WQ0038087_2022 Residual Annual Report_20230301 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0038087
Applicant/Permittee Terra Renewal Services, Inc
Email Notifications
Does this need review by the hydrogeologist? * Yes U No
Regional Office Winston-Salem
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* David Coyle
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
479-747-8192
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation High -Rate Infiltration
Other Wastewater Reclaimed Water
Closed -Loop Recycle Residuals
Single -Family Residence Wastewater Other
Irrigation
Permit Number:*
WQ0038087
Has Current Existing permit number
Applicant/Permittee Address*
PO Box 1746 Watkinsville GA 30677
Facility Name*
Terra Renewal Services Class B Residuals Program
Please provide comments/notes on your current submittal below.
This is the annual report for land application of residuals relevant to permit WQ0038087 based in Wilkes & Yadkin Counties. If there are any
questions, complications, or requests for additional information, please contact David Coyle @ 479-747-8192.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
NC—WQ0038087—Terra Renewal Ann Report _2022.pdf 35.59MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 3/1/2023

W�t M
fV
TERRA
renal
PO BOX 399 • DARDANELLE • ARKANSAS • 72834
479.747.8192
terrarenewal.com
2022 ANNUAL REPORT
for NC Land Application Permit Number:
WQ0038087
(Class B Residuals)
Permittee / Submitted By:
Terra Renewal Services
P.O. Box 399
Dardanelle, AR 72834
Attention:
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section
Non -Discharge Permitting Unit
512 N. Salisbury Street; 6t" Floor
Raleigh, NC 27604

TERRA
renewal
March 1, 2023
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permit Section
Non -Discharge Permitting Unit
Information Processing Unit
6th Floor
512 N. Salisbury Street
Raleigh, NC 27699
East Region Environmental Office
P.O. Box 1746
Watkinsville, GA 30677
phone [phone]
RE: 2022 Annual Report for Land Application Permit No. WQ0038087
Permittee: Terra Renewal Services, Inc
Dear Sir or Madam,
The enclosed documentation is intended to serve as the annual report for the land application of residuals
sources related to the above referenced permit in Wilkes and Yadkin Counties.
The following information is provided:
PPrmittPP-
Terra Renewal Services, Inc.
P.O. Box 399
Dardanelle, AR 72834
Preparer & Contact:
Terra Renewal Services, Inc
David C. Coyle; Senior Environmental Manager
P.O. Box 1746
Watkinsville, GA 30677
phone: [phone]
email: david.coyle(cDterrarenewal.com
These items are included with the report (in order):
1) The Annual Land Application Certification Form (ACF)
2) The Annual Residuals Sampling Summary Form (RSSF) and Annual Residuals Sampling
Summary Form — B (RSSF-B) for each residuals source
3) The Annual Metals Field Loading Summary Form (MFLSF), Annual Land Application Field
Summary Form (FSF), and Annual Land Application Field Summary Form Supplement (FSF-
SUP)
4) Lab Analyses for Residuals:
— Nutrients, Metals, TCLP, Other
— Fecal Density (Seven Set)
5) Annual Pathogen and Vector Attraction Reduction Form for NCAC 2T Rules (PVRF 2T)
6) Soil Test Reports (for fields applied in 2022)

Page 2
2022 Annual Report
WQ0038087
7) Complimentary Data:
— Executive Summary
— Storage Activity Summary
— Fecal Analysis Summary
— Poultry Litter Analysis Summary
— Poultry Litter Analyses
If additional information is required or there are any questions regarding this annual report, please contact
David Coyle via the information listed above. Thank you for your cooperation and attention to this matter.
Sincerely,
David C. Coyle
Senior Environmental Manager
NC LSS #1315

1
Annual Land Application Certification Form (ACF)

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0038087 County: Wilkes & Yadkin Year:
Facility Name (as shown on permit):
Land Application Operator:
Terra Renewal Services, Inc
2022
Terra Renewal Services, Inc Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
r❑ Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in thepermit:
57
Total number of fields utilized for land application during the year:
19
Total amount of dry tons applied during the year for all application sites:
1,171
Total number of acres utilizes for land application during the year:
521
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources.❑ Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T . I I I I were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
David C. Coyle; Senior Environmental Manager
Permittee Name and Title (type or print)
2/28/2023
Signature of Permittee
Date
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)
DENR FORM ACF (12/2006)

2
Annual Residuals Sampling Summary Form (RSSF)
Annual Residuals Sampling Summary Form — B (RSSF-B)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
11iWiTA_Y_QWV=
Residual Analysis Data
WQ0038087
Terra Renewal Services, Inc
AdvancePierre Foods - Claremont, NC
Laboratory:
1)
2)
3)
4)
5)
Pace Analytical Services, LLC
Parameter
(mg/kg)
Cone.
Limit
(mg/kg)a
Sample or Composite Date
12/27/22
Percent Solids (%)
NA
3.86
Arsenic
75
< 19
Cadmium
85
< 6.4
Copper
4,300
80
Chromium
NA
Lead
840
< 13
Mercury
57
< 2.1
Molybdenum
75
< 51
Nickel
420
< 51
Selenium
100
< 25
Zinc
7,500
66
Total Phosphorus
NA
3500
TKN
NA
100000
Ammonia -Nitrogen
NA
< 260
Nitrate and Nitrite
NA
65
'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
" 5---- 2/28/2023
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
WQ0038087
Terra Renewal Services
AdvancePierre Foods - Claremont, NC
Laboratory:
1)
2)
3)
4)
5)
Pace Analytical Services, LLC
Sample or • • - Date
Parameter
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
57,�
2/28/2023
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0038087 Laboratory: 1)
Facility Name: Terra Renewal Services, Inc 2)
Residual Source WQ # or NC0005126 3)
NPDES #: 4)
WWTP Name: RVAF (Tyson) - Harmony, NC 5)
Residual Analysis Data
Pace Analytical Services, LLC
Parameter
(mg/kg)
Cone.
Limit
(mg/kg)a
Sample or Composite Date
3/22/22
6/16/22
10/3/22
12/27/22
Percent Solids (%)
NA
1.4
2.2
2.17
3.69
Arsenic
75
< 17
< 10
< 11
< 19
Cadmium
85
< 5.8
< 3.4
< 3.6
< 6.3
Copper
4,300
22
< 6.7
7.6
58
Chromium
NA
Lead
840
< 12
< 6.7
< 7.2
< 13
Mercury
57
< 5.7
< 3.5
< 3.5
< 2.1
Molybdenum
75
< 46
< 27
< 29
< 51
Nickel
420
< 46
< 27
< 29
< 51
Selenium
100
< 23
< 13
< 14
< 25
Zinc
7,500
130
< 34
< 36
64
Total Phosphorus
NA
29000
39000
46000
9400
TKN
NA
83000
80000
75000
65000
Ammonia -Nitrogen
NA
26000
< 450
950
18000
Nitrate and Nitrite
NA
150
< 9.1
110
150
'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
5�� 2/28/2023
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
WQ0038087
Terra Renewal Services
NC0005126
RVAF (Tyson) - Harmony, NC
Laboratory:
1)
2)
3)
4)
5)
Pace Analytical Services, LLC
Sample or • • - Date
Parameter
:111
11
11
11
--------
::111
•1111
111
• 11
--------
-
: 11
11
•11
• 11
--------
'•
:111
1111
•111
• 11
--------
••
• 11
111
:•11
• 11
--------
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0038087 Laboratory: 1)
Facility Name: Terra Renewal Services, Inc 2)
Residual Source WQ # or WQ0038087 3)
NPDES #: 4)
WWTP Name: Mathis-1 Storage 5)
Residual Analysis Data
Pace Analytical Services, LLC
Parameter
(mg/kg)
Cone.
Limit
(mg/kg)a
Sample or Composite Date
3/22/22
6/16/22
10/3/22
12/27/22
Percent Solids (%)
NA
1.28
11.7
3.9
2.8
Arsenic
75
< 19
< 1.9
< 5.9
< 25
Cadmium
85
< 6.3
< 0.64
< 2.9
< 8.3
Copper
4,300
56
9.5
22
41
Chromium
NA
Lead
840
< 13
< 1.3
< 3.9
< 17
Mercury
57
< 5.8
< 0.64
< 2.1
< 2.9
Molybdenum
75
< 50
< 5.1
< 16
< 66
Nickel
420
< 50
< 5.1
< 16
< 66
Selenium
100
< 25
< 2.5
< 7.8
< 33
Zinc
7,500
300
25
47
260
Total Phosphorus
NA
22000
2800
10000
5700
TKN
NA
220000
21000
27000
69000
Ammonia -Nitrogen
NA
140000
12000
10000
10000
Nitrate and Nitrite
NA
200
1.9
48
110
'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
�� S� 2/28/2023
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
WQ0038087
Terra Renewal Services
WQ0038087
Mathis-1 Storage
Laboratory:
1)
2)
3)
4)
5)
Pace Analytical Services, LLC
Sample or • • - Date
Parameter
11
• 1
111
:11
--------
:111
:11
1111
11
--------
-
• 11
• 1
111
11
--------
' •
111
11
11
11
--------
• •
111
1
111
11
--------
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
57,�
2/28/2023
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
11iTA1iTA_Y_QKV=
Residual Annlvsis Data
WQ0038087
Terra Renewal Services, Inc
Tyson - Wilkesboro, NC
Laboratory:
1)
2)
3)
4)
5)
Pace Analytical Services, LLC
Parameter
(mg/kg)
Cone.
Limit
(mg/kg)a
Sample or Composite Date
3/22/22
6/16/22
10/3/22
12/27/22
Percent Solids (%)
NA
2.65
1.8
2.16
5.31
Arsenic
75
< 9.0
< 12
< 10
< 12
Cadmium
85
< 3.0
< 3.8
< 3.5
< 3.9
Copper
4,300
59
62
43
28
Chromium
NA
Lead
840
< 6.0
< 7.7
< 6.9
< 7.8
Mercury
57
< 2.9
< 4.2
< 3.6
< 1.5
Molybdenum
75
< 24
< 31
< 28
< 31
Nickel
420
< 24
< 31
< 28
< 31
Selenium
100
< 12
< 15
< 14
< 16
Zinc
7,500
85
64
80
< 39
Total Phosphorus
NA
3500
3900
3100
2300
TKN
NA
69000
36000
53000
36000
Ammonia -Nitrogen
NA
2300
< 560
3400
5400
Nitrate and Nitrite
NA
71
11
97
92
'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
WQ0038087
Terra Renewal Services, Inc
Tyson -Wilkesboro, NC
Laboratory:
1)
2)
3)
4)
5)
Pace Analytical Services, LLC
Sample or Composite Date
Parameter
(mg/kg)
3/22/22
6/16/22
10/3/22
12/27/22
Aluminum
< 240
850
< 280
< 310
Calcium
< 3000
< 3800
< 3500
< 3900
Magnesium
< 3000
< 3800
< 3500
< 3900
Potassium
< 3000
< 3800
< 3500
< 3900
Sodium
< 3000
< 3800
< 3500
< 3900
PAN
28988
14747
23337
17732
SAR (no units)
1.5
1.4
1.5
2.4
pH (SU)
4.9
3.9
4.6
4.4
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

3
Annual Metals Field Loading Summary Form (MFLSF)
Annual Land Application Field Summary Form (FSF)
Annual Land Application Field Summary Form Supplement (FSF-SUPP)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 78.83
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
23.4 Acres Permitted: 23.4 Site #: WK-MF-14 Field #:
12.5
Fairview
WK-MF-14
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
11/30/21
2
Tyson-
Wilkes
11/30/21
3
RVAF
6/16/22
4
Tyson-
Wilkes
6/16/22
5 j
6
7
8
9
Lj
11
12
% Solids
3.8
5.0
2.2
1.8
Arsenic
6.5
4.8
10.0
12.0
Cadmium
2.2
1.6
3.4
3.8
Copper
13.0
27.0
6.7
62.0
Chromium
Lead
4.3
3.2
6.7
7.7
Mercury
2.1
1.7
1 3.5
4.2
Molyb-
denum
17.0
13.0
27.0
31.0
Nickel
17.0
13.0
27.0
31.0
Selenium
8.7
6.4
13.0
15.0
Zinc
56.0
38.0
34.0
64.0
Total
Phos-
horus
19,000
3,700
39,000
3,900
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2
3
4
5J
6j
7
81
91
L01
11
12
y
DT/Ac./
App.
14
Event
0.81
1.77
0.54
0.25
Arsenic
0.011
0.017
0.011
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
Cadmium
0.004
0.006
0.004
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Copper
0.021
0.095
0.007
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.155
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.007
0.011
0.007
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Mercury
0.003
0.006
0.004
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Molyb-
0.028
0.046
0.029
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.118
denum
Nickel
0.028
0.046
0.029
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.118
Selenium
0.014
0.023
0.014
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
Zinc
0.091
0.134
0.037
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.294
Total
Phos-
30.856
13.061
42.276
1.950
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
88.143
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-14 Acres Utilized: 23.4
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 78.8130 Site #: WK-MF-14 Acres Permitted: 23.4
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 12.5
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 134 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
0
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4 �
o w
Z
o
?
?
ZZ
w Z
;
TKN
mg/kg
Z a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Dec
30000
3.8
0.203
RVAF
INC
1
0.4
1 59000
12000
1 58
12.538
NA
Corn-s
60000
5
0.535
Tyson -Wilkes
INC
1
0.4
52000
1500
44
23.249
NA
Corn-s
-Dec
Jan
90000
3.8
0.609
RVAF
INC
1
0.4
59000
12000
58
37.614
NA
Corn-s
Jan
138000
5
1.230
Tyson -Wilkes
INC
1
0.4
52000
1500
44
53.474
NA
Corn-s
Sep
6000
2.2
0.024
RVAF
INC
1
0.4
80000
450
9.1
Na
1.519
S.G
Sep
12000
1.8
0.038
Tyson -Wilkes
INC
1
0.4
36000
560
11
Na
1.135
S.G
Oct
132000
2.2
0.518
RVAF
INC
1
0.4
80000
450
9.1
Na
33.409
S.G.
Oct
66000
1.8
0.212
Tyson -Wilkes
INC
1
0.4
36000
560
11
Na
6.244
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
534000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
126.8741
42.307
Lime Applied
Annuallbs/acre
0.044
0.015
0.155
0.000
0.029
0.015
0.118
0.118
0.058
0.294
88.143
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.063
0.023
0.482
0.000
0.048
0.016
0.158
0.158
0.081
4.920
April
4000
Current Cumulative lbs/ac
0.107
0.038
0.637
0.000
0.077
0.031
0.276
0.276
0.139
5.214
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
134 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 72.72
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
13.7
Danripple
21 Acres Permitted: 21 Site #: WK-MRF-06 Field #: WK-MRF-06
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
11/30/21
2
Tyson-
Wilkes
11/30/21
3
Mathis-1
10/3/22
4
5
6
7
8
9
10 j
12
% Solids
3.8
5.0
3.9
Arsenic
6.5
4.8
5.9
Cadmium
2.2
1.6
2.9
Copper
13.0
27.0
22.0
Chromium
Lead
4.3
3.2
3.9
Mercury
2.1
1.7
1 2.1
Molyb-
denum
17.0
13.0
16.0
Nickel
17.0
13.0
16.0
Selenium
8.7
6.4
7.8
Zinc
56.0
38.0
47.0
Total
Phos-
horus
19,000
3,700
10,000
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2
L4j5J
6j
7
81
91
10
11
12
_3j
y
DT/Ac./
App.
14
Event
0.70
1.37
1.39
Arsenic
0.009
0.013
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.039
Cadmium
0.003
0.004
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Copper
0.018
0.074
0.061
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.153
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.006
0.009
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Mercury
0.003
0.005
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Molyb-
0.024
0.036
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.104
denum
Nickel
0.024
0.036
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.104
Selenium
0.012
0.018
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Zinc
0.078
0.104
0.131
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.313
Total
Phos-
26.562
10.138
27.880
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
64.580
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MRF-06 Acres Utilized: 21
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 72.3078 Site #: WK-MRF-06 Acres Permitted: 21.0
Operator: Terra Renewal Services Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 13.7
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 159 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
0
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4
o w
Z.°n
o
?
?
w
;
TKN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Jan
90000
3.8
0.679
RVAF
INC
1
0.4
1 59000
12000
1 58
41.912
NA
Corn-s
Jan
138000
5
1.370
Tyson -Wilkes
INC
1
0.4
52000
1500
44
59.585
NA
Corn-s
Nov
180000
3.9
1.394
Mathis-1
INC
1
0.4
27000
10000
48
Na
46.971
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
42
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
20.400
0.000
TOTALS:
42T
408000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
121.897
46.971
Lime Applied
Annuallbs/acre
0.039
0.016
0.153
0.000
0.026
0.013
0.104
0.104
0.051
0.313
64.580
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.716
0.336
0.986
0.000
0.672
0.068
0.944
0.945
0.762
5.496
April
2000
Current Cumulative lbs/ac
0.755
0.352
1.139
0.000
0.698
0.081
1.048
1.049
0.813
5.809
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
F 159 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically
digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Supplemental Information
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc
Land Owner: Mathis Properties, LLC
Operator: Terra Renewal Services
Crop 1 Name: Corn -silage
WQ Permit #: W00038087
Annual Dry Tons Applied:
Field #: WK-MRF-06
Site #: WK-MRF-06
Acres Utilized: 21
Acres Permitted: 21.0
Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 13.7
Crop 1 Max. PAN: 159.00 Crop 2 Name: Crop 2 Max PAN:
o
�; o
Q
Volume applied (enter
one)
Tons Gallons
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES 4, W 4,
Q
Fert., Animal
Waste, etc)
Soil
Cond.
(Drys
Wet,
Moist)
Precip.
Past 24
Hrs.
inches
a
o
co
w
+ o
Z
o
w
.°n
`;
rn
TKN
mg/kg
Z a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Remaining
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
April
42
55.5
1.110
Poultry Litter
S
0.5
18,384
20.4
NA
Corn-s
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
TOTALS:
421
0
0.000
20.4
0.000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
C **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date ***C.P.L.R: Cumulative Pollutant Loading Rate
DENR FORM FSF (SUPP) (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 68.15
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
10.6
Danripple
18.9 Acres Permitted: 18.9 Site #: WK-NIRF-03 Field #: WK-MRF-03
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
11/30/21
2
Tyson-
Wilkes
11/30/21
3
Mathis-1
10/3/22
4
5
6
7
8
9
10 j
12
% Solids
3.8
5.0
3.9
Arsenic
6.5
4.8
5.9
Cadmium
2.2
1.6
2.9
Copper
13.0
27.0
22.0
Chromium
Lead
4.3
3.2
3.9
Mercury
2.1
1.7
1 2.1
Molyb-
denum
17.0
13.0
16.0
Nickel
17.0
13.0
16.0
Selenium
8.7
6.4
7.8
Zinc
56.0
38.0
47.0
Total
Phos-
horus
19,000
3,700
10,000
Annual Heavy Metal Field Loadings Walculated in Ibs/acre):
Total
1 1
2
J
4 J
6j
7
81
91
10
11
12
_5j
y
DT/Ac./
App.
14
Event
0.70
1.46
1.45
0.00
0.00
0.00
Arsenic
0.009
0.014
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
Cadmium
0.003
0.005
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Copper
0.018
0.079
0.064
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.161
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.006
0.009
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
Mercury
0.003
0.005
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Molyb-
0.024
0.038
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.108
denum
Nickel
0.024
0.038
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.108
Selenium
0.012
0.019
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.053
Zinc
0.079
0.111
0.136
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.325
Total
Phos-
26.752
10.774
28.920
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
66.446
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
,__�C. sV
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MRF-03 Acres Utilized: 18.9
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 68.1545 Site #: WK-MRF-03 Acres Permitted: 18.9
Operator: Terra Renewal Services Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 10.6
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 125 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4
o w
Z.°n
o
?
?
w
;
TKN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Jan
84000
3.8
0.704
RVAF
INC
1
0.4
1 59000
12000
1 58
43.465
NA
Corn-s
Jan
132000
5
1.456
Tyson -Wilkes
INC
1
0.4
52000
1500
44
63.327
NA
Corn-s
Nov
168000
3.9
1.446
Mathis-1
INC
1
0.4
27000
10000
48
Na
48.711
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
19
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
10.200
0.000
TOTALS:
19
384000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
111699IF48711
Lime Applied
Annuallbs/acre
0.040
0.016
0.161
0.000
0.027
0.014
0.108
0.108
0.053
0.325
66.446
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.653
0.306
1.086
0.000
0.614
0.061
0.753
0.753
0.638
7.240
April
2000
Current Cumulative lbs/ac
0.693
0.322
1.247
0.000
0.641
0.075
0.861
0.861
0.691
7.565
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
F 125 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically
digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Supplemental Information
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: W00038087 Field #: WK-MRF-03 Acres Utilized: 18.9
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: Site #: WK-MRF-03 Acres Permitted: 18.9
Operator: Terra Renewal Services Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 10.6
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 125.00 Crop 2 Name: Crop 2 Max PAN:
o
�3 0
Q
Volume applied (enter
one)
Tons Gallons
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES 4, W 4,
Q
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry
Wet,
Moist)
Precip.
Past 24
Hrs.
nches
a
o
a
5s
w
+ o
o
w
°�
`;
rn
TKN
mg/kg
Z a
Ei
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Remaining
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
April
19
1 55.5
0.558
Poultry Litter
S
1
0.5
1 18,384
1 10.2
NA
I Corn-s
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
j
0.0
0.000
0.000
0.0
0.000
TOTALS:
19
0
0.000
10.2
0.000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
S� 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
- -� **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date ***C.P.L.R: Cumulative Pollutant Loading Rate
DENR FORM FSF (SUPP) (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 116.03
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
13.5
Danripple
25.3 Acres Permitted: 25.3 Site #: WK-NIRF-05 Field #: WK-MRF-05
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
Advance
Pierre
11/30/21
2
RVAF
11/30/21
3
Tyson-
Wilkes
11/30/21
4
Mathis-1
10/3/22
5
6
7
8
9
Lj
12
% Solids
7.0
3.8
5.0
3.9
Arsenic
1.0
6.5
4.8
5.9
Cadmium
1 0.3
2.2
1.6
2.9
Copper
1 450.0
13.0
27.0
22.0
Chromium
Lead
1.9
4.3
3.2
3.9
Mercury
0.3
2.1
1 1.7
2.1
Molyb-
denum
2.6
17.0
13.0
16.0
Nickel
35.0
17.0
13.0
16.0
Selenium
1.3
8.7
6.4
7.8
Zinc
140.0
56.0
38.0
47.0
Total
Phos-
horus
800
19,000
3,700
10,000
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2
3
4
6j
7
81
91
L01
11
12
_5j
DT/Ac./
App.
14
Event
0.07
1.05
2.08
1.39
Arsenic
0.000
0.014
0.020
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
Cadmium
0.000
0.005
0.007
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Copper
0.062
0.027
0.112
0.061
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.263
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.000
0.009
0.013
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.033
Mercury
0.000
0.004
0.007
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Molyb-
0.000
0.036
0.054
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.135
denum
Nickel
0.005
0.036
0.054
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.139
Selenium
0.000
0.018
0.027
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.067
Zinc
0.019
0.118
0.158
0.130
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.425
Total
Phos-
0.110
39.976
15.370
27.760
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
83.216
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
s14�
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MRF-05 Acres Utilized: 25.3
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 116.0303 Site #: WK-MRF-05 Acres Permitted: 25.3
Operator: Terra Renewal Services Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 13.5
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 167 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4
o w
Z
o
?
?
.°n
w
;
.°n
TKN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Jan
6000
6.95
0.069
Advance -Pierre
INC
1
0.4
1 11000
170
1 3.8
0.619
NA
Corn-s
Jan
168000
3.8
1.052
RVAF
INC
1
0.4
59000
12000
58
64.939
NA
Corn-s
Jan
252000
5
2.077
Tyson -Wilkes
INC
1
0.4
52000
1500
44
90.314
NA
Corn-s
Nov
216000
3.9
1.388
Mathis-1
INC
1
0.4
27000
10000
48
Na
46.786
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
25
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
10.200
0.000
TOTALS:
25T
642000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
166.073
46.786
Lime Applied
Annuallbs/acre
0.050
0.019
0.263
0.000
0.033
0.017
0.135
0.139
0.067
0.425
83.216
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.731
0.341
1.028
0.000
0.682
0.072
0.987
0.988
0.783
4.240
April
2000
Current Cumulative lbs/ac
0.781
0.360
1.291
0.000
0.715
0.089
1.122
1.127
0.850
4.665
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
1 167 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
S� 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically
digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Supplemental Information
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc
Land Owner: Mathis Properties, LLC
Operator: Terra Renewal Services
Crop 1 Name: Corn -silage
WQ Permit #: W00038087
Annual Dry Tons Applied:
Field #: WK-MRF-05
Site #: WK-MRF-05
Acres Utilized: 25.3
Acres Permitted: 25.3
Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 13.5
Crop 1 Max. PAN: 167.00 Crop 2 Name: Crop 2 Max PAN:
o
�; o
Q
Volume applied (enter
one)
Tons Gallons
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES 4, W 4,
Q
Fert., Animal
Waste, etc)
Soil
Cond.
(Drys
Wet,
Moist)
Precip.
Past 24
Hrs.
inches
a
o
co
w
+ o
Z
o
w
.°n
`;
rn
TKN
mg/kg
Z a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Remaining
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
April
25
55.5
0.548
Poultry Litter
S
0.5
18,384
10.2
NA
Corn-s
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
TOTALS:
251
0
0.000
10.2
0.000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
c �� 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date ***C.P.L.R: Cumulative Pollutant Loading Rate
DENR FORM FSF (SUPP) (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 100.33
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
11.2
Pfafftown
26.5 Acres Permitted: 26.5 Site #: WK-NIRF-12 Field #: WK-MRF-12
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
Advance
Pierre
11/30/21
2
RVAF
11/30/21
3
Tyson-
Wilkes
11/30/21
4
Mathis-1
12/8/21
5 j
Mathis-1
10/3/22
6 j
7
8
9
Lj
12
% Solids
7.0
3.8
5.0
8.5
3.9
Arsenic
1.0
6.5
4.8
2.7
5.9
Cadmium
1 0.3
2.2
1.6
0.9
2.9
Copper
1 450.0
13.0
27.0
22.0
22.0
Chromium
Lead
1.9
4.3
3.2
1.8
3.9
Mercury
0.3
2.1
1 1.7
0.9
2.1
Molyb-
denum
2.6
17.0
13.0
7.3
16.0
Nickel
35.0
17.0
13.0
7.3
16.0
Selenium
1.3
8.7
6.4
3.7
7.8
Zinc
140.0
56.0
38.0
9.1
47.0
Total
Phos-
horus
800
19,000
3,700
7,000
10,000
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2j
3 j
4
5 j
6j
7
81
91
L1
11
12
DT/Ac./
App.
14
Event
0.07
0.72
1.28
0.40
1.33
Arsenic
0.000
0.009
0.012
0.002
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
Cadmium
0.000
0.003
0.004
0.001
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Copper
0.059
0.019
0.069
0.018
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.223
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.000
0.006
0.008
0.001
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Mercury
0.000
0.003
0.004
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Molyb-
0.000
0.024
0.033
0.006
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.106
denum
Nickel
0.005
0.024
0.033
0.006
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.110
Selenium
0.000
0.012
0.016
0.003
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.053
Zinc
0.018
0.080
0.097
0.007
0.125
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.328
Total
Phos-
0.106
27.284
9.435
5.614
26.520
0.000
0.000
0.000
0.000
0.000
0.000
0.000
68.959
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MRF-12 Acres Utilized: 26.5
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 100.2927 Site #: WK-MRF-12 Acres Permitted: 26.5
Operator: Terra Renewal Services Predominant Soil Series: Pfafftown Cation Exchange Capacity (non 503): 11.2
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 168 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
0
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4
o w
Z
o
?
?
.°n
w
;
.°n
TKN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Jan
6000
6.95
0.066
Advance -Pierre
INC
1
0.4
1 11000
170
1 3.8
0.591
NA
Corn-s
Jan
120000
3.8
0.718
RVAF
INC
1
0.4
59000
12000
58
44.285
NA
Corn-s
Jan
162000
5
1.275
Tyson -Wilkes
INC
1
0.4
52000
1500
44
55.430
NA
Corn-s
Jan
30000
8.5
0.401
Mathis-1
INC
1
0.4
48000
17000
34
23.622
NA
Corn-s
Nov
216000
3.9
1.326
Mathis-1
INC
1
0.4
27000
10000
48
Na
44.667
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
27
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
10.200
0.000
TOTALS:
27
534000
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
134,128
44.667
Lime Applied
Annuallbs/acre
0.040
0.016
0.223
0.000
0.026
0.014
0.106
0.110
0.053
0.328
68.959
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.410
0.185
1.002
0.000
0.369
0.051
0.630
0.360
0.455
11.628
April
2000
Current Cumulative lbs/ac
0.450
0.201
1.225
0.000
0.395
0.065
0.736
0.470
0.508
11.956
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
1 168 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
e 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically
digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Supplemental Information
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: W00038087 Field #: WK-MRF-12 Acres Utilized: 26.5
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: Site #: WK-MRF-12 Acres Permitted: 26.5
Operator: Terra Renewal Services Predominant Soil Series: Pfafftown Cation Exchange Capacity (non 503): 11.2
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 168.00 Crop 2 Name: Crop 2 Max PAN:
o
�3 0
Q
Volume applied (enter
one)
Tons Gallons
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES 4, W 4,
Q
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry
Wet,
Moist)
Precip.
Past 24
Hrs.
nches
a
o
a
5s
w
+ o
o
w
°�
`;
rn
TKN
mg/kg
Z a
Ei
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Remaining
g
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
April
27
1 55.5
0.565
Poultry Litter
S
1
0.5
1 18,384
1 10.2
NA
I Corn-s
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
j
0.0
0.000
0.000
0.0
0.000
TOTALS:
27
0JIF
0.000
10.2
0.000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
s� 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
C J� **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date ***C.P.L.R: Cumulative Pollutant Loading Rate
DENR FORM FSF (SUPP) (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 146.35
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
41.6 Acres Permitted: 41.6 Site #: WK-CH-03 Field #:
8.1
Banister
WK-CH-03
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
11/30/21
2
Tyson-
Wilkes
11/30/21
3
Mathis-1
12/8/21
4
5
6
7
8
9
10 j
11
12
% Solids
3.8
5.0
8.5
Arsenic
6.5
4.8
2.7
Cadmium
2.2
1.6
0.9
Copper
13.0
27.0
22.0
Chromium
Lead
4.3
3.2
1.8
Mercury
2.1
1.7
1 0.9
Molyb-
denum
17.0
13.0
7.3
Nickel
17.0
13.0
7.3
Selenium
8.7
6.4
3.7
Zinc
56.0
38.0
9.1
Total
Phos-
horus
19,000
3,700
7,000
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2j
3j
L4j5J
6j
7
81
91
10
11
12
y
DT/Ac./
App.
14
Event
1.17
1.53
0.82
Arsenic
0.015
0.015
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Cadmium
0.005
0.005
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Copper
0.030
0.083
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.149
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.010
0.010
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
Mercury
0.005
0.005
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Molyb-
0.040
0.040
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.091
denum
Nickel
0.040
0.040
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.091
Selenium
0.020
0.020
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Zinc
0.131
0.117
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.262
Total
Phos-
44.308
11.352
11.452
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
67.112
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-CH-03 Acres Utilized: 41.6
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 146.3170 Site #: WK-CH-03 Acres Permitted: 41.6
Operator: Terra Renewal Services Predominant Soil Series: Banister Cation Exchange Capacity (non 503): 8.1
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 220 Crop 2 Name: Crop 2 Max. PAN:
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4 �
o w
Z
o
?
?
ZZ
w Z
;
TKN
mg/kg
Z a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Mar
306000
3.8
1.166
RVAF
INC
1
0.4
1 59000
12000
1 58
71.936
NA
Corn-s
Mar
306000
5
1.534
Tyson -Wilkes
INC
1
0.4
52000
1500
44
66.697
NA
Corn-s
Mar
96000
8.5
0.818
Mathis-1
INC
1
0.4
48000
17000
34
48.152
NA
Corn-s
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
42
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
10.200
0.000
T77s
4a
70800o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
196.984
0.000
Lime Applied
Annuallbs/acre
0.034
0.270
0.012
0.108
0.149
1.259
0.000
0.000
0.023
0.218
0.012
0.052
0.091
0.529
0.091
0.532
0.046
0.322
0.262
13.078
67.112
Date
lbs/ac
Prior Years Cumulative lbs/ac
April
4000
Current Cumulative lbs/ac
0.304
0.120
1.408
0.000
0.240
0.064
0.621
0.623
0.368
13.340
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
1 220
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Supplemental Information
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc
Land Owner: Mathis Properties
Operator: Terra Renewal Services
Crop 1 Name: Corn -silage
WQ Permit #: W00038087 Field #: WK-CH-03 Acres Utilized: 41.6
Annual Dry Tons Applied: Site #: WK-CH-03 Acres Permitted: 41.6
Predominant Soil Series: Banister Cation Exchange Capacity (non 503): 8.1
Crop 1 Max. PAN: 220.00 Crop 2 Name: Crop 2 Max PAN:
o
�; o
Q
Volume applied (enter
one)
Tons Gallons
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES 4, W 4,
Q
Fert., Animal
Waste, etc)
Soil
Cond.
(Drys
Wet,
Moist)
Precip.
Past 24
Hrs.
inches
a
o
co
w
+ o
Z
o
w
.°n
`;
rn
TKN
mg/kg
Z a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Remaining
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
April
42
55.5
0.560
Poultry Litter
S
0.5
18,384
10.2
NA
Corn-s
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
TOTALS:
421
0
0.000
10.2
0.000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date ***C.P.L.R: Cumulative Pollutant Loading Rate
DENR FORM FSF (SUPP) (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
Permit #: WQ0038087 Cation Exchange Capacity (non 503 only):
Operator: Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
Acres Used: 35.8 Acres Permitted: 35.8 Site #: WK-CH-04 Field #:
93.22
5.4
Codorus
WK-CH-04
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
11/30/21
2
Tyson-
Wilkes
11/30/21
3
Mathis-1
12/8/21
4
RVAF
3/22/22
5
Tyson-
Wilkes
3/22/22
6
Mathis-1
3/22/22
7
Advance
Pierre
11/30/21
8
9
10 j
11
12
% Solids
3.8
5.0
8.5
1.4
2.7
1.3
7.0
Arsenic
6.5
4.8
2.7
17.0
9.0
19.0
1.0
Cadmium
2.2
1.6
0.9
5.8
3.0
6.3
0.3
Copper
13.0
27.0
22.0
22.0
59.0
56.0
450.0
Chromium
Lead
4.3
3.2
1.8
12.0
6.0
13.0
1.9
Mercury
2.1
1.7
1 0.9
5.7
2.9
1 5.8
0.3
Molyb-
denum
17.0
13.0
7.3
46.0
24.0
50.0
2.6
Nickel
17.0
13.0
7.3
46.0
24.0
50.0
35.0
Selenium
8.7
6.4
3.7
23.0
12.0
25.0
1.3
Zinc
56.0
38.0
9.1
130.0
85.0
300.0
140.0
Total
Phos-
horus
19,000
3,700
7,000
29,000
3,500
22,000
800
Annual Heavy Metal Field Loadings Walculated in Ibs/acre):
Total
1 1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
App.
14
Event
0.32
0.73
0.18
0.35
0.95
0.03
0.05
Arsenic
0.004
0.007
0.001
0.012
0.017
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Cadmium
0.001
0.002
0.000
0.004
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Copper
0.008
0.040
0.008
0.015
0.112
0.003
0.044
0.000
0.000
0.000
0.000
0.000
0.230
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.003
0.005
0.001
0.008
0.011
0.001
0.000
1 0.000
0.000
1 0.000
0.000
0.000
0.029
Mercury
0.001
0.002
0.000
0.004
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Molyb-
0.011
0.019
0.003
0.032
0.045
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.113
denum
Nickel
0.011
0.019
0.003
0.032
0.045
0.003
0.003
0.000
0.000
0.000
0.000
0.000
0.116
Selenium
0.006
0.009
0.001
0.016
0.023
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.057
Zinc
0.036
0.056
0.003
0.092
0.161
0.016
0.014
0.000
0.000
0.000
0.000
0.000
0.377
Total
Phos-
12.122
5.432
2.492
20.416
6.615
1.188
0.078
0.000
0.000
0.000
0.000
0.000
48.343
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
I` __� eSe
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-CH-04 Acres Utilized: 35.8
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 93.1845 Site #: WK-CH-04 Acres Permitted: 35.8
Operator: Terra Renewal Services Predominant Soil Series: Codorus Cation Exchange Capacity (non 503): 5.4
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 206 Crop 2 Name: Crop 2 Max. PAN:
4
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
o w
Z
o
?
?
.°n
'�
w
;
�
1'KN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Mar
72000
3.8
0.319
RVAF
INC
1
0.4
59000
12000
1 58
19.668
NA
Corn-s
Mar
126000
5
0.734
Tyson -Wilkes
INC
1
0.4
52000
1500
44
31.913
NA
Corn-s
Mar
18000
8.5
0.178
Mathis-1
INC
1
0.4
48000
17000
34
10.491
NA
Corn-s
Apr
216000
1.4
0.352
RVAF
INC
1
0.4
83000
26000
150
34.484
NA
Corn-s
Apr
306000
2.65
0.945
Tyson -Wilkes
INC
1
0.4
69000
2300
71
54.880
NA
Corn-s
Apr
18000
1.28
0.027
Mathis-1
INC
1
0.4
220000
140000
200
9.243
NA
Corn-s
Apr
6000
6.95
0.049
Advance -Pierre
INC
1
0.4
11000
170
3.8
0.438
NA
Corn-s
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
36
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
10.200
0.000
TOTALS:
36
762000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
171.3161
0.000
Lime Applied
Annuallbs/acre
0.042
0.014
0.230
0.000
0.029
0.014
0.113
0.116
0.057
0.377
48.343
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.293
0.117
1.094
0.000
0.237
0.056
0.576
0.577
0.350
15.353
April
4000
Current Cumulative lbs/ac
0.335
0.131
1.324
0.000
0.265
0.070
0.690
0.694
0.407
15.730
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
206
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Supplemental Information
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc
Land Owner: Mathis Properties
Operator: Terra Renewal Services
Crop 1 Name: Corn -silage
WQ Permit #: W00038087 Field #: WK-CH-04 Acres Utilized: 35.8
Annual Dry Tons Applied: Site #: WK-CH-04 Acres Permitted: 35.8
Predominant Soil Series: Codorus Cation Exchange Capacity (non 503): 5.4
Crop 1 Max. PAN: 206.00 Crop 2 Name: Crop 2 Max PAN:
o
�; o
Q
Volume applied (enter
one)
Tons Gallons
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES 4, W 4,
Q
Fert., Animal
Waste, etc)
Soil
Cond.
(Drys
Wet,
Moist)
Precip.
Past 24
Hrs.
inches
a
o
co
w
+ o
Z
o
w
.°n
`;
rn
TKN
mg/kg
Z a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Remaining
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
April
36
55.5
0.558
Poultry Litter
S
0.5
18,384
10.2
NA
Corn-s
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
TOTALS:
361
0
0.000
10.2
0.000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
S� 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date ***C.P.L.R: Cumulative Pollutant Loading Rate
DENR FORM FSF (SUPP) (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 85.79
Permit #: WQ0038087 Cation Exchange Capacity (non 503 only): 4.2
Operator: Terra Renewal Services Owner: George F Ireland Trust Predominant Soil Series: Clifford
Acres Used: 25.6 Acres Permitted: 25.6 Site #: YK-DM-06 Field #: YK-DM-06
Residual Analysis Data (Heavy Metals and Total Phosohorus use m2/k2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
3/22/22
2
Tyson-
Wilkes
3/22/22
3
Advance
Pierre
11/30/21
4
RVAF
10/3/22
5
Tyson-
Wilkes
10/3/22
6j
7
8
9
10 j
12
% Solids
1.4
2.7
7.0
2.2
2.2
Arsenic
17.0
9.0
1.0
11.0
10.0
Cadmium
5.8
3.0
0.3
3.6
3.5
Copper
22.0
59.0
450.0
7.6
43.0
Chromium
Lead
12.0
6.0
1.9
7.2
6.9
Mercury
5.7
2.9
1 0.3
3.5
3.6
Molyb-
denum
46.0
24.0
2.6
29.0
28.0
Nickel
46.0
24.0
35.0
29.0
28.0
Selenium
23.0
12.0
1.3
14.0
14.0
Zinc
130.0
85.0
140.0
36.0
80.0
Total
Phos-
horus
29,000
3,500
800
46,000
3,100
Annual Heavy Metal Field Loadings Walculated in Ibs/acre):
Total
1 1
2
3
4
5
J
7
81
91
L01
11
12
y
DT/Ac./
App.
14
Event
0.89
1.63
0.07
0.28
0.49
Arsenic
0.030
0.029
0.000
0.006
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.076
Cadmium
0.010
0.010
0.000
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Copper
0.039
0.193
0.061
0.004
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.339
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.021
0.020
0.000
0.004
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Mercury
0.010
0.009
0.000
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Molyb-
0.082
0.078
0.000
0.016
0.027
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.204
denum
Nickel
0.082
0.078
0.005
0.016
0.027
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.208
Selenium
0.041
0.039
0.000
0.008
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.102
Zinc
0.231
0.277
0.019
0.020
0.078
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.625
Total
Phos-
51.562
11.424
0.109
25.392
3.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
91.500
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/25/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: YK-DM-06 Acres Utilized: 25.6
Land Owner: George F Ireland Trust Annual Dry Tons Applied: 85.7661 Site #: YK-DM-06 Acres Permitted: 25.6
Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.2
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 205 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4
o w
Z
o
?
?
.°n
w
;
.°n
TKN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Apr
132000
1.4
0.301
RVAF
INC
1
0.4
1 83000
26000
1 150
29.470
NA
Corn-s
Apr
126000
2.65
0.544
Tyson -Wilkes
INC
1
0.4
69000
2300
71
31.601
NA
Corn-s
May
6000
6.95
0.068
Advance -Pierre
INC
1
0.4
11000
170
3.8
0.612
NA
Corn-s
May
258000
1.4
0.588
RVAF
INC
1
0.4
83000
26000
150
57.601
NA
Corn-s
May
252000
2.65
1.088
Tyson -Wilkes
INC
1
0.4
69000
2300
71
63.202
NA
Corn-s
Nov
78000
2.17
0.276
RVAF
INC
1
0.4
75000
950
110
Na
16.917
S.G.
Nov
138000
2.16
0.486
Tyson -Wilkes
INC
1
0.4
53000
3400
97
Na
22.662
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
26
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
10.200
0.000
TOTALS:
26T
990000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
192.686
39.580
Lime Applied
Annuallbs/acre
0.076
0.026
0.339
0.000
0.052
0.025
0.204
0.208
0.102
0.625
91.500
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.181
0.066
0.795
0.000
0.141
0.049
0.421
0.423
0.230
1.789
Apr
4000
Current Cumulative lbs/ac
0.257
0.092
1.134
0.000
0.193
0.074
0.625
0.631
0.332
2.414
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
1 205 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
S� 2/25/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically
digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Supplemental Information
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc
Land Owner: George F Ireland Trust
Operator: Terra Renewal Services
Crop 1 Name: Corn -silage
WQ Permit #: W00038087 Field #: YK-DM-06 Acres Utilized: 25.6
Annual Dry Tons Applied: Site #: YK-DM-06 Acres Permitted: 25.6
Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.2
Crop 1 Max. PAN: 205.00 Crop 2 Name: Crop 2 Max PAN:
o
�; o
Q
Volume applied (enter
one)
Tons Gallons
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES 4, W 4,
Q
Fert., Animal
Waste, etc)
Soil
Cond.
(Drys
Wet,
Moist)
Precip.
Past 24
Hrs.
inches
a
o
co
w
+ o
Z
o
w
.°n
`;
rn
TKN
mg/kg
Z a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Remaining
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
April
26
55.5
0.564
Poultry Litter
S
0.5
18,384
10.2
NA
Corn-s
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.0
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
0.000
0.0
0.000
TOTALS:
261
0
0.0001
10.2
1 0.000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/25/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date ***C.P.L.R: Cumulative Pollutant Loading Rate
DENR FORM FSF (SUPP) (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 150.90
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
9.1
Fairview
51.5 Acres Permitted: 51.5 Site #: WK-YK-YF-5 Field #: WK-YK-YF-5
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
3/22/22
2
Tyson-
Wilkes
3/22/22
3
RVAF
6/16/22
4
Tyson-
Wilkes
6/16/22
5
Advance
Pierre
11/30/21
6
RVAF
10/3/22
7
Tyson-
Wilkes
10/3/22
8
9
Lj
11
12
% Solids
1.4
2.7
2.2
1.8
7.0
2.2
2.2
Arsenic
17.0
9.0
10.0
12.0
1.0
11.0
10.0
Cadmium
5.8
3.0
3.4
3.8
0.3
3.6
3.5
Copper
22.0
59.0
6.7
62.0
450.0
7.6
43.0
Chromium
Lead
12.0
6.0
6.7
7.7
1.9
7.2
6.9
Mercury
5.7
2.9
1 3.5
4.2
0.3
1 3.5
3.6
Molyb-
denum
46.0
24.0
27.0
31.0
2.6
29.0
28.0
Nickel
46.0
24.0
27.0
31.0
35.0
29.0
28.0
Selenium
23.0
12.0
13.0
15.0
1.3
14.0
14.0
Zinc
130.0
85.0
34.0
64.0
140.0
36.0
80.0
Total
Phos-
horus
29,000
3,500
39,000
3,900
800
46,000
3,100
Annual Heavy Metal Field Loadings Walculated in Ibs/acre):
Total
1 1
2
3
4
5J
6j
7
8
9
10
11
12
y
DT/Ac./
App.
14
Event
0.61
1.58
0.09
0.21
0.03
0.10
0.32
Arsenic
0.021
0.029
0.002
0.005
0.000
0.002
0.006
0.000
0.000
0.000
0.000
0.000
0.064
Cadmium
0.007
0.010
0.001
0.002
0.000
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.022
Copper
0.027
0.187
0.001
0.026
0.031
0.001
0.027
0.000
0.000
0.000
0.000
0.000
0.300
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.015
0.019
0.001
0.003
0.000
0.001
0.004
0.000
0.000
0.000
0.000
0.000
0.044
Mercury
0.007
0.009
0.001
0.002
0.000
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.021
Molyb-
0.056
0.076
0.005
0.013
0.000
0.006
0.018
0.000
0.000
0.000
0.000
0.000
0.173
denum
Nickel
0.056
0.076
0.005
0.013
0.002
0.006
0.018
0.000
0.000
0.000
0.000
0.000
0.175
Selenium
0.028
0.038
0.002
0.006
0.000
0.003
0.009
0.000
0.000
0.000
0.000
0.000
0.086
Zinc
0.158
0.269
0.006
0.027
0.010
0.007
0.050
0.000
0.000
0.000
0.000
0.000
0.526
Total
Phos-
35.148
11.088
6.708
1.638
0.054
8.740
1.953
0.000
0.000
0.000
0.000
0.000
65.329
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-YK-YF-05 Acres Utilized: 51.5
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 150.7780 Site #: WK-YK-YF-05 Acres Permitted: 51.5
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 9.1
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 153 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
4
Q
Volume applied
enter one Solids/
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
o w
Z
o
?
?
.°n
'�
w
;
�
1'KN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
May
102000
1.4
0.116
RVAF
INC
1
0.4
83000
26000
150
11.320
NA
Corn-s
May
144000
2.65
0.309
Tyson -Wilkes
INC
1
0.4
69000
2300
71
17.953
NA
Corn-s
Jun
432000
1.4
0.490
RVAF
INC
1
0.4
83000
26000
150
47.943
NA
Corn-s
Jun
594000
2.65
1.275
Tyson -Wilkes
INC
1
0.4
69000
2300
71
74.055
NA
Corn-s
Oct
48000
2.2
0.086
RVAF
INC
1
0.4
80000
450
9.1
Na
5.520
S.G.
Oct
144000
1.8
0.210
Tyson -Wilkes
INC
1
0.4
36000
560
11
Na
6.190
S.G.
Oct
6000
6.95
0.034
Advance -Pierre
INC
1
0.4
11000
170
3.8
Na
0.304
S.G.
Nov
54000
2.17
0.095
RVAF
INC
1
0.4
75000
950
110
Na
5.822
S.G.
Nov
180000
2.16
0.315
Tyson -Wilkes
INC
1
0.4
53000
3400
97
Na
14.694
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
o
1704000
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
151.270
32.530
Lime Applied
Annuallbs/acre
0.064
0.022
0.300
0.000
0.044
0.021
0.173
0.175
0.086
0.526
65.329
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.136
0.059
0.245
0.000
0.122
0.019
0.231
0.231
0.156
0.694
April
4000
Current Cumulative lbs/ac
0.200
Tom,
0.545
0.000
0.166
0.040
0.404
0.406
0.242
1.220
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
153 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
C� **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 96.25
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
23.3 Acres Permitted: 23.3 Site #: YK-YF-04 Field #:
8.9
Clifford
YK-YF-04
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
Advance
Pierre
11/30/21
2
RVAF
6/16/22
3
Tyson-
Wilkes
6/16/22
4
5
6
7
8
9
10 j
11
12
% Solids
7.0
2.2
1.8
Arsenic
1.0
10.0
12.0
Cadmium
1 0.3
3.4
3.8
Copper
1 450.0
6.7
62.0
Chromium
Lead
1.9
6.7
7.7
Mercury
0.3
3.5
1 4.2
Molyb-
denum
2.6
27.0
31.0
Nickel
35.0
27.0
31.0
Selenium
1.3
13.0
15.0
Zinc
140.0
34.0
64.0
Total
Phos-
horus
800
39,000
3,900
Annual Heavy Metal Field Loadings Walculated in Ibs/acre):
Total
1 1
2j
3j
L4j5J
6j
7
81
91
10
11
12
y
DT/Ac./
App.
14
Event
0.08
1.25
2.80
Arsenic
0.000
0.025
0.067
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.092
Cadmium
0.000
0.009
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
Copper
0.068
0.017
0.348
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.432
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.000
0.017
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
Mercury
0.000
0.009
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Molyb-
0.000
0.068
0.174
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.242
denum
Nickel
0.005
0.068
0.174
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.247
Selenium
0.000
0.033
0.084
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.117
Zinc
0.021
0.085
0.359
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.465
Total
Phos-
0.120
97.734
21.863
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
######
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: YK-YF-04 Acres Utilized: 23.3
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 96.2144 Site #: YK-YF-04 Acres Permitted: 23.3
Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 8.9
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 211 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
4
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
o w
Z
o
?
?
.°n
'�
w
;
�
1'KN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Jul
6000
6.95
0.075
Advance -Pierre
INC
1
0.4
11000
170
3.8
0.673
NA
Corn-s
Jul
228000
2.2
0.898
RVAF
INC
1
0.4
80000
450
9.1
57.955
NA
Corn-s
Jul
546000
1.8
1.759
Tyson -Wilkes
INC
1
0.4
36000
560
11
51.877
NA
Corn-s
Aug
36000
2.2
0.142
RVAF
INC
1
0.4
80000
450
9.1
9.151
NA
Corn-s
Aug
186000
1.8
0.599
Tyson -Wilkes
INC
1
0.4
36000
560
11
17.673
NA
Corn-s
Oct
54000
2.2
0.213
RVAF
INC
1
0.4
80000
450
9.1
Na
13.726
S.G.
Oct
138000
1.8
0.445
Tyson -Wilkes
INC
1
0.4
36000
560
11
Na
13.112
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
1194000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
137.3281
26.838
Lime Applied
Annuallbs/acre
0.092
0.030
0.432
0.000
0.060
0.032
0.242
0.247
0.117
0.465
119.717
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.145
0.067
0.227
0.000
0.135
0.012
0.207
0.207
0.159
0.558
April
4000
Current Cumulative lbs/ac
0.237
0.097
0.659
0.000
0.195
0.044
0.449
0.454
0.276
1.023
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
1 211 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
If. 5� 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 33.45
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
59.2 Acres Permitted: 59.2 Site #: WK-MF-23 Field #:
8.7
Fairview
W K-MF-23
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
6/16/22
2
Tyson-
Wilkes
6/16/22
3
4
5
6
7
8
9
10 j
11
12
% Solids
2.2
1.8
Arsenic
10.0
12.0
Cadmium
3.4
3.8
Copper
6.7
62.0
Chromium
Lead
6.7
7.7
Mercury
3.5
4.2
Molyb-
denum
27.0
31.0
Nickel
27.0
31.0
Selenium
13.0
15.0
Zinc
34.0
64.0
Total
Phos-
horus
39,000
3,900
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2j
3j
L4j5J
6j
7
81
91
10
11
12
y
DT/Ac./
App.
14
Event
0.18
0.39
Arsenic
0.004
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Cadmium
0.001
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
0.002
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.002
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Mercury
0.001
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.010
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
denum
Nickel
0.010
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Selenium
0.005
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Zinc
0.012
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.062
Total
Phos-
13.806
3.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.832
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-23 Acres Utilized: 59.2
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 33.4267 Site #: WK-MF-23 Acres Permitted: 59.2
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 8.1
Crop 1 Name: Small Grains Crop 1 Max. PAN: 95 Crop 2 Name: Crop 2 Max. PAN:
4
Q
Volume applied
enter one Solids/
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
o w
Z
o
?
?
.°n
'�
w
;
�
1'KN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Aug
114000
2.2
0.177
RVAF
INC
1
0.4
80000
450
9.1
11.405
NA
S.G
Aug
306000
1.8
0.388
Tyson -Wilkes
INC
1
0.4
36000
560
11
11.443
NA
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
420000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
22.848
0.000
Lime Applied
Annuallbs/acre
0.013
0.004
0.050
0.000
0.008
0.004
0.034
0.034
0.016
0.062
16.832
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.433
0.209
0.451
0.000
0.420
0.031
0.520
0.520
0.450
4.633
April
4000
Current Cumulative lbs/ac
0.446
0.213
0.501
0.000
0.428
0.035
0.554
0.554
0.466
4.695
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
F 95
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
s� 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 17.62
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
13.8 Acres Permitted: 13.8 Site #: WK-MF-15 Field #:
6.5
Fairview
WK-MF-15
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
6/16/22
2
Tyson-
Wilkes
6/16/22
3
4
5
6
7
8
9
10 j
11
12
% Solids
2.2
1.8
Arsenic
10.0
12.0
Cadmium
3.4
3.8
Copper
6.7
62.0
Chromium
Lead
6.7
7.7
Mercury
3.5
4.2
Molyb-
denum
27.0
31.0
Nickel
27.0
31.0
Selenium
13.0
15.0
Zinc
34.0
64.0
Total
Phos-
horus
39,000
3,900
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2j
3j
L4j5J
6j
7
81
91
10
11
12
y
DT/Ac./
App.
14
Event
0.56
0.72
Arsenic
0.011
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.028
Cadmium
0.004
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
0.007
0.089
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.097
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.007
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Mercury
0.004
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Molyb-
0.030
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.075
denum
Nickel
0.030
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.075
Selenium
0.015
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Zinc
0.038
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.130
Total
Phos-
43.602
5.600
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
49.202
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-15 Acres Utilized: 13.8
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 17.6141 Site #: WK-MF-15 Acres Permitted: 13.8
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 6.5
Crop 1 Name: Small Grains Crop 1 Max. PAN: 80 Crop 2 Name: Crop 2 Max. PAN:
4
Q
Volume applied
enter one Solids/
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
o w
Z
o
?
?
.°n
'�
w
;
�
1'KN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Aug
24000
2.2
0.160
RVAF
INC
1
0.4
80000
450
9.1
10.300
NA
S.G.
Aug
18000
1.8
0.098
Tyson -Wilkes
INC
1
0.4
36000
560
11
2.888
NA
S.G.
Sep
60000
2.2
0.399
RVAF
INC
1
0.4
80000
450
9.1
25.750
NA
S.G.
Sep
114000
1.8
0.620
Tyson -Wilkes
INC
1
0.4
36000
560
11
18.288
NA
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
216000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
57.226
0.000
Lime Applied
Annuallbs/acre
0.028
0.009
0.097
0.000
0.019
0.010
0.075
0.075
0.036
0.130
49.202
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.584
0.282
0.641
0.000
0.564
0.043
0.696
0.696
0.606
6.554
April
4000
Current Cumulative lbs/ac
0.612
0.291
0.738
0.000
0.583
0.053
0.771
0.771
0.642
6.684
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
1 80
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
Permit #: WQ0038087 Cation Exchange Capacity (non 503 only):
Operator: Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
Acres Used: 19.6 Acres Permitted: 19.6 Site #: WK-MF-10 Field #:
9.02
8.0
Fairview
WK-MF-10
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
6/16/22
2
Tyson-
Wilkes
6/16/22
3
4
5
6
7
8
9
10 j
11
12
% Solids
2.2
1.8
Arsenic
10.0
12.0
Cadmium
3.4
3.8
Copper
6.7
62.0
Chromium
Lead
6.7
7.7
Mercury
3.5
4.2
Molyb-
denum
27.0
31.0
Nickel
27.0
31.0
Selenium
13.0
15.0
Zinc
34.0
64.0
Total
Phos-
horus
39,000
3,900
Annual Heavy Metal Field Loadings Walculated in Ibs/acre):
Total
1 1
2j
3j
L4j5J
6j
7
81
91
10
11
12
y
DT/Ac./
App.
14
Event
0.25
0.21
0.00
Arsenic
0.005
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Cadmium
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
0.003
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.003
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Mercury
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.014
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
denum
Nickel
0.014
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Selenium
0.007
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Zinc
0.017
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
Total
Phos-
19.734
1.615
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
21.349
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-10 Acres Utilized: 19.6
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 9.0072 Site #: WK-MF-10 Acres Permitted: 19.6
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 8.0
Crop 1 Name: Small Grains Crop 1 Max. PAN: 95 Crop 2 Name: Crop 2 Max. PAN:
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4 �
o w
Z
o
?
?
ZZ
w Z
;
TKN
mg/kg
Z a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Sep
54000
2.2
0.253
RVAF
INC
1
0.4
1 80000
450
1 9.1
16.317
NA
S.G.
Sep
54000
1.8
0.207
Tyson -Wilkes
INC
1
0.4
36000
560
11
6.099
NA
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
108000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
22.417
0.000
Lime Applied
Annuallbs/acre
0.010
0.227
0.003
0.092
0.029
0.638
0.000
0.000
0.007
0.198
0.004
0.036
0.026
0.431
0.026
0.431
0.013
0.267
0.044
7.357
21.349
Date
lbs/ac
Prior Years Cumulative lbs/ac
April
4000
Current Cumulative lbs/ac
0.237
0.095
0.667
0.000
0.205
0.040
0.457
0.457
0.280
7.401
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
95
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
C7 f5�< 2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 16.70
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
22.5 Acres Permitted: 22.5 Site #: WK-MF-11 Field #:
8.0
Fairview
WK-MF-11
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
Advance
Pierre
11/30/21
2
RVAF
6/16/22
3
Tyson-
Wilkes
6/16/22
4
5
6
7
8
9
Lj
11
12
% Solids
7.0
2.2
1.8
Arsenic
1.0
10.0
12.0
Cadmium
1 0.3
3.4
3.8
Copper
1 450.0
6.7
62.0
Chromium
Lead
1.9
6.7
7.7
Mercury
0.3
3.5
1 4.2
Molyb-
denum
2.6
27.0
31.0
Nickel
35.0
27.0
31.0
Selenium
1.3
13.0
15.0
Zinc
140.0
34.0
64.0
Total
Phos-
horus
800
39,000
3,900
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2
L4j5J
6j
7
81
91
10
11
12
_3j
y
DT/Ac./
App.
14
Event
0.08
0.25
0.42
Arsenic
0.000
0.005
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Cadmium
0.000
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.069
0.003
0.052
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.125
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.000
0.003
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Mercury
0.000
0.002
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.000
0.013
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
denum
Nickel
0.005
0.013
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.045
Selenium
0.000
0.006
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Zinc
0.022
0.017
0.054
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.092
Total
Phos-
0.123
19.110
3.276
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
22.509
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-11 Acres Utilized: 22.5
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 16.7009 Site #: WK-MF-11 Acres Permitted: 2.2.5
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 8.0
Crop 1 Name: Small Grains Crop 1 Max. PAN: 80 Crop 2 Name: Crop 2 Max. PAN:
4
Q
Volume applied
enter one Solids/
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
o w
Z
o
?
?
.°n
'�
w
;
�
1'KN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Sep
6000
6.95
0.077
Advance -Pierre
INC
1
0.4
11000
170
3.8
0.696
NA
S.G.
Sep
60000
2.2
0.245
RVAF
INC
1
0.4
80000
450
9.1
15.794
NA
S.G.
Sep
126000
1.8
0.420
Tyson -Wilkes
INC
1
0.4
36000
560
11
12.397
NA
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
192000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
28.887
0.000
Lime Applied
Annuallbs/acre
0.015
0.005
0.125
0.000
0.010
0.005
0.040
0.045
0.019
0.092
22.509
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.333
0.154
0.531
0.000
0.315
0.031
0.469
0.469
0.360
5.529
April
4000
Current Cumulative lbs/ac
0.348
0.159
0.656
0.000
0.325
0.036
0.509
0.514
0.379
5.621
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
F 80
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 23.05
WQ0038087
Terra Renewal Services Owner:
33.8 Acres Permitted:
Cation Exchange Capacity (non 503 only):
Mathis Properties, LLC Predominant Soil Series:
33.8 Site #: WK-MF-13 Field #;
11.9
Fairview
WK-MF-13
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
6/16/22
2
Tyson-
Wilkes
6/16/22
3
4
5
6
7
8
9
10 j
11
12
% Solids
2.2
1.8
Arsenic
10.0
12.0
Cadmium
3.4
3.8
Copper
6.7
62.0
Chromium
Lead
6.7
7.7
Mercury
3.5
4.2
Molyb-
denum
27.0
31.0
Nickel
27.0
31.0
Selenium
13.0
15.0
Zinc
34.0
64.0
Total
Phos-
horus
39,000
3,900
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1 1
2j
3j
L4j5J
6j
7
81
91
10
11
12
y
DT/Ac./
App.
14
Event
0.31
0.37
Arsenic
0.006
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Cadmium
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.004
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.004
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Mercury
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.017
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
denum
Nickel
0.017
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
Selenium
0.008
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Zinc
0.021
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.069
Total
Phos-
24.102
2.909
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
27.011
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-13 Acres Utilized: 33.8
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 23.0684 Site #: WK-MF-13 Acres Permitted: 33.8
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 11.9
Crop 1 Name: Small Grains Crop 1 Max. PAN: 95 Crop 2 Name: Crop 2 Max. PAN:
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4 �
o w
Z
o
?
?
ZZ
w Z
;
TKN
mg/kg
Z a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Sep
114000
2.2
0.309
RVAF
INC
1
0.4
1 80000
450
1 9.1
19.976
NA
S.G
Sep
168000
1.8
0.373
Tyson -Wilkes
INC
1
0.4
36000
560
11
11.004
NA
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
282000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
30.979
0.000
Lime Applied
Annuallbs/acre
0.015
0.259
0.005
0.112
0.050
0.703
0.000
0.000
0.010
0.229
0.005
0.033
0.040
0.440
0.040
0.440
0.019
0.296
0.069
7.194
27.011
Date
lbs/ac
Prior Years Cumulative lbs/ac
April
4000
Current Cumulative lbs/ac
0.274
0.117
0.753
0.000
0.239
0.038
0.480
0.480
0.315
7.263
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
95
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 78.83
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
23.4 Acres Permitted: 23.4 Site #: WK-MF-14 Field #:
12.5
Fairview
WK-MF-14
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
11/30/21
2
Tyson-
Wilkes
11/30/21
3
RVAF
6/16/22
4
Tyson-
Wilkes
6/16/22
5 j
6
7
8
9
Lj
11
12
% Solids
3.8
5.0
2.2
1.8
Arsenic
6.5
4.8
10.0
12.0
Cadmium
2.2
1.6
3.4
3.8
Copper
13.0
27.0
6.7
62.0
Chromium
Lead
4.3
3.2
6.7
7.7
Mercury
2.1
1.7
1 3.5
4.2
Molyb-
denum
17.0
13.0
27.0
31.0
Nickel
17.0
13.0
27.0
31.0
Selenium
8.7
6.4
13.0
15.0
Zinc
56.0
38.0
34.0
64.0
Total
Phos-
horus
19,000
3,700
39,000
3,900
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2
3
4
5J
6j
7
81
91
L01
11
12
y
DT/Ac./
App.
14
Event
0.81
1.77
0.54
0.25
Arsenic
0.011
0.017
0.011
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
Cadmium
0.004
0.006
0.004
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Copper
0.021
0.095
0.007
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.155
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.007
0.011
0.007
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Mercury
0.003
0.006
0.004
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Molyb-
0.028
0.046
0.029
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.118
denum
Nickel
0.028
0.046
0.029
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.118
Selenium
0.014
0.023
0.014
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
Zinc
0.091
0.134
0.037
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.294
Total
Phos-
30.856
13.061
42.276
1.950
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
88.143
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-14 Acres Utilized: 23.4
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 78.8130 Site #: WK-MF-14 Acres Permitted: 23.4
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 12.5
Crop 1 Name: Corn -silage Crop 1 Max. PAN: 134 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50
0
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4 �
o w
Z
o
?
?
ZZ
w Z
;
TKN
mg/kg
Z a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Dec
30000
3.8
0.203
RVAF
INC
1
0.4
1 59000
12000
1 58
12.538
NA
Corn-s
60000
5
0.535
Tyson -Wilkes
INC
1
0.4
52000
1500
44
23.249
NA
Corn-s
-Dec
Jan
90000
3.8
0.609
RVAF
INC
1
0.4
59000
12000
58
37.614
NA
Corn-s
Jan
138000
5
1.230
Tyson -Wilkes
INC
1
0.4
52000
1500
44
53.474
NA
Corn-s
Sep
6000
2.2
0.024
RVAF
INC
1
0.4
80000
450
9.1
Na
1.519
S.G
Sep
12000
1.8
0.038
Tyson -Wilkes
INC
1
0.4
36000
560
11
Na
1.135
S.G
Oct
132000
2.2
0.518
RVAF
INC
1
0.4
80000
450
9.1
Na
33.409
S.G.
Oct
66000
1.8
0.212
Tyson -Wilkes
INC
1
0.4
36000
560
11
Na
6.244
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
534000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
126.8741
42.307
Lime Applied
Annuallbs/acre
0.044
0.015
0.155
0.000
0.029
0.015
0.118
0.118
0.058
0.294
88.143
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.063
0.023
0.482
0.000
0.048
0.016
0.158
0.158
0.081
4.920
April
4000
Current Cumulative lbs/ac
0.107
0.038
0.637
0.000
0.077
0.031
0.276
0.276
0.139
5.214
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
134 1 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 8.55
WQ0038087
Terra Renewal Services Owner:
10.3 Acres Permitted:
Cation Exchange Capacity (non 503 only):
Mathis Properties, LLC Predominant Soil Series:
10.3 Site #: WK-YF-07 Field #;
6.0
Fairview
W K-YF-07
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
Advance
Pierre
11/30/21
2
RVAF
6/16/22
3
Tyson-
Wilkes
6/16/22
4
5
6
7
8
9
10 j
11
12
% Solids
7.0
2.2
1.8
Arsenic
1.0
10.0
12.0
Cadmium
1 0.3
3.4
3.8
Copper
1 450.0
6.7
62.0
Chromium
Lead
1.9
6.7
7.7
Mercury
0.3
3.5
1 4.2
Molyb-
denum
2.6
27.0
31.0
Nickel
35.0
27.0
31.0
Selenium
1.3
13.0
15.0
Zinc
140.0
34.0
64.0
Total
Phos-
horus
800
39,000
3,900
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1 1
2
L4j5J
6j
7
81
91
10
11
12
_3j
y
DT/Ac./
App.
14
Event
0.17
0.27
0.39
Arsenic
0.000
0.005
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Cadmium
0.000
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.152
0.004
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.205
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.001
0.004
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Mercury
0.000
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.001
0.014
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
denum
Nickel
0.012
0.014
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Selenium
0.000
0.007
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Zinc
0.047
0.018
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.116
Total
Phos-
0.270
20.826
3.073
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
24.170
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-YF-07 Acres Utilized: 10.3
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 8.5443 Site #: WK-YF-07 Acres Permitted: 10.3
Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 6.0
Crop 1 Name: Small Grains Crop 1 Max. PAN: 95 Crop 2 Name: Crop 2 Max. PAN:
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4 �
o w
Z
o
?
?
ZZ
w Z
;
TKN
mg/kg
Z a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Oct
6000
6.95
0.169
Advance -Pierre
INC
1
0.4
1 11000
170
1 3.8
1.521
NA
S.G
Oct
30000
2.2
0.267
RVAF
INC
1
0.4
80000
450
9.1
17.250
NA
S.G
Oct
54000
1.8
0.394
Tyson -Wilkes
INC
1
0.4
36000
560
11
11.606
NA
S.G
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
0
90000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
30.378
0.000
Lime Applied
Annuallbs/acre
0.015
0.154
0.005
0.063
0.205
0.148
0.000
0.000
0.010
0.147
0.005
0.019
0.040
0.236
0.051
0.236
0.019
0.172
0.116
0.662
24.170
Date
lbs/ac
Prior Years Cumulative lbs/ac
Apr
4000
Current Cumulative lbs/ac
0.169
0.068
0.353
0.000
0.157
0.024
0.276
0.287
0.191
0.778
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
95
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 15.72
Permit #: WQ0038087 Cation Exchange Capacity (non 503 only): 8.8
Operator: Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series: Clifford
Acres Used: 22.3 Acres Permitted: 22.3 Site #: YK-YF-03 Field #: YK-YF-03
Residual Analysis Data (Heavy Metals and Total Phosohorus use m2/k2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
6/16/22
2
Tyson-
Wilkes
6/16/22
3
4
5
6
7
8
9
10 j
11
12
% Solids
2.2
1.8
Arsenic
10.0
12.0
Cadmium
3.4
3.8
Copper
6.7
62.0
Chromium
Lead
6.7
7.7
Mercury
3.5
4.2
Molyb-
denum
27.0
31.0
Nickel
27.0
31.0
Selenium
13.0
15.0
Zinc
34.0
64.0
Total
Phos-
horus
39,000
3,900
Annual Heavy Metal Field Loadings Walculated in Ibs/acre):
Total
1 1
2j
3j
L4j5J
6j
7
81
91
10
11
12
y
DT/Ac./
App.
14
Event
0.32
0.38
Arsenic
0.006
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Cadmium
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.004
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.004
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Mercury
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.017
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
denum
Nickel
0.017
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
Selenium
0.008
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Zinc
0.022
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.071
Total
Phos-
25.038
2.995
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
28.033
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: YK-YF-03 Acres Utilized: 22.3
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 15.7126 Site #: YK-YF-03 Acres Permitted: 22.3
Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 8.8
Crop 1 Name: Small Grains Crop 1 Max. PAN: 120 Crop 2 Name: Crop 2 Max. PAN:
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4 �
o w
Z
o
?
?
ZZ
w Z
;
TKN
mg/kg
Z a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Oct
78000
2.2
0.321
RVAF
INC
1
0.4
1 80000
450
1 9.1
20.716
NA
S.G.
Oct
114000
1.8
0.384
Tyson -Wilkes
INC
1
0.4
36000
560
11
11.317
NA
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
OF
192000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
32.033
0.000
Lime Applied
Annuallbs/acre
0.016
0.161
0.005
0.070
0.052
0.374
0.000
0.000
0.010
0.145
0.005
0.024
0.041
0.276
0.041
0.276
0.020
0.185
0.071
0.841
28.033
Date
lbs/ac
Prior Years Cumulative lbs/ac
April
4000
Current Cumulative lbs/ac
0.177
0.075
0.426
0.000
0.155
0.029
0.317
0.317
0.205
0.912
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
120
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 9.75
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
13.5 Acres Permitted: 13.5 Site #: YK-YF-01 Field #:
6.7
Nathalie
YK-YF-01
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
10/3/22
2
Tyson-
Wilkes
10/3/22
3
4
5
6
7
8
9
10 j
11
12
% Solids
2.2
2.2
Arsenic
11.0
10.0
Cadmium
3.6
3.5
Copper
7.6
43.0
Chromium
Lead
7.2
6.9
Mercury
3.5
3.6
Molyb-
denum
29.0
28.0
Nickel
29.0
28.0
Selenium
14.0
14.0
Zinc
36.0
80.0
Total
Phos-
horus
46,000
3,100
Annual Heavy Metal Field Loadings Walculated in lbs/acre):
Total
1 1
2
3
4
5J
6j
7
81
91
L01
11
12
y
DT/Ac./
App.
14
Event
0.36
0.36
Arsenic
0.008
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Cadmium
0.003
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.006
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.005
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Mercury
0.003
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.021
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
denum
Nickel
0.021
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
Selenium
0.010
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Zinc
0.026
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.084
Total
Phos-
33.304
2.232
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
35.536
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: YK-YF-01 Acres Utilized: 13.5
Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 9.7503 Site #: YK-YF-01 Acres Permitted: 13.5
Operator: Terra Renewal Services Predominant Soil Series: Nathalie Cation Exchange Capacity (non 503): 6.7
Crop 1 Name: Small Grains Crop 1 Max. PAN: 98 Crop 2 Name: Crop 2 Max. PAN:
0
Q
Volume applied
enter one Solids/
()
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4 �
o w
Z
o
?
?
ZZ
w Z
;
TKN
mg/kg
Z a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Nov
54000
2.17
0.362
RVAF
INC
1
0.4
1 75000
950
1 110
22.210
NA
S.G.
Nov
54000
2.16
0.360
Tyson -Wilkes
INC
1
0.4
53000
3400
97
16.816
NA
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
01
108000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
39.026
0.000
Lime Applied
Annuallbs/acre
0.015
0.209
0.005
0.090
0.036
0.596
0.000
0.000
0.010
0.188
0.005
0.028
0.041
0.353
0.041
0.358
0.020
0.239
0.084
1.117
35.536
Date
lbs/ac
Prior Years Cumulative lbs/ac
April
4000
Current Cumulative lbs/ac
0.224
0.095
0.632
0.000
0.198
0.033
0.394
0.399
0.259
1.201
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
F 98
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 29.21
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only): 5.1
Terra Renewal Services Owner: George F Ireland Trust Predominant Soil Series: Clifford
32.6 Acres Permitted: 32.6 Site #: WK-YK-DM-07 Field #: WK-YK-DM-07
Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft
Sample
or Com-
posite
Date
1
RVAF
10/3/22
2
Tyson-
Wilkes
10/3/22
3
4
5
6
7
8
9
10 j
12
% Solids
2.2
2.2
Arsenic
11.0
10.0
Cadmium
3.6
3.5
Copper
7.6
43.0
Chromium
Lead
7.2
6.9
Mercury
3.5
3.6
Molyb-
denum
29.0
28.0
Nickel
29.0
28.0
Selenium
14.0
14.0
Zinc
36.0
80.0
Total
Phos-
horus
46,000
3,100
Annual Heavy Metal Field Loadings Walculated in Ibs/acre):
Total
1 1
2
3
4
5J
6j
7
81
91
L01
11
12
y
DT/Ac./
App.
14
Event
0.37
0.53
Arsenic
0.008
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Cadmium
0.003
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
0.006
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.005
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Mercury
0.003
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Molyb-
0.021
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
denum
Nickel
0.021
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Selenium
0.010
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Zinc
0.026
0.085
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.111
Total
Phos-
33.672
3.286
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
36.958
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-YK-DM-07 Acres Utilized: 32.6
Land Owner: George F Ireland Trust Annual Dry Tons Applied: 29.2384 Site #: WK-YK-DM-07 Acres Permitted: 32.6
Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 5.1
Crop 1 Name: Small Grains Crop 1 Max. PAN: 120 Crop 2 Name: Crop 2 Max. PAN:
0
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
u
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(D�'
Wet
Moist)
Precip.
past 24
Hrs.
inches
a
4
o w
Z.°n
o
?
?
w
;
TKN
mg/kg
Z. a
a
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
Dec
132000
2.17
0.366
RVAF
INC
1
0.4
1 75000
950
1 110
22.482
NA
S.G.
Dec
192000
2.16
0.530
Tyson -Wilkes
INC
1
0.4
53000
3400
97
24.760
NA
S.G.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
0
3a4000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
47.242
0.000
Lime Applied
Annuallbs/acre
0.019
0.006
0.051
0.000
0.013
0.006
0.051
0.051
0.025
0.111
36.958
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.190
0.070
0.950
0.000
0.147
0.051
0.442
0.443
0.241
1.792
Apr
4000
Current Cumulative lbs/ac
0.209
0.076
1.001
0.000
0.160
0.057
0.493
0.494
0.266
1.903
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
F 120
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
2/28/2023 *Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically
digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

4
Laboratory Analyses:
- Nutrients, Metals, TCLP, Other

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: NC Samples
Lot Number:WL01015
Date Completed:01/26/2022
Revision Date: 01/19/2022
NIM�I�Mr�
01/27/2022 9:38 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 20

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: WL01015
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
This report supersedes all other versions of the same report.
Inorganic Metals
Due to the matrix and low percent solids, these samples had an initial weight that is 3x greater than
standard procedure: WL01015-001, WL01015-002, WL01015-003. The LOQ has been adjusted
accordingly.
Report Revision 01/27/22
Due to client request the % solids result was reanalyzed for sample -003. The sample yielded a lower
result and has been reported.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 20

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: WL01015
Sample Number Sample ID Matrix Date Sampled Date Received
001 Tyson/Willisboro Solid 11/30/2021 1130 12/01/2021
002 Tyson/Harmond
003 Advanced Foods/Claramont
(3 samples)
Solid 11/30/2021 1230 12/01/2021
Solid 11/30/2021 1430 12/01/2021
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 20

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: WL01015
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
001
Tyson/Willisboro
Solid
% Volatile Solids
SM 2540G-
98
%
8
001
Tyson/Willisboro
Solid
Ammonia - N (gas
350.1
1500
mg/kg
8
001
Tyson/Willisboro
Solid
Flashpoint (Pensky-
1010B
>140
° F
8
001
Tyson/Willisboro
Solid
Nitrate -Nitrite - N (soluble)
353.2
44
S
mg/kg
8
001
Tyson/Willisboro
Solid
Paint Filter Test
9095B
Fail
pass/fail
8
001
Tyson/Willisboro
Solid
Phosphorus
365.1
3700
S
mg/kg
8
001
Tyson/Willisboro
Solid
TKN
351.2
52000
S
mg/kg
8
001
Tyson/Willisboro
Solid
Aluminum
6010D
150
mg/kg
11
001
Tyson/Willisboro
Solid
Copper
6010D
27
mg/kg
11
001
Tyson/Willisboro
Solid
Zinc
601OD
38
mg/kg
11
002
Tyson/Harmond
Solid
% Volatile Solids
SM 2540G-
87
%
12
002
Tyson/Harmond
Solid
Ammonia - N (gas
350.1
12000
mg/kg
12
002
Tyson/Harmond
Solid
Flashpoint (Pensky-
1010B
>140
° F
12
002
Tyson/Harmond
Solid
Nitrate -Nitrite - N (soluble)
353.2
58
mg/kg
12
002
Tyson/Harmond
Solid
Paint Filter Test
9095B
Fail
pass/fail
12
002
Tyson/Harmond
Solid
Phosphorus
365.1
19000
S
mg/kg
12
002
Tyson/Harmond
Solid
TKN
351.2
59000
mg/kg
12
002
Tyson/Harmond
Solid
3+4-Methylphenol
8270E
0.83
mg/L
13
002
Tyson/Harmond
Solid
Aluminum
6010D
8100
mg/kg
15
002
Tyson/Harmond
Solid
Calcium
6010D
39000
mg/kg
15
002
Tyson/Harmond
Solid
Copper
6010D
13
mg/kg
15
002
Tyson/Harmond
Solid
Potassium
6010D
3600
mg/kg
15
002
Tyson/Harmond
Solid
Sodium
6010D
3700
mg/kg
15
002
Tyson/Harmond
Solid
Zinc
6010D
56
mg/kg
15
003
Advanced Foods/Claramont
Solid
% Volatile Solids
SM 2540G-
95
%
16
003
Advanced Foods/Claramont
Solid
Ammonia - N (gas
350.1
170
mg/kg
16
003
Advanced Foods/Claramont
Solid
Flashpoint (Pensky-
1010B
>140
'F
16
003
Advanced Foods/Claramont
Solid
Nitrate -Nitrite - N (soluble)
353.2
3.8
mg/kg
16
003
Advanced Foods/Claramont
Solid
Paint Filter Test
9095B
Fail
pass/fail
16
003
Advanced Foods/Claramont
Solid
Phosphorus
365.1
800
mg/kg
16
003
Advanced Foods/Claramont
Solid
TKN
351.2
11000
mg/kg
16
003
Advanced Foods/Claramont
Solid
Aluminum
6010D
3400
mg/kg
19
003
Advanced Foods/Claramont
Solid
Calcium
6010D
570
mg/kg
19
003
Advanced Foods/Claramont
Solid
Copper
6010D
450
mg/kg
19
003
Advanced Foods/Claramont
Solid
Lead
6010D
1.9
mg/kg
19
003
Advanced Foods/Claramont
Solid
Nickel
6010D
35
mg/kg
19
003
Advanced Foods/Claramont
Solid
Potassium
6010D
540
mg/kg
19
003
Advanced Foods/Claramont
Solid
Sodium
6010D
1700
mg/kg
19
003
Advanced Foods/Claramont
Solid
Zinc
6010D
140
mg/kg
19
(39 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-001
Description: Tyson/Willisboro Matrix: Solid
Date Sampled:11/30/2021 1130 % Solids: 4.96 12/03/2021 0215
Date Received:12/01/2021
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/07/2021 2024 MSG
24853
1 350.1
(Ammonia - N ) 350.1
2
12/06/2021 1541 DMA
24642
1
(Flashpoint () 1010B
1
12/08/2021 0850 KMC
24958
1
(Nitrate-Nitr) 353.2
1
12/04/2021 1640 AAB
24599
1
(Paint Filter) 9095B
1
12/10/2021 1118 KMC
1
(Phosphorus) 365.1
5
12/02/2021 1311 DMA
12/01/2021 1453 24173
1
(Reactive Cya) 7.3.3
1
12/03/2021 1030 AAB
12/02/2021 1117
1
(Reactive Sul) 7.3.4
1
12/08/2021 1626 SJL
12/02/2021 1117
1
(Soil pH meas) 9045D
1
12/12/2021 1927 NBW
25322
1 351.4
(TKN) 351.2
2
12/08/2021 1554 DMA
12/08/2021 1036 24899
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
98
%
1
Ammonia - N (gas diffusion)
350.1
1500
400
mg/kg
1
Flashpoint (Pensky-Martens Closed -Cup)
1010B
>140
140
o F
1
Nitrate -Nitrite - N (soluble)
353.2
44
S
4.0
mg/kg
1
Paint Filter Test
9095B
Fail
*
pass/fail
1
Phosphorus
7723-14-0
365.1
3700
S
500
mg/kg
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water @ 20.2 ° C
9045D
4.5
su
1
TKN
351.2
52000
S
2000
mg/kg
1
TCLP
Volatiles
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B 8260D
10 12/20/2021 1308 BWS
26259 12/07/2021 0012
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
Units
Run
Benzene
71-43-2
8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5
8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7
8260D
ND
0.050
mg/L
1
Chloroform
67-66-3
8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4
8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6
8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4
8260D
ND
0.010
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-001
Description: Tyson/Willisboro Matrix: Solid
Date Sampled:11/30/2021 1130 % Solids: 4.96 12/03/2021 0215
)ate Received:12/01/2021
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
78 70-130
1,2-Dichloroethane-d4
116 70-130
Toluene-d8
94 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E 1 01/10/2022 1828 CMF
12/10/2021 1730 25236 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
ND
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
87 37-129
2-Fluorophenol
54 24-127
Nitrobenzene-d5
72 38-127
Phenol-d5
73 28-128
Terphenyl-d14
100 10-148
2,4,6-Tribromophenol
108 41-144
TCLP Herbicides
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/8151A
8151A 1 12/16/2021 1602 DAL1
12/13/2021 0915 25336 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L 1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
55 50-112
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-001
Description: Tyson/Willisboro Matrix: Solid
Date Sampled:11/30/2021 1130 % Solids: 4.96 12/03/2021 0215
Date Received:12/01/2021
PCBs by GC
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3550C 366013/3665A 8082A 1 12/15/2021 2243 DAL1 12/03/2021 2140 24550
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Aroclor 1016
12674-11-2
8082A
ND
340
ug/kg
1
Aroclor 1221
11104-28-2
8082A
ND
340
ug/kg
1
Aroclor 1232
11141-16-5
8082A
ND
340
ug/kg
1
Aroclor 1242
53469-21-9
8082A
ND
340
ug/kg
1
Aroclor 1248
12672-29-6
8082A
ND
340
ug/kg
1
Aroclor 1254
11097-69-1
8082A
ND
340
ug/kg
1
Aroclor 1260
11096-82-5
8082A
ND
340
ug/kg
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
65 41-132
Tetrachloro-m-xylene
60 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 12/16/2021 1913 DAL1 12/10/2021 1700 25232 12/08/2021 1827
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC(Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
49 20-131
Tetrachloro-m-xylene
81 26-132
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/08/2021 0807 JAB2 12/08/2021 0331 24447
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 1.7
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-001
Description: Tyson/Willisboro Matrix: Solid
Date Sampled:11/30/2021 1130 % Solids: 4.96 12/03/2021 0215
Date Received:12/01/2021
TCLP Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3010A
6010D
1 12/10/2021 1230 KSH2
12/10/2021 0230 25139 12/08/2021 1827
1 1311/7470A
7470A
1 12/14/2021 1038 JAB2
12/14/2021 0642 25465 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2 6010D
ND
0.15
mg/L
1
Barium
7440-39-3 6010D
ND
0.25
mg/L
1
Cadmium
7440-43-9 6010D
ND
0.050
mg/L
1
Chromium
7440-47-3 601OD
ND
0.10
mg/L
1
Lead
7439-92-1 601OD
ND
0.10
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2 6010D
ND
0.20
mg/L
1
Silver
7440-22-4 6010D
ND
0.10
mg/L
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 12/03/2021 1115 KSH2
12/03/2021 0250 24274
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
150
130
mg/kg
1
Arsenic
7440-38-2 6010D
ND
4.8
mg/kg
1
Cadmium
7440-43-9 6010D
ND
1.6
mg/kg
1
Calcium
7440-70-2 6010D
ND
1600
mg/kg
1
Copper
7440-50-8 6010D
27
3.2
mg/kg
1
Lead
7439-92-1 601OD
ND
3.2
mg/kg
1
Magnesium
7439-95-4 6010D
ND
1600
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
13
mg/kg
1
Nickel
7440-02-0 601OD
ND
13
mg/kg
1
Potassium
7440-09-7 6010D
ND
1600
mg/kg
1
Selenium
7782-49-2 6010D
ND
6.4
mg/kg
1
Sodium
7440-23-5 6010D
ND
1600
mg/kg
1
Zinc
7440-66-6 6010D
38
16
mg/kg
1
Footnote(s): 'Paint Filter: 59mL collected;
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-002
Description: Tyson/Harmond Matrix: Solid
Date Sampled:11/30/2021 1230 % Solids: 3.81 12/03/2021 0215
Date Received:12/01/2021
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/07/2021 2024 MSG
24853
1 350.1
(Ammonia - N ) 350.1
10
12/06/2021 1417 DMA
24642
1
(Flashpoint () 1010B
1
12/08/2021 1006 KMC
24958
1
(Nitrate-Nitr) 353.2
1
12/04/2021 1645 AAB
24599
1
(Paint Filter) 9095B
1
12/10/2021 1118 KMC
1
(Phosphorus) 365.1
25
12/02/2021 1311 DMA
12/01/2021 1453 24173
1
(Reactive Cya) 7.3.3
1
12/03/2021 1043 AAB
12/02/2021 1117
1
(Reactive Sul) 7.3.4
1
12/08/2021 1626 SJL
12/02/2021 1117
1
(Soil pH meas) 9045D
1
12/12/2021 1928 NBW
25322
1 351.4
(TKN) 351.2
2
12/08/2021 1554 DMA
12/08/2021 1036 24899
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
87
%
1
Ammonia - N (gas diffusion)
350.1
12000
2600
mg/kg
1
Flashpoint (Pensky-Martens Closed -Cup)
1010B
>140
140
o F
1
Nitrate -Nitrite - N (soluble)
353.2
58
5.3
mg/kg
1
Paint Filter Test
9095B
Fail
pass/fail
1
Phosphorus
7723-14-0 365.1
19000 S
3300
mg/kg
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water @ 20.3 ° C
9045D
5.8
su
1
TKN
351.2
59000
2600
mg/kg
1
TCLP Volatiles
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B 8260D
10 12/20/2021 1333 BWS
26259 12/07/2021 0012
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-002
Description: Tyson/Harmond Matrix: Solid
Date Sampled:11/30/2021 1230 % Solids: 3.81 12/03/2021 0215
)ate Received:12/01/2021
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
80 70-130
1,2-Dichloroethane-d4
121 70-130
Toluene-d8
100 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E 1 01/12/2022 2303 CMF
12/10/2021 1730 25236 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
0.83
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
86 37-129
2-Fluorophenol
79 24-127
Nitrobenzene-d5
101 38-127
Phenol-d5
107 28-128
Terphenyl-d14
101 10-148
2,4,6-Tribromophenol
71 41-144
TCLP Herbicides
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/8151A
8151A 1 12/16/2021 1649 DAL1
12/13/2021 0915 25336 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L 1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
68 50-112
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-002
Description: Tyson/Harmond Matrix: Solid
Date Sampled:11/30/2021 1230 % Solids: 3.81 12/03/2021 0215
Date Received:12/01/2021
PCBs by GC
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3550C 366013/3665A 8082A 1 12/15/2021 2256 DAL1 12/03/2021 2140 24550
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Aroclor 1016
12674-11-2
8082A
ND
440
ug/kg
1
Aroclor 1221
11104-28-2
8082A
ND
440
ug/kg
1
Aroclor 1232
11141-16-5
8082A
ND
440
ug/kg
1
Aroclor 1242
53469-21-9
8082A
ND
440
ug/kg
1
Aroclor 1248
12672-29-6
8082A
ND
440
ug/kg
1
Aroclor 1254
11097-69-1
8082A
ND
440
ug/kg
1
Aroclor 1260
11096-82-5
8082A
ND
440
ug/kg
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
73 41-132
Tetrachloro-m-xylene
71 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 12/16/2021 1928 DAL1 12/10/2021 1700 25232 12/08/2021 1827
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC(Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
81 20-131
Tetrachloro-m-xylene
80 26-132
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/08/2021 0815 JAB2 12/08/2021 0331 24447
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 2.1
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-002
Description: Tyson/Harmond Matrix: Solid
Date Sampled:11/30/2021 1230 % Solids: 3.81 12/03/2021 0215
Date Received:12/01/2021
TCLP Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3010A
6010D
1 12/10/2021 1249 KSH2
12/10/2021 0230 25139 12/08/2021 1827
1 1311/7470A
7470A
1 12/14/2021 1051 JAB2
12/14/2021 0642 25465 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2 6010D
ND
0.15
mg/L
1
Barium
7440-39-3 6010D
ND
0.25
mg/L
1
Cadmium
7440-43-9 6010D
ND
0.050
mg/L
1
Chromium
7440-47-3 601OD
ND
0.10
mg/L
1
Lead
7439-92-1 601OD
ND
0.10
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2 6010D
ND
0.20
mg/L
1
Silver
7440-22-4 6010D
ND
0.10
mg/L
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 12/03/2021 1141 KSH2
12/03/2021 0250 24274
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
8100
170
mg/kg
1
Arsenic
7440-38-2 6010D
ND
6.5
mg/kg
1
Cadmium
7440-43-9 6010D
ND
2.2
mg/kg
1
Calcium
7440-70-2 6010D
39000
2200
mg/kg
1
Copper
7440-50-8 6010D
13
4.3
mg/kg
1
Lead
7439-92-1 601OD
ND
4.3
mg/kg
1
Magnesium
7439-95-4 6010D
ND
2200
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
17
mg/kg
1
Nickel
7440-02-0 601OD
ND
17
mg/kg
1
Potassium
7440-09-7 6010D
3600
2200
mg/kg
1
Selenium
7782-49-2 6010D
ND
8.7
mg/kg
1
Sodium
7440-23-5 6010D
3700
2200
mg/kg
1
Zinc
7440-66-6 6010D
56
22
mg/kg
1
Footnote(s): 'Paint Filter: 50ml- collected;
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-003
Description: Advanced Foods/Claramont Matrix: Solid
Date Sampled:11/30/2021 1430 % Solids: 6.95 01/24/2022 2259
Date Received:12/01/2021
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/07/2021 2024 MSG
24853
1 350.1
(Ammonia - N ) 350.1
1
12/06/2021 1419 DMA
24642
1
(Flashpoint () 1010B
1
12/08/2021 1040 KMC
24958
1
(Nitrate-Nitr) 353.2
1
12/04/2021 1647 AAB
24599
1
(Paint Filter) 9095B
1
12/10/2021 1118 KMC
1
(Phosphorus) 365.1
5
12/02/2021 1156 DMA
12/01/2021 1453 24173
1
(Reactive Cya) 7.3.3
1
12/03/2021 1032 AAB
12/02/2021 1117
1
(Reactive Sul) 7.3.4
1
12/08/2021 1626 SJL
12/02/2021 1117
1
(Soil pH meas) 9045D
1
12/12/2021 1932 NBW
25322
2 351.4
(TKN) 351.2
5
12/14/2021 1712 DMA
12/08/2021 1036 24899
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
95
%
1
Ammonia - N (gas diffusion)
350.1
170
41
mg/kg
1
Flashpoint (Pensky-Martens Closed -Cup)
1010B
>140
140
o F
1
Nitrate -Nitrite - N (soluble)
353.2
3.8
0.82
mg/kg
1
Paint Filter Test
9095B
Fail
pass/fail
1
Phosphorus
7723-14-0 365.1
800
100
mg/kg
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water @ 20.3 ° C
9045D
4.3
su
1
TKN
351.2
11000
1000
mg/kg
2
TCLP Volatiles
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B 8260D
10 12/20/2021 1358 BWS
26259 12/07/2021 0012
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-003
Description: Advanced Foods/Claramont Matrix: Solid
Date Sampled:11/30/2021 1430 % Solids: 6.95 01/24/2022 2259
)ate Received:12/01/2021
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
84 70-130
1,2-Dichloroethane-d4
122 70-130
Toluene-d8
101 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E 1 01/10/2022 1915 CMF
12/10/2021 1730 25236 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
ND
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
90 37-129
2-Fluorophenol
66 24-127
Nitrobenzene-d5
78 38-127
Phenol-d5
87 28-128
Terphenyl-d14
99 10-148
2,4,6-Tribromophenol
131 41-144
TCLP Herbicides
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/8151A
8151A 1 12/16/2021 1712 DAL1
12/13/2021 0915 25336 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L 1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
65 50-112
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-003
Description: Advanced Foods/Claramont Matrix: Solid
Date Sampled:11/30/2021 1430 % Solids: 6.95 01/24/2022 2259
Date Received:12/01/2021
PCBs by GC
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3550C 366013/3665A 8082A 1 12/15/2021 2309 DAL1 12/03/2021 2140 24550
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Aroclor 1016
12674-11-2
8082A
ND
69
ug/kg
1
Aroclor 1221
11104-28-2
8082A
ND
69
ug/kg
1
Aroclor 1232
11141-16-5
8082A
ND
69
ug/kg
1
Aroclor 1242
53469-21-9
8082A
ND
69
ug/kg
1
Aroclor 1248
12672-29-6
8082A
ND
69
ug/kg
1
Aroclor 1254
11097-69-1
8082A
ND
69
ug/kg
1
Aroclor 1260
11096-82-5
8082A
ND
69
ug/kg
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
72 41-132
Tetrachloro-m-xylene
69 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 12/16/2021 1944 DAL1 12/10/2021 1700 25232 12/08/2021 1827
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC(Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
79 20-131
Tetrachloro-m-xylene
66 26-132
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/08/2021 0817 JAB2 12/08/2021 0331 24447
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 0.31
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 20

Client: Terra Renewal Services, Inc. Laboratory ID:WL01015-003
Description: Advanced Foods/Claramont Matrix: Solid
Date Sampled:11/30/2021 1430 % Solids: 6.95 01/24/2022 2259
Date Received:12/01/2021
TCLP Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3010A
6010D
1 12/10/2021 1300 KSH2
12/10/2021 0230 25139 12/08/2021 1827
1 1311/7470A
7470A
1 12/14/2021 1054 JAB2
12/14/2021 0642 25465 12/08/2021 1827
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2 6010D
ND
0.15
mg/L
1
Barium
7440-39-3 6010D
ND
0.25
mg/L
1
Cadmium
7440-43-9 6010D
ND
0.050
mg/L
1
Chromium
7440-47-3 601OD
ND
0.10
mg/L
1
Lead
7439-92-1 601OD
ND
0.10
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2 6010D
ND
0.20
mg/L
1
Silver
7440-22-4 6010D
ND
0.10
mg/L
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 12/03/2021 1144 KSH2
12/03/2021 0250 24274
2 3050B
601OD
3 12/03/2021 1356 KSH2
12/03/2021 0250 24274
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
3400
26
mg/kg
1
Arsenic
7440-38-2 6010D
ND
0.96
mg/kg
1
Cadmium
7440-43-9 6010D
ND
0.32
mg/kg
1
Calcium
7440-70-2 6010D
570
320
mg/kg
1
Copper
7440-50-8 6010D
450
1.9
mg/kg
2
Lead
7439-92-1 6010D
1.9
0.64
mg/kg
1
Magnesium
7439-95-4 601OD
ND
320
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
2.6
mg/kg
1
Nickel
7440-02-0 6010D
35
2.6
mg/kg
1
Potassium
7440-09-7 6010D
540
320
mg/kg
1
Selenium
7782-49-2 6010D
ND
1.3
mg/kg
1
Sodium
7440-23-5 6010D
1700
320
mg/kg
1
Zinc
7440-66-6 6010D
140
3.2
mg/kg
1
Footnote(s): 'Paint Filter: 72mL collected;
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 20

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 20

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 20

PACE ANALYTICAL SERVICES, LLC
North Carolina Perrtnit Parameters
2, Rcsiduals a:iall be aoalyzoxl to they are - oura� Cpr�yefyatlou
ar_d RTtmvfjy Acr. (RCRA)_ 'Poe amijUp rrwivw V, [pliabibty, r�acii and toxicity
characiriatic lexclxi��g pxocedure TC sl�a 4y apacitied ku
4.tCer,hTnenl. A, aisd the Pcrmijae shall mfflin�xi l.Lww za ukr. :-3x a rtiini M of five years. Any
rxcePtia sT�s fir�»n tlae retluii aittieuts lu diLs vm litkm shall ixe specTicd ii A#tar.Lu=(A.
The TCLP awdygis shall include the Miming piErnmr-tcrs (th(,, in niftpms Per lit"
is it parenthpara};
LU
4
4
C}
�'sea.ic (5.0}
] ,�T}itilllorr�attiaene {7.5}
l�ikr4bene {2.0)
Pezimi lm-opbrM]. (100-0)
H nnum (] ODA)
1,2-Dichloroc brw (03)
T# nzgle {i}.5)
1.1-filchlaroe#hyLue (0.71
PyHdinc (5,0)
Selzer-Jm (1,0)
CaEVlriv (1-il)
2,4-Dhdtrota1ivac (0.13)
2,rb [e#sQcfikorida (CS)
Eridriu (0.02)
Sr1v (5-0)
ChlbrdsalC (0,01}
11exa&1urobcnacnc (0,;3)
Tetrae:7loroethyla (0. r)
-r~`liki obanzeita (100.0}
aAorcrfoiin (u_ 0)
1Sro iu�i (S.D'
egtaclli (aaud+tshydi xide) ; ToxaplYelae (U 5)
, i-bnrtadi (0.5) Tricaloroelhylene (0-5)
MCxlj.V 1{]rL1CL7MLUV (3.b1 2,%U-Tri&lvr4?4cal (400A)
meal Mob)
d ($.0) 7,4,6-Trir-}t'nnphcnoi (2,0)
v-Cr=Ql MOM)
Lindano (0.4)
2,4,5 ` P (Sslvox) (1-0)
p-Cresol (200-0)
-- Mcrc:uy (0.2)
Vinyl aliln6dde (0.2)
ao1(200.0)
Mr:iaQXWlk14u (10.0)
.2.s4-U. f10,01
h e#h l ttltyl kc,ttmo RO-0,0} --
._..
3_ An mab-sls shill be uvnduutel ar- residuals fbin each fourae gmicrating fkdhly at the tiapxmcy
Epeaifed in Alrachment A, and the I'ermiGtLIZ s13a11 j,a13Ll8i❑ Ole insults fir a-titrmum of live ycar&
The analysis shall inAudt the following pzxarnek+T;
Ablrninum -.
i
Am rionla-Nifmorn
Arsem
Cadrgum
calcium
( pGr
T rlcl
Magmsflm
WQ2036936 Yer6tin 1-D
1tiUmury
patasslum
MiAybdwum
Selr—uum
Nickel
Sodimu
1*x113�taNitrito �ltr�ger
T>i
Port: Total Solids
Ph
c
Fhosplxan,s
Volatile Solids
PCs!$
TERRA RENEWAL SERVICES
479 747-f I9?
31r,11 VffMan 140210
Pate 8 of 12
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 20

PACE ANALYTICAL SERVICES, LLC
Samples Receipt CheMist(5R3CI (MEj3aj w15j KeVL3e ,9/29f2020
. ace rr�r+yl,Caf t551-lii•Pkrthoiity_ Pace ENV • WCOL Page 1 ofi
aMPIC receipt C heddiSt (S'R
Client: araKerxnral Onaler lntpcvrM [;yi&,Lte- JI CiY 12rC11f21Y 1 I,cSti : WUJIO15
P
Pane GEjmt UPS Fecif;x Others V, No 1, Were CO80 i . seab PTeW 4311 fte coaltr7
s NU +� NA 2, if ;uEtotiw� scars were rep.ent, were they intact and unbrokcn7Ir1D-- `A C'1torirtr. St-ip ID= -` _ Teml by; r4rt
Wgi:na[ te.ntperdurz upon receipt? f)rrived (Corrected) Lemperaxtrc upon receipt %solid Suap-Cup [1): 3t-2bGl-2�G1
3.7 ++3.7 oe vli f Yiti rKA IKA oC NA fNA v�
Method: E[lamperatum Blank �--V]Againsr I.IotlicA IN Gan ID: III Our. Correc`c)n Far, -or; C `r~
Meal od 4�i 4x*hLut' U1 Wet 1 cr. ❑ 14'e Pa4❑ D r Ica ❑ Norre -
r IIf 1 t f of 4
❑ Yes
❑ Nu
I.Y I ]ri
- Cmpau urI I� awy CO et .,T,;, od G.v C, AwW; rnijCct fvlanager3Nlottlieol(
Pb1 wes ?dtxtifipd b}r� p}lorle f emlil I face-W-fact(cirr lz: nnp),
Yex
No
N,l
d. 15 1[le CClaruncruial CJuriel,'.s packing.0ip a7a0bed Lu this fora,'
zYes
71 Yes
Nu
�. Were proper custody procelimts (rel]nquishaYrcceived) fe€IOP cM
16. Were =ip[-u IDs AstLd on C-in C'f C?
_Yes
Yes
❑M
Na
7. % eJ%e sarn;,le 1D5 :israd w ill 8amp[c conminers?
&Was cu11Vticn date & time 144ud on the COO R_
yes
No
9. Was cullm4iun date & time I -Pled or, all sainpleconklinvrs7
J Ye~;
T'!o I
I0. Did all container Jabal j-0formation (I[}, date, lirae) ftgrcc wit1 Lila COC?
Q Yea
LANOI
I J J , WE't< tuts 0 be perfaimed listed on the C)OC4 -
❑ v's I LjNO
Yes No
Ycs No
El Yed '7No
1 i2- Did a.] samples arrive in Ihe. proper Mitainers fur cwh test aitdlar in goad conditias
(unroroken, lidw on, cri.`.);.
13. Was adequ* sa-1 [a vDlu1neavailubl.0
14- Wtwe JAI samples received wKin Vz the holding time or 48 hours, whEchcvcr caires J M- 0
15, Were zny 9pmplcE containers miFOngkxcess (circle Cnv) salrplc-e lent Iiajt�cl on f_,OC?
❑d NA 16. For VOA and RSK-L75 sialpies, wert�bubblw present "peg-tiiz#r" 4'ra"ar6inm in diam't
is any of the VOA Vlais?
V NA 17. Were all DROlmetali+nuLrient sam pies received at a pi of< 2?
[71NA 18- Wm a]I cywilde sarrmp'tM reooivcd at a Id > 121u1d suJ17c[r harm ley nxCi'v.d at a pH > 9`
A ..- . War all upp it a NI-kVTK Cyan +pliena i25. l: i j08.3 (-=z 0.5mg i) sarr.'p tFs rce of
20. VYCrC tilicllt rcmarkOracu�`� MS
ts (i.e- requrs(t:d dilutions, 1vtD des ig mtin is, etc...)
�❑ Yes ❑ ri;o �hi turrutly traimcri had Freff he COC into tie gammon[ seWon in LIMS?
Yes ND :-i, Was the UOleltumbcr Iister! tt7t INN: container label? I Fyvb,PUOLriv - —
5ample Preservation (I41ust he cl3mplet i ally s ,ply s} irt+rsarrcxtly preserved or wirtl headspace-)
Sarripia(h) m,' _. were t�eceivcd inmT-crtly presenTedand wcre adjusted a000rJ:rr',
in sample re+caiv[rtgW[1FI K mL Dfc'_rcle nr_o; fi I� O4, HNQ3, I✓]CI, hiu0li u�iur It! 1 t _
T' me of preseryanon If more OM OPreserve V-e is n"&d, p Icasv 11111E in Fit- ccxiiments below.
NA - - -
were reeeimil with bubbles >6 rnm ifS diarrML
tnples(s) NA wcre received with TKC m&+L (I f 4 J 9 is fJ{P ; and tyere
lu5CWkAUcord1ng1y ir, gamllk{ m0eiving wl[it sodium thiouiitsre(Na�S20x1vtitil 811eaJy 1D; A
bwtrnit lxbrls Hllplied by_ JR43Z UBP
Conlint:'aI.5;
0041: 129)Z12Q21
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 20

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: Mathis-1
Lot Number:WL10011
Date Completed:12/31/2021
NIM�I�Mr�
01/04/2022 8:49 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page Iof10

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: WL10011
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation:
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium,
Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal
Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 601 OD, VOC SM 6200 B-2011,
Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid
Chemical Material: TOC Walkley-Black.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to the matrix and low percent solids, the following samples have an initial weight that is 3x greater
than standard procedure: WL10011-001. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
The following sample was analyzed outside of analytical holding time: WL10011-001. Sample has been
qualified with an "H" accordingly.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 10

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: WL10011
Sample Number Sample ID Matrix Date Sampled Date Received
001 Mathis-1 Solid 12/08/2021 1630 12/10/2021
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of10

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: WL10011
Sample Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
Mathis-1
Solid
% Volatile Solids
SM 2540G-
95 BH
%
5
001
Mathis-1
Solid
Ammonia - N (gas
350.1
17000
mg/kg
5
001
Mathis-1
Solid
Nitrate -Nitrite - N (soluble)
353.2
34 S
mg/kg
5
001
Mathis-1
Solid
Phosphorus
365.1
7000
mg/kg
5
001
Mathis-1
Solid
TKN
351.2
48000
mg/kg
5
001
Mathis-1
Solid
Aluminum
601OD
3100
mg/kg
6
001
Mathis-1
Solid
Calcium
601OD
11000
mg/kg
6
001
Mathis-1
Solid
Copper
601OD
56
mg/kg
6
001
Mathis-1
Solid
Potassium
601OD
3000
mg/kg
6
001
Mathis-1
Solid
Sodium
601OD
1600
mg/kg
6
001
Mathis-1
Solid
Zinc
601OD
110
mg/kg
6
(11 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:WL10011-001
Description: Mathis-1 Matrix: Solid
Date Sampled:12/08/2021 1630 % Solids: 8.54 12/13/2021 2328
Date Received:12/10/2021
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
12/16/2021 1929 GAH
25969
2 350.1
(Ammonia - N) 350.1
50
12/30/2021 2230 DAK
27046
1
(Nitrate-Nitr) 353.2
1
12/17/2021 1118 AAB
26061
1
(Phosphorus) 365.1
25
12/14/2021 1219 DMA
12/11/2021 1559 25306
1
(Soil pH meas) 9045D
1
12/12/2021 2001 NBW
25322
1 351.4
(TKN) 351.2
5
12/15/2021 1757 DMA
12/15/2021 1231 25672
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
95 BH
%
1
Ammonia - N (gas diffusion)
350.1
17000
5900
mg/kg
2
Nitrate -Nitrite - N (soluble)
353.2
34 S
2.3
mg/kg
1
Phosphorus
7723-14-0 365.1
7000
1500
mg/kg
1
Soil pH measured in water C) 20.6 ° C
9045D
5.4
su
1
TKN
351.2
48000
2900
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/16/2021 2245 DAL1
12/12/2021 1825 25318
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
200
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
200
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
200
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
200
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
200
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
200
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
200
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
70 41-132
Tetrachloro-m-xylene
70 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/20/2021 0551 JAB2 12/20/2021 0225 25655
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 0.90
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:WL10011-001
Description: Mathis-1 Matrix: Solid
Date Sampled:12/08/2021 1630 % Solids: 8.54 12/13/2021 2328
Date Received:12/10/2021
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 12/21/2021 0800 JMH 12/20/2021 0042 26150
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
601OD
3100
73
mg/kg
1
Arsenic
7440-38-2
6010D
ND
2.7
mg/kg
1
Cadmium
7440-43-9
6010D
ND
0.91
mg/kg
1
Calcium
7440-70-2
6010D
11000
910
mg/kg
1
Copper
7440-50-8
6010D
56
1.8
mg/kg
1
Lead
7439-92-1
6010D
ND
1.8
mg/kg
1
Magnesium
7439-95-4
6010D
N D
910
mg/kg
1
Molybdenum
7439-98-7
6010D
N D
7.3
mg/kg
1
Nickel
7440-02-0
6010D
ND
7.3
mg/kg
1
Potassium
7440-09-7
6010D
3000
910
mg/kg
1
Selenium
7782-49-2
6010D
ND
3.7
mg/kg
1
Sodium
7440-23-5
6010D
1600
910
mg/kg
1
Zinc
7440-66-6
6010D
110
9.1
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure
Page 6 of 10

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 10

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 10

PACE ANALYTICAL SERVICES, LLC
North Carolina Permil Parameters
2 Xis duab stall be znalyzed w demmatraou dvti y are Conservation
at•.! RecorCTY Act {11-CF ti TM atgogj
requerrc�r specified in
A 't;dhUCKt A, t[1r1 tln Parmitt431e shill rnfi.lALu '.h, €w msulfs for a miuilmar- of five years. Any
cxceptiow f':om the rcLjmT% melt8 is this. coi4r Loa bliAll by specified in Attacla:amtA
,Ijle nmlysis sh211 b'cluiimU folly ILS rrarrmefM Me. ftlUkt ry level mmilEigramr per liter
A in =enamu a},
3_ AP aataiysis half WU&Qted Ct -cddt�als froul Moh 5ourac mratjng S cility at Jl e fctgjrwV
gpeciii&i iu A=lamerr, A, armi the Jtrmittm shall M1911tAL dir, resttlts fcr Z MinUMI t Df five yeas
the a-7atlysis sltaU iiuclude tLL: t'I)llowng panjbetuer&
W�
Atulvieum
pA��nuniH-I�tseq
AEawdc
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W
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W
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t~
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F___MO7y1_"deI31)Fn
9cl�tiium
Nirlcol
Sodium
Nitrate_Mitrite itrog=
1P=Mf TOW Solids
TKN
F
i.ro
]P7l�orx
volatile Solids
P B's
TERRA RENEWAL SERVICES
479-747-8102
.�1#I�cllmen�taC�C#ar_._..S4M1roe9: I
_ Date- a x R 4
WQ003035 Va7sion I'() L
Shall Veisian 1407 iO 1a­_ R of t)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 10

PACE ANALYTICAL SERVICES, LLC
Samples Receiprt Cherldist (5RCI 1ME00-18t-i5) Revised;9/29/2020
acGrlrwh lice I55uing,5.uthority: Pace ENV -buCOL Pagelof 1
aMPIC Receipt Checklist1� (SRC)
-client; Tcrr, ,:neY+f.l Copier Inspected byldu�u 2 '= ]MQ'202; Lts[.r. w..ICptl
[+4ceuts u-rec4:pt: LJ P-,3 M j lChcrilt A UPS U 1edEar
Yes ,-" 'No' :, WCF4; c-jsmd ' @fills pre�cnt iin Ole cooleO
Yes' No J NA 'Z If wst0dY sells wcrc prs�ert, wok rlijy intact and unrirokerj?
I I [ Scrip 10: KA Chlorine Strip JD: NA 1'Cstod by NA _
Oi:433a'. kmperatore 11pow rers:ipt! Derived (i'o:rected) Innipvratare nrpm receipt lyn; p[ ad Snap -Cap ID; 21-2"J
}.3 I'4,3 wC NA eNA DC 1+A ,HA eC, *lit {:lA o-C
Method: Temperature [3;r,nk J k iRst 13octles Jlt Ulm 1D IR Otert Coribution factor u °C
Method a s:oulan� Wei lop L1 Ice JjUks ❑ DTv fcc Ej �logra
❑ Yes ONO RINA 3• Jf 1.eml,ex,9nav {of mny cooler e:sceeded 6,0°C, k4as PrtsjeCt Mara r Notified?
1'M why Nod ied ay: phorc l email f face-t,rface (6T.r]e 0]10)-
w Yes Nc, QNA14. ]s the s rnmercia] vaunts: `s paeki slip rrt4rr;hcd ro this form'
Yes
No
15, iueVc Prtrper cu€.Inrly rocaduruy (relinquisYi lrec ivcr�) follavred`I
7W
Ll No
6. WOro sample Jds 11Stac On the CO M �—
YL-3
!No
7, 11 ere sm. p [a I Ds '-Jstcd ar al] aam>r le coiswhers?
YGS
No
hdo
S, W;4 cvliact]on d2dc time listed on dse COG.
9. Was celloction EO,; & tame listed On all sampie onnta:ase,4?
Yew
ties
No.
o
10. Did all 4=tainar :al,rl ii3fofrtation (ID. date, time) agrL:: with Uw CC]C7
l I , WMe E tasis to be performed listed 4n the COC?
YES
=Y05N-a
12- Drd all sainp;w arrive in tnc prop,- ::ontainerm fair mHc7 lest unWar is goad oudillan
(unbraken, lids i3rl,
13, Was arkxluaoa ;m"PI volunse available?Li —
Yes 0 14ri 14. Were all samples rmoived witltiirl Y2 tht: bolding time tw 48 'ioufb, wh.ic:iever:0ms s fir.
Yes No 15. Were an snmplCs containers Ini sine}ckceas(circle ogle) s,-rmples Nor IUcd oil Mr.?
LJ Yes ❑No7iXt 16. For VDA U.d RSK-175 �aruples, were bubbles present >"pea-siu'° ('l,"nr 6rnr11 in dlan
inarry oftl;e VDA vials?
Yes No VIN A I ?. Were all : KLVm�ta Isrnutrienr sash lea ved at a pH of = 27
yes No �'NA t R. Wer a a:l Cyanide 58c, Ics rece ivej Ara I3 > 12 and s u tf-A, yarn Les Mcoivxc at a pJi >
Q Ye5 J Na ❑7 fA I`, 1"fere all app]rca a NHx,'f h[,'C an tde p -c all 5, IJ6G8,3 G.3rngfl,) samples fC�s o:
�] Ces No �h1q 20` Wr rc client remar{cs,'rqup2t (i,e, rtquesl.d di]u+irmM, MSI)IST) �csi a2icns, sate.
correctly rranS"Ibcd frarn the COC iirur ll:tr c:arnmetrr..kecton in LJhr1S?
Yes LJ , J O I
12l. W;15 the quKirr n„Tnb5r iistod on the Ifyt;2, < 1130,-
mple Preservatsun (Mint ht~ completed for any samplz(.$) incorrcctl}' pnes�ved or w illi hcadspace.)
rnple(s) OJA WM Jr-wived uwturect=y pm�t+rwd and were ad�ssred accordingly
stunpi0 Fecnivinp., %]th EA _ mL of sFircla Ana, MSO4: 21N01, HCI, T+Tu01'i using SR P, 14A tre of preser"Hon 1`A TfMMOMttlais wtv prmeruatiue is needt�,l, please note in the =nmv_nm below,
NA
were r'eoc;ivedwith b-bbles:•6 min h diametcr.
41 Vl` k] ) - -- - wen rcccived with '1'RC > 0.5 mglL (lf *W14 is rro) and were
Ins;" accardingiy its sa mP1Pm rec-irinE, tyir]i srldium #JiitlfuIfaLL: with S11=1v 11)r err
harerr,-le labels HppJied by, JRG2
commerts.
Dblr: 171iV+f9Ql
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 10

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: NC Samples
Lot Number:XC23012
Date Completed:04/19/2022
Revision Date: 04/19/2022
NIM�I�Mr�
05/04/2022 11:35 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page Iof12

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XC23012
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 601 OD, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
This report supersedes all other versions of the same lot number
Inorganic Non -Metals
The method blank for prep batch 36105 contained the analyte total phosphorus greater than the method
acceptance criteria. The associated samples, contained detections for this analyte at concentrations
greater than 1 OX the value found in the method blank; therefore sample results are not impacted.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 12

Client: Terra Renewal Services, Inc. Laboratory ID:XC23012-001
Description: Tyson/Hammony Matrix: Solid
Date Sampled:03/22/2022 1100 % Solids: 1.40 03/24/2022 2321
Date Received:03/23/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
03/29/2022 2315 CVR
36466
1 350.1
(Ammonia - N) 350.1
10
03/29/2022 1805 DRD
36265
1
(Nitrate-Nitr) 353.2
1
03/29/2022 1631 KKP
36559
1
(Phosphorus) 365.1
10
03/28/2022 1316 DMA
03/25/2022 1354 36105
1
(Soil pH meas) 9045D
1
04/08/2022 1141 KMC
37634
1 351.4
(TKN) 351.2
1
03/26/2022 1719 DMA
03/25/2022 0000 36081
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
87
%
1
Ammonia - N (gas diffusion)
350.1
26000
7200
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
150
14
mg/kg
1
Phosphorus
7723-14-0 365.1
29000
3600
mg/kg
1
Soil pH measured in water C) 16.2 ° C
9045D
5.5
su
1
TKN
351.2
83000 S
3600
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 03/29/2022 2159 NCM
03/25/2022 1331 36088
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
1200
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
1200
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
1200
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
1200
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
1200
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
1200
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
1200
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
92 41-132
Tetrachloro-m-xylene
84 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 03/29/2022 0616 JAB2 03/29/2022 0421 36118
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 5.7
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 12

Client: Terra Renewal Services, Inc. Laboratory ID:XC23012-001
Description: Tyson/Hammony Matrix: Solid
Date Sampled:03/22/2022 1100 % Solids: 1.40 03/24/2022 2321
Date Received:03/23/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 03/28/2022 1050 KSH2 03/25/2022 0957 36071
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
18000
460
mg/kg
1
Arsenic
7440-38-2
6010D
ND
17
mg/kg
1
Cadmium
7440-43-9
6010D
ND
5.8
mg/kg
1
Calcium
7440-70-2
6010D
88000
5800
mg/kg
1
Copper
7440-50-8
6010D
22
12
mg/kg
1
Lead
7439-92-1
6010D
ND
12
mg/kg
1
Magnesium
7439-95-4
6010D
ND
5800
mg/kg
1
Molybdenum
7439-98-7
6010D
ND
46
mg/kg
1
Nickel
7440-02-0
6010D
ND
46
mg/kg
1
Potassium
7440-09-7
6010D
8000
5800
mg/kg
1
Selenium
7782-49-2
6010D
ND
23
mg/kg
1
Sodium
7440-23-5
6010D
9700
5800
mg/kg
1
Zinc
7440-66-6
6010D
130
58
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure
Page 4 of 12

Client: Terra Renewal Services, Inc. Laboratory ID:XC23012-002
Description: Tyson/Wilkesboro Matrix: Solid
Date Sampled:03/22/2022 1130 % Solids: 2.65 03/24/2022 2321
Date Received:03/23/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
03/29/2022 2315 CVR
36466
1 350.1
(Ammonia - N) 350.1
2
03/29/2022 1809 DRD
36265
1
(Nitrate-Nitr) 353.2
1
03/29/2022 1633 KKP
36559
1
(Phosphorus) 365.1
5
03/28/2022 1247 DMA
03/25/2022 1354 36105
1
(Soil pH meas) 9045D
1
04/08/2022 1142 KMC
37634
1 351.4
(TKN) 351.2
2
03/26/2022 1746 DMA
03/25/2022 0000 36081
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
98
%
1
Ammonia - N (gas diffusion)
350.1
2300 S
760
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
71
7.6
mg/kg
1
Phosphorus
7723-14-0 365.1
3500
940
mg/kg
1
Soil pH measured in water C) 17.1 ° C
9045D
4.9
su
1
TKN
351.2
69000
3800
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 03/29/2022 2212 NCM
03/25/2022 1331 36088
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
630
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
630
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
630
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
630
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
630
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
630
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
630
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
87 41-132
Tetrachloro-m-xylene
83 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 03/29/2022 0619 JAB2 03/29/2022 0421 36118
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 2.9
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 12

Client: Terra Renewal Services, Inc. Laboratory ID:XC23012-002
Description: Tyson/Wilkesboro Matrix: Solid
Date Sampled:03/22/2022 1130 % Solids: 2.65 03/24/2022 2321
Date Received:03/23/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 03/28/2022 1125 KSH2 03/25/2022 0957 36071
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
ND
240
mg/kg
1
Arsenic
7440-38-2
6010D
ND
9.0
mg/kg
1
Cadmium
7440-43-9
6010D
ND
3.0
mg/kg
1
Calcium
7440-70-2
6010D
ND
3000
mg/kg
1
Copper
7440-50-8
6010D
59
6.0
mg/kg
1
Lead
7439-92-1
6010D
ND
6.0
mg/kg
1
Magnesium
7439-95-4
6010D
ND
3000
mg/kg
1
Molybdenum
7439-98-7
6010D
ND
24
mg/kg
1
Nickel
7440-02-0
6010D
ND
24
mg/kg
1
Potassium
7440-09-7
6010D
ND
3000
mg/kg
1
Selenium
7782-49-2
6010D
ND
12
mg/kg
1
Sodium
7440-23-5
6010D
ND
3000
mg/kg
1
Zinc
7440-66-6
6010D
85
30
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure
Page 6 of 12

Client: Terra Renewal Services, Inc. Laboratory ID:XC23012-004
Description: Mathis Matrix: Solid
Date Sampled:03/22/2022 1230 % Solids: 1.28 03/24/2022 2321
Date Received:03/23/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
03/29/2022 2315 CVR
36466
1 350.1
(Ammonia - N) 350.1
50
03/29/2022 1815 DRD
36265
1
(Nitrate-Nitr) 353.2
1
03/29/2022 1636 KKP
36559
1
(Phosphorus) 365.1
10
03/28/2022 1247 DMA
03/25/2022 1354 36105
1
(Soil pH meas) 9045D
1
04/08/2022 1145 KMC
37634
1 351.4
(TKN) 351.2
5
03/26/2022 1733 DMA
03/25/2022 0000 36081
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
70
%
1
Ammonia - N (gas diffusion)
350.1
140000
39000
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
200
16
mg/kg
1
Phosphorus
7723-14-0 365.1
22000
3900
mg/kg
1
Soil pH measured in water @ 15.9 ° C
9045D
5.1
su
1
TKN
351.2
220000
20000
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 03/29/2022 2239 NCM
03/25/2022 1331 36088
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
1300
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
1300
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
1300
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
1300
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
1300
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
1300
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
1300
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
87 41-132
Tetrachloro-m-xylene
82 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 03/29/2022 0624 JAB2 03/29/2022 0421 36118
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 5.8
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 12

Client: Terra Renewal Services, Inc. Laboratory ID:XC23012-004
Description: Mathis Matrix: Solid
Date Sampled:03/22/2022 1230 % Solids: 1.28 03/24/2022 2321
Date Received:03/23/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 03/28/2022 1134 KSH2 03/25/2022 0957 36071
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
ND
500
mg/kg
1
Arsenic
7440-38-2
6010D
ND
19
mg/kg
1
Cadmium
7440-43-9
6010D
ND
6.3
mg/kg
1
Calcium
7440-70-2
6010D
38000
6300
mg/kg
1
Copper
7440-50-8
6010D
56
13
mg/kg
1
Lead
7439-92-1
6010D
ND
13
mg/kg
1
Magnesium
7439-95-4
6010D
ND
6300
mg/kg
1
Molybdenum
7439-98-7
6010D
ND
50
mg/kg
1
Nickel
7440-02-0
6010D
ND
50
mg/kg
1
Potassium
7440-09-7
6010D
25000
6300
mg/kg
1
Selenium
7782-49-2
6010D
ND
25
mg/kg
1
Sodium
7440-23-5
6010D
13000
6300
mg/kg
1
Zinc
7440-66-6
6010D
300
63
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure
Page 8 of 12

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 12

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 12

PACE ANALYTICAL SERVICES, LLC
Ar f+SarnRfes ReceipIt Cherkiist isRq (ME.DO_jgC j3}
Ca71 issuirffAuthorlty;fyacaFI-WC70L ��vlsQd-9l2�f�4;q
Sample Receipt C becklist (SRC) oft
Client. Tk^ra crra�l C,oIprIrs t i b ldutc;
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y43 too d NA 2. If cwtLyay sea[s ware •resottt, were O)a intm and urbmknn7
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8 PtL-H vc I; as receipt [t on-O mod) tAtnpe_r;tttrE II rccpip[ °nRnlid Snsp-CupID. a
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M4.1had 4corllant — IR Gain Co[�rxtian race °C
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171 yes QNo ONA ' [f temperawrc a F-mty :;evier egoeeded 6_0°G', wst Project Mranager Itiotircd?
libl vkas Notifiph
eri Icy: (rbe i Dora iJ 1 tac�to-fauc. {Circle Doe}.
yes Ala NAic dte anrr 3erCi; nuriar'S pack.ng slip Hitichexi to lair farm^
'cs No 3_ Weir furo r CuSfpdJv roucdurrs {rclinqu�the�lr,��ived) fiallc�wed?
,e Yes Na - Were sa[n*r[k. ]ih'_istan on t:lc
Yam; 7, 1'r'erc salirpiw 1DS listed on afl samplc conti�
Yes No R WLi ca11Cct'011 date & tiufe'isreda:t the GUC?
Yrs Nei 4, Was Cal Icutiotl date $time listed rn> all ram !a �
10. DF4 all can;a ne, bcl infi-m-nat--un (11), date, t[rnel8g,tc wi Jf ll,c CC,rL M7 yea No 1 -_ Wcfe tarts is be performed iisred a r the Ct}C
O Yes Lj N t, i ] 2. 1 ii a] I sa lttp4es arylye in the Pr". currta[n err for eneh test atfdllrn i n food ti4md]ripZ
(anbrukt� lids out, ctc.p _
atdegnptc sanipia vcalunte ayattabJe? —
Ye. , Tin 1-0. +Nero AJJ s urt ' receiveEWE r tJte I:❑ld'uig tirn or 48 hnw"s, whidwwr mines f[rst'x
Yes +r No I. V4'cre any sar»[es con [aif,crs�issingrcxcessy iCirCle; Due lair_ I lot [isred onQL�
yc []Aiu OMB ]b, i4er V0.4 un Rol{, iT.i salnles +wc re bubbles pre9enl°° sc-sixe" r 6rom in diautiWcr} rrI any of [lot; VOA vials? (J °o
Yes 1Ia , NA i 7, Werc a]] DkOlttie�'�il,+nutrient sa_rI Ins re, eiaix[ at a pH of < 2?
yes Nu V 1*fA 18. LVere all
4:}'a13IiiC SarRrl€S rs'apivrrl at a �u .ti 1-1 .....r
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O Elio NA ] Wert all appljk 7jvJe ti�13111 K N1cyarei a 1phe3nv]1 LS.1lt)vg.3 fl��5me�fLC sarn esaf Cc o:
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co�r ctl ' t1 Anscril,ea rM TIC jIC into ilic co[nmen[ "ctipg in I.;Tv15?
Yc: 7i. k4ru tfe uo$ontunhe: listul on thecontainel iaLel_
3�Iraple Pre ur4 tion ;M1ust be Damplcted for any sPr4p]c(s) hoorrect[-y preserved or widi h"dspaae.j�
s7�innlc�rl N� — —
'FJS
tvcfc rezin-ved in-correr,*;y prIUSOMM and vt am 44tisLcd accord. ti
s�erupie receiving 1%11h YA mL ofcircJe ortc: 1T`2 4, HNO.;, Her, NaoH tisiV SR 4 NA
Time ofpreservptian If more than one pjeSar+dti%1= is redi d, please note in tfte c�amtxenxs he;low,
SdmpJ�[s} nra,
+rare received Yvith bubbles >6 runt ill cli;�Y�r,
were coci Ve3C[ wish TTtC > U, 5mWL
jusaed asoortiiagly in sample receriving w�iJr sodi4Yi til iusu lfaw r O with Shea]}• I If iil4 is rrn j and vrcre
R hjuride app,icd by: KIO _ 03�z31xm.� �^ —
DatC:
CuramenlB; — —
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 12

PACE ANALYTICAL SERVICES, LLC
North Carolina Permit ParamaterB
2, Rc iduals shal be analyr$d fn demoiwt am they am urge C jnr mvcdion
Rat Rmoycry Act (1{L'.RA). The anal N
tiha �xcy spacified -tl
Attachr -t A, and the I'm itma shall maintain thcso rmsults for a mfiiramu of fi-ve vears— Aby
V. muxions am he rcquircmesits :n this Oecdi;ioii ShQU ktl. sp�-OifA in A*chmmt k
Thc�+iaiysis shall include the fnllovong param tors (do regulatory 143%r6 in milligratra per filer
is in parmthcscsy.
An arily8ia shall N, cundtiecd on residuals fO3M eQPh Wt�-Oc grncradug faoILy at the f_-egLenev
specified in Attaohrnorrt k &Ld the RTaittee small anain�--4n. the rcsulta f+x a minim m of firwc }scars,
The -artalyst5 shall irxcludc the foUow�ng pR:tmeters
ZA
l tmiirL4M
-
Awmrmi a-Nitrog-cu
A sen [e
[�
[ adimrur
W_
{ ��ICtIE�II
Copper
Lard
-.1viagrtesirmt
- l+Zr;!uiy
Maiybdenum
Nickl
NiTt'ate-Nitrii7e-4trugea
1'erMIL Total, Solidi
PH
Sodium
7
ftrc
nLo&pbrjnw lfolatila Solids
P B's
TERRA RENEWAL SERVICES
47�-747-aW
Atlachment bo OOC far,,...&wrce%: _. Date }
WQOO�6936 Veisina 1_0
5h&El Vt9ti-M 14O2LO
Fagc & of 12
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 12

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Lot Number:XF17004
Date Completed:07/05/2022
NIM�I�Mr�
07/07/2022 4:59 PM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page Iof14

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XF17004
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Non -Metals
The pH of sample XF17004-002 came to 3.9 which is outside the range of the pH meter. Therefore, a pH
1 Buffer Standard was read but failed to meet its true value. Results will be reported.
The method blank for prep batch 45640 contained the analyte total phosphorus greater than the method
acceptance criteria. The associated samplescontained detections for this analyte at concentrations
greater than 1 OX the value found in the method blank; therefore sample results are not impacted.
Inorganic Metals
Due to the matrix and low percent solids, the following samples have an initial weight that is 3x greater
than the standard procedure: XF17004-001, XF17004-002, XF17004-003. The LOQ has been adjusted
accordingly.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvww.pacelabs.com
Page 2 of 14

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XF17004
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
TYSON/ HARMONY
Solid
06/16/2022 0230
06/17/2022
002
TYSON/ WILKSOBORO
Solid
06/16/2022 0300
06/17/2022
003
MATHIS STORAGE WILL
Solid
06/16/2022 0330
06/17/2022
(3 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of14

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XF17OO4
Sample Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
TYSON/ HARMONY
Solid
% Volatile Solids
SM 2540G-
76
%
5
001
TYSON/ HARMONY
Solid
Phosphorus
365.1
39000
mg/kg
5
001
TYSON/ HARMONY
Solid
TKN
351.2
80000 S
mg/kg
5
001
TYSON/ HARMONY
Solid
Aluminum
6010D
4500
mg/kg
6
001
TYSON/ HARMONY
Solid
Calcium
6010D
90000
mg/kg
6
001
TYSON/ HARMONY
Solid
Potassium
6010D
10000
mg/kg
6
001
TYSON/ HARMONY
Solid
Sodium
6010D
12000
mg/kg
6
002
TYSON/ WILKSOBORO
Solid
% Volatile Solids
SM 2540G-
98
%
7
002
TYSON/ WILKSOBORO
Solid
Nitrate -Nitrite - N (soluble)
353.2
11
mg/kg
7
002
TYSON/ WILKSOBORO
Solid
Phosphorus
365.1
3900
mg/kg
7
002
TYSON/ WILKSOBORO
Solid
TKN
351.2
36000
mg/kg
7
002
TYSON/ WILKSOBORO
Solid
Aluminum
6010D
850
mg/kg
8
002
TYSON/ WILKSOBORO
Solid
Copper
6010D
62
mg/kg
8
002
TYSON/ WILKSOBORO
Solid
Zinc
6010D
64
mg/kg
8
003
MATHIS STORAGE WILL
Solid
% Volatile Solids
SM 2540G-
92
%
9
003
MATHIS STORAGE WILL
Solid
Ammonia - N (gas
350.1
12000 S
mg/kg
9
003
MATHIS STORAGE WILL
Solid
Nitrate -Nitrite - N (soluble)
353.2
1.9
mg/kg
9
003
MATHIS STORAGE WILL
Solid
Phosphorus
365.1
2800
mg/kg
9
003
MATHIS STORAGE WILL
Solid
TKN
351.2
21000
mg/kg
9
003
MATHIS STORAGE WILL
Solid
Aluminum
6010D
930
mg/kg
10
003
MATHIS STORAGE WILL
Solid
Calcium
6010D
3800
mg/kg
10
003
MATHIS STORAGE WILL
Solid
Copper
6010D
9.5
mg/kg
10
003
MATHIS STORAGE WILL
Solid
Potassium
6010D
2400
mg/kg
10
003
MATHIS STORAGE WILL
Solid
Sodium
6010D
870
mg/kg
10
003
MATHIS STORAGE WILL
Solid
Zinc
6010D
25
mg/kg
10
(25 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XF17004-001
Description: TYSON/ HARMONY Matrix: Solid
Date Sampled:06/16/2022 0230 % Solids: 2.20 06/19/2022 1843
Date Received:06/17/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
06/22/2022 2114 CVR
45863
1 350.1
(Ammonia - N) 350.1
1
06/22/2022 1141 CMM
45648
1
(Nitrate-Nitr) 353.2
1
06/24/2022 1832 KKP
46258
1
(Phosphorus) 365.1
25
06/21/2022 1609 DMA
06/21/2022 1008 45640
1
(Soil pH meas) 9045D
1
06/17/2022 1909 KKP
45410
1 351.4
(TKN) 351.2
2
06/22/2022 1222 DMA
06/21/2022 1148 45636
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
76
%
1
Ammonia - N (gas diffusion)
350.1
ND
450
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
ND S
9.1
mg/kg
1
Phosphorus
7723-14-0 365.1
39000
5700
mg/kg
1
Soil pH measured in water C) 24.3 ° C
9045D
6.6
su
1
TKN
351.2
80000 S
4500
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 3665A 8082A
1 06/23/2022 0145 CAW
06/20/2022 0000 45516
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
770
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
770
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
770
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
770
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
770
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
770
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
770
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
87 41-132
Tetrachloro-m-xylene
84 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 06/21/2022 0609 JAB2 06/21/2022 0300 45622
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 3.5
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XF17004-001
Description: TYSON/ HARMONY Matrix: Solid
Date Sampled:06/16/2022 0230 % Solids: 2.20 06/19/2022 1843
Date Received:06/17/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 06/24/2022 0254 JMH 06/23/2022 1010 45892
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
4500
270
mg/kg
1
Arsenic
7440-38-2
6010D
ND
10
mg/kg
1
Cadmium
7440-43-9
6010D
ND
3.4
mg/kg
1
Calcium
7440-70-2
6010D
90000
3400
mg/kg
1
Copper
7440-50-8
6010D
ND
6.7
mg/kg
1
Lead
7439-92-1
6010D
ND
6.7
mg/kg
1
Magnesium
7439-95-4
6010D
ND
3400
mg/kg
1
Molybdenum
7439-98-7
6010D
ND
27
mg/kg
1
Nickel
7440-02-0
6010D
ND
27
mg/kg
1
Potassium
7440-09-7
6010D
10000
3400
mg/kg
1
Selenium
7782-49-2
6010D
ND
13
mg/kg
1
Sodium
7440-23-5
6010D
12000
3400
mg/kg
1
Zinc
7440-66-6
6010D
ND
34
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure
Page 6 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XF17004-002
Description: TYSON/ WILKSOBORO Matrix: Solid
Date Sampled:06/16/2022 0300 % Solids: 1.80 06/19/2022 1843
Date Received:06/17/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
06/22/2022 2114 CVR
45863
1 350.1
(Ammonia - N) 350.1
1
06/22/2022 1143 CMM
45648
1
(Nitrate-Nitr) 353.2
1
06/24/2022 1837 KKP
46258
1
(Phosphorus) 365.1
2
06/21/2022 1616 DMA
06/21/2022 1008 45640
1
(Soil pH meas) 9045D
1
06/17/2022 1910 KKP
45410
1 351.4
(TKN) 351.2
1
06/22/2022 1217 DMA
06/21/2022 1148 45636
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
98
%
1
Ammonia - N (gas diffusion)
350.1
ND
560
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
11
11
mg/kg
1
Phosphorus
7723-14-0 365.1
3900
560
mg/kg
1
Soil pH measured in water C) 24.4 ° C
9045D
3.9
su
1
TKN
351.2
36000
2800
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 3665A 8082A
1 06/23/2022 0159 CAW
06/20/2022 0000 45516
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
940
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
940
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
940
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
940
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
940
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
940
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
940
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
92 41-132
Tetrachloro-m-xylene
89 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 06/21/2022 0611 JAB2 06/21/2022 0300 45622
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 4.2
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XF17004-002
Description: TYSON/ WILKSOBORO Matrix: Solid
Date Sampled:06/16/2022 0300 % Solids: 1.80 06/19/2022 1843
Date Received:06/17/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 06/24/2022 0321 JMH 06/23/2022 1010 45892
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
850
310
mg/kg
1
Arsenic
7440-38-2
6010D
ND
12
mg/kg
1
Cadmium
7440-43-9
6010D
ND
3.8
mg/kg
1
Calcium
7440-70-2
6010D
ND
3800
mg/kg
1
Copper
7440-50-8
6010D
62
7.7
mg/kg
1
Lead
7439-92-1
6010D
ND
7.7
mg/kg
1
Magnesium
7439-95-4
6010D
ND
3800
mg/kg
1
Molybdenum
7439-98-7
6010D
ND
31
mg/kg
1
Nickel
7440-02-0
6010D
ND
31
mg/kg
1
Potassium
7440-09-7
6010D
ND
3800
mg/kg
1
Selenium
7782-49-2
6010D
ND
15
mg/kg
1
Sodium
7440-23-5
6010D
ND
3800
mg/kg
1
Zinc
7440-66-6
6010D
64
38
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure
Page 8 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XF17004-003
Description: MATHIS STORAGE WILL Matrix: Solid
Date Sampled:06/16/2022 0330 % Solids: 11.7 06/19/2022 1843
Date Received:06/17/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
06/22/2022 2114 CVR
45863
1 350.1
(Ammonia - N) 350.1
50
06/22/2022 1229 CMM
45648
1
(Nitrate-Nitr) 353.2
1
06/24/2022 1844 KKP
46258
1
(Phosphorus) 365.1
10
06/21/2022 1616 DMA
06/21/2022 1008 45640
1
(Soil pH meas) 9045D
1
06/17/2022 1912 KKP
45410
1 351.4
(TKN) 351.2
5
06/22/2022 1228 DMA
06/21/2022 1148 45636
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
92
%
1
Ammonia - N (gas diffusion)
350.1
12000 S
4300
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
1.9
1.7
mg/kg
1
Phosphorus
7723-14-0 365.1
2800
430
mg/kg
1
Soil pH measured in water C) 24.2 ° C
9045D
5.2
su
1
TKN
351.2
21000
2100
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 3665A 8082A
1 06/23/2022 0212 CAW
06/20/2022 0000 45516
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
150
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
150
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
150
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
150
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
150
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
150
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
150
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
98 41-132
Tetrachloro-m-xylene
90 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 06/21/2022 0614 JAB2 06/21/2022 0300 45622
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 0.64
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XF17004-003
Description: MATHIS STORAGE WILL Matrix: Solid
Date Sampled:06/16/2022 0330 % Solids: 11.7 06/19/2022 1843
Date Received:06/17/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 06/24/2022 0325 JMH 06/23/2022 1010 45892
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
601OD
930
51
mg/kg
1
Arsenic
7440-38-2
6010D
ND
1.9
mg/kg
1
Cadmium
7440-43-9
6010D
ND
0.64
mg/kg
1
Calcium
7440-70-2
6010D
3800
640
mg/kg
1
Copper
7440-50-8
6010D
9.5
1.3
mg/kg
1
Lead
7439-92-1
6010D
ND
1.3
mg/kg
1
Magnesium
7439-95-4
6010D
ND
640
mg/kg
1
Molybdenum
7439-98-7
6010D
ND
5.1
mg/kg
1
Nickel
7440-02-0
6010D
ND
5.1
mg/kg
1
Potassium
7440-09-7
6010D
2400
640
mg/kg
1
Selenium
7782-49-2
6010D
ND
2.5
mg/kg
1
Sodium
7440-23-5
6010D
870
640
mg/kg
1
Zinc
7440-66-6
6010D
25
6.4
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure
Page 10 of 14

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 14

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 14

PACE ANALYTICAL SERVICES, LLC
North Garelina Punt Parameters
�. Residuals s1�31 >x zin;�iyu+d ftr demanstIat� Iltey �.rti ce C��naetvatian
axed J2wnvery Ad (R F-k,. Tile
sltia �� equcncy �pe��iea tin
ALIM M.rnt A. and tl> i tt shalll mutptp at tLt resllts for a u�nno -j fivc yeet.s. Any
e .CZpti�ms from thr 1egdfC :Es iu this eortd:tian sh�i i �e €pxafed in A#tlichmerst
Thv�na'iy.Sis Shaul inaiu& tlu. r.-;Jjawing zara,nexcrs (tFe T%GMJA1O1y level �ft mfflli�—amg pea' liner
is in parsnlbnaes}
i
3- An ar yms shall be =iductxl M r,:s AML f"3 41 J1 'Ouroe gm=at--n& fsoiiiiy at he fs:gnen.vY
n ad au Atbz]xnent A, arm &0 l'=Atee sU] muini.Wu this rmfL(8 For a mimlim of five years.
Tic analysk 91all iaeh:c 18 follon pan=kem
cc
w AlumiDiAn
A-nirAinia- ii z);an
�' J ArRenic
w Cadmium
CSIdUIIl
Capper —
ILI Lcad
Magnesium
Ivry
c�lyhcler_t�m
Idicl�el,
-Nitmtt, Nilrita Nitropffn
rCCUt TOM- S,; Ii[ls
Fott �iura
Scletiium
Willm
T.l{T,T
nic
Phosphrnu5 klnladia nlids
TERRA RENEWAL SERVICES
473-74T-8 02
PCQ's
Atdthmeni to GQC for.,.,,Souress. —'
WQDD36936 Versim 1.0 S1nft VaLmon 141MG g
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 14

PACE ANALYTICAL SERVICES, LLC
Samples Rereipt clhecldlst {Si Q IMEOGlse-IS) Revised-9J2912020
;�F eAraalyi�C l issuingAuthorlty, Pa.c ENV VVC k Pale 7 of i
Sample Receipt Checklist (SRC)
i:lien': 1'6RRA RPMMVAL Cuuli.'.r In:pcctrrl hyldate_ 'r f nrii i+2.n22 Lar #; xFi7,:'at
calls Ofreceipt: LJ Me 'liant ,r' UJ'S FedFx Odier_ —
EJ Yes[
14(1 Tin 1, WCrr' ci:s`.o 4 seals prMalt on thv ovule. ?
Y+
No RNA f_ [Frisiodv easels ware i cnl were the intact and unbroken'
pH Ship 1D- r' Chlorine Strip 1U: NATested : MA
iriginulteinperatlireup+minrolpl:JDerivad(C�wj%Dctc(f}tc-nlicraluroupoin"4e aipt %SolidSnap..Cup[1): NA
t5.3 r]5.5 0C NA ON;NA INA aC, NA /NA -uC
ietnod: Elf mperature Blank Lnkgaiu sl Battles [R G mi 11D, ¢ I R Ge n C'orrectiean Fnrinr: c 012
h W10d aromplar_l' ❑ wet Ica ❑ ICC Pocks ❑ rlrw I -cc 0 None --
'cs
U 1vI []NA'
I lCtr_rgreralal, ar"auuoaalc-cases-cdcd6.0°i',wasProjectManagert*adricd7
PM was Notif Psi by- Phc,ne I xi� � _1ce-gin-face (cilrle one)•
J y4g
_ Np
Lj NA
4, )!5 the cpmm_-rcwl cuurirr's packing slip att3clied to ibis fnnn?
I V I ye.3
LJ No
5. Were prApci umtu6y rrcunduresi (reij M�Uisl',ed %eccivc ) follawc f
Yes
No
6. Were sample OF, listed on :.her COI: i
VVe&
D
NO
7, Were sample Os listed on all srnple containers?
yes
LJ
No
8, Was Onl�eetian eats & tima listed on thv COC?
yoc
No
9, Was cot-ection cane Sa time listed on all sampl4 wnMill iers?
10, Did al: container label bif-minadon (11), datc, time.) ag= w[th tho COC?
Yes
Nfl
,( gyres
NO
11 _ Were tests to be pefornied lister cm the COO
�
LI'rCS; El 1 n
11 Did a 1, samplers arri ve in the prr~per enniainers for aacli test andror in good condition
(Lmhr4keyl, lid on, e1c.) f -- _--_--
183 No
13, Wa3 axkcpatc Sample yglume available?
Yasi
Ll two
114. Were all wnipLcN rccciyvd wi411in' 11!e lik3ldirLS tirnd or 49 IYouis, whiclieVer cartes first?
Yes'
No
l5. Woro ony samples contairers riissinWexcess (circle one) samples NDt liy#cd on CCU
L] yes
❑'lo
[-V]NA
6. For VOA and RSK-1 75 satnpyes, were bubbles preserl"a-sic°' (A°or Germ sat didrtehx)
in zcv Df die. #DA vials$ _
:7_ Were all DRO+melaWMItritnt saitlpits rtOel:VM AI a pH of <??
Yes
Ala
NA
Yes
Na
NA
_$- ltfere all evanide samples recei%Td at a P.H > :3 area sal::dc samples received at a pH ] 9?
❑ yes
El N
❑NA
19. Werc all apFlicable NH/1'KWc-.yaniddpirenclA25, J,"�C)8.3 (< 0_, mWQ sampim frac of
ruddual chlorrisen
❑
❑ N`'
�NA
2.4. Were client remarks.rr�equests (ix. rrqucstcd dilutions, MSI Ddo<ignartio3ls, -t ,...
correct y transcribed form the COC. into the commerI section in L. M&I
yes
21 No
21. Vyas the quote nwnbcr lis,cd on tF.c container label; tf yr:s, Outs e
arnplP rrvigervolion (ruiust he cnrnpiated fDr any .wipWs'. incorrectly preserved or with headspa(m.)
eu�il;l (s IIA wem received incorrectly preserved anal wey-e adjustad accardin5 ly
in sample reueiv[ngwith NA ail, ofcirelconc: H2SO4, HNO3, HCI, Iw40H using SR9 'Lf,
irm of pregeruation NA If mom than one pmeservative is nodcd, plcwc note in the comments bdow,
�-rrtnp[-*) t:A w(: re r-.ccivcud wElh bubbles fb rrrrrt ill d iurnel4r,
5ain}:les(s) NA _- — were received with TRC > G.5 niWL (If 919 IS no) and wem
�kdjusted accordingly in sample mcciving Ivit]l sodium thioaU]Fato (Nks,03) ;with Shealy ID,
SR ba:-ode labels =pl [cd by: TLC Doe: +S61:11?Mz
colnlrletw:
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 14

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: NC Samples
Lot Number:XJ04001
Date Completed:11/01/2022
Project Manager:Lucas Odom
E01, I , W101 1 M, �
11/02/2022 3:23 PM
Approved and released by:
Project Manager I: Kayla S. Holliday
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page Iof14

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XJ04001
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Non -Metals
The MS/MSD for batch 57675 associated with sample XJ04001-001, recovered outside of acceptance
criteria for Nitrate -Nitrite. All other QC passed, therefore, the data has been reported.
PCBs by GC
Due to matrix, the surrogate recovery for the following samples were outside control limits: XJ04001-002.
All other QC passed, therefore, the data has been reported.
Inorganic Metals
Due to the matrix and low percent solid, the following sample has an initial weight that is 3x greater than
standard procedure: XJ04001-001, XJ04001-002, XJ04001-003. The LOQ has been adjusted
accordingly.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvww.pacelabs.com
Page 2 of 14

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XJ04001
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
Tyson -Wilkesboro
Solid
10/03/20221230
10/04/2022
002
Tyson -Harmon
Solid
10/03/20221300
10/04/2022
003
Mathis 1- WI 1
Solid
10/03/2022 1330
10/04/2022
(3 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of14

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XJ04001
Sample
Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
Tyson -Wilkesboro
Solid
% Volatile Solids
SM 2540G-
100
%
5
001
Tyson -Wilkesboro
Solid
Ammonia - N (gas
350.1
3400
mg/kg
5
001
Tyson -Wilkesboro
Solid
Nitrate -Nitrite - N (soluble)
353.2
97 S
mg/kg
5
001
Tyson -Wilkesboro
Solid
Phosphorus
365.1
3100
mg/kg
5
001
Tyson -Wilkesboro
Solid
TKN
351.2
53000
mg/kg
5
001
Tyson -Wilkesboro
Solid
Copper
601OD
43
mg/kg
6
001
Tyson -Wilkesboro
Solid
Zinc
601OD
80
mg/kg
6
002
Tyson -Harmon
Solid
% Volatile Solids
SM 2540G-
80
%
7
002
Tyson -Harmon
Solid
Ammonia - N (gas
350.1
950
mg/kg
7
002
Tyson -Harmon
Solid
Nitrate -Nitrite - N (soluble)
353.2
110
mg/kg
7
002
Tyson -Harmon
Solid
Phosphorus
365.1
46000
mg/kg
7
002
Tyson -Harmon
Solid
TKN
351.2
75000
mg/kg
7
002
Tyson -Harmon
Solid
Aluminum
601OD
2500
mg/kg
8
002
Tyson -Harmon
Solid
Calcium
601OD
54000
mg/kg
8
002
Tyson -Harmon
Solid
Copper
601OD
7.6
mg/kg
8
002
Tyson -Harmon
Solid
Potassium
601OD
9000
mg/kg
8
002
Tyson -Harmon
Solid
Sodium
601OD
8900
mg/kg
8
003
Mathis 1- WI 1
Solid
% Volatile Solids
SM 2540G-
93
%
9
003
Mathis 1- WI 1
Solid
Ammonia - N (gas
350.1
10000
mg/kg
9
003
Mathis 1- WI 1
Solid
Nitrate -Nitrite - N (soluble)
353.2
48
mg/kg
9
003
Mathis 1- WI 1
Solid
Phosphorus
365.1
10000
mg/kg
9
003
Mathis 1- WI 1
Solid
TKN
351.2
27000
mg/kg
9
003
Mathis 1- WI 1
Solid
Aluminum
601OD
1000
mg/kg
10
003
Mathis 1- WI 1
Solid
Calcium
601OD
20000
mg/kg
10
003
Mathis 1- WI 1
Solid
Copper
601OD
22
mg/kg
10
003
Mathis 1- WI 1
Solid
Potassium
601OD
3300
mg/kg
10
003
Mathis 1- WI 1
Solid
Sodium
601OD
3000
mg/kg
10
003
Mathis 1- WI 1
Solid
Zinc
601OD
47
mg/kg
10
(28 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XJ04001-001
Description: Tyson -Wilkesboro Matrix: Solid
Date Sampled:10/03/2022 1230 % Solids: 2.16 10/11/2022 2200
)ate Received:10/04/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
10/06/2022 2215 CVR
56295
1 350.1
(Ammonia - N) 350.1
5
10/19/2022 1616 CMM
57366
1
(Nitrate-Nitr) 353.2
1
10/20/2022 1805 KKP
57675
1
(Phosphorus) 365.1
2
10/08/2022 1459 DMA
10/07/2022 1400 56358
1
(Soil pH meas) 9045D
1
10/12/2022 1527 KKP
56841
1 351.4
(TKN) 351.2
1
10/07/2022 1751 DMA
10/06/2022 1447 56231
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
100
%
1
Ammonia - N (gas diffusion)
350.1
3400
2300
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
97 S
9.3
mg/kg
1
Phosphorus
7723-14-0 365.1
3100
460
mg/kg
1
Soil pH measured in water C) 21.9 ° C
9045D
4.6
su
1
TKN
351.2
53000
2300
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 10/11/2022 2343 DAL1
10/09/2022 1236 56455
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
770
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
770
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
770
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
770
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
770
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
770
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
770
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
70 41-132
Tetrachloro-m-xylene
75 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 10/07/2022 1530 MRW2 10/07/2022 1138 55609
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471 B N D 3.6
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XJ04001-001
Description: Tyson -Wilkesboro Matrix: Solid
Date Sampled:10/03/2022 1230 % Solids: 2.16 10/11/2022 2200
Date Received:10/04/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 10/16/2022 1136 JMH 10/06/2022 1637 56156
2 3050B 6010D 1 10/17/2022 0417 JAB2 10/06/2022 1637 56156
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5
601 OD
ND
280
mg/kg
1
Arsenic
7440-38-2
601 OD
ND
10
mg/kg
1
Cadmium
7440-43-9
601 OD
ND
3.5
mg/kg
1
Calcium
7440-70-2
601 OD
ND
3500
mg/kg
1
Copper
7440-50-8
601 OD
43
6.9
mg/kg
1
Lead
7439-92-1
601 OD
N D
6.9
mg/kg
1
Magnesium
7439-95-4
601 OD
N D
3500
mg/kg
1
Molybdenum
7439-98-7
601 OD
N D
28
mg/kg
1
Nickel
7440-02-0
601 OD
ND
28
mg/kg
1
Potassium
7440-09-7
601 OD
N D
3500
mg/kg
1
Selenium
7782-49-2
601 OD
N D
14
mg/kg
1
Sodium
7440-23-5
601 OD
N D
3500
mg/kg
1
Zinc
7440-66-6
601 OD
80
35
mg/kg
2
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range Q - Surrogate failure
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 14

Client:Terra Renewal Services, Inc. Laboratory ID:XJ04001-002
Description: Tyson -Harmon Matrix: Solid
Date Sampled:10/03/2022 1300 % Solids: 2.17 10/11/2022 2200
)ate Received:10/04/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
10/06/2022 2215 CVR
56295
1 350.1
(Ammonia - N) 350.1
1
10/19/2022 1644 CMM
57366
1
(Nitrate-Nitr) 353.2
1
10/20/2022 1807 KKP
57675
1
(Phosphorus) 365.1
25
10/08/2022 1448 DMA
10/07/2022 1400 56358
1
(Soil pH meas) 9045D
1
10/12/2022 1529 KKP
56841
1 351.4
(TKN) 351.2
2
10/07/2022 1815 DMA
10/06/2022 1447 56231
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
80
%
1
Ammonia - N (gas diffusion)
350.1
950
460
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
110
9.2
mg/kg
1
Phosphorus
7723-14-0 365.1
46000
5800
mg/kg
1
Soil pH measured in water C) 21.6 ° C
9045D
7.5
su
1
TKN
351.2
75000
4600
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 3660B/3665A 8082A
1 10/12/2022 1820 DAL1
10/09/2022 1236 56455
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND Q
780
ug/kg
1
Aroclor 1221
11104-28-2 8082A
N D Q
780
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND Q
780
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND Q
780
ug/kg
1
Aroclor 1248
12672-29-6 8082A
N D Q
780
ug/kg
1
Aroclor 1254
11097-69-1 8082A
N D Q
780
ug/kg
1
Aroclor 1260
11096-82-5 8082A
N D Q
780
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
43 41-132
Tetrachloro-m-xylene N
31 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 10/07/2022 1532 MRW2 10/07/2022 1138 55609
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471 B N D 3.5
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 14

Client:Terra Renewal Services, Inc. Laboratory ID:XJ04001-002
Description: Tyson -Harmon Matrix: Solid
Date Sampled:10/03/2022 1300 % Solids: 2.17 10/11/2022 2200
Date Received:10/04/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 10/16/2022 1150 JMH 10/06/2022 1637 56156
2 3050B 6010D 1 10/17/2022 0421 JAB2 10/06/2022 1637 56156
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5
601 OD
2500
290
mg/kg
1
Arsenic
7440-38-2
601 OD
ND
11
mg/kg
1
Cadmium
7440-43-9
601 OD
ND
3.6
mg/kg
1
Calcium
7440-70-2
601 OD
54000
3600
mg/kg
1
Copper
7440-50-8
601 OD
7.6
7.2
mg/kg
1
Lead
7439-92-1
601 OD
N D
7.2
mg/kg
1
Magnesium
7439-95-4
601 OD
N D
3600
mg/kg
1
Molybdenum
7439-98-7
601 OD
N D
29
mg/kg
1
Nickel
7440-02-0
601 OD
ND
29
mg/kg
1
Potassium
7440-09-7
601 OD
9000
3600
mg/kg
2
Selenium
7782-49-2
601 OD
ND
14
mg/kg
1
Sodium
7440-23-5
601 OD
8900
3600
mg/kg
1
Zinc
7440-66-6
601 OD
ND
36
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range Q - Surrogate failure
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XJ04001-003
Description: Mathis 1- WIL 1 Matrix: Solid
Date Sampled:10/03/2022 1330 % Solids: 3.90 10/11/2022 2200
)ate Received:10/04/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
10/06/2022 2215 CVR
56295
1 350.1
(Ammonia - N) 350.1
10
10/19/2022 1646 CMM
57366
1
(Nitrate-Nitr) 353.2
1
10/20/2022 1809 KKP
57675
1
(Phosphorus) 365.1
10
10/08/2022 1429 DMA
10/07/2022 1400 56358
1
(Soil pH meas) 9045D
1
10/12/2022 1530 KKP
56841
1 351.4
(TKN) 351.2
1
10/07/2022 1801 DMA
10/06/2022 1447 56231
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
93
%
1
Ammonia - N (gas diffusion)
350.1
10000
2600
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
48
5.1
mg/kg
1
Phosphorus
7723-14-0 365.1
10000
1300
mg/kg
1
Soil pH measured in water C) 21.4 ° C
9045D
6.5
su
1
TKN
351.2
27000
1300
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 3660B/3665A 8082A
1 10/12/2022 0009 DAL1
10/09/2022 1236 56455
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
440
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
440
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
440
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
440
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
440
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
440
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
440
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
57 41-132
Tetrachloro-m-xylene
66 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 10/07/2022 1535 MRW2 10/07/2022 1138 55609
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471 B N D 2.1
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 14

Client: Terra Renewal Services, Inc. Laboratory ID:XJ04001-003
Description: Mathis 1- WIL 1 Matrix: Solid
Date Sampled:10/03/2022 1330 % Solids: 3.90 10/11/2022 2200
Date Received:10/04/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 10/16/2022 1155 JMH 10/06/2022 1637 56156
2 3050B 6010D 1 10/17/2022 0426 JAB2 10/06/2022 1637 56156
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5
601 OD
1000
160
mg/kg
1
Arsenic
7440-38-2
601 OD
N D
5.9
mg/kg
1
Cadmium
7440-43-9
601 OD
N D
2.0
mg/kg
1
Calcium
7440-70-2
601 OD
20000
2000
mg/kg
1
Copper
7440-50-8
601 OD
22
3.9
mg/kg
1
Lead
7439-92-1
601 OD
ND
3.9
mg/kg
1
Magnesium
7439-95-4
601 OD
ND
2000
mg/kg
1
Molybdenum
7439-98-7
601 OD
ND
16
mg/kg
1
Nickel
7440-02-0
601 OD
ND
16
mg/kg
1
Potassium
7440-09-7
601 OD
3300
2000
mg/kg
2
Selenium
7782-49-2
601 OD
ND
7.8
mg/kg
1
Sodium
7440-23-5
601 OD
3000
2000
mg/kg
1
Zinc
7440-66-6
601 OD
47
20
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range Q - Surrogate failure
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 14

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 14

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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 14

PACE ANALYTICAL SERVICES, LLC
North Carolina Permft Parameters
? itesidonl a shall �naEy od Eu clrmrevstrate .arc : w r.a GcuScxvariucL
andc�overy A,ct (R{R j,), `ncG aazl rs
shay [riles-� s}}e�;ficd i�
Al �$ CITE } sud �lre Pcriuitlr �lwli maitjtfL tt-O to results fty- a tliillilllulit of fiw, years Aw
cxccPtiama &m the 1ui mcnrs it I`hi.s. oo,r$iri-Ot A.0 be SptOifred ill AUmr:k-mcnf. A.
`RMz ELUIYMs shall inchde hz fol'ow_ng pa_anxel�rs Ctho regu:fitor/ lave: i rnklii s per Boar
in irl parmlhewr )-
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213eeifiad m-AMOhniMt A, and the Yerlaittrc shalj taint3ja the resr�Its for 4 Tni";.,,uLrl Qf--Ve yearn.
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dick& lUfil
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TERRA RENEWAL SERMCE
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 14

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 14

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: SC Samples
Lot Number:XL29022
Date Completed:01/17/2023
NIM�I�Mr�
01/18/2023 11:40 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XL29022
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
PCBs by GC
The laboratory control sample (LCS) passes, but laboratory control sample duplicate (LCSD) for
analytical batch 64424 recovered outside acceptance criteria. For the following sample(s) there was an
insufficient amount to perform a re -extraction or re -analysis: XL29022-001. The data has been reported.
Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for
prep batch 64296. An LCS/LCSD was run in lieu of an MS/MSD.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XL29O22
Sample Number Sample ID Matrix Date Sampled Date Received
001 ADVANCED PIRRE FOODS Solid 12/27/2022 1300 12/29/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

PACE ANALYTICAL SERVICES,
LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XL29O22
Sample
Sample ID
Matrix Parameter Method
Result Q
Units
Page
001
ADVANCED PIRRE FOODS
Solid % Volatile Solids SM 2540G-
95
%
5
001
ADVANCED PIRRE FOODS
Solid Nitrate -Nitrite - N (soluble) 353.2
65
mg/kg
5
001
ADVANCED PIRRE FOODS
Solid Phosphorus 365.1
3500
mg/kg
5
001
ADVANCED PIRRE FOODS
Solid TKN 351.2
100000 S
mg/kg
5
001
ADVANCED PIRRE FOODS
Solid Aluminum 6010D
2400
mg/kg
6
001
ADVANCED PIRRE FOODS
Solid Copper 6010D
80
mg/kg
6
001
ADVANCED PIRRE FOODS
Solid Sodium 6010D
19000
mg/kg
6
001
ADVANCED PIRRE FOODS
Solid Zinc 6010D
66
mg/kg
6
(8 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:XL29022-001
Description: ADVANCED PIRRE FOODS Matrix: Solid
Date Sampled:12/27/2022 1300 % Solids: 3.86 01/03/2023 1657
)ate Received:12/29/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
01/02/2023 1219 CBP
63963
1 350.1
(Ammonia - N) 350.1
1
01/14/2023 1151 CMM
64686
1
(Nitrate-Nitr) 353.2
1
01/13/2023 1110 CMM
64785
1
(Phosphorus) 365.1
5
01/09/2023 0831 DMA
01/04/2023 1242 64080
1
(Soil pH meas) 9045D
1
12/30/2022 1518 BMG2
63751
1 351.4
(TKN) 351.2
5
01/16/2023 1838 DMA
01/16/2023 0808 64877
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
95
%
1
Ammonia - N (gas diffusion)
350.1
ND
260
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
65
5.2
mg/kg
1
Phosphorus
7723-14-0 365.1
3500
650
mg/kg
1
Soil pH measured in water C) 15.2 ° C
9045D
9.4
su
1
TKN
351.2
100000 S
6500
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
3 3550C 3660B/3665A 8082A
1 01/09/2023 1218 DAL1
01/06/2023 1203 64296
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND L
440
ug/kg
3
Aroclor 1221
11104-28-2 8082A
ND
440
ug/kg
3
Aroclor 1232
11141-16-5 8082A
ND
440
ug/kg
3
Aroclor 1242
53469-21-9 8082A
ND
440
ug/kg
3
Aroclor 1248
12672-29-6 8082A
ND
440
ug/kg
3
Aroclor 1254
11097-69-1 8082A
ND
440
ug/kg
3
Aroclor 1260
11096-82-5 8082A
ND L
440
ug/kg
3
Run 3 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
44 41-132
Tetrachloro-m-xylene
39 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/30/2022 0925 JAB2 12/30/2022 0758 63874
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471 B N D 2.1
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:XL29022-001
Description: ADVANCED PIRRE FOODS Matrix: Solid
Date Sampled:12/27/2022 1300 % Solids: 3.86 01/03/2023 1657
Date Received:12/29/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 01/03/2023 2253 JMH 12/30/2022 0734 63870
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
601 OD
2400
510
mg/kg
1
Arsenic
7440-38-2
601 OD
ND
19
mg/kg
1
Cadmium
7440-43-9
601 OD
ND
6.4
mg/kg
1
Calcium
7440-70-2
601 OD
ND
6400
mg/kg
1
Copper
7440-50-8
601 OD
80
13
mg/kg
1
Lead
7439-92-1
601 OD
N D
13
mg/kg
1
Magnesium
7439-95-4
601 OD
N D
6400
mg/kg
1
Molybdenum
7439-98-7
601 OD
N D
51
mg/kg
1
Nickel
7440-02-0
601 OD
ND
51
mg/kg
1
Potassium
7440-09-7
601 OD
N D
6400
mg/kg
1
Selenium
7782-49-2
601 OD
ND
25
mg/kg
1
Sodium
7440-23-5
601 OD
19000
6400
mg/kg
1
Zinc
7440-66-6
601 OD
66
64
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 9

PACE ANALYTICAL SERVICES, LLC
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 9
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[3C# title: ENV4APA-VVCOL- {s VGZ_Sannple.s Raceipt Chmklist (5AC)
EfWctiva Me: 8f 202Z
Sample Receipt Cheeldist (SRC)
Cllcnl' T�PR 1 � 15'}4i cwal Ir1Spie JrDR%V 111'20Q} 1 "rr .a
Wat75 of�etpt' k'ace [`lirtl CJPS Xerl falter, _
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YES U NO IvrINA d. l-s 11Ee ccuw er&E cdtaiei''s 139CULIC ShP altaAd io tius fbnO
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Yts No fi, Were vmWlel-I.is &sled on the 00C and alt sfagplc eojjUXMV
Yes No 7, Was collection daze & arm Ls:ad wa dre CL3C aad all s11ale 74Dura Epe10 -
,I YCes No 8. Did 011Cantaillcylabel ki onyut6olE OD, daft, Eitue) aguct witL the cOC?
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'�.; ❑AIu lU. Did all Epluples ruaive ja :1rc proper comtnillms for'c.Bdj test a11Tol ue F.a0d COndirina
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EV'IYes ❑NO 13, Were ell Samplcg cmahbas acco=cd-fDj? (No li�i ijlf e3CCess)
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 9

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: SC Samples
Lot Number:XL29028
Date Completed:01/18/2023
NIM�I�Mr�
01/18/2023 11:49 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page Iof10

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XL29028
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 10

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XL29028
Sample Number Sample ID Matrix Date Sampled Date Received
001 Advanced Pirre Foods Solid 12/27/2022 1300 12/29/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of10

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XL29028
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 Advanced Pirre Foods Solid Flashpoint (Pensky- 1010B >140 ° F 5
001 Advanced Pirre Foods Solid 3+4-Methylphenol 8270E 0.11 mg/L 6
(2 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29028-001
Description: Advanced Pirre Foods Matrix: Solid
Date Sampled:12/27/2022 1300 % Solids: 13.2 01/05/2023 0109
Date Received:12/29/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date Batch
1
(Flashpoint () 1010B
1
01/13/2023 0121 CBP 64784
1
(Reactive Cya) 7.3.3
1
01/16/2023 1613 SJL 01/13/2023 1130
1
(Reactive Sul) 7.3.4
1
01/14/2023 0931 CVR 01/13/2023 1130
1
(Soil pH meas) 9045D
1
12/30/2022 1533 BMG2 63751
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Flashpoint (Pensky-Martens Closed -Cup)
1010B
>140
140
° F
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water C) 17.1 ° C
9045D
9.3
su
1
TCLP Volatiles
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/5030B 8260D 10 01/09/20231922 CDA 64449 12/29/20221645
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Benzene
71-43-2
8260D
ND
0.050
mg/L
2-Butanone (MEK)
78-93-3
8260D
ND
0.10
mg/L
Carbon tetrachloride
56-23-5
8260D
ND
0.050
mg/L
Chlorobenzene
108-90-7
8260D
ND
0.050
mg/L
Chloroform
67-66-3
8260D
ND
0.050
mg/L
1,2-Dichloroethane
107-06-2
8260D
ND
0.050
mg/L
1,1-Dichloroethene
75-35-4
8260D
ND
0.050
mg/L
Tetrachloroethene
127-18-4
8260D
ND
0.050
mg/L
Trichloroethene
79-01-6
8260D
ND
0.050
mg/L
Vinyl chloride
75-01-4
8260D
ND
0.010
mg/L
Run 1
Acceptance
Surrogate
Q % Recovery
Limits
Bromofluorobenzene
94
70-130
1,2-Dichloroethane-d4
91
70-130
Toluene-d8
95
70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 01/05/2023 1457 CMF
01/03/2023 1355 64019 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L 1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L 1
Hexachlorobenzene
118-74-1 8270E
N D L
0.040
mg/L 1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29028-001
Description: Advanced Pirre Foods Matrix: Solid
Date Sampled:12/27/2022 1300 % Solids: 13.2 01/05/2023 0109
Date Received: 12/29/2022
TCLP Semivolatiles
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8270E 1 01/05/2023 1457 CMF 01/03/2023 1355 64019 12/29/2022 1649
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Hexachloroethane
67-72-1
8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7
8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5
8270E
0.11
0.040
mg/L
1
Nitrobenzene
98-95-3
8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5
8270E
ND
0.20
mg/L
1
Pyridine
110-86-1
8270E
N D L
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4
8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2
8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery
Limits
2-Fluorobiphenyl
91
37-129
2-Fluorophenol
36
24-127
Nitrobenzene-d5
85
38-127
Phenol-d5
63
28-128
Terphenyl-d14
103
10-148
2,4,6-Tribromophenol
117
41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311 /8151 A
8151A
1 01/05/2023 1559 SAF
01 /03/2023 2007 64037 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L
1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
60 50-112
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8081B
1 01/05/20231805 DAL1
01/03/20231111 63978 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
gamma-BHC (Lindane)
58-89-9 8081 B
ND
0.00040
mg/L
1
Chlordane
57-74-9 8081 B
ND
0.0040
mg/L
1
Endrin
72-20-8 8081 B
ND
0.00040
mg/L
1
Heptachlor
76-44-8 8081 B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3 8081 B
ND
0.00040
mg/L
1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD
failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29028-001
Description: Advanced Pirre Foods Matrix: Solid
Date Sampled:12/27/2022 1300 % Solids: 13.2 01/05/2023 0109
)ate Received: 12/29/2022
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 01/05/20231805 DALI 01/03/20231111 63978 12/29/2022 1649
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Methoxychlor 72-43-5 8081 B N D 0.0016 mg/L 1
Toxaphene 8001-35-2 8081 B ND 0.0080 mg/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl 40 20-131
Tetrachloro-m-xylene 86 26-132
TCLP Metals
Run Prep Method
1 1311/3010A
1 1311/7470A
3 1311/3010A
Analytical Method
6010D
7470A
6010D
Dilution Analysis Date Analyst
1 01/05/2023 2057 JMH
1 01/05/2023 1645 MRW2
1 01/11/2023 2059 JMH
Prep Date Batch Leachate Date
01/05/2023 0910 64107 12/29/2022 1649
01/05/2023 1150 64188 12/29/2022 1649
01/11/2023 1118 64604 01/10/2023 1605
CAS Analytical
Parameter
Number Method
Result Q LOQ
Units
Run
Arsenic
7440-38-2 6010D
ND 0.15
mg/L
1
Barium
7440-39-3 6010D
ND 0.25
mg/L
3
Cadmium
7440-43-9 6010D
ND 0.050
mg/L
1
Chromium
7440-47-3 6010D
ND 0.10
mg/L
1
Lead
7439-92-1 6010D
ND 0.10
mg/L
1
Mercury
7439-97-6 7470A
ND 0.0020
mg/L
1
Selenium
7782-49-2 6010D
ND 0.20
mg/L
1
Silver
7440-22-4 6010D
ND 0.10
mg/L
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range Q - Surrogate failure
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 10

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 10

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
[phone]
Fax [phone] www.pacelabs.com
Page 9 of 10

PACE ANALYTICAL SERVICES, LLC
Lit# Title; ENV-FRKI-V'ICCtL-028gv02-.°,ampltin ecaiptChecklistySl Cj
fffsctivg Date' 9/212022
Soraple I eMpt Checklist (SRC)
CROIL: TF-fcRAP,ENE `.'�J• C`Mleir .C.ted ,'date= KDR%'- J I!I-M 2 Lori,- x1�r;lst
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No 7, Wars collection dsete & tiitrle listed en Il<c CW taxi all sairple co2Gniu '
No 8, Dial all ummin�er Iabei inkffmdon (in, date, tune) ogee with the Coe?
o9. Wer-u ttists m hr- l>�fomx '.d liswd on du COC?
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y�!-i No 13. l#ereall sRMplc� corttaLPAS accottuted for? (ND �atiiRsin�+exce4s) —
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 10

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: SC Samples
Lot Number:XL29027
Date Completed:01/17/2023
NIM�I�Mr�
01/18/2023 11:47 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
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Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XL29027
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
PCBs by GC
The laboratory control sample (LCS) passes, but laboratory control sample duplicate (LCSD) for
analytical batch 64424 recovered outside acceptance criteria. For the following sample(s) there was an
insufficient amount to perform a re -extraction or re -analysis: XL29027-001. The data has been reported.
Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for
prep batch 64296. An LCS/LCSD was run in lieu of an MS/MSD.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XL29027
Sample Number Sample ID Matrix Date Sampled Date Received
001 TYSON HARMONY Solid 12/27/2022 1130 12/29/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

PACE ANALYTICAL SERVICES,
LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XL29027
Sample
Sample ID
Matrix Parameter Method
Result Q
Units
Page
001
TYSON HARMONY
Solid % Volatile Solids SM 2540G-
97
%
5
001
TYSON HARMONY
Solid Ammonia - N (gas 350.1
18000
mg/kg
5
001
TYSON HARMONY
Solid Nitrate -Nitrite - N (soluble) 353.2
150
mg/kg
5
001
TYSON HARMONY
Solid Phosphorus 365.1
9400
mg/kg
5
001
TYSON HARMONY
Solid TKN 351.2
65000
mg/kg
5
001
TYSON HARMONY
Solid Aluminum 6010D
3500
mg/kg
6
001
TYSON HARMONY
Solid Copper 6010D
58
mg/kg
6
001
TYSON HARMONY
Solid Zinc 6010D
64
mg/kg
6
(8 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:XL29027-001
Description: TYSON HARMONY Matrix: Solid
Date Sampled:12/27/2022 1130 % Solids: 3.69 01/03/2023 1657
)ate Received:12/29/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
01/02/2023 1219 CBP
63963
1 350.1
(Ammonia - N) 350.1
50
01/14/2023 1155 CMM
64686
1
(Nitrate-Nitr) 353.2
1
01/13/2023 1112 CMM
64785
2
(Phosphorus) 365.1
10
01/11/2023 1213 DMA
01/04/2023 1242 64080
1
(Soil pH meas) 9045D
1
12/30/2022 1526 BMG2
63751
1 351.4
(TKN) 351.2
2
01/16/2023 1838 DMA
01/16/2023 0808 64877
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
97
%
1
Ammonia - N (gas diffusion)
350.1
18000
14000
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
150
5.4
mg/kg
1
Phosphorus
7723-14-0 365.1
9400
1400
mg/kg
2
Soil pH measured in water @ 15.9 ° C
9045D
5.1
su
1
TKN
351.2
65000
2700
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
3 3550C 366013/3665A 8082A
1 01/09/2023 1245 DAL1
01/06/2023 1203 64296
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND L
450
ug/kg
3
Aroclor 1221
11104-28-2 8082A
ND
450
ug/kg
3
Aroclor 1232
11141-16-5 8082A
ND
450
ug/kg
3
Aroclor 1242
53469-21-9 8082A
ND
450
ug/kg
3
Aroclor 1248
12672-29-6 8082A
ND
450
ug/kg
3
Aroclor 1254
11097-69-1 8082A
ND
450
ug/kg
3
Aroclor 1260
11096-82-5 8082A
ND L
450
ug/kg
3
Run 3 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
54 41-132
Tetrachloro-m-xylene
50 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/30/2022 0930 JAB2 12/30/2022 0758 63874
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471 B N D 2.1
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:XL29027-001
Description: TYSON HARMONY Matrix: Solid
Date Sampled:12/27/2022 1130 % Solids: 3.69 01/03/2023 1657
Date Received:12/29/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 01/03/2023 2301 JMH 12/30/2022 0734 63870
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
601 OD
3500
510
mg/kg
1
Arsenic
7440-38-2
601 OD
ND
19
mg/kg
1
Cadmium
7440-43-9
601 OD
ND
6.3
mg/kg
1
Calcium
7440-70-2
601 OD
ND
6300
mg/kg
1
Copper
7440-50-8
601 OD
58
13
mg/kg
1
Lead
7439-92-1
601 OD
ND
13
mg/kg
1
Magnesium
7439-95-4
601 OD
N D
6300
mg/kg
1
Molybdenum
7439-98-7
601 OD
N D
51
mg/kg
1
Nickel
7440-02-0
601 OD
ND
51
mg/kg
1
Potassium
7440-09-7
601 OD
N D
6300
mg/kg
1
Selenium
7782-49-2
601 OD
ND
25
mg/kg
1
Sodium
7440-23-5
601 OD
N D
6300
mg/kg
1
Zinc
7440-66-6
601 OD
64
63
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 9

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LLC (formerly
Shealy Environmental
Services,
Inc.)
106 Vantage Point Drive
West Columbia, SC 29172
[phone]
Fax [phone] www.pacelabs.com
Page 8 of 9
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PACE ANALYTICAL SERVICES, LLC
X4 Thle: ;ENV-PRM-:VCOL-07RG v02_5ama1e5 Keri�lp"tCheckW 1�5113CJ
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Strip ED: ,h'" _ chlorme StuYp ID: N" _ Tested -C— _
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No
'Were sa;+�1- le Ms fisted on dic COC mid all sam Cot1t�.EY1 ?
7- Was coLlectio l daft & Liiw Uveul m) t1kc C.`lJC and all sawple cantainen?
T!
YCS
es
NO
6- Did &ll cowniutr label liatcunlaiion (W-. datQ Lime) Wee'Adl the COC:?
J
Ycs
Nol
9, VWece uses to be verRmned list-ed on t1w COC?
❑Vtx M Dirt al't Samples .Rnjve hi the Ilrolior eantai leis tar each tea' 3ilWor in pod 0rn:didu°1
(unbrakm lids on. etc.r.
!Ayes -iN o 11. Was adcgtr lie sample VAJ111r, arL•a.ilable?
, 'cs Igo 12, wete till sam Ics recf?,red witilni �z lIx IwI[iulg t= al 48 hDL1S5, t+ ikhemer emne.; firs[?
QYes ❑No 13, NVue fill %ampin3 eautai=& ac-wined lion# micsj[�,`ctee��l
14. Wnt VOA, 8015CFnrlcli�gK-179 suutples itiee ofWbbies>-pea,�ize"('Werr5111 11
Eyes 71 ° OvarLarrLrlcml, io anof the V0A viW
ENa- Al nc[ 1 S. Were 0 DROhalsfmltrieat saiupks rcuived at fi H of,-- 2?
if
No ,f Iti A 1 �. �L�C1.�C all a �[�t SAdld lea TccLlvecl sl :{ H .-� 12 dncl �tiltidc sag lea i�c-ctvcrl fit a �H � 9?
- Were all applicable l�ki 1KN`���lide�'phe�ro ��? 5.1lb08" + (c �,�:tl�jr, sHnrp es flee of
❑Yes ❑N4 Em resscwq.l tlLloriue?
❑-Y--es ZNo ❑NA I s. was t11c gwtc iuu7ler Heed olt the conmiun Iabti? If yes, {%iota V
Sav�rle Pt'ese>s'vatlau [ltitlst ire completed Fol"ttu� ��31e{s) Itatrsrrccrl� IxicsCCL'ed or with iteads)sace-)
a gle(s) WA wcir rcecived mcurecdy pi-nnved and were Auslul act oidiasl;
ija saanlric r=cc iving with n3I, ofcuic [� uar: I�SCA, - ]? I, MCI, NaOH MV W.4 ';�' _,
(line -bfPreseLVatiCM . Ifinoae titan One pr ayatim is 11,-eded, plcasc now in die councnts bduw.
Sa u3plc(s) NA wem rec-lived vide bubbles >6 imil m diRMI!c er.
aiuples(s 'N21, receivcd Willi TR.0 t,5 ntg?I {If #F17 is �r j end x'eze
ad�tlsted accord;�,gy 1+l suplc icceivirg with 10;
IXLll11CL1 [5 ;
titrmix 10, 55360 Pace AnalydnA Services, LLE Pag
of I
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 9

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: SC Samples
Lot Number:XL29026
Date Completed:01/18/2023
NIM�I�Mr�
01/18/2023 11:46 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page Iof10

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XL29026
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 10

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XL29026
Sample Number Sample ID Matrix Date Sampled Date Received
001 TYSON HARMONY Solid 12/27/2022 1130 12/29/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of10

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XL29026
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 TYSON HARMONY Solid Flashpoint (Pensky- 1010B >140 ° F 5
001 TYSON HARMONY Solid 3+4-Methylphenol 8270E 0.10 mg/L 6
(2 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29026-001
Description: TYSON HARMONY Matrix: Solid
Date Sampled:12/27/2022 1130 % Solids: 5.36 01/03/2023 1657
Date Received:12/29/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date Batch
1
(Flashpoint () 1010B
1
01/13/2023 0033 CBP 64784
1
(Reactive Cya) 7.3.3
1
01/16/2023 1611 SJL 01/13/2023 1130
1
(Reactive Sul) 7.3.4
1
01/14/2023 0931 CVR 01/13/2023 1130
1
(Soil pH meas) 9045D
1
12/30/2022 1530 BMG2 63751
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Flashpoint (Pensky-Martens Closed -Cup)
1010B
>140
140
° F
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water C) 16.8 ° C
9045D
5.2
su
1
TCLP Volatiles
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/5030B 8260D 10 01/09/20231857 CDA 64449 12/29/20221645
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Benzene
71-43-2
8260D
ND
0.050
mg/L
2-Butanone (MEK)
78-93-3
8260D
ND
0.10
mg/L
Carbon tetrachloride
56-23-5
8260D
ND
0.050
mg/L
Chlorobenzene
108-90-7
8260D
ND
0.050
mg/L
Chloroform
67-66-3
8260D
ND
0.050
mg/L
1,2-Dichloroethane
107-06-2
8260D
ND
0.050
mg/L
1,1-Dichloroethene
75-35-4
8260D
ND
0.050
mg/L
Tetrachloroethene
127-18-4
8260D
ND
0.050
mg/L
Trichloroethene
79-01-6
8260D
ND
0.050
mg/L
Vinyl chloride
75-01-4
8260D
ND
0.010
mg/L
Run 1
Acceptance
Surrogate
Q % Recovery
Limits
Bromofluorobenzene
91
70-130
1,2-Dichloroethane-d4
90
70-130
Toluene-d8
94
70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 01/05/2023 1432 CMF
01/03/2023 1355 64019 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L 1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L 1
Hexachlorobenzene
118-74-1 8270E
N D L
0.040
mg/L 1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29026-001
Description: TYSON HARMONY Matrix: Solid
Date Sampled:12/27/2022 1130 % Solids: 5.36 01/03/2023 1657
Date Received: 12/29/2022
TCLP Semivolatiles
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8270E 1 01/05/2023 1432 CMF 01/03/2023 1355 64019 12/29/2022 1649
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Hexachloroethane
67-72-1
8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7
8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5
8270E
0.10
0.040
mg/L
1
Nitrobenzene
98-95-3
8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5
8270E
ND
0.20
mg/L
1
Pyridine
110-86-1
8270E
N D L
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4
8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2
8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery
Limits
2-Fluorobiphenyl
91
37-129
2-Fluorophenol
39
24-127
Nitrobenzene-d5
82
38-127
Phenol-d5
64
28-128
Terphenyl-d14
102
10-148
2,4,6-Tribromophenol
118
41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311 /8151 A
8151A
1 01 /05/2023 1536 SAF
01/03/2023 2007 64037 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L
1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
57 50-112
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8081B
1 01/05/20231749 DAL1
01/03/20231111 63978 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
gamma-BHC (Lindane)
58-89-9 8081 B
ND
0.00040
mg/L
1
Chlordane
57-74-9 8081 B
ND
0.0040
mg/L
1
Endrin
72-20-8 8081 B
ND
0.00040
mg/L
1
Heptachlor
76-44-8 8081 B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3 8081 B
ND
0.00040
mg/L
1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD
failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29026-001
Description: TYSON HARMONY Matrix: Solid
Date Sampled:12/27/2022 1130 % Solids: 5.36 01/03/2023 1657
)ate Received: 12/29/2022
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 01/05/20231749 DAL1 01/03/20231111 63978 12/29/2022 1649
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Methoxychlor 72-43-5 8081 B N D 0.0016 mg/L 1
Toxaphene 8001-35-2 8081 B ND 0.0080 mg/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl 33 20-131
Tetrachloro-m-xylene 85 26-132
TCLP Metals
Run Prep Method
1 1311/3010A
1 1311/7470A
3 1311/3010A
Analytical Method
6010D
7470A
6010D
Dilution Analysis Date Analyst
1 01/05/2023 2053 JMH
1 01/05/2023 1642 MRW2
1 01/11/2023 2055 JMH
Prep Date Batch Leachate Date
01/05/2023 0910 64107 12/29/2022 1649
01/05/2023 1150 64188 12/29/2022 1649
01/11/2023 1118 64604 01/10/2023 1605
CAS Analytical
Parameter
Number Method
Result Q LOQ
Units
Run
Arsenic
7440-38-2 6010D
ND 0.15
mg/L
1
Barium
7440-39-3 6010D
ND 0.25
mg/L
3
Cadmium
7440-43-9 6010D
ND 0.050
mg/L
1
Chromium
7440-47-3 6010D
ND 0.10
mg/L
1
Lead
7439-92-1 6010D
ND 0.10
mg/L
1
Mercury
7439-97-6 7470A
ND 0.0020
mg/L
1
Selenium
7782-49-2 6010D
ND 0.20
mg/L
1
Silver
7440-22-4 6010D
ND 0.10
mg/L
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range Q - Surrogate failure
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 10

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 10

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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 10
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PACE ANALYTICAL SERVICES, LLC
0OL Tide: FNV-FRM- C0L-0286 vG2 5arnp1rj- Rw.;eipt Eharklis# (SRC)
ELFactive Date- M12022
Sample Receipt Cheddist (SRC)
Chem. T3-R[k,k PIE, E'cVAi Cui:lC'r T119-f.ai!d ?dale- xISKR r I'.12 22 _906 XL
Lot #' ' '
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Na NA 2. itcustod 'sr* wm resells wcre they Ltitza land lmhrolp�u?
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1.4 i1A NA r+NA eNA oC MA i1trk oc.
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o ! NA 4. Is 11re eornnieMal conricr's pf &a 81ip attaclled to this form?
YcsJNLo
S. W,� . prr�acr mtodyproccdurcw (relinquish d'receivedj follatvM?
,I Yrs 6. w samplt ws Lisred M1 rllti COS[: alld all sar ple caotaiurrsl
kes N 7- 7. Was ralkdon dale & rigle ltsted U11 die OC*C:md all sample co ah ?
Yes Na & Ll d Lill coutlliw label l nfilrrinb)ul (ID, da..e, vru=} t%! Aith the COC?
V Yrs Na 9. WfAr [esm to be Mfclruwd listed on the COC.?
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(tinbr-Ami, I S 013. ere_)? _
Yes ❑ 111. W' q aL%juate saq)lc Volta= availalile7
Yes Na 12, -WILM all IAUlplcs recrived wlthi3l !4 the holdhig tilllc of 48 holes, 1143iche ev corers fiSSF'?
lay E]No 15, Wete 9115Mliale_s contafWas accomltni ko Dro 3�lissib lexcess
[]Yes [ N 01 4 14_ Wele. VOA- 8015C sal RSK-i75 &11 l rs ftce oftubblrs >-pea-size" '/"ol 6ir1 i_1
falnmrer) is My of 11w VOA ViAs?
15. Wirt
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LJY,m Z NolC_ I$ W-1a the gtaolc rnunber listed on the �on[ajmx
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'a u r�eeivcd iucofrec EIy prr�;MT4 and wee adj ststed
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alllplc�,s'� NA
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8UDFdh181Y in sampie r tiyi]IZ 16TI I S06Utl1 1111Mhte CNa.ISZ05} with Unique W. NA
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 10

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: SC Samples
Lot Number:XL29021
Date Completed:01/17/2023
NIM�I�Mr�
01/18/2023 11:35 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XL29021
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
PCBs by GC
The laboratory control sample (LCS) passes, but laboratory control sample duplicate (LCSD) for
analytical batch 64424 recovered outside acceptance criteria. For the following sample(s) there was an
insufficient amount to perform a re -extraction or re -analysis: XL29021-001. The data has been reported.
Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for
prep batch 64296. An LCS/LCSD was run in lieu of an MS/MSD.
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XL29021
Sample Number Sample ID Matrix Date Sampled Date Received
001 MATHIS-1 Solid 12/27/2022 0900 12/29/2022
(1 sample)
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

PACE ANALYTICAL SERVICES, LLC
Sample
Sample ID
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
(8 detections)
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XL29021
Matrix Parameter Method Result Q Units Page
Solid
% Volatile Solids
SM 2540G-
98
% 5
Solid
Ammonia - N (gas
350.1
10000
mg/kg 5
Solid
Nitrate -Nitrite - N (soluble)
353.2
110
mg/kg 5
Solid
Phosphorus
365.1
5700
mg/kg 5
Solid
TKN
351.2
69000
mg/kg 5
Solid
Aluminum
601OD
1800
mg/kg 6
Solid
Copper
601OD
41
mg/kg 6
Solid
Zinc
601OD
260
mg/kg 6
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Page 4 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:XL29021-001
Description: MATHIS-1 Matrix: Solid
Date Sampled:12/27/2022 0900 % Solids: 2.80 01/03/2023 1657
)ate Received:12/29/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
01/02/2023 1219 CBP
63963
1 350.1
(Ammonia - N) 350.1
10
01/14/2023 1149 CMM
64686
1
(Nitrate-Nitr) 353.2
1
01/13/2023 1109 CMM
64785
1
(Phosphorus) 365.1
5
01/09/2023 0831 DMA
01/04/2023 1242 64080
1
(Soil pH meas) 9045D
1
12/30/2022 1516 BMG2
63751
1 351.4
(TKN) 351.2
2
01/16/2023 1838 DMA
01/16/2023 0808 64877
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
98
%
1
Ammonia - N (gas diffusion)
350.1
10000
3600
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
110
7.1
mg/kg
1
Phosphorus
7723-14-0 365.1
5700
890
mg/kg
1
Soil pH measured in water C) 15.8 ° C
9045D
5.1
su
1
TKN
351.2
69000
3600
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
3 3550C 366013/3665A 8082A
1 01/09/2023 1205 DAL1
01/06/2023 1203 64296
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND L
610
ug/kg
3
Aroclor 1221
11104-28-2 8082A
ND
610
ug/kg
3
Aroclor 1232
11141-16-5 8082A
ND
610
ug/kg
3
Aroclor 1242
53469-21-9 8082A
ND
610
ug/kg
3
Aroclor 1248
12672-29-6 8082A
ND
610
ug/kg
3
Aroclor 1254
11097-69-1 8082A
ND
610
ug/kg
3
Aroclor 1260
11096-82-5 8082A
ND L
610
ug/kg
3
Run 3 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
74 41-132
Tetrachloro-m-xylene
70 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/30/2022 0922 JAB2 12/30/2022 0758 63874
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471 B N D 2.9
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:XL29021-001
Description: MATHIS-1 Matrix: Solid
Date Sampled:12/27/2022 0900 % Solids: 2.80 01/03/2023 1657
Date Received:12/29/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 01/03/2023 2249 JMH 12/30/2022 0734 63870
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
601 OD
1800
660
mg/kg
1
Arsenic
7440-38-2
601 OD
ND
25
mg/kg
1
Cadmium
7440-43-9
601 OD
ND
8.3
mg/kg
1
Calcium
7440-70-2
601 OD
ND
8300
mg/kg
1
Copper
7440-50-8
601 OD
41
17
mg/kg
1
Lead
7439-92-1
601 OD
N D
17
mg/kg
1
Magnesium
7439-95-4
601 OD
N D
8300
mg/kg
1
Molybdenum
7439-98-7
601 OD
N D
66
mg/kg
1
Nickel
7440-02-0
601 OD
ND
66
mg/kg
1
Potassium
7440-09-7
601 OD
N D
8300
mg/kg
1
Selenium
7782-49-2
601 OD
ND
33
mg/kg
1
Sodium
7440-23-5
601 OD
N D
8300
mg/kg
1
Zinc
7440-66-6
601 OD
260
83
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 9

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 9

PACE ANALYTICAL SERVICES, LLC
DC:# Title- ENV-FR'1L-)ACGL-02#3 1+0 � arnpiey liaoaipt C1i�ck!ist �SRCJ Eff"divA Date' 8j212027
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Page T of :1
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
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0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: SC Samples
Lot Number:XL29023
Date Completed:01/13/2023
NIM�I�Mr�
01/17/2023 4:10 PM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
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'ye I
ANSI NdmlAccre00- Board
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Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page Iof10

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XL29023
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
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Page 2 of 10

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XL29023
Sample Number Sample ID Matrix Date Sampled Date Received
001 MATHIS-1 Solid 12/27/2022 0900 12/29/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of10

PACE ANALYTICAL SERVICES, LLC
Sample Sample ID
001 MATHIS-1
(1 detection)
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XL29023
Matrix Parameter Method Result Q Units Page
Solid Flashpoint (Pensky- 1010B >140 ° F 5
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Client: Terra Renewal Services, Inc. Laboratory ID:XL29023-001
Description: MATHIS-1 Matrix: Solid
Date Sampled:12/27/2022 0900
Date Received:12/29/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date Batch
1
(Flashpoint () 1010B
1
01/12/2023 2138 CBP 64784
1
(Reactive Cya) 7.3.3
1
01/10/2023 1555 SJL 01/09/2023 1221
1
(Reactive Sul) 7.3.4
1
01/10/2023 1735 CVR 01/09/2023 1221
1
(Soil pH meas) 9045D
1
12/30/2022 1527 BMG2 63751
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Flashpoint (Pensky-Martens Closed -Cup)
1010B
>140
140
° F
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water C) 16.3 ° C
9045D
4.8
su
1
TCLP Volatiles
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/5030B 8260D 10 01/09/20231806 CDA 64449 12/29/20221645
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Benzene
71-43-2
8260D
ND
0.050
mg/L
2-Butanone (MEK)
78-93-3
8260D
ND S
0.10
mg/L
Carbon tetrachloride
56-23-5
8260D
ND
0.050
mg/L
Chlorobenzene
108-90-7
8260D
ND
0.050
mg/L
Chloroform
67-66-3
8260D
ND
0.050
mg/L
1,2-Dichloroethane
107-06-2
8260D
ND
0.050
mg/L
1,1-Dichloroethene
75-35-4
8260D
ND
0.050
mg/L
Tetrachloroethene
127-18-4
8260D
ND
0.050
mg/L
Trichloroethene
79-01-6
8260D
ND
0.050
mg/L
Vinyl chloride
75-01-4
8260D
ND
0.010
mg/L
Run 1
Acceptance
Surrogate
Q % Recovery
Limits
Bromofluorobenzene
91
70-130
1,2-Dichloroethane-d4
92
70-130
Toluene-d8
96
70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 01/05/2023 1317 CMF
01/03/2023 1355 64019 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L 1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L 1
Hexachlorobenzene
118-74-1 8270E
N D L
0.040
mg/L 1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 5 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29023-001
Description: MATHIS-1 Matrix: Solid
Date Sampled:12/27/2022 0900
Date Received: 12/29/2022
TCLP Semivolatiles
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8270E 1 01/05/2023 1317 CMF 01/03/2023 1355 64019 12/29/2022 1649
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Hexachloroethane
67-72-1
8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7
8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5
8270E
ND
0.040
mg/L
1
Nitrobenzene
98-95-3
8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5
8270E
ND
0.20
mg/L
1
Pyridine
110-86-1
8270E
N D L
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4
8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2
8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery
Limits
2-Fluorobiphenyl
91
37-129
2-Fluorophenol
72
24-127
Nitrobenzene-d5
87
38-127
Phenol-d5
74
28-128
Terphenyl-d14
96
10-148
2,4,6-Tribromophenol
111
41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311 /8151 A
8151A
1 01 /05/2023 1427 SAF
01 /03/2023 2007 64037 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L
1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
59 50-112
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8081B
1 01/05/20231702 DAL1
01/03/20231111 63978 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
gamma-BHC (Lindane)
58-89-9 8081 B
ND
0.00040
mg/L
1
Chlordane
57-74-9 8081 B
ND
0.0040
mg/L
1
Endrin
72-20-8 8081 B
ND
0.00040
mg/L
1
Heptachlor
76-44-8 8081 B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3 8081 B
ND
0.00040
mg/L
1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD
failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29023-001
Description: MATHIS-1 Matrix: Solid
Date Sampled:12/27/2022 0900
)ate Received: 12/29/2022
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 01/05/20231702 DAL1 01/03/20231111 63978 12/29/2022 1649
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Methoxychlor 72-43-5 8081 B N D 0.0016 mg/L 1
Toxaphene 8001-35-2 8081 B ND 0.0080 mg/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl 63 20-131
Tetrachloro-m-xylene 93 26-132
TCLP Metals
Run Prep Method
1 1311/3010A
1 1311/7470A
3 1311/3010A
Analytical Method
6010D
7470A
6010D
Dilution Analysis Date Analyst
1 01/05/2023 2034 JMH
1 01/05/2023 1631 MRW2
1 01/11/2023 2047 JMH
Prep Date Batch Leachate Date
01/05/2023 0910 64107 12/29/2022 1649
01/05/2023 1150 64188 12/29/2022 1649
01/11/2023 1118 64604 01/10/2023 1605
CAS Analytical
Parameter
Number Method
Result Q LOQ
Units
Run
Arsenic
7440-38-2 6010D
ND 0.15
mg/L
1
Barium
7440-39-3 6010D
ND 0.25
mg/L
3
Cadmium
7440-43-9 6010D
ND 0.050
mg/L
1
Chromium
7440-47-3 6010D
ND 0.10
mg/L
1
Lead
7439-92-1 6010D
ND 0.10
mg/L
1
Mercury
7439-97-6 7470A
ND 0.0020
mg/L
1
Selenium
7782-49-2 6010D
ND 0.20
mg/L
1
Silver
7440-22-4 6010D
ND 0.10
mg/L
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range Q - Surrogate failure
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 10

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 10

PACE ANALYTICAL SERVICES, LLC
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 10

PACE ANALYTICAL SERVICES, LLC
IQC#_! itle= E14V-FRM-WC4:I11-0286 vU2-. Ssrnplas i ceipt CftieckGst (SRC1
Effecti,fn Date; 8J2/2022
Sample Reeciipt Checklist (SRC)
Clien-t: � RENTS AL Cooluhisixetrdb�ldare; t, + :z+3P1�2 l r XL29M
lwlcans Of rloomeceipt: ?arc o Client UPS LedEx luflier
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7. Was coilectiou dmr4k time lisp an the C.Oc ; ud ail san1Irle � u„iriz€tcrs?
8, Did all coritiiiiwr label jalf+]1731l1_ipg) IJD, dwo, untie) agrcz uitii the COC-�
9_ Were Lrs rs to be Per ;ued lislLd on the COC?
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 10

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: SC Samples
Lot Number:XL29025
Date Completed:01/17/2023
NIM�I�Mr�
01/18/2023 11:43 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XL29025
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
PCBs by GC
The laboratory control sample (LCS) passes, but laboratory control sample duplicate (LCSD) for
analytical batch 64424 recovered outside acceptance criteria. For the following sample(s) there was an
insufficient amount to perform a re -extraction or re -analysis: XL29025-001. The data has been reported.
Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for
prep batch 64296. An LCS/LCSD was run in lieu of an MS/MSD.
Inorganic Non -Metals
Nitrate -Nitrite sample XL29025-001 assoicated with batch 64785 was analyzed in a bracket that had more
then 10 injections between QC which is a devation from the SOP. However, both opening and closing QC
were within range showing the instrument was incontrol and results should not be impacted. Data has
been reported
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XL29025
Sample Number Sample ID Matrix Date Sampled Date Received
001 TYSON WILKESBORO Solid 12/27/2022 1000 12/29/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

PACE ANALYTICAL SERVICES,
LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XL29025
Sample
Sample ID
Matrix Parameter Method
Result Q
Units
Page
001
TYSON WILKESBORO
Solid % Volatile Solids SM 2540G-
99
%
5
001
TYSON WILKESBORO
Solid Ammonia - N (gas 350.1
5400
mg/kg
5
001
TYSON WILKESBORO
Solid Nitrate -Nitrite - N (soluble) 353.2
92 S
mg/kg
5
001
TYSON WILKESBORO
Solid Phosphorus 365.1
2300 S
mg/kg
5
001
TYSON WILKESBORO
Solid TKN 351.2
36000
mg/kg
5
001
TYSON WILKESBORO
Solid Copper 6010D
28
mg/kg
6
(6 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:XL29025-001
Description: TYSON WILKESBORO Matrix: Solid
Date Sampled:12/27/2022 1000 % Solids: 5.31 01/03/2023 1657
)ate Received:12/29/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 2540G-1997
1
01/02/2023 1219 CBP
63963
1 350.1
(Ammonia - N) 350.1
10
01/14/2023 1153 CMM
64686
1
(Nitrate-Nitr) 353.2
1
01/13/2023 1119 CMM
64785
1
(Phosphorus) 365.1
5
01/09/2023 0831 DMA
01/04/2023 1242 64080
1
(Soil pH meas) 9045D
1
12/30/2022 1520 BMG2
63751
1 351.4
(TKN) 351.2
2
01/16/2023 1632 DMA
01/16/2023 0808 64877
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 2540G-1997
99
%
1
Ammonia - N (gas diffusion)
350.1
5400
1900
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
92 S
3.8
mg/kg
1
Phosphorus
7723-14-0 365.1
2300 S
470
mg/kg
1
Soil pH measured in water @ 15.5 ° C
9045D
4.4
su
1
TKN
351.2
36000
1900
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
3 3550C 366013/3665A 8082A
1 01/09/2023 1231 DAL1
01/06/2023 1203 64296
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND L
320
ug/kg
3
Aroclor 1221
11104-28-2 8082A
ND
320
ug/kg
3
Aroclor 1232
11141-16-5 8082A
ND
320
ug/kg
3
Aroclor 1242
53469-21-9 8082A
ND
320
ug/kg
3
Aroclor 1248
12672-29-6 8082A
ND
320
ug/kg
3
Aroclor 1254
11097-69-1 8082A
ND
320
ug/kg
3
Aroclor 1260
11096-82-5 8082A
ND L
320
ug/kg
3
Run 3 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
64 41-132
Tetrachloro-m-xylene
59 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/30/2022 0928 JAB2 12/30/2022 0758 63874
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471 B N D 1.5
mg/kg 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:XL29025-001
Description: TYSON WILKESBORO Matrix: Solid
Date Sampled:12/27/2022 1000 % Solids: 5.31 01/03/2023 1657
Date Received:12/29/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 01/03/2023 2257 JMH 12/30/2022 0734 63870
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
601 OD
ND
310
mg/kg
1
Arsenic
7440-38-2
601 OD
N D
12
mg/kg
1
Cadmium
7440-43-9
601 OD
ND
3.9
mg/kg
1
Calcium
7440-70-2
601 OD
ND
3900
mg/kg
1
Copper
7440-50-8
601 OD
28
7.8
mg/kg
1
Lead
7439-92-1
601 OD
N D
7.8
mg/kg
1
Magnesium
7439-95-4
601 OD
N D
3900
mg/kg
1
Molybdenum
7439-98-7
601 OD
N D
31
mg/kg
1
Nickel
7440-02-0
601 OD
ND
31
mg/kg
1
Potassium
7440-09-7
601 OD
N D
3900
mg/kg
1
Selenium
7782-49-2
601 OD
ND
16
mg/kg
1
Sodium
7440-23-5
601 OD
N D
3900
mg/kg
1
Zinc
7440-66-6
601 OD
N D
39
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40%
H - Out of holding time W - Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9
Q - Surrogate failure
L - LCS/LCSD failure
S - MS/MSD failure

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 9

PACE ANALYTICAL SERVICES, LLC
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 9

PACE ANALYTICAL SERVICES, LLC
DO_Titl$- Eli V-FRM-WCOL-0226 v02-5i�mples ReceiptCLh�kIM15RTr)
Ef etiVo Date: 812f2022
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yes No 4. is the couunercial crnu�.er'spacijug slip attadmd to -I, is fan? n
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9- W= LCsL`9 10 be 5-:ftU Cd listed oil ffic CX)(7?
10, Did all saji*es iruive in tlic proper emu.-iners far tMb test a xVor i u gmd cwRT=
[JH]broken, iids ou. etc.)?
11- Was n&quafrr .uk1 k volrulW avai'Jubk7
12. wem all s2mples received mr11 l LA [ll-, 11cilding tithe or d$ hours- whichever c0=5 f3rst?
13- Wcre all saapjcs c�mtnhters accalGnT4 foz? (No sui!ssingewes }
14. 'Were VOA, 801!50 aild 1 .K-?75 samples free of-bubblts `pea~si e" (%"ear CilMI �
diail=* in anvoftic VGA vials?
1$. Were all DRtNumalsfuutrielir Sfi - eS received Ld a PH of < 27
ara1]IT>12xmd
F—
jyesl 41 K01 ❑NA I18. MIS the qu❑lc unru6er lasted ou :h, coiltaioer label? if v 1, Ro4e #
ataRH>T-
�lfi I'tle�erv�tion {i�irlst lac �cxl:rplelcdforlxu�saropiefa7 it3[[nTefitlyInx�sm�cd or t��#lti Fie�ds}�IE�,�
anpk(sl NIL wclxleceivc�n7c�raellylrreservedlztxiu,��:ui�l�cted.
sluvple Tccei%* with NA '. 1°Cll lE vile: MSl4M, HIwT03- 14C], M011 mbig SR q _ A _
ine of }laQ$ 4aL NA
_ Y MOM d= c= preservative LQ I14 cda pkisc ]lf.2re iu dw uorlllatins bolow
NA
vl'erC FMLlved wiTh biL[ zs :-6 Mull iu dienTetef,
5autplCS(e) xx were received TRC > -D 5 MWL (If ivi.9 is nz?) and were
�1135tcd BCuvrkn;t1Yw sffiTE* itccivM9 With snrbuu rhioa t ntc (Na2S204l ivitll Unique M: }yA
U11lLIlC11rS; — — —
Pmg$ � bf l
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 9

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: SC Samples
Lot Number:XL29024
Date Completed:01/13/2023
01/17/2023 4:11 PM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page Iof10

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: XL29024
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 10

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: XL29024
Sample Number Sample ID Matrix Date Sampled Date Received
001 TYSON WILKESBORO Solid 12/27/2022 1000 12/29/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of10

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: XL29024
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 TYSON WILKESBORO Solid Flashpoint (Pensky- 1010B >140 ° F 5
(1 detection)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29024-001
Description: TYSON WILKESBORO Matrix: Solid
Date Sampled:12/27/2022 1000 % Solids: 3.50 01/03/2023 1657
Date Received:12/29/2022
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date Batch
1
(Flashpoint () 1010B
1
01/12/2023 2329 CBP 64784
1
(Reactive Cya) 7.3.3
1
01/06/2023 1414 SJL 01/03/2023 1236
1
(Reactive Sul) 7.3.4
1
01/10/2023 1735 CVR 01/09/2023 1221
1
(Soil pH meas) 9045D
1
12/30/2022 1528 BMG2 63751
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Flashpoint (Pensky-Martens Closed -Cup)
1010B
>140
140
° F
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water C) 16.1 ° C
9045D
3.8
su
1
TCLP Volatiles
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/5030B 8260D 10 01/09/20231831 CDA 64449 12/29/20221645
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Benzene
71-43-2
8260D
ND
0.050
mg/L
2-Butanone (MEK)
78-93-3
8260D
ND
0.10
mg/L
Carbon tetrachloride
56-23-5
8260D
ND
0.050
mg/L
Chlorobenzene
108-90-7
8260D
ND
0.050
mg/L
Chloroform
67-66-3
8260D
ND
0.050
mg/L
1,2-Dichloroethane
107-06-2
8260D
ND
0.050
mg/L
1,1-Dichloroethene
75-35-4
8260D
ND
0.050
mg/L
Tetrachloroethene
127-18-4
8260D
ND
0.050
mg/L
Trichloroethene
79-01-6
8260D
ND
0.050
mg/L
Vinyl chloride
75-01-4
8260D
ND
0.010
mg/L
Run 1
Acceptance
Surrogate
Q % Recovery
Limits
Bromofluorobenzene
93
70-130
1,2-Dichloroethane-d4
90
70-130
Toluene-d8
96
70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 01/05/2023 1342 CMF
01/03/2023 1355 64019 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L 1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L 1
Hexachlorobenzene
118-74-1 8270E
N D L
0.040
mg/L 1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L 1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29024-001
Description: TYSON WILKESBORO Matrix: Solid
Date Sampled:12/27/2022 1000 % Solids: 3.50 01/03/2023 1657
Date Received: 12/29/2022
TCLP Semivolatiles
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8270E 1 01/05/2023 1342 CMF 01/03/2023 1355 64019 12/29/2022 1649
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Hexachloroethane
67-72-1
8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7
8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5
8270E
ND
0.040
mg/L
1
Nitrobenzene
98-95-3
8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5
8270E
ND
0.20
mg/L
1
Pyridine
110-86-1
8270E
N D L
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4
8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2
8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery
Limits
2-Fluorobiphenyl
94
37-129
2-Fluorophenol
42
24-127
Nitrobenzene-d5
91
38-127
Phenol-d5
58
28-128
Terphenyl-d14
104
10-148
2,4,6-Tribromophenol
115
41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311 /8151 A
8151A
1 01 /05/2023 1513 SAF
01/03/2023 2007 64037 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L
1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
59 50-112
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8081B
1 01/05/20231734 DAL1
01/03/20231111 63978 12/29/2022 1649
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
gamma-BHC (Lindane)
58-89-9 8081 B
ND
0.00040
mg/L
1
Chlordane
57-74-9 8081 B
ND
0.0040
mg/L
1
Endrin
72-20-8 8081 B
ND
0.00040
mg/L
1
Heptachlor
76-44-8 8081 B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3 8081 B
ND
0.00040
mg/L
1
LOQ - Limit of Quantitation
B - Detected in the method blank
E - Quantitation of compound exceeded the calibration range
Q - Surrogate failure
ND - Not detected at or above the LOQ
N - Recovery is out of criteria
P - The RPD between two GC columns exceeds 40%
L - LCS/LCSD
failure
H - Out of holding time
W - Reported on wet weight basis
S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 10

Client: Terra Renewal Services, Inc. Laboratory ID:XL29024-001
Description: TYSON WILKESBORO Matrix: Solid
Date Sampled:12/27/2022 1000 % Solids: 3.50 01/03/2023 1657
)ate Received: 12/29/2022
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 01/05/20231734 DAL1 01/03/20231111 63978 12/29/2022 1649
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Methoxychlor 72-43-5 8081 B N D 0.0016 mg/L 1
Toxaphene 8001-35-2 8081 B ND 0.0080 mg/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl 58 20-131
Tetrachloro-m-xylene 94 26-132
TCLP Metals
Run Prep Method
1 1311/3010A
1 1311/7470A
3 1311/3010A
Analytical Method
6010D
7470A
6010D
Dilution Analysis Date Analyst
1 01/05/2023 2050 JMH
1 01/05/2023 1639 MRW2
1 01/11/2023 2051 JMH
Prep Date Batch Leachate Date
01/05/2023 0910 64107 12/29/2022 1649
01/05/2023 1150 64188 12/29/2022 1649
01/11/2023 1118 64604 01/10/2023 1605
CAS Analytical
Parameter
Number Method
Result Q LOQ
Units
Run
Arsenic
7440-38-2 6010D
ND 0.15
mg/L
1
Barium
7440-39-3 6010D
ND 0.25
mg/L
3
Cadmium
7440-43-9 6010D
ND 0.050
mg/L
1
Chromium
7440-47-3 6010D
ND 0.10
mg/L
1
Lead
7439-92-1 6010D
ND 0.10
mg/L
1
Mercury
7439-97-6 7470A
ND 0.0020
mg/L
1
Selenium
7782-49-2 6010D
ND 0.20
mg/L
1
Silver
7440-22-4 6010D
ND 0.10
mg/L
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range Q - Surrogate failure
ND - Not detected at or above the LOQ N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 10

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 10

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 10

PACE ANALYTICAL SERVICES, LLC
DC# Tn's. ENV-FRM-WCOL-0286vD2 samples R*ceiptChecklist(SRCj
Effective Date- 91'2M22
Sample receipt Checklist ( RQ
Mew: 11MRARUNE-WA Cuol�r Iusvet[all l�Y+[late; KDRW i 1.+2si12 Lit ��; Xl.�;'J,a
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7, N:'as collulion dale & [*zc iistcd oil Flee COC aid oil sample wjlt-31111 S -
Yes
Ho
S Did al.l confaanrr 1Acl infannarirm 00, date, TiJm) agree miU The COC?
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Yes
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9. Were tests M be Peffo=d fisted on Flee COC'.1
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10. Did. -ill salllpk5 arrive in tilt }roper o4�raiileis for eacil [e9E alld}'ar in good con�itiOD
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VVas a�cgts salnplev�ltune available?
1i_ WrrC all ! ar es receivvd widdn � tI1- hulibiq Ihnc or 43 lunu ;vlllcltcvcr fQ1t1C+ 1ii$*
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❑NO
13. Were 811 s3illples eant.incrs arr-ouutM t (NOPriLSStaI�jeX[�S)
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14. Werr,VOA, 901.5C anal RSK,17� sauquirs fret of bubbles: ` pm -sib' (Vii"er 61l�lll in
dimucttr) 11) ; Ily ofVOA Y2lLl�,2
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15.Wemall DI1OAntI2aIlsrnlitrient saiupies received at. a pH of < 2?EY
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16. Ware all cyaavde s 1 wu6vcd at a 1 r 12 and -Ldfide .mn les r =%ped at n � 9?
❑Yes
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a sample receiving Ath NA�ii L of CifL;L our: H2SG4, 1-EN 03, HC.1, NaOH using SR 'q
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sltrax ID; 5636p Paoa° Analytica 5ervic@s, LLC Pay
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 10

Laboratory Analyses:
- Seven Set Fecal Coliform Data

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 03/22/2022
Reported: 03/23/2022
For: ADVANCE CLAREMONT
Comments:
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220322-25-01
Fecal Coliforms
AC1
<3795
MPN/g
SM92210E-2006
03/22/2022
MD
220322-25-01
Percent Solids
AC1
5.27
%
SM2540B-2011
03/22/2022
MD
220322-25-02
Fecal Coliforms
AC2
<3781
MPN/g
SM92210E-2006
03/22/2022
MD
220322-25-02
Percent Solids
AC2
5.29
%
SM2540B-2011
03/22/2022
MD
220322-25-03
Fecal Coliforms
AC3
<3766
MPN/g
SM92210E-2006
03/22/2022
MD
220322-25-03
Percent Solids
AC3
5.31
%
SM2540B-2011
03/22/2022
MD
220322-25-04
Fecal Coliforms
AC4
<3774
MPN/g
SM92210E-2006
03/22/2022
MD
220322-25-04
Percent Solids
AC4
5.30
%
SM2540B-2011
03/22/2022
MD
220322-25-05
Fecal Coliforms
AC5
<3738
MPN/g
SM92210E-2006
03/22/2022
MD
220322-25-05
Percent Solids
AC5
5.35
%
SM2540B-2011
03/22/2022
MD
220322-25-06
Fecal Coliforms
AC6
<3781
MPN/g
SM92210E-2006
03/22/2022
MD
220322-25-06
Percent Solids
AC6
5.29
%
SM2540B-2011
03/22/2022
MD
220322-25-07
Fecal Coliforms
AC7
<3683
MPN/g
SM92210E-2006
03/22/2022
MD
220322-25-07
Percent Solids
AC7
5.43
%
SM2540B-2011
03/22/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220322-25-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220322-25-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220322-25-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220322-25-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220322-25-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220322-25-06 Temp on Arrival: 3.0
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220322-25-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 03/31/2022
Reported: 04/01 /2022
For: Tyson Harmony (B)
Comments: GEOMETRIC MEAN: 35,034 MPN/g
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220331-18-01
Fecal Coliforms
131
42328
MPN/g
SM92210E-2006
03/31/2022
MD
220331-18-01
Percent Solids
131
1.89
%
SM2540B-2011
03/31/2022
MD
220331-18-02
Fecal Coliforms
B2
10989
MPN/g
SM92210E-2006
03/31/2022
MD
220331-18-02
Percent Solids
B2
1.82
%
SM2540B-2011
03/31/2022
MD
220331-18-03
Fecal Coliforms
133
42781
MPN/g
SM92210E-2006
03/31/2022
MD
220331-18-03
Percent Solids
133
1.87
%
SM2540B-2011
03/31/2022
MD
220331-18-04
Fecal Coliforms
134
11173
MPN/g
SM92210E-2006
03/31/2022
MD
220331-18-04
Percent Solids
134
1.79
%
SM2540B-2011
03/31/2022
MD
220331-18-05
Fecal Coliforms
135
129214
MPN/g
SM92210E-2006
03/31/2022
MD
220331-18-05
Percent Solids
B5
1.78
%
SM2540B-2011
03/31/2022
MD
220331-18-06
Fecal Coliforms
B6
32258
MPN/g
SM92210E-2006
03/31/2022
MD
220331-18-06
Percent Solids
B6
1.86
%
SM2540B-2011
03/31/2022
MD
220331-18-07
Fecal Coliforms
B7
69893
MPN/g
SM92210E-2006
03/31/2022
MD
220331-18-07
Percent Solids
B7
1.86
%
SM2540B-2011
03/31/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220331-18-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220331-18-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220331-18-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220331-18-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220331-18-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220331-18-06 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220331-18-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4y4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 06/16/2022
Reported: 06/17/2022
For: Tyson Harmony
Comments: GEOMETRIC MEAN: 138,385 MPN/g
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220616-14-01
Fecal Coliforms
TH1
106762
MPN/g
SM92210E-2006
06/16/2022
MD
220616-14-01
Percent Solids
TH1
2.81
%
SM2540B-2011
06/16/2022
MD
220616-14-02
Fecal Coliforms
TH2
106762
MPN/g
SM92210E-2006
06/16/2022
MD
220616-14-02
Percent Solids
TH2
2.81
%
SM2540B-2011
06/16/2022
MD
220616-14-03
Fecal Coliforms
TH3
82437
MPN/g
SM92210E-2006
06/16/2022
MD
220616-14-03
Percent Solids
TH3
2.79
%
SM2540B-2011
06/16/2022
MD
220616-14-04
Fecal Coliforms
TH4
180505
MPN/g
SM92210E-2006
06/16/2022
MD
220616-14-04
Percent Solids
TH4
2.77
%
SM2540B-2011
06/16/2022
MD
220616-14-05
Fecal Coliforms
TH5
288889
MPN/g
SM92210E-2006
06/16/2022
MD
220616-14-05
Percent Solids
TH5
2.77
%
SM2540B-2011
06/16/2022
MD
220616-14-06
Fecal Coliforms
TH6
109890
MPN/g
SM92210E-2006
06/16/2022
MD
220616-14-06
Percent Solids
TH6
2.73
%
SM2540B-2011
06/16/2022
MD
220616-14-07
Fecal Coliforms
TH7
180505
MPN/g
SM92210E-2006
06/16/2022
MD
220616-14-07
Percent Solids
TH7
2.77
%
SM2540B-2011
06/16/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220616-14-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220616-14-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220616-14-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220616-14-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220616-14-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220616-14-06 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220616-14-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 09/29/2022
Reported: 09/30/2022
For: TYSON HARMONY
Comments: GEOEMTRIC MEAN: 46,833 MPN/g
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220929-20-01
Fecal Coliforms
TH-1
75472
MPN/g
SM92210E-2006
09/29/2022
MD
220929-20-01
Percent Solids
TH-1
10.6
%
SM2540B-2011
09/29/2022
MD
220929-20-02
Fecal Coliforms
TH-2
81136
MPN/g
SM92210E-2006
09/29/2022
MD
220929-20-02
Percent Solids
TH-2
9.86
%
SM2540B-2011
09/29/2022
MD
220929-20-03
Fecal Coliforms
TH-3
22549
MPN/g
SM92210E-2006
09/29/2022
MD
220929-20-03
Percent Solids
TH-3
10.2
%
SM2540B-2011
09/29/2022
MD
220929-20-04
Fecal Coliforms
TH-4
106796
MPN/g
SM92210E-2006
09/29/2022
MD
220929-20-04
Percent Solids
TH-4
10.3
%
SM2540B-2011
09/29/2022
MD
220929-20-05
Fecal Coliforms
TH-5
29126
MPN/g
SM92210E-2006
09/29/2022
MD
220929-20-05
Percent Solids
TH-5
10.3
%
SM2540B-2011
09/29/2022
MD
220929-20-06
Fecal Coliforms
TH-6
28302
MPN/g
SM92210E-2006
09/29/2022
MD
220929-20-06
Percent Solids
TH-6
10.6
%
SM2540B-2011
09/29/2022
MD
220929-20-07
Fecal Coliforms
TH-7
40650
MPN/g
SM92210E-2006
09/29/2022
MD
220929-20-07
Percent Solids
TH-7
12.3
%
SM2540B-2011
09/29/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220929-20-01 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-20-02 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-20-03 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-20-04 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-20-05 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-20-06 Temp on Arrival: 2.3
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-20-07 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 12/27/2022
Reported: 12/28/2022
For: Tyson -Harmony
Comments: GEOMETRIC MEAN: 16,726 MPN/g
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
221227-19-01
Fecal Coliforms
TH-1
13514
MPN/g
SM92210E-2006
12/27/2022
MD
221227-19-01
Percent Solids
TH-1
5.92
%
SM2540B-2011
12/27/2022
MD
221227-19-02
Fecal Coliforms
TH-2
10101
MPN/g
SM92210E-2006
12/27/2022
MD
221227-19-02
Percent Solids
TH-2
7.92
%
SM2540B-2011
12/27/2022
MD
221227-19-03
Fecal Coliforms
TH-3
14177
MPN/g
SM92210E-2006
12/27/2022
MD
221227-19-03
Percent Solids
TH-3
9.17
%
SM2540B-2011
12/27/2022
MD
221227-19-04
Fecal Coliforms
TH-4
15550
MPN/g
SM92210E-2006
12/27/2022
MD
221227-19-04
Percent Solids
TH-4
8.36
%
SM2540B-2011
12/27/2022
MD
221227-19-05
Fecal Coliforms
TH-5
14461
MPN/g
SM92210E-2006
12/27/2022
MD
221227-19-05
Percent Solids
TH-5
8.99
%
SM2540B-2011
12/27/2022
MD
221227-19-06
Fecal Coliforms
TH-6
18625
MPN/g
SM92210E-2006
12/27/2022
MD
221227-19-06
Percent Solids
TH-6
6.98
%
SM2540B-2011
12/27/2022
MD
221227-19-07
Fecal Coliforms
TH-7
45181
MPN/g
SM92210E-2006
12/27/2022
MD
221227-19-07
Percent Solids
TH-7
6.64
%
SM2540B-2011
12/27/2022
MD
Respectfully submitted,
X�- � �'?_ J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 221227-19-01 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 221227-19-02 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 221227-19-03 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 221227-19-04 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 221227-19-05 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 221227-19-06 Temp on Arrival:
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 221227-19-07 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 02/03/2022
Reported: 02/07/2022
For: MATHIS
Comments:
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220203-19-01
Fecal Coliforms
M1
<587
MPN/g
SM92210E-2006
02/03/2022
MD
220203-19-01
Percent Solids
M1
3.41
%
SM2540B-2011
02/03/2022
MD
220203-19-02
Fecal Coliforms
M2
<810
MPN/g
SM92210E-2006
02/03/2022
MD
220203-19-02
Percent Solids
M2
2.47
%
SM2540B-2011
02/03/2022
MD
220203-19-03
Fecal Coliforms
M3
<633
MPN/g
SM92210E-2006
02/03/2022
MD
220203-19-03
Percent Solids
M3
3.16
%
SM2540B-2011
02/03/2022
MD
220203-19-04
Fecal Coliforms
M4
<995
MPN/g
SM92210E-2006
02/03/2022
MD
220203-19-04
Percent Solids
M4
2.01
%
SM2540B-2011
02/03/2022
MD
220203-19-05
Fecal Coliforms
M5
<687
MPN/g
SM92210E-2006
02/03/2022
MD
220203-19-05
Percent Solids
M5
2.91
%
SM2540B-2011
02/03/2022
MD
220203-19-06
Fecal Coliforms
M6
<800
MPN/g
SM92210E-2006
02/03/2022
MD
220203-19-06
Percent Solids
M6
2.50
%
SM2540B-2011
02/03/2022
MD
220203-19-07
Fecal Coliforms
M7
<913
MPN/g
SM92210E-2006
02/03/2022
MD
220203-19-07
Percent Solids
M7
2.19
%
SM2540B-2011
02/03/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220203-19-01 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-19-02 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-19-03 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-19-04 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-19-05 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-19-06 Temp on Arrival: 2.3
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-19-07 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 06/28/2022
Reported: 06/30/2022
For: MATHIS
Comments:
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220628-20-01
Fecal Coliforms
M1
<1504
MPN/g
SM92210E-2006
06/28/2022
MD
220628-20-01
Percent Solids
M1
13.3
%
SM2540B-2011
06/28/2022
MD
220628-20-02
Fecal Coliforms
M2
<1550
MPN/g
SM92210E-2006
06/28/2022
MD
220628-20-02
Percent Solids
M2
12.9
%
SM2540B-2011
06/28/2022
MD
220628-20-03
Fecal Coliforms
M3
<1538
MPN/g
SM92210E-2006
06/28/2022
MD
220628-20-03
Percent Solids
M3
13.0
%
SM2540B-2011
06/28/2022
MD
220628-20-04
Fecal Coliforms
M4
<1527
MPN/g
SM92210E-2006
06/28/2022
MD
220628-20-04
Percent Solids
M4
13.1
%
SM2540B-2011
06/28/2022
MD
220628-20-05
Fecal Coliforms
M5
<1550
MPN/g
SM92210E-2006
06/28/2022
MD
220628-20-05
Percent Solids
M5
12.9
%
SM2540B-2011
06/28/2022
MD
220628-20-06
Fecal Coliforms
M6
<1563
MPN/g
SM92210E-2006
06/28/2022
MD
220628-20-06
Percent Solids
M6
12.8
%
SM2540B-2011
06/28/2022
MD
220628-20-07
Fecal Coliforms
M7
<1550
MPN/g
SM92210E-2006
06/28/2022
MD
220628-20-07
Percent Solids
M7
12.9
%
SM2540B-2011
06/28/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220628-20-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-20-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-20-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-20-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-20-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-20-06 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-20-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 09/26/2022
Reported: 09/28/2022
For: Mathis
Comments:
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220926-11-01
Fecal Coliforms
Mathis-1
2212
MPN/g
SM92210E-2006
09/26/2022
MD
220926-11-01
Percent Solids
Mathis-1
9.04
%
SM2540B-2011
09/26/2022
MD
220926-11-02
Fecal Coliforms
Mathis-2
2336
MPN/g
SM92210E-2006
09/26/2022
MD
220926-11-02
Percent Solids
Mathis-2
8.56
%
SM2540B-2011
09/26/2022
MD
220926-11-03
Fecal Coliforms
Mathis-3
<1974
MPN/g
SM92210E-2006
09/26/2022
MD
220926-11-03
Percent Solids
Mathis-3
10.13
%
SM2540B-2011
09/26/2022
MD
220926-11-04
Fecal Coliforms
Mathis-4
4292
MPN/g
SM92210E-2006
09/26/2022
MD
220926-11-04
Percent Solids
Mathis-4
9.32
%
SM2540B-2011
09/26/2022
MD
220926-11-05
Fecal Coliforms
Mathis-5
2328
MPN/g
SM92210E-2006
09/26/2022
MD
220926-11-05
Percent Solids
Mathis-5
8.59
%
SM2540B-2011
09/26/2022
MD
220926-11-06
Fecal Coliforms
Mathis-6
4667
MPN/g
SM92210E-2006
09/26/2022
MD
220926-11-06
Percent Solids
Mathis-6
8.57
%
SM2540B-2011
09/26/2022
MD
220926-11-07
Fecal Coliforms
Mathis-7
8969
MPN/g
SM92210E-2006
09/26/2022
MD
220926-11-07
Percent Solids
Mathis-7
8.92
%
SM2540B-2011
09/26/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220926-11-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220926-11-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220926-11-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220926-11-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220926-11-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220926-11-06 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220926-11-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4y4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 02/03/2022
Reported: 02/07/2022
For: Tyson Wilkesboro
Comments:
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220203-18-01
Fecal Coliforms
T1
<310
MPN/g
SM92210E-2006
02/03/2022
MD
220203-18-01
Percent Solids
T1
6.45
%
SM2540B-2011
02/03/2022
MD
220203-18-02
Fecal Coliforms
T2
<308
MPN/g
SM92210E-2006
02/03/2022
MD
220203-18-02
Percent Solids
T2
6.49
%
SM2540B-2011
02/03/2022
MD
220203-18-03
Fecal Coliforms
T3
<307
MPN/g
SM92210E-2006
02/03/2022
MD
220203-18-03
Percent Solids
T3
6.52
%
SM2540B-2011
02/03/2022
MD
220203-18-04
Fecal Coliforms
T4
<310
MPN/g
SM92210E-2006
02/03/2022
MD
220203-18-04
Percent Solids
T4
6.46
%
SM2540B-2011
02/03/2022
MD
220203-18-05
Fecal Coliforms
T5
<306
MPN/g
SM92210E-2006
02/03/2022
MD
220203-18-05
Percent Solids
T5
6.54
%
SM2540B-2011
02/03/2022
MD
220203-18-06
Fecal Coliforms
T6
<307
MPN/g
SM92210E-2006
02/03/2022
MD
220203-18-06
Percent Solids
T6
6.52
%
SM2540B-2011
02/03/2022
MD
220203-18-07
Fecal Coliforms
T7
<309
MPN/g
SM92210E-2006
02/03/2022
MD
220203-18-07
Percent Solids
T7
6.47
%
SM2540B-2011
02/03/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220203-18-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-18-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-18-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-18-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-18-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-18-06 Temp on Arrival: 3.0
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220203-18-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 06/28/2022
Reported: 06/30/2022
For: Tyson Wilkesboro
Comments:
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220628-19-01
Fecal Coliforms
TW-1
<1520
MPN/g
SM92210E-2006
06/28/2022
MD
220628-19-01
Percent Solids
TW-1
13.16
%
SM2540B-2011
06/28/2022
MD
220628-19-02
Fecal Coliforms
TW-2
<1563
MPN/g
SM92210E-2006
06/28/2022
MD
220628-19-02
Percent Solids
TW-2
12.8
%
SM2540B-2011
06/28/2022
MD
220628-19-03
Fecal Coliforms
TW-3
<1546
MPN/g
SM92210E-2006
06/28/2022
MD
220628-19-03
Percent Solids
TW-3
12.94
%
SM2540B-2011
06/28/2022
MD
220628-19-04
Fecal Coliforms
TW-4
<1539
MPN/g
SM92210E-2006
06/28/2022
MD
220628-19-04
Percent Solids
TW-4
13.0
%
SM2540B-2011
06/28/2022
MD
220628-19-05
Fecal Coliforms
TW-5
<1482
MPN/g
SM92210E-2006
06/28/2022
MD
220628-19-05
Percent Solids
TW-5
13.5
%
SM2540B-2011
06/28/2022
MD
220628-19-06
Fecal Coliforms
TW-6
<1539
MPN/g
SM92210E-2006
06/28/2022
MD
220628-19-06
Percent Solids
TW-6
13.0
%
SM2540B-2011
06/28/2022
MD
220628-19-07
Fecal Coliforms
TW-7
<1482
MPN/g
SM92210E-2006
06/28/2022
MD
220628-19-07
Percent Solids
TW-7
13.5
%
SM2540B-2011
06/28/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220628-19-01 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-19-02 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-19-03 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-19-04 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-19-05 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-19-06 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 220628-19-07 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 09/29/2022
Reported: 09/30/2022
For: TYSON WILKESBORO
Comments: GEOMETRIC MEAN: 31,264 MPN/g
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220929-19-01
Fecal Coliforms
TW-1
33333
MPN/g
SM92210E-2006
09/29/2022
MD
220929-19-01
Percent Solids
TW-1
15.0
%
SM2540B-2011
09/29/2022
MD
220929-19-02
Fecal Coliforms
TW-2
33333
MPN/g
SM92210E-2006
09/29/2022
MD
220929-19-02
Percent Solids
TW-2
15.0
%
SM2540B-2011
09/29/2022
MD
220929-19-03
Fecal Coliforms
TW-3
31650
MPN/g
SM92210E-2006
09/29/2022
MD
220929-19-03
Percent Solids
TW-3
15.8
%
SM2540B-2011
09/29/2022
MD
220929-19-04
Fecal Coliforms
TW-4
30675
MPN/g
SM92210E-2006
09/29/2022
MD
220929-19-04
Percent Solids
TW-4
16.3
%
SM2540B-2011
09/29/2022
MD
220929-19-05
Fecal Coliforms
TW-5
32468
MPN/g
SM92210E-2006
09/29/2022
MD
220929-19-05
Percent Solids
TW-5
15.4
%
SM2540B-2011
09/29/2022
MD
220929-19-06
Fecal Coliforms
TW-6
45161
MPN/g
SM92210E-2006
09/29/2022
MD
220929-19-06
Percent Solids
TW-6
15.5
%
SM2540B-2011
09/29/2022
MD
220929-19-07
Fecal Coliforms
TW-7
20000
MPN/g
SM92210E-2006
09/29/2022
MD
220929-19-07
Percent Solids
TW-7
15.0
%
SM2540B-2011
09/29/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220929-19-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-19-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-19-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-19-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-19-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-19-06 Temp on Arrival: 3.0
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220929-19-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Cameron Testing Services, Inc. Laboratory Report
NC DENR#654
NC PHHS #37799
US EPA #NC01918
Client:
TRSIDenali Water
CTS Proj.
2212-0320
DW Cert # 37799
Project:
Tyson Wilkesboro
Regulatory
Yes
Sample Information
Samplod
D. Epting Date 12/27/22
Received
J.
Cameron pate.
; 12/27/22
Analyses and Results
Lab ID
CL
x E m
Sample iA a o Analyta
Result
rS =
m E
L
�, :'
m
Std. Methods
v
n
Reference
a
2212-0320
-01 31uclge Or FeC. Coliforrn-S
673000
CFUIg
673000
12/28/22 Pa
9222D - MF
-02
<72100
CFUIg
721000
-03
<62200
CFurg
622000
-04
594000
CFUIg
594000
-05
<66200
CFUIg
662000
-06
1320000
CFUIg
662000
-07
<631250
cruig
6310oo
Geomean
719000
2212-0320 01
-01 nudge Or TS (%)
6.00
%
0.01
12/28/22 PD
2540 G -TS
-02
5.60
%
0.01
-03
6.50
%
0.01
-04
6.80
%
0.01
-05
6.10
%
0.01
-06
6.10
%
0.01
-07
6.40
%
a.01
Report
Review n / (� J
Project Manager
Date
219 S. Steele Str.
Sanford NC 27330
919-208-4240
[e-mail] camerontesting.com

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5
Annual Pathogen & Vector Attraction Reduction Form for NCAC 2T Rules
(FORM PVRF 2T)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087
WWTP Name: AdvancePierre Foods - Claremont, NC
NPDES Number: N/A
Monitoring Period: From l/l/2022 To 12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
1 Alt B (Alk Treatment)[]
Alt. C (Prior Testing)[]
AIt.D (No Prior Test) ❑
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
1 Thermophilic ❑
Beta Ray 111
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
3683
3760
3795
MPN/g
0
1/YR
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087
WWTP Name: RVAF (Tyson) - Harmony, NC
Monitoring Period: From l/l/2022 To
NPDES Number: N/A
3/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
10989
35034
129214
MPN/g
0
1/Qtr
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) 0
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle: Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087
WWTP Name: RVAF (Tyson) - Harmony, NC
Monitoring Period: From 4/l/2022 To
NPDES Number: N/A
6/30/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
82437
138385
288889
MPN/g
0
1/Qtr
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087
WWTP Name: RVAF (Tyson) - Harmony, NC
Monitoring Period: From 7/l/2022 To
NPDES Number: N/A
9/30/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
22549
46833
106796
MPN/g
0
1/Qtr
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087
WWTP Name: RVAF (Tyson) - Harmony, NC
Monitoring Period: From 10/1/2022 To
NPDES Number: N/A
12/31 /2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
10101
16726
45181
MPN/g
0
1/Qtr
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087
WWTP Name: Mathis-1 (Storage Facility)
Monitoring Period: From l/l/2022 To
NPDES Number: N/A
12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
587
763
995
MPN/g
0
1/YR
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087
WWTP Name: Mathis-1 (Storage Facility)
Monitoring Period: From l/l/2022 To
NPDES Number: N/A
12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
1504
1540
1563
MPN/g
0
1/YR
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087
WWTP Name: Mathis-1 (Storage Facility)
Monitoring Period: From l/l/2022 To
NPDES Number: N/A
12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
1974
3300
8969
MPN/g
0
1/YR
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc. WQ Permit Number: WQ0038087
WWTP Name: Tyson - Wilkesboro, NC
Monitoring Period: From l/l/2022 To
NPDES Number: N/A
3/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
306
308
310
MPN/g
0
1/Qtr
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) 0
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc. WQ Permit Number: WQ0038087
WWTP Name: Tyson - Wilkesboro, NC
Monitoring Period: From 4/l/2022 To
NPDES Number: N/A
6/30/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
1482
1524
1546
MPN/g
0
1/Qtr
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc. WQ Permit Number: WQ0038087
WWTP Name: Tyson - Wilkesboro, NC
Monitoring Period: From 7/l/2022 To
NPDES Number: N/A
9/30/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Q
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
20000
31624
45161
MPN/g
0
1/Qtr
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc. WQ Permit Number: WQ0038087
WWTP Name: Tyson - Wilkesboro, NC
Monitoring Period: From 10/1/2022 To
NPDES Number: N/A
12/31 /2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)[]
Alt. C (Prior Testing)❑
AIt.D (No Prior Test)
I Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density 0
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
.... ..... .... .... .... .... ..... ....
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
na ytica
Tech -
ni ue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
62200
267843
1320000
CFU/ g
0
1/ tr
Q
Grab
9222D
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1AIt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) r❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
r❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Enviro. Manager
Preparer Name and Title (type or print)
2/28/2023
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

6
Soil Test Reports
(for fields applied in 2022)

Page 1 of 5
Report Number: 22-325-0804
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year.'4M
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Farms
Farm: Mathis
SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
Date Received: 11/21/2022 Date Of Analysis: 11/22/2022 Date Of Report: 11/22/2022
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/Appm
M3
Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
DM0601
25804
1.0
92
113 VH
57 L
97 H
527 M
13 VL
6.2
0.5
4.1
DM0602
25806
1.2
100
82 H
62 L
96 H
517 M
13 VL
5.9
6.86
0.7
4.3
DM0701
25807
1.0
90
122 VH
76 L
156 H
728 M
14 VL
6.5
0.4
5.6
DM0702
25808
0.9
83
147 VH
84 M
113 H
562 M
13 VL
6.1
0.6
4.6
RJ0203
25809
1.2
97
180 VH
105 M
123 H
636 M
12 VL
6.1
0.7
5.2
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample lD
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
DM0601
3.6
19.7
64.3
1.4
12.2
10
L
16.5
VH
30 H
4.3 VH
0.5 L
DM0602
3.7
18.6
60.1
1.3
16.3
13
L
10.1
VH
46 H
2.7 H
0.4 L
DM0701
3.5
23.2
65.0
1.1
7.1
21
M
15.3
VH
75 VH
5.3 VH
0.8 M
DM0702
4.7
20.5
61.1
1.2
13.0
15
L
13.6
VH
67 VH
5.8 VH
0.7 M
RJ0203
5.2
19.7
61.2
1.0
13.5
17
M
12.6
VH
67 VH
7.0 VH
0.7 M
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. q
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

Page 1 of 5
Report Number: 22-325-0803
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year. "rM
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Farms
Farm: Mathis
SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
Date Received: 11 /21 /2022 Date Of Analysis: 11 /22/2022 Date Of Report: 11 /22/2022
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
CH0301
25793
1.0
87
308 VH
79 L
177 H
1118 H
19 VL
6.7
0.3
7.7
CH0302
25795
1.0
85
183 VH
76 L
188 H
1037 M
25 VL
6.6
0.4
7.5
CH0303
25796
1.2
93
252 VH
90 M
217 H
1298 H
29 VL
6.8
0.3
9.0
CH0401
25797
0.7
72
103 VH
50 VL
146 H
752 H
35 L
7.0
0.0
5.3
CH0402
25798
0.8
76
122 VH
70 L
146 H
781 H
31 L
7.0
0.0
5.4
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample ID
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
CH0301
2.6
19.2
72.6
1.1
3.9
20
M
31.7
VH
31 H
12.4 VH
1.0 M
CH0302
2.6
20.9
69.1
1.4
5.3
21
M
22.1
VH
28 H
7.9 VH
1.2 M
CH0303
2.6
20.1
72.1
1.4
3.3
22
M
31.2
VH
43 H
10.5 VH
1.2 M
CH0401
2.4
23.0
70.9
2.9
0.0
41
VH
12.6
VH
27 H
4.4 VH
1.0 M
CH0402
3.3
22.5
72.3
2.5
0.0
29
H
13.4
VH
58 VH
6.4 VH
0.9 M
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. p
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

Page 4 of 5
Report Number: 22-325-0803
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year. "rM
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Farms
Farm: Mathis
SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
Date Received: 11 /21 /2022 Date Of Analysis: 11 /22/2022 Date Of Report: 11 /22/2022
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
YF01
25799
1.3
102
275 VH
51 VL
216 VH
910 M
20 VL
6.9
0.1
6.7
YF0302
25800
1.3
101
501 VH
66 L
239 H
1396 H
33 VL
7.0
0.0
9.3
YF0301
25801
1.3
102
487 VH
64 L
234 H
1216 H
27 VL
7.0
0.0
8.3
YF0401
25802
1.2
92
477 VH
49 VL
180 H
1296 H
22 VL
6.9
0.1
8.3
YF0402
25803
1.2
92
551 VH
54 VL
214 H
1477 H
24 VL
6.9
0.1
9.5
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample ID
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
YF01
2.0
26.9
67.9
1.3
1.5
12
L
18.8
VH
25 H
10.8 VH
0.8 M
YF0302
1.8
21.4
75.1
1.5
0.0
13
L
43.9
VH
30 H
17.9 VH
1.1 M
YF0301
2.0
23.5
73.3
1.4
0.0
16
M
40.4
VH
28 H
16.6 VH
1.0 M
YF0401
1.5
18.1
78.1
1.2
1.2
14
L
34.5
VH
26 H
19.9 VH
1.0 M
YF0402
1.5
18.8
77.7
1.1
1.1
14
L
40.6
VH
26 H
25.3 VH
1.1 M
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. p
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

Page 1 of 5
Report Number: 22-325-0802
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year. "rM
SOIL ANALYSIS REPORT
Date Received: 11 /21 /2022 Date Of Analysis: 11 /22/2022 Date Of Report: 11 /22/2022
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Farms
Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
YF0501
25782
1.4
103
337 VH
78 L
230 H
1503 H
28 VL
6.7
0.5
10.3
YF0503
25784
1.6
113
328 VH
84 L
219 H
1345 H
22 VL
6.7
0.4
9.3
YF0502
25785
1.5
113
282 VH
75 L
194 H
1115 H
22 VL
6.8
0.2
7.7
YF07
25786
1.3
103
193 VH
52 VL
140 H
878 H
22 VL
6.8
0.2
6.0
mRF03
25787
1.5
109
578 VH
84 L
219 H
1505 H
25 VL
6.4
0.9
10.6
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample ID
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
YF0501
1.9
18.6
73.0
1.2
4.9
19
M
20.9
VH
23 H
16.8 VH
1.3 H
YF0503
2.3
19.6
72.3
1.0
4.3
16
M
30.3
VH
54 VH
12.2 VH
1.0 M
YF0502
2.5
21.0
72.4
1.2
2.6
14
L
23.0
VH
47 H
10.7 VH
0.9 M
YF07
2.2
19.4
73.2
1.6
3.3
12
L
13.8
VH
32 H
6.8 VH
0.7 M
mRF03
2.0
17.2
71.0
1.0
8.5
21
M
33.3
VH
36 H
24.7 VH
1.1 M
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. p
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

Page 3 of 5
Report Number: 22-325-0802
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year. "rM
SOIL ANALYSIS REPORT
Date Received: 11 /21 /2022 Date Of Analysis: 11 /22/2022 Date Of Report: 11 /22/2022
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Farms
Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
mRF061
25788
1.6
111
845 VH
152 H
272 H
2O53 H
31 VL
6.9
0.2
13.3
mRF06 2
25789
2.0
132
640 VH
176 H
311 H
2173 H
36 VL
7.0
0.0
14.1
mRF051
25790
1.9
124
607 VH
186 VH
327 H
2O32 H
36 VL
6.9
0.2
13.7
mRF05 2
25791
1.7
115
587 VH
161 H
315 H
2O03 H
38 VL
7.0
0.0
13.2
mF15
25792
1.6
119
74 H
61 L
176 H
823 M
32 L
6.4
0.6
6.5
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample ID
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
mRF061
2.9
17.0
77.2
1.0
1.5
25
M
44.7
VH
29 H
27.2 VH
1.3 H
mRF06 2
3.2
18.4
77.1
1.1
0.0
32
H
42.5
VH
33 H
25.3 VH
1.4 H
mRF051
3.5
19.9
74.2
1.1
1.5
29
H
37.9
VH
37 H
24.3 VH
1.2 M
mRF05 2
3.1
19.9
75.9
1.3
0.0
30
H
31.9
VH
30 H
22.4 VH
1.3 H
mF15
2.4
22.6
63.3
2.1
9.2
39
VH
10.4
VH
9 L
4.7 VH
1.1 M
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. p
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

Page 1 of 6
Report Number: 22-325-0801
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year. "rM
SOIL ANALYSIS REPORT
Date Received: 11 /21 /2022 Date Of Analysis: 11 /22/2022 Date Of Report: 11 /22/2022
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Famrs
Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
mRF121
25771
1.8
116
562 VH
154 H
363 H
2O30 H
36 VL
6.9
0.2
13.9
mRF12 2
25773
1.7
120
353 VH
72 L
206 H
1177 H
25 VL
6.6
0.5
8.4
mRF201
25774
1.7
122
144 VH
99 M
205 H
1209 H
32 VL
6.7
0.4
8.5
mRF20 2
25775
1.5
112
101 VH
97 M
206 H
1170 M
31 VL
6.7
0.4
8.4
mRF20 3
25776
1.6
116
96 H
62 L
188 H
1163 H
30 VL
6.6
0.5
8.2
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample ID
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
mRF121
2.8
21.8
73.0
1.1
1.4
35
H
41.0
VH
35 H
22.0 VH
1.4 H
mRF12 2
2.2
20.4
70.1
1.3
6.0
21
M
19.1
VH
34 H
13.7 VH
0.9 M
mRF201
3.0
20.1
71.1
1.6
4.7
31
H
14.1
VH
59 VH
11.2 VH
1.3 H
mRF20 2
3.0
20.4
69.6
1.6
4.8
29
H
10.5
VH
57 VH
9.0 VH
1.3 H
mRF20 3
1.9
19.1
70.9
1.6
6.1
27
H
9.6
VH
37 H
7.4 VH
1.1 M
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. p
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

Page 4 of 6
Report Number: 22-325-0801
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year. "rM
SOIL ANALYSIS REPORT
Date Received: 11 /21 /2022 Date Of Analysis: 11 /22/2022 Date Of Report: 11 /22/2022
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Famrs
Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
mRF211
25777
2.6
150
266 VH
148 H
244 H
1890 H
31 VL
6.7
0.6
12.6
mRF212
25778
1.9
131
149 VH
83 L
192 H
1109 M
33 VL
6.6
0.5
8.0
mRF23 01
25779
2.0
141
244 VH
99 M
199 H
789 M
30 VL
5.8
6.79
1.4
7.4
mRF23 02
25780
2.0
136
133 VH
76 L
214 H
1045 M
34 VL
6.1
1.2
8.6
mRF23 03
25781
2.0
136
164 VH
82 L
214 H
1094 M
31 VL
6.4
0.7
8.3
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample ID
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
mRF211
3.0
16.1
75.0
1.1
4.8
23
M
24.8
VH
44 H
19.3 VH
1.6 H
mRF212
2.7
20.0
69.3
1.8
6.3
35
H
13.9
VH
72 VH
11.2 VH
1.3 H
mRF23 01
3.4
22.4
53.3
1.8
18.9
33
H
17.3
VH
11 M
8.7 VH
0.9 M
mRF23 02
2.3
20.7
60.8
1.7
14.0
52
VH
18.0
VH
12 M
5.6 VH
0.9 M
mRF23 03
2.5
21.5
65.9
1.6
8.4
25
M
19.6
VH
11 M
6.7 VH
0.9 M
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. p
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

Page 1 of 4
Report Number: 22-325-0800
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year. "rM
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Farms
Farm: mathis
SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
Date Received: 11 /21 /2022 Date Of Analysis: 11 /22/2022 Date Of Report: 11 /22/2022
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
mF0901
25760
2.0
133
680 VH
77 L
285 H
1315 M
24 VL
6.3
1.1
10.4
mF0902
25762
1.7
121
531 VH
56 L
228 H
1180 M
20 VL
6.3
0.9
8.9
mF1001
25763
1.8
127
324 VH
41 VL
204 H
1020 M
27 VL
6.4
0.7
7.7
mF1002
25764
2.0
136
555 VH
61 L
176 H
1096 M
26 VL
6.2
1.0
8.2
mF1101
25765
1.7
121
480 VH
69 L
181 H
1100 M
23 VL
6.4
0.7
8.0
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample ID
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
mF0901
1.9
22.8
63.2
1.0
10.6
27
H
43.4
VH
19 M
25.0 VH
1.2 M
mF0902
1.6
21.3
66.3
1.0
10.1
20
M
31.5
VH
21 H
19.4 VH
1.0 M
mF1001
1.4
22.1
66.2
1.5
9.1
24
M
20.9
VH
18 M
15.4 VH
0.8 M
mF1002
1.9
17.9
66.8
1.4
12.2
21
M
26.1
VH
18 M
18.9 VH
1.1 M
mF1101
2.2
18.9
68.8
1.3
8.8
19
M
23.1
VH
19 M
19.8 VH
1.1 M
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. p
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

Page 3 of 4
Report Number: 22-325-0800
Account Number: 08494
Send To: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
WaypointT.0
ANALYTICAL
"Every acre... Every year. "rM
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: ASJ Mathis Farms
Farm: mathis
SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
Date Received: 11 /21 /2022 Date Of Analysis: 11 /22/2022 Date Of Report: 11 /22/2022
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
Sample ID
Field ID
Lab
Number
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm
Rate
ppm
Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
mF1102
25766
1.8
128
469 VH
54 VL
191 H
1161 M
27 VL
6.4
0.7
8.4
mF1301
25767
2.6
150
427 VH
127 H
205 H
1221 M
27 VL
6.0
6.78
1.5
9.8
mF1302
25768
2.5
150
936 VH
244 VH
202 M
2071 H
47 VL
6.5
1.0
13.9
mF1401
25769
2.1
137
852 VH
198 VH
224 M
1926 H
41 VL
6.4
1.2
13.4
mF1402
25770
1.7
117
678 VH
133 M
221 H
1711 H
35 VL
6.6
0.7
11.6
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
Sample ID
Field ID
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm
Rate
Zn
ppm
Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
mF1102
1.6
18.9
69.1
1.4
8.3
21
M
23.0
VH
19 M
19.3 VH
1.3 H
mF1301
3.3
17.4
62.3
1.2
15.3
24
M
35.8
VH
18 M
17.1 VH
0.8 M
mF1302
4.5
12.1
74.5
1.5
7.2
21
M
58.9
VH
18 M
32.9 VH
1.5 H
mF1401
3.8
13.9
71.9
1.3
9.0
22
M
58.7
VH
17 M
35.7 VH
1.4 H
mF1402
2.9
15.9
73.8
1.3
6.0
14
L
49.4
VH
19 M
36.4 VH
1.3 H
Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a
soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. p
H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by 1awi� lit G/owu/
C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Virginia, Inc. a
Pauric Mc Groary Ph.D., CPAg

7
COMPLIMENTARY DATA:
Executive Summary
Storage Activity Summary
Fecal Analysis Summary
Poultry Litter Analysis Summary
Poultry Litter Analyses

Executive Summary
Annual Report - 2022
Permit No. WQ0038087
Permittee: Terra Renewal Services, Inc
Dry Tons ADDlied Der Source
TERRA
renewal
Feld ID
Permitted
Acres
Utilized
Acres
Application
Period
(Months)
Crop
PAN RATE
2022
(lb/ac)
PAN Applied
Residuals
(lb/ac)
PAN Applied
Supplement*
(lb/ac)
Total PAN
Applied
(lb/ac)
AdvPierre
Claremont
(DT/Field)
RVAF
Harmony
(DT/Field)
Tyson
Wilkesboro
(DT/Field)
Mathis-1
Storage
(DT/Field)
Annual Dry
Tons Applied
(DT/Field)
NC-WK-MF-14
23.4
23.4
Dec -Jan
Sep -Oct
Corn Silage
Sm Grains
134
50
127
127
42
0.0
31.7
47.2
0.0
78.9
NC-WK-MRF-06
21.0
21.0
Jan
Corn Silage
159
50
102
20.4
122
47
0.0
14.3
28.8
29.3
72.4
NC-WK-MRF-03
18.9
18.9
Jan
Nov
Corn Silage
Sm Grains
125
1 50
107
10.2
117
1 49
0.0
13.3
27.5
27.3
68.1
NC-WK-MRF-05
25.3
25.3
Jan -Feb
Nov
Corn Silage
Sm Grains
167
50
156
10.2
166
47
1.7
26.6
52.5
35.1
115.9
NC-WK-MRF-12
26.5
26.5
Feb
Nov
Corn Silage
Sm Grains
168
50
124
10.2
134
45
1.8
19.0
33.8
45.8
100.4
NC-WK-CH-3
41.6
41.6
Mar
Nov
Corn Silage
Sm Grains
220
187
10.2
197
0.0
48.5
63.8
34.0
146.3
NC-WK-CH-4
35.8
35.8
Mar -Apr
Corn Silage
206
161
10.2
171
1.8
24.0
60.1
7.3
93.2
NC-WK-DM-6
25.6
25.6
Apr -May
Nov
Corn Silage
Sm Grains
205
50
183
10.2
193
40
1.7
29.8
54.2
0.0
85.7
NC-YK-WK-YF-05
51.5
51.5
May -Jul
Oct -Nov
Corn Silage
Sm Grains
153
50
151
151
33
1.8
40.5
108.6
0.0
150.9
NC-YK-YF-04
23.3
23.3
Jul -Aug
Oct
Corn Silage
Sm Grains
211
50
137
137
26
1.8
29.2
65.3
0.0
96.3
NC-WK-MF-23
59.2
59.2
Aug
Sm Grains
95
23
23
0.0
10.5
23.0
0.0
33.5
NC-WK-MF-15
13.8
13.8
Aug -Sep
Sm Grains
80
57
57
0.0
7.7
9.9
0.0
17.6
NC-WK-MF-10
19.6
19.6
Sep
Sm Grains
95
22
22
0.0
5.0
4.1
0.0
9.1
NC-WK-MF-11
22.5
22.5
Sep
Sm Grains
80
29
29
1.7
5.5
9.5
0.0
16.7
NC-WK-MF-13
33.8
33.8
Sep
Sm Grains
95
31
31
0.0
10.4
12.6
0.0
23.0
NC-WK-YF-07
10.3
10.3
Oct
Sm Grains
95
30
30
1.7
2.8
4.1
0.0
8.5
NC-YK-YF-03
22.3
22.3
Oct
Sm Grains
120
32
32
0.0
7.2
8.6
0.0
15.8
NC-YK-YF-01
13.5
13.5
Nov
Sm Grains
98
39
39
0.0
4.9
4.9
0.0
9.8
NC-YK-DM-07
32.6
32.6
Dec
Sm Grains
120
47
47
0.0
11.9
17.3
0.0
29.2
TOTALS: 521 14 343 636 179 1,171

Summary of Storage Activity in Mathis-1 Storage Tanks far Calendar Year 2022
Loads In
Volume In
Dry Volume In
Loads Out
Volume Out
Dry Volume Out
Week
Ending
Wilkesboro Harmony
(# x 6,000 gal) (# x 6,000 gal)
Wilkesboro Harmony
(gallons) (gallons)
Wilkesboro Harmony
(Dry Tons) (Dry Tons)
Mathis-1
(# x 6,000 gal)
Mathis-1
(gallons)
Mathis-1
(Dry Tons)
1/7/2022
10 5
60,000 30,000
7.5 3.0
0
0
0.0
1/14/2022
0 0
0 0
0.0 0.0
0
0
0.0
1/21/2022
0 1
0 6,000
0.0 0.6
0
0
0.0
1/28/2022
1 3
6,000 18,000
0.8 1.8
0
0
0.0
2/4/2022
5 7
30,000 42,000
3.8 4.2
0
0
0.0
2/11/2022
10 9
60,000 54,000
7.5 5.4
0
0
0.0
2/18/2022
0 0
0 0
0.0 0.0
5
30,000
5.8
2/25/2022
12 8
72,000 48,000
9.0 4.8
0
0
0.0
3/4/2022
4 4
24,000 24,000
3.0 2.4
0
0
0.0
3/11/2022
3 3
18,000 18,000
2.3 1.8
16
96,000
18.4
3/18/2022
9 6
54,000 36,000
6.8 3.6
0
0
0.0
3/25/2022
6 4
36,000 24,000
4.5 2.4
4
18,000
3.5
4/1/2022
3 0
18,000 0
2.3 0.0
0
6,000
1.2
4/8/2022
2 0
12,000 0
1.5 0.0
0
0
0.0
4/15/2022
0 0
0 0
0.0 0.0
0
0
0.0
4/22/2022
5 0
30,000 0
3.8 0.0
0
0
0.0
4/29/2022
0 0
0 0
0.0 0.0
0
0
0.0
5/6/2022
0 3
0 18,000
0.0 1.8
0
0
0.0
5/13/2022
1 1
6,000 6,000
0.8 0.6
0
0
0.0
5/20/2022
0 0
0 0
0.0 0.0
0
0
0.0
5/27/2022
5 15
30,000 90,000
3.8 9.0
0
0
0.0
6/3/2022
0 5
0 30,000
0.0 3.0
0
0
0.0
6/10/2022
0 0
0 0
0.0 0.0
0
0
0.0
6/17/2022
0 0
0 0
0.0 0.0
0
0
0.0
6/24/2022
0 0
0 0
0.0 0.0
0
0
0.0
7/1/2022
0 0
0 0
0.0 0.0
0
0
0.0
7/8/2022
2 1
12,000 6,000
1.5 0.6
0
0
0.0
7/15/2022
1 6
6,000 36,000
0.8 3.6
0
0
0.0
7/22/2022
0 0
0 0
0.0 0.0
0
0
0.0
7/29/2022
0 0
0 0
0.0 0.0
0
0
0.0
8/5/2022
1 1
6,000 6,000
0.8 0.6
0
0
0.0
8/12/2022
2 1
12,000 6,000
1.5 0.6
0
0
0.0
8/19/2022
3 1
18,000 6,000
2.3 0.6
0
0
0.0
8/26/2022
0 0
0 0
0.0 0.0
0
0
0.0
9/2/2022
2 2
12,000 12,000
1.5 1.2
0
0
0.0
9/9/2022
3 2
18,000 12,000
2.3 1.2
0
0
0.0
9/16/2022
3 4
18,000 24,000
2.3 2.4
0
0
0.0
9/23/2022
0 0
0 0
0.0 0.0
0
0
0.0
9/30/2022
0 0
0 0
0.0 0.0
0
0
0.0
10/7/2022
3 1
18,000 6,000
2.3 0.6
0
0
0.0
10/14/2022
3 0
18,000 0
2.3 0.0
0
0
0.0
10/21/2022
1 1
6,000 6,000
0.8 0.6
0
0
0.0
10/28/2022
0 0
0 0
0.0 0.0
0
0
0.0
11/4/2022
4 3
24,000 18,000
3.0 1.8
0
0
0.0
11/11/2022
5 6
30,000 36,000
3.8 3.6
0
0
0.0
11/18/2022
19 13
114,000 78,000
14.3 7.8
0
0
0.0
11/25/2022
0 0
0 0
0.0 0.0
130
780,000
149.6
12/2/2022
5 3
30,000 18,000
3.8 1.8
0
0
0.0
12/9/2022
13 11
78,000 66,000
9.8 6.6
0
0
0.0
12/16/2022
11 5
66,000 30,000
8.3 3.0
0
0
0.0
12/23/2022
3 7
18,000 42,000
2.3 4.2
0
0
0.0
12/30/2022
6 3
36,000 18,000
4.5 1.8
0
0
0.0
TOTALS: 166 145 996,000 870,000 125 87 155 930,000 178

Fecal Analysis Summary - 2022
Permit No: WQ0038087
Permittee: Terra Renewal Services, Inc
TERRA
renewal
Facility: AdvancePierre Foods -Claremont
Result (MPN/gram)
Sample Date 1 2 3 4 5 6 7 Geo Mean
3/22/2022 3,795 3,781 3,766 3,774 3,738 3,781 3,683 3,760
Facility: RVAF
(Tyson) - Harmony
Result (MPN/gram)
Sample Date
1
2
3
4
5
6
7
Geo Mean
3/31/2022
42,328
10,989
42,781
11,173
129,214
32,258
69,893
35,034
6/16/2022
106,762
106,762
82,437
180,505
288,889
109,890
180,505
138,385
9/29/2022
75,472
81,136
22,549
106,796
29,126
28,302
40,650
46,833
12/27/2022
13,514
10,101
14,177
15,550
14,461
18,625
45,181
16,726
Sample Date
1
2
2/3/2022
310
308
6/28/2022
1,520
1,563
9/29/2022
33,333
33,333
12/27/2022
673,000
72,100
Result (MPN or CFU/gram)
3
4
5
6
7
Geo Mean
307
310
306
307
309
308
1,546
1,539
1,482
1,539
1,482
1,524
31,650
30,675
32,468
45,161
20,000
31,624
62,200
594,000
66,200
1,320,000
631,250
267,843
Facility: Mathis-1 (Storage)
Result (MPN/gram)
Sample Date
1
2
3 4 5
6
7
Geo Mean
2/3/2022
587
810
633 995 687
800
913
763
6/28/2022
1,504
1,550
1,538 1,527 1,550
1,563
1,550
1,540
10/12/2021
2,212
2,336
1,974 4,292 2,328
4,667
8,969
3,300

Poultry Litter Analysis Summary - 2022
Source: ASJ Mathis Farms
Sample ID
Total N
(ppm)
Dry Matter
N
PAN
(lb/ton)
MF-1
19,200
66.5
12.8
MF-2
23,800
73.5
17.5
M F-3
24,100
66.8
16.1
MF-4
26,700
65.2
17.4
MF-5
21,500
56.9
12.2
MF-6
30,600
82.2
25.2
MF-7
13,400
40.6
5.4
MF-8
6,930
43.7
3.0
MF-9
16,400
52.6
8.6
MF-10
11,400
41.5
4.7
MF-11
18,800
45.4
8.5
MF-12
7,780
30.8
2.4
Average: 18,384 55.5 10.2
lb/ton = ((%DM/100)*2000 lb/ton) * (Total N ppm/1,000,000) * (MR)
MR = Mineralization Rate = 50% (expressed as decimal: 0.5)

NCDA&CS Agronomic Division
Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
4�Predictive
Client: Luke Mathis
Advisor:
'
ASJ Mathis Farms, LLC
615 Mathis Farm Rd
w A Waste
Report Roaring River, NC 28669
Wilkes County
you„EDkal'" Links to Helpful
Information Sampled: Not Provided
Received: 03/02/2022
Farm: Not Provided
Completed: 03/16/2022 PALS #: 801
PALS #:
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF1
Nitrogen (N) P K Ca Mg S Fe Mn Zn
Cu
B Mo
C Al Na Cl
Code: HLB
Total N: 19200 8150 26200 11000 3720 6000 920 376 281
282
41.4 -
- 892 8350 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD CCE
ALE
C:N
DM
Farm Silo
(10 S/cm) (MS/cm) (Unitless) (lb/yd3) (%)
(tons)
(Unitless)
(%)
- - - - -
-
-
66.5
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe Mn Zn
Cu
B Mo
Al Na Cl
Broadcast
19.2 24.8 41.8 14.6 4.95 7.98 1.23 0.50 0.37
0.38
0.06 -
1.19 11.1
Soil Incorporated
23.0 24.8 41.8 14.6 4.95 7.98 1.23 0.50 0.37
0.38
0.06 -
1.19 11.1 -
North Carolina
f 'a
x
=l
{
Tobacco Trust Fund Commission
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture.

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 2 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF2
Nitrogen (N) P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code: HLB
Total N: 23800 111400 26500 39900 18000 10200 6450
463 845
378
44.7
-
- 4130 6960 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N SS EC pH BD
CCE
ALE
C:N
DM
Sparks place
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
73.5
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
23.8 38.4 46.8 58.6 26.5 15.0 9.48
0.68 1.24
0.56
0.07
-
6.07 10.2 -
Soillncorporated
28.6 38.4 46.8 58.6 26.5 15.0 9.48
0.68 1.24
0.56
0.07
-
6.07 10.2 -

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 3 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF3
Nitrogen (N) P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code: HLB
Total N: 24100 14500 38600 19900 6880 11100 3750
509 436
449
56.0
-
- 4230 9980 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N SS EC pH BD
CCE
ALE
C:N
DM
River shed
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
66.8
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
24.1 44.5 61.8 26.6 9.19 14.8 5.00
0.68 0.58
0.60
0.08
-
5.65 13.3 -
Soillncorporated
28.9 44.5 61.8 26.6 9.19 14.8 5.00
0.68 0.58
0.60
0.08
-
5.65 13.3 -

NCDA&CS Agronomic Division Phone:
[phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 4 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF4
Nitrogen (N)
P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na Cl
Code: HLB
Total N: 26700
18100 38100 25100 8820 14400 8880
772 537
582
61.9
-
- 10300 11200 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD
CCE
ALE
C:N
DM
Chatham Road
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
65.2
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na Cl
Broadcast
26.7 54.1 59.6 32.7 11.5 18.8 11.6
1.01 0.70
0.76
0.08
-
13.4 14.6 -
Soillncorporated
32.0 54.1 59.6 32.7 11.5 18.8 11.6
1.01 0.70
0.76
0.08
-
13.4 14.6 -

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 5 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF5
Nitrogen (N) P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code: HLB
Total N: 21500 114000 47100 14800 7730 8230 5440
851 530
418
68.4
-
- 8430 6460 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N SS EC pH BD
CCE
ALE
C:N
DM
Jonesville Farm
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
56.9
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
21.5 36.5 64.3 16.9 8.80 9.37 6.20
0.97 0.60
0.48
0.08
-
9.60 7.36 -
Soillncorporated
25.9 36.5 64.3 16.9 8.80 9.37 6.20
0.97 0.60
0.48
0.08
-
9.60 7.36 -

NCDA&CS Agronomic Division Phone:
[phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 6 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF6
Nitrogen (N)
P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code: HLB
Total N: 30600
10400 30400 16100 5070 9370 3040
372 355
345
46.7
-
- 2870 8710 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD
CCE
ALE
C:N
DM
YADKIN FARM
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
82.2
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
30.6 39.3 60.1 26.4 8.34 15.4 5.00
0.61 0.58
0.57
0.08
-
4.73 14.3 -
Soillncorporated
36.7 39.3 60.1 26.4 8.34 15.4 5.00
0.61 0.58
0.57
0.08
-
4.73 14.3 -

NCDA&CS Agronomic Division Phone:
[phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 7 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF7
Nitrogen (N)
P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code:HLB
Total N:13400
19100 13700 36200 16600 3980 16500
1120 811
419
35.1
-
- 21100 1950 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD
CCE
ALE
C:N
DM
ASHLEY SCLAR
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
40.6
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
13.4 35.5 13.3 29.4 13.5 3.24 13.4
0.91 0.66
0.34
0.03
-
17.2 1.58 -
Soillncorporated
16.1 35.5 13.3 29.4 13.5 3.24 13.4
0.91 0.66
0.34
0.03
-
17.2 1.58 -

NCDA&CS Agronomic Division Phone:
[phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 8 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF8
Nitrogen (N)
P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na Cl
Code: HLB
Total N: 6930
3970 5830 14900 2820 1530 2130
802 319
142
24.8
-
- 2770 4650 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD
CCE
ALE
C:N
DM
CASS 21
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
43.7
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na Cl
Broadcast
6.93 7.95 6.11 13.0 2.46 1.33 1.86
0.70 0.28
0.12
0.02
-
2.42 4.06 -
Soillncorporated
8.32 7.95 6.11 13.0 2.46 1.33 1.86
0.70 0.28
0.12
0.02
-
2.42 4.06 -

NCDA&CS Agronomic Division Phone:
[phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 9 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF9
Nitrogen (N)
P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code:HLB
Total N:16400
22200 17200 31700 10500 4880 12300
755 564
504
41.1
-
- 11300 3790 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD
CCE
ALE
C:N
DM
MONEY RD
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
52.6
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
16.4 53.4 21.7 33.4 11.0 5.14 12.9
0.80 0.59
0.53
0.04
-
11.9 3.99 -
Soillncorporated
19.6 53.4 21.7 33.4 11.0 5.14 12.9
0.80 0.59
0.53
0.04
-
11.9 3.99 -

NCDA&CS Agronomic Division Phone:
[phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 10 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF10
Nitrogen (N)
P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code:HLB
Total N:11400
114100 21000 19000 7420 5800 4680
555 463
419
39.9
-
- 5040 4850 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD
CCE
ALE
C:N
DM
Bethel Bottom
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
41.5
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
11.4 26.8 20.9 15.8 6.16 4.81 3.88
0.46 0.38
0.35
0.03
-
4.18 4.02 -
Soillncorporated
13.7 26.8 20.9 15.8 6.16 4.81 3.88
0.46 0.38
0.35
0.03
-
4.18 4.02 -

NCDA&CS Agronomic Division Phone:
[phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 11 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF11
Nitrogen (N)
P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code:HLB
Total N:18800
21200 37200 21400 11600 6940 7730
1230 604
450
65.3
-
- 6280 3650 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD
CCE
ALE
C:N
DM
Jenkins NW
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
45.4
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
18.8 44.1 40.6 19.5 10.5 6.30 7.02
1.11 0.55
0.41
0.06
-
5.70 3.32 -
Soillncorporated
22.5 44.1 40.6 19.5 10.5 6.30 7.02
1.11 0.55
0.41
0.06
-
5.70 3.32 -

NCDA&CS Agronomic Division Phone:
[phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-WO04639
Luke Mathis
Sampled: Not Provided I Received: 03/02/2022 1
Completed: 03/16/2022
Page 12 of 13
Sample Information
Nutrient Measurements are given in units of parts per million (ppm), unless otherwise specified.
Other Results
ID: MF12
Nitrogen (N)
P K Ca Mg S Fe
Mn Zn
Cu
B
Mo
C Al Na CI
Code: HLB
Total N: 7780
9460 6990 16700 4540 2290 1640
424 291
275
24.8
-
- 1760 1100 -
Description: Poultry
Inorganic:
Broiler House
NH4-N
Grower Comments:
NO3-N
SS EC pH BD
CCE
ALE
C:N
DM
Berry's Lane
(10 S/cm) (MS/CM) (Unitless) (lb/yd3)
(%)
(tons)
(Unitless)
(%)
- - - -
-
-
-
30.8
Estimate of Nutrients Available for First Year (lb/ton)
Other Results (lb/ton)
Application Method:
N P205 K20 Ca Mg S Fe
Mn Zn
Cu
B
Mo
Al Na CI
Broadcast
7.78 13.3 5.16 10.3 2.79 1.41 1.01
0.26 0.18
0.17
0.02
-
1.08 0.68 -
Soillncorporated
9.34 13.3 5.16 10.3 2.79 1.41 1.01
0.26 0.18
0.17
0.02
-
1.08 0.68 -

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY22-W004639
Luke Mathis Sampled: Not Provided I Received: 03/02/2022 1 Completed: 03/16/2022 Page 13 of 13
Understanding the Waste Report
Nutrient concentrations and other data on this report are provided so that waste materials can be applied at agronomic rates, thereby supplementing or reducing fertilizer
application and preventing environmental contamination. In reading the Laboratory Results section, remember that materials with < 15% dry matter (generally liquids) are
analyzed as received; all other wastes are dried first. Values in the Estimate of Nutrients Available for First Crop section are based on the type of waste and method of
application you specify and reflects the fact that only 40-60% of the nitrogen becomes available within one year of application. The remainder may ormay not ever become
available.
ALE is Agricultural Lime Equivalence. The ALE
DM% is percent Dry Matter [for semi -solid and
Al = Aluminum
Cu = Copper
NH4-N = Ammonium -N
indicates the amount of the waste material that
solid waste, this value facilitates conversion of
As = Arsenic
Fe = Iron
Ni = Nickel
provides a limiting effect equivalent to one ton of
dry -basis concentrations (ppm) back to
B = Boron
K = Potassium
NO3-N = Nitrate -N
agricultural grade limestone.
wet -basis of original sample].
Ca = Calcium
Mg = Magnesium
P = Phosphorus
BD is Bulk Density in Ib/yd3.
EC (Electrical Conductivity) measures
Cd = Cadmium
Mn = Manganese
Pb = Lead
CCE is Calcium Carbonate Equivalence and is
salinity, or soluble salts (SS).
Cl = Chloride
Mo = Molybdenum
S = Sulfur
used to determine ALE.
pH measures basicity/acidity.
Cr = Chromium
N = Nitrogen
Se = Selenium
C:N ratio is the Carbon:Nitrogen ratio.
Na = Sodium
meq/L = milliequivalent per liter; mS = millisiemens; ppm = parts per million or mg/L; S = siemens; T = trace (<0.005 lb/unit)
Additional information: www.ncagr.gov/agronomi/pdffiles/uwaste.pdf & www.ncagr.qov/agronomi/pdffiles/wasteguide.pdf