NC0022187_Permit Issuance_20060418

Michael F. Easley
Governor
D. E. Benton
Chief Deputy Secretary
North Carolina Department of Environment and Natural Resources
Alan W. Klimek, P.E., Director
Division of Water Quality
April 18, 2006
Mr. Ken Watson, Complex Manager
Motiva Enterprises, LLC
410 Tom Sadler Road
Charlotte, North Carolina 28214
Subject: Issuance of NPDES Permit NCO022187
Tom Sadler Road, Paw Creek
Charlotte — North Terminal
Mecklenburg County .
Dear Mr. Watson:
The Division of Water Quality (the Division) hereby issues the attached NPDES permit for the
subject facility. This permit is issued pursuant to the requirements of North Carolina General
Statute 143-215:1 and the Memorandum of Agreement between North Carolina and the U.S.
Environmental Protection Agency dated May 9, 1994, or as subsequently amended.
RENEWAL SUMMARY
The Division's renewal evaluation includes a reasonable potential analysis (RPA), in
accordance with permitting guidance provided by the EPA. The Division has made the
following decisions based on current information and your discharge Monitoring Reports
(DMRs) submitted over the last permit cycle:
• Deleted lead from permit (no RP).
• Deleted 1;2 DCA from permit (no RP).
• Turbidity — (RP = yes); added permit limit.
• Benzene — (RP = yes) retained permit limit and monthly monitoring.
• Iron — (RP = yes) continue monitoring.
• Manganese — added permit limit; continue monitoring.
• Naphthalene — added monthly monitoring per Bulk Storage SOP 2005 (not included in
previous permit; diesel stored onsite).
NCDENR
N. C. Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 919-733-5083 Customer Service
1-800-623-7748

Issuance of NPDES Permit NCO022187
Motiva Enterprises, LLC
Charlotte North Terminal
Page 2of 2
If any parts, monitoring frequencies, or sampling requirements contained in this permit are
unacceptable to you, you have the right to an adjudicatory hearing, upon written request, within
thirty (30) days following receipt of this letter. You must submit this request in the form of a
written petition, conforming to Chapter 150B of the North Carolina General Statutes, and file it
with the office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North Carolina
27699-6714. Unless such a demand is made, this permit shall be final and binding.
Please notice that this permit is not transferable except after notifying the Division of Water
Quality. The Division of Water Quality may modify, or revoke and reissue this permit. This
permit does not affect your legal requirements to obtain other permits required by the Division of
Water Quality, the Division of Land Resources, the Coastal Area Management Act, or other
federal or local governments.
If you have questions concerning this permit, please call Joe Corporon at [phone],
extension 597 or email joe.corporon ncmail.net.
Sincerely,
6r : Alan W. Klimek, P.E.
Attached: NPDES Permit, NC0022187
cc: Central Files
Aquatic Toxicology Unit
Mooresville Regional Office, Surface Water Protection
HLS Frog

M
Permit NC0022187
STATE OF NORTH CAROLINA
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WATER QUALITY
PERMIT
TO DISCHARGE WASTEWATER UNDER THE
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
DES
In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards
and regulations promulgated and adopted by the North Carolina Environmental Management
Commission, and the Federal Water Pollution Control Act, as amended,
Motiva Enterprises LLC
is hereby authorized to discharge wastewater from outfalls located at the
Charlotte -North Terminal
410 Tom Sadler Road
Paw Creek near Charlotte
Mecklenburg County
to receiving waters designated as an unnamed tributary to Gum Branch in the Catawba River Basin in
accordance with effluent limitations, monitoring requirements, and other conditions set'fortffi in Parts I,
II, III and IV hereof
This permit shall become effective dune 1, 2006.
This permit and authorization to discharge shall expire at midnight on June 30, 2010.
Signed this day April 18, 2006.
,�� •. Alan W. Klimek, P.E., Director
Division of Water Quality
By Authority of the Environmental Management Commission

Permit NCO022187
SUPPLEMENT TO PERMIT COVER SHEET
All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby
revoked, and as of this issuance, any previously issued permit bearing this number is no longer effective.
Therefore, the exclusive authority to operate and discharge from this facility arises under the permit
conditions, requirements, terms, and provisions described herein.
Motiva Enterprises, LLC
is hereby authorized:
1. to continue to operate the existing Water Pollution Control System consisting of
• an oil/water separator and waste holding tank (servicing the truck -loading rack)
• a groundwater remediation system (intermittent)
• surface tank secondary -containment bermed area, and
• a stormwater detention pond (with hand -operated discharge valve)
located at the Charlotte -North Terminal, 410 Tom Sadler Road, Paw Creek, Mecklenburg County, and
2. to discharge from said treatment facility through Outfall 001 at a specified location (see attached
map) into an unnamed tributary to Gum Branch, a WS-IV waterbody located within the Catawba
River Basin.

UT of Gum
Branch
�S 1y.. 9 � `•J unn.iu
I
.T------------
it
Outfall 001
;'
(flows north)
__ } • i� • ~L ."+ U �1 !,yl is 1S kF -4. 1- .may.
1 fit` � �.. ` , ",.y\ � a• A � .
Motiva Enterprises, LLC Tom§
,• ,F� { °�• �*- Approximate Property
Yam- � . ��_ "' .,1:,,�,,,,�.-•).�, Boundarj
NC Hwy 27
Motiva Enterprises, LLC
Charlotte -North Terminal
State Grid/Ouad: F15SW / Mt Island Lake, NC Permitted Flow: not limited
Latitude: 35° 16' 59" N Longitude: 800 56' 10" W
Receiving Stream: UT to Gum Branch Sub -Basin: 03-08-34
Drainage Basin: Catawba River Basin Stream Class: WS-IV
Facility
Location
not to scale
North 7ES Permit No. NCO022187
Mecklenburg Count

Permit NCO022187
A. (L) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS
During the period beginning on the effective date of the permit and lasting until expiration, the Permittee
is authorized to discharge stormwater and treated groundwater from outfall 001. Such discharges
shall be limited and monitored by the Permittee as specified below:
EFFLUENT _.. ,
'CHARACTERISTICS r "1Vlonthly<
"'
C LIlVIITS
' ' 1VIONITORING REQUIREMENTS
Avera e >
=Daily :
^:Maaumum
1dleasurement`
_; Ere uenc"
Sample
T e
Sample Locat11
ion
Flowl
Episodic
1
Effluent
Total Suspended Solids
30.0 mg/L
Monthly
Grab
Effluent
Oil and Grease2
Monthly
Grab
Effluent
Turbidity3
50 NTU
Monthly
Grab
Effluent
Phenol
Monthly
Grab
Effluent
Benzene
1.19 g/L
Monthly
Grab
Effluent
Toluene
Monthly
Grab
Effluent
Ethyl Benzene
Monthly
Grab
Effluent
Xylene
Monthly
Grab
Effluent
Naphthalene
Monthly
Grab
Effluent
Methyl Tertiary -Butyl Ether
TBE)
Monthly
Grab
Effluent
EPA Method 625
Semi-annually
Grab
Effluent
Iron
Monthly
Grab
Effluent
Manganese
200 g/L
Monthly
Grab
Effluent
Acute Toxicity4
Annually
Grab
Effluent
Footnotes:
1. Flow — During periods of no flow, the Permittee shall submit a monthly Discharge Monitoring Report
(DMR) indicating "No discharge." Flow must be monitored with each discharge and may be
monitored in one of four ways:
a) measure flow continuously;
b) calculate flow based on total rainfall per area draining to the outfall; exclude built -upon
area (best method for facilities with large runoff -collection ponds);
c) estimate flow at 20-minute intervals during the entire discharge event; or
d) report flow based on discharge pump logs.
2. Oil and Grease — Where possible, the grab sample for oil and grease should be skimmed from
the surface of a quiescent (calm water) zone.
3. Turbidity — Effluent shall not cause receiving stream turbidity to exceed 50 NTU. If receiving stream
background turbidity exceeds 50 NTU, effluent shall not cause this background value to increase.
4. Acute Toxicity (Fathead Minnow, 24-hour), Annual [see Special Condition A.(2.)].
There shall be no discharge of floating solids or foam visible in other than trace amounts.
There shall be no direct discharge of tank solids, tank bottom water, or the rag layer.
Following hydrostatic tank or pipe testing, the Permittee shall not discharge wastes containing
benzene concentrations greater than 1.19 µg/L, or toluene concentrations greater than 11 µg/l.

Permit NC0022187-
EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS
SPECIAL CONDITIONS.
A. (2.) ACUTE TOXICITY MONITORING (ANNUAL)
The Permittee shall conduct annual toxicity tests using protocols defined as definitive in EPA Document
EPA/600/4-90/027 entitled "Methods for Measuring the Acute Toxicity of Effluents to Freshwater and
Marine Organisms." The monitoring shall be performed as a Fathead Minnow (Pimephales promelas)
24-hour static test. Effluent samples for self -monitoring purposes must be obtained below all waste
treatment. The permittee will conduct one test annually, with the annual period beginning in January of
the calendar year of the effective date of the permit.' The annual test requirement must be performed and
reported by June 30. If no discharge occurs by June 30, notification will be made to the Division by this
date. Toxicity testing will be performed on the next discharge event for the annual test requirement.
The parameter code for this test is TAE6C. All toxicity testing results required as part of this permit
condition will be entered on the .Effluent Discharge Form (MR-1) for the month in which it was
performed, using the appropriate parameter code. Additionally, DWQ Form AT-1 (original) is to be sent.
to the following address:
Attention: North Carolina Division of Water Quality
Environmental Sciences Branch
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Branch no later
than 30 days after the end of the reporting period for which the report is made.
Test data shall be complete and accurate and include all supporting chemical/physical measurements
performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine
of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of
the waste stream.
Should any test data from either these monitoring requirements or tests performed by the North Carolina
Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re-
opened and modified to include alternate monitoring requirements or limits.
NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control
organism survival and appropriate environmental controls, shall constitute an invalid test and will
require immediate follow-up testing to be completed no later than the last day of the month following the
month of the initial monitoring.

Permit NCO022187
A. (3.) MTBE MONITORING - SPECIAL CONDITION
For the protection of public health, oil terminals that discharge to waters classified as water supply
(WS waters) will adhere to the following action plan: As stated in Part A. (1), the Permittee shall
monitor MTBE monthly for the duration of this permit. If, after one year of monthly monitoring,
MTBE is not detected (or after twelve data points have been collected over a six-month period), the
Permittee may request the Division to reduce the MTBE monitoring frequency. Such a reduction
shall be considered a minor permit modification.

I
FILE CONTENTS:
Left side:
❑ BIMS Tracking Slip
NPDES PERMIT
DRAFT &FINAL
CHECK LIST
Facility �� 6 �^� �'� J r —
Permit No.
NPDES Permit Writer:
Right side: L�
❑ Streamline Package Sheet (to region, only if streamli d)
E�Draft Permit Cover Letter. (add new policy text; s rize major anges to pe t)
l�� raft Permit (order: cover, supple ent, map, effl nt sheets, speci 1 conditions)
Facility Map (E-Map: include f ility Outfalls; and D sample loc tions)
l act Sheet. (documents per it writer's iss s and re -issue logic)
Er Permit Writer's Notes (if not in Fac Sheet -- chro ogy, strategy, DMR Review, RPA, etc.)
C9��Staff Report from Region (as approp 'ate -- not need if streamlined)
��Id Permit (Te ' , E uent Sheets and Special Conditions)
C-1/,Permit Application. (Ne ermit or Renewal; any additional permittee correspondence)
LY Acknowledgement Letter (NPDES Unit written response to Renewal Application)
❑ 1Permittee Responses (to acknowledgement letter, if any)
I9' Waste Load Allocation (reference date; notes if recalculated for current action) Of�
Note: Italics indicate special conditions not always required or applicable.
���
E�Su miffed to A ���df Peer Review: Date ��idmin cutoff date
®' Peer Review completed by Date
O' Updated Public Notice System [date] rC Updated BIMS Events: [date] (- Fez
15 Submitted for Public Notice on Newspaper Notice Received
ZDraft Permi [Mailed E-Mailed] to (Regional Staff) by
Regional Office Review /Approval completed by 4114� Zk�t>"(,7�Received on [Date] I 1164PRUJo
❑ Additional Review by [TOX/DEH]
Actual Notice date(s)
initiated by Date
❑ Additional Review/Approval completed by
❑ EPA Review Draft sent to initiated by
❑ EPA Review /Approval [mail / E-mail] completed by
Date
Date
Date_
Date Received
FINAL to Mike / Susan / Tom / it r signature on 1167M4(,0Letter Dated It A"'4(p
❑ Additional Review [other]
8 Final Files transferred to Server (Permits Folder) A {o BIMS Final Updates: Events
_Limits V
19 1
Version 060ct05

DENR/DWQ
FACT SHEET FOR NPDES PERMIT DEVELOPMENT
NPDES No. NCO022187
Facility Information
Applicant/Facility Name:
NCO022187 — Motiva Enterprises, LLC
Applicant Address:
Mr. Ken Watson, Complex Manager
Facility Address:
410 Tom Sadler Road; Charlotte, NC 28214
Permitted Flow
Not limited
Type of Waste:
Stormwater, truck -loading rack wastewater, groundwater remediation
effluent
Facility/Permit Status:
Active / Renewal
County:
Mecklenburg
Miscellaneous
Receiving Stream: UT to Gum Branch Regional Office: Mooresville
Stream Classification: WS-IV State Grid / USGS Quad: F 15 SW/Mountain
Island Lake
303(d) Listed? No Permit Writer: Joe Corporon
Subbasin: 03-08-34 Date: l OFebO6
Drainage Area (miz): 0.02
Summer 7Q10 (cfs) 0
Winter 7Q10 (cfs): 0
30Q2 (cfs) 0
Average Flow (cfs): 0.02
IWC (%): 100%
Lat. 35° 16' S9" N Long. 80° 56' 10" W
BACKGROUND
Waste Load Allocation (WLA) and Bulk -Storage SOP. A Waste Load Allocation was last conducted in
April 1994, when the receiving stream, Gum Branch, was classified C waters. The Division subsequently re-
classified Gum Branch as WS-IV waters prior to last renewal. This WLA recommended monitoring for
benzene, toluene, ethylbenzene, lead, and MTBE with permit limits for TSS and oil and grease. The Division
established new effluent limits and monitoring requirements for the previous permit according to
Requirements for Discharges from Oil and Petroleum Storage Facilities (SOP 2001, version 30Jul0l).
PERMITTING STRATEGY
New SOP for Oil Terminals: The Division establish renewal criteria for this permit according to the
NPDES Permitting Requirements for Petroleum Bulk -Storage 2005 Permitting Strategy, version September 9,
2005 (2005 SOP). This document established 12 criteria for renewal including reasonable potential analyses
(see Renewal Summary). Database for this RPA is attached to this document.
Reasonable Potential Analysis (RPA): The Division conducted a reasonable potential analysis according to
EPA guidelines in order to establish potential for a given parameter to exceed its water quality stream
standard. The Division established a list of parameters of concern (POCs) based on the previous permit. These
parameters include benzene, toluene, turbidity, iron, lead, manganese, and 1,2 Dichloroethane (DCA). In
addition, the Division calculated phenol limits appropriate for a discharge to water supply (WS-IV) waters
considering a total of eight discharges to this water shed (see 2005 SOP, item 11).
Fact Sheet
NPDES NCO022187
Renewal
Page I

Phenol Calculation. The phenol limits calculation considers phenol loading for all terminals discharging to
WS waters in the Paw Creek area. For this permit:
Outfall 001 Highest flow recorded in 2003 =
Therefore,
Outfall001 = 0.48lbs./day x 1
8.34 0.688 MGD
0.084 mg/L = 80 µg/L
Based on a loading of 80 µg/L, this facility's phenol data do not indicate reasonable potential to exceed the
water -quality standard.
RENEWAL SUMMARY
• Delete lead (no RP).
• Delete 1,2 DCA (no RP).
• Turbidity (RP = Yes); add permit limit.
• Benzene — (RP = yes) retain permit limit and monthly monitoring.
• Iron - (RP = yes) continue monitoring.
• Manganese - (RP = yes; WS standard 200 µg/L) Add permit limit; continue monitoring.
• MTBE retain monthly monitoring (multiple hits; Permittee has submitted "action plan").
• Naphthalene — add monthly monitoring per Guidance Document (not included in previous permit;
diesel stored onsite).
Note: Database for the RPA is attached to this document.
PROPOSED SCHEDULE FOR PERMIT ISSUANCE
Draft Permit to Public Notice:
Permit Scheduled to Issue:
NPDES DIVISION CONTACT
March 1, 2006
April 24, 2006
If you have quest egardin y of the above information or on the attached permit, please contact Joe
Corporon, NP S P gram fist at [phone] ext. 597.
NAME: DATE:
Fact Sheet
NPDES NC0022187
Renewal
Page 2

REASONABLE POTENTIAL ANALYSIS
Motiva Enterprizes LLC - Charlotte North
NCO022187
Time Period Jan01 - Dec05
Ow (MGD) 0,688
WWTP Class I
7010S (cls) 0
1WC (%) ® 701OS
100
701OW (cis) 0
® 701OW
100
3002 lots) 0
@ 3002
100
Avg. Stream Flow, OA (cts) 0.02
® OA
98.159
Rec'vingStream UT of Gum Branch
Stream Class WS-IV
Outfall 001
Ow = 0.688 MGD
STANDARDS &
PARAMETER
TYPE
CRITERIA (2)
POL
Units
REASONABLE POTENTIAL RESULTS
RECOMMENDED ACTION
NC WOS/ ,FAV/
n oDet Mes Pred Cw Allowable LYi
(1)
Chronic A,, O,
Acute: WA
Benzene
NC
., ',5
WA _ _ ___
_ _ _ _ _ _ _ _ _ _ _ _ _-_ _
Chronic: 1
_
Yes. Continue limit ane monitoring
Acute. N/A
Toluene
C
3
ug/L
48 2
7.5
_______
______
Chronic:_11
___
No_RP BTEX monitoring_manditory per_to SOP 2G:
Continue monitoring.
Acute. 15
EPA625
NC..
G
N/A ________
Chroni_ c: 2
insufficient data - continue monitoring
Acute. 1,022
MTBE
NC
ug4.
0 0
WA___
Chronic: 50
Many hits documented
Acute. 7
NC
- Ai- _
ug/L
0 0
WA
_ _
- ---_—_--- -_--
Chronic:--- 7---
Acute: 22
NC
5 N _..
!0
ug/L
0 0
WA
_- - _ - _ - - _ _
Chronic: 5
Acute: WA
NC
1,800
ug/L
0 0
WA
_
—_—______ __-___
Chronic:- 1800
Acute: 34
Lead
NC
25 N 33.8
ug/L
47 11
8.5
_____ __
_ _ _ _ _ _ _ _________
_ _
Chronic: 25
No RP - delete moor.
Acute: WA
1..2 DCE
NC
12
ng/L
23 0
0.5
_ _ __12
_-------------------------
Chronic:
No;, - aez:.
Acute WA
Iron
A
3.=JO
ug4
0 0 WA
Chronic: 3,500
_
many hits above standarc, RP Yes
AL , theretore o if n0 tps
Acute. WA
Manganese
NC
ug/L
35 34 3,156.0 _ _ ___
_ _ _ _ _ _ — — ___ _____ _
Chronic. 200
___
RP = Yes add permit limit
Acute: N/A
Phenol
A
of N
,g/L
40 10
72-0I—I __
Chronic: 80
No RP therefore no limit. Continue monitoring
^?r SOP 2005
Acute: 50
= Yes -- r:..
Turbidity
NC
ntu
42 42
83.3
_ _ _ _
_------------...................
Chronic: AVALUE
Acute: 1
NC
--= A'
ug/L
0 0
WA
Chronic:_—_ O_—_
Acute: 67
Zinc
NC
50 AL 67
ug/L
0 0
WA ____
________________ _
Chronic: 50
Action Level Parameter - It no tox / no limit
Legend: " Freshwater Discharge
C = Carcinogenic
NC = Non-carcinogenic
A = Aesthetic
22187 Motiva RPA 2006, rpa
2/14/2006

Table 1. Project Information
Facility Name
WWTP Grade
NPDES Permit
Outfall
Flow, Ow (MGD)
Receiving Stream
Stream Class
7Q10s (cfs)
7Q10w (cfs)
30Q2 (cfs)
QA (cfs)
Time Period
Data Source(s)
Motiva Enterprizes LLC - Charlotte North
I
NCO022187
001
0.688
UT of Gum Branch
WS-Iy
0.0
0.0
0.0
0.02
Jan01 - Dec05
DMRs/BIMS
(Note: Bulk Storage Petroleum - flow is MAX for the
permit cycle)
Par01
Par02
Par03
Par04
Par05
Par06
Par07
Par08
Par09
Par10
Par11
Par12
Par13
Par14
Par15
Table 2. Parameters of Concern
Name Type Chronic Modifier Acute PQL Units
Benzene
NC
C
1.19
ugA-
Toluene
11
ug/L
EPA 625
NC
2
15
ug/L
MTBE
NC
50
1022
ug/L
NC
7
AL
7.3
ug/L
NC
5
N
22
10
ug/L
NC
1800
ug/L
Lead
NC
25
N
33.8
ug/L
1,2 DCE
NC
12
ng/L
Iron
A
3500
ug/L
Manganese
NC
200
ug/L
Phenol
A
80
N
ug/L
Turbidity
NC
50
ntu
Zinc
NC
0.06
AL
1.23
ug/L
NC
50
AL
67
ug/L
22187 Motiva RPA 2006, input
2/14/2006

REASONABLE POTENTIAL ANALYSIS
Date Data
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
199
200
Benzene
BDL=1/2DL Results
Std Dev.
NO DATA
Mean
NO DATA
C.V.
NO DATA
n
0
Mult Factor =
N/A
Max. Value
0.0
Max. Pred Cw
N/A
Date Data
1 Jan-2001
2 Feb-2001
3 Mar-2001
4 Apr-2001
5 May-2001
6 Jun-2001
7 Jul-2001
8 Aug-2001
9 Sep-2001
10 Oct-2001
11 Nov-2001
12 Dec-2001
13 Jan-2002 1
14 Feb-2002 , 1
15 Mar-2002s' 1
16 Apr-2002 1
17 May-2002 : 1
18 Jun-2002 1
19 Jul-2002 1
20 Aug-2002 " 1
21 Sep-2002 1
22 Oct-2002 1
23 Nov-2002 1
24 Dec-2002 1
25 Jan-2003 1
26 Feb-2003 1
27 Mar-2003 2.9
28 Apr-2003 1
29 May-2003 1
30 Jun-2003 1
31 Jul-2003 1
32 Aug-2003.E 1
33 Sep-2003 1
34 Oct-2003 1
35 Nov-2003 1
36 Dec-2003 1
37 Jan-2004 1
38 Feb-2004 3.5
39 Mar-2004 1
40 Apr-2004 1
41 May-2004 1
42 Jun-2004 1
43 Jul-2004 1
44 Aug-2004 1
45 Sep-2004 1
46 Oct-2004 1
47 Nov-2004 1
48 Dec-2004 1
49 Jan-2005 1
50 Feb-2005 1
51 Mar-2005 1
52 Apr-2005 1
53 May-2005 1
54 Jun-2005 1
55 Jul-2005 1
56 Aug-2005 1
57 Sep-2005 1
58 Oct-2005 1
59 Nov-2005 1
60 Dec-2005 1
199
Toluene
BDL=1/2DL Results
Std Dev.
Mean
C.V.
n
Mull Factor=
Max. Value
Max. Pred Cw
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
2.9
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
3.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5487
0.6125
0.8959
48
2.1400
3.5
7.5
22187 Motiva RPA 2006, data
1 2/14/2006

REASONABLE POTENTIAL ANALYSIS
EPA 625
MTBE
Date Data
BDL=1/2DL Results
Date Data
BDL=1/2DL Results
1
Std Dev.
NO DATA
1
Std Dev.
NO DATA
2
Mean
NO DATA
2
Mean
NO DATA
3
C V.
NO DATA
3
C.V.
NO DATA
4
n
0
4
n
0
5
5
6
Mult Factor =
N/A
6
Mult Factor =
N/A
7
Max. Value
0.0 ug/L
7
Max. Value
0.0 ug/L
8
Max. Pred Cw
N/A ug/L
8
Max Pred Cw
N/A ug/L
9
9
10
10
11
11
12
12
13
13
14
14
15
15
16
16
17
17
18
18
19
19
20
20
21
21
22
22
23
23
24
24
25
25
26
26
27
27
28
28
29
29
30
30
31
31
32
32
33
33
34
34
35
35
36
36
37
37
38
38
39
39
40
40
41
41
42
42
43
43
44
44
45
45
46
46
47
47
48
48
49
49
50
50
51
51
52
52
53
53
54
54
55
55
56
56
57
57
58
58
59
59
60
60
199
199
200
200
22187 Motiva RPA 2006, data
2- 2/14/2006

REASONABLE POTENTIAL ANALYSIS
Lead
1,2 DCE
Date Data
BDL=1/2DL
Results
Date Data
BDL=1/2DL
Results
1
Jan-2002
4
4.0
Std Dev.
1.0914
1
Jan-2002
1.0
0.5
Sid Dev.
0.0000
2
Feb-2002
3
3.0
Mean
2.4021
2
Feb-2002
1.0
0.5
Mean
0.5000
3
Mar-2002
3
3.0
C.V.
0.4543
3
Mar-2002
C.V.
0.0000
4
Apr-2002
5.5
5.5
n
47
4
Apr-2002
1.0
0.5
n
23
5
May-2002
2
1.0
5
May-2002
6
Jun-2002
2
1.0
Mult Factor =
1.5500
6
Jun-2002
Mult Factor =
1.00
7
Jul-2002
2
1.0
Max. Value
5.5 ug/L
7
Jul-2002
1.0
0.5
Max. Value
0.5 ng/L
8
Aug-2002
3.8
3.8
Max. Pred Cw
8.5 ug/L
8
Aug-2002
Max. Pred Cw
0.5 ng/L
9
Sep-2002
2
1.0
9
Sep-2002
10
Oct-2002
2
1.0
10
Oct-2002
1.0
0.5
11
Nov-2002
4.2
4.2
11
Nov-2002
12
Dec-2002
4
4.0
12
Dec-2002
13
Jan-2003
5
2.5
13
Jan-2003
1.0
0.5
14
Feb-2003
5.5
5.5
14
Feb-2003
15
Mar-2003
5
2.5
15
Mar-2003
16
Apr-2003
5
2.5
16
Apr-2003
1.0
0.5
17
May-2003
5
2.5
17
May-2003
18
Jun-2003
5
2.5
18
Jun-2003
19
Jul-2003
5
2.5
19
Jul-2003
1.0
0.5
20
Aug-2003
5
2.5
20
Aug-2003
21
Sep-2003
no discharge
21
Sep-2003
22
Oct-2003
5
2.5
22
Oct-2003
1.0
0.5
23
Nov-2003
5
2.5
23
Nov-2003
24
Dec-2003
5
2.5
24
Dec-2003
25
Jan-2004
5
2.5
25
Jan-2004
1.0
0.5
26
Feb-2004
5
2.5
26
Feb-2004
1.0
0.5
27
Mar-2004
5
2.5
27
Mar-2004
1.0
0.5
28
Apr-2004
5
2.5
28
Apr-2004
1.0
0.5
29
May-2004
5
2.5
29
May-2004
10
0.5
30
Jun-2004
5
2.5
30
Jun-2004
1.0
0.5
31
Jul-2004
5
2.5
31
Jul-2004
1.0
0.5
32
Aug-2004
5
2.5
32
Aug-2004
1.0
0.5
33
Sep-2004
5
2.5
33
Sep-2004
1.0
0.5
34
Oct-2004
5
2.5
34
Oct-2004
1.0
0.5
35
Nov-2004
5
2.5
35
Nov-2004
36
Dec-2004
5
2.5
36
Dec-2004
37
Jan-2005
2
1.0
37
Jan-2005
1.0
0.5
38
Feb-2005
2
1.0
38
Feb-2005
39
Mar-2005
2
1.0
39
Mar-2005
40
Apr-2005
3
3.0
40
Apr-2005
1.0
0.5
41
May-2005
2
1.0
41
May-2005
42
Jun-2005
2
2.0
42
Jun-2005
43
Jul-2005
2
1.0
43
Jul-2005
1.0
0.5
44
Aug-2005
5
2.5
44
Aug-2005
45
Sep-2005
2
1.0
45
Sep-2005
46
Oct-2005
2.9
2.9
46
Oct-2005
1.0
0.5
47
Nov-2005
2
1.0
47
Nov-2005
48
Dec-2005
5
2.5
48
Dec-2005
49
49
50
50
51
51
52
52
53
53
54
54
55
55
56
56
57
57
58
58
59
59
60
60
199
199
200
200
22187 Motiva RPA 2006, data
-3- 2/14/2006

REASONABLE POTENTIAL ANALYSIS
Iron
Manganese
Date Data
BDL=1/2DL Results
Date Data
BDL=1/2DL
Results
1
Std Dev.
NO DATA
1
Jan-2003
100
50.0
Std Dev.
237.8566
2
Mean
NO DATA
2
Feb-2003
230
230.0
Mean
239.0571
3
C.V.
NO DATA
3
Mar-2003
340
340.0
C.V.
0.9950
4
n
0
4
Apr-2003
300
300.0
n
35
5
5
May-2003
150
150.0
6
Mult Factor =
N/A
6
Jun-2003
150
150.0
Mult Factor =
2.6300
7
Max. Value
0.0 ug/L
7
Jul-2003
250
250.0
Max. Value
1200.0 ug/L
8
Max. Fred Cw
N/A ug/L
8
Aug-2003
110
110.0
Max. Pred Cw
3156.0 ug/L
9
9
Sep-2003
110
110.0
10
10
Oct-2003
150
150.0
11
11
Nov-2003
130
130.0
12
12
Dec-2003
170
170.0
13
13
Jan-2004
140
140.0
14
14
Feb-2004
410
410.0
15
15
Mar-2004
100
100.0
16
16
Apr-2004
740
740.0
17
17
May-2004
660
660.0
18
18
Jun-2004
380
380.0
19
19
Jul-2004
310
310.0
20
20
Aug-2004
120
120.0
21
21
Sep-2004
120
120.0
22
22
Oct-2004
98
98.0
23
23
Nov-2004
77
77.0
24
24
Dec-2004
68
68.0
25
25
Jan-2005
1,200
1200.0
26
26
Feb-2005
570
570.0
27
27
Mar-2005
220
220.0
28
28
Apr-2005
140
140.0
29
29
May-2005
110
110.0
30
30
Jun-2005
110
110.0
31
31
Jul-2005
85
85.0
32
32
Aug-2005
130
130.0
33
33
Sep-2005
no discharge
34
34
Oct-2005
66
66.0
35
35
Nov-2005
323
323.0
36
36
Dec-2005
50
50.0
37
37
38
38
39
39
40
40
41
41
42
42
43
43
44
44
45
45
46
46
47
47
48
48
49
49
50
50
51
51
52
52
53
53
54
54
55
55
56
56
57
57
58
58
59
59
60
60
199
199
200
200
22187 Motiva RPA 2006, data
4- 2/14/2006

REASONABLE POTENTIAL ANALYSIS
Phenols
Turbidity
Date Data
BDL=1/2DL
Results
Date Data
BDL=1/2DL
Results
1
2001
0.01
0.005
Std Dev.
8.5727
1
Sep-2001
34
34
Std Dev.
9.6733
2
2002
0.01
0.005
Mean
8.1523
2
Oct-2001
Mean
18.1905
3
2002
50.
25
C.V.
1.0516
3
Nov-2001
C.V.
0.5318
4
2002
0.01
0.005
n
40
4
Dec-2001
16
16
n
42
5
2002
10.
5
5
Jan-2002
16
16
6
2002
10.
5
Mult Factor =
2.5700
6
Feb-2002
23
23
Mult Factor =
1.7000
7
2002
20.
20.0
Max. Value
28.0 ug/L
7
Mar-2002
16
16
Max. Value
49.0 ntu
8
2002
23.
23
Max. Pred Cw
72.0 ug/L
8
Apr-2002
18
18
Max. Pred Cw
83.3 ntu
9
2002
10.
5
9
May-2002
30
30
10
2002
10.
5
10
Jun-2002
28
28
11
2002
10.
5
11
Jul-2002
8
8
12
2002
10.
5
12
Aug-2002
26
26
13
2002
21.
21
13
Sep-2002
23
23
14
2003
28.
28
14
Oct-2002
23
23
15
2003
5.
2.5
15
Nov-2002
16
16
16
2003
5.
2.5
16
Dec-2002
29
29
17
2003
50.
25
17
Jan-2003
11
11
18
2003
10.
5
18
Feb-2003
21
21
19
2003
10.
5
19
Mar-2003
26
26
20
2003
10.
5
20
Apr-2003
18
18
21
2003
5.
2.5
21
May-2003
28
28
22
2003
0.007
0.007
22
Jun-2003
26
26
23
2003
10.
5
23
Jul-2003
25
25
24
2003
14.
14
24
Aug-2003
11
11
25
2003
10.
5
25
Sep-2003
14
14
26
2004
10.
5
26
Oct-2003
12
12
27
2004
5.
3
27
Nov-2003
9
9
28
2004
0.01
0.01
28
Dec-2003
13
13
29
2004
10.
5
29
Jan-2004
9
9
30
2004
10.
5
30
Feb-2004
14
14
31
2004
31
Mar-2004
15
15
32
2004
5.
2.5
32
Apr-2004
20
20
33
2004
5.
2.5
33
May-2004
6
6
34
2004
34
Jun-2004
9
9
35
2004
21.
21
35
Jul-2004
18
18
36
2004
0.059
0.059
36
Aug-2004
8
8
37
2004
50.
25
37
Sep-2004
17
17
38
2005
0.0085
0.0043
38
Oct-2004
16
16
39
2005
15.
15
39
Nov-2004
6
6
40
2005
10.
5
40
Dec-2004
7
7
41
2005
10.
5
41
Jan-2005
6
6
42
2005
42
Feb-2005
49
49
43
2005
14.
14
43
Mar-2005
39
39
44
2005
44
Apr-2005
5
5
45
2005
45
May-2005
46
2005
46
Jun-2005
47
47
Jul-2005
48
48
Aug-2005
49
49
Sep-2005
50
50
Oct-2005
51
51
Nov-2005
52
52
Dec-2005
53
53
May-2005
54
54
Jun-2005
55
55
Jul-2005
56
56
Aug-2005
57
57
Sep-2005
58
58
Oct-2005
59
59
Nov-2005
60
60
Dec-2005
199
199
200
200
22187 Motiva RPA 2006, data
5 - 2/14/2006

REASONABLE POTENTIAL ANALYSIS
Zinc
Date Data
BDL=1/2DL Results
1
Jan-2002
Std Dev.
NO DATA
2
Feb-2002
Mean
NO DATA
3
Mar-2002
C.V.
NO DATA
4
Apr-2002
n
0
5
May-2002
6
Jun-2002
MultFactor=
N/A
7
Jul-2002
Max. Value
0.0 ug/L
8
Aug-2002
Max. Pred Cw
N/A ug/L
9
Sep-2002
10
Oct-2002
11
Nov-2002
12
Dec-2002
13
Jan-2003
14
Feb-2003
15
Mar-2003
16
Apr-2003
17
May-2003
18
Jun-2003
19
Jul-2003
20
Aug-2003
21
Sep-2003
22
Oct-2003
23
Nov-2003
24
Dec-2003
25
Jan-2004
26
Feb-2004
27
Mar-2004
28
Apr-2004
29
May-2004
30
Jun-2004
31
Jul-2004
32
Aug-2004
33
Sep-2004
34
Oct-2004
35
Nov-2004
36
Dec-2004
37
Jan-2005
38
Feb-2005
39
Mar-2005
40
Apr-2005
41
May-2005
42
Jun-2005
43
Jul-2005
44
Aug-2005
45
Sep-2005
46
Oct-2005
47
Nov-2005
48
Dec-2005
49
50
51
52
53
54
55
56
57
58
59
60
199
200
22187 Motiva RPA 2006, data
6 - 2/14/2006

The Knight Publishing Co., Inc.
Charlotte, NC
North Carolina } ss Affidavit of Publication
Mecklenburg County}
THE CHARLOTTE OBSERVER
--------------------------------------------------+-- -------------------------
y PUBIJ�lND;ICE _
' STATE OF. NORTH CAROUNA
ENVIRONMENTAL MANAGEMENT COMMISSIOWNPDES UNIT
1617 MAIL' SE"CE CENTER .
t y ,q, RALEIGH, NC 27699.1617
NCDENR/DWQ/NPDES I NOTIFICATION OF;1147NT TO ISSUE A NPDES
�,� i9��i >Nw PERMIT
CAROLYN BRYANT ( On66.baWof- 66rollgMafaAf and apphcate of NCGenera1
1617 MAIL SERVICE C T R I UI�a1�1 ms Noi» Carols aFr vi °`� a" lawtul `d' ei0
RAL E I G H N C 2 7 6 9 9 -1617 I s) whisam
to StSW a Natrona) Pollu t MArge Ehrermc6n System
t asc"g Aare �A Ind k191ow
p
��� dihierwf� !�f!?�;sr.prtfl
wrM weir t9.
130 days after the � a d this nnoficce NI cornrnents
I mew `W ;per.!m.. Sdoi"off t15 Nck ti «a` d
'iNal6uQuelrh't'maftPublic meeting for the or000sed
REFERENCE: 30045571
5656793 Citgo Petroleum
Before the undersigned, a Notary Public of said
County and State, duly authorized to administer
oaths affirmations, etc., personally appeared,
being duly sworn or affirmed according to law,
doth depose and say that he/she is a
representative of the Knight Publishing Company a
corporation organized and doing business under the
laws of the State of Delaware, and publishing a
newspaper known as The Charlotte Observer in the
city of Charlotte, County of Mecklenburg and Sta
of North Carolina and that as such he/she is
familiar with the books, records, files and
business of said Corporation and by reference o
the files of said publication
the attached advertisement was inserted. T
following is correctly copied from the boo and
files of the aforesaid Corporation and
Publication.
PUBLISHED ON: 03/04 Z'ez�_'I..
Tnirg[Tondltlons P yy�� � va(leble
r a � ' � t�t WWNN Matt QU �Fer
I cress or. I the Point Source Branch at (919)
" 1= -j a irldeW$Z&NPQE3 p6mA
oh bliY nation. Interested persons may
t%rll tell at N. gali—Street;
27 dg TjeZvreEn
s d 'a
a hours 8 00 .m, and 5:00
Ylnfarriatmnon, I :.. � iry .' •c:J.
i�ai��vrrggCl�raeic
um jN0002� ,appXed tc
)artltareBawr,m turdty `ere
lira qi . rated ware, wasreloadaYo-
SVaer" # nn�flei,L�r�'ni�r+al�.'r�;ly�!s
! I i7) applied for renewal of Oi
it;W-4 rLl:
twmry d cum. Brand, in
1. TTMs as�Zr y ' KmAie' �and ' are s
rig strsamtl&"1 ( yifntarXwM w-uaas Nlct;
isa• CLC (NC004689° `MQl( %t"r�rigWal gf .'s pi }:"
rgiktqn Arta wwA�twrflI M.
hrwlrty Gmit7wTrf Tbj��,rrtra`
11<6q
AD SPAC 104 LINE
FILED O 03/10
------ - - ---
/06 -- -------------- --- - -- --------------------
NAME: TITLE: M
DATE:
In Testimony Whe of I have hereunto set my hand and affixed my seal, the
day and year aforesaid.
Notac _—_—_—_— My Commission Expires:
ti]IrfSn?4:`i� _.' .6',^ i n .j 7
V CO�, SiV6
a

DENR/DWQ
FACT SHEET FOR NPDES PERMIT DEVELOPMENT
NPDES No. NCO022187
Facility Information,
Applicant/Facility Name:
NC0022187 — Motiva Enterprises, LLC
A licantAddress:,. ..
Mr. Ken Watson, Complex Manager
Facility Address:,...: . _ .
410 Tom Sadler Road; Charlotte, NC 28214
Permitted'Flow-i '
Not limited
Type;of ,Waste:
"`
Stormwater, truck -loading rack wastewater, groundwater remediation
effluent
Facility ennitStatus:
Active / Renewal
County: ° . ':: ':
Mecklenburg
BACKGROUND
Waste Load Allocation (WLA) and Bulk -Storage SOP. A Waste Load Allocation was last conducted in
April 1994, when the receiving stream, Gum Branch, was classified C waters. The Division subsequently re-
classified Gum Branch as WS-1V waters prior to last renewal. This WLA recommended monitoring for
benzene, toluene, ethylbenzene, lead, and MTBE with permit limits for TSS and oil and grease. The Division
established new effluent limits and monitoring requirements for the previous permit according to
Requirements for Discharges from Oil and Petroleum Storage Facilities (SOP 2001, version 30ul01).
PERMITTING STRATEGY
New SOP for Oil Terminals: The Division establish renewal criteria for this permit according to the
NPDES Permitting Requirements for Petroleum Bulk -Storage 2005 Permitting Strategy, version September 9,
2005 (2005 SOP). This document established 12 criteria for renewal including reasonable potential analyses
(see Renewal Summary). Database for this RPA is attached to this document.
Reasonable Potential Analysis (RPA): The Division conducted a reasonable potential analysis according to
EPA guidelines in order to establish potential for a given parameter to exceed its water quality stream
standard. The Division established a list of parameters of concern (POCs) based on the previous permit. These
parameters include benzene, toluene, turbidity, iron, lead, manganese, and 1,2 Dichloroethane (DCA). In
addition, the Division calculated phenol limits appropriate for a discharge to water supply (WS-IV) waters
considering a total of eight discharges to this water shed (see 2005 SOP, item 11).
. Fact Sheet
NPDES NCO022187
Renewal
Page 1

REGIONAL OFFICE COMMENTS
j ftl--/ 1��,
47
NAME: �Tl/ ��/� �b L/— (�=� E /,ol-- DATE: -- G-s ' C
SUPERVISOR: DATE: b
NPDES SUPERVISOR: DATE:
Fact Sheet
NPDES NCO022187
Renewal
Page 3

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■■■■■■■■■■■■■■■■■■■■■■■■■■■■OEM■MENOENNEE
■■■■■■■■■■■■■■■■MEEMM■MEMEMEME■■■O■■■m■■■
EMMMME ME EMEMEMEN ME
MM■MEMO■■MME■OMEN■■■■■■■■M■ IM■M■MME■EMEM■
■OMEN®■■■■■OEM■■MN■■MMMr MMMMIMMIMMMMMMMMMM
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MEMEMMNMEMMEMEN■■MONO ■EM MIMMMMMMMMMMMMMMM

MONITORING REPORT(MR) VIOLATIONS for:
Report Date: 02/01/06
Page: 1 of 1
Permit: nc0022187
MRs Between: 1-2002
and 12-2005
Region: %
Violation
Category: %
Program Category: %
Facility Name: %
Param Name: %
County: %
Subbasin: %
Violation Action: %
PERMIT: NCO022187
FACILITY: Motiva Enterprises LLC - Paw Creek Terminal
COUNTY: Mecklenburg REGION: Mooresville
Limit Violation
MONITORING OUTFALL
VIOLATION
UNIT OF
CALCULATED
REPORT / PPI LOCATION
PARAMETER
DATE
FREQUENCY
MEASURE
LIMIT
VALUE
VIOLATION TYPE
VIOLATION ACTION
03 - 2002 001 Effluent
Benzene, Dissolved
03/31/02
Monthly
ug/I
1.19
12
Daily Maximum Exceeded
BIMS Pre -Production
Violation
04 - 2003 001 Effluent
Benzene, Dissolved
04/30/03
Monthly
ug/I
1.19
10
Daily Maximum Exceeded
Proceed to NOV
01 - 2005 001 Effluent
Benzene, Dissolved
01/31/05
Monthly
ug/I
1.19
6
Daily Maximum Exceeded
Proceed to NOV
04 - 2005 001 Effluent
Benzene, Dissolved
04/30/05
Monthly
ug/I
1.19
1.3
Daily Maximum Exceeded
Proceed to NOV
Reporting Violation
MONITORING OUTFALL
VIOLATION
UNIT OF
CALCULATED
REPORT / PPI LOCATION
PARAMETER
DATE
FREQUENCY
MEASURE
LIMIT
VALUE
VIOLATION TYPE
VIOLATION ACTION
01 - 2002 001 Effluent
1,2-dichloroethane
01/31/02
Quarterly
ug/I
Parameter Missing
BIMS Pre -Production
Violation
01 - 2002 001 Effluent
Ethylbenzene
01/31/02
Monthly
ug/I
Parameter Missing
BIMS Pre -Production
Violation
01 - 2002 001 Effluent
Iron, Total (as Fe)
01/31/02
Monthly
ug/I
Parameter Missing
BIMS Pre -Production
Violation
08 - 2005 001 Effluent
LC50 STAT 24hr ACU
08/31/05
Annually
percent
Parameter Missing
None
Pimephales
01 - 2002 001 Effluent
Manganese, Total (as Mn)
01/31/02
Monthly
ug/I
Parameter Missing
BIMS Pre -Production
Violation
01 - 2002 001 Effluent
Methyl Tert-Butyl Ether
01/31/02
Monthly
ug/I
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BIMS Pre -Production
Violation
12 - 2004 001 Effluent
Turbidity, HCH Turbidimiter
12/31/04
Monthly
ntu
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No Action, Data Entry
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Error

DATE:
TO:
FROM:
SUBJECT:
MEMORANDUM
September 08, 2005
NPDES Program
Joe R. Corporon, L.G.
Permit Writer
Revised Guidance to Permit Writers — Allowable Phenol Loads for Bulk
Oil Terminals in the Paw Creek Area, Catawba River Basin.
As part of the newly revised Standard Operating Procedures — Permit Requirements for
Discharges from Oil and Petroleum Storage Facilities (SOP-2001), the Division has
recalculated the allowable load for phenol. New numbers are appropriate for bulk oil
distribution terminals discharging to an unnamed tributary of Gum Branch (WS-IV) and an
unnamed tributary of Long Creek (WS-IV CA), both within subbasin 030834. This document
affects eight (8) permitted facilities discharging to WS waters (see Table 1).
I have made these calculations considering the following background and assumptions:
1. The water quality stream standard comes from the EPA Document Ambient Water
Quality Criteria for Chlorinated Phenols. This standard has been included in the North
Carolina 2B .0200 Rules and has been applied to Water Supply (WS) waters since 1990.
2. The standard for chlorinated phenolic compounds is 1.0 µg/L. Although it is unlikely
that petroleum bulk storage facilities would discharge chlorinated phenolic compounds,
they may discharge phenol. Therefore, the Division is concerned that phenol (at levels of
1 µg/L or greater) has potential to create "daughter compounds" at downstream water
intakes where water is drawn from the river and chlorinated. It is therefore appropriate to
calculate allowable phenol load near the closest water intake downstream of these bulk
storage facilities.
3. I have applied the 30Q2 flow because the standard is based on potential aesthetic
concerns (taste and odor associated with chlorinated phenols in fish and drinking water).
I have applied the standard (1.0 µg/L) near the confluence of Long Creek and the
Catawba River (approximately 1,000 feet upstream) where the Division calculated 30Q2
flow at 716 cfs (based on Clariant Corporation's 1996 WLA, NC0004375). Therefore,
the allowable wasteload for each of nine (9) dischargers is calculated:
716 cfs x 0.001 mg/L x 8.34 = 3.85 lbs./day total phenol
1.55
3.85 lbs./day of phenol = 0.48 lbs./day per discharger
8 dischargers
Paw Creek
Phenol Calculations Memorandum --July 27, 2005
Page I

To evaluate reasonable potential for phenol:
1) Use the facility's average wasteload/stormwater flow (highest monthly average flow
during the last permit cycle) to convert the calculated individual wasteload allocation
(per facility) of 0.48 lbs./day to a concentration in mg/L.�
Single-Outfall Example: HighestjUDw for Outfall 001 =>85
MGD
001 = 0.481bs./day x 1
8.34 MGD
Two-Outfall Example: Highest flow for Outfall 001 = 0.55 MGD -�
Highest flow for Outfall 002 = 0.84 MGD RPA
[Divide alble wasteload by the number of outfalls (0.48 lbs/day divide]
001 = 0.24 lbs./day 1 = .05 mg/L
8.34 MGD
002 = 0.241bs./day x 1 = 0. 03 mg/L
8.34 4 MGD
2) Proceed with re nable potential analysis (RPA) using result in mg/L) as limit.
Table 1 -- This guidance applies to the following NPDES facilities:
PERMIT
NUMBER
DISCHARGER
RECEIVING
STREAM
NCO021962
CITGO Petroleum — Paw Creek
Gum Branch
NCO022187
Motiva Enterprises LLC — Paw Creek
Gum Branch
NCO031038
Colonial Pipeline — Charlotte DF
Gum Branch
NCO032891
Kinder Morgan Southeast Term., LLC
Gum Branch
NCO046213
Marathon Ashland Petroleum LCC
Long Creek
NC0004839
Kinder Morgan Southeast Term., Char.
Long Creek
NC0005185
Me ellan Terminals Holdings, LP
Long Creek
NCO046892
Motivia Enterprises LLC, Charlotte South
Long Creek
Paw Creek
Phenol Calculations Memorandum -- September 08, 2005
Page 2

SOC PRIORITY PROJECT: Yes_ No X
To: Permits and Engineering Unit
Water Quality Section
Attention: Carolyn Bryant
Date: March 8, 2005
NPDES STAFF REPORT AND RECOMMENDATION
County: Mecklenburg
MRO No.: 05-07
Permit No. NCO022187
PART I - GENERAL INFORMATION
1. Facility and address: Motiva Enterprises
410 Tom Sadler Rd.
Paw Creek, North Carolina 28214
2. Date of investigation: 02-28-05
3. Report prepared by: Samar Bou-Ghazale, Env. Engineer I
4. Persons contacted and telephone number: Mr. Ken Watson, Terminal Manager; (704) 399-
1904.
5. Directions to site: From the junction of Highway I-85 and Highway 27 in Charlotte, travel
west on Highway 27 (Freedom Drive) approximately three (3) miles to Old Mt. Holly Road.
Turn right onto Old Mt. Holly Road and travel approximately 0.2 mile to Tom Sadler Road.
Turn left onto Tom Sadler Road and travel approximately 0.2 mile. Motiva Enterprises is
located on the right (north) side of Tom Sadler Road.
6. Discharge point(s). List for all discharge points:
Latitude: 350 16' 59" Longitude: 800 56' 10"
Attach a U.S.G.S. map extract and indicate treatment facility site and discharge point on map.
USGS Quad No.: F 15 SW USGS Quad Name: Mountain Island
7. Site size and expansion are consistent with application?
Yes X No_ If No, explain:

8. Topography (relationship to flood plain included): Sloping north toward an intermittent
stream at the rate of 2 to 6%. The site is not located in a flood plain.
9. Location of nearest dwelling: None within 1000 feet of the discharge point.
10. Receiving stream or affected surface waters: Unnamed tributary to Gum Branch.
a. Classification: WS IV
b. River Basin and Subbasin No.: Catawba River Basin; 030834
C. Describe receiving stream features and pertinent downstream uses: Discharge is into
an intermittent stream on the north side of the site. This stream flows through an
undeveloped area prior to merging with a tributary to Gum Branch. There are several
other industrial and domestic wastewater discharges into Gum Branch. General C
classification uses downstream
PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS
1. a. Volume of wastewater to be permitted:
Discharge is intermittent depending on rainfall. The types of fuels stored are
regular unleaded, premium unleaded and mid -grade gasoline (which is a mixture of
regular unleaded and premium unleaded), high sulfur diesel, and low sulfur diesel.
b. What is the current permitted capacity of the wastewater treatment facility? N/A.
C. Actual treatment capacity of the current facility (current design capacity)? N/A.
d. Date(s) and construction activities allowed by previous Authorizations to
Construct issued in the previous two years: N/A
e. Please provide a description of existing or substantially constructed wastewater
treatment facilities: The existing treatment facilities consist of an oil water
separator located below the loading/unloading, a storage tank and a pond
constructed at the lower end of the facility. The discharge from the pond is
controlled by an outfall control valve, and the amount of discharge depends on
rainfall Storm water is also directed to the pond via the storm water drainage
system Discharge from the groundwater remediation system permit #
NCG510177 has ceased.
f. Please provide a description of proposed wastewater treatment facilities: N/A
NPDES Permit Staff Report
Page 2

g. Possible toxic impacts to surface waters: Due to nature of the wastewater there
could be some toxicity concern.
h. Pretreatment Program (POTWs only): N/A.
2. Residuals handling and utilization/disposal scheme: Tank water bottom and solids are
pumped and hauled by US Filter in Concord, tel# [phone].
3. Treatment plant classification: Class I.
4. SIC Code(s): 5171
Primary: 53
Main Treatment Unit Code: 53000
PART III - OTHER PERTINENT INFORMATION
1. Is this facility being constructed with Construction Grant Funds or are any public monies
involved (municipals only)? N/A.
2. Special monitoring or limitations (including toxicity) requests: Acute toxicity monitoring is
already included in the permit.
3. Important SOC, JOC or Compliance Schedule dates: (please indicate) N/A.
4. Alternative Analysis Evaluation: Has the facility evaluated all of the non -discharge
options available. Please provide regional perspective for each option evaluated.
Spray irrigation: N/A
Connection to regional Sewer System: N/A
S. Air Quality and/or Groundwater concerns or hazardous material utilized at this facility that
may impact water quality, air quality or groundwater? Hazardous material stored at the
site may be a constant threat to the groundwater. Air Quality Permits may be required by
Mecklenburg County.
PART IV - EVALUATION AND RECOMMENDATIONS
The Permittee, Motiva Enterprises is requesting NPDES Permit renewal for the discharge
of treated stormwater from the subject facility. A review of the past year's self -monitoring data,
NPDES Permit Staff Report
Page 3

from 02/2004 through 01/2005, revealed no violations.
It is recommended that the NPDES permit for this facility be renewed.
Signature of Report Premier
Surface Water Pye ection Regional Supervisor
0 S
Date
NPDES Permit Staff Report
Page 4

UM
CERTIFIED MAIL #70041160 0000 8009 5074
RETURN RECEIPT REQUESTED
December 21, 2004
Mr. Charles H. Weaver, Jr.
NC DENR/Water Quality/NPDES Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: Permit Renewal Application
NPDES Permit: NCO022187
Motiva Enterprises LLC — Charlotte North Terminal
Dear Mr. Weaver:
MOTIVA
ENTERPRISES LLC
Motiva Enterprises LLC — Charlotte North Terminal is hereby requesting renewal of NPDES Permit
NC0022187. The subject permit expires on June 30, 2005. No physical changes have been made to
the wastewater treatment components at the facility since the last permit.
The Charlotte -North Terminal does not generate sludge as part of wastewater discharge; therefore no
sludge management plan is necessary for this facility.
As requested please find enclosed the following items:
• Cover letter requesting renewal of permit and documenting any changes at the facility since
issuance of the last permit including a narrative description of the sludge management plan if
applicable. (One signed original and two copies);
• Completed NPDES Permit Application — Short Form C, included as Attachment A (One signed
original and two copies);
• Delegation of Authority documentation included as Attachment -A;.—
If you have any questions, please contact me at [phone].
Very truly yours,
Motiva Enterprises LLC
Nicola E. Cloutier
Environmental Engineer
Attachments
cc: Charlotte -North Terminal Files
N. E. Cloutier
P.O. Box P476 Alexandria, Virginia 22301
d
10FC
Phone: [phone] Fax: [phone]

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UNLUKCU or:i SHELL OIL PRODUCT'S US
MOTIVA FACILITY #058060
REVIEWED eY: 410 TOM SADLER ROAD
CHARLOTTE, NORTH CAROLINA
NORTH; Groundwater & Environmental Services, Inc.
ONE NORTH COMMERCE CENTER, 5293 CAPITAL BLVD., RALEIGIi, NC 27E
SCALE IN FEET DATE I FIGURE
0 120 7-7-03

X
MOTIVA
ENTERPRISES LLC
Amy, Tev = & Saudi Artwr n Wcr*!-g Toeeth�
DATE: NOVEMBER 27, 2000
TO: GENERAL MANAGER DISTRIBUTION
REGIONAL MANAGERS
MANAGER(S) SAFETY, HEALTH & ENVIRONMENT
TERMINAL MANAGERS AND SUPERINTENDENTS
FROM: VICE PRESIDENT — COMMERCIAL MARKETING & DISTRIBUTION
SUBJECT: RESPONSIBLE OFFICIAL DELEGATION TO DULY AUTHORIZED
REPRESENTATIVE
The purpose of this memo is to provide to the named delegatees (addressees) certain environmental authorities to
enable them to conduct the necessary environmental compliance work of the Company. They are authorized to act
on my behalf as duly authorized representative concerning environmental permit mattei:s, which mg include
signature on permits, applications, amendments and reports and so forth. These authorities shall always be
exercised consistent with the Limited Liability Company Agreement of the Company and policies in the best interest
of the Company and its owners as dictated by prudent business judgment and in strict accordance with the letter and
spirit of the Company's Code of Conduct and all current Company policies and procedures.
You are hereby authorized as follows:
Permit Applications, Amendments, Modifications, Transfers, Reports and Other Information
To the extent Permitted by law, pursuant to the United States Environmental Protection Agency's pen -nit
regulations under federal statutes and regulations under state environmental statutes, authority to sign environmental
permit applications, requests for permit amendments, modifications or transfers, reports, and other information
provided to governmental agencies in connection with environmental pen -nits is hereby assigned and delegated to
persons occupying or acting in the capacity of the delegatees.
Reports and Other Information
In the absence of the Terminal Manager or Superintendent, the Supervisor may perform the same duties as stated
above.
Scope and subdelegation:
Persons occupying or acting in the capacity of the delegatees may sign for those facilities or activities, which are
within their overall operational responsibility. Person(s) occupying positions designated to sign permit applications
may further delegate authority to sign reports and submit information to the extent permitted by applicable law.
Ralph J_ Grimmer
Vice President — Commercial Marketing & Distribution