NC0027227_Renewal (Application)_20230622

ROY COOPER
Governor
ELIZABETH S. BISER
Secretary
RICHARD E. ROGERS, JR.
Director
Craig Kumpel
Sunoco Midstream LLC
8111 Westchester Dr Ste 600
Dallas, TX 75225
Subject: Permit Renewal
Application No. NCO027227
Sunoco Midstream - Selma
Johnston County
Dear Permiee:
NORTH CAROLINA
Environmental Quality
June 22, 2023
The Water Quality Permitting Section acknowledges the April 18, 2023 receipt of your permit renewal application and
supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting
branch. Per G.S. 150E-3 your current permit does not expire until permit decision on the application is made.
Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The
permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a
timely manner to requests for additional information necessary to allow a complete review of the application and renewal
of the permit.
Information regarding the status of your renewal application can be found online using the Department of Environmental
Quality's Environmental Application Tracker at:
https•//deg.nc gov/permits-regulations/permit-guidance/environmental-application-tracker
If you have any additional questions about the permit, please contact the primary reviewer of the application using the
links available within the Application Tracker.
ec: WQPS Laserfiche File w/application
Sincerely,
Cynthia Demery
Administrative Assistant
Water Quality Permitting Section
North Carollna Department of Environmental Quality I Division of Water Resources
r Rakigh Regional Office I 3800 Barrett Drive I Raleigh. North Carofina 27609
919.791.4200

�-4 ZENITR -3,
April 10, 2023
John Hennessy
NPDES Permit Section CPI
Department of Water Resources �O
North Carolina Department of Environmental Quality
217 West Jones Street
Raleigh, NC 27603
RE: NPDES Permit No. NC0027227 Renewal Application
Zenith Energy Terminals Holdings LLC
2999 W. Oak Street
Selma, NC 27576
Dear Mr. Hennessy:
RECEIVED
APR 17 2023
NCDEQ/DWR/NPDES
Zenith Energy Terminals Holdings LLC (Zenith Energy) is submitting this NPDES Permit renewal
application for our Selma, North Carolina terminal. Attached to this cover letter are the following forms
and supporting documentation:
• EPA NPDES Form 1 - General Information
- EPA NPDES Form 1 Attachment - Topographic Map
• EPA NPDES Form 2F - Stormwater Discharges Associated with Industrial Activity
- EPA NPDES Form 2F Attachment 1 - Drainage Map
- EPA NPDES Form 2F Attachment 2 - Analytical Reports
Zenith Energy appreciates your consideration of the matter. Please do not hesitate to contact Mr.
Shannon Caldwell at [phone] or myself at [phone] if you have any questions on this
matter.
Sincerely,
Andrew G. Danhof, Jr.,
Manager, Environmental and Regulatory
3900 Essex Lane, Suite 7001 Houston, TX 77027
Phone: [phone]

Mr. John Hennessy
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA 1NPDES Form 1
April 10, 2023

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110000347134
NCO027227
Zenith Energy Selma
OMB No. 2040-0004
Form
U.S. Environmental Protection Agency
1
\=/EPA Application for NPDES Permit to Discharge Wastewater
NPDES
GENERAL INFORMATION
SECTION•
•Dr
1.1 Applicants Not Required to Submit Form 1
1.1.1
Is the facility a new or existing publicly owned
1.1.2
Is the facility a new or existing treatment works
treatment works?
treating domestic sewage?
If yes, STOP. Do NOT complete No
If yes, STOP. Do NOT No
Form 1. Complete Form 2A.
complete Form 1. Complete
Form 2S.
1.2
Applicants Required to Submit Form 1
w
1.2.1
Is the facility a concentrated animal feeding
1.2.2
Is the facility an existing manufacturing,
operation or a concentrated aquatic animal
commercial, mining, or silvicultural facility that is
a
production facility?
currently discharging process wastewater?
oYes
4 Complete Form 1 No
Yes + Complete Form 0✓ No
z
and Form 2B.
1 and Form 2C.
a
1.2.3
Is the facility a new manufacturing, commercial,
1.2.4
Is the facility a new or existing manufacturing,
mining, or silvicultural facility that has not yet
commercial, mining, or silvicultural facility that
=
commenced to discharge?
discharges only nonprocess wastewater?
d
Yes 4 Complete Form 1 No
0 Yes + Complete Form 0 No
U,
and Form 2D.
1 and Form 2E.
1.2.5
Is the facility a new or existing facility whose
discharge is composed entirely of stormwater
a
associated with industrial activity or whose
discharge is composed of both stormwater and
non-stormwater?
❑✓ Yes + Complete Form 1 No
and Form 2F
unless exempted by
40 CFR
122.26(b)(14)(x) or
(b)(15).
SECTIONADDRESS.
• •
2.1
Facility Name
Zenith Energy Selma
0
2.2
EPA Identification Number
o
u
C
110000347134
v
2.3
Facility Contact
H
d
Name (first and last)
Title
Phone number
a
Andrew Danhof
Manager, Environmental & Regulatory
[phone]
Email address
[e-mail]
2.4
Facility Mailing Address
zStreet
or P.O. box
3900 Essex Lane, Suite 700
City or town
State
ZIP code
Houston
TX
77027
EPA Form 3510-1 (revised 3-19) Page 1

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110000347134
NCO027227
Zenith Energy Selma
OMB No. 2040-0004
N
2.5
Facility Location
o .y
Street, route number, or other specific identifier
Q 0
2999 W. Oak Street
rn
o
County name
County code (if known)
z
Johnston
E _j
City or town
State ZIP code
z m
Selma
NC 27576
SECTION•
NAICS CODES1
3.1
SIC Code(s)
Description (optional)
4226
Special Warehousing and Storage, NEC
m
0
U
U)
V
z
3.2
NAICS Code(s)
Description (optional)
-a
`6
493190
Other Warehousing and Storage
U
U)
SECTIONOPERATOR
INFORMATION (40
4.1
Name of Operator
Zenith Energy Terminals Holdings LLC
0
4.2
Is the name you listed in Item 4.1 also the owner?
€
El Yes El No
0
Z
4.3
Operator Status
❑ Public —federal ❑ Public —state ❑ Other public (specify)
o
❑� Private ❑ Other (specify)
4.4
Phone Number of Operator
[phone]
4.5
Operator Address
w
Street or P.O. Box
d
3900 Essex Lane, Suite 700
c .S
City or town
State
ZIP code
0 o
a U
Houston
TX
77027
a
Email address of operator
O
[e-mail]
SECTION•1
5.1
Is the facility located on Indian Land?
❑ Yes ❑✓ No
EPA Form 3510-1 (revised 3-19) Page 2

4 Idenfificafion Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
ENVIRONMENTAL1
6.1 Existing Environmental Permits (check all that apply and print or type the corresponding permit number for each)
m NPDES (discharges to surface ❑ RCRA (hazardous wastes) ❑ UIC (underground injection of
water) I fluids)
❑ PSD (air emissions)
❑ Ocean dumping (MPRSA)
❑ Nonattainment program (CAA)
❑ Dredge or fill (CWA Section 404)
❑ NESHAPs (CAA)
IZI Other (specify)
NC Air Permit No. 042961118
71 I Have you attached a topographic map containing all required information to this application? (See instructions for
cospecific requirements.)
a
a
d
e
m
L
M
R
Z
❑✓ Yes ❑ No ❑ CAFO—Not Applicable (See requirements in Form 2B.)
8.1 IDescribe the nature of your business.
Storage and loading of petroleum products.
9.1 1 Does your facility use cooling water?
d ❑ Yes ❑✓ No + SKIP to Item 10.1.
3 9.2 Identify the source of cooling water. (Note that facilities that use a cooling water intake structure as described at
a, b 40 CFR 125, Subparts I and J may have additional application requirements at 40 CFR 122.21(r). Consult with your
YNPDES permitting authority to determine what specific information needs to be submitted and when.)
V c
10.1 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(m)? (Check all that
apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and
when.)
d ❑ Fundamentally different factors (CWA ❑ Water quality related effluent limitations (CWA Section
d Section 301(n)) 302(b)(2))
❑ Non -conventional pollutants (CWA ❑ Thermal discharges (CWA Section 316(a))
= Section 301(c) and (g))
❑✓ Not applicable
EPA Form 3510-1 (revised 3-19) Page 3

EPA Identification Number NPDES Permit Number
Facility Name Form Approved 03/05/19
110000347134 NCO027227
Zenith Energy Selma OMB No. 2040-0004
SECTION•
1
11.1
In Column 1 below, mark the sections of Form 1 that you have completed and are submitting with your application.
For each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note
that not all applicants are required to provide attachments.
Column 1
Column 2
❑✓ Section 1: Activities Requiring an NPDES Permit
❑ w/ attachments
✓❑ Section 2: Name, Mailing Address, and Location
❑ w/ attachments
❑✓ Section 3: SIC Codes
❑ w/ attachments
✓❑ Section 4: Operator Information
❑ w/ attachments
❑✓ Section 5: Indian Land
❑ w/ attachments
❑� Section 6: Existing Environmental Permits
❑ w/ attachments
d
E
❑✓ Section 7: Ma
w/ topographic
❑ Elw/ additional attachments
cop
ma
N
o
w
0Section 8: Nature of Business
❑ w/ attachments
R
w
❑✓ Section 9: Cooling Water Intake Structures
❑ w/ attachments
d
�'
❑✓ Section 10: Variance Requests
❑ w/ attachments
v
c
�_
❑ Section 11: Checklist and Certification Statement
❑ w/ attachments
Y
t
11.2
Certification Statement
U
1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualfied personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete. I am aware that then: are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations.
Name (print or type first and last name)
Official title
Shannon Caldwell
Vice President - HSE and Regulatory
Signature
Date signed
\�
Ll
EPA Form 3510-1 (revised 3-19) Page 4

Mr. John Hennessy
NPDES Permit No. NCO027227 Renewal Application
Zenith Enema Selma
EPA NPDES Form 1 Attachment
Topographic Map
April 10, 2023

R
tURNAGE
. W. -kke- AM.
Outfall #1
Lat 3i 33' 11.50' N
Zenith Energy Terminals
-ut
Long: 78° 18' 45.6' W
2999 West Oak Street
-4w -err
-WW
Selma, NC27576
4M.A
Lat 35° 33' 15.5' N
Long. 7r 18' 410' W
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Z. I EPA Form 1 Figure 1- Topographic Map
29vi ns�r o� s�r,.i Selma Terminal _
gym, NC zee NPDES Permit N. NC007M7 ReneH al Application - I +�
-NPD

Mr. John Hennessy
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA NPDES Form 2F
April 10, 2023

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
Form U.S Environmental Protection Agency
2F \`. EPA Application for NPDES Permit to Discharge Wastewater
NPDES STORMWATER DISCHARGES ASSOCIATED WITH INDUSTRIAL ACTIVITY
SECTIONOUTFALL LOCATION1 •
1.1 Provide information on each of the facility's outfalls in the table below
Outfall Receiving Water Name Latitude Longitude
Number
01 Neuse River 35� 33' 10.99" N 70' 18' 45.60" W
c
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SECTION'• ) •
2.1 Are you presently required by any federal, state, or local authority to meet an implementation schedule for constructing,
upgrading, or operating wastewater treatment equipment or practices or any other environmental programs that could
affect the discharges described in this application?
❑ Yes ✓❑ No 4 SKIP to Section 3.
2.2 Briefly identify each applicable project in the table below.
Brief Identification and Affected Outfalls Final Compliance Dates
Description of Project (list outfall numbers) Source(s) of Discharge
Required Projected
v,
c
a
E
a�
0
a
E
2.3 Have you attached sheets describing any additional water pollution control programs (or other environmental projects
that may affect your discharges) that you now have underway or planned? (Optional Item)
❑ Yes ❑ No
EPA Form 3510-2F (Revised 3-19) Page 1

EPA Identification
Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000347134
NCO027227 Zenith Energy Selma OMB No. 2040-M
SECTIONDRAINAGE
1
0
3.1
Have you attached a site drainage map containing all required information to this application? (See instructions for
M C
specific guidance.)
o
® Yes ❑ No
SECTIONPOLLUTANT
SOURCES
4.1
Provide information on the facility's pollutant sources in the table below.
Outfall
Impervious Surface Area
Total Surface Area Drained
Number
(within a mile radius of the facility)
(within a mile radius of the facility)
specify units
specify unds
1
2.55
acres
0.81
acres
specify units
specify units
specfy units
specify units
specify units
specify units
specify unds
specify units
specify units
specify units
4.2
Provide a narrative description of the facility's significant material in the space below. (See instructions for content
requirements.)
The significant materials stored at the facility are gasoline, diesel, and ethanol that is denatured with gasoline. The
a�
significant materials are stored in several large aboveground storage tanks which are surrounded by an earthern berm.
U
oThe
significant materials enter the facility via pipeline and exit the facility via a truck loading rack.
N
Fertilizers, pesticides, herbicides, and soil conditioners are rarely if ever used at the facility.
0
a
4.3
Provide the location and a description of existing structural and non-structural control measures to reduce pollutants in
stormwater runoff. See instructions for specificguidance.)
Stormwater Treatment
Codes
Outfall
from
Number
Control Measures and Treatment
Exhibit
2F-1
list
1
Inspections prior to discharge
Not Applica
EPA Form 3510-2F (Revised 3-19) Page 2

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
SECTION•N STORMWATER DISCHARGES (40
5.1 1 certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the
presence of non-stormwater discharges. Moreover, I certify that the outfalls identified as having non-stormwater
discharges are described in either an accompanying NPDES Form 2C. 2D, or 2E application.
Name (print or type first and last name) Official title
Shannon Caldwell Vice President - HSE & Regulatory
Signature Date signed
an 5.2 Provide the testing information requested in the table below.
Outfall Onsite Drainage Points
o Number Description of Testing Method Used Date(s) of Testing Directly Observed
During Test
d
is
1 N/A - There are no non-stormwater discharges.
0
in
c
0
Z
SECTION. SIGNIFICANT LEAKS OR 1
6•1 Describe any significant leaks or spills of toxic or hazardous pollutants in the last three years.
.a There were no significant leaks or spills within the last three years.
rn
0
Y
f6
d
J
C
V
.0
N
SECTION•' • i
See the instructions to determine the pollutants and parameters you are required to monitor and, in turn, the tables you must
o com fete. Not all applicants need to complete each table.
E7.1 Is this a new source or new discharge?
w ❑ Yes -+ See instructions regarding submission of ❑ No 4 See instructions regarding submission of
` estimated data. actual data.
a
C Tables A, B, C, and D
N 7.2 Have you completed Table A for each outfall?
0 ❑✓ Yes ❑ No
EPA Form 3510-2F (Revised 3-19) Page 3

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110000347134
NCO027227
Zenith Energy Selma
OMB No. 2040-0004
7.3
Is the facility subject to an effluent limitation guideline (ELG) or effluent limitations in an NPDES permit for its process
wastewater?
❑ Yes ❑ No 4 SKIP to Item 7.5.
7.4
Have you completed Table B by providing quantitative data for those pollutants that are (1) limited either directly or
indirectly in an ELG and/or (2) subject to effluent limitations in an NPDES permit for the facility's process wastewater?
❑ Yes ❑ No
7.5
Do you know or have reason to believe any pollutants in Exhibit 2F-2 are present in the discharge?
❑ Yes El No 4 SKIP to Item 7.7.
7.6
Have you listed all pollutants in Exhibit 2F-2 that you know or have reason to believe are present in the discharge and
provided quantitative data or an explanation for those pollutants in Table C?
❑ Yes ❑ No
7.7
Do you qualify for a small business exemption under the criteria specified in the Instructions?
❑ Yes +SKIP to Item 7.18. ✓❑ No
7.8
Do you know or have reason to believe any pollutants in Exhibit 2F-3 are present in the discharge?
❑✓ Yes Cl No + SKIP to Item 7.10.
7.9
Have you listed all pollutants in Exhibit 2F-3 that you know or have reason to believe are present in the discharge in
Table C?
r
00
0Yes C]No
0
7.10
Do you expect any of the pollutants in Exhibit 2F-3 to be discharged in concentrations of 10 ppb or greater?
M
€
❑ Yes ✓❑ No + SKIP to Item 7.12.
0
s
7.11
Have you provided quantitative data in Table C for those pollutants in Exhibit 2F-3 that you expect to be discharged in
rn
concentrations of 10 ppb or greater?
R
Yes ❑ No
AA
7.12
Do you expect acrolein, acrylonitrile, 2,4-dinitrophenol, or 2-methyl-4,6-dinitrophenol to be discharged in concentrations
of 100 ppb or greater?
❑ Yes [Z] No + SKIP to Item 7.14.
7.13
Have you provided quantitative data in Table C for the pollutants identified in Item 7.12 that you expect to be
discharged in concentrations of 100 ppb or greater?
❑ Yes ❑ No
7.14
Have you provided quantitative data or an explanation in Table C for pollutants you expect to be present in the
discharge at concentrations less than 10 ppb (or less than 100 ppb for the pollutants identified in Item 7.12)?
❑ Yes 0 No
7.15
Do you know or have reason to believe any pollutants in Exhibit 2F-4 are present in the discharge?
❑ Yes [Z] No + SKIP to Item 7.17.
7.16
Have you listed pollutants in Exhibit 2F-4 that you know or believe to be present in the discharge and provided an
explanation in Table C?
❑ Yes ❑ No
7.17
Have you provided information for the storm event(s) sampled in Table D?
❑ Yes ❑✓ No
EPA Form 3510-2F (Revised 3-19) Page 4

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110000347134
NCO027227
Zenith Energy Selma
OMB No. 2040-0004
Used or Manufactured Toxics
7.18
Is any pollutant listed on Exhibits 2F-2 through 2F-4 a substance or a component of a substance used or
omanufactured
as an intermediate or final product or byproduct?
❑ Yes ❑ No 4 SKIP to Section 8.
c
0
Ca
7.19
List the pollutants below, including TCDD if applicable.
1. 4. 7.
d
2. 5. 8.
s
U
0
3. 6. 9.
SECTION
8. BIOLOGICAL
TOXICITY TESTING DATA (40 CFR 122.21 (g)(1 1))
8.1
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on
any of your discharges or on a receiving water in relation to your discharge within the last three years?
0
❑ Yes ❑ No 4 SKIP to Section 9.
F'
8.2
Identify the tests and their purposes
below.
X
Test(s)
Purpose of Test(s)
Submitted to NPDES
Permitting Authority?
Date Submitted
0
~
Whole Effluent Toxicity
NPDES Requirement
❑✓ Yes ❑ No
02/22/2023
is
U
0
❑ Yes ❑ No
m0
❑ Yes ❑ No
SECTION•
-• •- •
9.1
Were any of the analyses reported in Section 7 (on Tables A through C) performed by a contract laboratory or
consulting firm?
❑✓ Yes ❑ No + SKIP to Section 10.
9.2
Provide information for each contract laboratory or consulting firm below.
Laboratory Number 1
Laboratory Number 2
Laboratory Number 3
Name of laboratory/firm
Pace Analytical
0
0
c
Laboratory address
N
9800 Kincey Ave. Suite 100
v
Huntersville, NC 28078
c
U
10
o
Phone number
U
[phone]
Pollutant(s) analyzed
Benzene, Toluene,
Ethylbenzene, Naphthalene,
total suspended solids, volatile
organics, semivolatile organics,
oil & grease, total phenolics,
turbidity, and xylene.
EPA Form 3510-2F (Revised 3-19) Page 5

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
SECTION1 CHECKLIST AND CERTIFICATION1
10.1 In Column 1 below, mark the sections of Form 2F that you have completed and are submitting with your application. For
each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not
all applicants are required to com lete all sections or provide attachments.
Column 1
Column 2
0 Section 1
❑ w/ attachments (e.g., responses for additional outfalls)
❑✓ Section 2
❑ w/ attachments
0 Section 3
w/ site drainage map
0 Section 4
❑ w/ attachments
0 Section 5
❑ w/ attachments
.-
0 Section 6
❑ w/ attachments
c
d
0 Section 7
❑✓ Table A ❑ w/ small business exemption request
0
c
El Table B ✓❑ w/ analytical results as an attachment
w
w
❑ Table C ❑ Table D
❑✓ Section 8
❑ w/attachments
-a
c
�_❑
Section 9
❑ w/attachments (e.g., responses for additional contact laboratories or firms)
Y
t
0 Section 10
❑
c.�
10.2
Certification Statement
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible
for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine
and imprisonment for knowing violations.
Name (print or type first and last name)
Official title
Shannon Caldwelll
Vice President of HSE & Regulatory
Signature
Date signed
EPA Form 3510-2F (Revised 3-19) Page 6

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma OMB No.2040-M
TABLE A. CONVENTIONAL AND NON CONVENT10NAL1
You must provide the results of at least one anah sis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details and requirements.
Pollutant or Parameter
Maximum Daily Discharge
(specify units)
Average Daily Discharge
(specify units)
Number of Storm
Events Sampled
Source of
Information
(new source/new
dischargers only, use
codes in instructions)
Grab Sample Taken
During First
30 Minutes
Flow -Weighted
Composite
Grab Sample Taken
During First
30 Minutes
Flow -Weighted
Composite
1.
Oil and grease
c4.9 mg/L
<4.9 mg/L
2
2.
Biochemical oxygen demand (BODe)
3.
Chemical oxygen demand (COD)
4.
Total suspended solids (TSS)
5.6 mg/L
4.7 mg/L
2
5.
Total phosphorus
6.
Total Kjeldahl nitrogen (TKN)
7.
Total nitrogen (as N)
pH (minimum)
8.
pH (maximum)
Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2F (Revised 3-19) Page 7

EPA Identficafion Number NPDES Permit Number Facility Name Outfall Number Form Approved MOM
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
List each pollutant that is limited in an effluent limitation guideline (ELG) that the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater (if the
facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details and requirements.
Pollutant and CAS Number (if available)
Maximum Daily Discharge
(spec fij units)
Average Daily Discharge
(speciry units)
Number of Storm
Events Sampled
Source of
Information
(new source/new
dischargers only; use
codes in instructions)
Grab Sample Taken
During First
30 Minutes
Flow -Weighted
Composite
Grab Sample Taken
During First
30 Minutes
Flow -Weighted
Composite
Benzene (71-43-2)
< 1.0 ug/L
< 1.0 ug/L
2
Ethylbenzene (100-41-4)
< 1.0 ug/L
< 1.0 ug/L
2
Naphthalene (91-20-3)
< 5.0 ug/L
< 5.0 ug/L
2
Toluene (108-88-3)
< 1.0 ug/L
< 1.0 ug/L
2
Xylene (1330-20-7)
< 3.0 ug/L
< 3.0 ug/L
2
Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
EPA Form Z10-21' (Revised 319) Page 9
R E E IVIED
APR 17 2023

Mr. John Hennessy
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA NPDES Form 2F Attachment 1
Topographic Map
April 10, 2023

r
r
Drainage Area
�� i`u'fall rl
ERRT EN
OJTrpLL Na 1
[mpen-iousSurfaces —
r^
Direction of
Storm Water
fLc Flow
lJ� rwrcaTr
LM
�— _Drainage
Area
Impervious
Surfaces in
Drainage
Lmbp R.d P _ Area
iaa W
e �
1
GASpLll1E M
ASI1 �
TN II0 /r
G�SRRE TMr( 11W iM�. I103 TpMII n0a
�„�_ nffsu n¢sEL RuxL
to �—
I�
C
ca�w,c scu - rm —
7rnt6 em® Temlmals EPA Form 2F - Drainage Map
2999VWeAOASUM Selma Terminal
...�. Sehrk NC DS76 NFDES Permit N. NC0027227 Renewal Application w
SEL-NDPES-2

Mr. John Hennessy
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA NPDES Form 2F Attachment 2
Analytical Reports
April 10, 2023

acmnalytical
ww.pwWabs.com
I
May 03, 2022
Ben Smith
Zenith Energy Terminals
2999 West Oak Street
Selma, NC 27576
RE: Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Dear Ben Smith:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
Enclosed are the analytical results for sample(s) received by the laboratory on April 22, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sarah Graham
[e-mail]
[phone]
Project Manager
Enclosures
cc: Andrew Danhof, Zenith Energy
Bridget Fountain, Zenith Terminals
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
[phone]
Page 1 of 14

1�;5'cieAnalyfical"
riwip�eNe9s.com
I
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VrginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
vrginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 14

ljceAnalyfical"
www.pactiabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
MONTHLY STORMWATER
92600585
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92600585001
OUTFALL 1
EPA 1664B
ICO
1
PASI-C
EPA624.1
SAS
8
PASI-C
SM 213OB-2011
CDC
1
PASI-A
SM 254OD-2015
MA132
1
PASI-A
EPA420.4 Rev 1.0 1993
KDF1
1
PASI-A
PASI-A= Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 14

?eceAnalytical
www.pacolabs.com
ANALYTICAL RESULTS
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Pace Analytical Services, LLC
9800 Kinsey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL 1 Lab ID: 92600585001 Collected: 04/22/22 04:00 Received: 04/22/22 08:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Oil and Grease
624 Volatile Organics
Benzene
Ethylbenzene
Naphthalene
Toluene
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
Toluene-d8 (S)
1,2-Dichloroethane-d4 (S)
2130E Turbidity
Turbidity
2540D Total Suspended Solids
Total Suspended Solids
420.4 Phenolics, Total
Phenolics, Total Recoverable
Date: 05/03/2022 10:34 AM
Analytical Method: EPA 1664B
Pace Analytical Services - Chariotte
ND mg/L
4.9
1
04/25/22 22:34
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
ND ug/L
1.0
1
04/26/2219:40
71-43-2
ND ug/L
1.0
1
04/26/2219:40
100-41-4
ND ug/L
5.0
1
04/26/2219:40
91-20-3
ND ug/L
1.0
1
04/26/2219:40
108-88-3
ND ug/L
3.0
1
04/26/2219:40
1330-20-7
103 %
70-130
1
04/26/2219:40
460-00-4
107 %
70-130
1
04/26/2219:40
2037-26-5
95 %
70-130
1
04/26/2219:40
17060-07-0
Analytical Method: SM 213OB-2011
Pace Analytical Services - Asheville
6.3 NTU 1.0 1 04/23/2214:27
Analytical Method: SM 2540D-2015
Pace Analytical Services - Asheville
5.6 mg/L 2.5 1 04126/2212:41
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services - Asheville
ND mg/L 0.020 1 05/02/2213:09 05/03/2209:02 64743-03-9 M1,R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 14

aceAnalytical
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I
QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 693977
Analysis Method:
EPA 1664E
QC Batch Method: EPA 1664B
Analysis Description:
1664 HEM, Oil and Grease
Laboratory:
Pace Analytical Services - Charlotte
Associated Lab Samples: 92600585001
METHOD BLANK: 3625107
Matrix: Water
Associated Lab Samples: 92600585001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0 04/25/22 22:34
LABORATORY CONTROL SAMPLE:
3625108
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
40 34.2
86 78-114
MATRIX SPIKE SAMPLE:
3625109
92600773001 Spike
MS MS % Rec
Parameter
Units
Result Conc.
Result % Rec Limits Qualifiers
Oil and Grease
mg/L
ND 38.6
31.2 79 78-114
SAMPLE DUPLICATE: 3625110
92600773002 Dup
Parameter
Units
Result Result
RPD Qualifiers
Oil and Grease
mg/L
ND 1.81
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 14

aceAnalytical
ww.pacalabs.cma
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
QC Batch: 694160
Analysis Method:
EPA 624.1
QC Batch Method: EPA 624.1
Analysis Description:
624 MSV
Laboratory:
Pace Analytical Services - Charlotte
Associated Lab Samples: 92600585001
METHOD BLANK: 3625966
Matrix: Water
Associated Lab Samples: 92600585001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Benzene
ug/L
ND
1.0
04/26/22 12:14
Ethylbenzene
ug/L
ND
1.0
04/26/22 12:14
Naphthalene
ug/L
ND
5.0
04/26/22 12:14
Toluene
ug/L
ND
1.0
04/26/22 12:14
Xylene (Total)
ug/L
ND
3.0
04/26/22 12:14
1,2-Dichloroethane-d4 (S)
%
91
70-130
04/26/22 12:14
4-Bromofluorobenzene (S)
%
103
70-130
04/26/22 12:14
Toluene-d8 (S)
%
107
70-130
04/26/22 12:14
LABORATORY CONTROL SAMPLE:
3625967
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Benzene
ug/L
20
18.0
90
70-130
Ethylbenzene
ug/L
20
18.0
90
70-130
Naphthalene
ug/L
20
20.0
100
70-133
Toluene
ug/L
20
18.2
91
70-130
Xylene (Total)
ug/L
60
54.1
90
70-130
1,2-Dichloroethane-d4 (S)
%
99
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3625968
3625969
MS
MSD
92600721001
Spike
Spike
MS
MSD MS MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD Qual
Benzene
ug/L
ND
80
80
81.9
80.0
102 100
75-125
2
Ethylbenzene
ug/L
ND
80
80
87.0
83.5
109 104
75-134
4
Naphthalene
ug/L
ND
80
80
78.8
74.0
98 92
57-150
6
Toluene
ug/L
0.41
80
80
473
462
76 62
75-134
2 M1
mg/L
Xylene (Total)
ug/L
ND
240
240
259
249
108 104
66-145
4
1,2-Dichloroethane-d4 (S)
%
95 99
70-130
4-Bromofluorobenzene (S)
%
102 101
70-130
Toluene-d8 (S)
%
98 99
70-130
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC.
Page 6 of 14

aceAnalytical
ww.paeNabs.eae
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
QC Batch: 693760
Analysis Method:
SM 213OB-2011
QC Batch Method: SM 213OB-2011
Analysis Description:
2130E Turbidity
Laboratory:
Pace Analytical Services - Asheville
Associated Lab Samples: 92600585001
METHOD BLANK: 3624143
Matrix: Water
Associated Lab Samples: 92600585001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Turbidity
NTU
ND
1.0 04/23/2214:25
LABORATORY CONTROL SAMPLE: 3624144
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Turbidity
NTU
10 10
100 90-110
SAMPLE DUPLICATE: 3624145
92600585001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Turbidity
NTU
6.3
6.3 0
RECEIVED
APR 17 2023
NCDEQ/DWR/NPDES
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 14

1�;a'ce Analytical
www.pecalabs.com
I
QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
QC Batch: 694058 Analysis Method: SM 254OD-2015
QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92600585001
METHOD BLANK: 3625544
Associated Lab Samples: 92600585001
Parameter Units
Total Suspended Solids mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2.5 04/26/2212:38
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE & LCSD: 3625545 3625877
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Total Suspended Solids mg/L 250 254 246 102 98 90-110 3 25
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC.
Page 8 of 14

aceAnalytical
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QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
QC Batch: 695057 Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92600585001
METHOD BLANK: 3630318
Associated Lab Samples: 92600585001
Parameter Units
Phenolics, Total Recoverable mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.020 05/03/22 07:45
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3630319
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phenolics, Total Recoverable mg/L 0.05 0.049 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3630320 3630321
MS MSD
35710941001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L 0.0076 0.05 0.05 0.049 0.056 85 98 90-110 12 M1,R1
U
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3630322 3630323
MS MSD
92600585001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L ND 0.05 0.05 0.049 0.040 99 81 90-110 20 M1,R1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC.
Page 9 of 14

Pace Analytical Services, LLC
aceMalytical ® 9800 Kincey Ave. Suite100
Huntersville, NC 28078078
WWW.oecelebs.cm [phone]
I
QUALIFIERS
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
'Total' may vary slightly from the sum of the reported component parameters.
Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 14

1�l;ace Analj4ical
www.pacWabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Lab ID
Sample ID
QC Batch Method
QC Batch
92600585001
OUTFALL 1
EPA 1664B
693977
92600585001
OUTFALL 1
EPA 624.1
694160
92600585001
OUTFALL 1
SM 2130E-2011
693760
92600585001
OUTFALL 1
SM 254OD-2015
694058
92600585001
OUTFALL 1
EPA 420.4 Rev 1.0 1993
695057
Date: 05/03/2022 10:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
EPA 420.4 Rev 1.0 1993 695382
Page 11 of 14

Document Name:
Document Revised: November 15, 2021
aCBl�lidlj/flCc?I •
Sample Condition Receipt SOUR)
Pagel of 2
Document No.:
Issuing Authority:
-�
F•CAR•CS-033•Rev.08
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑' Eden[3 Greenwood ❑ Huntersville ❑ RaleighjD' Mechanicsville❑ AtlantaQ Kemersville[]
USampleCandition Client Name: r_ Prr W01t a 92/3600585
ZCtll net , 1ert�. r`�e
(outlet: Feg ❑UPS QClien
❑ II I II"'II I I(' III (�II
Commercial ace❑0 her:
Custody Seal Present? [-]Yes PNO Seals Intact? Oyes NV-- 92600!385
f
DatelinitialsPerson Examining contents:� ZZ• 2Z t..—
Packing Material: []Bubble Wrap []Bubble Bags ❑None Other Biological Tissue Frozen?
Thermometer: Q QYes []No ❑N/A
❑ IR Gun IM- L r []Wet ❑Blue []None
Type of fee:
G� Correction Factor:
Cooler Temp: l Add/Subtract ('C) (j • 0 Temp should be above freezing to VC
q ❑Samples out of temp criteria. Samples on ice, cooling process
CooierTempCarrected('C ` ` hasbegun
USDA Regulated Sod ( OVA, water sample)
Qid samples origin to in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samp'esoriginate from a foreign source (Intematlonaliy,
YES EA includina Haanll and Prmrtn Rient? r Wa. riw.�
Cormments Discre an .
[C�I.In.fstod Present?
es
No
❑N A
1.
am les Arrived within Hold Time?
❑Na
❑N A
2.
Short Hold Time Analysis J<72 hr.)?
Yes
ONo
N/A
3.
Rush Turn Around lime Re uestad?
Llyes
No
[]N/A
4.
Sufficient Volume?
C�ites
No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
Zes
es
[]NO
QNo
❑N/A
EINIA
6.
C�Issolvedanal
Yes
No
❑N/A
7.
D5am les Field Filtered?
Yes
No
N/A
g.
Sample Labels Match COC?
Includes Date/Time/ID/Analysis Matrix:
Yes
❑No
❑N/A
9.
Headspace In VOA Vials >5.6mm ?
es
No
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
[]Yes
Yes
[]NO
No
❑N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Date/Time:
Date:
Project Manager SRF Review: Date:
Field Data Required? ❑Yes ❑No
. I i
t
I 1
Page 12 of 14

N
F~+
O
%a
J
W
A
W
N
-
Itemtt
BP4U-125 mL Plastic Unpreserved (N/A) (C�)
BP3U-250 mL Plastic Unpreserved (N/A)
SP2U-500 mL Plastic Unpreserved (N/A)
BP1U-1 liter Plastic Unpreserved (N/A)
6P4S-12S mL Plastic H2SO4 (pH < 2) (C1-)
MN-250 mL plastic HNO3 (pH < 2)
BP42-125 mL Plastic ZN Acetate & NaOH (>9)
BP4B-125 mL Plastic NaOH (pH > 12) (d-)
WGFU-Wide-mouthed Glass Jar Unpreserved
AG1U-1 liter Amber Unpreserved (N/A) (CH
AGIM-1 liter Amber HO (pH < 2)
AG3U-250 mL Amber Unpreserved (N/A) (CI-)
AG1S.1 liter Amber H?SO4 (pH < 21
AG35-250 mi. Amber H2504 (pH < 2)
z
ZZZZZ
IX
- AG3A(DGMA 250 mL Amber NH4CI (N/A)(CI-)
I
DG9H-40 mL VOA HO (N/A)
VGST-40 mL VOA Na25203 (N/A)
VGSU-40 mLVOA Unpreserved (N/A)
Dt;9p-40 mL VOA I-I3POA (µ/A)
VOAK (3 vials per kit)-5035 kit (N/A)
V/GK (3 viab per kit)-VPH/Gas kit (N/A)
SPST-125 ml Sterile Plastic (N/A - lab)
SPZT-250 ml Sterile Plastic (N/A— lab)
BP3A-250 mL Plastic (NH2)2504 (9.3-9.7)
AGOU-100 mL Amber Unpreserved vials (N/A)
VSGU-20.mL Scintillation vials (N/A)
DG9U-40 mi. Amber Unpreserved vials (N/A)
V
.0.

CHAIN -OF -CUSTODY I Analytical Request Document
ace ^ The Chain -of -Custody is a LEGAL [DOCUMENT. All relevant fields must be completed accurately.
Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at httm-1/infe, n—Lihc I— —
—11— . Section C
Required Client Information: Required Project Irrilormation: Invoice Information:
Fage Of
Company. 1
y,. Zen: th Ener gy Termna:s Ropor[Ta: Be, S7h Attention:
Address: 2999 West Oak Street Copy To: Company Name:
Selma. NC 27576
Em3;1: bensmittitxzenithterrNrials.com Purchase
Order it:
Address:
Pace Quoto:
Phone: [phone] Fax Projw
Requested Due Date: Project
Nam: Morit'lly SIOmrA,31,er
IN:
Pace Project Manmiqar. sarah,grahamapacelabs.com,
--- ---
Pace Profile ik 10746.2
NC:
R-i
MATRIX CODE
COLLECTED
Preservatives
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DATE Signed: 1..

aceAnalytical
www.wwsbs.com
December 02, 2022
Ben Smith
Zenith Energy Terminals
2999 West Oak Street
Selma, NC 27576
RE: Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Dear Ben Smith:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on November 16, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ariel S Fitzgerald
[e-mail]
[phone]
Project Manager
Enclosures
cc: Andrew Danhof, Zenith Energy
Bridget Fountain, Zenith Terminals
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 14

aceAnalytical
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Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky LIST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kinsey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 14

_ ?vceAnalyfical"
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I
SAMPLE ANALYTE COUNT
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92636946001 FALL OUT 1
SM 213OB-2011
AED
1
PASI-E
SM 254OD-2015
VLG
1
PASI-E
EPA 1664E
REL
1
PASI-C
EPA624.1
SAS
8
PASI-C
EPA420.4 Rev 1.0 1993
KDF1
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 3 of 14

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ANALYTICAL RESULTS
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: FALL OUT 1
Parameters
Lab ID: 92636946001 Collected: 11/16/22 06:01
Results Units Report Limit DF
Received: 11/16/22 08:50 Matrix: Water
Prepared Analyzed CAS No. Qual
2130E Turbidity EDN
Analytical Method: SM 213OB-2011
Pace Analytical Services - Eden
Turbidity
4.4 NTU
1.0
1
11/17/2217:39
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
3.8 mg/L
2.5
1
11/18/22 14:53
HEM, Oil and Grease
Analytical Method: EPA 1664E
Pace Analytical Services - Charlotte
Oil and Grease
ND mg/L
4.9
1
12/02/22 01:20
624 Volatile Organics
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
Benzene
ND ug/L
1.0
1
11/22/22 19:43
71-43-2
Ethylbenzene
ND ug/L
1.0
1
11/22/22 19:43
100-41-4
Naphthalene
ND ug/L
5.0
1
11/22/22 19:43
91-20-3
Toluene
ND ug/L
1.0
1
11/22/22 19:43
108-88-3
Xylene (Total)
ND ug/L
3.0
1
11/22/22 19:43
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101 %
70-130
1
11/22/22 19:43
460-00-4
Toluene-d8 (S)
106 %
70-130
1
11/22/22 19:43
2037-26-5
1,2-Dichloroethane-d4 (S)
84 %
70-130
1
11/22/22 19:43
17060-07-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services - Asheville
Phenolics, Total Recoverable
ND mg/L
0.020
1
11/29/22 11:10 11/30/22 07:52
64743-03-9 M1
Date: 12/02/2022 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 14

11ce Analytical
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Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 737883
QC Batch Method: SM 213OB-2011
Associated Lab Samples: 92636946001
METHOD BLANK: 3840397
Associated Lab Samples: 92636946001
Parameter Units
Turbidity NTU
LABORATORY CONTROL SAMPLE: 3840398
Parameter Units
Turbidity NTU
SAMPLE DUPLICATE: 3840399
Parameter Units
Turbidity NTU
SAMPLE DUPLICATE: 3840400
Parameter
Turbidity
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: SM 213OB-2011
Analysis Description: 2130B Turbidity EDN
Laboratory: Pace Analytical Services - Eden
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 11/17/2217:38
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
20 19.8 99 90-110
92636946001 Dup
Result Result RPD Qualifiers
4.4 4.6 4
92636986001 Dup
Units Result Result
NTU 8.3 8.2
RPD Qualifiers
1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 14

�JceAnalyfical"
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QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 738103 Analysis Method: SM 254OD-2015
QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92636946001
METHOD BLANK: 3841247
Associated Lab Samples: 92636946001
Parameter Units
Total Suspended Solids mg/L
LABORATORY CONTROL SAMPLE: 3841248
Parameter Units
Total Suspended Solids mg/L
SAMPLE DUPLICATE: 3841249
Parameter
Total Suspended Solids
SAMPLE DUPLICATE: 3841250
Parameter
Total Suspended Solids
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2.5 11/18/2214:45
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 242 97 90-110
Units
92636671001
Result
Dup
Result
mg/L
36.5
36.2
Units
92636954001
Result
Dup
Result
mg/L
800
1060
RPD Qualifiers
1
RPD Qualifiers
28 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 14

aceAnalytical
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QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 740573 Analysis Method: EPA 1664E
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92636946001
METHOD BLANK: 3852864 Matrix: Water
Associated Lab Samples: 92636946001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 12/02/22 01:20
LABORATORY CONTROL SAMPLE: 3852865
Parameter Units
Oil and Grease mg/L
MATRIX SPIKE SAMPLE: 3852866
Parameter Units
Oil and Grease mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
40 36.5 91 78-114
35760623001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
1 A U 39.2 32.6 81 78-114
SAMPLE DUPLICATE: 3852867
35761797001 Dup
Parameter Units Result Result
Oil and Grease mg/L 1.1U ND
RPD Qualifiers
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 14

aceAnalytical
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QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 738817 Analysis Method: EPA 624.1
QC Batch Method: EPA 624.1 Analysis Description: 624 MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92636946001
METHOD BLANK: 3844910
Associated Lab Samples: 92636946001
Parameter
Benzene
Ethylbenzene
Naphthalene
Toluene
Xylene (Total)
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Matrix: Water
Units
Blank
Result
Reporting
Limit
Analyzed
ug/L
ND
1.0
1112212212:15
ug/L
ND
1.0
11/22/2212:15
ug/L
ND
5.0
11/22/2212:15
ug/L
ND
1.0
11122/2212:15
ug/L
ND
3.0
11/22/2212:15
%
84
70-130
11/22/2212:15
%
104
70-130
11/22/2212:15
%
105
70-130
11122/2212:15
Qualifiers
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
3844911
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Benzene
ug/L
20
18.7
93
70-130
Ethylbenzene
ug/L
20
21.0
105
70-130
Naphthalene
ug/L
20
24.0
120
70-130
Toluene
ug/L
20
18.8
94
70-130
Xylene (Total)
ug/L
60
64.4
107
70-130
1,2-Dichloroethane-d4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
95
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3844912
3844913
MS
MSD
92637069001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Benzene
ug/L
ND
20
20
22.1
21.3
110
107
70-142
3
Ethylbenzene
ug/L
ND
20
20
22.1
22.3
110
111
70-143
1
Naphthalene
ug/L
ND
20
20
21.7
22.0
108
110
62-149
2
Toluene
ug/L
ND
20
20
22.0
21.8
110
109
69-144
1
Xylene (Total)
ug/L
ND
60
60
65.8
66.2
110
110
61-163
1
1,2-Dichloroethane-d4 (S)
%
103
105
70-130
4-Bromofluorobenzene (S)
%
100
101
70-130
Toluene-d8 (S)
%
99
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 14

aceAnalytical e
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Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 739433
QC Batch Method: EPA 420.4 Rev 1.0 1993
Associated Lab Samples: 92636946001
METHOD BLANK: 3847539
Associated Lab Samples: 92636946001
Parameter Units
Phenolics, Total Recoverable mg/L
LABORATORY CONTROL SAMPLE: 3847540
Parameter Units
Phenolics, Total Recoverable mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA420.4 Rev 1.0 1993
Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.020 11/30/22 06:50
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.05 0.052 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3847541 3847542
MS MSD
92636946001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Phenolics, Total Recoverable mg/L ND 0.05 0.05 0.052 0.052 79 81 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3847543 3847544
MS MSD
92636991001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L ND 0.05 0.05 0.048 0.051 92 99 90-110 7
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 14

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QUALIFIERS
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 14

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Lab ID
Sample ID
QC Batch Method
QC Batch
92636946001
FALL OUT 1
SM 2130E-2011
737883
92636946001
FALL OUT 1
SM 254OD-2015
738103
92636946001
FALL OUT 1
EPA 1664B
740573
92636946001
FALL OUT 1
EPA 624.1
738817
92636946001
FALL OUT 1
EPA 420.4 Rev 1.0 1993
739433
Date: 12/02/2022 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
EPA 420.4 Rev 1.0 1993 739782
Page 11 of 14

,rDC� TINe: ENV-FRM44UN1-0064 V87 Tech Spec Sample Condition
i
/ it Upon Receipt
Laboratory recatvlrig sal*go:
Asheville ❑ Eden ❑ Greenwood ❑
Huntwsvl@e ❑ Raleigh Medmfl asW9e❑ Atlanta[] Kernersville❑ 1
_ Clem Naane:
2HnIvIonProject
WO# d 92fi3fi •
946
Courier: iJFeoEx CUPS
❑ Commercial ❑Pace
USPS
❑,�.nt
CarrlerTrm*Mg Number:
92636946
Custody Seat Present? Yes /N-
❑5eais
IataCt?. []Yes
/IYO� / Ii
Dalejutials person Examl
Material: ❑Bubble W teP ❑Bubble Bags �or}e
t
ring Contents:?Packing
❑ Other lliolagicatTTsstte Frozen?
Thermometer: ©IR 6un ID:
TWO WWet
❑yes ❑No QN/A
Cooler Tamp ('C p Correction Factor;
of Lae:
yyam�,,
❑ Blue [INone t
t
Ad/Subtract
('C)
Temp should be above freezing to 6'C
Corrected CoolerTomp{•C): Z-
[lSamplesout oftemp crIteria.Samples onlce,co&4process
USDAResulatedSoil( N/A,watersample)
has begun ( '
Did samples o inate is quarantine zone within the United
❑Yes o
States: CA, NY, or SC (check maps)? DM samples origtnate from a foreign source Ante tFonalty, }i '
Inducting
liawaB and Puerto Ricop []yes No !
Commerrts/Discre n 4 ,
Cwtod Present?
a No N/A
2.
Arrived Within Fold Time?
ya A
2. l
FhW
ld Time Ana is C72 hr. T
(]Yes N/A
3.n"nd
Time Re nested?
Yes [iN(A
4,
tVolume?
No ON A
5.ontaJners
Used?
Ana ❑NIA
6.
Containers Used?
ea No A
ntel�ts�ntacL? _ _
r .ram
'
Dissolved anal gs: Sinn les Field filtered?
QYes []No
Sample labels Match COC7 ❑Yes QNo A
r ! I
9- CdC is n V 11�;;,WA
-Includes Date/Time/ID/Ana! Matrix:
Z(Y!(71t'r
!
Heads ace in VOA Vials >5 6mmJ? O
10. k—
Trip Blank Present?
❑yam ❑
HA
U.Tri
Blank Custody Seals Present?
I
j
COMMENTS/SAMPLE DfSCREPANCy
Field Data A@ Wlred? ❑Yes []No
Lot ID of split Containers:
Teml►to;: Temp must he maintained
l
CLIENT NnT laT-i WRES0LUn0N
!
at er C_Q 3�mcord to
every2Q.minutea.
i
T"T- opened: Temp.
�
!
1'
putan tooter �
Titnos TeaHFs t ,
Person Contacted: patafMle:
f
Project Manager SCURF Reviews Date: !
Project Manager SRF Review:�V
Date:
i
Qualtrax Document 1D: 70677 Page i of 2
1
Page 12 of 141

4 F
—m
�
kCatY
sPau_ 125 mLPlastic Unpreserved IWA) (C} )
"3U-250 rAL PhsHc unpraserved (%/A)
@ v o
6
b1'2t13�0 rM,P�agc unarearsved (WA)
O
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9P1U-111LerPlasm UnWeserved
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SAMPLE
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t HAIN-KUSTODY / Analytical Request Document
Chaff -of Custaly is a LEGAL DOCUMENT. All relevant fields must be completed
a sample via this chain of custody constitutes ackrtomscigment and ac-pmnca of ttw pace Terms and Conditions found athttps:l/infc.paeelabs.com/hubfs
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aceAnalytical
w+w.pacolabs.com
February 02, 2022
Ben Smith
Zenith Energy Terminals
2999 West Oak Street
Selma, NC 27576
RE: Project: WET Testing - NCO027227
Pace Project No.: 92582619
Dear Ben Smith:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on January 13, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network
If you have any questions concerning this report, please feel free to contact me.
Sincerely, O�
Sarah Graham
[e-mail]
[phone]
Project Manager
Enclosures
cc: Andrew Danhof, Zenith Energy
Bridget Fountain, Zenith Terminals
Fes.'
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 8

Document Name:
Document Revised: November 15, 2021
■_
Condition U SOUR
Page 1 of 2
—.-Sample
Document No.:
Issuing Authority:
F-CAR-0-033-Rev.08
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden[ Greenwood ❑ Huntersville ❑ Raleig Mechanicsville[] Atlanta[]Kernersville[I
Sample Condition Client Name:
Upon Receipt Pro
"� -j �5ft:
x d 11 r?Lp% ��a
Courier. ❑F d Ex UPS USPS ❑Client
❑ Commercial ce []Other:
Custody Seat Present? Ely es No Seals Intact? ❑Yeso nM.
Packing Material: ❑bubble Wrap .�8ubble Bags []None ❑ Other
Thermometer: �!;�
El IRGun ID: c� Iiy� wet ❑alas
type of ke:
Conectfon Factor: V
Cooler temp: — Add/Subtract ('C)
Cooler Temp Corrected:.
USDA Regulated Sall ( N/A, water sample)
Did samples originate In a quarantine Zone within the United States: CA, NY, or SC (check maps)?
MYes F lNo
WO#:92582619
111111111111111111111p
I--- —
D.ta/inkUls Person GxamhdaQ Cerrtents9 i -
Biological TissucFrozen?
[]None❑Yes ONO , N/A
Temp should be above freezing to VC
©Samples out of temp criteria. Samples on Ice, cooling process
has baaun
Did samples originate from a foreign source (Internationally,
indudma Hawait and Puerto Rim)? I W s 11No
Comments/of
Chaln of Custody Present?
&Yes
No N/A
1.
Samples Arrived within Hold Time?
Yes
No ❑N/A
2.
Short Hold Time Analysis <72 hr.)?
vas
N/A
3.
Rush Turn Around Time Requested?
liyess
&K QN/A
4.
Sufficient Volume?
lafes
No N/A
5. .
Correct Containers Used?
-Pace Containers Used?
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[IN. CIN/A
No N A
6.
Containers intact?
Yes
No ONJA
7.
Dissolved ana ix Samples Reid Filtered?
Yes
No A
8. -
Sample Labels Match CDC?
-Includes Date/Time/lD/Ana sis Matrbc:
1es
Vv / `
[]No []NIA
4,
Headspacein VOA Vials >S-6mrn ?
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No /A
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Trip Blank Present?
Trip Blank Custody Seals Present?
CIVes
Yas
[]No ',J�riV/A
law /A
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COMMENTS/SAMPLE DISCREPANCY
Lot ID of spllt containers:
CLIENT NOTIFICATION/RFSO(�UTIION(��
OAI\� ItJlll �]�eM- - 1
Person contacted:
Datetrime:
Project Manager SCURF Review: Date:
Project Manager SRF Review. Date:
Field Dah Requked? Dyes ❑No
Page 2 of 8

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OP11.1-1 liter Plastic Unp vserved (N/A)
BMS-12S mL Plastic H2SO4 (pH < 2) (CI-)
8P3W250 mL plastic HNO3 (pH < 2)
BME--125 mL Plastic ZN Acetate & NaOH (>9)
BP45-125 mL Plastic NaOH (pH > 12) (CI-)
WGFU-Wide-mouthed {lass jar Unpreserved
AGW-1 liter Amber Unpreserved (N/A) (CI-)
AGIH-2 liter Amber Hd (pH < 2).
A6311.1-250 mL Amber Unpreserved (N/A) (Cl-)
ZZA615-1
liter Amber H2SO4 (pH < 2)
AG3S-250 mL Amber 825O4 (pH < 2)
AG3A(DG3A)-250 mL Amber NH4Cl (N/A)(C1-)
DG9H-40 mt VOA HC1(N/A)
VG9i-40 ml. VOA Na2S2O3 (N/A)
VO9U-40 mL VOA Unpreserved (N/A)
DGEIP-40 mL VOA 1-131`O4 (N/A)
VOAK 13 vials per kit)-5035 kit (N/A)
V/t'.K (3 vials per ldt)-VPH/Gas kit (N/A)
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��

E,.,T.,.T,.,
P.O. Box 16414, Greenvlle, CC 29606
((64) 077.6442 . rAx [phone]
4 Craftsman Cuuc. Gr:-er, SC 29650
Pimephales promelas 24-Hour Acute Definitive Test
EPA-821-R-02-013 Method 2000
Client: ZENITH ENERGY
Facility: OUTFALL 1
NPDES #: NCO027227
Test Date: 14-Jan-22
Laboratory ID #: T61026
Test Reviewed and Approved By:
4/
Robert W. Kelley, Ph.D.
President
Certification #E87819
Test results presented in this report conform to all requirements of
NELAC, conducted under NELAC Certification Number E87819
Florida Dept. of Health. Included results pertain only to providedales.
ge 1 of 4
f�'A -P. 6,1 ,V...z
Patrick D. Timms
QA/QC Officer
SCDHEC Certification #23104
NCDENR Certification # 022 Page 5 of 8

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50
Date 27-Jan-22
Facility: ZENITH ENERGY OUTFALL 1 NPDES# NCO027227 Pipe # 001 County:
Laboratory Performing Test:
X
Comments
Signature of Operator in Responsible Charge
X 4147,
Signature of Laboratory Supervisor
MAIL ORIGINAL TO Environmental Sciences Branch
Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results
Calculated t=
Critical Value=
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction=
# Young Produced FT..Control
Avg, Reprod.
Adult (L)ive (D)ead
Control
Effluent
Treatment 2
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced I I I I I I I I T I I % 3rd Brood PASS FAIL
Adult (L)ive (D)ead
Complete This for Either Test Test Start Date
Collection(Start) 14-Jan-22
pH 1st sample 1st sample 2nd sample Sample 1 13-Jan-22 Sample 2 NA
Control
Treatment 2 Grab Comp Duration 1st 2nd
Sample 1 X Tox Tox
Sample 2 Dilution Sample Sample
start end start end start end
D.O. lstsa a tstsa le 2nd sa le Hardness(mg/L) 85.4
Control Spec. Cond. (pmhos) 317 19
Treatment 2 Chlorine (mg/L) <0.05
Sample Temp. at receipt (°C) 0.5
LC50/Acute Toxicity Test
(Mortality expressed as %, combining replicates)
0 6.25 12.5 25 50 100 Concentration
0 0 0 0 0 0 B I I Mortality starttend startlend
LC50 = > 100 % Method of Determination 7.8 7.7 Control 7.7 7.1
95% Confidence Limits Moving Average Pfoblt 7.1 7.1 High Conc. 9.4 7.4
NA0% NA % Spearman Karber ROther X pH D.O.
DEM Form AT-1 Page 6 of 8
Page 2 of 4

24 Hour Acute Toxicity Test
Test Method: EPA 821 R-02-012 : Method 2000 Pimeohales Dromelas
lClient:
Sample a
Start Date: 01/14/22 Time: 03:40 PM
Set By: AM
Ended By. AM
End Date: 01/15/22 Time: 04:36 PM
Test Vessel
Test Solution Volume
Incubator
Transfer Volume
Dilution Water
Fathead Minnows
500 mL plastic cup
200 mL
#1
0.5 mL
MHSF
Randomization pattern per SOP lNeonates from common holding vessel
Light: 50 -100 ft-c. 16 hr ligbt 18 hr dark
TEST ORGANISMS
for Ceriodap nia du isComments:
Date Removed: Between: and: FISH HATCHED ON 1/3/22
ime hales promelas Source: ABS -a s old: I 1 BTW 1500-1630 ET
sido sis hakia Source: Days old:
Test Organisms Pre Fed by: AM Time: 1300
MORTALITY DATA
®ME
�Mortality
h
Initial
Final
em
24."67.
D.O.
H
R.
Cond/
Salini
B :
AM
Tern
25"37.
D.O.
H
7.
Cond/
Salini
B
A
�24.61
TX 1
7.9
AM
25.31
6.91
6
ABM
24.8
7.7
7.9
AM
25.3
K41
7.5
1
1 AM
!249
8.1
7.81
1 AM
2531
7.11
T5
A%,l
25J.1
8.41
7.71
JAM
25.3
7.1
F77TE
V%I
9.4
7.1
AM
25.3
7.43
\\I
LC
m L
PPT
°C
tng/L
PPT
Page 3 of 4
Page 7 of 8

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Chain of Custody
PASI Charlotte Laboratory aceAnalytl%al a
lIIIll�llnl�l�llIIIIIV����IIUII�I 0�4k e ��Mb&CM
Workorder: 92582619 Workorder Name: WET Testinca - NCO027227 Results RermeestM Rw 1 /94/9n99
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Sarah Graham
Pace Analytical Charlotte
ETT Environmental P. 0�
t/�
-�.
9800 Kincey Ave. Suite 100
4 Craftsman Court
.
Huntersville, NC 28078
Greer, SC 29650
'
Phone[phone]
864 877-6942
o
Email: sarah.graham@pacelabs,com
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State of Sample Origin: NC�HINIV
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s Thursday January 13, 2022 3:32:04 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1