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HomeMy WebLinkAboutWQ0002857_Monitoring - 03-2023_20230427Monitoring Report Submittal ..................................................... Permit Number#* WQ0002857 Name of Facility:* Piedmont Custom Meats WWTF Month: * March Year: * 2023 Report Information Type* Upload Document* NDMR, NDAR-1, NDAR-2, NDMLR Piedmont Custom —March 2023.pdf 2.23MB PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). Confirmation Email Address: * Jessica. Mize@pacelabs.com Name of Submitter: * Jessica Mize Signature: Date of submittal: 4/27/2023 This will be filled in automatically Initial Review Reviewer: Wanda.Gerald Is the project number correct?* W00002857 Is the monitoring report accepted?* Yes NO Regional Office* Winston-Salem Reviewer: _anonymous Review Date: 5/24/2023 Page 1 of 3 NON -DISCHARGE WASTE WATER MONITORING REPORT PERMIT NUMBER: W00002857 MONTH: March YEAR: 2023 FACILITY NAME: Piedmont Custom Meats WWTF COUNTY: Caswell Flow Monitoring Point: Effluent: U Influent: Parameter Monitoring Point: Effluent: Influent: I I Surface Water (SW)7 SW Code/Name- Was There Effluent Flow for this Month Generated At This Facility: Yes: 0 No: D A * Operator Arrival Time 2400 Clock Operator Time on Site ORC on Site? 50050 00400 50060 00310 00610 00530 31616 70300 00620 00625 00940 D0600 00665 Daily Rate (Flow) into Treatment S,slem pH Residual Chlorine HOD-5 20'C NH-3-N TSS Fecal Coliform (Geo-metric Mew•) US NO.3.N TKN Chloride Total Nilrogm Total Phosphoms HRS YIN GALLONS UNITS mWL MG/L MG/L MG/L /100ML MG/L MG/L MG/L MG/L MG/L MG/L 1 901 2 1000 0.25 Y 901 6.6 <0.01 3 _ 901 4 824 s 824: 6 824 7;. 0830, 0.25 .:,,.v ., .. 824 6.7 <0.01 ;, ...._ 8 824 9 824 101 1 824 In 1009• : , 12 1,009 13 1,009 14 1,009 15 1009 16 0952 0.25 Y 1,009 6.6 <0.01 17 1009 181 1,112 19 1,112 10 1,112 21'- 1112;'; 22 1,112 23 1055 0.25 Y 1112 6.5 <0.01 24 1,112 2s 967 26 967 27.: ,> 967 _',. ..... 28 0830 0.25 Y 967 6.5 <0.01 67.8 30.6 62.5 641 565 16.9 58.5 143 113 2.2 29 967 30 967 31 ::: 967 Average 971 <0.01 67.8 30.6 62.5 641 565 16.9 58.5 143 113 2.2 Daily Maximum 1,112 6.70 <0.01 67.8 30.6 1 62.5 1 641 1 565 16.9 1 58.5 143 113 2.2 Daily Minimum 824 6.50 <0.01 67.8 30.6 62.5 641 565 1 16.9 58.5 143 113 2.2 Monthly Limits ( Avg) 5000 Composite 0 / Grab (G) Operator in Responsible Charge (ORC): Glenn Price Grade: SI Phone: 336-996-2841 Check Box if ORC Has Changed: 71 ORC Certification Number: 987931/20771 Certified Laboratories (1): Pace Analytical Services (2): Person(s) Collecting Samples: Glenn Price Mail ORIGINAL and Two COPIES to: ATTN: Non -Discharge Compliance Unit X J, DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHA Division of Water Quality By this signature, 1 certify that this report is accurate and 1617 Mail Service Center complete to the best of my knowledge. RALEIGH, NC 27699-1617 DENR Form NDAR-1 (5/2003) NON DISCHARGE WASTEWATER MONITORING REPORT FACILITY STATUS: Please answer the following question: Compliant 1. Does all monitoring data and sampling frequencies meet permit requirements? If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance with its permit. Provide in your explanation the date(s) of the non-compliance and describe the corrective action(s) taken. Attach additional sheets if necessary. "1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that a qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." l/`'2` 7-a 3 Baron Neal McDuffte (Signature of Permitee)* Date (Name of Signing Official -Please print or type) Baron Neal McDuffie (Authorized Agent) (Permittee-Please print or type) 9683 Kerfs Chapel Road Gibsonville. NC (Permittee Address) 01002 Arsenic 01022 Boron 00310 BOD5 01027 Cadmium 00916 Calcium 00940 Chloride 50060 Chlorine, Total Residual 01034 Chromium 00340 COD Field Services Director (Pace Analytical Services) PARAMETER CODES 31504 Coliform, Total 00094 Conductivity 01042 Copper 00300 Dissolved Oxygen 31616 Fecal Coliform 01051 Lead 00927 Magnesium 71900 Mercury 00610 NH3 as N 01067 Nickel (Position or Title) 336-582-8247 (Phone Number) 00600 Nitrogen, Total 00630 NO2 & NO3 00620 NO3 00556 Oil & Grease W 09 PAN (Plant Available 00400 pH 32730 Phenols 00665 Phosphorus, Total 00937 Potassium 00545 Settleable Matter 03/31 /21 (Permit Exp. Date) 00929 Sodium 00931 SAR 00745 Sulfide 00515 TDS 00010 Temperature 00625 TKN 00680 TOC 00530 TSS/TSR 00076 Turbidi 01092 Zinc Parameter Code assistance may be obtained by calling the Water Quality Compliance/Enforcement Unit at (919) 733-5083, extension 529. The monthly average for Fecal Coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting facility's permit for reporting data. * If signed by other than the Permittec, delegation of signatory authority must be on rile with the state per 15A NCAC 2B.0506 (b) (2) (D). Page 2 of 3 NON -DISCHARGE APPLICATION REPORT SPRAY IRRIGATION SITE(S) THERE ARE TWO APPLICATION FIELDS PER PAGE. USE ADDIDTIONAL PAGES AS NEEDED PERMIT NUMBER: W00002857 MONTH: March YEAR: 2023 FACILITY NAME: Piedmont Custom Meats WWTF COUNTY: Caswell Formulas: Daily Loading (inches) = [Volume Applied (gallons) x 0.1336 (cubic feet/gallon) x 12 (Incheslfoot)) / (Area Sprayed (acres) x 43.560 (square feet/acre) or = [Volume Applied (gallons) / [Area Sprayed (acres) x 27,152 (gallons/acre-inch). Maximum Hourly Loading (inches) = Daily Loading (inches) / [Time irrigated (minutes) / 60 (minutesihour)] Monthly Loading (inches) =Sum of Daily Loading (inches) 12 Month Floating Total (inches) = Sum of this month's Monthly Loading (inches) and previous 11 month's Monthly Loadings (inches) Average Weekly Loading (inches) = [Monthly Loading (inches/month) / Number of days in the month (days/month)] x 7 (daysMreek) Did Irrigation Occur On This Field: I Did Irrigation Occur On This Field. QMUMLIPtale (inches) 1 • • • ®®®®®®®®®®® I I I 1r I I I I I I I I I Weather Codes: C-clear. PC -partly cloudy, Cl-cloudy, R-rain, tin -snow. SI-sleet Spray Irrigation Operator in Responsible Charge (ORC): Glenn Price Phone: 336-996-2841 ORC Certification Number: 987931/20771 Check Box if ORC Has Changed Mail ORIGINAL and Two COPIES to: ATTN: Non -Discharge Compliance Unit X DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) Division of Water Quality By this signature, I certify that this report is accurate and 1617 Mail Service Center complete to the best of my knowledge. RALEIGH, NC 27699-1617 DENR Form NDAR-1 (5/2003) FACILITY STATUS: Please indicate( by inserting Y(es) or N (o) in the appropriate box) whether the facility has been compliant with the following permit requirements: (Note: If a requirement does not apply to your facility put (NA) in the compliant box.) Compliant (Y,N) 1. The application rate(s) did not exceed the limit(s) specified in the permit. 2. Adequate measures were taken to prevent wastewater runoff from the site(s). 3. A suitable vegetative cover was maintained on the site(s) in accordance with the permit. 4. All buffer zones as specified in the permit were maintained during each application. S. The freeboard in the treatment and/or storage lagoon(s) was not less than the limit(s) specified in the permit. If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance with its permit. Provide in your explanation the date(s) of the non-compliance and describe the corrective action(s) taken. Attach additional sheets if necessary. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that a qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief true, accurate, and complete. I am aware that there are significant penalties for submitting false info tion, including the possibility of fines and imprisonment for knowing violations." 9- 7 3 Baron Neal McDuffie (Signature of Permitee)* Date (Name of Signing Official -Please print or type) Baron Neal McDuffie (Authorized Agent) (Permittee-Please print or type) 9683 Kerr's Chapel Road Gibsonville. NC (Permittee Address) Field Services Director (Pace Analytical Services) (Position or Title) 336-582-8247 (Phone Number) 03/31 /21 (Permit Exp. Date) * If signed by other than the Permittee, delegation of signatory authority must be on file with the state per 15A NCAC 213.0506 (b) (2) (D). DENR Form NDAR-1 (5/2003) Page 3 of 3 NON -DISCHARGE APPLICATION REPORT SPRAY IRRIGATION SITE(S) THERE ARE TWO APPLICATION FIELDS PER PAGE. USE ADDIDTIONAL PAGES AS NEEDED PERMIT NUMBER: WQ0002857 MONTH: March YEAR: 2023 FACILITY NAME: Piedmont Custom Meats WWTF COUNTY: Caswell Formulas: Daily Loading (inches) = [Volume Applied (gallons) x 0.1336 (cubic feet/gallon) x 12 (inches/(oot)] / (Area Sprayed (acres) x 43,560 (square feet/acre) or = [Volume Applied (gallons) / [Area Sprayed (acres) x 27.152 (gallonslacre-inch). Maximum Hourly Loading (inches) = Daily Loading (inches) / [rime irrigated (minutes) / 60 (minutes/hour)] Monthly Loading (inches) =Sum of Daily Loading (inches) 12 Month Floating Total (inches) = Sum of this month's Monthly Loading (inches) and previous 11 month's Monthly Loadings (inches) Average Weekly Loading (inches) = (Monthly Loading (inches/month) / Number of days in the month (days/month )] x 7 (dayshveek) ' © Did Irrigation Occur On This Field Yes� No Did Irrigation Occur Yes NoU ®®®®®®®®®®® 0 II I II I II ,it rawer s. ones: s -clear, ri-partly CIO uny, L i-cloudy, K-ram, Nn-snow, NI -sleet Spray Irrigation Operator in Responsible Charge (ORC): Glenn Price Phone: 336-996-2841 ORC Certification Number: 987931/20771 Check Box if OR�Has Changed: Mail ORIGINAL and Two COPIES to: ATTN: Non -Discharge Compliance Unit DENR Division of Water Quality 1617 Mail Service Center RALEIGII, NC 27699-1617 X (SIGNATURE OF OPERATOR IN RESPONSIBLE CIIARGE) By this signature, I certify that this report is accurate and complete to the best of my knowledge. DENR Form NDAR-1 (5/2003) FACILITY STATUS: Please indicate( by inserting Y(es) or N (o) in the appropriate box) whether the facility has been compliant with the following permit requirements: (Note: If a requirement does not apply to your facility put (NA) in the compliant box.) Compliant (Y,N) 1. The application rate(s) did not exceed the limit(s) specified in the permit. 2. Adequate measures were taken to prevent wastewater runoff from the site(s). 4 3. A suitable vegetative cover was maintained on the site(s) in accordance with the permit. 4. All buffer zones as specified in the permit were maintained during each application. 5. The freeboard in the treatment and/or storage lagoon(s) was not less than the limit(s) specified in the permit. If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance with its permit. Provide in your explanation the date(s) of the non-compliance and describe the corrective action(s) taken. Attach additional sheets if necessary. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that a qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." "— C -2 % 3 Baron Neal McDuffie Signature of Permitee)* Date (Name of Signing Official -Please print or type) Baron Neal McDuffie (Authorized Aeent (Perm ittee-Please print or type) 9683 Kerr's Chapel Road Gibsonville. NC (Permittee Address) Field Services Director (Pace Analytical Services) (Position or Title) 336-582-8247 (Phone Number) 03/31 /21 (Permit Exp. Date) * If signed by other than the Permittee, delegation of signatory authority must be on file with the state per 15A NCAC 213.0506 (b) (2) (D). DENR Form NDAR-1 (5/2003) aceAnalXical'r' www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 April 11, 2023 Larry Moore Piedmont Custom Meats 430 NC Highway 49 South Asheboro, NC 27205 RE: Project: Piedmont Custom Meats Pace Project No.: 92659063 Dear Larry Moore: Enclosed are the analytical results for sample(s) received by the laboratory on March 28, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacelabs.com 704-977-0981 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 Project: Piedmont Custom Meats Pace Project No.: 92659063 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VrginiaNELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 VrginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, LLC. Page 2 of 23 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 SAMPLE ANALYTE COUNT Project: Piedmont Custom Meats Pace Project No.: 92659063 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92659063001 MW-1 SM 2540C-2015 LRB 1 PASI-E EPA 353.2 Rev 2.0 1993 AED 1 PASI-E SM 922213-2015 MWF 1 PASI-E EPA 120.1-1982 YEG 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92659063002 MW-4 SM 2540C-2015 LRB 1 PASI-E EPA 353.2 Rev 2.0 1993 AED 1 PASI-E SM 922213-2015 MWF 1 PASI-E EPA 120.1-1982 YEG 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92659063003 MW-5 SM 254OC-2015 LRB 1 PASI-E EPA 353.2 Rev 2.0 1993 AED 1 PASI-E SM 9222D-2015 MWF 1 PASI-E EPA 120.1-1982 YEG 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92659063004 Effluent SM 2540C-2015 LRB 1 PASI-E SM 254OD-2015 VLG 1 PASI-E EPA 353.2 Rev 2.0 1993 SRS 2 PASI-E SM 521OB-2016 SRS 1 PASI-E SM 9222D-2015 MWF 1 PASI-E TKN+NO3+NO2 Calculation MDW 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.01993 Zip 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 23 aceAnalytical QD www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Piedmont Custom Meats Pace Project No.: 92659063 Sample: MW-1 Lab ID: 92659063001 Collected: 03/28/23 09:00 Received: 03/28/23 10:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Total Dissolved Solids 353.2 NO2/NO3 unpres EDN Nitrogen, Nitrate MBIO 9222D Fecal Coliform EDN Fecal Coliforms 120.1 Specific Conductance Specific Conductance 300.0 IC Anions 28 Days Chloride Sulfate 350.1 Ammonia Nitrogen, Ammonia 5310E TOC Total Organic Carbon Date: 04/11/2023 10:25 AM Analytical Method: SM 2540C-2015 Pace Analytical Services - Eden 266 mg/L 25.0 1 03/31/2310:52 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Eden 18.5 mg1L 0.20 5 03/29/2310:21 14797-55-8 Analytical Method: SM 922213-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Eden ND CFU/100 mL 1.0 1 03/28/23 16:33 03129/23 15:20 D6 Analytical Method: EPA 120.1-1982 Pace Analytical Services -Asheville 451 umhos/cm 10.0 1 04/05/2310:15 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville 51.7 mg/L 1.0 1 03/31/23 00:53 16887-00-6 7.8 mg1L 1.0 1 03/31/23 00:53 14808-79-8 Analytical Method: EPA 350.1 Rev 2,0 1993 Pace Analytical Services -Asheville NO mg/L 0.10 1 04/05/2312:20 7664.41-7 Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville ND mg1L 1.0 1 04/03/23 23:16 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, L.I.C. Page 4 of 23 aceAnalytical www.pacclabs.com I ANALYTICAL RESULTS Project: Piedmont Custom Meats Pace Project No.: 92659063 Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 Sample: MW-4 Lab ID: 92659063002 Collected: 03/28/23 09:33 Received: 03/28/23 10:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2640C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services - Eden Total Dissolved Solids 525 mg/L 125 1 03/31123 10:53 353.2 NO2JN03 unpres EDN Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Nitrate 1.9 mg/L 0.040 1 03/29/23 10:13 14797-55-8 MBIO 922gD Fecal Collform EDN Analytical Method: SM 922213-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Eden Fecal Coliforms ND CFU/100 mL 1.0 1 03/28/23 16:33 03/29/23 15:20 D6 120.1 Specific Conductance Analytical Method: EPA 120.1-1982 Pace Analytical Services - Asheville Specific Conductance 1120 umhos/cm 10.0 1 04/05/23 10:17 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 270 mg/L 6.0 6 03/31/23 08:47 16887-00-6 Sulfate 7A mg/L 1.0 1 03/31/23 01:09 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 04/05/23 12:22 7664-41-7 5310E TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 04/03/23 23:34 7440-44-0 Date: 04/11/2023 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, I.I.C. Page 5 of 23 aceAnalytical www.pacelabs.com I ANALYTICAL RESULTS Project: Piedmont Custom Meats Pace Project No.: 92659063 Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 Sample: MW-5 Lab ID: 92659063003 Collected: 03/28/23 09:50 Received: 03/28/23 10:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services - Eden Total Dissolved Sollds 173 mg/L 25.0 1 03/31/23 10:52 353.2 NO2/NO3 unpres EDN Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Nitrate 0.18 mg1L 0.040 1 03/29/23 10:15 14797-55-8 MBIO 9222D Fecal Coliform EDN Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Eden Fecal Coliforms ND CFU/100 mL 1.0 1 03/28/23 16:33 03/29/23 15:20 D6 120.1 Specific Conductance Analytical Method: EPA 120.1-1982 Pace Analytical Services -Asheville Specific Conductance 254 umhos/cm 10.0 1 04/05/23 10:21 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Chloride 55.8 mg1L 1.0 1 03/31/23 01:24 16887-00-6 Sulfate ND mg1L 1.0 1 03/31/23 01:24 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 04/05/23 12:23 7664-41-7 5310B TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 04/03/23 23:53 7440-44-0 Date: 04/11/2023 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 23 aceAnalytical www.pacalabs.cam Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 ANALYTICAL RESULTS Project: Piedmont Custom Meats Pace Project No.: 92659063 Sample: Effluent Lab ID: 92659063004 Collected: 03/28/23 09:10 Received: 03/28/23 10:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services - Eden Total Dissolved Solids 565 mg1L 125 1 03/31/23 10:53 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Eden Total Suspended Solids ND mg/L 62.5 1 04/03/23 12:49 353.2 NO2/NO3 unpres EDN Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, NO2 plus NO3 54.4 mglL 1.0 25 03/30/23 09:03 Nitrogen, Nitrate 16.9 mg/L 1.0 25 03/30/23 09:03 14797-55-8 5210E BOD, 5 day EDN Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Eden BOD, 5 day 67.8 mg/L 2.0 1 03/29/23 11:30 04/03/23 10:35 MBIO 9222D Fecal Coliform EDN Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Eden Fecal Collforms 641 CFU/100 mL 1.0 1 03/28/23 16:33 03/29/23 15:20 D6 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services -Asheville Total Nitrogen 113 mg/L 0.040 1 04/05/23 19:08 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville Chloride 143 mg/L 15.0 15 03/31/23 09:02 16887-00-6 M1 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia 30.6 mg/L 0.50 5 04/05/23 12:24 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Kjeldahl, Total 58.5 mg/L 2.5 5 04/04/23 15:41 04/05/23 05:37 7727-37-9 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 2.2 mg/L 0.050 1 04105/2311:27 04/0512315:04 7723-14-0 Date: 04/11/2023 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, LLC. Page 7 of 23 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 QC Batch: 765155 Analysis Method: SM 254OC-2015 QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 METHOD BLANK: 3972996 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 03/31/23 10:52 LABORATORY CONTROL SAMPLE: 3972997 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 256 102 90-110 SAMPLE DUPLICATE: 3972998 92659063003 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 173 176 2 SAMPLE DUPLICATE: 3972999 92659063001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 266 269 1 Results presented on this page are In the units Indicated by the "Units" colurnn except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/11/202310:25 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 23 aceAnalytical www.pacolabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 QC Batch: 765477 Analysis Method: SM 254OD-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92659063004 METHOD BLANK: 3974496 Matrix: Water Associated Lab Samples: 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 04/03/23 12:44 LABORATORY CONTROL SAMPLE: 3974497 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 244 98 90-110 SAMPLE DUPLICATE: 3974498 92659679001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 76.5 81.0 6 SAMPLE DUPLICATE: 3974499 92659685004 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 44.0 41.7 5 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/11/2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 23 aCato. AnalXical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 QC Batch: 764489 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92659063001, 92659063002, 92659063003 METHOD BLANK: 3969826 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 03129/23 10:08 LABORATORY CONTROL SAMPLE: 3969827 Spike LCS LCS % Rec Parameter Units Conc. Result %, Rec Limits Qualifiers Nitrogen, Nitrate mg1L 1.5 1.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3969828 3969829 MS MSD 92659063001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 18.5 1.5 1.5 19.9 20.1 97 105 90-110 1 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of tho result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 04/11 /2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 23 aceAnalytical www.pacclabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 QC Batch: 764778 Analysis Method: EPA 353.2 Rev 2.01993 QC Batch Method: EPA 353.2 Rev 2.01993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92659063004 METHOD BLANK: 3971175 Matrix: Water Associated Lab Samples: 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 03/30/23 09:17 Nitrogen, NO2 plus NO3 mg/L ND 0.040 03/30/23 09:17 LABORATORY CONTROL SAMPLE: 3971176 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.4 91 90-110 Nitrogen, NO2 plus NO3 mg/L 2.5 2.4 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971177 3971178 MS MSD 92659525005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.66 1.5 1.5 2.1 2.1 96 94 90-110 2 Nitrogen, NO2 plus NO3 mg/L 0.66 2.5 2.5 3.2 3.1 100 97 90-110 2 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 04/11/2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 23 aceAnalytical www.pacolabs.com I QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QC Batch: 764518 Analysis Method: SM 521OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210B BOD, 5 day Final EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92659063004 METHOD BLANK: 3969880 Matrix: Water Associated Lab Samples: 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L ND 2.0 04/03/23 09:51 LABORATORY CONTROL SAMPLE: 3969881 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day mg/L 198 188 95 84.6-115 SAMPLE DUPLICATE: 3969883 92659190002 Dup Parameter Units Result Result RPD Qualifiers BOD, 5 day mg/L 141 125 12 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 04/1112023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 23 aceAnalytical www.pacelabs.cam Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 QC Batch: 764425 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform( MF)-EDN Laboratory: Paoe Analytical Services - Eden Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 METHOD BLANK: 3969665 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 03/29/23 15:20 METHOD BLANK: 3971599 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 03/29/23 15:20 METHOD BLANK: 3971600 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 03/29/23 15:20 SAMPLE DUPLICATE: 3971851 92659261004 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms CFU/100 mL 560 740 28 D6 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/11/2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 23 aceAnalytical www.pacclabs.com I QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QC Batch: 766037 Analysis Method: EPA 120.1-1982 QC Batch Method: EPA 120.1-1982 Analysis Description: 120.1 Specific Conductance Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92659063001, 92659063002, 92659063003 METHOD BLANK: 3977292 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Specific Conductance umhos/cm ND 10.0 04/05/23 10:04 LABORATORY CONTROL SAMPLE: 3977293 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Specific Conductance umhos/cm 1410 1420 101 90-110 SAMPLE DUPLICATE: 3977294 92659063002 Dup Parameter Units Result Result RPD Qualifiers Specific Conductance umhos/cm 1120 1120 0 SAMPLE DUPLICATE: 3977295 92659525001 Dup Parameter Units Result Result RPD Qualifiers Specific Conductance umhos/cm 45.1 46.1 0 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/11/2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 23 aCue Ana lyNo/ www.pacelshs.cotn QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QC Batch: 764799 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 METHOD BLANK: 3971223 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/30/2314:22 Sulfate mg/L ND 1.0 03/30/2314:22 LABORATORY CONTROL SAMPLE: 3971224 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 50 49.8 100 90-110 Sulfate mg/L 50 49.3 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971225 3971226 MS MSD 92659179002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Chloride mg/L 909 50 50 959 960 101 102 90-110 0 Sulfate mg/L 246 50 50 286 288 80 85 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971227 3971228 MS MSD 92659063004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 143 50 50 185 189 84 91 90-110 2 M1 Sulfate mg/L 41.9 50 50 94.7 95.8 106 108 90-110 1 Results presented on this page are In the units Indicated by the 'Units" column except where an alternate unit Is presented to the rlght of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 04/11/2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 23 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 QC Batch: 766027 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 METHOD BLANK: 3977245 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003, 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 04/05/23 11:43 LABORATORY CONTROL SAMPLE: 3977246 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977247 3977248 MS MSD 92660202001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.2 5.2 102 102 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977249 3977250 MS MSD 92660204001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.1 5.1 99 99 90-110 0 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/11 /2023 10:25 AM without the written consent of Pace Analytical Services, I.I.C. Page 16 of 23 aconAnalytical www.pacclabs.com I QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QC Batch: 765768 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92659063004 METHOD BLANK: 3975903 Matrix: Water Associated Lab Samples: 92659063004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg/L ND 0.50 04/05/23 03:49 LABORATORY CONTROL SAMPLE: 3975904 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 9.5 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975905 3975906 MS MSD 92658992002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 71.0 10 10 87.5 84.2 165 132 90-110 4 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975907 3975908 MS MSD 92658992003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 51.2 10 10 59.6 56.0 83 48 90-110 6 M1 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/11/2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 23 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 QC Batch: 765869 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92659063004 METHOD BLANK: 3976483 Associated Lab Samples: 92659063004 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 04105/2315:01 LABORATORY CONTROL SAMPLE: 3976484 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3976485 3976486 MS MSD 92659063004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 2.2 2.5 2.5 4.8 4.8 105 106 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3976487 3976488 MS MSD 92659109001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 3.0 2.5 2.5 5.7 5.7 109 108 90-110 0 Results presented on this page are In the units Indicated by the "Units' column except where an attemate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/11 /2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 23 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custom Meats Pace Project No.: 92659063 QC Batch: 765462 Analysis Method: SM 531OB-2014 QC Batch Method: SM 531OB-2014 Analysis Description: 5310B TOC Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92659063001, 92659063002, 92659063003 METHOD BLANK: 3974423 Matrix: Water Associated Lab Samples: 92659063001, 92659063002, 92659063003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 04/03/23 14:27 LABORATORY CONTROL SAMPLE: 3974425 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.1 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974426 3974427 MS MSD 92659672001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 1.0 25 25 24.5 24.3 94 93 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3974428 3974429 MS MSD 92659545005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 24.9 24.5 97 95 90-110 2 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resulL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 04/11/2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 23 aceAna1j&a1 www.pacalabs.cam Pace Analytical Services, LLC 1377 South Park Drive Kernersville, NC 27284 (704)977-0981 QUALIFIERS Project: Piedmont Custom Meats Pace Project No.: 92659063 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporfing Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte In a specific matrix. S - Surrogate 1,2-Diphenythydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/11/2023 10:25 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 23 aceAnalytical www.paceiiibs.com Pace Analytical Services, LLC 1377 South Park Drive Kemersville, NC 27284 (704)977-0981 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Piedmont Custom Meats Pace Project No.: 92659063 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92659063001 MW-1 SM 254OC-2015 765155 92659063002 MW-4 SM 254OC-2015 765155 92659063003 MW-5 SM 254OC-2015 765155 92659063004 Effluent SM 254OC-2015 765155 92659063004 Effluent SM 254OD-2015 765477 92669063001 MW-1 EPA 353.2 Rev 2.0 1993 764489 92659063002 MW-4 EPA 353.2 Rev 2.0 1993 764489 92659063003 MW-5 EPA 353.2 Rev 2.0 1993 764489 92659063004 Effluent EPA 353.2 Rev 2.0 1993 764778 92659063004 Effluent SM 521OB-2016 764518 SM 521OB-2016 764786 92659063001 MW-1 SM 9222D-2015 764425 SM 9222D-2015 764881 92659063002 MW-4 SM 9222D-2015 764425 SM 9222D-2015 764881 92659063003 MW-5 SM 9222D-2015 764425 SM 922213-2015 764881 92659063004 Effluent SM 9222D-2015 764425 SM 922213-2015 764881 92659063001 MW-1 EPA 120.1-1982 766037 92659063002 MW-4 EPA 120.1-1982 766037 92659063003 MW-5 EPA 120.1-1982 766037 92659063004 Effluent TKN+NO3+NO2 766265 Calculation 92659063001 MW-1 EPA 300.0 Rev 2.1 1993 764799 92659063002 MW-4 EPA 300.0 Rev 2.1 1993 764799 92659063003 MW-5 EPA 300.0 Rev 2.1 1993 764799 92659063004 Effluent EPA 300.0 Rev 2.1 1993 764799 92659063001 MW-1 EPA 350.1 Rev 2.0 1993 766027 92659063002 MW-4 EPA 350.1 Rev 2.0 1993 766027 92659063003 111 EPA 350.1 Rev 2.0 1993 766027 92659063004 Effluent EPA 350.1 Rev 2.0 1993 766027 92659063004 Effluent EPA 351.2 Rev 2.0 1993 765768 EPA 351.2 Rev 2.0 1993 765989 92659063004 Effluent EPA 365.1 Rev 2.0 1993 765869 EPA 365.1 Rev 2.0 1993 766150 92659063001 111 SM 531OB-2014 765462 92659063002 11 SM 531OB-2014 765462 92659063003 MW-5 SM 531OB-2014 765462 Date: 04/11/2023 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, LLC. 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DROi8,31S (watery DOC, tUig "Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Project i# l d7 a f 7 4 a C •71 w i J r_ y v C. C. N 7 O y ry 9' O 2 .1: !O u ¢ p 2 o U i Cr a b =1 ti ] T `� a O 7 p T n v+� n, �� ti• 1" T _ i — i �� _ 1 ri c7. n { �S n .0 l7 0. y Z y Q ry T ._ L w .` m Z �J I N v 4 m N m a m OV1 r a m '., _, a m .tEi --f N o a m O N Z rr, n m ~ N v a m any N m -r 0. m } i 'S 'Q '.' •. t9 C .n'_.. r V Q .._.�.. E ry N 4" 4 ....— A N ^, V Q ul ti7 +L ._.._.. C N t9 O "i ? E O7 tb Q_..?_. 4 U E .� Q t7 Q O F, b l7 .__.} '� C� is > in O _.__.__. •r t:� 0 vt O ....__._....._._....... Q v y } 6; n E M ,n V ZX E d v� �......... . - n ; �_ /• S C RJ 1_ .f �,:,� tJ Q G en Q w ? F7 C rJ t7 O i 10 �i \1� pH Adjustment log for Preserved Samples Sample 10 Type of Preservative , pH upon receipt Gate preservation adjusted Time preservation �— Amount of Preservative -adjustedadded .....__....._......�._.....__......._......_..._.. --._........_ --- ,...... tot 4 I j wale: Yvnenl^vtr MUM n a uracrepanty JO UM& NUFM taros nJ Ulnipi ante+ SJlnpf�s, a copy of this lo, m wd he See to th±e Ncirth Caruhna 4EHr4x Certltif.at,un 011,ce (i.e Out of hold, incorrect preservative, out of temp, incorrect cnntainer,y Qualtrax Docuinent U. 70677 Page 2 of 2 Page 23 of 23