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NC0063096_Fact Sheet_20230321
Fact Sheet NPDES Permit No. NCO063096 Permit Writer / e-mail Contact: Gary Perlmutter / gary.perlmutter@ncdenr.gov Date: March 17, 2023 Division / Branch: NC Division of Water Resources / NPDES Municipal Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: ❑X Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers: EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW): EPA Form 2A, three (3) effluent pollutant scans, four (4) 2nd species WET tests. • For Existing Dischargers (Non-POTW): EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: Town of Holly Springs Utley Creek Water Reclamation Facility (WRF) Applicant Address: P.O. Box 8, Holly Springs, NC 27540 Facility Address: 150 Treatment Plant Road Permitted Flow: 6.0 / 8.0 MGD Facility Type/Waste: MAJOR Municipal; 95% domestic, 5% industrial' Facility Class: Grade IV Treatment Units: Bar screens, Grit removal, Activated sludge with anaerobic, anoxic and reaeration basins, Secondary clarifiers, Tertiary filters, UV disinfection, Cascade aeration, Aerobic digester, Solids stabilization, Dewatering, Biofilter for odor control Pretreatment Program (Y/N) Yes, active County: Wake Region Raleigh Footnote. 1. Based on total permitted flow of 0.3 MGD. Briefly describe the proposed permitting action and facility background: The Town of Holly Springs has applied for NPDES permit renewal and submitted a renewal application dated 1/22/2021, received by the Division on 1/29/2021. In the cover letter to the application, the Town made the following requests: NCO063096 • Reduce monitoring frequencies of effluent BOD, TSS, Ammonia and Fecal Coliform; • Remove effluent monitoring of Total Lead; • Remove effluent monitoring of Orthophosphate, or if maintained provide justification; • Reduce monitoring frequencies of all instream parameters; • Provide an opportunity to review the draft permit prior to its public notice. These requests will be addressed in the appropriate sections of this Fact Sheet below. This facility serves a population of — 41,000 residents and operates a pretreatment program with two (2) Significant Industrial Users (SIUs), one of which is a Categorical Industrial User (CIU). The SIUs are Southern Wake Landfill and Seqirus (formerly Novartis Vaccines; 40 CFR Category 439), each with an active Industrial User Permit (IUP) issued by the Town. In addition, a draft IUP was submitted to the Division by the Town for Amgen Inc. in July 2022, and Fujifllm Diosynth Biotechnologies has applied for an IUP with the Town in September 2022. In light of these new industrial dischargers, quarterly monitoring for Chlorides will be increased to monthly in the permit based on additional industrial dischargers and impacts on headworks. Review of the application found it incomplete with the required four 2nd species toxicity reports and Chemical Addendum lacking. These items were received by request on 2/16/2023. The three required effluent pollutant scans were run in February 2018, May 2019 and August 2020; the four 2nd species tests were conducted in November 2019 and February, May and August 2020. Sludge management: Wasted sludge is digested, dewatered, collected in boxes, then picked up by McGill for offsite composting. 2. Receiving Waterbody Information Receiving Waterbody Information Outfall(s) / Receiving Stream(s): Outfall 001 / Utley Creek Stream Segment: 18-7-5.5 Stream Classification: No C Drainage Area (mi2): 0.73 Summer 7Q10 (cfs): 0.11 Winter 7Q10 (cfs): 0.25 30Q2 (cfs): 0.32 Average Flow (cfs): 0.82 IWC (% effluent): 99% 2022 303(d) listed / parameter: No' Subject to TMDL / parameter: Statewide TMDL / Mercury Basin / HUC: Cape Fear / 03030004 USGS Topo Quad: Apex, NC Footnote. 1. The receiving stream segment has no monitoring stations, so no data are available for assessment. Therefore, the stream segment is neither listed in any of the Division's biennial Integrated Reports nor in any 303(d) list as impaired. Page 2 of 15 NC0063096 3. Effluent Data Summary Effluent data is summarized below for the period November 2017 (the current permit effective date) through December 2022. Parameter Units Average Max Min Permit Limit' Flow MGD 2.324 4.561 1.112 MA = 6.0 BOD, summer mg/L 2.0 5.7 < 2.0 MA = 5.0 WA = 7.5 BOD, winter mg/L 2.0 10.1 < 2.0 MA = 10.0 WA = 15.0 BOD removal % 99.2 99.7 83.3 > 85 Ammonia (NH3-N), mg/L 0.16 5.00 < 0.1 MA = 1.0 summer WA = 3.0 Ammonia (NH3-N), mg/L 0.20 2.38 < 0.1 MA = 2.0 winter WA = 6.0 Total Suspended Solids mg/L 2.50 3.0 < 2.5 MA = 30.0 (TSS) WA = 45.0 TSS removal % 99.2 100.0 95.0 > 85 Dissolved Oxygen (DO) mg/L 8.9 10.7 7.5 DA > 7.0 PH SU 8.04 8.39 7.66 6.0 - 9.0 Fecal Coliform #/100 mL 1.2 1300 < 1 MA = 200 WA = 400 Total Residual Chlorine µg/L NA 2 DM = 17 (TRC) Temperature °C 21.6 28.8 13.8 Conductivity µmhos/cm 756 1153 472 Total Kjeldahl Nitrogen mg/L 1.08 3.45 0.20 (TKN) Nitrite + Nitrate Nitrogen mg/L 0.96 4.49 0.08 (NO2 + NO3) Total Nitrogen (TN) mg/L 2.03 6.83 0.35 MA = 5.0 Total Phosphorus (TP) mg/L 0.12 0.63 < 0.03 MA = 0.5 Orthophosphate mg/L 0.08 0.42 < 0.02 MA = 0.27 Total Hardness mg/L 140.6 237.0 89.2 (as CaCO3) Total Chlorides µg/L 78.1 99.3 54.1 Total Lead µg/L 2.6 10.0 < 0.1 MA = 11.1 DM = 285.0 Footnotes. 1. MA = Monthly Average; WA = Weekly Average; DA = Daily Average; DM = Daily Maximum. 2. No TRC data available in DMRs or PPAs; facility uses LTV for disinfection. The highest annual average effluent flow is 2.494 MGD or 41.5% of the permitted flow in calendar year (CY) 2022. Page 3 of 15 NCO063096 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/L of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will beproposedfor this permit action: The Town requested reduction of instream parameters to quarterly in the permit renewal application. The current permit requires instream monitoring for DO, Temperature, pH, Conductivity, BOD5, N143-N, TKN, NO2+NO3, TN, Orthophosphate, TP, Chlorophyll -a and Turbidity at various locations and frequencies (Table 1). Downstream locations D2 and D3 are —1.25 and —2.1 miles below the outfall, respectively. These latter downstream monitoring locations were added to the permit in a modification for the expansion from 2.4 MGD to the current flow tiers in 2012 based on historical concerns of eutrophication in Thomas Millpond and Green Tree Reservoir. 16, Table 1. Instream monitoring locations, parameters and frequencies. Sample Location / Sample Location Description / Parameter(s) Frequency Outfall Geocoordinates U / 001 Upstream 35.64494°N, 78.84963°W Total Hardness Quarterly U / 001 Upstream DO Temperature, pH, Conductivity 3/week (Jun -Sep) 35.64494°N, 78.84963°W Weekly (Oct -May) D1 / 001 Immediately downstream DO Temperature, Conductivity p p H y 3/week (Jun -Sep) 35.64486°N, 78.85276°W Weekly (Oct -May) DO, Temperature, pH, D2 / 1D2 Thomas Millpond Conductivity, BOD, NH3-N, TKN, Monthly 35.64633°N, 78.87128°W NO2+NO3, TN, Orthophosphate, TP, Chlorophyll -a, Turbidity Below Green Tree Reservoir DO, Temperature, pH, D3 / 1D3 Dam Conductivity, BOD, NH3-N, TKN, Monthly 35.64481°N, 78.88473°W NO2+NO3, TN, Orthophosphate, TP, Chlorophyll -a, Turbidity Hardness is monitored upstream only for use in Reasonable Potential Analysis for hardness -dependent dissolved metals and is discussed in the RPA portion of this fact sheet (see Subsection 6.4.). The remaining instream data are treated here. Instream data from submitted DMRs spanning November 2017, the effective date of the current permit, through December 2022, were reviewed. The data were checked against applicable stream standards as well as for effluent impacts, the latter via statistical testing of downstream averages against the upstream average of each parameter using t-test with the level of significance (p-value) set at 0.05. The data are summarized in Table 3 and discussed below. Page 4 of 15 NCO063096 Table 2. Instream Data Summary: averages with ranges in parentheses. *Significantly different from Upstream (U); **Significantly different between sites. Upstream Downstream Parameter, units Standard U D1 D2 D3 DO, mg/L 8.89 8.64* 9.84* 8.73 5.0 (6.96-14.01) (7.52-11.80) (3.76-16.96) (6.05-10.70) Temperature, °C 18.6 22.9* 19.9 18.2 32.0 (2.2-27.2) (8.7-29.9) (9.2-31.9) (7.4-28.6) pH, SU 7.42 8.14* 8.13* 7.76* 6.0-9.0 (6.99-9.17) (7.18-8.45) (7.33-9.31) (7.07-8.60) Conductivity, 91 693 * 598 * 548 * µmhos/cm (45-456) (103-1314) (328-971) (254-928) BOD, mg/L -- -- 2.22 2.25 (< 2 - 3.85) (< 2 - 4.81) Ammonia, mg/L -- -- 0.14 0.14 (< 0.01 - < 0.5) (0.03 - < 0.5) TKN, mg/L __ __ 0.97 (< 0.25 - 2.^ 0.95 (< 0.2 - 2.86) NOz+NOs, mg/L -- -- 0.61 0.58 (< 0.01- 3.68) (< 0.02 - 3.42) TN, mg/L __ __ 1.57 1.52 (0.41 - 5.07) (0.38 - 4.89) Orthophosphate, 0.077 ON, 0.084 mg/L (0.024 - < 0.5) (0.027 - < 0.5) TP, mg/L __ 0.132** 0.098 (0.022 - 0.877) (0.028 - 0.34) Chlorophyll -a, -- 4.3 3.6 40 mg/L (< 1 - 28.9) (< 1- 16.0) Turbidity, NTU -- -- 1 ** 50 (2.22 - 55.7) (1.69 136) Dissolved Oxygen (DO) - DO is in the permit as a parameter of concern for aquatic life. Minima of all stations except D2 were above the stream standard of 5.0 mg/L. Two D2 measurements were below the standard in summer, 2022: 4.69 mg/L on 7/13/2022 and 3.76 mg/L on 8/3/2022. Significant differences were found between the upstream and D 1 and D2, but not D3 with the average at D 1 lower than upstream and that at D2 higher than upstream. Concurrent effluent average DO is similar and does not appear to be affecting the instream DO. Temperature - Temperature is in the permit as a parameter of concern for aquatic life. Maxima of all stations were below the 32°C standard for lower piedmont and coastal plain waters. Significant differences were found between the upstream and D 1 only, with the D 1 average 4.6°C higher. Paired upstream and D 1 measurements revealed increases over the 2.8°C standard increase in 371 sampling events or 83%. Concurrent effluent temperatures appear higher, with substantially higher winter minima, suggesting its effect on the immediate downstream temperature. pH- pH is in the permit as a parameter of concern for aquatic life. Both the upstream and downstream D2 stations had values outside the standard range of 6.0-9.0 SU, all of which were > 9.0 SU. Averages of all downstream stations were significantly higher than the upstream average when statistically tested and show Page 5 of 15 NCO063096 a decreasing trend with distance from the outfall. Concurrent effluent pH on average appeared higher than the upstream, but not downstream averages. Conductivity — Conductivity is in the permit as an indicator of industrial sources. The Town has an active pretreatment program with a growing list of SIUs and potential SIUs. Average downstream conductivity is over 5X that of upstream with averages decreasing with distance from the outfall. Concurrent effluent average Conductivity was higher than the highest downstream average (DI) by over 50 µmhos/cm, indicating its impact on the stream conductivity. Fecal Coliform — Fecal coliform was previously in the permit as an instream monitoring parameter until a modification in 2015. Division instream monitoring guidance for fecal coliform and conductivity (DWQ 2002) allows for removal of fecal coliform monitoring from a permit unless the receiving water is impaired due to coliform or is a Class B waterbody. Utley Creek is neither impaired nor Class B, and the effluent data reviewed have a geometric mean of 1.2 cfu/100 mL with most data below detection at 1 cfu/100 mL. Based on this information, instream fecal coliform monitoring is not required and will not be added to the permit. Monitoring frequencies for parameters in U and D1 are set in accordance with 15A NCAC 02B .0500 and will be maintained in the permit. Additional parameters — In addition to the above parameters, BOD, Ammonia, TKN, NO2+NO3, TN, Orthophosphate, TP, Chlorophyll -a, and Turbidity are required in the permit, monitored in downstream sites D2 and D3 only. Only TP tested significantly different between stations (higher at 132), and several of the parameters are largely reported as below detection (Table 4). No stream samples yielded results above the 40 µg/L standard for Chlorophyll -a, and four yielded results above the 50 NTU standard for Turbidity (one at D2 and three at D3). Most of the elevated turbidity values were since November 2022; recent satellite imagery via Google maps show construction activities just north of D3, suggesting disturbed soil as a source of turbidity at that station. Table 3. Number and percentage of nondetects of additional instream monitoring data among 62 sampling events from Nov. 2017 — Dec. 2022. Parameter D2 D3 BOD 40 (65%) 44 (71%) Ammonia 49 (79%) 40 (65%) TKN 1 (2%) 2 (3%) NO2+NO3 NAN6 (10%) 8 (13%) Orthophosphate 33 (53%) 33 (53%) Total Phosphorus 6 (10%) 8 (13%) Chlorophyll -a 27 (44%) 21 (34%) Trends of recent increase in concentrations were also found in BOD, nitrogen species and Total Nitrogen, Total Phosphorus and Chlorophyll -a, at both D2 and D3. Based on the relatively low concentrations with increasing recent trends, plus the growth in the area, monitoring for these additional parameters will be maintained in the permit. To gain a better understanding of the effluent's impact on the stream, upstream monitoring will be added to the permit for all additional parameters, at the same frequencies as downstream. Utley Creek drains into Harris Lake, a cooling water reservoir for the Harris Nuclear Plant, owned by Duke Energy. DWR lake monitoring station CPFWOC 1 is located in the White Oak Arm of the lake, — 4.15 miles below the outfall. There are no recent DWR data, but the Division receives annual monitoring reports from Page 6 of 15 NCO063096 Duke Energy for the entire reservoir, and data from 2015 - 2019 were available for review. Lake station S2 is in the White Oak arm, at approximately the same location as CFPWOCI. The 2019 report notes that the reservoir is well mixed in the winter months and become trophic to hypertrophic in summer (July - September). The report also notes that nutrient (nitrogen and phosphorus) concentrations appear to increase since 2014. Annual averages at S2 appear lower than those at either D2 or D3 instream sites (Table 4). Table 4. Effluent, downstream (132, 133) and lake (S2) nutrient annual average data. Total Nitrogen Total Phosphorus Year Effluent D2 D3 S2 Effluent D2 D3 S2 2017 2.83 2.13 2.14 0.66 0.15 0.14 0.12 0.05 2018 3.12 2.56 2.62 0.91 0.20 0.20 0.17 0.08 2019 1.60 0.98 1.00 1.10 0.10 0.09 0.08 0.08 2020 1.31 1.30 1.00 0.79 0.10 0.16 0.08 0.12 2021 1.45 1.20 1.05 0.85 0.09 0.08 7 0.06 2022 2.45 1.72 1.77 NA 0.09 12 0.09 NA IF Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): YES Name of Monitoring Coalition: Middle Cape Fear River Basin Association (MCFRBA). Based on site specific concerns, instream monitoring is not waived for monitoring coalition participation. 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): From February 2019 through January 2023 (past 5 years) no limit violations were reported. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 16 of 16 quarterly chronic toxicity tests, as well as all 4 second species chronic toxicity tests, sampled in November 2019, February, May and August 2020. Summarize the results from the most recent compliance inspection: The most recent facility inspection, conducted on 12/19/2022, reported no compliance issues. 6. Water Quality -Based Effluent Limitations (WQBELs) 6.1. Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q 10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): A QUAL2K model was run in 2014 for the expansion to the current flow tiers at the current discharge location. The model did not result in any dilution factors as the receiving stream is a discharge -dominant flow. Page 7 of 15 NC0063096 If applicable, describe any mixing zones established in accordance with 15A NCAC 2B.0204(b): NA 6.2. Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/L for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: Limitations for BOD are speculative effluent limits based on QUAL2K stream model performed in September 2014 and CE- QUAL-W2 lake response modeling performed in 2009 for instream DO protection. The limits for DO was changed from 6.0 mg/L to 7.0 mg/L to be consistent with previous analyses and permits per the Speculative Letter in Holly Springs Environmental Assessment Addendum in December 2014. No changes are proposed from the previous permit limits. 6.3. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/L (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 µg/L) and capped at 28 µg/L (acute impacts). Due to analytical issues, all TRC values reported below 50 µg/L are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: Limitations for ammonia in the current permit of MA = 1.0 / 2.0 mg/L in summer / winter and WA = 3.0 / 6.0 mg/L in summer / winter are based on speculative limits derived from QUAL2K stream modeling performed in 2014 and CE-QUAL-W2 lake response modeling performed in 2009. The speculative nutrient limits were originally developed to protect downstream Harris Lake from excessive nutrient enrichment. A Wasteload Allocation (WLA) was calculated for protection against Ammonia toxicity using the WRF's design flow of 6.0 and 8.0 MGD and the receiving stream's 7Q10 of 0.11 cfs summer and 0.25 cfs winter. Resulting allowable concentrations were the same as the current for the summer, but more slightly protective in the winter at 1.8 mg/L MA / 5.4 mg/L WA for both flow tiers. Ammonia limits are maintained in the permit. The current permit TRC limit is 17 µg/L, to be applied when the plant is using chlorination for disinfection. This facility uses UV disinfection with a backup chlorination disinfection system on site. The WLA used for Ammonia limits also resulted in a TRC allowable concentration as protective as the current limit. No changes are proposed. , 6.4. Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of '/2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. Effluent and upstream hardness sampling is required in the current permit despite its near negligible summer 7Q10 of 0.11 cfs. Average effluent hardness is 140.6 mg/L and upstream hardness is 24.3 mg/L, the latter lower than the default value of 25 mg/L. Therefore, the default value was used in the RPA. Page 8 of 15 NC0063096 A reasonable potential analysis was conducted on effluent toxicant data collected between November 2018 and December 2022. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: None. • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was > 50% of the allowable concentration: None. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was < 50% of the allowable concentration: All reviewed. • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: None. o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: None. No detections were reported among additional parameters analyzed. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. 6.5. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This is a Major POTW, and a chronic WET limit at 90% effluent will continue on a quarterly frequency for both flow tiers. 6.6. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (> 1 ng/L) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/L) and/or if any individual value exceeds a TBEL value of 47 ng/L. The current permit has a Mercury Minimization Plan (MMP) special condition. A MMP summary was submitted with the permit application. Page 9 of 15 NC0063096 Table 5. Mercury Effluent Data Summary. 2018 2019 2020 2021 2022 # of Samples 3 1 1 4 7 Annual Average Conc. n /L 1.4 0.5 0.5 0.5 1.0 Maximum Conc., n /L 2.51 0.50 0.50 0.59 1.84 TBEL, n /L 47 WQBEL, ng/L 12.9 Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required. Since the facility is > 2 MGD and reported quantifiable levels of mercury (> 1 ng/L), the mercury minimization plan (MMP) will be maintained in the permit. 6.7. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: The receiving water has no TMDL or nutrient management strategy as the Harris Lake reservoir it flows into is used primarily as a cooling water source for Harris Nuclear Plant. Nutrient (Total Nitrogen, Total Phosphorus and Orthophosphate) limits in the current permit are based on a nutrient response model developed for discharge to Harris Lake, when the outfall was proposed to be relocated downstream of two impoundments: Thomas Millpond and Green Tree Reservoir, both of which have histories of algal blooms caused by excess nutrients. The model indicated that the lake is highly responsive to phosphorus, in particular orthophosphate. A QUAL2K model was run in 2014 with updated information on the impoundments, namely that Thomas Millpond has decreased in size and depth due to a partial dam break and increased sedimentation, thus reducing nutrient effects. Based on model results that the receiving waters would be protected, the permit was modified in 2015 maintaining the outfall location. Due to evidence of growth in the service area plus recent increases in nutrient concentrations, especially nitrogen, in the effluent and downstream locations (Table 5), current limits and monitoring frequencies will be maintained. In particular, orthophosphate monitoring will be maintained as this form of phosphorus is directly taken up by algae and thus linked to algal blooms. The current permit has re -opener special conditions for supplementary nutrient monitoring, dam modification, and downstream water quality. These will be maintained. 6.8. Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: Holly Springs participated in the 2019 POTW survey of PFAS chemicals, showing detections in multiple parameters, including PFOA and PFOS, as well as 1,4-Dioxane. The Town also submitted effluent data collected in July 2022 as part of the required Chemical Addendum, also showing detections in these parameters. 1,4-Dioxane was not included; the Town stated in the Chemical Addendum: "We currently have no reason to believe any POC, with approved methods, that are not covered in Permit NC0063096 are present in the discharge from the facility." Summary data are in Table 6. Page 10 of 15 NCO063096 Table 6. Influent and Effluent Data of 1,4-Dioxane and PFAS Chemicals. Parameter Influent July 2019 Influent Aug 2019 Influent Sep 2019 Effluent July 2022 1,4-Dioxane, µg/L < 2.0 4.3 10.2 NA Perfluorooctanoic acid (PFOA), ng/L < 10 10 10 24.2 Perfluorooctanesulfonic acid (PFOS), ng/L < 10 12 7.6 4.02 Perfluorohepanoic acid (PFHpA), ng/L 13 21 27 6.09 Perfluorohexanoic acid (PFHxA), ng/L 19 27 37 40.2 Perfluoropentanoic acid (PFPeA), ng/L 19 21 ,.4 31 71.3 Perfluorobutanoic acid (PFBA), ng/L < 10 < 8.2 8 20.2 Perfluorobutanesulfonic acid (PFBS), ng/L j < 9.2 j < 7.2 1 6 22.6 Utley Creek WRF discharges into a Class C waterbody upstream Harris Lake, Class WS-V with a water supply watershed located —17 miles downstream in the Cape Fear River. Because 1,4-Dioxane was detected at concentrations high enough for further evaluation, monthly monitoring for this parameter will be added to the permit. In addition, a permit reopener special condition regarding 1,4-Dioxane based on changes toward limits, monitoring or treatment will be added to the permit. Based on detection of PFAS chemicals reported in the Chemical Addendum, monitoring of PFAS chemicals will be added to the permit at a quarterly frequency. Since an EPA method for sampling and analyzing PFAS in wastewater is not currently available, the PFAS sampling requirement in the Permit includes a delayed implementation until the first full calendar quarter beginning 6 months after EPA has a final wastewater method in 40 CFR 136 published in the Federal Register. This date may be extended upon request and if there are no NC -certified labs. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody.• NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H. 0107( c)(2) (B), 40CFR 122.47, and EPA May 2007 Memo: NA If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B.0226 for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/L BOD5/TSS for Monthly Average, and 45 mg/L for BOD5/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BOD5/TSS included in the permit? YES. Review of BOD and TSS data found only one occurrence of less than 85% removal: of BOD on 7/31/2020 due to a low influent concentration. If NO, provide a justification (e.g., waste stabilization pond). NA Page 11 of 15 NCO063096 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 213.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): YES. If YES, confirm that antibacksliding provisions are not violated: Limits for Total Lead and monitoring requirements have been removed from the permit due to Reasonable Potential Analysis of recent effluent data, including hardness data (both upstream and effluent) yielding results of no reasonable potential of exceeding stream water quality standards. 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 213.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. The Town requested reduced monitoring frequencies for BOD, TSS, Ammonia and Fecal Coliform with justification in the permit renewal application. Effluent data from the past three years (January 2020 December 2022) were evaluated and found all target parameters to meet the criteria. Monitoring for BOD, TSS, Ammonia and Fecal Coliform will be reduced from daily to 2/week. For instream monitoring, refer to Section 4. Page 12 of 15 NC0063096 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Proposed Permitting Actions Table 7. Current Permit Conditions and Proposed Changes 1,2 Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 6.0 / 8.0 MGD No change 15A NCAC 2B .0505 Summer: MA = 5.0 mg/L WQBEL. QUAL2K model WA = 7.5 mg/L No change in limits. performed in September 2014. BOD5 Winter: BAT recommended in Speculative MA = 10 mg/L Monitor 2/week (6.0 Limits Letter in 2014. WA = 15 mg/L MGD only) Effluent data meet criteria for Monitor Daily reduced monitoring frequency. No change in limits. TBEL. Secondary treatment MA = 30 mg/L standards/40 CFR 133 / 15A NCAC TSS WA = 45 mg/L Monitor 2/week (6.0 2B .0406. Monitor Daily MGD only) Effluent data meet criteria for reduced monitoring frequency. Summer: WQBEL. QUAL2K model MA = 1 mg/L WA = 3 mg/L No change in limits. performed in September 2014. NH3-N Winter: BAT recommended in Speculative MA = 2 mg/L Monitor 2/week (6.0 Limits Letter in 2014. WA = 6 mg/L MGD only) Effluent data meet criteria for Monitor Daily reduced monitoring frequency. > 7 mg/L WQBEL. QUAL2K model DO No change in limit or performed in September 2014 and Monitor Daily monitoring frequency. EA Addendum submitted to Pam Behm on 12/17/2014. p H 6 — 9 SU No change in limit or WQBEL. State WQ standard, 15A Monitor Daily monitoring frequency. NCAC 2B .0200 MA = 200 /100 mL No change in limits. WQBEL. State WQ standard, 15A Fecal Coliform WA = 400 /100 mL NCAC 2B .0200. Monitor Daily Monitor 2/week (6.0 Effluent data meet criteria for MGD only) reduced monitoring frequency. Temperature Monitor daily No change State reporting requirements, 15A NCAC 2B .0508. Page 13 of 15 NC0063096 Parameter Current Permit Proposed Change Basis for Condition/Change IF DM = 17 µg/L No change in limit or - Total Residual Monitor daily* monitoring frequency. WQBEL. State WQ standard 15A Chlorine (TRC) *if chlorine or chlorine Revise footnote to ' NCAC 2B .0200. derivatives is added to monitor if chlorination the treatment process is used for disinfection Conductivity Monitor daily No change. State reporting requirements, 15A NCAC 213.0508. TKN Monitor weekly No change To calculate Total Nitrogen NO2+NO3 Monitor weekly No change To calculate Total Nitrogen MA = 5 mg/L No change in limit or WQBEL. Nutrient response model Total Nitrogen Monitor weekly monitoring frequency. for discharge to Harris Lake performed in 2009. MA = 0.5 mg/L No change in limit or WQBEL. Nutrient response model Total Phosphorus Monitor weekly monitoring frequency. for discharge to Harris Lake performed in 2009. No change in limit or WQBEL. Nutrient response model MA = 0.27 mg/L monitoring frequency. for discharge to Harris Lake Orthophosphorus Monitor weekly Correct parameter "Total performed in 2009. spelling to ICIS Parameter Codes spreadsheet, Orthophosphate" 10/12/2022. Monitor effluent and Required to assess dissolved metal Total Hardness instream, upstream of No change limitations. discharge, quarterly Total Chlorides Monitor quarterly Increase to monthly Potential new industrial sources of chlorides. MA = 11.1 µg/L RPA: maximum predicted value < Total Lead DM = 285 µg/L Remove from permit 50% of allowable concentration. Monitor monthly Add monthly monitoring and Based on limited effluent data 1,4-Dioxane No requirement reopener special showing detection, more results are 71 condition needed to evaluate. Add quarterly PFAS No requirement monitoring with PFAS chemicals detected in influent delayed and effluent samples. implementation Downstream No change To provide a background dataset parameters at D2 Monitor monthly downstream; add upstream for comparison with and D3 upstream monitoring downstream data. Chronic limit, 90% WQBEL. No toxics in toxic Toxicity Test effluent No change amounts. 15A NCAC 213.0200 and Monitor quarterly 15A NCAC 213.0500 Effluent Pollutant Three times per permit No change 40 CFR 122 Scan cycle Page 14 of 15 NC0063096 Parameter Current Permit Proposed Change Basis for Condition/Change Mercury Revise language WQBEL. Consistent with 2012 Minimization Plan Special Condition toward maintenance Statewide Mercury TMDL (MMP) Implementation. Electronic Special Condition Update language In accordance with EPA Electronic Reporting Reporting Rule 2015. Footnotes. 1. Limits and/or monitoring frequencies apply to both flow tiers unless otherwise specified. 2. MGD = Million gallons per day; MA = Monthly Average; WA = Weekly Average; DM = Daily Max. 13. Public Notice Schedule Permit to Public Notice: mm/dd/2023 Per 15A NCAC 21-1.0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. NPDES Division Contact If you have any questions regarding any of the above information or on the attached permit, please contact Gary Perlmutter at (919) 707-3611 or via email at gary.perlmutter@ncdenr.gov. 15. Fact Sheet Addendum (if applicable) Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes If Yes, list changes and their basis below: 16. Fact Sheet Attachments (if applicable) • Cover letter to permit renewal application • Four 2nd species test results • NPDES Pretreatment POC form • WET Summary sheet, p. 44 • Compliance inspection report, 12/19/2022 • NH3/TRC WLA calculation forms for 6.0 and 8.0 flow tiers • RPA Spreadsheet Summary for 6.0 and 8.0 flow tiers • Dissolved Metals Fact Sheet Memo • MMP Summary • Mercury TMDL Evaluation, 6.0 and 8.0 flow tiers • Chemical Addendum • Chemical Addendum — Supplemental datasheet • 2019 POTW influent PFAS data • Monitoring Reduction spreadsheet Page 15 of 15 �.f tlnfl, s,e n O II f � rlki+r THE Town OF Holly Sprin"c P.O. sox 8 128 S. Main Street Holly Springs, N.C. 27540 www.hollyspringsnc.us January 22, 2021 CERTIFIED MAIL RETURN RECEIPT REQUESTED Mr. Michael Montebello NPDES Permitting Unit Supervisor 1617 Mail Service Center Raleigh, NC 27699-1617 RECEIVED JAN 2 9 2021 NCDEQ/DWR/NPDES Subject: NPDES Permit Renewal Request — Town of Holly Springs, #NC0063096 Dear Mr. Montebello: This serves as a request by the Town of Holly Springs to renew NPDES Permit No. NC0063096. Enclosed are one signed original and two (2) copies of the permit renewal package as required. The Town's permit expires July 31, 2021. As per NCDENR document "DWQ Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities" dated October 22, 2012, we respectfully request that the monitoring frequencies for BOD5, TSS, NH3-N, and Fecal Coliform be reduced from daily to twice per week. The Town of Holly Springs Utley Creek Water Reclamation Facility is an Exceptionally Performing Facility. For your review, please see attached document, "Justification for Reduced Monitoring for the Town of Holly Springs Utley Creek Water Reclamation Facility NC0063096." In addition, the Town of Holly Springs also requests the following changes be incorporated into the renewed permit: 1. Removal of additional monitoring requirements for Total Lead. Total Lead has been less than detection for the entire permit cycle and should no longer qualify as a reasonable potential concern. 2. Removal of Orthophosphorus monitoring requirement. It is the Town's position that the Orthophosphorus requirement is redundant because of the existence of the Total Phosphorus monitoring requirement. The discharge limitations on both parameters are reasonably proportional to one another, thereby creating the redundancy. If DEQ determines that Orthophosphorus shall remain a monitoring requirement, the Town respectfully requests rationale. 3. Monitoring frequency reduction to quarterly for all instream monitoring requirements at sample locations U, D1, D2, and D3. (919)552-6221 THE TO” OF Hoffy spri 1g,S P.O. Box 8 128 S. Main Street Holly Springs, N.C. 27540 www.hollyspringsnc.us The Town of Holly Springs further requests that a prompt initial review of this application be made to verify that it is complete as submitted and no additional information is needed at this time. Please provide a written response once this review has been completed. A brief email to seann.byrdghollysprin sg nc.us would be ideal. The Town of Holly Springs also respectfully requests that an "owner's" draft of the reissued permit be provided to us prior to public notice for comment so that we may review, and follow up with your office if we note any items of concern. If you have questions or need additional information please contact me at (919) 577-1090 or via email at terry.foster@hollyspringsnc.us. Sincerely, Terry Foster Treatment Plant Manager/ORC Town of Holly Springs NC CC: Kendra Parrish, Director of Utilities and Infrastructure Seann Byrd, Interim Water Resources Director (919)552-6221 aceAnalytical wwwpacelabs.com February 21, 2020 Debra Batten Town of Holly Springs 150 Treatment Plant Rd Holly Springs, NC 27540 RE: Project: Toxicity Pace Project No.: 92463382 Dear Debra Batten: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersvllle, NC 28078 (704)878-9092 Enclosed are the analytical results for sample(s) received by the laboratory on February 03, 2020. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely,, Amanda Payne amanda.payne@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Seann Byrd, Town of Holly Springs Terry Foster, Town of Holly Springs This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, U.C. Page 1 of 24 Document Name: Document Revised; February 7, 1018 I Semple Condition Upon Recelpt(SCUR) Pa e 1 of 2 BCBAR3IyllCBl Document No, Document No,: Issuing Authority: 06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ EdenEl Greenwood ❑ Huntersville ❑ Raleighlo Mechanicsville[] • Client T- Name: r-r WO# : 92463382 �1rProject tE: Courier: []Fed Ex ❑UPS ❑LISPS ❑Client ❑ Commercial []pace ❑Other:_ Custody Seal Present? ❑Yes ®No Seals Intact? ❑Yes EfNo IIIIII62 I IIIII II III Date/Initials Person Examining Contents.zAl '7-ZN Packing Material; ❑Bubble Wrap ❑Bubble Bags ®None ❑ Other Biological Tissue Frozen? Thermometer: p []Yes❑No ®N/A ❑IRGun ID! qly-y-�U7 Type oflem Mwet []Blue ❑None Cooler Temp ('C): � I , 7 - Correction Factor: Add/Subtract ('C) 0.0 � Temp should 6e above freezing to VC Cooler Temp Corrected (°C): I • []Samples out of temp criteria. Samples on Ice, cooling process has begun USDA Regulated Soil (�o N/A, water sample) Old samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, my.. HNn Ie.1..A1ne Ya...all veA o..nl,. O6,.H rive. M- Comments/Discrepancy: of Custody Present? NYes []No ❑N/A 1. es Arrived within Hold Time? �Pes [-]No ❑N/A 2. Hold Time Analysis (<71 hr,)? ❑Yes ❑No ❑N/A 3. urn Around Time Requested? Yes ®No ❑N/A 4. nt Volume? ®Yes []NO ❑N/A S. t Containers Used? e Containers Used? panalysfs: Dyes . & es ❑No ❑No ❑N/A ❑N/A 6. ners Intact? '�(r Yes [IN. ❑N/A 7. ed analysis: Samples Field Filtd?❑Yes No ®H/A B. Labels Match COC? udes Date/Time/ID/Analysis Matrix: ❑Yes ❑No ❑N/A 9. Headspace in VOA Vials (>5-6mm)? []Yes No N/A 10. Trip Blank Pre sent? Trip Blank Custody Seals Present? ❑yes ❑Yez []No No QN/A N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/time: Field Data Required? []Yes ❑No Project Manager SCURF Review: Date: a l )a -I :"t o Project Manager SRF Review: Date: _7- 1IZ IZD Page 2 of 24 Document Name: Document Revised: Febmary 7, 2018 Sample Conditlon Upon Recelpt(SCUR) Page 1 of 2 7C8M8lytlCai Document No.: Issuing Authority: F-CAR•CSS033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Collform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project# , WO# : 92463382 PM: RP Due Date: 02/17/20 CLIENTi 82-Ho11y Spy � Z w n $ E � Z Bi n E � 2 w n E � 2 u m` G N v oO E ry v x Z U E A Z �7 $ E 1✓ n x p m u E 9 L j m y'o a Q u '' c au ar N a `m � 2 q, b E E 1(1 v x e, x m� O E N Z x z E E m E ¢ a Z E > E > a^ arxr, E o z os ; .br 0 > � y g1 R ,`,�, n > a ¢ ? — E � ? E o YI ') ( 1 m V U i o � S 2 E S r o E o N Q 10 u cd, yEi E 1 2 3 4 5 6 7 8 9 SO 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot If •....e .ni .._.�_..__.in _i�_�neu„o f.. wt!f! ,inn rlklnarin Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a cupr v, i 6 ��, in v�i� oe..in.�a�e �nn.n..o..n..._ __...... ......_.._.. _...__ , Out of hold, Incorrect preservative, out of tamp, Incorrect containers. Page 3 of 24 n 'y �. � ;0 All3 c ll (1 y 3 V (G)Grnb(C)Campesllo a n a O N c b =J O Z r h- y5 O N F m 1 u o• a11 Clean WaielAcl Stomnvnlcr �' � n e8 Sediment n C a g gg� Non -Regulatory N of Conlniners S 8 i 3 o Plnssfc Glass �, !n 4 o noo' volume S '- a R �. leo s d 5 ;x::. 4° m RICH u o L Actlle Passmnil > S' Acute MuIIiCone. Chronic PasslPnil Chronic Mnitl-Coot. a a — Q dubia D aamompa y 3 "_ x, Pnlhcnd Minnow u o e MYsid Shrimp � e o N Silverside a• o O IIynllcln a uo O n Chirononurs q 5 TI E/I'RE 0o � o n C J) 3 WBR Mncroinverlchrnlc lD o. m j y 3 o0n g o 0 u v 0 u O � b N 7 G c O I: IT AMMWD LAB W II Page 4 of 24 ?aceA alyficaal. WIR 2018 Laboratory receiving samples: Raleigh Mechanicsville❑ Asheville ❑ EderI Greenwood ❑ Huntersville ❑ }} momCllentName: Project0: Wo# : 92463382 �✓A C) d� �✓ PM: RP Dus Dele: 02/17/20 Courier: FedEx ❑UPS ❑uses pcuent CLIENT: 92-Hoj�Y Sp9 ❑ Commercial apace ❑Other.Ea No Seal Present? []Yes RJNo Sealsintact? t❑]�Y''es tallo pate/Initials Person Examiningeontenty ZO Z-5'-20 Packing Material: ❑ Bubble Wrap I ❑Bubblegags' IgNone El other Biological Tissue Frozen? []yes []No PN/A Thermometer: aF�gOC Typaofha: ffWet ❑Blue []None ❑IRGun10: 1/ J Cooler Temp('C): � • 6 Correction Factor:Add/SubtrAct('C) 0,0 Temp should be above freezing to 6'C Cooler Temp Corrected('C): j ❑Samples out oftomp cdteda. samples on Ice, cooling process has begun USDA Regulated Sell aq N/A, water sample) Did samples originate In a quarantine zone within the United States; CA, NY, or (dteck maps)? DldincludnglHawaes ii and Puerto Ricol?❑YesCe (internationally, Correct Containers Used? Sample Labels Match COC? COMMENTS/SAMPLE DISCREPANCY Person contacted; (]No ❑N/A 16. )kYes []NO ❑N/A I.9. Project Manager SCURF Review: I Project Manager SLIP Review: Date/Time: Field Data Required? []Yes ❑No Date: yr Date:/Z() Page 5 of 24 —' o ri o c a z��s3 A F c 5' o' sV c �.. Q F o w y aO a � I I I \ I y �Dq yC � r; Yv I I I I ql Clemt Nolcr Acl ro n �C�1 � Stormenler a 4 O Sediment a C C Non -Regulatory N of Containers n c 'a a Plastic Glass _ 8. nP Volume P g a Ice G a w o{�u3i� a i ^ M-P _ L a Actne Pass/Pall Y ' Aculc Mulli-Conc, �G Chronic Pnss/Pail ^ z • Chronic Mnlli-Cone. a C. dubia D. ambi tin s a = -ten Z 8 X Pnlhced Minnow = 3 0 3. ` M sid Shrimp d ? '• Silverside rt R R N H nllela Chirononms E ' n e TURF WER q ^ , ey Macminvenebralc lD U � 3 a "— N o ~ � w5 5-9 (0 9 (R1 C) a 9 � O �y ,3o GTf ASSIGNED LAB ID 11 s n O Page 6 of 24 Document Name: Document Revised: February 7, 2018 MAfOICBl Sample Condition Upon Recelpt(SCUR) Page loft Issuing Authority: Document No.: F-CAR-CS•033.111 06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville In RaleighW Mechanicsville❑ Client Name: WO# : 92463382 Project#: PM: AP Due Data: 02/17/20 —Fcyc�l(-'Oct u'yCLIENT: 92-Holly Sag Courier: ❑Fed Ex ❑UPS ❑U P5 " Client ❑ Commercial ,[]Pace ❑Other:_ Custody Seal Present? []Yes go Seals Intact? ❑Yes ONo V" Z'( r Date/Initiau Person Examining Contents:_ 2.4• IV Packing Material:. []Bubble Wrap fallubble Bags None ❑ Other Biological Tissue Frozen? ❑Yes ❑No ❑N/A Thermometer: � O S Type of Ice: kP/et ❑glue []None RR Gun ID Cooler Temp (•C): S. CO / 4Correction Fact . Subtract °C) n �� Temp should be above freezing to VC Cooler Temp Corrected(•C): S.�• ❑Samples out of temp criteria. Samples on Ice, cooling process has begun USDA Regulated $oil (Zq N/A, water sample) Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, Yes Urvo --- Comments/Discrepancy: Chain of Custody Present? �,�(/ . y []No N/A 1. Samples Arrived within Hold lime? yes []NO []NIA 2. Short Hold Time Analysis(<72 hr.)? s []No N/A 3. Rush Turn Around Time Requested? ❑Yes kagi, []N/A 4. Sufficient Volume? Ps No ❑N/A S. Correct Containers Used? -Pace Containers Used? kFjJeS yes []No QNO ❑N/A ❑N A 6. Containers intact? ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? Yes No /A g. Sample Labels Match COC? -Includes Date/Time/ID/Analysls Matrix: Headspace In VOA Vials>S-6mm)? ❑Yes ❑No ❑No ❑ N/A N/A 9. 30. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ❑No /A 61A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Field Data Required? ❑Yes []No Project Manager SCURF Review: V s - y V` Date: Project Manager SRF Review: r Date: 2 w Page e 7 of 24 Document Name: Document Revised: February 7, 2018 Sam le Condition Upon Recei t(BCUR) Page 1 of 2 Document No.: Issuing Authority: dL'BA118I1,r/Cr7I �" F-CAR-033-Rev.06 Pace Carolinas Quality Office 'Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Project WO# : 92463382 pN; AP Due Date: 02/17/20 CLIENT: 92—Holly Spp u 2 2 is C J E E m b 2 i J E m < 9 n J m U v Oa E m V Z V m m a E m A o Z E so o J y E as 3 9 n J a U' a _ n x Q a. el a — e J Q E le a¢ y ¢ m l7 V O a E U' a G E U' a z E 0 0 o>> O E m� U' z E'x l0' U' o>> Q Z A \ E N E a E m E a> x a' m c�} o 1 2 3 J 6 6 7 B 9 10 11 12 PH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservalion adjusted Amount of Preservative added Lot a Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will he tent to the North Carolina DEHNR Cen1fl atlon Office (i.e. Out of hold, incorrect preservative, out of temp, Incorrect containers. Page 8 of 24 • o S 3 O f�a y v my rn N y n T [` I j —�i p.9 u 3� y c. 2 = �. \ .'. (I . f a (C) Cmb(C) Ca,,.,ile j a.Zca_a M — O. O n m ".] 1d 10 O RE 3 oem 4 a b � n .o y I 1 I I I(q1 G• 0 V c'7 v a O I I I o y ^n O 1 I I I I� � a .^°.• 4 M1 g N o ? I I ET < 0 I Clcml \Voter Acl o j � � o m ' Slmmmmcr c h Sediment _ 9 Non-Regulnjcay m' " v of Containers u n 1r. Plastic fi n b Class Volume o Q 5' c, a m n � nIce C zor2 O ;>4 Acute Pnss/foil !u ' Aculc Mulli-Cone. Chronic Pnss/fail 0 o Chronic Mulli-Cone. - n a C. dubia D. ambigun .{ 3 i= O i'C v p1 p^ ^ 3 fadlend h•111111a\Y p p Mysid Shrimp w Silverside '- a a o �° Iiynllcla ro Chironmtus a 7l C WER Nhwot"m alm at -ID R- v i 0 n C9 ig a C g n T. w a b ^ 0 0 El = 5 o •� a S ' a E'ITASSIGNED LAB ID It �J r j Page 9 of 24 �+ Document Name: Document Revised: February 7, 2018 Sample Condition Upon Recelpt(SCUR) Pagel of 2 8CBM2jyfICBj Document No.: Issuing Authority: F•CAR-CS-033•Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville 0 Eden Greenwood ❑ Huntersville ❑ RaleighRl Mechanicsville Client Name: w0# : 92463382 'own O� Hotty S Project#: , r s PM: AP Due Dale: 02/17/20 Courier: ❑Fed Ex ❑UPS [fUSPS' ❑Client ❑Commercial HPace ❑other:_ CLIENT: 92—Holly Spg Custody Seal Present? ❑Yes [9140 Seals Intact? ❑Yes MNo Packing Material: []Bubble Wrap ❑Bubble Bags [None ❑ Other Thermometer: c ❑IBGun ID: C . V Type of ice: ©Wet ❑Blue Cooler Temp ('C): I—) - I Correction Factor: Add/Subtract ('C) Q, Cooler Temp Corrected (°C): L1 Date/Initlals Person Examining Contents: ll" 2'10 Z G Biological Tissue Frozen? []None ❑Yes ❑No INN/A Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil (29 N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, nye� nN •^a wrr Llres UNa Comments/Discrepancy: ody Present? ZYes ❑Na ❑N/A 1. ed within Hold Time? RTurn j1Yes ❑No ❑N/A 2. me Analysis(<72 hr.)? ❑Yes ❑No ❑N/A 3. ound Time Requested? ❑Yes No ❑N/A 4. me? ®Yes ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? Yes Yes ❑No ON a ❑N/A ❑N/A 6. Containers Intact? (Yes []NO ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes []No f9N/A 8. Sample Labels Match CDC? -Includes Date/Time/ID/Analysis Matrix: ti✓ ) [Yes []No ❑N/A 9, Headspace in VOA Vials(>5.6mm)? ❑Yes []NO N/A 10. [Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No Elio mN/A MmIA 11. COMMENTS/SAMPLE DISCREPANCY I ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: bic� Project Manager SRF Review: �'rl Date/Time: Field Data Required? ❑Yes ONO Date: I�LLZI 1-0 Date: ���Z'.lit La Page 10 of 24 Document Name: Document Revised: February 7, 2018 . BCBfjRd7�j/fjCBj Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Document No.; Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project # WO# : 92463382 PM: AP Due Date: 02/17/20 CLIENT: 92-Holly Spg e Z a m n J a E m Z a m n J u a E m Q 2 n J U a E m 2 2 w n J n c `a m .. V 0. y O N a E m n 0 Z n pE m O Z ¢ 2 N u a E m n o z y a yE� m m N _ °' t ° E a 3 m J E a m a v a a E a a a V a ¢ E a v x a �_ E ¢ `a a V n o x `w ¢ E a Dp Z E ¢ E ry �, a G p¢ > E o z O O > E > z n O E > ¢ m O E o Z. .. o Y g ''g V-i >> Q x > J. �' ^ I z ♦n = n ,� E a a z y = h E— < d rJ of O s Z Z. a pE a y y c E o Z = = in E z 9 v n a ¢ E 1 L 2 3 4 S 6 7 8 9 10 IN11 12 PH Adjustment Log for Preserved Samples Sample 10 Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lotx Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ji.e. out of hold, Incorrect preservative, out of temp, Incorrect containers. Page 11 of 24 =� 5in2 o• � 0 3 ^ y T r" �-• ,� w -� — � un�•-3n v � (C)Creb (Cl Comaoeile hl O m ` 2 g � z gto N �ia o N o O ✓• 3 lT a C 7 CN o 3 - o •� e I I I I ��, I • ,o y ej � � I I I 1 I I I I In �I•�, @y e o. w In 'a '� a a O n, I I I I / ICI.• n ^' ti O Clean%Ya(er Act OStormwater o g h Sediment A 3 Non -Regulatory CC I IN of Cou(amers Plastic Glass a p Y VOIIIIIIC a A a Ice `a cS CCc i7'zi� 4n IA J 4o x9ro _ e Passtrail > m ' nbiaW ;\Aculemulli-Conc. biguRnd •w* o Z Minuolyd Shrimp Silverside rs'• II allele a o V. O Chironmaus u ^o E O 9 TIEURE w El C WER N gv_ i Macroinvericbralc I n iv o 3 i3 3 w v 3 & W � R w O• w N N 9 - oli O_ v G J iR5 S 0 0 51 ul b N j ETF ASSIGNED LAB ID II s W e� 0 I~ Page 12 of 24 (604) B77.6942 . PN( (004) 077.0930 P.D. Box 1W4, Greenville, CC 20606 4 Cruflsman Courl, Greer, SC 29650 Ceriodaphnia dubia Survival and Reproduction Test EPA-821-R-02-013 Method 1002 Client: TOWN OF HOLLY SPRINGS Facility: UTLEY CREEK NPDES #: NCO063096 Test Date: 04-Feb-20 Laboratory ID #: T55801 Test Reviewed and Approved By: Robert W. Kelley, Ph.D. QA/QC Officer Certification #E87819 Test msulh presented in this report conform to all requimm ms of Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NELAC, conducted under NELAC Ccailication Number E87819 Florida Dept. of Health. Included results pertain only to provided samples. Page 1 of 6 NCDENR Certification # 022 Page 13 of 24 Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date 17-Feb-20 Facility: Town of Holly Springs - Utley Creek NPDES# NCO063096 Pipe # 001 County. Wake LaboratoryPerforming Test: X Comment. Signature of Operal in Responsible Charge Signature of Laboratory Supervisor MAIL UKIGINAL TO North Carolina Cer'odaohnia Chronic Pass/Fail Reproduction Toxicity Test CONTROL ORGANISMS # Young Produced Adult (L)ive (plead Effluent% TREATMENT 2 ORGANISMS 1 2 3 #Voung Protlucetl [H24Adult (L)im (D)ead 6 7 8 9 10 pH isl sample 1st sample 2nd sample Control 1 7.7 8.1 7.8 8.3 7.6 8.1 Treatment 2 1 8.0 8.5 7.9 8.8 8.0 8.6 sled and start and start end D.O. lst sam le isl sam la 2ntl sam le Control Treatment 2 LC50/Acute Toxicity Test (Mortality expressed as %, combining Environmental Sciences Branch Div. of Water Quality N.C. DENR 1621 Mall Service Center Raleigh, North Carolina 27699-1621 L IL IL IL IL IL 1 02-Feb-20 Iculated t=-0.6798 itical Value= 2.508 Reduction= -1.9% 0% Control 21.9 Control 0% malmenl2 22.3 Treatment ] enlml CV 7.4% PASS FAIL %3rtl Brood 100% X Test Start Date 04-Fab-20 Sample 7 04-Fab-20 Grab Comp Duration 1st 2nd Sample 1 1 1 X 24hrs. T. Tax Sample 1 1 X I 241fim. Dilution Sample Sample Hardness (mg/L) 84.0 Spec. Cond. (pmhos) 30 5599 5t Chlorine(mg/L) <,05 <,05 o Modality st.Wond starVend LC50 = % Method of Determination Control 95% Confidence Limits Moving Average Probit HI9h Conc. % Spearman xarbar ROther pH D.O. Organism Tested Ce/ioda hnia di. bia DEM Form AT-1 Page 14 of 24 Page 2 of 6 STATISTICAL ANALYSIS RESULTS Facility: HOLLY SPRINGS NPDEW NC0063096 Sample ID: EFFLUENT GTTN T55801 Date: 04-Feb-20 Laboratory: Certification M NCO22 I Exp. Date; 11/1/2020 Survival Data 7 Day Survival Test Used: FISHERS TEST Control 100% Test Statistic: P= 1.000 Effluent 100% Critical Value: P= 0.01 PASS: The effluent does not reduce survival of the test organisms. Reproduction Data Ram Data Test for Normality Mean youngifemale Std. Dev. - Test Used: Shapiro-Wilks Test: Control 21.9 1.62 Effluent 22.3 1.37 W: 0.965 Critical Value: 0.884 nalysis for Differences in Reproduction Test for Homogeneity of Variance Test Used: Equal Variance t Test. Test Used: F Test Calculated t= -0.68 F= 1.40 Critical Value— 2.51 Critical Value— 5.32 The data are homogeneous In variance PASS: The effluent is not chronically toxic. Page 15 of 24 Page 3 of 6 Control Mortality and Reproduction by Test Day i 2 3 4 5 6 7 a Total source rap R10 1-23 1 +5+8 9 22 T4 1.24 2 +4+7 10 21 GG91-22 3 +3+8 11 22 191-23 4 5 +6+11 24 1171-22 5 +4+7 13 24 N10 1-23 6 +3+8 12 23 V71-24 7 +3+9 9 21 HH101-2 a +5+7 10 22 H61.23 9 4 +6+8 18 Et 1-24 10 +4+8 11 23 JJ4 1-22 11 +3+9 10 22 WO 1-24 12 5 +7+9 21 13 N/A 0 14 N/A 0 15 N/A 0 16 N/A 0 17 N/A 0 18 N/A 0 19 N/A olMean 20 N/A 01 21.9 90 % Effluent Mortality and Reproduction by Test Day 1 2 3 4 5 6 7 e Total R10 1-2 1 +5+7 9 21 T4 1-24 2 +4+7 12 23 GG9 1- 3 +4+8 12 24 19 1-23 4 4 +6+10 20 117 1-22 5 +5+8 9 22 N10 1-2 6 +3+9 11 23 V71-24 7 +4+9 12 25 HH101 8 +4+8 10 22 H61-23 9 +3+9 10 22 E1 1-24 10 1 1 +4+7 1 1 11 22 JJ4 1-2 11 +4+7 12 23 W6 1-21 12 4 +7+10 21 0 13 N/A 0 0 14 N/A 0 0 5 N/A 0 0 16 N/A 0 0 17 N/A 0 0 18 N/A 0 0 19 N/A o Mean 0 20 N/A 0 22.3 rena led AM JG JG AM AM JC JC JC 11-Feb-20 F. Ilme led Sren OIMB PM 0]:]O PM 0 BPM 0&OS RM 0]]s RM OR:19 PM f0:19 RM JC Now :tem "° Old Wrap. °C 24.7 25.3 25.2 24.8 24.9 cowl New lama.°c 24.6 24.5 Page 16 of 24 Page 4 of 6 n �(W0 Y'W DO u 10, IF CII EIY'I CI9NDISSW.LLE1 � N U 0. E 5 r ,. U r❑n p Zr J W qN W _ y p �` E E 11i N 1uy '1ypp�' O U u E oil W E lau- J Ql nllt.lgal.lanlll O,lnlllrg ION, 8 � El q ,a SIIll10Il0.11g� ,h l 2 c u a all!slnnl!S a C M � G7 a dulPyg P!sdlN _ Hnlouu!4V ,v o 8 a Plmlpo5 �. v H o N unWilflau yj u n!gnp'D _ - 'nuuJ-AIIgN apmulp !III.IFSSIIIj alllu,lll7 � G � 'DIIO�-IIIIIInI Bllla\! .� C 6 IIII��SS0113111n\V --.�. 03 6l OII a u �VZO�� xSS^�1 v x G N � nl111110� a g \ SAID E g n!Isu!d V c n siaupuu03. ,!n 6 w q ,Caoluln5ay-u0N V V N U o 0 IuaunPaS 2 .IOIDAMAOIS InW.lalury\ unaID F' U ii o 2 — � I I I I I I I I I E V N S I I I I E o W N v i o O .^ '1 pO A V OCCC C ts y h Y r T O w �L m N Q YO+ O F ' — 3 2 9 4 � O u p � � o N o � w Ki ai T Pd L1-. A N q 4 N 3 o1llminluJ (J)4uu0(D) '� 0 'O E r 3 E `1 E .Ei C] P 1 p0924e o Al 9 I/❑I EIVI CI.INDISM1.I.3 N b �u � a � VN G o s ,•CUE E 6 v QI nln)q�laanuloaoulAl 21AM_ y O4 91LU91'I' E c�� SIIl1101111.II11;J f.° n � p u0 ,ao y :IpIS.lOA1!S .a Z d f11111.u1S pls,fp� ,� O 1 � 9 !�. ,� o Ei moun!IN p11�41141 '>G F� kl � � � "pp E H O o w c7 � w o m nn5lAum'Q E Illc!Ilp'� Ec IPU/ssn�1 onm•14D X � s •� g •ouaD'!Iln!N �Uloy .i Img/ssIld 01111V .! O n adsag MHO ��i�v/n� n1 fl N P a O1111110A p eSSu1D E upsuld u` 1: u S.laulnpmD to it z ] 0 fi � ,C101111115ay-LION Ulawipag a° � .1o111A11111U1S � IDV.ta)ury11nre1D a ^� I I a I� I I p1 0 .a LI I I o N I I I 1 E u q W y a ^y F- p o 1= QQ o E N O p N VI 10 J l[' Q u pz ^lls�dl�ly (a)m•1�(n1 '� cr-'T _. � h a, m 6 4 � a� N Z� i a E a nl a rn i-1� a O N P g' ✓bAO o U W to ti n nI O F o` w age E,)'onvFnlmuln. P.O. BOX "1 t,414, Greenville, 5C 29b06 (E64) B77.6942 . FAX (864) 977.6938 4 Craftsman Court, Greer, SC 29650 Fathead Minnow Survival and Growth Test EPA-821-R-02-013 Method 1000 Permit Renewal Second Species Testing Client: TOWN OF HOLLY SPRINGS Facility: UTLEY CREEK NPDES #: NCO063096 Test Date: 06-Feb-20 Laboratory Sample ID #: T55801 CD Test Reviewed and Approved By: Robert W. Kelley, PhD. QA/QC Officer Certification #E87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Cenificetion Number E87819 Florida Dept. of Health. Included results pertain only to provided samples. Forbad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR Certification # 022 Page 19 of 24 Page 1 of 6 ..nr naym•rvuu-em emcrau anuu rvnmrow rvlW11-wncemr.'am Ies[ Facility: Town of Holly Springs - Utley Creek NPDES # NC0063096 Pipe #: 001 County: % i.a�4✓/s�J" t. MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Test Initiation Date/Time 02/06/20 % Eff. Rapt. Control Surviving # Original # Wt/original (mg) E-22.51 Surviving # Original # Wt/original (mg) F-45.01 Surviving # Original # Wtloriginal (mg) 75 01 Surviving # Original # Wt/original (mg) 90.0 Surviving # Original # Wt/original (mg) 100.0 Surviving # Original # Wt/original (mg) Water Quality Data Control pH (SU) Init/Fin DO (mg)rL) Init/Fin Temp (C) Inif/Fin High Concentration pH (SU) Init/Fin DO (mglL) Init/Fin Temp (C) Init/Fin Sample Collection Start Date Grab Composite (Duration) Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) Chlorine(mg/L) Temp at Receipt ( C) / 12:30 PM Avg WUSurv. Control 0.6898 2 4 4 10 1 10 10 1 10 10 1 10 10 1 10 0.6350 1 0.6230 0.6180 1 0.8830 9 10 9 9 10 10 9 9 0.5640 0.5580 0.6822 0.7533 10 10 10 10 10 10 10 10 0.4280 0.6510 0.5580 0.7200 10 10 10 10 10 10 10 10 0.5520 0.6120 0.6120 0.6990 10 1 10 9 10 10 10 10 10 0.5390 1 0.6390 1 0.5870 1 0.7020 10 10 10 10 10 10 10 10 0.5960 0.7540 0.4830 0.7270 % Survival 100.0% Avg Wt (mg) 0.6898 % Survival Avg Wt (mg) 0.6394 % Survival 100.0% Avg Wt (mg) 0.5893 % Survival 100.0% Avg Wt (mg) 0.6188 % Survival Avg Wt (mg) 0.6168 % Survival 100.0% Avg Wt (mg) 0.6400 Test Organisms Cultured In -House X Outside Supplier Hatch Date: 02/04/20 Hatch Time: _ Day 0 1 2 3 4 5 6 7 7.6 / - 7.7 / 8.2 1 7.8 / 7.8 1 7.7 / 8.0 1 7.7 / 7.9 1 8.1 / 7.7 1 7.9 / 7.4 ----/ I 8.1 / - 8.2 / 7.3 7.3 / 6.3 8.1 / 7.6 8.0 / 7.3 7.5 / 6.7 7.6 / 13.5 ----/ 6.6 24.7 / - 24.6 / 25.0 24.5 / 25.3 24.6 / 24.8 24.7 / 25.0 24.6 / 25.3 24.5 / 25.2 ---- / 25.5 n 1 2 ..1 a 5 R 7 8.0 / - 1 8.3 / 8.4 1 7.9 / 8.2 1 8.1 / 8.6 18.3 / 8.3 1 7.8 / 8.0 8.0 / 7.9 1 ----/ 6.1 9.1 / - 8.0 / 7.0 9.0 / 6.5 8.0 / 7.7 8.1 / 7.0 8.9 / 5.6 8.2 / 6.4 ----/ 6.7 25.0 / - 124.7 / 25.0 124.8 / 25.3 124.8 / 24.8 124.7 / 25.0 124.8 / 25.3 124.7 / 25.2 1 Dilution H2O Hardness (mg/L) 82.0 Alkalinity(mg/L) 57.6 Conductivity (umhos/cm) 307 Survival Growth Overall Result Normal no yes ChV >100.00% Hom. Var. es Yes NOEC 100.0% 100.0% LOEC >100.00% >100.00% ChV >100.00% >100.00% Method Steel's Test T-Test Slats Survival Growth Cone. Critical Calculated Critical Calculated 23% 10.00 16.00 2.41 0.68 45% 10.00 18.00 2.41 1.36 75% 10.00 18.00 2.41 0.96 90% 10.00 16.00 2.41 0.98 100% 10.00 18.00 2.41 0.67 DWQ Form AT-5 (1/04) Page 3 of 6 g )o q 86ed s .bzj; 6 d N N, 5 ro ro b b (!1 0 p _ pp 3 a (G)Grna (C)Cmnpmila 0 N o' � n 7 � } & 9L �. o �• C °�c•a Q yJ Inv WO a ❑ O O tA o_ 1 F a 1 I I I 1 I I , In o ry n 0 I I I 1 I art' � U. O I I I 1 I 0 o sRn Clean Wnler Slorn»valer q, u'n Sedinicot S y 3 Non -Regulatory C C 11 or Containers a. Plnstic n 'o Class y 3 c Volume m t� Ice 'O HCora O Acme Pnss/1>uil 6 Acule Multl-Conc, �G Chronic Pnss/I°nil o Chronfe Muftf-Coto. o - 0 X C.<hlbin D. amitigtm H B o o S X, f§Inteml Polinuoty o . 8 fl 9, y t Mysid Sbrim t • Z? w S � $Ilyemide F' 3 rt �� b N I-lyullnht ro N p• a p `» Chlrononnts o. El r --. WEIR h-0ncminvcrlclo mo I tJ 0 �l S g R go, ✓G. w rn � e liTT ASSIONED LAB ID 11 bi 4Z JO �Z a6ed g JO Z 96ed peso )ou lP )sal-tl/N PPPO=O L'bZ dwel rypmlu00 'aslm aylo PalOu sselun swsryeBl OL aney sdm lltl sluewwo0 m xo-tl-•++bda Poylaw)+el AtlOZZ BS I' elw+ln SZ D. dw+l rom APOIIISI 4 4011 I p+olegwgl I-OSZ wnlon t+Pi Iw 006 aaatl9P C% q Pgwawngn 0UZ/OE4 JSHNI jol+m uopnlla 000N +d.tlt+al 1WOOL b00E6 awp woq oaN OZ-geH-60 I-P woq'oaN OHd S3lVHd3Wld wslueaaotsal OP RN P19 PePa1S Wd of:ZI aw11 Pal a Pets oZ-gej qa ales Pal BPate Z gtuoN ON N.aQdN 1NAmAAA aldwae SONIHdS AllOH Pa110 00 IOOSSl EM gjo g a6ed EO C} C� ry 'a (C)CrnD (C)Cmnpndla I ° n � ^7 y n ry_ � •ice o e o tL b �` q � 0 6' � �• � I.— � �; o c 4 G• 0 z r-or� N V' l � - c � w I I I I R »• cZ atO 1 I 1 I �• 1 I I I Clean Water Act ro o• ^ Slormwaler ry a Sediment 3 cNon-ReRnlntory ( f/ or Containers 0 0 a '?<. 11I11slic Glass iy Et c Volume 0. Ice a \ ma -- Acute Pass/Fail Aculc Moill-Cole. X Chl'onie Puss/Fail P a Chronic mlulu-Cone. - , R. nmbibuo .I n = tq X o Fnlhend minnow o Mysid Shrimp 'r6• ,n2 SilvomIde o � y 111 liynlleln � Clilmnomus a 0 n n o. 9 TIE/1'RE —_ WER a 57 a 1 �. o Macroinvertebndo ID = 7 3 13 3 by C Q o R n V N 5 5 ' o rya Q, ri V N e ® F PTASSIGNED LAB IDII �, goo g do g 96ed o°Zc� d ,y 3 ,^o fit` ey .� .�, v C': •-r� m �' 7 N 0 3 o A y b w� by 3 b e rh, N y (C)Crna (C)Cmnpnrha �' n 'vi. 't e �7y pry d 6 fn q y� o a hoc ? N ro o rl''1 o a tt f z i y i a d L tA o r c� �. a. S• R a G o O o a 9 E ✓ n e. 1 o n M I I I I a o rn n A Ca I I I I e A� v p,p I I I I Ir� na s c a6 Lq e Z U. I I I I 1� N c o z I I I I I o. $, Clean Wnter Act ,y SI°rmwoler p an Sediment = c. 9 Non -Regulatory c io Tr tv {lol'Conlainers Plastic n N R c C _ Class Volatile Q o 0 a 7 Ice � a R 'i � ov 4`n� 4gsoro es o. y. 7e; Acute Pass/Inil r S Acute Adult( -Cone. ?G Chronic Pnss/l§IiI e a' a o Chronic Nlulli-Cone, - n — n C. Aubin D. ambigun .I � p�G Pnlhcad Minnow o Mysid Shrimp a� Silverside - 0 0 b Hynllclo ro Chh'onomus ry � "I'IC/I'RE nv 3 c Pa^ WRR Macroinvcdcbraw I a a it 9 n nC �✓ o � Elo ry. C e KN 11 N• W •o c ? O o g' a ry B N j p^ G•I'•I'ASSIGNGD LAB ID It ry • J W �J laceAnalyfica( www.pacelabs.com May 19, 2020 Debra Batten Town of Holly Springs 150 Treatment Plant Rd Holly Springs, NC 27540 RE: Project: TOXICITY Pace Project No.: 92476030 Dear Debra Batten: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersvllle, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on May 04, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is attached to this report in its entirety. The test results provided in this final report were generated by each of the following laboratories within the Pace Network If you have any questions concerning this report, please feel free to contact me. Sincerely, l/�. -Pµrl Amanda Payne amanda.payne@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Seann Byrd, Town of Holly Springs Terry Foster, Town of Holly Springs REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 Laboratory receiving samples: AshevilleEl EdenO Greenwood[] Huntersvilfe'❑ RaleighE Mechanicsville❑ Client lllI-entName: WO# : 92476030 Uwn U•F Ao 114 S/2/'iWPr*ct# Courier: ❑Fed Ex ❑UPS ❑USP v Client II I II' II IIII II I II I III ❑Commercial �C]Pace ❑Other:_ 92476030 Custody seal Present? ❑Yes �KNo Seals Intact? []Yes MNo Date/Inklab Person Examining Contents: Z RI Parking Material: ❑Bubble Wrap []Bubble Bags faillone ❑ Other Biological Tissue Frozen? Thermometer: ❑yes Do ®N/A ❑IB Gun ID: Type of Ice: wet ❑Blue ❑None Coaler Temp ('G):.6. v Correction Factor: Add/Subtract('C( —(,, Temp shouldbe aMve freezing to 6'C Cooler Temp Corrected rC(: S y 4ymp!esout ofiemp criteria. Samples Was, moBngprocmz has begun USDARegulated Soil (94 N/A,xatersampie) ' Old samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? L Time SuNiclent Volume? G5,Y'ea ❑No ❑N/A 5. Correct Containers Used? 9Y. [IN. ❑N/A G. -Pace Containers Used? MY- rlw, rIWA Sample Labels Match CDC? 1M Trip COMMENTS/SAMPLE DISCREPANCY QYes [IN. ❑N/A 19. Did mmpfasodgWtg OCM a tarelgr scarce (Intematlamily, mdudfneHavnd and Paean Ricol? rlYas nNo Lot 10 of split containers: CLIENT NOTIFICAT:ON(NESOLUTION Person contacted: Date/Time: Reld0au Requhed? ❑Yes ONO Page 2 of 23 Project Manager SCURF Review! Date: =Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Excepnew voA, Conform, TOC, Oil and Greece, ORO/8015 (water) OOC, I LHg **Bottom half of box is to list number of bottle. Project WO# : 92476030 PM: AP Due Date: 05/18/20 CLIENT: 92—Holly Spill _$c• �E CJ E 1 a �d E E a- E .l E O n �EE ai �FF Q ,an 3 8 p, Q E z rV m O > qJE E 4E t7E a S yoI 1� o p 4 Il 12 13 �a 5 6 7 B a 10 ll u PH Adjustment Log for Preserved Samples Sample 10 Type of Presanialdia pH upon receipt onto presemd.n adjusted Time preserva0en Amcunt olPresemtivo lot} adjusted added u..a, n...u.. n[uua r.mn-mnn nfnn Il.a. Page 3 of 23 V..rs. pah�nn�-wham Ie a Al ...--, aM,11l a NMh Carolina compliance samples, a copy m .ni. rv......... —..... „, mg 33 0 W R Cn m d n C. rS.' c o 6 C) 2 7 -i.. M 0 0 u — m » ^ (C) Crnb(Q Comymile a. n "ZJ m — F y'e E'. p c s o rn y N I I I 1 ^ o c I I I I o Z I I I I I Cleml Wn(cr Acl o' a Slornmater g p a Sediment n a M d a Non -Regulatory Hq Hof Conlainem n Plnslic F Q ' o, Volume a> Ice ri rt zz bops^ Q u x„ o QQQ O Acote Pass/Pnil @� Amu. Mulli-Cone. 6 f1 '� Chronic PnsslPnil Chronic Mnlli-Colic. C. dubia D. ambigun H 3 8 o^ Pnthend Minnow u 3 v yMysid Shrimp 4 n S! tk R Silvorside o R I'lyallela .e o = O 1 Chirmlomus j TerRE IWER ^,0 3 CI Mocroinverfcbmic I fi n n an I:IT ASSIGNEDLA6 ID/' Page 4 of 23 ;aceAnalyttcal Sample Receiving Non -Conformance Form (NCF) Date: S >���z J Evaluated by: Z I [torWkorder x okorder/Login Label Here or List Pace Client:/ Number or MTJL Log -in Number Here 1. If Chain -of -Custody (COC) Is not received: contact client and if necessary, fill out a COC and indicate that it was filled out by lab personnel. Note issues on this NCF. 2. If COC is incomplete, check applicable Issues below and add details where apuronriate: Collection date/time missing or I Analyses or analytes: missing or I Samples listed on COC do not match samples incorrect clarification needed received (missing additional etc.) Sample IN on COC do not I I _ match sample labels Required trip blanks were not received Required signatures are missing Comments/Details/Other Issues not listed above: Ibl 61;1-4 J,d noi- Per- All 2,AA �q.:,w �n GoG, 3. Sample integrity Issues: check applicable issues below and add details where appropriate: Samples: Condition needs to be brought to Samples: Past holding time lab ersonnel's attention details below Preservation: Improper Temperature: not within acceptance criteria (typically Samples: Not field filtered Containers: Broken or compromised 0-6C Samples: Insufficient volume received Containers: Incorrect Temperature: Samples arrived frozen Samples: Cooler damaged or Custody Seals: Missing or compromised on compromised samples, trip blanks or coolers Vials received with improper heads ace Samples: contain chlorine or sulfides Packing Material: Insufficient/Im ro er Other: Comments/Details: 4. If Samples not preserved properly and Sample Receiving adiusts PH, add details below: Sample ID: Date/Time: Amount/type pres added: Preserved by: Initial and Final H: Lot # of pres added: Sample ID: Date/Time: Amounlftype pres added: Preserved by: Initial and Final H: Lot If of pres added: Sample ID: Date/Time: Amount/type pres added: Preserved by: Initial and Final H: Lot If of pres added: F-ALL-C-01 1 -rev.00, 05Ju12O18 Page 5 of 23 Laboratory receiving samples: Asheville 0 EdenO Greenwood[] Nuntersvitfe ❑ RaleighE MechanicsvilleQ Client Name: W0# : 92476030 Own OC 80/jz Project: S r,�l� PM: RP Due Date: 06/18/20 Courier: QFed Fx Uun LJUSPS 'U El commercial 1409ce 1JCM r:_ Client CLIENT: 92—Holly Spp rystodpSeal Present? Des qNo Seals Intact? 01'es ONO _ Date/InitlaVason Fxandning Content': Zr'rlT .`J'L'Z�r Packing Material: []Bubble Wrap - QBubble Bags None El other SleloglcalTLcsue Frozen? Thermometer G P []Yes ONO ZN/A (]Bieun ID, Typaof low ®Wet Dim QNone Cooler Temp ('Cj: , y. Z Corractlon factor: Add/Subtract ('C) — Yl. I Cooler Temp Corrected rCjs v . _ Temp should be above firming to 6'C ❑Sampwout oftemp rdtera. samptes an ire, Moungprorers USDA has tegua Regulated Soil (� N/A, xater <a-mple( old sampfes arlglnate in a quanntlne zonexithfn the united States: CA, NY, or SC (check naps(? old samples oeouta tam a ramign warre llntemeoimy, rlY„< Flu., Short Correct Containers Used? Sample labels Match CDC? COMMEWS/SAMPLE DISCREPANCY Myer LJHo [fN/A 1 5. OYU QNo ON/A 6. ea ONO EIWA Oev QNo ON/A 7. OYes ON. WWA 6 (.Ores ON- QN/A 9. wr tat ID of splk containers• Ci INUIItIG1T ON/RESOLUTION Person contacted: Date/Time: Held Data Required? OYn []NO Protect Manager SCURF ,-RReview: protect hlanaeer !PF Data: Page 6 of 23 4- a 9 U 'Check mark top half of box if pH and/or dechlorination is verNled and w(thin the acceptance range for preservation samples. Eueptlons: VOA, Corsform, TOC, Oil and Grease, DRO/8015 (water( 00S tLH9 "8ottam half of box Is to I(st number of bottle Projects WON: 92476030 PM: AP Due Date: 03/18/20 CLIENT: 92—Holly Spp c z Q 0 Z 2 Z 6 t5 n v u u v V 3 m a. a aE a m a 3 m iy y c c c n _2 a a a m a n 9 o E c { E A O O o o $ n h > J > S gJe E Ev` E gg E E E a a E Y E E E E —a, : E E >> PH Adjustment Log for Preserved Samples Sample ID Type of Preservallve pH upon receipt Oats preservation adjusted Time preservation adjusted Amount of Pmserntive added Lot Page 7 of 23 Vote: 'Nheneverhere fs a diatrepancraffecting ,Yarth Carolina mmpnance vmples,a<apv arms,n,m n�n,.,.��. w+m norm �armma usm.ncn„n�n�•• n... o��o t m N d 2 = 0 -' 3 n 3 a N `< (G) Gmb(C) Cmnpmhe (�. 0 3 F> n n z o c r• Mk zq�R � p IJ w IJ Jv � 8 a _y ¢ 3 .&� N m O o = rN e - vi y yo P' c � 9a I I 1 I tl 1CT _ e b 'm Q `O N� x I 1 I I 1 1 1 1 IC Iry n c^ I I I I P � I I I I 1 Ir� S c. Clean Water Act Slmmwaler p rS Sedimcnl c tan Z! 3 Non -Regulatory C c Nor Containers n Plastic Clings E ` Volume a ICC ] C � rt `��zorE 3 n G Acule Pass/Pail a Acutc Multi-Conc. Chronic Pnsslfail a o' Chronic Mnili-Conezz �- ` C. dubia D. ambigua y 3 = C N o O v' g Fnlhcnd Minnow 0 a 3 0 0 �I Mysid Shriml t1i a`, Silverside a'• , o R e ti Id nllela G ro o In o Q Chironamus j w 3 C lam+ WER hdncroinvertebraw ID R O L N 4R 9' o c El ^ S n d fyY� � w ^m N ^ 5 rl o S §. 3 o e 'o A u g v G'Il'ASSIGNED LA6ID I! Page 8 of 23 Document No.: Lsso/ngAuthonty: :aralinas Duartty Office Laboratory receiving samples: Asheville 0 Eden[] Greenwood] Huntersvfife [] ffalelghjQ' MachanlosvilleEl Client Name: wo# : 92476030 ' Tel,,-'- -Y� ROUX Swl'r-ry ProJec PM: AP Due Date: 05/18/20 Courier []Fed Fx QuPS ❑Commercial fPace SPS �ptpv_ CLIENT: 92-Holly Spg Custody Seal Ffesent? Dyes JRNo Seals intact? Dyes ONo '` DateQnit61s 1ersen FxaMnington[enlssz — S•�T-Lo Parking Matedal: []Bubble Wtap - []Bubble Rags [gNane D other SlologlcalTIssus Frozen? Thermometer. /J � ,,,� Dyes []No EN/A OIBGun ID: Q / u!-05 - Type o/lie: . Wet ORlue ONone CoolerTemp rc): , 3 1 Correction Factor: Add/Subtract VC) — Q Temp should be abase Cooler Temp Corrected (•CJ: i _3 freezNgto 6'C ❑SamP�outoftemp mieda.5ampfescn Ice, ro.tlng prorest hube¢un USDA Regulated Soil (K) N/A water sample) Dldsamptes Originate in a quarantine zone within the United Oates: CA, W, or SC (check maps)? Short HaldTbne Anatysis(42 hr.)? ®1'ea Oxo EIWA 11 Rush Tum Ammost Time RenunMn,R n,._. rvu_ M... .i Correct Containers Used? Sample labels Match COC? COMMENTS/SAMPLE MSCREpANCy ) Yes QNo ON/A 16, PYe. QNo ON/A 1 9. 10. a faralgn source Iintemadamgy, Field Data Required? []Yes []No Lot ID of split containers: WENT NOTIFICATION/RESOLUTION Person contacted: Date/T1me: Project.Manager SCURF Review: Date: Project Mena... SRF R.,dmu• e..,,.. Page 9 of 23 *Check mark top half of box lf pH and/,kn��aw Project,`�O$: 2�7�§�@ wk�mw_ �.¥� _m _a PM: AP o Date: e z _#. VOA, _mTor, Off and _mm (water) CO; U.Hg CLIENT: s kBvs _ half & box m_ list number abottle k� \ / / \ } f a 4 } { } } { E E E EE EE ! k k/}{\}!))}/k%}$}} §.�||>>>3; aLU aAdjustment Log for Preserved sp� Sample +w__.r__.___•_ed . . ___ \_ _ __ �- m I i mwo,a �o Y n (G) Grnb(C) Cmnneslle n b i i= w J tll �i n m m a 0 3 o E S m 17 n ° rNi c� I 1 I I O Clean lVnlcr Acl ro Stormnnter o, Sediment c h g C C Non -Regulatory „ i( UP COI11nInerS n Plastic Class C 0 Volumc a N � � n r^, Ice o�^ S R"3.Rr0 0 �q / \ Acute Pass/Foil On ` Acldc Mulli-Conc. a \ .. Chronic Pnssmnil n Chronic Mufti -Cone. — C. dnbic D. nmbigml y n 3 g N a, m 3 g 6 Pnlhcnd Minnow o `7 :! a °o � m m Silverside - I yallela ro o' c'o O Chiroucmus G ^ _ n TIMIT WERS Nlncroinverlebrnle ID a it v n` C 0 z o c c 3. n N N W n 7 N 6 v n e o 3 n 0 a � a 'o n b � a u 7 ,°3 I: I'I'ASSIONGb LAB 1D 11 c. ^ r, U N n M Page 11 of 23 ET.-anIntin,, P.O. Box 16414, Creenv Ile, CC 29606 (E64) B77.6942 , 17AX (064) 677.6930 4 Craftsman Court, Greer, SC 29650 Ceriodaphnia dubia Survival and Reproduction Test EPA-821-R-02-013 Method 1002 Client: TOWN OF HOLLY SPRINGS Facility: UTLEY CREEK NPDES #: NCO063096 Test Date: 05-may-20 Laboratory ID #: T56433 C DUBIA Test Reviewed and Approved By: 41 Robert W. Kelley, Ph.D. QA/QC Officer - Certification #E87819 Test results presented in this report conform to all requirements of Forbad Rostampour Laboratory Director SCDHEC Certification #23104 NELAC, conducted underNELAC Certification Number E87819 Florida Dept. of Ficalth. Included results pertain only to provided samples. Page 1 of 6 NCDENR Certification # 022 Page 12 of 23 Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date 14-May-20 Facility: Town of Holly Springs - Utley Creek NPDES# NCO063096 Pipe # 001 County: Wake Laboratory Performing Test: X Comments Sigifature of OperaKr in sponsible Charge X Signature of Laboratory Supervisor MAIL ORIGINAL TO Environmental Sciences Branch Div. of Water quality N.C. DENR 1621 Mall Service Center Raleigh, North Carolina 27699-1621 North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results Calculated t=-0.6393 Critical Value= 2.508 CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 %Reduction= -2.8% #Young Produced 21 19 19 25 23 17 22 25 %Mortality Avg. Reprod. Adml (L)ive (D)eae [HE L L L L L L L L 0% 21.2 Control Control Effluent % 90.0% 0% 21.8 Tmamum[2 Treatment Control Cv TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 a 9 10 11 12 11.5% #Young produced 1 22 1 21 1 20 1 23 1 20 24 22 22 24 1T 23 23 %3rd Brood PASS FAIL Adult (L)iv. (D)ead L L L L L L L L L L L L 100% X Complete This for Either Teal Test St.aWts Collection (Slart) Date 05-May-20 pH lataemple ample 2ntlsample sample 03-May-20 Sample 05-May-20 Control 7.8 8.0 7.8 8.0 7.8 8.2 Sample T�ce iDu,,t on) Treatment 2 1 8.2 8.4 7.9 8.6 crab comp DureUon 1st 2ntl Sample 1 X 24hrs. Tox Tox Sample X 29hrs. Dilution Sample Sample D.O. sled and start and start and lst sam le lst sam la 2ntl sam la Hardness (mg/L) $1.6 Control 7.9 7.9 7.9 7.9 7.7 7.6 Spec. Cord. (pmhos) 312 000 000 Treatment 2 8.8 8.1 8.2 8.2 9.1 7.8 Chlorine (mg/L) <.05 <.05 Sample Temp. at receipt VC) 0.4 0.4 LC50/Acute Toxicity Test staNend steNend Control High Cone. pH D.O. Page 13 of 23 Page 2 of 6 STATISTICAL ANALYSIS RESULTS Facility: TOWN OF HOLLY SPRINGS NPDESN NC0063096 Sample ID: EFFLUENT ETra T56433CDUBIA I Date: 05-May-20 Laboratory: Certification it: NCO22 I Exp. Date: I1/l/2020 Survival Data 7 Day Survival Test Used: FISHERS TEST Control 100% Test Statistic: P= 1.000 Effluent 100% Critical Value: P= 0.01 PASS: The effluent does not reduce survival of the test organisms. Reproduction Data Raw Data Test forNonnality Mean young/female Std. Dev. Test Used: Shapiro -Wilke Test: Control 21.2 2.44 Effuent 21.8 2.01 W: 0.966 Critical Value: - 0.884 Analysisfor Differences in Reproduction Test for Homogeneity of Variance Test Used: Equal Variance t Test. Test Used: F Test Calculated t= -0.64 F= 1.48 Critical Value— 2.51 Critical Value, 5.32 - The data are homogeneous in variance PASS: The effluent is not chronically toxic. Page 14 of 23 Page 3 of 6 Control Mortality and Reproduction by Test Day 1 2 3 4 5 6 7 8 Total source I rep R3 4-23 1 +3+7 11 21 X6 4.24 2 +4+5 t0 19 1114-22 3 +3+9 9 21 B8 4-24 4 +3+6 13 22 J4 4-23 5 4 +7+10 21 7 4-24 6 +2+8 9 19 113 4-22 7 +3+6 10 19 F10 4.24 8 4 +9+12 25 GG84.29 9 4 +B+11 23 9 4-24 10 +3+7 7 17 KKB 4-29 11 +3+8 11 22 E7 4-24 12 3 +10+12 25 13 N/A 0 14 N/A 0 15 N/A 0 16 N/A 0 17 N/A 0 18 N/A 0 19 N/A o jMean 20 N/A 01 21.2 90 % Effluent Mortality and Reproduction by Test Day 1 2 3 4 5 6 7 8 Total R3 4-23 1 +3+7 12 22 X6 4-24 2 +3+5 13 21 1114-22 3 +4+7 9 20 B6 4-24 4 +3+8 12 23 A 4-23 5 3 +7+10 20 W7 4-2 B +4+8 12 24 113 4-22 7 +3+7 12 22 F10 4-2 e 4 +9+9 22 GG6 4- 9 4 +e+12 24 A9 4-24 10 1 1 +3+7 1 1 71 17 KKIS 4-2 11 +3+9 11 23 E7 4-24 12 4 +8+11 23 0 13 N/A 0 0 14 WA 0 0 15 WA 0 0 16 N/A 0 0 17 N/A 0 0 18 N/A 0 0 19 N/A o Mean 0 20 N/A ol 21.8 renew fed JC JG JG JC JC AM AM AM End DaQO 12-May-20 me (ed 6reneW Old tem . °C 24.7 10'.N AM 25.1 D>SD PM ID:]9AM AM 25.1 25 24.9 caavol New t.mp•c 24.6 24.5 Lab# T56433 C DUBIA Dllent TOWN OF HOLLY EFFLUENT MC0063096 a N 5 ate 05-May-20 ime 03:30 PM d By AM Test Organism lCeriodaphrea dubla Neo. born date 04-Ma -20 Neo. born time 1700-2200 Test Type INCCPF than Water Dllor MHSF Uma f Cow.Cow. WC 90 3rd BROOD Test vessels 30 ml Test volume 15 ml Incubator# 1 LI ht 16108dk initial Temp-C 24.8 Setenastrum 0.05 m1 IAT 0.05 ml Test method Er.s21e-D2-on;laa2 II Commante II Page 4 of 6 Page 15 of 23 f m u a 11 CII fIV'1 CIeINDISSW.LLEI �. n w F .O h U � liTl 5 O l' Si a Pi u N a }pd 8 N •tii, kr y u o 0 15 d E o F © CII 11HM qq IF Bll,l/B I.L 6 N U •� a�� snuwun.pyJ E 'x" o Cl p a � apls.lanllg .� � u k` V (IllIL11IS Ill., :b O nwull1w pnallpld nn9lgtwl'p h 43 w o N 14<II1P ;� E W — I 'a11n7-gllty�l alllu,lll� e e u Ipinl/ssu,l aplonlp rouop-lgnlN aUmV .� c Inld/ssutl a111aV _O �G fl-I ryry Z55 > m �1 P LpL SS�AO —AA�Ae B u v a`. aal P o p C 011llllOA a n SSUID uogsuld o 's saouppop do II j D slolulll5all-IION U luanllpas °i aalnnutlIDl$ C o u, •� a loV.1olum uvolJ U =' c i V ••yy��44II I I I I g c Ei I\tll I I I I Z .d � pp v •a — WW b_0 W I I I I I W u v ^1 79 E n ! 5 of C N & a c P 'Q 'nL' '^o 0 0 1=1 Q V 1 N N U.°.i n' e 6 F outodmuJ lJ)9uaD (Ol V 4 S `O E r Fn h a o o F, 9Ei u19E o V rage o of ti W' MY Nal [IV'I (13NDISSW,1,.1.%I U a N o 0 F .n — a U e u 4' -• Q C N `J o F E Sr F H y CII a111XIIIAaA111RIn111A1 p a iRld/81.1. snwrnlo.gy� ' a N O c .p ,o 11111III4I.1 M 4 o = �b .�` F. u d allIFJOAII$ p• m I-0 r V I .p y � tt— III Ji�IAI O 8 � C. A\olllll �\J I)IIa1lIII;J � � � !7 1' � W o IIIL 1(Illlll'n F IIIQIII)'3 _ ° •a110�•IIIII�I aI110.111J � �"• e IIIL,I(Fslld altlll.11l7 U •� vno3•I6nIN 1010V •et llll;J(SSllll 01111V is a u a nal VE auuyoA C a ._ F E t ssolp allsold u u v � ] svaupll000 Jo/1 ••� ,CaWnp19a21-uoH E C n loaus mol.Ia11IA\IIIAOIf ? f' C C O d IaV.10)UM 1111.113 O •' I I I i I n v v v `71 I I I I W u' rn y I I I I I I I I I I N E �ti 41 0 �d E W o e^ L N d > e S w .� F� O u o 2 R a y In r_ o1RuAnluJ iJ)4�^ol0) `J \ E 4 E •-. 'C w a U W in rn �• v°i v1 1 ) .fir 2J' [J � `�' � Page 6 of 6 E eVrantawlaint. P.G. Box 16414, Greenville, SC 28606 (E64) 877-6942 . FAX (864) 817.6938 4 Craftsman Court, Greer, SC 29650 Fathead Minnow Survival and Growth Test EPA-821-R-02-013 Method 1000 Permit Renewal Second Species Testing Client: TOWN OF HOLLY SPRINGS Facility: UTLEY CREEK NPDES M NCO063096 Test Date: 05-May-20 Laboratory Sample ID #: T56433 PYROMELAS Test Reviewed and Approved By: V Robert W. Kelley, Ph.D. QA/QC Officer �Certification W87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept. of Health. Included results pertain only to provided samples. Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NCDENR Certification # 022 Page 18 of 23 Page 1 of 6 Facility: Town of Holly Springs - Utley Creek NPDES # NC0063096 Pipe #: 001 County: Wake Signature of Operator in Responsible Charge MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699.1621 Test Initiation Datetrime 05/05/20 / 03:30 PM % Eff. Repl. 1 2 4 Control Surviving # Original # Wt/original (mg) 22.5 Surviving # Original # Wt/original (mg) 45.0 Surviving # Original # Wt/original (mg) 76.0 Surviving # Original # Wt/original (mg) 90.0 Surviving # Original # Wtoriginal (mg) 100.0 Surviving # Original # Wtoriginal (mg) Avg Wt/Surv. Control 0.7037 Test Organisms 4 Cultured In -House 10 9 10 10 10 9 10 10 0.7130 0.6467 0.7200 1 0.7350 10 1 10 10 1 10 10 1 10 1 10 1 10 0.6040 1 0.4900 1 0.6300 1 0.6610 10 1 9 10 1 10 10 1 9 10 1 10 0.6410 1 0.6411 0.6720 1 0.6780 10 10 10 9 10 10 10 9 0.7060 1 0.7990 1 0.6910 1 0.6567 9 1 10 9 1 10 9 1 10 1 9 1 10 0.5867 1 0.6750 1 0.6333 1 0.7170 10 1 10 10 1 8 10 1 10 1 10 1 10 0.8590 1 0.7710 1 0.5840 1 0.6250 % Survival 100.0% Xe Outside Supplier Avg Wt (mg) 0.7037 Hatch Date: 05/04/20 % Survival 100.0% Hatch Time: Avg Wt (mg) 0.5963 % Survival 100.0% Avg Wt (mg) 0.6560 Survival 100.0% Avg Wt (mg) 0.7129 % Survival 100.0% Avg Wt (mg) 0.6530 % Survival Avg Wt (mg) 0.7098 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH (SU) Init/Fin DO (mg/L) Init/Fin Temp (C) InittFin High Concentration 0 1 2 3 4 5 6 7 pH (SU) Init/Fin DO (mg/L.) Init/Fin 7.7 / - 7.8 / 7.7 7.7 / 7.5 7.8 / 8.1 7.6 / 7.7 7.8 I 7.6 7.8 / 7.6 ----/ 7.6 7.9 / - 7.7 / 6.9 7.9 / 6.6 7.7 / 7.0 7.6 / 6.2 7.6 / 6.3 7.8 / 5.4 ----/ 6.5 24.7 / - 0.0 / 25.5 24.5 / 24.2 24.4 / 24.7 24.4 / 24.6 24.5 / 25.0 24.6 / 25.3 ---- / 25.1 8.1 / - 8.2 / 8.2 8.0 / 8.1 8.2 / 8.2 8.1 I 8.3 8.0 / 8.0 8.5 / 8.4 ----/ 8.2 8.3 I - 7.9 / 6.6 9.1 / 7.1 7.8 / 6.8 8.6 / 6.5 8.0 / 6.1 7.4 / 6.0 ----/ 6.8 Sample 1 2 Collection Start Date Grab Composite (Duration) Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) Chlorine(mg/L) Temp at Receipt ( C) Dilution H2O Hardness (mg/L) 81.6 Alkalinity (mglL) 60.6 Conductivity (umhos/cm) 312 Survival Growth Normal no Hom. Var. es Yes es NOEC 100.0% 100.0% ChV >100.00% >100.00% Method Steel's Test T-Test Overall Result ChV Slats Survival Growth Cone. Critical Calculated Critical 23% 10.00 18.00 2.41 45% 10.00 18.00 2.41 76% 10.00 18.00 2.41 90% 10.00 18.00 2.41 100% 10.00 16.00 2.41 Calculated 0.90 -0.18 ninin c.,..., er_a 141nnt Page 2 of 6 Leb# T56433 P.PROME client HOLLY SPRINGS Samp1e10 EFFLUENT NPDESU NC0063096 County Month 5 Start S fed Data 05-May-20 Start S fed Time 03:30 PM Started 6 fed By JZ Test Organism P.PROMELAS Neo. born date 04-May-20 ban. born time 9:30-11:001VIT Tea Type NCCU Nunn" Water MHSF 4124C Units for cons % %3fd BROOD Tostvessels 400.1 Teet,volume 150 ml Incubator# 1 Li94d i61t/6dk InlRFI Temp°C 25 Artemlz 0.1 2z Ea Testmothod EPA9ai-R-02L13:1000 Comments All reps have 10 organisms unless noted otherwise. Control ire temp 247 D=Dead N/A -Lost or not used Page 3 of 6 Page 20 of 23 0 u ME m � v P (11 41V'1 CIRNDISSV.I.Lfl n F .�y b UV U b O E v O 3 Q ry U iy r E O U E O ^J Y N olAelgalAanu!aonW CII o, � N U e 3 ail.1/i:1L6 snulouu.ggD 'T a 9,0 P aI11SA0A!Ij N ,n •u a E Awwq!nl puayuli Z ungiqull•p g ti 4 w mgnP'p E u rouo,')-!IPIW oploallD B e u pn�!Issnl! oµm.u�� •auoD-!IIIIIN 01110V ❑ bi IIII:!/fiSlll! ollla�/ O L yy ,r,eA.SCEG ^erg m AI x o - . u � F u v 001 a G F c alnll!OA a 'u C ssnlD ' .E E of suld e V S.lalllllllloa {o li C c ] 5 dloluplsoy-uuN UO m luoug S� .10111d\lllJol$ JOY AnIuM uoolO w U = c c E a o, 'l I I 1 I F EnEo Lq E I I I I I C c o ifZZS a ^ o JE_ g y U 4 V •.F I-' H O , c b y c Q E E a. '` U u c u A z g E G � H CA c y r a uglunump 1p)galp (ol V o ,o E u ¢� J Q h" Y2� 7 yV � 'a � •e pit P a E 'g0f.E230 V L An N w w rage 4 or 6 I U 1101 UTI CIe1N01SSV,l..l 'I 2 Y w N 0., ro V d P C U 0 FF� .ti-. Al E U F o it I� �) u .P CII wn.IgoLlanuloawgq nnttiolloAPID �N a e .°)o � nlnpu6Ll a r g � a � � q h\o11111Ir�I)I:�IIIILI � e o aq n H � � w o to nn9lqum •0 v .� = o "�' •a oll0 I Il I 'l �•.11 IN •.11oltIJ 61 I.sd0.1 ') •a •otloo-IIInW otnoy 6 r! O m ^ \ ti71 I!Ikl/ssnd wnow V .A y3y QQY,Yn� kii'��g vA v oil � m U e V, ssnlp ollsold y e D ] siolnnlao0 •lo Il rCnwnp15o2I-uoly e ul:,tlllpaS g° O�O C � aalunuuaolS r" C .� .-6 U = c lay.la111M (10013 S� O F 6 Z Fi 0. E W o ^y F p N .� •• •_ 6 � .� a U w 0. W H CNxiq iYi C r I W Syy A s •p Ur .P R e11mAlIluJ (J) I.f)IJ) T ��- F E 3 aF q a x E N c o ram- u •VJI {' � 1 — E K u � ;� w Q•�, 66y��a� 3' Page 5 of 6 rl!FI !LM r® rV1 Y u Pik !l UI LIV'1 CIi:INDISSV.I„I,FI � N S w C F .O tl U yy T ' fa Pil a F N h ri k 00 a U E o%I � � a � � CII ala,Igau�nulolmgN 12 %RL1/aLl. l'�qzU $ SIIl110110.1111� O o0 ,Lo y nlnpn6l-I a a Hof `I` 1�.a�. C � c F � p' OIIIF,IOAIIS :µ V y, Ill,- H tip w o a mmu41N Puaypl� 8 b N � `o w 5,' W o .n 111191QI11U •CI III(IIII) ;7 E u _ - MII0,711111 NI BIII0.1117 c \ .� III. SFu OIIIOAI a '0110�-IIIIiNf OIIIO�1 •55 IIU:IlSFIIII 01110V x 67 O_ I u NJ 0 y N Gall u 1-00N� -AM12i.Ae sR. a'L W � O C � •� � 01111110% UO11F111d 9I01IIUµ103 AO !! D P O � � AuW1119ay-LION e)IIOUII�OS U o ,10111AIULIOIS o� y h .o L lay.101uM unlD z== u a I I I I O o E eo W b u � a po• a g y�7 0 C T 3 W O p o ,6 rb w d ~ 3 OIIIUfI110, 17%IIR1i 1.71 0 ` r c = u 4�4, ek3®f 23a i a � �' t0 aye 0 uI 0 aceAnalytical www.pacelebs.com August 31, 2020 Debra Batten Town of Holly Springs 150 Treatment Plant Rd Holly Springs, INC 27540 RE: Project: Bioassay -Revised Report Pace Project No.: 92488902 Dear Debra Batten: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on August 03, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is attached to this report in its entirety. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: This revision was issued on 08/31/20 to report the Fathead Minnow species Bioassay results. If you have any questions concerning this report, please feel free to contact me. Sincerely, A. -Payer Amanda Payne amanda.payne@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Seaton Byrd, Town of Holly Springs Terry Foster, Town of Holly Springs REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 31 P.O. Box 16414, Greenville, SC 29606 (664) B77s942 . Fill.. (864) 877.6938 4 Craftsman Court, Greer, SC 29660 Fathead Minnow Survival and Growth Test EPA-821-R-02-013 Method 1000 Permit Renewal Second Species Testing Client: TOWN OF HOLLY SPRINGS Facility: UTLEY CREEK NPDES #: NCO063096 Test Date: 04-Aug-20 Laboratory Sample ID #: T57100 P promelas Test Reviewed and Approved By: V Robert W. Kelley, Ph.D. QA/QC Officer r5erl CerHtication #B87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept. of Health. Included results promo only to provided samples. Farhad Rostampour Laboratory Director SCDHEC Ceti£catlon#23104 NCDENR ceroacatimt # 022 Page 26 of 31 Page 1 of 6 uem Iwo cuy nc", .m .. m,. Facility: Town of Holly Springs - Utley Creek NPDES # NCO063096 Pipe #: 001 County: WAKE Responsible Charge MAIL ORIGINAL TO: Environmental Sciences Branch Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Test Initiation Date/rime 08/04/20 / 03:30 PM % Eff. Repl. 1 2 Control Surviving# Original # Wt/original (mg) 22.5 Surviving # Original # Wt/original (mg) 45.0 Surviving # Original # Wt/original (mg) 75.0 Surviving # Original # Wt/original (mg) 90.0 Surviving # Original # Wt/original (mg) Avg Wt/Surv. Control 0.6016 4 4 10 9 10 10 10 9 10 10 0.5550 0.5822 0.6460 1 0.6230 10 10 9 10 10 10 9 1 10 0.6380 0.7090 0,7567 1- 0.6470 8 0 10 10 8 10 10 10 0.7863 0.6670 1 0.7170 10 9 9 10 10 9 9 10 0.7230 0.7133 0,9189 1 0.7380 10 10 10 T 10 10 10 10 10.. 0.7200 0.6310 0.7500 1 0.7050 Test Organisms Cultured In -House % Survival 100.0 / = Outside Supplier Avg Wt (mg) 0.6016 Hatch Dale: 08/03/20 % Survival 100.0 % Hatch Time: 0900-1130M Avg Wt (mg) 0.6877 % Survival 100.0 Avg Wt (mg) 0.7208 % Survival 100.0% Avg Wt (mg) 0.7733 % Survival 100.0 Avg Wt (mg) 0.7015 E-1-o-ool Surviving# %Survival Original # Wt/original (mg) Avg Wt (mg) 0.7108 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH (SU) Init/Fin DO (mg/L) Init/Fin Temp (C) Inil/Fin High Concentration 0 1 2 3 4 5 6 7 pH (SU) Init/Fin DO (mg/L) Init/Fin ji Temp (C) Init/Fin 10 10 10 8 10 10 10 9 0,7320 0.5530 0.7680 0.7900 7.6 / - 7.7 / 7.9 8.2 / 7.9 7.7 / 8.1 7.8 / 7.6 7.6 / 7.7 7.7 / 7.8 7.5 / - 8.1 / 7.7 6.9 / 6.3 8.0 / 7.6 7.7 ! 6.8 7.4 / 6.5 8.0 / 7.2 ---- / 7.8 24.7 / - 24.fi / 25.3 24.7 / 25.5 24.5 / 25.1 24.6 / 25.6 24.6 / 25.3 24.6 / 25.2 ---- / 24.7 8.1 / - 8.3 / 8.2 8.1 / 8.4 8.6 / 8.5 8.0 / 8.1 8.2 / 8,2 8.4 ! 8.1 ---- / 8.2 8.8 / - 8.2 / 7.4 8.0 / 6.0 8.1 / 7.2 9.4 / 6.5 7.3 / 6.1 8.1 / 6.6 ---- / 7.5 25.0 / - 24.8 / 25.3 25.0 / 25.5 24.7 / 25.1 25.2 / 25.6 24.7 / 25.3 24.9 / 25.2 ----/ 24.7 Sample Collection Start Date Grab Composite (Duration) Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) Chlorine(mg/L) Temp at Receipt ( C) Dilution H2O Hardness (mg/L) Alkalinity (mg/L)Conductivity M306 (umhos/cm) Survival Growth Normal no yes Hom. Var. es yes NOEC 100.0% 100.0% LOEC >100.00% >100.00% ChV >100.00% >100.00% Method Steel's Test T-Test Overall Result ChV >100.00% Slats Survival Growth Cone. Critical Calculated Critical Calculated 23 % 10.00 18.00 2.41 -1.70 45% 10.00 18.00 2.41 72.35 ' 75°/ 10.00 18.00 2.41 -3.38 90% 10.00 18.00 2.41 -1.97 100% 10.00 16.00 2.41 -2.15 Page 2 of 6 NEE MINNEEMINE BE MINERINININNEIN BE MEN ME MMI MMERWESMIENEWMIE Lab# T57100 P promelas client TOWN OF HOLLY Sempb to EFFLUENT NPDES# NCO063096 county WAKE Month 6 Start a fad Date 04-Aug-20 Start &fad Time 03:30 PM Started &fed By AM Te.t Organism IPIMEPHALE3 PROL Ned. born date 03-Aug-20 Ned.born tone 10900-113OMT Test Type NCCO Dilution Water MHSF 1-31-20D Onto far Gen.. k3rd BROOD Testvdsseis 400 m1 Test volume 250.1 Incubator# 1 Light 161V8dk Initial Tomp'a 25 ANemm .isg 2xDAY Test metbotl EPP a)t-Rd3d1):1000 Commands Allreps Lave 10 organisms unless noted otherwise. Control in[ temp ORGANISMS= SOURCE= ADS 814/20 ,48HRS OLD D=Dead N/A -Lost or not used Page 3 of 6 Page 28 of 31 1101 8V'I Q'INDI913V,Lill a n�F O F `\ �I QI olwgo6wnalmouy,I N9M raj 8 91IJIr71.L �y 666 e � ,E{ snulolmilgD VI I w tmplIS Pl,VW � � m � MalnyW y � k pompud O i> ,� ai W t111 lytl� IU'Q I��w-fry{ n 91111'D ,� � �auop•Plnpy oluoayD Illldlssodoluoi1lD ' �°{ � . �auoD�ppllq aUloa� o Iludlseu� alnnV fJ MunloA d n eso(D u allsuld wou wo03 yo p ololn aw•uoly IM le SW td MIIFlnE 04 valDMgW IG�a Inv AM uue10 t m O nn q .+' - { FL W ��l� U A a • t� Q ps e C7 tj W ary �7 Q S S 111 Do (p tQ 31 Page 4 of 6 J Le � � v 0. If 01 [IV'I CI:IIVOISSy,I..l.:i � m � N x U m u O N N n. u i ° H P a. l n •N, ° F m a H u ti u �l GIaPugalaa,wlalanlN Uj _ MIJ 111 U a G v SIIUIppp,ll(�� c° Ao nlallMfl a � J C e 4' tIwF14S Pls,(YV o Q a A. a nwun!YV Pna1W°;I H p o 0 P o ff al8lqum .a r w o vi alqup'� c'z 11nd/ssnl aluo,u�� rouap-NIItbV splay WINS311d shay ° °JLOLYNO W � N jTSL Tao! N A � p1111I10t\ k ssulp 'j c c s ° aIISL'la U � p v a p smumluoJ Jo IF 'c:T-- ,Q079p0iay-UON U g Iualulpas .mpwiluolS a° c o p R •p U u �- o aay.lalum uualJ y g �I` I l� I 1 I 1 �•q � a I I i 1 �• b —Nu' �I Q ca o .LWca i N O 1 7 C '' 0 i n.xj.ryQ a)�.Fi FF l.' 3'� a�y U o a P w n% 10 'S0 40 $,°�I- C,b`Opfov Page 5 of 6 q ii Ol gV'(113N0(SSV,1.1i1 � R NI a E .G ra n q 5n� m U)udgouonlgo,anpq 21DM� iRIJ 6 51111101101111� N a v � ek�,o °� '� ulslluRfl r� o �` 8 �'ur h, ap)smnllS Awl.19S VIsRW1 ,� r+ a g :� a. u � Y � mam11W PoalUud / 9 H till Illlllu'(I � aq°. W o N ulqup'p ., R,� •ouop'IIIuW olu019J , ." 6 6 IIU Vssud 61HOND q ' 'OUOL)-pluyl ouloV 6 a pud/ssud 01113V Y1 G aFA1xd •8 G I� 5 d ovj I g OwIIJOA Y MID 9a ollsuldid � a �' slou ulunp ,{a It a NolUInBUuluoN umugpog e 5 3 JOIUM1010lg U UU IOV.fWtl/,{uualp dl I I I I � 1 11 I I I C I I 1 y U �I [krw M i I 1 I ro � o •y }EYJ e 5 CIS PI c'i � � � �gg¢� o n. 1 .11 Yn 1LU y U V I-r o W Page 31 of 31 Page 6 of 6 rlll�' A c' P.O. Box 16414, Greenville, SC 29606 (664) 077-6942 , FAX (064) 07 T6930 4 Craftsman Ctxlrl, Greer, SC 29660 Ceriodaphnia dubia Survival and Reproduction Test EPA-821-R-02-013 Method 1002 Client: TOWN OF HOLLY SPRINGS Facility: UTLEY CREEK NPDES #: NCO063096 Test Date: 04-Aug-20 Laboratory ID #: T57100 C DUBIA Test Reviewed andApprovedBy: W/Vf Robert W. Kelley, Ph.D. QA/QC Officer Certification #L87819 Test results presented in this report canform to all reepmemeuts of Farhad Rostampour Laboratory Director SCDHEC Certification #23104 NELAC, conducted under NELAC Certification Number E87819 Florida Dept. of Flealth. Included results pertain only to provided samples. Page 1 of 6 NCDENR Certification # 022 Page 20 of 31 Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date 14-Aug-20 Facility: Town of Holly Springs - Utley Creek NPDES# NCO063096 Pipe # 001 County: Wake Laboratory Perro g Test: X Comments Signature of Operator in Responsible Charge Signature of Laboratory Supervisor MAIL ORIGINAL TO Environmental Sciences Branch Div. of Water Quality N.C. DENR 1621 Mail Service Center Raleigh, North Carolina 27699-1621 North Carolina Ceriodanhnia Chronic Pass/Fail Renroduction Toxicity Test CONTROL ORGANISMS # Young Produced Adult (L)Ive (Hired Effluent% TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 t0 11 12 #Young Produced 19 21 1 23 1 20 1 19 20 20 1 22 1 21 1 21 21 19 Adult (L)Ive (D)eed L L L L L L L L L L L L Comolete This for Either Test pH ist sample fist sample 2nd sample Sample 02-Aug-20 Control 7.6 8.2 7.8 8.2 7.7 8.1 Treatment 2 8.2 8.6 8.1 8.5 8.1 8.5 Grab comp Hurane Sample i X 24hm. Sample 2 X 24hm. start end start end start end D.O. 1st sam le lst sam le 2nd sem le Hardness (milli-) Control 8.1 7.5 7.4 7.8 7.9 8.7 Spec. Cord.(pmhos) Treatment 2 8.9 7.5 7.5 7.9 8,3 8.7 Chlodne (mglL) LC50/Acute Toxicity Test (Mortality expressed as %, combining Ilculated t= 1.97 itical Value= 2.508 Reduction= 5.0% 0% Control 21.6 Control 0% realment2 20.5 Treatment orhol CV 6.7% PASS FAIL %3rd Broad 100 % X Test Start Dale 04-Aug-20 Samole2 04-Aug-20 let 2nd Tex TeX Dilution Sample Sample 83.7 .05 W., Mortality star/end staNend LC50 = % Method of Determination Control 95% Confidence Hired. Moving Average Problt ® High Cone. % % Spearman Kerber Other pH D.O. Organism Tested Cerioda hnia dubia DEM Form AT-1 Page 21 of 31 Page 2 of 6 STATISTICAL ANALYSIS RESULTS Survival Data 7 Day Survival Test Used: FISHERS TEST Control 100% Test Statistic: P= 1.000 Effluent 100% Critical Value: P= 0.01 PASS: The effluent does not reduce survival of the test organisms. Reproduction Data Rain Data Test for Normality Mean young/female Std. Dev. Test Used: Shapira-Willcs Test Control 2t.6 1.44 Effluent 20.5 1.24 W: 0.953 Critical Value: 0.884 Analysisfor Differences in Rep, odaction Test for Homogeneity of Variance Test Used: Equal Variance t Test. Test Used: FTest Calculated t= 1.97 F= 1.35 Critical Value= 2.51 Critical Value= 5.32 The data are homogeneous in variance PASS: The effluent is not chronically toxic. Page 22 of 31 Page 3 of 6 Control Mortality and Reproduction by Test Day 1 2 3 4 5 6 7 8 Total source 1,.p G10 7-23 1 +4+8 11 23 V3 7-24 2 +3+9 10 22 04 7-23 3 +4+7 9 20 X3 7-24 4 +4+8 12 24 R7 7-23 5 +3+8 11 22 P8 7-23 6 +4+8 9 21 W 1 7-24 7 +3+9 11 23 ITS 7-23 8 +4+7 11 22 R1 7-23 9 +4+8 10 22 F6 7-24 10 +4+7 1 9 20 T8 7-24 11 4 +7+10 21 M3 7-23 12 5 +6+8 19 13 NIA 0 14 NIA 0 15 NIA 0 16 NIA 0 17 N/A 0 18 N/A 0 19 N/A 0 can 20 1 NIA 0 21.6 90 % Effluent Mortality and Reproduction by Test Day 1 2 3 4 5 6 7 8 Total G10 7-2 1 4 +6+9 19 V3 7-24 2 +4+7 10 21 04 7-23 3 +4+8 11 23 X3 7-24 4 +3+7 10 20 R7 7-23 5 3 +7+9 19 P8 7-23 6 +3+7 10 20 W1 7-2 7 +3+8 9 20 R5 7-23 a +4+7 11 22 R17-23 9 +3+8 10 21 F6 7-24 10 1 1 a +6+9 21 T8 7-24 11 +4+7 10 21 M3 7-2 12 3 +6+10 19 0 131 NIA 0 0 14 N/A 0 0 15 NIA 0 0 16 NIA 0 0 17 NIA 0 0 18 NIA 0 0 19 N/A 0 Mean 0 20 NIA 0 20.5 reAew,'�,,, JG Jz En Date,= fed",,._ JC JG JC AM Jz AM 11-AU -20 Om9 tad&renew rnnl pain PAt oz:n eu 024.9 0 taa ntn JC Newtamp.?O .' 25.0 Old temp. °C 25.5 25.3 24.7 Control Nowtemp.=c 24.6 24.8 Page 23 of 31 Page 4 of 6 g }o q a6ed Nr. �, IQI (il'All/�r.'OItlnO511J N iRi alley V a N m '� � jryl7jy c �AQy+ � Y1 1 (`yam p' i I I I I aqp o. Cay gg I I I i Clean Wmcr Aol Stormtivnlor 9edimsnt 3 Non-Rogulatory 5 N ot Coatn nors n & Plastic Man Volume S 'pygJ Too Tr 'ell - RIP I � Acuto Puss/Pull Aaata II'i11R1•COila, • � j.� 'y ChronloPnes/Full � � • Chranla Malll-Gong C, t�l dubla D, nMi �i Alibi&1111 MUM Minnow H y ��-�1�� rt � gp y 4lynllaln Chlra1101111i5 R I?v _ u TIAlTR6 fd B r 8 WER MnorohreoNDbmlo ID 0' n , �p ® $ 4 41,,M� D �b vl UI v BTT g;o g o6ed O 9J ae P � si 0 0 y 3 Fz C) g rrn E h Y n 9 O• rri� �v X. q a C o n z ry� w N F kN- on FV h O a � r a a LA poi � y y 9 io � I I I I cv a m 0 El 'n" �• � 9 uo Q I I i I I I i I i i r l �• n a - o� c Q Clenn Wnter Ad a y Slm�nnvnlcr '° a a " 0 R Sediment a m b Non-Regalnloty �C � -IL- # of Containers N o Plasiic w a ''� a Glnss Volume m, N w toe a a TNo_YTi w } uo I m =i ior�'� o. Actde Pass/Pnil a �. Acute Muili-Cone. Chronic PnsSA'nil > -' �p•o• �- � Chronic Mnlli-Cone, n M \� C. duhin D. ambiglia .{ 3 UJ o M S S Pnlhend Minna„' o g ,n •v K% ,y Mysid shrimp 3 silvol'snlo G' rt � ti I�lynlleln G ro o• au p Chirononnis ry � _ 'I Il:/fliL WEIR li o � Nlacroinvailubrate ID ' v f n rs. m s G s v o � 3 av V (I N D � a u rn Nr GfT ASSIGNED LAB IDiI L aceAnalytical www.pacelabs.com November 26, 2019 Debra Batten Town of Holly Springs 150 Treatment Plant Rd Holly Springs, NC 27540 RE: Project: Toxicity Pace Project No.: 92452107 Dear Debra Batten: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on November 04, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Val. f� Amanda Payne amanda.payne@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Seann Byrd, Town of Holly Springs Terry Foster, Town of Holly Springs REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 Document Name: Document Revised: February 7, 2018 Semple Condition Upon Recel t(SCURI PaLe 1 of Document No,: Issuing Authority: 806Ana(yl1ca1' ' F-CAR-CS-033-Rev.06 Pace Carolinas Quality Off Ice Laboratory receiving samples: Asheville [Q EdenO Greenwood ❑ Client Name: Huntersville❑ Raleigh project#: Courier: ❑Fed Ex ❑UPS r lusps \ Cllent ❑ Commercial t;QPace ❑Other:_ t! Mechanicsville❑ 52107 111 Custody Seal Present? []Yes �E o Seals intact? ❑Yes ./ :ate/IntBals Person examining Contents: 11#4119 Packing Material; ❑Bubble Wrap - []Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer; []Yes❑No ❑N/A Ajg Gun ID; Type of laet '}Wet []Blue []None 1I21_- Cooler Temp ('C); 'i<� Correction Factor Add/ubt -C) © C) Tempshould be above tree:ingto 6'C Cooler Temp Corrected('C):[]samples out oftemp criteria. Samples an Ice, cooling process hasbegun USDA Regulated Sall (M N/A, water sample) Did samples originate In a quarantine zone within the United States: CA, NY, or SC(check maps)? old samples originate from a foreign source(internatlonally, M.. ".,. Ineludine Hawaii and Puerto Rico)? ❑Yes ONO Comments/Distrepa ncy: Chain of Custody Present? Yes QNO N/A 1. Samples Arrived within Hold Time? as QNo ❑N/A 2. Short Hold Time Analysis (472 hr.)? Yes LINO ❑N/A 3. Rush Turn Around Time Requested? Yes JgNo N/A 4. Sufficient Volume? es No ONIA S. Correct Containers Used? -Pace Containers Used? es es []No No ❑N/A N A 6. Containers intact? j4Yes No N/A 7. Dissolved analysis: Samples Field Filtered? []Yes Elflo. /A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: $ns WTI ❑No ❑N/A 9. Headspace In VOA Vials >S-6mm7 Yes No /A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes Yes ❑No No /A /A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION ' Person contacted: Date/Time: Project Manager SCURF Review: }P Project Manager SRF Review: Field Dale Required? ❑Yes []NO Date: L( () 0 1151 Date: ( ) 01 Page 2 of 23 Document Name: Sam le Condition Upon Recel t SCUR) Document Revised: February 7, 2018 Page 1 of 2 8C8Aflal"Ca F' Document No.: F-CAR-CS-033-Rev.06 Issuing Authodtyi Pace Carolinas Quall Office *Check mark top half of box if pH and/or dechlorination is Project If W0# ' 92452107 verified and within the acceptance range for preservation pill AP Due Data: 11/18/19 samples, CLIENT: ,92—Holly Spg Exceptions: VOA, Collform, TOC, Oil and Grease, DR0/8015 (Water) DOC, LLHg **Bottom half of box Is to list number of bottle y� C J Y E yy; L J ggu E aye ` J ppu E C J n t`y ! 0 x E 6 T y E u E 6 Z u E E r b 9 6 .u�. V S �i dF _ ? E o ry n d dE V v a J o P 2 9W J, E .ti "� Q O x E m '2d' > E 4 c ¢J > E Y m x E 2 QNr E M y 'e SL .: .t I V o. _ -r E Z\6 Y 4 m E t,. nu u iad E y b C J at E gz 2 o 'A 5 E e J o 1 2 3 4 5 6 7, 9 30 11 LL 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina OEHNR CertiRatlon Office (1.0. Out of hold, Incorrect preservative, out of tamp, Incorrect containers. Page 3 of 23 I �I MW ° v fl Ctl Cl\+'I (I -I c u E � N C. e _ O O � u F NN r- 4 F T L g 01 as CII au:agapanuloJauly � Q � 0 0 21i.1A\ e 'FOLU11.1. snumuapl� O � � a nlapu,Cl{ a £ � W y u .� � F. '� 8 v Q111111IS OIs,CI>y F? � O o w A\°IIIIII�y l)IlBlllll,! u1181yuN 'Q e M Z L• o aly11P'J E m _ - •ou°J-!11°W°play) � IPI:1/ssu+l aluay� rouOD-1111I y alaoy .� IIII,11S511d allla\/ \ F 46,8s.ut � d _ n "" 5 p Baal F� � d L i ° F 'g E� ssulp apsuld o sJoumPloa ,JOBca IZTI p ,(10tuln3ay-uoN fi E W v U n Q lualu 1pas e° $ o 4 —5 Jolumallo)s la\+Jolum tmalo U o S ryry I�j1 1 I 1 U c E o m Sr- t F o o V a a � o o V S Gp n W 12 a E p O^ N -- W 1- Iv m m CI �- V 4 O C o ✓ O. C V V Ci F W U wi u° on tL '> E p ear_ ti SrY co O O C ^ = E n. Document Name: Document Revised: February 7,2018 Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Document No.: Issuing Authority: aceAnalytical f-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville Q Eden[] Greenwood ❑ Huntersvlile ❑ Ralelgh0/IVlechanicsvllle0 Client Name: WO# : 92452107 .. -t— Project N: F-rr/rolvA OF moill i S/pp 1'? PM: AP Due Data: 11/18/19 Courier: ❑Fed Ex ❑UPS ❑USPS Client CLIENT: 92—Holly Spp ❑ Commercial �>ce / ❑Other:_ Custody Seal Present? []Yes©0" Seals Intact? Ryes ONO Date/Initials Person Examining Contents: ZA 14 A-G Packing Material: []Bubble Wrap ❑Bubble Bags [DNdne ❑ Other Biological Tissue Frozen? Thermometer: ❑Yes []NoQP� ❑IRGun ID: ell JUt75 Type of ice: OWet ❑clue []None Cooler Temp (°C): I I Correction Factor: Add/Subtract (°C) ). (') Temp should be above freezing to 6°C Cooler Temp Corrected(`C): LJ1 []Samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil ( A, water sample) Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Internationally, rv, _ "'. _ ..A..m.,...--a end V ,en M-17 -Ivnc MIN. Commants/Discrepancy: Chain of Custody Present? j LI w1e [_]No ❑N/A 1. Samples Arrived within Hold Time? DeYs ❑No ❑N/A 2. Short Hold Time Analysis(02 hr.)? QYes mKo-�QN/A 3. Rush Turn Around Time Requested? Elves Ej]No ❑N/A A. Sufficient Volume? OYzs [IN. N/A 5. Correct Containers Used? -Pace Containers Used? QYe El]Y [IN. ❑No ❑N/A ❑N/A G. Containers Intact? Q es ❑Na QN/A 7. Dissolved analysis: Samples Field Filtered? QYes []NO ❑N,A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: ❑Yes []NO ❑N/A 9. Headspace in VOA Vials (>5-6mm)? QYes ❑No �- EJ /5 A 10, Trip Blank Present? Trip Blank Custody Seals Present? QYes []Yes []No ONO [JWA- ©N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: k j[ .�/t-' Project Manager SRF Review: 1 Alp Date/Time: Field Data Required? ❑Yes ❑No Date: I ( I Z I Date: I I I t/I,-"J Page 5 of 23 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Receipt(SOUR) Page 1 of 2 7C6Ana1y11Ca1' Document No.: Issuing Authority: F-CAR-CS-033-Rev,06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Collform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project a Wait : g2452107 pMt pp Due Data: 11/18/19 CLIENT: 92-Holly Spp d a N N ¢ a �' 6 y, 6 Ot x o ad+ 6 fz Q 0 u v1 ff v A _ ¢ - y ia.EEEE E w 'e ¢ z N Q E ,lO� a [-E n d E O a z 2• E r� m V' �j E O Z 0Z �?p O E aNVm>m¢>° > E O a E O v°i •9 z N j ii m_ 2 m ,n E N ? ry '^ E ,/O� l ^ _ o y, e d aEEOO OOO v�i a W 4EEEiEEEEa•� i 2 3 4 5 6 7 B 9 10 I1 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot If h II DEHNRC rtf flat ^no -en> Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this farm will be sent to the Plort Caro na e i ica Out of hold, incorrect preservative, out of temp, Incorrect containers. Page 6 of 23 E 7i u f/QI iIV'I CIINDI$$V .LLEI a n � — o 0 � E � c 2 0 o E M N u •o CII 011lllla\IBAU10.1111(.� � E o u 1 $I1t11o11oilEla ,� j [:.l u <Illlllll$ I115�C1�\. �� u 55a tmR.I Iltlu •cl M y ti 10 0 m _ rouo�-!IPI��aluo.I11J ° � � o pn;Ifssn�anwayJ �• •auop-11119•\ a111aV 'p IIILIfS51111 a11IaV -( i:.l Taal ii C r s S '� a � __ Uallsold ti o ye, SaS u � 5 p ' =121110;lop 2 ,Oo1uplBay-uoN E C U F � luattll(la$ Iola,\\tt1.101$ e° � o 0 Iavn)UA\fluor �I I I 1 I •G a G I I I I < 7 J U CCU � V '•+1 I i i I n o n � � E t o f p _ E 0 v o c � a 'o q GL Ei v a 1- U al � E \ o n �ae 002 U w Document Name: Sample CondlUan Upon Racelpt(SCUR) Document Revised; February 7, 2018 Page 1 of 2 Document No,: F-CAR•CS-033-RAV.06 Issuing Authority: Pace CarolinasQuall Office .,i 08,4 Bty101 Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville ❑ Raleigh] Mechaniesville❑ CllentNeme: WO# : 92452107 Tewv < l�el� S r Project q PM AP Due Data: 11/18/19 Courier: ❑Fed Ex EMS ❑Commercial (Pace ❑USP5 Mother:_ uclient CLIENT: 92-Hotly Spill Custody Seal Present? ❑Yes ®No, Sealslntact? ❑Yes ao Data/initials Parson Examining Contents; ss 18114 Packing Material: ❑bubble Wrap []Bubble Sags MNone ❑ Other Biological Tissua Frozen? Thermometer: �/ ❑Yes ❑No MN/A SIR Gun ID; I'Cac�K� Type of ice: lylWet []Blue ❑Nono Cooler Temp (°C): 1. 1 Correction Factor; Add/Subtract (°C) 6.6 Temp should be above freezing to 6°C Cooler Temp Corrected (°C): _..:) i QSamplm out of temp criteria. samples on lee, cooling process has begun USDA Regulated Solf /A, water sample) Did samples originate Ina quarantlne zone within the United States: CA, NY, or SC(check maps)? Did samples originate from a foreign source (internationally, . o. N.A.,. u—mu and nirnp f-tvea Who rub 14. comments/Discrepancy., Chain of Custody Present? 6Yes []NO N/A 1. Samples Arrived within Hold Time? Wye ❑No ❑N/A 2. Short Hold Time Analysis 42 hr.? 09Yes []NO CINIA 3. Rush Turn Around Time Requested? Yes Mo N/A 4. Sufficient Volume? SYas I77jNo N/A S. Correct Containers Used? -Pace Containers Used? MYes es ❑No RNo ❑N/A N/A 6. ' Containers Intact? gyu No Dissolved analysis: Samples Field Filtered? []Yes E2140 N/A 8. Sample Labels Match COC? -includes Date/Time/ID/Analysis Matrix: ,f7 &Yes ❑No ❑N/A 9. v.° o Headspace In VOA Vials (>S-6mm)? Trip Blank Present? Trip Blank Custocly,Seiols Present? ❑Yes []Yes lJYes QN. ❑No No N/A N/A N A 10. 11. COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes EINo `l y'rw (0,1 - r(vi�drI HOC_ 01, 11,1419 - a w, E lflo/�-z Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Mne V 1X Date/Time: Date; 11 Ili I al Date; I117/L01 Page 8 of 23 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Rece( t SCURj Page 1 of 2 aceMalyticaf" Document No.: Issuing Authority: F-CAR•C"33-Rev.06 Pace Carolinas Quallty Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation . samples. Exceptions:VOA, Caliform, TOC, Oil and Grease, DRO/8015 (water( DOC, LLHg **Bottom half of box is to list number of bottle Project It WO# : 92452107 PM: AP Due Data: 11/18/19 CLIENT: 92-Holly Spy y E gg IJ 9 5Q� j Z D. V x n V 5 u, V pz i E m E A z E 3 i o a pOI aEE [a N V D aEE .°g� q V 4 = •�• v a o ixr y Z O ggqE \ Z C� E o ggqE .Q` O E E O > Z 8', y ,ar, E Pvl gg of a o Q $ o 4 E 1 2 3 NNN 4 5 7 6 9 10 SI 12 PH Adjustment Log for Preserved Samples Sample to Type of Preservative pH upon receipt Date preservation adjusted Time presodtlon adjus Amountaddedervative Lot# .. .. .._..._,. MHhlamrmwlll be sent to the North Carolina DEHNR Certlflcadon OMce it I, Note: Whenever there is a mscrepancy aneaung nu,u, --,........ ..... r.--. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 9 of 23 k m m _DISS V ) ) _+w § | ! ! > !� Fi » \ \ [ I ma`s 1101 OV`I OIJNDISSV dUltl +� N J O F .�4 ,j�n ea N � �s9 Fli U u F " pl nluagalsomgwllIV aam 12 e 8 d all.11all T 4 c ulallu 1.1 naplsaonllS � mounlyV pnoylnd h t o 5 5 F ,� � a o m It118!gIt10'Q nlgup•p x •ouoo-p111IN oplonl� �,, � c � Iludlssod oplanlp +' y2 •awp'!1111W oU10V •� a 11110sud 01110V 40! •n 5 a § 3 ZY a5.eaa �.� rID _ •A OR11110A ( v ••` 6 ssulD OPsuld 0 slmuuco Joµ � ,Cmlupt80y-uoN lnaugpag �6 ° C �u aolmwuaolS. ^' o q .e D G toy aaWM uualp a 3 I I I I 1 1 I I Is � 1 D q �d r^ zj $ tg �1 Q uIgo I 01 M 11 z ca � a � •q � L•: � tj x � 8 DIImtIa1DJ (D)9D+`�(D) t' � •`p7 u >+ d �.p,^: •d '6 U +L ..� °' per, tC N W \A Page 11 of 23 Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date 15-Nov-19 Facility: Town of Holly Springs - Utley Creek NPDES# NCO063096 Pipe # 001 County: Wake Laboratory Performing Test: - X comments Si nature of 00e-rator4rn Responsible Charge Signature of Laboratory Supervisor MAIL ORIGINAL TO Environmental Sciences Branch Div. of Water Quality N.C. OENR 1621 Mall Service Center Raleigh, North Carolina 27699-1621 North Carolina Ceriodaphnia Chronic Pass/Fail Reproduction Toxicity Test CONTROL ORGANISMS # Young Produced Adult (L)lve (Diced Effluent % culated t= 0.5852 :ical Value= 2.508 Reduction= 1.9% ouality Avg. Reprod. 0% 21.7 Control Control 0% 21.3 TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 a 9 10 11 12 8.9% #Young Produced E20 24 23 19 21 21 21 23 19 22 21 21 %3rd Brootl PASS FAIL Adult (L)ive togas,L L L L L L L L L L L 100% X Complete This for Either Test Test Stan Data Collection fctadl Bats 05-Nov-19 pH lot sample lst sample 2nd sample Sample 03-Noo-19 Sample 05-1,10v-19 Control 7.8 8.2 7.6 8.3 7.6 8.2 Treatment 2 8.1 8.6 8.2 8.8 8.2 8.7 Grab Comp Duration 1st 2nd Sample 1 X 24hrs. Tax Tax Sample 2 X 24hrs. Dilution Sample Sample D.O. start end start and start and isl sam le lst sam l0 2nd sam le Hardness (nglL) 84.0 Control 8.2 8.2 7.5 8.6 8.2 8.0 Spec. Cond. arenas) 318 748 749 Treatment 2 8.4 8.1 9.0 8.3 8.9 7,8 Chlorine (mglL) <.05 <.05 Sample Temp. at receipt (°C) 0.1 0.2 LC50/Acute Toxicity Test (Mortality expressed as %, combining replicates) ]Concentration Mortality st.Wend st.rY.nd LC50 = % Method of Determination I Cannot 95% Confitlence limits Moving Average Probit I High Cone. % Spearman Kerber ROlher pH D.O. Organism Tested uenooapnnia ouoia DEM Form AT-1 Page 2 of 6 Page 13 of 23 Eln.nlontaino, (664) 077.43W . FAX (864) 877.093B CO. Box 16414. Greenville, SC 29606 4 QuIlsrridn Ccxtrl, Greer, SC 29060 Ceriodaphnia dubia Survival and Reproduction Test EPA-821-R-02-013 Method 1002 Client: TOWN OF HOLLY SPRINGS Facility: UTLEY CREEK NPDES #: NCO063096 Test Date: 05-Nov-19 Laboratory ID #: T55286 PF Test Reviewed and Approved By: Robert W. Kelley, PLO. QA/QC Officer Certification #E87819 Test results presented in this report conform to all requirements of Farhad Rostantpour Laboratory Director SCDHEC Certification 423104 NELAC, conducted under NELAC Certification Number E87819 Florida Dept. of Health. Included results pertain only to provided sam les. age 1 of 6 NCDENR Certification # 022 Page 12 of 23 STATISTICAL ANALYSIS RESULTS Facility: TOWN OF HOLLY SPRINGS NPDHSO NC0063096 Sample ID: FINAL EFF error T55286 Pr Date: 05-Nov-19 Laboratory: Certification fl: NCO22 I Eat. Date: il/l/2020 Survival Data 7 Day Survival Test Used: FISHERS TEST Control 100 % Test Statistic: P= 1.000 Effluent 100% Critical Value: P= 0.01 PASS: The effluent does not reduce survival of the test organisms. Reproduction Data Rand Data Test for Normality Mean young/female Std. Dcv, Test Used: Shapiro-Wilks Test: Control 21.7 1.92 Effluent 21.3 1.54 W: 0.939 Critical Value: 0.884 Analysisfor Differences in Reproduction Tesi for Homogeneity of Variance Test Used: Equal Variance t Test. Test Used: F Test Calculated t— 0.59 F= 1.55 Critical Value— 2.51 Critical Value= 532 The data are homogeneous in variance PASS: The effluent is not chronically toxic. Page 14 of 23 Page 3 of 6 Control Mortality and Reproduction by Test Day 7 2 3 4 5 6 7 8 Totai source Iran 11110-23 1 +4+6 12 22 JJ1 10-23 2 +5+6 11 22 N6 10-24 3 5 +8+11 24 01010-24 4 +2+7 8 17 L2 10-24 5 4 +6+12 22 L4 10-24 6 +5+8 10 23 W310-25 7 +4+6 12 22 X3 10-25 8 3 +6+10 19 E1 10-26 9 4 +7+10 21 A2 10-25 10 5 +7+11 23 III 10-23 11 +3+8 12 23 JJ1 10-23 12 +4+7 11 22 13 N/AE 0 14 N/A 0 15 N/A 0 16 N/A 0 17 N/A 0 18 N/A 0 19 N/A o IMean 20 N/A ol 21.7 90 % Effluent Mortality and Reproduction by Test Day 1 2 3 4 5 6 7 8 Total Ill 10-2 1 +3+8 9 20 JJ1 10- 2 +4+7 13 24 N6 10-2 3 4 +9+40 23 01010- 4 4 +7+8 19 L2 10-2 5 4 +7+10 21 L4 10-2 6 +4+6 11 21 W3 10- 7 +3+7 11 21 X310-2 a +2+9 12 23 El 10-2 9 4 +6+9 19 A2 10-2 10 1 1 a +8+10 22 III 10-2 11 +3+8 to 21 if 10-: 12 +4+7 10 21 0 13 N/A 0 0 14 NIA 0 0 15 N/A d 0 0 111 N/A 0 0 17 NIA 0 0 18 N/A 0 0 19 N/A o Mean 01 20 INIA I 0 21.3 modusilffmm C JC 12-NOV-19 wMEMEEL-i—C JC JC AM JC JC p111 PM 01'."1. 7.2e AM 08:. AN p JC 24.7 24.5 Old temp. °C 25 24.6 24.8 conuol New temp. -0 24.3 24.3 Page 15 of 23 Page 4 of 6 licit MORNOISSV IU.fl ! e p cil otwyo6mna)oaoaW - 6ualoumplD 0 oPlunnllS y , B ;� o ngnlSPla W 9 ,# w una)gwa'a $ w "d ti W911P'0 . � � 'y 'ouap•)IDIW oiumyp . 6C IIt4l/seu�C olunAyp I� ' ', � � ronaci•pplyy olnay , ® 110�88ad Bllio�/�41 T F 8 W p d $ . ® RaulO 6 v ollsald u/0u Wuo3 ,7a Noluinaaya,a)y Joluumo)S a a N 19 y I I 1 0 4&� gvyb - olPodmcp(0) awD(0) 4J 0 J O a Page 16 of 23 Page 5 of 6 u Es I/ QI EIV9 DaNDISSV1,1A7 C�6 C o K kU gb 9 E± � � u � p, •u& wf •� '_' • � Fdpj N "' � n�.� ,� QlnivagDpoeulnmuW KIM � a �qq nmuulW PuoyNd l{ H � o un9�Ituu'Q� � W vm •D d �gg 'DUUD•pUIWapImslD a IIUd/ssud alUu.Igp � B gu •nuuD'IIPJWoivay '�{ IIUd(csUdDlnaV C �b a� r A uvu aDl �n olll�llo/� � •8 � E .e � �` OVOID NN�Id waUNluoD do fdofupt aq•uDly 7uNWIpDg � ^' � o NDsunsulUlS �° °i Jo .JDIum UNDID J I I I I 9 �( .g .. 41 1 0 p g � s�Ji r N, VJ OF 8g Cf $ p TK a W Page 6 of 6 Page 17 of 23 Facility: Town of Holly Springs - Utley Creek NPDES # NG0063096 Pipe #: 001 County: MAIL ORIGINAL TO: Environmental Sciences Brandt Division of Water Quality NC DENR 1621 Mail Service Center Raleigh, NC 27699-1621 Test initiation Datefrime 11/05/19 / 03:50 PM Eff. Repl. 1 2 4 Control Surviving # Original It Wt/original (mg) 22.5 Surviving # Original # Wt/original (mg) 45.0 Surviving # Original # Wt/original (mg) 75.0 Surviving # Original # Wt/original (mg) 90.0 Surviving # Original # Wt/original (mg) 100.0 Surviving # Original # Wt/original (mg) Avg WI/Surv. Control 0.6649 4 10 10 9 10 10 0 10 10 0.6620 0.7130 0.6170 1 0.5990 9 10 9 9 10 10 10 9 0.5270 0.6550 0.5170 0.5700 9 10 10 10 9 10 10 10 0.6433 0.6890 0.58501 0.4900 10 10 10 10 10 0 10 10 0.4860 0.4830 0.7030 1 0.6350 8 10 10 9 10 10 10 9 0.4470 0.5570 0.5450 0.6122 10 9 8 9 10 9 10 10 0,6070 0.4989 1 0.5120 0.5740 Test Organisms Cultured In -House %Survival 97.5% X Outside Supplier Avg Wt (mg) 0.6478 Hatch Date: 11/04/19 Survival 94.90% Hatch Time: 0930-it00M Avg Wt (mg) 0.5673 Survival 100.0 Avg Wt (mg) 0.6018 Survival 100.0 Avg Wt (mg) 0.5768 % Survival Avg Wt (mg) 0.5403 % Survival Avg Wt (mg) 0,5480 Water Quality Data Day Control 0 1 2 3 4 5 6 7 pH (SU) Init/Fin DO (mg/L) Init/Fin Temp (C) Init/Fin High Concentration 0 1 2 3 4 5 6 7 pH (SU) Init/Fin DO (mg/L) Init/Firs Temp (C) [nit/Fin 7.7 / - 7.8 / 7.7 7.7 / 7.7 7.8 ! 8.2 7.7 / 7.6 7.6 / 7.8 7.6 / 7.9 ----/ 7.9 8.0 ! - 8.0 / 7.2 7.9 / 6.5 7.9 / 6.9 7.4 / 5.8 8.0 / 7.1 8.0 ----/ 6.8 24.7 / - 24.3 / 25.5 24.3 ! 25.0 24,4 / 25.3 24.5 / 25.6 24.3 / 24.8 24.4 8.1 / - 8.1 / 8.2 8.2 / 8.4 8.4 / 8.4 8.1 / 8.3 8.4 / 8.5 8.5 ! 8.5 ---- 9.4 / - 7.9 / 7.2 9.2 / 6.8 8.1 / 6.3 8.7 / 6.2 8.3 / 7.1 8.1 / 6.7 25.0 / - 24.7 / 25.5 24.7 / 25.0 25.1 / 25.3 25.7 I 25.6 24.4 / 24.8 24.6 / Sample Collection Start Date Grab Composite (Duration) Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) Chlorine(mg/L) Temp at Receipt ( C) Dilution H2O Hardness (mg/L) Alkalinity(mglL)Conductivity(umhos/cm) M57�06 Survival Growth Normal as yes Hom. Var. es yes NOEC 100.0% 100.0% LOEC >100.00% >100.00% ChV >100.00% >100.00% Method T-Test T-Test Overall Result ChV >100.00% Stats Survival Growth Corso. Critical Calculated Critical Calculated 23% 2,41 0.57 2.41 1.53 45% 2,41 -0.57 2.41 0.87 75% 2.41 -0.57 2.41 1.35 90 % 2.41 0.50 2.41 2.04 100% 2.41 1.07 2.41 1,89 Page 2 of 6 Elnuranlen.n. P.G, Box 16414, Greenville, SC 29606 (664)877-6942.FAX (864)877.6938 4 Craftsman Court, Greer, SC 29650 Fathead Minnow Survival and Growth Test EPA-821-R-02-013 Method 1000 Permit Renewal Second Species Testing Client: TOWN OF HOLLY SPRINGS Facility: UTLEY CREEK NPDES #: NCO063096 Test Date: 05-Nov-19 Laboratory Sample ID #: T55286 P promelas Test Reviewed and Approved By: Robert W. Kelley, Ph.D. QA/QC Officer Certification #C87819 Test results presented in this report conform to all requirements of NELAC, conducted under NELAC Certification Number E87819 Florida Dept. of Health. Included results pertain only to provided samples. Forbad Rostampota Laboratory Director SCDHEC Certification#23104 NCDENR Cerdfication # 022 Page 18 of 23 Page 1 of 6 Lab4 T55286 P promelas Client HOLLY SPRINGS samplelo FINAL EFFLUENT NPDESM NC0063096 County Month start a fed Date 05-Nov-19 Start 8 fed Time 03:50 PM Started a tea By JC Test organism IPIMEPHALES PRO Neo. born date 04-Nov-19 Noo.born time 0930-110OMT Test Type NCCD DBmron water MHSF 10131119A Units foreonc. %3rd BROOD Test vessels 400.1 Test volume 250 mI Incubatory 1 LIBhI 161t/8d1, Initial Temp-C 25 Artomia .1592XDAY Test method z.olaa000 Comments Ail reps have 10 organisms unless noted otherwise. Control mi tamp -24.2 ORGANISMS SOURCE=ADS 11/5110 <48HRS OLD D=Dead N/A -Lost or not used Page 20 of 23 Page 3 of 6 I iipl tlV'I4F�NOISSV 10.g ' 0 b "u_ O yy � �{❑Ulf ,tl O oN❑ j�j� Vl V tNgpi r� zr u o � 8 QI OIWgo6lonul0A011w uhIIllFft . " gpp I/lrlisllls w — c.: " H g I o � � p' Mam1IW pooNlug � '0110'J•rlliw q hill, I - w ounyop ,` c' esutp 6 g . ollsuld � V,09 UIL103 0 .7 luolulpo5 JolumuJO)s .ta .Isla uuulp cr- I I I I gg o 8 � " A M N1 y a z oil,udma�b)QwA (o) �1 t i_- �tl F84 Page 4 of 6 Page 21 of 23 0 � �•��` .� II UI flV'I UEINDISSV.L.I. Pi 1.0 n 13 LEl 's '� '$ }t (iI utusgn(mmlln1o11W _. 110% g RKEIRIJ. S ,� s n $ ,� susasnmpp m}INSVIs W �' � o �cq B moilinW lwmpud I^ unB�Kltnu'p� _ F y � � V1 O q IC W o i3 �5 W911P'0 t,�y3 P � rouoU•Iliniq oplanlp 'Psup.IIIIIW nlnay 11 Ilud/ssudaPtoy �b k � 000110� � 'g0 p !� �� �' All seUIP sPssld ❑0091a0330 Aolupteau•uoK a IusWipag `� iulw.uusulS w lov .Iulum usalp tb o 1 1 I 1 t I 1 I I 1 I I 1 I I q � a P Y e g v \ �w t a 031mlls1471o) 9t'b(0) �k 1 3 ' 11 a k "". Seim Page 22 of 23 Page 5 of 6 w1 Page 23 of 23 Page 6 of 6 A B C D E F I G I H I I I J K L M N O 1 P 1 NPDES/PT POC Review Form Version:2022.06.22 2 1. Facility's General Information 3 Date of (draft) Review 2/10/2023 c. POC review due to: e. Contact Information 4 Date of (final) Review Municipal NPDES renewal 0 Regional Office (RO) Raleigh 5 NPDES Permit Writer (pw) Gary Perlmutter HWA-AT/LTMP Review ❑ RO PT Staff Cheng Zhang RO NPDES Staff Scott Vinson 6 Perm ittee- Facility Name Town of Holly Springs - Utley Creek WRF New Industries ❑ Facility PT Staff, email 7 NPDES Permit Number NCO063096 WWTP expansion F ❑ f. Receiving Stream 8 NPDES Permit Effective Date 11/1/2017 Stream reclass./adjustment ❑ Outfall 1 9 Chemical Addendum Submittal Date Outfall relocation/adjustment ❑ Receiving Stream: Utley Creek QA, cfs: 0.82 10 NPDES Permit Public Notice Date 7Q10 update ❑ Stream Class C 7Q10 (S), cfs: 0.11 11 eDMR data evaluated from: to Other POC review trigger, explain: Oufall Lat. 35.38.42 N Outfall Long. 78.51.07 W 12 a. WWTP Capacity Summary Outfall II 13 Current Permitted Flow, mgd 6.0 Designed Flow, m d 6.0 Receiving Stream: QA, cfs: 14 Permitted SIU Flow, mgd 0.30 d. IU Summary Stream Class 7Q10, cfs: 15 b. PT Docs. Summary # IUs Oufall Lat. Outfall Long. 16 L IWS approval date 6/2/2022 # SIUs 2 Is there a PWS downstream of the Facility's Outfalls? ❑ YES 0 NO 17 N 'E-L/STMP approval date: 9/12/2022 # CIUs 1 Comments: 18 E a U) W HWA approval date 9/14/2022 I # NSCIUs A draft IUP was prepared for Amgen Inc in July 2022. Fugifilm Diasynth Biotechnologies has applied for an IUP in November 2022. 19 # IUs w/Local Permits or Other ITypes 20 Z 2. Industrial Users' Information. 21 # Industrial User (IU) Name IU Activity IU Non Conventional Pollutans & Toxic Pollutant IUP Effective Date 22 1 Amgen, Inc. Biotech TN, TP, Orthophosphate, Cd, Chlorides, Cr, Cu, CN, Mo, Pb, Ni, Ag, Zn, several organic chemicals, Priority Pollutants, TDS Draft 23 2 Fujifilm Diosynth Biotechnologies 439 A & D NH3-TN, TP, Orthophosphate, Chlorides, As, Cd, Cr, Cu, CN, Pb, Hg, Mo, Ni Se, Ag, Zn, several organic chemicals, Priority Pollutants, PFAS Draft 24 3 Seqirus, Inc. 439.17&47 NH3-N, Chlorides, Hg, Mo, TN, TP, Priority Pollutants, several organic chemicals 7/13/2018 25 4 South Wake Landfill Landfill NH3-N, Cd, Chlorides, Cr, Cu, CN, FOG, Pb, Hg, Mo, Ni, TN, TP, Orthophosphate, Zn, TTO 1/1/2019 26 5 31 Comment: 32 3. Status of Pretreatment Program (check all that apply) 33 Status of Pretreatment Program (check all that apply) 34 ❑ 1) facility has no SIU's, does have Division approved Pretreatment Program that is INACTIVE 2) facility has no SIU's, does not have Division approved Pretreatment Program 3) facility has SIUs and DWQ approved Pretreatment Program 35 ❑ 36 ❑ 37 p 3a) Full Program with LTMP 3b) Modified Program with STMP 4) additional conditions regarding Pretreatment attached or listed below 5) facility's sludge is being land applied or composted 6) facility's sludge is incinerated (add Beryllium and Mercury sampling according to § 503.43) 38 ❑ 39 ❑ 40 p 41 ❑ 42 ❑ 7) facility's sludge is taken to a landfill, if yes which landfill: 43 ❑ 8) other 44 Sludge Disposal Plan: Wasted sludge is digested, dewatered, collected in boxes, then picked up by McGill for offsite composting. 45 46 47 Sludge Permit No: Page 1 63096 POC Review Form A B C D E F G H I I J I K I L M N O P 48 4. LTMP/STMP and HWA Review 49 PW: Find USTMP document, HWA spreadsheet, DMR, previous and new NPDES permit for next section. 50 a Cn c U a Parameter of Concern (POC) Check List New NPDES POC Previous NPDES POC Required by EPA PT(1) POC due to Sludge (2) POC due to SIU (3) POTW POC (4) o /a Removal Rate L/STMP Effluent Freq NPDES Effluent Freq PQLs review Comment 51 PQL from L/STMP, ug/I Required PQL per NPDES permit Recomm. PQL, ug/I 52 0 Flow ❑ 0 0 ❑ 53 p BOD Li 0 0 ❑ 2.0 mg/L 54 0 TSS ❑ 0 0 ❑ 2.5 mg/L 55 0 NH3 ❑ ❑r ❑r ❑ 0.1 mg/L 56 0 Arsenic ❑ ❑ ❑ ❑ ❑ 2.0 57 ❑ Barium ❑ ❑ ❑ ❑ ❑ 58 ❑ Beryllium(5) ❑ ❑ ❑ ❑ ❑ 59 p Cadmium(1) ❑ ❑ p ❑ ❑ ❑ 0.5 0.5 60 p Chromium(1) ❑ ❑ 0 ❑ ❑ ❑ 2.0 10.0 61 0 Copper(1) ❑ ❑ p ❑ ❑ ❑ 2.0 2.0 62 p Cyanide ❑ ❑ ❑ p ❑ 5.0 63 0 Lead(1) ❑ p p ❑ ❑ ❑ 2.0 2.0 64 0 Mercury(5) ❑ ❑ ❑ ❑ ❑ 0.001 0.001 65 0 Molybdenum ❑ ❑ ❑ ❑ ❑ 10.0 10.0 66 p Nickel(1) ❑ ❑ p ❑ ❑ ❑ 2.0 5.0 67 p Selenium ❑ ❑ ❑ ❑ ❑ 1.0 68 0 Silver ❑ ❑ ❑ ❑ ❑ 1.0 1.0 69 0 Zinc(1) ❑ ❑ ❑ ❑ ❑ ❑ 10.0 10.0 70 ❑ Sludge Flow to Disposal ❑ ❑ ❑ 71 ❑ % Solids to Disposal ❑ ❑ ❑ 72 ❑ Oil & Grease ❑ ❑ 73 0 TN ❑ 0 0 ❑ 74 0 T P ❑ 0 ❑� ❑ 75 0 Orthophosphate ❑ p ❑ ❑ 76 0 Chlorides ❑ p 0 ❑ 2 mg/L 77 ❑r 1,4-Dioxane 0 ❑ ❑ ❑ Recommend adding parameter 78 0 PFAS 0 ❑ ❑ ❑ Recommend adding parameter with delayed im lementation per NPDES permit 79 ❑ ❑ ❑ ❑ 80 ❑ ❑ ❑ ❑ ❑ 81 ❑ ❑ ❑ ❑ ❑ 82 Footnotes: (1) Always in the LTMP/STMP due to EPA -PT requirement (2) Only in LTMP/STMP if listed in sludge permit (3) Only in LTMP/STMP while SIU still discharges to POTW (4) Only in LTMP/STMP when pollutant is still of concern to POTW (5) In LTMP/STMP, if sewage sludge is incinerated Please use blue tont for the into updated by pw Please use red font for POC that need to be added/modified in L/STMP sampling plan ease use orange font and strikethrough for PDX that may be removed from USTIVIP POC listisampling plan Blue shaded cell (D60:1-182): Parameters usually included under that POC list 83 84 85 86 87 88 89 90 91 92 5. Comments 93 Facility Summary/background information/NPDES-PT regulatory action: POC to be added/modified in L/STMP: 94 ORC's comments on IU/POC: 95 POC submitted through Chemical Addendum or Supplemental Chemical Datasheet: 96 Additional pollutants added to L/STMP due to POTW s concerns: 97 NPDES pw's comments on IU/POC: 98 6. Pretreatment updates in response to NPDES permit renewal 99 NPDES Permit Effective Date 1180 days after effective (date): I Permit writer, please add list of required/recommended PT updates in NPDES permit cover letter. Page 2 63096 POC Review Form Whole Effluent Toxicity Testing and Self Monitoring Summary Holly Springs WWTP-Utley Crk NCO063096/001 County: Wake Ceri7dPF Begin: 11/1/2017 chr lim: 90% (at 6 or NonComp: Single J F M A M 2019 - Pass - - Pass 2020 - >100 Pass - - Pass 100(P) 2021 - Pass - - Pass 2022 - Pass - - Pass Hospira, Inc. NC0001589/003 County: Nash Fthd24PF Begin: 8/1/2021 Ac P/F Monit: 90% Ft NonComp: J F M A M 2019 H H H 2020 H 2021 2021 H 2022 H 2022 - - Pass - - House of Raeford - Wallace Division NC0003344/001 County: Duplin Ceri7dPF Begin: 3/1/2019 chr lim: 57% @ 1.5M NonComp: Single J F M A M 2019 - - Fail >88 >88 2020 - - Pass - - 2021 - - Pass - - 2022 - - Pass - - Hubert WTP NCO083321/001 County: Onslow Mysd24PF Begin: 7/1/2020 Ac P/F: 90% Mysd NonComp: J F M A M 2019 - - Fail - - 2020 - - Fail - - 2021 - - Pass - - 2022 Fail Fail Fail INVALID Fail Fail Fail Huffman Finishing NCO025135/001 County: Caldwell Ceri7dPF Begin: 5/1/2016 chr lim: 0.96% NonComp: Single J F M A M 2019 - - Pass - - 2020 - - Pass - - 2021 - - Pass - - 2022 - - Pass - - Region: RRO 7Q10: 0.11 J J Region: RRO 7Q10: l J H H H H Pass Region: WIRO 7Q10: 1.77 J J Pass Pass Pass Pass Region: WIRO 7Q10: J J Fail Pass Pass Pass Region: ARID 7Q10: 40 J l Pass Pass Pass Pass Basin: CPF07 Feb May Aug Nov PF: 8 IWC: 95 Freq: Q A S O Pass >100(P) Pass - - Pass Pass Basin: TAR02 Mar Jun Sep Dec PF: IWC: Freq: Q A S O H H Pass H Pass Basin: CPF22 Mar Jun Sep Dec PF: 1.5 IWC: 57 Freq: Q A S O Pass - Pass Pass Pass Pass - Basin: WOK01 Mar Jun Sep Dec PF: 0.518 IWC: Freq: Q A S O Fail - Pass Fail Fail Pass - Basin: CTB32 Mar Jun Sep Dec PF: 0.25 IWC: 0.96 Freq: Q A S O Pass - Pass Pass Pass SOC JOC: N Pass>100 Pass Pass Pass SOC—JOC: N SOC JOC: N C D H H Pass H Pass D Pass Pass Pass Pass SOC JOC: N D Fail Pass Fail Pass Pass SOC JOC: N D Pass Pass Pass Pass Leizend: P= Fathead minnow (Pimohales Dromelas). H=No Flow (facilitv is active), s = Split test between Certified Labs Page 44 of 98 United States Environmental Protection Agency Form Approved. EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 1 2 u 3 I NC0063096 111 121 22/12/19 I17 18 LC] I 19 I s I 20L] 21111I I I I I I I II I I I I I I I I I I I I I I I I I I I I I I I II I I I I I r6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA ---------------------- Reserved ------------------- 67 I 72 I n, I 71 I 74 79 I I I I I I I80 701 I 71 I LL -1 I I LJ Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 09:OOAM 22/12/19 17/11/01 Holly Springs WWTP 150 Treatment Plant Rd Exit Time/Date Permit Expiration Date Holly Springs NC 27540 11:OOAM 22/12/19 21/07/31 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Terry Ray Foster/ORC/919-577-1090/ Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Seann Byrd,PO Box 8 Holly Springs NC 275400008//919-577-3151/9195772280 No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit 0 Flow Measurement Operations & Maintenar Records/Reports Self -Monitoring Progran 0 Facility Site Review Compliance Schedules Effluent/Receiving Wate Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Stephanie Goss DWR/RRO WQ/919-791-4200/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type NCO063096 I11 12I 22/12/19 117 18 i c i Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Page# Permit: NCO063096 Owner -Facility: Holly Springs WWTP Inspection Date: 12/19/2022 Inspection Type: Compliance Evaluation Compliance Schedules Yes No NA NE Is there a compliance schedule for this facility? ❑ ❑ ❑ Is the facility compliant with the permit and conditions for the review period? 0 ❑ ❑ ❑ Comment: Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? 0 ❑ ❑ ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable ❑ ❑ ❑ Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new ■ ❑ ❑ ❑ application? Is the facility as described in the permit? ■ ❑ ❑ ❑ # Are there any special conditions for the permit? ❑ ❑ 0 ❑ Is access to the plant site restricted to the general public? 0 ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? 0 ❑ ❑ ❑ Comment: Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? 0 ❑ ❑ ❑ Is all required information readily available, complete and current? ■ ❑ ❑ ❑ Are all records maintained for 3 years (lab. reg. required 5 years)? 0 ❑ ❑ ❑ Are analytical results consistent with data reported on DMRs? 0 ❑ ❑ ❑ Is the chain -of -custody complete? 0 ❑ ❑ ❑ Dates, times and location of sampling ❑ Name of individual performing the sampling ❑ Results of analysis and calibration ❑ Dates of analysis ❑ Name of person performing analyses ❑ Transported COCs ❑ Are DMRs complete: do they include all permit parameters? ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ ❑ Page# 3 Permit: NCO063096 Owner -Facility: Holly Springs WWTP Inspection Date: 12/19/2022 Inspection Type: Compliance Evaluation Record Keeping Yes No NA NE (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified 0 ❑ ❑ ❑ operator on each shift? Is the ORC visitation log available and current? 0 ❑ ❑ ❑ Is the ORC certified at grade equal to or higher than the facility classification? ■ ❑ ❑ ❑ Is the backup operator certified at one grade less or greater than the facility ❑ ❑ ❑ classification? Is a copy of the current NPDES permit available on site? 0 ❑ ❑ ❑ Facility has copy of previous year's Annual Report on file for review? 0 ❑ ❑ ❑ Comment: Effluent Pipe Yes No NA NE Is right of way to the outfall properly maintained? 0 ❑ ❑ ❑ Are the receiving water free of foam other than trace amounts and other debris? 0 ❑ ❑ ❑ If effluent (diffuser pipes are required) are they operating properly? ❑ ❑ ■ ❑ Comment: Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? ■ ❑ ❑ ❑ Is flow meter calibrated annually? 0 ❑ ❑ ❑ Is the flow meter operational? 0 ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ❑ ❑ ❑ Comment: Flow Measurement - Influent Yes No NA NE # Is flow meter used for reporting? 0 ❑ ❑ ❑ Is flow meter calibrated annually? M ❑ ❑ ❑ Is the flow meter operational? 0 ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ❑ ❑ ❑ Comment: Bar Screens Yes No NA NE Type of bar screen a.Manual ❑ b.Mechanical Page# 4 Permit: NC0063096 Owner -Facility: Holly Springs WWTP Inspection Date: 12/19/2022 Inspection Type: Compliance Evaluation Bar Screens Yes No NA NE Are the bars adequately screening debris? ❑ ❑ ❑ Is the screen free of excessive debris? ❑ ❑ ❑ ■ Is disposal of screening in compliance? 0 ❑ ❑ ❑ Is the unit in good condition? 0 ❑ ❑ ❑ Comment: Grit Removal Yes No NA NE Type of grit removal a.Manual ❑ b.Mechanical Is the grit free of excessive organic matter? ❑ ❑ ❑ Is the grit free of excessive odor? 0 ❑ ❑ ❑ # Is disposal of grit in compliance? 0 ❑ ❑ ❑ Comment: Secondary Clarifier Yes No NA NE Is the clarifier free of black and odorous wastewater? 0 ❑ ❑ ❑ Is the site free of excessive buildup of solids in center well of circular clarifier? ■ ❑ ❑ ❑ Are weirs level? 0 ❑ ❑ ❑ Is the site free of weir blockage? 0 ❑ ❑ ❑ Is the site free of evidence of short-circuiting? 0 ❑ ❑ ❑ Is scum removal adequate? ■ ❑ ❑ ❑ Is the site free of excessive floating sludge? ■ ❑ ❑ ❑ Is the drive unit operational? 0 ❑ ❑ ❑ Is the return rate acceptable (low turbulence)? ❑ ❑ ❑ Is the overflow clear of excessive solids/pin floc? ■ ❑ ❑ ❑ Is the sludge blanket level acceptable? (Approximately'/4 of the sidewall depth) ■ ❑ ❑ ❑ Comment: Filtration (High Rate Tertiary) Yes No NA NE Type of operation: Cross flow Is the filter media present? ❑ ❑ 0 ❑ Is the filter surface free of clogging? 0 ❑ ❑ ❑ Page# 5 Permit: NCO063096 Inspection Date: 12/19/2022 Filtration (High Rate Tertiary) Is the filter free of growth? Is the air scour operational? Owner -Facility: Holly Springs WWTP Inspection Type: Compliance Evaluation Is the scouring acceptable? Is the clear well free of excessive solids and filter media? Comment: Disinfection - UV Are extra UV bulbs available on site? Are UV bulbs clean? Is UV intensity adequate? Is transmittance at or above designed level? Is there a backup system on site? Is effluent clear and free of solids? Comment: Standby Power Is automatically activated standby power available? Is the generator tested by interrupting primary power source? Is the generator tested under load? Was generator tested & operational during the inspection? Do the generator(s) have adequate capacity to operate the entire wastewater site? Is there an emergency agreement with a fuel vendor for extended run on back-up power? Is the generator fuel level monitored? Comment: Laboratory Are field parameters performed by certified personnel or laboratory? Are all other parameters(excluding field parameters) performed by a certified lab? # Is the facility using a contract lab? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ❑ ❑ ❑ ■ ■ ❑ ❑ ❑ Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ❑ ❑ ❑ ■ ■ ❑ ❑ ❑ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ Page# 6 Permit: NCO063096 Inspection Date: 12/19/2022 Owner -Facility: Holly Springs WWTP Inspection Type: Compliance Evaluation Laboratory Incubator (BOD) set to 20.0 degrees Celsius +/- 1.0 degrees? Comment: Effluent Sampling Is composite sampling flow proportional? Is sample collected below all treatment units? Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type representative)? Comment: Oxidation Ditches Are the aerators operational? Are the aerators free of excessive solids build up? # Is the foam the proper color for the treatment process? Does the foam cover less than 25% of the basin's surface? Is the DO level acceptable? Are settleometer results acceptable (> 30 minutes)? Is the DO level acceptable?(1.0 to 3.0 mg/1) Are settelometer results acceptable?(400 to 800 ml/I in 30 minutes) Yes No NA NE ■ ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ Comment: There was foa on approx. 50% of thesurface of basin #2 due to the basin iust being brought into use and the empty basin had duckweek and some debris in it. Mr. Foster stated they foam is being eliminated as the basin is in operation. Page# 7 NH3/TRC WLA Calculations Town of Holly Springs - Utley Creek WRF Permit No. NC0063096 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 6 Enter s7Q10 (cfs): 0.11 Enter w7Q10 (cfs): 0.25 Total Residual Chlorine (TRC) Ammonia (Summer) Daily Maximum Limit (ug/1) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 0.11 s7Q10 (CFS) 0.11 DESIGN FLOW (MGD) 6 DESIGN FLOW (MGD) 6 DESIGN FLOW (CFS) 9.3 DESIGN FLOW (CFS) 9.3 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 98.83 IWC (%) 98.83 Allowable Conc. (ug/1) 17 Allowable Conc. (mg/1) 1.0 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 0.25 Monthly Average Limit: 200/100ml DESIGN FLOW (MGD) 6 (If DF >331; Monitor) DESIGN FLOW (CFS) 9.3 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 1.01 Upstream Bkgd (mg/1) 0.22 IWC (%) 97.38 Allowable Conc. (mg/1) 1.8 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/I Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) NH3/TRC WLA Calculations Town of Holly Springs - Utley Creek WRF Permit No. NC0063096 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 8 Enter s7Q10 (cfs): 0.11 Enter w7Q10 (cfs): 0.25 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 0.11 s7Q10 (CFS) 0.11 DESIGN FLOW (MGD) 8 DESIGN FLOW (MGD) 8 DESIGN FLOW (CFS) 12.4 DESIGN FLOW (CFS) 12.4 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 99.12 IWC (%) 99.12 Allowable Conc. (ug/1) 17 Allowable Conc. (mg/1) 1.0 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 0.25 Monthly Average Limit: 200/100m1 DESIGN FLOW (MGD) 8 (If DF >331; Monitor) DESIGN FLOW (CFS) 12.4 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 1.01 Upstream Bkgd (mg/1) 0.22 IWC (%) 98.02 Allowable Conc. (mg/1) 1.8 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/l to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/l Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Project Information Table 2. Parameters of Concern ❑ CHECK IF HQW OR ORW WQS Name WQS Type Chronic Modifier Facility Name WWTP/WTP Class NPDES Permit Outfal I Flow, Qw (MGD) Receiving Stream HUC Number Stream Class Town of Holly Springs - Utley Creek WRF Grade IV NCO063096 001 6.000 Utley Creek 03030004 C ❑ Apply WS Hardness WQC 7Q10s (cfs) 7Q10w (cfs) 30Q2 (cfs) QA (cfs) 1 Q10s (cfs) 0.11 0.25 0.32 0.82 0.09 Effluent Hardness Upstream Hardness Combined Hardness Chronic - - - - - - - - - - - - - Combined Hardness Acute 135.23 mg/L (Avg) 24.35 mg/L (Avg) 133.94 mg/L - - - - - - - - - - - - - - - - - - - - - - 134.17 mg/L Data Source(s) Data sources include permittee-submitted DMRs and PPAs. ❑ CHECK TO APPLY MODEL Par01 Par02 Par03 Par04 Par05 Par06E Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 2.0943 FW 14.0173 ug/L Chlorides Aquatic Life NC 230 FW mg/L Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 465.4930 FW 3583.6348 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 33.0717 FW 50.9995 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 18.7823 FW 482.8924 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 154.0306 FW 1388.8440 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 5.3331 ug/L Zinc Aquatic Life NC 525.4573 FW 521.9635 ug/L Antimony Aquatic Life NC 640 FW pg/L Thallium Aquatic Life NC 2 FW pg/L 63096 RPA 6.0 MGD, input 4/28/2023 REASONABLE POTENTIAL ANALYSIS H1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Effluent Hardness I Date Data BDL=1/2DL 1 /6/2020 132 132 2/3/2020 116 116 3/2/2020 109 109 4/8/2020 118 118 5/4/2020 139 139 6/2/2020 136 136 7/7/2020 130 130 8/3/2020 129 129 9/2/2020 123 123 10/7/2020 150 150 11 /2/2020 140 140 12/9/2020 132 132 1 /6/2021 94.9 94.9 2/1 /2021 104 104 3/1/2021 89.2 89.2 3/31 /2021 110 110 4/7/2021 122 122 5/3/2021 122 122 6/2/2021 92.5 92.5 7/7/2021 154 154 8/4/2021 165 165 9/1 /2021 175 175 10/6/2021 151 151 11 /3/2021 132 132 12/1 /2021 160 160 1 /5/2022 136 136 2/10/2022 114 114 3/2/2022 122 122 4/6/2022 128 128 5/3/2022 139 139 6/8/2022 131 131 7/6/2022 174 174 8/3/2022 173 173 9/6/2022 193 193 10/5/2022 152 152 11 /9/2022 172 172 12/14/2022 144 144 Results Std Dev. Mean C.V. n 10th Per value Average Value Max. Value Use "PASTE SPECIAL - Values" then "COPY". Maximum data points = 58 24.5860 135.2324 0.1818 37 107.00 mg/L 135.23 mg/L 193.00 mg/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Upstream Hardness Values" then "COPY". Maximum data points = 58 Date Data BDL=1/2DL Results 11 /14/2017 20 20 Std Dev. 3.1628 1 /31 /2018 28 28 Mean 24.3458 4/17/2018 28 28 C.V. 0.1299 6/6/2018 24 24 n 24 7/5/2018 24 24 10th Per value 20.64 mg/L 9/5/2018 28 28 Average Value 24.35 mg/L 11/8/2018 28 28 Max. Value 29.30 mg/L 2/13/2019 25.7 25.7 5/6/2019 23 23 5/20/2019 23 23 8/6/2019 20.1 20.1 11 /4/2019 23.3 23.3 2/5/2020 27.1 27.1 5/4/2020 24.1 24.1 8/3/2020 15.5 15.5 11 /2/2020 24.2 24.2 2/1 /2021 21.9 21.9 5/26/2021 24.3 24.3 8/4/2021 23.9 23.9 11 /2/2021 23.3 23.3 2/9/2022 29.3 29.3 5/2/2022 23 23 8/3/2022 24.6 24.6 11 /7/2022 28 28 63096 RPA 6.0 MGD, data -2- 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Date Data 1 2 2/6/2018 < 3 5/23/2018 4 8/14/2018 < 5 8/3/2022 < 6 9/6/2022 < 7 11 /9/2022 < 8 12/14/2022 < 9 2/6/2018 < 10 5/16/2019 < 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Arsenic Use "PASTE SPECIAL - Values" then "COPY". Par03 Beryllium Maximum data points = 58 BDL=1/2DL Results Date Data BDL=1/2DL Results Std Dev. 0.3909 1 8/14/2018 < 0.5 0.25 Std Dev. 2 1 Mean 1.0556 2 5/16/2019 < 0.5 0.25 Mean 2 2 C.V. (default) 0.6000 3 2/6/2018 < 0.5 0.25 C.V. (default) 2 1 n 9 4 8/1 /2020 < 1 0.5 n 1 0.5 5 2 1 Mult Factor = 1.81 6 Mult Factor = 2 1 Max. Value 2.0 ug/L 7 Max. Value 2 1 Max. Pred Cw 3.6 ug/L 8 Max. Pred Cw 2 1 9 2 1 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY". Maximum data points = 58 0.1250 0.3125 0.6000 4 2.59 0.50 ug/L 1.30 ug/L -3- 63096 RPA 6.0 MGD, data 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par04 Par05 Use "PASTE SPECIAL - Use "PASTE SPECIAL - Cadmium Values" then "COPY". Chlorides Values" then "COPY". Maximum data points Maximum data points = 58 = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 12/20/2017 < 2 1 Std Dev. 0.1962 1 12/20/2017 97 97 Std Dev. 11.6708 2 2/6/2018 < 0.15 0.075 Mean 0.1553 2 2/6/2018 90 90 Mean 78.1 3 5/23/2018 0.15 0.15 C.V. 1.2635 3 5/23/2018 94 94 C.V. 0.1494 4 8/14/2018 < 0.15 0.075 n 33 4 8/14/2018 66 66 n 30 5 11 /8/2018 < 0.15 0.075 5 11 /8/2018 70 70 6 2/5/2019 < 0.15 0.075 Mult Factor = 1.32 6 2/5/2019 63 63 Mult Factor = 1.1 7 5/16/2019 < 0.15 0.075 Max. Value 1.000 ug/L 7 5/16/2019 75 75 Max. Value 99.3 mg/L 8 8/6/2019 < 1 0.5 Max. Pred Cw 1.320 ug/L 8 6/28/2019 76 76 Max. Pred Cw 104.3 mg/L 9 11 /6/2019 < 1 0.5 9 8/6/2019 83.9 83.9 10 2/3/2020 < 0.1 0.05 10 11 /6/2019 81.3 81.3 11 5/4/2020 < 0.1 0.05 11 2/3/2020 62 62 12 8/3/2020 < 0.1 0.05 12 5/6/2020 72.6 72.6 13 11 /2/2020 < 0.1 0.05 13 8/3/2020 82 82 14 2/1 /2021 < 0.1 0.05 14 11 /2/2020 58.3 58.3 15 3/31 /2021 < 0.2 0.1 15 2/1 /2021 54.1 54.1 16 4/7/2021 < 0.2 0.1 16 3/31 /2021 76 76 17 5/3/2021 < 0.2 0.1 17 4/7/2021 87.7 87.7 18 7/7/2021 < 0.2 0.1 18 5/3/2021 91 91 19 8/4/2021 < 0.2 0.1 19 8/4/2021 99.3 99.3 20 10/6/2021 < 0.2 0.1 20 10/6/2021 81 81 21 11 /3/2021 < 0.2 0.1 21 11 /3/2021 72.6 72.6 22 12/1 /2021 < 0.2 0.1 22 12/1 /2021 74.6 74.6 23 1 /5/2022 < 0.2 0.1 23 1 /5/2022 64.6 64.6 24 2/10/2022 < 0.2 0.1 24 2/10/2022 92.9 92.9 25 3/2/2022 < 0.2 0.1 25 3/2/2022 92.2 92.2 26 4/6/2022 < 0.2 0.1 26 4/6/2022 78.4 78.4 27 5/3/2022 < 0.2 0.1 27 5/3/2022 74.3 74.3 28 6/8/2022 < 0.5 0.25 28 6/8/2022 83.4 83.4 29 8/3/2022 < 1 0.5 29 8/3/2022 74.3 74.3 30 9/6/2022 < 0.15 0.075 30 11 /9/2022 75.4 75.4 31 10/5/2022 < 0.15 0.075 31 32 11 /9/2022 < 0.15 0.075 32 33 12/14/2022 < 0.15 0.075 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 63096 RPA 6.0 MGD, data -4- 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par06 Par07 Use "PASTE SPECIAL - Chlorinated Phenolic Compounds values" then "COPY Maximum data points = 58 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Total Phenolic Compounds 1 Date Data 2/6/2018 NO DATA NO DATA 2 5/16/2019 < NO DATA 3 8/1/2020 < 0 4 5 N/A 6 N/A ug/L 7 N/A ug/L 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 BDL=1/2DL Results 22 22 Std Dev. 10 5 Mean 20 10 C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY". Maximum data points = 58 8.7369 12.3333 0.6000 3 3.00 22.0 ug/L 66.0 ug/L 63096 RPA 6.0 MGD, data -5- 4/28/2023 REASONABLE POTENTIAL ANALYSIS 63096 RPA 6.0 MGD, data 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par10 Chromium, Total Date Data BDL=1/2DL Results 1 12/20/2017 < 5 2.5 Std Dev. 2 2/6/2018 2.5 2.5 Mean 3 5/23/2018 3.13 3.13 C.V. 4 8/14/2018 2.9 2.9 n 5 11 /8/2018 < 2 1 6 2/5/2019 2.45 2.45 Mult Factor = 7 5/16/2019 < 2 1 Max. Value 8 8/6/2019 < 5 2.5 Max. Pred Cw 9 11 /6/2019 < 5 2.5 10 2/3/2020 < 5 2.5 11 5/4/2020 < 5 2.5 12 8/3/2020 < 5 2.5 13 11 /2/2020 < 5 2.5 14 2/1/2021 < 5 2.5 15 3/31 /2021 < 5 2.5 16 4/7/2021 < 5 2.5 17 5/3/2021 < 5 2.5 18 7/7/2021 < 5 2.5 19 8/4/2021 < 5 2.5 20 10/6/2021 < 5 2.5 21 11 /3/2021 < 5 2.5 22 12/1/2021 < 5 2.5 23 1 /5/2022 < 5 2.5 24 2/10/2022 < 5 2.5 25 3/2/2022 < 5 2.5 26 4/6/2022 < 5 2.5 27 5/3/2022 < 5 2.5 28 6/8/2022 < 5 2.5 29 8/3/2022 < 1 0.5 30 9/6/2022 < 2 1 31 10/5/2022 < 2 1 32 11 /9/2022 < 2 1 33 12/14/2022 < 2 1 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Pall Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 0.6850 2.1964 0.3119 33 1.09 3.1 Ng/L 3.4 dig/L Use "PASTE SPECIAL - Copper Values" then "COPY". Maximum data points = 58 Date Data BDL=1/2DL Results 1 12/20/2017 4 4 Std Dev. 2 2/6/2018 2.63 2.63 Mean 3 5/23/2018 2.57 2.57 C.V. 4 8/14/2018 2.52 2.52 n 5 11 /8/2018 3.58 3.58 6 2/5/2019 8.71 8.71 Mult Factor = 7 5/16/2019 2.71 2.71 Max. Value 8 8/6/2019 < 2.5 1.25 Max. Pred Cw 9 11 /6/2019 1.3 1.3 10 2/3/2020 0.8 0.8 11 5/4/2020 0.52 0.52 12 8/3/2020 1.2 1.2 13 11 /2/2020 0.78 0.78 14 2/1 /2021 1.1 1.1 15 3/31 /2021 < 2 1 16 4/7/2021 < 2 1 17 5/3/2021 < 2 1 18 7/7/2021 < 2 1 19 8/4/2021 < 2 1 20 10/6/2021 < 2 1 21 11 /3/2021 < 2 1 22 12/1 /2021 < 2 1 23 1 /5/2022 < 2 1 24 2/10/2022 < 2 1 25 3/2/2022 < 2 1 26 4/6/2022 < 2 1 27 5/3/2022 < 2 1 28 6/8/2022 < 5 2.5 29 8/3/2022 1.26 1.26 30 9/6/2022 < 2 1 31 10/5/2022 < 2 1 32 11 /9/2022 < 2 1 33 12/14/2022 < 2 1 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 1.5246 1.6494 0.9243 33 1.25 8.71 ug/L 10.89 ug/L -7- 63096 RPA 6.0 MGD, data 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par12 Date Data 1 12/20/2017 < 2 2/6/2018 < 3 5/23/2018 < 4 8/14/2018 < 5 11 /8/2018 < 6 2/5/2019 < 7 5/16/2019 < 8 8/6/2019 < 9 11 /6/2019 < 10 2/3/2020 < 11 5/6/2020 < 12 8/3/2020 < 13 11 /2/2020 < 14 2/1/2021 < 15 3/31 /2021 < 16 4/7/2021 < 17 5/3/2021 < 18 8/4/2021 < 19 10/6/2021 < 20 11 /3/2021 < 21 12/1/2021 < 22 1 /5/2022 < 23 2/10/2022 < 24 3/2/2022 < 25 4/6/2022 < 26 5/3/2022 < 27 6/8/2022 < 28 8/3/2022 < 29 9/6/2022 < 30 10/5/2022 < 31 11 /9/2022 < 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Par13 Use "PASTE SPECIAL- Use "PASTE SPECIAL - Cyanide Values" then "COPY". Fluoride Values" then "COPY". Maximum data points Maximum data points = 58 = 58 BDL=1/2DL Results Date Data BDL=1/2DL Results 5 5 Std Dev. 0.0000 1 Std Dev. NO DATA 5 5 Mean 5.00 2 Mean NO DATA 5 5 C.V. 0.0000 3 C.V. NO DATA 5 5 n 31 4 n 0 5 5 5 5 5 Mult Factor = 1.00 6 Mult Factor = N/A 5 5 Max. Value 5.0 ug/L 7 Max. Value N/A ug/L 5 5 Max. Pred Cw 5.0 ug/L 8 Max. Pred Cw N/A ug/L 5 5 9 5 5 10 5 5 11 5 5 12 5 5 13 5 5 14 5 5 15 5 5 16 5 5 17 5 5 18 5 5 19 5 5 20 5 5 21 5 5 22 5 5 23 5 5 24 5 5 25 5 5 26 5 5 27 5 5 28 5 5 29 5 5 30 5 5 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 63096 RPA 6.0 MGD, data -8- 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par14 Date 1 1 /6/2020 < 2 2/3/2020 < 3 3/2/2020 < 4 4/8/2020 < 5 5/4/2020 < 6 6/2/2020 < 7 7/7/2020 < 8 8/3/2020 < 9 9/2/2020 < 10 10/7/2020 < 11 11 /2/2020 < 12 12/9/2020 < 13 1 /6/2021 < 14 2/1/2021 < 15 3/1/2021 < 16 3/31 /2021 < 17 4/7/2021 < 18 5/3/2021 < 19 6/2/2021 < 20 7/7/2021 < 21 8/4/2021 < 22 9/1/2021 < 23 10/6/2021 < 24 11 /3/2021 < 25 12/1/2021 < 26 1 /5/2022 < 27 2/10/2022 < 28 3/2/2022 < 29 4/6/2022 < 30 5/3/2022 < 31 6/8/2022 < 32 7/6/2022 < 33 8/3/2022 < 34 9/6/2022 < 35 10/5/2022 < 36 11 /9/2022 < 37 12/14/2022 < 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Par15 Use "PASTE SPECIAL- Use "PASTE SPECIAL - Lead Values" then "COPY". Mercury Values" then "COPY". Maximum data points Maximum data points = 58 = 58 BDL=1/2DL Results Date Data BDL=1/2DL Results 0.1 0.05 Std Dev. 1.1345 1 Std Dev. NO DATA 0.1 0.05 Mean 1.6311 2 Mean NO DATA 0.1 0.05 C.V. 0.6955 3 C.V. NO DATA 0.1 0.05 n 37 4 n 0 0.1 0.05 5 0.1 0.05 Mult Factor = 1.15 6 Mult Factor = N/A 0.1 0.05 Max. Value 2.500 ug/L 7 Max. Value N/A ng/L 5 2.5 Max. Pred Cw 2.875 ug/L 8 Max. Pred Cw N/A ng/L 5 2.5 9 5 2.5 10 5 2.5 11 5 2.5 12 5 2.5 13 5 2.5 14 5 2.5 15 5 2.5 16 5 2.5 17 5 2.5 18 5 2.5 19 5 2.5 20 5 2.5 21 5 2.5 22 5 2.5 23 5 2.5 24 5 2.5 25 5 2.5 26 5 2.5 27 5 2.5 28 5 2.5 29 5 2.5 30 1 0.5 31 1 0.5 32 1 0.5 33 0.5 0.25 34 0.5 0.25 35 0.5 0.25 36 0.5 0.25 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 63096 RPA 6.0 MGD, data -9- 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par16 Date Data 1 12/20/2017 < 2 2/6/2018 < 3 5/23/2018 4 8/14/2018 5 8/3/2022 < 6 9/6/2022 7 10/5/2022 8 11 /9/2022 < 9 12/14/2022 < 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Par17 & Par18 Use "PASTE SPECIAL- Use "PASTE SPECIAL - Molybdenum Values" then "COPY". Nickel Values" then "COPY". Maximum data points Maximum data points = 58 = 58 BDL=1/2DL Results Date Data BDL=1/2DL Results 5 2.5 Std Dev. 2.4306 1 Std Dev. 0.5069 2 1 Mean 2.9100 2 2/6/2018 2.63 2.63 Mean 2.4391 3.48 3.48 C.V. (default) 0.6000 3 5/23/2018 2.98 2.98 C.V. 0.2078 8.71 8.71 n 9 4 8/14/2018 2.59 2.59 n 32 5 2.5 5 11 /8/2018 4.53 4.53 2 2 Mult Factor = 1.81 6 2/5/2019 2.01 2.01 Mult Factor = 1.06 4 4 Max. Value 8.7 ug/L 7 5/16/2019 2.04 2.04 Max. Value 4.5 Ng/L 2 1 Max. Pred Cw 15.8 ug/L 8 8/6/2019 < 5 2.5 Max. Pred Cw 4.8 Ng/L 2 1 9 11 /6/2019 < 5 2.5 10 2/3/2020 < 5 2.5 11 5/4/2020 < 5 2.5 12 8/3/2020 < 5 2.5 13 11 /2/2020 < 5 2.5 14 2/1 /2021 < 5 2.5 15 3/31 /2021 < 5 2.5 16 4/7/2021 < 5 2.5 17 5/3/2021 < 5 2.5 18 7/7/2021 < 5 2.5 19 8/4/2021 < 5 2.5 20 10/6/2021 < 5 2.5 21 11 /3/2021 < 5 2.5 22 12/1 /2021 < 5 2.5 23 1 /5/2022 < 5 2.5 24 2/10/2022 < 5 2.5 25 3/2/2022 < 5 2.5 26 4/6/2022 < 5 2.5 27 5/3/2022 < 5 2.5 28 6/8/2022 < 5 2.5 29 8/3/2022 1.37 1.37 30 9/6/2022 2 2 31 10/5/2022 2.1 2.1 32 11 /9/2022 1.9 1.9 33 12/14/2022 1.4 1.4 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 -10- 63096 RPA 6.0 MGD, data 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par19 Date Data 1 2 2/6/2018 < 3 5/23/2018 4 8/14/2018 < 5 12/9/2020 < 6 8/3/2022 < 7 9/6/2022 < 8 10/5/2022 < 9 11 /9/2022 < 10 12/14/2022 < 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Par20 Use "PASTE SPECIAL- Use "PASTE SPECIAL - Selenium Values" then "COPY". Silver Values" then "COPY". Maximum data points Maximum data points = 58 = 58 BDL=1/2DL Results Date Data BDL=1/2DL Results Std Dev. 0.7906 1 Std Dev. 0.1208 5 2.5 Mean 0.9167 2 2/6/2018 < 0.5 0.25 Mean 0.2563 2 2 C.V. (default) 0.6000 3 5/23/2018 0.5 0.5 C.V. (default) 0.6000 2 1 n 9 4 8/14/2018 < 0.5 0.25 n 8 0.5 0.25 5 8/3/2022 < 0.1 0.05 1 0.5 Mult Factor = 1.81 6 9/6/2022 < 0.5 0.25 Mult Factor = 1.90 1 0.5 Max. Value 2.5 ug/L 7 10/5/2022 < 0.5 0.25 Max. Value 0.500 ug/L 1 0.5 Max. Pred Cw 4.5 ug/L 8 11/9/2022 < 0.5 0.25 Max. Pred Cw 0.950 ug/L 1 0.5 9 12/14/2022 < 0.5 0.25 1 0.5 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 63096 RPA 6.0 MGD, data - 11 - 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par21 Date Data 1 12/20/2017 2 2/6/2018 3 5/23/2018 4 8/14/2018 5 11 /8/2018 6 2/5/2019 7 5/16/2019 8 8/6/2019 9 11 /6/2019 10 2/3/2020 11 5/4/2020 12 8/3/2020 13 11 /2/2020 14 2/1/2021 15 3/31 /2021 16 4/7/2021 17 5/3/2021 18 7/7/2021 19 8/4/2021 20 10/6/2021 21 11 /3/2021 22 12/1 /2021 23 1 /5/2022 24 2/10/2022 25 3/2/2022 26 4/6/2022 27 5/3/2022 28 6/8/2022 29 8/3/2022 30 9/6/2022 31 10/5/2022 32 11 /9/2022 33 12/14/2022 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Par22 Use "PASTE SPECIAL- ZInC Values" then "COPY" . Maximum data points = 58 BDL=1/2DL Results 44 44 Std Dev. 37.4 37.4 Mean 42 42 C.V. 42.7 42.7 n 33.3 33.3 95.5 95.5 Mult Factor = 43 43 Max. Value 37.1 37.1 Max. Pred Cw 47.4 47.4 66.6 66.6 37 37 26.1 26.1 40.5 40.5 50.1 50.1 53.8 53.8 48.6 48.6 49.6 49.6 48.6 48.6 48 48 62 62 79.4 79.4 52.4 52.4 130 130 56 56 46.9 46.9 45.5 45.5 41.7 41.7 37.7 37.7 27.9 27.9 31 31 25 25 24 24 26 26 21.1218 47.7818 0.4420 33 1.13 130.0 ug/L 146.9 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Antimony Date Data BDL=1/2DL Results 8/14/2018 0.65 0.65 Std Dev. 2/6/2019 0.79 0.79 Mean 5/16/2019 < 0.5 0.25 C.V. (default) 8/1 /2020 < 5 2.5 n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY". Maximum data points = 58 0.9950 1.0475 0.6000 4 2.59 2.500000 pg/L 6.475000 pg/L -12- 63096 RPA 6.0 MGD, data 4/28/2023 REASONABLE POTENTIAL ANALYSIS Par23 Par24 Use "PASTE SPECIAL- Use "PASTE SPECIAL - Thallium Values" then "COPY". O Values" then "COPY". Maximum data points Maximum data points = 58 = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 8/14/2018 < 0.5 0.25 Std Dev. 2.3750 1 Std Dev. NO DATA 2 2/6/2018 < 0.5 0.25 Mean 1.4375 2 Mean NO DATA 3 5/16/2019 < 0.5 0.25 C.V. (default) 0.6000 3 C.V. NO DATA 4 8/1/2020 < 10 5 n 4 4 n 0 5 5 6 Mult Factor = 2.59 6 Mult Factor = N/A 7 Max. Value 5.000000 dig/L 7 Max. Value N/A 8 Max. Pred Cw 12.950000 dig/L 8 Max. Pred Cw N/A 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 63096 RPA 6.0 MGD, data -13- 4/28/2023 Town of Holly Springs - Utley Creek WRF Outfall 001 NCO063096 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Qw (MGD) = 6.0000 1Q10S (cfs) = 0.09 7Q10S (cfs) = 0.11 7Q10W (cfs) = 0.25 30Q2 (cfs) = 0.32 Avg. Stream Flow, QA (cfs) = 0.82 Receiving Stream: Utley Creek HUC 03030004 WWTP/WTP Class: Grade IV IWC% @ 1Q10S = 99.04153355 IWC% @ 7Q10S = 98.83103082 IWC% @ 7Q10W = 97.38219895 IWC% @ 30Q2 = 96.67359667 IW%C @ QA = 91.8972332 Stream Class: C Qw = 6 MGD COMBINED HARDNESS (mg/L) Acute = 134.17 mg/L Chronic = 133.94 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J Applied Chronic Acute0. n # Det. Max Pred Cw Allowable Cw Standard Acute (FW): 343.3 Arsenic C 150 FW(7Q10s) 340 ug/L 9 1 3.6 _____ Chronic (FW) 151.8 C.V. (default) Nw o value > Allowable Arsenic C 10 HH/WS(Qavg) ug/L Note: n < 9 __ ___ _ _ _ Chronic (HH) 10.9 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute: 65.63 Beryllium NC 6.5 FW(7Q10s) 65 ug/L 4 0 1.30 ___ _ ______ ____ _ _ _ _ _ _ _ _ __________ Note: n < 9 C.V. (default) Chronic: 6.58 No detects. No monitoring required. Limited data set NO DETECTS Max MDL = 1 Acute: 14.153 Cadmium NC 2.0943 FW(7Q10s) 14.0173 ug/L 33 1 1.320 ------------------------------------------------ Chronic: 2.119 All nondetects with one detection at 0.15 ug/L. No No value > Allowable Cw limits or monitoring required. Acute: NO WQS Chlorides NC 230 FW(7Q10s) mg/L 30 30 104.3 ------------------------------------------------ Chronic: 232.7 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A --Chronic: ----- 1-0--- --------------------------- Acute: NO WQS Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 1 66.0 Note: n < 9 C.V. (default) _ _ _ _ _ _ _ _ _ _ Chronic: 310.3 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute: 3,618.3 Chromium III NC 465.4930 FW(7Q10s) 3583.6348 µg/L 0 0 N/A -_ _ ----- -_ -- _ ---- Chronic: --------------------------- Acute: 16.2 Chromium VI NC 11 FW(7Q10s) 16 µg/L 0 0 N/A -_ _ ----- _ - _ -Chronic: --- --------------------------- Tot Cr value(s) < 5 and < Cr VI Allowable Cw Chromium, Total NC µg/L 33 4 3.4 Max reported value = 3.13 a: No monitoring required if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. 63096 RPA 6.0 MGD, rpa Page 14 of 16 4/28/2023 Town of Holly Springs - Utley Creek WRF Outfall 001 NCO063096 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 6 MGD Acute: 51.49 Copper NC 33.0717 FW(7Q10s) 50.9995 ug/L 33 14 10.89 Chronic: 33.46 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 22.2 Cyanide NC 5 FW(7Q10s) 22 10 ug/L 31 0 5.0 -_ _ ----- ---- -Chronic: 5 1 --------------------------- No detects. No monitoring required. NO DETECTS Max MDL 10 Acute: NO WQS Fluoride NC 1800 FW(7Q10s) ug/L 0 0 N/A -_ _ ----_ _ -Ch-- Chronic: 1,8- --------------------------- Acute: 487.566 Lead NC 18.7823 FW(7Q10s) 482.8924 ug/L 37 0 2.875 ------------------------------------------------ Chronic: 19.004 No detects. No monitoring required. NO DETECTS Max MDL = 5 Acute: NO WQS Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A --Chronic: ----- --- --------------------------- 12.1 Acute: NO WQS Molybdenum NC 2000 HH(7Q 1 Os) ug/L 9 4 15.8 Note: n < 9 C.V. (default) Chronic: 2,023.7 No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute (FW): 1,402.3 Nickel NC 154.0306 FW(7Q10s) 1388.8440 µg/L 32 11 4.8 _ _ _ _ _ _ _ _ _ _ _ _ Chronic (FW) 155.9 _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No N_o value > Allowable Cw Monitoring required Nickel NC 25.0000 WS(7Q10s) µg/L Chronic (WS) 25.3 No value > Allowable Cw Acute: 56.5 Selenium NC 5 FW(7Q10s) 56 ug/L 9 1 4.5 Note: n < 9 C.V. (default) _ _ _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 5.1 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute: 5.385 Silver NC 0.06 FW(7Q10s) 5.3331 ug/L 8 1 0.950 Note: n < 9 C.V. (default) _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 0.061 _ _ _ _ _ _ _ _ _ _ _ _ _ All nondetects at < 0.5 - < 0.1 ug/L with 1 detect at Limited data set 7 values > Allowable Cw 0.5 ug/L (< PQL of 1 ug/L). No monitoring. Acute: 527.0 Zinc NC 525.4573 FW(7Q10s) 521.9635 ug/L 33 33 146.9 ------------------------------------------------ Chronic: 531.7 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Antimony NC 640 FW(7Q10s) µg/L 4 2 6.47500 Note: n < 9 C.V. (default) Chronic: 647.56989 No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute: NO WQS Thallium NC 2 FW(7Q lOs) µg/L 4 0 12.95000 Note: n < 9 C.V. (default) _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 2.02366 _ _ _ _ _ _ _ _ _ _ _ _ _ All nondetects with one at < 10 ug/L (PQL < 2.0 ug/L). Limited data set NO DETECTS Max MDL = 10 No monitoring required, but analyze to PQL Acute: 63096 RPA 6.0 MGD, rpa Page 15 of 16 4/28/2023 Town of Holly Springs - Utley Creek WRF Outfall 001 NCO063096 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 6 MGD 0 0 N/A _ _ ------------- Chronic: --------------------------- Acute: 0 0 N/A --Chronic:----------- --------------------------- 63096 RPA 6.0 MGD, rpa Page 16 of 16 4/28/2023 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Table 1. Project Information ❑ CHECK IF HQW OR ORW WQS Facility Name Town of Holly Springs - Utley Creek WRF WWTP/WTP Class Grade IV NPDES Permit NCO063096 Outfal I 001 Flow, Qw (MGD) 8.000 Receiving Stream Utley Creek HUC Number 03030004 Stream Class ❑ Apply WS Hardness WQC C 7Q10s (cfs) 0.11 7Q10w (cfs) 0.25 30Q2 (cfs) 0.32 QA (cfs) 0.82 1 Q10s (cfs) 135.23 mg/L (Avg) Effluent Hardness Upstream Hardness 24.35 mg/L (Avg) Combined Hardness Chronic - - - - - - - - - - - - - 134.26 mg/L - - - - - - - - - - - - - - - - - - - - - - Combined Hardness Acute 134.43 mg/L Data Source(s) Data sources include permittee-submitted DMRs and PPAs. i EL ❑ CHECK TO APPLY MODEL REQUIRED DATA ENTRY Par01 Par02 Par03 Par04 Par05 Par06E Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name WQs Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 2.0981 FW 14.0413 ug/L Chlorides Aquatic Life NC 230 FW mg/L Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 466.4070 FW 3589.4042 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 33.1394 FW 51.0940 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 18.8309 FW 483.9162 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 154.3431 FW 1391.1538 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 5.3512 ug/L Zinc Aquatic Life NC 526.5248 FW 522.8329 ug/L Antimony Aquatic Life NC 640 FW pg/L Thallium Aquatic Life NC 2 FW pg/L 63096 RPA 8.0 MGD, input 4/28/2023 Town of Holly Springs - Utley Creek WRF Outfall 001 NCO063096 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Qw (MGD) = 8.0000 1Q10S (cfs) = 0.09 7Q10S (cfs) = 0.11 7Q10W (cfs) = 0.25 30Q2 (cfs) = 0.32 Avg. Stream Flow, QA (cfs) = 0.82 Receiving Stream: Utley Creek HUC 03030004 WWTP/WTP Class: Grade IV IWC% @ 1Q10S = 99.27942354 IWC% @ 7Q10S = 99.12070344 IWC% @ 7Q10W = 98.02371542 IWC% @ 30Q2 = 97.48427673 IW%C @ QA = 93.79727685 Stream Class: C Qw = 8 MGD COMBINED HARDNESS (mg/L) Acute = 134.43 mg/L Chronic = 134.26 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J CY Applied Chronic Acutea. D n # Det. Max Pred Cw Allowable Cw Standard Acute (FW): 342.5 Arsenic C 150 FW(7Q10s) 340 ug/L 9 1 3.6 _____ Chronic (FW) 151.3 C.V. (default) Nw o value > Allowable Arsenic C 10 HH/WS(Qavg) ug/L Note: n < 9 __ ___ _ _ _ Chronic (HH) 10.7 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute: 65.47 Beryllium NC 6.5 FW(7Q10s) 65 ug/L 4 0 1.30 ___ _ ______ ____ _ _ _ _ _ _ _ _ __________ Note: n < 9 C.V. (default) Chronic: 6.56 No detects. No monitoring required. Limited data set NO DETECTS Max MDL = 1 Acute: 14.143 Cadmium NC 2.0981 FW(7Q10s) 14.0413 ug/L 33 1 1.320 ------------------------------------------------ Chronic: 2.117 All nondetects with one detection at 0.15 ug/L. No No value > Allowable Cw limits or monitoring required. Acute: NO WQS Chlorides NC 230 FW(7Q10s) mg/L 30 30 104.3 ------------------------------------------------ Chronic: 232.0 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A --Chronic: ----- 1-0--- --------------------------- Acute: NO WQS Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 1 66.0 Note: n < 9 C.V. (default) _ _ _ _ _ _ _ _ _ _ Chronic: 307.7 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute: 3,615.5 Chromium III NC 466.4070 FW(7Q10s) 3589.4042 µg/L 0 0 N/A -_ _ ----- -_ -- _ ---- Chronic: --------------------------- Acute: 16.1 Chromium VI NC 11 FW(7Q10s) 16 µg/L 0 0 N/A -_ _ ----- _ - _ -Chronic: --- --------------------------- Tot Cr value(s) < 5 and < Cr VI Allowable Cw Chromium, Total NC µg/L 33 4 3.4 Max reported value = 3.13 a: No monitoring required if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. 63096 RPA 8.0 MGD, rpa Page 2 of 3 4/28/2023 Town of Holly Springs - Utley Creek WRF Outfall 001 NCO063096 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 8 MGD Acute: 51.46 Copper NC 33.1394 FW(7Q10s) 51.0940 ug/L 33 14 10.89 _ _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 33.43 _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 22.2 Cyanide NC 5 FW(7Q10s) 22 10 ug/L 31 0 5.0 -_ _ ----- -O --- -Chronic: 5 --------------------------- No detects. No monitoring required. NO DETECTS Max MDL 10 Acute: NO WQS Fluoride NC 1800 FW(7Q10s) ug/L 0 0 N/A -_ _ ----_ -_ -Ch-- Chronic: 1, --------------------------- Acute: 487.428 Lead NC 18.8309 FW(7Q10s) 483.9162 ug/L 37 0 2.875 ------------------------------------------------ Chronic: 18.998 No detects. No monitoring required. NO DETECTS Max MDL = 5 Acute: NO WQS Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A --Chronic: ----- --- --------------------------- 12.1 Acute: NO WQS Molybdenum NC 2000 HH(7Q 1 Os) ug/L 9 4 15.8 Note: n < 9 C.V. (default) Chronic: 2,017.7 No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute (FW): 1,401.3 Nickel NC 154.3431 FW(7Q10s) 1391.1538 µg/L 32 11 4.8 _ _ _ _ _ _ _ _ _ _ _ _ Chronic (FW) 155.7 _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No N_o value > Allowable Cw Monitoring required Nickel NC 25.0000 WS(7Q10s) µg/L Chronic (WS) 25.2 No value > Allowable Cw Acute: 56.4 Selenium NC 5 FW(7Q10s) 56 ug/L 9 1 4.5 Note: n < 9 C.V. (default) _ _ _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 5.0 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute: 5.390 Silver NC 0.06 FW(7Q10s) 5.3512 ug/L 8 1 0.950 Note: n < 9 C.V. (default) _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 0.061 _ _ _ _ _ _ _ _ _ _ _ _ _ All nondetects at < 0.5 - < 0.1 ug/L with 1 detect at Limited data set 7 values > Allowable Cw 0.5 ug/L (< PQL of 1 ug/L). No monitoring. Acute: 526.6 Zinc NC 526.5248 FW(7Q10s) 522.8329 ug/L 33 33 146.9 ------------------------------------------------ Chronic: 531.2 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: NO WQS Antimony NC 640 FW(7Q10s) µg/L 4 2 6.47500 Note: n < 9 C.V. (default) Chronic: 645.67742 No RP, limited dataset. No monitoring requred. Limited data set No value > Allowable Cw Acute: NO WQS Thallium NC 2 FW(7Q I Os) µg/L 4 0 12.95000 Note: n < 9 C.V. (default) _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 2.01774 _ _ _ _ _ _ _ _ _ _ _ _ _ All nondetects with one at < 10 ug/L (PQL < 2.0 ug/L). Limited data set NO DETECTS Max MDL = 10 No monitoring required, but analyze to PQL 63096 RPA 8.0 MGD, rpa Page 3 of 3 4/28/2023 Permit No. NC0063096 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Q ality Standards/A uatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/l (Dissolved) Acute SW, µg/l (Dissolved) Chronic SW, µg/l (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 213.0200 (e.g., arsenic at 10 µg/l for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.136672-[ln hardness](0.041838)} e^{0.9151 [In hardness]-3.1485{ Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} e^{0.9151[In hardness]-3.6236} Cadmium, Chronic WER*{1.101672-[ln hardness](0.041838)} e^{0.7998[ln hardness]-4.4451} Chromium III, Acute WER*0.316 e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 e^{0.9422[ln hardness]-1.700} Copper, Chronic WER*0.960 e^{0.8545[ln hardness]-1.702} Lead, Acute WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[ln hardness]-1.4601 Lead, Chronic WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[ln hardness]-4.705} Nickel, Acute WER*0.998 e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 e^{0.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NCO063096 Silver, Acute WER*0.85 • e^{1.72[ln hardness]-6.59) Silver, Chronic Not applicable Zinc, Acute WER*0.978 e^{0.8473[ln hardness]+0.884) Zinc, Chronic WER*0.986 e^{0.8473[ln hardness]+0.884) General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WQBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q 10 (the spreadsheet automatically calculates the 1 Q 10 using the formula 1 Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NCO063096 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) _ (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q 10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q 10, cfs) The Combined Hardness for acute is the same but the calculation uses the IQ 10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { [Kpo] [ss(I+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q 10 + Qw) (Cwgs)-(s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q 10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q 10 may be incorporated as applicable: 1 Q 10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0063096 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness, mg/L 135.2 Permittee submitted DMRs (Total as CaCO3) Average Upstream Hardness, mg/L 24.3 Permittee submitted DMRs (Total as CaCO3) 7Q10 summer (cfs) 0.11 Reported in previous permit Fact Sheet 1Q10 (cfs) 0.09 Calculated in RPA spreadsheet Permitted Flow (MGD) 6018.0 Design flow Date: February 28, 2023 Permit Writer: Gary Perlmutter Page 4 of 4 4/28/23 WQS = 12 ng/L MERCURY WQBEL/TBEL EVALUATION V:2013-6 Facility Name Holly Springs - Utley Creek WWTP / NC0063096 No Limit Required /Permit No. MMP Required Total Mercury 1631E PQL = 0.5 ng/L 7Q10s = 0.730 cfs WQBEL = 12.94 ng/L Date Modifier Data Entry Value Permitted Flow = 6.000 47 ng/L 2/6/18 1.26 1.26 5/18/18 2.51 2.51 10/18/18 < 0.5 0.5 1.4 ng/L - Annual Average for 2018 5/16/19 < 0.05 0.5 0.5 ng/L - Annual Average for 2019 8/3/20 < 0.5 0.5 0.5 ng/L - Annual Average for 2020 3/31/21 < 0.5 0.5 11/17/21 < 0.5 0.5 12/15/21 < 0.5 0.5 12/29/21 0.589 0.589 0.5 ng/L - Annual Average for 2021 1/5/22 0.515 0.515 2/23/22 1.84 1.84 3/22/22 1.25 1.25 5/4/22 < 0.5 0.5 8/3/22 < 0.5 0.5 11/9/22 1.73 1.73 12/14/22 < 0.0002 0.5 1.0 ng/L - Annual Average for 2022 EPA Identification Number NPDES Number Facility Name Outfall Number NCO063096 Utley Creek Reclimation Facility 1 Method Number (if Estimated Concentration (If Pollutant (Required) CAS number Applicable) Reason Pollutant Believed Present in Discharge Known) We currently have no reason to believe any POC, with approved methods, that are not covered in Permit NCO063096 are present in the discharge from the facility. A Enter a date to enable dropdowns for other columns Analyte Name Ana lyte Acronym Date Results (ng/L) MMEN NMePFOSAE PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnDA PFTrDA PFDoDA PFTeDA PFBS PFPeS PFHxS PFHpS PFOS PFNS PFDS 4:2 FTS 6:2 FTS 8:2 FTS PFOSA N-McFOSAA N-EtFOSAA HFPO-DA PFMOAA PFMOPrA PF02HxA PF030A PF04DA NMePFOSAE ADONA 9CI-PF30NS 11CI-PF3OUdS 10:2 FTS FBSA NVHOS N-EtFOSA N-EtFOSE NFDHA N-McFOSA N-McFOSE PEPA PFECA-G PFEESA PFHxDA PFMOAA PF05DA JPMPA 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 7/28/2022 20.2 71.3 40.2 6.09 24.2 0.669 0.374 ND ND ND ND 22.6 0.665 3.36 0.14 4.02 ND ND ND 0.899 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5.48 ND ND ND ND ND ND ND ND ND ND ND ND ND Perfluorohexanesulfonic acid Perfluorobutanoic acid Perfluorobutanesulfonic acid Perfluorohe tanoic acid Perfluorododecanoic acid Perfluoro 3,5,7,9-tetraoxadecanoic acid Perfluorouodecanoic acid Perfluorooctadecanoic Perfluorododecanoic acid Perfluorononanoic acid N-meth 1 erfluoro-l-octanesulfonamide Perfluorohexanoic acid Perfluorodecanesulfonic acid Perfluorobutanesulfonic acid Perfluorohexadecanoic acid Perfluoroethox ethanesulfonic acid Perfluoro-2-methox acetic acid 11-chloroeicosafluoro-3-oxaundecane-l-sulfonate 2-(N-eth 1 erfluoro-l-octanesulfonamido)-ethanol 2- -Eth 1 erfluorooctanesulfonamido acetic acid Perfluorohexanesulfonic acid Hexafluoropropylene oxide dimer acid DFSA 9-chlorohexadecafluoro-3-oxanonane-l-sulfonate Perfluorodecanoic acid Perfluorododecanesulfonic acid Perfluoroethoxypropanoic acid Perfluoroethoxypropionic acid Perfluoroethox sulfonic acid NaflonByproduct 1 2- -meth 1 erfluoro-l-octanesulfonamido -ethanol 9-Chlorohexadecafluoro-3-oxanonane-l-sulfonic Acid (9C1- MONS) 11-Chloroeicosafluoro-3-oxaundecane-l-sulfonic Acid 11C1-PF3OUdS 10:2 fluorotelomersulfonic acid Perfluorobut lsul honamide Naflon Byproduct 2 Byproduct 6 F-53B Major Nonafluoro-3,6-dioxahe tanoic acid N-Meth 1- erfluorooctanesulfonamide MMF NEtFOSAA Perfluoro-3-methox ro anoic acid 1,1,2,2-Tetrafluoro-2- erfluoroethox ethanesulfonic acid Perfluorobutanoic acid Perfluorodecanoic acid Perfluorohe tanesulfonic acid Perfluorooctanesulfonic acid Reduction in Frequency Evalaution Facility: Utley Cr WWTP Permit No. NC0063096 Review period (use 3 01/2020 - 12/2022 yrs) Approval Criteria: Y/N? 1. Not currently under SOC Y 2. Not on EPA Quarterly noncompliance report Y 3. Facility or employees convicted of CWA violations N # of non - Monthly 3-yr mean # daily # daily Reduce Weekly 50% 200% 200% monthly #civil penalty Data Review Units average (geo mean < 50%7 samples <15? samples < 20? > 2? > 1? Frequency? average limit limit MA for FC) MA >200% WA >200% limit asessment (Yes/No) violations BOD (Weighted) mg/L 10.63 7.08 1 3.5 1.00 Y 14.17 0 Y 0 N 0 N Y TSS mg/L 45.00 30.00 15 1.23 Y 60.00 0 Y 0 N 0 N Y Ammonia (weighted) mg/L 4.25 1.42 0.7 0.06 Y 2.83 0 Y 0 N 0 N Y Fecal Coliform #/100 400.00 200.00 100 1 0.7044975 Y 800 1 Y 0 N 0 N Y