WQ0028693_Groundwater Monitoring Report March 2023_20230419

C 4'V-59A C'OIiIPL_I NC E REPORT DORM Perrilit 4 WQ0028693
(.Suhafit one each ma nituring period with Gil -50 )oral r.l
1
Enter date monitoring results were due. (4130/2023 ) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
X
2
Was any required information missing; on the GW-59 report forms?
YES
I,
x
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? if thu cans-wer is "Yes", a price! lire Regiorau! (7fJicefa giaidurace.
4
Are any monitored constituents equal to or alcove the established standards?
YES
NO
If the answer to question 4 is "NO" skip to section 6.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
Sarre constituent(s) in the same wefts) in the last two years?
YES
NO
If the answer to question 5 is "NO", skip to section B.
If the answer to question 5 is "YES", list in the space provided below, each welt with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
MW-01R: pH 5.53
MW-2: pH 5.81
MW-3: pH 5.89
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
N
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided .below.
If the answer to question 7 is "NO". contact the Regional Office within 90 days: an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the oermittee to a Notice of Violation,
fines, and/or penalties.
8
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) Is true and complete to the best of my knowledge.
vwj--- - Lf S 2-3
Signature of Permittee (or Authorized Agent) Date
GW-59A 1 21V,200 3

SUBMIT FORM ON YELLOW PAPER ONLY
t7EPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMA710N PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
prease Pont CleadyorType
PERMIT Number: Expiration Date: 413012025
Facility Name: Mountaintop Golf & Lake Club
Nan -Discharge WQ0028693 UIC
Permit Name (if different): Mountaintop Community Association Inc
NPDES Other
Facility Address: P.O. Sox 1460
TYPE OF PERMITTED OPERATION BEING MONITORED
Cashiers NC
28717 County Jackson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: MVV-01 R
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-01 R
Date sample collected: 3/20/2023
FIELD ANALYSES:
WAS
Well Depth: 25.6 ft.
Well Diameter: 2 in.
pH 00400: 5-53 units Temp. coolo: 12-4 °C
DRY at
Depth to Water Level 82546: 12.58 ft. below measuring point Screened Interval: 15-6 ft. to
25.6 ft. Spec. Cond. 00094: 108.5 µMhos
—
time of
sampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085 None
check
Volume of water pumpedlbailed before sampling:
gallons
Appearance Hazy Turbid
here:❑
Samples for metals were collected unfiltered: ■❑ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed. 4/1812023
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD co335
mg1L
Nitrite (NO.) as N o0615 <0.040
mg1L
Pb - Lead D1o51 ug/L
Coliform: MF Fecal 31318 1
1100mL
Nitrate (NO3) as N 00620 0.19
mg/L Zn - Zinc 01092 mglL
Coliform: MF Total 31504
1100mL
Phosphorus: Total as P 00665 0.41
mg/L
(Note. Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
ssolved Solids:Total7a30o 61.0
mg/L
Al - Aluminum 911o5
mg1L
PH (Lab) 00403
units
Ba - Barium 01007
uglL
TOC 00680 1.7
mg/L.
Ca - Calcium oosls
mg/L
Chloride 00e40 20.3
mg/L
Cd - Cadmium 01027
ug1L
Arsenic 01002
ug1L
Chromium: Total 01034
ug1L
Grease and Oils D0552
mg1L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GCIMS, HPLC)
Phenol 32730
ug1L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) © No (0)
pecific Conductance 000gs
µMhos
K - Potassium 00937
mg/L VOC 7873 method # SB 6200B
Total Ammonia o0610 <0.10
mg/L
Mg - Magnesium oc927
mg/L method #
(Ammonia Nitrogen; NH3as N; Ammonia Nitrogen. Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influert Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. [am aware that there are significant penalties for submitting false information. including the possibility of fines and imprisonment for knowing violations.
Robert P. Barr / Authorized Agent ME: 'f-11 -2.�?
Pernnittee (or Authorized Agent) Name and Title - Ple2se print or type Signature of - D
GVV-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
r
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Cfeady or Type
PERMIT Number: Expiration Date: 4/30/2025
Facility Name Mountaintop Golf 8r Lake Club
Non -Discharge VVQ0028693 UIC
Permit Name (if different): Mountaintop Community Association Inc
NPDES Other
Facility Address: P.O. Box 1460
TYPE OF PERMITTED OPERATION BEING MONITORED
Cashiers NC
28717 County Jackson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑r Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: MW-2
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑ Other:
Gom Permil}
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-2
Date sample collected: 3/30/2023
FIELD ANALYSES:
WAS
Well Depth: 33.73 ft.
Well Diameter: 2 in,
pH 00400: 5.81 units Temp. 00010: 12.0 °C
DRY at
Depth to Water Level 62546: 13.6 ft. below measuring point Screened Interval: 42 ft. to
32
ft, Spec, Cond. 00094 142.2 pMhos
time of
sampling,check
Measuring Point is ft. above land surface
Relative M.P. Elevation: ft.
Odor 000s5: Norte
Volume of water pumped/bailed before sampling:
gallons
Appearance Clear
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 41l3/2023
Laboratory Name: Pace Analytical
Certification No, 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD oo335
mg/L
Nitrite (NO2) as N 00615 <0.040
mg/L Pb - Lead o1o51 ug1L
Coliform: MF Fecal 31616 <1
1101
Nitrate (NO.) as N 00620 1.5
mg/L
Zn - Zinc o1092 mg/L
Coliform: MF Total 31504
1100mL
Phosphorus: Total as P o0665 <0-50
mg/L
(Notes Use MPN method for highly turbid Samples)
Orthophosphate 705a7
mg/L Other (Specify Compounds and Concentration Units):
ssolved Solids:Total 70300 100
mg/L
Al -Aluminum o1105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug1L
TOC oo6sc <1.0
mg1L
Ca - Calcium oog16
mg/L
Chloride 0094a 4.1
mg/L
Cd - Cadmium 01027
ug1L
Arsenic 01002
ug/L
Chromium: Total 01034
ug1L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GCIMS, HPLC)
Phenol 32730
ug1L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71901)
ug1L Lab Report Attached? ❑ Yes (1) ❑■ No (0)
Specific Conductance 000ss
j.tMhos
K - Potassium 00937
mg/L VOC 7873 method # SM 6200B
Total Ammonia 00610 <0-10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen. NH, as N: Ammonia Nitrogen. Total)
Mn - Manganese o1055
ug/L , method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOC& mg/L Effluent Total VOCs: mg/L VOC Removal%
GW-59 Rev, 06-07-2018

SUBMIT FORM ON Y ELLO\RA PERONLY
• .
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 4/30/2025
Facility Name: Mountaintop Golf & Lake Club
Non -Discharge W00028693 UIC
Permit Name (if different): Mountaintop Community A $ociation Inc
NPDES Other
Facility Address: P.O. Box 1460
TYPE OF PERMITTED OPERATION BEING MONITORED
Cashiers NC
28717 County Jackson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Bob Barr
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: MW-3
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑ Other:
(from Per rill
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-3
Date sample collected: 3/3012023
FIELD ANALYSES:
WAS
Well Depth: 160 ft.
Well Diameter: 4 in.
pH 00400: 5-89 units Temp. 000lo: 16.8 -C
DRY at
Depth to Water Level 82546: 11.69 ft. below measuring point Screened Interval: ft.
to
ft. Spec. Cond. 00094: 83.6 µMhos
time of
sampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation: _ft.
Odor00085: None
check
Volume of water pumped/bailed before sampling:
gallons
Appearance Clear
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 4/18/2023
Laboratory Name: Pee A rely tial
Certification No. 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.041
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 <1
/100mL
Nitrate (NO3) as N 00620 <0.040
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.50
mg/L
(Note: Use WIN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
[issolved Solids:Total 703oo 52.0
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC omm <1.0
mg/L
Ca - Calcium 00916
mg/L
Chloride 0094o 3.2
mg/L
Cd -Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034 _
ug/L
Grease and Oils 00552
mg/L
Cu -Copper 01042�^_mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
_ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945_
mg/L
Hg - Mercury 71900
_ug/L Lab Report Attached? ❑ Yes (1) ❑■ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method # SM 6200E
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen: NH,as N; Ammonia Nitrogen. Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: — mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that. to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
Robert P. Barr / A uthorizedA gent I •
Permittee (or Authorized Agent) Name and Title - Please print or type Signature oPOP"ermittee (Tr Authorized Agent) (Date)
GW-59 Rev.06-07-2018

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MOUNTAIN TOP MWS
Pace Project No.: 92659750
Sample: MW-01R Lab ID: 92659750001 Collected: 03/30/23 13:25 Received: 03/30/23 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
04/18/23 11:53
Collected By
Mark
1
04/18/23 11:53
Swann
Collected Date
3/30/23
1
04/18/23 11:53
Collected Time
1325
1
04/18/23 11:53
pH
5.53 Std. Units
1
04/18/23 11:53
Temperature
12.1 deg C
1
04/18/23 11:53
Static Water Level
12.58 feet
1
04/18/23 11:53
Specific Conductance
108.5 umhos/cm
1
04/18/23 11:53
Oxygen, Dissolved
3.88 mg/L
1
04/18/23 11:53
7782-44-7
Total Well Depth
25.6 feet
1
04/18/23 11:53
REDOX
145.4 my
1
04/18/23 11:53
Turbidity
178.6 NTU
1
04/18/23 11:53
Odor
None
1
04/18/23 11:53
Appearance
Hazy
1
04/18/23 11:53
Turbid
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
61.0 mg/L 25.0
1
03/31/23 20:02
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 2.0
2
03/30/23 16:50 03/31/23 15:53
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
04/07/23 14:01
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.19 mg/L 0.040
1
03/31/23 04:19
14797-55-8
Nitrogen, Nitrite
ND mg/L 0.040
1
03/31/23 04:19
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.41 mg/L 0.050
1
04/06/2315:33 04/07/2311:39
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
20.3 mg/L 1.0
1
04/05/2319:32
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1.7 mg/L 1.0
1
04/07/23 04:48
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/18/2023 11:57 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 20

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MOUNTAIN TOP MWS
Pace Project No.: 92659750
Sample: MW-2 Lab ID: 92659750002 Collected: 03/30/23 13:00 Received: 03/30/23 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
04/18/23 11:46
Collected By
Mark
1
04/18/23 11:46
Swann
Collected Date
3/30/23
1
04/18/23 11:46
Collected Time
1300
1
04/18/23 11:46
pH
5.81 Std. Units
1
04/18/23 11:46
Temperature
12.0 deg C
1
04/18/23 11:46
Static Water Level
13.6 feet
1
04/18/23 11:46
Specific Conductance
142.4 umhos/cm
1
04/18/23 11:46
Oxygen, Dissolved
3.03 mg/L
1
04/18/23 11:46
7782-44-7
Total Well Depth
33.73 feet
1
04/18/23 11:46
REDOX
194.7 my
1
04/18/23 11:46
Turbidity
0.27 NTU
1
04/18/23 11:46
Odor
None
1
04/18/23 11:46
Appearance
Clear
1
04/18/23 11:46
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
100 mg/L 25.0
1
03/31/23 20:02
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
03/30/23 16:50 03/31/23 15:53
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
04/07/23 14:02
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
1.5 mg/L 0.040
1
03/31/23 04:17
14797-55-8
Nitrogen, Nitrite
ND mg/L 0.040
1
03/31/23 04:17
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
04/06/2315:33 04/07/2311:40
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
4.1 mg/L 1.0
1
04/05/2319:35
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
04/07/23 05:08
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/18/2023 11:57 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 20

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MOUNTAIN TOP MWS
Pace Project No.: 92659750
Sample: MW-3 Lab ID: 92659750003 Collected: 03/30/23 12:30 Received: 03/30/23 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
04/18/23 11:49
Collected By
Mark
1
04/18/23 11:49
Swann
Collected Date
3/30/23
1
04/18/23 11:49
Collected Time
1230
1
04/18/23 11:49
pH
5.89 Std. Units
1
04/18/23 11:49
Temperature
16.8 deg C
1
04/18/23 11:49
Static Water Level
11.69 feet
1
04/18/23 11:49
Specific Conductance
83.6 umhos/cm
1
04/18/23 11:49
Oxygen, Dissolved
4.82 mg/L
1
04/18/23 11:49
7782-44-7
Total Well Depth
160 feet
1
04/18/23 11:49
REDOX
205.8 my
1
04/18/23 11:49
Turbidity
5.69 NTU
1
04/18/23 11:49
Odor
None
1
04/18/23 11:49
Appearance
Clear
1
04/18/23 11:49
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
52.0 mg/L 25.0
1
03/31/23 20:02
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
03/30/23 16:50 03/31/23 15:53
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
04/08/23 11:10
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L 0.040
1
03/31/23 04:13
14797-55-8
Nitrogen, Nitrite
ND mg/L 0.040
1
03/31/23 04:13
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
04/06/2315:33 04/07/2311:41
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
3.2 mg/L 1.0
1
04/05/2319:55
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
04/07/23 05:26
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/18/2023 11:57 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 20

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: MOUNTAIN TOP MWS
Pace Project No.: 92659750
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
H1 Analysis conducted outside the EPA method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/18/2023 11:57 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 20

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Page 19 of 20

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
April 18, 2023
Kimber Reese
RPB Systems Inc.
P.O. Box 1325
Asheville, NC 28802
RE: Project: MOUNTAIN TOP MWS
Pace Project No.: 92659750
Dear Kimber Reese:
Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Dyson
[e-mail]
[phone]
Project Manager
Enclosures
cc: Mr. Robert Barr, RPB Systems Inc.
Ms. Liz Barr, RPB Systems Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 20

Date Issued November 27, 2 118
Document Name Field data Sheet
FaLe: 1 of,
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Document Number: F-CAR-FLD-lbl-rev.02
Office
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Name and Affiliation (Sampler(s): M
Name and Affiliation (Inspector):—
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Total Well Depth: y ft
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Multi Factor': c(� ["(Rad1us/12)2 x3.14x 7.481
Casing Volume: 'A1/ 12Z Z gallons
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Date Purged: % / 3 ° /_ Start: /'S' - Finish: � f ®" Purge Rate: (• "a- [n 9 c 1,r_ , _
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50 Diss Uxy (mg/L): Time: Fe 2+ mg/L:
Specific Cond. (uS) i 0 i? •j Time: S .� % Res. Cl (mg/L)/(µg/L): T me:
Sample pH (s.u.): S ,'' i Time: � Odor: N) vL Time: }
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Date Issued: November 27,2018
Document Name: Field data Sheet
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CNDCanunnt Number: P-CAR-FLD-001-rev.02
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Field Data Sheet
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Total Well Depth: 1 7ft
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Static . Water Level-41 4 11 Jt
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Par e Information
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Sample pH (s.u.): r, 00 1 Time: Odor, A10,Vo_ Time:
ReDoxI I .. (mV):_ T'i I ne: I5 Appearance: Time:
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Date Issued November 27, 2018
Document Name: Field data Sheet -
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Document Number: F-CAR-FLD-001-rev.02
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Height of Water Column: %tfa, jl ft Cal. 3 Volumes: 9y' rSS gallons
Pump Intake: % ft
Purge Informati©n
DatePurged-3—j22.��' ),3 Start:S Finish: 1 r Purge Rate:
Purging Method: �a�,Jh�f! ! Total Volume Purged:T0 (gallons'
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