The URL can be used to link to this page

Home My WebLink AboutNC0022187_Permit Application_20060818f%, CAt�J AA!D AoTf FI C-b- ' ' C`n DGT�aC7ro) CERTIFIED MAIL #7005 1160 0001 4318 8353 15AAM iENTERPRISES LLC)OM O TIVA RETURN RECEIPT REQUESTED kWP41 August 17, 2006 Mr. Joe Corporon NC DENR/Water Quality/NPDES Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: Permit Modification Application NPDES Permit: NCO022187 Motiva Enterprises LLC — Charlotte North Terminal Dear Mr. Corporon: V � W v pENR . wptER WN H Motiva Enterprises LLC — Charlotte North Terminal is requesting modification of NPDES Permit NC0022187. The permit currently contains a limit for manganese of 200 ug/I. Motiva believes that manganese is naturally occurring in the environment and, as such, should not be limited by the permit. Attachments C and D of this correspondence contain analytical results of soil and groundwater samples that document a relatively high background concentration of manganese (as compared to the permit limit of 200 ug/1). Soil data published by the United States Geological Survey (USGS) in 1981 indicate manganese soil concentrations of 300 ppm in a sample collected within a couple of miles of the Charlotte North Terminal. Analytical results of soil samples recently collected in the receiving bed upstream of the facility's discharge confirm the USGS data. Manganese soil concentrations ranged from 258 ppm to 740 ppm in the three samples collected. Groundwater monitoring data also indicate elevated concentrations of manganese (ranging from 71 ug/I to 1840 ug/1), which appear to be due to contact with the local soils. The Motiva Charlotte North Terminal does not manufacture, store or use products containing manganese compounds, nor are we aware of past activities that could have involved such compounds. Therefore, the likely source of the manganese detections in previous stormwater samples is contact with the local soils, which is beyond Motiva's control. Accordingly, Motiva respectfully requests the Agency to modify Permit NCO02187 by removing the limit on manganese. Please find attached the following items to support this modification request: • Cover letter requesting modification of permit and documenting no changes at the facility since issuance of the last permit including a narrative explaining that no sludge management plan is required. (One signed original and two copies); • Attachment A - Completed NPDES Permit Application — Short Form C, included (One signed original and two copies); • Attachment B — Figures and Tables • Attachment C — Soil Analytical Data • Attachment D — Groundwater Analytical Data • Attachment E - Delegation of Authority documentation • Check in the amount of $215.00 to cover the fee for a major modification of a minor industrial source permit. 2232 Ten Ten Road Apex, North Carolina 27539 Phone: (919) 362-0070 Fax: (919) 362-0716 Mr. Joe Corporon August 17, 2006 Page 2 There have been no changes in the treatment system for the Charlotte North Terminal since the issuance of the last permit. The terminal does not generate sludge as part of its wastewater discharge. Therefore, no sludge management plan is necessary for this facility. If you have any questions, please contact me at (919) 362-0070. Sincerely, Motiva Enterprises LLC A �' --'� Philip Morris Environmental Engineer Attachments CERTIFIED MAIL #7005 1160 0001 4318 8353 RETURN RECEIPT REQUESTED August 17, 2006 Mr. Joe Corporon NC DENR/Water Quality/NPDES Unit 1617 Mail'Service Center Raleigh, NC 27699-1617 Re: Permit Modification Application NPDES Permit: NCO022187 Motiva Enterprises LLC — Charlotte North Terminal Dear Mr. Corporon: o MOTIVA ENTERPRISES LLC Motiva Enterprises LLC — Charlotte North Terminal is requesting modification of NPDES Permit NC0022187. The permit currently contains a limit for manganese of 200 ug/I: Motiva believes that manganese is naturally occurring in the environment and, as such, should not be limited by the permit. Attachments C and D of this correspondence contain analytical results of soil and groundwater samples that document a relatively high background concentration of manganese (as compared to the permit limit of 200 ug/1). Soil data published by the United States Geological Survey (USGS) in 1981 indicate manganese soil concentrations of 300 ppm in a sample collected within a couple of miles of the Charlotte North Terminal. Analytical results of soil samples recently collected in the receiving bed upstream of the facility's discharge confirm the USGS data. Manganese soil concentrations ranged from 258 ppm to 740 ppm in the three samples collected. Groundwater monitoring data also indicate elevated concentrations of manganese (ranging from 71 ugh to 1840 ug/1), which appear to be due to contact with the local soils. The Motiva Charlotte North Terminal does not manufacture, store or use products containing manganese compounds, nor are we aware of past activities that could have involved such compounds. - Therefore, the likely source of the manganese detections in previous stormwater samples is contact with the local soils, which is beyond Motiva's control. Accordingly, Motiva respectfully requests the Agency to modify Permit NCO02187 by removing the limit on manganese. Please find attached the following items to support this modification request: • Cover letter requesting modification of permit and documenting no changes at the facility since issuance of the last permit including a narrative explaining that no sludge management plan is required. (One signed original and two copies); • Attachment A - Completed NPDES Permit Application — Short Form C, included (One signed original and two copies); • Attachment B — Figures and Tables • Attachment C — Soil Analytical Data • Attachment D — Groundwater Analytical Data • Attachment E - Delegation of Authority documentation • Check in the amount of $215.00 to cover the fee for a major modification source permit. of a minor industrial 2232 Ten Ten Road Apex, North Carolina 27539 Phone: (919) 362-0070 Fax: 19191 362-0716 Mr. Joe Corporon August 17, 2006 Page 2 There have been no changes in the treatment system for the Charlotte North Terminal since the issuance of the last permit. The terminal does not generate sludge as part of its wastewater discharge. Therefore, no sludge management plan is necessary for this facility. If you have any questions, please contact me at (919) 362-0070. Sincerely, Motiva Enterprises LLC 1�4`--'� Philip Morris Environmental Engineer Attachments Attachment A — NPDES Permit Application Short Form C (Signed Original and Two Copies) NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial Minor industrial, manufacturing and commercial facilities. Mail the complete application to: N. C. Department of Environment and Natural Resources Division of Water Quality / NPDES Unit 1617 Mail Service Center, Raleigh, NC 27699-1617 NPDES Permit Number INC0022187 If you are completing this form in computer use the TAB key or the up - down arrows to move from one field to the next. To check the boxes, click your mouse on top of the box. Otherwise, please print or type. 1. Contact Information: Owner Name Facility Name Mailing Address City State / Zip Code Teleph'a t e Number Fax Number e-mail Address Motiva Enterprises LLC Motiva Enterprises LLC - Charlotte North Terminal 410 Tom Sadler Road Charlotte North Carolina / 28214 (704)399-3301 (704)394-8988 sam.baker@motivaent.com 2. Location of facility producing discharge: Check here if same as above Street Address or State Road City State / Zip Code County 3. Operator Information: Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the Operator in Responsible Charge or ORC) Name Motiva Enterprises LLC Mailing Address 410 Tom Sadler Road City Charlotte State / Zip Code North Carolina / 28214 Telephone Number (704)399-3301 Fax Number (704)394-8988 Page 1 of 4 C-MI 03/05 NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial Minor industrial, manufacturing and commercial facilities. 4. Ownership Status: Federal ❑ State ❑ Private ® Public ❑ S. Standard Industrial Classification (SIC) code(s): 5171 6. Number of employees: 6 7. Describe the treatment system List all installed waste treatment components with capacities, describe the processes that generate wastewaters. If the space provided is not sufficient attach a separate sheet of paper with the system description. Stormwater from the loading rack area gravity flows to an 10,000-gallon in -ground SPCC Tank (oil/water separator). The water leg of the separator gravity flows to the dike and comingles with stormwater collected within the diked area, which is then discharged under operator supervision to the retention pond and eventually out through Outfall 001 under supervision. Recovered product from the SPCC Tank is routed to the Flush Tank, thg, contents of which are periodically pumped back into storage. The ground water remediation system here is only an air sparge system. No recovery or process of water. S. Is facility covered under federal effluent limitation guidelines? No ® Yes ❑ If yes, specify the category? 9. Principal product(s) produced: N/A* Principal raw material(s) consumed: N/A* Briefly describe the manufacturing process(es): Page 2 of 4 C-MI 03/05 n NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial Minor industrial, manufacturing and commercial facilities. * The facility is a distribution terminal for gasoline and petroleum distillates. It does not produce, manufacture or consume products or raw materials. Gasoline and distillates are received via pipeline, which are then stored in above ground storage tanks. All products are loaded out via tanker truck through the terminal's loading rack. 10. Amount of principal product produced or raw material consumed /T;..f nnr71nr7mit_C nfnmr1urtinn nilPr the last three nears) Product Produced or Raw Material Product Produced or Raw Material Consumed Consumed AVERAGE PEAK per Day 600,000 gallons (based on 2005 data) 770,000 gallons (based on 2005 data) per Month 18,000,000 gallons (based on 2005 data) 23,000,000 gallons (based on 2005 data) per Year 1213,000,000 gallons (based on 2005 data) 11. Frequency of discharge: Continuous ❑ Intermittent If intermittent: Days per week discharge occurs: varies with rainfall Duration: 12. Types of wastewater discharged to surface waters only Discharge Flow GALLONS PER DAY Sanitary - monthly average N/A Utility water, etc. - monthly average N/A Process water - monthly average N/A Stormwater - monthly average 726,000 gallons (dependent on rainfall) Page 3 of 4 C-MI 03l05 NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial Minor industrial, manufacturing and commercial facilities. Other - monthly average Explain: N / A Monthly Average total discharge (all types) 726,000 gallons (dependent on rainfall) 13. Number of separate discharge points: 1 Outfall Identification number(s) 001 - Stormwater from loading rack and tank dikes 14. Name of receiving stream(s) (Provide a map showing the exact location of each outfall, including latitude and longitude Un-named tributary to Gum Branch 15. Effluent Data Provide data for the parameters listed. Temperature and pH shall be grab samples, for all otherparameters 24hour composite sampling shall be used. If more than one analysis is reported, report daily maximum and monthly average. If only one analysis is reported, report as daily maximum. Parameter Daily Maximum Monthly Average Units of Measurement Biochemical Oxygen Demand (BOD5) Chemical Oxygen Demand (COD) Total Organic Carbon Total Suspended Solids See Attached Summary - Ammonia as N Temperature (Summer) Temperature (Winter) pH' Fecal Coliform (If sanitary waste is present) Total Residual Chlorine (if chlorine is used) < Page 4 of 4 C-MI 03/05 NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial Minor industrial, manufacturing and commercial facilities. 16. List all permits, construction approvals and/or applications (check all that apply and provide permit numbers or check none if not appiicabler Type Permit Number Type Permit Number Hazardous Waste (RCRA) UIC (SDWA) NPDES PSD (CAA) Non -attainment program (CAA) WI0300060 NCO022187 NESHAPS (CAA) Ocean Dumping (MPRSA) Dredge or fill (Section 404 or CWA) Other 02-130-689 (Air) 17. List any chemicals that may be discharged (Please list and explain source and potential amounts.) None in addition to compounds being analyzed. —der 18. Is this facility located on Indian country? (check one) Yes ❑ No 19. Applicant Certification I certify that I am familiar with the information contained in the application and that to the best of my knowledge and belief such information is true, complete, and accurate. Sam Baker Terminal Superintendent Printed name of Person Signing Title of Date North Carolina General Statute 143-215.6 (b)(2) provides that: Any person who knowingly makes any false statement representation, or certification in any application, record, report, plan, or other document files or required to be maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or monitoring device or method required to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable by a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section 1001 provides a punishment by a fine of not more than $25,000 or imprisonment not more than 5 years, or both, for a similar offense.) Page 5 of 4 C-MI 03/05 Attachment B — Figures and Tables �-n UT of Gum �1 h Bran C. �r y t L •_ ! 13 Yam 4:� < ., ♦ ,}.,, � ` / /.� : -t>♦.,•�ft.L.� ,r!! x� 4,-'lf**t„ ► Outfa11001; `\ #J (flows north) `�� t\ �t' ,,. •' • ?: •f .�•t ,( ,1 J �" _I ��i�1.J.��%4^S, t-'s'..�r. F v� .+� ...'`..: t • -�--j .+c" i.ta 'r ,: f �R • if �, • -:*, o '".r-_'; Motiva Enterprises, LLC •• - •. • • r� • + �..� Approximate Property p r� " t��~ '�� • _JT,�,Boundary o ;yy'-'^�{3., y' :. '' "' t � tit � G ti!''4 �, �, /// l f tir � �! _ • "'1 � {. 3 !•i�i„� R'- �f � ��- ;^+.� ti. S 1''v "Sf� a� � r X. rs w , a NC r i'1°-5' �. � /, C/ � T�'�} � ,.ar<"` :� cI�^•� vl A �,�,.� ,� t _ s �'�' it. r i�,+' � *.q ;i: ,.in /�l�l��( !\�*�:.�,..... .}�-L�i"�, ��f�:.s .1�.;7I.x..�.,�1� ".'ti. A� Y-�X .-.t.`C-..s:..tc• tea;:. ;: ,+i..` Motiva Enterprises, LLC Charlotte -North Terminal State Grid/Quad: F15SW / Mt Island fake, NC Permitted Flow: not limited Latitude: 35' 16' 59" N Longitude: 80' 56' 10" W Receiving UT to Gum Branch Sub -Basin: 03-08-34 Drainage Basin: Catawba River Basin Stream Class: WS-iv W-28 �W-14 x x x X— +MW-21 *MW-22 ..... OFFICE/WAREHOUSE GRASS MW-244� CONCRETE MW-12 RW-44� MW-1 MW-8 IMW-29 I + MW-31 +MW-32 + MS AS-11 AS-12 _ AS-14 15 AS-8 p9 13 13+ AS-13 0 13 13AS + A-i6 AS-7p cc AS_ MW-19 MW-20 MW-15 DAS-4 UAS-5 AS-6 — fly O /ce +MW-11 MW-10y 3 RW-5,`.. RW-2\MW- PUMP AS—lp HOUSE W— SUMP (94RW-3 MW-18 AV—JEf?5/ + MW-7 UNLO EMpry MW—fi DIESEL DILL / DFlRE \ BLDG. CONTAINMENT BMW-2 MW-3 DINE +MW-26 + LEGEND + MONITORING WELL LOCATION DEEP MONITORING WELL LOCATION 4, RECOVERY WELL LOCATION +MW-30 p AIR SPARGE WELL LOCATION �I STREAM SAMPLE LOCATION ABANDONED WELL LOCATION ---- PROPERTY LINE -x—x- FENCE ® STORM SEWER DRAIN —PP— PLANTATION PIPELINE —CP— COLONIAL PIPELINE —SS— STORM SEWER US UPSTREAM MS MIDSTREAM DS DOWNSTREAM uw so nwehu s �-clmau sv rc 0 120 240 SCALE FEET 9874 MAIN STREET SUITE 100 WOODSTOCK, GA. 30188 • 770-926-8883 ASSOCIATES NO.: DRAWING DATE: S A'FlLE: 11—OS-04 T058060—SIT SITE MAP 4T` SHELL OIL PRODUCTS U.S. PM: MOTIVA COST CENTER #058060 BB TION: 410 TOM SADLER ROAD PE/RG: CHARLOTTE, NORTH CAROLINA ;NED: DETAILED: PROJECT NO.: FlGURE: BB ARA ST058060 2 Motiva Enterprises LLC - Charlotte North Terminal Outfall 001 Flow/TSS Summary : Month Zoos:: 2004 on ow , {1ds, gallons) TSSe{106,gallons) on, . ow TS_ S (mg/l) January 0.43 ND 0.61 6 February 0.50 19 1.72 8 March 0.77 13 0.94 12 April 0.47 13 0.65 30 May 0.1.3 6 0.28 6 June 0.55 24 2.20 19 July 0.56 19 0.90 28 August 0.33 17 1.11 10 September No Data 1.51 18 October 0.42 10 0.40 22 November 0.31 31 0.65 5 December 0.71 15 0.57 5 Annual Ava 0.47 13.94 0.96 14.08 Attachment C — Soil Data TestAimerica ANALYTICAL TESTING CORPORATION 2960 Foster Creighton Road Nashville, TN 37204' 800-765-0980' Fax 615-726-3404 Client Pangean-CMD (Woodstock) / SHELL (13655) Work Order: NPH1617 9874 Main Street, Suite 100 Project Name: 410 Tom Sadler, Charlotte NC Woodstock, GA 30188 Project Number: SAP 058060 Atm Kylie McCord Received: 08/11/06 08:15 ANALYTICAL REPORT Dilution Analysis Analyte Result Flag Units -------------------------------------------------------------------------------------------------------- MRL Factor Date/Time ------------------------------------- Method Batch Sample ID: NPH1617-01 (SB-1- Soil) Sampled: 08/10/06 09:20 General Chemistry Parameters %Dry Solids 75.3 % 0.500 1 08/15/0610:35 SW-846 6082245 Total Metals by EPA Method 601013 Manganese 302 mg/kg 0.996 1 08/14/06 19:56 SW846 6010B 6082418 Sample ID: NPH1617-02 (SB-2 - Soil) Sampled: 08/10/06 09:30 General Chemistry Parameters % Dry Solids 80.4 % 0.500 1 08/15/06 10:35 SW-846 6082245 Total Metals by EPA Method 6010B Manganese 258 mg/kg 1.00 1 08/14/06 20:00 SW846 6010B 6082418 Sample ID: NPH1617-03 (SB-3 - Soil) Sampled: 08/10/06 09:40 General Chemistry Parameters %Dry Solids 75.7 % 0.500 1 08/15/0610:35 SW-846 6082245 Total Metals by EPA Method 6010B Manganese 740 mg/kg 0.982 1 08/14/06 20:04 SW846 6010B 6082418 Page 2 of 8 ` Jul 24 06 11:43a 1 Anna Tillman 404-486-8258 Y ' p.1 U ITM ST 6'_'FS JEFAFd%,= OF 7M INTERIOR GEOLOGICAL SUIWEY CA'EMICAL ANALYSES OF SOILS AIM OTHER SUWICIAL MATERIALS CF T!Z CONTERI ?ICIIS IPv=1 STATES B Josephine G. Boerngen and Hansford T. Shacklette Open -File Report 81-197 1981 This report is preliminary and bas not -been edited or reviewed for conformity with U.S. Geological Survey standards or nozenclature U IWO 0 Sample LAtl- Long- Oak* Site and Soil bescri,ptions No. State County tulle Rude Colin. i 6CS97850 NC OURKE 35 41 81 38 65 7 US 64 5 1411 W HICKORY; RED CLAY GC197550 NC CHATHAM 35 45 79 59 6S 7 US 64 9 MI I P!TTS9OROJ RED AND YELLOW CLAY GE210650 NC C."AT"AN 35 44 79 30 65 7 US WARD US 15 JkT 2.2 Mi 11 PITISBORO; SOIL NOT DESCRIBED GC210950 WC CLEVELAND 35 23 91 AS 65 ? Rr Z26 .1 Mi W HWY. SE MARTIN MICA MINE; 81100110N SOIL 6CI97150 NC CRAVEN 35 4 ?? 6 65 7 US 17 5 NJ S NEW BERNE; BLACK SAND GC197750 MC DAVIE 35 54 80 30 65 7 US 64 1 Of U "OCKSIVILLE; RED*CLAT GEZI0550 mc DURHAM 36 40 79 0 65 ? J-8S AND' US IC! JCT W EDGE DURHAM; SOIL NOT DESCRIBED GC1973s0 HC EDGECOMBE 35 46 11 37 65 ? AT 42 2 MI SE PINETOPS; GRAY SAND 6098050 NC MAYWOOD 35 29 81 0 65 7 US 19 AT DELLWOOD,l YELLOW MICACE6US LOAN GC0632SC1 mc HOKE 34 513 79 10 70 10 US 401§2 MI E RAEFORD; INTRAZONALJ SANDY* OLD PINE-DECID. FOREST rV-111 4_S NC J011NSfON 3S ze 78 16 6S * 7 US 70 AT SMITHFIELD; YELLOW -GRAY SAND 6CO60258 mc HE Cock. E Neu NG is Is 80 52 73 10 BEAIFLES FORD NO 1*5 Mi N 1-85 At CHARLOTTE) RESIDUAL SOIL ON GRANITE 34 GC197650 NC RANDOLPH 3S 40. 5 1 US 64 2.5 W,._AS1lt8ORO.p'.j1LLOW CLAY WITH QUARTZ Cc 2 1 uIvo 80 a ..MI.. f OF us sz; 84icarom GCOBO350 mc SURAT 36 32 80 31 73 10 AT 105 z2 ht V JCI STATE MOUNTAIN 401 STOUT RESIDUAL ON PHYLLIS& GC2119SO 14C WATAUGA 36 14 91 39 6S 7 US 121 3 81 W UOONE WHERE LINVILLE Clia ROAD GOES HE; 9 HORIZON SOIL GCO84050 fir—Nik's- 46 0 102 27 74 It I Mi E JCI AT A 9 AT 12,, 9.141 E HETTINGER: PRAIRIE LOAN ON BILISTONE GC2416s0 "D BARNES 47 5 98 0 66 8 1-94 Al VALLEY CIfVJ SOIL NOT DESCRIBED Gt2474s0 NO BOWMAN 46 IS 103 ZS 66 6 US 11S I MI N BOWMAN; SOIL NOW DESCRIBED GC247650 no RUHLEIGII 46 4S 100 AS 66 A US 10 to BISMARK; SOIL NOT DESCRIBED GC267050 NO CASS 46 43 97 15 68 8 21 18 1 MI S I Mi I LYNCHBURG; BLACK ORGANIC TOPSOIL CLAY TEXTURE GC267250 No DICKEY 46 0 98 4 65 8 41 1 9 Mi 5 OAXES1 IMMATURE A-[ MDR, PROFILE SOME IRON STAINING fitOSIOSO NO DIVIDE 48 54 103 S 74 8 AT 5 5 Mi V NOONAN; LIGHT BROWN PRAIRIE SOIL 6CO53850 no Dunn 47 20 102 22 74 If JCI AT 200 9 8 3 Mi SW HOLLIDATI PRAIRIE SOIL OVER TILL 6CO63SSD 00 GOLDEN VALLEY 46 AS 101 SS 74 11 AT 16 1*5 Mi No 4 Mi to GOLVA; SOIL ON COLLUVIUM FROM CLINKER BED GC2666SO no GRANO FORKS 47 is 97 23 64 6 US 2 1 MI N EMERADID I Mi S U$2J BLACK ORGANIC TOPSOIL SANDI-SUBSOIL GC266250 No MC HENRY 49 15 fOO SS 64 8 us 2 3 Mi E AND .5 Mi S NORWICH; BLACK CLAY CULTIVATED FIELD GC083650 AD MC KENZIE 47 34 103 49 74 11 LITTLE MISSOURI NAT GRASSLAND; LIGHT BROWN PRAIRIE SOIL GC0113750 NO "C 99"119 A? 24 105 15 74 It Of 85 1.5 NJ NU GRASSY DUTY[; LIGHT BROWN LOAN GC265850 No MC KENZIE 46 6 103 15 69 8 US BS 4 Mi M JCI US 2 6 WILLISTON; SILTY TEXTURE CULTIVATED FIELD 6CO91250 00 MC LEAN 47 30 101 15 74 3 JCI Al 48 A ZOO 3 MI E 916 OERO; LIGHT BROWN LOAN* CULTIVATED ACOAISSO no MORTON 46 53 101 47 74 8 Of 49 1 01 N 1-943 LIGHT BROWN PRAIRIE LOAN GC2665SO NO NELSON 48 0 98 17 68 8 US Z 2 MI E LAKOTA; BLACK ORGANIC TOPSOIL LIGHT SANDY SUBSOIL 6C266150 NO PIERCE AS 22 99 $6 68 0 US 2 1 Mi EAND *S Mi S RUGBY; SILTY TOPSOIL# SANDY SUBSOIL GC2671SO NO SARGENT 46 13 97 30 68 8 CO 00 2 01 SW MILNOR S Mi SW 41 13; DARK TOPSOIL SUBSOIL IRON -STAINS SCO83950 No STARK 46 37 102 20 74 11 AT 6 5 Mi 6 OF HEART RIVER; LIGHT BROWN LOAN OVER SHALE SC247550 NO STARK 46 SO 103 20 66 8 US GS IN BELFIELD! SOIL NOT DESCRIBED GC247156 NO SIUISMAN 46 55 99 20 66 A 1-94 IN MEDINA FIELD; SOIL 1101 DESCRIBED GC266450 No TOWNER 411 24 99 11 68 A US 251 1 MI E MAZA ON CO ADI BLACK SANDY TOPSOIL HIGH ORGANIC GC266950 No IRAILL 47 19 97 25 63 9 CO RD I Mi S m5 Mi W CLIFFORD; SAND AND SILT CULTIVATED GC0811510 No WARD 48 49 102 8 74 6 US S? P Mi E HOMBELLS; LIGHT BROWN PRAIRIE SOIL GC266150 NO WARD 48 It 11011 48 68 9 CO AD 2 MI E AND .5 Mi, S UE1111101.0; CLAYEY TEXTURE WITH GRAVELS GC2659S0 No WILLIAMS 48 19 103 13 68 A US 2 6 Mi W PAT .5 Mi 5 HWVS PRAIRIE SOILS GRASSLAND 6(2660SO N6 WILLIAMS 48 23 103 0 611 a CO 90 ? Mi W IIOGA; CLAYEY KAHL 0 HORIZON. CULTIVATED FIELD GCO411SO Nil CARROLL As 40 71 15 66 10 AT 25 1,1 Mi W WESI-OSSIPEE; SANDY 0 HORIZON ON SANDY TILL GCO399s0 Nil coos 44 16 711 10 66 10 AT 16 8 Oil S ERROL: 8 HORIZON GCO41OS0 Nil GRAFTON 43 ss 72 S 66 10 US A I Ml'E YE51 CANAAN; OLIVE CLAYEY SAND GCO11950 NJ ATLANIJC 39 36 74 IS 72 9 NY 563 .5 NJ 5 GREEN BANK; GRAY SANDY SOIL 6CO32150 NJ CAPE MAY 38 59 74 57 72 9 CAPE MAY FERRY 1103 YELLOW SANDY SOIL �0 LD D q, Cu Table 1.--Location• description, and concentration of elements for samples of s surficfal materiets--COntinue0 Sample fig. F >< Fe 2 GA PPM Go Pp■ fig Pp■ 1 Ppm Kf >< La PON Li PP m M X Mn GC/97650 .017 3.00 30 -- .06 -- 1.S0 9 PPm GC .013 3.00 -- -- 100 27 200 ISO 106SO GCZI0950 .009 7.00 1S Is -- .06 -- 2.60 100 52 .7DO 300 GC214950 .004 7.00 30 -- .10 -- .50 N 13 .500 3.000 GC1971SO .024 .70 5 -- .10 '" . 50 30 51 .300 100 GC19.77SO .010 5.00 20 __ SOB - .35 30 11 .070 100 GC210SSO .004 1.50 10 .11 '17 N 11 .500 10000 6C197350 1C.001 3.00 N -- �Si .-- .6S N 13 .200 700 GC1980S0 .02A J.00 30 __ a 8 .OSO 100 G[g63250 .018 -• -- •01 -- -- 2.00 50 1J .700 S00 6C197450 .044. .70 S -- .03 '- -- -- <S -- -- 00011U2S0 -- .022••• .85 7.0 •-4.26 N 6 .070 100 &C 1976S0 .003 2.00 15 _ .31 S`--N 10 .200 300 6 .D30�`71� GC2108SO .009 7.00 '10 .05 -- .65 a 21 .500 200 GCO®OSSO G[211950 .OSO 7.00 30 1.52 all . 6.0 .11 2.22 N 100 24 an .700 2i000 G[084050 .o28 .070 7.011 1.50 3Q IS -- 1.25 N 18 A SO .500 700 700 GC247850 .021 2.00 1S -- .04 c.s 1.76 N 25 3.000 30O GC247450 .030 2.00 1S -- .19 -' 1.64 30 20 1.000 2.300 GC247650 .035 2.00 1S -- •OT ®- 2.10 50 25 1.000 S00 GC267U50 .033 5.00 20 -- .O6 - 1.75 SO 23 1.000 300 G[267250 ® .011 1.00 T "- .09 -- 1.80 SO 29 1.500 700 }+ GCOf11050 OCO83850 -' -- 1.50 . 10 1.10 .03 .03 <.S 1.80 1.56 30 N 10 12 .300 300 GC083550 .060 1.S0 2.00 f0 20 1.37 .03 .6 1.56 N 14 .300 .300 300 300 6C2666SO .006 1.50 10 .97 •. .02 1.2 1.80 N 2S 2.000 Y00 Gt266250 .020 2.00 t5 -_ .O3 _ 1.20 N 9 .300 300 GCO83650 .OSO 2.00 20 1.34 .05 1.50 1. SO 18 .700 TOO'' GCO83T50 .050 7.40 26 1.26 .04 �7 < 1.71 71 N 2.000 340 GC26S850 .020 3.00 15 .S SO 2S 2S .700 700 GC081250 .040 2.00 10 1.39 .OS 1.80 S0 21 1.500 300 GCo81350 .040 2.00 1S 1.25 .03 .9 1.1 1.80 <30 16 .700 S00 GC266550 .0 3.00 1D -• .OG 05 1.82 <30 2q 1.000 S00 GC266350 .016 16 3.00 9S -- ..06 1.60 c30 16 .700 ISO GC267150 .017 5.00' is -- `- 1.60 lU 20 .700 500 GCOB3950 GC24?SSO .U60 .043 ;.Op 5.00 30 •66 .OS .08 c.S 1.90 1.8c 30 N 23 30 .700 1.S00 S00 700 GC2477SO .105 1.00 15 10 -- -- •05 -- 2.07 SO 26 .700 700 4C2664S0 .016 2.00 15 -- .06 - 1.15 N 11 2.000 1.500 GCI66950 .012 2.00 15 -- .u; " 1.i0 N 12 .500 S00 GCOA115U. 2.U0 iS 1.« .03 '02 -- 1.50 1.40 N it .300 300 GC2661SO .033 3.00 2D -� 66 N 20 .500 S00 GC265950. •.037 2.00 -- .08 -- 1.90 N 28 2.000 S00 .002 2.00 20 0 -- .02 1.50 a 20 2.000 300 6CO41150 .003 30 -- .06 -- 1.70 30 29 2.000 Soo 6CO39950 .017 5.00 30 -- .03 - 2.S0 SO 21 .300 T00 6CO41050 G[061050 .Oil 3.00 3.00 3U .23 AS .95 N 1S .500 Soo 0001195U -- .2U k I.06 .Ot c.S 2.00 SO 16 16 1.ODtl 00 700 Gc03zls0 -- 1.00 5 1.03 .05 1.6 N .0 30 .71 <!0 a .200 300 Attachment D — Groundwater Data GROUNDWATER ANALYTICAL DATA Manganese Motiva Enterprises LLC 410 Tom Sadler Road (Charlotte North) Charlotte, North Carolina Well ID Date Sampled Total Manganese (Ng/L) MW-15 10/25/05 268 12/07/05 71.2 06/22/06 390 MW-16 10/25/05 350 12/07/05 149 06/22/06 1,040 MW-19 10/25/05 1,120 12/07/05 651 06/22/06 620 M W-20 10/25/05 NA 12/08/05 94.6 06/22/06 NA RW-5 10/25/05 1,840 12/07/05 145 06/22/06 740 Method 6010B PASheffiorth Camlina\410 Tom Sadler\Reports\Semiannual\200611st\Tables and Graphs.xls Page 1 of 1 Attachment E — Delegation of Authority Documentation A DATE; NTON"UNW3ER 28, 20 US TO: GEIN R M,NIAINAGER .-DIS-TWOUTION REGIONAL M&NAGE RS NIAL14yiWER OF 11EXUR, UYNIPLEX M . XNAGE RS, TERINTMAL NIANAGERS XNDSLTERTN'TENDENT S (each acting Individulally) DRMN SNUTH, VICE Pnvm)mwLLC SUPpLN", DjSj'R1RU1*lOTN',,AND CONMERCLkI, -AN, ARKETIINC, SUBJECT, "RESPONSMLE OrFICUL" DELEGATION Pursuant to tile, delegated authorities 'Mated to the as Vice President of -Supply, Pist fioA, and CO;Mm6rcial NlarlkMt 9 ribu !I of Motiva Eniffivises LLC ("Compraky) by the President and Chief ENecutive Officer of the CompanyYOU-are berebY authorized and empowered each acting. iqdiViduaI1y, hi the, name and. on behalf of the Comr1any, to the . extent perntittivd. by laNy, �to act on behalf of the Company as a duly authorized representafive concerning certain specific, 011'OrOnmelltal rriattc� 11CCLssary-to the operation of die Compaqy"s business. This diler 4 below gaiion s1r 11 include the matters het out. These I autbod tics,sitalt al*,ays be exercised consistent with the Limited Liability Company A91.'ecinent of the C-016pany .,and policies i . n Uto best interest of the Company anti its o-8vaers as diciated. by. prudent busintssjudgment strict accordance with the letter and spirit of the Company's Code of Conduct and all, current Coiriptiny policie,;'and You fare hercli,-.v authorkedvvith respect to the folioiving watters: Perinit Applications, Amendments, Modifications, 'I'Mosters, ROort and Cither'Inf6rination To the extent permitted bra law, pursuant to flie-United States Enviroadieutal Protection Agcricy,79.pdrikit fegUlatiolls under rddOral . to .1 1 . utes and regutations tulder slate environmental smjwtes, you ,qc,bqr;qby Jelegawd authority to. sitarenvivoi . unental, pernrit- applicati6ns,.reqtiests for permit aniendflIcInts, modifications or tranifers, reports, and other infoiination provided togovermijental agejjcies, in connection with environmental pervnim Delegation to Supervisor In the of the Complex-Mahager, or,Superinteirdent, flte-Sujnrvi5or = perform :he same duties as s - tated albove,%&qth respect to rcpnrt.�,and other information. Scope and subdelegation whic. ar u, slaall siren for those facilities or activities, which arc la,ithin your overal I operational responsibility -and h e appropriate; for your title -and position. You may ftirther deie_P1,tc authority to sign reports and submit in I forina ation to - the extent permitted by applicable law. Please file -or provide theso delegations to the office of the Company's Corporate Secretary Office. rises'LLC Vice President8upply, bistribution, and:Coirdnercial Mariketing