Loading...
HomeMy WebLinkAboutWQ0007798_Monitoring (Report)_20230414ERM March 31, 2023 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Mr. Mike Rogers NCDEQ —Division of Water Resources — UIC Program 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Phone 919-807-6496 ogersCo' ncdenr.gov via FedEx Reference: 2022 Annual Groundwater Monitoring Report Former Toastmaster Facility 17160 Plant Road Laurinburg, North Carolina Permit No. WQ0007798 Dear Mr. Rogers: F phone: +1 704 541 8345 +1 704 541 8416 .erm.com ERM NC, Inc., on behalf of Toastmaster, Inc., is pleased to present the results of the 2022 annual groundwater monitoring events as well as groundwater remediation activities conducted at the subject site. The enclosed report was completed in accordance with Non -discharge Permit No. WQ0007798. Please let me know if you have any questions about the application. I can be reached at 704-409-3438 or michael.presslgy(�i_)err. Sincerely, P Michael Pressley, P.G. Principal Consultant enclosure cc: Toastmaster, Inc. — Jim Skaggs DWR Fayetteville Regional Office RECEIVED APR 14 2023 HIC DEQ/DWR Central Office sustainable solutions in n7ore competitive world ERM 2022 Annual Groundwater Monitoring Report Toastmaster, Inc. — Ingraham Time Products Facility Laurinburg, North Carolina RECENIE® Permit No. WQ0007798 APR 14 2023 29 March 2023 NC DEQ/OWR Project No.: 0588976 Central Office -J--- The business of sustainability L R I rN � r 4W t Y� PLO 29 March 2023 2022 Annual Groundwater Monitoring Report Toastmaster, Inc. — Ingraham Time Products Facility Laurinburg, North Carolina Permit No. WQ0007798 _0001* VEAL 2223 Nye' lo,];"c�•�': $ s�aE°deeturtaeau�e'vo. Michael Pressley, P.G. Project Manager ERM NC, Inc. 300 West Summit Ave, Suite 330 Charlotte, North Carolina 28203 © Copyright 2023 by ERM Worldwide Group Ltd and / or its affiliates ("ERM"). All rights reserved. No part of this work may be reproduced or transmitted in any form, or by any means, without the prior written permission of ERM "- 76-4-, �-- Rick Tarravechia, P.G. Partner in Charge www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 CONTENTS CONTENTS 1. INTRODUCTION................................................................................................................................1 1.1 Scope of Work.................................................................................................................................................1 2. BACKGROUND INFORMATION.......................................................................................................1 2.1 Site Location....................................................................................................................................................1 2.2 Site History & Previous Investigations.............................................................................................................1 2.3 Geology & Hydrogeology.................................................................................................................................3 3. METHODOLOGY............................................................................................................................... 3 3.1 Groundwater Elevation Measurements............................................................................................................3 3.2 Groundwater Sample Collection......................................................................................................................4 4. GROUNDWATER MONITORING RESULTS....................................................................................4 4.1 Groundwater Elevations and Flow...................................................................................................................4 4.2 Groundwater Analyses.....................................................................................................................................4 5. REMEDIATION SYSTEM OPERATIONS..........................................................................................4 6. DISCUSSIONS AND CONCLUSION................................................................................................. 5 List of Figures Figure 1 - Site Location Map Figure 2 - Site Map Figure 3 — Groundwater Flow Map — May 2022 Figure 4 — Groundwater Flow Map — November 2022 Figure 5 - Groundwater Analytical Summary Map — May 2022 Figure 6 - Groundwater Analytical Summary Map — November 2022 Figure 7 — TCE Isoconcentration Map — May 2022 Figure 8 - TCE Isoconcentration — November 2022 List of Tables 1 Monitor Well Construction Data 2 Field Parameters 3 Groundwater Elevation Summary 4 Groundwater Analytical Summary- 2022 5 Historical Groundwater Analytical Summary- 2022 6 Graphs of TCE and cis-1,2-DCE Concentrations versus Time — Selected Indicator Wells 7 Monthly Influent and Effluent Sample Results for 2022 www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Page ii CONTENTS APPENDIX Al GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORMS - MAY 2022 APPENDIX A2 GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORMS - NOVEMBER 2022 APPENDIX 131 LABORATORY ANALYTICAL REPORT - MAY 2022 APPENDIX B2 LABORATORY ANALYTICAL REPORT - NOVEMBER 2022 APPENDIX C LABORATORY ANALYTICAL REPORTS - MONTHLY INFLUENT & EFFLUENT SAMPLES 2022 www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Page ii INTRODUCTION INTRODUCTION ERM NC, Inc. (ERM) of Charlotte, North Carolina has conducted the permit -required semi-annual groundwater monitoring during 2022 at the Toastmaster, Inc., Ingraham Time Products facility located at 17160 Plant Road in Laurinburg, North Carolina. Groundwater at the Site has been impacted by volatile organic compounds (VOCs), particularly trichloroethene (TCE). The current remedial approach for the existing groundwater plume is the operation of an extraction and treatment system. The system consists of three recovery wells through which VOC-impacted groundwater is extracted (pumped) and conveyed to an above -ground treatment system. The treated groundwater is then re -introduced to the surficial aquifer via an infiltration gallery. The groundwater extraction and treatment system operates under Non - Discharge Permit No. WQ0007798, which is effective February 1, 2019 through January 31, 2024. 1.1 Scope of Work The scope of work for the semi-annual monitoring event included: ■ Measurement of depth to water in eight groundwater monitor wells (MW-3, 5, 6, 7, 9, 10, 11, and 14) and the subsequent calculation of groundwater elevations in these same wells; and ■ Collection and analysis of groundwater samples from monitor wells MW-7 and MW-14 for VOCs. 2. BACKGROUND INFORMATION 2.1 Site Location The Toastmaster facility is located at 17160 Plant Road in Laurinburg (Scotland County), North Carolina. Figure 1 presents a Site location map. A detailed Site map is included as Figure 2. The facility is situated approximately one quarter of a mile northwest of the intersection of US401 and US15/US501. The surrounding property land uses are primarily mixed commercial and industrial. The 50-acre property contains a single building and an adjoining warehouse which are approximately 220,000 square feet in size. 2.2 Site History & Previous Investigations The following section presents a summary of historical Site activities and previous investigations. These details were obtained through a review of historical reports, discussions with facility and corporate personnel, and historical correspondence. The Toastmaster facility was originally developed in 1959 as the Ingraham Time Products clock manufacturing facility. The following provides a summary of previous Site ownership: 1959-1968 Ingraham Company 1968-1980 McGraw Edison Company 1980-1983 Toastmaster, Inc. 1983-1990 Magic Chef, Inc. 1990-Present Toastmaster, Inc. The Toastmaster facility ceased active operations in 2002. Between 2002 and 2004, the Site was utilized as a warehouse. During 2004, all on -site operations ceased. Manufacturing operations formerly conducted on -site during the lifespan of the facility included the manufacture, assembly, and packaging of www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Page 1 BACKGROUND INFORMATION electrical clocks and timers, waffle bakers, and sandwich toasters. Operations associated with manufacturing included the following: ■ Plastic molding: where resins are molded into parts using machinery which heats and shapes the resin into the desired form; ■ Tooling operations: including stamping machines and drill presses; ■ Silk screening: where ink is applied to the clock faces; ■ Chromium and nickel electroplating: Electroplating operations were formerly conducted in association with the manufacture of metal clock parts; ■ Wood cutting and sanding operations: where wood blanks are formed, cut to size, and sanded; and ■ Spray and dipping operations: including three dry filter paint booths and one dip tank which are used to apply finishings to the clock bodies. An on -site wastewater treatment plant was constructed during initial Site development in 1959. The wastewater treatment plant was used to treat plating wastewater formerly generated at the plant. Chromium and nickel electroplating wastewaters were treated to precipitate metals after hexavalent chromium had been reduced to trivalent chromium. The wastewater treatment plant included two large concrete settling tanks. Supernatant from the settling process was routed to a large unlined surface impoundment. Settled solids were spread in an unlined drying bed. Supernatant from the drying beds was collected and added to the effluent from the settling tank in the unlined surface impoundment. Liquid from the unlined surface impoundment was discharged to Irvin Creek until 1980, when the discharge was re- routed to the sanitary sewer system. The wastewater treatment operations were discontinued in 1984 and the treatment plant underwent a RCRA closure. At that time, Toastmaster voluntarily installed monitor wells to confirm the absence of groundwater contamination. The monitor wells were sampled by both the state agency and Toastmaster. According to the Environmental Audit Report prepared by Water and Air Research, Inc. in 1990, no chromium, cadmium, or cyanide had been detected in the groundwater samples collected from the wastewater treatment plant area. However, lead, nickel, and zinc were detected at concentrations substantially above background levels. A TCE recovery still was operated on the northwest side of the building from the late 1960s until the early 1990s. A fire pit, where the local fire department would practice extinguishing fires, was also located on - Site to the southwest of the building in the approximate location of the existing groundwater remediation system. TCE was identified in groundwater at the site in the early 1990s. A Site Characterization Report (SCR) was prepared by Groundwater Technology in 1991 to define the lateral and vertical extent of TCE impacted groundwater at the Site. The report indicated the presence of TCE and associated daughter compounds in the vicinity of the facility and extending to the south and southwest. Three potential source areas were identified, including: 1) The area along the northwestern side of the plant; 2) An area to the southwest of the plant in the vicinity of the now removed waste treatment system; and 3) The area to the extreme south of the Site where the removed waste treatment system was relocated. TCE concentrations in groundwater at that time ranged from 25 to 12,000 parts per billion (ppb). www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Page 2 3. METHODOLOGY No significant areas of affected soil have been identified at the Site. During the previous assessment, nine soil samples were collected from seven locations across the Site and analyzed for TCE using EPA Method 8010. TCE was not detected at concentrations greater than the laboratory method detection limit in the soil samples collected. Additionally, free product has not been detected in groundwater at the Site. A Corrective Action Plan (CAP), prepared by Richard Catlin and Associates, was approved by the North Carolina Department of Environment and Natural Resources (NCDENR) (currently called the NC Department of Environmental Quality (NCDEQ)) on July 2, 1993. The CAP focused on mitigation of TCE in the three potential source areas identified in the 1991 SCR. The overall Site remediation strategy consisted of the installation of three groundwater recovery wells. Based on the lack of detected TCE in soils, the proposed Site remedy focused on the recovery and treatment of TCE affected groundwater. A groundwater treatment system is currently in operation to address the TCE impacted groundwater at the Site. The groundwater extraction and treatment system operates under Non -Discharge Permit No. WQ0007798, issued by the NCDEQ, effective February 1, 2019 and will expire on January 31, 2024. The treatment system includes three recovery wells which discharge to an aeration tank and carbon filtration system for effluent treatment. At the time of the system design, treated groundwater could not be discharged to the municipal wastewater treatment plant. Consequently, a 500-foot long infiltration gallery was constructed along the northwest part of the Site to accept the effluent discharge. Fourteen groundwater monitor wells exist at the Site. In accordance with the permit, groundwater samples are collected from two of these wells (MW-7 and 14) on a semi-annual basis to monitor VOC concentrations at the Site 2.3 Geology & Hydrogeology The Laurinburg area lies in the Flatwoods section of the Middendorf Formation. Drainage is accomplished through large, sluggish streams and swampy flood plains. The Middendorf is underlain by the Cretaceous age Blackwoods Formation, which primarily consists of alternating clay and fine-grained sand layers. Surficial soils consist of fine- to medium -grained sandy clay mixtures. The geology beneath the Site is characterized by alternating clay and sand layers and is mapped as being underlain by several aquifers. Two significant zones of low permeability have been identified at the Site. The upper aquifer, present at a depth of approximately 15 feet below ground surface, is known as the surficial sand aquifer. The surficial sand aquifer has maximum thickness of 30 feet in the northern part of the Site and appears to become thinner towards the south end of the Site. The lower aquifer, known as the Cretaceous sand aquifer, begins at a depth of approximately 45 to 50 feet below ground surface. During sampling conducted as part of the SCR, groundwater was encountered between 12 and 17 feet below the ground surface. Shallow groundwater velocity at the Site was estimated to be 22.1 feet per year, with a general flow direction of south-southwest. 3. METHODOLOGY 3.1 Groundwater Elevation Measurements Groundwater monitoring events were conducted on May 10, 2022 and November 29, 2022. Prior to collection of groundwater samples, static water level measurements were obtained in eight of the Site monitor wells (MW-3, 5, 6, 7, 9, 10, 11, and 14) using an electronic water level meter. These measurements were used to establish the depth to groundwater in order to calculate groundwater elevations and the hydraulic gradient across the Site. The water level meter was decontaminated with an www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Page 3 4. GROUNDWATER MONITORING RESULTS alconox/water mix and a distilled water rinse between wells. Groundwater levels and their corresponding elevations are provided in Table 3. 3.2 Groundwater Sample Collection Groundwater samples collected from monitor wells MW-7 and MW-14 were analyzed for VOCs. Both wells were purged prior to sample collection using low -flow sampling procedures with a peristaltic pump (located at the ground surface) and dedicated polyethylene tubing inserted to the approximate mid -point of each well screen. The monitor wells were purged until field parameters stabilized or until at least three well bore volumes were extracted. Field measurements were collected for temperature, dissolved oxygen (DO), pH, oxidation reduction potential (ORP), specific conductance, and turbidity. Well construction details are presented in Table 1. Summary tables of field parameter measurements are presented in Table 2. Following purging, samples were collected in laboratory -provided containers. The samples were placed in chilled, insulated, shipping containers, and delivered under the appropriate chain -of -custody protocol to Pace Analytical Services, LLC., a North Carolina -certified laboratory, located in West Columbia, South Carolina. The collected samples were analyzed for VOCs using EPA Method 8260B. Groundwater Quality Monitoring Compliance Report Forms (GW-59 and GW-59A) for the 2022 events are included in Appendix A. 4. GROUNDWATER MONITORING RESULTS 4.1 Groundwater Elevations and Flow Groundwater flow in the surficial sand aquifer is to the south-southwest under an approximate hydraulic gradient of 0.012 as measured between monitor wells MW-5 and MW-6. The groundwater flow direction is consistent with historical observations. Figures 3 and 4 illustrate the groundwater flow directions for the May and November sampling events, respectively. 4.2 Groundwater Analyses The results of the May and November 2022 groundwater analyses are summarized in Table 4. TCE and cis-1,2-dichloroethene (DCE) were the only two VOCs detected during either sampling event. TCE concentrations exceeded the North Carolina 2L Groundwater Standards of 3.0 pg/L in both MW-7 and MW-14 during both events, with concentrations ranging from 11 pg/L to 49 pg/L. Cis-1,2 DCE concentrations were well under its 2L Standard of 70 pg/L. Figures 5 and 6 illustrate the groundwater analytical results for the May and November sampling events, respectively. Figures 7 and 8 present isoconcentration maps for TCE, the most prevalent compound in groundwater, for the May and November 2022 monitoring events. A historical summary of VOC data is presented as Table 5. Concentration versus time graphs for TCE and cis 1,2-DCE are presented as Table 6. Copies of the laboratory analytical reports for the two monitoring events are included in Appendix B. 5. REMEDIATION SYSTEM OPERATIONS The on -site groundwater remediation system consists of three recovery wells that are located in the southeast portion of the Site (RW-1), central portion of the Site (RW-2), and northwest portion of the Site (RW-3) (see Figure 2). Submersible pumps in each well pump VOC-impacted groundwater via www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Page 4 6. DISCUSSIONS AND CONCLUSION underground lines to an above ground treatment system located in the central portion of the Site, adjacent to RW-2. The initial remediation system operated from 1998 to 2020 when it was replaced with newer components. The new system was started in April 2020 and operates in the same manner as the previous system, which involves pumping water through a multi -tray air stripper and then through carbon filter media to absorb residual VOCs. The carbon media is contained within three canisters manifolded together. The treated groundwater is then pumped via underground piping to a subsurface infiltration gallery located in the northwest portion of the Site. Treated groundwater percolates into the surficial aquifer under gravity flow. Approximately 2,427,100 gallons of groundwater were treated from January through December 2022. Per the discharge permit, influent and effluent samples are collected on a monthly basis and analyzed for VOCs and pH. Laboratory reports for monthly samples are provided in Appendix C. Analytical results indicate that VOCs were removed at rates ranging from 67% to 100%. TCE was removed at levels ranging from 99.6% to 100%. There were no effluent exceedances during 2022. The remediation system was operational 40% of year, from January through December 2022. The longest shut down time was between late April and early October (196 days), during which time repairs were made to an underground system line. The second shut down was between first of November and mid -December to replace the air stripper discharge pump. The pH for influent has historically been below the permit required 6.5-8.5, with a range of 5.1 to 6.2 during 2022. Effluent pH was slightly higher, ranging from 5.7 to 6.4. These pH values are considered background for the shallow coastal plain groundwater. A summary of the monthly results for 2022 are provided in Table 7. 6. DISCUSSIONS AND CONCLUSION Groundwater remediation activities during 2022 included the operation of a pump and treat system and semi-annual sampling of two monitor wells (MW-7 and MW-14) located downgradient of the system infiltration gallery. The following summarizes data collection and Site activities during 2022: ■ Two VOCs (TCE and cis 1,2-DCE) were detected in groundwater samples collected during the May and November 2022 monitoring events. TCE exceeded its 2L Groundwater Standard of 3.0 pg/L in both MW-7 and MW-14, with the highest concentration in MW-14 at 49 pg/L in November. Overall, TCE concentrations in MW-7 and MW-14 have been decreasing since 2012. Cis-1,2-DCE was below the groundwater standard of 70 pg/L in both wells with concentrations ranging from not detected to 1.1 pg/L. Groundwater flow directions and hydraulic gradients during the 2022 were generally correlative with previous monitoring events conducted at the Site. Field parameter values, including pH, specific conductance, ORP, and temperature are also correlative with past sampling events and are within realistic ranges for the area. The remediation system treated approximately 2,427,100 gallons of groundwater during 2022. It was operational approximately 40% of the time, with the remaining time being shut down on two occasions: late April to early October to repair an underground system line; and the first of www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Page 5 6. DISCUSSIONS AND CONCLUSION November to mid -December to replace the air stripper discharge pump. There were no effluent exceedances during 2022. In accordance with the Non -Discharge Permit (No. W00007798), semi-annual groundwater monitoring will continue in 2023 and influent/effluent samples will be collected from the remediation system on a monthly basis. The next groundwater monitoring event is scheduled for June 2023. www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Page 6 FIGURES www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 E - � �� �aa a -f 'k ff• N d �a 7 { O t` i+ del �1 cea a �►~ - •• ^� it = Sch k Stewart LO � r' 47 " . - i3ar~ J 4' r �,• 4 ■ V µ D •• �� 'd L n } J Y i _ _ �'.: eat• ' - ' i f4f • �'•.. o c ram`= � t ' • - ''� r .�� wig ° CQAST f Mlddl � hl wf rat n �r,•ti- ,. } �•,-7- Heig y laao �� b ■-`�a'' Unccs3n tS" r s �24,000 1 inch = 2,000 feet °o • 3 Feet U 9 L Legend y Figure 1 Property Line Site Location Map Former Ingraham Time Products Facility Toastmaster, Inc. LD ERMNC, Inc. Laurinburg, North Carolina o ERM www.erm.com Source: Copyright:© 2013 National Geographic Society, i-cubed Coordinate System: NAD 1983 StatePlane North Carolina RIPS 3200 Feet II `� I MW-8 I I + -• t I O - I I MW-5.'.i�yi I i II RW-3 I II I I A . d0 I r I I I - ' .. � s• I I I I\ e y I ` - - - - - - - - - - \ I I ---- MW-11 RC-15 Z1T RW-2 — MW-7G(j — \ I MW-13 \ \ MW-1 \\\\ MW-2 RW-1 U\ MW-3 I I MW=6 MW-4J M�W-9 I \- MW_12 p,6 1:2,400 1 Inch = 200 feet 0 200 Feet 5 Legend Figure 2 o Monitor Well Building Parcels Site Map Former Ingraham o Recovery Well Fence Former Wastewater Treatment Facility Time Products Facility ERM NC, Inc. - — — Road Injection Gallery Toastmaster, Inc. ERM www.erm.com Site Treatment Area Laurinburg, North Carolina na u MW-6 MY (99 (99.19) 0 MW-9 (100.43) ! MW-10 (99.00) F E p,6 y t F _ _ N a m m E ti. U 1:2,400 1 inch 200 feet ; 0 200 Feet a� 2 N 0 Monitor Well Former Wastewater Treatment Facility Figure 3 Site Injection Gallery Groundwater Flow Map - May 2022 0 o Treatment Area Former Ingraham N Groundwater Elevation Contour Time Products Facility a —► General Groundwater Flow Direction Toastmaster, Inc. �, ERM NC, Inc. (100.43) - Groundwater Elevation at Well N ERM www.erm.com Based on an arbitrary 100 ft datum NM - Not Monitored Laurinburg, North Carolina Coordinate Svstem: NAD 1983 StatePlane North Carolina RIPS 3200 Feet n n Ll x MW-9 ((98.79) 1:2,400 1 inch t 200 feet 0 200 Feet MW-10 (97.33) 0 L� I I I I I 1 I I I I I I I I I I I I I I I I I I I 000, I — —' C CI 5 j0 Monitor Well Former Wastewater Treatment Facility Figure 4 o site Injection Gallery Groundwater Flow Map - Nov 2022 o Treatment Area Former Ingraham U) N Groundwater Elevation Contour Time Products Facility 0 a —► General Groundwater Flow Direction Toastmaster, Inc. �, ERM NC, Inc. (102.80) - Groundwater Elevation at Well www.erm.com Laurinbur North Carolina N ERM Based on an arbitrary 100 ft datum NM - Not Monitored g Coordinate Svstem: NAD 1983 State Plane North Carolina RIPS 3200 Feet II L1 I I I t I r-w#^•� I I I I II I y K I MW-7 5/10/2022 — — I / \ \ — cis-1,2-DCE --------- 1.1 -, s ( 1 TCE 47 MW-11 MW-14 \ — (105.15(105.43 _ � n , look\ / L \ u MW-14 5/1012022 Y cis-1,2-DCE 1.1 \ - TCE 11 \ MW-3 MW-6 (99.96) (99.19) O 3 MW9 (100.43) J \ �} MW-10 'o (99.00) J Analyte NC 2L Standard Chloroform r' 70 µg/L�': cis-1,2- Dichloroethene (DCE) 70 pg/L �R6 Tetrachloroethene (PCE) 0.7 pg/L X Trichloroethene (TCE) 3 pg/L U e Bold Indicates exceedence of NC 2L Standard NS = Not Sampled 1:2,400 1 inch 200 fe pg/L = micrograms per liter n 0 200 All results shown in pg/L n 0 v Feet ND - Not Detected 0 0 Monitor Well Former Wastewater Treatment Facility Figure 5 Site j?QS Injection Gallery GW Analytical Summary Map - May 2022 Treatment Area Former Ingraham n Time Products Facility D t Toastmaster, Inc. n ERMNc,Inc. D ERM www.erm.COm Laurinburg, North Carolina Coordinate Svstem: NAD 1983 StatePlane North Carolina RIPS 3200 Feet 3 0 w z E 0 0 Z NW A c� 0 XX U z MW-14 11/29/2022 cis-1,2-DCE ND TCE 49 N 1:2,400 1 inch # 200 fe�f h 0 200Feet Jr % 2 CO Site Former Wastewater Treatment Facility 0 Injection Gallery Treatment Area U) U) 0 a 0ERM NC, Inc. U) QERM www.erm.com I L 1 I I 1 I I I I I I I I I I I I I I I I I I — — J ❑r �nrr-r ucaicvcc _ F LU cis-1,2-DCE ND \ / TCE 38 0 �\ \ w \ \ U) \ \ Et \ 2 \ \ v \ \ J \ \ Z \ \ N N MW-3 MW-6 (98.46) Y (98:09) 0 -- / /• m \l d \ y \' z U h Z MW-10 U5 (97.33) z O Analyte NC 2L Standard s U) cis-1,2- Dichloroethene (DCE) 70 pg/L VIA 0 Tetrachloroethene (PCE) 0.7 pg/L w Trichloroethene (TCE) 3 pg/L Bold Indicates exceedence of NC 2L Standard a 0 NS = Not Sampled a pg/L = micrograms per liter ¢w All results shown in pg/L m� ND - Not Detected .Q o E U ry Figure 6 GW Analytical Summary Map - Nov 2021 Former Ingraham Lu Time Products Facility Toastmaster, Inc. z i Laurinburg, North Carolina 0. 22 U)U) 0 0 N �I I M O Ui CO CO W y W moor-:1 R1 1:2,400 1 inch 4 200 feet U)I 0 200 Feet O 0 Monitor Well Former Wastewater Treatment Facility 19 0 Recovery Well �>M Injection Gallery 0 Site Treatment Area U) U) TCE Isoconcentration Contours - May 2022 c� 0 3 ug/L UERM NC, Inc. i , 10 ug/L S, ERM www.erm.com a 0 W c m W � 2 U) \ \ \ v \ O \ \ J � \ Z � � N �\ a II MW76 2 0(NS) Z z Z Cd a z 0 Q vS r. y U) @a c Q c W � m c o n w m c £ U N Figure 7 m TCE Isoconcentration Map — May 2022 Former Ingraham L6 Time Products Facility 0_ Toastmaster, Inc. z U Laurinburg, North Carolina CO II L1 I T Pill 4o II I MW-5 1 I (Ng) i i�' I , 4 I - I I II I =n4= .. I = II I " I 3 � .t y i I �" I • ll i - - - - -- 1 1\ I MW-11 MW-14 (49) — — ^MW-7 O u © — (38), r— _ � 1 V 1 3 � \ > y � MW-3 BMW-6 (NS) b .r ('NS) MW-r9 / (NS) 1�� J MVV�1 U 7 n n n O y 1:2,400 1 inch r 200 feet � dG1 4 i Feet y 0 Monitor Well Former Wastewater Treatment Facility Figure 8 Site Injection Gallery TCE Isoconcentration Map - November 2022 Treatment Area Former Ingraham D TCE Isoconcentration Contours - November 2022 Time Products Facility L ERMNC,Inc. 3 ug/L Toastmaster, Inc. n ERM ` ww.erm.cont 10 ug/L Laurinburg, North Carolina Coordinate Svstem: NAD 1983 StatePlane North Carolina RIPS 3200 Feet TABLES www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 TABLE 1 MONITOR WELL CONSTRUCTION DATA TOASTMASTER, INC. INGRAHAM TIME PRODUCTS FACILITY LAURINBURG, NORTH CAROLINA Well ID TOC Elevation (ft amsl) Well Total Depth (ft bgs) Diameter (in) Screened Interval (ft bgs) MW-3 112.34 22 2 2-22 MW-5 119.78 25 2 15-25 MW-6 112.94 35 2 15-35 MW-7 120.81 40 2 15-40 MW-9 117.15 25 2 7-25 M W-10 110.83 25 4 6-25 M W-11 117.57 25 4 6-25 MW-14 119.03 30 4 6-30 Notes: TOC = top of casing amsl = above mean sea level bgs = below ground surface NA = not available TABLE 2 NATURAL ATTENUATION AND FIELD MEASUREMENT PARAMETERS TOASTMASTER, INC. INGRAHAM TIME PRODUCTS FACILITY LAURINBURG, NORTH CAROLINA Field Parameters (units as shown) Date Sampled Temp (deg C) p H Conductivity (umhos/cm) Turbidity (NTUs) ORP (millivolts) DO (mg/1) Sample ID 5/10/2022 13.73 4.94 124 6.3 331 0.91 MW-7 11 /29/2022 15.84 3.92 60 6.5 407 2.96 5/10/2022 18.35 4.90 52 0.1 375 4.78 MW-14 11 /29/2022 16.70 4.13 114 9.2 376 2.41 General Criteria for Natural Attenuation >20 5 to 9 --- --- < -100* <0.5 Notes: Water chemistry parameters were taken in the field after each well bore volume Data in this table represent the observed parameter values at completion of well development/ purge. Bold data indicate positive conditions for natural attenuation processes ORP = Oxidation Reduction Potential DO = Dissolved Oxygen * Indicates likely reductive pathway TABLE 3 GROUNDWATER ELEVATIONS SUMMARY TOASTMASTER, INC. LAURINBURG, NORTH CAROLINA PAGE 1 OF 2 Well No. Top of Casing Elevation (feet)' 112.34 Well No. Top of Casing Elevation (feet)* 119.78 Well No. Top of Casing Elevation (feet)' 112.94 Well No. Top of Casing Elevation (feet)' 120.81 MW-3 Dates: MW-5 Dates: MW-6 Dates: MW-7 Dates: Water Depth (Ft. BTOC) Water Elevation (Ft.) Water Depth (Ft. BTOC) Water Elevation (Ft.) Water Depth (Ft. BTOC) Water Elevation (Ft.) Water Depth (Ft. BTOC) Water Elevation (Ft.) 11/17/2006 11.33 101.01 11/17/2006 8.21 111.57 11/17/2006 13.15 99.79 5/3/2007 10.16 102.18 5/3/2007 8.72 111.06 5/3/2007 11.57 101.37 5/14/2008 10.65 101.69 5/14/2008 8.21 111.57 5/14/2008 11.93 101.01 11/13/2008 11.45 100.89 11/13/2008 9.50 110.28 11/13/2008 12.76 100.18 5/12/2009 10.80 101.54 5/12/2009 7.82 111.96 5/12/2009 12.14 100.80 -- 11/19/2009 12.66 99.68 11/19/2009 9.82 109.96 11/19/2009 13.93 99.01 -- 5/12/2010 12.40 99.94 5/12/2010 11.38 108.40 5/12/2010 13.71 99.23 -- 11/10/2010 12.79 99.55 11/10/2010 11.30 108.48 11/10/2010 14.15 98.79 - 5/4/2011 12.23 100.11 5/4/2011 9.94 109.84 5/4/2011 13.63 99.31 -- 11 /22/2011 14.82 97.52 11 /22/2011 11.43 108.35 11 /22/2011 14.23 98.71 - 5/15/2012 12.71 99.63 5/15/2012 10.00 109.78 5/15/2012 14.34 98.60 - 11/19/2012 13.90 98.44 11/19/2012 12.42 107.36 11/19/2012 15.21 97.73 - 5/22/2013 9.42 102.92 5/22/2013 6.29 113.49 5/22/2013 11.03 101.91 - 11/13/2013 13.82 98.52 11/13/2013 12.94 106.84 11/13/2013 15.19 97.75 - 5/13/2014 11.21 101.13 5/13/2014 8.81 110.97 5/13/2014 12.35 100.59 5/13/2014 13.02 107.79 11/19/2014 14.44 97.90 11/19/2014 14.92 104.86 11/19/2014 15.01 97.93 1 11/19/2014 18.07 102.74 5/28/2015 12.69 99.65 5/28/2015 10.62 109.16 5/28/2015 13.98 98.96 5/28/2015 14.80 106.01 11 /5/2015 12.37 99.97 11 /5/2015 6.32 113.46 11 /5/2015 14.19 98.75 11 /5/2015 12.98 107.83 5/12/2016 12.00 100.34 5/12/2016 9.88 109.90 5/12/2016 13.19 99.75 5/12/2016 14.53 106.28 11 /4/2016 10.53 101.81 11 /4/2016 8.48 111.30 11 /4/2016 11.64 101.30 11 /4/2016 12.30 108.51 7/18/2017 13.18 99.16 7/18/2017 10.57 109.21 7/18/2017 14.54 98.40 7/18/2017 14.75 106.06 5/31 /2018 10.38 101.96 5/31 /2018 6.86 112.92 5/31 /2018 11.74 101.20 5/31 /2018 10.95 109.86 11 /6/2018 10.23 102.11 11 /6/2018 7.31 112.47 11 /6/2018 11.46 101.48 11 /6/2018 11.26 109.55 5/6/2019 10.06 102.28 5/6/2019 7.28 112.50 5/6/2019 11.27 101.67 5/6/2019 10.57 110.24 11 /7/2019 14.55 97.79 11 /6/2018 14.56 105.22 11 /7/2019 15.91 97.03 11 /7/2019 17.58 103.23 5/12/2020 13.10 99.24 5/12/2020 9.05 110.73 5/12/2020 14.80 98.14 5/12/2020 14.10 106.71 11/18/2020 11.30 101.04 11/18/2020 7.44 112.34 11/18/2020 13.05 99.89 11/18/2020 12.30 108.51 5/20/2021 13.80 98.54 5/20/2021 11.35 108.43 5/20/2021 15.70 97.24 5/20/2021 15.30 105.51 11/15/2021 16.91 95.43 11/15/2021 15.52 104.26 11/15/2021 18.80 94.14 11/15/2021 19.05 101.76 5/10/2022 12.38 99.96 5/10/2022 9.97 109.81 5/10/2022 13.75 99.19 5/10/2022 14.80 106.01 11 /29/2022 13.88 98.46 11 /29/2022 13.06 106.72 111/29/20221 14.85 98.09 11 /29/2022 16.90 103.91 Ft BTOC = Feet below top of casing " Top of Casing measured to an arbitrary datum of 100.00 feet. TABLE 3 GROUNDWATER ELEVATIONS SUMMARY TOASTMASTER, INC. LAURINBURG, NORTH CAROLINA PAGE 2OF2 Well No. Top of Casing Elevation (feet)` 117.15 Well No. Top of Casing Elevation (feet)• 110.83 Well No. Top of Casing Elevation (feet)* 117.57 Well No. Top of Casing Elevation (feet)` 119.03 MW-9 Dates: MW-10 Dates: MWA 1 Dates: MW-14 Dates: Water Depth (Ft. BTOC) Water Elevation (Ft.) Water Depth (Ft. BTOC) Water Elevation (Ft.) Water Depth (Ft. BTOC) Water Elevation (Ft.) Water Depth (Ft. BTOC Water Elevation (Ft.) 11/17/2006 15.23 101.92 11/17/2006 11.34 99.49 11/17/2006 9.87 107.70 11/17/2006 12.18 106.85 5/3/2007 10.64 106.51 5/3/2007 8.31 102.52 5/3/2007 10.64 106.93 5/3/2007 10.92 108.11 5/14/2008 14.66 102.49 5/14/2008 8.56 102.27 5/14/2008 9.95 107.62 5/14/2008 10.97 108.06 11/13/2008 15.26 103.77 11/13/2008 9.86 100.97 11/13/2008 11.60 105.97 11/13/2008 12.22 106.81 5/12/2009 14.73 102.42 5/12/2009 8.75 102.08 5/12/2009 9.56 108.01 5/12/2009 12.05 106.98 11/19/2009 16.90 100.25 11/19/2009 12.42 98.41 11/19/2009 12.94 104.63 11/19/2009 14.93 104.10 5/12/2010 16.06 101.09 5/12/2010 10.97 99.86 5/12/2010 12.95 104.62 5/12/2010 13.68 105.35 11/10/2010 16.60 100.55 11/10/2010 12.02 98.81 11/10/2010 13.06 104.51 11/10/2010 14.08 104.95 5/4/2011 16.19 100.96 5/4/2011 10.90 99.93 5/4/2011 12.24 105.33 5/4/2011 13.13 105.90 11 /22/2011 16.40 100.75 11 /22/2011 11.91 98.92 11 /22/2011 13.04 104.53 11 /22/2011 14.04 104.99 5/15/2012 16.08 101.07 5/15/2012 11.35 99.48 5/15/2012 12.10 105.47 5/15/2012 13.45 105.58 11/19/2012 17.60 99.55 11/19/2012 13.08 97.75 11/19/2012 14.58 102.99 11/19/2012 15.73 103.30 5/22/2013 13.67 103.48 5/22/2013 7.44 103.39 5/22/2013 7.52 110.05 5/22/2013 9.2 109.83 11/13/2013 17.63 99.52 1/13/2013 12.92 97.91 11/13/2013 14.32 103.25 11/13/2013 15.43 103.60 5/13/2014 14.99 102.16 5/13/2014 9.40 101.43 5/13/2014 11.12 106.45 5/13/2014 11.72 107.31 11/19/2014 18.59 98.56 11/19/2014 13.86 96.97 11/19/2014 15.37 102.20 11/19/2014 16.75 102.28 5/28/2015 16.29 100.86 5/28/2015 11.28 99.55 5/28/2015 12.80 104.77 5/28/2015 13.57 105.46 11 /5/2015 16.02 101.13 11 /5/2015 12.06 98.77 11 /5/2015 9.31 108.26 11 /5/2015 13.33 105.70 5/12/2016 16.10 101.05 5/12/2016 10.73 100.10 5/12/2016 12.07 105.50 5/12/2016 13.42 105.61 11 /4/2016 14.65 102.50 11 /4/2016 8.58 102.25 11 /4/2016 10.38 107.19 11 /4/2016 10.92 108.11 7/18/2017 17.22 99.93 7/18/2017 12.49 98.34 7/18/2017 12.39 105.18 7/18/2017 14.14 104.89 5/31 /2018 14.39 102.76 5/31 /2018 8.52 102.31 5/31 /2018 8.59 108.98 5/31 /2018 10.18 108.85 11 /6/2018 14.10 103.05 11 /6/2018 8.05 102.78 11 /6/2018 9.02 108.55 11 /6/2018 10.19 108.84 5/6/2019 13.91 103.24 5/6/2019 7.57 103.26 5/6/2019 7.81 109.76 5/6/2019 9.76 109.27 11 /7/2019 18.92 98.23 11 /7/2019 14.03 96.80 11 /7/2019 14.95 102.62 11 /7/2019 16.61 102.42 5/12/2020 15.90 101.25 5/12/2020 10.60 100.23 5/12/2020 11.55 106.02 5/12/2020 12.20 106.83 11/18/2020 14.90 102.25 11/18/2020 9.50 101.33 11/18/2020 9.83 107.74 11/18/2020 10.22 108.81 5/20/2021 16.43 100.72 5/20/2021 11.28 99.55 5/20/2021 12.95 104.62 5/20/2021 13.10 105.93 11/15/2021 20.08 97.07 11/15/2021 15.41 95.42 11/15/2021 16.69 100.88 11/15/2021 18.03 101.00 5/10/2022 16.72 100.43 5/10/2022 11.83 99.00 5/10/2022 12.42 105.15 5/10/2022 13.60 105.43 11/29/2022 18.36 98.79 11/29/2022 13.50 97.33 11/29/2022 14.05 103.52 11/29/2022 16.23 102.80 Ft BTOC = Feet below top of casing Top of Casing measured to an arbitrary datum of 100.00 feet. TABLE 4 GROUNDWATER ANALYTICAL SUMMARY - 2022 VOLATILE ORGANIC COMPOUNDS TOASTMASTER, INC. LAURINBURG, NORTH CAROLINA SAMPLE LOCATION SAMPLE DATE DETECTED VOCs (lag/L) cis-1,2-DCE TCE NC 2L Groundwater Standards 70 3 M W-7 5/10/2022 1.1 47 1 /29/2022 <5.0 38 MW-14 5/10/2022 1.1 11 11 /29/2022 <5.0 49 TCE = trichloroethene, PCE = tetrachloroethene DCE = dichloroethene, VOC = volatile organic compound, ND = Not Detected (below quantitation limits), pg/I = micrograms per liter, MW = monitor well, NC 2L GW STD = North Carolina groundwater standard TABLE 5 HISTORICAL GROUNDWATER ANALYTICAL SUMMARY VOLATILE ORGANIC COMPOUNDS TOASTMASTER, INC. LAURINBURG, NORTH CAROLINA Page 1 of 2 SAMPLE LOCATION SAMPLE DATE DETECTED VOLATILE ORGANIC COMPOUNDS BY EPA METHOD 8260 (pg/1) PCE TCE 1,1-DCE cis-1,2-DCE Chloroform NC 2L Groundwater Standards 0.7 3 350 70 70 5/13/2014 ND 100 ND 1.4 ND 11/19/2014 13 130 ND 13 ND 5/28/2015 ND 160 ND 1.5 ND 11/5/2015 ND 180 ND 1.8 ND 5/12/2016 3.6 120 ND 1.8 ND 11/4/2016 4.5 110 ND 1.9 ND 7/18/2017 0.54 54 ND 1.2 ND 5/31/2018 ND 110 ND 1.4 ND MW-7 11/6/2018 11 110 ND 1.8 ND 5/6/2019 79 90 ND 8.5 ND 11/7/2019 4.5 45 ND 1.4 ND 5/12/2020 ND 87 ND 1.1 ND 11/18/2020 ND 100 ND 1.6 ND 5/20/2021 3.2 44 ND 1.2 ND 11/15/2021 4.9 31 ND 0.68 ND 5/10/2022 ND 47 ND 1.1 ND 11/29/2022 ND 38 ND ND ND Notes: PCE = tetrachloroethene, TCE = trichloroethene, DCE = dichloroethene, VOC = volatile organic compound, DCP = Dichloropropane, ND = Not Detected (below quantitation limits), ug/I = micrograms per liter, MW = monitor well, NC GW STD = North Carolina ground water standard, NA = not available, "/' - sample/duplicate TABLE 5 HISTORICAL GROUNDWATER ANALYTICAL SUMMARY VOLATILE ORGANIC COMPOUNDS TOASTMASTER, INC. LAURINBURG, NORTH CAROLINA Page 2 of 2 SAMPLE LOCATION SAMPLE DATE DETECTED VOLATILE ORGANIC COMPOUNDS BY EPA METHOD 8260 (pg/1) PCE TCE 1,1-DCE cis-1,2-DCE Chloroform NC 2L Groundwater Standards 0.7 3 350 70 70 2/25/2005 ND 3.9 ND ND ND 5/18/2005 ND 4.7 ND ND ND 11/9/2005 ND 19.5 ND 4.28 ND 5/25/2006 ND ND ND ND ND 11/17/2006 ND 76.2 ND ND ND 5/3/2007 ND 6.7 ND ND ND 11/30/2007 ND 17 ND ND ND 5/14/2008 ND 16 ND 1.6 ND 11/13/2008 ND 39 0.55 3.0 ND 5/12/2009 ND 23 ND 4.6 ND 11/19/2009 ND 130 ND 25 ND 5/12/2010 ND 150 0.67 8.7 ND 11/10/2010 ND 220/230 1.5/1.7 14/15 ND 5/4/2011 ND 280 1.1 13 ND 11/22/2011 ND 240 1.4 17 ND 5/15/2012 ND 170 0.61 31 ND 11/19/2012 ND 140 ND 19 ND MW-14 5/22/2013 ND 190 ND 13 ND 11/13/2013 ND 100 ND 6.6 ND 5/13/2014 ND 87 ND 11 0.54 11/19/2014 ND 110 ND 7.9 ND 5/28/2015 ND 130 ND 16 ND 11/5/2015 ND 110 ND 13 ND 5/12/2016 ND 98 ND 9.4 ND 11/4/2016 ND 72 0.77 8.3 ND 7/18/2017 ND 110 0.71 11 ND 5/31/2018 ND 29 ND 2.3 ND 11/6/2018 ND 35 ND 5.2 ND 5/6/2019 ND 25 ND 2.5 ND 11/7/2019 ND 6.7 ND 0.52 ND 5/12/2020 ND 16 ND 0.93 ND 11/18/2020 ND 4.4 ND ND ND 5/20/2021 ND 4.3 ND ND ND 11/15/2021 ND 1.5 ND 0.68 ND 5/10/2022 ND 11 ND 1.1 ND 11/29/2022 ND 49 ND ND ND Notes: PCE = tetrachloroethene, TCE = trichloroethene, DCE = dichloroethene, VOC = volatile organic compound, DCP = Dichloropropane, ND = Not Detected (below quantitation limits), ug/I = micrograms per liter, MW = monitor well, NC GW STD = North Carolina ground water standard, NA = not available, "/' - sample/duplicate TABLE 6 GRAPHS OF TCE AND cis-1,2-DCE CONCENTRATIONS VS. TIME TOASTMASTER, INC. LAURINBURG, NORTH CAROLINA Well MW 7 - TCE 300 250 J 1 200 W U ~ 150 0 C O �@ 100 L N t 50 O U 0 Well MW 14 - TCE 300 250 J rn w 200 U H 0 150 0 100 c m u 0 50 U 0 O O O O O O M r O N N N N @ @ t0 t0 @ @ t0 t0 t0 @ @ t0 t0 @ @ @ t0 t0 @ 20.0 J OI S v 15.0 G N W g 10.0 0 C O 5.0 C u C O U 0.0 V 35 J s 30 w U O 25 N w 20 .v C 15 0 10 c d 0 5 U 0 Well MW 7 - cis 1,2-DCE Well MW 14 - cis 1,2-13CE TABLE 7 MONTHLY INFLUENT AND EFFLUENT SAMPLE RESULTS FOR 2022 TOASTMASTER, INC. INGRAHAM TIME PRODUCTS FACILITY LAURINBURG, NORTH CAROLINA Influent Concentration (Ng/L) Effluent Concentration (Ng/L) Sample Month PCE TCE cis-1,2-DCE PH o PCE (/o Removal) o TCE (/o Removal) o 1,1-DCE (/o Removal) cis-1,2-DCE (/o Removal) pH 2L GW Standard 0.7 3 70 6.5-8.5 0.7 3 150 70 6.5-8.5 January 0.65 160 6.8 5.1 ND (100%) ND (100%) ND (100%) ND (100%) 6.0 February 0.82 200 7.7 5.3 ND (100%) ND (100%) ND (100%) 0.8 (89.6%) 6.1 March 0.66 170 6.8 5.7 ND (100%) ND (100%) ND (100%) 1.7 (75%) 6.4 April 0.73 120 7.0 5.4 ND (100%) ND (100%) ND (100%) 1.1 (84%) 5.7 May --- --- --- --- --- NA --- NA --- NA --- NA --- June --- --- --- --- --- NA --- NA --- NA --- NA --- July --- --- --- --- --- NA --- NA --- NA --- NA --- August --- --- --- --- --- NA --- NA --- NA --- NA --- September --- --- --- --- --- NA --- NA --- NA --- NA --- October ND 140 8.1 6.2 ND (100%) ND (100%) ND (100%) 1.1 (86%) 6.3 November --- --- --- --- --- NA --- NA --- NA --- NA --- December 0.95 170 8.1 5.8 ND (100%) 0.71 (99.6%) ND (100%) 2.7 (67%) 6.4 Notes: -- System was not operational Bold data exceed 21-Standard or outside of range for pH. ND- Not Detected above practical quantitation limits NS - Not Sampled DCE - Dichloroethene PCE- Tetrachloroethene TCE- Trichloroethene pg/I - micrograms per liter APPENDIX Al GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORMS - MAY 2022 www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 GW-59A COMPLIANCE REPORT FORM Permit # WQ000779 (Submit one each monitoring period with GW-59 forms.) I Enter date monitoring results were due. ( 2-30-23 ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is 'YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, YES INO missing identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Office for uidance. 4 Aug any monitored constituents equal to or above the established standards? ES O If the answer to question 4 is "NO'; skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: MW-7 TCE — 47 ug/L, MW-14 TCE — 49 ug/L. 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is 'NO'; skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). See Table 5 of the report. 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YE NO groundwater quality problem? If the answer to question 7 is A 'YES'; describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. The site's remedial approach for the existing plume of VOC affected groundwater consists of a series of recovery wells through which VOC-impacted groundwater is extracted and transferred to an above -ground treatment system. The treated groundwater is then re -introduced to the surficial aquifer via an infiltration gallery 8 The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. �a4, 3-13-2023 Signature of Permittee or Authorized Agent)Date GW-59A 12/8/2003 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER QUALITY -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, INC 27699-1617 Phone: (919) 733-3221 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Toastmaster, Inc. Non -Discharge WQ0007798 UIC Permit Name (if different): NPDES Other Facility Address: 17260 Plant Road TYPE OF PERMITTED OPERATION BEING MONITORED Laurinbur (street) NC 28352 County Scotland ❑ Lagoon ❑x Remediation: Infiltration Gallery (City) (Stet.) ❑ Spray Field El Remediation: Contact Person: Jim Skaggs Telephone#: 903-357-3242 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Lat 34048'5.92" Long 79o27'47.18" No. of wells to be sampled: 2 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-7 Date sample collected: 5/20/2022 FIELD ANALYSES: WAS Well Depth: 40 ft. Well Diameter: 2 in. pH 4.94 units Temp. 13.73 °C DRY at Depth to Water Level: 14.80 ft. below measuring point Screened Interval: 15 ft. to 40 ft. Spec. Cond. 124 µ Mhos time of sampling, Measuring Point is NM ft. above land surface Relative M.P. Elevation: 120.81 ft. Odor NM check Volume of water pumped/bailed before sampling: 4•0 gallons Appearance NM here: ❑ Samples for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 5/21/2022 Laboratory Name: Shealy Environmental (Pace Analytical) Certification No. 329 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD NA mg/I Nitrite (NO2) as N NA mg/I Pb - Lead NA mg/I Coliform: MF Fecal NA /100ml Nitrate (NO3) as N NA mg/I Zn - Zinc NA mg/I Coliform: MF Total NA /100mi Phosphorus: Total as P NA mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate NA mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total NA mg/I Al - Aluminum NA mg/I cis-1,2-DCE: 1.1 ug/L pH (when analyzed) NA units Ba - Barium NA mg/I TICE: 47 ug/L TOC NA mg/I Ca - Calcium NA mg/I Chloride NA mg/I Cd - Cadmium NA mg/I Arsenic NA mg/I Chromium: Total NA mg/I Grease and Oils NA mg/I Cu - Copper NA mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol NA mg/I Fe - Iron NA mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate NA mg/I Hg - Mercury NA mg/I Report Attached? ® Yes (1) ❑ No (0) Specific Conductance NA µMhos K - Potassium NA mg/I VOC method # 8260B Total Ammonia NA mg/I Mg - Magnesium NA mg/I method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese NA mg/I , method # TKN as N NA mg/I Ni - Nickel NA mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Michael Pressley Permittee (or Authorized Agent) Name and Title - Please print or type NA mg/L Effluent Total VOCs: Signature of Permittee (or Authorized Agent) NA mg/L VOC Removal% NA approved methods 3-13-2023 (Date) GW-59 Rev.1/2007 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER QUALITY -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, INC 27699-1617 Phone: (919) 733-3221 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Toastmaster, Inc. Non -Discharge WQ0007798 UIC Permit Name (if different): NPDES Other Facility Address: 17260 Plant Road TYPE OF PERMITTED OPERATION BEING MONITORED Laurinburq NC County Scotland ❑ Lagoon 0 Remediation: Infiltration Gallery (City) (Stet.) (Zip) ❑ Spray Field El Remediation: Contact Person: Jim Skaggs Telephone#: 903-357-3242 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Lat 34o47'56.6" Long 79o27'47.3" No. of wells to be sampled: 2 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-14 Date sample collected: 5/10/2022 FIELD ANALYSES: WAS Well Depth: 31.72 ft. Well Diameter: 4 in. pH 4.90 units Temp. 18.35 °C DRY at Depth to Water Level: 13.60 ft. below measuring point Screened Interval: 6 ft. to 25 ft. Spec. Cond. 375 µ Mhos time of sampling, Measuring Point is NM ft. above land surface Relative M.P. Elevation: 119.03 ft. Odor NM check Volume of water pumped/bailed before sampling: 2 gallons Appearance NM here: ❑ Samples for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 5/21/2022 Laboratory Name: Shealy Environmental (Pace Analytical) Certification No. 329 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD NA mg/I Nitrite (NO2) as N NA mg/I Pb - Lead NA mg/I Coliform: MF Fecal NA /100ml Nitrate (NO3) as N NA mg/I Zn - Zinc NA mg/I Coliform: MF Total NA /100mi Phosphorus: Total as P NA mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate NA mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total NA mg/I Al - Aluminum NA mg/I cis-1,2-DCE 1.1 ug/L pH (when analyzed) NA units Ba - Barium NA mg/I TICE 11 ug/L TOC NA mg/I Ca - Calcium NA mg/I Chloride NA mg/I Cd - Cadmium NA mg/I Arsenic NA mg/I Chromium: Total NA mg/I Grease and Oils NA mg/I Cu - Copper NA mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol NA mg/I Fe - Iron NA mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate NA mg/I Hg - Mercury NA mg/I Report Attached? ® Yes (1) ❑ No (0) Specific Conductance NA µMhos K - Potassium NA mg/I VOC method # 8260B Total Ammonia NA mg/I Mg - Magnesium NA mg/I method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese NA mg/I , method # TKN as N NA mg/I Ni - Nickel NA mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: NA mg/L Effluent Total VOCs: NA mg/L VOC Removal% NA Michael Pressley Permittee (or Authorized Agent) Name and Title - Please print or type J� 3-13-2023 Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.1/2007 APPENDIX A2 GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORMS - NOVEMBER 2022 www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER QUALITY -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, INC 27699-1617 Phone: (919) 733-3221 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Toastmaster, Inc. Non -Discharge WQ0007798 UIC Permit Name (if different): NPDES Other Facility Address: 17260 Plant Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon 0 Remediation: Infiltration Gallery Laurinbur (street) NC 28352 County Scotland (City) (Stet.) ❑ Spray Field El Remediation: Contact Person: Jim Skaggs Telephone#: 903-357-3242 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Lat 34048'5.92" Long 79o27'47.18" No. of wells to be sampled: 2 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-7 Date sample collected: 11/29/2022 FIELD ANALYSES: WAS Well Depth: 40 ft. Well Diameter: 2 in. pH 3.92 units Temp. 15.84 °C DRY at Depth to Water Level: 16.90 ft. below measuring point Screened Interval: 15 ft. to 40 ft. Spec. Cond. 60 µ Mhos time of sampling, Measuring Point is NM ft. above land surface Relative M.P. Elevation: 120.81 ft. Odor NM check Volume of water pumped/bailed before sampling: 1.0 gallons Appearance NM here: ❑ Samples for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 12/02/2022 Laboratory Name: Pace Analytical, LLC Certification No. 329 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD NA mg/I Nitrite (NO2) as N NA mg/I Pb - Lead NA mg/I Coliform: MF Fecal NA /100ml Nitrate (NO3) as N NA mg/I Zn - Zinc NA mg/I Coliform: MF Total NA /100mi Phosphorus: Total as P NA mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate NA mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total NA mg/I Al - Aluminum NA mg/I cis-1,2-DCE: <5.0 ug/L pH (when analyzed) NA units Ba - Barium NA mg/I TICE: 38 ug/L TOC NA mg/I Ca - Calcium NA mg/I Chloride NA mg/I Cd - Cadmium NA mg/I Arsenic NA mg/I Chromium: Total NA mg/I Grease and Oils NA mg/I Cu - Copper NA mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol NA mg/I Fe - Iron NA mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate NA mg/I Hg - Mercury NA mg/I Report Attached? ® Yes (1) ❑ No (0) Specific Conductance NA µMhos K - Potassium NA mg/I VOC method # 8260B Total Ammonia NA mg/I Mg - Magnesium NA mg/I method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese NA mg/I , method # TKN as N NA mg/I Ni - Nickel NA mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Michael Pressley Permittee (or Authorized Aqent) Name and Title - Please print or type NA mg/L Effluent Total VOCs: Signature of Permittee (or Authorized Agent) NA mg/L VOC Removal% NA approved.. 3-13-2023 (Date) GW-59 Rev.1/2007 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER QUALITY -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, INC 27699-1617 Phone: (919) 733-3221 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Toastmaster, Inc. Non -Discharge WQ0007798 UIC Permit Name (if different): NPDES Other Facility Address: 17260 Plant Road TYPE OF PERMITTED OPERATION BEING MONITORED Laurinburq NC County Scotland ❑ Lagoon 0 Remediation: Infiltration Gallery (City) (Stet.) (Zip) ❑ Spray Field El Remediation: Contact Person: Jim Skaggs Telephone#: 903-357-3242 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Lat 34o47'56.6" Long 79o27'47.3" No. of wells to be sampled: 2 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-14 Date sample collected: 11/29/2022 FIELD ANALYSES: WAS Well Depth: 31.72 ft. Well Diameter: 4 in. pH 4.13 units Temp. 16.70 °C DRY at Depth to Water Level: 16.23 ft. below measuring point Screened Interval: 6 ft. to 25 ft. Spec. Cond. 376 µ Mhos time of sampling, Measuring Point is NM ft. above land surface Relative M.P. Elevation: 119.03 ft. Odor NM check Volume of water pumped/bailed before sampling: 1.0 gallons Appearance NM here: ❑ Samples for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 12/02/2022 Laboratory Name: Pace Analytical LLC Certification No. 329 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD NA mg/I Nitrite (NO2) as N NA mg/I Pb - Lead NA mg/I Coliform: MF Fecal NA /100ml Nitrate (NO3) as N NA mg/I Zn - Zinc NA mg/I Coliform: MF Total NA /100mi Phosphorus: Total as P NA mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate NA mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total NA mg/I Al - Aluminum NA mg/I cis-1,2-DCE <5.0 ug/L pH (when analyzed) NA units Ba - Barium NA mg/I TICE 49 ug/L TOC NA mg/I Ca - Calcium NA mg/I Chloride NA mg/I Cd - Cadmium NA mg/I Arsenic NA mg/I Chromium: Total NA mg/I Grease and Oils NA mg/I Cu - Copper NA mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol NA mg/I Fe - Iron NA mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate NA mg/I Hg - Mercury NA mg/I Report Attached? ® Yes (1) ❑ No (0) Specific Conductance NA µMhos K - Potassium NA mg/I VOC method # 8260B Total Ammonia NA mg/I Mg - Magnesium NA mg/I method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese NA mg/I , method # TKN as N NA mg/I Ni - Nickel NA mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Michael Pressley Permittee (or Authorized Agent) Name and Title - Please print or type NA mg/L Effluent Total VOCs: �a 6T Signature of Permittee (or Authorized Agent) NA mg/L VOC Removal% NA approved methods 3-13-2023 (Date) GW-59 Rev.1/2007 APPENDIX 131 LABORATORY ANALYTICAL REPORT - MAY 2022 www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Report of Analysis ERM NC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Michael Pressley Project Name: Toastmaster Lot Number:XE11017 Date Completed:05/26/2022 /� doa',' 06/01/2022 12:47 PM Approved and released by: Project Manager I: Hannah K. Lucas �q RCCAA16 2W _ AM fiafkeWAcsredi}angr &WO A C C A E O[ Y E d iESTIHG LABOft4TOPY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 13 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM NC, Inc. Lot Number: XE11017 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 13 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM NC, Inc. Lot Number: XE11017 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-7-WG-20220510 Aqueous 05/10/20221045 05/11/2022 002 MW-14-WG-20220510 Aqueous 05/10/20221000 05/11/2022 003 Trip Blank Aqueous 05/10/2022 05/11/2022 (3 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 13 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM NC, Inc. Lot Number: XE11017 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-7-WG-20220510 Aqueous cis- 1,2-Dichloroethene 8260D 1.1 ug/L 7 001 MW-7-WG-20220510 Aqueous Trichloroethene 8260D 47 ug/L 7 002 MW-14-WG-20220510 Aqueous cis- 1,2-Dichloroethene 8260D 1.1 ug/L 8 002 MW-14-WG-20220510 Aqueous Trichloroethene 8260D 11 ug/L 8 (4 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 13 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XE11017-001 Description: MW-7-WG-20220510 Matrix: Aqueous Date Sampled:05/10/2022 1045 Date Received:05/11/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/21/2022 0128 SDC 42525 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1, 1 -Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.1 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 47 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 13 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XE11017-002 Description: MW-14-WG-20220510 Matrix: Aqueous Date Sampled:05/10/2022 1000 Date Received:05/11/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/21/2022 0151 SDC 42525 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1, 1 -Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.1 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 11 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 13 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XE11017-003 Description: Trip Blank Matrix: Aqueous Date Sampled:05/10/2022 Date Received:05/11/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/21/2022 0042 SDC 42525 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 13 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 13 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ42525-001 Matrix: Aqueous Batch:42525 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ Units Analysis Date Bromodichloromethane ND 1 0.50 ug/L 05/20/2022 2347 Bromoform ND 1 0.50 ug/L 05/20/2022 2347 Bromomethane (Methyl bromide) ND 1 0.50 ug/L 05/20/2022 2347 Carbon tetrachloride ND 1 0.50 ug/L 05/20/2022 2347 Chlorobenzene ND 1 0.50 ug/L 05/20/2022 2347 Chloroethane ND 1 0.50 ug/L 05/20/2022 2347 Chloroform ND 1 0.50 ug/L 05/20/2022 2347 Chloromethane (Methyl chloride) ND 1 0.50 ug/L 05/20/2022 2347 Dibromochloromethane ND 1 0.50 ug/L 05/20/2022 2347 1,2-Dibromoethane (EDB) ND 1 0.50 ug/L 05/20/2022 2347 1,2-Dichlorobenzene ND 1 0.50 ug/L 05/20/2022 2347 1,3-Dichlorobenzene ND 1 0.50 ug/L 05/20/2022 2347 1,4-Dichlorobenzene ND 1 0.50 ug/L 05/20/2022 2347 1,1-Dichloroethane ND 1 0.50 ug/L 05/20/2022 2347 1,2-Dichloroethane ND 1 0.50 ug/L 05/20/2022 2347 1,1-Dichloroethene ND 1 0.50 ug/L 05/20/2022 2347 cis- 1,2-Dichloroethene ND 1 0.50 ug/L 05/20/2022 2347 trans- 1,2-Dichloroethene ND 1 0.50 ug/L 05/20/2022 2347 1,2-Dichloropropane ND 1 0.50 ug/L 05/20/2022 2347 cis- 1,3-Dichloropropene ND 1 0.50 ug/L 05/20/2022 2347 trans- 1,3-Dichloropropene ND 1 0.50 ug/L 05/20/2022 2347 Methylene chloride ND 1 0.50 ug/L 05/20/2022 2347 1,1,2,2-Tetrachloroethane ND 1 0.50 ug/L 05/20/2022 2347 Tetrachloroethene ND 1 0.50 ug/L 05/20/2022 2347 1,1,1-Trichloroethane ND 1 0.50 ug/L 05/20/2022 2347 1,1,2-Trichloroethane ND 1 0.50 ug/L 05/20/2022 2347 Trichloroethene ND 1 0.50 ug/L 05/20/2022 2347 Trichlorofluoromethane ND 1 0.50 ug/L 05/20/2022 2347 Vinyl chloride ND 1 0.50 ug/L 05/20/2022 2347 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 102 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 13 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ42525-002 Matrix: Aqueous Batch:42525 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Bromodichloromethane 50 44 1 87 70-130 05/20/2022 2121 Bromoform 50 41 1 82 70-130 05/20/2022 2121 Bromomethane (Methyl bromide) 50 39 1 78 70-130 05/20/2022 2121 Carbon tetrachloride 50 44 1 87 70-130 05/20/2022 2121 Chlorobenzene 50 47 1 95 70-130 05/20/2022 2121 Chloroethane 50 41 1 82 70-130 05/20/2022 2121 Chloroform 50 45 1 89 70-130 05/20/2022 2121 Chloromethane (Methyl chloride) 50 39 1 78 60-140 05/20/2022 2121 Dibromochloromethane 50 43 1 86 70-130 05/20/2022 2121 1,2-Dibromoethane (EDB) 50 49 1 98 70-130 05/20/2022 2121 1,2-Dichlorobenzene 50 48 1 96 70-130 05/20/2022 2121 1,3-Dichlorobenzene 50 47 1 95 70-130 05/20/2022 2121 1,4-Dichlorobenzene 50 46 1 92 70-130 05/20/2022 2121 1,1-Dichloroethane 50 47 1 93 70-130 05/20/2022 2121 1,2-Dichloroethane 50 45 1 89 70-130 05/20/2022 2121 1,1-Dichloroethene 50 46 1 92 70-130 05/20/2022 2121 cis- 1,2-Dichloroethene 50 47 1 94 70-130 05/20/2022 2121 trans- 1,2-Dichloroethene 50 46 1 93 70-130 05/20/2022 2121 1,2-Dichloropropane 50 48 1 96 70-130 05/20/2022 2121 cis- 1,3-Dichloropropene 50 51 1 102 70-130 05/20/2022 2121 trans- 1,3-Dichloropropene 50 51 1 102 70-130 05/20/2022 2121 Methylene chloride 50 44 1 89 70-130 05/20/2022 2121 1,1,2,2-Tetrachloroethane 50 47 1 95 70-130 05/20/2022 2121 Tetrachloroethene 50 49 1 98 70-130 05/20/2022 2121 1,1,1-Trichloroethane 50 45 1 90 70-130 05/20/2022 2121 1,1,2-Trichloroethane 50 47 1 94 70-130 05/20/2022 2121 Trichloroethene 50 48 1 96 70-130 05/20/2022 2121 Trichlorofluoromethane 50 40 1 80 70-130 05/20/2022 2121 Vinyl chloride 50 38 1 75 70-130 05/20/2022 2121 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 82 70-130 Toluene-d8 92 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 13 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 13 PACE ANALYTICAL SERVICES, LLC CO C%J cy) d M z J {Ij [fl y t3 o Z LU 11 a d, � /LU i V i L^ !` p 2 gg � ars�ss e9 -0iG.R',f lusxr� i x I i s 4 � F7 I + I .J L irl _RI i ,¢ems 5 � 3 Q I t-- R x7 cl� -4 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 13 PACE ANALYTICAL SERVICES, LLC SampldsFleQeiptCherklist wnoisc-1:5 i � } Re'11sed=5{z912t}�c Anmj+t,�af kssuing I utharfty: Pare E' 1V - WCO' Page 1 of 1 alr> ple Receipt Checklist (SRC) Clicrlt fR f'.a6l I'JIr4jQQrvd bydrle; kAR f Oirl]11.r �Ot : XE21LI17 Mo nts of r e4ipr Para Ciitnt tJ i'5 ; Lyj FWEx F R 1.lther- L l Yes L l�l0 1. WVL-O cugody seah lorr Mt (M the CaolerF JYes Vo - NA,2.1F4;us,odyhrF11svw+ere We5=t,tkeretli intactand nnl>Inkrn? PW Strip lU: vn _ Chlorine SGr:p 1 NA Tested lsy; HA _ 09 Orl;21 tempeTallllt�upon rerneipa f Dujytj (Carrec d) tCrnpellllarc upon receipt 'lSrFlid St1ap•C,p Ib: 22-W 5.0 _�S,q eC NA IM V NAL A eC �A iNA o r Vrleliod; ❑✓ Tnmllerawr2 Blank ❑k airist Bottilw iR Cun ,r7= 5 JR Gun Call+aCtipq yaClar. ° T klethod ufr:oaianu � wet 1-0 F ]c*4 1?lxckc Ntsne d Yes o �R'A 3. if r�clnp-2 atm)a a Fany cbolu exceeded 6.0"C,PM ;L] wws Notified by; one i cmvil / act-W-face (circle cnedlo NA4.:sthe commcresalcoaR{cr'spaukingslip attmchpdto%isfttml? )(Cs No cry prnl xr a�stodv p ccadures (rclin isiic�d'rccived) Followed? V Yes rjNr fi. e a 5d3nplc 113e lisl d an I�aC CO[ ,' ,, Yes No 7. Were umple 1D. I;�lledon all Sample ennminem? V Yes No 8. W= LvJlert on dote& 6me litter; on the COC? -� J Yes No S'as Cc]k-etiart dale & dine 16Wd an all aampl a conheir. m- V ✓ Ycs No 10, Did all amtaioler lirb4l'uArtnatian (ID, date, time) agroc wkh the Ci7C? 71 Ycs e+la 11- Wem Le-sLc fo be rF {fled ]ists:d an the Cs(1C? Yes El No 12. Di{i uJI 5amples arrive (unbm ca-, lids ouz, ctc-p �'CS Nc1 13- Wud adeglhtle sample Ycs Nu 14. Wet� all samples retci Yes hlO I.S. iV:! sa,nplescxign Ej fa ❑NA 1G.For 'OAandRSK-l7' 1n all of li1-- VOA VW8. Ycs Ncr MNA M Wov ail cyanide sauoro: ❑ Yrs D NO ❑� NA 1 ` w C#c al [ applJ bJe. N] rSbidaHJ r!MorJre? ©Yes El Ni) LINA 20. %Vcrc oUnt rernurks -N Lcon'ectiy tran�cribc7d from Yes TVo 7.1. Uk'a9 LtL a cote ntxntbar 'vampbeYLm- vrvxtiam (Just becornplcmd t any; YMM131e(X) U.; n say rrpli: mceivirtg xy ith NA rnL of chose tree- T4? "itne cf preSeW O.on MA� - 117 MON than nr1 sa np]a(s) Na s#ed aecordiagly in 5,9niplo rsoc3vin_9 wide soditin) R hucace lahcl;ap}rl[}d by-, '7DC t the proper Cirnl�3iners for each test an&O[- itj good .onditiolk Plume available ad with--n Va Cleholding lime or48 hptlt'S, whichever dames irrst? ]nsos rn Lzing�'=x --ss {Circle ones lleS Not ]isW. on COUP sairiplcs. were bubHes irres=t�"pear-sire" {rfd"ur bmm in diam31 tricnt samples received at a pH OF-.-! 2? a receivrd at a plk �- 12 and solfidc sari r ]r5 reoei4 e ] at tl p Fi -} 4- cyacn_�3 t~rtOU �.1i606-3 1 <1) 111kvU) �iunoleA CT .M nt- sts (i.e. requc5tcd di lotions, MS,"1dSD &a--gnat=ous, CDC irltll the comas A seetiQn in LJlwf$? :d on IC Ool706or IaE1el? Tryes- Qj()W y 1 two pi4(5) incorrmAy prey=rvcd or wM beadspace-) wena ri=x ived jvwrectly prncrwM and were adjwtiWa accnidingly 4, FT 03t FIC:I, NaOH uSillg SK #'fin lervative is ree6.AL ples7so nato is the comments b4Jer'r. +vu-v receJved WWI hubb les >6 mm in diarnetcr- '%ayrW rrc�-; ved wit]) TRC 0. S tl.YL (If 21 J 9 :s no) and +AVm sul-are ft,%W with 5hea]y TD. NA paw: 4:+! IF2f�22 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 13 APPENDIX B2 LABORATORY ANALYTICAL REPORT - NOVEMBER 2022 www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 07, 2022 Mr. Michael Pressley ERM 300 West Summit Ave Suite 330 Charlotte, NC 28203 RE: Project: TOASTMASTER Pace Project No.: 92638865 Dear Mr. Pressley: Enclosed are the analytical results for sample(s) received by the laboratory on November 30, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Zachary J Tierney zachary.tierney@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Anthony King -Foreman, ERM REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: TOASTMASTER Pace Project No.: 92638865 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: TOASTMASTER Pace Project No.: 92638865 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92638865001 MW-7-WG-20221129 EPA 8260D CL 71 PASI-C 92638865002 ME-14-WG-20221129 EPA 8260D CL 71 PASI-C 92638865003 T13-1-WQ-20221129 EPA 8260D CL 71 PASI-C PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: TOASTMASTER Pace Project No.: 92638865 Sample: MW-7-WG-20221129 Lab ID: 92638865001 Collected: 11/29/22 00:00 Received: 11/30/22 11:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 12/02/22 00:52 67-64-1 Benzene ND ug/L 5.0 1 12/02/22 00:52 71-43-2 Bromobenzene ND ug/L 5.0 1 12/02/22 00:52 108-86-1 Bromochloromethane ND ug/L 5.0 1 12/02/22 00:52 74-97-5 Bromodichloromethane ND ug/L 5.0 1 12/02/22 00:52 75-27-4 Bromoform ND ug/L 5.0 1 12/02/22 00:52 75-25-2 Bromomethane ND ug/L 10.0 1 12/02/22 00:52 74-83-9 v2 2-Butanone (MEK) ND ug/L 10.0 1 12/02/22 00:52 78-93-3 tert-Butyl Alcohol ND ug/L 100 1 12/02/22 00:52 75-65-0 v1 n-Butylbenzene ND ug/L 5.0 1 12/02/22 00:52 104-51-8 sec-Butylbenzene ND ug/L 5.0 1 12/02/22 00:52 135-98-8 tert-Butyl benzene ND ug/L 5.0 1 12/02/22 00:52 98-06-6 Carbon tetrachloride ND ug/L 5.0 1 12/02/22 00:52 56-23-5 Chlorobenzene ND ug/L 5.0 1 12/02/22 00:52 108-90-7 Chloroethane ND ug/L 10.0 1 12/02/22 00:52 75-00-3 Chloroform ND ug/L 5.0 1 12/02/22 00:52 67-66-3 Chloromethane ND ug/L 5.0 1 12/02/22 00:52 74-87-3 2-Chlorotoluene ND ug/L 5.0 1 12/02/22 00:52 95-49-8 4-Chlorotoluene ND ug/L 5.0 1 12/02/22 00:52 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 12/02/22 00:52 96-12-8 Dibromochloromethane ND ug/L 5.0 1 12/02/22 00:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 1 12/02/22 00:52 106-93-4 Dibromomethane ND ug/L 5.0 1 12/02/22 00:52 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 1 12/02/22 00:52 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 1 12/02/22 00:52 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 1 12/02/22 00:52 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 1 12/02/22 00:52 75-71-8 1,1-Dichloroethane ND ug/L 5.0 1 12/02/22 00:52 75-34-3 1,2-Dichloroethane ND ug/L 5.0 1 12/02/22 00:52 107-06-2 1,2-Dichloroethene (Total) ND ug/L 5.0 1 12/02/22 00:52 540-59-0 1,1-Dichloroethene ND ug/L 5.0 1 12/02/22 00:52 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 1 12/02/22 00:52 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 1 12/02/22 00:52 156-60-5 1,2-Dichloropropane ND ug/L 5.0 1 12/02/22 00:52 78-87-5 1,3-Dichloropropane ND ug/L 5.0 1 12/02/22 00:52 142-28-9 2,2-Dichloropropane ND ug/L 5.0 1 12/02/22 00:52 594-20-7 1,1-Dichloropropene ND ug/L 5.0 1 12/02/22 00:52 563-58-6 cis-1,3-Dichloropropene ND ug/L 5.0 1 12/02/22 00:52 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 5.0 1 12/02/22 00:52 10061-02-6 Diisopropyl ether ND ug/L 5.0 1 12/02/22 00:52 108-20-3 Ethylbenzene ND ug/L 5.0 1 12/02/22 00:52 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 12/02/22 00:52 87-68-3 2-Hexanone ND ug/L 10.0 1 12/02/22 00:52 591-78-6 Isopropylbenzene (Cumene) ND ug/L 5.0 1 12/02/22 00:52 98-82-8 p-Isopropyltoluene ND ug/L 5.0 1 12/02/22 00:52 99-87-6 Methylene Chloride ND ug/L 5.0 1 12/02/22 00:52 75-09-2 L1,v1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: TOASTMASTER Pace Project No.: 92638865 Sample: MW-7-WG-20221129 Lab ID: 92638865001 Collected: 11/29/22 00:00 Received: 11/30/22 11:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 1 12/02/22 00:52 108-10-1 Methyl-tert-butyl ether ND ug/L 5.0 1 12/02/22 00:52 1634-04-4 Naphthalene ND ug/L 5.0 1 12/02/22 00:52 91-20-3 n-Propylbenzene ND ug/L 5.0 1 12/02/22 00:52 103-65-1 Styrene ND ug/L 5.0 1 12/02/22 00:52 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 1 12/02/22 00:52 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 5.0 1 12/02/22 00:52 79-34-5 Tetrachloroethene ND ug/L 5.0 1 12/02/22 00:52 127-18-4 Toluene ND ug/L 5.0 1 12/02/22 00:52 108-88-3 1,2,3-Trichlorobenzene ND ug/L 5.0 1 12/02/22 00:52 87-61-6 1,2,4-Trichlorobenzene ND ug/L 5.0 1 12/02/22 00:52 120-82-1 1,1,1-Trichloroethane ND ug/L 5.0 1 12/02/22 00:52 71-55-6 1,1,2-Trichloroethane ND ug/L 5.0 1 12/02/22 00:52 79-00-5 Trichloroethene 37.8 ug/L 5.0 1 12/02/22 00:52 79-01-6 Trichlorofluoromethane ND ug/L 10.0 1 12/02/22 00:52 75-69-4 1,2,3-Trichloropropane ND ug/L 5.0 1 12/02/22 00:52 96-18-4 1,2,4-Trimethylbenzene ND ug/L 5.0 1 12/02/22 00:52 95-63-6 1,3,5-Trimethylbenzene ND ug/L 5.0 1 12/02/22 00:52 108-67-8 Vinyl acetate ND ug/L 10.0 1 12/02/22 00:52 108-05-4 Vinyl chloride ND ug/L 5.0 1 12/02/22 00:52 75-01-4 m&p-Xylene ND ug/L 10.0 1 12/02/22 00:52 179601-23-1 o-Xylene ND ug/L 5.0 1 12/02/22 00:52 95-47-6 Surrogates 4-Bromofluorobenzene (S) 95 % 70-130 1 12/02/22 00:52 460-00-4 1,2-Dichloroethane-d4 (S) 83 % 70-130 1 12/02/22 00:52 17060-07-0 Toluene-d8(S) 98 % 70-130 1 12/02/22 00:52 2037-26-5 Sample: ME-14-WG-20221129 Lab ID: 92638865002 Collected: 11/29/22 10:05 Received: 11/30/22 11:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) tert-Butyl Alcohol n-Butylbenzene sec-Butylbenzene tert-Butyl benzene Date: 12/07/2022 04:25 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 25.0 1 12/02/22 01:28 67-64-1 5.0 1 12/02/22 01:28 71-43-2 5.0 1 12/02/22 01:28 108-86-1 5.0 1 12/02/22 01:28 74-97-5 5.0 1 12/02/22 01:28 75-27-4 5.0 1 12/02/22 01:28 75-25-2 10.0 1 12/02/22 01:28 74-83-9 10.0 1 12/02/22 01:28 78-93-3 100 1 12/02/22 01:28 75-65-0 5.0 1 12/02/22 01:28 104-51-8 5.0 1 12/02/22 01:28 135-98-8 5.0 1 12/02/22 01:28 98-06-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2,v3 v1 Page 5 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: TOASTMASTER Pace Project No.: 92638865 Sample: ME-14-WG-20221129 Lab ID: 92638865002 Collected: 11/29/22 10:05 Received: 11/30/22 11:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Carbon tetrachloride ND ug/L 5.0 1 12/02/22 01:28 56-23-5 Chlorobenzene ND ug/L 5.0 1 12/02/22 01:28 108-90-7 Chloroethane ND ug/L 10.0 1 12/02/22 01:28 75-00-3 Chloroform ND ug/L 5.0 1 12/02/22 01:28 67-66-3 Chloromethane ND ug/L 5.0 1 12/02/22 01:28 74-87-3 2-Chlorotoluene ND ug/L 5.0 1 12/02/22 01:28 95-49-8 4-Chlorotoluene ND ug/L 5.0 1 12/02/22 01:28 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 12/02/22 01:28 96-12-8 Dibromochloromethane ND ug/L 5.0 1 12/02/22 01:28 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 1 12/02/22 01:28 106-93-4 Dibromomethane ND ug/L 5.0 1 12/02/22 01:28 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 1 12/02/22 01:28 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 1 12/02/22 01:28 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 1 12/02/22 01:28 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 1 12/02/22 01:28 75-71-8 1,1-Dichloroethane ND ug/L 5.0 1 12/02/22 01:28 75-34-3 1,2-Dichloroethane ND ug/L 5.0 1 12/02/22 01:28 107-06-2 1,2-Dichloroethene (Total) ND ug/L 5.0 1 12/02/22 01:28 540-59-0 1,1-Dichloroethene ND ug/L 5.0 1 12/02/22 01:28 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 1 12/02/22 01:28 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 1 12/02/22 01:28 156-60-5 1,2-Dichloropropane ND ug/L 5.0 1 12/02/22 01:28 78-87-5 1,3-Dichloropropane ND ug/L 5.0 1 12/02/22 01:28 142-28-9 2,2-Dichloropropane ND ug/L 5.0 1 12/02/22 01:28 594-20-7 1,1-Dichloropropene ND ug/L 5.0 1 12/02/22 01:28 563-58-6 cis-1,3-Dichloropropene ND ug/L 5.0 1 12/02/22 01:28 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 5.0 1 12/02/22 01:28 10061-02-6 Diisopropyl ether ND ug/L 5.0 1 12/02/22 01:28 108-20-3 Ethylbenzene ND ug/L 5.0 1 12/02/22 01:28 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 12/02/22 01:28 87-68-3 2-Hexanone ND ug/L 10.0 1 12/02/22 01:28 591-78-6 Isopropylbenzene (Cumene) ND ug/L 5.0 1 12/02/22 01:28 98-82-8 p-Isopropyltoluene ND ug/L 5.0 1 12/02/22 01:28 99-87-6 Methylene Chloride ND ug/L 5.0 1 12/02/22 01:28 75-09-2 L1,v1 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 1 12/02/22 01:28 108-10-1 Methyl-tert-butyl ether ND ug/L 5.0 1 12/02/22 01:28 1634-04-4 Naphthalene ND ug/L 5.0 1 12/02/22 01:28 91-20-3 n-Propylbenzene ND ug/L 5.0 1 12/02/22 01:28 103-65-1 Styrene ND ug/L 5.0 1 12/02/22 01:28 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 1 12/02/22 01:28 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 5.0 1 12/02/22 01:28 79-34-5 Tetrachloroethene ND ug/L 5.0 1 12/02/22 01:28 127-18-4 Toluene ND ug/L 5.0 1 12/02/22 01:28 108-88-3 1,2,3-Trichlorobenzene ND ug/L 5.0 1 12/02/22 01:28 87-61-6 1,2,4-Trichlorobenzene ND ug/L 5.0 1 12/02/22 01:28 120-82-1 1,1,1-Trichloroethane ND ug/L 5.0 1 12/02/22 01:28 71-55-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: TOASTMASTER Pace Project No.: 92638865 Sample: ME-14-WG-20221129 Lab ID: 92638865002 Collected: 11/29/22 10:05 Received: 11/30/22 11:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,1,2-Trichloroethane ND ug/L 5.0 1 12/02/22 01:28 79-00-5 Trichloroethene 48.8 ug/L 5.0 1 12/02/22 01:28 79-01-6 Trichlorofluoromethane ND ug/L 10.0 1 12/02/22 01:28 75-69-4 1,2,3-Trichloropropane ND ug/L 5.0 1 12/02/22 01:28 96-18-4 1,2,4-Trimethylbenzene ND ug/L 5.0 1 12/02/22 01:28 95-63-6 1,3,5-Trimethylbenzene ND ug/L 5.0 1 12/02/22 01:28 108-67-8 Vinyl acetate ND ug/L 10.0 1 12/02/22 01:28 108-05-4 Vinyl chloride ND ug/L 5.0 1 12/02/22 01:28 75-01-4 m&p-Xylene ND ug/L 10.0 1 12/02/22 01:28 179601-23-1 o-Xylene ND ug/L 5.0 1 12/02/22 01:28 95-47-6 Surrogates 4-Bromofluorobenzene (S) 95 % 70-130 1 12/02/22 01:28 460-00-4 1,2-Dichloroethane-d4 (S) 85 % 70-130 1 12/02/22 01:28 17060-07-0 Toluene-d8(S) 97 % 70-130 1 12/02/22 01:28 2037-26-5 Sample: TB-1-WQ-20221129 Lab ID: 92638865003 Collected: 11/29/22 00:00 Received: 11/30/22 11:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 12/06/22 19:58 67-64-1 Benzene ND ug/L 5.0 1 12/06/22 19:58 71-43-2 Bromobenzene ND ug/L 5.0 1 12/06/22 19:58 108-86-1 Bromochloromethane ND ug/L 5.0 1 12/06/22 19:58 74-97-5 Bromodichloromethane ND ug/L 5.0 1 12/06/22 19:58 75-27-4 Bromoform ND ug/L 5.0 1 12/06/22 19:58 75-25-2 Bromomethane ND ug/L 10.0 1 12/06/22 19:58 74-83-9 2-Butanone (MEK) ND ug/L 10.0 1 12/06/22 19:58 78-93-3 tert-Butyl Alcohol ND ug/L 100 1 12/06/22 19:58 75-65-0 n-Butylbenzene ND ug/L 5.0 1 12/06/22 19:58 104-51-8 sec-Butylbenzene ND ug/L 5.0 1 12/06/22 19:58 135-98-8 tert-Butyl benzene ND ug/L 5.0 1 12/06/22 19:58 98-06-6 Carbon tetrachloride ND ug/L 5.0 1 12/06/22 19:58 56-23-5 Chlorobenzene ND ug/L 5.0 1 12/06/22 19:58 108-90-7 Chloroethane ND ug/L 10.0 1 12/06/22 19:58 75-00-3 Chloroform ND ug/L 5.0 1 12/06/22 19:58 67-66-3 Chloromethane ND ug/L 5.0 1 12/06/22 19:58 74-87-3 2-Chlorotoluene ND ug/L 5.0 1 12/06/22 19:58 95-49-8 4-Chlorotoluene ND ug/L 5.0 1 12/06/22 19:58 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 12/06/22 19:58 96-12-8 Dibromochloromethane ND ug/L 5.0 1 12/06/22 19:58 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 1 12/06/22 19:58 106-93-4 Dibromomethane ND ug/L 5.0 1 12/06/22 19:58 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 1 12/06/22 19:58 95-50-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: TOASTMASTER Pace Project No.: 92638865 Sample: TB-1-WQ-20221129 Lab ID: 92638865003 Collected: 11/29/22 00:00 Received: 11/30/22 11:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,3-Dichlorobenzene ND ug/L 5.0 1 12/06/22 19:58 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 1 12/06/22 19:58 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 1 12/06/22 19:58 75-71-8 1,1-Dichloroethane ND ug/L 5.0 1 12/06/22 19:58 75-34-3 1,2-Dichloroethane ND ug/L 5.0 1 12/06/22 19:58 107-06-2 1,2-Dichloroethene (Total) ND ug/L 5.0 1 12/06/22 19:58 540-59-0 1,1-Dichloroethene ND ug/L 5.0 1 12/06/22 19:58 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 1 12/06/22 19:58 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 1 12/06/22 19:58 156-60-5 1,2-Dichloropropane ND ug/L 5.0 1 12/06/22 19:58 78-87-5 1,3-Dichloropropane ND ug/L 5.0 1 12/06/22 19:58 142-28-9 2,2-Dichloropropane ND ug/L 5.0 1 12/06/22 19:58 594-20-7 1,1-Dichloropropene ND ug/L 5.0 1 12/06/22 19:58 563-58-6 cis-1,3-Dichloropropene ND ug/L 5.0 1 12/06/22 19:58 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 5.0 1 12/06/22 19:58 10061-02-6 Diisopropyl ether ND ug/L 5.0 1 12/06/22 19:58 108-20-3 Ethylbenzene ND ug/L 5.0 1 12/06/22 19:58 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 12/06/22 19:58 87-68-3 2-Hexanone ND ug/L 10.0 1 12/06/22 19:58 591-78-6 Isopropylbenzene (Cumene) ND ug/L 5.0 1 12/06/22 19:58 98-82-8 p-Isopropyltoluene ND ug/L 5.0 1 12/06/22 19:58 99-87-6 Methylene Chloride ND ug/L 5.0 1 12/06/22 19:58 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 1 12/06/22 19:58 108-10-1 Methyl-tert-butyl ether ND ug/L 5.0 1 12/06/22 19:58 1634-04-4 Naphthalene ND ug/L 5.0 1 12/06/22 19:58 91-20-3 n-Propylbenzene ND ug/L 5.0 1 12/06/22 19:58 103-65-1 Styrene ND ug/L 5.0 1 12/06/22 19:58 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 1 12/06/22 19:58 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 5.0 1 12/06/22 19:58 79-34-5 Tetrachloroethene ND ug/L 5.0 1 12/06/22 19:58 127-18-4 Toluene ND ug/L 5.0 1 12/06/22 19:58 108-88-3 1,2,3-Trichlorobenzene ND ug/L 5.0 1 12/06/22 19:58 87-61-6 1,2,4-Trichlorobenzene ND ug/L 5.0 1 12/06/22 19:58 120-82-1 1,1,1-Trichloroethane ND ug/L 5.0 1 12/06/22 19:58 71-55-6 1,1,2-Trichloroethane ND ug/L 5.0 1 12/06/22 19:58 79-00-5 Trichloroethene ND ug/L 5.0 1 12/06/22 19:58 79-01-6 Trichlorofluoromethane ND ug/L 10.0 1 12/06/22 19:58 75-69-4 1,2,3-Trichloropropane ND ug/L 5.0 1 12/06/22 19:58 96-18-4 1,2,4-Trimethylbenzene ND ug/L 5.0 1 12/06/22 19:58 95-63-6 1,3,5-Trimethylbenzene ND ug/L 5.0 1 12/06/22 19:58 108-67-8 Vinyl acetate ND ug/L 10.0 1 12/06/22 19:58 108-05-4 Vinyl chloride ND ug/L 5.0 1 12/06/22 19:58 75-01-4 m&p-Xylene ND ug/L 10.0 1 12/06/22 19:58 179601-23-1 o-Xylene ND ug/L 5.0 1 12/06/22 19:58 95-47-6 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 12/06/22 19:58 460-00-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: TOASTMASTER Pace Project No.: 92638865 Sample: TB-1-WQ-20221129 Lab ID: 92638865003 Collected: 11/29/22 00:00 Received: 11/30/22 11:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Surrogates 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/06/22 19:58 17060-07-0 Toluene-d8(S) 101 % 70-130 1 12/06/22 19:58 2037-26-5 Date: 12/07/2022 04:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 QC Batch: 740493 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92638865001, 92638865002 METHOD BLANK: 3852496 Associated Lab Samples: 92638865001, 92638865002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/01/22 17:56 1,1,1-Trichloroethane ug/L ND 5.0 12/01/22 17:56 1,1,2,2-Tetrachloroethane ug/L ND 5.0 12/01/22 17:56 1,1,2-Trichloroethane ug/L ND 5.0 12/01/22 17:56 1,1-Dichloroethane ug/L ND 5.0 12/01/22 17:56 1,1-Dichloroethene ug/L ND 5.0 12/01/22 17:56 1,1-Dichloropropene ug/L ND 5.0 12/01/22 17:56 1,2,3-Trichlorobenzene ug/L ND 5.0 12/01/22 17:56 1,2,3-Trichloropropane ug/L ND 5.0 12/01/22 17:56 1,2,4-Trichlorobenzene ug/L ND 5.0 12/01/22 17:56 1,2,4-Trimethylbenzene ug/L ND 5.0 12/01/22 17:56 1,2-Dibromo-3-chloropropane ug/L ND 5.0 12/01/22 17:56 1,2-Dibromoethane (EDB) ug/L ND 5.0 12/01/22 17:56 1,2-Dichlorobenzene ug/L ND 5.0 12/01/22 17:56 1,2-Dichloroethane ug/L ND 5.0 12/01/22 17:56 1,2-Dichloroethene (Total) ug/L ND 5.0 12/01/22 17:56 1,2-Dichloropropane ug/L ND 5.0 12/01/22 17:56 1,3,5-Trimethylbenzene ug/L ND 5.0 12/01/22 17:56 1,3-Dichlorobenzene ug/L ND 5.0 12/01/22 17:56 1,3-Dichloropropane ug/L ND 5.0 12/01/22 17:56 1,4-Dichlorobenzene ug/L ND 5.0 12/01/22 17:56 2,2-Dichloropropane ug/L ND 5.0 12/01/22 17:56 2-Butanone (MEK) ug/L ND 10.0 12/01/22 17:56 2-Chlorotoluene ug/L ND 5.0 12/01/22 17:56 2-Hexanone ug/L ND 10.0 12/01/22 17:56 4-Chlorotoluene ug/L ND 5.0 12/01/22 17:56 4-Methyl-2-pentanone (MIBK) ug/L ND 10.0 12/01/22 17:56 Acetone ug/L ND 25.0 12/01/22 17:56 Benzene ug/L ND 5.0 12/01/22 17:56 Bromobenzene ug/L ND 5.0 12/01/22 17:56 Bromochloromethane ug/L ND 5.0 12/01/22 17:56 Bromodichloromethane ug/L ND 5.0 12/01/22 17:56 Bromoform ug/L ND 5.0 12/01/22 17:56 Bromomethane ug/L ND 10.0 12/01/22 17:56 v2 Carbon tetrachloride ug/L ND 5.0 12/01/22 17:56 Chlorobenzene ug/L ND 5.0 12/01/22 17:56 Chloroethane ug/L ND 10.0 12/01/22 17:56 Chloroform ug/L ND 5.0 12/01/22 17:56 Chloromethane ug/L ND 5.0 12/01/22 17:56 cis-1,2-Dichloroethene ug/L ND 5.0 12/01/22 17:56 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 METHOD BLANK: 3852496 Associated Lab Samples: 92638865001, 92638865002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed cis-1,3-Dichloropropene ug/L ND 5.0 12/01/22 17:56 Dibromochloromethane ug/L ND 5.0 12/01/22 17:56 Dibromomethane ug/L ND 5.0 12/01/22 17:56 Dichlorodifluoromethane ug/L ND 5.0 12/01/22 17:56 Diisopropyl ether ug/L ND 5.0 12/01/22 17:56 Ethylbenzene ug/L ND 5.0 12/01/22 17:56 Hexachloro-1,3-butadiene ug/L ND 5.0 12/01/22 17:56 Isopropylbenzene (Cumene) ug/L ND 5.0 12/01/22 17:56 m&p-Xylene ug/L ND 10.0 12/01/22 17:56 Methyl-tert-butyl ether ug/L ND 5.0 12/01/22 17:56 Methylene Chloride ug/L ND 5.0 12/01/22 17:56 n-Butylbenzene ug/L ND 5.0 12/01/22 17:56 n-Propylbenzene ug/L ND 5.0 12/01/22 17:56 Naphthalene ug/L ND 5.0 12/01/22 17:56 o-Xylene ug/L ND 5.0 12/01/22 17:56 p-Isopropyltoluene ug/L ND 5.0 12/01/22 17:56 sec-Butylbenzene ug/L ND 5.0 12/01/22 17:56 Styrene ug/L ND 5.0 12/01/22 17:56 tert-Butyl Alcohol ug/L ND 100 12/01/22 17:56 tert-Butyl benzene ug/L ND 5.0 12/01/22 17:56 Tetrachloroethene ug/L ND 5.0 12/01/22 17:56 Toluene ug/L ND 5.0 12/01/22 17:56 trans-1,2-Dichloroethene ug/L ND 5.0 12/01/22 17:56 trans- 1,3-Dichloropropene ug/L ND 5.0 12/01/22 17:56 Trichloroethene ug/L ND 5.0 12/01/22 17:56 Trichlorofluoromethane ug/L ND 10.0 12/01/22 17:56 Vinyl acetate ug/L ND 10.0 12/01/22 17:56 Vinyl chloride ug/L ND 5.0 12/01/22 17:56 1,2-Dichloroethane-d4 (S) % 83 70-130 12/01/22 17:56 4-Bromofluorobenzene (S) % 96 70-130 12/01/22 17:56 Toluene-d8 (S) % 101 70-130 12/01/22 17:56 v1 v1 Qualifiers LABORATORY CONTROL SAMPLE: 3852497 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.2 100 70-130 1,1,1-Trichloroethane ug/L 50 46.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.6 97 70-130 1,1,2-Trichloroethane ug/L 50 51.3 103 70-130 1,1-Dichloroethane ug/L 50 46.0 92 70-130 1,1-Dichloroethene ug/L 50 50.3 101 70-130 1,1-Dichloropropene ug/L 50 50.6 101 70-130 1,2,3-Trichlorobenzene ug/L 50 57.4 115 70-130 1,2,3-Trichloropropane ug/L 50 46.2 92 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 26 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 LABORATORY CONTROL SAMPLE: Parameter 3852497 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/L 50 54.5 109 70-130 1,2,4-Trimethylbenzene ug/L 50 48.5 97 70-130 1,2-Dibromo-3-chloropropane ug/L 50 52.9 106 70-131 1,2-Dibromoethane (EDB) ug/L 50 52.4 105 70-130 1,2-Dichlorobenzene ug/L 50 51.6 103 70-130 1,2-Dichloroethane ug/L 50 42.6 85 70-130 1,2-Dichloroethene (Total) ug/L 93.8 1,2-Dichloropropane ug/L 50 49.8 100 70-130 1,3,5-Trimethylbenzene ug/L 50 48.0 96 70-130 1,3-Dichlorobenzene ug/L 50 50.8 102 70-130 1,3-Dichloropropane ug/L 50 48.5 97 70-130 1,4-Dichlorobenzene ug/L 50 50.2 100 70-130 2,2-Dichloropropane ug/L 50 43.3 87 68-135 2-Butanone (MEK) ug/L 100 90.5 90 70-134 2-Chlorotoluene ug/L 50 47.1 94 70-130 2-Hexanone ug/L 100 86.2 86 70-131 4-Chlorotoluene ug/L 50 46.2 92 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 85.3 85 70-130 Acetone ug/L 100 86.8 87 70-133 Benzene ug/L 50 49.1 98 70-130 Bromobenzene ug/L 50 51.7 103 70-130 Bromochloromethane ug/L 50 54.4 109 70-130 Bromodichloromethane ug/L 50 46.7 93 70-130 Bromoform ug/L 50 50.0 100 70-130 Bromomethane ug/L 50 39.5 79 45-151 v3 Carbon tetrachloride ug/L 50 43.6 87 70-130 Chlorobenzene ug/L 50 50.4 101 70-130 Chloroethane ug/L 50 47.1 94 39-152 Chloroform ug/L 50 46.4 93 70-130 Chloromethane ug/L 50 52.6 105 58-130 cis-1,2-Dichloroethene ug/L 50 45.9 92 70-130 cis-1,3-Dichloropropene ug/L 50 49.2 98 70-130 Dibromochloromethane ug/L 50 50.0 100 70-130 Dibromomethane ug/L 50 56.2 112 70-130 Dichlorodifluoromethane ug/L 50 57.0 114 54-133 Diisopropyl ether ug/L 50 46.2 92 70-130 Ethylbenzene ug/L 50 47.3 95 70-130 Hexachloro-1,3-butadiene ug/L 50 51.2 102 70-135 Isopropylbenzene (Cumene) ug/L 50 47.3 95 70-130 m&p-Xylene ug/L 100 95.3 95 70-130 Methyl-tert-butyl ether ug/L 50 50.2 100 70-130 Methylene Chloride ug/L 50 71.3 143 66-130 L1,v1 n-Butylbenzene ug/L 50 46.5 93 70-130 n-Propylbenzene ug/L 50 46.0 92 70-130 Naphthalene ug/L 50 58.5 117 70-130 o-Xylene ug/L 50 49.3 99 70-130 p-Isopropyltoluene ug/L 50 48.9 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 LABORATORY CONTROL SAMPLE: 3852497 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers sec-Butylbenzene ug/L 50 46.4 93 70-130 Styrene ug/L 50 49.3 99 70-130 tert-Butyl Alcohol ug/L 500 654 131 68-134 v1 tert-Butyl benzene ug/L 50 40.4 81 63-130 Tetrachloroethene ug/L 50 51.4 103 70-130 Toluene ug/L 50 48.9 98 70-130 trans-1,2-Dichloroethene ug/L 50 48.0 96 70-130 trans- 1,3-Dichloropropene ug/L 50 47.6 95 70-130 Trichloroethene ug/L 50 53.8 108 70-130 Trichlorofluoromethane ug/L 50 42.0 84 62-130 Vinyl acetate ug/L 100 89.3 89 70-144 Vinyl chloride ug/L 50 53.1 106 62-130 1,2-Dichloroethane-d4 (S) % 85 70-130 4-Bromofluorobenzene (S) % 94 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: 3852499 92638865002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.3 102 70-141 1,1,1-Trichloroethane ug/L ND 20 20.2 101 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 20.1 101 69-142 1,1,2-Trichloroethane ug/L ND 20 20.7 103 70-138 1,1-Dichloroethane ug/L ND 20 20.0 100 70-150 1,1-Dichloroethene ug/L ND 20 22.2 111 70-156 1,1-Dichloropropene ug/L ND 20 21.7 108 70-150 1,2,3-Trichlorobenzene ug/L ND 20 21.4 107 70-148 1,2,3-Trichloropropane ug/L ND 20 18.7 94 70-140 1,2,4-Trichlorobenzene ug/L ND 20 20.6 103 70-146 1,2,4-Trimethylbenzene ug/L ND 20 20.2 101 70-149 1,2-Dibromo-3-chloropropane ug/L ND 20 19.8 99 68-146 1,2-Dibromoethane (EDB) ug/L ND 20 21.4 107 70-138 1,2-Dichlorobenzene ug/L ND 20 21.3 106 70-141 1,2-Dichloroethane ug/L ND 20 18.6 93 69-143 1,2-Dichloroethene (Total) ug/L ND 44.2 1,2-Dichloropropane ug/L ND 20 20.7 103 68-156 1,3,5-Trimethylbenzene ug/L ND 20 20.1 101 70-153 1,3-Dichlorobenzene ug/L ND 20 21.5 107 70-143 1,3-Dichloropropane ug/L ND 20 19.9 100 70-138 1,4-Dichlorobenzene ug/L ND 20 20.7 103 70-142 2,2-Dichloropropane ug/L ND 20 17.8 89 52-170 2-Butanone (MEK) ug/L ND 40 36.0 90 60-157 2-Chlorotoluene ug/L ND 20 20.0 100 70-147 2-Hexanone ug/L ND 40 32.6 82 68-146 4-Chlorotoluene ug/L ND 20 19.8 99 70-142 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 MATRIX SPIKE SAMPLE: 3852499 92638865002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 4-Methyl-2-pentanone (MIBK) ug/L ND 40 32.7 82 70-141 Acetone ug/L ND 40 35.6 89 58-157 Benzene ug/L ND 20 20.8 104 70-142 Bromobenzene ug/L ND 20 21.5 107 70-143 Bromochloromethane ug/L ND 20 22.3 111 70-146 Bromodichloromethane ug/L ND 20 19.2 96 70-139 Bromoform ug/L ND 20 18.9 94 64-140 Bromomethane ug/L ND 20 15.8 79 28-192 v3 Carbon tetrachloride ug/L ND 20 19.0 95 70-148 Chlorobenzene ug/L ND 20 21.5 107 70-141 Chloroethane ug/L ND 20 26.1 130 58-191 Chloroform ug/L ND 20 19.8 99 70-148 Chloromethane ug/L ND 20 23.3 117 43-162 cis-1,2-Dichloroethene ug/L ND 20 23.4 98 68-151 cis-1,3-Dichloropropene ug/L ND 20 19.0 95 70-139 Dibromochloromethane ug/L ND 20 19.6 98 70-144 Dibromomethane ug/L ND 20 23.4 117 70-139 Dichlorodifluoromethane ug/L ND 20 28.2 141 39-171 Diisopropyl ether ug/L ND 20 18.1 91 67-142 Ethylbenzene ug/L ND 20 20.6 103 70-143 Hexachloro-1,3-butadiene ug/L ND 20 20.6 103 64-163 Isopropylbenzene (Cumene) ug/L ND 20 20.4 102 70-145 m&p-Xylene ug/L ND 40 41.5 104 70-144 Methyl-tert-butyl ether ug/L ND 20 18.5 92 65-143 Methylene Chloride ug/L ND 20 15.7 79 62-149 v1 n-Butylbenzene ug/L ND 20 18.6 93 65-163 n-Propylbenzene ug/L ND 20 19.4 97 70-152 Naphthalene ug/L ND 20 21.5 107 67-147 o-Xylene ug/L ND 20 20.8 104 70-145 p-Isopropyltoluene ug/L ND 20 20.0 100 70-147 sec-Butylbenzene ug/L ND 20 19.8 99 70-144 Styrene ug/L ND 20 20.1 100 70-143 tert-Butyl Alcohol ug/L ND 200 279 139 35-200 v1 tert-Butyl benzene ug/L ND 20 17.3 86 62-133 Tetrachloroethene ug/L ND 20 22.1 111 70-145 Toluene ug/L ND 20 20.8 104 70-142 trans-1,2-Dichloroethene ug/L ND 20 20.8 104 70-151 trans- 1,3-Dichloropropene ug/L ND 20 18.4 92 70-139 Trichloroethene ug/L 48.8 20 74.5 128 62-146 Trichlorofluoromethane ug/L ND 20 20.7 103 63-153 Vinyl acetate ug/L ND 40 30.7 77 61-162 Vinyl chloride ug/L ND 20 23.9 119 61-163 1,2-Dichloroethane-d4 (S) % 84 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 SAMPLE DUPLICATE: 3852498 Parameter Units 92638865001 Result Dup Result 1,1,1,2-Tetrachloroethane ug/L ND ND 1,1,1-Trichloroethane ug/L ND ND 1,1,2,2-Tetrachloroethane ug/L ND ND 1,1,2-Trichloroethane ug/L ND ND 1,1-Dichloroethane ug/L ND ND 1,1-Dichloroethene ug/L ND ND 1,1-Dichloropropene ug/L ND ND 1,2,3-Trichlorobenzene ug/L ND ND 1,2,3-Trichloropropane ug/L ND ND 1,2,4-Trichlorobenzene ug/L ND ND 1,2,4-Trimethylbenzene ug/L ND ND 1,2-Dibromo-3-chloropropane ug/L ND ND 1,2-Dibromoethane (EDB) ug/L ND ND 1,2-Dichlorobenzene ug/L ND ND 1,2-Dichloroethane ug/L ND ND 1,2-Dichloroethene (Total) ug/L ND ND 1,2-Dichloropropane ug/L ND ND 1,3,5-Trimethylbenzene ug/L ND ND 1,3-Dichlorobenzene ug/L ND ND 1,3-Dichloropropane ug/L ND ND 1,4-Dichlorobenzene ug/L ND ND 2,2-Dichloropropane ug/L ND ND 2-Butanone (MEK) ug/L ND ND 2-Chlorotoluene ug/L ND ND 2-Hexanone ug/L ND ND 4-Chlorotoluene ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Benzene ug/L ND ND Bromobenzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Dichlorodifluoromethane ug/L ND ND Diisopropyl ether ug/L ND ND Ethylbenzene ug/L ND ND Hexachloro-1,3-butadiene ug/L ND ND RPD Qualifiers v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 SAMPLE DUPLICATE: 3852498 Parameter Units 92638865001 Result Dup Result Isopropylbenzene (Cumene) ug/L ND ND m&p-Xylene ug/L ND ND Methyl-tert-butyl ether ug/L ND ND Methylene Chloride ug/L ND ND n-Butylbenzene ug/L ND ND n-Propylbenzene ug/L ND ND Naphthalene ug/L ND ND o-Xylene ug/L ND ND p-Isopropyltoluene ug/L ND ND sec-Butylbenzene ug/L ND ND Styrene ug/L ND ND tert-Butyl Alcohol ug/L ND ND tert-Butyl benzene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND Trichloroethene ug/L 37.8 36.3 Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND 1,2-Dichloroethane-d4 (S) % 83 83 4-Bromofluorobenzene (S) % 95 95 Toluene-d8 (S) % 98 98 RPD Qualifiers 4 v1 v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 QC Batch: 741466 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92638865003 METHOD BLANK: 3857204 Associated Lab Samples: 92638865003 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/06/22 19:40 1,1,1-Trichloroethane ug/L ND 5.0 12/06/22 19:40 1,1,2,2-Tetrachloroethane ug/L ND 5.0 12/06/22 19:40 1,1,2-Trichloroethane ug/L ND 5.0 12/06/22 19:40 1,1-Dichloroethane ug/L ND 5.0 12/06/22 19:40 1,1-Dichloroethene ug/L ND 5.0 12/06/22 19:40 1,1-Dichloropropene ug/L ND 5.0 12/06/22 19:40 1,2,3-Trichlorobenzene ug/L ND 5.0 12/06/22 19:40 1,2,3-Trichloropropane ug/L ND 5.0 12/06/22 19:40 1,2,4-Trichlorobenzene ug/L ND 5.0 12/06/22 19:40 1,2,4-Trimethylbenzene ug/L ND 5.0 12/06/22 19:40 1,2-Dibromo-3-chloropropane ug/L ND 5.0 12/06/22 19:40 1,2-Dibromoethane (EDB) ug/L ND 5.0 12/06/22 19:40 1,2-Dichlorobenzene ug/L ND 5.0 12/06/22 19:40 1,2-Dichloroethane ug/L ND 5.0 12/06/22 19:40 1,2-Dichloroethene (Total) ug/L ND 5.0 12/06/22 19:40 1,2-Dichloropropane ug/L ND 5.0 12/06/22 19:40 1,3,5-Trimethylbenzene ug/L ND 5.0 12/06/22 19:40 1,3-Dichlorobenzene ug/L ND 5.0 12/06/22 19:40 1,3-Dichloropropane ug/L ND 5.0 12/06/22 19:40 1,4-Dichlorobenzene ug/L ND 5.0 12/06/22 19:40 2,2-Dichloropropane ug/L ND 5.0 12/06/22 19:40 2-Butanone (MEK) ug/L ND 10.0 12/06/22 19:40 2-Chlorotoluene ug/L ND 5.0 12/06/22 19:40 2-Hexanone ug/L ND 10.0 12/06/22 19:40 4-Chlorotoluene ug/L ND 5.0 12/06/22 19:40 4-Methyl-2-pentanone (MIBK) ug/L ND 10.0 12/06/22 19:40 Acetone ug/L ND 25.0 12/06/22 19:40 Benzene ug/L ND 5.0 12/06/22 19:40 Bromobenzene ug/L ND 5.0 12/06/22 19:40 Bromochloromethane ug/L ND 5.0 12/06/22 19:40 Bromodichloromethane ug/L ND 5.0 12/06/22 19:40 Bromoform ug/L ND 5.0 12/06/22 19:40 Bromomethane ug/L ND 10.0 12/06/22 19:40 Carbon tetrachloride ug/L ND 5.0 12/06/22 19:40 Chlorobenzene ug/L ND 5.0 12/06/22 19:40 Chloroethane ug/L ND 10.0 12/06/22 19:40 Chloroform ug/L ND 5.0 12/06/22 19:40 Chloromethane ug/L ND 5.0 12/06/22 19:40 cis-1,2-Dichloroethene ug/L ND 5.0 12/06/22 19:40 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 METHOD BLANK: 3857204 Associated Lab Samples: 92638865003 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed cis-1,3-Dichloropropene ug/L ND 5.0 12/06/22 19:40 Dibromochloromethane ug/L ND 5.0 12/06/22 19:40 Dibromomethane ug/L ND 5.0 12/06/22 19:40 Dichlorodifluoromethane ug/L ND 5.0 12/06/22 19:40 Diisopropyl ether ug/L ND 5.0 12/06/22 19:40 Ethylbenzene ug/L ND 5.0 12/06/22 19:40 Hexachloro-1,3-butadiene ug/L ND 5.0 12/06/22 19:40 Isopropylbenzene (Cumene) ug/L ND 5.0 12/06/22 19:40 m&p-Xylene ug/L ND 10.0 12/06/22 19:40 Methyl-tert-butyl ether ug/L ND 5.0 12/06/22 19:40 Methylene Chloride ug/L ND 5.0 12/06/22 19:40 n-Butylbenzene ug/L ND 5.0 12/06/22 19:40 n-Propylbenzene ug/L ND 5.0 12/06/22 19:40 Naphthalene ug/L ND 5.0 12/06/22 19:40 o-Xylene ug/L ND 5.0 12/06/22 19:40 p-Isopropyltoluene ug/L ND 5.0 12/06/22 19:40 sec-Butylbenzene ug/L ND 5.0 12/06/22 19:40 Styrene ug/L ND 5.0 12/06/22 19:40 tert-Butyl Alcohol ug/L ND 100 12/06/22 19:40 tert-Butyl benzene ug/L ND 5.0 12/06/22 19:40 Tetrachloroethene ug/L ND 5.0 12/06/22 19:40 Toluene ug/L ND 5.0 12/06/22 19:40 trans-1,2-Dichloroethene ug/L ND 5.0 12/06/22 19:40 trans- 1,3-Dichloropropene ug/L ND 5.0 12/06/22 19:40 Trichloroethene ug/L ND 5.0 12/06/22 19:40 Trichlorofluoromethane ug/L ND 10.0 12/06/22 19:40 Vinyl acetate ug/L ND 10.0 12/06/22 19:40 Vinyl chloride ug/L ND 5.0 12/06/22 19:40 1,2-Dichloroethane-d4 (S) % 98 70-130 12/06/22 19:40 4-Bromofluorobenzene (S) % 99 70-130 12/06/22 19:40 Toluene-d8 (S) % 102 70-130 12/06/22 19:40 Qualifiers LABORATORY CONTROL SAMPLE: 3857205 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.6 105 70-130 1,1,1-Trichloroethane ug/L 50 50.7 101 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.8 102 70-130 1,1,2-Trichloroethane ug/L 50 50.7 101 70-130 1,1-Dichloroethane ug/L 50 50.8 102 70-130 1,1-Dichloroethene ug/L 50 50.6 101 70-130 1,1-Dichloropropene ug/L 50 52.7 105 70-130 1,2,3-Trichlorobenzene ug/L 50 53.7 107 70-130 1,2,3-Trichloropropane ug/L 50 51.0 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 LABORATORY CONTROL SAMPLE: Parameter 3857205 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2,4-Trichlorobenzene ug/L 50 52.4 105 70-130 1,2,4-Trimethylbenzene ug/L 50 50.3 101 70-130 1,2-Dibromo-3-chloropropane ug/L 50 50.6 101 70-131 1,2-Dibromoethane (EDB) ug/L 50 51.8 104 70-130 1,2-Dichlorobenzene ug/L 50 51.5 103 70-130 1,2-Dichloroethane ug/L 50 51.3 103 70-130 1,2-Dichloroethene (Total) ug/L 99.9 1,2-Dichloropropane ug/L 50 50.1 100 70-130 1,3,5-Trimethylbenzene ug/L 50 50.8 102 70-130 1,3-Dichlorobenzene ug/L 50 51.6 103 70-130 1,3-Dichloropropane ug/L 50 50.1 100 70-130 1,4-Dichlorobenzene ug/L 50 50.3 101 70-130 2,2-Dichloropropane ug/L 50 48.6 97 68-135 2-Butanone (MEK) ug/L 100 102 102 70-134 2-Chlorotoluene ug/L 50 49.3 99 70-130 2-Hexanone ug/L 100 104 104 70-131 4-Chlorotoluene ug/L 50 49.8 100 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 101 101 70-130 Acetone ug/L 100 93.3 93 70-133 Benzene ug/L 50 48.2 96 70-130 Bromobenzene ug/L 50 49.2 98 70-130 Bromochloromethane ug/L 50 51.8 104 70-130 Bromodichloromethane ug/L 50 51.6 103 70-130 Bromoform ug/L 50 54.3 109 70-130 Bromomethane ug/L 50 44.3 89 45-151 Carbon tetrachloride ug/L 50 49.2 98 70-130 Chlorobenzene ug/L 50 50.4 101 70-130 Chloroethane ug/L 50 37.6 75 39-152 Chloroform ug/L 50 52.1 104 70-130 Chloromethane ug/L 50 54.3 109 58-130 cis-1,2-Dichloroethene ug/L 50 50.2 100 70-130 cis-1,3-Dichloropropene ug/L 50 51.5 103 70-130 Dibromochloromethane ug/L 50 51.7 103 70-130 Dibromomethane ug/L 50 50.0 100 70-130 Dichlorodifluoromethane ug/L 50 50.0 100 54-133 Diisopropyl ether ug/L 50 49.8 100 70-130 Ethylbenzene ug/L 50 49.6 99 70-130 Hexachloro-1,3-butadiene ug/L 50 51.2 102 70-135 Isopropylbenzene(Cumene) ug/L 50 48.8 98 70-130 m&p-Xylene ug/L 100 100 100 70-130 Methyl-tert-butyl ether ug/L 50 48.8 98 70-130 Methylene Chloride ug/L 50 49.0 98 66-130 n-Butylbenzene ug/L 50 51.3 103 70-130 n-Propylbenzene ug/L 50 49.2 98 70-130 Naphthalene ug/L 50 53.4 107 70-130 o-Xylene ug/L 50 50.7 101 70-130 p-Isopropyltoluene ug/L 50 51.9 104 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 LABORATORY CONTROL SAMPLE: 3857205 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers sec-Butylbenzene ug/L 50 49.6 99 70-130 Styrene ug/L 50 51.6 103 70-130 tert-Butyl Alcohol ug/L 500 500 100 68-134 tert-Butyl benzene ug/L 50 43.3 87 63-130 Tetrachloroethene ug/L 50 47.9 96 70-130 Toluene ug/L 50 48.7 97 70-130 trans-1,2-Dichloroethene ug/L 50 49.7 99 70-130 trans- 1,3-Dichloropropene ug/L 50 51.9 104 70-130 Trichloroethene ug/L 50 51.5 103 70-130 Trichlorofluoromethane ug/L 50 47.2 94 62-130 Vinyl acetate ug/L 100 110 110 70-144 Vinyl chloride ug/L 50 53.3 107 62-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3857206 3857207 MS MSD 92639244021 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 500 500 568 564 114 113 70-141 1 1,1,1-Trichloroethane ug/L ND 500 500 570 571 114 114 70-150 0 1,1,2,2-Tetrachloroethane ug/L ND 500 500 521 519 104 104 69-142 0 1,1,2-Trichloroethane ug/L ND 500 500 539 542 108 108 70-138 1 1,1-Dichloroethane ug/L ND 500 500 574 557 115 111 70-150 3 1,1-Dichloroethene ug/L ND 500 500 585 596 117 119 70-156 2 1,1-Dichloropropene ug/L ND 500 500 590 594 118 119 70-150 1 1,2,3-Trichlorobenzene ug/L ND 500 500 520 572 104 114 70-148 9 1,2,3-Trichloropropane ug/L ND 500 500 525 504 105 101 70-140 4 1,2,4-Trichlorobenzene ug/L ND 500 500 535 546 107 109 70-146 2 1,2,4-Trimethylbenzene ug/L ND 500 500 552 540 110 108 70-149 2 1,2-Dibromo-3-chloropropane ug/L ND 500 500 548 523 110 105 68-146 4 1,2-Dibromoethane (EDB) ug/L ND 500 500 547 540 109 108 70-138 1 1,2-Dichlorobenzene ug/L ND 500 500 552 556 110 111 70-141 1 1,2-Dichloroethane ug/L ND 500 500 509 508 102 102 69-143 0 1,2-Dichloroethene (Total) ug/L ND 1120 1150 2 1,2-Dichloropropane ug/L ND 500 500 548 538 110 108 68-156 2 1,3,5-Trimethylbenzene ug/L ND 500 500 555 551 111 110 70-153 1 1,3-Dichlorobenzene ug/L ND 500 500 553 556 111 111 70-143 0 1,3-Dichloropropane ug/L ND 500 500 532 533 106 107 70-138 0 1,4-Dichlorobenzene ug/L ND 500 500 542 531 108 106 70-142 2 2,2-Dichloropropane ug/L ND 500 500 525 526 104 104 52-170 0 2-Butanone (MEK) ug/L ND 1000 1000 1010 970 101 97 60-157 4 2-Chlorotoluene ug/L ND 500 500 554 542 111 108 70-147 2 2-Hexanone ug/L ND 1000 1000 1010 962 101 96 68-146 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 26 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: TOASTMASTER Pace Project No.: 92638865 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3857206 3857207 MS MSD 92639244021 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 4-Chlorotoluene ug/L ND 500 500 540 532 108 106 70-142 2 4-Methyl-2-pentanone (MIBK) ug/L ND 1000 1000 1020 961 102 96 70-141 6 Acetone ug/L ND 1000 1000 929 926 93 93 58-157 0 Benzene ug/L ND 500 500 538 530 108 106 70-142 1 Bromobenzene ug/L ND 500 500 554 554 111 111 70-143 0 Bromochloromethane ug/L ND 500 500 561 567 112 113 70-146 1 Bromodichloromethane ug/L ND 500 500 556 540 111 108 70-139 3 Bromoform ug/L ND 500 500 574 553 115 111 64-140 4 Bromomethane ug/L ND 500 500 353 425 71 85 28-192 18 Carbon tetrachloride ug/L ND 500 500 580 565 116 113 70-148 3 Chlorobenzene ug/L ND 500 500 553 552 109 109 70-141 0 Chloroethane ug/L ND 500 500 505 522 101 104 58-191 3 Chloroform ug/L ND 500 500 557 581 110 115 70-148 4 Chloromethane ug/L ND 500 500 599 618 118 122 43-162 3 cis-1,2-Dichloroethene ug/L ND 500 500 559 572 109 111 68-151 2 cis-1,3-Dichloropropene ug/L ND 500 500 542 538 108 108 70-139 1 Dibromochloromethane ug/L ND 500 500 561 542 112 108 70-144 3 Dibromomethane ug/L ND 500 500 544 545 109 109 70-139 0 Dichlorodifluoromethane ug/L ND 500 500 534 544 107 109 39-171 2 Diisopropyl ether ug/L ND 500 500 527 534 105 106 67-142 1 Ethylbenzene ug/L ND 500 500 550 554 110 111 70-143 1 Hexachloro-1,3-butadiene ug/L ND 500 500 573 577 115 115 64-163 1 Isopropylbenzene (Cumene) ug/L ND 500 500 542 541 108 108 70-145 0 m&p-Xylene ug/L ND 1000 1000 1100 1110 110 111 70-144 1 Methyl-tert-butyl ether ug/L ND 500 500 517 514 103 103 65-143 1 Methylene Chloride ug/L ND 500 500 543 539 109 108 62-149 1 n-Butylbenzene ug/L ND 500 500 528 524 106 105 65-163 1 n-Propylbenzene ug/L ND 500 500 547 541 109 108 70-152 1 Naphthalene ug/L ND 500 500 517 544 103 109 67-147 5 o-Xylene ug/L ND 500 500 550 548 110 110 70-145 0 p-Isopropyltoluene ug/L ND 500 500 568 559 114 112 70-147 2 sec-Butylbenzene ug/L ND 500 500 547 539 109 108 70-144 1 Styrene ug/L ND 500 500 548 552 110 110 70-143 1 tert-Butyl Alcohol ug/L ND 5000 5000 5100 4890 102 98 35-200 4 tert-Butyl benzene ug/L ND 500 500 489 484 98 97 62-133 1 Tetrachloroethene ug/L 3830 500 500 4670 4650 168 163 70-145 1 M1 Toluene ug/L ND 500 500 541 539 107 106 70-142 0 trans-1,2-Dichloroethene ug/L ND 500 500 565 580 113 116 70-151 3 trans- 1,3-Dichloropropene ug/L ND 500 500 532 527 106 105 70-139 1 Trichloroethene ug/L ND 500 500 613 624 113 115 62-146 2 Trichlorofluoromethane ug/L ND 500 500 477 485 95 97 63-153 2 Vinyl acetate ug/L ND 1000 1000 1100 1080 110 108 61-162 2 Vinyl chloride ug/L ND 500 500 609 610 122 122 61-163 0 1,2-Dichloroethane-d4 (S) % 91 95 70-130 4-Bromofluorobenzene (S) % 100 99 70-130 Toluene-d8(S) % 99 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: TOASTMASTER Pace Project No.: 92638865 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 26 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: TOASTMASTER Pace Project No.: 92638865 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92638865001 MW-7-WG-20221129 EPA 8260D 740493 92638865002 ME-14-WG-20221129 EPA 8260D 740493 92638865003 TBA-WQ-20221129 EPA 8260D 741466 Date: 12/07/2022 04:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 23 of 26 ca-rnlvl-riuN i-uurss vu t -bample Vonclition upon Receipt ace 21202205/12/2022 Laboratory receiving samples: Asheville ❑ Edeno Greenwood ❑ Huntersville 0 Raleigh❑ Mechanicsville❑ Atlanta[ Kernar-111_r-7 Sample + Client Name: / �4Q�] ( QQ Upon , r ( rV Project #): �0#' 9263886 HIM Mal Courier; QFEd Ex ❑UPS ❑U5P5 Illll1 ❑Client ❑ Commercial ❑Pate ❑other: 926381365 Custody Seal Present? ❑Yes ❑No Seals Intact? ❑Yes ❑No Date/Initials Person Examining contents:_ Packing Material; ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other Thermometer: ❑ IR Gun ID: Type of Ice: L7 wet ❑Blue Correction Factor: Cooler Temp: U Add/Subtract (°C) —1 — 1 Cooler Temp Corrected (°C): USDA Regulated Sail ( [] N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? FlYes FlNo Chain of Custody Present? Samples Arrived within Hold Time? Short hold Time Analysis (02 hr.)? Rush Turn Around Time Requested? Sufficient Volume? Correct Containers Used? -Pace Containers Used? Containers Intact? Dissolved analysis: Samples Field Filtered? Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix Headspace in VDA Vials (>5-6mm)? Trip Blank Present? Trip Blank Custody Seals Present? COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: - _. PrPiect Manager SRF Review: jJYes jJN4 LJN/A 1, ❑'res ❑No El N/A 2. ❑Yes ❑No ❑N/A 3. []Yes ❑No ❑N/A 4. []Yes ❑Na ❑N/A 5. ❑Yes ❑No ❑N/A 6. ❑Yes [:]No ❑N/A ❑Yes [:)No ❑N/A 7, ❑Yes ❑No ❑N/A 8, QYes ❑No ❑N/A 9. LjYes ❑No ❑N/A 10. ❑Yes ❑No El N/A 11. Biological Tissue Frozen? ❑Yes ❑No ❑N/A ❑None Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples on ice, cooling process has hegun Did samples originate from a foreign source (internationally, including Hawaii and Puerto Rico)? ❑Yes ❑Pia Comments/Dlscre aancv: Lot 10 of split containers: Date/Time: Date: Date: Field Data Required? ❑Yes ❑No U 1 Qualtrax ID: 69614 Page 1 of 2 Page 24 of 26 ' Ur�Ce VvT I IL41i. 6.11v r I%IVI rIuld i-uuoa vV I _admpie LOrtuixionupori meceilax Effective Date; 05112 1z/2o22 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg *"Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Project # W01t • 92.6388155 PM: LIT Due Date: 12/07/22 CLIENT: 82-ERM -F = a HZ z E m v N a mot-. fY n. J Ln a m N a " N a J a rn a m m m r1 7 .V'- 1p a J o Wl N a m a a Z c VN _ro Cl d ri 7 rl a m _. v n O VI S uEi N �.,.� vt tq a m _ N y n O 2 u .�N a �J o w N Z tM1 a m m dl M o Q z u_ a J vEi N ,.., N O a m -- n = ? a Z u ,N a J uEi N r{ m C a go3 c m a d j ° E LL � a v a 7 E Q ~ 61 ri ti to a _ V Q. U_ n E Q a _ rl S .f 0 ¢ v W `L ` '� ¢ J E o n N rM1 U a r4 v a 0 ry x d a Q v ri rl a ry v H inV 2 "d E ¢ E o� N M W a -; u ¢ ._ 2 .� f J E o� O5 LO a \ _ U S O > E a C1 ID o z O vMi '~ z 4 > J E o 01 ID > ` z n"n v w EX EX > J E 0 O� l7 > a z O CL_ro m x Q > J E o O1 0 a Z O = 4 O J E d OS a „ l;j S j ' , a N ° U' ro 1 Z u m �- d � H .J E n va, i z ++ a W N �J E o N 0.m tA of m Q1 v o N N ? Hai 4 .-J E 0 M m ? a�i ;' „ W G E < E E o O a M a z v 2 Ip y�j _o c •• L _ V E Q E E t'j a o 1 2 ti 3 4 5 6 7 8 9 10 \NI - 11 12 pH Adjustment Log for Preserved Samples Sample tf] Type pH upon receipt Date preservation adjusted Time preservation adjusted Amount of preservative Lodi added - Note: Wherievef there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be Pent to the North Carolina DEN Certification Office (i.e. ` Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID:69614 Page 2 of 2 Page 25 of 26 IN5- ED a V I TEMP In C Received on Ice (Y7N) Custody Sealed Cooler (YIN) Samples Intact (Y/N) A VI N -3 O I N3 on r o A N m c, - O r w O m a P p ti z b " n 3 N Cb C p D N d 3 m K w N v n m 0 6 c o m L L A n O aL Z 0 p 1 o ¢ W N 3 n MATRIX CODE (see valid modes to lefl) r 0 o SAMPLETYPE (G=GRAB C=Coklp} a _ O 3N w m (n n m 0 a x o F z J O K n SAMPLE TEMP AT COLLECTION @ OF CONTAINERS Unpreserved H2SO4 HNO3 HCI NaOH NaM03 Methanol Other Analyses Test VOCs 8260 Trip Blank Residual Chlorine (YM N D 3 0 0 1 rs y - I. •V N ram` DO r m n r n ^ � \+ m w = o C- n a m n S' Z OCD s a Q N -n m O , '� C n n m m' C) m a _�. n ei' o m tn' cn ° o �Gv y m n m N m ry w D a n ((D oN v Z N m a Z�. Z 0 'r N D 3 n n p1 o _ n W M YIN d r U)i m 3 S rn Q m lu m f(] Cr D N C lU M D A. Q M UI n -6 Q1 { Z n 0 C N m m � C N N nl � a � � n � Z n m G N a o 7 � O Page 26 of 26 APPENDIX C LABORATORY ANALYTICAL REPORTS - MONTHLY INFLUENT & EFFLUENT SAMPLES 2022 www.erm.com Version: Project No.: 0588976 Client: 29 March 2023 Report of Analysis ERM NC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Michael Pressley Project Name: Toastmaster Lot Number:XA20013 Date Completed:01/28/2022 /� doa',' 01 /28/2022 12:24 PM Approved and released by: Project Manager I: Hannah K. Lucas �q RCCAA16 2W _ AM fiafkeWAcsredi}angr &WO A C C A E O[ Y E d iESTIHG LABOft4TOPY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 14 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM NC, Inc. Lot Number: XA20013 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Volatiles The laboratory control sample (LCS) associated with batch 29118 had bromomethane recovered above the acceptance limits. This could potentially result in a high bias on analytical results. There were no detections for this compound in the samples associated with this batch; therefore, data quality is not impacted. Inorganic non-metals The pH analysis associated with the samples in this report were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 14 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM NC, Inc. Lot Number: XA20013 Sample Number Sample ID Matrix Date Sampled Date Received 001 Inf-1-IN Aqueous 01/19/20221000 01/20/2022 002 Eff-2-Ef Aqueous 01/19/20221000 01/20/2022 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 14 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM NC, Inc. Lot Number: XA20013 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Inf-1-IN Aqueous cis- 1,2-Dichloroethene 8260D 6.8 ug/L 6 001 Inf-1-IN Aqueous Tetrachloroethene 8260D 0.65 ug/L 6 001 Inf-1-IN Aqueous Trichloroethene 8260D 160 ug/L 6 (3 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XA20013-001 Description: Inf-1-IN Matrix: Aqueous Date Sampled:01/19/2022 1000 Date Received: 0 1 /20/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 01/23/2022 1701 NBW 29247 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@12°C SM 4500-H B-20 5.1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 5 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XA20013-001 Description: Inf-1-IN Matrix: Aqueous Date Sampled:01/19/2022 1000 Date Received: 0 1 /20/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/21/20221134 BWS 29118 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 6.8 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.65 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 160 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 88 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XA20013-002 Description: Eff-2-Ef Matrix: Aqueous Date Sampled:01/19/2022 1000 Date Received: 0 1 /20/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 01/23/2022 1703 NBW 29247 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@12.8°C SM 4500-H B-20 6.0 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 7 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XA20013-002 Description: Eff-2-Ef Matrix: Aqueous Date Sampled:01/19/2022 1000 Date Received: 0 1 /20/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/21/20221159 BWS 29118 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 98 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 14 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 14 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ29118-001 Matrix: Aqueous Batch: 29118 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ Units Analysis Date Bromodichloromethane ND 1 0.50 ug/L 01/21/2022 0944 Bromoform ND 1 0.50 ug/L 01/21/2022 0944 Bromomethane (Methyl bromide) ND 1 0.50 ug/L 01/21/2022 0944 Carbon tetrachloride ND 1 0.50 ug/L 01/21/2022 0944 Chlorobenzene ND 1 0.50 ug/L 01/21/2022 0944 Chloroethane ND 1 0.50 ug/L 01/21/2022 0944 Chloroform ND 1 0.50 ug/L 01/21/2022 0944 Chloromethane (Methyl chloride) ND 1 0.50 ug/L 01/21/2022 0944 Dibromochloromethane ND 1 0.50 ug/L 01/21/2022 0944 1,2-Dibromoethane (EDB) ND 1 0.50 ug/L 01/21/2022 0944 1,2-Dichlorobenzene ND 1 0.50 ug/L 01/21/2022 0944 1,3-Dichlorobenzene ND 1 0.50 ug/L 01/21/2022 0944 1,4-Dichlorobenzene ND 1 0.50 ug/L 01/21/2022 0944 1,1-Dichloroethane ND 1 0.50 ug/L 01/21/2022 0944 1,2-Dichloroethane ND 1 0.50 ug/L 01/21/2022 0944 1,1-Dichloroethene ND 1 0.50 ug/L 01/21/2022 0944 cis- 1,2-Dichloroethene ND 1 0.50 ug/L 01/21/2022 0944 trans- 1,2-Dichloroethene ND 1 0.50 ug/L 01/21/2022 0944 1,2-Dichloropropane ND 1 0.50 ug/L 01/21/2022 0944 cis- 1,3-Dichloropropene ND 1 0.50 ug/L 01/21/2022 0944 trans- 1,3-Dichloropropene ND 1 0.50 ug/L 01/21/2022 0944 Methylene chloride ND 1 0.50 ug/L 01/21/2022 0944 1,1,2,2-Tetrachloroethane ND 1 0.50 ug/L 01/21/2022 0944 Tetrachloroethene ND 1 0.50 ug/L 01/21/2022 0944 1,1,1-Trichloroethane ND 1 0.50 ug/L 01/21/2022 0944 1,1,2-Trichloroethane ND 1 0.50 ug/L 01/21/2022 0944 Trichloroethene ND 1 0.50 ug/L 01/21/2022 0944 Trichlorofluoromethane ND 1 0.50 ug/L 01/21/2022 0944 Vinyl chloride ND 1 0.50 ug/L 01/21/2022 0944 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 101 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 14 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ29118-002 Matrix: Aqueous Batch: 29118 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Bromodichloromethane 50 49 1 98 70-130 01/21/2022 0855 Bromoform 50 46 1 91 70-130 01/21/2022 0855 Bromomethane (Methyl bromide) 50 66 N 1 133 70-130 01/21/2022 0855 Carbon tetrachloride 50 44 1 88 70-130 01/21/2022 0855 Chlorobenzene 50 50 1 100 70-130 01/21/2022 0855 Chloroethane 50 51 1 103 70-130 01/21/2022 0855 Chloroform 50 49 1 98 70-130 01/21/2022 0855 Chloromethane (Methyl chloride) 50 54 1 108 60-140 01/21/2022 0855 Dibromochloromethane 50 48 1 96 70-130 01/21/2022 0855 1,2-Dibromoethane (EDB) 50 52 1 104 70-130 01/21/2022 0855 1,2-Dichlorobenzene 50 49 1 99 70-130 01/21/2022 0855 1,3-Dichlorobenzene 50 49 1 98 70-130 01/21/2022 0855 1,4-Dichlorobenzene 50 49 1 98 70-130 01/21/2022 0855 1,1-Dichloroethane 50 50 1 100 70-130 01/21/2022 0855 1,2-Dichloroethane 50 50 1 100 70-130 01/21/2022 0855 1,1-Dichloroethene 50 50 1 100 70-130 01/21/2022 0855 cis- 1,2-Dichloroethene 50 48 1 96 70-130 01/21/2022 0855 trans- 1,2-Dichloroethene 50 50 1 101 70-130 01/21/2022 0855 1,2-Dichloropropane 50 49 1 99 70-130 01/21/2022 0855 cis- 1,3-Dichloropropene 50 51 1 102 70-130 01/21/2022 0855 trans- 1,3-Dichloropropene 50 50 1 101 70-130 01/21/2022 0855 Methylene chloride 50 51 1 102 70-130 01/21/2022 0855 1,1,2,2-Tetrachloroethane 50 55 1 111 70-130 01/21/2022 0855 Tetrachloroethene 50 48 1 97 70-130 01/21/2022 0855 1,1,1-Trichloroethane 50 46 1 92 70-130 01/21/2022 0855 1,1,2-Trichloroethane 50 52 1 105 70-130 01/21/2022 0855 Trichloroethene 50 48 1 96 70-130 01/21/2022 0855 Trichlorofluoromethane 50 51 1 102 70-130 01/21/2022 0855 Vinyl chloride 50 55 1 111 70-130 01/21/2022 0855 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 14 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 14 PACE ANALYTICAL SERVICES, LLC I r f�-1 Qj r 1" N r`51 +'4v AAV LLJ 4 C Ca i7YS F I �I FORS 4 , G � � � `3'�•I — r C 6 EL d aos Ma uu..dr a 03LO ` ti x• I I Q � I I I I I i Ln t J. o I 4 AI I a'2 x 1 L--- LA ru w r s f I- .1 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 14 PACE ANALYTICAL SERVICES, LLC SampJyS R-McNptChukAis! (SRC)IME001J9{-15) Revi5ed:9/29/2020 url2?dfYl2sa, ]- IIirig AW.10rity. Face ENV- Wr_4L Page 1 of 1 Sample receipt CheclkJist (SRC) C l iertl; F tM Cooler Tnsl,rr ted [a ,`slulr= ME] J xA 2M 13 Wears ofraaaipt Pace ITO; , 17edT?x DdS 'cs No I, Were cV5Wdv seals pr2Serlt ao m cook 'te5 190 V NA 12, Ifcusloci ' seals w�rc pret:nII., WVam Iey inluel and unbrok- nWd pH Strip TD; WA Q[]arinc Strip ID., NA Teyed by: "A riQiJsrl bomperatDre Ulibn eceipt 1 l erivcri (C`.awrnrt[XD terrlperaLure upnn receipt °'a8c:lid tinap Cud I — J.2 r l,2 w NA 1WA o NA eN 1 NA Velhnd: J TempCJatul+e B-1an'.k ❑o, mdnsE+f3Uttle3 II~; Gun IU- _ IR fern C4reeclir,r3 Factol. u oc 4fetltiod of coolant; Wei lco Ice Pocks ElD lac N221e Yes ❑ X0 21MA '. 1f f=Pr'Mttuc of u3y et�erler exeery[rr. G.O C, was PrGiect Manaiger Ntitiricrl'e ?NJ was Nnrified 1_iy_ pliw c f email 1 Face tD-face {Girck am) - Yes XJa NA 4. Is rl,-aCornmernia[ courier's p=kin.gslip attached io [lus fior[n? l Yes Tda 5. V rc proper CU54{];Jy prs3cerh Ices (re 1=1syuishedlreceived) fa I:o'.u0d? RYes Two 6- Al a-eSample IDS listed ujr the COC? — yes ❑ ?+Ta 7-Wcre saanplC 113s J �ted on tI] I €aI trl,Jr cimtn inera? ❑'Yes No 8. W&B colJeerion date & Lime listed ail Iti C=7 Y= "o 9- V4'ru 0e13E ti[Fir date 8c titpc I:sh;d an aL' s ra la cuu[aiaers'? — — Yes No ] 0- TX6 all cQnMirner JalaeJ infinrrnarioa (ID, da,e, time) agree wick tf,c C O C:7 ,r Yes Na 11. }Mere tests to be perforrrtx[ listed an the CQC? lzlymc []No 12. Did a[] smmplas arriyr in the proper conrairre for cacll rest[ anailor [:s g()cad t!4Mditiok 1(1P0brrjkc.,La, lids pfl,Ctt:.}7 X�NqoJ 3- Was a uide sample V!r[Ln,r avai=able? =4. ereall Fz�mple5recei"CWwitli_r'Athctwldiublimr4r48ltours,v,'Efiahcy"comes tlrs 15- 1h M any strrples containers missirti�'exD�tis (LircEe onc) saran ltr tq-at listed pn G0C16. Farr Vd?A and RSK-175 salnplrz, were L•ubbles Freserrt�'°ea sire" (�;'ar 6mm in diameter) [n aify rIF'h� VQA vials? ' 17- Wcre all DPQ m�l�+r[u[rient sanip_oS rccci►'od al a pl:i of <215 18- Were aJ[ cyankk sam les MCCive 1 at a pH P 12 and sulfide samples receivod at a Prl > t)'? o ©No [71 A 1 - Wtrn aJL applienNo H-ITKKiryaniuuPhana 25-IJbU ,3 (';0, ) aarrtplcs froe of residua] t111�riri�� �yvb 20. Were clitni retnsrk-5ifequcsts (i.a- mques[eddilutions, MA.+[+ gD deli ,�atlionsetc,,,c+-rrrKI17transcribed fiwn the CDC i-Lto The cro"11TI It section in LIMO 'e CS Tire 2J. Was the [ate=t,nhcm 1i�ted on he container ]abaft If uola ;: 3umplle Prcurvatio,i (Must lse en>r,ple ed fcr arry 5ampie4) lns�?rrwdy proscrtired nr with heal pacx,) rnp lo(s) x•# zmplc reeuiving with KA me of prdservafion NA NA WCrLe reoeJ%red 111001-,+crt1y preserved and wern adjusted mcordingly .mL of ciTr�k oae'. l-TM504, J`1ND'i, TiC1, NaO14 using SR # KA . Jf Mort #lien un a preservative i} n$eded, plcam rote in tits ow n.r]cnts Mow - Were received with hubbles >6 �nm it diarneler. _were T-occMtd wirh 7'f;tC > p.� rn�lL fT�lrl4 isN�l aria'Nwv acoordinglw irr �qjmpla receiving with scdiurr, tJo[ast2]N' W (N32LS Oa) witja Sltefily JJJ' trrt har'N'Kie, Uetc applJed by: ME" Date O:r'2,]n ' ('rnr2rmts: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 14 Report of Analysis ERM NC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Michael Pressley Project Name: Toastmaster Lot Number:XB09047 Date Completed:02/15/2022 Revision Date: 02/25/2022 /� doa',' 03/01/2022 3:36 PM Approved and released by: Project Manager I: Hannah K. Lucas �q RCCA 2W _A16 A C C A E O[ Y E d iESTIHG LABOft4TOPY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 14 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM NC, Inc. Lot Number: XB09047 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. This report supersedes and replaces any prior reports issued under this lot number. The attached chain of custody was seperated to two reports per client request. Inorganic non-metals The pH analysis associated with the samples in this report were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 14 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM NC, Inc. Lot Number: XB09047 Sample Number Sample ID Matrix Date Sampled Date Received 001 INF-1-IN Aqueous 02/08/2022 0945 02/09/2022 002 EFF-2-EF Aqueous 02/08/2022 0945 02/09/2022 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 14 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM NC, Inc. Lot Number: XB09047 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 INF-1-IN Aqueous cis- 1,2-Dichloroethene 8260D 7.7 ug/L 6 001 INF-1-IN Aqueous Tetrachloroethene 8260D 0.82 ug/L 6 001 INF-1-IN Aqueous Trichloroethene 8260D 200 ug/L 6 002 EFF-2-EF Aqueous cis- 1,2-Dichloroethene 8260D 0.81 ug/L 8 (4 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XB09047-001 Description: INF-1-IN Matrix: Aqueous Date Sampled:02/08/2022 0945 Date Received:02/09/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 02/13/2022 1553 NBW 31643 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@17.8°C SM 4500-H B-20 5.3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 5 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XB09047-001 Description: INF-1-IN Matrix: Aqueous Date Sampled:02/08/2022 0945 Date Received:02/09/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 02/11/20221319 BWS 31516 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 7.7 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.82 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 200 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 89 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XB09047-002 Description: EFF-2-EF Matrix: Aqueous Date Sampled:02/08/2022 0945 Date Received:02/09/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 02/13/2022 1558 NBW 31643 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@17.9°C SM 4500-H B-20 6.1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 7 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XB09047-002 Description: EFF-2-EF Matrix: Aqueous Date Sampled:02/08/2022 0945 Date Received:02/09/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 02/11/20221203 BWS 31516 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.81 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 14 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 14 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ31516-001 Matrix: Aqueous Batch: 31516 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ Units Analysis Date Bromodichloromethane ND 1 0.50 ug/L 02/11/2022 0948 Bromoform ND 1 0.50 ug/L 02/11/2022 0948 Bromomethane (Methyl bromide) ND 1 0.50 ug/L 02/11/2022 0948 Carbon tetrachloride ND 1 0.50 ug/L 02/11/2022 0948 Chlorobenzene ND 1 0.50 ug/L 02/11/2022 0948 Chloroethane ND 1 0.50 ug/L 02/11/2022 0948 Chloroform ND 1 0.50 ug/L 02/11/2022 0948 Chloromethane (Methyl chloride) ND 1 0.50 ug/L 02/11/2022 0948 Dibromochloromethane ND 1 0.50 ug/L 02/11/2022 0948 1,2-Dibromoethane (EDB) ND 1 0.50 ug/L 02/11/2022 0948 1,2-Dichlorobenzene ND 1 0.50 ug/L 02/11/2022 0948 1,3-Dichlorobenzene ND 1 0.50 ug/L 02/11/2022 0948 1,4-Dichlorobenzene ND 1 0.50 ug/L 02/11/2022 0948 1,1-Dichloroethane ND 1 0.50 ug/L 02/11/2022 0948 1,2-Dichloroethane ND 1 0.50 ug/L 02/11/2022 0948 1,1-Dichloroethene ND 1 0.50 ug/L 02/11/2022 0948 cis- 1,2-Dichloroethene ND 1 0.50 ug/L 02/11/2022 0948 trans- 1,2-Dichloroethene ND 1 0.50 ug/L 02/11/2022 0948 1,2-Dichloropropane ND 1 0.50 ug/L 02/11/2022 0948 cis- 1,3-Dichloropropene ND 1 0.50 ug/L 02/11/2022 0948 trans- 1,3-Dichloropropene ND 1 0.50 ug/L 02/11/2022 0948 Methylene chloride ND 1 0.50 ug/L 02/11/2022 0948 1,1,2,2-Tetrachloroethane ND 1 0.50 ug/L 02/11/2022 0948 Tetrachloroethene ND 1 0.50 ug/L 02/11/2022 0948 1,1,1-Trichloroethane ND 1 0.50 ug/L 02/11/2022 0948 1,1,2-Trichloroethane ND 1 0.50 ug/L 02/11/2022 0948 Trichloroethene ND 1 0.50 ug/L 02/11/2022 0948 Trichlorofluoromethane ND 1 0.50 ug/L 02/11/2022 0948 Vinyl chloride ND 1 0.50 ug/L 02/11/2022 0948 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 14 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ31516-002 Matrix: Aqueous Batch: 31516 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Bromodichloromethane 50 48 1 95 70-130 02/11/2022 0858 Bromoform 50 51 1 101 70-130 02/11/2022 0858 Bromomethane (Methyl bromide) 50 47 1 95 70-130 02/11/2022 0858 Carbon tetrachloride 50 49 1 97 70-130 02/11/2022 0858 Chlorobenzene 50 50 1 100 70-130 02/11/2022 0858 Chloroethane 50 46 1 92 70-130 02/11/2022 0858 Chloroform 50 46 1 92 70-130 02/11/2022 0858 Chloromethane (Methyl chloride) 50 46 1 92 60-140 02/11/2022 0858 Dibromochloromethane 50 50 1 100 70-130 02/11/2022 0858 1,2-Dibromoethane (EDB) 50 49 1 97 70-130 02/11/2022 0858 1,2-Dichlorobenzene 50 50 1 100 70-130 02/11/2022 0858 1,3-Dichlorobenzene 50 51 1 101 70-130 02/11/2022 0858 1,4-Dichlorobenzene 50 48 1 96 70-130 02/11/2022 0858 1,1-Dichloroethane 50 46 1 93 70-130 02/11/2022 0858 1,2-Dichloroethane 50 46 1 92 70-130 02/11/2022 0858 1,1-Dichloroethene 50 50 1 100 70-130 02/11/2022 0858 cis- 1,2-Dichloroethene 50 47 1 95 70-130 02/11/2022 0858 trans- 1,2-Dichloroethene 50 49 1 99 70-130 02/11/2022 0858 1,2-Dichloropropane 50 48 1 97 70-130 02/11/2022 0858 cis- 1,3-Dichloropropene 50 51 1 102 70-130 02/11/2022 0858 trans- 1,3-Dichloropropene 50 49 1 98 70-130 02/11/2022 0858 Methylene chloride 50 46 1 91 70-130 02/11/2022 0858 1,1,2,2-Tetrachloroethane 50 46 1 91 70-130 02/11/2022 0858 Tetrachloroethene 50 55 1 109 70-130 02/11/2022 0858 1,1,1-Trichloroethane 50 49 1 99 70-130 02/11/2022 0858 1,1,2-Trichloroethane 50 48 1 96 70-130 02/11/2022 0858 Trichloroethene 50 52 1 104 70-130 02/11/2022 0858 Trichlorofluoromethane 50 49 1 99 70-130 02/11/2022 0858 Vinyl chloride 50 45 1 90 70-130 02/11/2022 0858 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 89 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 14 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 14 PACE ANALYTICAL SERVICES, LLC O x L —A Ui I- E o ' 1r ra uh LU u- 4 0 z 4 ELJ w a QO ;1 F 1 K-'� L IM11"O K A + � b E y�i 7 , ,.. � 5 k m c ' 9 2h g u Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 14 PACE ANALYTICAL SERVICES, LLC C6Ar iytir, arnples Reopipt ChedEdigt (SRC) {114U9EOOIW—�Si IsstringAutharity: PdrE ENV- WCUL P i0`I Sample Receipt Cheekdist (SRC) Clirrtl EF3`� C001cr Irr vctsd bvAnLc: Mr-.Fl } rL axr-022 {_ X1304047 Lat;. NIM1715 OfTnceipL: _ Face Client �ip5 FcsdFa€ C3ther Per, No _ ], 14' ctL!;WY seal%r."5ent on tic caarer? - Ycs No NA 2. 1f cl-t"Ody coalesonL. „crc lhvc intact and Lmbrokan'd Pn 5[riP :U; .!KAChla-ine $tiri li]; W" Tested by; 3 rigi1123 trmp4lature upon i'er arr ipt f Drrived �Cec�cted) ternpCTaLurc upatl rur:Cipr % 01i+i Sna tlp ID; 11A h!CtElod:�J TeriF:cr4Wre I]l n �aiasr ilotk;cs JRGun 1E1; ' _ IRCiro CDrrvcriort Fa4tur: 0 _cc MC00:1 ofcvvlant. LJ,' li a roc. 12 Icc 11a1:k4 D Icy Nicu1c Q Yes is Ifwmperanl,ofll" oyoi:olerewiceoed 6.01 kyn� Lpl Ol�f.4 p;e£t L4tanzgerNo[iticr3? PM was Notified bp'. phoi>e f retail f 11"'c-1:04aw (circle nnc), V Yes Nq [tiA 4. is the Ca:rlrnercial em er's packing slip Mashed to t:lis 11orm7 Yes No S. Werr. prope�-custodyprocedplxal (rolingtrishe&-waived) followed? J -"c-q N'0 b, Were cam plc 117s L-1-d on the ADC? Ycs No 7, Were sanipin- JN listed on 3.11 sumple. coritailieni? Yes No 9, Was cullectior date a iiri4 ris[c�j on d,(-.()Cr? Ye.� No 4, Was eoilcction r7Io& drrtC lis-edon aJIs=plla c nt ineas? { Yes No' 10. Did a'i cx ntainw Leber information (11}, rJ.tic, +irrc) stgre� wild tJtte CUC'� yes, Vic' 11. Were Lusts to �8 perfarm4d listed on the COCA ❑ Ycs �] Nu 12. Did ull s=Plrs aLrivo in the proper contEinem fhr-anch Lest andfor in good condition (nrbroket7. Lrds on; rm.)' _ YeS No 13, Wa€ adpauate sc,nlple volume av4ihible? Ytl' No Yc6 14, Y oir all sample4 rccBiTd within 1 the holding tirnp Dr 48 114n,rs, whiaever comes first? N6 15. WvrQ Alm5an1p1eS 44nlaLlSers TT1154JIi.Q 11CL55 (1,Irc18 Oile3 49m3 Les Not I.SLrd or. COC? ❑ yes U No LINA 16. For TV0A and W{ Ku 175 sautiples. were bubbles preEent >`pja-size" (,/d°or 61nm ill dia meter) ,n Mny of the VOA vials`? Yu� No ONA I l 7, Wero $ll Dlrqhrelai.nurrienL warn le; rca shad at a pJJ u: ,6 2.? Yns Ja Y,s 0Na Nlti l�_'iVen all snide Sal rlplcs -e€dived at m pJi > 12 nild amlficle salr.pios -me ivM at H = 97 N?L sere 1 ip eNFJ,�iKl cyamidelphenDiG25.1.'6t}S_ (<U_SrruLVU yarn csfi•enof 20. Were t]ivntiernrali€slreger�Is (i_c. -quested dilutinrss, MSr h WOY 0 NodNA ! MSD desinadoCs: cLE...) €o redly MULBVIlhedfrom t11c COO intothe oxame�1� Xtioji i,, Nu 2,, Was the uote tllmlber ]ihd Itcon ainr r label? If yes13 QaotiexnpeFrer4'aan:-E— t Lae CDn�pleted Foe any ple{sj iracaneot[y pregel4 oi' l�itF. hear6fil,aoe_) — Sanftic(sj ran were reucivcd in ormetly presurved Laid were adjustedaccordin I� in naz,pfe rec>Givitig wiWIL of cil-cle dj= iMIN, HNO3, i-ii_:4 N20H nsol_u Sly i1 t4A tpn Df pr s-F�ratiotl WJfmore than Due preurvatiyE is needtJ, please riwa ill klio annlmellts be:o4u, SEMPle(S) wire 1 ciWCd with bubbles>6 rnm in dia.IileLr r. Sanlpjes(s) NAre�e:ved �,tiih '11{C' � 1},j nil. (rf �' 19 1ti fPo) ahc3 4u Pre juAud accordingly in samglc rcceivLsg wN, sodiuni thillmltfate (Na2S;!Dj with Sliemly [] '� _ 5RbancodalabelsLppliadby.-.1RGx _ Dam: 01MV24)2A Crrnmeins; '— � Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 14 Report of Analysis ERM NC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Michael Pressley Project Name: Toastmaster Lot Number:XC15012 Date Completed:04/03/2022 /� doa',' 04/05/2022 10:19 AM Approved and released by: Project Manager I: Hannah K. Lucas �q RCCAA16 2W _ AM fiafkeWAcsredi}angr &WO A C C A E O[ Y E d iESTIHG LABOft4TOPY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 14 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM NC, Inc. Lot Number: XC15012 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Inorganic non-metals The pH analysis associated with the samples in this report were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 14 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM NC, Inc. Lot Number: XC15012 Sample Number Sample ID Matrix Date Sampled Date Received 001 INF-1-IN Aqueous 03/14/20221030 03/15/2022 002 EFF-2-EF Aqueous 03/14/20221030 03/15/2022 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 14 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM NC, Inc. Lot Number: XC15012 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 INF-1-IN Aqueous cis- 1,2-Dichloroethene 8260D 6.8 ug/L 6 001 INF-1-IN Aqueous Tetrachloroethene 8260D 0.66 ug/L 6 001 INF-1-IN Aqueous Trichloroethene 8260D 170 ug/L 6 002 EFF-2-EF Aqueous cis- 1,2-Dichloroethene 8260D 1.7 ug/L 8 (4 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XC15012-001 Description: INF-1-IN Matrix: Aqueous Date Sampled:03/14/2022 1030 Date Received:03/15/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 04/03/2022 1740 NBW 36974 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@19.3°C SM 4500-H B-20 5.7 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 5 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XC15012-001 Description: INF-1-IN Matrix: Aqueous Date Sampled:03/14/2022 1030 Date Received:03/15/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 03/20/2022 0628 BBW 35462 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 6.8 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.66 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 170 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 80 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XC15012-002 Description: EFF-2-EF Matrix: Aqueous Date Sampled:03/14/2022 1030 Date Received:03/15/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 04/03/2022 1746 NBW 36974 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@19.4°C SM 4500-H B-20 6.4 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 7 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XC15012-002 Description: EFF-2-EF Matrix: Aqueous Date Sampled:03/14/2022 1030 Date Received:03/15/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 03/20/2022 0653 BBW 35462 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.7 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 83 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 14 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 14 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ35462-001 Matrix: Aqueous Batch: 35462 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ Units Analysis Date Bromodichloromethane ND 1 0.50 ug/L 03/19/2022 2236 Bromoform ND 1 0.50 ug/L 03/19/2022 2236 Bromomethane (Methyl bromide) ND 1 0.50 ug/L 03/19/2022 2236 Carbon tetrachloride ND 1 0.50 ug/L 03/19/2022 2236 Chlorobenzene ND 1 0.50 ug/L 03/19/2022 2236 Chloroethane ND 1 0.50 ug/L 03/19/2022 2236 Chloroform ND 1 0.50 ug/L 03/19/2022 2236 Chloromethane (Methyl chloride) ND 1 0.50 ug/L 03/19/2022 2236 Dibromochloromethane ND 1 0.50 ug/L 03/19/2022 2236 1,2-Dibromoethane (EDB) ND 1 0.50 ug/L 03/19/2022 2236 1,2-Dichlorobenzene ND 1 0.50 ug/L 03/19/2022 2236 1,3-Dichlorobenzene ND 1 0.50 ug/L 03/19/2022 2236 1,4-Dichlorobenzene ND 1 0.50 ug/L 03/19/2022 2236 1,1-Dichloroethane ND 1 0.50 ug/L 03/19/2022 2236 1,2-Dichloroethane ND 1 0.50 ug/L 03/19/2022 2236 1,1-Dichloroethene ND 1 0.50 ug/L 03/19/2022 2236 cis- 1,2-Dichloroethene ND 1 0.50 ug/L 03/19/2022 2236 trans- 1,2-Dichloroethene ND 1 0.50 ug/L 03/19/2022 2236 1,2-Dichloropropane ND 1 0.50 ug/L 03/19/2022 2236 cis- 1,3-Dichloropropene ND 1 0.50 ug/L 03/19/2022 2236 trans- 1,3-Dichloropropene ND 1 0.50 ug/L 03/19/2022 2236 Methylene chloride ND 1 0.50 ug/L 03/19/2022 2236 1,1,2,2-Tetrachloroethane ND 1 0.50 ug/L 03/19/2022 2236 Tetrachloroethene ND 1 0.50 ug/L 03/19/2022 2236 1,1,1-Trichloroethane ND 1 0.50 ug/L 03/19/2022 2236 1,1,2-Trichloroethane ND 1 0.50 ug/L 03/19/2022 2236 Trichloroethene ND 1 0.50 ug/L 03/19/2022 2236 Trichlorofluoromethane ND 1 0.50 ug/L 03/19/2022 2236 Vinyl chloride ND 1 0.50 ug/L 03/19/2022 2236 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 82 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 14 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ35462-002 Matrix: Aqueous Batch: 35462 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Bromodichloromethane 50 43 1 86 70-130 03/19/2022 2036 Bromoform 50 46 1 91 70-130 03/19/2022 2036 Bromomethane (Methyl bromide) 50 55 1 110 70-130 03/19/2022 2036 Carbon tetrachloride 50 45 1 90 70-130 03/19/2022 2036 Chlorobenzene 50 48 1 95 70-130 03/19/2022 2036 Chloroethane 50 49 1 98 70-130 03/19/2022 2036 Chloroform 50 43 1 86 70-130 03/19/2022 2036 Chloromethane (Methyl chloride) 50 49 1 98 60-140 03/19/2022 2036 Dibromochloromethane 50 46 1 91 70-130 03/19/2022 2036 1,2-Dibromoethane (EDB) 50 49 1 97 70-130 03/19/2022 2036 1,2-Dichlorobenzene 50 48 1 96 70-130 03/19/2022 2036 1,3-Dichlorobenzene 50 48 1 96 70-130 03/19/2022 2036 1,4-Dichlorobenzene 50 46 1 92 70-130 03/19/2022 2036 1,1-Dichloroethane 50 45 1 90 70-130 03/19/2022 2036 1,2-Dichloroethane 50 43 1 86 70-130 03/19/2022 2036 1,1-Dichloroethene 50 49 1 98 70-130 03/19/2022 2036 cis- 1,2-Dichloroethene 50 47 1 94 70-130 03/19/2022 2036 trans- 1,2-Dichloroethene 50 48 1 97 70-130 03/19/2022 2036 1,2-Dichloropropane 50 47 1 93 70-130 03/19/2022 2036 cis- 1,3-Dichloropropene 50 48 1 95 70-130 03/19/2022 2036 trans- 1,3-Dichloropropene 50 47 1 93 70-130 03/19/2022 2036 Methylene chloride 50 43 1 86 70-130 03/19/2022 2036 1,1,2,2-Tetrachloroethane 50 45 1 91 70-130 03/19/2022 2036 Tetrachloroethene 50 52 1 104 70-130 03/19/2022 2036 1,1,1-Trichloroethane 50 46 1 93 70-130 03/19/2022 2036 1,1,2-Trichloroethane 50 47 1 93 70-130 03/19/2022 2036 Trichloroethene 50 47 1 94 70-130 03/19/2022 2036 Trichlorofluoromethane 50 51 1 103 70-130 03/19/2022 2036 Vinyl chloride 50 48 1 96 70-130 03/19/2022 2036 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 85 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 14 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 14 PACE ANALYTICAL SERVICES, LLC IIJ ' o = G fLc ❑ !LI M JF3 OD cc 2 L T F f r '.';r 7 W07 k wu�+= �x:aoc HOW -- - — i 4 n r; I� C R ti I. li ct k � Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 14 PACE ANALYTICAL SERVICES, LLC eArrafy�+ 58rrrplesReceiptChecklist (SRC)I ur�oniac-is} Revised:9f29JZ 2{) a! [53uing .fitlthorlt r' ?�L:e EN V - Wt• I Rage 1 of i Sample Receipt ChechJist (SRC} Client: ' Cooler Tuspwed Iri'idato: [t f iAil }r M2 Lot A; XCLM12 Mcan, tPrrcticnpr Pace Client Ul'S FcdLx Otlr� * q No J , W -- a to 5tody 3c�rls sen# oat tl=e cooler? J Yes NO 1w A 2. I F; unto l seals vhvre 1 �tion#, were t i J13M # and unbroken? PH Sir[p ID. CEtl;rrntc StiiM ID: NA TeS#Cd by' M, Oriw"al tcmperaMQM 2A 1 `oaa reccipt.' Deriveyl (Oorr= d) tpmpt;ratum upon r=z,pr blid ua[a (��p ID NA 12.4 nC TfA L NA QC 'AA DNA cC NA j NA oC — Icb3 ' LZ]TeMF1rFH1IHrO Blank ❑'l &Q Bottles IR Gun lD_ S JR {run ffOtrectiou FWWF-- 'C N42thod vi cooJ;krlL: © WM J.'o ❑ ke Packs L1 Lary _oe -r—F Nonr, -lcmperaAuraofanye<aOJcr exceedod 6.0°C, was iroject Nfaaager Nu4i ficd?F%1was'4ate .Mby_ pl C- :MRU Saco-to4u-c (circle one), MLJI�N 4, 1s xhc vo nmercial cout3er'b peeking slily P.ktached tic th:a tontt? 5, Were prnper MISI ady prrcedures (reliltquishad?rec6lvcd) foiloWL:d? 6. V_e:eSwmple IDs listed otr t1r�COC' Yes TJa ' 7, 1Vera Umple IDs ii'rtod cat all sample cun;niners? -es tic R. Was uFlimlion dales & time lWcd on [he OOC'i _ 9- :�'as eoJ 14atfivn mate &rime listed on eJ I sam pl is containrrs7 J Yes No i0, Did aJJ onnhiner label info-maeipr (fD, date, time} a ec w:dI tl�e flC? � Yes No [ 1- Were�w'9 ro be performed l[st,:d an the COG? vi Yss ❑ NE,l3 Di d ml l samp'.es ar-i,, irr [ha p>ti r a'3ntai ne" far carp test nXOr i n ��,od conch t ion (iuLbrok:u L lids nn, e,t-)? Yes k J rVo 12. Was ad&F, late sample vDlume a►v�riJable? Yes Ala 14.Vde��r]lsamplesroceived%VIIhinf�theboldingLimcor484ovF&,,vlticT,cvcraouw%lirs4? yr:s No 15 Were a nu sZVnples aurl H in ors tit is9in9!excey5 (circle, QJiQ sum less loot listed on coc? — 1'as , Ju 16 for VOA and R� K-175 Sam plr:s, -err bubf�le� P s.-nt>-1,e+r size' {y."ar btn7i i n dialneG ❑, in ally L'tfi� VOA vials'l' I Yas NoM.—A 17. -W-jj ; all DRC tnetals'uul.-io sasarnples nzoeiYL!d at a nH of <2° Yes No1$, V4'oL� all r:vanide sarnnl receivcd 91 a PH > 12 a.4 suJf ldc sore lea receivc� ui a 1%H > 97 ❑!',- ❑ No dNA 1 4'mre all jai, ,iicahle NHy+ KNJcy�n�[[efph,kno 23, k�bU83 (: 0. marl.) eut�pies froe o residual chlo6, 0 Ycr ❑NL) ONA Pk. Were el:ent ranarksiregm its ri.a. requestex( dilutions, �ejVMSD dosignatiays, ctc..,) cwmAY lronsc7haLi fmn tiw COC inh) the cortiznmt €ecd on in L I NIS^ ciaagnottnurniberfiEtcd on tbo tiattaint:r ;abel? lfvvrrs, Ounte i1 unFale Pn-wrvatian 4hlust be cmnple:ed for any sun pic(s) inr rrecfJy areserved or with ]teadspice,l urplc{s} ai3 tware rcce[ved iricrecrly FTcsuved snd were vdiumd accrn-diugly sample rt�x;ivin4& with h _ rn mL OFOrole one, MSO4, T' NO% FIC:1, AIaO1j n;jng Sit 44 '4A me ofprosaruatiori MA Ifirwothan nnnpitservutive is neodzd, pJe :note in I[te CriJn,nc,l.¢ bela'.t, w9re received With bubbles >6 ,,,m in diamctcr, wnpte s)-:" were recr:vtd with TRC -0,5 rny/L K�19 isllrr)artd wero- adjus ed accr~rci -r 031 in smnl)k receiving will sudium Chios I[fara {Na,S,()�t with Slron]y If)! NA ��— SR.b-�u,cur:cJabelsapp]Jedby: Krifc l]ata oats — ,4Ull177enL3: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 14 Report of Analysis ERM NC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Michael Pressley Project Name: Toastmaster Laurinburg Site Lot Number:XD29014 Date Completed:05/13/2022 /� doa',' 05/17/2022 1:58 PM Approved and released by: Project Manager I: Hannah K. Lucas �q RCCAA16 2W _ AM fiafkeWAcsredi}angr &WO A C C A E O[ Y E d iESTIHG LABOft4TOPY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 14 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM NC, Inc. Lot Number: XD29014 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Inorganic non-metals The pH analysis associated with the samples in this report were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 14 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM NC, Inc. Lot Number: XD29014 Sample Number Sample ID Matrix Date Sampled Date Received 001 INF-1-IN Aqueous 04/28/20221200 04/29/2022 002 EFFF-2-EF Aqueous 04/28/20221200 04/29/2022 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 14 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM NC, Inc. Lot Number: XD29014 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 INF-1-IN Aqueous cis- 1,2-Dichloroethene 8260D 4.7 ug/L 6 001 INF-1-IN Aqueous Tetrachloroethene 8260D 0.73 ug/L 6 001 INF-1-IN Aqueous Trichloroethene 8260D 120 ug/L 6 002 EFFF-2-EF Aqueous cis- 1,2-Dichloroethene 8260D 2.1 ug/L 8 (4 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XD29014-001 Description: INF-1-IN Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 05/05/2022 1424 KKP 40606 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@16.4°C SM 4500-H B-20 5.4 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 5 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XD29014-001 Description: INF-1-IN Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0233 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 4.7 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.73 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 120 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XD29014-002 Description: EFFF-2-EF Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 05/05/2022 1432 KKP 40606 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@15.9°C SM 4500-H B-20 5.7 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 7 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XD29014-002 Description: EFFF-2-EF Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0257 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 2.1 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 14 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 14 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ41354-001 Matrix: Aqueous Batch:41354 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ Units Analysis Date Bromodichloromethane ND 1 0.50 ug/L 05/11/2022 2142 Bromoform ND 1 0.50 ug/L 05/11/2022 2142 Bromomethane (Methyl bromide) ND 1 0.50 ug/L 05/11/2022 2142 Carbon tetrachloride ND 1 0.50 ug/L 05/11/2022 2142 Chlorobenzene ND 1 0.50 ug/L 05/11/2022 2142 Chloroethane ND 1 0.50 ug/L 05/11/2022 2142 Chloroform ND 1 0.50 ug/L 05/11/2022 2142 Chloromethane (Methyl chloride) ND 1 0.50 ug/L 05/11/2022 2142 Dibromochloromethane ND 1 0.50 ug/L 05/11/2022 2142 1,2-Dibromoethane (EDB) ND 1 0.50 ug/L 05/11/2022 2142 1,2-Dichlorobenzene ND 1 0.50 ug/L 05/11/2022 2142 1,3-Dichlorobenzene ND 1 0.50 ug/L 05/11/2022 2142 1,4-Dichlorobenzene ND 1 0.50 ug/L 05/11/2022 2142 1,1-Dichloroethane ND 1 0.50 ug/L 05/11/2022 2142 1,2-Dichloroethane ND 1 0.50 ug/L 05/11/2022 2142 1,1-Dichloroethene ND 1 0.50 ug/L 05/11/2022 2142 cis- 1,2-Dichloroethene ND 1 0.50 ug/L 05/11/2022 2142 trans- 1,2-Dichloroethene ND 1 0.50 ug/L 05/11/2022 2142 1,2-Dichloropropane ND 1 0.50 ug/L 05/11/2022 2142 cis- 1,3-Dichloropropene ND 1 0.50 ug/L 05/11/2022 2142 trans- 1,3-Dichloropropene ND 1 0.50 ug/L 05/11/2022 2142 Methylene chloride ND 1 0.50 ug/L 05/11/2022 2142 1,1,2,2-Tetrachloroethane ND 1 0.50 ug/L 05/11/2022 2142 Tetrachloroethene ND 1 0.50 ug/L 05/11/2022 2142 1,1,1-Trichloroethane ND 1 0.50 ug/L 05/11/2022 2142 1,1,2-Trichloroethane ND 1 0.50 ug/L 05/11/2022 2142 Trichloroethene ND 1 0.50 ug/L 05/11/2022 2142 Trichlorofluoromethane ND 1 0.50 ug/L 05/11/2022 2142 Vinyl chloride ND 1 0.50 ug/L 05/11/2022 2142 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 101 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 14 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ41354-002 Matrix: Aqueous Batch:41354 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Bromodichloromethane 50 43 1 87 70-130 05/11/2022 2041 Bromoform 50 40 1 79 70-130 05/11/2022 2041 Bromomethane (Methyl bromide) 50 46 1 92 70-130 05/11/2022 2041 Carbon tetrachloride 50 42 1 84 70-130 05/11/2022 2041 Chlorobenzene 50 46 1 91 70-130 05/11/2022 2041 Chloroethane 50 47 1 94 70-130 05/11/2022 2041 Chloroform 50 45 1 90 70-130 05/11/2022 2041 Chloromethane (Methyl chloride) 50 50 1 100 60-140 05/11/2022 2041 Dibromochloromethane 50 42 1 84 70-130 05/11/2022 2041 1,2-Dibromoethane (EDB) 50 46 1 93 70-130 05/11/2022 2041 1,2-Dichlorobenzene 50 46 1 92 70-130 05/11/2022 2041 1,3-Dichlorobenzene 50 45 1 90 70-130 05/11/2022 2041 1,4-Dichlorobenzene 50 44 1 88 70-130 05/11/2022 2041 1,1-Dichloroethane 50 45 1 91 70-130 05/11/2022 2041 1,2-Dichloroethane 50 46 1 91 70-130 05/11/2022 2041 1,1-Dichloroethene 50 46 1 92 70-130 05/11/2022 2041 cis- 1,2-Dichloroethene 50 46 1 91 70-130 05/11/2022 2041 trans- 1,2-Dichloroethene 50 45 1 90 70-130 05/11/2022 2041 1,2-Dichloropropane 50 46 1 92 70-130 05/11/2022 2041 cis- 1,3-Dichloropropene 50 49 1 98 70-130 05/11/2022 2041 trans- 1,3-Dichloropropene 50 48 1 96 70-130 05/11/2022 2041 Methylene chloride 50 43 1 86 70-130 05/11/2022 2041 1,1,2,2-Tetrachloroethane 50 44 1 89 70-130 05/11/2022 2041 Tetrachloroethene 50 46 1 93 70-130 05/11/2022 2041 1,1,1-Trichloroethane 50 45 1 89 70-130 05/11/2022 2041 1,1,2-Trichloroethane 50 44 1 88 70-130 05/11/2022 2041 Trichloroethene 50 47 1 93 70-130 05/11/2022 2041 Trichlorofluoromethane 50 45 1 90 70-130 05/11/2022 2041 Vinyl chloride 50 46 1 93 70-130 05/11/2022 2041 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 85 70-130 1,2-Dichloroethane-d4 84 70-130 Toluene-d8 88 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 14 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 14 PACE ANALYTICAL SERVICES, LLC IMS v, i+Yr , WL= h1JC4 �T zMw r J�hRJ .. M y' 4 s t. •a ,�' T.] I F '1 2" 1 A M k E} 4 Q fi m q m x rj o-i d Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 14 PACE ANALYTICAL SERVICES, LLC Samples Receipt CherWisr01110(MJc0411sC-151 ac l5suingAuthurity:Poem, IENV-Wr.Ot Sample Receipt Checklist (-SR ) Cliun-:Ikh] CuaJcrlusccted2yj&lta: IM /04M.21P-'� LottXD2Wl4 MC irai ofrccelpt= Pacx -Clicnt U?5- Yrs l No ] . k4`are c,asrotiv seals rt:,2cnr an the 0001ar_' Ye9 NO J NA 2- 117Cusrody t?Qala wcm present woly dWy' i-ac-3nif unbrDkgri? ply Strip ID. rat. _ Chlorine Strip ID; w^ 1'f-.91ed b3; HA OdLdna'.�M'perature upon receipt! Derived (Carrc:cfcd) #empzratumT Uparl rer'tipt %SU]ic Sn ap-Cup IL): -.2 J1.2 PC f NA DC; NA (NA n� r A7 � NA t� t7,'thod: QTanperaturc Blaiik [�4gairls' BMLics Ik Oun fl): 5 ]R Giin Carreelion ]attcior: Mexlwd D'roolaia: Q V.'r-t ra Q Ice Par4s 0 22 lie Q N"': Ycx �No. L�2w]A 3. 1. tc-nFier.iturc 0= .aw rr�ulcr excee�leti (},Q°C, tv s Yrojact Trta-tagar Nurificd9 ]' was l+fnrili ed by. P111 r:e I emr_aii i faoe DD-fuc%- (rire:e oine). cs 14-P NA 4 Is the CojunOereial courier's puking slip zttached la Lhiy foynm?Ilicgible '{ No S. Wane prorwr castadv prtrDcdures (trim lislidIrcxreived) followed? Yes Na 6. Were sainpk IDS Jilted on The, C.00 f YCS Na 7, Mora Sam#le 1015 lisk:d an al l sfltrtple mijaine s') Yes, Na S. was col-irction date & time fisltxl on tlfe COC? . Ye-% No 9. Was eolltWon datetime'1E$Xd on aJ lsarrmplo colltiil1 icfr.57 ✓ YCA ❑ No I0. Uld a I] O tltacitar labc:. L-lfo-inm ion (ID: LLw, time) zgmo with the COC"j V 1 Ye5 ,Vo' 1, %Vei+e u1-1 ill, parFanTioJ Iisluci on the COC-� Rr_rised-9{29j2024 Nee 1 of 1 ,� T ' ❑ 12. Di d all JUJUPIes ar: ive in the proper corMitie rs for c ar•h ter# EMd/rw i„ goad cord_ti4n (rtnhlmkan, 11[l5 on, ctcj? ❑ Yes N{l 13. Wes adequate Caro :e vo]ullle uveiTsbla? Yo5 Np 14_ era all sarapkts rece"Ved wifhiu !6 the hak irlg amc or M 130UFS, ,VJmicheVW.COme8 rime? 'LE No 15_ Were auy ram les cantainers miasin • exocss {Ciruh: rxnel sar-iplc5 Not listed Qn C ? ❑Yes I f \ry NA 16. h'or VOA zmd RSK-175 sarnplos, were b-.f M w preGedt>"pra-rise'° N'or6u,Iri in diameler) In any a''Ihe VOA vh&s? g A°o J NA 17_ V4�ure 11 t 'm is{ntit lreceiw:d at a pl [ of� No ,F NA 1 F, Were all cyanide sartulsa received at a pT-1> I � ttnd sulfine sainplea received at,a pH 92 0 Yo5 ❑ � to FNA Wtre all aprkable h1H� 1lCtti,cus�h'cklp'�enal, a. ,6Qt_3 (� ,5m� samples frco of residual chlcrhie? ❑ Yes �Nu MNA 20. 'D ac]ientrensarks�gtlps rets{f,C_ rcga,s*,eddiluttors, MS;MSD desgrr� itians, ctr,,,j COrr,xtiy nna,i;rrribed food the COC into the cmm�lwnt ses,,l:ur. in LIMS? Yes No ? l , 4'as th uaoe -fufnb;,r l ra-ted ei l ffie couair r Jabel? If yc5, Qucrc nigl,Ie PresmNsition Wis5t bo omnplwed for any salrpla(5) ia'cmTectly pm%rved Or witt healik,aoe_) a�rrple(s} la� tvera receivc3 :uc0rt-zt.tly preserved and v�ere adjusted C{xsiingly in sample rc:,civillg Witlm NA m L of oircic ave: i -50q, HNO3, HC Nac7FI using SR g r'' of preservation ?� 1f rnom than on a prWw-- 4 w is aeedrd, please neln ir. the eatnmattrs helovw. Sajnpla•(s) NA -w= received with bubbles >6 mm in diEnie&r_ pler{Z) RA were received with TRC > O..S In};L (if 19 isup) and wire adjus t dCcos,di"in Sar_la]a receiving, with sgdium dl10suIfalr (1 EIIL;, 3) with Shealy ID- NA R J3:,.AAc lahek applied by_ TEC per 4lnlij{' ifs. - Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 14 Report of Analysis ERM NC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Michael Pressley Project Name: Toastmaster Lot Number:XJ07015 Date Completed:10/24/2022 10/24/2022 11:50 AM Approved and released by: Project Manager II: Edward Barnett �q RCCAA16 2W _ Am fiafkeWAcsrediHngr &WO A C C A E O[ Y E d iESTIHG LABOft4TOPY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 14 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM NC, Inc. Lot Number: XJ07015 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 14 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM NC, Inc. Lot Number: XJ07015 Sample Number Sample ID Matrix Date Sampled Date Received 001 INF-1-IN Aqueous 10/05/20221045 10/06/2022 002 EFF-2-EF Aqueous 10/05/20221045 10/06/2022 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 14 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM NC, Inc. Lot Number: XJ07015 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 INF-1-IN Aqueous Chloromethane (Methyl 8260D 1.3 ug/L 6 001 INF-1-IN Aqueous cis- 1,2-Dichloroethene 8260D 7.0 ug/L 6 001 INF-1-IN Aqueous Trichloroethene 8260D 140 ug/L 6 002 EFF-2-EF Aqueous Chloromethane (Methyl 8260D 1.1 ug/L 8 002 EFF-2-EF Aqueous cis- 1,2-Dichloroethene 8260D 1.7 ug/L 8 (5 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XJ07015-001 Description: INF-1-IN Matrix: Aqueous Date Sampled:10/05/2022 1045 Date Received:10/06/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 10/12/2022 1409 KKP 56840 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@20.5°C SM 4500-H B-20 6.2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 5 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XJ07015-001 Description: INF-1-IN Matrix: Aqueous Date Sampled:10/05/2022 1045 Date Received:10/06/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/17/20221400 BBW 57254 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 1.3 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 7.0 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 140 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 83 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 90 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XJ07015-002 Description: EFF-2-EF Matrix: Aqueous Date Sampled:10/05/2022 1045 Date Received:10/06/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 10/12/2022 1326 KKP 56840 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@19.7°C SM 4500-H B-20 6.3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 7 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XJ07015-002 Description: EFF-2-EF Matrix: Aqueous Date Sampled:10/05/2022 1045 Date Received:10/06/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/17/20221424 BBW 57254 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 1.1 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.7 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D ND 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 14 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 14 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ57254-001 Matrix: Aqueous Batch: 57254 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ Units Analysis Date Bromodichloromethane ND 1 0.50 ug/L 10/17/2022 1042 Bromoform ND 1 0.50 ug/L 10/17/2022 1042 Bromomethane (Methyl bromide) ND 1 0.50 ug/L 10/17/2022 1042 Carbon tetrachloride ND 1 0.50 ug/L 10/17/2022 1042 Chlorobenzene ND 1 0.50 ug/L 10/17/2022 1042 Chloroethane ND 1 0.50 ug/L 10/17/2022 1042 Chloroform ND 1 0.50 ug/L 10/17/2022 1042 Chloromethane (Methyl chloride) ND 1 0.50 ug/L 10/17/2022 1042 Dibromochloromethane ND 1 0.50 ug/L 10/17/2022 1042 1,2-Dibromoethane (EDB) ND 1 0.50 ug/L 10/17/2022 1042 1,2-Dichlorobenzene ND 1 0.50 ug/L 10/17/2022 1042 1,3-Dichlorobenzene ND 1 0.50 ug/L 10/17/2022 1042 1,4-Dichlorobenzene ND 1 0.50 ug/L 10/17/2022 1042 1,1-Dichloroethane ND 1 0.50 ug/L 10/17/2022 1042 1,2-Dichloroethane ND 1 0.50 ug/L 10/17/2022 1042 1,1-Dichloroethene ND 1 0.50 ug/L 10/17/2022 1042 cis- 1,2-Dichloroethene ND 1 0.50 ug/L 10/17/2022 1042 trans- 1,2-Dichloroethene ND 1 0.50 ug/L 10/17/2022 1042 1,2-Dichloropropane ND 1 0.50 ug/L 10/17/2022 1042 cis- 1,3-Dichloropropene ND 1 0.50 ug/L 10/17/2022 1042 trans- 1,3-Dichloropropene ND 1 0.50 ug/L 10/17/2022 1042 Methylene chloride ND 1 0.50 ug/L 10/17/2022 1042 1,1,2,2-Tetrachloroethane ND 1 0.50 ug/L 10/17/2022 1042 Tetrachloroethene ND 1 0.50 ug/L 10/17/2022 1042 1,1,1-Trichloroethane ND 1 0.50 ug/L 10/17/2022 1042 1,1,2-Trichloroethane ND 1 0.50 ug/L 10/17/2022 1042 Trichloroethene ND 1 0.50 ug/L 10/17/2022 1042 Trichlorofluoromethane ND 1 0.50 ug/L 10/17/2022 1042 Vinyl chloride ND 1 0.50 ug/L 10/17/2022 1042 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 14 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ57254-002 Matrix: Aqueous Batch: 57254 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Bromodichloromethane 50 52 1 104 70-130 10/17/2022 0927 Bromoform 50 45 1 89 70-130 10/17/2022 0927 Bromomethane (Methyl bromide) 50 60 1 121 70-130 10/17/2022 0927 Carbon tetrachloride 50 53 1 106 70-130 10/17/2022 0927 Chlorobenzene 50 49 1 99 70-130 10/17/2022 0927 Chloroethane 50 57 1 114 70-130 10/17/2022 0927 Chloroform 50 51 1 101 70-130 10/17/2022 0927 Chloromethane (Methyl chloride) 50 58 1 117 60-140 10/17/2022 0927 Dibromochloromethane 50 52 1 104 70-130 10/17/2022 0927 1,2-Dibromoethane (EDB) 50 52 1 104 70-130 10/17/2022 0927 1,2-Dichlorobenzene 50 50 1 100 70-130 10/17/2022 0927 1,3-Dichlorobenzene 50 49 1 98 70-130 10/17/2022 0927 1,4-Dichlorobenzene 50 48 1 95 70-130 10/17/2022 0927 1,1-Dichloroethane 50 53 1 105 70-130 10/17/2022 0927 1,2-Dichloroethane 50 54 1 109 70-130 10/17/2022 0927 1,1-Dichloroethene 50 52 1 104 70-130 10/17/2022 0927 cis- 1,2-Dichloroethene 50 50 1 101 70-130 10/17/2022 0927 trans- 1,2-Dichloroethene 50 51 1 102 70-130 10/17/2022 0927 1,2-Dichloropropane 50 53 1 106 70-130 10/17/2022 0927 cis- 1,3-Dichloropropene 50 56 1 112 70-130 10/17/2022 0927 trans- 1,3-Dichloropropene 50 56 1 111 70-130 10/17/2022 0927 Methylene chloride 50 53 1 106 70-130 10/17/2022 0927 1,1,2,2-Tetrachloroethane 50 56 1 111 70-130 10/17/2022 0927 Tetrachloroethene 50 47 1 95 70-130 10/17/2022 0927 1,1,1-Trichloroethane 50 53 1 105 70-130 10/17/2022 0927 1,1,2-Trichloroethane 50 52 1 104 70-130 10/17/2022 0927 Trichloroethene 50 49 1 97 70-130 10/17/2022 0927 Trichlorofluoromethane 50 57 1 114 70-130 10/17/2022 0927 Vinyl chloride 50 59 1 119 70-130 10/17/2022 0927 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 110 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 14 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 14 PACE ANALYTICAL SERVICES, LLC LL ' c 7� L L � M F. O 03 . 1� Z 1 R L@ � �nr sns AM !� ti 4 ' y 5 5 M rs u x w a b 2 o- It Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 14 PACE ANALYTICAL SERVICES, LLC DLL i 6e: ENV-FRf4M-WC4L-07.86vL12-Sompies IZecQ'pt C�eckrrst (SP.c) Effective Date: 8f2f 202Z Sample Receipt C keckjist (SRC) Clime f FM - COVIM lT!291 cc[ed bvfdatc: I, 10: 7r2t1' Lot q ?i715 Mr— TVY LS NQ [ . Welt �ST13[ly 5CAlS pi�SErit oil the coolel.? yes ill} NA 2. if ciLSt0ti sL�alS 'NCl c 2Se1ll, luck they iatt l anal lmkak y? , smp ID., TP's cbhxiae Sttsp ILA; Ifh rcued by, NIL Origilaal 1rlry7 MtUe Up ll lfti }r ! De iv d ,Cl r'L'TCd) ica3Epernt'3re uraII rs rcipt °l5irlirJ 51fap-C ula ID:2,4 ++2.4 t(1 NA + NA 0C� NFA f NA 3C NA !Nix o� NA M�tibo�: QTerl�lxranl> #�aul:[J SrBcrltlLs l Ou1� ID: _ TR Cuu Con'Wi l FHtif1r Virrhod of coottiu[: Wet Ice lcc Fick DrY Tce i�* ��� � �� � 3, �Jer� �vode�s rcocp�ed at rnbelcr��u 6.0°C7 uo, vas 1'ra,�ect It'lallzr�crncti�crlF P 0 was Notiftod by- phouw; ! Omit l i <Ke-to-faw. {cure eH,R-). . Yes x+io N•%. 4. rs the cOni7riCmW MAW pm1dqg slip arlxleJ,ltd ro This r'on j +J Yes N ,, Well •Uf7c'F custodyproccdllres (1e1rllel111--rJrccVkviceivcxl) followed'! + ' s No VkrCrsaulpiclDs lisrcd oil the COC and all saniple L nraium. , 'es No ?. iVas ivv[Icctjon date & t ige Ned atr the CQC aZ 11 &ll4le caltlailaers7 . Ycs lYa 8_ laid all contain-1 JK1 iufvrntian mil_ dat�C. tilnc) a�ee i[lr tic l [ Yen No 9_ wLtr- tn13 [o be p7r' ml d listed Orr rile Coo? E I No 10. D'(1 Ali s3,lnpfCS aariVC irl the Prx11s T CblltAifielS fir cash test it Our in ri lad �a Ation LJ (lu>Uraleelr. Lids oo>, etc,)7 Yes NO 11. MIS adcgmk =ii plc vuhum ab'al]Iableg, Yes No l R'ere 211 saWks rvceived lViTIDI) ; t11e 1laldin Ilium or48 h ils, '.vWchewr c{3ul<r� &rsC7 ZYes E]No 13_ Wcrean sat17ples coll#8iircrs accollilted Ayr'l (>10rni55111 Q Yes El No DNA 14, W VOA. 8015C {ttui 1{ _175 saalpin er" of €al[3hles crianrerer) it: anvof the VDA vials? Yes 1No , r1 is_ urge all DDRQ&u>etAlsluutme-ni w eS received at a pH or-r 2? Yes 34u r 3rit11 saelJtes rccekmdar a iH > I alul -%I I deUPICS rcccived nr a pH {r } OYes ONO 17.1 [re stt app svlc Ii TK11Uc]altlr r}i ObG .ii {IS,3 { 0_Sln .)a; Jcs#rec of r� Ta N� residaal! cllloriiie? 11Y41 Or" EI NA I R. Was the quote nuallbu fisted ou the :arErp hXT IRW? ]f)'es, Qr,ote j iorrgplc l�laC cl'aarti�ru (lwi-lst be ccllupletedfor• any sausple(s', iucorrecflyprMeL-ktd or with hCa Race.) i,anlplc(s) t vkle feeel'ved imCoM41yprrstL ved anus wcte ad�zas'er[ accor:3.1 rr smrlple rtcoivitxg with _1ylL cf circic one: H2�{j, HIN-03, HCJ, rN[aOH j1gi11g R #? NA J iIIl>r ofpie5l:r atiorl lftlwre t$31L WIC plts val ivr is ueedtd,please WC ill tllc colniMil:s irel€ow. anlplo(s) lea �Wem Mewed with bllbblcs >6 rnm ] i diaru[tet, sau;p]es(s) x�� _ v�cfe trceirer� vi#h 'i'�C ? 0.51ri�L t,If �1 S ES uo) 1111d R'rrt ijnstad accoidin�lyxu s�nt�ii:lt�ciwing >.��t11 �odiir]ll tliitxslaff2atc ;Na�S�O�} w7t]1 Liai[llrc ill: �n Coup tlenrs� ua[#rax 1 = 56360 Pam" Arialytical sarvkes, LLC Page Iof4 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 14 Report of Analysis ERM NC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Michael Pressley Project Name: Toastmaster Lot Number:XL16013 Date Completed:12/21/2022 12/22/2022 7:06 AM Approved and released by: Project Manager II: Edward Barnett �q RCCAA16 2W _ Am fiafkeWAcsrediHngr &WO A C C A E O[ Y E d iESTIHG LABOft4TOPY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 14 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM NC, Inc. Lot Number: XL16013 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 14 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM NC, Inc. Lot Number: XL16013 Sample Number Sample ID Matrix Date Sampled Date Received 001 INF-1 Aqueous 12/15/2022 0945 12/16/2022 002 EFF-2 Aqueous 12/15/2022 0945 12/16/2022 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 14 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM NC, Inc. Lot Number: XL16013 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 INF-1 Aqueous cis- 1,2-Dichloroethene 8260D 8.1 ug/L 6 001 INF-1 Aqueous Tetrachloroethene 8260D 0.95 ug/L 6 001 INF-1 Aqueous Trichloroethene 8260D 170 ug/L 6 002 EFF-2 Aqueous cis- 1,2-Dichloroethene 8260D 2.7 ug/L 8 002 EFF-2 Aqueous Trichloroethene 8260D 0.71 ug/L 8 (5 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XL16013-001 Description: INF-1 Matrix: Aqueous Date Sampled:12/15/2022 0945 Date Received:12/16/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 12/21/2022 1245 JJM 63372 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@11.7°C SM 4500-H B-20 5.8 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 5 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XL16013-001 Description: INF-1 Matrix: Aqueous Date Sampled:12/15/2022 0945 Date Received:12/16/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 12/20/20221628 CDA 63242 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 8.1 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.95 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 170 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 93 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 14 Inorganic non-metals Client:ERM NC, Inc. Laboratory ID:XL16013-002 Description: EFF-2 Matrix: Aqueous Date Sampled:12/15/2022 0945 Date Received:12/16/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (pH) SM 4500-H B-2011 1 12/21/2022 1253 JJM 63372 CAS Analytical Parameter Number Method Result Q LOQ Units Run pH@11.9°C SM 4500-H B-20 6.4 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com su 1 Q = Surrogate failure L = LCS/LCSD failure S = MS/MSD failure Page 7 of 14 Volatile Organic Compounds by GC/MS Client:ERM NC, Inc. Laboratory ID:XL16013-002 Description: EFF-2 Matrix: Aqueous Date Sampled:12/15/2022 0945 Date Received:12/16/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 12/20/20221652 CDA 63242 CAS Analytical Parameter Number Method Result Q LOQ Units Run Bromodichloromethane 75-27-4 8260D ND 0.50 ug/L 1 Bromoform 75-25-2 8260D ND 0.50 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 0.50 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.50 ug/L 1 Chlorobenzene 108-90-7 8260D ND 0.50 ug/L 1 Chloroethane 75-00-3 8260D ND 0.50 ug/L 1 Chloroform 67-66-3 8260D ND 0.50 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 0.50 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 0.50 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 0.50 ug/L 1 1,3-Dichlorobenzene 541-73-1 8260D ND 0.50 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 0.50 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 0.50 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.50 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.50 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 2.7 0.50 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 0.50 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 0.50 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 0.50 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 0.50 ug/L 1 Methylene chloride 75-09-2 8260D ND 0.50 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 0.50 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 0.50 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 0.50 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 0.50 ug/L 1 Trichloroethene 79-01-6 8260D 0.71 0.50 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 0.50 ug/L 1 Vinyl chloride 75-01-4 8260D ND 0.50 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 91 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure NO = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 14 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 14 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ63242-001 Matrix: Aqueous Batch: 63242 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ Units Analysis Date Bromodichloromethane ND 1 0.50 ug/L 12/20/2022 1210 Bromoform ND 1 0.50 ug/L 12/20/2022 1210 Bromomethane (Methyl bromide) ND 1 0.50 ug/L 12/20/2022 1210 Carbon tetrachloride ND 1 0.50 ug/L 12/20/2022 1210 Chlorobenzene ND 1 0.50 ug/L 12/20/2022 1210 Chloroethane ND 1 0.50 ug/L 12/20/2022 1210 Chloroform ND 1 0.50 ug/L 12/20/2022 1210 Chloromethane (Methyl chloride) ND 1 0.50 ug/L 12/20/2022 1210 Dibromochloromethane ND 1 0.50 ug/L 12/20/2022 1210 1,2-Dibromoethane (EDB) ND 1 0.50 ug/L 12/20/2022 1210 1,2-Dichlorobenzene ND 1 0.50 ug/L 12/20/2022 1210 1,3-Dichlorobenzene ND 1 0.50 ug/L 12/20/2022 1210 1,4-Dichlorobenzene ND 1 0.50 ug/L 12/20/2022 1210 1,1-Dichloroethane ND 1 0.50 ug/L 12/20/2022 1210 1,2-Dichloroethane ND 1 0.50 ug/L 12/20/2022 1210 1,1-Dichloroethene ND 1 0.50 ug/L 12/20/2022 1210 cis- 1,2-Dichloroethene ND 1 0.50 ug/L 12/20/2022 1210 trans- 1,2-Dichloroethene ND 1 0.50 ug/L 12/20/2022 1210 1,2-Dichloropropane ND 1 0.50 ug/L 12/20/2022 1210 cis- 1,3-Dichloropropene ND 1 0.50 ug/L 12/20/2022 1210 trans- 1,3-Dichloropropene ND 1 0.50 ug/L 12/20/2022 1210 Methylene chloride ND 1 0.50 ug/L 12/20/2022 1210 1,1,2,2-Tetrachloroethane ND 1 0.50 ug/L 12/20/2022 1210 Tetrachloroethene ND 1 0.50 ug/L 12/20/2022 1210 1,1,1-Trichloroethane ND 1 0.50 ug/L 12/20/2022 1210 1,1,2-Trichloroethane ND 1 0.50 ug/L 12/20/2022 1210 Trichloroethene ND 1 0.50 ug/L 12/20/2022 1210 Trichlorofluoromethane ND 1 0.50 ug/L 12/20/2022 1210 Vinyl chloride ND 1 0.50 ug/L 12/20/2022 1210 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 92 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 14 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ63242-002 Matrix: Aqueous Batch: 63242 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Bromodichloromethane 50 49 1 98 70-130 12/20/2022 1028 Bromoform 50 55 1 110 70-130 12/20/2022 1028 Bromomethane (Methyl bromide) 50 58 1 115 70-130 12/20/2022 1028 Carbon tetrachloride 50 46 1 91 70-130 12/20/2022 1028 Chlorobenzene 50 49 1 99 70-130 12/20/2022 1028 Chloroethane 50 51 1 101 70-130 12/20/2022 1028 Chloroform 50 42 1 83 70-130 12/20/2022 1028 Chloromethane (Methyl chloride) 50 54 1 108 60-140 12/20/2022 1028 Dibromochloromethane 50 56 1 111 70-130 12/20/2022 1028 1,2-Dibromoethane (EDB) 50 52 1 104 70-130 12/20/2022 1028 1,2-Dichlorobenzene 50 51 1 102 70-130 12/20/2022 1028 1,3-Dichlorobenzene 50 51 1 103 70-130 12/20/2022 1028 1,4-Dichlorobenzene 50 48 1 96 70-130 12/20/2022 1028 1,1-Dichloroethane 50 41 1 83 70-130 12/20/2022 1028 1,2-Dichloroethane 50 44 1 89 70-130 12/20/2022 1028 1,1-Dichloroethene 50 43 1 86 70-130 12/20/2022 1028 cis- 1,2-Dichloroethene 50 46 1 93 70-130 12/20/2022 1028 trans- 1,2-Dichloroethene 50 46 1 92 70-130 12/20/2022 1028 1,2-Dichloropropane 50 46 1 92 70-130 12/20/2022 1028 cis- 1,3-Dichloropropene 50 53 1 106 70-130 12/20/2022 1028 trans- 1,3-Dichloropropene 50 44 1 88 70-130 12/20/2022 1028 Methylene chloride 50 40 1 79 70-130 12/20/2022 1028 1,1,2,2-Tetrachloroethane 50 48 1 95 70-130 12/20/2022 1028 Tetrachloroethene 50 54 1 108 70-130 12/20/2022 1028 1,1,1-Trichloroethane 50 43 1 86 70-130 12/20/2022 1028 1,1,2-Trichloroethane 50 49 1 97 70-130 12/20/2022 1028 Trichloroethene 50 51 1 103 70-130 12/20/2022 1028 Trichlorofluoromethane 50 52 1 104 70-130 12/20/2022 1028 Vinyl chloride 50 57 1 113 70-130 12/20/2022 1028 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 83 70-130 Toluene-d8 86 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 14 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 14 PACE ANALYTICAL SERVICES, LLC g � J t� L1 W .!2 E 4 U 1 ? 99 L] U J a c z LU 13, CL ep O A, - ID Ia as Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 14 PACE ANALYTICAL SERVICES, LLC DGIf Title: ENV-FRPA-VOOOL-0286vO7_SamO en Rec-ffiO C heahat ISM i EfifeWve Date: 8/21202-2 ' Sample. Receipt bec.00 ($ ) Clienr. FRM Con ler ]rL"P ULC6 W, date- LIA I- Means ofteceipt: Pace Chen[ :777 ,-7 I F- Ex t�tErer _ — ,/ y rs NO 1. Wclt cwTndy acals toll tUe caok& VJ yes Nc 7+fA 2, )fens 5ertls sac rcge�ti- wire U uitacr and twbml:m? l-I S1rip M- NA Cliloa_`itHe snit it}_ Tested by:NA — _ ot,igi" ft'R7peratwr upw reccipt 1 DcnVed (Conte ted) 1k3%Km ttt1tO- IVR I=CV ° Soiid S ,.Cup ID, NA i . ? 7 12.1 0C NA f 2 A uC MA ! NA oC Pie) f WA °C #lid r n rsali,� Rlatrlr �A tist t B tl�es Ili Gait �D' r w -Gun Urredol Fw r ° c111-orl ofcoolam- Wept ice 1cr hacks Ury Ice Noel: � 5'cs [itio 3-Were a1T a%D�lci-s received INor bclaw �,,Q°�7 'no, was )?iojttt T�laP vas Rabid br^ ph-aue f cumil r face-to-face fcirck ). KL]NA 4- is the c n=itld cowicCs pwkvtg sl>pOM'c red to this fDMI I'llyes No5- Wetr pL%er cr,stod}�pmedmcs Ceelhi. W5hed+n-ecived'� fallanved",I Yes 1496, W sat? It Ms listed nit the OOC a11d all saanp]e corm Gera? ycs No[ 7, Was Collection iftte & tilue Wsled on the COO SPA all smy'I'le C0ltlai:it¢s? � No S. Lid a]I cailx� label infbri3iatioui (ID, dale, Jwith Eire C0C? I Y CS j I [1 9. WC1T tests to be purfeluied IM-' 1 on %t C4C? � Qi�ts �htif 10. Did all sainpacs arrive in ,1Le propm CoWff u-n-j fk!r e-01 lest andior in goad cgtstdi ton (t<U WDl mi, lids Lim. etcX1 _ I d Yes No 111. Was at apa[t: bffiWle volume avai.iab]O � Y# , No ].2. CrC all s3utples 1eCei%red wkhin'r2 die JoJd1 ^ t,nic Dr U luatIVs. u�luclie�ver Cctrs fif l? i ,❑Yes E]N 13. Mere al-L samples cc'ntairi= accokwted tor? (No irus3 e�e�s� 05ies L]Na ❑mlk 14- Wmt t: VOA, 8015C mid 75 samples free of Inibblcs >"pea -sip" C./--or 6unu ill diani w) in goy of fbc VOA vilils? 4`cs No —[, A 15. 'Were all DRXtucMh:A uTrient sanigAes receKmd at. a pE of < 2? Ycs No ,/ A 16. Wcrc all cMiide s . 1es rccchrcd al a PH > 12 Md Sulffik Samples ieoei-ved at R JH > 99ZI1qj DN° �` 17. CfC uppllcable NH 1 kG-Ktcyantdelp eno I 5.1 0.51 4 Q 5,-M } c: fx cx Of �'r� residua]. CI1IDrale"7 I I& Was the quatc unrubef liste-d on the coulauxtf Ukl' If yes, Qw1t; 4 i _ I �tn�plePre�ei��alliolp{?+rlus[6�conlpletextfnrattysaivpie�s�i[1rcxrccFlypr�se�'�edorwit111ua[dsp�ee-) Sau,plefs) 1�crc rcceived incofrccilyprmcrved rued weie ndjlislcd auuwi1u ly atsanrpLe iacci� ng with al>. Dfcirtlt one' IMSW, 11NM, EEL NaOM iWng SR to �. 1 Frn A _ >=E'ur Ar,111ail Line prt-ctrvali is nccd4d, Please Hole 1i1 the canut tl5 belo W. It le{3} NA Were lecciwd wh Nibbles 76Aria its. diameter, ' Sanipies(s; wA wait receiver) wit'1RC > 0.5 wwt (11#19 is pro) aad vim adjusted amordiiieyia samplt raxiv4 with sodiut:l tllliosulAte CNkSzOO •,� 6 L1 irltte I ll= NA rulkimmil3, Nattrax [D: Pace'' of I Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 14 ERM has over 160 offices across the following countries and territories worldwide Argentina New Zealand ERM NC, Inc. Australia Panama 300 West Summit Ave Belgium Peru Suite 330 Brazil Poland Charlotte, NC 28203 Canada Portugal T:704-541-8345 China Puerto Rico F: 704-624-7928 Colombia Romania France Russia www.erm.com Germany Singapore Hong Kong South Africa Hungary South Korea India Spain Indonesia Sweden Ireland Taiwan Italy Thailand Japan UAE Kazakhstan UK Kenya US Malaysia Vietnam Mexico The Netherlands The business of sustainability ERM