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HomeMy WebLinkAboutNC0000078_DWR ARO Groundwater Split Sampling Results_20230315 (2)PO Number # Loc. Descr.:DAVIDSON RIVER VILLAGE ECUSTA ASB-Q88V2 Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:03/15/2023 Collect Time:11:54 Date Received:03/17/2023 Time Received:07:00 Location ID:1P88Q88V2 County:Transylvania Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:SURFACEWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/24/2023 Emergency COC Yes/No Sample ID:AD08368 4/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD08368 LAB MSWIFT°CSample temperature at receipt by lab 3/17/231.6 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 4/5/230.05 0.05 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 4/5/230.03 0.17 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 3/28/230.03 0.03 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 4/11/230.4 0.4 MET EPA 200.7 Rev4.4 JJURGEVICHug/LUAl by ICP7429-90-5 3/30/235050 EPA 200.7 Rev4.4 JJURGEVICHug/LUBa by ICP7440-38-3 3/30/231010 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 3/30/235050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/28/235.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 3/28/232.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 3/30/235050 EPA 245.1 Rev3 JJURGEVICHug/LUHg 245.17439-97-6 4/6/230.20 0.20 EPA 200.7 Rev4.4 JJURGEVICHug/LUMn by ICP7439-96-5 3/30/231010 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 3/30/230.10 1.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUNi by ICPMS7440-02-0 3/28/232.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/28/232.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 3/28/231010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:DAVIDSON RIVER VILLAGE ECUSTA ASB-ASB01 Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:03/15/2023 Collect Time:13:14 Date Received:03/17/2023 Time Received:07:00 Location ID:1P88ASB01 County:Transylvania Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:SURFACEWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/24/2023 Emergency COC Yes/No Sample ID:AD08369 4/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD08369 LAB MSWIFT°CSample temperature at receipt by lab 3/17/231.6 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 4/5/230.05 0.05 EPA 353.2 REV 2 ALWILLIAMSmg/L as NUNO2+NO3 as N in liquidE701177 4/5/230.03 0.03 EPA 365.1 REV 2 ALWILLIAMSmg/L as PPhosphorus_total as P in liquid7723-14-0 3/28/230.03 0.37 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 4/11/230.4 0.4 MET EPA 200.7 Rev4.4 JJURGEVICHug/LUAl by ICP7429-90-5 3/30/235050 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 3/30/231096 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 3/30/235050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/28/235.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 3/28/232.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LFe by ICP7439-89-6 3/30/2350750 EPA 245.1 Rev3 JJURGEVICHug/LUHg 245.17439-97-6 4/6/230.20 0.20 EPA 200.7 Rev4.4 JJURGEVICHug/LMn by ICP7439-96-5 3/30/23101800 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 3/30/230.10 30 EPA 200.8 Rev5.4 JJURGEVICHug/LNi by ICPMS7440-02-0 3/28/232.0 2.7 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/28/232.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 3/28/231010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:DAVISON RIVER VILLAGE ECUSTA ASB-ASB02 Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:03/15/2023 Collect Time:14:42 Date Received:03/17/2023 Time Received:07:00 Location ID:1P88ASB02 County:Transylvania Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:SURFACEWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/24/2023 Emergency COC Yes/No Sample ID:AD08370 4/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD08370 LAB MSWIFT°CSample temperature at receipt by lab 3/17/231.6 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 4/5/230.05 0.05 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 4/5/230.03 0.68 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 3/28/230.03 0.03 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 4/11/230.4 0.4 MET EPA 200.7 Rev4.4 JJURGEVICHug/LAl by ICP7429-90-5 3/30/2350580 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 3/30/231062 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 3/30/235050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/28/235.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 3/28/232.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LFe by ICP7439-89-6 3/30/2350550 EPA 245.1 Rev3 JJURGEVICHug/LUHg 245.17439-97-6 4/6/230.20 0.20 EPA 200.7 Rev4.4 JJURGEVICHug/LUMn by ICP7439-96-5 3/30/231010 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 3/30/230.10 12 EPA 200.8 Rev5.4 JJURGEVICHug/LUNi by ICPMS7440-02-0 3/28/232.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/28/232.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 3/28/231010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:DAVIDSON RIVER Loc. Type:River/Stream Collector:B LAVERTY Collect Date:03/15/2023 Collect Time:14:57 Date Received:03/17/2023 Time Received:07:00 Location ID:1P88DAVIDSON County:Transylvania Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:SURFACEWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/24/2023 Emergency COC Yes/No Sample ID:AD08371 4/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD08371 LAB MSWIFT°CSample temperature at receipt by lab 3/17/231.6 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 4/5/230.05 0.05 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 4/5/230.03 0.05 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 3/28/230.03 0.03 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 4/11/230.4 0.4 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:FRENCH BROAD RIVER Loc. Type:River/Stream Collector:B LAVERTY Collect Date:03/15/2023 Collect Time:15:06 Date Received:03/17/2023 Time Received:07:00 Location ID:1P88FRENCHBROAD County:Transylvania Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:SURFACEWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/24/2023 Emergency COC Yes/No Sample ID:AD08372 4/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD08372 LAB MSWIFT°CSample temperature at receipt by lab 3/17/231.6 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NNH3 as N in liquid7664-41-7 4/5/230.05 0.06 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 4/5/230.03 0.11 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 3/28/230.03 0.03 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 4/11/230.4 0.4 Others EPA 365.1 REV 2 ALWILLIAMS% RSD%RPD LFM/LFMDUP forPHOSTOTP_Liq 3/28/231.709402 EPA 365.1 REV 2 ALWILLIAMSmg/L as PAmt Spiked for Phosphorus, total as P in 3/28/230.02 0.200 EPA 365.1 REV 2 ALWILLIAMS%LFM DUP Recovery for PHOSTOTP_Liq 3/28/230.01 110 EPA 365.1 REV 2 ALWILLIAMSmg/L as PLFM DUP Result for TOTALPHOSPOROUS 3/28/230.02 0.236 EPA 365.1 REV 2 ALWILLIAMSmg/L as PLFM for Phosphorus_total as P in liq 3/28/230.02 0.232 EPA 365.1 REV 2 ALWILLIAMS%LFM Recovery for PHOSTOTP_Liq 3/28/230.02 108 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. X X X X X Thallium (Tl) Tin (Sn) Titanium (Ti) X Vanadium (V) X Zinc (Zn) Mercury 1631, low-level X X X X X X X X X X Residue: Suspended (Suspended Solids )A X Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A X Silica A Sulfide A - J X Phytoplankton / Algae Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides / / Lithium (Li)A - C A - C Chromium (Cr), Total Davidson River Village ASB - Monitoring well Q88V2Location Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent QATime (24 hr): (begin/end)11:54 AM : 3/15/2023 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 1 Priority: Ambient Location Code:1P88Q88V2 Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring Well Q88V2 County:Transylvania Water Matrix: ARO Solution Routine Compliance COC Emergency Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K)A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E Sulfuric Acid - Lot#2263030; Nitric Acid- Lot#2263080 Revision 4/4/2022Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X X Thallium (Tl) Tin (Sn) Titanium (Ti) X Vanadium (V) X Zinc (Zn) Mercury 1631, low-level X X X X X X X X X X Residue: Suspended (Suspended Solids )A X Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A X Silica A Sulfide A - J X Phytoplankton / Algae Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides / / Lithium (Li)A - C A - C Chromium (Cr), Total Davidson River Village ASB - Monitoring well ASB-01Location Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent QATime (24 hr): (begin/end)1:14 PM : 3/15/2023 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 2 Priority: Ambient Location Code:1P88ASB01 Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring Well ASB-01 County:Transylvania Water Matrix: ARO Solution Routine Compliance COC Emergency Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K)A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E Sulfuric Acid - Lot#2263030; Nitric Acid- Lot#2263080 Revision 4/4/2022Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X X Thallium (Tl) Tin (Sn) Titanium (Ti) X Vanadium (V) X Zinc (Zn) Mercury 1631, low-level X X X X X X X X X X Residue: Suspended (Suspended Solids )A X Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A X Silica A Sulfide A - J X Phytoplankton / Algae Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides / / Lithium (Li)A - C A - C Chromium (Cr), Total Davidson River Village ASB - Monitoring well ASB-02Location Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Sulfuric Acid - Lot#2263030; Nitric Acid- Lot#2263080 Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent QATime (24 hr): (begin/end)2:42 PM : 3/15/2023 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 3 Priority: Ambient Location Code:1P88ASB02 Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring Well ASB-02 County:Transylvania Water Matrix: ARO Solution Routine Compliance COC Emergency Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K)A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E Revision 4/4/2022Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X Thallium (Tl) Tin (Sn) Titanium (Ti) Vanadium (V) Zinc (Zn) Mercury 1631, low-level X X X X Residue: Suspended (Suspended Solids )A Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A Silica A Sulfide A - J Phytoplankton / Algae Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides / / Lithium (Li)A - C A - C Chromium (Cr), Total Davidson River @ Old Hendersonville HighwayLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Sulfuirc Acid - Lot#2263030 Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent QATime (24 hr): (begin/end)2:57 PM : 3/15/2023 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 4 Priority: Ambient Location Code:1P88DAVIDSON Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes: County:Transylvania Water Matrix: ARO French Broad River Solution Routine Compliance COC Emergency Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K)A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E Revision 4/4/2022Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X Thallium (Tl) Tin (Sn) Titanium (Ti) Vanadium (V) Zinc (Zn) Mercury 1631, low-level X X X X Residue: Suspended (Suspended Solids )A Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A Silica A Sulfide A - J Phytoplankton / Algae Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides / / Lithium (Li)A - C A - C Chromium (Cr), Total French Broad River @ Everett RoadLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Sulfuirc Acid - Lot#2263030 Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent QATime (24 hr): (begin/end)3:06 PM : 3/15/2023 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 5 Priority: Ambient Location Code:1P88FRENCHBROAD Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes: County:Transylvania Water Matrix: ARO French Broad River Solution Routine Compliance COC Emergency Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K)A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E Revision 4/4/2022Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size