NC0027227_Renewal Application_20230417

�� RH[fM EMIRGY
April 10, 2023
John Hennessy
NPDES Permit Section
Department of Water Resources
North Carolina Department of Environmental Quality
217 West Jones Street
Raleigh, NC 27603
RE: NPDES Permit No. NC0027227 Renewal Application
Zenith Energy Terminals Holdings LLC
2999 W. Oak Street
Selma, NC 27576
Dear Mr. Hennessy:
RECEIVED
APR 17 2023
NCDEQ/DWR/NPDES
Zenith Energy Terminals Holdings LLC (Zenith Energy) is submitting this NPDES Permit renewal
application for our Selma, North Carolina terminal. Attached to this cover letter are the following forms
and supporting documentation:
• EPA NPDES Form 1 - General Information
- EPA NPDES Form 1 Attachment -Topographic Map
• EPA NPDES Form 2F - Stormwater Discharges Associated with Industrial Activity
- EPA NPDES Form 2F Attachment 1 - Drainage Map
- EPA NPDES Form 2F Attachment 2 - Analytical Reports
Zenith Energy appreciates your consideration of the matter. Please do not hesitate to contact Mr.
Shannon Caldwell at [phone] or myself at [phone] if you have any questions on this
matter.
Sincerely,
Andrew G. Danhof, ]
Manager, Environmental and Regulatory
3900 Essex Lane, Suite 7001 Houston, TX 77027
Phone: [phone]

Mr. John Hennessy April 10, 2023
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA NPDES Form 1

EPA Idenfification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110000347134
NCO027227
Zenith Energy Selma
WE No. 2040-0004
Form
U.S. Environmental Protection Agency
1
�iEPA
Application for NPDES Permit to Discharge Wastewater
NPDES
GENERAL INFORMATION
SECTION•
•• r
1.1
Applicants Not Required to Submit Form 1
1.1.1
Is the facility a new or existing publicly owned
1.1.2
Is the facility a new or existing treatment works
treatment works?
treating domestic sewage?
If yes, STOP. Do NOT complete No
If yes, STOP. Do NOT ✓❑ No
Form 1. Complete Form 2A.
complete Form 1. Complete
Form 2S.
1.2
Applicants Required to Submit Form 1
1.2.1
Is the facility a concentrated animal feeding
1.2.2
Is the facility an existing manufacturing,
E
operation or a concentrated aquatic animal
commercial, mining, or silvicultural facility that is
a.
production facility?
currentlydischarging
g g process wastewater
oYes
4 Complete Form 1 No
Yes + Complete Form No
a
z
and Form 2B.
1 and Form 2C.
1.2.3
Is the facility a new manufacturing, commercial,
1.2.4
Is the facility anew or existing manufacturing,
mining, or silvicultural facility that has not yet
commercial, mining, or silvicultural facility that
commenced to discharge?
discharges only nonprocess wastewater?
Yes 4 Complete Form 1 No
Yes 4 Complete Form No
and Form 2D.
1 and Form 2E.
2
1.2.5
Is the facility a new or existing facility whose
'—
discharge is composed entirely of stormwater
a
associated with industrial activity or whose
discharge is composed of both stormwater and
non-stormwater?
0 Yes 4 Complete Form 1 ❑ No
and Form 2F
unless exempted by
40 CFR
122.26(b)(14)(x) or
b 15.
SECTION••
AND LOCATION (40
2.1 1
Facility Name
Zenith Energy Selma
`0
2.2
EPA Identification Number
u
110000347134
v
A
2.3
Facility Contact
g
Name (first and last)
Title
Phone number
Andrew Danhof
Manager, Environmental & Regulatory
[phone]
Email address
:q
[e-mail]
E
2.4
Facility Mailing Address
z
Street or P.O. box
3900 Essex Lane, Suite 700
City or town
State
ZIP code
Houston
TX
77027
EPA Form 3510-1 (revised 3-19) Page 1

EPA Identficabon Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110000347134
NC0027227
Zenith Energy Selma
OMB No. 2040-0004
y
2.5
Facility Location
aStreet,
route number, or other specific identifier
rn U
2999 W. Oak Street
o
County name
County code (if known)
Johnston
0
City or town
State ZIP code
Z m
Selma
NC 27576
SECTION•
NAICS CODESI
3.1
SIC Code(s)
Description (optional)
4226
Special Warehousing and Storage, NEC
N
N
O
U
u1
U
Z
3.2
NAICSCode(s)
Description (optional)
v
c
U493190
Other Warehousing and Storage
rn
4.1
Name of Operator
Zenith Energy Terminals Holdings LLC
4.2
Is the name you listed in Item 4.1 also the owner?
7UN�2
Yes ❑ No
43
0 rator Status
❑ Public —federal ❑ Public —state ❑ Other public (specify)
p
ID Private ❑ Other (specify)
4.4
Phone Number of Operator
[phone]
4.5
OpqratorAddress
w
Street or P.O. Box
d
3900 Essex Lane, Suite 700
0
5
1E
City or town
State
ZIP code
0 0
A U
Houston
TX
77027
o
mail address of operator
[e-mail]
SECTION•
• I
�,
5.1
Is the facility located on Indian Land?
1
❑ Yes ID No
EPA Form 3510-1 (revised 3-19) Page 2

EPA Identification Number NPDES Permit Number Fadliry Name Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
SECTION•• 1
,iiii6.1 Existing Environmental Permits (check all that apply and print or type the corresponding permit number for each)
® NPDES (discharges to surface
❑ RCRA (hazardous wastes)
❑ UIC (underground injection of
o
water)
fluids)
w` a
❑ NESHAPs (CAA)
❑ PSD (air emissions)
❑ Nonattainment program (CAA)
M
w
❑ Other (specify)
❑ Ocean dumping (MPRSA)
❑ Dredge or fill (CWA Section 404)
NC Air Permit No. 042961R18
•
1
7.1
Have you attached a topographic map containing all required information to this application? (See instructions for
A
specific requirements.)
❑ Yes ❑ No ❑ CAFO—Not Applicable (See requirements in Form 2B.)
SECTIONOF
. 1
8.1
Describe the nature of your business.
Storage and loading of petroleum products.
Ul
ul
N
C
m
O
N
R
Z
SECTION••
r
9.1
Does your facility use cooling water?
❑ Yes No 4 SKIP to Item 10.1.
9.2
Identify the source of cooling water. (Note that facilities that use a cooling water intake structure as described at
= H
40 CFR 125, Subparts I and J may have additional application requirements at 40 CFR 122.21(r). Consult with your
o d
NPDES permitting authority to determine what specific information needs to be submitted and when.)
O Y
U
C
SECTION1
VARIANCE
REQUESTS1 1
777
Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(m)? (Check all that
apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and
when.)
C❑
Fundamentally different factors (CWA ❑ Water quality related effluent limitations (CWA Section
Section 301(n)) 302(b)(2))
A
❑ Non -conventional pollutants (CWA ❑ Thermal discharges (CWA Section 316(a))
Section 301(c) and (g))
❑� Not applicable
EPA Form 35104 (revised 3.19) Page 3

EPA Identifiradan Number NPDES Permit Number Facility Name Form Approved 0305/19
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
SECTION•
r
11.1
In Column 1 below, mark the sections of Form 1 that you have completed and are submitting with your application.
For each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note
that not all applicants are required to provide attachments.
Column 1
Column 2
0 Section 1: Activities Requiring an NPDES Permit
❑ w/ attachments
❑✓ Section 2: Name, Mailing Address, and Location
❑ w/ attachments
Section 3: SIC Codes
❑ w/ attachments
✓❑ Section 4: Operator Information
❑ w/ attachments
❑� Section 5: Indian Land
❑ w/ attachments
❑� Section 6: Existing Environmental Permits
❑ w/ attachments
E
E
A
❑✓ Section 7: Map
0 wl topographic
❑ w/ additional attachments
ma
o
❑� Section 8: Nature of Business
❑ w/ attachments
w
�c
❑✓ Section 9: Cooling Water Intake Structures
❑ w/ attachments
v
0 Section 10: Variance Requests
❑ w/ attachments
A
�_
❑� Section 11: Checklist and Certification Statement
❑ w/ attachments
Y
t
11.2
Certification Statement
U
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision
in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations.
Name (print or type first and last name)
Official tille
Shannon Caldwell
Vice President - HSE and Regulatory
Signature
Date
Datesignneedd
„�
`iw "� `CSC GL'UA
% /
7 l t 1 (Z. -n
EPA Form 3510-1 (revised 3.19) Pape 4

Mr. John Hennessy April 10, 2023
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA NPDES Form 1 Attachment
Topographic Map

1URNAGE RP.
-
Outlall tl
1 Wt, l7 S7'11.i0'N
ZeitiN Fmrgv Termiiuls
�
Y -W'
Selma. NC
-w
� �
-
IaC35°3T 15,5' 1i.5'N
----,
L. g:7g°18'/1.WW
±t
15o
-
Fd50 cm
� yLL -i•b
b w
�
IN ST
BUFFALO RU
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—
SEI.MA ti-;�
yy \
BYP70
Leek remieie EPA Form l Fig.. l-TopograpWc Map
AAlVeiakgxnr Selma Terminal
w , xc ugly M'DFS Permit N. NC002722/ Renewal Application I • I

Mr. John Hennessy April 10, 2023
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA NPDES Form 2F

EPA Identificaton Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
Form U.S Environmental Protection Agency
2F =,EPA Application for NPDES Permit to Discharge Wastewater
NPDES STORMWATER DISCHARGES ASSOCIATED WITH INDUSTRIAL ACTIVITY
SECTIONOUTFALL LOCATION•r
1.1 Provide information on each of the facili 's outfalls in the table below
Outfall Receiving Water Name Latitude Longitude
Number
01 Neuse River 35' 33' 10.99" N 70° 18' 45.60" W
0
0
.�
0
0
A
0
SECTION"• 1
2.1 Are you presently required by any federal, state, or local authority to meet an implementation schedule for constructing,
upgrading, or operating wastewater treatment equipment or practices or any other environmental programs that could
affect the discharges described in this application?
❑ Yes ✓❑ No 4 SKIP to Section 3.
2.2 Brieffy identify each applicable project in the table below.
Brief Identification and Affected Ouffalls Source(s) of Discharge final Compliance Dates
Description of Project (list outfall numbers)
Required Projected
12
c
E
d
0
E
E
2.3 Have you attached sheets describing any additional water pollution control programs (or other environmental projects
that may affect your discharges) that you now have underway or planned? (Optional Item)
❑ Yes ❑ No
EPA Form 3510-2F (Revised 3-19) Pagel

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000347134 NC0027227 Zenith Energy Selma OMB No. 2040-0004
SECTIONDR ,r
3.1 Have you attached a site drainage map containing all required information to this application? (See instructions for
specific guidance.)
Go��
o ® Yes ❑ No
SECTION• • r
M77 Provide information on the facility's pollutant sources in the table below.
Outfall
Impervious Surface Area
Total Surface Area Drained
Number
(within a mile radius of the facility)
(within a mfle radius of the facility)
specify units
specify units
1
2.55
acres
0.81
acres
specify units
specify units
specify units
specify units
specify units
specify units
spe* units
specify units
sperafyunits
specify, units
4.2
Provide a narrative description of the facility's significant material in the space below. (See instructions for content
requirements.)
The significant materials stored at the facility are gasoline, diesel, and ethanol that is denatured with gasoline. The
significant materials are stored in several large aboveground storage tanks which are surrounded by an earthern berm.
c
The significant materials enter the facility via pipeline and exit the facility via a truck loading rack.
M
Fertilizers, pesticides, herbicides, and soil conditioners are rarely if ever used at the facility.
0
a
4.3
Provide the location and a description of existing structural and non-structural control measures to reduce pollutants in
stormwater runoff. See instructions forspecificguidance.)
Stormwater Treatment
Codes
Outfall
from
Number
Control Measures and Treatment
Exhibit
2F-1
fist
1
Inspections prior to discharge
Not Applica
EPA Form 3510-2F (Revised 3-19) Page 2

Idenfificalon Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma OMB No. 2040-0004
NON STORMWATER40
5.1 11 certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the
presence of non-stormwater discharges. Moreover, I car* that the outfalls identified as having non-stormwater
discharges are described in either an accomoanvina NPDES Form 2C. 2D. or 2E aw ication.
Shannon Caldwell
Signature
o,
5.2
Provide the testin
A
L
N
Oulfall
'o
Number
d
m
1
0
c
0
z
a
a
information requested in the table below.
Description of Tesfing Method Used
N/A - There are no non-stormwater discharges.
Vice President - HSE & Regulatory
Date signed
Onsite Drainage Points
Date(s) of Testing I Directly Observed
6.1 1Describe any significant leaks or spills of toxic or hazardous pollutants in the last three years.
There were no significant leaks or spills within the last three years.
se the instructions to determine the pollutants and parameters you are required to monitor and, in turn, the tables you must
Wlete. Not all aoDlicants need to comDlete each table.
7.1 1 Is this a new source or new discharge?
❑ Yes + See instructions regarding submission of ❑ No + See instructions regarding submission of
estimated data. actual data.
ables A, B, C, and D
7.2 1Have you completed Table A for each outfall?
[a Yes ❑ No
EPA Form 3510-21F (Revised 3-19) Page 3

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110000347134
NCO027227
Zenith Energy Selma
OMB No. 2040-0004
7.3
Is the facility subject to an effluent limitation guideline (ELG) or effluent limitations in an NPDES permit for its process
wastewater?
❑ Yes 0 No 4 SKIP to Item 7.5.
7.4
Have you completed Table B by providing quantitative data for those pollutants that are (1) limited either directly or
indirectly in an ELG andlor (2) subject to effluent limitations in an NPDES permit for the facility's process wastewater?
❑ Yes ❑ No
7.5
Do you know or have reason to believe any pollutants in Exhibit 2F-2 are present in the discharge?
❑ Yes 0 No + SKIP to Item 7.7.
7.6
Have you listed all pollutants in Exhibit 217-2 that you know or have reason to believe are present in the discharge and
provided quantitative data or an explanation for those pollutants in Table C?
❑ Yes ❑ No
7.7
Do you qualify for a small business exemption under the criteria specified in the Instructions?
❑ Yes +SKIP to Item 7.18. ❑ No
7.8
Do you know or have reason to believe any pollutants in Exhibit 2F-3 are present in the discharge?
0 Yes ❑ No + SKIP to Item 7.10.
d
7.9
Have you listed all pollutants in Exhibit 2F-3 that you know or have reason to believe are present in the discharge in
Table C?
Yes ❑ No
0
7.10
Do you expect any of the pollutants in Exhibit 2F-3 to be discharged in concentrations of 10 ppb or greater?
€
❑ Yes No 4 SKIP to Item 7.12.
0
7.11
Have you provided quantitative data in Table C for those pollutants in Exhibit 2F-3 that you expect to be discharged in
Q'
concentrations of 10 ppb or greater?
A
❑ Yes ❑ No
N
7.12
Do you expect acrolein, acrylonibile, 2,4-dinitrophenol, or 2-methyl4,6-dinitrophenol to be discharged in concentrations
of 100 ppb or greater?
❑ Yes 0 No 4 SKIP to Item 7.14.
7.13
Have you provided quantitative data in Table C for the pollutants identified in Item 7.12 that you expect to be
discharged in concentrations of 100 ppb or greater?
❑ Yes ❑ No
7.14
Have you provided quantitative data or an explanation in Table C for pollutants you expect to be present in the
discharge at concentrations less than 10 ppb (or less than 100 ppb for the pollutants identified in Item 7.12)?
❑ Yes 0 No
7.15
Do you know or have reason to believe any pollutants in Exhibit 2F-4 are present in the discharge?
❑ Yes 0 No 4 SKIP to Item 7.17.
7.16
Have you listed pollutants in Exhibit 2F-4 that you know or believe to be present in the discharge and provided an
explanation in Table C?
❑ Yes ❑ No
7.17
Have you provided information for the storm event(s) sampled in Table D?
❑ Yes 0 No
EPA Form 3510-2F (Revised 3-19) Page 4

EPA Identificalion Number
NPDES Permit Number
Facility Name
Form Approved 03105/19
110000347134
NCO027227
Zenith Energy Selma
OMB No. 20404004
Used or Manufactured Toxics
79
7.18
Is any pollutant listed on Exhibits 2F-2 through 2F-4 a substance or a component of a substance used or
o
manufactured as an intermediate or final product or byproduct?
c
0
❑ Yes No 4 SKIP to Section 8.
7.19
List the pollutants below, including TCDD if applicable.
c
1. 4. 7.
m
M
2. 5. 8.
r
u
0
3. 6. 9.
SECTIONBIOLOGICAL
TOXICITYD r
8.1
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on
9
any of your discharges or on a receiving water in relation to your discharge within the last three years?
c
❑ Yes ❑ No 4 SKIP to Section 9.
8.2
Identify the tests and their purposes below.
u�
Togs)
Purpose of Test(s)
Submitted to NPDES
Date Submitted
•K
Permittin Author' ?
0
~
m
0
Whole Effluent Toxicity
NPDES Requirement
❑✓ Yes ❑ No
02/22/2023
❑ Yes ❑ No
•m
❑ Yes ❑ No
SECTION•
•- • .r
9.1
Were any of the analyses reported in Section 7 (on Tables A through C) performed by a contract laboratory or
consulting firm?
0 Yes ❑ No 4 SKIP to Section 10.
9.2
Provide information for each contract laboratory or consulting firm below.
Laboratory Number 1
Laboratory Number 2
Laboratory Number 3
Name of laboratory/firm
Pace Analytical
c
0
0
Laboratory address
�
9800 Kincey Ave. Suite 100
m
Huntersville, NC 28078
c
Q
U
W
o
Phone number
V
[phone]
Pollutant(s) analyzed
Benzene, Toluene,
Ethylbenzene, Naphthalene,
total suspended solids, volatile
organics, semivolatile organics,
oil & grease, total phenolics,
turbidity, and xylene.
EPA Form 3510-21' (Revised 3-19) Page 5

EPA Identification Number NPDES Permit Number Facility Name
Form Approved 03/05/19
110000347134 NCO027227 Zenith Energy Selma
OMB No. 2040-0004
SECTION1
CHECKLIST
AND CERTIFICATION1
10.1
In Column 1 below, mark the sections of Form 2F that you have completed and are submitting with your application. For
each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not
all applicants are required to com lete all sections or provide attachments.
Column 1
Column 2
El Section 1
❑ w/ attachments (e.g., responses for additional outfalls)
El Section 2
❑ wl attachments
❑ Section 3
© wl site drainage map
❑ Section 4
❑ w/ attachments
U Section 5
❑ w/ attachments
Section 6
❑ w/ attachments
�❑
❑ Section 7
❑� Table A ❑ wl small business exemption request
❑ Table B ❑ w/ analytical results as an attachment
0
❑ Table C ❑ Table D
z
r
0
© Section 8
❑ wlattachments
c
w
a
❑� Section 9
❑ wlattachments (e.g., responses for additional contact laboratories or firms)
x
t❑
Section 10
❑
10.2
Certification Statement
1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible
for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine
and imprisonment for knowing violations.
Name (print or type first and last name)
Official title
Shannon Caldwell
Vice President of HSE & Regulatory
Signature
Date signed
EPA Form 3510-2F (Revised 3-19) Page 6

EPAIdero9ration Number NPI)EZ20Number Faalxy Name Ouaall Number Form Aypioced03A5119
330000347134 N00027227 Zenith Energy Selma OMB No.20400004
TABLE A. CONVENTIONAL AND NON CONVENTIONAL40
You must provide the results of at least one anal sis for every pollutant in this table. Complete one table for each outfall. See InsWctions for additional details and re uirements.
Pollutant or Parameter
Maximum Daily Discharge
(soeary arms)
Average Daily Discharge
tun)
Number of Storm
Events Sampled
Source of
Information
(nees urremere
urgers only use
codesin ir�usaons)
Grab Sample Taken
During First
30 Minutes
Flow -Weighted
ornP�ife
Grab Sample Taken
During First
30 Minutes
Flor•WMglded
Composite
1.
Oil and grease
W.9 mg/L
U.9 mg/L
2
2.
Biochemical oxygen demand (BODs)
3.
Chemical oxygen demand (COD)
4.
Total suspended solids (TSS)
5.6 mg/L
4.7 mg/L
2
5.
Total phosphorus
6.
Total Keldahl nitrogen (TKN)
7.
Total nitrogen (as M
pH (minimum)
8.
pH (maximum)
r Sampling shall be conducted according to sufficiently sensitive test procedures (Le., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. Sea instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-21' (Revised 319) Page 7

EPAldenti5ratlen Number NPOES Perns Number Facility Name Oudtl Number Form Apprmed 010N79
110000347134 N00027227 Zenith Energy Selma OMB No. 20400004
TABLE B.CERTA IN CONVENTIONAL AND NON CONVENTIONAL•• . 40
List each pollutant that is limited in an effluent limitation guideline (ELG) that the facility is subject to or any pollutant listed in the facility's NPDES pennit for its process wastewater (if the
facility is operating under an existing NPDES permit). Complete one table for each outfall. See the instructions for additional details and requirements.
Pollutant and CAS Number (if available)
Maximum Dairy Discharge
( units)
Average Daily Discharge
a nN
Number of Storm
Events Sampled
Source of
Information
(new sounelnaw
dschagersonly; use
moesininshu (ions)
Grab Sample Taken
During First
30 Minutes
Flow -Weighted
Composite
Grab Sample Taken
During First
30 Minutes
Flow -Weighted
Composite
Benzene (7143-2)
< 1.0 ug/L
<1.0 ug/L
2
Ethylbenzene(100414)
<1.0 ug/L
<1.0 ug/L
2
Naphthalene (91-20-3)
<5.0 ug/L
<5.0 ug/L
2
Toluene (108-88-3)
<1.0 ug/L
< 1.0 ug/L
2
Xylene (1330-20-7)
<3.0 ug/L
<3.0 ug/L
2
r Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under40 GFR 136 for me analysis of pollutants Or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 GFR 122.21(ex3).
EPA Form 351112F (Reuied 319)
APR 17 2023
Nff)r--r "A"n"i'lFTS
Pa3e 9

Mr. John Hennessy April 10, 2023
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA NPDES Form 2F Attachment 1
Topographic Map

Mail XI Direction of
O Storm Water
Flow
/ rmreerr rac
Drainage
Area
Impeonrri ro r uar�ea avr
us
Drainage
Surfaces in
\ Drainage
\ imp e.a wa• Area
ae
rwma�"i+*irmua r ua � 4
Y �xnEm®Temvuk CPA Form 2F-Drainage Map
iunn'w0#5mvv Selma Terminal m
_ ._ Sdeia NCD4M NPDES Permit N. NCO027227 Renewal Appl¢ation _I

Mr. John Hennessy April 10, 2023
NPDES Permit No. NCO027227 Renewal Application
Zenith Energy Selma
EPA NPDES Form 2F Attachment 2
Analytical Reports

IceAnalXical'
May 03, 2022
Ben Smith
Zenith Energy Terminals
2999 West Oak Street
Selma, INC 27576
RE: Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Dear Ben Smith:
Pace Analytical services, LLC
9800 Kinmy Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on April 22, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me
Sincerely,
Sarah Graham
[e-mail]
[phone]
Project Manager
Enclosures
cc: Andrew Danhof, Zenith Energy
Bridget Fountain, Zenith Terminals
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 14

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Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Pace Analytical Services, LLC
980010ncey Ave- Suite100
Huntersville, NC 28078
[phone]
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
140114[t110IMCaP.P]
South Carolina Certification #: 99006001
South Carolina Drinking Water Cart. #: 99006003
Flodda/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water#: LA029
Virginia(VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
1ArginialVELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 14

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SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
MONTHLY STORMWATER
92600585
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92600585001
OUTFALL 1
EPA 1664B
ICO
i
PASI-C
EPA 624.1
SAS
8
PASI-C
SM 213OB-2011
CDC
1
PASI-A
SM 254OD-2015
MAB2
1
PASI-A
EPA 420.4 Rev 1.0 1993
KDF1
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 14

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ANALYTICAL RESULTS
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Pace Analytical Services, LLC
9800 Kinsey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL 1 Lab ID: 92600585001 Collected: 04/22/22 04:00 Received: 04/22/22 08:05 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Oil and Grease
624 Volatile Organics
Benzene
Ethylbenzene
Naphthalene
Toluene
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
Toluene-d8 (S)
1,2-Dichloroethane-d4 (S)
2130B Turbidity
Turbidity
2640D Total Suspended Solids
Total Suspended Solids
420.4 Phenolics, Total
Phenolics, Total Recoverable
Date: 05/03/2022 10:34 AM
Analytical Method: EPA 1664E
Pace Analytical Services - Charlotte
NO mg/L
4.9
1
04/25/22 22:34
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
NO ug/L
1.0
1
04126/2219:40
71-43-2
NO ug/L
1.0
1
04/26/22 19:40
100-41A
NO ug/L
5.0
1
04/26/22 19:40
91-20-3
ND ug/L
1.0
1
04126/2219:40
108-88-3
NO ug/L
3.0
1
04126/2219:40
1330-20-7
103 %
70-130
1
04/26/22 19:40
460-004
107 %
70-130
1
04/26/22 19:40
2037-26-5
95 %
70-130
1
04/26/22 19:40
17060-07-0
Analytical Method: SM 213OB-2011
Pace Analytical Services -Asheville
6.3 NTU
1.0
1
04/2312214:27
Analytical Method: SM 2540D-2015
Pace Analytical Services -Asheville
5.6 mg/L
2.5
1
04/26/2212:41
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation
Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services -Asheville
NO mg/L
0.020
1
05/02/2213:09 05/0312209:02
64743-03-9 M1. R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wntten consent of Pace Analytical Services, LLC.
Page 4 of 14

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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite too
Huntersville, NC 28078
[phone]
Project:
MONTHLY STORMWATER
Pace Project No.:
92600585
QC Batch:
693977
Analysis Method: EPA 1664B
QC Batch Method:
EPA 1664B
Analysis Description: 1664 HEM, Oil and Grease
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92600585001
METHOD BLANK: 3625107 Matrix: Water
Associated Lab Samples: 92600585001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L.NO 5.0 04/25/22 22:34
LABORATORY CONTROL SAMPLE:
3625108
Spike LCS
LCS
% Rec
Parameter
Units
Cona Result
% Rec
Limits
Qualifiers
Oil and Grease
mg/L
40 34.2
86
78-114
MATRIX SPIKE SAMPLE:
3625109
92600773001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
%Rec
Limits Qualifiers
Oil and Grease
mg/L
NO 38.6
31.2
79
78-114
SAMPLE DUPLICATE: 3625110
92600773002 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Oil and Grease
mg/L
ND 1.81
Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 14

aceAnalytical e
www.pacalasa.cala
I
Project:
MONTHLY STORMWATER
Pace Project No.:
92600585
QC Batch:
694160
QC Batch Method:
EPA 624.1
Associated Lab Samples: 92600585001
QUALITY CONTROL DATA
Analysis Method: EPA 624.1
Analysis Description: 624 MSV
Laboratory: Pace Analytical Services - Charlotte
Pace Analytical Services, LLC
9800 Kincey Ave. Sufte 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 3625966
Matrix: Water
Associated Lab Samples: 92600585001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Benzene
ug/L
ND
1.0
04/26/2212:14
Ethylbenzene
ug/L
NO
1.0
04/26/2212:14
Naphthalene
ug/L
NO
5.0
04/26/2212,14
Toluene
ug/L
ND
1.0
04/26/2212:14
Xylene (Total)
ug/L
NO
3.0
04/2622 12:14
1,2-Dichloroethane-d4 (S)
%
91
70-130
04/2622 12:14
4-Bromofluorobenzene (S)
%
103
70-130
042622 12:14
Toluene-d8 (S)
%
107
70-130
04/2622 12:14
LABORATORY CONTROL SAMPLE:
3625967
Spike
LCS
LCS %Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Benzene
ug/L
20
18.0
90
70-130
Ethylbenzene
ug/L
20
18.0
90
70-130
Naphthalene
ug/L
20
20.0
100
70-133
Toluene
ug/L
20
18.2
91
70-130
Xylene (Total)
ug/L
60
54.1
90
70-130
1,2-Dichloroethane-d4 (S)
%
99
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8(S)
%
100
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3625968
3625969
MS
MSD
92600721001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conic.
Conc.
Result
Result
% Rec
% Rec
Limits
ROD Qual
Benzene
ug/L
NO
80
80
81.9
80.0
102
100
75-125
2
Ethylbenzene
ug/L
ND
80
80
87.0
83.5
109
104
75-134
4
Naphthalene
ug/L
NO
80
80
78.8
74.0
98
92
57-150
6
Toluene
ug/L
0.41
80
80
473
462
76
62
75-134
2 M1
mg/L
Xylene (Total)
ug/L
NO
240
240
259
249
108
104
66-145
4
1,2-Dichloroethane-d4 (S)
%
95
99
70-130
4-Bromofluorobenzene (S)
%
102
101
70-130
Toluene-d8 (S)
%
98
99
70-130
Results presentee on this page are in the unite indicatee by the'Unhs' column except where an ahemate unit is presentee to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/032022 10:34 AM without the written consent of Pace Analytical Services, LLC.
Page 6 of 14

_ aceAnalytical e
ww.pacelaba.cam
QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
QC Batch: 693760 Analysis Method: SM 213OB-2011
QC Batch Method: SM 213OB-2011 Analysis Description: 2130E Turbidity
Laboratory: Pace Analy6pl Services - Asheville
Associated Lab Samples: 92600585001
METHOD BLANK: 3624143 Matrix: Water
Associated Lab Samples: 92600585001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Turbidity NTU NO 1.0 04/2312214:25
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)8769092
LABORATORY CONTROL SAMPLE:
3624144
Spike
LCS LCS
%Rec
Parameter
Units
Cone.
Result %Rec
Limits Qualifiers
Turbidity
NTU
10
10 100
90-110
SAMPLE DUPLICATE: 3624145
92600585001
Dup
Parameter
Units
Result
Result RPD
Qualifiers
Turbidity
NTU
6.3
6.3
0
RECEIVED
APR 17 2023
NCDEQ/DWR/NPDES
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is present" to the right of result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/031202210:34 AM without the written consent or Pace Analytical Services,LLC. Page 7of 14

acek7alytical
waw.Dacela0s.cam
Project:
MONTHLY STORMWATER
Pace Project No.:
92600585
QC Batch:
694058
OC Batch Method:
SM 2540D-2015
Associated Lab Samples: 92600585001
METHOD BLANK: 3625W
Associated Lab Samples: 92600585001
QUALITY CONTROL DATA
Analysis Method:
Analysis Description:
Laboratory:
Matrix: Water
SM 254OD-2015
2540D Total Suspended Solids
Pace Analytical Services - Asheville
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L NO 2.5 04IM22 12:38
Pace Analytical Services, LLC
9800 Kinsey Ave. Suite too
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE & LCSD:
3625545
3625877
Spike
LCS LCSD
LCS LCSD % Rec Max
Parameter
Units
Conc.
Result Result
% Rec % Rec Limits RPD RPD Qualifiers
Total Suspended Solids
mg/L
250
254 246
102 98 90-110 3 25
Results presented on this page are in the units indicated by the ^Units" column except where an ahemate unit is preserdetl to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC.
Page 8 of 14

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I
QUALITY CONTROL DATA
Pace Analytical Services, LLC
98001(inceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project. MONTHLY STORMWATER
Pace Project No.: 92600585
QC Batch: 695057
Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993
Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92600585001
METHOD BLANK: 3630318
Matrix: Water
Associated Lab Samples: 92600585001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Phenolics, Total Recoverable mg/L
ND 0.020
05/03/22 07:45
LABORATORY CONTROL SAMPLE: 3630319
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
%Rec Limits Qualifiers
Phenolics, Total Recoverable mg/L
0.05 0.049
98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3630320 3630321
MS MSD
35710941001
Spike Spike MS
MSD MS MSD
%Rec
Parameter Units Result
Conc. Conc. Result
Result %Rec %Rec
Limits RPD Qual
Phenolics, Total Recoverable mg/L 0.0076
0.05 0.05 0.049
0.056 85 98
90.110 12 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3630322 3630323
MS MSD
92600585001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc, Conc Result
Result % Rec % Rec
Limits RPD Qual
Phenolics, Total Recoverable mg/L NO
0.05 0.05 0,049
0.040 99 81
90-110 20 M1,R1
Results presented on this page are in the units indicated by the "units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC.
Page 9 of 14

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QUALIFIERS
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
NO - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kinoey Ave. Suite 100
Huntersville, NC 28078
[phone]
POL- Practical Quantitation Limit.
RL- Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270, The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
OUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
'Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited anaytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/03/2022 10:34 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 14

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: MONTHLY STORMWATER
Pace Project No.: 92600585
Lab ID
Sample ID
QC Batch Method
QC Batch
92600585001
OUTFALL 1
EPA 1664B
693977
92600585001
OUTFALL 1
EPA 624.1
694160
92600685001
OUTFALL 1
SM 2130E-2011
693760
92600585001
OUTFALL 1
SM 2540D-2015
694058
92600585001
OUTFALL 1
EPA 420.4 Rev 1.0 1993
695057
Date: 05/03/2022 10:34 AM
REPORT OF LABORATORY ANALYSIS
This vepon shall not t>e reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
EPA420.4 Rev 1.0 1993 695382
Page 11 of 14

laboratory receli ing samples:
Asheville ❑ Eden❑ Greenwood [] Huntersville ❑ Raleigh�Mechanicsellle❑ Atlanta❑ Kemersville❑
C ient Name: Pr/ WO# : 92600585
cetuw: 0 c t❑uPsncf�lsps der M porn
0 Commercial ace ❑0ther:,_ 111111 I'll I I I' IIII I III
Custody Sal Present? Oyes o Seals 92600585
�N ❑Yes �JNo'
Paddng Material: ❑Rubble Wrap ❑Bubble Rags ❑None Other
Thermometer.
❑III Gun 10: '?az s Typeofla: ❑Wet ❑Blue
G? correction Factor:
Cooleriemp: _L• S_ Add/Subtmct('C) (0 -U
Calder Temp Corrected ('Cl--
USDA Regulated Soll f N/A, water sample)
Date/InItla6Penon EuminNg Contenb:`L' Z2� 22 ll�
Biological Tissue Frozen?
[]NOW ❑Yes ONO ❑N/A -
Temp should be above freezing to 6'C - -
❑Sampmc autof temp aherla. Samples on to, cooling preen
hasbegun
COMMENTS(SAMPLE DISCREPANCY Field Data Required? ❑Yes []No
Lot ID of split comalnen:
CLIENT NOTIFIGnON/RESOLU?ION
Person contacted:
Proleet Manager SCURF Review:
Date/nme:
Date:
PrelOct Manager SRF Review: Date;
j I I
Page 12 of 14

Document Name:
Document Revised: November 15, 2021
San ktandl Upon Rece SOUR
Page 2of2
Document No.:
Issuing Auth W.
t
FC42,04133-Re1rM
Pace Carolinas Qu9IftY Office
*Check mark top half of box if pH and/or dechlorination Is
verified and within the acceptance range for preservation
samples.
Eaupdorw VOA, CGRrorrm, TOC, OD and Grease, DRO/9015 (water) DOC, LLNg
**Bottom half of box Is to list number of bottles
°'e"R WO# : 92600585 j
PH: SNG
Owe
CLIENT: 92—Zen! hENGale: 05/06/22
on
No
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Page 13 of 14

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December 02, 2022
Ben Smith
Zenith Energy Terminals
2999 West Oak Street
Selma, NC 27576
RE: Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Dear Ben Smith:
Pace Analytical services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NO 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on November 16, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Chadotte
• Pace Analytical Services - Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Adel S Fitzgerald
[e-mail]
[phone]
Project Manager
Enclosures
cc: Andrew Danhof, Zenith Energy
Bridget Fountain, Zenith Terminals
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wriaen consent of Pace Analytical Services, LLC.
Page 1 of 14

;aoAnalytical R
www.pecelebs.com
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Pace Analytical Services Charlotte
South Carolina laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification It: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cart. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water#: LA029
Virginia/VELAP Certification #_460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
Pace Analytical Services, LLC
9800 Kinsey Ave. Suite too
Huntersville, NC 28078
[phone]
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification #: 633
North Carolina Drinking Water Certification #: 37738 Virginia/VELAP Certification #: 460025 _
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 14

PaceAnalytical
-- www.pacelabUDIn
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
98001(incey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92636946001 FALL OUT 1
SM 213OB-2011
AED
1
PASI-E
SM 254OD-2015
VLG
i
PASI-E
EPA 1664E
REL
1
PASI-C
EPA 624.1
SAS
8
PASI-C
EPA 420.4 Rev 1.0 1993
li
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 14

aceAnalytical
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
980010ncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Sample: FALLOUT 1 Lab ID: 92636946001 Collected: 11116122 06:01 Received: 11/16/22 08:50 Matrk Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua[
2130E Turbidity EDN
Analytical Method: SM 213OB-2011
Pace Analytical Services - Eden
Turbidity
4.4 NTU
1.0
1
11/17/2217:39
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
3.8 mg/L
2.5
1
11/18/22 14:53
HEM, Oil and Grease
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Oil and Grease
ND mg/L
4.9
1
12/02/22 01:20
624 Volatile Organics
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
Benzene
NO ug/L
1.0
1
11/22122 19:43
71-43-2
Ethylbenzene
ND ug/L
1.0
1
11/22/22 19:43
100414
Naphthalene
NO ug/L
5.0
1
11/22/2219:43
91-20-3
Toluene
NO ug/L
1.0
1
11/22/22 19:43
108-88-3
Xylene (Total)
ND ug/L
3.0
1
11/22/22 19:43
1330-20-7
Surrogates
4-Bromo6uorobenzene (S)
101 %
70-130
1
11/22/22 19:43
46D-00-4
Toluene-d8(S)
106 %
70-130
1
11122/22 19:43
2037-26-5
1,2-Dichloroethane-d4 (S)
84 %
70-130
1
11122/22 19:43
17060-07-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services -Asheville
Phenolics, Total Recoverable
NO mg1L
0.020
1
11/29/22 11:10 11/30/22 07:52
64743-03-9 Mt
Date: 12/02/2022 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC,
Page 4 of 14

ZeAnalXical'
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I
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Klncey Ave. Suite 100
Huntersvllle, NC 28078
[phone]
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 737883
Analysis Method:
SM 213OB-2011
QC Batch Method: SM 213OB-2011
Analysis Description:
2130B Turbidity EDN
Laboratory:
Pace Analytical Services - Eden
Associated Lab Samples: 92636946001
METHOD BLANK: 3840397
Matrix: Water
Associated Lab Samples: 92636946001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Turbidity
NTU
NO
1.0 11/17/2217:38
LABORATORY CONTROL SAMPLE: 3840398
Spike LCS
LCS % Ree
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Turbidity
NTU
20 19.8
99 90-110
SAMPLE DUPLICATE: 3840399
92636946001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Turbidity
NTU
4.4
4.6 4
SAMPLE DUPLICATE: 3840400
92636986001 Dup
Parameter
Units
Result Result
RPO Qualifiers
Turbidity
NTU
8.3
8.2 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 14

aceAnalj6cal e
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QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 738103 Analysis Method: SM 254OD-2015
QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92636946001
METHOD BLANK: 3841247
Associated Lab Samples: 92636946DOI
Parameter
Units
Total Suspended Solids
mg/L.
LABORATORY CONTROL SAMPLE: 3841248
Parameter
Units
Total Suspended Solids
mg1L
Pace Analytical Services, LLC
98001oncey Ave. Suite too
Huntersville, NC 28078
(704)87&9092
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 2.5 11/1812214:45
Spike LCS LCS %Rec
Conc Result %Rec Limits Qualifiers
250 242 97 90-110
SAMPLE DUPLICATE: 3841249
92636671001 Dup
Parameter Units Result Result RPD
Total Suspended Solids mg/L 36.5 36.2 1
SAMPLE DUPLICATE: 3841250
92636954001 Dup
Parameter Units Result Result
Total Suspended Solids mg/L 800 1060
Qualifiers
RPD Qualifiers
28 D6
Results presented on this page are in the units indicated by the "Units" column except where an axereate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 14

aceAnalyticalT'
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunteraville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 740573 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92636946001
METHOD BLANK: 3852864
Associated Lab Samples: 92636946001
Parameter Units
Oil and Grease mg/L
LABORATORY CONTROL SAMPLE: 3852865
Parameter Units
Oil and Grease mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 5.0 1210212201:20
Spike LCS LCS % Rec
Cones Result % Rec Limits Qualifiers
40 36.5 91 78-114
MATRIX SPIKE SAMPLE:
3852866
35760623001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Oil and Grease
mg/L
1JU
39.2
32.6
81
78-114
SAMPLE DUPLICATE: 3852867
35761797001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Oil and Grease
mg/L
1AU
ND
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the tight of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC- Page 7 of 14

Z5OAnalytical
www.pacelabs.cont
Project:
MONTHLY STORMWATER
Pace Project No.:
92636M
QC Batch:
738817
QC Batch Method:
EPA 624.1
Associated Lab Samples: 92636946001
METHOD BLANK: 3844910
Associated Lab Samples: 92636946001
QUALITY CONTROL DATA
Analysis Method: EPA624A
Analysis Description: 624 MSV
Laboratory: Pace Analytical Services - Charlotte
Matrix: Water
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Benzene
ug/L
NO
1.0
11/2212212:15
Ethylbenzene
ug/L
ND
1.0
11/22/22 12:15
Naphthalene
ug/L
NO
5.0
11/22/22 12:15
Toluene
ug/L
NO
1.0
11/22122 12:15
Xylene (Total)
uglL
ND
3.0
11/22/22 12:15
1,2-Dichloroethaned4 (S)
%
84
70-130
11/22/22 12:15
4-Bmmofluorobenzene (S)
%
104
70-130
11/22/22 12:15
Toluened8 (S)
%
105
70-130
11/22/22 12:15
LABORATORY CONTROL SAMPLE:
3844911
Spike
LCS
LCS %
Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Benzene
ug/L
20
18.7
93
70-130
Ethylbenzene
ug/L
20
21.0
105
70-130
Naphthalene
ug/L
20
24.0
120
70-130
Toluene
ug/L
20
18.8
94
70-130
Xylene (Total)
ug/L
60
64.4
107
70-130
1,2-Dichloroethaned4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluened8 (S)
%
95
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3844912
3844913
MS
MSD
92637069001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Cono.
Result
Result
%Rec
%Rec
Limits
RPD Dual
Benzene
ug/L
NO
20
20
22.1
21.3
110
107
70-142
3
Ethylbenzene
ug/L
NO
20
20
22.1
22.3
110
111
70-143
1
Naphthalene
ug/L
NO
20
20
21.7
22.0
108
110
62-149
2
Toluene
ug/L
ND
20
20
22.0
21.8
110
109
69-144
1
Xylene (Total)
ug/L
NO
60
60
65.8
66.2
110
110
61-163
1
1,2-Dichlomethaned4 (S)
%
103
105
70-130
4-Bmmofluorobenzene (S)
%
100
101
70-130
Toluene-d8 (S)
%
99
100
70-130
Resuas presented on this page are In the units Indicated by the' Untts" column except where an altemate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 14

aceAnalytical e
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 rincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
QC Batch: 739433
Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993
Analysis Description: 420.4
Phenolics
Laboratory: Pace Analytical Services
-Asheville
Associated Lab Samples: 92636946001
METHOD BLANK: 3847539
Matrix: Water
Associated Lab Samples: 92636946001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Phenolics, Total Recoverable mg/L
NO 0.020
11/3022 06:50
LABORATORY CONTROL SAMPLE: 3847540
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
%Rec Limits
Qualifiers
Phenolics, Total Recoverable ml
0.05 0.052
105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3847541 3847542
MS MSD
92636946001
Spike Spike MS
MSD MS
MSD %Rec
Parameter Units Result
Conc. Conc, Result
Result % Rec
% Rec Limits RPD Dual
Phenolics, Total Recoverable mg/L ND
0.05 0.05 0.052
0.052 79
81 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3847543 3847544
MS MSD
92636991001
Spike Spike MS
MSD MS
MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result %Rec
%Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L ND
0.05 0.05 0.048
0.051 92
99 90-110 7
Results presented on this page are in the units Indicated by the "Units' column except where an ahemate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/022022 02:27 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 14

aceAnalytical e
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I
QUALIFIERS
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
NO - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite too
Huntersville, NC 28078
[phone]
PQL- Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyze in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate h recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results am not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
'Total' may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
Ml Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/02/2022 02:27 PM without the written consent of Pace Analytical Services, LLG Page 10 of 14

aceAnalytica(
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I
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: MONTHLY STORMWATER
Pace Project No.: 92636946
Lab ID
Sample ID
QC Batch Method
QC Batch
92636946001
FALL OUT 1
SM 2130E-2011
737883
92636946001
FALL OUT 1
SM 254OD-2016
738103
92636946001
FALL OUT 1
EPA 16648
740573
92636946001
FALL OUT 1
EPA 624A
738817
92636946001
FALL OUT 1
EPA 420.4 Rev 1.0 1993
739433
Date: 12/02/2022 02:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
EPA 420.4 Rev 1.0 1993 739782
Page 11 of 14

Anc:Cnne:
upcn Rep
Vol Tech Spec sanwi® rion"On
Achevllle ❑ Eden ❑ Gfew wood ❑ HuntwMffe ❑ "Ieigv MWmksAe[l AtIanNE] xenuusAe❑ !
Client Name:
?0&�P�—US�M�Qp"
Ex�`k WO# � 92636946
Courier.L
�ICommercial ❑Pace I
�er'�sPwmbr: aseae
Qiaadysnl Present? Yea Snets ibtew []Yes '"po �
❑ No /aate/1Ntiaii cerson Fsuminirrg Contems:
PaddngMaterlal: EjBUbbla Wrap i
QBubbla Bags one ❑ Other BlofogirAT�ie Froun7 {
Thermometer: ❑ at Gun ID: - ❑rK Elan QN/A j
I 1
,�
iypeoflae: Wet ❑Blae ❑None ! �.
CaolerTeeap(t): 2,q Cem�Oapaiha Addlb mct('C) Y1
-i. ren+P should be.trove Preebngto 6'e
Coraected CoolerTeanpl'C, Z- QSamplesaWoftmpaaer®.Samplesonlcp coflnjprmW
USDA RetWated Shc( N/A, water simple) hisbegun
Did am orlainote QumardBce zone wehm the United states: rA, NY, wu (check maps)? og smptrs warm nmn a forerun more rxrtnln(nnnda..
Correct ContWoM Used?
Sample Labels Match CDC?
Ona OwA 16.
ONO i A
Person Contacted: Dawraw —.
Prolact Manager SCURF Wean
Project Manager SRF Review:Y
QUsltrax Document ID: 70677
Date:
Dater
Field note kWrired?
Pape 1 ot2
Mo -

..�,.r�"UU04 •Vt_rs h apse San
Upon ftecsipt
..�.ae tlfioticv Deli wmfvi
'Chadc nmktop hmNaf box W pH and/or dablorbsom Pr*4 B
praervattan famplef,
Owe"*= V"QWxkNC,. 01 ad Coen, DwIsais aw)oo.1Wg
a'Yattmcthoof box btoYetmsnberof, woo
***Cho* aG unprwrvad NYtates for ddorMs
3
UO Bald, In mim* WSennva, a t of tamp, inmrtaa mrc km)
Qualtrax DodnneM 1D: 70877
Wadi : 92636946
pN: ASF Due Dale: 22/02/22
CLIENT: 82-ZentlhENG
amw
Paga 2 of 2
i
i
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II
i I i
I I
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I
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i
Page i3 i

e
__ aceAnalytical
wWW.Pecele03.c4m
February 02, 2022
Ben Smith
Zenith Energy Terminals
2999 West Oak Street
Selma, NC 27576
RE: Project: WET Testing - NCO027227
Pace Project No.: 92582619
Dear Ben Smith:
Pace Analytical services, LLC
9800 xinmy Ave- Suite 100
Huntersville, NC 28078
(704)8759092
Enclosed are the analytical results for sample(s) received by the laboratory on January 13, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sarah Graham
[e-mail]
[phone]
Project Manager
Enclosures
cc: Andrew Danhof, Zenith Energy
Bridget Fountain, Zenith Terminals
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, U.C.
Page 1 of 8

- -
Document Name:
Document Revised: November 15, 2021
r
" a
Ss Condition U SCUR
Pa t of 2-
.Document No.:
Issuing Authority:
_ �1'
FCAR.CS-033.Rev,Og -
'Pace Carolinas Quali tJNire
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Hunterwille ❑ Raleig-llAechanicsville[j Atlanta❑ Kernersville❑
client Name: �.larojeCLWO# : 92582619
under: odd PS OU PS'A y' �o ` IIIIII II IIIIIIIII II III
❑ Commercial Pace ❑Other:_ " ' 92582619
Custody Seal preunt? ❑Yes 11(JNO Seals Intact? ❑Yes YJFJo .p
CCC �" �T oata/InaiakPwon mmkdsgtontemnl
Packing Material: []Bubble Wrap lecwbble Bags ❑Nome/ ❑ 'Other
Thermomaten „r SIWet ❑aloe
❑iRe�n ID: y� f1 U� Type of loe: r"'t
CotteNoo Factor: (/ V
Cooler Temp:---r",_ 19 Add/Subtractr000 V �
Cooler Temp CormctecircI. P- -
USDA Regulated Sell i WNIA, water sample)
Did samples originate In a quammine zone within the United States: CA, NY, or SC jdleck maps}?
f1o_ flu
eloksgical TisweF ?
. ❑Yes []NO WA
[]NOW
Temp should be above freezing to 6"C
❑Samples out oftemp atserie. Samples on ice, cooling proms
has begun
Did samples oftnatefmm a foreign source Ilmemationally,
:,.liui'v,s Naunll and A.M Rim17 FIVes r1No
-
Comments/DI
Chain of Custody Present?
Yes
nN. A
1.
Samples Arrived within Hold Thee?
ON. ❑WA
L
Short MW Time Analysis e72 hr.)?
Yes
DWQQhLA
3.
RushTumAraund Time Requested?
Yes
WA
4.
SuigdemVdume7
es
ElNo N/A
S.
Correct Containers Used?
-Pam Containers Used?
es
Yes
[IN.❑N/A
No DMIA
6. -
Containers Intact?
Yes
[JN. ONIA
7.
Dissolved am Ls: Samples Held Filtered?
Elft
EjNo A
a -
Sample tdbels Match CDC?
-Includes Date/TimeAD/Ana ads Matrbr.
'RYM
w
[]No ❑N/A
9.
Headspacein VDAVlak >S-6min 7
%Yes
No -UWA
10.
iQl�
tie �QQ� Cl fl�r"I
Trip Blank Presem7
Inip, BlankCustady Seals Present?
cs
Yn
1--]No ,WA
No JJKJA
IL
COMMENTS/SAMPLE VISCREPANCY
Fidd Date Requkgd? ❑Yes []No
Person contacted: Date/Time:
Project Manager SCURF Review Dare:
ProlectManager SRFRovnewn. new: ,
Page 2 of

Dowment
Doesiment
`Check mark top hall of box H pH and/or dechlorination is Project If
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Collform,= Oil and Grease, DXO/e915 (water) DIX "i
""Bottom half of box is to list number of bottles
locomen Revised: November 15, 2021
Paw 2 of 2
IssuingAuniority,.
Pam Carolinas Ouallty Office
WO#:92582619
PM: SMG Due Date: 01/24/22
CLIENT: 92—ZenIthENG
MESSOMENNE
MEN
ELI
�■
■
■n
Note: Whenever there is a dlscrepanly affecting mrtAWmana camplmnce samples, a copy ov ma, soma me m sena w me north i mina vmrva viinm uvnv ce p.e.
out of hold, Incorrect ioe atlae, out oftamp, Incorrectcumainars.
Page 3 of 8',

ET.-T.....
P.O. Box 16414 Creentelle.:C 29606
(E84)677-6842.rAX [phone]
4 Craflarnan Ctnxl, Gt-at, SC 29650
Pimephales promelas 24-Hour Acute Definitive Test
EPA-821-R-02-013 Method 2000
Client: ZENITH ENERGY
Facility: OUTFALL 1
NPDES #: NCO027227
Test Date: 14-Jan-22
Laboratory ID #: T61026
Test Reviewed and Approved By:
4/
Robert W. Kelley, Ph.D.
President
Admits
Mr
Certification #E87819
Test results presented in this report conform to all requirement of
P't-A -:�). ate'
Patrick D. Timms
QA/QC Officer
.SCDHEC Certification#23m
NELAC, conducted under NELAC Certification Number E87819
Florida Dept. of Health. Included results pertain only to provided sanPICS.
age 1 of 4
NCDENR Certification # 022 Page 5 of 8

Effluent Toxicity Report Form - Chronic PasslFail and Acute LC50
Date 27-Jan-22
Facility: ZENITH ENERGY OUTFALL 1 NPDES# NCO027227 Pipe # 001 County:
Laboratory Performing Test:
X
Comments
Signature of Operator in Responsible Charge X 'c'f'"r �7A
i✓
Signature of Laboratory Supervisor
MAIL ORIGINAL TO Environmental sciences Branch
Div. of Water quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
t r.. rr •t •t t
CONTROL ORGANISMS
# Young produced!
Adult (L)ive (D)ead
Effluent %
Iculated t=
tical Value=
Reduction=
Control
TreaMent2 Treatment
Central Go
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
#Young Produced %3rd Broad PASS FAIL
Adult (L)ive (0)ead
Complete This for Either Test Test Start Date
Wlection (Start) Date 4- Jan -22
pH lstsample lstsample 2nd sample Sample 13Jan-22 Semple NA
Control Samule
TYse (Duration)
Treatment 2 Gab comp oaafion 1s1 zntl
Sample 1 X Tax Ton
Sample 2 Dilution Sample Sample
Start and start end sun and D.O. lst sam le lst sam le 2nd sa fe Hardness (mglL) 8$.4
Control Spec. Cord. (pmhos) 317 19
Treatment Chlorine(mg/L)
Sample Temp. at receipt (°C) D.$
LC501Acute Toxicity Test
(Mortality expressed as %, mmbining replicates)
0 6.25 12.5 25 50 100 ]Concentration
Q 0 0 0 0 0 1 1 1 Mortality sWNend starVend
LC50 = > 100 % Method of Determination 7.8 77 Control 1 7.71 7.1
95% Confidence Limits Moving Average Probit O 7.11 7.1 High Cone. 1 9.41 7.4
NPeu NA % Spearman Karber ROther X _ pH D.O.
Page 6 of 8
Page 2 of 4

24 Hour Acute Toxicity Test
12M th d 2000 Pime h ' ales accruals -
I est manned. EPA 821 R-02-0
e o P
ent:
am e
Start Date: 01 /14/22 Time: 03:40 PM
Set By: AM
Ended By* AM
End Date: 01/15/22 Time: 04:36 PM
Test Vessel
Test Solution Volume Incubator
Transfer Volume Dilution Water
Fatheatl ows
r111-1Minnplastic wp
200 mL 91
0.5 mL MHSF
RancloomationvefitmaianSOP INeortate. from common holding vessel t: 50-1 ftc. 16 far fi&W 8hr dark
TEST ORGANISMS
or Cerlo ap aia u to Comments:
Date Removed: Between: and: FISH HATCHED ON 1/3/22
ime hales romelas Source: ABS a old: 11 BTW 1500-1630 ET
sido sis bahia Source: Days old:
Test Organisms Pre Fed by: AM Time: 1300
MORTALITY DATA
®M
Initial
Final
emc
O.O.
PH
Condl
Salini
BY:
Teru
O.O.
H
Cond/
Salini
BY:
24.6
7.7
7.N
AM
25.3
7.1
7.7
AM
24.6
7.8
79
AM
25.31
691
7.6
AM
2487-77F
7.9
AM
25.31
6.91
7.5
AM
24.91
8.11
7.8
AM
25.31
7.11
T51
JAM
--T7M-
25.11
8AI
7.71
25-3
1 7,11
7,4
25,11
9.4
7.1
AM
25.3
7.4
71
AM
°C
m L
PPT
°C
m L
PPT
Page 3 of 4
Page 7 of 8

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Page 8 of 8
Page 4 of 4