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HomeMy WebLinkAboutNC0025071_Wasteload Allocation_19920520NPDES WASTE LOAD ALLOCATION PERMIT NO,: NCO025071 PERMITTEE NAME: City of Eden FACILITY NAME: Mebane Bridge W WTP Facility Status: Existing Permit Status: Renewal Major -4 Minor Pipe No.: 001 Design Capacity: 13.5 MGD Domestic (% of Flow): Industrial (% of Flow): 29.2 % Comments: plant expanded from 7.0 MGD RECEIVING STREAM: Dan River Class: C Sub -Basin: 03-02-03 Reference USGS Quad: B20NW (please attach) County: Rockingham Regional Office: Winston-Salem Regional Office Previous Exp. Date: 2/28/92 Treatment Plant Class: IV Classification changes within three miles: None within 3 miles. PLOTTED Requested by. Rosanne Barona Date: 10/7/91 Prepared by: Date: `�r[p Reviewed by: f tG. >✓' Date: rbh �OA t+� 4o21S / as—_ ti1�1�f— / Modeler Date Rec. # 1J t nv r, Drainage Area (mil ) 1? oo Avg. Streamflow (cfs): 1 L 7Z + 7Q10 (cfs) Winter 7Q10 (cfs) 57 30Q2 (cfs) %¢ Toxicity Limits: IWC `- % Acute/( E if Downstream Location: NCSR 1964 bridge Downstream Location: NCSR 700 bridge Parameters: DO, Temp, Fecal Coliform, Conductivity, PH - - Three times a week (June, July, August and September), once a _ week during the rest of the year. Upstream Location: Downstream Location: Parameters: Above Eden Water Supply Intake on Smith River NC Hwy 87 bridge NCSR 1761 bridge (individual samples on transect at 114, 1/2 and 3/4 of the distance across the river). Color, pH Monthly Average Summer Winter Wastetlow (MGD): 13.5 13.5 BOD5 (mg/1): 30 30 NH3N (mg/1): 12.7 monitor DO (mgft monitor monitor TSS (mg/1): 30 30 Fecal Col. V100 in]): 200 200 PH (SU): 6.0-9.0 6.0-9.0 Residual Chlorine (µg/1): 28 28 Oil & Grease (mgll): TP (mg/l): monitor monitor TN (mg/1): monitor monitor Daily Max Daily Max Color (ADMI): 4 4,8.,to W300 Cadmium (µg/1): monitor monitor Chromium (µg/l): monitor monitor Copper (µg/1): monitor monitor Nickel (µg/l): monitor monitor Lead (µg/1): 399 399 Zinc (µg/l): monitor monitor Cyanide (µg/l): 78 78 Phenols (µg/1): monitor monitor Mercury (µg/1): 0.191 0.191 Silver (µg/1): monitor monitor Comments: Facility should coordinate monitoring efforts at the NC 700 bridge with Fieldcrest Cannon so as not to duplicate data. RECEIVED N.C. Dept. NRCD Facility Name: NPDES No.: Type of Waste: Facility Status: Permit Status: Receiving Stream: Stream Classification: Subbasin: County: Regional Office: Requestor: Date of Request: Topo Quad: FACT SHEET FOR WASTELOAD ALLOCATION Request # 6470 City of Eden --Mebane Bridge W WTP NCO025071 70.8% Domestic, 29.2% Industrial Existing Renewal Dan River C 03-02-03 Rockingham Stream Characteristic: Winston-Salem Regional Office USGS # Rosanne Barona Date: 10/8/91 Drainage Area (mi2): B20NW Summer 7Q10 (cfs): Wasteload Allocation Summary (approach taken, correspondence with region, EPA, etc.) Renewal of NPDES permit at existing levels. Schedule Requirepents and Winter 7Q10 (cfs): Average Flow, (cfs): 30Q2 (cfs): I�VC (%): = DEC 16 1991 Winston-Salem Regional Office 1700 313 578 1620 704 6 �' b us _sue C_ x = �� _ �, Recommended by: r(k ��x .ti, C �� -c Date: 12 3 • g r °a Reviewed by 12- 13 I � I rc / re Slob/r'ui� i Instream Assessment: rti [' � n i4 � Date: L LJ C.1 C), Regional Supervisor: Date: Permits & Engineering: t Date: RETURN TO TECHNICAL SERVICES BY: 1+I 1T(5 9 -2— 2 Existing Limits: Wasteflow (MGD): BOD5 (mg/1): NH3N (mg/1): DO (mg/1): TSS (mg/1). Fecal Col. (/100 ml): pH (SU): Residual Chlorine (µg/1): Oil & Grease (mg/1): TP (mg/1): TN (mg/1): Recommended Limits: Wasteflow (MGD): BOD5 (mg/1): NH3N (mg/1): DO (mg/1): TSS (mg/1): Fecal Col. 000 ml): pH (SU): Residual Chlorine (µg/l): Oil & Grease (mg/1): TP (mg/1): TN (mg/1): CONVENTIONAL PARAMETERS Monthly Average Summer Winter 13.5 13.5 30 30 12.7 monitor monitor monitor 30 30 200 200 6.0-9.0 6.0-9.0 28 28 monitor monitor monitor monitor Monthly Average Summer Winter 13.5 13.5 30 30 12.7 monitor monitor monitor 30 30 200 200 6.0-9.0 6.0-9.0 28 28 monitor monitor monitor monitor Limits Changes Due To: Change in 7Q10 data Change in stream classification Relocation of discharge Change in wasteflow Other (onsite toxicity study, interaction, etc.) Instream data New regulations/standards/procedures New facility information WQ or EL EL WQ EL EL EL WQ Parameters) Affected (explanation of any modifications to past modeling analysis including new flows, rates, field data, interacting discharges) (See page 4 for miscellaneous and special conditions, if applicable) 3 TOMCS/METALS Type of Toxicity Test: Chronic Toxicity Pass/Fail (Ceriodaphina) Existing Limit: 6% Recommended Limit: 6% Monitoring Schedule: Feb, May, Aug, Nov Existing Limits Daily Max. Color (ADW: 300 Cadmium (µg/1): monitor Chromium (µg/1): monitor Copper (µg/1): monitor Nickel (µg/1): monitor Lead (µg/1): 399 Zinc (µg/1): monitor Cyanide (µg/1): 78 Phenols (µg/l): monitor Mercury (µg/1): 0.191 Silver (µg/1): monitor Recommended Limits Daily Max. WQ or EL Color (ADMI): a.L40 WQ Cadmium (µg/1): monitor Chromium (41): monitor Copper (µg/l): monitor Nickel (µg/1): monitor Lead (µg/1): 399 WQ Zinc (4g)1): monitor Cyanide (µg/l): 78 WQ Phenols (µg/1): monitor Mercury (µg/1): 0.191 WQ Silver (µg/1): monitor Limits Changes Due To: Parameter(s) Affected Change in 7Q10 data Change in stream classification Relocation of discharge Change in wasteflow New pretreatment information Failing toxicity test C016y lihti�+ Cb1j6idjr6 Inkr&II brc W ice'Other (onsite toxicity study, interaction, etc.) NeW ��-10 d qAw yocl an a pY y CYPet�, and 9 � vw X Parameter(s) are water quality limited. For some parameters, the available load capacity of �" ,-Att I;m the immediate receiving water will be consumed. This may affect future water quality based effluent limitations for additional dischargers within this portion of the watershed. •s No parameters are water quality limited, but this discharge may affect future allocations. INSTREAM MONITORING REQUIREMENTS Upstream Location: NCSR 1964 bridge Downstream Location: NCSR 700 bridge Parameters: DO, Temp, Fecal Coliform, Conductivity, pH Special instream monitoring locations or monitoring frequencies: Three times a week (June, July, August and September), once a week during the rest of the year. FaGy� Should ewrd;naie monibrj'mj eAror(3 luCwead?Ce wig �ie/dcrPsf C'anoost - SoaS not lv pupli A -be cicc Upstream Location: Above Eden Water Supply Intake on Smith River Downstream Location: NC Hwy 87 bridge NCSR 1761 bridge (individual samples on transect at 1/4, 1/2 and 3/4 of the distance across the river). Parameters: Color, pH MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS Adequacy of Existing Treatment Has the facility demonstrated the ability to meet the proposed new limits with existing treatment facilities? Yes No ✓ If no, which parameters cannot be met? �o�i� il�,: �✓ �.i�iY,h.. i Would a "phasing in" of the new limits be appropriate? Yes .,/ No If yes, please provide a schedule (and basis for that schedule) with the regional office recommendations: If no, why not? Special Instructions or Conditions Wasteload sent to EPA? (Major) _ (Y or N) (If yes, then attach schematic, toxics spreadsheet, copy of model, or, if not modeled, then old assumptions that were made, and description of how it fits into basinwide plan) Additional Information attached? + (Y or N) If yes, explain with attachments. • Facility Name ��N i Q�r� ��c —Perrriit4A05671 Pipe # ma CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in: 1.) The North Carolina Ceriodaphnia chronic effluent bioassay procedure (North Carolina Chronic Bioassay Procedure - Revised *September 1989) or subsequent versions. The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is --�—To (defined as treatment two in the North Carolina procedure document). The permit holder shall perform r r monitoring using this procedure to establish compliance with the permit condition. The first test will be rrmg after thirty from the effective date of this permit during the months of au A" w B ✓ . Effluent sampling for this testing shall be performed at the NPDES pernutted al effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. 7Q 10 31 "b cfs Permitted Flow 3. S MGD IWC e. % Basin&Sub-basin o3-oz-4p3 Receiving ream r)e v+ a e—Ir- County f �o�cvhal,4w�- Date _/L /�(• 9i QCL PIF Version 9191 DIVISION OF ENVIRONMENTAL MANAGEMENT Recommendations for Color Monitoring Per 15 A NCAC 2B.0211(b)3(F) for colored wastes, the permittee shall discharge only such amounts as will not render the waters injurious to public health, secondary recreation, or aquatic life and wildlife or adversely affect the palatability of fish, aesthetic quality or impair the waters for any designated uses. For the purpose of measuring compliance with this requirement, the permittee shall perform the following: Within 120 days of the effective date of this permit, the permittee shall begin monitoring for color at the Effluent, Upstream, and Downstream at designated sites (see part I.A.). The samples shall be analyzed using the Spectrophotometric Method (2120 C.) in the 17th edition of Standard Methods. The calculations must be done using the weighted ordinance method. The test should be performed using a spectropho- tometer with a 2.0 nanometer (ran) band pass and 50 millimeter cell path. The operating range should begin at 400 nm and end at 700 nm (using 10 nm intervals) and measure transmittance values at 31 wavelengths. The results shall be calculated and reported in ADMI color units from the information indicated (see reference below for worksheets and examples for calculation of ADMI values). Analyze samples free from turbidity or at "true color" through the filtration method using a .45 micron filter (centrifugation is not necessary). Samples shall be collected on 3 consecutive days (between Tuesday and Friday) during each month for twelve months following permit issuance, and on 3 consecutive days per quarter thereafter. Effluent samples shall be composited over 24 hours, while instream samples shall be grab samples. For Publicly -Owned Treatment Works (POTWs) with an approved pretreatment program, this sampling regime (or alternative monitoring program approved by the Division's Pretreat- ment Program) should be incorporated within the POTW's approved headworks long-term monitoring program which should also include monitoring to assess industrial sources of color and POTW color removal efficiency. For the purpose of reporting: The ADMI values shall be reported at natural and standard pH (7.6 SU) for all three sites. In addition to the ADMI measurements reported on the permittee's DMR, the permittee shall attach a narrative description of visual observations made during each sampling event using a form provided by the Division. Such a description shall include perceived color in the effluent and receiving stream (i.e. whether effluent plume is noticeable and, if so, the approximate width and length of the plume), rainfall, and streamflow. Also, the permittee shall verify on this form that the type of spectrophotometer (indicating band pass (ran) and cell path (mm)) employed, and method used for filtration are in accordance with the requirements of this permit condition. Reference (for calculating ADMI values): Allen, W., W.B. Prescott, R.E. Derby, C.E. Garland, J.M. Peret & M. Saltzman. 1973. Determination of color water and wastewater by means of ADMI color values. Eng. Ext. Ser. No. 142:661. EI.: ON.r JY_r.=R �1��71L?NATF�x1LYf �I TAPX WIZDM 1 �W _ S' DYLtN ma;( STArVi PA"I H 1 1-- : ►.wt 1!i°t1,�GG OMW C* rus�x aWrare.rtrc+i oaew T - S &AC I E _ &A -M �Git.GC '§PThG BEDS RAV.• �i18r .L7 G6Y nm LELEMD '�'a` --�- lhtSlaCe�FR FLOC:]_ TA%K aN F.CC PEM FROL MMM TAW ®RA 5" SLUXIE L h RAA DE::A%'r CUVW iAd&%W OrLT4W rAMW rAW rj%vlw C."Vactm sq.- fmq MOT. AAM gz mmma —�j Li aw L Tax ;011,11, j --L Nalf STAMW Ewr LACA:XW F-Vd-, Ml-.,W I BEDS FLOW LEOM R.Ae pftLw. BLACM ro9w *PSWITAV7,f ALMM -o.--AACD _ ezWL-A 3o/ram, n G� /io vLLW �V-.Y` 3 D// 1 2. c,v re. w.� u.p �.c>�.c `�j EN ."Dr/ 2 �f - C� \V ve�fStJ� �fF'e c3�.f,4 .tlC /fl � Ctdq,c��1��L1lrJ� (��1NlC.tJ.1l2C� �--++� cVAA-k-1ti14-1 "f- _ow 4JC`> S C ✓�r7 o GZ.e 55 rs.-) v 4�k s cwt_a� 'cdch-KPl ae& aria ww �o II T3C w - 1j0 Tcw�. Cond., �Gca( co(, vrm Bol>s p AWar SuffIY ln%ka -5m� Q:K', - �2 �0 O N: $7 -DOLk L. er [,,,tpaf.ca.`.) - colavl- D �C M,1 - I)an Clre e colo2 ►noh�-{-r" Xt 1 �z , c... 3/y 6-1p rz Jtr 0 3 p 2 p =/ J $(Zyl1� �7 G"j 10/2T/�i @Y,rjlp I F 11 13.9 k f1�L. Ca,e�,.�TL �7 S, _og � "„DfR 0• �� Q..�= O.S MG9 JP = noo—;Z S $g 010�402400 ��i0pn llbvnS l� @1O. 313 cF5 n QP= 1621 cis .+,moo- i,8 eQa-'7o$cE1 csofi: 141 �JfQ w,9�0: c-BO cFs ^ NP,nO� O SI�Q� �o2z ,06 c{5 C.3ofl ' loo o �s 81? 0201406soJ 847 DA . V)11 — t sa Ot 0.140621St y ` "QA: lbbS c(S ql co_o.qwlgo= SRi sc} 3OQ2= 1.4 I � V $ 8 020140661 J' �� T ¢� • qA: t c} S •Y` w,i:`l: o n c E t. 5,,(�-1 \\A s-,A'? 1 c(6, } ••1 0Z0-14oP_0 0 ww c� GA=\I3o QA;�64V 4� y, c s,ca._ _ 18 c� s t�c� N00 QOw,�IR w�glo> �-a8 88� o O'141460� I QW =I, o DA= y1 ._.. 60 QP- 41 cp S 3OQ2= 8.o c}s SUMMER CAD'q 'rAz7 CITY OF EDEN, DRY CREEK AND MEBANE BRIDGE WWTP ---------- MODEL RESULTS --- Discharger : CITY OF EDEN Receiving Stream : DAN RIVER ------------------------------------------------- The End D.O. is 6.49 mg/l. The End CBOD is 8.08 mg/l. The End NBOD is 3.60 mg/l. ------------------------------------------------- WLA WLA WLA DO Min CBOD NBOD DO Waste Flow (mg/1) Milepoint Reach # (mg/1) (mg/1) ---- (mg/1) -- (mgd) ---------- Segment 1 ---------------------- 6.49 9.90 8 ---- Reach 1��}c�' 60.00 57.15 0.00 13.50000 Reach 2 0.00 0.00 0.00 0.00000 Reach 3 141.00 0.00 0.00 5.20000 Reach 4 ���Z�^`S� 276.00 0.00 0.00 0.50000 Reach 5 0.00 0.00 0.00 0.00000 Reach 6 0.00 0.00 0.00 0.00000 Reach 7 60.00 90.00 0.00 1.00000 Reach 8 0.00 0.00 0.00 0.00000 L • v ' SUMMER CITY OF EDEN, DRY CREEK AND MEBANE BRIDGE WWTP •I Seg # I Reach # I Seg Mi I D.O. I CBOD I NBOD I Flow I 1 1 0.00 6.97 5.63 4.52 333.93 1 1 0.10 6.97 5.62 4.51 333.97 1 1 0.20 6.96 5.61 4.49 334.01 1 1 0.30 6.96 5.60 4.48 334.05 1 1 0.40 6.95 5.59 4.46 334.09 1 1 0.50 6.95 5.58 4.45 334.13 1 1 0.60 6.94 5.57 4.44 334.18 1 1 0.70 6.94 5.56 4.42 334.22 1 1 0.80 6.93 5.55 4.41 334.26 1 1 0.90 6.93 5.54 4.40 334.30 1 1 1.00 6.93 5.53 4.39 334.34 1 1 1.10 6.92 5.52 4.37 334.39 1 1 1.20 6.92 5.51 4.36 334.43 1 1 1.30 6.91 5.50 4.35 334.47 1 1 1.40 6.91 5.49 4.33 334.51 1 2 1.40 6.91 5.49 4.33 334.51 1 2 1.50 6.91 5.48 4.32 334.55 1 2 1.60 6.90 5.47 4.31 334.60 1 2 1.70 6.90 5.46 4.29 334.64 1 2 1.80 6.89 5.45 4.28 334.68 1 2 1.90 6.89 5.44 4.27 334.72 1 2 2.00 6.89 5.43 4.26 334.76 1 2 2.10 6.88 5.41 4.24 334.81 1 3 2.10 6.72 8.60 4.14 342.87 1 3 2.20 6.72 8.59 4.13 342.91 1 3 2.30 6.71 8.57 4.12 342.95 1 3 2.40 6.71 8.55 4.11 342.99 1 4 2.40 6.69 9.16 4.10 343.77 1 4 2.50 6.68 9.14 4.09 343.77 1 5 2.50 6.69 9.12 4.08 344.67 1 5 2.60 6.68 9.10 4.06 344.93 1 5 2.70 6.68 9.08 4.05 345.19 1 5 2.80 6.67 9.06 4.04 345.46 1 5 2.90 6.67 9.04 4.02 345.72 1 5 3.00 6.66 9.01 4.01 345.98 1 5 3.10 6.66 8.99 4.00 346.25 1 5 3.20 6.65 8.97 3.98 346.51 1 5 3.30 6.65 8.95 3.97 346.77 1 6 3.30 6.65 8.95 3.97 346.97 1 6 3.40 6.64 8.93 3.96 346.99 1 6 3.50 6.64 8.91 3.94 347.02 1 6 3.60 6.63 8.90 3.93 347.04 1 6 3.70 6.63 8.88 3.92 347.06 1 6 3.80 6.63 8.87 3.91 347.09 1 6 3.90 6.62 8.85 3.90 347.11 1 6 4.00 6.62 8.83 3.89 347.13 1 6 4.10 6.61 8.82 3.88 347.16 1 6 4.20 6.61 8.80 3.86 347.18 1 6 4.30 6.61 8.78 3.85 347.20 1 6 4.40 6.60 8.77 3.84 347.22 1 6 4.50 6.60 8.75 3.83 347.25 1 6 4.60 6.60 8.74 3.82 347.27 1 6 4.70 6.59 8.72 3.81 347.29 1 6 4.80 6.59 8.71 3.80 347.32 1 6 4.90 6.59 8.69 3.79 347.34 1 6 5.00 6.58 8.67 3.78 347.36 • T 1 6 5.10 6.58 8.66 3.77 347.39 1 6 5.20 6.58 8.64 3.76 347.41 1 6 5.30 6.57 8.63 3.74 347.43 1 6 5.40 6.57 8.61 3.73 347.45 1 6 5.50 6.57 8.59 3.72 347.48 1 6 5.60 6.57 8.58 3.71 347.50 1 6 5.70 6.57 8.56 3.70 347.52 1 6 5.80 6.56 8.55 3.69 347.55 1 6 5.90 6.56 8.53 3.68 347.57 1 6 6.00 6.56 8.52 3.67 347.59 1 6 6.10 6.56 8.50 3.66 347.62 1 6 6.20 6.55 8.49 3.65 347.64 1 6 6.30 6.55 8.47 3.64 347.66 1 6 6.40 6.55 8.45 3.63 347.68 1 6 6.50 6.55 8.44 3.62 347.71 1 6 6.60 6.55 8.42 3.61 347.73 1 6 6.70 6.55 8.41 3.60 347.75 1 6 6.80 6.55 8.39 3.59 347.78 1 7 6.80 6.52 8.62 3.97 349.33 1 8 6.80 6.53 8.54 3.93 353.53 1 8 6.90 6.53 8.53 3.92 353.55 1 8 7.00 6.52 8.51 3.91 353.56 1 8 7.10 6.52 8.50 3.90 353.58 1 8 7.20 6.52 8.48 3.89 353.60 1 8 7.30 6.52 8.47 3.88 353.62 1 8 7.40 6.52 8.45 3.87 353.64 1 8 7.50 6.51 8.44 3.86 353.66 1 8 7.60 6.51 8.42 3.84 353.67 1 8 7.70 6.51 8.41 3.83 353.69 1 8 7.80 6.51 8.39 3.82 353.71 1 8 7.90 6.51 8.38 3.81 353.73 1 8 8.00 6.51 8.36 3.80 353.75 1 8 8.10 6.50 8.35 3.79 353.77 1 8 8.20 6.50 8.33 3.78 353.78 1 8 8.30 6.50 8.32 3.77 353.80 1 8 8.40 6.50 8.30 3.76 353.82 1 8 8.50 6.50 8.29 3.75 353.84 1 8 8.60 6.50 8.27 3.74 353.86 1 8 8.70 6.50 8.26 3.73 353.88 1 8 8.80 6.50 8.24 3.71 353.89 1 8 8.90 6.50 8.23 3.70 353.91 1 8 9.00 6.50 8.21 3.69 353.93 1 8 9.10 6.50 8.20 3.68 353.95 1 8 9.20 6.50 8.18 3.67 353.97 1 8 9.30 6.50 8.17 3.66 353.99 1 8 9.40 6.50 8.15 3.65 354.01 1 8 9.50 6.49 8.14 3.64 354.02 1 8 9.60 6.49 8.12 3.63 354.04 1 8 9.70 6.49 8.11 3.62 354.06 1 8 9.80 6.49 8.09 3.61 354.08 1 8 9.90 6.49 8.08 3.60 354.10 Seg # I Reach # I Seg Mi I D.O. I CBOD I NBOD I Flow a *** MODEL SUMMARY DATA *** 'Discharger Receiving Stream Summer 7Q10 Design Temperature: CITY OF EDEN Subbasin : 030203 DAN RIVER Stream Class: C 313. Winter 7Q10 : 578. 25. ILENGTHI SLOPEI VELOCITY I DEPTHI Kd I Kd I Ka I Ka I KN I -------------------------------------------------------------------------------- I mile I ft/mil fps I ft Idesignl @204 Idesignl @20;fi Idesignl Segment 1 I I 1 1.401 I 2.301 0.929 I 1 4.90 I I 1 0.28 1 0.22 I I 1 2.10 I I 1.881 I 0.44 1 Reach -------------------------------------------------------------------------------- 1 1 1 1 1 1 1 1 1 1 1 Segment 1 I I 1 0.701 I 2.301 0.930 I 1 4.90 I I 1 0.28 10.22 I I 1 2.10 1 I 1.881 I 0.44 1 Reach -------------------------------------------------------------------------------- 2 1 1 1 I 1 1 1 1 1 1 Segment 1 I I 1 0.301 I 2.301 0.947 I 1 4.91 I I 1 0.28 1 0.22 I I 1 2.14 1 I 1.921 I 0.44 1 Reach -------------------------------------------------------------------------------- 3 1 1 1 1 1 1 1 1 1 1 Segment 1 I I 1 0.101 I 2.301 0.948 I 1 4.92 I I 1 0.28 1 0.22 I I 1 2.14 1 I 1.921 I 0.44 1 Reach -------------------------------------------------------------------------------- 4 1 1 1 1 1 1 1 1 1 1 Segment 1 I I 1 0.801 I 2.301 0.949 I 1 4.93 I I 10.28 1 0.22 I I 1 2.14 1 I 1.921 I 0.44 1 Reach -------------------------------------------------------------------------------- 5 1 1 1 1 1 1 1 1 1 1 Segment 1 I I 1 3.521 I 2.301 0.950 I 14.94 I I 1 0.28 1 0.22 I I 1 2.14 1 I 1.921 I 0.44 1 Reach -------------------------------------------------------------------------------- 6 1 1 1 1 1 1 1 1 1 1 Segment 1 I I 1 0.031 I 2.301 0.954 I 1 4.94 I I 1 0.28 1 0.22 I I 1 2.15 1 I 1.931 I 0.44 1 Reach -------------------------------------------------------------------------------- 7 1 1 1 1 1 1 1 1 1 1 Segment 1 I I 1 3.101 I 2.301 0.953 I 1 4.97 I I 1 0.28 1 0.22 I I 1 2.15 I I 1.931 I 0.44 1 Reach -------------------------------------------------------------------------------- 8 1 1 1 1 1 1 1 1 1 1 I Flow cfs Segment 1 Reach 1 Waste 120.925 Headwaters1313.000 Tributary I 0.000 * Runoff I 0.420 I CBOD I NBOD I D.O. I I mg/1 I mg/1 I mg/1 I 1 60.000 157.150 I 0.000 2.000 I 1.000 ( 7.440 I 0.000 1 0.000 i 7.440 I 2.000 1 1.000 I 7.440 Segment 1 Reach 2 Waste 1 0.000 1 0.000 I 0.000 1 0.000 T Tributary I 0.000 I 0.000 I 0.000 I 7.440 * Runoff I 0.420 I 2.000 I 1.000 I 7.440 Segment 1 Reach 3 Waste I 8.060 1141.000 I 0.000 I 0.000 Tributary I 0.000 I 0.000 I 0.000 I 7.440 * Runoff I 0.420 I 2.000 I 1.000 I 7.440 Segment 1 Reach 4 Waste I 0.775 1276.000 I 0.000 I 0.000 Tributary I 0.000 I 0.000 I 0.000 I 7.440 * Runoff ( 0.000 I 0.000 I 0.000 I 7.440 Segment 1 Reach 5 Waste I 0.000 I 0.000 I 0.000 I 0.000 Tributary I 0.900 I 2.000 ( 1.000 ( 7.440 * Runoff I 2.630 I 2.000 I 1.000 I 7.440 Segment 1 Reach 6 Waste ( 0.000 I 0.000 I 0.000 I 0.000 Tributary I 0.200 I 2.000 I 1.000 I 7.440 * Runoff I 0.230 I 2.000 I 1.000 I 7.440 Segment 1 Reach 7 Waste ( 1.550 160.000 190.000 I 0.000 Tributary I 0.000 I 0.000 I 0.000 I 7.440 * Runoff I 0..000 I 0.000 I 0.000 I 7.440 Segment 1 Reach 8 Waste I 0.000 I 0.000 I 0.000 I 0.000 Tributary I 4.200 I 2.000 I 1.000 I 7.440 * Runoff I 0.184 I 2.000 I 1.000 I 7.440 * Runoff flow is in cfs/mile II Ammonia/Chlorine Worksheet lI IlFacillty: II (Town of Eden--Melbane Bridge WWTP Permit Number: NCO025071 II IlReceiving Stream: Modeler: njb II ]Dan River II Date: 17-Oct-91 II II II------------------------------------- I l Summer I ------------------------_-----------II I II IlNitrogen as NH3 ]Residual Chlorine II II 7010 We): 313.000 I I 7010 (cfs): I 313.000 II II Design Flow (MGD): 13.500 1 Design Flow (MGD): 13.500 II II Design Flaw (cfa): 20.925 1 Design Flow (cfs): 20.925 II II Stream STD (mg/1): 1.000 1 Stream STD (ug/l): 17.000 II IlBackground level (mg/1): 0.220 (Background level (ug/1): 0.000 II II IWC (8): 6.266 1 IWC (R): 6.266 II IlAllowable concentration jillowable concentration II II of NH3-N (mg/1): _ -00 of Chlorine (ug/1): 271.289 II II (Allowable concentration II IlWinter I of Chlorine (mg/1): 0.271 II IlNitrogen as NH3 I II II II 7Q10 (cfs): 578.000 I I II II Design Flow (MGD): 13.500 1 II II Design Flow (cfs): 20.925 I II II Stream STD (mg/1): 1.800 1 II IlBackground level (mg/1): 0.220 1 II 11 IWC (8): 3.494 1 II IlAllowable concentration I II II of NH3-N (mg/1): II--------------------------------------------------------------------------II 45.443 I II 11/14/91 ver 3.1 Facility: NPDES Permit No.: Status (E, P, or M): Permitted Flow: Actual Average Flow: Subbasin: Receiving Stream: Stream Classification: 7010: INC: Stn'd / Bkq Pollutant AL Cone. (ug/1) (ug/1) Cadmium S 2.0 Chromium S 50.0 Copper AL 7.0 Nickel S 88.0 Lead S 25.0 Zinc AL 50.0 Cyanide S 5.0 Mercury S 0.012 Silver AL 0.06 Selenium S 5.00 Arsenic S 50.00 Phenols S NA NH3-N C T.R.Chlor.AL 17.0 Pollutant Cadmium S Chromium S Copper AL Nickel S Lad S zinc AL Cyanide S Mercury S Silver AL Selenium S Arsenic S ✓phenols S NH3-N C T.R.Chlor.AL T 0 X I C S R E V I E W City of Eden--Melbane Bridge WWTP NCO025071 E 13.5 mgd 6.7 mgd 030203 Dan River I -------- PRETREATMENT DATA -------------- I ---- EFLLUENT DATA---- I C I ACTUAL PERMITTEDI I 313.0 efs I Ind. + Ind. + I FREQUENCY 1 6.27 A I Domestic PERMITTED Domestic I OBSERVED of Chronicl Removal Domestic Eff. Load 4 (4/d) 704 0.07 754 0.24 404 0.96 31% 0.48 80% 1.19 19% 5.01 584 0.00 85% 0.0 934 0.24 04 0.0 04 0.0 04 0.0 04 0.0 04 0.0 --------- ALLOWABLE PRDCT'D Effluent Effluent Cone. using Allowable CHRONIC ACTUAL Load Criteria Influent (4/d) (ug/1) (ug/1) 11.62 31.916 1.13 348.59 797.909 2.30 20.33 111.707 89.68 222.29 1404.320 29.26 217.87 398.955 6.93 107.59 797.909 111.10 20.75 79.791 0.82 0.14 0.191 0.03 1.49 0.957 0.36 8.71 79.791 0.00 87.15 797.909 0.00 0.000 10.45 0.000 271.289 Act.Ind. Total Industrial Total I Eflluent Criteria I Load Load Load Load I Cone. Violationsl (4/d) (t/d) (4/d) (4/d) I (ug/1) (4vio/Osam)I 0.1403 0.210 0.4190 0.489 I I 0.2723 0.512 11.9070 12.147 I 60.0 I I 7.3500 8.310 29.1913 30.151 1 401.0 N 1.8780 2.358 3.2835 3.764 1 75.0 I P 0.7360 1.926 2.2055 3.396 1 65.0 1 U 2.6160 7.626 33.5060 30.516 1 260.0 I T 0.1086 0.109 1 16.0 I 0.0 0.012 0.3 I S 0.0476 0.286 I 20.0 I E I C I T 0.6 0.581 I 1 0 I N I I I I I I PRDCT'D PRDCT'O-------- MONITOR/LIMIT -------- 1--ADTN'L REC6ADTN'S-- Effluent Instream I Recomm'd using Cone. Based on Based on Based on I FREQUENCY INSTREAM PERMIT using ACTUAL PERMITTED OBSERVED I Eff. Mon. Monitor. Influent OBSERVED Influent Influent Effluent I based on Recomm'd ? (ug/1) (ug/1) Loading Loading Data I OBSERVED (YES/NO) ________ ________ ________ ________ _________I _________ ________ 2.6385 0.000 Monitor Monitor I 54.6176 3.760 Monitor Monitor I NCAC NO 325.3724 25.128 Monitor Monitor Monitor I Weekly YES 46.7051 4.700 Monitor Monitor Monitor I NCAC NO 12.2140 4.073 Monitor Monitor !I NCAC NO 561.1121 16.293 Monitor Monitor Monitor I Monthly NO 0.0000 1.003 Monitor ® I NCAC NO 0.0000 0.019 qmwLimit NCAC YES 0.0000 1.253 Monitor Monitor I Weekly YES 0.0000 0.000 I 0.0000 0.000 I 0.0000 0.000 0.000 I 0.000 City of Eden W WTP--Mebane Bridge * Color (pH **Color (pH 7.6) Upstream Downstream Upstream Downstream Upstream Downstream Downstream NCSR 1964 Hwy 700 Smith River -Eden Water Sul NC 1761 (Center) Hwy 87 SR 1761 (North) SR 1761 (South) Date Temp DO Fecal Temp DO Fecal pH *00082 **00083 pH *00082 **00083 pH *00082 **00083 pH *00082 **00083 pl-[ *00082 **00083'i= z Oct-91 16.0 9.1 71.0 16.0 9.3 122.0 7.9-7.7 43 44 7.8-7.6 48 45 7.6-7.4 53 50 7.8-7.6 48 46 7 3-7.6 45 48 Sep-91 21.0 8.1 130.0 27.0 7.7 159.0 7.8-7.5 <36 <36 7.7-7.5 42 41 7.7-7.4 48 49 7.7-7.6 44 44 7.7-7.5 45 43 <?-> Aug-91 23.0 8.3 188.0 23.0 8.2 199.0 7.9-7.6 <32 <32 7.3-7.5 <38 <37 7.7-7.6 <40 <39 7.7-7.5 <41 <41 7.6-7.5 <38 <36 `' Jul-91 24.0 8.1 166.0 25.0 8.1 251.0 7.8-7.5 <33 <33 7.7-7.4 <43 <39 7.6-7.2 <40 <43 7.7-7.4 <42 <46 7.7-7.4 <38 <3911*,= Jun-91 21.0 8.6 284.0 22.0 8.5 381.0 7.7-7.4 <56 <58 7.6-7.2 <45 <44 7.6-7.2 <52 <50 7.6-7.2 <44 <48 7.6-7.2 <46 May-91 19.01 9.01 342.0 1 19.0 8.9 363.0 7.7-7.5 <27 <25 7.5-7.3 <46 <46 7.5-7.3 <51 <40 7.6-7.3 <48 <55 7.5-7.4 Apr-91 15.01 10.01 168.0 1 15.01 10.0 165.0 7.7-7.6 <26 <25 7.5-7.3 <35 <38 7.5-7.3 <33 <35 7.5-7.3 <38 <36 7.5-7.3 <40 <38'<>< Mar-91 11.01 10.51 179.0 12.0 10.5 217.0 7.7-7.4 <31 <32 7.5-7.3 <36 <35 7.5-7.3 <38 <37 7.5-7.3 <35 <37 7.5-7.3 <35 <35 -:1 Feb-91 9.01 11.71 73.0 10.0 11.8 88.0 7.6-7.6 <25 <39 7.6-7.5 <29 <28 7.5-7.4 <30 <29 7.5-7.5 <28 <28 73-7.5 <29 <29 Jan-91 9.01 11.81 178.0 9.0 11.9 201.0 7.6-7.6 43 41 7.5-7.4 48 49 7.5-7.3 46 48 7.5-7.4 48 45 7.5-7.3 52 51 Dec-90 12.6 13.5 1514.0 11.5 10.5 1425.0 7.6-7.3 49 54 7.6-7.3 52 52 7.5-7.2 461 45 7.7-7.5 351 34 7.6-7.3 55 54 Nov-90 12.0 10.3 204.0 12.0 10.4 234.0 7.7-7.6 32 31 7.6-7.5 271 31 7.5-7.4 28 29 7.5-7.5 <25 <25 7.5-7.5 <25 <25 Oct-90 17.0 8.9 477.0 17.0 8.91 372.0 7.6-7.2 79 721 17.5-7.3 62 62 7.6-7.3 32 31 No Data Sep-90 20.0 8.4 165.0 20.0 8.3 182.0 7.8-7.6 38 38 7.7-7.5 35 38 7.9-7.4 33 34 Aug-901eylfJaa.; Jul-90 23.0 7.6 251.0 23.0 8.3 284.0 7.8-7.3 60 62 7.8-6.9 67 67 7.6-6.9 55 57 Jun-901 22.01 8.61 186.0 22.0 8.5 181.0 7.6-7.3 53 511 17.7-7.5 7.6-7.0 37 35 u P- /19-19 / pan v,'lc� � ve laped 4r- X66hcu-9ers in. � YY�a.�/a �i . �' be,AN qiU Wa-�tii SuP/�y. �. own off' M a yc dan Ma baAJ ,Fpi ��( e vA' Oi y &-teK� = ee4renu tw 5 mac-lr ; 5YAO j 4c, f; v, kw i n � � Borne v/O wI*�-k jn,54uaWc. �Okc�ei3 PVY OLY04OLMWruTP Da.K ,qd -z! q. b 6 C,� 1�.5vey�l= a6.9a5cl; �b �,Tew. G.pd �iivev, -§asi /t-5 �7Q1O �l�cvs E kackpatct 6oel4l �1'lar�'n�r�ll� \Je, WWT F 7 4/0 r 191oc{s Colov = D Nor. cpgADM1 kAn melunegr r3.5rrl cl yr yCrteKWwTP ).o rnqd 07A16 I;rj - %a4K -him juporU/o /iat&J Gco w,s h,1165 ,ha�ctr�ct �7Alo� v�•Con�)tYrIGD*CuI = &741,0-fmgd)�55 �171ab t 04 Anrni) +a7./,25 Cw=(yat�.�ta�.�ah)�'a�F � i a36 N ecu - y53.5a..ti � Ua38.y�IC2 #7. i a5" -� Ctu=�,�D►'Y►_T C�oloY ,In%ill Use �10,4DY►1I January 14, 1992 MEMORANDUM" TO: Carla Sanderson THROUGH: Steve Mauney 1 6 1992 FROM: Ron Linville ' :BRANCH Subject: Color Limits Eden -Dry Creek & Mebane Bridge WWTPs Mayodan WWTP Rockingham County After a review of the proposed ADMI Limits for Eden -Mebane Bridge WWTP and Eden -Dry Creek WWTP, and discussions with the Public Utilities Director of Eden, the WSRO recommends that the Eden's request of January 2, 1992 be allowed if at all feasible. That recommendation is that the color limit at the Mebane Bridge facility remain 300 ADMI as this is the limit that the City was told to target for Compliance in their SOC. (As the plant upgrade is currently under construction, it would seem that we are changing the rules after the game has started.) The City is aware that color limits may change due to reallocation of color parameters. Additionally, the City has requested a tighter limit at the Dry Creek facility to offset their request to maintain the higher limit at Mebane Bridge as they plan to pump colored water to the Mebane Bridge plant (upon completion of the SOC) from the Dry Creek area through the Railroad Pump Station. This color limit for Dry Creek could be from 100-240 ADMI depending on the modeling requirements. The WSRO would further recommend relaxed monitoring at the Dry Creek WWTP due to this diversion and the small flow (0.5-1.0 MGD) from this facility. Page 2 This memo also confirms that the Mayodan WWTP will be given a color limit of 240 ADMI. Although there is little color at that location at the present time, the potential for future color discharges does exist (Unifi & Tultex) and should therefore be addressed beforehand. It would be conceivable and is recommended that this location could also receive relaxed monitoring requirements until such time as color from this WWTP becomes more significant Please note that Mr. Dennis Asbury has requested a copy of the modeling summaries in his letter. You may wish to respond to his request The WSRO cannot accommodate him on this matter. If we can be of further assistance on this matter or if we can further clarify our reasoning, please do not hesitate to call. cc: WSRO Central Files City of Eden January 2, 1992 Mr. James R. Linville, Environmental Technician Winston-Salem Regional Office N. C. Department of Environment, Health, and Natural Resources 8025 North Point Boulevard, Suite 100 Winston-Salem, NC 27106-3203 Dear Mr. Linville: SUBJECT: MEBANE BRIDGE WWTP: NPDES NCO025071 DRY CREEK WWTP; NPDES NCO025151 ADMI COLOR LIMIT REDUCTION r _ AFCEIVED - N.C. Dept. NRCD JAM 3 1992 Winston-Salem Regional Office This letter is in response to our recent conversations regarding plans to reduce ADMI color limits for the subject facilities. As you are aware, the City of Eden is in the midst of a $23,000,000 water and sewer improvement program. The improvements to the Mebane Bridge WWTP are scheduled for completion six months from now. Those improvements include color removal facilities. Prior to design of the color removal facilities, City officials and the City's consulting engineers met with state officials to determine what target ADMI levels to design for. Based on NC-DEM modeling studies, the City planned for a 300 ADMI color limit. I am surprised that before we can even get our color removal facilities installed and establish a track record, the state is lowering the limit. I feel that it would be more reasonable to retain the 300 ADMI color limit until we have the new facilities in place, and have proven that levels below 300 ADMI units are feasible. Historical records in Martinsville, Virginia suggest that color levels below 300 ADMI units are feasible. However, there are some inherent physical differences between the Martinsville WWTP and the Mebane Bridge WWTP. Additionally, there is a significant difference in the influent ADMI color loading on the two plants. The influent ADMI color at the Mebane Bridge WWTP is about five times that seen at the Martinsville plant. 350 West Stadium Drive • Eden, North Carolina 27288-3299 • Fax (919) 623-4041 P r K It should be noted that the City's current sewer improvement plans do not include any improvements at the Dry Creek WWTP. The existing plans call for all textile wastewater from The City's two major color producing industries, Sara Lee Knit Products (formerly Pannill Knitting) and Pluma, Inc., to be pumped to the Mebane Bridge WWTP where color removal facilities are being installed. The only textile wastewater that will flow to the Dry Creek WWTP after all improvements are completed will be from the Fieldcrest Cannon Draper Dye House. The Dye House discharge predates both Sara Lee and Pluma. ADMI color data collected at the Dry Creek WWTP prior to the opening of Sara Lee and Pluma showed that Dry Creek WWTP ADMI effluent levels were consistently below 100 ADMI color units. Consideration should be given to the possibility of reducing the Dry Creek ADMI requirement to include monitoring only, and to leaving the Mebane Bridge WWTP limit at 300 ADMI units until a track record can be established. I hope this info,.,mation is helpful. I would appreciate copies of the modeling summaries which show that a 240 ADMI limit is needed at the Mebane Bridge and Dry Creek WWTP's. Should you have any questions about this matter, please call me. Sincerely, Q� - Dennis Asbury Public Utilities Director DA:bwj c: Steve Routh, City Manager David Cain; Finkbeiner, Pettis and Strout Terry Shelton, Wastewater Superintendent MEMO DATE: SUBJECT: TO: / EdW 61ebafu dr 1011 CIO* C% ,�ru E1 resu l 'CI _ r ; boo �m-�- �Prri iX e % r�r cf� a(s.yDrw`T I�1a�oc ww7� pn� ")t ,�n� ov C l� wMTP >�educeo cr L _ ,25 1( 0pP "A' l!� �ha/r�^d �oU�yLZ uFrom: ".m... North Carolina Department of Environment, �° Health, and Natural Resources g� Printed onRe oieaPaper 2,11 9� Memorandum This is your copy I have made one for each of you. To: Carla Ruth Trevor From: towm Subject: Color Data Here are the color data I collected from instream at Eden --Mebane Bridge WWTP and the two ambient stations that monitor for color in that area. I have included a map with distances and locations of the players except the location of the Eden water supply intake station on the Smith River (the Smith River instream station for Eden--mebane Bridge). I think it is close to the confluence of the Dan and Smith Rivers, more than likely downstream of the AMS on the Smith River. I include data from color parameter 82 only because it was the first one. The data from parameter 83 is about the same and I have it also if we need it. The plots are the same except one has lines connecting points and the other does not. I plotted only June through September data where the facility collected three times a week but I have in the table the entire data set from June 1990 to August 1991. If you would like any other statistical analysis done on any of these data let me know. �A,s� � �z o7 r e � CA ri M W W V P _ 3 7•� Jc-yL` r c4�C_ Vim) W\ a ac'5w. 300 250 M 100 50 L Dan -Smith -Mayo River Area --Color Parameter 82 ■ Dan R Hwy 87 ❑ Dan R SR 1761 (center) • Smith R O AMS# 02074WO • AMS# 02070500 000000000000000000000000000000000000000000000000000000 a�OOa�OOOa�a�a�a�c�OOOOOOOOOOOOOOOa�a�a�OOOOa�a�Oa�OOa�OOOa�a�OOa�a�a�OOO `cOM-4OWWOr-+Nmt,.-0"MWOV-4mwt*-00d'c0O--' t,- Woo'011OW NNNNM�wt,-"M�t-0��locO[` ���� ��� � �� N N N N N N +-4 N N N M �����+-i N N N N N N CC cG CG ����������1N N N �����♦���%%. O �����"I%% %%%. %,.% wwwwwowwww NNNNNNNNNN OOwwwwwwww OOOOOOOOOO 350 115 250 Vol W1 KII Dan -Smith -Mayo River Area --Color Parameter 82 Dan R Hwy 87 Dan R SR 1761 Smith R (center) AMS# AMS# 02074000 02070500 ■ MOM 4MMMO�NWt*-MNMWOWO+-4N t,-WMMef Mw �NMwMOgtMt,-NMd't-0+4,'tm t- \ \ \ � 9- 4 � +- 4 N N N N N N \ \ \ r-I +—I r" 4 +-i r- 4 i--1 N N N M \ \ \ \ \ � � � r-+ N N N N N M \ \ \ � � +-4 � N N N N N N CO CO CO \\\%%.. t` \\\%_.. \00 00 a0 00 00 \\\1%1% \\\\\\\\\\ wwwwwwwwww t`t_NNNNtit`tiN wwwwwwwwww MOOMMOMMOM Eden --Mebane Bridge WWTP AMS# Date Dan R. Hwy 87 Dan R. SR 1761 Smith R. 2074000 2070500 6/5/90 28 42 33 6/6/90 33 24 35 6/8/90 36 26 17 6/11/90 160 175 305 6/13/90 31 37 38 24 6/15/90 21 24 35 6/18/90 28 18 40 6/20/90 24 15 24 6/21/90 9 6/22/90 24 21 30 6/25/90 21 20 25 6/27/90 17 31 29 6/29/90 16 16 27 7/2/90 16 18 19 7/3/90 19 16 21 7/5/90 14 17 18 7/10/90 19 19 19 7/11/90 23 22 24 7/13/90 26 28 24 7/16/90 243 309 197 150 7/17/90 136 193 128 45 7/19/90 68 47 43 7/23/90 37 41 113 7/24/90 35 57 103 7/26/90 46 51 33 7/30/90 29 58 39 8/1/90 54 31 55 8/2/90 30 27 29 8/7/90 28 37 37 8/8/90 23 31 27 8/9/90 29 22 21 8/13/90 9 8/14/90 32 31 43 8/15/90 26 48 31 20 8/16/90 24 41 38 8/21/90 33 35 74 8/22/90 35 41 41 8/23/90 41 30 33 8/28/90 28 36 42 8/29/90 35 32 27 8/30/90 47 35 35 9/4/90 32 30 32 9/5/90 30 30 31 9/7/90 25 25 25 9/12/90 30 25 29 9/13/90 34 31 35 9/14/90 28 38 43 9/17/90 51 49 44 33 9/20/90 36 52 28 9/21/90 25 25 25 9/24/90 21 9/25/90 31 31 31 9/26/90 33 45 33 9/27/90 25 42 25 10/3/90 <25 33 27 10/11/90 170 84 240 10/15/90 35 10/17/90 65 63 36 10/26/90 80 82 57 10/30/90 43 46 33 10/31/90 17 11/8/90 37 25 37 11/13/90 19 11/15/90 27 32 43 15 11/21/90 25 <25 <25 11/29/90 <25 <25 12/6/90 73 82 53 19 12/12/90 13 12/13/90 <25 <25 <25 12/20/90 <25 <25 <25 12/27/90 59 76 37 1/3/91 30 33 <25 1/9/91 57 54 47 1/14/91 29 1/17/91 71 80 95 1/22/91 31 1/23/91 46 49 <25 1/31/91 <25 25 <25 2/7/91 <25 <25 <25 2/14/91 <25 <25 <25 2/21/91 44 42 <25 2/28/91 <25 <25 <25 3/7/91 66 53 49 3/14/91 <25 <25 <25 3/21/91 35 39 <25 3/28/91 <25 <25 <25 4/4/91 48 48 30 1 4/11/91 <25 26 <25 7 4/16/91 48 4/18/91 37 41 <25 4/24/91 <25 <25 <25 5/2/91 78 63 <25 5/9/91 25 <25 <25 5/14/91 25 5/15/91 33 5/16/91 34 <25 <25 5/23/91 79 80 32 5/30/91 38 39 28 6/3/91 30 <25 56 6/4/91 45 33 35 6/5/91 47 31 <25 6/10/91 <25 <25 27 6/11/91 <25 <25 26 6/12/91 13 6/13/91 <25 <25 <25 6/17/91 <25 <25 28 36 6/18/91 38 26 43 6/20/19 152 118 139 6/24/91 112 78 121 6/25/91 75 104 126 6/27/91 29 <25 <25 7/1/91 36 <25 <25 7/2/91 <25 <25 <25 7/3/91 <25 <25 27 7/8/91 45 45 <25 7/9/91 31 <25 26 7/11/91 26 62 <25 7/15/91 122 103 69 7/16/91 57 80 57 26 7/18/91 35 36 <25 15 7/22/91 46 53 37 7/23/91 40 59 31 7/25/91 <25 <25 <25 7/29/91 41 47 58 7/30/91 40 401 44 NPDES PRETREATMENT INFORMATION REQUEST FORM I ^vim CV K.�M FACILITY NAMEvt p j c NPDES NO. NCO p� o I I REQUESTER: pj DATE: _/_/ REGION:_ PERMIT CONDITIONS COVERING PRETREATMENT This facility has no SIUs and should not have pretreatment language. This facility should and/or is developing a pretreatment program. Please include the following conditions: Program Development ; Phase I due Phase II due Additional Conditions / (attached) ✓ This facility is currently implementing a pretr tment program. Please include the following conditions: Program 7mplanentation Additional Conditions (attached) I 1 SIG FLAW - TOTAL: b'M I - COMPOSITION: TEXTrr.F': MGD METAL FINISHING: MGD OTHER: MGD MGD MGD i MGD I � I I HEADWORKS REVIEW I PASS I I PARAMETER !THROUGH DAILY LOAD IN LBS/DAY ACTUAL ' ALLJFIASLE DOMEST7C PERMITTED INDUSTRIAL % REMOVAL Cd Cr yn i � ESL Cu J� I Ni �� I I P,.Zn CN h I Penol ' I I I Other I � I ' OM illy 1C11� ./IJI���1/I •/ ilk NPDES PRET ZEATNENT INFORMATION REQUEST FORM 'FACILITY NAME: / NPDES N0. NCo0 L ' r REQUESTER:'DATE:/_FZ REGION : r r r ' This facility has no SIUs and should not have pretreatment language. This facility should and/or is developing a pretreatment program. Please include the following conditions: Program Development r Phase I due Phase IIdue / /— ditional Conditions ' r (attached) This faciLi is currently implementing a etreatment program. Please include the following conditions: r Program Implementation Additional Conditions r (attached) ' r ' r ' r SIGNIFICANT INDUSTRIAL USERS' (81 SIU FLOW - TC.PAL : 1.1 p 4101- 1.•) r PARAMETER r r Cd Cr Cu Ni Pb Zn GH �• �I�fati �M •NS PAS TH r ' x �D i Ir: 0 r r� TEXTILE: � FINISHING: Ie ACTUAL INDUSTRIAL % REMOVAL N4o 23 �� �qo RECEIVED: / / REVIEWED BY : $ RE'II�ID : ( ' �a/31 r r r 1'ne sAs system z 09:57 Thursday, October 3, 1991 ' � r __w----------------------------- NPDES=NC0025071---------------------------- Variable Sum PIPE 4.0000000 _TYPE_ 0 _FREQ_ 105.0000000 MCDL 0.1403059 MCRL 0.2722510 MCUL 7.3497779 MNIL 1.8783668 MPBL 0.7360015 MZNL 2.6156172 MCNL 0.1085584 MHGL 0.0022987 MALL 0.0475964 MASL 0.3685513 MPHENOLL 0.5812751 MFLL MBODL 3209.71 MCODL 13650.52 MTSSL 844.1857462 MTOLUL MFLOW ---------------------- 3.0904399 The SAS System 1 • 09:57 Thursday, October 3, 1991 ♦ T OBS NPDES IUNUM PIPE _TYPE_ _FREQ- MCDL MCRL MCUL 1. NCO025071 1004 1 0 24 0.015415 0.01305 0.15396 2 NCO025071 1005 1 0 22 0.018428 0.19917 0.15118 3 NCO025071 1008 1 0 27 0.041815 0.04971 5.40957 4 NCO025071 1009 1 0 32 0.064648 0.01033 1.63507 OBS MNIL MPBL MZNL MCNL MHGL MAGL MASL 1 0.05087 0.05558 0.41362 2 0.15888 0.15565 0.70930 3 1.08612 0.41457 0.93725 0.10856 .0022987 0.047596 0.36855 4 0.58250 0.11021 0.55544 OBS MPHENOLL MFLL MBODL MCODL MTSSL MTOLUL MFLOW 1 0.10304 378.75 1679.82 183.447 0.37043 2 0.09861 709.43 1882.82 328.499 0.55181 3 0.27173 1484.67 7394.76 200.640 1.29964 4 0.10790 636.86 2693.13 131.601 0.86856 1L t • C 1L _ ► ..�\► \ ii �' f 1 I i 1 1' 1 1 f 1 ! i_ ►-:i: `\ i f 1 1 f 1 1 1 i 1.•: `i.: __ ►\ '�•11 1 is i- :.11 1 1 i 1 _ _ C _.:. ` _ _.�i 1 l.i� L_ ii• MOM WIN! ! f 1 1 i f f • • :-- •�—� •� \� - - \� •� IffWO • : _ � . i 11 � _ � • � \ � i _ � •� f � fly f • 1 f EDEN (MEB BRID.) IUP LOAD, 10/3/91, page 1 11 �� • 14LG MLEM, FOR • • • 11m• fa• 1 •�L �� • `f_ I i 1 1 1IM i • • P., Me , ! • / �, • • • • , �, L L ! SM • i� '� it f�- EDEN (MEB BRID.) IUP LOAD, 10/3/91, page 2 f `i WIM�, 14W LIMIT 1/ _•• •, Ifl If_ 11 •. 1 f 1• 1 f: 1 1 ._ 1 '. _ 1 1 PROEM ff' 11 • i •f•: 1 1 1 1 1 f , f 1 I f i i 0 000�' ��O �-fl f EDEN (MEB BRID.) IUP LOAD, 10/3/91, page 3 • V, r Z ANNUAL POLLUTANT A►:ALYSIS MONITORING REQUIREMENT REPORTING FORM A (Revised June 1990) I. Facility Information NPDES Permit No: N00025017 Discharge (Pipe) No: 001 Year: 1991 Facility Name: City of Eden, Mebane Bridge WWTP class: IV County: Rockingham Person(s) Collecting Samples: Roy Edwards Status of facility wastewater treatment operation on day of sampling: Typical Yes X No If no, explain briefly: Analytical Laboratory: Burlington Research, Inc. (WO#-91-06-185) II. Sampling 24 hr composite for main sample/grab sample for pirgeeble fraction Date Sampled: (composite sample) Sampling begun (date, time): Thursday. June 13, 1991; 12:30 PH Sampling finished (date, time): _ Friday. June 14, 1991: 12:30 PH Date and time sampled (grab sample): Friday. June 14, 1991; 12:30 PH Corresponding sample taken for toxicity testing: Yes X (BRI WON 91-06-138) No Page 1 of 13 44b INSTRUCTIONS The purpose of this document and the NC DENNR memo of October 30, 1990 (Tedder)/mailing of December 1990 is to stondard- ize the sampling, analysia and reporting procedures to be used for the Annual Pollutant Analysis Monitoring (APAM) Require- ment as described in the permit. Sampling 1 - Take a 24-hour composite sample from the final effluent during mid -week (Wednseday through Friday). Collect a grab sample for the volatile organic fraction when collection of the 24-hour composite sample is completed. Follow any other sampling instructions provided by the laboratory performing the analysis. 2 - Indicate in the space provided on Page 1 of 13 this page whether a corresponding sample for toxicity testing was taken. 3 - Make note of any unusual wastewater treatment operating conditions occurring on the day of sampling in the space pro- vided on Page 1 of 13. Analysis 4 - Analyze the effluent for pollutants listed on the APAM form, including those to be identified and approximately quan- tified under the 10 significant peaks rule, using appropriate EPA -approved methods for each of the analytic fractions. other analytical methods can be substituted only with prior, written approval of the Director of the Division of Environmen- tal Management (DEM). Read and distribute to the laboratory performing the analysis the accompanying memo (Tedder, October 1990) clarifying analytical requirements. 5 - Identify chemicals to be analyzed for according to the 10 significant peaks rule (as described in item 2 of the Annual Pollutant Analysis Monitoring Requirement in the permit) using a GC/MS library search. Tentative identification is all that is required; confirmation by standard injection is not necessary. Estimate the concentration of each based on an internal standard having the closest retention time. Reporting 6 - ouantitation limit Targets that should be met are listed on this Revised APAM Reporting Form A. Report the use of any higher quantition limit and an explanation as to why the listed quantitation limit target could not be met. Examples of acceptable reasons for not meeting a quantitation limit target could be high background concentrations in a sample, or the necessity for sample fraction dilution to bring a chemical to within a quantifiable concentration. List any quantitation limit different (whether higher or lower) from the target in the column provided for the purpose. 7 - If a chemical is found to be below the quantitation limit, report the concentration detected as less than (or 10) the quantitation limit in the appropriate space. Provide a concentration estimate for chemicals detected in concentrations greater than the detection limit and less than the quantitation limit. Enter the detection limit in parentheses beside the estimate. Chemicals detected in concentrations above the quantitation limits must be quantified. ouantitation limit and detection limit are defined in the NC DEIINR memo (Tedder, October 1990). Enter the total number of peaks detected In each analytic fraction in the appropriate space on this Revised APAM Form A. Report all concentrations in units of micro- grams per liter (ug/L) and metals as total recoverable metal. If no peaks to be identified under the 10 significant peaks rule are observed, enter "none" in the space provided for "other" compounds in each appropriate Provide the concentration estimate and retention time for "unknowns""was well as for "significant peaks" fraction section. tural assignment can be made. g peaks for which a struc- 8 - If "significant peaks" are found, provide probable molecular weight, library match probability, retention time, ident- ification basis, and HS scan number each. In addition, list internal standards and their retention times. 9 - In the section labeled "Organic Analytical information", (Page 11 of 13) include for each organic fraction the method, extraction technique, GC operating conditions, and surrogate recovery. Report the size of the GC/MS library being utilized in the appropriate space. 10 - Use copies of this Annual Pollutant Analysis Monitoring Revised Form A to report the results of the analysis. Both the analytical laboratory representative and the facility operator in responsible charge should sign completed forms (last page). 11 - Mail two completed copies of the form (and the laboratory report, If submitted to the facility on a different form) to: ATTN: Central Files, Division of Environmental Management, HC DEIINR, P.O. Box 27687, Raleigh, NC 27611. Hail the APAM form separately from Discharge Monitoring Reports. Page 2 of 13 A. Purgeable (Volatile Organic) Fraction, EPA Method 624 Number of chemicals detected in Fraction Fraction STORET Number 84085 STORET Number Compound Quent tat on Limit Target Quentitat on Limit* Concentration Detected GC/MS Confirmation? . Pollutants to be analyzed or: (ug/ ) (ug/L) (ug/L) Yes No 34210 342T5 30036- 32 001 32144 Acrolein 100 NO Yes Acrylonitrt a 100 NO Yes Benzene ND Yes Bromodich oromet ene 5 ND Yes Bromoform 5 ND Yes 3 + + � 32102 —343OF Bromot.t ane 10 ND Yes Carbon tetrachloride 5 ND Yes Chlorobenzene 6 ND Yes 34311 34576 32106 Chtoroethane id ND Yes 2-Chtoroethyt vinyl ether 10 ND Yes Chloroform 5 Yes 34418- 32210 34496 3�1,2-Dichloroethene 3450 34546 Ch t oromet ane 10 ND Yes [t romoch oromet ane 5 ND Yes ,1-Dichloroethane 5 NO Yes 5 ND Yes -Dichloroethy ene 5 ND Yes trans- ,2-Dtc loroethy ene 5 ND Yes 34541 3470 346 99 —MTF 34423 34516 34 7r 340 0 34506- 1,2-Dichioropropane ND Yes cis ,3-Dtc oropropane 5 ND Yes trans 1,3•Dichloropropene 5 ND Yes Ethylbeenzene 8 ND Yes Methylene c6loride 5 ND Yes ,2,2-Tetrach oroe tene 7 NO Yes Tetrachtoroethytene 5 ND Yes Toluene 6 NO Yes 1,1,1-lrichtoroethene 5 NO Yes 34511 39180 34488 39175 -7 [�dt , , -Trtc oroet ane 5 ND Yes Trichioroethytene 5 NO Yes Trichtorofturomethene 10 NO Yes Vinyl chloride ND Yes event from auent tat on M'I t tnrnot _ ND=None Detected. < = As per instructions. Page 3 of 13 44* A2. Other Purgeebles (up to 10 highest peaks). Conpound Probable Molecular Weight Est. Conc. (ug/L) —79 Library Hatch Probability M Retention Time (RT) (Min) I enttf cet on Basis (Check all that apply) Scan Number Library Match Manuel Interpretation RT 2-Hethy - -Nitro-Propane 97 1793— X X Complete only if non -targeted compounds are present: Internal Standard 1,4 - Diftuorobenzene Chlombenzene - d5 Page 4 of 13 Retention Time (Min) 25.8 4 46 B. Acid Extractable Fraction, EPA Method 625 Number of chemicals detected in Fraction Fraction STORET Number 45582 STORET Number Compound Ouantitation Limit Target Quantitation Limit* Concentration Detected GUMS Confirmation? 1. Pottutants to be ana yze or: (ug/L) (ug/L) (ug/L) Yes No 34452 34586 .34601- 34606 346 6 -Chtoro- -met y phenol io ND Yes -C oro eno 0 ND Yes , -Dic oro eno w- ND Yes 2, -Dimet y eno 0 ND Yes 2, -Dinitro eno 0 ND Yes 34657 34591 34646 39032 34694 -3462F * if ifferent 2 -Met h y I. - 4, 6 - d initro eno?— 50 ND Yes 2-Nitrophenot 10 ND Yes 4-Nitrophenot so ND Yes Pentachlorophenot 50 ND Yes Phenot 10 ND Yes 2, , -Trtc oro ieno 0 ND Yes from auantttntion limit tnraAt ND=None Detected. < = As per instructions. Page 5 of 13 '46 0 B2. Other Acid Extractebles (up to 10 highest peaks). Compound Probable Molecular Weight Est. Conc. (ug/L) Library Match Probability M Retention Time (RT) (Min) Identif cat on 8as s (Check all that apply) Scan Number Library Match Manuel Interpretation RT NONE Complete only if non -targeted compounds are present: Internal Standard 1,4 - Dic oro nzene - d4 Naphtha ene - d8 Acenap t lane - Phenant rene - d 0 Chrysene - Perylene - Page 6 of 13 Retention Time (Min) 10.50 .2 24.50 33.22 a _ o C. Bnse/Neutral Fraction, EPA Method 625 Number of chemicals detected in Fraction Fraction STORET Number 45583 SiORET Number Compound Quantitation Limit Target Quentii tion Limit* Concentration Detected GC/MS Confirmation? I. PoLLUtants to 13.6 ana yze or: (ug/L) (ug/L) (ug/L) Yes No 4205 34 000 -NW 39120 34526 Acenaphthene 10 ND Yes Acena t y ene lu ND Yes Ant racene io ND Yes Benzidine 50 ND Yes Benz (a) anthracene 10 NO Yes 34247 34230 3452 Benzo (a) pyrene 10 NO Yes Benzo (b) f uorant ene 10 NO Yes Benzo (g i) pert' ene 10 ND Yes -342 88 3427 -3Z= 3 1100 4466336 -34298 Benzo ( ) uorant ene 10 NO Yes Bis(2-c oroet oxy) methane 10 ND Yes Bis(2-c oroet y) et er 10 ND Yes Bis( -c oroisopropy ) ether 10 ND Yes Bis(2-et y exy ) pht a ate 10 ND Yes 4-Bromophenyl. phenylether io ND Yes 34581 34641 Butyl Eenzylit a ate 10 ND Yes 2-C oronapht atene 10 ND Yes 4-Ch orophenyphenyl et er 10 ND Yes 34328 34� 34536 —93W 34571 34631 -34336 34341 391 00 —NUT C rysene 10 ND Yes Di enz (a, ) ant racene io ND Yes ,2-Dich orobenzene 10 ND Yes i,3-Dichlorobenzene 10 ND Yes 1,4-Dichtorobenzene 10 ND Yes 3,3-Dichtorobenzidine 20 ND Yes Diethyl t a ate 10 ND Yes Dimethyt phthalate 10 ND Yes Di-n-butythatate 10 328.0 Yes 462b- 34596 -3W -Dinitroto uene 10 ND Yes ,6-Dinitroto uene 10 ND Yes Di-n-octy t a ate 10 ND Yes 34376 34381 --- — rnntinitnel_ -Di eny y razine ND Yes Fluoranthene 10 ND Yes F uorene 1lila0nne ne*n..te i _ •.. 10 .---—�--•_--_-- ND Yes Page 7 of 13 44 � T • r C. Base/Neutral Fraction (Continued) STORET Number Compound I. Potlutants to be analyzed for: 39700 Hexach oro nzene -3439F Hexac lorobutediene 34386 Hexach orocyc epentediene --J4396 Hexac loroet ene 34403 I eno( ,2, -cd) pyrene 344 88 Isophorone 34699 Naphthatene 34447 Nitrobenzene 344438 N-n tros imet y am ne 34428 N-n troso- i-n-propylemine 34 333 N-nitrosodlienytamlFe 34461 Phenanthrene 34 Pyrene 3455 F 1,2,4-Trichiorobenzene ouentitation Limit Target (ug/L) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 * If different from quant totion target. ND=None Detected. < = As per instructions. Quentitotion Limit* (ug/L) Page 8 of 13 Concentration Detected (ug/L) ND ND ND ND ND ND ND ND ND ND ND ND ND ND Confirm Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes itiont No I 9 � a J i C2. Other Base/Neutrals (up to 10 highest peaks). Compound NONE Probable Molecular Weight Est. Conc. (ug/L) Library Match Probabitity M Retention Time (RT) (Min) identification Basis (Check all that apply) Scan Nurber Library Match Manuel interpretation RT Complete only if non -targeted compounds are present: Internat Standard 1,4 - Dic oro enzene - Napht a ene d8 Acenap t hene - P enant rene ----dio Chrysene 2 Pery ene - Page 9 of 13 Retention Time (Min) 10.90 .2 19.80 24.50 .2 .4.jo u a ' D. Organochlorine/Organophosphorus Pesticides and PCB's Number of chemicals detected in Fraction 0 Fraction STORET Number 00188 STORET Number Compound Quant tation Limit Target Quant tation Limit* Concentration Detected Con Duel rmat Col. on7 GC/MS 1. Pollutants Organochlorine to be analyzed or: Pesticides/PCB's: EPA Method (ug/L) 8080 (ug/L) (ug/ ) Yes o Yes - - - - _ - - - - - - - - - - - - - - - - - o - - - - - - - - - - - - - - - - - - - - - - 39330 39337 39338 34259 39340 39350 39310 39320 39300 39380 34�361 34356 34351 39390 34 66 39 0 39420 39480 39755 39400 34671 39488 39492 39496 39500 39504 39508 A drip 0.05 0.25 NO Y a pha-BIIC 0.05 0.25 ND Y Beta-BIIC 0.05 0.25 ND Y Delta-BHC 0.1 0.25 ND Y Gamma-BIIC (Li ane) 0.05 0. 5 ND Y Chtordane 0.2 0.25 ND Y Y , '-DDD 0.1 0.29 ND , ,-DDE 0.1 0.25 ND Y ,41-DDT 0.1 0.25 ND Y Die drip 0.02 0.25 ND Y Endosutfan I (a pha) 0.1 0.25 NO Y Endosutfan If (be -to) 0.1 0.25 ND Y Endosulfan sulfate 0.7 0.25 ND Y Endrin 0.06 0.25 ND Y Endrin atdehyae 0.2 0.25 ND Y Heptachtor 0.05 0.25 ND Y Heptachlor epoxide 0.8 0.25 ND Y Methoxychtor 0.5 0.25 ND Y Mirex o.2 0.25 ND Y Toxophene 2.4 2.5 ND Y PCB 0 6 o.5 2.5 ND Y PCB 1291 o.5 2.5 ND Y PCB 1232 0.5 2.5 ND Y PCB 1242 0.5 2.5 ND Y PCB 1248 0.5 2.5 ND Y PCB 1254 1.0 2.5 ND Y PCB 1260 1.0 2,5 ND Y ND=None Detected- < _ At nor inatriertiftne * Values listed are quantitation limits consistently achievable in wastewater matrices. Page 10 of 13 a 0 e s � r D. Pesticides (Continued). STORET Compound Number Quatitat on Limit Target Quant tat on Limit* Concentration Detected Confirmation? Dual Col. GC/MS Yes No Y . Pollutants to be analyzed for: Orgenophosphorus Pesticides: EPA Method (ug/L) 625/8080 (ug/L) (ug/L) Yes No 39560 Demeton 2.5 ND 39540 Parathion (ethyl) o.6 ND Y E. Herbicides, EPA Method 8150 Number of chemicals detected in Fraction 0 Fraction STORET Number 00148 STORET Number Compound Quant tat on Limit Target Quentitation Limit* Concentration Detected Confirmation? Dual Column I. Pollutants to be analyzed for: (ug/L) (ug/L) (ug/L) Yes No 39730 39OU 39740 2, -D 12 HD No Si I vex 2 ND No 2, ,5-T 2 ND No '77f different from auant I tat inn I im!t tnrnat ND=None Detectable. < = As per instructions. Organic Analytical Information: Organic Fraction Method 6R— Extraction GC Operating Conditions Column Description Surrogates (Spikes) Batch Continuous Length X 1D, Fitm Thickness, Column Type, Carrier Gas & Flow Rate, Temperature Program Compound •� Recovery x: 905 Purgeable N/A 75m x 0.53mm, 3.0mm, DB-624 Bromofluorobenzene He, cc/m C (9 Hin). , -D c oroet ane- �05', • C 2 60C/min. 2000C, C/min. Totuene-dg ` 19 Acid Extractable 625 X 30m x 0. 2mr, 1.0mm, DB- 2-F uor.o eno He, 2cc/m n., 400 C 0 m n) Phenol- . d �— -719 3200 C, 80 C/min. , , -Tr romo eno Base/Neutral Ext. 625 X 30m x O.32mm, 1.0mm, DO-5, 2-F uoro i eny • 54 He, 2cc/min., 400 C ( min) Nitrobenzene— —� 320* C, 80 C/min. -Ter eny - �— �0 Example: Acid Extractable 625 X Om x O.25mm, 0. um, DO- , He, 30 cm6sec, 40 C (4 min) - 270 C, 10 /min -P eno GC/MS Library size (number of reference spectra): 42,222 Page 11 of 13 't a . � f .. � � r F. Metals and Other Chemicals Number of Metals and Other Chemicats (as tlsted betox) detected in Semple 7 Fraction STORET Number 78240 STORET Quanitation Number Compound Limit Target . Pottutants to be analyzed or: I (ug/L) 01104 01077 —UTUUF o 001Z 01027 7TU34- 01042 01051 —7190 AIuninun Antimony Arsenic eery tun cadmium C romi um Copper Lea 001077 01147 `UTD7r Mercury Nice Selenium s t ver 01092 Zinc 2. Other inorganics: 0 0 10 25 2 0 0.2 0 Quantitoion Limit's Concentration Detected (ug/ ) (ug/L) 0 420 0 BDL �'— eo 0 BDL o.5 BDL BDL 2 70 BDL 0 BDL BDL 3 01007 0OPW 00720 00951 Barium 500 100 BDL Chloride 0 0229,000 Cyanide 20 17 BDL Ftuori2e 100 100 980 Page 12 of 13 f P O Analytical Laboratory Representatives: L. . Steven G. Yocklovich Director, Chromatography Laboratories Richard A. Diehl Director, Environmental Laboratories Date Facility operator in Responsible charge (ORQ: 6; /e-o,4 1 certify that this r port is accurate and complete to the best of my knowledge: Signed: N*\' L Date: Page 13 of 13 .k44 P e , e • e • Y Facility Information: Annual Pollutant Analysis Monitoring Requirement Reporting Form A (Revised June' 1990) Page 1 of 9 NPDES Permit No: r ('_, GO • !S Discharge Pipe) No: (301 ear: Y19 1 Facility Nam e-•&- v% A, z A. 4� ;', c W �,► N'T Class: I County:�DCkiri!ahrim Person(s) Collecting Samples: �_ A 17, 5 Status of facility wastewater treatment operation on day of sampling: typical: ✓Yes No If no, explain briefly: Analytical Laboratory: rzig F (:,I-N 24 fir composite for main sample / grab sample for purgeable fraction Date Sampled: (composite sample) Corresponding sample taken for toxicity testing: Samoifng begun (date, tirne): 6-13 f i L) 0 Yes Sampling finished (date, time):16` t w ` 9,1 1 D3 U No Date and time sampled (grab sample):16 -14 -q I I X GI 0 Instructions The puroose of this document and the accompanying memo Is to standardize the sampling, analysis and reporting procedures to be used for the Annual Pollutant Analysis Monitoring (APAM) Requirement as described In the permit. Sampling 1 • Take a 2•1-hour composite sample from the final effluent during midweek (Wednesday through Friday). Collect a grab sample for the volatile organic l:acticn when collection of the 24-hour composite sample is completed. Follow any other sampling instructions provided by the laboratory performing the analysis. - Indicate in the space provided at the top of this page whether a corresponding sample for toxicity testing was taken. 3 Maize note of any unusual wastewater treatment operating conditions occurring on the day of sampling in the space provided on the form. Analysis 4 • Analyze the effluent for pollutants listed on the APAM form, Including those to be identified and approximately quantified under the 10 significant peaks rule, using appropriate EPA -approved melhcos for pact of the analytic iractions. Other analytical methods can be substituted �niv with prior. viril!en aoproval of the Director of the Division of Environmental Management (OEM). Read and distribute to the laboratory performing the analysis the accompanving memo (Tedder, October i990) clarifying analytical requirements. • Identify chemicals to be analyzed for according to the 10 significant Peaks rule (as described In item 2 of the Annual Pollutant Analysis Monitoring Reaulrernent in ilia permit) using a GC1MS library search. Tentative laentificatlon Is all that Is required; confirmation by standard Injection is not necessary. Estimate the concentration of each based on an internal standard having the closest retention time. Reporting 6 - Ouentiiation Limit Targets that should be met are listed on this Revised APAM Reporting Form A. Report the use of any higher quantita- lion limit and an explanation as to why the listed quantitallon Ilrnit target could not be met. Examples of acceptable reasons for not meeting a quantitatlon limit target could be high background concentrations in a sample, or the necessity for sample fraction dilution to bring a chemical to within a quantifiable concentration. List any quantitatlon limit dilfertent (whether higher or lower) from the target in the column provided for this purpose. 7 • if a chemical !s found to be below the quantitatlon limit. report the concentration detected as less than (or '<') the quantitatlon limit in the appropriate soace. Provide a concentration estimate for chemicals detected In concentrations greater than the detection limit and less than the quantitatlon limit. Enter the detection limit In parentheses beside the estimate. Chemicals detected in concentrations above the quan- Illation limits must be quantified. Ouantilation limit and detection limit are defined to the accompanying memo (Tedder, October 1990). Enter the total number of peaks detected in each analytic fraction in the appropriate spats on this Revised APAM Form A. Report all concentrations In untls of micrograms per liter (ug11) and metals as total recoverable metal. If no peaks to be Identified under the 10 significant peaks rule are observed, enter "none" In the space provided for "other" compounds In each appropriate analytic fraction section. Provide the concentra- tion estimate and retention time for "unknowns" as well as for "significant peaks" for which a structural assignment can be made. 8 If "significant peaks" are found, provide probable molecular weight, library match probability, retention time. Identification basis, and NIS scan number for each. In addition, list Internal standards and their retention limes. 9 In the section labeled "Organic Analytical Information" (p. 9), Include for each organic fraction the method, extraction technique, GC operating conditions, and surrogate recovery. Report the size of the GC/MS library being utilized In the appropriate space. to - Use copies of this Annual Pollutant Analysis Monitoring Revised Form A to report the results of the analysis. Both the analytical laboratory representative and the facility operator In responsible charge should sign completed forms (last page). 11 • Mail Iwo completed copies of the form (and the laboratory report, if submitted to the facility on a different form) to: ATTN: Central Files, Division of Environmental Management, NC DEHNR, P.O. Box 27687, Raleigh, NC 27611. Mail the APAM form separately from Discharge Monitoring Reports. 446 A, s Burlington Research Post Office Box 2481.615 Huffman MITI Road • (919) 584.5564 • Burlington, NC 27215 • Fax If (919) 584-5564 Ext. 202 CHAIN OF CUSTODY RECORD CLIENT: (—' Y L L-- A CONTACT PERSONJ�P_yi-w 5 �� e l •�. o r� Facility/Site --� p., rr� ehn ne.� Pal c� 'e. VJJ WTP Phone Number: `��`� a`'.� �-`l 9 �-1 m��r. Sampler: (Print) (,\C)y A WTI 1? AS Purchase Order #: Sampler: (Signature) SAMPLE ID SAMPLE COLLECTION SAMPLE TYPE NO, OF COW TAINERS SENT ANALYSES REQUIRED COMPOSITE HAND AUTO GRAB DATE TIME STARTED DATE TIME ENDED 1-Dt30 .30 X 0 ,R CLIENT USE: If l tlinqu', d by: (St natture) 9 Vve2b/ •^ gnat 1 Date/Tlme U/ /1 //\\J 71 1 lip llsl�n Received by: (Signature) 7 DatelTime 3thod of Shipment: n LMD vbC WILT: acely Le FR M: (Signature Recelv d for b by: (Signature) Datetriml 6114191 ethod of Shipment: , vv C< White —ORIGINAL- CLIENT REPORT Pink —ACCOUNTING Canary —LABORATORY Goldenrod —ACKNOWLEDGEMENT 160 140 120 100 80 60 40 20 0 AMS# 02070500 Color Data 1989-91 Color 82 Color 83 N 0 -4 w m M N O -4 M N l` M d' +-4 It M N m d' m M w It w it N w O ti •-+ O N ,-� ,-1 .-� r-1 ,-� r-1 r-1 N r--� ,� r-1 .-1 r-I ,--� ,--� .-� N p ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ *--� N M lqt m w N O O �-+ N N M d� Lf� CO l� 00 G� O �-+ N +--� d' its CO [� M O 0 0 0 0 0 0 0 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ago ono 0Oo aOo aOo aOa oOo ago ono ono o � � � 0 0 0 0 XS: AMS# 02070500 (82) Mean: Std. Dev.: Std. Error. Variance: CoeL Var.: Count: 128.17 21.43 3.91 459.32 76.09 T30 Minimum: Maximum: Ran e: Sum: Sum of r.: # Missing: 1 1120 1119 845 37121 0 t 95%: 95% Lower. 95% Upper. # < 10th %: 1 Oth W 25th W 8 20.16 136.17 3 112 116 50th %: 75th W 90th W # > 90th W f2l.5 135 48.5 3 AMS# 02070500 (83) Mean: Std. Dev.: Std. Error. Variance: CoeL Var.: Count: 128.33 126.57 14.85 1706.02 193.78 130 1 Minimum: Maximum: Ran e: Sum: Sum of r.: # Missing: 3 1150 147 1850 44558 0 t 95%: 95% Lower: 95% Upper. # < 10th W 1Oth W 25th W 19.92 1118.41 F38.26 3 111.5 115 50th W 75th %: 90th W # > 90th W 120.5 131 149 2 Histogram of X3: AMS# 02070500 (82) 10 9 8 7 6- 5- ❑ AMS# 0207... U 4 3 2 1 0 0 20 40 60 80 100 120 140 AMS# 02070500 (82) Histogram of is AMS# 02070500 (83) 10 9 8 7 fi 0 5 ❑ AMS# 0207... U 4 3 2 1 0 0 1& 0 20 40 so 80 160 120 140 160 AMS# 02070500 (83) Paired t-Test Xi: AMS# 02070500 (82) Yi: AMS# 02070500 (88) DF: Mean X - Y: Paired t value: Prob. (2-tail): 129 1-.17 1-14 1.8892 J 2 #ma'©o J 1 �,/A —lc- 350 250 150 I 50 Ell Dan -Smith -Mayo River Area --Color Parameter 82 Dan R Hwy 87 Dan R SR 1761 Smith R. (center) AMS# AMS# 02074000 02070500 "3O U 000000000000000000000000000000000000000000000000000000 a�a�a�a�a�rnrnrna�a�rna�a�o�a�a�a�a�a�a�a�a�a�rnrna�a�a�rna�a�rnrna�.a�a�a�a�a�a�o�a�a�rnc�rna�rna�rna�a�a�a� Mow r-immmo --l"MrI_ONMMO+--IMwt-Mmgz WO�Nt-MMMdtWWNMWMOd'tAtiNMd'tiOq;:vmot` � � � r+ --{ r-+ � N N N N N N � � � � � •-+ *-� --� � N N N M � � � � � +--� r-+ � � N N N N N M � � � � � --+ r-+ N N N N N N �w 0 0 o w ���������� CO CO CO CO CO C� CO CO CO CD [� h ti [` !` [� h L` [� a0 00 00 00 00 00 00 a0 00 00 O O O M M O O O O O 350 Q 250 1 150 100 50 L Dan -Smith -Mayo River Area --Color Parameter 82 ■ Dan R Hwy 87 ❑ Dan R SR 1761 (center) • Smith R O AMS# 02074000 • AMS# 02070500 000000000000000000000000000000000000000000000000000000 a�O�O�o�a�rna�O�a�rna�a�a�rnO�O�o�rnO�O�a�a�a�a�a�a�rnO�rnrnrno�rnO�O�O�a�O�a�rna�rnrna�O�rnrnrna�r�O�rnO�r� mom __(M tf3 w O� N tf) l� ON M to O M 0 l` O M d' o O r-' N l` 0 0 M d' MO N M QO O O d' m l� N M o l� 0 r 4 d' M w t­ � �NNNNNN���NNNM����� NNNNNM���"4r-+r­4*-+NNNNNN C000CGCOwwwowC`OC`OC`Owt�[-l`�l\ �[` ����t-tII_ 00000�M0\0M0�00`OG`00�00�00�00`0OOOMOMMOOMMOM 160 140 120 100 80 60 40 20 0 AMS# 02074000 Color Data 1989-91 m- Color 82 a- Color 83 0 0 0 0 0 o O O O 0 0 ao ao 0o ao 0o ao ao 0o ao ao ao 00 � rn a� rn o� rn rn � rn rn a� rn rn a� c� o� o� v� M to t� l� CO to O 0 0 l- w w w CO QO r-4 r-+ r-, N N r-1 � N r-+ N N r-4 N N r-4 +--4 r-i M r 4 r-i N r-4 . 4 r-4 r1 N � � � CIO � r-4 � � � � � � � � � � � r-i N M d' m 0 l* 0 r-4 N -4 N M d' M 0 l- W 0 0 r-I N r-4 d' M 0 l� O r-1 r-4 r-1 r•i r-4 � 4w Xr. AMS#02074000 (82) Mean: Std. Dev.: Std. Error. Variance: Coef. Var.: Count: 37 136.82 6.72 11355.52 199.51 130 Minimum: Maximum: Ran e: Sum: Sum of r.: # Missing: 2 1150 1148 1110 180380 0 Ot.q.5%: 95% Lower: 95% Upper. # < 10th W IOth %: 25th %: 113.75 23.25 F5O.75 2 9 115 50th W 75th %: 90th W # > 90th W 125.5 138 83 3 B2: AMS# 02074000 (83) Mean: Std. Dev.: Std. Error. Variance: Coef. Var.: Count: 135.2 134.95 F63 T1221.27 7TW.28 130 Minimum: Maximum: Ran e: Sum: Sum of r.: # Missing 1 1150 1149 11056 172588_ 0 t 95%: 95% Lower: 95% Upper. # < loth W loth W 25th W 113.05 122.15 1,0.25 3 8.5 15 50th W 75th W 90th W # > 90th W 125.5 134 T83 3 Histogram of XI: AMS#02074000 7 6 5 4 0 p AMS#02074... U 3 2 1 0 0 20 40 60 80 160 120 140 160 AMS#02074000 (82) Histogram of X2: AMS# 02074000 o AMS# 0207... 0 20 40 60 80 100 120 140 160 AMS# 02074000 (83) Paired t-Test Xr. AMS#02074000 (S2) Y:L: AMS# 02074000 (S3) DF: Mean X - Y: Paired t value: Prob. (2-tail): 129 TLS 11.91 1.0664