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HomeMy WebLinkAboutAppendix F - MetalsAPPENDIX F 2019 Sediment and Water Column Metals (CD/DVD only) Table F-1. Minimum and maximum 2019 values for each detected metal and the creek sediment in which it was detected. Control creeks are indicated with an asterisk (*). Neither silver (Ag), cadmium (Cd), nor molybdenum (Mo) was detected in any creek. Metal Al (%) As (pg/g) Cr (pg/g) Cu (pg/g) Fe (%) Se (pg/g) Zn (pg/g) Min Max Min Max Min Max Min Max Min Max Min Max Min Max Range Creek 0.04 3.20 HC MD 3.20 8.10 PA D11 0.84 47 HC D19* 4.10 30.20 PA* MD* 0.03 22.9 HC BR 1.70 4.90 PA* DK* 2.10 85.50 HC JK JK = HC = Huddles Cut MD* = Muddy PA* = PA2 D11 = DC11 D19* = DC19 BR = Broomfield DK* = Duck Jacks Table F-2. Values of sediment metals detected in 2019 in the PCS creeks study. Creeks are listed with most upstream creek on South Creek first (Broomfield Swamp Creek) and proceed downstream by creek to Hickory Point and Muddy Creek, then upriver along the Pamlico to the most western creeks. Control creeks are indicated with an asterisk (*) and less than symbol (<) indicates the reporting limit for undetected metals in a creek sample. Al (%) (g g) (g/g) (g g) (pg/g) (g/g) Fe (%) (g/g) (g/g) (g/g) Creek Broomfield 2.29 <1.6 6.10 <1.6 28.6 13.70 22.9 <7.4 4.70 73.7 SCUT1* 0.98 <1.0 3.50 <1.0 11.9 6.00 9.21 <5.7 1.80 40.4 Jacks 2.41 <1.40 7.60 <1.40 31.50 14.10 2.58 <7.0 4.70 85.50 Little* 2.40 <1.7 5.50 <1.7 33.40 13.00 2.05 <5.5 3.30 70.50 Jacobs 2.76 <1.5 7.50 <1.5 37.40 15.10 2.83 <7.3 4.80 69.20 PA2* 0.77 <1.0 3.20 <1.0 12.50 4.10 0.90 <4.5 1.70 22.20 Drinkwater 2.69 <1.8 7.10 <1.8 36.40 13.70 2.74 <9.1 4.50 71.80 Long* 2.83 <1.6 6.60 <1.6 41.80 14.00 2.76 <9.5 4.30 73.20 Tooley 2.44 <1.5 7.10 <1.5 36.30 11.30 2.67 <8.0 3.90 67.20 Muddy* 3.20 <1.6 6.70 <1.6 43.70 30.20 2.56 <7.5 4.30 81.10 Huddles Cut 0.04 <0.41 <0.41 <0.41 0.84 <0.41 0.03 <2.1 <0.41 2.10 Porter 3.01 <1.3 7.40 <1.3 42.00 16.90 3.67 <7.4 4.80 65.10 DCUT11 1.69 <2.5 8.10 <2.5 19.00 12.50 2.59 <13 4.40 61.90 DCUT19* 1.03 <1.7 5.90 <1.7 47.00 10.90 1.72 <9.6 2.90 43.90 Duck* 2.37 <1.7 7.00 <1.7 31.70 23.60 3.60 <8.3 4.90 66.60 All mean Control* mean 2.06 1.94 NA NA 6.38 5.49 NA NA 30.27 31.71 14.22 14.54 4.19 3.26 NA NA 4.04 3.57 59.63 56.84 Other mean 2.17 NA 7.27 NA 29.01 13.90 5.00 NA 4.52 62.06 F-1 Table F-3. Values for physical parameters of 2019 sediment samples from PCS study creeks. Control creeks are indicated with an asterisk (*). Creek Bulk density (g/cm3) Water content (% by weight) Water content (% by Volume) Dry sediment densi 3y (g/cm) % Soil -solid as dry weight Porosity Total organic carbon (g/kg) Broomfield Creek 0.38 69.19 85.00 0.004 30.81 0.86 45.30 SCUT1* 0.51 61.05 80.00 0.005 38.95 0.81 42.30 Jacks Creek 0.27 76.72 88.00 0.003 23.28 0.90 91.80 Little Creek* 0.36 69.89 84.00 0.004 30.11 0.86 55.70 Jacobs Creek 0.27 76.92 89.00 0.003 23.08 0.90 68.50 PA2* 0.95 39.89 64.00 0.010 60.11 0.64 17.20 Drinkwater Creek 0.30 74.49 87.00 0.003 25.51 0.89 74.90 Long Creek* 0.31 73.69 87.00 0.003 26.31 0.88 52.20 Tooley Creek 0.35 71.37 88.00 0.004 28.63 0.87 46.70 Muddy Creek* 0.26 77.05 89.00 0.003 22.95 0.90 62.90 Huddles Cut 1.54 16.39 30.00 0.015 83.61 0.42 1.30 Porter Creek 0.32 73.34 87.00 0.003 26.66 0.88 57.10 DCUT11 0.20 82.24 91.00 0.002 17.76 0.93 125.00 DCUT19* 0.26 76.65 87.00 0.003 23.35 0.90 123.00 Duck Creek* 0.24 78.84 91.00 0.002 21.16 0.91 82.60 Mean all (SD) 0.43 (0.36) 67.85 (17.43) 81.80 (15.76) 0.004 (0.004) 32.15 (17.43) 0.84 (0.13) 63.10 (33.75) Mean control (SD) 0.41 (0.25) 68.15 (13.83) 83.14 (9.15) 0.004 (0.003) 31.20 (12.94) 0.84 (0.10) 62.27 (33.36) Mean other (SD) 0.45 (0.44) 67.58 (21.06) 80.63 (20.53) 0.005 (0.004) 33.24 (22.61) 0.83 (0.17) 63.83 (36.37) F-2 Table F-4. Values of total recoverable metals in the 2019 PCS creek study water samples. Four values were detected in 2019. Values with less than symbol (<) were not detected at the reporting limit shown. Recoverable metals 2019 water column Creek Ag (pg/L) As (pg/L) Cd (pg/L) Cr (pg/L) Cu (pg/L) Fe (pg/L) Mo (pg/L) (pg�L) Zn (pg/L) Broomfield Creek <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 SCUT1* <5.0 <5.0 <5.0 <5.0 <5.0 561.00 <250 <5.0 <100 Jacks Creek <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 Little Creek* <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 Jacobs Creek <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 PA2* <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 Drinkwater Creek <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 Long Creek* <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 Tooley Creek <5.0 <5.0 <5.0 <5.0 5.7 <500 <250 <5.0 <100 Muddy Creek* <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 Huddles Cut <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 Porter Creek <5.0 <5.0 <5.0 <5.0 5.3 <500 <250 <5.0 <100 DCUT11 <5.0 <5.0 <5.0 <5.0 8.1 <500 <250 <5.0 <100 DCUT19* <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 Duck Creek* <5.0 <5.0 <5.0 <5.0 <5.0 <500 <250 <5.0 <100 F-3