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Home My WebLink AboutNC0001970_Annual Report_20230623i TRC 2023 First Semi -Annual Groundwater Monitoring Report Pickles Manufacturing LLC (Formerly Bay Valley Foods, Formerly Dean Pickle and Specialty Products) Brine Yard Area June 23, 2023 Prepared by: Jim Hurley, MS, El Project Environmental Engineer I TRC Project No. 528255.0003.0000 Prepared For: Pickles Manufacturing, LLC 354 North Faison Avenue Faison, Duplin County, North Carolina Prepared By: TRC Companies LLC 114 Edinburgh South Drive, Suite 200 Cary, NC 27511 Reviewed by: Andrew Rodak, P.E. Senior Project Manager i TRC TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................................................1 2.0 GROUNDWATER MONITORING...................................................................................2 2.1 Groundwater Elevations..................................................................................................... 2 2.2 Groundwater Sampling....................................................................................................... 2 2.3 Groundwater Analytical Results......................................................................................... 2 3.0 STATISTICAL EVALUATION OF CONCENTRATION TRENDS....................................3 4.0 CONCLUSIONS AND RECOMMENDATION..................................................................3 5.0 REFERENCES................................................................................................................4 TABLES Table 1 Depth to Groundwater Measurements and Groundwater Elevations Table 2 Historical Chloride Concentrations in Monitoring Wells Table 3 Historical and Current Total Dissolved Solids Concentrations in Monitoring Wells FIGURES Figure 1 Site Location Map Figure 2 Site Layout Figure 3 Potentiometric Surface Map - March 2023 Figure 4 Chloride and Total Dissolved Solids Concentrations - March 2023 APPENDICES Appendix A Groundwater Quality Compliance Forms (GW-59), Laboratory Analytical Report and Chain -of -Custody Records Appendix B Chloride and Total Dissolved Solids Concentrations Through Time Charts Appendix C Mann Kendall Statistical Analysis Worksheets First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 i 10 Ik TrRC 1.0 Introduction TRC Companies LLC (TRC) presents this first Semi-annual Report of 2023 for Tri-annual Sampling — First Event, summarizing the results of the March 2023 groundwater monitoring activities at the Pickles Manufacturing (PM) (formerly Bay Valley Foods, LLC, formerly Dean's Pickles and Specialty Foods) facility in Faison, North Carolina. Bay Valley is located approximately 2,000 feet north of the center of Faison, near the intersection of North Carolina Highways 117 and 403 (Figure 1). Groundwater monitoring at the Pickles Manufacturing site is conducted in accordance with the North Carolina Department of Environmental Quality (NCDEQ) Division of Water Resources (DWR) program that includes collecting groundwater samples from six monitoring wells associated with lined lagoons. The monitoring wells MW-1 through MW-5 and MW-8 are sampled tri-annually (i.e. every four months), and reports are prepared and submitted semi- annually to the DWR Regional office in Wilmington, North Carolina. The laboratory analytical results for monitored constituents are also submitted semiannually to the DWR office in Raleigh, North Carolina on Groundwater Quality Compliance Report Forms (GW-59). Additional monitoring wells on the site were installed for compliance with the NCDEQ - Division of Waste Management (DWM) program and are not associated with the lined lagoons; therefore, laboratory analytical results from the DWM monitoring wells are not discussed in this report. Forms for the March 2023 groundwater monitoring event are provided in Appendix A. The site layout is shown in Figure 2. Constituents monitored as part of the DWR events include: • Aluminum • Sulfate • Sodium • pH • Chloride • Orthophosphate • Nitrate • Total Dissolved Solids (TDS) • Ammonia • Total Organic Carbon (TOC) The primary constituents of concern at the site under the DWR monitoring program are chloride and TDS; therefore, this report details findings for these constituents. In 2000, PM installed linings in the treatment lagoons and drying beds to minimize vertical movement of constituents of concern (COCs) into groundwater. In 2009, PM installed a new, lined stormwater retention pond and sentinel monitoring well MW-8. Since 2007, PM has performed all groundwater sampling at the site. TRC has not supervised, directed, or conducted any activities related to groundwater monitoring, and has prepared reports based exclusively on information provided by PM. The results summarized in this report are for the March 27, 2023 sampling event. First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 1 �i TrR C 2.0 Groundwater Monitoring 2.1 Groundwater Elevations In March 2023, prior to collecting groundwater samples, PM personnel measured depth -to - groundwater in six monitoring wells (MW-1, MW-2, MW-3A, MW-4A, MW-5, and MW-8). The monitoring wells are located upgradient of, downgradient of, or cross -gradient to the lagoons. PM personnel measured depth -to -groundwater from an established measuring point on the polyvinyl chloride well casing using an electronic water level indicator (Table 1). The depth -to - groundwater measurements were used to calculate the groundwater elevation in feet above mean sea level (ft-amsl). TRC used the groundwater elevations to prepare potentiometric surface maps (Figure 3). Based upon the groundwater elevations, groundwater at the site likely flows to the west toward Panther Branch, which is consistent with previous reports. 2.2 Groundwater Sampling On March 27, 2023 Bay Valley personnel reportedly collected groundwater samples using new, disposable, "sink -fast" bailers and nylon twine. Each well was purged by removing approximately five gallons of water, or until dry. Once dry, wells were allowed to recharge prior to sampling. Samples were collected directly into laboratory -supplied containers, placed in a cooler on ice, and shipped under standard chain -of -custody protocol to Environmental Chemists of Wilmington, North Carolina, a North Carolina certified laboratory, for analysis. The current and historical laboratory analytical results for chloride and TDS are summarized in Tables 2 and 3, respectively. Copies of the laboratory analytical reports and chain -of -custody records are provided in Appendix A. 2.3 Groundwater Analytical Results TRC compared the laboratory analytical results for chloride and total dissolved solids (TDS) to the 15A NCAC 2L Groundwater Quality Standards (NC 2L Standards), which are the regulatory clean-up levels under the DWR program. The analytical laboratory reported chloride concentrations above the MDL but below the NC 2L Standard of 250 mg/L in groundwater samples collected from MW-1, MW-3A, MW-5 and MW-8 during the March sampling event, consistent with historical trends. The sample from monitoring well MW-4A exceeded the Standard, as it has in every historic sampling event except March 2021. Monitoring well MW-2 was dry in March. The laboratory analytical results are summarized in Table 2. The analytical laboratory reported TDS concentrations above the MDL but below the NC 2L Standard of 500 mg/L in groundwater samples collected from MW-1, MW-3A, MW-5 and MW-8 during the March sampling event, consistent with historical trends. Monitoring well MW-2 was dry in March 2023. The sample from monitoring well MW-4A exceeded the Standard in March, as it has in every historic sampling event except March 2021. The laboratory analytical results are summarized in Table 3. Chloride and TDS concentrations for the March 2023 groundwater sampling event are shown on Figure 4. Charts of historical concentrations of chloride and TDS are presented in Appendix B. First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 2 �i TrRC 3.0 Statistical Evaluation of Concentration Trends Historical data indicate decreasing concentration trends in TDS and chloride between 1995 and 2019. However, trends for more recent years are less discernable. Using the Mann -Kendall statistical method, TRC evaluated the concentration trends for chloride and TDS in groundwater samples collected from the monitoring wells for the past 40 sampling events. Chloride and TDS concentrations from March 2010 through March 2023 were entered into the Mann -Kendall Toolkit developed by GSI Environmental, Inc. (Conner et al, 2014). The results indicate that chloride concentrations show no trend in MW-1 at 76.4% confidence, are increasing in monitoring well MW-2 at 97.8% confidence, are stable in MW-3A at 78.1 % confidence, are decreasing in MW-4A at 98.7% confidence, show no trend in MW-5 at 82.3% confidence, and are decreasing in MW-8 at 99.3% confidence. The results of the Mann -Kendall analysis indicate that TDS is increasing in monitoring wells MW-1, MW-2 and MW-5 at 99.9% confidence (although MW-1 and MW-5 concentrations remain well below regulatory limits), while TDS is stable in MW-3A at 81.1 % confidence, is decreasing in MW-4A at 99.6% confidence, and is decreasing in monitoring well MW-8 at 97.2% confidence. The Mann -Kendall statistics worksheets for chloride and TDS are provided in Appendix C. 4.0 Conclusions and Recommendation The data suggest concentrations of chloride and TDS in groundwater have generally declined since the lining of the treatment lagoons and drying beds in 2000. The lining was installed to minimize the vertical migration and leaching of COCs from the source into groundwater. As shown in the chloride and TDS concentration charts (Appendix B), the long-term concentration trends are generally decreasing; however, chloride and TDS concentrations in groundwater samples collected from monitoring wells MW-2, MW-3A and MW-4A have been reported above their respective NC 2L Standards one or more times in recent sampling events. The laboratory analytical results for samples collected from MW-2 indicate that TDS concentrations were above the NC 2L Standard in eleven of the last 15 samples collected, and chloride concentrations were above the NC 2L Standard in eight of the last 15 samples collected. As discussed in Section 3.0, TRC calculated Mann -Kendall statistics for chloride and TDS concentration trends. The data suggest generally stable to declining trends in COCs in wells downgradient from the treatment lagoons and drying beds, while TDS and chlorine concentrations are increasing at MW-2, as illustrated by the Mann -Kendall statistical analysis shown in Appendix C. Chloride and TDS at the site have historically been reported at concentrations above the NC 2L Standard. The highest concentrations of chloride and TDS have been measured in groundwater samples collected from monitoring well MW-4A, which is located immediately downgradient of the lagoons and drying beds. March 2021 marks the only historic event in which chloride and TDS concentrations were below the NC 2L Standard in samples collected from MW-4A. Based upon the recent NC 2L Standard exceedances, TRC will continue to evaluate trends in MW-2, MW-3A and MW-4A. Based on current and historical site data, TRC recommends continuing tri-annual sampling and semi-annual reporting to evaluate chloride and TDS concentrations in the brine yard area groundwater monitoring wells. First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 3 �i TrRC 5.0 References Connor, J. A., S.K. Farhat, and M. Vanderford, 2014. GSI Mann -Kendall Toolkit for Quantitative Analysis of Plume Concentration Trends. Groundwater. doi: 10.1111/gwat.12277. First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 4 10 Ik TrRC Tables First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 Table 1 Depth to Groundwater Measurements and Groundwater Elevations Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Well ID Total Depth (ft bgs') Top of Casing Elevation (ft NAVD882) March 27, 2023 De Depth to p Water (ft btoc3) Groundwater Elevation (ft NAVD88) MW-1 25.0 163.2 16.8 146.4 MW-2 15.5 160.9 11.1 149.8 MW-3A 24.0 143.1 17.2 125.9 MW-4A 19.5 139.1 14.5 124.6 MW-5 14.0 155.4 14.5 140.9 MW-8 10.0 134.7 9.2 125.5 Notes: 1) ft bgs - feet below ground surface 2) ft NAVD88 - feet above the North American Vertical Datum 1988 3) ft btoc - feet below top of casing Table 2 Historical Chloride Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) WellI.D. Mar-95 Jul-95 Sep-95 Nov-95 Mar-96 Jul-96 Oct-96 Nov-96 Mar-97 Jul-97 Sep-97 Nov-97 Feb-98 Mar-98 MW-1 9 10 7 8 14 7 10 8 9 17 5 6 1,450 7 MW-2 918 1,420 2,550 1,100 1,080 1,790 720 1,130 1,080 1,720 926 1,270 330 758 MW-3A 38 22 52 100 57 158 55 26 64 122 205 228 3,330 34 MW-4A NA NA NA NA NA NA 3,449 2,740 NA NA 3,505 NA NA NA MW-5 16 10 20 7 16 7 9 8 9 9 25 8 NA 12 MW-8 NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NC 2L Standard = 250 mg/L NAV - Not available Bold values indicate concentrations above the NC 2L Standard Table 2 Page 1 of 7 Table 2 Historical Chloride Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) WellI.D. Jul-98 Nov-98 Mar-99 Jul-99 Mar-00 Jul-00 Nov-00 Feb-01 Mar-01 Jul-01 Nov-01 Mar-02 Jul-02 Nov-02 MW-1 6 9 8 5 7 5 7 6.1 6 5 8 13 6 5 MW-2 993 1,950 1,060 990 252 213 156 130 145 133 143 177 156 146 MW-3A 74 262 71 317 51 379 376 160 121 330 447 51 474 410 MW-4A 2,490 2,800 2,590 2,730 1,890 1,840 2,130 2,200 2,060 1,700 1,620 1,630 1,150 1,140 MW-5 6 17 17 8 41 8 11 8.8 12 13 9 60 15 17 MW-8 NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NC 2L Standard = 250 mg/L NAV - Not available Bold values indicate concentrations above the NC 2L Standard Table 2 Page 2 of 7 Table 2 Historical Chloride Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) Well I.D. Mar-03 Jul-03 Nov-03 Mar-04 Jul-04 Nov-04 Apr-05 Jul-05 Nov-05 Mar-06 Jul-06 Nov-06 Mar-07 May-07 MW-1 6 8 5 6 10 9 6 6 5 7 4 5 8 NA MW-2 106 98 164 141 187 194 159 152 165 163 167 149 76 620 MW-3A 28 19 259 101 624 674 246 727 639 322 52 489 473 461 MW-4A 1,230 937 1,090 882 869 833 781 839 758 727 646 620 650 NA MW-5 28 13 8 8.0 8 NR 8 9 10 7 11 7 7 NA MW-8 NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NC 2L Standard = 250 mg/L NAV - Not available Bold values indicate concentrations above the NC 2L Standard Table 2 Page 3 of 7 Table 2 Historical Chloride Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) WellI.D. Jul-07 Nov-07 Mar-08 Jul-08 Nov-08 Mar-09 Jul-09 Nov-09 Mar-10 Jul-10 Nov-10 Mar-11 Jul-11 Nov-11 MW-1 8.73 6 8 7 5.56 11.5 389 4.46 7.8 4.6 5.0 7.9 7.2 6.0 MW-2 709 NA 202 400 380 160 416 175 95.9 349 274 302 NA NA MW-3A 475 479 19 208 37.5 63.2 500 68.6 26.5 338 148 195 340 764 MW-4A 716 780 632 1,040 848 9.34 995 802 707 740 787 821 998 350 MW-5 13.9 10 7 11 21.7 626 23.0 9.34 7.1 9.5 8.4 11.5 12.1 12.7 MW-8 NAV NAV NAV NAV NAV NAV NAV NAV 8.0 NA NA 9.3 NA 144 Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NC 2L Standard = 250 mg/L NAV - Not available Bold values indicate concentrations above the NC 2L Standard Table 2 Page 4 of 7 Table 2 Historical Chloride Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) WellI.D. Mar-12 Jul-12 Nov-12 Mar-13 Jul-13 Nov-13 Mar-14 Jul-14 Nov-14 Mar-15 Jul-15 Nov-15 Mar-16 Jul-16 MW-1 5.7 <1 6.7 5.5 7.1 7.2 7.8 5.7 7.1 <5 5 6 5 <5 MW-2 NA NA NA 39.7 NA 87.4 18.1 41.7 99.3 33 81 26 103 64 MW-3A 180 119 301 185 20.8 306 58.4 71.2 240 81 230 16 145 252 MW-4A 527 724 693 381 427 788 464 625 650 433 721 415 433 389 MW-5 12.3 9.6 11.9 13.0 5.7 135 8.7 17.6 18.7 <5 11 6 <5 5 MW-8 36.9 NA NA 87.7 NA 15.3 13.2 13.9 11.0 <5 8 7 5 5 Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NC 2L Standard = 250 mg/L NAV - Not available Bold values indicate concentrations above the NC 2L Standard Table 2 Page 5 of 7 Table 2 Historical Chloride Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) WellI.D. Nov-16 Mar-17 Jul-17 Nov-17 Mar-18 Jul-18 Nov-18 Mar-19 Jul-19 Nov-19 Mar-20 Jul-20 Nov-20 Mar-21 MW-1 <5 8 <5 <5 8 <5 6 5 <5 12 6 10 6 8 MW-2 257 349 238 751 507 435 42 241 683 702 240 318 DRY 14 MW-3A 57 322 265 293 202 202 180 87 177 273 41 123 13 25 MW-4A 322 554 420 617 335 1260 601 457 1500 1080 485 415 284 209 MW-5 9 16 10 12 7 12 8 10 16 13 12 12 11 10 MW-8 6 7 6 11 17 36 8 5 DRY DRY 7 6 33 5 Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NC 2L Standard = 250 mg/L NAV - Not available Bold values indicate concentrations above the NC 2L Standard Table 2 Page 6 of 7 Table 2 Historical Chloride Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) Well I.D. Jul-21 Nov-21 Mar-22 Jul-22 Nov-22 Mar-23 MW-1 6 7 9 6 <5 12 MW-2 64 689 242 836 DRY DRY MW-3A 243 281 232 271 106 121 MW-4A 427 613 549 521 429 367 MW-5 5 13 14 <5 17 17 MW-8 5 DRY <5 DRY DRY 8 Notes: All units in milligrams per liter (mg/L) NC 2L Standard = 250 mg/L Bold values indicate concentrations above the NC 2L Standard NA - Not Analyzed NAV - Not available Table 2 Page 7 of 7 Table 3 Historical and Current Total Dissolved Solids Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) Well I.D. Jul-95 Sep-95 Nov-95 Jul-96 Oct-96 Nov-96 Mar-97 Jul-97 Sep-97 Nov-97 Mar-98 Jul-98 Nov-98 Mar-99 MW-1 31 28 36 53 17 43 36 42 94 30 63 39 21 40 MW-2 2,420 4,298 1,730 2,940 1,064 1,960 1,870 2,950 2,892 1,970 1,420 1,720 3,440 1,770 MW-3A 6 168 275 414 78 71 119 276 656 408 112 169 535 146 MW-4A NA NA NA NA 4,769 4,560 NA NA 5,672 NA NA 4,050 4,580 3,940 MW-5 16 58 9 59 42 35 32 72 116 38 159 45 55 60 MW-8 NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NAV - Not Available Bold values indicate concentrations above the NC 2L Standard NC 2L Standard = 500 mg/L Table 3 Page 1 of 7 Table 3 Historical and Current Total Dissolved Solids Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) Well I.D. Jul-99 Mar-00 Jul-00 Nov-00 Feb-01 Mar-01 Jul-01 Nov-01 Mar-02 Jul-02 Nov-02 Mar-03 Jul-03 Nov-03 MW-1 36 53 38 44 60 14 58 112 28 54 44 <10 76 <20 MW-2 1,680 515 443 376 320 302 292 333 310 320 290 263 263 420 MW-3A 660 122 792 693 400 240 730 854 64 834 702 130 92 370 MW-4A 5,400 3,200 3,560 3,500 3,300 3,220 2,690 2,730 2,440 2,210 1,960 2,080 1,620 1,560 MW-5 53 121 46 69 76 48 70 112 164 60 66 103 130 92 MW-8 NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NAV - Not Available Bold values indicate concentrations above the NC 2L Standard NC 2L Standard = 500 mg/L Table 3 Page 2 of 7 Table 3 Historical and Current Total Dissolved Solids Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) Well I.D. Mar-04 Jul-04 Nov-04 Apr-05 Jul-05 Nov-05 Mar-06 Jul-06 Nov-06 Mar-07 May-07 Jul-07 Nov-07 Mar-08 MW-1 34 52 30.0 35.0 31.0 13.0 37.0 36.0 16.0 54.0 NA 27.0 27.0 19.0 MW-2 228 423 447 370 373 338 312 396 350 175 1,310 1,340 NA 184 MW-3A 172 1,290 1,050 340 1,422 1,074 520 91.0 968 936 878 889 698 42.0 MW-4A 1,500 1,477 1,380 1,450 1,552 1,304 1,340 1,060 1,210 1,310 NA 1,380 1,480 1,180 MW-5 74.0 86.0 35.0 78.0 62.0 36.0 50.0 67.0 58.0 62.0 NA 56.0 54.0 61.0 MW-8 NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV NAV Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NAV - Not Available Bold values indicate concentrations above the NC 2L Standard NC 2L Standard = 500 mg/L Table 3 Page 3 of 7 Table 3 Historical and Current Total Dissolved Solids Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) Well I.D. Jul-08 Nov-08 Mar-09 Jul-09 Nov-09 Mar-10 Jul-10 Nov-10 Mar-11 Jul-11 Nov-11 Mar-12 Jul-12 Nov-12 MW-1 34.0 40.0 37.5 36.0 17.0 124 32.5 25.0 40.0 36.0 30.8 37.0 33.3 31.0 MW-2 794 654 311 648 337 292 695 NA NA NA NA NA NA NA MW-3A 606 86.0 113 512 191 92.0 610 261 212 560 664 288 544 462 MW-4A 2,010 1,312 52.5 1,580 1,410 1,170 1,510 1,320 1,360 1,770 1,410 970 2,080 1,290 MW-5 60.0 91.0 1,080 99.0 56.0 88.0 71.0 55.0 42.0 59.4 75.3 59.3 86.0 65.0 MW-8 NAV NAV NAV NAV NAV 78.0 NA 66.0 45.0 NA NA 101 NA 620 Notes: All units in milligrams per liter (mg/L) Mar-uy - Suspected mislabeling of MW-4A and MW-5 samples. NA - Not Analyzed NAV - Not Available Bold values indicate concentrations above the NC 2L Standard NC 2L Standard = 500 mg/L Table 3 Page 4of7 Table 3 Historical and Current Total Dissolved Solids Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) WellI.D. Mar-13 Jul-13 Nov-13 Jul-13 Nov-13 Mar-14 Jul-14 Nov-14 Mar-15 Jul-15 Nov-15 Mar-16 Jul-16 Nov-16 MW-1 <25 49.0 50.0 49.0 50.0 25.0 28.0 <25.0 33 20 34 35 33 37 MW-2 185 380 NA 380 NA NA 228 237 172 296 172 284 414 655 MW-3A 395 52.0 524 52.0 524 252 334 375 153 470 68 282 477 56 MW-4A 914 932 1,450 932 1,450 935 1,150 880 733 1,160 762 750 939 692 MW-5 55.0 184 313 184 313 96.0 92.0 53.0 85 70 91 80 84 87 MW-8 218 NA 79.0 NA 79.0 57.0 61.2 43.0 42 63 50 42 61 47 Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NAV - Not Available Bold values indicate concentrations above the NC 2L Standard NC 2L Standard = 500 mg/L Table 3 Page 5 of 7 Table 3 Historical and Current Total Dissolved Solids Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) WellI.D. Mar-17 Jul-17 Nov-17 Mar-18 Jul-18 Nov-18 Mar-19 Jul-19 Nov-19 Mar-20 Jul-20 Nov-20 Mar-21 Jul-21 MW-1 51 40 40 60 41 35 42 46 30 47 56 37 61 56 MW-2 651 718 1,890 1,120 877 190 513 1,160 1,430 382 982 DRY 536 377 MW-3A 475 471 476 428 430 195 186 409 391 96 258 52 79 508 MW-4A 849 763 1,350 705 1,490 980 651 2,090 2,010 750 861 546 416 612 MW-5 100 92 79 105 108 100 98 99 84 97 100 221 330 134 MW-8 55 46 80 58 240 74 47 DRY DRY 45 52 33 43 53 Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NAV - Not Available Bold values indicate concentrations above the NC 2L Standard NC 2L Standard = 500 mg/L Table 3 Page 6 of 7 Table 3 Historical and Current Total Dissolved Solids Concentrations in Monitoring Wells Pickles Manufacturing (formerly Bay Valley Foods), Faison, NC TRC Project No. 528255.0003.0000 Date Sampled and Results (mg/L) WellI.D. Nov-21 Mar-22 Jul-22 Nov-22 Mar-23 MW-1 54 67 47 39 72 MW-2 1,370 446 1,480 DRY DRY MW-3A 559 396 506 295 178 MW-4A 944 1,000 987 1,000 772 MW-5 119 144 256 108 187 MW-8 DRY 59 DRY DRY 52 Notes: All units in milligrams per liter (mg/L) NA - Not Analyzed NAV - Not Available Bold values indicate concentrations above the NC 2L Standard NC 2L Standard = 500 mg/L Table 3 Page 7 of 7 10 Ik TrRC Figures First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 2� O O her 1 � 11� Q O �o SITE �Q Z "a �CIR = 4 U50 403 D �^ � 1 rn SOLOMA1 N ST ME 70 � di O V► F Q F d a 50 J �pYLpR"Rp _ 150 EppICE O y 1,50� REFERENCE: USGS 7.5 MINUTE 3 TOPOGRAPHIC MAP o d FAISON, NC 2013 U 0 1000 2000 B,� seedy SCALE IN FEET m PROJECT: DRAWN BY: K STARK PICKLES MANUFACTURING LLC CHECKED BY: J HURLEY FAISON, NORTH CAROLINA APPROVED BY: B YUNCU TizcDATE: MAY 2023 W aQ 114 Edinburgh South Drive, Suite 200 TITLE: PROJ. NO.: 528255.0003.0000 r� Cary, North Carolina 27511 SITE LOCATION MAP FILE: Pickles Manufacturing LLC.dwg Phone: 919.827.0864 t� 00 www.tresolutions.com FIGURE 1 2017-10-21 CATES & SONS\ DB 985, PG 363 MB 12, PG 75 (38.2 ACRE TRACT) CATES & SONS DB 931, PG 598 (1) MB 11, PG 116 �r c � �m �m -a w 9Q NOTE: =z `Z BASE MAP PROVIDED BY BAY VALLEY; MW AND RW LOCATIONS PROVIDED BY KCI. =o MIT 11, PG 116 (PORTION OF TRACT 2) OF TRACT 2) � I / MW-14 w 00 �z PROJECT: <i TRIC TITLE. 114 Edinburgh South Drive, Suite 200 Cary, North Carolina 27511 Phone: 919.827.0864 www.tresolutions.com BAY VALLEY FOODS, LLC DB 922, PG 537 MB 1, PG 16 (19.98+\— ACRE TRACT) LEGEND Shallow Monitoring Well Recovery Well Deep Monitoring Well 0 250 SCALE IN FEET 500 DRAWN BY: K STARK PICKLES MANUFACTURING LLC CHECKED BY: J HURLEY FAISON, NORTH CAROLINA APPROVED BY: B YUNCU DATE: MAY 2023 PROD. NO.: 528255.0003.0000 SITE LAYOUT FILE: Pickles Manufacturing LLC.dwg FIGURE 2 reon: 2017-10-21 CATES & SONS\ DB 985, PG 363 MB 12, PG 75 (38.2 ACRE TRACT) CATES & SONS DB 931, PG 598 (1) MB 11, PG 116 �r c � �m �m =o w NOTES: Z 1) BASE MAP PROVIDED BY BAY VALLEY; MW AND RW LOCATIONS PROVIDED BY `Z KCI. 2) MW-8 WAS NOT USED TO CREATE CONTOURS. =o MIT 11, PG 116 (PORTION OF TRACT 2) OF TRACT 2) � I 14 w 00 �z PROJECT: <i Tizc 114 Edinburgh South Drive, Suite 200 TITLE. Cary, North Carolina 27511 Phone: 919.827.0864 www.tresolutions.com BAY VALLEY FOODS, LLC DB 922, PG 537 MB 1, PG 16 (19.98+\— ACRE TRACT) LEGEND Shallow Monitoring Well O Recovery Well ® Deep Monitoring Well m Wastewater Effluent Discharge Point —144— Groundwater Contour (Dashed where inferred) Inferred Direction of Groundwater Flow 149.8 Groundwater Elevation (ft amsl) 0 250 500 SCALE IN FEET DRAWN BY: K STARK PICKLES MANUFACTURING LLC CHECKED BY: J HURLEY FAISON, NORTH CAROLINA APPROVED BY: B YUNCU DATE: MAY 2023 PROD. NO.: 528255.0003.0000 POTENTIOMETRIC SURFACE MAP FILE: Pickles Manufacturing LLC.dwg MARCH 2O23 FIGURE 3 version: 2017-10-21 CATES & SONS\ DB 985, PG 363 MB 12, PG 75 (38.2 ACRE TRACT) CATES & SONS DB 931, PG 598 (1) MB 11, PG 116 �r c � �m �m a� uaJ NOTES: ¢ 1) BASE MAP PROVIDED BY BAY VALLEY; MW AND RW LOCATIONS PROVIDED `Z BY KCI. 2) ALL CONCENTRATIONS IN MILLIGRAMS PER LITER (mg/L). =o MIT 11, PG 116 (PORTION OF TRACT 2) OF TRACT 2) � I MW-14 w 00 �z PROJECT: <i Tizc 114 Edinburgh South Drive, Suite 200 Cary, North Carolina 27511 Phone: 919.827.0864 www.tresolutions.com PICKLES MANUFACTURING LLC FAISON, NORTH CAROLINA TITLE: CHLORIDE AND TDS CONCENTRATIONS MARCH 2O23 BAY VALLEY FOODS, LLC DB 922, PG 537 MB 1, PG 16 (19.98+\— ACRE TRACT) LEGEND Shallow Monitoring Well O Recovery Well Deep Monitoring Well [171 Chloride Concentration (mg/L) (187) TDS Concentration (mg/L) 0 250 500 SCALE IN FEET DRAWN BY: K STARK CHECKED BY: J HURLEY APPROVED BY: B YUNCU DATE: MAY 2023 PROD. NO.: 528255.0003.0000 FILE: Pickles Manufacturing LLC.dwg FIGURE 4 reon: 2017-10-21 10 Ik TrRC Appendix A Groundwater Quality Compliance Forms (GW-59), Laboratory Analytical Report and Chain -of -Custody Records First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 ��FTTW, -TIM W" �_- ___ . , - , , , 4 -!! Al2 -MMT�m IL -SWAIT F08MQN GPLOUNZW-ATER QUALITY MONITORING, C0IZPL1kWqE REPORT FORM Facility Ad(jy�zz- W8Kt0=WrV-S1te Name, County ' I TeloptWA9. A No. W Wella W611 fdAnliucation Nur([rorn'PdrMjty W-A 7P Well Depth-, v Y It. Well Smened tnleryl: Cf. to.2 q � it. "Cwk0=0 InRuent (901. _ fLbe1pw-rR�aAVrjngpoint, 0 Eff(T-Lent (99.) BolhV � P kFOMP. EJENW[on Trr 1.- Gallons.of, water -pMp8=jR1jQ(f 6 to OO Field ari"is: W Q. pyM0,113g, Date� samplecaecta& , Specific ConoputartQe umhos TP P. PC..Cwqr FABAMEJgRa (.$amp [a& f or rfloa is W'Rra 011ected 'COD -Codfacm; MF Feca[ M9A /1-ojoml C01 ifor M-". M F Total (*48- U96- MPN MeLth ad for Disso1vod,_S.0j1dx T..'Qtar pH (when anajyzed� TOO 0.77 MqAL tlxfd /A Arsenic. MgA M-gA Mq/1 * Conductance 'uMh M-9/1 TcJWAmmonia _W riff P9R MIT. /.Vr— P-�D 0 19 t_xPj0,k DATE!- U.10. TYPE 92 -PZMd= OPEFTAT10a BEtNo Mo NlTa reD -/ Lagwn _F[13MQ01At1*n; Inliqratim-eariery. _6dray -Flelcl —Nmw4w. —Land-ApffilliWIC0 of Sikidgg 01har, NQM -Values 8 hQu Id r8l tQCV C(laso We dand r-01101dal coAcentmuons. late sample 4n*nd, Laboratory Marna:A— c� Car'llcatign No. ke4e# Y YES; —NO . Arad ffaldxal%jlnad Nitri.!e , Mz),az N 04 0 _1 M9A Nitrate .Vo-) as t .. IV Phou , p0qrus: Total as P mg 0dft00hP-$P6W 0. 7�- mgg Ai - AWNnum. 126 Ba - Ra4V.m Ca . Qdioj:u MgA Cd - CA80vu mgil Chrodem: Total Mwj ov -.-Copper ' mg/I Fe - ironM94 Hg - MeMury Mg/1 K - Potasol'. MgA Mg -Map estum M!;A Mn - Mrtcoarrage mgA. Ni - Nickel MgA K 1_6 a MDA Zn - ZRo MgA Ammonla Nitrogen; 0 M911 Other (zpe$jN canpo4rRds Aqd Coricerilrallon U ait�) ORGANICS, (SPO olty- Wat an 0 Me%Qd X Altub lab re part.) RePott Attached? fifes- —(I) No _.(0) VOG meftd 4 volhod -0 /I S(1113 64 ROU DWATEF3 QUALITY 01AI1' RI - � DEpAFr4 * �'NAXEB�.i COMPLIANCE E REPORT FORM Mg fi1A1 f=acilily Name:. one% � a.print leariyr or Typa Permit Nama-lif d[iferent}: Facility Addce W moty . ontacr Perin: Ta{ept3arle /17 Well L0M11or� Site i�laxne: � ,_..� NO. of 911s to. ba ampled: Wel11daIRIMcatlon Num erCorn Porm9t), - krGround reter�Teat�t�rtt alsrna° Well'Deplh: _ _fi. � iNe1[ E�it3rtt�tefv. � {rti, �h{ck.4ne�� Infl�Uent (9.8).. crc�rietCEnterve3:_� _[I.lo It, Q Et#uer� (9s Depth to Wa[or Level:._.. 4)_ '? ft. below mess�tnrsg pojnt. McAsUing Poht.(M.P.) is:— jt, a ue-[arid 5u i elarive P, fevaton.Err.lt.; a1[orts of �tv ttn pu>knpadlh ia�e before-e rnpiing: � Data 8amrla ca�g000d: � Field analysis: phi 'Specillo Conductance ._' _uMhos Temp- R°C:. odor — Appearance L- —14 ' .OP E]4�i M.lkir NrltA[L RE$.#kJ PEFtMT#: JM4LZ-'4� 1 ' ' L-XPI RATION DATE., 4z Noo•Di;charge.__ � jC NPn --�-7— OPEHATION BJ=-[N MQNITORED' Lsgpqn _Fkt}tnWIl floe: In1Q1rat[o11 Geljc uy Spray.F[.ald _€lamed 0.w- F101 y OastrlWtar � Lano-Apptiaddari o1'3ludpa NOTE;. Valued shouid reflect disso[vaci ana . colt*Dial ca.nC�entrat[ons. Date.4.ample.analyzed: Labmtory Name- � � 'x• CemnGEttion No_ Ssmptes for matstio-waro co[Iected unflite d—LYM —NO '; and field acidif led QE -. -.-- iiform: �i41i= �ecai — /1 Mgfl 0MI hlitrite {iO) as N Nitrate:(.NO3) -as N MgA Mg1t oliforM, VF Totai !100MI Phosphorus. Total as P ., �..—MgA ,(r4ata.'lls4'MPH TM.15 0dfarhtghlYturhldxrMplaa) Dlssol�fad ollds: ToW mgfi r#I'[wh9Sphate. Al - fidumfntim M gA TQheji,anaiyzGd)�- until Ba - Ba6m rng#t mg).[ ors �. n1g).1 .tea - t4lclum mgA rserlr .�_ MgA rr�gl Cd - Cadmimn Chromium; Total .Mgll t ale a>aiti �s M . u - ap} er m gA nol t# — ,. �_UMhos m rrl i Fe -iron. Hg } eroury _ '--- MgAvui m gA .r'. OOd c it ctan a K � Potasslqrrl -- _ .. M gA Taal Ammonik TKN as N MgA Mg - MagngSjurn mgfl m9A Mn - Manganese �_ rnbA YES KO) N1- Nickel MGA Pb - e.aciL MgA n - Zlnc mgA Ammonia Wtrag6n 019A 15r ( papllq Cornpwinds-and" om"ItOon,Unb). ORGANICS.- (GC GCfM ,HPLO) (Sp,$ RY test anti . !00 A-. Attach N4 report.) RePartAte(ftd? .9s,_(1) Ro �(0) Vac - meftol4 mel?iod 9 meftd Rev, 002000xF GROUNDWATER QUALITY l 0I lT FjjR : 1EMPLI]A CE. REPORTFORM Facillty t4mme-�_._ -P r0l Name (if'd4rlerent}: Facillty'Addtg s.�.� Contact Person: _ __f Wsll LocatioW SijG Narita: UIRMIT MR .OJT XELLoApAPF_R . e Prm c Crowly or ] ype f Gusty No. of Wells ta.bo.SDropled: slf .IV> bar(from:Pafmlt): , . 4^' -FvG mfidnterTteatmeat 3y81e[ns Wett Depth, —It. 'Woo bila rtow �, irti, C*k0npsM Influent 98 }` Screen ft. to � � `7 � .t�` �. 0Wh to Water Levo�:..,. ft be[cw musuring point. I � # 8 } Measuring P.olrft.(M.P.) is;� it, shove farad AcriaZ, Relatl+re-M,p. r= evatfon fr[ tt,:._,,�_ Gal Ions of,wate.r pvmprailed nefere sampttrog; Ckate sample Colteoted. µ Flaid anatysis: p peciflc taondr�c#arice a 4hos Temp, , odor _— .Appearance RA,MMEI (aMP18s for metals were cclfected u COD ri'1gA Col iforrti: MF°Fecal, _ _ - �,110Orrti Coliforrn: r Total. ---_—.,114.Orrtl AHots. Usa mpA Imotbodfar'Notyturhlti,aam. foak. Dr lv�ld olIC1S: Tota�tl. 1 .Phi (�rkreln enJaiyzed) _ IngA - u k#s TOGrrSgI Chloride --" - .—_ _ mgjl Ar enic' rngll Gregs� acid Oils� - . — - m gA phenol Zulfate MqA Specific COndu[ctance LdMhm Total Ammonia mgvf TKN as N mg/1 a � Y �NVCFC�H[�1�9T:S:�iA'[EI#iA6'RE54UAC� � f 0MON, t±RQUND.�iYA7 F3:SJ;C1 JON PEAMCT4, %j EXPJRATI,0N DATE: 1- Norx-Discharge .UI —_-- ciE ___ —. OPU RATION BE ING' MC.NITORED .� Lagoon—13erno00Qn: Jnl3ttraticn.ci$Clesy _ pray-Fiald _f#emediaW: ,..� F9alary 0J31fbU*r �Land'AppftAtian oI',$I000e �_ Olher; ValUMI DhQUld rRMWt'd.lssolved'arrci . d1laldetl'corrcerktMAan . Date sample analyzed:. ` d Laboratory flame: erlIJIfication No.. _ — -. tered— YES —NO and fileld.aoldlfled Nrtrtte :(N.02) as N M A Nitrate (NO) oz K mbA Phosphoms: Total a ' P MgA dhophosphat& rngh AI - -Atum InureMv Ba -Barium Mg/.1 Ca- Galclum, -, .,. —.;.�..��, mgA d - atir71[um mum Chrorr'Ilum: Total gfl u - .Coppet• m gA Fe - Iran m gA H,9 - Mercury _.. — m t K - Potassit:trrk . --- rrigl1 •� "' Mg -�M gneslum rrt gA Mn - Manganese m gA YES —140) ill - Nickel MgA Pb - Lead- n - Zinc MgA iirlU7'tiOTaUtto,gen. rygA Other (pecffy-_Ccupaunda•land: oncentr�lilori.Units} a t ;(Speclty-Wet. arrd .method -#.,.Aitgch fah roport:) #te st Affached? Yes,_(i) Igo voc rrteihod 4 3 method #r: GROUNDWATER QUALITY MONITORINQ-. eEMPLIANeE REPORT FORM facifity'Narn ' e Permm Name: Facility Addre aW.EWIT PORM'.ON YLLLMPAPER -'ONI-Y nhP"od PrJnf Cle Hy or- Type ioiv, rR.,&,r efapone no _75;;g Contact Persar�: 4. T. -Y-7y/ x. Welt Locatton(4e Namo-� 65-42.4 1iq. .01 W,611's to tP arnpla& kMelllcreRft i umber(fr6rn;Pa well j Influent (9.8). Sc refened'Interyal: .x it. Depth to-Watoreave.- "ft. b_e[qwmaasur1ng-poinL EfflUent (9.9) meaAudng Point'(Mip.) Is-.:— ft. at*vs laod-&Oacs. Relative M.P. Els9atilon In N: Gallons of water pumped/bailed Date sample collepted:.3 Field analysis: nw' -q-t , SP961ic C.codttdta=a WOWS 11C, Odor Ap eneun PA RAM F,1E B S (Samples. for met4s -were collected COD Coliform: MF Fecal /1 m. 00MIgA _ f',Coliform, MF Total - _cmatervno mpiR mawcd:farhfQh,1y,1UrPldTzMptoaj Dissolved Solids: Total, pH (whenanalyzed) units TOC -7 341—mvi Amnic -.Gf,ELa$e,Sffd' -Oils Mg Phenol. .- - 1. 'Sulfate ISO.6 .. p.doetanra. r ..rrgA vMhos _Total Ammania rn gA TANT:as�.N I EKTRO�OMUEOHJT-�& NA L U oyj� DIVq0ti 8S 4 CEWER PE IT 'C'70 EXP`1AATiQN'DA-, E J 'J 1 2-4 NOPOPcharge Q I C1__ NPDES'— AC 04�,,E> 9,W, ERAT-kQ' 2 OP r"PEBM1=D_N BEING MONITORED _ - - - Renofttm: . . . . . . . . ... SPmy-F1!GId _p4molasm. � Olarj:WWWor :-� Land-ApqjkaUW.of-SIudCo Other: &OM Values 4000.w(lapt dissaftd 'and'. adiloidal concentrations. Date sampleanalyzed., Laboratory Ijame- —Z& y 1 y7zs,- zt:Er__1 03rdfication No. __ -0,2.-V tGM4 4 YES- —NO and flaidacidified Nitrite ft0j)as N zo.o.� M911 Nitrate NO3).as N 4j IS MgA Ph.osphorus.-lotal.afs P.— M9A Orth.qphopph ' ate-____ .0-75 -Mo A Aluminum inum- . - S163 .,mgA Ba - Parfuni i —.Mg/, Ca - CaTefm, .0 Cd - -Cadm;um -Mi M6, ebromilarix Total. ou - -c6pper rn Fe - Iron M9A .Hg - Mercuiv K - PQtaW Mg - Magnesium Mn - marig-Whose. mg11 muI —.f:- Y12 _NO) Ni - ickd Pb - M9A mqA Zn - Zinc M9A Ammonia Mg/l Other (Spec" Comg9und5-and Ccncenl!WlPa UnU) �td - Ta?5;7 ORGANICS:. (Q%!3CNS.HPLC) Ppecify tqol and rnathod.#. AUach.lab report.) R9Pqr.t.4ftq11i3d? 'YGrs--(I,) No —0) VCG # = 'method 4 = mathr-wf A -- -A GROUNDWATER QUALITY i:ON.IT.RI Gi: Facility Name-,-.�. Permit Nana~ (if dilferenty Facility Addrpss:- SUBMIT RM :ON all4 Y Type Contact PeLs.on: 27)c LON T�119ph.onae K. V17AD, ai ` > Well Lacat{an! lte.lVame: [ . oi-Wells to tmft rrplad-, Well Identification Number (frorn;Perm[t__ 1�I- WrGrocltt [ater'�atmentSysteons. Well Depth �I-� 4L Well Diameter, _ Z in. creepad interval. ` - it. to C 10ck�0 tea .} .En1l�uent (98) -....��....:Ii. 0Dept#t to:Watertavel:. _ft. bat 'meaaufin r-Pa1nt. �Ei#Cent (9) Measuring Point (M:P.) fs-_ It. above iattd s.urfacc��. relative M.P. Elevaiion in- W. Gallons at water pumped/balled. before-.saEmplir,g: �5�. Date sample collected: 3 - Field analysis: pH-- L+ , specific C0nduCWPe 'UMhos Temp. °C, Odor . Appegrsnce - PARAr�'CI; as (Samples for metals were Collected COD mg fI Cofiform: MF Fecal f100MI Coliform: MF Total f10om1 (Nate Una n1RF1 mothod'101--bIgMtylurhlal sam Jua) Dissol!v�d Total 1 .oiids; PH ( iheA,6nalyzed)� rrl li t`s TOG .+ iu- M Chlodd'a . __ - .._ _ .._, � M911 Ar ig�,ic mVA Grease. and .Oars: m qA F?-tnoi ..Irn gA -Sulfate. < e, m SA ,Specific COndu tanoe umhw Total Ammonia. rrl �l TKN w N mill t �f 1}E110Th1ty7 QF EtlilllFiINEHT:#Al1RlIL. RStlRC �WATF_a aUALUY D1=10YA dg nr�a+ aTE sl<C71or# I V16 MAIL-SIERV10E C VXTER PERMIT # :"'EXPIRATION -CAT.t4 Non -Discharge- vi NPDE Vx _ OPER►IT1.0N BEING WN70RED Lapa4nRama(Paliota:t4�flltr�tiarr.Geit�ry �Spray�Flettl �E�erstadlatlar�; Rotmy,Dlstrabutor . i. rr :APP0aat1o6 T-Sludgp Other; = Values should reflect disaoltved erld . colloidal; comcentrr�ftRs. 'Date sample anslyxed: - C$boratoty+ Name: OertifiCalon NQ_ _ �91 teced / YES NO ' and field Etcii3ifie4 Nltrlte :(NOg) as Nam ` g{l itrater'(N%-),as N. 257 M9/1 .Phosphorus: Total as.P mg{i .000o0hosphate O• x mg4 Al' , Alum hum. mgA MgA Ca - Caldurn mg Cd - Cadmium m ' Chromium,. Total mWl Cu -Capper mg)l Fe - Iran mgA Fig - Mercury :r��ll K - Patas,9l . .mqA M9 - maxesWM MWI Mn - Manganese MgA yEr, — No) Ni - Nickel Pb - Le m Zn -Zinc mgA CAher (peci(�': 6rnpounds ami..0onceniration,:Units) r � RrA l !�..{r:tl�tiC�tatIHP i.� (SPOA Ep:teat and mothad #. Attacb'#sl;-mparr.) FtOort*Mched Ye. _(1) 'No:(.o) VCC rnetbod .9 rnet#iod # :GW-5 .. - Rev. =000 anatu oet e,Qe,u} �� ,�s a •; -:+! - R f� -,-- p-$.-v--,.��-- �-.------:F}.�. - .-..- ..�-�,,.�� ^�---„- ^�-� _ - - � t ,SUBMIT FORM ON .R J DW TERk QUALITY MoNT R1NC;: ANCE REPORT FORM Phase PrInI Cfearry.or Type Facility blame: 434 _C Permit Name-difterMt), FaCW1V-"dM4t*- C—) .Goptact'-Po(son Well LocaiiorJ ite Jaunty � •�'` �aCepttnne• f�: '1� �- . No. of We Ile to be arrtpled: I Well Iden#i0cafion Number (ire m .P:erm1q; Well Pe 1h., !'.a�o�t1¢'�t�l�rTrt�trtt��S�slerrti9: P fF, VJoIIi].itxteg9r:. in, CheckOew creep�ci lnterral,. _ � _.fk. to __. tk, Depth.#o tl Or Level- '� ft,- 10w- '.1€�asuOrr9 point. � Effluent �99 M04-gjUrin9 P60t (M,P,) is:_._...w. IL eNve land surface, Ftolabve PA.P, Elevation Jr, rj,, GMOM Of WOOF Purnpoditlj d before aamplirrg:J� Dale sample collected,: -x�,� Field analysis: pH__ 4, Specific Conductartca ' uly,ts Temp. 5-- ' . Nor � Appearance -33F PERMIT O: Nw-Discharge tJi NPOE }" . j .Qp.r:KAT-QN 13E1k4 11 ONITCRED Lagoon —SuMdIallon inliltragon eArlery �.�4my Field _RamsGi %wt _.Flowy Djawbuto LarLd A.PPikallon OkSludge �_ Okhar: NQM Valtmsshquldreftwt-dfssolved.and . 001103081 concentrations. Date sampkE analyzed; �- Laboratory Namj!p #,c�►h� ertif[catiorx tea.,..Zt'. (Samples for Wiatals.were col1"Od Un(jitered��YE QD � 190 i nnd'fi'efd.ac�dlifad aaiform; lu1F Fiscal. "Fora, mgA 11�OOrrtl Nitrite'{Jf} as t �#itre,te.{NO3)'as o. m gA �'�' oli#nrrtt: PE+11= Phosph'p us; Total as P m , A r: (Matti, V¢4M�Rffiaehad:ra#'hlfjh1,j vrhle�aajUgk*aj Dissolved.-acifd : Totaf. Oril�ophc,Sphae V . V9 .PH (WhertV-18lyzad} — - _—. mgA onit Al - Alumitxum Ba - Barium: .yd � - -• V ..� .. Chloride .�_ MgA a alolum mgA mqA a , , i0.r ettii . - - -- -,.-,— _ _ _ -mgA rr gA d -Cadmium_ . hromfum; Total Mg/I � Grease end .Oilsi Ihend� - - �.t ,.�_ M9A CU �- a'pper -Sulfaita ifs 4ndu tarp e. m 1 Fs lrt r� Kg - Mewury rltc�!! Ttai:rrxroliia�. u.f� hop . mg K - l =Wu - .[agmtesfr. •--,--'---�•-�----•--�.,. rn qA mgll TF f a rrtg/l Mn - Mangarneso j. YES No) Ni - Ni ktel m Zn - Zrio Mg/1 AMmonA Nitrogon mgA Other .(Spmty t s .ar .. onteril at ,ClrfCtsj R alfNi.C.S:.(GC GC I1 3,HPLC) pe0I1j. test And Moth as! t. Attach lab report: Rg rtAtteched? Ye —(T) No _(0) VD . method 4 :.method # G W-5 A CU,MPI DANCE REPORT FORM Permit # /VG 0&Dt q 17 (Submit Cif. each nr01111or1ng period with GW.59 for s.) g Enter date monitoring results ware due, ( �`1�1�z?,3► Nil this rnonitoring report (GIN-59 and be submitted after the established due date? 2 Was any required information missing on the GW_-59 report forms? it me answer to question 1 or 2 Is `YES , list in the space provided below the well ideratittcatioraoumbers) and explain the problems encountered In obtaining the required Information. we(� ,9 Wa5, �_r� 3 Are any of the moaltor wells is need of repair or malatenaace (damaged rasing, aalocked or talissiag cap, identification plate, area overgrown, etc.)? if theWMwr is ..yes ... contact the Regional Officeforguidance. 4 Are any monitored constituents equal to or above tho Astahq.hea .•,..a.._.�_� rr me answer to question 4 Is WO-, skip to section 8. If the answer to question 4 Is "YES" list the affected wells IndMdusily with constituent(s) and concentmifm(s) exceeding standards In the space provided below. same constituent(s) In the same wrell($) in the last two years? If me answer to question 5 Is NO*, skip to section 8. ` If Me answer to question 5 Is "YES", list In the space provided below, each well with consatuent(s) exceeding standards, concentratlon(s) reported, and sample collection date for each occurrence (for the last two years). 6 Are ttw monitoring wens listed In section 5 located at or beyond the review boundary? If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE WMEDIATEL. Y FOR GUIDANCE If the answer is "NO", monitoring wells may be Improperfy located; contact the Regional office. Is the permitted implementing groundwater quality problem? it me answer to question 7 is -YES, describe these actions in the space provided below. If the answer to question 7 Is "NO" aef ft &09LO_nal !thin 0 da • an evaluation ma re ! e In the lm c the ! sat s s a n at re f w gild co flan boil a s su u dl this clll Fa!! re da so ma sub ect the s~rmf !a a N ti et - fines. and/or Waides. $ The person completing this portion (GW-S9A) of the rrtonitoring report should sign below and submit this form with OW59 forms for required wells to the address provided at the tap ofthe currentGW-59 form. I hereby acknowledge that the above IMcrrnaf n`was evaltia�o� report (Compliance Report GW49A) Is true slid coFnpl*-to ftwb4t of lily kei ed a;"' st�;' ,A Signature of Permittee (or Authorized Agent) Date YES Monitoring Well #2 Chlorides ppm TDS ppm Date 11/19/2020 No water No water 1/21/2021 138 315 3/29/2021 14 536 7/29/2021 64 377 11/23/2021 689 1370 1/26/2022 51 418 3/29/2022 242 446 7/25/2022 836 1480 11/17/2022 No water No water 1/27/2023 No water No water 3/27/2023 No water No water Monitoring Well #4A Chlorides ppm TDS ppm Date 11/19/2020 284 546 1/21/2021 369 801 3/29/2021 209 416 7/29/2021 427 612 11/23/2021 613 944 1/26/2022 458 796 3/29/2022 549 1000 7/25/2022 521 987 11/17/2022 429 1000 1/27/2023 423 1570 3/27/2023 367 772 Monitoring Well #3 Chlorides ppm TDS ppm Date 11/19/2020 13 52 1/21/2021 29 216 3/29/2021 25 79 7/29/2021 243 508 11/23/2021 281 559 1/26/2022 356 538 3/29/2022 232 396 7/25/2022 271 506 11/17/2022 106 295 1/27/2023 189 504 3/27/2023 121 178 envirochem ANALYTICAL A CONSULTING CHEMISTS Bay Valley Foods -Faison 354 North Faison Avenue Faison NC 28341 Attention: Lab ID Sample ID: 23-15140 Site: MW-1 Test Sodium Aluminum Sulfate Ammonia Nitrogen Total Dissolved Solids (TDS) Orthophosphate Total Organic Carbon (TOC) Chloride Nitrate Nitrogen (Calc) Nitrite Nitrogen N itrate+Nitrite-Nitrogen Nitrate Nitrogen Lab ID Sample ID: 23-15141 Site: MW-2 Test Dry Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 - 910.392.0223 lab . 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, INC 28540 • 910.347.5843 l.,ab/Fax info&nvironmentalchemists.com Date of Report: Apr 14, 2023 Customer PO #: Customer ID: 15030024 Report #: 2023-05989 Project ID: Groundwater Monitoring Collect Date/Time Matrix Sampled by 3/27/2023 8 15 AM Water JR Killette Method Results Date Analyzed EPA 200 7. Rev 4 4 1994 EPA 200 7 Rev 4 4 1994 EPA 300 0 Rev 2 1 1993 EPA 350 1 Rev 2 0. 1993 SM 2540 C-2015 SM 4500 P E•2011 SM 5310 9-2014 SM4500 C E-2011 EPA 353 2 Rev 2 0 1993 EPA 353 2 Rev 2 0 1993 Sub"don Method nn Method Collect Date/Time 3/27/2023 8:32 AM 49.0 mg/L 3.06 mg/L <5 mg/L < 0.2 mg/L 72 mglL 0.14 mg/L 0.7 mg/L 12 mg/L < 0.02 mg/L 6.20 mg/L 6.20 mg/L Matrix Sampled by Water JR Killette 04/07/2023 04/07/2023 04/04/2023 03/29/2023 03/29/2023 03/29/2023 03/30/2023 03/30/2023 03/29/2023 03/31 /2023 04/04/2023 Results Date Analyzed Report 2023-05989 Page 1 of 6 Environmental Chemists, Inc. .: iW`p4Yu' 6602 Windmill Way, Wilmington, NC 28405 . 910.392.0223 Lab + 910.392.4424 Fax 710 Sowsertown Road, Manteo, NC 27954 . 252.473.5M Lab/Fax + 255-A Wilmington Highway, Jacksonville, NC 2&%0 • 910.347.5843 Lab/Fax ANALYTICAL a CONSULTING CHEMISTS info@environmentskhcmists.com Bay Valley Foods -Faison Date of Report: Apr 14, 2023 354 North Faison Avenue Customer PO #: Faison NC 28341 Customer ID: 15030024 Attention: Report #: 2023-05989 Project ID. Groundwater Monitoring Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-15142 site: MW-3 3/27/2023 8.42 AM Water JR Killette Test Method Results Date Analyzed Sodium EPA 200 7 Rev 4 4 1994 49.8 mg/L 04114/2023 Aluminum EPA 2007 Rev 4.4 1994 1.98mg/L 04/05/2023 Sulfate EPA Sao 0 Rev 21 1993 <5 mg/L 04/04/2023 Ammonia Nitrogen EPA 3501 Rev 2.0. 1993 < 0.2 mg/L 03/29/2023 Total Dissolved Solids (TDS) sM 2540 C4015 178 mg/L 03/29/2023 Orthophosphate 5M 4500 P E-2011 0.09 mg/L 03/29/2023 Total Organic Carbon (TOC) SM 5310 B-2014 0.6 mg/L 03/30/2023 Chloride SM45M C E 2011 121 mg/L 03/30/2023 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353 2 Rev 2 0 1993 < 0.02 mg/L 03/2912023 Nitrate+Nitrite-Nitrogen EPA 353 2 Rev 2 0 1993 4.62 mg/L 03/31 /2023 Nitrate Nitrogen Subtraction Method 4.62 mg/L 04/04/2023 Report N' 2023.0$989 Page 2 of 6 envirochem ANALYTICAL & CONSULTING CHEMISTS Bay Valley Foods -Faison 354 North Faison Avenue Faison NC 28341 Attention: Lab ID Sample ID: 23-15143 Site: MW-4 Test Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 2ti405 . 910.392.0223 Lab . 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 . 252.4733702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 * 910.347.5843 Lab/Fax info@environmentalchemistacom Date of Report: Apr 14, 2023 Customer PO #: Customer ID: 15030024 Report #: 2023-05989 Project ID: Groundwater Monitoring Collect Datefrime Matrix Sampled by 3/27/2023 9 06 AM Water JR Killette Method Results Date Analyzed Sodium EPA 200 7. Rev 4 4 1094 299 mgJL 04/14/2023 Aluminum EPA 200 7 Rev 4.4 1994 0.583 mg/L 04/05/2023 Sulfate EPA 300 D Rev 21 1993 53 mg/L 04/04/2023 Ammonia Nitrogen EPA 350 1 Rev 2 0 1993 2 0 mg/L 03/29/2023 Total Dissolved Solids (TDS) SM 2540 C-2015 772 mg/L 03/29/2023 Orthophosphate SM 4500 P E-2011 0 19 mg/L 03/29/2023 Total Organic Carbon (TOC) SM 5310 8.2014 2.7 mg/L 03/30/2023 Chloride SM4500 CI E-2011 367 mg/L 03/3012023 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353 2 Rev 2 0 1993 < 0.02 mg/L 03/29/2023 Nitrate+Nitrite-Nitrogen EPA 3532 Rev 20 1993 4.25mg/L 03/31/2023 Nitrate Nitrogen Subtracbm McOW 4.25 mg/L 04/04/2023 Report # 2023-05980 Page 3 of 5 - Environmental. Chemists, Inc. enviroe em 6602 Windmill Way, Wilmington, NC 28405 a 910.392.0223 Lab a 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28M a 910.347.5843 Lab/Fax ANALYTICAL A CONSULTING CHEMISTS info&nvironmentalchemismcom Bay Valley Foods -Faison Date of Report: Apr 14. 2023 354 North Faison Avenue Customer PO #: Faison NC 28341 Customer 10: 15030024 Attention: Report #: 2023-05989 Project ID: Groundwater Monitoring Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-15144 Site: MW-5 3/27/2023 9:22 AM Water JR Killette Test Method Results Date Analyzed Sodium EPA 200 7 Rev 4 4 19N 3.96 mg/L 04/07/2023 Aluminum EPA2007 Rev 44 1994 2.32 mg/L 04/05/2023 Sulfate EPA300.0 Rev 21 19s3 <5mg/L 04/04/2023 Ammonia Nitrogen EPA 350 1 Rev 2.0 1993 < 0.2 mg/L 03/29/2023 Total Dissolved Solids (TDS) SM 2540 C-2015 187 mg/L 03/29/2023 Orthophosphate SM 4500 P E.2011 0.10 mg/L 03/29/2023 Total Organic Carbon (TOC) SM 5310 &2014 2.0 mg1L 03/30/2023 Chloride SM4500 CI E-2011 17 mg1L 03/30/2023 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353 2 Rev 2 0 1993 < 0.02 mg/L 03/29/2023 Nitrate+Nitrite-Nitrogen EPA 353 2. Rev 2 0. 1993 9.05 mg/L 03/31/2023 Nitrate Nitrogen Subtrashon Method 9.05 mg/L 04/04/2023 Report 0 2023.05989 Page 4 of 5 rr LL enviroe • ANALYTICAL & CONSULTING CHEMISTS Bay Valley Foods -Faison 354 North Faison Avenue Faison NC Attention: Lab ID Sample ID: 23-15145 Site: MW-8 Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 ■ 910.392.0223 Lab + 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 . 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info@environmentalchemismcorn Date of Report: Apr 14, 2023 Customer PO #: 28341 Customer ID: 15030024 Report #: 2023-05989 Project ID: Groundwater Monitoring Collect DateTTime Matrix Sampled by 3/27/2023 9:42 AM Water JR Killette Test Method Results Date Analyzed Sodium EPA 200 7 Rev 44 1994 4.64 mg/L 04/07/2023 Aluminum EPA 200 7 Rev 4 4 1994 4.85 mg/L 04/05/2023 Sulfate EPA 300 0 Rev 2 1 1993 13 mg/L 04/04/2023 Ammonia Nitrogen EPA 360 1 Rev 2 0 1993 < 0.2 mg/L 03/29/2023 Total Dissolved Solids (TDS) SM2540C-2015 52 mg/L 03/29/2023 Orthophosphate SM 4500 P E-2011 0.09 mg/L 03/29/2023 Total Organic Carbon (TOC) SM 5310 B-2014 5 9 mg/L 03/30/2023 Chloride SM4500 c E-2011 8 mg/L 03/30/2023 Nitrate Nitrogen (Catc) Nitrite Nitrogen EPA 353 2 Rev 2 0 1993 < 0 02 mg/L 03/29/2023 Nitrate+Nitrite-Nitrogen EPA 353.2 Rev 2 0 1993 0.09 mg/L 03/30/2023 Nitrate Nitrogen subtraction Method 0.09 mg/L 04/04/2023 Comment: Reviewed by: Report* 2023 05989 Page 5o15 Environmental Chemist, Inc., Wilmington, NC tab 494 6602 W,ndrn ; Way Wilmington, NC 28405 910 392 0223 Sample Receipt Checklist Clean; i-}►�}I u h'✓t-�.�G Date: e,Q3 Report Nxnber. _ 2023- D SCJ a C Receipt of sample: ECHEM Pickup IV Client Delivery ❑ UPS ❑ FedEx ❑ Other iD ❑ YES 10 NO N) N/A 1. /ere custody seals present on the cooler? ❑ YES ❑ NO N/A 2. If custody seals were present, were they intact/unbroke:n7) Original temperature upon receipt `C Corrected temperature upon receipt How temperature taken: ❑ Temperature Blank 14 Aga'nst Bottles IR Gu:n 10, Thomas Traceab!e S/N 210885809 flR Gu-i Correction Facto- IC: 0.0 I2 YES ❑ NO 3. If temperature of coo;ar exceeded 6'C, was Project Mgr./QA nouf ed? YES ❑ NO 4 Were proper custody p-ocedJres (rel nqj;shed/rece;ved) fo'ioued? YES ❑ NO 5. Were sample I0's l,sted on the COCA YES ❑ NO 6. Were sample, ID's I.s:ed on sample costa ner57 YES ❑ NO 7 Were collection da:e a -id t'-rin- I sted o-i the COC7 Yi:S ❑ NO 8 V/e.-E tests to be performed 15ted on the COC? Y; 5 ❑ NO 9 D:d sa-np'es a'rive in proper costa nz's fo- each test? � YES ❑ i`J'D 10. D:d sa'np!_, a•r;ve in good co-ed ton for each t?,=.? YC5 ❑ ii 11. V-as aJegJ?:e i?.,i'7 t vo U'ii_ a/a a�'e? YES ❑ f:D 12. %Verr s�T,p:rs recei: _.d ::h n proper no d ,n n"- for rea.! -d t_ ts s:s ? : c5 ❑ 1,5 13, VIe; E acid p-ese,: ed sa'rap es r,}ece .ed a. a PH o` <2? !t� ❑ iiD 14 1%.e•i E�GrI '�: ��n J� rlu d a: a p-.i >12. ❑ YES ❑ (<:O 15 Vile s.,'" d3 camp -s rece :ed a: a p-i >9? Yes ❑ Pl_D 15 l'/e'= Y,�3/Tf':J?r;= ^:�' rcLe _d a: a Cn'w' rte rc, :IJ� o a0 S rn/,? ❑ �J f�••� ❑ i:D 17 V., SJ:- r:"" E a: a c� r_s d.� •r=S ❑ �.7 1e !`.?' G':�n:a��sl�ia._ "�'T7:�i .: c.�J' Sample Preservation i ='j ^ r• COMMENTS: DOC Q', 002 R,.i 1 `C ENVIRONMENTAL CHEMISTS, INC o E:n9",�-0223'FAX9910392.442 24 NCDENR: DWR CERTIFICATION # 94 NCDHHS: = CERTIFICATION 4 37729 info@environmentats lchemh .com Analytical 8 Consulting Chemists COLLECTION AND CHAIN OF CUSTODY Client: Bay Valley Foods PROJECT NAME: groundwater monitoring 110 REPORT NO: z -Z) ADDRESS: 354 North Faison Avenue CONTACT NAME: Donovan Brock PO NO, Faison, NC 28341 REPORT TO: PHONFIFAX:S10.267.4711 x251 COPY TO: Donovan Brock@baygllgyfoods.com Sampled By: SAMPLE TYPE: I = Influent, E - Effluent. W = Well, ST = Stream, SO = Soil, SL = Sludge, Other. Sample Identification Collection o a E S v r " d $ " W Z PRESERVATION ANALYSIS REQtIESTEQ Date Time Temp = o Well: 3--�7-3 Is A�' LJ c X Chbride,Onho P TDS, Suffate, NO2 G Depth to water. C P —Go X 4 NO3, NH3 G Gallons bailed: C P X G G H (field): C P X ITOC G G Odor: C P G G Color. C P G G C P G G C P G G C P G G Total of 6 wells due in January, March, July, November wells: 1,2,3A,4A,$ and 8). Transfer Relinquished By- Date/Time Rpolved By: DatelTime 1 when Received By:, Rejected: Resampte Kequeszea: By; Date: Time: RkkOUND: Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION 8 94 NCDHKS: DLS CERTIFICATION 0 37729 COLLECTION AND CHAIN OF CUSTODY 6602 Windmill Way Wilmington, NC 28405 OFFICE: 910-392-0223 FAX 910-392-4424 info@environmentalchemists.com Client: Say Vall!j Foods PROJECT NAME: groundwater monitoring REPORT NO: ADDRESS: 364 North Faison Avenue CONTACT NAME: Donovan Brock PO NO: Faison, NC 28347 1 REPORT TO: PHONEIFAX:910.267.4711 x251 COPY TO: IDonovan Brock ba alle ods.Com Sampled Bv: 7ve - ill r,SAMPLE TYPE: I a Influent. E = Effluent. W = Well. ST = Stream. SO = Soil, SL n Sludge, Other: Sample Identification Collection m E $ a a o 2.. o se Q ur m PRESERVATION ANALYSIS REQUESTED Date Time em �+ , $ o W ih �✓ Well: 3 �� ►- 1--fa C t94 Ix Chloride,Ortho P, TDS, Sulfate, NO2 G Depth to water �f C P r X NO3. NH3 G G /G x. Gallons L C P I X JAI. Na G G H Id : C P X TOC G G Odor. C P G G Color. C P G G C P G G i C P t �- G G C P G G Total of 6 wells due in Jan uary, March, July, November (wells: 1,2,3A,4A,S and 8). Transfer Relinquished DateMme ived By: DateiTime 2. / 1 L#1 Temperature when Received Delivered By: By: ndmill Way ENVIRONMENTAL CHEMISTS, INC OFFICE: 0,392-0223E Wilmington,0-392-44245 NCDENR: DWQ CERTIFICATION 0 94 NCDHHS: DLS CERTIFICATION 0 37729 info@env1ronmentalchemists.com Analytical 8 Consulting Chemists COLLECTION AND CHAIN OF CUSTODY Client: Bay Valley Foods PROJECT NAME: groundwater monitoring REPORT NO: 2Z_ SYM ADDRESS: 354 North Faison Avenue CONTACT NAME: Donovan Brock PO NO: Faison, NC 28341 REPORT TO: PHONEIFAX:910.267.4711 x251 jI COPY TO: 113onovan Brock@bayvalIELbods.com tSampled By: SAMPLE TYPE: I = Influent, E a Effluent, W = Well, ST - Stream, SO = Soil, SL = Sludge, Other. Sample Identification Collection >s v ` O y d m E g a s rr m z PRESERVATION ANALYSIS REQUESTED Date Time Tern w a _ .. Well: J U Chloride.Ortho P. TDS, Sulfate, NO2 G ,_2 Depth to water: C P / X 11403. NH3 G G :;� Gallons bailed: l�_ C P X Al, Na G G H (field): S a b C P X TOC G G Odor: " `" C P G F G Color:"`' C P G G C P G G C P G G 1 7 C P G G Total of 6 wells due in Janusry, March, July, November (wells: 1,2,3A,4A,5 and 0). Transfer Relinquished DateMme Received Sy: DateTrne 1. g�4t 2. J Temperature when Received "C: L. Lj Accepted: Rejected:, Delivered By: ... -� _Received By: C 1A ..__ Time•- 2 Windmill Way 3405 ENVIRONMENTAL CHEMISTS, I N C OFFICE: 10-3 Z-0 23 FAX 9110-392-4424 Analytical & Cons► ring Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentalchemists.com COLLECTION AND CHAIN OF CUSTODY Client: Bay Valley Foods PROJECT NAME: groundwater monitoring REPORT NO: 45 . ADDRESS: 364 North Faison Avenue CONTACT NAME: Donovan Brock PO NO: Faison, NC 28341 REPORT TO: PHONFJFAX:910.267.4711 x261 COPY TO: 10onovan $rock ba ails oods.com [Sampled By: '40 SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other. Sample Identification Collection a 3 n - a o w z PRESERVATION ANALYSIS REQUESTED Date Time Tempy Y c ° /J Well: % 7^577777 .c�- C X Chloride,Ortho P, TDS, Sulfate, Not G Depth to water. J y C P X NO3, NH3 G G Gallons bailed: '� C P X AI, Na G G H ifielft �� ' C P X ITOC G G Odor. " C P G G Color: C P G G C P G G C P G G C P G G Total of 6 wells due in Janusry, March, July, November (wells: 1,2,3A,4A,5 and 8). Transfer Relinquished ime ved By: DateMme 1.-- 2. c� Temperature when Received "C: ____Accepted: Rejected: Resample Requested: Delivered By: f" �►r Received By: f,/#0.0 Date: Time: It-I.Mc- — ARO Analytical S Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION g 37729 COLLECTION AND CHAIN OF CUSTODY 6602 Windmill Way Wilmington, NC 2i140S OFFICE: 910-392-0223 FAX 910-392.4424 infaWnvironmentalchem ists.com Client: Bu Valig Foods PROJECT NAME: groundwater monitoring REPORT NO: ADDRESS: 354 North Faison Avenue CONTACT NAME: Donovan Brock PO NO: Faison, NC 28341 REPORT TO: PHONEIFAX:910.267.4711 x261 COPY TO: laonovan BrockAbayvalleyfoods.com Sampled Bv: SAMPLE TYPE: I = Influent. E = Effluent W = Well, ST - Stream, SO = Soil, SL = Sludge, Other: Sample Identification8 Collection •- p tiY o g PRESERVATION ANALYSIS REQUESTED Date Time Temp d = = z d o fh Well: Id c Pqq11x I ichionde.Ortho P, TDS, Sulfate, NO2 G G S Depth to Water C P X NO3, NH3 G G 1 Gallons bailed: a �a- C P X At, Na G G H (field): Sb 1 c P X ITOC G G Odor. C P G G Color: C P G G C P G G C P G G C P G G Total of 6 wells due in January, March, July, November wells:1,2,3A,4AS and 8). Transfer Relinquished DatelTime Received By: Dataffime 1, 12./ Temperature when Received IDeliivered By: By; ample Kequesteo• a: Time: Comments: —rt O Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION 0 94 NCDHHS: DLS CERTIFICATION 0 37729 COLLECTION AND CHAIN OF CUSTODY 6602 Windmill Way Wilmington, NC 2905 OFFICE: 910-392-0223 FAX 910-392-0424 info&nvironmentalchem ists.com Client: Bay Valley Foods PROJECT NAME: groundwater monitoring REPORT NO: ADDRESS: 354 North Faison Avenue CONTACT NAME: Donovan Brock PO NO: Faison, NC 28341 REPORT TO: PHONEIFAX:910.267.4711 x251 COPY TO: Donovan Brock ba alle aods.com Samoled Bv: SAMPLE TYPE: I = Influent. E = Effluent, W = Well, ST = Stream, SO = Soil, St_ = Sludge, Other. + Sample Identification Collection a g o V v m o V a E V m z PRESERVATION ANALYSIS REQUESTED Date Time Temp w z i X Xn W Well: p C X ChWWee,Ortho P TDS, SuftW Not G Depth to water. C P 2 X NO3. NH3 G G Gallons bailed: C P X Al, Na G G H (field): C P X [TOO G G Odor: h/o r-� C P G G Color. C P G G C P G G C P G G C P G G Total of 6 wells due in Jan urary, March, July, November wells: 1,2,3A,4A,5 and 8). Transfer Relinquished DateMme opecelved By: Daterrime 1 <: 2. Temperature when Received "C: Accepted: ✓ Rejected: Resample Requested: Delivered By: Received By: /'� A - Date: Time: Comments: N D: 10 Ik TrRC Appendix B Chloride and Total Dissolved Solids Concentrations through Time Charts First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 3,500 3,000 2,500 E c O s 1,500 v 1,000 500 Historic Chloride Concentrations in MW-1 through MW-5 and MW-8 Mdr, Mdr, Mdr, Mdr, Mdr, Mdr, Md� Mdr, Mdr, Md� Mdr. Mdr, Mdr, Mdr, Md�, Mdr, Mdr, Mdi; 4 d 4 d Md� 4 d,, 4,1 4 d 4 d 4,1 4 d 4,1 4, � 4 d 9S 96 9) 98 99 00 07 O2 O,� O4 OS 06 0> 08 09 70 77 72 73 74 7S 76 7) 78 79 �?O 23 �4 Date Historic Total Dissolved Solids Concentrations in MW-1 through MW-5 and MW-8 5,500 5,000 J E 4,500 c 0 4,000 c 0 V C v 3,500 0 —0 3,000 �. > 2,500 0 0 c6 2,000 0 1,500 1,000 500 0 C` CIA C0 C0 00 Is, �a� mat Oat 4� ,�O ,�N ,�0, ,�-' �1 ,LO ti� ;Lti 'Lb mat, 4a Oat, 4a 4a 4a fat, �a�, mat 4a �a�, Date 10 Ik TrRC Appendix C Mann Kendall Statistical Analysis Worksheets First Semi -Annual Report 2023 — Pickles Manufacturing June 23, 2023 TRC Project No. 528255.0003.0000 MANN-KENDALL for Constituent Trend TOOLKIT Analysis Evaluation Date: 17-May-23 Job ID: 528255.0003.0000 Facility Name: Pickles Manufacturing, LLC Constituent: Chloride Conducted By: Jim Hurley Concentration Units: m /L Sampling PointlD: MW-1 I MW-2 I MW-3A I MW-4A I MW-5 I MW-8 Event Sampling Date ..... 10 CHLORIDESampling • • it - 1 1311 10 8 96 27 1 707 7.1 8 2 7/ 8 10 5 349 338 740 9.5 3 11/10/10 5 274 148 787 8A 4 3 24 11 8 302 195 821 11.5 9.3 5 71411 7 340 998 12.1 6 11 1511 6 764 350 12.7 144 7 3 22 12 5.7 180 527 12.3 36.9 8 71212 0.5 119 724 9.6 9 11 15 12 6.7 301 693 11.9 10 3 28 13 5.5 40 185 381 13 87.7 11 7/16/13 7.1 21 427 5.7 12 11 2613 7.2 87.4 306 788 135 15.3 13 3/27/14 7.8 18 58 464 8.7 13.2 14 7/22/14 5.7 41.7 71 625 17.6 13.9 15 11/20/14 7.1 99 240 650 18.7 11 16 3/15/15 2.5 33 81 433 2.5 2.5 17 7/1/15 5 81 230 721 11 8 18 11/1/15 6 26 16 415 6 7 19 3/1/16 5 103 145 433 2.5 5 20 7/1/16 2.5 64 252 389 5 5 21 11/1/16 2.5 257 57 322 9 6 22 3/23/17 8 349 322 554 16 7 23 7 20 17 2.5 238 265 420 10 6 24 11/21/17 2.5 751 293 617 12 11 25 3 23 18 8 507 202 335 7 17 26 7 19 18 3 435 202 1260 12 36 27 11 1518 6 42 180 601 8 8 28 3/17/2019 5 241 87 457 10 5 29 7/1/2019 3 683 177 1500 16 30 11/1/2019 12 702 273 1080 13 31 3/19/2020 6 240 41 485 12 7 32 7/30/2020 10 318 123 415 12 6 33 11/19/2020 6 13 284 11 33 34 3/19/2021 8 14 25 209 10 5 35 7/29/2021 6 64 243 427 5 5 36 11/23/2021 7 689 281 613 13 37 3/29/2022 9 1 242 232 549 1 14 2.5 38 7/25/2022 6 1 836 271 521 1 2.5 39 11/17/20221 3 1 106 429 i 17 40 3/27/2023 12 121 367 17 1 8 Coefficient of Variation: - r Mann -Kendall Statistic (S): Confidence Factor: l Concentration Trend: . r 10000 _MW-1 J 1000 -MW-2 Mw-3A -MW-4A C� v 100vegLkA ��MW-8 = -MW-8 O a 10 Y c�i 1 c O U 0.1 07109 12/14 09117 06120 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95 % = Increasing or Decreasing; >_ 90 % = Probably Increasing or Probably Decreasing; < 90 % and S>0 = No Trend; < 90 % , S<_0, and COV >_ 1 = No Trend; < 90 % and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc, www.gsi-net.com MANN-KENDALL for Constituent Evaluation Date: 17-May-23 Facility Name: Pickles Manufacturing, LLC Conducted By: Jim Hurley TOOLKIT Trend Analysis Job ID: 528255.0003.0000 Constituent: Total Dissolved Solids Concentration Units: m /L Sampling PointlD: MW-1 I MW-2 I MW-3A I MW-4A I MW-5 I MW-8 Sampling Event 1 Sampling Date 3/11/10 124 292 92 • 1,170 • M0 I 88 78 2 7/8/10 33 695 610 1,510 71 3 11/1/10 25 261 1,320 55 66 4 3/24/11 40 212 1,360 42 45 5 7/14/11 36 560 1,770 59.4 6 11/15/11 31 664 1,410 75.3 7 3/22/12 37 288 970 59.3 101 8 7/12/12 33 544 2,080 86 9 11/15/12 31 462 1,290 65 620 10 3/28/13 13 185 395 914 55 218 11 7/16/13 49 380 52 932 184 12 11/26/13 50 524 1,450 313 79 13 3/27/14 25 252 935 96 57 14 7/22/14 28 228 334 1,150 92 61.2 15 11/20/14 13 237 375 880 53 1 43 16 3/15/15 33 172 153 733 85 42 17 7/1/15 20 296 470 1,160 70 63 18 11/15/15 34 172 68 762 91 50 19 3/1/16 35 284 282 750 80 42 20 7/16/16 33 414 477 939 84 61 21 11/1/16 37 655 56 692 87 47 22 3/23/17 51 651 475 849 100 55 23 7/21/17 40 718 471 763 92 46 24 11/20/17 40 1,890 476 1,350 79 80 25 3/23/2018 60 1,120 428 705 105 58 26 7/20/2018 41 877 430 1,490 108 240 27 11/15/18 35 190 195 980 100 74 28 3/17/2019 42 513 186 651 98 47 29 7/1/2019 46 1,160 409 2,090 99 30 11/1/2019 30 1,430 391 2,010 84 31 3/19/2020 47 382 96 750 97 45 32 7/30/2020 56 982 258 861 100 52 33 11/19/2020 37 52 546 221 33 34 3/19/2021 61 536 79 416 330 43 5 7/29/2021 5 77 5OF 612 134 53 36 11/23/2021 54 1, 3 70 559 944 119 37 3/29/2022 67 1 446 39 1,000 144 59 38 7/25/2022 47 1 1,480 75—oT 1 987 256 39 111/17/20221 39 295 1,000 108 40 3/27/2023 7 178 772 187 52 Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: Concentration 1000 J C� 1000 v Q 100 i+ t3 L Y y 10 i I _Mw 1 BMW-2 -MW-3A -MW-4A -MW-5 -MW-8 t� c O U 1 07/09 2/14 09117 06120 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>O) or decreasing (S<O): >95 % = Increasing or Decreasing; >_ 90 % = Probably Increasing or Probably Decreasing; < 90 % and S>O = No Trend; < 90 % , S<_0, and COV >_ 1 = No Trend; < 90 % and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc, www.gsi-net.com