WQ0032016_Groundwater Monitoring report March 2023_20230419

G"--59A COMPLIANCE REPORT FORIM Perm t # WQ0032016
(Siduuit wife each uuurlluriut parlor! with G)J-59.1orms.l
1
Enter date monitoring results were due. (4/30/2023 ) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
X
7
Was any required information missing on the G`rV-59 report forms'.
YE5
NO
X
tF the answer to question 1 or 2 is "YES", list in the space provided below the well identification numbers) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged easing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.).' ffrhe answer is "Ye,s ", cwr lace the Regional Q)Yicefor giridnrrce.
4
Are any monitored constituents equal to or above the established standards?
Y1 S
NO
1f the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constifuent(s) and concenlration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
1V0
same constituents) in the saute well(s) In the last two years?
If the answer to question 5 is "NO", skip to section 8. a
if the answer to question 5 is "YES", list in the space provided below, each weft with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
MW-1: pH 6.3; Fe 0.602
MW-2: pH 5.3; Fe 0,472
MW-3: Fe 18.4; Mn 0.636
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YE5
N0
If the answer is "YES" a groundwater quality problem may be occurring, CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "A10", contact the Regional QfFace within 90 da, a; an evaluation may be
reuuired to determine the impact the waste diseosal system is having at the review and compliance
,boundaries surrounding this facility. Failure to do so malr subiect the germittee to a Notice of Violation,
fines, andlor penalties.
S
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-559A))jIs true and complete to the best of mf yknowledge.
j
Y". ` 7 I q Z
Signature of Permittee (or Authorized Agent) Date
C05'-59= 11,82003

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
• •
DEPARTMENT OF ENVIRONMENTAL QUALIFY - DIV. OF WATER RESOURCES
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION Please PrintCfearfyorType
PERMIT Number: Expiration Date: 613012028
Facility Name: Rose Hill Plantation Development, LLC
Non -Discharge UIC
Permit Name (if different):
NPDES Other WQ0032016
Facility Address: 3041 New Leicester Highway
TYPE OF PERMITTED OPERATION BEING MONITORED
Leicester NC 28748 County Buncombe
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation.
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Well # 1(MW A on GW-1b)
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑0 Other: Surface Irrigation
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): Well # 1 Upgradient
Date sample collected: 3/22/2023
FIELD ANALYSES:
WAS
Well Depth: 69 ft.
Well Diameter: 2 in.
pH 00400 6.3 units Temp. aoolo; 14.1 °C
DRY at
Depth to Water Level 82546: 38-39 ft. below measuring
p g point Screened Interval: 49 ft. to
69
ft. Spec. Cond. 000s4 47.6 f`Mhos
time of
Measuring Point is 2-5 ft. above land surface
Relative M.P. Elevation: ft.
Odorsampling,
Boom: None
check
Volume of water pumpedlbailed before sampling:
gallons
Appearance Clear
here:
❑
Samples for metals were collected unfiltered ❑■ YES
El NO and field acidified: ❑■ YES [I NO
LABORATORY INFORMATION
Date sample analyzed: 402/2023
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD oo335 mglL
Nitrite (NO2) as N oo615 <0,040
mglL Pb - Lead oios1 <5.0 uglL
Coliform: MF Fecal 31616 <1 1100mL
Nitrate (NO3) as IN 00620 c0.040
mglL Zn -Zinc 01092 <10.0 mglL
Coliform: MF Total 31504 1100mL
Phosphorus: Total as P oo665 0.084
mg/L
(Note: Use MPN method for highly turbid Samples)
Orthophosphate 70507
mglL Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 54-0 mglL
Al - Aluminum o11os
mglL
pH (Lab) 004n3 units
Ba - Barium 01007 23.0
uglL
TOC 00680 <1-0 mglL
Ca - Calcium oog16
mg1L
Chloride 00940 1.2 mglL
Cd - Cadmium 01027
uglL
Arsenic 01002 <10.0 uglL
Chromium: Total 01034 <5.0
uglL
Grease and Oils 00552 mglL
Cu - Copper 01042 <5A
mglL ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32731) uglL
Fe - Iron 01045 602
uglL
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mglL
Hg - Mercury 71900
uglL
Lab Report Attached? ❑ Yes (1) ❑A No (0)
Specific Conductance 00095 ftMhoS
K - Potassium 00937
mglL VOC 7B73 method # SM 62008
Total Ammonia na610 <0.10 mglL
Mg - Magnesium 00927
mg1L method #
(Ammonia Nitrogen; NH., as N; Ammonia Nitrogen, Total)
Mn - Manganese n1o55 12.0
uglL
method #
TKN as N 00625 <0.50 mg1L
Ni - Nickel 01067
uglL
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Effluent Total VOCs: mglL VOC Removal%
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION mease tannt cteany or Type
Facility Name: Rose Hiil Plantation Development, Li
Permit Name (if different):
Facility Address: 3041 New Leicester Highway
Leicester NC 28748 County Buncombe
ontact Person: Bob Barr
fell Location/Site Name: Well # 2(1 B on GW-1 b)
Telephone#: [phone]
No. of wells to be sampled: 3
DEPARTMENT OF ENVIRONMENTAL QUALITY- DIV. OF WATER RESOURC,
INFORMATION PROCESSING UNIT
1517 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
PERMIT Number: Expiration Date: 6/30/2028
Non -Discharge UIC
NPDES Other W00032016
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump 0 Other: Surface Irrigation
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): Well # 2 downgradient
Date sample collected: 3/22/2023
FIELD ANALYSES:
Well Depth: 30 ft.
Well Diameter: 2 in.
pH 0040o 5.3 units Temp. coolo: 12.4 oC
Depth to Water Level 82546: 29.4 ft, below measuring
point
Screened Interval: 10 ft.
to 30 ft.
Spec. Cond. 00094: 29.4 µMhos
Measuring Point is 2-5 ft. above land surface
Relative M.P. Elevation:
ft.
Odor 00085: None
Volume of water pumped/bailed before sampling:
gallons
Appearance Clear
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑
NO
LABORATORY INFORMATION
Date sample analyzed: 411212023
Laboratory Name: Pace Analytical
Certification No, 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 0os15 <0.040
mg1L
Pb - Lead o10s1 <5_0 ug/L
Coliform: MF Fecal 31s16 <1.)
110omL
Nitrate (i as N 00620 0.80
mg/L
Zn - Zinc 01092 <10.0 mg/L
Coliform: MF Total 31504
1100ri
Phosphorus: Total as P oo66s <0.050
ni
(NoteUse MPN method for highly turbid samples)
Orthophosphate 70507
mglL
Other (Specify Compounds and Concentration Units):
)issolved Solids:Total 70300 32.0
mg/L
Al - Aluminum o1105
mg/L
pH (Lab) 00403
units
Ba - Barium o1007 24.3
ug/L
TOC o06sa <1.0
mg/L
Ca - Calcium acs16
mg/L
Chloride 0094o 4.0
mg/L
Cd - Cadmium 01027
uglL
Arsenic 01002 <10.0
ug/L
Chromium: Total 01034 <5.0
uglL
Grease and Oils 00562
mg/L
Cu - Copper 01042 <5.0
ni
ORGANICS: (by GC, GCIMS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045 472
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑ Yes (1) ❑■ No (0)
Specific Conductance o0095
µMhos
K - Potassium 00937
mg/L
VOC 7873 method # SM 6200B
Total Ammonia ooslo <0.10
mg/L
Mg - Magnesium 00927
ri
method #
(Ammonia Nitrogen; NH. as N; Ammonia Nitrogen, Total)
Mn - Manganese oloss 6.0
11
,method #
TKN as N 00625 <0.50
mglL
Ni - Nickel 01067
ug1L
method #
For Remediation Systems Only (Attach Lab Reports):
Influent Total VOCs: mWL
Effluent Total VOCs: mg/L VOC Removal%
Robert P. Barr 1 Authorized Agent
PermiHee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.06-07-2018
Signature of Permittee (or Authorized Agent)
23
DRY at
time of
sampling,
check
here: ❑

SUBMIT FORM ON YELLOW PAPER ONLY
•
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• • •
•
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearf T
v or Type y
!PERMIT Number: Expiration Date: 6/30/2028
Facility Name: Rose Hill Plantation Development, LLC
Non -Discharge UIC
Permit Name (if different):
NPDES Other WQ 0 32016
Facility Address: 3041 New Leicester Highway
TYPE OF PERMITTED OPERATION BEING MONITORED
Leicester NC
28748 County Buncombe
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Well # 3
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑■ Other: Surface Irrigation
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): Well # 3
Date sample collected: 3/22/2023
FIELD ANALYSES:
WAS
Well Depth: 14 ft.
Well Diameter: 2 in.
pH 00400: 6.84 units Temp. 00010 8.6 °C
DRY at
4.39 ft. below measuring point
Depth to Water Level 82sas: g p
Screened Interval: 4 ft. to
14
ft. Spec. Cond. 00094: 110.5 µMhos
time of
sampling,check
Measuring Point is 0 ft. above land surface
Relative M.P. Elevation: _ ft.
Odor 00085: None
Volume of water pumped/bailed before sampling:
gallons
Appearance Clear
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:4/12/2023
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOZ) as N oo615 <0.040
mg/L Pb -Lead 01051 <5.0 ug/L
Coliform: MF Fecal 31616 <1.0
/10i
Nitrate (NO3) as N 00620 <0.040
mg/L Zn -Zinc 01092 <10.0 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 0.64
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
ssolved Solids:Total 703oo 80.0
mg/L
Al - Aluminum oilo5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007 15.7
ug/L
TOC 00680 <1.0
mg/L
Ca - Calcium oos16
mg/L
Chloride 0094o 5.0
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 <10.0
ug/L
Chromium: Total 01034 <5.0
ug/L
Grease and Oils 00552 _
mg/L
Cu - Copper 01042 <5.0
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045 18400
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 _
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) K No (0)
Specific Conductance 000ss
FlMhos
K - Potassium 00937
mg/L
VOC 7873 method # SM 62008
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen. NH3asN: Ammonia Nitrogen. Total)
Mn - Manganese 01055 636
ug/L , method #
TKN as N 00625 <0.50
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Robert P. Barr / Authorized Agent
Permittee (or Authorized Agent) Name and Title - Please print or type
(or Authonzeo Agent)
N Z-3
Ovate)
GW-59 Rev.06-07-2018

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: ROSE HILL MW
Pace Project No.: 92658289
Sample: MWA Lab ID: 92658289001 Collected: 03/22/23 10:10 Received: 03/22/23 15:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
04/12/23 09:35
Collected By
Sam
1
04/12/23 09:35
Warlick
Collected Date
3/22/23
1
04/12/23 09:35
Collected Time
1010
1
04/12/23 09:35
pH
6.3 Std. Units
1
04/12/23 09:35
Temperature
14.1 deg C
1
04/12/23 09:35
Static Water Level
38.39 feet
1
04/12/23 09:35
Specific Conductance
47.6 umhos/cm
1
04/12/23 09:35
Oxygen, Dissolved
3.0 mg/L
1
04/12/23 09:35
7782-44-7
Total Well Depth
69.0 feet
1
04/12/23 09:35
REDOX
25.1 my
1
04/12/23 09:35
Turbidity
9.6 NTU
1
04/12/23 09:35
Odor
None
1
04/12/23 09:35
Appearance
Clear
1
04/12/23 09:35
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Arsenic
ND ug/L
10.0
1 03/23/23 01:56
03/23/23 12:07
7440-38-2
Barium
23.0 ug/L
5.0
1 03/23/23 01:56
03/23/23 12:07
7440-39-3
Chromium
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:07
7440-47-3
Copper
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:07
7440-50-8
Iron
602 ug/L
50.0
1 03/23/23 01:56
03/23/23 12:07
7439-89-6
Lead
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:07
7439-92-1
Manganese
12.0 ug/L
5.0
1 03/23/23 01:56
03/23/23 12:07
7439-96-5
Zinc
ND ug/L
10.0
1 03/23/23 01:56
03/23/23 12:07
7440-66-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
54.0 mg/L
25.0
1
03/23/23 12:22
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1 03/22/23 16:07
03/23/23 15:15
Total Nitrogen Calculation
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services -Asheville
Total Nitrogen
0.15 mg/L
0.040
1
03/31/23 14:46
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
03/31/23 11:25
7664-41-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2023 03:07 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: ROSE HILL MW
Pace Project No.: 92658289
Sample: MW-1 Lab ID: 92658289001 Collected: 03/22/23 10:10 Received: 03/22/23 15:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Kjeldahl, Total
ND mg/L 0.50
1
03/29/23 15:29 03/30/23 05:51
7727-37-9
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L 0.040
1
03/23/23 01:56
14797-55-8
Nitrogen, Nitrite
ND mg/L 0.040
1
03/23/23 01:56
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.084 mg/L 0.050
1
04/03/2316:16 04/04/2311:06
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
1.2 mg/L 1.0
1
03/27/2317:36
16887-00-6
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
03/24/23 07:42
7440-44-0
Date: 04/19/2023 03:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: ROSE HILL MW
Pace Project No.: 92658289
Sample: MW-2 Lab ID: 92658289002 Collected: 03/22/23 11:50 Received: 03/22/23 15:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
04/19/23 15:04
Collected By
Sam
1
04/19/23 15:04
Warlick
Collected Date
3/22/23
1
04/19/23 15:04
Collected Time
1050
1
04/19/23 15:04
pH
5.3 Std. Units
1
04/19/23 15:04
Temperature
12.4 deg C
1
04/19/23 15:04
Static Water Level
12.11 feet
1
04/19/23 15:04
Specific Conductance
29.4 umhos/cm
1
04/19/23 15:04
Oxygen, Dissolved
6.1 mg/L
1
04/19/23 15:04
7782-44-7
Total Well Depth
30.0 feet
1
04/19/23 15:04
REDOX
80.8 my
1
04/19/23 15:04
Turbidity
9.9 NTU
1
04/19/23 15:04
Odor
None
1
04/19/23 15:04
Appearance
Clear
1
04/19/23 15:04
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Arsenic
ND ug/L
10.0
1 03/23/23 01:56
03/23/23 12:11
7440-38-2
Barium
24.3 ug/L
5.0
1 03/23/23 01:56
03/23/23 12:11
7440-39-3
Chromium
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:11
7440-47-3
Copper
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:11
7440-50-8
Iron
472 ug/L
50.0
1 03/23/23 01:56
03/23/23 12:11
7439-89-6
Lead
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:11
7439-92-1
Manganese
6.0 ug/L
5.0
1 03/23/23 01:56
03/23/23 12:11
7439-96-5
Zinc
ND ug/L
10.0
1 03/23/23 01:56
03/23/23 12:11
7440-66-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
32.0 mg/L
25.0
1
03/23/23 12:22
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1 03/22/23 16:07
03/23/23 15:15
Total Nitrogen Calculation
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services -Asheville
Total Nitrogen
0.80 mg/L
0.040
1
03/31/23 14:46
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
03/31/23 11:27
7664-41-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2023 03:07 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: ROSE HILL MW
Pace Project No.: 92658289
Sample: MW-2 Lab ID: 92658289002 Collected: 03/22/23 11:50 Received: 03/22/23 15:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Kjeldahl, Total
ND mg/L 0.50
1
03/29/23 15:29 03/30/23 05:54
7727-37-9
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.80 mg/L 0.040
1
03/23/23 01:59
14797-55-8
Nitrogen, Nitrite
ND mg/L 0.040
1
03/23/23 01:59
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
04/03/2316:16 04/04/2311:10
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
4.0 mg/L 1.0
1
03/27/2317:37
16887-00-6
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
03/24/23 08:38
7440-44-0
Date: 04/19/2023 03:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: ROSE HILL MW
Pace Project No.: 92658289
Sample: MW-313 Lab ID: 92658289003 Collected: 03/22/23 13:50 Received: 03/22/23 15:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
04/12/23 09:33
Collected By
Mark
1
04/12/23 09:33
Swann
Collected Date
3/22123
1
04/12/23 09:33
Collected Time
1350
1
04/12/23 09:33
pH
6.84 Std. Units
1
04/12/23 09:33
Temperature
8.6 deg C
1
04/12/23 09:33
Static Water Level
4.39 feet
1
04/12/23 09:33
Specific Conductance
110.5 umhos/cm
1
04/12/23 09:33
Oxygen, Dissolved
0.22 mg/L
1
04/12/23 09:33
7782-44-7
Total Well Depth
14 feet
1
04/12/23 09:33
REDOX
-117.6 my
1
04/12/23 09:33
Turbidity
8.75 NTU
1
04/12/23 09:33
Odor
None
1
04/12/23 09:33
Appearance
Clear
1
04/12/23 09:33
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Arsenic
ND ug/L
10.0
1 03/23/23 01:56
03/23/23 12:14
7440-38-2
Barium
15.7 ug/L
5.0
1 03/23/23 01:56
03/23/23 12:14
7440-39-3
Chromium
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:14
7440-47-3
Copper
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:14
7440-50-8
Iron
18400 ug/L
50.0
1 03/23/23 01:56
03/23/23 12:14
7439-89-6
Lead
ND ug/L
5.0
1 03/23/23 01:56
03/23/23 12:14
7439-92-1
Manganese
636 ug/L
5.0
1 03/23/23 01:56
03/23/23 12:14
7439-96-5
Zinc
ND ug/L
10.0
1 03/23/23 01:56
03/23/23 12:14
7440-66-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
80.0 mg/L
25.0
1
03/23/23 12:22
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1 03/22/23 16:07
03/23/23 15:15
Total Nitrogen Calculation
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services -Asheville
Total Nitrogen
0.044 mg/L
0.040
1
03/31/23 14:46
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
03/31/23 11:28
7664-41-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2023 03:07 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: ROSE HILL MW
Pace Project No.: 92658289
Sample: MW-313 Lab ID: 92658289003 Collected: 03/22/23 13:50 Received: 03/22/23 15:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Kjeldahl, Total
ND mg/L 0.50
1
03/29/23 15:29 03/30/23 05:56
7727-37-9
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L 0.040
1
03/23/23 02:22
14797-55-8
Nitrogen, Nitrite
ND mg/L 0.040
1
03/23/23 02:22
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.64 mg/L 0.050
1
04/03/2316:16 04/04/2311:12
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
5.0 mg/L 1.0
1
03/27/2317:38
16887-00-6
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
03/24/23 09:35
7440-44-0
Date: 04/19/2023 03:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 24

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: ROSE HILL MW
Pace Project No.: 92658289
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/19/2023 03:07 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 24

CHAIN -OF -CUSTODY 1 Analytical Request Document
- ace The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at httDs:lftnfo.i3acelabs.com/hubfs/Das-standard-terms.odf
Section A Section 8 Section C
Required Client Information: Required Project Information: Invoice Information:
Page: 1 Of 1
Company: RPi3 Systems Inc.
Report To: Robert Barr
Attention:
Address: P.O. Box 1325
Copy To:
Company Name:
Asheville, NC 28802
Address:
Regulatory Agency
Small: [e-mail]
Purchase Order #:
Pace Quote:
Phone, [phone] Fax
Project Name: Rose Hill MW
Pace Prejed Manager: [e-mail],
State I Location
Requested Due Dale:
Project M
Pace Profile #; 2315
NC
Requested
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
April 19, 2023
Kimber Reese
RPB Systems Inc.
P.O. Box 1325
Asheville, INC 28802
RE: Project: ROSE HILL MW
Pace Project No.: 92658289
Dear Kimber Reese:
Enclosed are the analytical results for sample(s) received by the laboratory on March 22, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Dyson
[e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. Robert Barr, RPB Systems Inc.
Ms. Liz Barr, RPB Systems Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 24

Document Name Field data Sheet
Document Number: F-CAR-PLD-001-mv.02
I
Name and Affiliation
Name and Affiliation (Inspector):
Well Information
Well ID: 41Id"S6 Well Locked:
WeII Diameter: Construction:
Total Well Depth:
Static Water Level: 1kS 5 (t
Height of Water Column: G, 6 ft
Office
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Date: -�,JI ia-Ia 3 By:
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Multi Factor*:_,._f" _ [•(Radius/12)2 0.14 x 7.481
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Cal. 3 Volumes: G°!q x°�allons
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