NC0006254_Groundwater Monitoring Report March 2023_20230427

PO Box 604 ▪ Fletcher, NC 28732 ▪ Cell: 828-508-4510

March 28, 2023
Mr. Brett Laverty
NCDEQ Division of Water Resources
Asheville Regional Office
2090 US Highway 70
Swannanoa, NC 28778

RE: Groundwater Analytical Results – March 13, 2023
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina

Mr. Laverty:

On March 13, 2023, Singleton Environmental, Inc. (SEI) visited the Blue Ridge Tissue site located
at 1427 Yadkin River Road in Patterson, North Carolina, to collect groundwater samples from
monitoring wells MW-1, MW-2, MW-3, MW-4, MW-6, MW-7 and MW-8. The depth to
groundwater in the monitoring wells ranged from 5.03 feet in MW-4 to 50.41 feet in MW-2.
Refer to Table 1 for all monitoring well groundwater depths, and Figure 1 for all monitoring well
locations.

All groundwater samples, except for MW-2 were collected using a peristaltic pump connected to a
Horiba U52-2 water quality meter with a flow-through-cell to collect groundwater parameters
(temperature, pH, specific conductivity, dissolved oxygen, ORP, and turbidity). Groundwater
sample MW-2 was collected using a clear PVC bailer.

The groundwater samples were submitted on ice to Pace Analytical for the analysis of 8-RCRA
Metals, pH, ammonia, TKN, sulfate, nitrogen, nitrite and nitrate.

The laboratory analysis of groundwater sample MW-1 detected concentrations of iron and
manganese above the NCAC 2L groundwater standards. The iron was detected at a lower
concentration than the November 2022 analysis and manganese was detected at a higher
concentration than the November 2022 analysis.

The laboratory analysis of groundwater sample MW-2 detected concentrations of barium, iron,
manganese, arsenic, chromium, and ammonia above the NCAC 2L groundwater standards.
Monitoring well MW-2 was dry in November 2022; however, the results are comparable to the
July 2022 concentrations.

The laboratory analysis of groundwater sample MW-3 detected concentrations of arsenic, iron,
manganese, and ammonia above the NCAC 2L groundwater standards. All concentrations were
lower than the November 2022 concentrations.

Singleton Environmental, Inc.

Singleton Environmental, Inc.
The laboratory analysis of groundwater sample MW-4 detected concentrations of total iron and
total manganese above the NCAC 2L groundwater standards. Both concentrations were slightly
lower than the November 2022 concentrations.

Laboratory analysis of groundwater samples MW-6, MW-7, and MW-8 did not detect any
concentrations exceeding the NCAC 2L groundwater standards.

The analytical results are shown on Table 2 and the attached laboratory data sheets.

During the April 2017 groundwater sampling event, AECOM reported a possible sheen on the
groundwater in monitoring well MW-4. During the March 2023 event a sheen was not observed.

The compound levels detected in the groundwater analysis for the March 2023 sampling event
detected relatively lower concentration levels in monitoring wells MW -1, MW-2, MW-3, MW-4
and MW-7 compared to the November 2022 concentrations. Therefore, Singleton Environmental,
Inc. recommends sampling the monitoring wells again in July 2023 to continue tracking the
groundwater concentration and groundwater level trends.

If you have any questions, you can reach me at [phone].

Sincerely,

Chris Singleton, P.G.
Singleton Environmental, Inc.

cc: Dave Hallock, Blue Ridge Tissue Corporation

Attachments
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Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/AirbusDS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and theGIS User Community
Figure
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Site Layout MapBlue Ridge Tissue CorporationPatterson, North Carolina
Legend
Property Boundary
Yadkin River Flow Direction#
Land Surface Elevation Contour (ft above mean sea level)
Monitoring Well Location
Abandoned Water Well#0@A
Well ID Date Installed Total Depth (feet
bls)
Screened Interval
(feet bls)
Top of Casing
Elevation (feet msl)
Date Water Level
Measured
Depth to Water (feet
BTOC)
Groundwater Elevation
(feet msl)
MW-1 02/08/11 11 6-11 1253.71 03/13/23 12.00 1,241.71
MW-2 08/12/09 50 40-50 1323.03 03/13/23 50.41 1,272.62
MW-3 08/13/09 20 10-20 1299.02 03/13/23 20.21 1,278.81
MW-4 08/13/09 15 5-15 1247.23 03/13/23 5.03 1,242.20
MW-5 08/16/11 21 11-21 1285.46 N/A N/A N/A
MW-6 08/06/14 29 19-29 1341.55 03/13/23 28.56 1,312.99
MW-7 08/06/14 24 14-24 1274.41 03/13/23 17.47 1,256.94
MW-8 08/06/14 20 10-20 1253.14 03/13/23 13.57 1,239.57
Notes:
bls - feet below land surface BTOC - below top of casing msl - above mean sea level NG - not gauged
AECOM
Table 1
Monitoring Well Construction and Groundwater Elevations
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina
Sample ID MW-1 MW-2*MW-3 MW-4 MW-6 MW-7 MW-8
Sample Date 03/13/23 03/13/23 03/13/23 03/13/23 03/13/23 03/13/23 03/13/23
Temperature (°C)NS 11.8 N/A 16.70 16.50 15.00 14.80 15.40
pH (standard units)NS 6.70 N/A 6.50 6.20 6.90 6.34 7.10
Specific Conductivity (mS/cm)NS 0.436 N/A 0.73 0.36 0.03 0.12 0.11
Dissolved Oxygen (mg/L)NS 0.00 N/A 2.22 0.60 6.12 3.84 6.28
ORP (mV)NS 81.0 N/A 105.00 187.0 166.00 196.0 79.0
Turbidity (NTU)NS 6.5 N/A 630.00 5.7 3.20 6 3.1
Gallons Pumped NS 2 N/A <1.0 2.5 1.50 2.5 2
Cloudy/Odor No/No No/Odor Cloudy/Odor Cloudy/Odor No/No No/No No/No No/No
Total Barium (ug/L)700 229 2370 250 115 66.7 53.1 13
Total Iron (ug/L)300 21700 70700 32700 18000 110 52.2 170
Total Manganese (ug/L)50 4010 443 4190 1550 11.4 ND 2.9
Arsenic (ug/L)10 ND 14.6 2.6 2.6 ND ND ND
Chromium (ug/L)10 ND 14.8 ND 1.3 ND ND ND
Lead (ug/L)15 ND 5.6 ND ND ND ND ND
Sulfate (mg/L)N/A ND ND 15.7 4.6 ND 2.1 15.8
Ammonia (mg/L)1.5 0.43 17.3 14.5 0.55 ND ND ND
TKN (mg/L)N/A 0.68 17.6 16 0.92 ND ND ND
Nitrogen NO2 plus NO3 (mg/L)N/A ND ND 0.25 ND 0.130 1.1 2.8
Nitrate (mg/L)10 ND ND 0.25 ND 0.130 1.1 2.8
Nitrite (mg/L)1 ND ND ND ND ND ND ND
pH (standard units)N/A 6.5 6.7 6.6 6.4 5.4 6.2 6
Total Disolved Solids (mg/L)N/A N/A 395 N/A N/A N/A N/A N/A
EPA Method 6200B for VOCs N/A N/A N/A N/A N/A N/A N/A N/A
Notes:
Samples analyzed for total and dissolved iron, barium and manganese by EPA Method 200.7
2L Standard - North Carolina groundwater quality standards established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section 0.20
°C - degrees Celsius
µS/cm - microsiemens per centimeter
EPA - United States Environmental Protection Agency mg/L - milligrams per liter
mV - millivolt
NA - Not analyzed NS - No standard
NTU - Nephelometric Turbidity Unit
RCRA - Resource Conservation Recovery Act
Bold samples indicate concentrations above the 2L Standard
*MW-2 purged with disposable bailer, water quality parameters collected from same bail as sample.
2L
Standard
Field Parameters
Analytical Parameters
Table 2
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina
#=CL#
March 24, 2023
LIMS USE: FR - CHRIS SINGLETON
LIMS OBJECT ID: 92656572
92656572
Project:
Pace Project No.:
RE:
Chris Singleton
Singleton Environmental
105 Charlotte Highway
Asheville, NC 28803
BLUE RIDGE TISSUE CORP
Dear Chris Singleton:
Enclosed are the analytical results for sample(s) received by the laboratory on March 13, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 25
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 25
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92656572001 MW-1 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-AARJ
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92656572002 MW-2 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 2540C-2015 1 PASI-AJMH1
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-AARJ
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92656572003 MW-3 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-AARJ
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92656572004 MW-4 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-AARJ
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92656572005 MW-6 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-AARJ
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92656572006 MW-7 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-AARJ
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 25
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92656572007 MW-8 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-AJCM
EPA 350.1 Rev 2.0 1993 1 PASI-AARJ
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Sample:MW-1 Lab ID:92656572001 Collected:03/13/23 10:30 Received:03/13/23 14:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic ND ug/L 03/17/23 07:16 7440-38-203/15/23 09:311.0 1
Barium 229 ug/L 03/21/23 20:16 7440-39-303/15/23 09:315.0 5
Chromium ND ug/L 03/17/23 07:16 7440-47-303/15/23 09:311.0 1
Iron 21700 ug/L 03/21/23 20:16 7439-89-603/15/23 09:312505
Lead ND ug/L 03/17/23 07:16 7439-92-103/15/23 09:311.0 1
Manganese 4010 ug/L 03/21/23 20:19 7439-96-503/15/23 09:3150.0 25
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.5 Std. Units 03/14/23 14:24 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate ND mg/L 03/14/23 22:06 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 0.43 mg/L 03/15/23 12:31 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 0.68 mg/L 03/16/23 05:31 7727-37-903/15/23 20:000.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 03/14/23 14:390.040 1
Nitrogen, Nitrate ND mg/L 03/14/23 14:39 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/14/23 14:39 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Sample:MW-2 Lab ID:92656572002 Collected:03/13/23 10:45 Received:03/13/23 14:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic 14.6 ug/L 03/20/23 21:49 7440-38-203/15/23 09:311.0 1
Barium 2370 ug/L 03/20/23 21:58 7440-39-3 M103/15/23 09:3125.0 25
Chromium 14.8 ug/L 03/20/23 21:49 7440-47-303/15/23 09:311.0 1
Iron 70700 ug/L 03/21/23 20:27 7439-89-6 M103/15/23 09:31125025
Lead 5.6 ug/L 03/20/23 21:49 7439-92-103/15/23 09:311.0 1
Manganese 443 ug/L 03/21/23 20:23 7439-96-5 M103/15/23 09:3110.0 5
Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 395 mg/L 03/15/23 10:4625.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.7 Std. Units 03/14/23 14:28 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate ND mg/L 03/14/23 22:21 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 17.3 mg/L 03/15/23 12:36 7664-41-70.20 2
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 17.6 mg/L 03/16/23 05:32 7727-37-903/15/23 20:000.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 03/14/23 14:420.040 1
Nitrogen, Nitrate ND mg/L 03/14/23 14:42 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/14/23 14:42 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Sample:MW-3 Lab ID:92656572003 Collected:03/13/23 10:55 Received:03/13/23 14:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic 2.6 ug/L 03/17/23 07:32 7440-38-203/15/23 09:311.0 1
Barium 250 ug/L 03/20/23 22:40 7440-39-303/15/23 09:315.0 5
Chromium ND ug/L 03/17/23 07:32 7440-47-303/15/23 09:311.0 1
Iron 32700 ug/L 03/21/23 20:46 7439-89-603/15/23 09:31125025
Lead ND ug/L 03/17/23 07:32 7439-92-103/15/23 09:311.0 1
Manganese 4190 ug/L 03/21/23 20:46 7439-96-503/15/23 09:3150.0 25
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.6 Std. Units 03/14/23 14:31 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 15.7 mg/L 03/14/23 22:36 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 14.5 mg/L 03/15/23 12:40 7664-41-70.20 2
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 16.0 mg/L 03/16/23 05:36 7727-37-903/15/23 20:000.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 0.25 mg/L 03/14/23 14:430.040 1
Nitrogen, Nitrate 0.25 mg/L 03/14/23 14:43 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/14/23 14:43 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Sample:MW-4 Lab ID:92656572004 Collected:03/13/23 13:00 Received:03/13/23 14:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic 2.6 ug/L 03/17/23 07:36 7440-38-203/15/23 09:311.0 1
Barium 115 ug/L 03/17/23 07:36 7440-39-303/15/23 09:311.0 1
Chromium 1.3 ug/L 03/17/23 07:36 7440-47-303/15/23 09:311.0 1
Iron 18000 ug/L 03/21/23 20:50 7439-89-603/15/23 09:3150010
Lead ND ug/L 03/17/23 07:36 7439-92-103/15/23 09:311.0 1
Manganese 1550 ug/L 03/21/23 20:50 7439-96-503/15/23 09:3120.0 10
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.4 Std. Units 03/14/23 14:44 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 4.6 mg/L 03/14/23 23:20 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 0.55 mg/L 03/15/23 12:48 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 0.92 mg/L 03/16/23 05:37 7727-37-903/15/23 20:000.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 03/14/23 14:470.040 1
Nitrogen, Nitrate ND mg/L 03/14/23 14:47 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/14/23 14:47 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Sample:MW-6 Lab ID:92656572005 Collected:03/13/23 11:54 Received:03/13/23 14:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic ND ug/L 03/17/23 07:47 7440-38-203/15/23 09:311.0 1
Barium 66.7 ug/L 03/17/23 07:47 7440-39-303/15/23 09:311.0 1
Chromium ND ug/L 03/17/23 07:47 7440-47-303/15/23 09:311.0 1
Iron 110 ug/L 03/17/23 07:47 7439-89-603/15/23 09:3150.0 1
Lead ND ug/L 03/17/23 07:47 7439-92-103/15/23 09:311.0 1
Manganese 11.4 ug/L 03/17/23 07:47 7439-96-503/15/23 09:312.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 5.4 Std. Units 03/14/23 14:36 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate ND mg/L 03/14/23 23:35 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 03/15/23 12:49 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 03/16/23 05:38 7727-37-903/15/23 20:000.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 0.13 mg/L 03/14/23 14:450.040 1
Nitrogen, Nitrate 0.13 mg/L 03/14/23 14:45 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/14/23 14:45 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Sample:MW-7 Lab ID:92656572006 Collected:03/13/23 12:40 Received:03/13/23 14:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic ND ug/L 03/17/23 07:51 7440-38-203/15/23 09:311.0 1
Barium 53.1 ug/L 03/17/23 07:51 7440-39-303/15/23 09:311.0 1
Chromium ND ug/L 03/17/23 07:51 7440-47-303/15/23 09:311.0 1
Iron 52.2 ug/L 03/17/23 07:51 7439-89-603/15/23 09:3150.0 1
Lead ND ug/L 03/17/23 07:51 7439-92-103/15/23 09:311.0 1
Manganese ND ug/L 03/17/23 07:51 7439-96-503/15/23 09:312.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.2 Std. Units 03/14/23 14:40 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 2.1 mg/L 03/14/23 23:50 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 03/15/23 12:51 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 03/16/23 05:39 7727-37-903/15/23 20:000.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 1.1 mg/L 03/14/23 14:460.040 1
Nitrogen, Nitrate 1.1 mg/L 03/14/23 14:46 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/14/23 14:46 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Sample:MW-8 Lab ID:92656572007 Collected:03/13/23 11:20 Received:03/13/23 14:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic ND ug/L 03/17/23 07:55 7440-38-203/15/23 09:311.0 1
Barium 9.5 ug/L 03/17/23 07:55 7440-39-303/15/23 09:311.0 1
Chromium ND ug/L 03/17/23 07:55 7440-47-303/15/23 09:311.0 1
Iron ND ug/L 03/17/23 07:55 7439-89-603/15/23 09:3150.0 1
Lead ND ug/L 03/17/23 07:55 7439-92-103/15/23 09:311.0 1
Manganese ND ug/L 03/17/23 07:55 7439-96-503/15/23 09:312.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.0 Std. Units 03/14/23 14:33 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 15.8 mg/L 03/15/23 00:05 14808-79-81.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 03/15/23 12:52 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 03/16/23 05:40 7727-37-903/15/23 20:000.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 2.8 mg/L 03/14/23 14:440.040 1
Nitrogen, Nitrate 2.8 mg/L 03/14/23 14:44 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/14/23 14:44 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
761453
EPA 200.8 Rev 5.4 1994
EPA 200.8 Rev 5.4 1994
200.8 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3955029
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Matrix:Water
Analyzed
Arsenic ug/L ND 1.0 03/21/23 19:30
Barium ug/L ND 1.0 03/21/23 19:30
Chromium ug/L ND 1.0 03/21/23 19:30
Iron ug/L ND 50.0 03/21/23 19:30
Lead ug/L ND 1.0 03/21/23 19:30
Manganese ug/L ND 2.0 03/21/23 19:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3955030LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 48.250 96 85-115
Barium ug/L 49.350 99 85-115
Chromium ug/L 49.650 99 85-115
Iron ug/L 12701250 102 85-115
Lead ug/L 48.150 96 85-115
Manganese ug/L 50.150 100 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955031MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92655540001
3955032
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 50 97 70-13098 150ND48.6 49.1
Barium ug/L 50 98 70-13099 1500.0085
mg/L
57.6 57.9
Chromium ug/L 50 98 70-13098 050ND49.5 49.4
Iron ug/L 1250 99 70-130100 112500.14
mg/L
1380 1390
Lead ug/L 50 96 70-13097 150ND48.0 48.5
Manganese ug/L 50 98 70-13098 0500.035
mg/L
84.2 84.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955033MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656572002
3955034
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 50 103 70-130109 45014.6 66.0 68.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955033MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656572002
3955034
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Barium ug/L M150-57 70-130-226 450237023402260
Chromium ug/L 50 99 70-130110 85014.8 64.6 69.8
Iron ug/L M1125031470-130-49 61250707007470070100
Lead ug/L 50 99 70-130107 8505.6 55.0 59.3
Manganese ug/L M1505070-130104 650443468496
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
761502
SM 2540C-2015
SM 2540C-2015
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92656572002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3955190
Associated Lab Samples:92656572002
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 03/15/23 10:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3955191LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 274250 109 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92656373003
3955192SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 339 3351
Parameter Units
Dup
Result QualifiersRPDResult
92656752008
3955193SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 124 1123
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
761199
SM 4500-H+B-2011
SM 4500-H+B-2011
4500H+B pH
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Parameter Units
Dup
Result QualifiersRPDResult
92656572004
3953739SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 6.4 H306.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
761372
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3954805
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Matrix:Water
Analyzed
Sulfate mg/L ND 1.0 03/14/23 20:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3954806LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate mg/L 50.050 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3954807MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656317001
3954808
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfate mg/L 50 99 90-110103 35010.5 59.9 61.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3954879MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656285008
3954880
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfate mg/L M15012190-11096 150121012701260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
761469
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92656572001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3955080
Associated Lab Samples:92656572001
Matrix:Water
Analyzed
Nitrogen, Ammonia mg/L ND 0.10 03/15/23 11:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3955081LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.05 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955082MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92654158003
3955083
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 96 90-11096 0541.3 46.1 46.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955084MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656696001
3955085
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 99 90-11098 05ND5.0 4.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
761471
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3955090
Associated Lab Samples:92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Matrix:Water
Analyzed
Nitrogen, Ammonia mg/L ND 0.10 03/15/23 12:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3955091LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.05 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955092MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656572002
3955093
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 105 90-110106 0517.3 22.6 22.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955094MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656572003
3955095
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 97 90-11097 0514.5 19.4 19.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
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Asheville, NC 28804
[phone]
Page 18 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
761536
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3955389
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Matrix:Water
Analyzed
Nitrogen, Kjeldahl, Total mg/L ND 0.50 03/16/23 05:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3955390LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 9.810 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955391MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656704002
3955392
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 102 90-11095 8100.56 10.8 10.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3955393MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656704003
3955394
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 100 90-110101 1100.72 10.7 10.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
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Asheville, NC 28804
[phone]
Page 19 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
761294
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
353.2 Nitrate + Nitrite, Unpres.
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3954281
Associated Lab Samples:92656572001, 92656572002, 92656572003, 92656572004, 92656572005, 92656572006, 92656572007
Matrix:Water
Analyzed
Nitrogen, Nitrate mg/L ND 0.040 03/14/23 14:28
Nitrogen, Nitrite mg/L ND 0.040 03/14/23 14:28
Nitrogen, NO2 plus NO3 mg/L ND 0.040 03/14/23 14:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3954282LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate mg/L 1.51.5 99 90-110
Nitrogen, Nitrite mg/L 1.01 100 90-110
Nitrogen, NO2 plus NO3 mg/L 2.52.5 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3954283MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656507001
3954284
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 103 90-110103 01.50.26 1.8 1.8
Nitrogen, Nitrite mg/L 1 108 90-110108 01ND1.1 1.1
Nitrogen, NO2 plus NO3 mg/L 2.5 105 90-110105 02.50.26 2.9 2.9
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3954285MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92656507002
3954286
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 97 90-11095 11.50.31 1.8 1.7
Nitrogen, Nitrite mg/L 1 102 90-110103 11ND1.0 1.0
Nitrogen, NO2 plus NO3 mg/L 2.5 99 90-11099 12.50.31 2.8 2.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
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[phone]
Page 20 of 25
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 21 of 25
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92656572
BLUE RIDGE TISSUE CORP
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92656572001 761453 761591MW-1 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92656572002 761453 761591MW-2 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92656572003 761453 761591MW-3 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92656572004 761453 761591MW-4 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92656572005 761453 761591MW-6 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92656572006 761453 761591MW-7 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92656572007 761453 761591MW-8 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92656572002 761502MW-2 SM 2540C-2015
92656572001 761199MW-1 SM 4500-H+B-2011
92656572002 761199MW-2 SM 4500-H+B-2011
92656572003 761199MW-3 SM 4500-H+B-2011
92656572004 761199MW-4 SM 4500-H+B-2011
92656572005 761199MW-6 SM 4500-H+B-2011
92656572006 761199MW-7 SM 4500-H+B-2011
92656572007 761199MW-8 SM 4500-H+B-2011
92656572001 761372MW-1 EPA 300.0 Rev 2.1 1993
92656572002 761372MW-2 EPA 300.0 Rev 2.1 1993
92656572003 761372MW-3 EPA 300.0 Rev 2.1 1993
92656572004 761372MW-4 EPA 300.0 Rev 2.1 1993
92656572005 761372MW-6 EPA 300.0 Rev 2.1 1993
92656572006 761372MW-7 EPA 300.0 Rev 2.1 1993
92656572007 761372MW-8 EPA 300.0 Rev 2.1 1993
92656572001 761469MW-1 EPA 350.1 Rev 2.0 1993
92656572002 761471MW-2 EPA 350.1 Rev 2.0 1993
92656572003 761471MW-3 EPA 350.1 Rev 2.0 1993
92656572004 761471MW-4 EPA 350.1 Rev 2.0 1993
92656572005 761471MW-6 EPA 350.1 Rev 2.0 1993
92656572006 761471MW-7 EPA 350.1 Rev 2.0 1993
92656572007 761471MW-8 EPA 350.1 Rev 2.0 1993
92656572001 761536 761702MW-1 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92656572002 761536 761702MW-2 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92656572003 761536 761702MW-3 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92656572004 761536 761702MW-4 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92656572005 761536 761702MW-6 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92656572006 761536 761702MW-7 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92656572007 761536 761702MW-8 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92656572001 761294MW-1 EPA 353.2 Rev 2.0 1993
92656572002 761294MW-2 EPA 353.2 Rev 2.0 1993
92656572003 761294MW-3 EPA 353.2 Rev 2.0 1993
92656572004 761294MW-4 EPA 353.2 Rev 2.0 1993
92656572005 761294MW-6 EPA 353.2 Rev 2.0 1993
92656572006 761294MW-7 EPA 353.2 Rev 2.0 1993
92656572007 761294MW-8 EPA 353.2 Rev 2.0 1993
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/24/2023 06:21 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 22 of 25
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