45 AM without the written consent of Pace Analytical Services, LLC.
Page 6 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CIF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
QC Batch: 695290 Analysis Method: EPA 9040C
QC Batch Method: EPA 9040C Analysis Description: 9040 pH
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92601766001
SAMPLE DUPLICATE: 3631686
92600746001
Dup
Parameter
Units
Result
Result RPD Qualifiers
pH at 25 Degrees C
Std. Units
6.8
6.8 0 H3
SAMPLE DUPLICATE: 3631687
92601766001
Dup
Parameter
Units
Result
Result RPD Qualifiers
pH at 25 Degrees C
Std. Units
7.0
7.0 0 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 11:45 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CIF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
QC Batch: 695518 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92601766001
METHOD BLANK: 3632715
Associated Lab Samples: 92601766001
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
LABORATORY CONTROL SAMPLE: 3632716
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.50 05/05/22 02:23
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
10 9.6 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3632717 3632718
MS MSD
92601295003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 0.73 10 10 10.8 11.2 101 104 90-110 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 11:45 AM without the written consent of Pace Analytical Services, LLC.
Page 8 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CIF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
QC Batch: 695525 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92601766001
METHOD BLANK: 3632735
Associated Lab Samples: 92601766001
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
LABORATORY CONTROL SAMPLE: 3632736
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.040 05/04/22 09:59
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 2.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3632737 3632738
MS MSD
92601726012 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.12 2.5 2.5 2.5 2.5 94 94 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3632739 3632740
MS MSD
92601726013 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.12 2.5 2.5 2.6 2.6 98 98 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 11:45 AM without the written consent of Pace Analytical Services, LLC.
Page 9 of 15

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: CIF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
QC Batch: 696010 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92601766001
METHOD BLANK: 3635084
Associated Lab Samples: 92601766001
Parameter Units
Phosphorus mg/L
LABORATORY CONTROL SAMPLE: 3635085
Parameter Units
Phosphorus mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.050 05/04/22 21:22
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 2.5 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3635086 3635087
MS MSD
92600641001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 1.9 2.5 2.5 4.5 4.6 106 109 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3635088 3635089
MS MSD
92600760002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 2.3 2.5 2.5 5.0 5.0 108 112 90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 11:45 AM without the written consent of Pace Analytical Services, LLC.
Page 10 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: CF Nitrogen 21-1218, Ph P1
Pace Project No.: 92601766
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 11:45 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 15

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
CF Nitrogen 21-1218, Ph P1
92601766
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92601766001
114466
EPA 350.1 Rev 2.0 1993
695694
92601766001
114466
EPA 3010A
696502
EPA 6010D
696635
92601766001
114466
EPA 9040C
695290
92601766001
114466
TKN+NO3+NO2
696373
Calculation
92601766001
114466
EPA 351.2 Rev 2.0 1993
695518
EPA 351.2 Rev 2.0 1993
696131
92601766001
114466
EPA 353.2 Rev 2.0 1993
695525
92601766001
114466
EPA 365.1 Rev 2.0 1993
696010
EPA 365.1 Rev 2.0 1993
696098
Date: 05/16/2022 11:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 15

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Document Name: Document Revfsed: November 15, 2021
I
Sample Condition Upon Receipt (SCUR) Page 1 of 2
.� aCBARa�ftlGc7� Document No.: Issuing Authority:
F-CAR-CS-033-Rev.0S Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Fluntersville ❑ Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville[�
Client Name:
Courier: ❑Fed Fx �/ +`f `❑UPS ❑U5PS c lProject 4:
ent
❑ Commercial ❑Pace ❑Other;
Custody5eal Present? ❑Yes [�o Seals Intact? Dyes ❑ oN r
Date/Initials Person Examining Contents: r
Packing Material: ❑Bubble Wrap ❑Bubble Bags None ❑ Other Biological Tissue Frozen?
Thermometer: ❑Yes [-]NoN/A
FT I R Gun ID:�oUZ ❑wet ❑Blue ❑None
3.1 Type of I e:
Correction Factor:
Cooler Temp: Add/Subtract (°Cj Temp should be above freezing to fi"C
❑Samples out of temp criteria. Samples an ice, cooling process
Cooler Temp Corrected (°C): I has begun
U5DA Regulated Soil ( /A, water sample)
Did samples on to in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
Dyes Na Induding Hawaii and Puerto Rical? ❑Yes ❑No
Comments/ Discre ciancv:
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (<72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Fiftered?
Sample Labels Match COC?
-Includes Date/Time/JD/Analysis Matrix:
Headspace in VOA Vials (55-Gmm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
IYes LINO IJN/A 1.
Yes ❑Na ❑N/A 2.
i
Yes [-IN. ❑N/A 3.
Yes /QNo ❑N/A 1 4
Yes
❑No
❑N/A
5.
Yey
❑No
❑N/A
15,es
[_]No
❑N/A
Yes
❑No
[-]N/A
7,
Yes
[]NO
N/A
S.
Yes
[-]No
❑N/A
g,
❑Yes [-]No
IlYes I-lNo
A 10.
A 11.
Date/Time:
Lot ID of split containers:
Date:
Date:
Field Data Required? ❑Yes�{��
Page 14 of 15

I
:
F-Cn,;-05-C-3-Re;,C'_
`C h. -2 Z 3 tc, h3!r'cf LcX c PH or d2ci,ICIir,aticn is Pro;2c,
v2'i ;e 2 ti':I_,„ Ch2 2.C=^`.37C2 ra-7, for' p'252'Va icln
5-a M.^. I2S.
C--, Ci; a Ere3_e,(.v.1_e)
"Sct'cl� ha!`ccx is tc Ii5; rull,^ : er of b0.t'25
z
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9-1�
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>
•: ••' •� i i � I V� V' Vi I NI I I I I � \I �I I
N -H
J
i
pH Adjustment Lo; for Preserved 5ampfes
ample ID pH upcn ri!czip; Date prasarva Lion adjusted Timei I pre�zrr3.ion
adjusted
Anount of Rreservativ2
added
I I �
F
is a asrrepa-;cy a�z[r`nd Ca-c!�r,,; cc^-el;ance sam�le5, a [avy cf t^i5 fc�-r'rrL' �.? seat to tce far;^ CrcSr.a CE;,',?
Cc' nulc,, ir[orre[: prese^,a:,4e, out of temp, irccrreC' [antair.ers.
Page 15 of 15

Waypointo
ANALYTICAL
8/16/2022
Soil Plus, LLC
Joyce Barrett
P.O. Box 1396
Oxford, NC, 27565
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Ref: Analytical Testing
Revised Report Number: 22-213-9002 (Original Report 22-213-0002)
Project Description: CF Ind.
Dear Joyce Barrett:
Waypoint Analytical Virginia, Inc. received sample(s) on 8/1/2022 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
TOWIT Mt Gram/
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 5

(2)
Waypoint.
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax
804-271-6446
ANALYTICAL
www.waypointanalytical.com
Sample
Summary Table
Report Number: 22-213-9002
Client Project Description: CF Ind.
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
58780
CF 072722
Aqueous
07/27/2022 15:00
08/01/2022
SM-4500-111-13C
WP MTN
58780
CF 072722
Aqueous
07/27/2022 15:00
08/01/2022
SM-4500-NH3C-TKN
WP MTN
58780
CF 072722
Aqueous
07/27/2022 15:00
08/01/2022
4500NO3F-2011
WP MTN
58780
CF 072722
Aqueous
07/27/2022 15:00
08/01/2022
6010D
WP MTN
58780
CF 072722
Aqueous
07/27/2022 15:00
08/01/2022
9045D
WP MTN
58780
CF 072722
Aqueous
07/27/2022 15:00
08/01/2022
SM-2540B
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 2 of 5

Waypoint.0
ANALYTICAL
04596
Soil Plus, LLC
Project CF Ind.
Joyce Barrett
P.O. Box 1396
Information
Oxford , NC 27565
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Original Report Date : 08/09/2022
Revised Report Date: 08/16/2022
Received : 08/01/2022
Report Number : 22-213-9002 REPOR T OF A NA L YSIS
Lab No : 58780 Matrix: Aqueous
Sample ID : CF 072722 Sampled: 7/27/2022 15:00
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Total Solids
Total Kjeldahl Nitrogen
Phosphorus
Potassium
Calcium
Magnesium
Sodium
Nitrate+Nitrite-N
pH
Test
749
m9/L
216
mg/L
3.09
mg/L
33.0
mg/L
47.9
m9/L
14.2
mg/L
27.4
m9/L
243
mg/L
6.9
s.u.
Results Units
21
1
08/03/22 17:27
ADM
SM-2540B
5.00
1
08/08/22 07:00
JPJ
')M-4500-NH3C-TKP
0.100
1
08/03/22 23:24
EAL
6010D
0.500
5
08/04/22 14:26
EAL
6010D
0.500
1
08/03/22 23:24
EAL
6010D
0.100
1
08/03/22 23:24
EAL
6010D
0.500
1
08/03/22 23:24
EAL
6010D
10.0
100
08/08/22 14:47
ZBD
4500NO3F-2011
1
08/16/22 00:00
DRS
9045D
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Ammonia Nitrogen 40.9 mg/L 1.00
Aluminum 0.831 m9/L 0.100
Qualifiers/ DF Dilution Factor
Definitions
1 08/05/2211:00 ZBD SM-4500-NH3C
1 08/03/22 23:24 EAL 6010D
MQL Method Quantitation Limit
Page 3 of 5

WayPAo 0nt,..
NALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 04596
Customer Name: Soil Plus, LLC
Report Number: 22-213-0002
Shipping Method
0 Fed Ex 0 US Postal 0 Lab 0 Other:
UPS 0 Client 0 Courier Thermometer ID:
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
* Yes
0 No
COC agrees with sample label(s)?
0 Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments
Signature: David Lennon Date & Time: 08/01/2022 10:05:03
Page 4 of 5

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Waypointo
ANALYTICAL
10/31 /2022
Soil Plus, LLC
Joyce Barrett
P.O. Box 1396
Oxford, NC, 27565
Ref: Analytical Testing
Report Number: 22-293-0003
Project Description: CF Ind.
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Dear Joyce Barrett:
Waypoint Analytical Virginia, Inc. received sample(s) on 10/20/2022 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
TOWIT Mt Gram/
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 6

(2)
Waypoint. 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-293-0003
Client Project Description: CF Ind.
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
59721
CF
101922
Aqueous
59721
CF
101922
Aqueous
59721
CF
101922
Aqueous
59721
CF
101922
Aqueous
59721
CF
101922
Aqueous
10/19/2022
11:00
10/20/2022
10/19/2022
11:00
10/20/2022
10/19/2022
11:00
10/20/2022
10/19/2022
11:00
10/20/2022
10/19/2022
11:00
10/20/2022
SM-4500-NH3C-TKN
WP MTN
4500NO3F-2011
WP MTN
6010D
WP MTN
9045D
WP MTN
SM-4500-NH3C
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 2 of 6

Waypoint.0
ANALYTICAL
04596
Soil Plus, LLC
Project CF Ind.
Joyce Barrett
P.O. Box 1396
Information
Oxford , NC 27565
Report Number : 22-293-0003
REPORTO
Lab No : 59721
Sample ID : CF 101922
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Report Date : 10/31/2022
Received: 10/20/2022
�Aw t pt &(Pwr
VALYSIS Pauric Mc Groary Ph.D., CPA
Agronomist
Matrix: Aqueous
Sampled: 10/ 19/ 2022 11:00
Test
Results
Units
MQL
DF Date / Time
Analyzed
By
Analytical
Method
Calcium
50.3
mg/L
0.500
1 10/27/2211:34
EAL
6010D
Sodium
27.5
mg/L
0.500
1 10/27/2211:34
EAL
6010D
Aluminum
0.660
mg/L
0.100
1 10/27/2211:34
6010D
Test
Results
Units
MQL
DF Date / Time
By
Analytical
Analyzed
Method
Nitrate+Nitrite-N 230 mg/L 2.00 20 10/26/2215:55 ZBD 4500NO3F-2011
Phosphorus 3.00 mg/L 0.100 1 10/27/22 11:34 EAL 6010D
Total Kjeldahl Nitrogen
205
mg/L
5.00
1
10/27/22 10:30
JPJ ;M-4500-NH3C-TKP
Potassium
33.4
mg/L
0.500
5
10/27/2212:01
EAL 6010D
Magnesium
13.3
mg/L
0.100
1
10/27/2211:34
EAL 6010D
Ammonia Nitrogen
30.8
mg/L
1.00
1
10/26/22 11:00
ZBD SM-4500-NH3C
pH
7.0
s.u.
1
10/28/22 16:20
SAR 9045D
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 3 of 6

Waypointo
ANALYTICAL
7621 Whitepine !toad, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Client: Soil Plus, LLC CASE NARRATIVE
Project: CF Ind.
Lab Report Number: 22-293-0003
Date: 10/28/2022
Nitrate + Nitrite Nitrogen Method 4500NO3F-2016
QC Batch No: L645419
The MS/MSD recoveries are outside QC limits due to the level of analyte present in the parent sample relative to
the spike level. RPD is based on the MS/MSD results and should be evaluated as laboratory duplicates.
Metals Analysis Method 6010D
Sample 82484 (GW-1)
Analyte: Potassium
QC Batch No: 1-645624/1-645257
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 6

WayPAo 0nt,..
NALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 04596
Customer Name: Soil Plus, LLC
Report Number: 22-293-0003
Shipping Method
0 Fed Ex 0 US Postal 0 Lab 0 Other:
UPS 0 Client 0 Courier Thermometer ID:
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
* Yes
0 No
COC agrees with sample label(s)?
0 Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments
Signature: David Lennon Date & Time: 10/20/2022 09:11:09
Page 5 of 6

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