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HomeMy WebLinkAboutWQ0004967_DWR ARO Groundwater Split Sampling Results_20221128PO Number # Loc. Descr.:ALL JUICE REALTY 352 JET STREET HENDERSONVILLE Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:11/28/2022 Collect Time:10:46 Date Received:11/30/2022 Time Received:07:00 Location ID:1P45MW7 County:Henderson Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/10/2023 Emergency COC Yes/No Sample ID:AD04927 1/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD04927 LAB MSWIFT°CSample temperature at receipt by lab 11/30/223.9 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 12/13/220.02 0.02 EPA 353.2 REV 2 ALWILLIAMSmg/L as NPNO2+NO3 as N in liquidE701177 12/13/220.04 1.7 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 12/14/220.02 0.02 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 12/14/220.3 0.3 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 1/9/2310130 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 1/9/235050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 1/9/235050 EPA 200.7 Rev4.4 JJURGEVICHug/LMn by ICP7439-96-5 1/9/2310330 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 1/9/230.10 6.2 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 12/21/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 12/21/221010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:ALL JUICE REALTY 352 JET STREET HENDERSONVILLE Loc. Type:River/Stream Collector:B LAVERTY Collect Date:11/28/2022 Collect Time:11:00 Date Received:11/30/2022 Time Received:07:00 Location ID:1P45BDUS County:Henderson Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:SURFACEWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To FRBRiver Basin 04/10/2023 Emergency COC Yes/No Sample ID:AD04928 12/21/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD04928 LAB MSWIFT°CSample temperature at receipt by lab 11/30/223.9 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NNH3 as N in liquid7664-41-7 12/13/220.02 0.03 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 12/13/220.02 0.08 EPA 365.1 REV 2 ALWILLIAMSmg/L as PPhosphorus_total as P in liquid7723-14-0 12/14/220.02 0.53 EPA 351.2 REV 2 ALWILLIAMSmg/L as NTotal Kjeldahl N as N in liquidTKN_N 12/14/220.3 3.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:ALL JUICE REALTY 352 JET STREET HENDERSONVILLE Loc. Type:River/Stream Collector:B LAVERTY Collect Date:11/28/2022 Collect Time:11:35 Date Received:11/30/2022 Time Received:07:00 Location ID:1P455W1 County:Henderson Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:SURFACEWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To FRBRiver Basin 04/10/2023 Emergency COC Yes/No Sample ID:AD04929 1/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD04929 LAB MSWIFT°CSample temperature at receipt by lab 11/30/223.9 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NNH3 as N in liquid7664-41-7 12/13/220.02 0.13 EPA 353.2 REV 2 ALWILLIAMSmg/L as NUNO2+NO3 as N in liquidE701177 12/13/220.02 0.02 EPA 365.1 REV 2 ALWILLIAMSmg/L as PPhosphorus_total as P in liquid7723-14-0 12/14/220.02 0.28 EPA 351.2 REV 2 ALWILLIAMSmg/L as NTotal Kjeldahl N as N in liquidTKN_N 12/14/220.3 1.3 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 1/9/231012 EPA 200.8 Rev5.4 JJURGEVICHug/LUCd by ICPMS7440-43-9 12/21/220.50 0.50 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 1/9/235050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 12/21/225.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LCu by ICPMS7440-50-8 12/21/222.0 14 EPA 200.7 Rev4.4 JJURGEVICHug/LFe by ICP7439-89-6 1/9/23501900 EPA 200.7 Rev4.4 JJURGEVICHug/LMn by ICP7439-96-5 1/9/231044 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 1/9/230.10 22 EPA 200.8 Rev5.4 JJURGEVICHug/LPb by ICPMS7439-92-1 12/21/222.0 3.2 EPA 200.8 Rev5.4 JJURGEVICHug/LZn by ICPMS7440-66-6 12/21/221017 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:ALL JUICE REALTY 352 JET STREET HENDERSONVILLE Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:11/28/2022 Collect Time:12:58 Date Received:11/30/2022 Time Received:07:00 Location ID:1P45MW2 County:Henderson Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/10/2023 Emergency COC Yes/No Sample ID:AD04930 1/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD04930 LAB MSWIFT°CSample temperature at receipt by lab 11/30/223.9 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NPNH3 as N in liquid7664-41-7 12/13/220.5 28 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 12/13/220.02 0.04 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 12/14/220.02 0.02 EPA 351.2 REV 2 ALWILLIAMSmg/L as NPTotal Kjeldahl N as N in liquidTKN_N 12/14/22628 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 1/9/2310130 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 1/9/235050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LFe by ICP7439-89-6 1/9/23504300 EPA 200.7 Rev4.4 JJURGEVICHug/LPMn by ICP7439-96-5 1/9/2310012000 EPA 200.7 Rev4.4 JJURGEVICHmg/LPNa by ICP7440-23-5 1/9/230.3 72 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 12/21/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 12/21/221010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:ALL JUICE REALTY 352 JET STREET HENDERSONVILLE Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:11/28/2022 Collect Time:13:32 Date Received:11/30/2022 Time Received:07:00 Location ID:ARO_NLC County:Henderson Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/10/2023 Emergency COC Yes/No Sample ID:AD04931 1/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD04931 LAB MSWIFT°CSample temperature at receipt by lab 11/30/223.9 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NPNH3 as N in liquid7664-41-7 12/13/220.1 3.5 EPA 353.2 REV 2 ALWILLIAMSmg/L as NPNO2+NO3 as N in liquidE701177 12/13/220.1 4.6 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 12/14/220.02 0.02 EPA 351.2 REV 2 ALWILLIAMSmg/L as NPTotal Kjeldahl N as N in liquidTKN_N 12/14/220.6 3.4 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 1/9/2310580 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 1/9/235050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 1/9/235050 EPA 200.7 Rev4.4 JJURGEVICHug/LPMn by ICP7439-96-5 1/9/23505300 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 1/9/230.10 15 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 12/21/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 12/21/221010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:ALL JUICE REALTY 352 JET STREET HENDERSONVILLE Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:11/28/2022 Collect Time:14:31 Date Received:11/30/2022 Time Received:07:00 Location ID:ARO_NLC County:Henderson Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/10/2023 Emergency COC Yes/No Sample ID:AD04932 1/19/23Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AD04932 LAB MSWIFT°CSample temperature at receipt by lab 11/30/223.9 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 12/13/220.02 0.02 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 12/13/220.02 0.43 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 12/14/220.02 0.02 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 12/14/220.3 0.3 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 1/9/231012 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 1/9/235050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 12/21/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 1/9/235050 EPA 200.7 Rev4.4 JJURGEVICHug/LMn by ICP7439-96-5 1/9/231018 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 1/9/230.10 4.7 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 12/21/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 12/21/221010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) Mercury 1631, low-level X X X X X X X X X Residue: Suspended (Suspended Solids )A Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A Silica A Sulfide A - J X Phytoplankton / Algae A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW7 County:Henderson Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)10:46 AM : 11/28/2022 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 1 Priority: Ambient Location Code:1P45MW7 Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent / / Lithium (Li)A - C A - C Chromium (Cr), Total AllJuice Realty, LLC. - 352 Jet Street HendersonvilleLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Nitric Acid Lot #NA2263080; Sulfuric Acid Lot#SA2263030 Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides Revision 4/4/2022 Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. X X X X Thallium (Tl) Tin (Sn) Titanium (Ti) Vanadium (V) Zinc (Zn) Mercury 1631, low-level X X X X Residue: Suspended (Suspended Solids )A Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A Silica A Sulfide A - J Phytoplankton / Algae A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Boundary Ditch Upstream County:Henderson Water Matrix: ARO French Broad River Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)11:00 AM : 11/28/2022 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 2 Priority: Ambient Location Code:1P45BDUS Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent / / Lithium (Li)A - C A - C Chromium (Cr), Total AllJuice Realty, LLC. - 352 Jet Street HendersonvilleLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Sulfuric Acid Lot#SA2263030 Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides Revision 4/4/2022 Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) X Mercury 1631, low-level X X X X X X X X X X Residue: Suspended (Suspended Solids )A Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A Silica A Sulfide A - J X Phytoplankton / Algae A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Boundary Ditch SW-1 County:Henderson Water Matrix: ARO French Broad River Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)11:35 AM : 11/28/2022 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 3 Priority: Ambient Location Code:1P45SW1 Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent / / Lithium (Li)A - C A - C Chromium (Cr), Total AllJuice Realty, LLC. - 352 Jet Street HendersonvilleLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Nitric Acid Lot #NA2263080; Sulfuric Acid Lot#SA2263030 Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides Revision 4/4/2022 Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) Mercury 1631, low-level X X X X X X X X X Residue: Suspended (Suspended Solids )A Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A Silica A Sulfide A - J X Phytoplankton / Algae A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW2 County:Henderson Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)12:58 PM : 11/28/2022 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 4 Priority: Ambient Location Code:1P45MW2 Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent / / Lithium (Li)A - C A - C Chromium (Cr), Total AllJuice Realty, LLC. - 352 Jet Street HendersonvilleLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Nitric Acid Lot #NA2263080; Sulfuric Acid Lot#SA2263030 Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides Revision 4/4/2022 Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) Mercury 1631, low-level X X X X X X X X X Residue: Suspended (Suspended Solids )A Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A Silica A Sulfide A - J X Phytoplankton / Algae A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW6 County:Henderson Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)1:32 PM : 11/28/2022 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 5 Priority: Ambient Location Code:1P45MW6 Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent / / Lithium (Li)A - C A - C Chromium (Cr), Total AllJuice Realty, LLC. - 352 Jet Street HendersonvilleLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Nitric Acid Lot #NA2263080; Sulfuric Acid Lot#SA2263030 Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides Revision 4/4/2022 Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) Mercury 1631, low-level X X X X X X X X X Residue: Suspended (Suspended Solids )A Residue: Volatile/Fixed, Suspended A TDS - Total Dissolved Solids A Silica A Sulfide A - J X Phytoplankton / Algae A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) E A - C A - R Biological: E Tannin & Lignin Perfluorinated Compounds (PFAS) Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Metals Parameters Con't: A - C A - C Semi-Volatile Organics (BNAs) E E Organophosphorus Pesticides Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C Orthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt A B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A Color: ADMI Cyanide, Total Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Preservative A Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters: Aluminum (Al) A - D A - D A A - Z E A A - I Preservative Antimony (Sb) Chlorophyll a Y E E Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) A A Microcystin E Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Field Blank Calcium (Ca) Other: E A - C Login file: Conductivity (µmhos/cm): Metals Parameters: North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW9 County:Henderson Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)2:31 PM : 11/28/2022 Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 6 Priority: Ambient Location Code:1P45MW9 Brett Laverty Location Type: Monitoring Well Trip Blank / / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : Received By: E E PCBs (polychlorinated biphenyls) E E E Tag ID Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent / / Lithium (Li)A - C A - C Chromium (Cr), Total AllJuice Realty, LLC. - 352 Jet Street HendersonvilleLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: E Secchi Depth: Lot #s / Collector Comments: Filtered in Field Water Temp (oC):pH (s.u.): Nitric Acid Lot #NA2263080; Sulfuric Acid Lot#SA2263030 Field Parameters (optional): Preservative : Y Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L Organochlorine Pesticides Organonitrogen Pesticides Revision 4/4/2022 Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter.