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NCS000581_Fact sheet binder_20230714
DEQ / DEMLR FACT SHEET FOR NPDES INDUSTRIAL INDIVIDUAL STORMWATER PERMIT DEVELOPMENT Basic Information for Permit Issuance and Renewals: Permit Writer/Date Brianna Young 7/3/2023 Permit Number NCS000581 Owner/Facility Name Duke Energy Progress,LLC/Roxboro Steam Electric Plant SIC AICS Code/Category 4911 /Electric power services Basin Name/Sub-basin number Roanoke/03-02-05 Receiving Stream/HUC Hyco River(including Hyco Lake below elevation 410)/030101040507 Stream Classification/Stream Segment WS-V,B/22-58- 0.5 Is the stream impaired on 303 d list]? No Any TMDLs? No Any threatened and/or endangered species? No; See Section 2 below Any compliance concerns? See Section 2 below Any permit mods since lastpermit? Yes; See Section 1 below New expiration date 7/31/2028 Comments on Draft Permit? See Section 6 below Section 1. Facility Activities and Process: The Duke Energy Progress, LLC Roxboro Steam Electric Plant is an electric generating facility consisting of four coal fired units with a total generating capacity of 2,558.2 megawatts. Per the April 2023 DEMLR inspection report, the stormwater permit is issued for a flat staging and laydown area which has a railroad track that carries gypsum, limestone and coal in rail cars that circles the entire laydown area. The laydown area consists of large pipe sections that looked clean with no visible residue, staged in small areas around the site, and Conex Boxes and miscellaneous materials located in different areas of the yard. Letter from Duke Energy dated 5/2/2017: The station will be undertaking process improvement work in the vicinity of stormwater outfall SW-3 and request elimination the outfall. The removal will consist of plugging the existing concrete conveyance pipe then adding grout to fully eliminate any discrete discharge. The grading in this area will result in only sheet flow in the future. Outfall SW001 (SW-A): North loop of plant Drainage area consist of delivery trucks and train cars travelling through the area carrying limestone, gypsum, and coal. Drainage area is north of the plant and enclosed by a rail line. Additional outfalls Outfall SWO03: Plugged Outlet structure plugged. Drainage area previously consisted of the west access road, a warehouse, grassy swale, and small area adjacent to an access road where chemical deliveries may take place. Page 1 of 7 Why Industrial Sites with Stormwater are Subject to a Permit: Federal NPDES regulations define stormwater discharge associated with industrial activity in 40 CFR §122.26 (b)(14) as: "the discharge from any conveyance that is used for collecting and conveying storm water and that is directly related to manufacturing,processing or raw materials storage areas at an industrial plant. The term does not include discharges from facilities or activities excluded from the NPDES program under this part 122. For the categories of industries identified in this section, the term includes, but is not limited to, storm water [sic] discharges from industrial plant yards; immediate access roads and rail lines used or traveled by carriers of raw materials, manufactured products, waste material, or byproducts used or created by the facility; material handling sites; refuse sites; sites used for the application or disposal of process waste waters (as defined at part 401 of this chapter); sites used for the storage and maintenance of material handling equipment; sites used for residual treatment, storage, or disposal; shipping and receiving areas; manufacturing buildings; storage areas (including tank farms) for raw materials, and intermediate and final products; and areas where industrial activity has taken place in the past and significant materials remain and are exposed to storm water. For the purposes of this paragraph, material handling activities include storage, loading and unloading, transportation, or conveyance of any raw material, intermediate product, final product, byproduct or waste product. The term excludes areas located on plant lands separate from the plant's industrial activities, such as office buildings and accompanying parking lots as long as the drainage from the excluded areas is not mixed with storm water [sic] drained from the above described areas." Section 2. Monitoring Information and Compliance History: • March 2017 to May 2022,benchmarks exceeded for: o SW-A: TSS Ix Threatened/Endangered Species: There are no threatened/endangered species at the discharge location, however, in the vicinity there are: Ringed Witch Grass (Dichanthelium annulum; NC status: E), Carolina Birdfoot-trefoil (Acmispon helleri; NC status: T), Tall Boneset(Eupatorium saltuense;NC status: SR-L), and Small Rabbit- Tobacco (Pseudognaphalium micradenium; NC status: SR-T). Section 3. Proposed Monitoring for Stormwater Discharges: The Division considered potential pollutants from past and present industrial activities (coal-fired electric generation) and data was submitted for March 2017 to May 2022. Quantitative sampling included pH, TSS, O&G, boron, zinc, antimony, arsenic, beryllium, cadmium, chromium, copper, lead, nickel, selenium, silver, thallium, and mercury. Unlike most stormwater permits in its program, the Division is proposing a permit structure with outfall- specific monitoring for discharges. Parameters are based on potential pollutants in the drainage area, sampling results, and in some cases, dependent upon future activities (e.g., ash removal through the drainage area). Below is a table of the proposed monitoring for each outfall at the Roxboro Steam Electric Plant site. Page 2 of 7 Outfall SWO01 (SW-A) Quarterly monitoring Total Suspended Solids BASIS: Potential pollutant from drainage area and BMP effectiveness (TSS) indicator. Quarterly monitoring H BASIS: Pollutant indicator and important to interpreting toxicity potential p of metals. Quarterly monitoring Total Rainfall BASIS: Discharge potential indicator Quarterly monitoring Non-Polar Oil &Grease BASIS: Potential pollutant from lubricants; Method 1664 SGT-HEM targets petroleum-based O&G Quarterly monitoring Monthly Oil Usage BASIS: Potential pollutant from drainage area Quarterly monitoring Antimony(Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Arsenic (Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Beryllium(Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Cadmium (Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Chromium(Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Copper (Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Lead(Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Mercury (Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Nickel (Total) BASIS: Coal combustion waste (CCW) constituents. Selenium(Total) Quarterly monitoring BASIS: Coal combustion waste CCW constituents. Page 3 of 7 Quarterly monitoring Silver(Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Thallium (Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Zinc (Total) BASIS: Coal combustion waste (CCW) constituents. Quarterly monitoring Boron BASIS: Coal combustion waste (CCW) constituent/ coal tracer. Quarterly monitoring Total Hardness BASIS: Monitoring for hardness dependent metals required. Stormwater Benchmarks and Tiered Response: Rather than limits,North Carolina NPDES Stormwater permits contain benchmark concentrations. Stormwater benchmarks are numerical action levels for stormwater monitoring. Benchmarks are not effluent limits, and benchmark exceedances are not permit violations. Benchmarks provide facilities a tool for assessing the significance of pollutants in stormwater discharges and the effectiveness of best management practices (BMPs). Benchmark concentrations are intended as guidelines for the facility's development and implementation of the Stormwater Pollution Prevention Plan(SWPPP). Benchmark exceedances require the permittee to increase monitoring, increase management actions, increase record keeping, and/or install stormwater BMPs in a tiered program. The permit establishes a tiered approach to specify actions the permittee must take in response to analytical results above benchmark concentrations. The tiered structure of the permit provides the permittee and DEMLR wide flexibility to address issues that may arise with one or more parameters and/or outfalls. Metals benchmarks are calculated to mimic acute water quality standards and with the guidance of DWR. NC DWR follows established federal procedures for calculating acute standards when developing the benchmarks. Just like the acute standards, metals benchmarks normally reflect one half of the calculated Final Acute Value (the "1/2 FAV"). In most cases, translation into total recoverable values is based on an assumed hardness of 25 mg/L and a total suspended solids (TSS) concentration of 10 mg/L. Acute standards protect aquatic life from negative impacts of short-term exposure to higher levels of chemicals where the discharge enters a waterbody. The Stormwater Permitting Program applies this approach because of the ephemeral nature of rainfall events. The Division may evaluate results to determine if a smaller suite of parameters for some outfalls is adequate to characterize potential pollution or BMP effectiveness. For example, one or more metals or other parameters may serve as an adequate tracer for the presence of ash pollution during disturbance or ash removal in specific drainage areas at this site. For parameters that do not have a stormwater benchmark, the Division may develop a benchmark value if appropriate toxicity data become available or if rising trends in concentrations suggest a persistent source. A summary of the benchmarks in the draft permit, and their basis, is below: Page 4 of 7 Parameter Benchmark Basis Antimony Total 340 /L Acute Aquatic Criterion, '/2 FAV Arsenic Total 340 /L Acute Aquatic Criterion, '/2 FAV Beryllium Total 65 /L Acute Aquatic Criterion, '/2 FAV Boron 34,000 µg/L CCW/Coal constituent;Narrative National Recommended Water Quality Criterion Cadmium Total 3 /L Acute Aquatic Criterion, '/2 FAV '/2 FAV; Based on(Cr III+Cr VI) acute thresholds and Chromium(Total) 905 µg/L assumption that industrial activities here are not a source of hexavalent chromium Copper Total 10 /L Acute Aquatic Criterion, '/2 FAV Lead Total 75 /L Acute A uatic Criterion, '/2 FAV Mercury (Total) 12 ng/L CCW/Coal Constituent; Chronic 02B standard Nickel Total 335 /L Acute Aquatic Criterion, '/2 FAV Selenium(Total) 5 µg/L '/2 FAV,NC-specific, based on 1986 Study on Se impacts in NC Silver Total 0.3 /L Acute Aquatic Criterion, '/2 FAV Thallium Total 2,000 CCW/Coal constituent; Based on EPA Safe Drinking Water (Total) µg/L Act MCL Zinc Total 126 µg/L Acute Aquatic Criterion, '/2 FAV Total Suspended 100 mg/L National Urban Runoff Program(NURP) Study, 1983 Solids TSS H 6 s.u. —9 s.u. NC Water Quality Standard(Range) Non-Polar Oil & Review of other state's daily maximum benchmark Grease 15 mg/L concentration for this more targeted O&G;NC WQS that EPA Method 1664 does not allow oil sheen in waters SGT-HEM Stormwater Pollution Prevention Plan: The proposed permit conditions reflect the EPA and NC's pollution prevention approach to stormwater permitting. The Division's maintains that implementation of Best Management Practices (BMPs) and traditional stormwater management practices that control the source of pollutants meets the definition of Best Available Technology (BAT) and Best Conventional Pollutant Control Technology(BCT). The permit conditions are not numeric effluent limitations but are designed to be flexible requirements for implementing site-specific plans to minimize and control pollutants in stormwater discharges associated with the industrial activity. Title 40 Code of Federal Regulations (CFR) §122.44(k)(2) authorizes the use of BMPs in lieu of numeric effluent limitations in NPDES permits when the agency finds numeric effluent limitations to be infeasible. The agency may also impose BMP requirements which are "reasonably necessary" to carry out the purposes of the Act under the authority of 40 CFR 122.44(k)(3). The conditions proposed in this draft permit are included under the authority of both of these regulatory provisions. In essence, the pollution prevention and BMP requirements operate as limitations on effluent discharges that reflect the application of BAT/BCT. Mercury Monitoring Requirements: The proposed permit requires mercury to be measured in stormwater samples by EPA Method 1631E, which can detect levels as low as 0.5 ng/l. This requirement is consistent with recent federal rule-making that requires NPDES permittees to monitor discharges with sufficiently sensitive test procedures approved under 40 CFR §136. Modifications to 40 CFR §122.44(i) require a method that has a minimum level (ML) at or below the effluent limit (not applicable here), or the lowest minimum level (ML) of EPA approved analytical methods for the measured parameter. Based Page 5 of 7 on results, Method 1631E will be required to quantify levels in these discharges. NC DEMLR understands that this method is more costly and requires a more intensive sampling protocol than most other parameters, and that fish tissue sampling will be provided during the permit cycle. Therefore, no benchmark applies that would trigger tiered response actions. Proposed permit provisions also allow the permittee to use field blank and/or method blank concentrations to adjust reported mercury levels as long as documented is submitted with the Data Monitoring Report DMR). Flexibility in Tier Responses: Tier Two actions provide an opportunity for the permittee to propose an alternative monitoring plan for approval by the Region: • Alternatively, in lieu of steps 2 and 3, the permittee may, after two consecutive exceedances, exercise the option of contacting the DEMLR Regional Engineer as provided below in Tier Three. The Regional Engineer may direct the response actions on the part of the permittee as provided in Tier Three, including reduced or additional sampling parameters or frequency. • If pursuing the alternative above after two consecutive exceedances, the permittee may propose an alternative monitoring plan for approval by the Regional Engineer. The permit therefore allows the permittee to petition the Regional Office for monitoring changes sooner than Tier Three (upon any four benchmark exceedances) and gives guidance on one option to take. For example, the permittee may request that mercury only be monitored semi-annually under the tiers, or that only parameters over the benchmark be monitored more frequently. In this way, changes to the monitoring scheme for any outfall could be handled outside of a permit modification. Other Proposed Requirements: • It is standard for Stormwater Pollution Prevention Plan(SWPPP)requirements to include an annual certification that stormwater outfalls have been evaluated for the presence of non- stormwater discharges, and if any are identified, how those discharges are permitted or otherwise authorized. • Requirement to submit a request for permit modification if the facility identifies or creates any new outfalls, removes outfalls, or alters any drainage area that changes potential pollutants. • The Division expects the permittee to apply best professional judgment and consider the safety of its personnel in fulfilling sampling obligations under the permit. • Federal regulations require electronic submittal of all discharge monitoring reports (DMRs). If a state does not establish a system to receive such submittals, then permittees must submit DMRs electronically to the EPA. • Quarterly QualitativeNisual Monitoring to assure regular observation of outfalls throughout year. Section 4. Changes from previous permit to draft: • Monitoring increased from semi-annually to quarterly for all parameters (qualitative and quantitative) • "No discharge" clarifications made • eDMR requirement added • Feasibility study removed • Boilerplate language moved into body of the permit; boilerplate no longer attached • Monitoring for total hardness added for all outfalls as monitoring for hardness dependent metals is required Page 6 of 7 • Benchmarks updated for parameters per guidance from DWR Standards group on stormwater benchmarks • Outfall SWO03 removed from permit as outfall was plugged Section 5. Changes from draft to flnal: • None Section 6. Discussions with the Facility and Regional Office: • Initial contact with facility: 7/6/2022 • Initial contact with Regional Office: 7/7/2022 • Draft sent to CO peer review: N/A • Draft sent to Regional Office: 5/25/2023 • Final permit sent for supervisor signature: 6/30/2023 Section 7. Comments received on draft permit: • Lori Tollie (Duke Energy; via email 6/14/2023): Duke Energy has no comments to submit after review of the draft NPDES Stormwater Permit for Roxboro Steam Station. • Shawn Guyer (PWS; via email 7/3/2023): The PWS Section concurs with the issuance of this permit provided the facility is operated and maintained properly, the stated effluent limits are met prior to discharge, and the discharge does not contravene the designated water quality standards. Page 7 of 7 Beaufort G�the The Herald-Pock Hill el Nuevo Herald-Miami Sun Nev,s-Myrtle Beach Bellingham Herald Idaho Statesman Raleigh N�s&Observer Th.Telegraph-Macon &11'mrllr� Bradenton Herald Island Packet The Olympian Obispo Daily Charotte Obszr�r LeDaington HeFald-Leader Fort Worth Star-Telegrarn Wichita Eagle Fresno Bea Miami Herald Sun Herald-8dond AFFIDAVIT OF PUBLICATION A=nt4 OrderNtmber Idelttifimum Order PO Arnow Cols Deptlt 311106 42M PdrdLe0Ad-IPLOR46020-IPLOR4602 $47750 2 24L Attention: Joyce Sanford Clark STATE OF NORTH MOLINA NC DENR ENGERGY MINERAL&LAND RESOURCES COUNTY OFWW COUNTY OF DURHAM 1612 MAIL SERVICE CENTER Before the undersigned,a Notary Public of Dallas RALEIGH,NC 276991612 County,Texas,duly commissioned and authorized to administer oaths,affirmations,etc,personally joyce.sanford@deq.nc.gov appeared Tara Pennington,who being duly sworn or affirmed,according to law,cloth depose and say that he NORTH CAROLINA ENVIRONMENTAL MANAGEMENT or she is Accounts Receivable Specialist of the News& COMMISSION INTENT TO ISSUE Observer Publishing Company.a corporation organized NPDES STORMWATFR DISCHARGE PERMITS and doing business under the Laws of the State of North The North Carolina Environmental Management Commission proposes to Issue g NPDES srormwater discharge pennitis)to the person(s) listed below. Public Carolina,and publishing a newspaper known as The canmem or objection to the drat permits is Invited.Written comments regarding ; News&Observer.Wake and State aforesaid,the said the proposed Penh will be accepted until 30 days attar the publish dale of this notice and considered In the final determination regarding pennt Issuance and newspaper in which such notice,paper,document,or Bee�mmtirccedces provisions.The may hold of the a publicChearingn of Energy,should there Inera,and Land be al significant legal advertisement was published was,at the time of degree of public interest Please man comments and/or information requests to each and every such publication,a newspaper meeting DEMUR at 1612 Mail Service Center,Raleigh,NC 2 7 699-1 612. all Of the requirements • Duke Energy Progress,LLC[526 S Church Street.Charlotte,NCI has re- q 'ements and qualifications of Section 1- quested renewal of pern t NCSOD0581 for the Roxboro Steam Electric 597 of the General Statutes of North Carolina and was a Plant in Person County.This facility discharges to Hyco River in the Roo- qualified news g poke River Be In. q paper within the meaning of Section 1-597 Interested persons may visit DEMURR at 512 N.Salisbury street,Raleigh,NC ; of the General Statutes of North Carolina,and that as 27604 to review information on file.Andltcnal information on NPDES permits such he or she makes this affidavit;and is familiar with and this notice may be found on our websik:hdpsy/deq.nc.gw/aboWtlM- stone/energy-mineml-and-land-rewurces/sto m ter/slot Ater-progmm/ the books,files and business of said corporation and by storavater-public-notices,or by contacting Brlanna Young atbrianna.young® j referencetothefilesofsaid ublication the attached nafencgov or 91 9-7 073 6 4 7. P IPLO124602 ; advertisement for NC DENR ENGERGY MINERAL&LAND May 29 2023 RESOURCES was inserted in the aforesaid newspaper on dates as follows: 1 insertion(s)published on: 05/29/23 certl or decare un derpenatyo perluryt aft e foregoing is true and correct Sty a.b d,e. Hafc4te-r Notary Public inand for the stateo exas,resi mg in Dallas County STEPHANIE HATCHER s. -lam My Notary 10#13359" %'a. i'•' Expires January 14.2026 Extra charge for lost or du prute affidavit. Legal do:u mend please do not destoyi Young, Brianna A From: Guyer, Shawn Sent: Monday,July 3, 2023 11:23 AM To: Young, Brianna A Subject: RE: Draft NPDES Permit NCS000581 Brianna, The PWS Section concurs with the issuance of this permit provided the facility is operated and maintained properly,the stated effluent limits are met prior to discharge, and the discharge does not contravene the designated water quality standards. Shawn Shawn F. Guyer, P.E. Deputy Section Chief- Technical Services Branch Head Division of Water Resources, Public Water Supply Section North Carolina Department of Environmental Quality Office: (919) 707-9102 1 Mobile: (919) 605-6016 Shawn.Guyer@deg.nc.gov NEW EMAIL ADDRESS ,�: D E '�7'` NORTH CAROLINA kl ; Department of Environmental Quality Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From:Young, Brianna A<Brianna.Young@deq.nc.gov> Sent:Thursday, May 25, 2023 8:34 AM To: Guyer, Shawn <shawn.guyer@deq.nc.gov> Subject: Draft NPDES Permit NCS000581 Good morning, Please find attached the draft NPDES stormwater permit NCS000581 for the Roxboro Steam Electric Plant.This facility discharges to class WS-V, B waters. Please provide any comments by June 26, 2023. Thank you, Brianna Young, MS(she/her/hers) Industrial Individual Permits Coordinator Stormwater Permitting Program NC DEQ/Division of Energy, Mineral, and Land Resources (DEMLR) 1 Brianna.Young@deg.nc.gov(e-mail preferred)PLEASE NOTE NEW EMAIL 919-707-3647 (office) Mailing address: 1612 Mail Service Center, Raleigh, NC 27699-1612 Physical address: 512 North Salisbury Street, Raleigh, NC 27604 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Based on the current guidance to minimize the spread of COVID-19,the Department of Environmental Quality has adjusted operations to protect the health and safety of the staff and public. Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email.We appreciate your patience as we continue to serve the public during this challenging time. Email correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties by an authorized state official. 2 Young, Brianna A From: Tollie, Lori White <Lori.Tollie@duke-energy.com> Sent: Wednesday,June 14, 2023 10:44 AM To: Young, Brianna A; Howard, Robert E; Conner, Steven B Cc: McDaniel, Kim Spence Subject: RE: [EXTERNAL] Draft NPDES Permit NCS000581 CAUTION: External email. Do not click links or open attachments unless verified. Report suspicious emails with the Report Message button located on your Outlook menu bar on the Home tab. Brianna, Duke Energy has no comments to submit after review of the draft NPDES Stormwater Permit for Roxboro Steam Station. Thank you for the opportunity to review. Lori W.Tollie Duke Energy Permitting&Compliance 500 Utility Drive Lewisville,NC 27012 Cell: (336) 408-2591 Office: (336) 854-4916 From:Young, Brianna A<Brianna.Young@deq.nc.gov> Sent:Thursday, May 25, 2023 8:34 AM To: Bednarcik,Jessica L<Jessica.Bed narcik@duke-energy.com> Cc:Tollie, Lori White<Lori.Tollie@duke-energy.com> Subject: [EXTERNAL] Draft NPDES Permit NCS000581 CAUTION! STOP. • expecting and spelling correct? Does the content make sense? Can you verify the sender? If suspicious report it, then do not click links, open attachments or enter your ID or password. Good morning, Please find attached the draft NPDES stormwater permit NCS000581 for the Roxboro Steam Electric Plant.A hard copy of this draft permit will be placed in the mail to Jessica Bednarcik. Please provide any comments by June 26, 2023. Thank you, Brianna Young, MS(she/her/hers) Industrial Individual Permits Coordinator Stormwater Permitting Program NC DEQ/Division of Energy, Mineral, and Land Resources (DEMLR) Brianna.Young@deq.nc.gov(e-mail preferred)PLEASE NOTE NEW EMAIL 919-707-3647 (office) Mailing address: 1612 Mail Service Center, Raleigh, NC 27699-1612 Physical address: 512 North Salisbury Street, Raleigh, NC 27604 1 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Based on the current guidance to minimize the spread of COVID-19,the Department of Environmental Quality has adjusted operations to protect the health and safety of the staff and public. Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email.We appreciate your patience as we continue to serve the public during this challenging time. Email correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties by an authorized state official. 2 Young, Brianna A From: Young, Brianna A Sent: Wednesday, May 3, 2023 3:20 PM To: Valentine, Thad Cc: Lawyer, Mike Subject: RE: NCS000581 Per my notes,the drainage area for SW001 consists of delivery trucks and train cars travelling through the area carrying limestone, gypsum, and coal. I am including Mike on this email for his input as this relates to a Duke facility. Question: Should we proceed with the permit renewal, or does the discharge area not constitute industrial activity needing a stormwater permit,therefore rescind the permit? Brianna Young, MS(she/her/hers) Industrial Individual Permits Coordinator Stormwater Permitting Program NC DEQ/Division of Energy, Mineral, and Land Resources (DEMLR) Brlanna.Young@ncdenr.gov(e-mail preferred) 919-707-3647 (office) Mailing address: 1612 Mail Service Center, Raleigh, NC 27699-1612 Physical address: 512 North Salisbury Street, Raleigh, NC 27604 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Based on the current guidance to minimize the spread of COVID-19,the Department of Environmental Quality has adjusted operations to protect the health and safety of the staff and public. Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email.We appreciate your patience as we continue to serve the public during this challenging time. From:Valentine,Thad <thad.valentine@ncdenr.gov> Sent:Wednesday, May 3, 2023 3:12 PM To:Young, Brianna A<Brianna.Young@ncdenr.gov> Subject: NCS000581 Brianna I looked at the Duke Energy facility in Semora, NCS000581 and I was a little confuse on why they had a stormwater permit for that site. Nearly the entire site is covered by a wastewater permit except for a small 3.5 acre laydown yard with a few Conex boxes, a little pipe and misc equipment stored there. I don't believe they understood why they had it either and looking at there sample data, it doesn't appear they have ever had anything even close to what would require a permit for a sample. I have included some pictures and a sample spreadsheet with sample data from 3/2017-01/2020 and a snip of the permit area shown as a small diamond shape just above the middle of the site as a representation of the size.The data shows that the readings are far below benchmark. I don't know if that should even require a permit, but I want your thoughts on this Let me know what you think before I enter my inspection report 1 Thad Valentine Environmental Senior Specialist— RRO Division of Energy, Mineral, and Land Resources— Land Quality Section Department of Environmental Quality 919 791 4220 office thad.valentine(c�ncdenr.gov 1628 Mail Service Center, Raleigh, North Carolina 27699 2 ppN N N qr v O O p N Lr) n O O 0 0 0 0 0 O O O O Q O n C3 OV O a V V OV 0 0 O 0 O oO 0 0 ri Q ^ -4 Ln N N 00 N Q li eti Q O 0 ul O O O O Q 0 0 0 0 n H N O O 0 O N V 0 O O O d n O O O O n n o0 oV 0 0 v V d a a a o 0 0 0 0 N t-F Q Ol V1 o rq ry m o o m u1 a w n 1° O O '^ O �n o 0 Co Q 0 ca 0 0 .� d o O ,I v a o o O d O 0 0 0 o �d O a 0 0 0 0 0 p v 0 d V OV O V v v 0 V V Q .-1 p Ln N N Q Ol +� tn 0 0 0 o 0 0 0 0 r-4 O O O o o dQ 0 n V a 0 o 0 d n o0 0 o 0 n ` ^ 0 a dO o v o 0 d 6 o o a c 0 n 00 N m �--I NO Q lD ZD n lO O d 0 0 in � o 0 0 1-4d O C3 0 O Q O a 0 a co � N N O O O Q O O O d C p (D OV O 6 d � a 0 � C p Ci e-I m � m w o M v vi ^� `1 u�i m `1 � N a o a a a a a o Q Q a o o ry O O O O V V O O O O O O O CZ 00 O O O O V V d 0 v v V n 00 N LP 0 � Q N N O O o 0 0 N O p 0 N n I� O v Q `i V 0 O n 0 00 0 0 0 0 Ln ro 1-4 N M ^ r^-1 0 0 00 O O O O O -4-4 O O O �- N 0 0 0 0 V V O O O 0 0 0 0 0 0 1� O O O O O p V V v Q O O C7 0 a O p 0 ^ �--I Ln 00 N Q n M It o " o 0 0 0 0 0 0 as o uy Q O O O u1 V O O O 0 0 0 0 0 0 0 ol con d O 0 a C) C) a p 6 a CD, Q r-i Ln V .^-r m rn °O rn N Q u1 a Q o°Q0 �^, a CD 0 0 0 0 0 0 0 0 0 0 0 o Q Q °O 14 'I a o rn NA OLr� ^ n O p 0 OV OV O O O v o 0 0 a N 0 0 0 0 n'1 V e1 O p N eq l0 ^ � ��, v 0 0 0 0 o a 0 o a o 4 0 ry v Ln oacfl V 600010aaoo0 '8 , oo v O Y 00 N V d C LLn 0 -2 O n 00 N Or-I r Q Q n v 0 nn N o 0 0 o a o 0 0 0 Q o rn N oNn a o � 00 3 m rn 0 0 0 o v V o n 0 0 o 0 o 0 0 N to o d �n z V) 0 6 o 0 0 0 Q 0 Qo 0 0 0 0 0 0 ¢ ; ^ 0 0 o a v v M n 0 0 v N Q V O C E Z O a Q Y o E r Inv fa 3 — a, — E o a � m x 0 a � c N 06 o to M w -0 k D � Q � M ro '� x o v vs m O O Ln a Q u n E •N Y 0 m Q a m u Q Z c� cn - Ln O d vs � Q u �, E '�, O ILL, 6. 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Is i MINNO { iU. .w ` .LI t�1' Ar at ow IN k r . . p.- r r. . alp . . . iit SIMMONS 31,111 Ala I VVIP Aw IN .. — �. a 'ItfL . d t n p IV It A IN L14� NI 14 k If � . � IL I Gi1r _ - ._ n ; IN r - arIr NI N it . . . a 41, IN Y , 0 k j A as to )/ L , s � -� PERSC 048 F PE47 RS2r PERSO-043 1700 D.irra.+ay RC PERSO-033 ' BG,bc GI]l70l V IFgL a Gatc PERSO-038 NtH9:LL0 J�l l Young, Brianna A From: Valentine, Thad Sent: Monday, May 22, 2023 11:14 AM To: Young, Brianna A Subject: NCS000581 NOI Inspection Attachments: NCS000581_InspRpt_20230426.pdf Brianna This is the report for the Duke Energy (Semora)facility that was completed for the NOI. I don't see that there are any changes to the existing permit and it should be renewable as is. Let me know if you have any questions Thad Valentine Environmental Senior Specialist— RRO Division of Energy, Mineral, and Land Resources— Land Quality Section Department of Environmental Quality 919 791 4220 office thad.valentine(a_ncdenr.gov 1628 Mail Service Center, Raleigh, North Carolina 27699 Compliance Inspection Report Permit:NCS000581 Effective: 06/23/17 Expiration: 12/31/21 Owner: Duke Energy Carolinas LLC SOC: Effective: Expiration: Facility: Roxboro Steam Electric Plant County: Person 1700 Dunnaway Rd Region: Raleigh Semora NC 27343 Contact Person:Jason Haynes Title: Phone: Directions to Facility: System Classifications: SWNC, Primary ORC: Certification: Phone: Secondary ORC(s): On-Site Representative(s): Related Permits: Inspection Date: 04/26/2023 Entry Time 01:20PM Exit Time: 03:20PM Primary Inspector:Thaddeus W Valentine Phone: Secondary Inspector(s): Reason for Inspection: Routine Inspection Type: Compliance Evaluation Permit Inspection Type: Stormwater Discharge, Individual Facility Status: Compliant ❑ Not Compliant Question Areas: Storm Water (See attachment summary) Page 1 of 3 Permit: NCS000581 Owner-Facility:Duke Energy Carolinas LLC Inspection Date: 04/26/2023 Inspection Type:Compliance Evaluation Reason for Visit: Routine Inspection Summary: I meet with Robert Howard, Lori Tollie and others to inspect the site and evaluate the effectiveness of their stormwater permit program. We reviewed the required documents for the permit before walking the site and I found that everything was detailed and complete. The stormwater permit is issued for a flat staging and laydown area of 3.5 to 5 acreas with the plant and associated materials located to the South and Hyco Lake to the East, North and West. The area has a railroad track which carries gypsum, limestone and coal in rail cars that circles the entire laydown area. This laydown area consist of large pipe sections that looked clean with no visible residue, staged in small areas around the site . There are Conex Boxes and miscellaneous materials located in different areas of the yard. The sample outlet can be found at the one discharge point on the East side of the permit area. Site BMP's consist of grass and ditches. The stormwater pollution prevention plan (SP3)appeared to be in order and all the requirements of the plan are being followed. The one exception being the spill log.We recommend that the(SP3)contain a list of spills or leaks for the last threee years. If there were no spills or leaks during any year, please provide on the spill/leak document that there were no spills for that year. We recommend that all spills or leaks that occurr be listed on this document, regardless of the quantaty and whether its reportable.We also ask that the manner of recovered and the mode of disoposal of any spilled/leaked materials be listed on that document. That is the only recommendation for this facilities stormwater permit and all other requirements of the permit are being addressed as required Page 2 of 3 Permit: NCS000581 Owner-Facility:Duke Energy Carolinas LLC Inspection Date: 04/26/2023 Inspection Type:Compliance Evaluation Reason for Visit: Routine Stormwater Pollution Prevention Plan Yes No NA NE Does the site have a Stormwater Pollution Prevention Plan? ❑ ❑ ❑ #Does the Plan include a General Location (USGS) map? ❑ ❑ ❑ #Does the Plan include a"Narrative Description of Practices"? ❑ ❑ ❑ #Does the Plan include a detailed site map including outfall locations and drainage areas? ❑ ❑ ❑ #Does the Plan include a list of significant spills occurring during the past 3 years? ❑ ❑ ❑ #Has the facility evaluated feasible alternatives to current practices? ❑ ❑ ❑ #Does the facility provide all necessary secondary containment? ❑ ❑ ❑ #Does the Plan include a BMP summary? ❑ ❑ ❑ #Does the Plan include a Spill Prevention and Response Plan (SPRP)? ❑ ❑ ❑ #Does the Plan include a Preventative Maintenance and Good Housekeeping Plan? ❑ ❑ ❑ #Does the facility provide and document Employee Training? 0 ❑ ❑ ❑ #Does the Plan include a list of Responsible Party(s)? 0 ❑ ❑ ❑ # Is the Plan reviewed and updated annually? 0 ❑ ❑ ❑ #Does the Plan include a Stormwater Facility Inspection Program? 0 ❑ ❑ ❑ Has the Stormwater Pollution Prevention Plan been implemented? 0 ❑ ❑ ❑ Comment: All information was provided other than teh spill log Qualitative Monitoring Yes No NA NE Has the facility conducted its Qualitative Monitoring? 0 ❑ ❑ ❑ Comment: Provided Analytical Monitoring Yes No NA NE Has the facility conducted its Analytical monitoring? 0 ❑ ❑ ❑ #Has the facility conducted its Analytical monitoring from Vehicle Maintenance areas? ❑ ❑ 0 ❑ Comment: Provided Permit and Outfalls Yes No NA NE # Is a copy of the Permit and the Certificate of Coverage available at the site? 0 ❑ ❑ ❑ #Were all outfalls observed during the inspection? ❑ ❑ ❑ # If the facility has representative outfall status, is it properly documented by the Division? ❑ ❑ ❑ #Has the facility evaluated all illicit(non stormwater)discharges? 0 ❑ ❑ ❑ Comment: The facility has a copy of the latest COC and have evaluated for ellicit discharges Page 3 of 3 Young, Brianna A From: Tollie, Lori White <Lori.Tollie@duke-energy.com> Sent: Wednesday,July 13, 2022 12:23 PM To: Young, Brianna A; Bednarcik,Jessica L Cc: Winston, Cynthia C Subject: RE: [EXTERNAL] Roxboro Steam Electric Plant stormwater permit NCS000581 Attachments: SW-A Industrial Activity.pdf, Summary of Analytical Monitoring Roxboro.xlsx CAUTION: External email. Do not click links or open attachments unless you verify.Send all suspicious email as an attachment to Report Spam. Hi Brianna, I have compiled the additional information you requested. Please let me know if you have any questions.Thank you. • Latitude/Longitude of each outfall; Roxboro has 1 SW outfall (SW-A) o Latitude 36.4877, Longitude 79.0719 • Description of industrial activity in each drainage area; o Attached SW-A Industrial Activity pdf • An electronic spreadsheet summarizing all of the monitoring data that has been collected since the effective date of the current permit; o Attached Summary of Analytical Monitoring Roxboro 2017-2022 • Verification that the information in the renewal application is still complete and correct; and an explanation of any operational changes since the renewal application was submitted. o The renewal package is still complete and correct. No operational changes have occurred since the renewal package was submitted on January 27, 2021 Lori W.Tollie Duke Energy Permitting&Compliance 500 Utility Drive Lewisville,NC 27012 Cell: (336) 408-2591 Office: (336) 854-4916 From:Young, Brianna A<Brianna.Young@ncdenr.gov> Sent:Wednesday,July 6, 2022 1:50 PM To: Bednarcik,Jessica L<Jessica.Bed narcik@duke-energy.com> 1 Cc:Tollie, Lori White<Lori.Tollie@duke-energy.com> Subject: [EXTERNAL] Roxboro Steam Electric Plant stormwater permit NCS000581 STOP.CAUTION! EXTERNAL SENDER *** ASSESS.VERIFYH Were • expecting and spelling correct? Does the content make sense? Can you verify the sender? If suspicious report it, then do not click links, open attachments or enter your ID or password. Good afternoon, The Division of Energy, Mineral, and Land Resources (DEMLR) Stormwater Permitting Program acknowledges receipt of your renewal application for coverage under NPDES Permit Number NCS000581, received in our offices on January 27, 2021. Please continue to comply with all conditions and monitoring requirements in your current NPDES stormwater permit. As long as you have submitted a complete renewal request package and maintain compliance with those permit conditions, stormwater discharges from this facility are authorized by that permit until the Division issues a renewal permit or notifies you of an alternative action. I am working on renewing the individual stormwater permit for the Roxboro Steam Electric Plant (NCS000581). I need additional information in order to 1) confirm that the information I have is correct and 2) make sure the permit adequately serves the needs of the facility. Please provide the following: • Latitude/longitude of each outfall; • Description of industrial activity in each drainage area; • An electronic spreadsheet summarizing all of the monitoring data that has been collected since the effective date of the current permit; • Verification that the information in the renewal application is still complete and correct; and • An explanation of any operational changes since the renewal application was submitted. Enter your stormwater permit number into the Stormwater Permit Summary Report and you will see a form that includes the address of the facility, contact information for the permit, and the regulated stormwater outfall(s) for the facility. Please review the facility information to make sure it is correct. Information can be updated using the links provided below, where applicable: • Facility/Company name or ownership: Name/Ownership Change Form • Owner Affiliation (Legally responsible person; i.e., someone with the company who is designated to represent the company per signatory requirements or another authorized representative): Permit Contact Update Request Form • Delegation of Signature Authority (DOSA): Permit Contact Update Request Form • Billing contact: Permit Contact Update Request Form • Permit contact: Permit Contact Update Request Form • Facility contact: Permit Contact Update Request Form • Facility address only: Email Bethany og ulias • Stormwater outfall information: Email Bethany Georgoulias • Visit the eDMR Six Steps website and complete Steps 1 and 2. • Pay outstanding permit fees: Stormwater ePUment website Once I have the above listed information, I can continue my review. You will receive a draft permit for a 30-day comment period. During this time we will be able to address any comments or concerns you have. During the same 30-day period, the draft will be sent to a Regional Office staff member for review as well as out to public notice. Once all comments and concerns are addressed, you may be issued a final permit. Please contact me if you have any questions. 2 Thank you, Brianna Young, MS(she/her/hers) Industrial Individual Permits Coordinator Stormwater Program NC DEQ/Division of Energy, Mineral, and Land Resources (DEMLR) Brianna.Young@ncdenr.gov(e-mail preferred) 919-707-3647 (office) Mailing address: 1612 Mail Service Center, Raleigh, NC 27699-1612 Physical address: 512 North Salisbury Street, Raleigh, NC 27604 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Based on the current guidance to minimize the spread of COVID-19,the Department of Environmental Quality has adjusted operations to protect the health and safety of the staff and public. Many employees are working remotely or are on staggered shifts. Please check with the appropriate staff before visiting our offices,as we may be able to handle your requests by phone or email.We appreciate your patience as we continue to serve the public during this challenging time. 3 3.1.3.1 Inventonj of Storer fvater Exposure mid Process Activities [Part 11, Section. A.1.b] Storrrrwa ter E.tposureItem Associated Location Commeats 0 11 I fa 11 Limestone SIV-A Access road Delivery tricks and train cars south of S -A travel tluough drainage area. drainage area -No loading or unloading operations take glace in dranage tuea. Gypsum SI V-A Access road Delivery trucks and train cars south of SW-A travel through drainage area. drainage area No loading or unloading operations take place in drainage meal Coal SW-A Access road Delivery trucks and train cars south of SW-A travel through drainage area. drainage area No loading or unloading operations take place in drainage tuea. Summary of Analytical Monitoring Data 2017-2022 Roxboro Steam Electric Plant NPDES Permit No. NCS000581 Stormwater Outfall SWA Date Sampled 3/14/2017 5/10/2017 8/14/2017 11/9/2017 1/23/2018 5/29/2018 8/2/2018 10/11/2018 6/7/2019 7/23/2019 10/31/2019 12/17/2019 1/7/2020 Rainfall 0.37 0.399 0.588 0.559 0.3 0.21 0.409 3.47 1.6 1.89 0.62 0.19 0.22 pH 6.94 6.69 7.27 7.07 7.27 7.68 7.4 6.82 6.68 7.11 6.74 7.21 7.4 copper 0.00471 0.00403 0.00325 0.0041 0.00531 0.00766 0.00537 0.00534 0.00507 0.00444 selenium 0.00144 0.00119 0.00168 0.00172 <0.001 0.00107 <0.001 <0.001 <0.001 <0.001 mercury 0.00000383 0.00000389 0.0000038 0.00000373 0.00000152 0.00000425 0.00000526 0.00000382 zinc 0.007 0.01 <0.005 0.009 0.022 0.014 0.006 0.053 0.006 0.009 tss <5 <5 10 5 <5 11 6.8 110 7 10 <2.5 <2.5 O&G <4 <5 <4 <4.4 <5 <5 <5 <5 Boron <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.061 <0.05 <0.05 <0.05 <0.05 Ag 0.0003 <0.0003 <0.0003 0.0003 0.0003 0.0003 0.0003 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 As <0.001 <0.001 <0.001 <0.001 <0.001 0.00101 0.001 0.001 <0.001 0.001 0.001 0.001 0.001 Be <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Cd <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Cr <0.001 <0.001 <0.001 <0.001 <0.001 0.00119 0.00151 0.001 0.00559 0.001 <0.001 <0.001 <0.001 Ni <0.001 <0.00122 0.0016 <0.001 <0.00128 0.00261 0.00235 0.017 0.00441 0.0015 0.0167 0.00138 0.00126 Pb <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 0.0013 <0.001 <0.001 <0.001 <0.001 Sb <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 TI <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 Stormwater Outfall SWA Date Sampled 2/6/2020 4/30/2020 9/17/2020 3/1/2021 7/8/2021 2/23/2022 5/24/2022 Rainfall 1.69 1.01 2.58 0.26 1.4 0.83 0.88 pH 7.2 7.2 8 7 6.9 7.26 7.2 copper 0.00321 0.00311 0.00388 0.00967 0.00421 selenium <0.001 0.00165 <0.001 <0.001 <0.001 <0.001 mercury 0.00000343 0.00000347 0.00000453 0.00000451 0.00000586 zinc <0.05 0.005 0.006 0.017 <0.005 tss <2.8 8.4 3.9 7.4 24 4.8 2.9 O&G <5 <5 <5 <5 <5 <5 Boron <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 Ag <0.0002 <0.0002 <0.0002 <0.0002 <0.0003 <0.0003 <0.0003 As <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Be <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Cd <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Cr <0.001 <0.001 <0.001 <0.001 0.00283 <0.001 <0.001 Ni <0.001 0.00108 0.0013 0.00102 0.00319 0.00106 Pb <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 Sb <0.001 I <0.001 I <0.001 I <0.001 I <0.001 I <0.001 I <0.001 TI <0.0002 1 <0.0002 1 <0.0002 1 <0.0002 1 <0.0002 1 <0.0002 1 <0.0002 Young, Brianna A From: Young, Brianna A Sent: Wednesday,July 6, 2022 1:50 PM To: Bednarcik,Jessica L Cc: Tollie, Lori White Subject: Roxboro Steam Electric Plant stormwater permit NCS000581 Good afternoon, The Division of Energy, Mineral, and Land Resources (DEMLR) Stormwater Permitting Program acknowledges receipt of your renewal application for coverage under NPDES Permit Number NCS000581, received in our offices on January 27, 2021. Please continue to comply with all conditions and monitoring requirements in your current NPDES stormwater permit. As long as you have submitted a complete renewal request package and maintain compliance with those permit conditions, stormwater discharges from this facility are authorized by that permit until the Division issues a renewal permit or notifies you of an alternative action. I am working on renewing the individual stormwater permit for the Roxboro Steam Electric Plant (NCS000581). I need additional information in order to 1) confirm that the information I have is correct and 2) make sure the permit adequately serves the needs of the facility. Please provide the following: • Latitude/longitude of each outfall; • Description of industrial activity in each drainage area; • An electronic spreadsheet summarizing all of the monitoring data that has been collected since the effective date of the current permit; • Verification that the information in the renewal application is still complete and correct; and • An explanation of any operational changes since the renewal application was submitted. Enter your stormwater permit number into the Stormwater Permit Summary Report and you will see a form that includes the address of the facility,contact information for the permit, and the regulated stormwater outfall(s)for the facility. Please review the facility information to make sure it is correct. Information can be updated using the links provided below,where applicable: • Facility/Company name or ownership: Name/Ownership Change Form • Owner Affiliation(Legally responsible person; i.e., someone with the company who is designated to represent the company per signatory requirements or another authorized representative): Permit Contact Update Request Form • Delegation of Signature Authority (DOSA): Permit Contact Update Request Form • Billing contact: Permit Contact Update Request Form • Permit contact: Permit Contact Update Request Form • Facility contact: Permit Contact Update Request Form • Facility address only: Email Bethany og ulias • Stormwater outfall information: Email Bethany Geor og ulias • Visit the eDMR Six Steps website and complete Steps 1 and 2. • Pay outstanding permit fees: Stormwater ePgMent website Once I have the above listed information, I can continue my review. You will receive a draft permit for a 30-day comment period. During this time we will be able to address any comments or concerns you have. During the 1 same 30-day period, the draft will be sent to a Regional Office staff member for review as well as out to public notice. Once all comments and concerns are addressed, you may be issued a final permit. Please contact me if you have any questions. Thank you, Brianna Young, MS(she/her/hers) Industrial Individual Permits Coordinator Stormwater Program NC DEQ/Division of Energy, Mineral, and Land Resources (DEMLR) Brianna.Young@ncdenr.gov(e-mail preferred) 919-707-3647 (office) Mailing address: 1612 Mail Service Center, Raleigh, NC 27699-1612 Physical address: 512 North Salisbury Street, Raleigh, NC 27604 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Based on the current guidance to minimize the spread of COVID-19,the Department of Environmental Quality has adjusted operations to protect the health and safety of the staff and public. Many employees are working remotely or are on staggered shifts. Please check with the appropriate staff before visiting our offices,as we may be able to handle your requests by phone or email.We appreciate your patience as we continue to serve the public during this challenging time. 2 Roxboro Steam Electric Plant Duke Energy Progress,LLC DUKE 1700 Dunna«av Road ' ENERGY. Semora,NC 27343 File: 12520 R January 21,2021 Ms. Suzanne McCoy NC DEMLR Stormwater Program 1612 Mail Service Center Raleigh,NC 27699-1612 '� D r• 1 � Subject: Duke Energy Progress,LLC. JAN 27 2021 Roxboro Steam Electric Plant DENR-LAND CUAUTY NPDES Industrial Stormwater Permit NCS000581 STORMWATER PERM171NG Renewal Request Dear Ms.McCoy: Duke Energy Progress,LLC is submitting herewith, supplemental information in support of renewal and reissuance of NPDES permit NCS000581 for the Roxboro Steam Electric Plant.The subject NPDES permit expires December 31,2021. Attached is the renewal application and duplicate copies of all supplementary information. Should you have any questions please contact Ms. Lori Tollie at Lori.Tollie CTdllke-cnergy.coni or at (336)-854-4916. Sincerely, Tom Copolo General Manger—Roxboro Plant Attachments: Renewal Application Supplemental Information Site map from the Stormwater Pollution Prevention Plan Summary of Analytical Monitoring Results Summary of Visual Monitoring Results Significant Site Changes Certification of Development and Implementation of SPPP Fish Tissue Monitoring Results GWA Permit Coverage Renewal Application Form NCDENR National Pollutant Discharge Elimination System NPDES Permit Number Stormwater Individual Permit NCS000581 Please provide your permit number in box in the upper right hand corner, complete the information in the space provided below and return the completed renewal form along with the required supplemental information to the address indicated. Owner Information * Address to which permit correspondence wi//be mailed Owner/Organization Name: Duke Fnergy Prngrass i i C_ Owner Contact: Paul Draovi h -Senior VP EHS,Operations Support&CCP Mailing Address: PO Box 1006q Charlotte, NC 28201 E(,:'F C - Phone Number: 980-373-0408 �� 2 � � Fax Number: LI E-mail address: Paul.Draovitch@duke-energy.com C3ENR-LAND QUALITY Facility Information STORMWATER PERMITTING Facility Name: Roxboro Steam Electric Plant Facility Physical Address: 1700 Dunnaway Road Semora, NC 27343 Facility Contact: Tom Copolo Mailing Address: 1700 Dunnaway Road Semora, NC 27343 Phone Number: 336-597-7307 Fax Number: E-mail address: Tom.Copolo@duke-energy.com Permit Information Permit Contact: Lori Tollie Mailing Address: 2500 Fairfax Road Greensboro, NC 27407 Phone Number: 336-854-4916 Fax Number: E-mail address: Lori.Tollie@duke-energy.com Discharge Information Receiving Stream: Hyco Reservoir Stream Class: WS-V Basin: Roanoke Sub-Basin: ROA05 Number of Outfalls: 1 outfall (SW-A) Facility/Activity Changes Please describe below any changes to your facility or activities since issuance of your permit. Attached a separate sheet if necessary. No changes have occurred in the drainage area of outfall SW-A CERTIFICATION I certify that I am familiar with the information contained in the application and that to the best of my knowledge and belief such information 's true cgr0lete and accurate. Signature Date 01 bN I�A4o4o �M 1N� f2Et,�aTk4•o.ds Print or type name of person signing above Title SW Individual Permit Coverage Renewal Please return this completed application form Stormwater Permitting Program and requested supplemental information to: 1612 Mail Service Center Raleigh, North Carolina 27699-1612 SUPPLEMENTAL INFORMATION REQUIRED FOR RENEWAL OF INDIVIDUAL NPDES STORMWATER PERMIT Two copies of each of the following shall accompany this submittal in order for the application to be considered complete: (Do not submit the site Stormwater Pollution Prevention Plan) Initials LWT 1. A current Site Map from the Stormwater Pollution Prevention Plan. The location of industrial activities (including storage of materials, disposal areas, process areas and loading and unloading areas), drainage structures, drainage areas for each outfall, building locations and impervious surfaces should be clearly noted. LWT 2. A summary of Analytical Monitoring results during the term of the existing permit (if your permit required analytical sampling). Do not submit individual lab reports. The summary can consist of a table including such items as outfall number, parameters sampled, lab results, date sampled, and storm event data. LWT 3. A summary of the Visual Monitoring results. Do not submit individual monitoring reports. The summary can consist of a table including such items as outfall number, parameters surveyed, observations, and date monitoring conducted. LWT 4. A summary of the Best Management Practices utilized at the permitted facility. Summary should consist of a short narrative description of each BMP's in place at the facility. If the implementation of any BMP's is planned, please include information on these BMP's. LWT 5. A short narrative describing any significant changes in industrial activities at the permitted facility. Significant changes could include the addition or deletion of work processes, changes in material handling practices, changes in material storage practices, and/or changes in the raw materials used by the facility. LWT 6. Certification of the development and implementation of a Stormwater Pollution Prevention Plan for the permitted facility (Sign and return attached form). If the final year analytical monitoring of the existing permit term has not been completed prior to filing the renewal submittal, then the last years monitoring results should be submitted within 30 days of receipt of the laboratory reports. (i.e. do not withhold renewal submittal waiting on lab results) Roxboro Steam Electric Station Stormwater Permit NCS000581 Individual Permit Application Supplemental Information Attachment 1 Site Map 0 co LO ,..F•F�� _.� .„�� i6 CD O m r V u o 0 =Z mT o C Z T w 3 T t Q W O Q.Q1 'o-• C Z m E o7 0 •• B EW(nO h �If.�o�a p x f) 0 0 3' EW o 4ait C � U co a N O O wA r� n N U l6 7 `u LI O [•p� a W uj a Z Im 'a N'o �^ 2•d`a` N yyE E o�E ©Pl&� � t a �r�t� aEE a °l 1 ram' 432 ` 1 N 6gt yY r +F ' o .t 'n Attachment 2 Analytical Monitoring Results N 0V r-1 00 N r-I r-I c1 c-i c-I N 4 O C o Lfl 0 0 0 0 0 0 0 0 0 N ^ O O 0 O 0 NV 0 O O o 0 0 C o o C O O O V O O O CD CD CDO V Oo V O O V V V 0 V V Ov r O Q1 00 N O N 14 o 0 o O � 0 0 0 0 0 0 `� O CD O O O N V 0 O CDO CD O I� O v O O V V 0 0 0 0 00 0 0 0 O O V O V - C Ol Lf) lNO n 0 0 0 vl O O O O O O l^D 0 0 0 O O O r-1 O O O l0 O O C V O O O O O O o 0 0 0 6 V CC O V v O V V V O V V Ov r-I 1 O Q> N ci m ri ri Ln N c-I ci V1 ci ri N Ow a-i C 0 0 ^ 0 0 0 0 0 0 0 0 0 \ c-I n O v C O V v Ov C o C o 0 0 0 Ov O J) N M r-I m N O CODO C l0 O O O O Ln Ln � r-I 0 0 r-I O C O o C o 0 0 0 C � `� 0 0 0 0 0 C 0 � 6 0 LO v V V V 0 0 0 V V 00 -i N N O �Y W O O o 0 0 0 o O 00 m W OV O O Ov CD 6 6 6 O r-I 00 m rl C Ql CoE O m0 -t � u'1 m0 0 Q O0 Ln C-r o o O N � C) 0 p 00 C o 0 0 0 0 � 0 0 0 \ n O o 0 O C V Ov 0 0 O O O O O C 0 W O O O O V V 0 0 V V V 0 00 r-I `1 ci m ci ci Q1 r-I c-I ci N rljN lD � O NO `� g 0 0 0 0 0 N C O C � o Il O CDCD 0 0 0 0 0 6 0 O V CD V V 0 o V V v Ln I 00 00 00 N m ^ c-i O CD Ln O CD O O c-i CDC 0 � N O O O CD � v CD 0 6 6 6 6 q 6 O O O O O O CDC M o n 0 0 V v 0 r140 0 oC O V O V V V V O V V vv V t\ c 1 Ln 00 u'1 m c-1 ri c-1 ri ri CD 0 N N ul n m LD C O o 0 0 0 0 0 0 0 � O O O O O O O O O O O O C I� O O O V O o 6 0 C 6 0 0 0 V V O V V V V V V V Ov c n 0000 C d^ O Ul o CO O c�-I m to O ,-� c-I ci ci lD c-I c-I O O c�-I u �''� L() NO CD N o 0 0 0 0 0 O O O 0 0 0 0 0 N °,.ri° O0 m r-i O M Ln N 0 1� 0 0 0 0 Ov o 0 0 0 0 O 0 0 0 rl N 0 0 0 � m v 0 0 o v v o 0 0 Cco O1 0 N m ^ O i0 O m m Ln C r-� r-I ci ri N .--I ri O O fV 0) 11 Ln C O C O o 0 0 0 o C �� p N Ln m °�° 0 0 v o 0 0 0 0 0 0 0 o m � oo v o v v v c-I � Ln m ° C ^ 00 O d o o m in m ri ra H ri ri r-1 H No N N m Lo •i N Q N m a) It r-I C O O O O O O O O O O o Q O 0) N m O o C W U 3 m Ol O o CC O v v O O O O O O O O O o 3 N lD O O O N Ln •i, v Z N O lD O O O O V O O o 6 0 0 0 o H � r-I ^ 0 0 0 V v w 0 IH O O O O V V V V V V V v N 0 V o Z O O Q -t 0 E a o N v furo ° a 3 — v — E i E ° w E v Q Q L c �o Q m v •p o a 'a = o v °o 0 tw n au L cEo m = p v c 06 V) w Z V) O O V) w Q L, E N .,� O m Q Q CO,U U Z a cn P 2 O D v� n. u E 'n, O `^ 0 0 0 0 0 rI o 0 O 0 0 0 0 0 0 0 0 0 0 v o 0 0 0 0 0 0 0 v v v v v o v v v N ci c-I �-I c-i W c-I ci N 0 0 0 0 0 � 0 0 0 O O O O O O O O V v V v v v 0 V V Ov N c-I ci H ci c-i r-I c-I N � 0 0 0 0 0 0 0 0 0 O O O O O O O O O v 0 0 0 0 0 0 0 0 6 V V v V v V V V V c O i m Q Q coU U Z a Ln �_- Attachment 3 Summary of Visual Monitoring Data 0 v N O O 0 > Z Z Z c-i u cD = O v v ' N C: .-1 ci ci O O O d' > rri TiOc Z Z Z O u u c=L 00 C y O a) ^ a)N L tjo O N .--i N O O O > � � � Z Z Z m u \ f o v ° u C 00 N v N tlO 0 .�.1 O O O > N - O: Z Z Z O u m m 00 v U LJO m O v N N N O O O N > m - O0 Z Z Z O u N L u Ln v U 00 N C) O s v v N on C N —q N O O O (n > m - O0 Z Z Z o u ` m v U a O ci N Y . m ci N N O O O Ln > \ 00 C O O O > CY, 0 Z Z Z O u — O N `� N Z Z Z M u ci t6 m \ O m ti v ri v U � U C O r, y p N N ON \ ci N —1 O O O Ln 'a>--+ \ v O N ci N O O O Q ,> L = Z Z Z O u C u Z Z Z U p \ a m m m N 00 v u cu N b,O Y • \ _� O O O m \ 00 C ci ci 0 v O Z Z Z *' ci — O Z Z Z "2 -1 p u M C p u C LL l N O fO co O u U v M CJ > 00 (a m 0 _' OcV s v n v Q p m v v +' d p CO ci N ci Z z Z In a"' \ N cA N O O O W m u 0 Lry ,� i c O u m t Z Z Z u r0 of N 00 C ci cr u Z m u n O w O i O L j L- D O.. -O O M — O v Y ' Q -O p (p — O N O ,N m LO 0- �_ -a � LLL O O N 3 V m E Ln Lo 0 oo \ = N E w 4° v n v .o LL E v v a cu o LL E 75 E x a o M a '- o o N v o •� v L Y o Lo 'L ° _� o a ° v o •� u 7 O +� n O 7 O = = L F. u O O (6 O - 7 O -1-0 /6 U n z n U O U Ln n w j > Ln — w Q O Ln O 0 U O v N n LL > . n w Q O Attachment 4 Summary of Best Management Practices 3.2.3.1 Nonstructural Best Management Practices (BMP's) are methods, procedures, processes,prohibitions of practices and other management controls which serve to eliminate, mitigate, or reduce pollutant loadings in stormwater discharges. Examples of BMP's for the Roxboro Electric Generating Plant include: • Source Reduction • Good Housekeeping • Preventive Maintenance • Visual Inspections • Spill Prevention and Response • Erosion and Sediment Control • Stormwater Runoff Management • Employee Training • Recordkeeping and Reporting • Recycling • Treatment 3.2.3.2 Source Reduction Source reduction measures reduced stormwater pollution by reducing the quantity of materials,which may contact stormwater. The source reductions measures to be implemented may require modifications in present work habits and practices. Example components of source reduction are: • Good Housekeeping • Preventive Maintenance • Visual Inspections • Spill Prevention and Response • Erosion and Sediment Control Many of the components of source reduction are addressed as main components of the BMP, therefore, source reduction should be considered under each of the other BMP components. 3.2.3.3 Good Housekeeping Good housekeeping practices are designed to maintain a clean and orderly work environment. Good housekeeping practices should be incorporated in the day-to-day conduct of operations and maintenance. A clean and orderly work area reduces the possibility of accidental spills caused by the mishandling of chemicals and equipment. Well-maintained material and chemical storage areas reduce the possibility of stormwater mixing with pollutants. The following practices shall be performed on a regular basis: ERM NC,INC. 3-3 398458 • Maintain clean and dry floors, ground surfaces, work, and process areas through the use of brooms, shovels, vacuum cleaners, mops and cleaning equipment. • Regular pickup and disposal of waste materials. • Proper operation of equipment. • Routine visual inspections by qualified personnel for leaks or spills, and for conditions which may lead to a leak or spill (such as the hazardous waste inspections being performed at various areas throughout the Roxboro Plant). • Training of employees in spill prevention and cleanup procedures • Bags storing dry chemicals shall be raised off the floor, preferably by pallet, to prevent any unwanted interaction of the chemical with water. • Walkways shall be maintained free of obstructions to facilitate inspection for leaks or spills. The Fossil Chemistry Technician, assigned the NPDES ORC responsibilities, routinely inspects work and storage areas for best housekeeping practices. Corrections are handled by work orders tracked through Maximo, the Company work order management system, on an as needed basis. 3.2.3.4 Preventive Maintenance Roxboro Plant has various inspections and site assessment practices in place to assist with detection of potential problems. Preventive maintenance schedules vary based on the potential risk by the source. In general, the Roxboro Plant is well manned in order to ensure the facility is a reliable and efficient source of electricity. Preventive maintenance will be performed to ensure that stormwater management facilities and controls operate correctly and effectively and to reduce their breakdowns and failure. Specific activities include: • Periodic inspection, cleanout and maintenance of catch basins, containment areas, ditches, and conveyance equipment. • Periodic scheduled inspection and testing of equipment and systems, including pumps,valves,pipes, storage tanks, and controls. • Proper scheduled maintenance of equipment and facilities. Additional preventive maintenance information will be provided as a separate section of the SPPP. 3.2.3.5 Visual Inspections Visual inspections will be performed in conjunction with other BMP's, such as housekeeping and preventive maintenance, and also as a separate activity (see section 7 "Visual Inspection"). ERM NC,INC. 3-4 398458 3.2.3.6 Spill Prevention and Response Spill prevention will be achieved by good housekeeping, visual inspection, and preventive maintenance, and through training of personnel in material handling and storage procedures, and the use of equipment. Training in proper spill identification and cleanup procedures, including the use of equipment and the notification and documentation procedures, will be the main components of spill response. Specific spill preventative measures will include: • Piping protection, such as routing, coatings and wrappings, and cathodic protection where appropriate. • Adherence to current unloading procedures and practices,including monitoring and verification of all connections and seals. • Proper valve and control settings, and adequate labels, markings, and communications, to ensure that accidental closures or openings do not occur. • Adequate securities to prevent non-authorized access to facilities. • Appropriate documentation of actions taken. Spill response will be in accordance with existing Plant Procedures, including the Spill Prevention, Control and Countermeasure (SPCC) Plan and the Hazardous Substance Notification Procedure. Training is essential to a well-executed spill response. Personnel will be trained to identify potential stormwater pollution occurrences as may occur during a spill event, and respond in the appropriate manner. 3.2.3.7 Erosion and Sediment Control Areas under construction, or where accelerated erosion or sedimentation is occurring, will be monitored and corrective measures will be implemented as necessary. A Sediment Erosion Control Plan may be needed. The Environmental Site Coordinator will decide. Vegetation or equivalent stabilization of the ground will be performed to reduce/eliminate accelerated erosion. 3.2.3.8 StornlWater Runoff Management Uncontaminated stormwater will be diverted away from potential sources of contamination, and discharged to a stabilized conveyance structure. Contaminated waters will be directed to the appropriate treatment facilities prior to discharge. Diversion efforts should be made to reduce the quantity of contaminated stormwater that must be collected and treated depending on conditions. Vehicle washing should be performed in areas away from stormwater drains. ERM NC,INC. 3-5 398458 3.2.3.9 Employee Training General training of employees will emphasize good housekeeping, and preventive methods, procedures, and practices. Responsibilities will be clearly communicated to personnel, including notification procedures for preventive and corrective measures. Maintenance and inspection personnel will have the authority to follow-up on areas requiring improvement. Plant personnel will be trained in safety and clean-up operations and to recognize spills which may contribute to stormwater pollution. 3.2.3.10 Recordkeeping and Reports Training documentation will utilize the current training documentation tool. Maintenance activities will be documented in the current Maximo work management tool. Reports will be sent to the plant file 12520R located in the Environmental Coordinators Office. 3.2.3.11 Recycling No recycling of contaminated stormwater occurs at the Roxboro Plant. Recycling of some solid and universal wastes occurs at the Roxboro Plant. 3.2.3.12 Treatment Treatment measures will be the last step prior to the discharge of contaminated stormwater. Treatment is employed at the plant for those areas where, due to site constraints, other BMP's have been found to be infeasible or too costly to implement. Periodic vacuuming of storm drain catch basins will be conducted in high risk areas as needed. 3.3 SPILL PREVENTION AND RESPONSE PLAN[PART II, SECTION A.31 This SPPP contains the required elements of a Spill Prevention and Response Plan (SPRP), as outlined in Part II, Section A.3 of the permit. Roxboro Plant has strategically located spill response materials throughout the facility. Areas where potential spills could contribute pollutants to stormwater have been identified on Figure 2 and 3 of this Plan, along with the associated drainage points. Spill response training is provided to applicable employees on an initial hire and annual basis. In the event of a spill, Roxboro Plant employees are to respond only to incidental releases where the substance can be absorbed, neutralized, or otherwise controlled at the time of release by employees in the immediate release area or by maintenance personnel. An occurrence which results,or is likely to result, in an uncontrolled release of a hazardous substance requiring a response effort by employees from outside the immediate release area or by other designated responders (i.e., mutual-aid groups,fire ERM NC,INC. 3-6 398458 departments, etc.) is considered an"emergency response." Roxboro Plant employees are not to perform emergency responses, and such responses are only to be performed by personnel trained in accordance with 29 CFR 1910.120. All employees responsible for implementation of the SPRP are indicated in Section 3.3.2 of this Plan. The signature of each employee indicated in Section 3.3.2 is required, acknowledging that they have completed training and are aware of their responsibilities under this Plan. The annual stormwater training, course ENW009,is tracked and documented electronically by the Company sponsored system. 3.3.1 Spill Prevention & Response Team (SPRT) [Part II, Section A.3] The responsibilities of the SPRT Team include keeping all records, overseeing qualitative monitoring and analytical sampling, coordinating training program, implementing spill response and prevention measures, and ensuring good housekeeping at the facility. 3.3.2 Emergency Response Personnel: Facility and Local Robert Howard (EHS Professional) Office: 336-598-4077 Mobile: 336-503-2875 Ryan Enoch (NPDES ORC) Office: 336-598-7609 Mobile: 434-579-7699 Amber Sarver Office: 336-597-6139 Mobile: 336-597-0747 Scott Brooks Office: 336-597-6201 Mobile: 336-583-0143 Matthew Sumner Office: 336-597-6118 Mobile: 336-583-5453 Chris Clayton Office: 336-597-6246 Kevin Clayton Office: 336-330-2055 Mobile 336-504-9104 John Conner Office 336-597-6270 Mobile 434-222-5078 Lee Davis Office 336-597-6120 Mobile 336-592-5204 Fire Department(CEFFO VFD) 911 Police Department(Person County Sheriff) 911 State of North Carolina Highway Patrol 911 Person Memorial Hospital 336-599-2121 Person County EMS 911 Haz Mat Environmental,Charlotte,NC 704-332-5600 (Emergency Spill Response Contractor) Shamrock Environmental Corp., Greensboro,NC 800-881-1098 (Emergency Spill Response Contractor) 336-385-1989 Containment Controls, INC,Hope Mills NC 888-624-6555 (Emergency Spill Response Contractor) 3.3.3 Emergency Response: Federal and State Contacts National Response Center (NRC) 800-424-8802 State Emergency Response Commission(SERC) 919-715-2632 Local Emergency Planning Committee(LEPC) 828-652-3982 NC Department of Environmental Quality 919-733-1278 (NCDEQ-Raleigh Central Office) NC Department of Environmental Quality 919-791-4200 (NCDEQ- Raleigh Regional Office) Regional Environmental Protection Agency(EPA) 404-881-3016 800-424-8802 CHEMTREC(Chemical Transportation 800-424-9300 Emergency Center: transportation-related spills) EPA RCRA/Superfund Hotline 800-424-9346 OTHER: Attachment 5 Narrative of Significant Site Changes No significant changes have occurred in the drainage area of SW outfall SW-A Attachment 6 Certification of Development and Implementation of Stormwater Pollution Prevention Plan STORMWATER POLLUTION PREVENTION PLAN DEVELOPMENT AND IMPLEMENTATION CERTIFICATION North Carolina Division of Energy, Mineral, and Land Resources-Storm water Permitting Facility Name: Roxboro Steam Electric Plant Permit Number: NCS000581 Location Address: 1700 Dunnaway Road Semora,NC 27343 County: Person "I certify, under penalty of law, that the Stormwater Pollution Prevention Plan (SPPP) document and all attachments were developed and implemented under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information required by the SPPP. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information gathered is, to the best of my knowledge and belief, true, accurate and complete." And "I certify that the SPPP has been developed, signed and retained at the named facility location, and the SPPP has been fully implemented at this facility location in accordance with the terms and conditions of the stormwater discharge permit." And "I am aware that there are significant penalties for falsifying information, including the possibility of fines and imprisonment for knowing violations." Sign (according to permit signatory requirements) and return this Certification. DO NOT SEND STORMWATER POLLUTION PREVENTION PLAN WITH THIS CERTIFICATION. Signature Date 6t/At 121 Oµ [ _ApoL.o &MUt �EC.STsT.ods Print or type name of person signing above Title SPPP Certification 10/13 Attachment 7 Fish Tissue Monitoring Results Roxboro Stearn Electric Plant Industrial Storm Water Permit No. NCS000581 Arsenic,Mercury,and Selenium Monitoring of Fish in Hyco Reservoir Person County,North Carolina Duke Energy Progress January, 2021 Table of Contents Page 1.0 Introduction................................................................................................................................................. 1 2.0 Study Site Description and Sampling Locations ......................................................................................... 1 3.0 Target Species.............................................................................................................................................. 1 4.0 Field Sampling Methods.............................................................................................................................. 1 5.0 Laboratory Processing and Arsenic, Mercury, and Selenium Analysis....................................................... 1 6.0 Data Analysis and Reporting....................................................................................................................... 2 7.0 References.................................................................................................................................................... 2 List of Figures Figure Page g_ l Hyco Reservoir fish tissue monitoring locations from 2017 through 2019................................................. 3 List of Tables Table page 1 Arsenic, mercury, and selenium concentrations in axial muscle tissue of fish in Hyco Reservoir from2017 through 2019 .............................................................................................................................. 4 i 1.0 Introduction Duke Energy Progress, Inc. (DEP) owns and operates the Roxboro Steam Electric Plant (Roxboro) located on Hyco Reservoir in Person County, North Carolina. As required by Roxboro's Wastewater National Pollutant Discharge Elimination System (NPDES) Permit No. NC003425, DEP is required to monitor arsenic, selenium, and mercury in fish tissue in Hyco Reservoir near the ash pond discharge under monitoring plans approved by the North Carolina Division of Water Resources. Additionally, DEP operates under the requirements of Industrial Stormwater NPDES Permit No. NCS000581 which requires the reporting of the fish tissue monitoring required under the wastewater permit. This report is submitted to fulfill the reporting of fish tissue monitoring as required by the Industrial Stormwater permit from 2017 through 2019. Supporting data for this report has been submitted the North Carolina Division of Water Resources as an element of the wastewater permitting process. 2.0 Study Site Description and Sampling Locations Fish were collected for individual muscle tissue trace elements analysis at two areas within Hyco Reservoir (Figure 1). An area upstream (C) of the discharge point serves as a reference location to monitor background trace element concentrations in fish muscle tissue, and an area in the immediate vicinity of the discharge location (D) serves to monitor near-field uptake and assimilation of elements in fish muscle tissue. 3.0 Target Species The target fish were sunfish (preferred Bluegill), black bass (preferred Largemouth Bass) and catfish (preferred White Catfish). Where the full complement of preferred target species was not available, fish from the same genus or family were included as necessary (Table 1). As recommended by the U.S. Environmental Protection Agency (USEPA) an attempt was made to limit the smallest fish to 75% of the largest fish total length by species depending on availability (USEPA 2000). 4.0 Field Sampling Methods Fish were collected using electrofishing procedures specified in the DEP Biology Program Procedures Manual (Procedure NR-00080, Rev. 2 and NR-00095, Rev. 1) which is approved by the North Carolina Department of Environmental Quality under the DEP Biological Laboratory Certification (# 006). Only live fish of good condition were retained and put in a labeled bag and placed on ice until frozen for analysis. Ancillary fisheries data including species, total length (mm), and total weight (g) were also recorded. Fish collected were transferred to a freezer daily and maintained frozen until processing at the DEP New Hill Trace Element Laboratory. Associated water quality data including water temperature, dissolved oxygen, and specific conductance were recorded daily at the surface at each sampling location (available on request). 5.0 Laboratory Processing and Arsenic,Mercury, and Selenium Analysis Fish samples were processed and analyzed individually in the DEP Trace Element Laboratory according to procedure NR-00107, Rev. 4 Trace Element Monitoring Laboratory Procedure. Pace Analytical conducted the metals concentration analysis in 2018 in accordance with EPA methods 6020 and 7471. Quality control was 1 achieved utilizing analytical standards, replicates, and certified reference materials. Following analysis, residual processed samples were archived and will be kept for at least two years in the event that re-analysis is needed. 6.0 Data Analysis and Reporting Arsenic, mercury, and selenium concentrations (converted to µg/g wet weight) in the fish muscle tissue collected from 2017 through 2019 are presented in Table 1. In addition to the length and weight of each fish, the dry-to-wet weight ratios are provided to convert the arsenic, mercury, and selenium concentrations wet weight values back to dry weight values as desired. Arsenic From 2017 through 2019, arsenic concentrations in the 183 fish collected were well below the USEPA recreational screening value of 1.2 µg/g (wet weight) (USEPA 2000). Mercury Of the 183 fish collected from 2017 to 2019, only two fish exhibited concentrations of mercury slightly above the USEPA recreational screening value of 0.4 µg/g (wet weight) (USEPA 2000). Both occurrences were in Largemouth Bass collected in 2019 at the reference sampling location (Table 1). Selenium From 2017 through 2019, selenium concentrations in the 183 fish collected were well below the USEPA recreational screening value of 20 µg/g (wet weight) (USEPA 2000). 7.0 References USEPA. 2000. Guidance for assessing chemical contaminant data for use in fish advisories. Vol. 1: Fish sampling and analysis. 3rd Edition. Washington, DC. Office of Water. 2 Roxboro Steam Electric Plant Afterbay Reservoir Cane Creek NORTH CAROLINA r ` r Auxiiary + tntak Main ♦ Z Area D am Plant Site ,` �♦ Intake Canal r Dry Ash Landfill i Discharge �..-'Ash Settling Pond - Outfall#003) % N t S Person-Caswell Lake Authority } r Cobbs Creek �---Area C r North Hyco Creek 0 1 2 3 South Hyco Creek I I I I Kilometers 0 1 2 L 1 I Miles Figure 1. Hyco Reservoir fish tissue monitoring locations from 2017 through 2019. 3 Table 1. Arsenic, mercury, and selenium concentrations (wet weight) in axial muscle tissue of fish in Hyco Reservoir from 2017 through 2019. Collection I Dry-to-Wet Date Location Fish Species Length Weight Ratios Arsenic Mercu Selenium 10/4/2017 i C Bluegill 165 i 81 i 0.19 i <0.04 i 0.16 1 0.51 --------- --------+......---------+---------------- +-------------+----------------+---------------------+--------------+---------------+-----------------I 10/4/2017 C Bluegill i 166 1 86 i 0.19 i <0.04 0.19 i 0.44 --------- --------+--------------+---------------- +-------------+-----------------------------------------------------+---------------+----------------- 1 i 10/4/2017 i �--------- -------+-------C--------i Bluegill i 168 i 76 i 0.17 i <0.03 0.17 0.83 ------------------------------+-------------+----------------1--------------------- +----------------- 10/4/2017 Ii C Bluegill 1 169 1 80 1 0.19 i <0.04 0.08 0.61 ---------------------+---------------- ---------------- +---------- - -----------------------------------------------------+---------------+-----------------I 6/28/2017 C Bluegill i 179 99 i 0.17 1 0.03 0.17 i 0.82 ' ---------- ---------+--------------- ---------------- +------------------------------+---------------------+--------------+---------------+----------------- i 6/28/2017 C Bluegill 182 106 1 0.18 0.13 i 0.21 1 0.56 i---------- ---------+--------------- ----------------- +----------------------------------------------------+--------------+----0---------------------------- I 6/28/2017 + C Bluegill i 174 99 1 0.19 i 0.04 i 0.10 ! 0.61 i---------- ---------+------------- ----------------- +----------------------------------------------------+--------------+---------------+----------------- I 6/28/2017 C Bluegill 180 i 98 i 0.19 0.04 ! 0.11 i 0.86 i---------- ---------+-------------- ---------------- +------------------------------+---------------------+--------------+---------------+-----------------i 6/28/2017 i C ---------- -- 181 - - 115 + 0.19 0.04 i 0.11 i 1.67 -------+- --- -------------- -----------+---------------------+--------------+---------------+----------------- 9/6/2017 C + 1 174 90 i 0.17 <0.03 ! 0.30 i 0.31 Blueg>11_________ 3/7/2017 ---------- -------+------C--------�--L---a-r emouth-B---a-s-s---+---286 303 i 0.21 0.15 i 0.16 i 0.86 I----------------------------------------------------------------+---------------+----------------- 3/7/2017 i C Largemouth Bass 303 399 i 0.21 0.13 i 0.24 i 0.86 ---------- ---------1---------------1---------------------------------------------F--------------------------------------+--------------+---------------+-----------------I 3/7/2017 1 C Largemouth +emouth Bass 305 i 392 i 0.20 i 0.14 i 0.15 i 0.90 + -i--------------------- ---------------- ------- ---------------------- -------------+---------------- ---------------------+--------------+---------------+-----------------i 3/7/2017 C Largemouth Bass 310 1 390 0.20 <0.04 i 0.25 1 0.78 11 ---------- --------+......----------+-------------------------------+--------------F----------------+---------------------+--------------+---------------+-----------------1 3/7/2017 i C i Lar emouth Bass i 335 i 545 i 0.20 i <0.12 i 0.19 i 0.82 --------- --------+----------------+-------g----------------------+-------------+----------------+--------------------+--------------+---------------+-----------------{ 3/7/2017 i C i Largemouth Bass i 341 ; 505 i 0.20 i <0.14 i 0.22 1 1.12 F---------- --------+------------------------ ----------------------+...----------+----------------+---------------------+--------------+---------------+-----------------{ 3/7/2017 C i Largemouth Bass i 341 + 521 i 0.20 i <0.04 i 0.21 1 0.88 ' --------- -------+----------------+------- -- --+-------------+----------------+-----0.20 < 3/7/2017 C i Largemouth Bass i 286 i 318 i 0.19 i <0.04 i 0.18 i 0.70 ---------------------+----------------+------- ----------------------+-------------+----------------+--------------------+--------------- ----------- ----+-------------i i 3/7/2017 i C i ------------------ --------+----------------�--L---a-r-g-e-m---o--u--t h-Bass--i---332 i 428 i 0.20 i <0.06 i 0.25 i 0.76 ------ -------- ------- -------------------- + ----------+----------------+------------------------------------- ---------------+------------ ----- i-3/7/201-7-----+ C Largemouth 716 i 0.20 i <0.06 i 0.32 i 0.72 -B --+-------------+----------------+----- --------------+--------------+---------------+----------------- 9/6/2017 C White Catfish 1 248 i 170 i 0.17 i <0.03 i 0.13 i 0.19 F---------------------+----------------+------------------------------+----------------------------------------------------+--------------- ---------------+-----------------1 9/6/2017 1 C i White Catfish i 261 1 213 i 0.18 i <0.04 ! 0.12 i 0.61 F---------------------+----------------+---------------------------- --------------I-----------------+---------------------+--------------+---------------+-----------------I 9/6/2017 1 C Ii White Catfish 267 i 227 i 0.18 i <0.04 i 0.14 i 0.27 --------------------------------------+----- ------------------------------+---------------------+--------------+---------------+----------------- 9/6/2017 1 C White Catfish i 268 1 236 i 0.19 i <0.04 i 0.06 i 0.21 ---------------------+----------------+------------------------------+-------------+--------------------------------------+--------------+---------------+-----------------{ i 9/6/2017 i C White Catfish 286 i 288 i 0.19 i <0.04 i 0.16 i 0.21 ---------------------+---------------- -------------+--------------------------------------+--------------+---------------+----------------- 9/6/2017 1i C White Catfish 293 1 315 i 0.19 i <0.04 i 0.09 i 0.95 ---------------------+----------------+-----------------------------+-------------+----------------+---------------------+--------------+---------------+-----------------I i 9/6/2017 ! C ! White Catfish ! 298 i 316 i 0.18 1 <0.04 i 0.09 1 1.58 i ---------------------+----------------+-----------------------------+-------------+----------------+---------------------+--------------+---------------+-----------------i 9/6/2017 i C i White Catfish i 305 i 315 i 0.19 1 0.04 i 0.09 ! 1.31 + + + + +I--------------------- ----------------+------------------------------+------------- ---------------- --------------------- -------------- ---------------I------------------1 i 9/6/2017 i C White Catfish i 335 ; 441 i 0.17 ! 0.03 i 0.07 i 0.31 iI----------------------------+F---------------- - ----------------- +i-------------+----------------+---------------------+--------------+---------------+----------------- 9/6/2017 C White Catfish 299 i 351 i 0.17 i <0.03 i 0.10 i 0.15i --------+------------F----------------+--------------------+-------------+---------------+----------------1 5/24/2017 i D I B-u-egill i----176 i 116 i 0.20 i 0.10 i 0.11 i 1.88 ---------------------+---------------------- ---------+----------------+----------------------+--------------+---------------+------------ -----I 5/24/2017 i D 1 180 1 114 1 0.21 i 0.06 i 0.07 2.08 5/24/2017 i D 1 182 1 137 i 0.21 i 0.13 i 0.08 i 2.04 ------- - ----- -+--------------------------------- +------------------------------+------------------------------------- ---------------+-----------------1 5/24/2017 i D i Bluegill i 184 i 140 i 0.19 i 0.04 i 0.09 i 1.62 i------- - ----- -}--------------------------------- +--------------P-----------------------------------------------------+---------------+----------------- I 5/24/2017 D 1 186 i 157 i 0.20 i <0.12 i <0.05 1.54 I------- - -------+-------------------------------- +-------------+--------------------------------------+--------------+---------------+-----------------I 5/24/2017 i D 1 ---B _________i----188 142 i 0.22 i-<0.07 i <0.06 i 1.89 -- --- +-------------------- ----------P----------------4----------------------+ ------------+---------------+----------------- 5/24/2017 i D 1 Bluegill_________ 193 + 145 1 0.20 <0.08 i 0.08 1 1.96 I------- - ---------+----------------+----------------- +-------------+----------------+---------------------+-------------+---------------+-----------------1 5/24/2017 i D i Bluegill i 195 + 128 i 0.17 1 <0.20 i 0.09 1 2.24 F------- - ----- -+-------------------------------- +--------------P 128 1 ------------+---------------+-----------------i 5/24/2017 D Bluegill i 196 1 141 i 0.17 <0.20 i 0.07 1 1.80 F------- - -------4-----------------I----------------- +--------------F----------------1----------------------+--------------+---------------+----------------- I 5/24/2017 ; D 1 Bluegill i 205 1 150 1 0.17 i <0.20 i 0.07 ! 1.97 F---------- ----- ------------------I----------------- +--------------p-----------------------------------------------------+---------------------------------I i 3/7/2017 i D ; Largemouth Bass 303 1 352 i 0.20 i 0.18 i 0.23 i 1.08 I-------- ----- -4-----------------+-------- -------------------------------------F-----------------------------------------------------+---------------+----------------- 1 3/7/2017 i D i Largemouth Bass i 315 1 346 i 0.20 i <0.18 i 0.18 i 1.62 ---------- ----- -+----------------+------- -------------------------------------P--------------------------------------a---------------+---------------+-----------------1 3/7/2017 D Largemouth Bass ! 323 367 i 0.20 i 0.10 0.21 i 1.94 4 Collection Dry-to-Wet Date Location Fish Species Length Weight Ratio' Arsenic Mercury Selenium 3/7/2017 -------- ----......+i D Largemouth Bass 345 555 i 0.21 i <0.19 i 0.21 i 1.51 ------- ------- +-------------------------------a-------------------------------------+---------------+------------ ----------------- 1 D Largemouth Bass 326 i 429 i 0.21 i 0.15 i 0.22 --------------------+------ --------+-------g------------------+-------------+----------------+---------------------+--------------+---------------+ -------------2.08II i 3/7/2017 i D i Largemouth Bass 328 i 491 0.21 i 0.25 i 0.19 i 1.58 i �------------------+-----------------------------------------------+----------F----------------+---------------------+--------------+---------------+----------------� 3/7/2017 D La i Laremouth Bass 334 i 43 i ------- ---------+--------------+------ ------------- 0.19 i 0.15 0.24 2.03+------- ----------+------- ----+---------------+ ------------- 3/7/2017 I i D i Largemouth Bass i 339 i 479 i 0.20 1 0.18 ; 0.27 i 1.98 ---------------------+----------------+------- ----------------------+-------------+----------------+------------------------------------+---------------+----------------I 3/7/2017 i D i -------------- ---- --- + Lar emouth Bass 348 i - 479 i 0.20 i 0.10 i -----------i 2.12 --------+---------------- - g--------------------- +-- ----------+ +---- . +------------ -----i3/7/201-7------i+ D i Laremouth Bass 353 i 575 i 0.20 i 0.14 i 0.29 i 1.74 ------ ------- ------g---------------------+------------- ---------------- jI 9/19/2017 i D i White Catfish i 202 i 76 i 0.17 i 0.03 i <0.05 i 1.41 F-------------------+---------------+-----------------------------+-------------+----------------+------------------------------------+---------------+-----------------I 9/19/2017 i D i White Catfish i 202 i 87 i 0.17 i 0.03 i 0.12 i 1.34 ---------------------+----------------+------------------------------+-------------+----------------+---------------------+--------------+---------------+-----------------I i 9/19/2017 i D i White Catfish i ---- --- ---------+--------------+----- ---+-- . . . 0.87---------------------------+-------0 -7-------- ----+---------------+----------------- 9/19/2017 + i D i F-------- --------+ White Catfish 228 i 116 i 0.16 i 0.03 i 0.08 i 1.02 -------------- -------------+----------- ---------------+------------------------------+------------- ----I i 9/19/2017 i D i White Catfish i 234 i 132 i 0.17 i 0.03 i 0.06 i 1.17 i --------- ------ -+---------------+-----------------------------+-------------+----------------+---------------------+--------------+---------------+-----------------I i 9/19/2017 D i White i Catfish 237 i 156 i 0.17 i 0.03 i 0.07 i 1.00 ---------------------+---------------- ------------- ----------------+--------------------- + - - +----------------- 9/19/2017 I i D White Catfish i 240 178 i 0.18 i 0.04 i 0.06 i 0.85 i ----------------+----------------+-----------------------------+-------------------------------+---------------------+--------------+--------------+----------------- I 9/19/2017 i D i White Catfish 269 i 227 i 0.18 i 0.04 i 0.09 i 0.77 -------- --------+----------------+----------------------------+-------------+----------------+---------------------+--------------+-------------+-----------------I 9/19/2017 D i White Catfish__ 271 i 236 i 0.19 0.04 +i-----0--.-1-0-- 1.46 ---------------------+--------------- +--------------F----------------+---------- -------+-------------- ----+----------------- 9/19/2017 i i D F------------------+ White Catfish 275 i 240 i 0.18 i <0.04 i 0.13 i 1.06 ------ -------- ------------------------------+---------------------+--------------+---------------+- ------------i i---------------------+----------------4--------------------------------+-------------+--------------------------------------+--------------+---------------+-----------------i 6/8/2018 i C i Bluegill i 176 i 97 i 0.20 i 0.04 i 0.07 0.48 12/19/2018 C i i Bluegill 159 66 i 0.19 <0.03 i 0.08 ----------------------+--------------------------------- + +i-----0-.42 ----i 12/20/2018 165 C -----------------+------- + ------- 75 i 0.19 <0.03 0.09 0.29 -------------------------------------------------------------------+---------------+----------------- 12/20/2018 I i C I - Blue ill 165 79 i 0.21 <0.03 0.07 i - ----+--------------+---------------- + +-----0--.-4--0------i -12/20/2018 i C i i 170 i 81 0.19 <0.03 0.03 0.30 --- -- ---------+--------------+--------B-uegil +-----------+----------------+---------------------+-------------+-------------+----------------I -------- ----------+ i -12/20/2018 C Blueill_________ 172 i 84 0.18 i + 0.10 i 0.47 0.05 ------ ------- ---------------- -------------+----------------+---------------------- -----------+- -----------+-----------------I 12/20/2018 C ----------------------------------------------------------------+++- Blu eill +i 185 i 110 i 0.14 ;i 0.03 i 0.05 i 0.25 --------------------------------g +-----------------------------+---------------------+--------------+---------------+------------ ----- 12/19/2018 C Bluegill i 144 - -50 i 0.18 i <0.03 ---0.08 i 0.27k -- - - ----+-------------- ---------------- +-------------- ----------+---------------------+---------- -+ -----------+----------------- -12/19/2018 i C RedearSunfsh i i 210 i 0.20 i 0.05 i 0.12 i 0.48 ----+------ -------- ------------------------------- ---+----------------- ---------------------+--------------+---------------+-----------------i-12/19/2018 C Warmouth 169 ; 101 0.20 0.03 i 0.13 i 0.40 ------ --------+-------------------------------+--------------F----------------+---------------------+- -----------+ -----------+----------------- 6/8/2018 C Largemouth Bass 320 409 i 0.20 i 0.08 i 0.17 i 0.54 -------------+-- -- -+------ II{I ---------------------+---------------------+--------------+---------------+-----------------I 6/8/2018 C i Largemouth Bass : 339 509 i 0.20 i 0.06 i 0.26 i 0.58 �------ ---------+---------------- ------- ----------------------+-------------+----------------+------------------------------------- ---------------+-----------------I 6/8/2018 i C i Largemouth Bass i 296 i 274 i 0.20 i <0.11 i 0.15 i 0.58 ------- ---------+-------------+------fl----------------------+-------------+----------------+---------------------+--------------+---------------+-----------------I i 6/8/2018 i C i Largemouth Bass i 299 i 292 i 0.20 i <0.13 i 0.24 i 0.66 i -------- ----------+----------------+------------------------------+--------------F----------------+--------------------+-------------+---------------+-----------------I 6/8/2018 i C i I--------- -------+ Largemouth Bass 306 1 333 ---- ---- 0.20 i <-0.15--+i ---0--.-2-8-----+----0--.-6--4 ---------------+-------g--------------------- ------------- -----------------+----------- 6/8/2018 -----I C Largemouth Bass 316 i 407 0.20 ! <0.08 i 0.22 i 0.66 ---------------------- ------------+------- ----------------------+----------------------------------------------------+--------------+---------------+----------------- { 6/8/2018 ! C i Largemouth Bass 1 322 i 458 i 0.21 i <0.16 i 0.19 i 0.63 ------- ---------+------------ ------- -----------------------+-------------+-----------------------------------------------------+---------------+----------------- I i 6/8/2018 i C Largemouth Bass 1 331 i 476 i 0.20 i <0.09 0.20 i 0.68 i F------- ----------+--------------- ------- ----------------------+--------------I----------------+---------------------+-------------+--------------+-----------------I 6/8/2018 i------C---- Largemouth Bass i 339 i 4-9--5-- i 0.20 0.15 0.28 i 0.64 --------------------- -+------------------ -----+------- - ------- +----------------- 6/8/2018384I------ ------ ------C-- Largemouth Bass 384 821 i 0.21 0.08 i 0.25 ik- - ------+ ----------+------ ------------------------------------ - + ---------------+-----0--.-5--7 -12/20/201-8--+-----C + Channel Catfish 3 + i .......i------------------------------ -----7 -- 400 0.19 <0.03 i- 0.08 0.25 ------�i 8 ----- -----+------- ---------+ --+ ---------+----------------- 12/20/2018 i C i Channel Catfish 541 i 1500 i 0.18 i <0.03 0.29 i 0.40 I------- ----------+----------------+-----------------------------+------ -----+----------------+---------------------+-------------+-------------+-----------------I 12/20/2018 i C i Channel Catfish i i60 i 1700 i 0.20 i <0.03 i 0.08 i 0.42 ---------------------+----------------+------------------------------+-------------+----------------+---------------------+--------------+---------------+-----------------I 12/20/2018 i C Channel --------- -- Catfish 610 i 2500 i 0.18 i <0.03 i 0.34 -0.32 I----+------ -------- +--------------F----------------+---------------------+-------------+- ------- ------------- 12/20/2018 C Flat Bullhead i 305 400 i 0.19 i 0.03 i 0.17 0.25 ----------------+-------------�---------------------------+------ ------------------+-------------------+-------------+---------------+-----------------I 12/20/2018 i C ! White Catfish 342 i 510 i 0.18 i 0.03 i 0.09 ' 0.29 i ------- ---------+----------------�------------------------------+-----------+----------------+---------------------+--------------+---------------+----------------- 12/20/2018 i C i White Catfish 375 i 710 i 0.17 i 0.03 i 0.12 i 0.27 ---------------------+----------------+-------------------------------+-------------+----------------+---------------------+--------------+---------------+-----------------I 12/20/2018 i C White Catfish 580 i 2600 0.19 i 0.03 ' 0.23 0.38 ----------------- 5 Collection Dry-to-Wet Date Location Fish Species Length Weight Ratio' Arsenic Merc Selenium 12/20/2018 i C White Catfish i 339 i 541 1 0.18 i 0.03 1 0.10 1 0.36 ' ---------- ---------+------- -------+-------------+----------------+---------------------+--------------+---------------+-----------------i 6/6/2018 D Bluegill 161 1 90 1 0.20 1 0.13 1 0.03 i 1.16 ---------- ---------+----------------+---------------- --------------------------------------------------------------------+---------------+----------------- � 6/6/2018 D i Bluegill 1 161 1 92 1 0.21 ! 0.10 i 0.03 i 1.43 F--------- -------+-------------- ----------------- +-------------------------------------------------------------------- ---------------+----------------- � 6/6/2018 D + Bluegill 1 166 1 103 + 0.20 1 0.09 1 0.04 1 1.32 F--------- ---- --+--------------+---------------- +-----------------------------------------------------------------------------------+----------------- { i 6/6/2018 i D Bluegill 1 174 1 105 1 0.19 1 0.14 1 0.06 1 1.16 i -------- ---------+-------------------------------- +--------------i---------------+----------------------------------------------------+----------------- i 6/6/2018 D 1 Bluegill 1 183 117 1 0.19 1 0.10 1 0.04 1 1.25 -------- ----- --+------ ------I------------------------------+------------------------------+---------------------+--------------+---------------+-----------------i 6/6/2018 i D Bluegill i 191 + 119 1 0.19 1 0.08 ! 0.06 1 1.31 --------- --------+------------I----------------- +--------------F----------------+---------------------+--------------+--------------+-----------------� 3/15/2018 D Bluegill_________! 173 95 1 0.19 1 <0.15 ; 0.06 1 1.50 --------- ---------+------------a---------------- +----------F----------------}---------------------+--------------+---------------+-----------------{ 3/15/2018 D Bluegill 181 105 1 0.18 ! <0.25 i 0.06 i 1.24 F--------- ---------+------------- ---------------- +-------------+----------------+------------------------------------+---------------+-----------------{ 3/15/2018 D 181 i 108 i 0.19 1 <0.09 i 0.06 i 2.05 Bluegill 3/15/2018 D Bluegill 191 1 139 i 0.20 ! <0.16 i 0.05 ! 1.54 ---------------------+----------......+---------------- +-------------+----------------+---------------------+--------------+---------------+-----------------i 3/15/2018 D ! Largemouth Bass ! 297 1 326 i 0.21 1 0.23 i 0.19 i 0.84 �---------- ---------+-------------+----------------- ---+-------------+----------------+---------------------+--------------+---------------+-----------------� 3/15/2018 D Largemouth Bass 302 1 363 1 0.21 1 0.17 ! 0.15 ' 0.86 ' ------------------+-------------+------- - ---+-------------+----------------+---------------------+--------------+---------------+-----------------i 3/15/2018 i D i Largemouth Bass i 319 i 475 ! 0.21 1 0.18 i 0.17 1 0.90 -------- ---------+-------------+------- ----------------------+-------------+--------------------------------------+--------------+---------------+----------------- � 3/15/2018 D Largemouth Bass 1 324 1 450 1 0.21 1 0.16 1 0.25 ' 1.03 k--------- ---------+------------- ------- - ---+-------------+---------------- ------------------------------------+---------------+----------------- i 3/15/2018 D Largemouth Bass i 325 1 465 1 0.20 i 0.07 0.15 1.38 i-------- --------+-------------4-------- - ---+--------------F--------------------------------------+-------------+--------------+-----------------� 3/15/2018 D Largemouth Bass 1 352 1 597 1 0.21 i 0.23 1 0.27 0.90 --------- ---------+---------------+------- ----------------------+-------------+----------------+------------------------------------+---------------+----------------- � 3/15/2018 D Largemouth Bass ; 355 1 630 1 0.19 i 0.14 ; 0.25 1 1.22 ------------------+------------+------- ----------------------+-------------+----------------+---------------------+--------------+---------------+----------------- i 3/15/2018 D Largemouth Bass i 321 1 409 i 0.20 i 0.24 1 0.32 1.32 k------ -- ---------+----------------�------- -------- ---+------------------------------+---------------------+--------------+---------------+----------------- { 3/15/2018 D 1 Largemouth Bass 1 327 1 454 i 0.21 i 0.20 1 0.29 1.28 F-------------------+------------------------- ----------------------+-------------+--------------------------------------+--------------+---------------+----------------- i 3/15/2018 D 1 Largemouth Bass ; 330 ; 508 1 0.19 i 0.11 1 0.23 1 1.39 ------ ------------+----------------}-------- -------------------------------------+--------------------------------------+--------------+---------------+----------------- i 12/20/2018 D ; Channel Catfish 1 526 + 1300 1 0.19 1 <0.03 1 0.08 1 0.68 ---------- ---------+----------------+-------------------------------+-----------------------------+---------------------+--------------+---------------+-----------------i 12/20/2018 1 D i Channel Catfish ; 490 1 1084 i 0.19 i <0.04 ; 0.05 i 0.78 --------- --------+----------------+-------------------------------+------------------------------+---------------------+--------------+---------------+-----------------i 12/20/2018 1 D Channel Catfish 1 544 1 1326 1 0.20 1 <0.03 1 0.10 1 0.64 ---------- --------+----------------+-------------------------------+-----------------------------------------------------------------------------------+-----------------i 12/20/2018 1 D i Flat Bullhead 280 1 278 1 0.18 1 0.03 1 0.07 1 0.27 ---------- --------+----------------+-------------------------------+-----------+----------------+---------------------+--------------+---------------+-----------------� 12/20/2018 1 D 1 White Catfish 370 1 633 i 0.16 i 0.02 1 0.07 1 0.26 ---------- --------+----------------+-------------------------------+-------------------------------------------------------------------+---------------+-----------------i 12/20/2018 1 D i White Catfish 292 1 299 1 0.18 1 <0.03 ! 0.06 1 1.06 ' --------------------------------------}--------------------------------+------------------------------+---------------------+--------------+---------------+-----------------i 12/20/2018 1 D 1 White Catfish 310 ; 360 1 0.15 ! 0.02 1 0.10 1 0.29 k---------- --------+------------------------------------------------+-----------------------------------------------------------------------------------+-----------------{ 12/20/2018 1 D + White Catfish 1 385 ; 657 1 0.17 1 0.03 1 0.08 ; 0.15 ----------------------------------------------------------------------+----------------------------------------------------+--------------+---------------+----------------- � 12/20/2018 D White Catfish 400 1 908 0.17 ! 0.03 1 0.07 i 0.32 --------- --------+---------------�-------------------------------+-----------k----------------+---------------------+--------------+---------------+-----------------i 6/8/2018 D 1 White Catfish i 254 1 174 1 0.21 1 <0.03 1 0.04 1.74 ---------- --------+------------------------------------------------+-----------i--------------------------------------+--------------+--------------+----------------i 12/11/2019 C i Bluegill_________I 140 1 40 1 0.19 1 0.17 1 <0.06 1 0.67 --------- --------+---------------+----------------- +----------....k--------------------------------------+--------------+---------------+-----------------� 12/11/2019 C Bluegill 155 1 68 1 0.18 i 0.16 i 0.07 0.51 ---------------------+----------------+---------------- +---------------------------------------------------+--------------+---------------+-----------------� 12/11/2019 C Bluegill ! 192 1 116 1 0.19 i 0.16 1 0.09 i 0.58 F-------------------+--------------------------------- +------------------------------+------------------------------------+---------------+-----------------i i 6/28/2019 C Redear Sunfish 1 254 1 235 1 0.21 i 0.23 1 <0.06 i 1.33 F------- --------------------------4--------------------------------+------------------------------+---------------------+--------------+---------------+-----------------� 12/11/2019 C Redear Sunfish 1 220 1 166 1 0.19 1 0.15 1 0.11 1 0.53 ' -------------------+---------------- ------------------------------+------------------------------+------------------------------------+---------------+-----------------i 12/11/2019 C Redear Sunfish 224 1 190 i 0.20 1 0.17 1 <0.06 ' 0.58 ' ---------------------+---------------+-------------------------------+----------------------------------------------------+--------------+---------------+-----------------i 6/28/2019 1 C Redear Sunfish 202 1 138 1 0.21 1 0.18 ! 0.09 1 0.64 ---------------------+----------------�------------------------------+-------------+-----------------------------------------------------+---------------+-----------------a 6/28/2019 C Redear Sunfish 202 1 138 0.20 i 0.74 1 <0.06 ! 1.37 --------------------+--------------�------------------------------+-------------------------------------------------------------------+---------------+-----------------i 6/28/2019 C i Redear Sunfish 220 191 1 0.21 i 0.18 i 0.07 i 0.54 r------ ----------4-----------------}-------------------------------+-------------+-----------------------------------------------------+---------------+-----------------i 6/28/2019 1 C Redear Sunfish 234 1 206 1 0.17 1 0.20 1 0.10 1 1.90 r---------------------+----------------+------------------------------+-------------+----------------+---------------------+------------+----------+----------------i 6/28/2019 1 C i Redear Sunfish i 234 i 208 1 0.21 i 0.17 ! <0.06 ! 0.63 ------- ---------+----------------+------------------------------+-------------+--------------------------------------+--------------+---------------+-----------------i 9/4/2019 1 C 1 Largemouth Bass 1 315 1 339 1 0.20 i 0.16 1 0.21 1 0.49 ' r---------------------+----------------}-------- ----------------------a--------------+----------------+----------------------+--------------+---------------+----------------- ' 9/4/2019 i C !__Largemouth Bass ; 327 402 1 0.20 i 0.24 ! 0.20 i 0.62 I--------------- --+-------------- ----- ----------------------+-------------+--------------------------------------+--------------+---------------+----------------- � 9/4/2019 C Largemouth Bass 342 546 0.21 0.18 <0.33 0.53 6 Collection Dry-to-Wet Date Location Fish Species Length Wei ht Ratio' Arselli_c Mercu Selenium 9/4/2019 C i Largemouth Bass- 362 i 519 i 0.20 i 0.18 i 0.24a-----0--.-5--6 ---------------------+---------------- +------------------------------------------------------------------- -9/4/2019-----+ Lam 756 0--- 1 ------C -+-- -- --- ------- -----+------- == - -+------- - --- 0 59 - -- -------- 6/28/2019 -ii C Largemouth Bass i 351 563 i 0.21 i 0.18 i 0.25 i 0.54 F-------- ------ -+----------------+------- ------- --a--------------+----------------+---------------------+--------------+---------------+----------------- g- � 9/4/2019 C Lar emouth Bass i 331 i 437 i 0.20 i 0.18 i 0.38 0.53 ----------------- 9/4/2019 + CLaremouth Bass 390 787 0.200. L .4 0.66- ----- ------ ------- -- g --+--- ---- --- -----+------- -------+-- 9--- -01- 1 --- ---- 6/28/2019 i i C i F--------------- --------- -+ ---.......�--L---a-r emouth Bass i 326 i 420 i 0.20 i 0.22 i 0.16 + 0.60 ------- -------+-------g----------------- a---------------F----------------+---------------------+--------------+---------------+------------ ----- �-9/4/201-9------i+ C L i i ...... rg-mouth . . . . - - -+---- ----+------- -- -+------- -------+----0-- ---------------+----------------- 12/11/2019 ii! C ------------------ ------- Flat Bullhead i 260 i 170 i 0.18 i 0.13 <0.05 i 0.33 i+--------- ---------+-------------+--------------------------------------+--------------+---------------+----------------- 9/4/2019 F--------------- -+ C White Catfish 1 265 i 194 i 0.13 i 0.09 i 0.08 i 0.23 ----- ------- -----+-------------F----------------+------------------------------------+---------------+------------ ----- 9/4/2019 CWhite Catfish---- 275 244 i 0.18 i 0.14 --<0.05 i 0.27 ---------------------+---------------- +-------------+----------------+------------------------------------+ -------------+----------------- 9/4/2019 �a i C i White Catfish 290 i 270 0.17 0.13 0.06 i 0.26 �-------- -- -----+----------------+-------------------------------+------- -+--------------+------------------+-------------+---------------+----------------i 9/4/2019 C i White Catfish i 315 349 i 0.17 i 0.13 i 0.05 i 0.25 F-------------------+----------------+------------------------------+-------------+----------------+---------------------+--------------+---------------+-----------------I F---1--2----/----1-1--/2----0------1--9--++ i White Catfish----i---317 410 +i 0.16 i 0.12 i 0.09 --0.25 ------- ----- -----------F----------------+---------------------+--------------+----------- ------------ -12/11/2019 C i White Catfish 365 i 676 0.17 i 0. 3 i 0.07 0.21 ------- ------------- -----+------------------------------ ---- -----------------------+-------------+----------- + -------------a{ --1-2--/--11/2019 C White Catfish ; 380 i 646 i 0.18 0.13 i 0.08 i -- -----+------ --------+------------------------------- +----------------+ + 0--.73 ---i 12/11/2019 I C i White Catfish i 425 i 1022 i 0.15 0.12 i 0.10 i 0.51 s------------------+----------------4--------------------------------+-------------+----------------+---------------------+-------------+---------------+-----------------� 9/4/2019 C White Catfish ; 293 240 i 0.17 i 0.12 i 0.06 ! 0.78 i--------------- -i---------------- ------------------------------+------------ ----------------+------------------------------------+---------------+-----------------� 6/27/2019 i D Bluegill i 184 1 111 i 0.20 ; 0.20 i <0.06 i 1.35 i ------- ------- -+---------------}---------------- +------------------------------+---------------------+--------------+---------------+----------------- i i 6/27/2019 i D i--------------------- + Bluegill i ------+------ ------ ---------------- _______-_+----2--0-1------ 117 i 0.18 0.26 <0.05 1.83 ------ -------+---------------------+--------------+---------------+------------ ----- -9/4/2019------ D Bluegill i 170 i 75 i 0.19 i 0.21 i 0.06 i ---------------- ---------------- i--------------+----------------+---------------------+--------------+---------------+------1-.-5--4------- 12/11/2019 {i D Bluegill 167 i 76 i 0.19 i 0.26 i <0.06 i 1.42 ------------------+---------------------------------- +-------------+----------------+---------------------+--------------+---------------+-----------------� 12/11/2019 D Bluegill i 174 1 84 i 0.19 i 0.20 i 0.06 i 1.73 ------- ------- -+---------------+---------------- +------------------------------+---------------------+--------------+--------------+-----------------� 12/11/2019 D Bluegill i 180 91 i 0.19 i 0.21 0.07 i 1.5 ---------------------+-------------- ----------------- +------------------------------+---------------------+--------------+---------------+-----------------� 12/11/2019 - -----D Bluegill i 180 i 91 i 0.18 i 0.21 0.07 i 1.42k-- -- ---+ ---------------- +------------- ----------------+---------------------+--- + ----+----------------- 12/11/2019 +i D i Bluegill i 181 i 81 i 0.16 i 0.20 i 0.07 i 1.33 i -----------------+----------------+----------------- a--------------+----------------+---------------------+--------------+--------------+----------------- i 6/28/2019 D i Redear Sunfish 1 202 i 128 0.20 i 0.18 i <0.06 2.52 -------------------+----------------+-------------------------------a--------------+----------------+---------------------+--------------+-------------+---------------{ 6/28/2019 i D ------------ Redear Sunfish i 206 i 142 i 0.21 i 0. 6 i <0.06 ------- +- -1-.-7--9 -------{ 6/28/2019 i D Largemouth Bass i 386 i 706 0.19 i 0.18 i 0.19 i 1.18 ------ ---------+------------+------- --------------------+-----------------------------}---------------------+--------------+---------------+-----------------i 9/4/2019 i D i F------- ----------+----------------+--L---a-r-gemouth Bass i 305 ; 359 1 ------0--.2---1------+---0--.-2--3----+i----------- i 1.65 ---------------------+------------- --+----------------{ i 9/4/2019 D i Largemouth Bass 333 i 485 i 0.23 i 0.23 i 0.21 i 1.80 F----------------+----------------+------- ------------------------------------+---------------------------------------------------------------------+----------------- � 11/26/2019 i D i --------- ----- -+ Largemouth Bass 287 298 i 0.17 i 0.19 --0--.-0--6-- i 1.75 ------ --------+------- -- --+-------------+----------------+---------------------+----- ---+----------------- 11/26/2019 i i D i Largemouth Bass 288 i 268 i 0.22 i 0.29 i 0.11 i 1.94 ------------------+----------------+-------------------------------+------------------------------+---------------------+--------------+---------------+-----------------i 11/26/2019 i D Largemouth Bass i 293 281 i 0.22 i 0.27 i 0.09 ! 2.13 ------ ------ -+----------------+------- ---------------------------------------------------------------------------+--------------+---------------+----------------{ 11/26/2019 D i -- Largemouth Bass + 294 i 340 0.23 ----i----0--.-2-6-----+i----0--.-1--2 --- --- +------- -------+------- --------------------- ------------------------------+ ----+----0--.-4--9 ------- --1--1-/-2-6-/2--0-1-9-.... -D-- +--L----- ----------- Bassa1 ------ ------ . . . 2.00 - - -+----- ------F----------------+------- - -------+ 0-2 - +---------------+----------------- 11/26/2019 ! D i Largemouth Bass i 304 i 344 i 0.21 i 0.26 --0--.-0-8- 0.51 ---------------------+---------------+------- -- --+------------+----- -----+------- --------+---- ----+----------------- 11/26/2019 � i D i Largemouth Bass i 305 351 i 0.23 i 0.26 0.09k---- +------ --------+-------g----------------------+ + + 2.49------------ 11/26/2019 { i D ! ------- ------- -+- Largemouth Bass 380 670 i 0.22 i 0.27 0.20 i 1.74 i------ ------- -- ---------------- -----+---------------------+--------------+ -----------+----------------- 11/26/2019 D Largemouth Bass ; 460 1 1150 i 0.19 i 0.19 i 0.34 i --- --------------+-------g----------------- 0.44 - +------------------------------+---------------------+--------------+---------------+------ ----- 9/4/2019 i D i Largemouth Bass ; 340 ;------5-2--7------+i--------0--.2---1--------+i----0--.-4--0-----+i-----0--.-23 -- --------+------ --------+------- ----------------------+ i 1.98 ----12/11/2019 D Channel Catfish -+ ------------ . . . � 0.85 12/11/2019 i D ! Channel Catfish 520 i 1150 i 0.18 i 0.14 i 0.06 i 1.04 ------- ------- -+----------------+------------------------------+------------+----------------+---------------------+ ------------+---------------+-----------------i i 12/11/2019 i D - + Channel Catfish 530 1400 0.18 i 0.14 i <0.05k-- -- - +------- ------- i 0--.-7--3-------� 12/11/2019 i D i i - Channel Catfish 1 538 1400 0.19 i 0.15 i 0.06 i 0.66k-- -- ---+--------------+--- -------------+----------------------------------------------------+---------------+----------------- 12/11/2019 { D Channel Catfish i 552 i 1250 i 0.17 i 0.13 i 0.09 i 0.77 i F------ - -------+----------------+------------------------------+------------------------------+---------------------+--------------+---------------+-----------------� 12/11/2019 D i Channel Catfish 500 950 i 0.19 0.16 <0.06 0.82 ------------- 7 Collection Dry-to-Wet Date Location Fish Species Length Weight Ratio' Arsenic Merc Selenium 12/11/2019 D Channel Catfish 505 1050 1 0.17 1 0.13 1 0.11 1 1.2 11 6 --------- --------+----------------+------------------------------+-------------+-----------------------------------------------------+---------------+-----------------� 12/11/2019 D Snail Bullhead 284 1 2201 0.18 1 0.15 i 0.06 1 0.45 I--------- --------+------------1-------------------------------+------------+--------------+--------------------+-------------+---------------+---------------1 12/11/2019 D i White Catfish i 388 1 730 1 0.16 i 0.12 1 0.07 1 0.30 ---------- ---------+---------------+---------------------------+-----------+----------------+------------------------------------+---------------+-----------------1 12/11/2019 D White Catfish 405 804 0.16 0.12 0.08 0.84 --------- ---------------------------------------------------------- ----------=----------------=----------16 ------ To convert to a dry weight,divide the wet weight concentrations by the dry-to-wet weight ratio. 8