WQ0003504_2022 Residual Annual Report_20230228 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0003504
Applicant/Permittee City of Durham
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Raleigh
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Brent Collins
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
336-399-3646
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0003504
Has Current Existing permit number
Applicant/Permittee Address*
101 City Hall Plaza, Durham NC 27701
Facility Name*
City of Durham Class B Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Durham Annual Report - WQ0003504.pdf 13.04MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/28/2023

City of Durham
2022 Annual Report
Residuals Land Application
Permit No. WQ0003 504
Prepared By:
EMA Resources, Inc.
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

February 15, 2023
DENR/Water Quality Section
Non -Discharge Compliance Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2022 Annual Report — City of Durham
Treatment and Land Application of Residuals
Permit No. WQ0003504
Dear Sir or Madam:
Enclosed is one copy of the 2022 Annual Report for the above referenced land
application permit.
During 2022 EMA Resources, Inc. land applied 3273.64 dry tons of wastewater residuals
to 786.7 acres of private farmland. There were 529.56 dry tons of residuals from the
Brown WTP land applied under this permit. The Brown WTP was added as a source to
EMA Resource's land application permit and the remaining residuals were land applied
under that permit once it was approved. There was no land application from the North
Durham WRF. Please contact Brent Collins - Director of Technical Services if you have
any further questions regarding this report.
Sincerely,
Brent Collins
Director of Technical Services
brent.collins2emaresourcesinc.com
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0003504 County: Durham Year:
2022
Facility Name (as shown on permit):
Land Application Operator:
City of Durham
EMA Resources Inc. Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
0 Yes ❑ No - If No, slip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Aanlication Summary:
Total number of application fields in thepermit:
139
Total number of fields utilized for land application during the year:
37
Total amount of dry tons applied during the year for all application sites:
F 3273.64
Total number of acres utilizes. for land application during the year:
1 786.7
Part B - Annual Comaiance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Quality, 0 Yes ❑ No
tf no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
Iimit specified in the pen -nit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached..
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading
Rates in 15A NCAC 02T .I 105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .l I 1 l were complied with (applicable to 40 CFR Part 503
regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified
in the pen -nit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the pen -nit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the possibility
of fines and imprisonment for knowing violations."
Don Greeley - Water Management Director-
Permittee Name and Title (type or print) Signature of Permittee Date
;2�f—e 1/2/2023
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WQ0003504
City of Durham
03-32-010(A)
WWTP Name: Brown Water Treatment Plant
Residual Analysis Data
Laboratory
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
(mg/kg)
Conc.
Limit
(m k )o
Sample or Composite Date
113122
5/11/22
7/8/22
10/3/22
Percent Solids
NA
21.9
21.1
18.8
21.5
Arsenic
75
16.1
1.26
5.31
38.1
Cadmium
85
0.913
5.21
19.5
0.67
Copper
4,300
363
573
1620
2610
Chromium
NA
10.8
13.6
12
12.7
Lead
840
11.5
132
14.2
16.2
Mercury
57
0.0316
0.0502
0.0369
0.0698
Molybdenum
75
6.16
3.1
4.31
4.36
Nickel
420
29.2
58.8
56.4
107
Selenium
100
14.6
30.3
17
7.44
Zinc
7,500
37
67.3
64.9
169
Total Phosphorus
NA
991
986
830
814
TKN
NA
10300
8290
9890
7400
Ammonia -Nitrogen
NA
280
1000
1150
411
Nitrate and Nitrite
NA
30.9
338
34
20.9
J For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
9 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
-7-/2yl)-y
Signature of Preparer *
*Preparer is defined in 40 C:FR fart 503.9(r) and 15A NCAC 2T .1 102 (26)
Date

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0003504
Facility Name: City of Durham
Residual Source 03-32-010(A)
NPDES # or WQ#:
WWTP Name: Brown Water Treatment Plant
Residual Analvsis Data
Laboratory: 1) Waypoint Analytical
2)
3)
4)
5)
Sample or Composite Date
Parameter
(mg/kg)
I/3/22
5/11/22
718122
1013/22
Alununum
3670
10900
7870
4160
Calcium
t770
1170
1090
1500
Magnesium
193
332
309
221
pH
5
5.1
5.1
4.9
Potassium
282
265
212
144
Sodium
594
402
379
302
PAN
4179
3754
4105
3022
SAR
1.67
1.22
1.13
0.89
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Si�ature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date

Waypointo
ANALYTICAL
1 /12/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-004-0031
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 1/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2022
Arkansas
State Program
88-0650
02/07/2022
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-004-0031
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-004-0031
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97025 Brown W FP Solids 01/03/2022 12:40 01/04/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-004-0031
Date: 1 /11 /2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 97025 (Brown WTP)
QC Batch No: 1-593850/1-593519
This sample was analyzed at a dilution due to IEC interference/matrix interference.
Analyte: Aluminum
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97328
Analyte: Arsenic
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 97328
Analyte: Calcium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97328
Analyte: Chromium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97328
Analyte: Iron
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Potassium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97328
Analyte: Manganese
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 97025 (Brown WTP)
Analyte: Lead
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Analyte: Mercury
QC Batch No: 1-593529/1-593334
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number : 22-004-0031
Lab No : 97025
Sample ID: Brown WTP
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
REPORT OFANALYSIS
Report Date : 01/12/2022
Received : 01/04/2022
Danyale Love
Project Manager
Matrix: Solids
Sampled: 1/3/2022 12:40
Test
Results
Units
MDL
MQL
DF
Date / Time
Analyzed
By
Analytical
Method
Moisture
78.1
%
0.010
1
01/04/22 16:05
FMM
SW-DRYWT
Ammonia Nitrogen
2803
mg/Kg -
dry
73.1
457
1
01/11/22 13:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
30.9
mg/Kg -
dry
22.7
22.7
1
01/10/22 15:17
ZBD
4500NO3F-2011
Organic N
99953
mg/Kg -
dry
758.0
1
01/11/22 13:30
CALCULATION
pH
5.0
S.U.
1
01/06/2215:16
DRS
9045D
Total Solids
21.9
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Volatile Solids
31.4
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Kjeldahl Nitrogen
10300
mg/Kg -
dry
758
1
01/11/22 14:54
CLP
4500NORGD-2011
Phosphorus
991
mg/Kg -
dry
126
228
10
01/11/22 13:38
EAL
6010D
Aluminum
3670
mg/Kg -
dry
211
228
10
01/11/22 13:38
EAL
6010D
Arsenic
16.13
mg/Kg -
dry
11.0
22.8
10
01/11/22 13:38
EAL
6010D
Cadmium
<0.913
mg/Kg -
dry
0.913
4.57
10
01/11/22 13:38
EAL
6010D
Calcium
<1770
mg/Kg -
dry
1770
2280
10
01/11/22 13:38
EAL
6010D
Chromium
<10.8
mg/Kg -
dry
10.8
11.4
10
01/11/22 13:38
EAL
6010D
Copper
363
mg/Kg -
dry
14.2
22.8
10
01/11/22 13:38
EAL
6010D
Iron
408000
mg/Kg -
dry
389
457
10
01/11/22 13:38
EAL
6010D
Lead
11.53
mg/Kg -
dry
8.22
13.7
10
01/11/22 13:38
EAL
6010D
Magnesium
1933
mg/Kg -
dry
118
228
10
01/11/22 13:38
EAL
6010D
Manganese
3630
mg/Kg -
dry
14.8
22.8
10
01/11/22 13:38
EAL
6010D
Mercury
<0.0316
mg/Kg -
dry
0.0316
0.0726
1
01/07/22 12:43
JW2
7471A
Molybdenum
<6.16
mg/Kg -
dry
6.16
11.4
10
01/11/22 13:38
EAL
6010D
Nickel
29.2
mg/Kg -
dry
5.48
11.4
10
01/11/22 13:38
EAL
6010D
Potassium
<282
mg/Kg -
dry
282
457
10
01/11/22 13:38
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions L
Limit Exceeded
MQL
Method Quantitation Limit
Page 6 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Project Durham, NC
Mr. Brent Collins
755 Yadkinville Rd
Information
Mocksville , NC 27028
Report Number : 22-004-0031
Lab No : 97025
Sample ID: Brown WTP
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
REPORT OFANALYSIS
Report Date : 01/12/2022
Received : 01/04/2022
Danyale Love
Project Manager
Matrix: Solids
Sampled: 1/3/2022 12:40
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Selenium
Sodium
Zinc
Sulfur
Sodium Absorption Ratio
Qualifiers/ DF Dilution Factor
Definitions
<14.6
mg/Kg -
dry
14.6
22.8
10
01/11/22 13:38
EAL
6010D
<594
mg/Kg -
dry
594
1140
10
01/11/22 13:38
EAL
6010D
<37.0
mg/Kg -
dry
37.0
57.1
10
01/11/22 13:38
EAL
6010D
5890
mg/Kg -
dry
237
457
10
01/11/22 13:38
EAL
6010D
<0.01
Ratio
0.01
0.01
10
01/11/22 13:38
CALCULATION
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-004-0031
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 01/04/2022 10:20:14
Page 8 of 9

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Page 9 of 9

Brown 1 /3/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
594
130.086
23 5.655913
Calcium
1770
387.63
20 19.3815
Magnesium
193
42.267
12 3.52225
Percent Solids
21.9
SAR
1.67
SAR =
Na+
a (Ca2+ + M;42+ )
5.65591
0.5( 19.382 2 + 3.52225 2 )

Waypointo
ANALYTICAL
5/19/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-132-0036
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 5/12/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-132-0036
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-132-0036
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
90566 Brown W FP Solids 05/11/2022 10:45 05/12/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-132-0036
Date: 5/19/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 90600 (TB-11-3)
Analyte: Aluminum
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Arsenic
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 90600 (TB-11-3)
Analyte: Calcium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Chromium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Iron
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Potassium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Manganese
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Analyte: Phosphorus
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90566 (Brown WTP)
Analyte: Selenium
QC Batch No: 1-616955/1-616254
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 90600 (TB-11-3)
Analyte: Selenium
QC Batch No: 1-616955/1-616254
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 90600 (TB-11-3)
Analyte: Selenium
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 90592 (TB-7-3)
Analyte: Mercury
QC Batch No: 1-616692/1-615833
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 05/19/2022
//Received : 05/12/2022
C.�.-�,...dJ l.�-
Connie Cook
Report Number : 22-132-0036
REPORT OFANALYSIS
Project
Manager
Lab No : 90566
Matrix:
Solids
Sample ID: Brown WTP
Sampled:
5/11/2022
10:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
78.9
%
1
05/18/22 16:00
FMM
SW-DRYWT
Ammonia Nitrogen
1000
mg/Kg -
dry
75.8
474
1
05/19/22 14:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
338
mg/Kg -
dry
21.8
21.8
1
05/17/22 14:38
ZBD
4500NO3F-2016
Organic N
7294
mg/Kg -
dry
411.4
829.4
1
05/17/22 16:39
CALCULATION
pH
5.1
S.U.
1
05/19/2215:08
DRS
9045D
Total Solids
21.1
%
0.010
0.010
1
05/18/22 16:00
FMM
2540G-2011
Total Volatile Solids
34.4
%
0.010
0.010
1
05/18/22 16:00
FMM
2540G-2011
Total Kjeldahl Nitrogen
8290
mg/Kg -
dry
829
1
05/17/22 16:39
CLP 4500NORGD-2011
Phosphorus
986
mg/Kg -
dry
13.1
23.7
1
05/18/22 18:10
TJS
6010D
Aluminum
10900
mg/Kg -
dry
21.9
23.7
1
05/18/22 18:10
TJS
6010D
Arsenic
1.263
mg/Kg -
dry
1.14
2.37
1
05/18/22 18:10
TJS
6010D
Cadmium
5.21
mg/Kg -
dry
0.0947
0.474
1
05/18/22 18:10
TJS
6010D
Calcium
1170
mg/Kg -
dry
183
237
1
05/18/22 18:10
TJS
6010D
Chromium
13.6
mg/Kg -
dry
1.12
1.18
1
05/18/22 18:10
TJS
6010D
Copper
573
mg/Kg -
dry
1.47
2.37
1
05/18/22 18:10
TJS
6010D
Iron
334000
mg/Kg -
dry
806
948
20
05/19/22 12:01
TJS
6010D
Lead
13.2
mg/Kg -
dry
0.853
1.42
1
05/18/22 18:10
TJS
6010D
Magnesium
332
mg/Kg -
dry
12.2
23.7
1
05/18/22 18:10
TJS
6010D
Manganese
4980
mg/Kg -
dry
7.73
11.8
5
05/19/22 11:56
TJS
6010D
Mercury
0.05023
mg/Kg -
dry
0.0330
0.758
1
05/17/22 12:17
JTR
7471A
Molybdenum
3.10
mg/Kg -
dry
0.639
1.18
1
05/18/22 18:10
TJS
6010D
Nickel
58.8
mg/Kg -
dry
0.568
1.18
1
05/18/22 18:10
TJS
6010D
Potassium
265
mg/Kg -
dry
29.3
47.4
1
05/18/22 18:10
TJS
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 6 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 05/19/2022
755 Yadkinville Rd
Information :
Received : 05/12/2022
Mocksville , NC 27028
/!
Connie Cook
Report Number : 22-132-0036
REPORT OFANALYSIS
Project Manager
Lab No : 90566
Matrix: Solids
Sample ID: Brown WTP
Sampled: 5/11/2022 10:45
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<30.3
mg/Kg - dry
30.3
47.4 20 05/19/22 12:01 TJS 6010D
Sodium
402
mg/Kg - dry
61.6
118 1 05/18/22 18:10 TJS 6010D
Zinc
67.3
mg/Kg - dry
3.84
5.92 1 05/18/22 18:10 TJS 6010D
Sulfur
2550
mg/Kg - dry
24.5
47.4 1 05/18/22 18:10 TJS 6010D
Sodium Absorption Ratio
1.22
Ratio
0.01
0.01 1 05/18/22 18:10 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-132-0036
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 05/12/2022 09:50:18
Page 8 of 9

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Page 9 of 9

Brown 5/11 /22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
402
84.822
23 3.687913
Calcium
1170
246.87
20 12.3435
Magnesium
332
70.052
12 5.837667
Percent Solids
21.1
SAR
1.22
SAR =
Na+
a (Ca2+ + M;42+ )
3.68791
0.5( 12.344 2 + 5.83767 2 )

Waypointo
ANALYTICAL
7/27/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-193-0015
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 7/12/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-193-0015
Page 2 of 8

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-193-0015
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97768 Brown W FP Solids 07/08/2022 09:00 07/12/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-193-0015
Date: 7/26/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 97768 (Brown WTP)
Analyte: Aluminum
QC Batch No: 1-627396/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Iron
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Manganese
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Selenium
QC Batch No: 1-627396/1-626741
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 97768 (Brown WTP)
Analyte: Selenium
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 98409 (Little Patuxent Class A 1)
Analyte: Mercury
QC Batch No: 1-626964/1-626559
The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control
acceptance ranges. Matrix interference is suspected
Page 4 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 07/27/2022
Received : 07/12/2022
" l.�-
Connie Cook
Report Number : 22-193-0015
REPORT OFANALYSIS
Project
Manager
Lab No : 97768
Matrix:
Solids
Sample ID: Brown WTP
Sampled:
7/8/2022
9:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
81.2
%
1
07/12/22 15:45
FMM
SW-DRYWT
Ammonia Nitrogen
1150
mg/Kg -
dry
85.1
532
1
07/26/22 15:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
34.0
mg/Kg -
dry
26.6
26.6
1
07/19/22 14:59
ZBD
4500NO3F-2016
Organic N
8745
mg/Kg -
dry
590.4
1191
1
07/15/22 13:19
CALCULATION
pH
5.1
S.U.
1
07/18/2215:04
DRS
9045D
Total Solids
18.8
%
0.010
0.010
1
07/12/22 15:45
FMM
2540G-2011
Total Volatile Solids
37.3
%
0.010
0.010
1
07/12/22 15:45
FMM
2540G-2011
Total Kjeldahl Nitrogen
9890
mg/Kg -
dry
1190
1
07/15/22 13:19
CLP 4500NORGD-2011
Phosphorus
830
mg/Kg -
dry
14.7
26.6
1
07/18/22 20:37
EAL
6010D
Aluminum
7870
mg/Kg -
dry
24.6
26.6
1
07/18/22 20:37
EAL
6010D
Arsenic
5.31
mg/Kg -
dry
1.28
2.66
1
07/18/22 20:37
EAL
6010D
Cadmium
19.5
mg/Kg -
dry
0.106
0.532
1
07/18/22 20:37
EAL
6010D
Calcium
1090
mg/Kg -
dry
206
266
1
07/18/22 20:37
EAL
6010D
Chromium
12.0
mg/Kg -
dry
1.26
1.33
1
07/18/22 20:37
EAL
6010D
Copper
1620
mg/Kg -
dry
1.65
2.66
1
07/18/22 20:37
EAL
6010D
Iron
409000
mg/Kg -
dry
453
532
10
07/19/22 20:11
EAL
6010D
Lead
14.2
mg/Kg -
dry
0.957
1.60
1
07/18/22 20:37
EAL
6010D
Magnesium
309
mg/Kg -
dry
13.7
26.6
1
07/18/22 20:37
EAL
6010D
Manganese
5740
mg/Kg -
dry
17.3
26.6
10
07/19/22 20:11
EAL
6010D
Mercury
<0.0369
mg/Kg -
dry
0.0369
0.846
1
07/15/22 14:08
JTR
7471A
Molybdenum
4.31
mg/Kg -
dry
0.718
1.33
1
07/18/22 20:37
EAL
6010D
Nickel
56.4
mg/Kg -
dry
0.638
1.33
1
07/18/22 20:37
EAL
6010D
Potassium
212
mg/Kg -
dry
32.9
53.2
1
07/20/22 18:40
TJS
6010D
Qualifiers/ DF Dilution Factor
MQL
Method Quantitation Limit
Definitions
Page 5 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Project Durham, NC
Mr. Brent Collins
755 Yadkinville Rd
Information
Mocksville , NC 27028
Report Number : 22-193-0015
Lab No : 97768
Sample ID: Brown WTP
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
REPORT OFANALYSIS
Report Date : 07/27/2022
Received : 07/12/2022
" l.�—
Connie Cook
Project Manager
Matrix: Solids
Sampled: 7/8/2022 9:00
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Selenium
Sodium
Zinc
Sulfur
Sodium Absorption Ratio
Qualifiers/ DF Dilution Factor
Definitions
<17.0
mg/Kg -
dry
17.0
26.6
10
07/19/22 20:11
EAL
6010D
379
mg/Kg -
dry
69.1
133
1
07/18/22 20:37
EAL
6010D
64.9
mg/Kg -
dry
4.31
6.65
1
07/18/22 20:37
EAL
6010D
3530
mg/Kg -
dry
27.6
53.2
1
07/18/22 20:37
EAL
6010D
1.13
Ratio
0.01
0.01
1
07/18/22 20:37
CALCULATION
MQL Method Quantitation Limit
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-193-0015
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 07/12/2022 09:40:31
Page 7 of 8

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Page 8 of 8

Brown 7/8/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
379
71.252
23 3.097913
Calcium
1090
204.92
20 10.246
Magnesium
309
58.092
12 4.841
Percent Solids
18.8
SAR
1.13
SAR =
Na+
a (Ca2+ + M;42+ )
3.09791
0.5( 10.246 2 + 4.84100 2 )

Waypointo
ANALYTICAL
10/13/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-277-0022
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 10/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-277-0022
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-277-0022
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
92505 Brown W FP Solids 10/03/2022 10:30 10/04/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-277-0022
Date: 10/12/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 92505 (Brown WTP)
Analyte: Calcium
QC Batch No: 1-641846/1-641319
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 92505 (Brown WTP)
Analyte: Potassium
QC Batch No: 1-641846/1-641319
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 97015 (Bolster)
Analyte: Potassium
QC Batch No: 1-641846/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 92505 (Brown WTP)
Analyte: Magnesium
QC Batch No: 1-641846/1-641319
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 97015 (Bolster)
Analyte: Magnesium
QC Batch No: 1-642077/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 92505 (Brown WTP)
Analyte: Sodium
QC Batch No: 1-641846/1-641319
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 97015 (Bolster)
Analyte: Sodium
QC Batch No: 1-641846/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 10/18/2022
nReceived : 10/04/2022
C-�*�-� =
Connie Cook
Report Number : 22-277-0022
REPORT OFANALYSIS
Project
Manager
Lab No : 92505
Matrix:
Solids
Sample ID: Brown WTP
Sampled:
10/3/2022
10:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
78.5
%
1
10/07/2215:44
FMM
SW-DRYWT
Ammonia Nitrogen
4113
mg/Kg -
dry
74.4
465
1
10/12/22 15:20
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<20.9
mg/Kg -
dry
20.9
20.9
1
10/08/22 11:26
ZBD
4500NO3F-2016
Organic N
69863
mg/Kg -
dry
930.2
1874
1
10/06/22 14:57
CALCULATION
pH
4.9
S.U.
1
10/11/2216:00
SAR
9045D
Total Solids
21.5
%
0.010
0.010
1
10/07/22 15:44
FMM
2540G-2011
Total Kjeldahl Nitrogen
7400
mg/Kg -
dry
1870
1
10/06/22 14:57
ANH 4500NORGD-2011
Phosphorus
814
mg/Kg -
dry
64.2
116
5
10/07/22 23:32
EAL
6010D
Aluminum
4160
mg/Kg -
dry
107
116
5
10/14/22 06:07
TJS
6010D
Arsenic
38.1
mg/Kg -
dry
5.58
11.6
5
10/07/22 23:32
EAL
6010D
Cadmium
0.6703
mg/Kg -
dry
0.465
2.33
5
10/07/22 23:32
EAL
6010D
Calcium
1500
mg/Kg -
dry
902
1160
5
10/07/22 23:32
TJS
6010D
Chromium
12.7
mg/Kg -
dry
5.49
5.81
5
10/14/22 06:07
TJS
6010D
Copper
2610
mg/Kg -
dry
7.21
11.6
5
10/07/22 23:32
EAL
6010D
Iron
366000
mg/Kg -
dry
396
465
10
10/14/22 06:02
TJS
6010D
Lead
16.2
mg/Kg -
dry
4.19
6.98
5
10/07/22 23:32
EAL
6010D
Magnesium
221
mg/Kg -
dry
60.0
116
5
10/07/22 23:32
TJS
6010D
Manganese
19400
mg/Kg -
dry
15.1
23.3
10
10/14/22 06:02
TJS
6010D
Mercury
0.06983
mg/Kg -
dry
0.0280
0.642
1
10/14/22 12:39
TJS
7471B
Molybdenum
4.363
mg/Kg -
dry
3.14
5.81
5
10/07/22 23:32
EAL
6010D
Nickel
107
mg/Kg -
dry
2.79
5.81
5
10/07/22 23:32
EAL
6010D
Potassium
<144
mg/Kg -
dry
144
233
5
10/07/22 23:32
TJS
6010D
Selenium
<7.44
mg/Kg -
dry
7.44
11.6
5
10/07/22 23:32
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 10/18/2022
755 Yadkinville Rd
Information :
Received : 10/04/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-277-0022
REPORT OFANALYSIS
Project Manager
Lab No : 92505
Matrix: Solids
Sample ID: Brown WTP
Sampled: 10/3/2022 10:30
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Sodium
<302
mg/Kg - dry
302
581 5 10/07/22 23:32 TJS 6010D
Zinc
169
mg/Kg - dry
18.8
29.1 5 10/07/22 23:32 EAL 6010D
Sulfur
3400
mg/Kg - dry
120
233 5 10/07/22 23:32 6010D
Sodium Absorption Ratio
<0.01
Ratio
0.01
0.01 5 10/07/22 23:32 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 6 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-277-0022
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IMakayla Weaver Date & Time: 10/04/2022 09:23:46
Page 7 of 9

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Brown 10/3/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 302 64.93 23 2.823043
Calcium 1500 322.5 20 16.125
Magnesium 221 47.515 12 3.959583
Percent Solids 21.5
SAR 0.89
SAR — Na
2 (Ca2+ + Mg2- )
2.82304
0.5( 16.125 2 + 3.95958 2 )

ace Analytical ' ANALYTICAL REPORT
March 07, 2022
EMA Resources
Sample Delivery Group: L1462872
Samples Received: 02/17/2022
Project Number:
Description: Sludge
Report To: Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By: , �-
Justin Carr
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
N
� T
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 1 of34

TABLE OF CONTENTS
Cp: Cover Page
u
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
Fss]
BROWN WTP L1462872-01
5
Fn
Qc: Quality Control Summary
7
Wet Chemistry by Method 9012 B
7
Fr
Wet Chemistry by Method 9045D
8
Wet Chemistry by Method D93/1010A
9
Rc
Mercury by Method 7470A
10
F
Metals (ICP) by Method 6010D
11
Volatile Organic Compounds (GC/MS) by Method 8260D
12
[Al
Chlorinated Acid Herbicides (GC) by Method 8151A
14
Pesticides (GC) by Method 8081B
15
RC
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
16
GI: Glossary of Terms
18
Al: Accreditations & Locations
19
Sc: Sample Chain of Custody
20
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:
EMA Resources L1462372
03/07/22 17:11
2 of34

SAMPLE SUMMARY
Collected by
BROWN WTP L1462872-01 Waste Brent Collins
Collected date/time Received date/time
02/16/22 08:30 02/17/22 09:30 C
P
Method
Batch
Dilution Preparation
Analysis
Analyst
date/time
date/time
Preparation by Method 1311
WG1822047
1 02/23/22 0810
02/23/22 08:10
JAV
Preparation by Method 1311
WG1822926
1 02/24/2210:16
02/24/2210:16
JWS
Wet Chemistry by Method 9012 B
WG1821197
1 02/21/22 2138
02/22/2213:36
LDT
Wet Chemistry by Method 9045D
WG1819608
1 02/19/22 09:00
02/19/2213:00
GI
Wet Chemistry by Method D93/1010A
WG1821036
1 02/21/22 0100
02/21/22 0100
WOS
Mercury by Method 7470A
WG1823061
1 02/24/22 09:45
02/24/2213:43
CLL
Metals (ICP) by Method 6010D
WG1823102
1 02/24/2210:36
02/24/2215:29
KMG
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1824477
1 02/27/2218:03
02/27/22 18:03
BMB
Chlorinated Acid Herbicides (GC) by Method 8151A
WG1825661
1 03/02/22 08:02
03/02/2218:56
CCW
Pesticides (GC) by Method 8081B
WG1825495
1 03/02/22 08:42
03/02/2214:03
AO
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
WG1824791
1 03/04/22 06:25
03/04/2214:52
LEA
Subcontracted Analyses
WG1822593
1 02/25/22 00:00
02/25/22 00:00
ANF
Location
FC
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fn
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fr
Mt. Juliet, TN
Mt. Juliet, TN
Rc
Mt. Juliet, TN
Subcontract
GI
F
RC
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1462372 03/07/22 17:11
PAGE:
3 of34

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the FP
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data. 0
Fr
Rc
GI
Justin Carr [Al
Project Manager
RC
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
L1462372 -01 contains subout data that is included after the chain of custody.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 4 of 34

SAMPLE RESULTS - 01
L1462872
BROWN WTP
Collected date/time: 02/16/22 08:30
Preparation by Method 1311
Result Qualifier Prep
Batch
Analyte
date / time
TCLP Extraction
2/23/2022 8:10:29 AM
WG1822047
TCLP ZHE Extraction
- 2/24/202210:16:52 AM
WG1822926
Fluid
1 2/23/2022 8:10:29 AM
WG1822047
Initial pH
5.75 2/23/2022 8:10:29 AM
WG1822047
Final pH
5.08 2/23/2022 8:10:29 AM
WG1822047
Wet Chemistry by Method 9012 B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reactive Cyanide 0.638 0.250
Wet Chemistry by Method 9045D
Dilution Analysis Batch
date / time
1 02/22/202213:36 WG1821197
Result Qualifier
Dilution Analysis
Batch
Analyte su
date / time
Corrosivity by pH 5.57 T8
1 02/19/2022 13:00
WG1819608
Sample Narrative:
L1462872-01 WG1819608: 5.57 at19.4C
Wet Chemistry by Method D93/1010A
Result Qualifier
Dilution Analysis
Batch
Analyte Deg. F
date / time
Ignitability DNI at170
1 02/21/2022 0100
WG1821036
Mercury by Method 7470A
Result
Analyte mg/I
Mercury ND
Metals (ICP) by Method 6010D
Qualifier RDL Limit Dilution Analysis Batch
mg/I mg/I date / time
0.0100 0.20 1 02/24/202213:43 WG1823061
Result
Qualifier RDL
Limit
Analyte
mg/I
mg/I
mg/I
Arsenic
ND
0.100
5
Barium
0.205
0.100
100
Cadmium
ND
0.100
1
Chromium
ND
0.100
5
Lead
ND
0.100
5
Selenium
ND
0.100
1
Silver
ND
0.100
5
Volatile Organic Compounds (GC/MS) by Method 8260D
Dilution Analysis Batch
date / time
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Benzene
ND
0.0500
0.50
1 02/27/202218:03
WG1824477
Carbon tetrachloride
ND
0.0500
0.50
1 02/27/202218:03
WG1824477
Chlorobenzene
ND
0.0500
100
1 02/27/202218:03
WG1824477
Chloroform
ND
0.250
6
1 02/27/202218:03
WG1824477
1,2-Dichloroethane
ND
0.0500
0.50
1 02/27/202218:03
WG1824477
1,1-Dichloroethene
ND
0.0500
0.70
1 02/27/202218:03
WG1824477
2-Butanone (MEK)
ND
0.500
200
1 02/27/202218:03
WG1824477
Tetrachloroethene
ND
0.0500
0.70
1 02/27/202218:03
WG1824477
Trichloroethene
ND
0.0500
0.50
1 02/27/202218:03
WG1824477
Vinyl chloride
ND
0.0500
0.20
1 02/27/202218:03
WG1824477
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
EMA Resources
L1462372
03/07/22 17:11 5 of 34

BROWN WTP SAMPLE RESULTS
- 01
Collected date/time: 02/16/22 08:30 L1462872
Volatile Organic Compounds (GC/MS) by Method 8260D
Result Qualifier RDL Limit Dilution
Analysis
Batch
Analyte mg/I mg/I mg/I
date/time
(S) Toluene-dH 113 80.0-120
021271202218.03
WG1824477
(S) 4-Bromofluorobenzene 89.5 77.0-126
021271202218.03
WG1824477
(S) 1,2-Dichloroethone-d4 94.3 70.0-130
021271202218.03
WG1824477
Chlorinated Acid Herbicides (GC) by Method 8151A
Result Qualifier
RDL Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I mg/I
date/time
2,4,5-TP (Silvex) ND
0.00200 1
1 03/02/2022 18:56
WG1825661
2,4-D ND
0.00200 10
1 03/02/202218:56
WG1825661
(S) Z4-Dichlorophenyl Acetic Acid 83.0
14.0-158
031021202218.56
WG1825661
Pesticides (GC) by Method 8081B
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Chlordane
ND
0.00500
0.03
1 03/02/202214:03
WG1825495
Endrin
ND
0.00500
0.02
1 03/02/202214:03
WG1825495
Heptachlor
ND
0.00500
0.0080
1 03/02/202214:03
WG1825495
Heptachlor epoxide
ND
0.00500
0.0080
1 03/02/2022 14:03
WG1825495
Lindane
ND
0.00500
0.40
1 03/02/202214:03
WG1825495
Methoxychlor
ND
0.00500
10
1 03/02/202214:03
WG1825495
Toxaphene
ND
0.0100
0.50
1 03/02/202214:03
WG1825495
(S) Decochlorobiphenyl
81.5
10.0-128
0310212022 14.03
WG1825495
(S) Tetrochloro-m-xylene
70.0
10.0-127
0310212022 14.03
WG1825495
Semi Volatile Organic Compounds
(GC/MS) by Method 8270E
Analyte
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachloroethane
Nitrobenzene
Pyridine
3&4-Methyl Phenol
2-Methylphenol
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
(S) 2-Fluorophenol
(S) Phenol-d5
(S) Nitrobenzene-d5
(S) 2-Fluorobiphenyl
(S) Z4, 6-Tribromophenol
(S) p-Terphenyl-d14
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
mg/I
mg/I
mg/I
date/time
ND
0.100
7.50
1 03/04/202214:52
WG1824791
ND
0.100
0.13
1 03/04/202214:52
WG1824791
ND
0.100
0.13
1 03/04/202214:52
WG1824791
ND
0.100
0.50
1 03/04/202214:52
WG1824791
ND
0.100
3
1 03/04/202214:52
WG1824791
ND
0.100
2
1 03/04/202214:52
WG1824791
ND
0.100
5
1 03/04/202214:52
WG1824791
ND
0.100
400
1 03/04/202214:52
WG1824791
ND
0.100
200
1 03/04/202214:52
WG1824791
ND
0.100
100
1 03/04/202214:52
WG1824791
ND
0.100
400
1 03/04/202214:52
WG1824791
ND
0.100
2
1 03/04/202214:52
WG1824791
42.4
10.0-120
031041202214.52
WG1824791
27.7
10.0-120
031041202214.52
WG1824791
78.9
10.0-127
031041202214.52
WG1824791
78.9
10.0-130
031041202214.52
WG1824791
83.0
10.0-155
031041202214.52
WG1824791
92.0
10.0-128
0310412022 14.52
WG1824791
ACCOUNT:
EMA Resources
PROJECT: SDG: DATE/TIME: PAGE:
L1462372 03/07/2217:11 6 of34

WG1821197
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3762532-1 02/22/22 1322
MB Result
Analyte mg/kg
Reactive Cyanide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.0390 0.250
L1462850-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1462872-01
(OS) L1462350-01 02/22/22 13:30 • (DUP) R3762532-3 02/22/22 13:31
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide 0.424 0.437 1 3.02 20
L1462872-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1462372-01 02/22/22 13:36 • (DUP) R3762532-6 02/22/22 13:37
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide 0.638 0.583 1 8.98 20
Laboratory Control Sample (LCS)
(LCS) R3762532-2 02/22/22 1323
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Cyanide 2.50 2.52 101
Rec. Limits LCS Qualifier
85.0-115
L1462850-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462350-01 02/22/22 13:30 • (MS) R3762532-4 02/22/22 13:34 • (MSD) R3762532-5 02/22/22 13:35
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec.
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 0.424 0.595 0.438 10.2 0.855
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 75.0-125 J6 J3 J6 30.3 20
L1462970-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462970-01 02/22/22 13:33 • (MS) R3762532-7 02/22/22 13:39 • (MSD) R3762532-8 02/22/22 13:40
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 ND 1.00 1.11 60.0 66.8 1 75.0-125 J6 J6 10.7 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 7 of 34

WG1819608 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9045D L1462872-01
L1462467-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1462467-02 02/19/22 13:00 • (DUP) R3761702-2 02/19/22 13:00
Original Result DUP Result Dilution DUP RPD
Analyte su su
Corrosivity by pH 7.63 7.63 1 0.000
Sample Narrative:
OS: 7.63 at19C
DUP 7.63 at19C
Laboratory Control Sample (LCS)
DUP Qualifier DUP RPD
Limits
(LCS) R3761702-1 02/19/22 13:00
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte su su
Corrosivity by pH 10.0 9.95 99.5 99.0-101
Sample Narrative:
LCS: 9.95 at18.6C
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 3 of 34

WG1821036 QUALITY CONTROL SUMMARY
Wet Chemistry by Method D93/1010A L1462872-01
L1463101-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1463101-02 02/21/22 01:00 • (DUP) R3762219-3 02/21/22 0100
Original Result DUP Result Dilution DUP RPD
Analyte Deg. F Deg. F
Ignitability 132 140 1 5.90
DUP Qualifier DUP RPD
Limits
i
10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3762219-1 02/21/22 01:00 • (LCSD) R3762219-2 02/21/22 0100
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte Deg. F Deg. F Deg. F
Ignitability 126 128 122 101 96.5 95.6-104 4.82 10
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 9 of 34

WG1823061 QUALITY CONTROL SUMMARY
Mercury by Method 7470A L1462872-01
Method Blank (MB)
(MB) R3763464-1 02/24/22 1313
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/I mg/I mg/I
Mercury U 0.00330 0.0100
Laboratory Control Sample (LCS)
(LCS) R3763464-2 02/24/22 1324
Spike Amount LCS Result LCS Rec.
Analyte mg/I mg/I
Mercury 0.0300 0.0310 103
Rec. Limits LCS Qualifier
80.0-120
L1459816-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1459316-02 02/24/22 13:26 • (MS) R3763464-3 02/24/22 13:29 • (MSD) R3763464-4 02/24/22 13:31
Spike Amount
Original Result
MS Result
MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Mercury 0.0300
ND
0.0326
0.0332 109 111 1 75.0-125 1.70 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 10 of 34

WG1823102
Metals (ICP) by Method 6010D
Method Blank (MB)
(MB) R3763533-1 02/24/22 1512
MB Result
MB Qualifier MB MDL
MB RDL
Analyte mg/I
mg/I
mg/I
Arsenic U
0.0333
0.100
Barium U
0.0333
0.100
Cadmium U
0.0333
0.100
Chromium U
0.0333
0.100
Lead U
0.0333
0.100
Selenium U
0.0333
0.100
Silver U
0.0333
0.100
Laboratory Control Sample (LCS)
(LCS) R3763588-2 02/24/22 1514
QUALITY CONTROL SUMMARY
L1462872-01
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
Analyte
mg/I
mg/I
Arsenic
10.0
9.46
94.6
80.0-120
Barium
10.0
9.62
96.2
80.0-120
Cadmium
10.0
9.52
95.2
80.0-120
Chromium
10.0
9.93
99.3
80.0-120
Lead
10.0
9.44
94.4
80.0-120
Selenium
10.0
10.3
103
80.0-120
Silver
2.00
1.75
87.7
80.0-120
LCS Qualifier
L1459816-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1459316-02 02/24/22 15:17 • (MS) R3763533-4 02/24/22 15:23 • (MSD) R3763533-5 02/24/22 15:26
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Arsenic
10.0
ND
9.44
9.25
94.4
92.5
Barium
10.0
0.421
9.94
9.88
95.2
94.6
Cadmium
10.0
ND
9.45
9.44
94.5
94.4
Chromium
10.0
ND
9.93
9.84
99.3
98.4
Lead
10.0
ND
9.42
9.32
93.6
92.6
Selenium
10.0
ND
10.2
10.2
102
102
Silver
2.00
ND
1.76
1.74
87.8
87.1
Dilution Rec. Limits
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
MS Qualifier MSD Qualifier RPD
1.95
0.626
0.0823
0.879
1.09
0.465
0.872
RPD Limits
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG:
EMA Resources L1462372
DATE/TIME:
03/07/22 17:11
PAGE:
11 of 34

WG1824477 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1462872-01
Method Blank (MB)
(MB) R3764355-3 02/27/22 13:43
MB Result
Analyte
mg/I
Benzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chloroform
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
2-Butanone (MEK)
U
Tetrachloroethene
U
Trichloroethene
U
Vinyl chloride
U
(S) Toluene-dH
115
(S) 4-Bromofluorobenzene 91.4
(S) 1,2-Dichloroethane-d4 90.5
MB Qualifier MB MDL
mg/I
MB RDL
mg/I
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
0.0833
0.250
0.0167
0.0500
0.0167
0.0500
0.167
0.500
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
80.0-120
77.0-126
70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3764355-1 02/27/22 10:38 • (LCSD) R3764355-2 02/27/22 12:39
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
Analyte
mg/I
mg/I
mg/I
Benzene
0.250
0.251
0.275
100
110
70.0-123
Carbon tetrachloride
0.250
0.229
0.222
91.6
88.8
68.0-126
Chlorobenzene
0.250
0.260
0.294
104
118
80.0-121
Chloroform
0.250
0.253
0.274
101
110
73.0-120
1,2-Dichloroethane
0.250
0.248
0.274
99.2
110
70.0-128
1,1-Dichloroethene
0.250
0.249
0.258
99.6
103
71.0-124
2-Butanone (MEK)
1.25
1.09
1.21
87.2
96.8
44.0-160
Tetrachloroethene
0.250
0.265
0.266
106
106
72.0-132
Trichloroethene
0.250
0.245
0.261
98.0
104
78.0-124
Vinyl chloride
0.250
0.289
0.291
116
116
67.0-131
(S) Toluene-dH
112
113
80.0-120
(S) 4-Bromofluorobenzene
91.1
90.5
77.0-126
(S) 1,2-Dichloroethane-d4
94.0
94.0
70.0-130
LCS Qualifier
LCSD Qualifier RPD
9.13
3.10
12.3
7.97
9.96
3.55
10.4
0.377
6.32
0.690
RPD Limits
20
20
20
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 12 of 34

WG1824477 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1462872-01
L1464040-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1464040-04 02/27/22 20:50 • (MS) R3764355-4 02/27/22 21:11 • (MSD) R3764355-5 02/27/22 2132
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Benzene 0.250
ND
0.166
0.168
66.4
67.2
1 17.0-158
1.20
27
Carbon tetrachloride 0.250
ND
0.160
0.168
64.0
67.2
1 23.0-159
4.88
28
Chlorobenzene 0.250
ND
0.219
0.219
87.6
87.6
1 33.0-152
0.000
27
Chloroform 0.250
ND
ND
ND
83.6
84.4
1 29.0-154
0.952
28
1,2-Dichloroethane 0.250
ND
0.201
0.196
80.4
78.4
1 29.0-151
2.52
27
1,1-Dichloroethene 0.250
ND
0.119
0.118
47.6
47.2
1 11.0-160
0.844
29
2-Butanone (MEK) 1.25
ND
1.05
1.12
84.0
89.6
1 10.0-160
6.45
32
Tetrachloroethene 0.250
3.96
3.77
3.56
0.000
0.000
1 10.0-160
V_ V_ 5.73
27
Trichloroethene 0.250
ND
0.170
0.173
68.0
69.2
1 10.0-160
1.75
25
Vinyl chloride 0.250
ND
0.130
0.126
52.0
50.4
1 10.0-160
3.12
27
(S) Toluene-dH
110
110
80.0-120
(S) 4-Bromofluorobenzene
97.6
95.1
77.0-126
(S) 1,2-Dichloroethane-d4
94.6
94.0
70.0-130
L1462927-03 Original Sample
(OS) • Matrix Spike (MS)
(OS) L1462927-03 02/27/22 13:45 • (MS) R3764355-6 02/27/22 2152
Spike Amount
Original Result
MS Result
MS Rec.
Dilution
Rec. Limits
MS Qualifier
Analyte mg/I
mg/I
mg/I
Benzene 0.250
ND
0.169
67.6
1
17.0-158
Carbon tetrachloride 0.250
ND
0.165
66.0
1
23.0-159
Chlorobenzene 0.250
ND
0.218
87.2
1
33.0-152
Chloroform 0.250
ND
ND
84.0
1
29.0-154
1,2-Dichloroethane 0.250
ND
0.199
79.6
1
29.0-151
1,1-Dichloroethene 0.250
ND
0.119
47.6
1
11.0-160
2-Butanone (MEK) 1.25
ND
1.05
84.0
1
10.0-160
Tetrachloroethene 0.250
ND
0.202
80.8
1
10.0-160
Trichloroethene 0.250
ND
0.184
73.6
1
10.0-160
Vinyl chloride 0.250
ND
0.131
52.4
1
10.0-160
(S) Toluene-dH
119
80.0-120
(S) 4-Bromofluorobenzene
97.6
77.0-126
(S) 1,2-Dichloroethane-d4
93.9
70.0-130
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
EMA Resources
L1462372
03/07/22 17:11
13 of 34

WG1825661
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
(MB) R3765374-1 03/02/22 16:58
MB Result
Analyte mg/I
2,4,5-TP (Silvex) U
2,4-D U
(S) Z4-Dichlorophenyl Acetic 70.0
Acid
QUALITY CONTROL SUMMARY
L1462872-01
MB Qualifier MB MDL
MB RDL
mg/I
mg/I
0.000667
0.00200
0.000667
0.00200
14.0-158
Laboratory Control Sample (LCS)
(LCS) R3765874-2 03/02/22 1713
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
2,4,5-TP (Silvex) 0.0500
0.0417
83.4
50.0-125
2,4-D 0.0500
0.0451
90.2
50.0-120
(S) Z4-Dichlorophenyl Acetic
74.0
14. 0-158
Acid
L1463588-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1463533-01 03/02/22 20:24 • (MS) R3765874-3 03/02/22 20:38 • (MSD) R3765874-4 03/02/22 20:53
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
2,4,5-TP (Silvex)
0.0500
ND
0.0416
0.0359
83.2
71.8
2,4-D
0.0500
ND
0.0401
0.0407
80.2
81.4
(S) Z4-Dichlorophenyl Acetic
74.4
74.2
Acid
ACCOUNT:
EMA Resources
PROJECT:
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 50.0-125 14.7 20
1 50.0-120 1.49 20
14.0-158
SDG: DATE/TIME: PAGE:
L1462372 03/07/22 17:11 14 of 34

WG1825495
Pesticides (GC) by Method 8081B
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1462872-01
(MB) R3765616-1 03/02/22 1337
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Chlordane
U
0.00167
0.00500
Endrin
U
0.00167
0.00500
Heptachlor
U
0.00167
0.00500
Heptachlor epoxide
U
0.00167
0.00500
Gamma BHC
U
0.00167
0.00500
Methoxychlor
U
0.00167
0.00500
Toxaphene
U
0.00333
0.0100
(S) Decachlorobiphenyl
89.0
10.0-128
(S) Tetrochloro-m-xylene
71.5
10.0-127
Laboratory Control Sample (LCS)
(LCS) R3765616-2 03/02/22 13:46
Spike Amount
LCS Result
Analyte
mg/I
mg/I
Endrin
0.0100
0.00938
Heptachlor
0.0100
0.00904
Heptachlor epoxide
0.0100
0.00928
Gamma BHC
0.0100
0.00965
Methoxychlor
0.0100
0.0110
(S) Decachlorobiphenyl
(S) Tetrochloro-m-xylene
LCS Rec. Rec. Limits LCS Qualifier
93.8
90.4
92.8
96.5
110
94.7
81.1
57.0-134
27.0-132
57.0-130
55.0-129
54.0-155
10.0-128
10.0-127
P
L1462872-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462372-01 03/02/22 14:03 • (MS) R3765616-3 03/02/22 14:12 • (MSD) R3765616-4 03/02/22 14:21
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Endrin
0.0100
ND
0.00939
0.00836
93.9
83.6
Heptachlor
0.0100
ND
0.00884
0.00793
88.4
79.3
Heptachlor epoxide
0.0100
ND
0.00942
0.00838
94.2
83.8
Gamma BHC
0.0100
ND
0.00973
0.00856
97.3
85.6
Methoxychlor
0.0100
ND
0.0110
0.00987
110
98.7
(S) Decachlorobiphenyl
96.6
87.2
(S) Tetrochloro-m-xylene
80.2
68.8
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
1 10.0-160
11.6
1 16.0-136
10.9
1 10.0-160
11.7
1 14.0-141
12.8
1 10.0-160
P P 10.8
10.0-128
10.0-127
RPD Limits
39
40
36
40
34
ACCOUNT:
EMA Resources
PROJECT:
SDG: DATE/TIME:
L1462372 03/07/22 17:11
PAGE:
15 of 34

WG1824791 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1462872-01
Method Blank (MB)
(MB) R3766433-2 03/04/22 1141
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
U
0.0333
0.100
2,4-Dinitrotoluene
U
0.0333
0.100
Hexachlorobenzene
U
0.0333
0.100
Hexachloro-1,3-butadiene
U
0.0333
0.100
Hexachloroethane
U
0.0333
0.100
Nitrobenzene
U
0.0333
0.100
Pyridine
U
0.0333
0.100
3&4-Methyl Phenol
U
0.0333
0.100
2-Methylphenol
U
0.0333
0.100
Pentachlorophenol
U
0.0333
0.100
2,4,5-Trichlorophenol
U
0.0333
0.100
2,4,6-Trichlorophenol
U
0.0333
0.100
(S) 2-Fluorophenol
45.8
10.0-120
(S) Phenol-d5
28.0
10.0-120
(S) Nitrobenzene-d5
80.8
10.0-127
(S) 2-Fluorobiphenyl
83.4
10.0-130
(S) 2,4, 6-Tribromophenol
83.5
10. 0-155
(S) p-Terphenyl-d14
93.2
10.0-128
Laboratory Control Sample (LCS)
(LCS) R3766483-1 03/04/22 1120
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
1,4-Dichlorobenzene 0.500
0.443
88.6
18.0-120
2,4-Dinitrotoluene 0.500
0.610
122
49.0-124
Hexachlorobenzene 0.500
0.545
109
44.0-120
Hexachloro-1,3-butadiene 0.500
0.336
67.2
19.0-120
Hexachloroethane 0.500
0.456
91.2
15.0-120
Nitrobenzene 0.500
0.422
84.4
27.0-120
Pyridine 0.500
0.158
31.6
10.0-120
3&4-Methyl Phenol 0.500
0.410
82.0
31.0-120
2-Methylphenol 0.500
0.396
79.2
28.0-120
Pentachlorophenol 0.500
0.422
84.4
23.0-120
2,4,5-Trichlorophenol 0.500
0.498
99.6
44.0-120
2,4,6-Trichlorophenol 0.500
0.452
90.4
42.0-120
(S) 2-Fluorophenol
48.5
10.0-120
(S) Phenol-d5
32.2
10.0-120
(S) Nitrobenzene-d5
80.0
10.0-127
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1462872 03/07/22 17:11 16 of 34

WG1824791 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1462872-01
Laboratory Control Sample (LCS)
(LCS) R3766483-1 03/04/22 1120
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/I mg/I
(S) 2-Fluorobiphenyl 88.4 10.0-130
(S) 2,4, 6-Tribromophenol 99.0 10. 0-155
(S) p-Terphenyl-d14 89.9 10.0-128
L1462338-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462333-02 03/04/22 13:27 • (MS) R3766483-3 03/04/22 13:48 • (MSD) R3766483-4 03/04/22 14:09
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
Analyte
mg/I
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
0.500
ND
0.356
0.346
71.2
69.2
1 17.0-120
2.85
2,4-Dinitrotoluene
0.500
ND
0.505
0.482
101
96.4
1 39.0-125
4.66
Hexachlorobenzene
0.500
ND
0.460
0.441
92.0
88.2
1 35.0-122
4.22
HexachIaro-1,3-butadiene
0.500
ND
0.285
0.299
57.0
59.8
1 12.0-120
4.79
Hexachloroethane
0.500
ND
0.383
0.378
76.6
75.6
1 10.0-120
1.31
Nitrobenzene
0.500
ND
0.381
0.385
76.2
77.0
1 12.0-120
1.04
Pyridine
0.500
ND
0.120
0.127
24.0
25.4
1 10.0-120
5.67
3&4-Methyl Phenol
0.500
ND
0.447
0.445
89.4
89.0
1 10.0-120
0.448
2-Methylphenol
0.500
0.171
0.502
0.501
66.2
66.0
1 10.0-120
0.199
Pentachlorophenol
0.500
ND
0.390
0.378
78.0
75.6
1 10.0-128
3.12
2,4,5-Trichlorophenol
0.500
ND
0.406
0.397
81.2
79.4
1 33.0-120
2.24
2,4,6-Trichlorophenol
0.500
ND
0.381
0.372
76.2
74.4
1 26.0-120
2.39
(S) 2-Fluorophenol
41.3
39.2
10.0-120
(S) Phenol-d5
27.6
26.9
10.0-120
(S) Nitrobenzene-d5
76.1
74.9
10.0-127
(S) 2-Fluorobiphenyl
75.4
72.9
10.0-130
(S)2,4,6-Tribromophenol
89.0
83.0
10.0-155
(S) p-Terphenyl-d14
83.9
80.6
10.0-128
RPD Limits
40
25
24
34
40
30
37
36
30
37
31
31
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 17 of 34

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
u
Fc
Fss]
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
Fn
RDL
Reported Detection Limit.
Rec.
Recovery.
Fr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
F
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
F
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Rc
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe
samples from the time of collection until delivery to the laboratory for analysis.
This section ofyour report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J3
The associated batch QC was outside the established quality control range for precision.
J6
The sample matrix interfered with the ability to make any accurate determination, spike value is low.
P
RPD between the primary and confirmatory analysis exceeded 40%.
T8
Sample(s) received past/too close to holding time expiration.
v
The sample concentration is too high to evaluate accurate spike recoveries.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1462372 03/07/22 17:11 13 of 34

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
N E-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TNO02
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704 _
Georgia
NELAP
North Carolina 3
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky' 6
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee'"
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas5
LABO152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A2 LA
A2LA— ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A2 LA — ISO 17025 5
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
Rc
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1462372 03/07/22 17:11
PAGE:
19 of 34

Company Name/Address:
E MA Resources
Billing Information:
Mr. Brent Collins LChks
An
Iv is /Contall
/ r
s rvative
Chain of Custody Page — of
755 Yadkinviile Road
aCE AnaIytlCa�
755 Yadkinville Road
Mocksville, NC 27028
Mocksville, INC 27028
,
sunm5r `6anon Rdk tta lhn d-n M[,,todv
easamp
SpI51iluln acknowledgmanl and acceptance of [he
i Terms and [nndiliona found al',
httn//info.pattiaM.mm uMslpas-Woodard
ermr.pei
Report to:
Mr. Brent Collins
Email To,
brent.collins ema'esourcesinc.com;ro .wnitak
y
Project Description:
Sludge
city/State llease
Collected: �11r�OM JNG TPT
Circle
MT Cl ET
SDG #
Phone [phone]
Client Project #
Lab Project #
1060
`
a
°
Z
W
J
ry
U
6
Z
U
j
a
V
h-
Acctnum; kMAKkS
Tempiate:T11413
Prelogin: P895405
PM: 807 -Justin Carr
PB;�y—
Collected by (print):
��� ���a
Site/Facility ID #
P.O. #
Collected by (signature),
Immediately
Packed on Ice N _ Y
Rush) (Lab MUST Be Notified) Quote #
Same Day _ Five Day
'_Next Day _ 5 Day (Rad Only) Date Results Needed
_ Two Day _ 10 Day (Rod Only) No.
_ Three Day of
snipped via: FedEX Ground
Sample ID
Comp/Grab
Matrix'
Depth
Date
Time
ntrs
T
Remar6a Sample # (lab or,iy)
�rown YJ'rP
C
s5
3 '
Z1,�lZL
�'3a
2
X
X
' Matrix:Remarks:
SS - Soil AIR - Air F- Filter pH Temp
GW Groundwater B- Bioassa y Flow Other
WW - WasteWater
sar'1` t
COC Seal Present/intact: r [aF t N
CDC Signed/Accurate: /t N
Bottles arrive intact: "e' N
Correct bottles used: Y _N
DW - Drinking Water
OT - Other Samples returned via: Tracking #
UPS FedEx
Sufficient volume sent: _N
If Aonlicable
VCA Zero Headspace: 'f N
_ _ —Courier
_
PAD Screen On Correct/Checked: N
PAD Screen <0.5 mR/hr:
Relinquished by ; (Signature) Date:
q g I
Z%1ZZ
Time
j,7o
Received by: (Signature)
Trip Blank Received: Yes/ o
,leoti
TBR
BR -
Relinquished by: (Signature) Date:
Time:
Received by: (Signature)
Tee�mp: CBottles Rece.
�'f'
1 6 /
If preservation required by Login: Date/Time
Relinquished by: (Signature) Date,
Time
i'ved far I by: (5ignatur)
a e: Time;
�/ v2L 30
Hold:
Condit'
NCF , 0

urofins
Environment Testing
America
ANALYTICAL REPORT
Eurofins Chicago
2417 Bond Street
University Park, IL 60484
Tel: [phone]
Laboratory Job ID: 500-212792-1
Client Project/Site: WG1822593
For
Pace Analytical National
12065 Lebanon Rd
Mt Juliet, Tennessee 37122
Attn: Jimmy Huckaba
Authorized for release by:
212512022 2:46:10 PM
Jim Knapp, Project Manager II
[phone]
[e-mail]
Designee for
Sandie Fredrick, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for
accredited parameters, exceptions are noted in this report. This report may not be reproduced
except in full, and with written approval from the laboratory. For questions please contact the
Project Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
12
13
14

Client: Pace Analytical National
Project/Site: WG1822593
Laboratory Job ID: 500-212792-1
Table of Contents
Cover Page ..............................................
Table of Contents .........................................
2
Case Narrative ...........................................
3
Detection Summary ........................................
4
Method Summary .........................................
5
Sample Summary .........................................
6
Client Sample Results ......................................
7
Definitions ...............................................
8
QC Association ...........................................
9
QC Sample Results ........................................
10
Chronicle ................................................
11
Certification Summary ......................................
12
Chain of Custody ..........................................
13
Receipt Checklists .........................................
14
12
13
14
Eurofins Chicago
Page 2 of 14 2/25/2022

Case Narrative
Client: Pace Analytical National
Project/Site: WG1822593
Job ID: 500-212792-1
Laboratory: Eurofins Chicago
Narrative
Job Narrative
500-212792-1
Comments
No additional comments.
Job ID: 500-212792-1
Receipt
The sample was received on 2/24/2022 10:00 AM. Unless otherwise noted below, the sample arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 1.20 C.
General Chemistry
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
12
13
14
Eurofins Chicago
Page 3 of 14 2/25/2022

Detection Summary
Client: Pace Analytical National Job ID: 500-212792-1
Project/Site: WG1822593
Client Sample ID: BROWN WTP Lab Sample ID: 500-212792-1
ENo Detections.
This Detection Summary does not include radiochemical test results.
F47
12
13
14
Eurofins Chicago
Page 4 of 14 2/25/2022

Method Summary
Client: Pace Analytical National
Project/Site: WG1822593
Method Method Description
9034 Sulfide, Reactive
7.3.4 Sulfide, Reactive
Protocol References:
Job ID: 500-212792-1
Protocol Laboratory
SW846 TAL CHI
SW846 TAL CHI
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL CHI = Eurofins Chicago, 2417 Bond Street, University Park, IL 60484, TEL [phone]
12
13
14
Eurofins Chicago
Page 5 of 14 2/25/2022

Sample Summary
Client: Pace Analytical National
Project/Site: WG1822593
Lab Sample ID Client Sample ID Matrix Collected Received
500-212792-1 BROWN WTP Solid 02/16/22 08:30 02/24/22 10:00
Job ID: 500-212792-1
12
13
14
Page 6 of 14 Eurofins--J?N2922

Client Sample Results
Client: Pace Analytical National
Project/Site: WG1822593
Job ID: 500-212792-1
Client Sample ID: BROWN WTP Lab Sample ID: 500-212792-1
Date Collected: 02/16/22 08:30 Matrix: Solid
Date Received: 02/24/22 10:00
General Chemistry
Analyte Result Qualifier LOQ LOD Unit D Prepared Analyzed Dil Fac
Sulfide, Reactive <3.7 46.9 3.7 mg/Kg 02/24/22 19:05 02/25/22 11:02 1
12
13
14
Eurofins Chicago
Page 7 of 14 2/25/2022

Definitions/Glossary
Client: Pace Analytical National
Project/Site: WG1822593
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
II Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level'
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRIES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Job ID: 500-212792-1
0
12
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Eurofins Chicago
Page 8 of 14 2/25/2022

QC Association Summary
Client: Pace Analytical National
Project/Site: WG1822593
General Chemistry
Prep Batch: 644394
Job ID: 500-212792-1
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
500-212792-1
BROWN WTP
Total/NA
Solid
7.3.4
MB 500-644394/1-A
Method Blank
Total/NA
Solid
7.3.4
LCS 500-644394/2-A
Lab Control Sample
Total/NA
Solid
7.3.4
Analysis Batch: 644530
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
500-212792-1
BROWN WTP
Total/NA
Solid
9034
644394
MB 500-644394/1-A
Method Blank
Total/NA
Solid
9034
644394
LCS 500-644394/2-A
Lab Control Sample
Total/NA
Solid
9034
644394
12
13
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Eurofins Chicago
Page 9 of 14 2/25/2022

QC Sample Results
Client: Pace Analytical National
Project/Site: WG1822593
Job I D: 500-212792-1
Method: 9034 - Sulfide, Reactive
Lab Sample ID: MB 500-644394/1-A Client Sample ID: Method Blank
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 644530 Prep Batch: 644394
MB MB
Analyte Result Qualifier LOQ LOD Unit D Prepared Analyzed Dil Fac
Sulfide, Reactive <3.9 50.0 3.9 mg/Kg 02/24/22 18:46 02/25/22 10:49 1
Lab Sample ID: LCS 500-644394/2-A Client Sample ID: Lab Control Sample
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 644530 Prep Batch: 644394
Spike LCS LCS %Rec.
Analyte Added Result Qualifier Unit D %Rec Limits
Sulfide, Reactive 198 162.9 mg/Kg 82 80 -120
12
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Eurofins Chicago
Page 10 of 14 2/25/2022

Lab Chronicle
Client: Pace Analytical National
Project/Site: WG1822593
Job ID: 500-212792-1
Client Sample ID: BROWN WTP Lab Sample ID: 500-212792-1
Date Collected: 02/16/22 08:30 Matrix: Solid
Date Received: 02/24/22 10:00
Batch
Batch
Dilution Batch
Prepared
Prep Type Type
Method
Run Factor Number
or Analyzed Analyst Lab
Total/NA Prep
7.3.4
644394
02/24/22 19:05 TMS TAL CHI
Total/NA Analysis
9034
1 644530
02/25/22 11:02 TMS TAL CHI
Laboratory References:
TAL CHI = Eurofins Chicago, 2417
Bond Street, University
Park, IL 60484, TEL [phone]
11
12
13
14
Eurofins Chicago
Page 11 of 14 2/25/2022

Accreditation/Certification Summary
Client: Pace Analytical National
Project/Site: WG1822593
Laboratory: Eurofins Chicago
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority
Program
California
State
Georgia
State
Georgia (DWW)
State
Hawaii
State
Illinois
NELAP
Indiana
State
Iowa
State
Kansas
NELAP
Kentucky (UST)
State
Kentucky (WWW)
State
Louisiana
NELAP
Mississippi
State
North Carolina (WWW/SW)
State
North Dakota
State
Oklahoma
State
South Carolina
State
USDA
US Federal Programs
Wisconsin
State
Wyoming
State
Job ID: 500-212792-1
Identification Number Expiration Date
2903
04-29-22
N/A
04-29-22
939
04-30-21
NA
04-29-22
IL00035
04-29-22
C-1 L-02
04-29-22
082
05-01-22
E-10161
10-31-22
Al # 108083
04-29-22
KY90023
12-31-22
02046
06-30-22
NA
04-30-22
291
12-31-22
R-194
04-29-22
8908
08-31-22
77001003
04-29-22
P330-18-00018
02-11-24
999580010
08-31-22
8TMS-Q
04-30-22
Accreditation/Certification renewal pending - accreditation/certification considered valid.
Eurofins Chicago
Page 12 of 14 2/25/2022

Batch Date/Time. 02/23/22 13 47
Sub -Contract Lab IACIPR
Address: 2417 Bond Street
City/State: University Park, 1I
60484
Contact:
San dra. Fredrrcktd Eurofinset. com
Owner Lab: PACLMTJL
kddress: 12065I ebanon Rd
City/State: Mt, Joliet, TN 37122
Phone: [phone]
Fax: [phone]
a—
WO.VvG 18225500-212792 COC
Lntad: M1;TI SuboutI'evn(&pacelabs corri
Results Due Date: 03/09/22
LSC. Purchase Order #: 1 1462872
Send Reports to: James C 1Juckaba
12065 Lebanon Rd
Mt Juliet, TN 37122
Phone [phone]
Fax [phone]
Sample ID Sample Number Sample Comments
Container ID Matrix State Collect Date Description Lab Use Only Lab Use Only
BROWN WTP SS NC 02/16/22 08 30 Miscellaneous Analysis 2 L1462872-01 Reactive Sulfide
Relinquished by: 4 Date a -al -C)vd.
Recre,�ed by: � Date LIP
Relinquished by
Recieved by: Date
Page 13 of 14 2/25/2022

Client: Pace Analytical National
Login Number: 212792
List Number: 1
Creator: Scott, Sherri L
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
True
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
1.2
Job Number: 500-212792-1
List Source: Eurofins Chicago
12
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Eurofins Chicago
Page 14 of 14 2/25/2022

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0003504 Laboratory:
Facility Name: City of Durham
Residual Source WQ # or
NPDES #:
NCO047597
WWTP Name: South Durham WRF
Residual Analysis Data
1) Waypoint Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Cone.
Limit
(m ).'
Sample or Composite
Date
113/22
3/l/22
5111122
7/8/22
10/3/22
11/8/22
Percent Solids (°f°)
NA
15.6
12.8
18
13
15.8
16.3
Arsenic
75
3.21
3.56
3.74
6.96
4.92
4.29
Cadmium
8.5
1.04
0.691
0.683
0.969
0.848
0.816
Copper
4,300
429
361
366
441
465
494
Chromium
NA
19.8
17.1
19.3
20.1
21.9
19.9
Lead
840
32.3
17.9
15.7
17.9
18.3
15.5
Mercury
57
0.301
0.472
0.257
0.628
0.38
0.712
Molybdenum
75
32.1
15.5
15.1
23.7
21.8
23.9
Nickel
420
19.5
16.4
15.9
16.5
18.4
19.2
Selenium
100
6.22
2.91
4.07
5.76
6.65
6.2
Zinc
7,500
2900
2590
2520
2820
3050
3090
Total Phosphorus
NA
41900
36400
34300
39900
40800
39500
TKN
NA
62200
53800
59400
51200
50900
53700
Ammonia -Nitrogen
NA
8650
9840
10600
12500
9810
6500
Nitrate and Nitrite
NA
55.1
39
78.9
41
1690
150
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1 102 (26)
Z-_2 y-2
Date
DENR FORM RSSF (1212006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
WQ0003504 Laboratory:
Facility Name:
City of Durham
Residual Source
NCO047597
NPDRS # or WQ#:
WWTP Name:
South Durham WRF
Residual Analysis Data
l) Waypoint Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Sample or Composite Date
1/3/22
3/l/22
5/11/22
7l8/22
10/3/22
11/8/22
Aluminum
33500
25400
26100
33200
34400
31300
Calcium
20400
17800
19000
20500
20400
22300
Magnesium
6040
5340
5070
5790
6030
6260
pH
8.3
8.2
7.5
8
7.7
6.7
Potassium
3230
2960
3260
3310
3170
3100
Sodium
897
672
817
954
969
926
PAN
15090
13751
15139
14031
14813
12840
SAR
0.56
0.4
0.58
0.54
0.61
0.57
"l certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
=v2j;/,-2-T
Date
DENR FORM RSSF - B (12/2006)

Waypointo
ANALYTICAL
1 /17/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC, 27028
Ref: Analytical Testing
Revised Lab Report Number: 22-004-0034
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 1/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2022
Arkansas
State Program
88-0650
02/07/2022
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-004-0034
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-004-0034
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97042 South Durham Solids 01/03/2022 12:05 01/04/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-004-0034
Date: 1 /11 /2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
This report is being revised in order to add CCE to the project sample.
Metals Analysis Method 601 OD
Sample 97328
Analyte: Aluminum
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Arsenic
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Analyte: Calcium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Chromium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Iron
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Potassium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Manganese
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Lead
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypoint".0 -
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97329
Analyte: Mercury
QC Batch No: 1-593529/1-593334
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Road
Mocksville , NC 27028
Report Number : 22-004-0034
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Original Report Date : 01/11/2022
Revised Report Date: 01/17/2022
Received : 01/04/2022
REPORT OFANALYSIS
Lab No : 97042
Matrix: Solids
Sample ID : South Durham
Sampled:
1/3/2022
12:05
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Neutralizing Value (%CCE)
19.9
%
0.1
1
01/17/22 11:26
DXT
AOAC 955.01
Moisture
84.4
%
0.010
1
01/04/22 16:05
FMM
SW-DRYWT
Ammonia Nitrogen
8650
mg/Kg -
dry
103
641
1
01/11/22 13:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
55.1
mg/Kg -
dry
30.6
30.6
1
01/10/22 15:19
ZBD
4500NO3F-2011
Organic N
53590
mg/Kg -
dry
10900
1
01/11/22 13:30
CALCULATION
pH
8.3
S.U.
1
01/06/2215:16
DRS
9045D
Total Solids
15.6
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Volatile Solids
68.1
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Kjeldahl Nitrogen
62200
mg/Kg -
dry
10900
10
01/11/22 14:59
CLP 4500NORGD-2011
Phosphorus
41900
mg/Kg -
dry
17.7
32.1
1
01/11/22 01:23
EAL
6010D
Aluminum
33500
mg/Kg -
dry
29.6
32.1
1
01/11/22 01:23
EAL
6010D
Arsenic
3.21
mg/Kg -
dry
1.54
3.21
1
01/11/22 01:23
EAL
6010D
Cadmium
1.04
mg/Kg -
dry
0.128
0.641
1
01/11/22 01:23
EAL
6010D
Calcium
20400
mg/Kg -
dry
248
321
1
01/11/22 01:23
EAL
6010D
Chromium
19.8
mg/Kg -
dry
1.51
1.60
1
01/11/22 01:23
EAL
6010D
Copper
429
mg/Kg -
dry
1.99
3.21
1
01/11/22 01:23
EAL
6010D
Iron
16900
mg/Kg -
dry
54.6
64.1
1
01/11/22 01:23
EAL
6010D
Lead
32.3
mg/Kg -
dry
1.15
1.92
1
01/11/22 01:23
EAL
6010D
Magnesium
6040
mg/Kg -
dry
16.5
32.1
1
01/11/22 01:23
EAL
6010D
Manganese
533
mg/Kg -
dry
2.08
3.21
1
01/11/22 01:23
EAL
6010D
Mercury
0.301
mg/Kg -
dry
0.0442
0.101
1
01/07/22 12:50
JW2
7471A
Molybdenum
32.1
mg/Kg -
dry
0.865
1.60
1
01/11/22 01:23
EAL
6010D
Nickel
19.5
mg/Kg -
dry
0.769
1.60
1
01/11/22 01:23
EAL
6010D
Qualifiers/ DF
Dilution Factor
L
Limit Exceeded
Definitions MQL
Method Quantitation Limit
Page 6 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Project Durham, NC
Mr. Brent Collins
755 Yadkinville Road
Information
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Original Report Date : 01/11/2022
Revised Report Date: 01/17/2022
Received : 01/04/2022
Report Number : 22-004-0034 REPORT OFANALYSIS
Lab No : 97042
Sample ID : South Durham
Matrix: Solids
Sampled: 1/3/2022 12:05
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Potassium
3230
mg/Kg -
dry
39.6
64.1
1
01/11/22 01:23 EAL
6010D
Selenium
6.22
mg/Kg -
dry
2.05
3.21
1
01/11/22 01:23 EAL
6010D
Sodium
897
mg/Kg -
dry
83.3
160
1
01/11/22 01:23 EAL
6010D
Zinc
2900
mg/Kg -
dry
5.19
8.01
1
01/11/22 01:23 EAL
6010D
Sulfur
15600
mg/Kg -
dry
33.2
64.1
1
01/11/22 01:23 EAL
6010D
Sodium Absorption Ratio
0.55
Ratio
0.01
0.01
1
01/11/22 01:23
CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
L Limit Exceeded
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-004-0034
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 01/04/2022 10:25:43
Page 8 of 9

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Page 9 of 9

South 1 /3/2022
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
897
139.932
23 6.084
Calcium
20400
3182.4
20 159.12
Magnesium
6040
942.24
12 78.52
Percent Solids
15.6
SAR
0.56
SAR =
Na+
a (Ca2+ + M;42+ )
6.08400
0.5( 159.12 2 + 78.52000 2 )

Waypointo
ANALYTICAL
3/9/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-061-0009
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 3/2/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-061-0009
Page 2 of 8

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-061-0009
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
99705 South Durham Solids 03/01/2022 09:30 03/02/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-061-0009
Date: 3/9/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 85689 (WRC-Eco Gro (March))
Analyte: Aluminum
QC Batch No: 1-603764/1-603023
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 85689 (WRC-Eco Gro (March))
Analyte: Iron
QC Batch No: 1-603764/1-603023
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 85689 (WRC-Eco Gro (March))
Analyte: Phosphorus
QC Batch No: 1-603764/1-603023
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 03/09/2022
nReceived : 03/02/2022
C-�*�-� =
Connie Cook
Report Number : 22-061-0009
REPORT OFANALYSIS
Project
Manager
Lab No : 99705
Matrix:
Solids
Sample ID : South Durham
Sampled:
3/1/2022
9:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Neutralizing Value (%CCE)
7.2
%
0.1
1
03/07/22 09:15
DXT
AOAC 955.01
Moisture
87.2
%
1
03/07/22 16:11
FMM
SW-DRYWT
Ammonia Nitrogen
9840
mg/Kg -
dry
125
781
1
03/09/22 14:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<39.0
mg/Kg -
dry
39.0
39.0
1
03/08/22 14:36
ZBD
4500NO3F-2011
Organic N
43910
mg/Kg -
dry
1750
1
03/09/22 14:00
CALCULATION
pH
8.2
S.U.
1
03/09/2215:36
DRS
9045D
Total Solids
12.8
%
0.010
0.010
1
03/07/22 16:11
FMM
2540G-2011
Total Volatile Solids
66.8
%
0.010
0.010
1
03/07/22 16:11
FMM
2540G-2011
Total Kjeldahl Nitrogen
53800
mg/Kg -
dry
1750
1
03/09/22 15:54
CLP 4500NORGD-2011
Phosphorus
36400
mg/Kg -
dry
21.6
39.1
1
03/09/22 04:57
TJS
6010D
Aluminum
25400
mg/Kg -
dry
36.1
39.1
1
03/09/22 04:57
TJS
6010D
Arsenic
3.563
mg/Kg -
dry
1.88
3.91
1
03/09/22 04:57
TJS
6010D
Cadmium
0.6913
mg/Kg -
dry
0.156
0.781
1
03/09/22 04:57
TJS
6010D
Calcium
17800
mg/Kg -
dry
302
391
1
03/09/22 04:57
TJS
6010D
Chromium
17.1
mg/Kg -
dry
1.84
1.95
1
03/09/22 04:57
TJS
6010D
Copper
361
mg/Kg -
dry
2.42
3.91
1
03/09/22 04:57
TJS
6010D
Iron
16800
mg/Kg -
dry
66.6
78.1
1
03/09/22 04:57
TJS
6010D
Lead
17.9
mg/Kg -
dry
1.41
2.34
1
03/09/22 04:57
TJS
6010D
Magnesium
5340
mg/Kg -
dry
20.2
39.1
1
03/09/22 04:57
TJS
6010D
Manganese
524
mg/Kg -
dry
2.54
3.91
1
03/09/22 04:57
TJS
6010D
Mercury
0.472
mg/Kg -
dry
0.0517
0.119
1
03/03/22 12:12
JW2
7471A
Molybdenum
15.5
mg/Kg -
dry
1.05
1.95
1
03/09/22 04:57
TJS
6010D
Nickel
16.4
mg/Kg -
dry
0.937
1.95
1
03/09/22 04:57
TJS
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 03/09/2022
755 Yadkinville Rd
Information :
Received : 03/02/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-061-0009
REPORT OFANALYSIS
Project Manager
Lab No : 99705
Matrix: Solids
Sample ID : South Durham
Sampled: 3/1/2022 9:30
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Potassium
2960
mg/Kg - dry
48.3
78.1 1 03/09/22 04:57 TJS 6010D
Selenium
2.913
mg/Kg - dry
2.50
3.91 1 03/09/22 04:57 TJS 6010D
Sodium
672
mg/Kg - dry
102
195 1 03/09/22 04:57 TJS 6010D
Zinc
2590
mg/Kg - dry
6.33
9.77 1 03/09/22 04:57 TJS 6010D
Sulfur
12700
mg/Kg - dry
40.5
78.1 1 03/09/22 04:57 TJS 6010D
Sodium Absorption Ratio
0.40
Ratio
0.01
0.01 1 03/09/22 04:57 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-061-0009
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IMakayla Weaver Date & Time: 03/02/2022 09:28:39
Page 7 of 8

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Page 8 of 8

South 3/1/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
672
86.016
23 3.739826
Calcium
17800
2278.4
20 113.92
Magnesium
5340
683.52
12 56.96
Percent Solids
12.8
SAR
0.40
SAR =
Na+
a (Ca2+ + M;42+ )
3.73983
0.5( 113.92 2 + 56.96000 2 )

Waypointo
ANALYTICAL
5/20/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-132-0037
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 5/12/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-132-0037
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-132-0037
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
90568 South Durham Solids 05/11/2022 10:00 05/12/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-132-0037
Date: 5/19/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 90600 (TB-11-3)
Analyte: Aluminum
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Arsenic
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 90600 (TB-11-3)
Analyte: Calcium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Chromium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Iron
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Potassium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Manganese
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 90600 (TB-11-3)
Analyte: Phosphorus
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Selenium
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 90592 (TB-7-3)
Analyte: Mercury
QC Batch No: 1-616692/1-615833
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 05/20/2022
Received : 05/12/2022
" l.�-
Connie Cook
Report Number : 22-132-0037
REPORT OFANALYSIS
Project
Manager
Lab No : 90568
Matrix:
Solids
Sample ID : South Durham
Sampled:
5/11/2022
10:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Neutralizing Value (%CCE)
10.5
%
0.1
1
05/19/22 14:16
DXT
AOAC 955.01
Moisture
82.0
%
1
05/18/22 16:00
FMM
SW-DRYWT
Ammonia Nitrogen
10600
mg/Kg -
dry
88.9
556
1
05/19/22 14:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
78.9
mg/Kg -
dry
25.3
25.3
1
05/17/22 14:38
ZBD
4500NO3F-2016
Organic N
48890
mg/Kg -
dry
5156
10390
1
05/17/22 17:12
CALCULATION
pH
7.5
S.U.
1
05/19/2215:08
DRS
9045D
Total Solids
18.0
%
0.010
0.010
1
05/18/22 16:00
FMM
2540G-2011
Total Volatile Solids
63.7
%
0.010
0.010
1
05/18/22 16:00
FMM
2540G-2011
Total Kjeldahl Nitrogen
59400
mg/Kg -
dry
10400
10
05/17/22 17:12
CLP 4500NORGD-2011
Phosphorus
34300
mg/Kg -
dry
15.3
27.8
1
05/18/22 18:15
TJS
6010D
Aluminum
26100
mg/Kg -
dry
25.7
27.8
1
05/18/22 18:15
TJS
6010D
Arsenic
3.74
mg/Kg -
dry
1.33
2.78
1
05/18/22 18:15
TJS
6010D
Cadmium
0.683
mg/Kg -
dry
0.111
0.556
1
05/18/22 18:15
TJS
6010D
Calcium
19000
mg/Kg -
dry
215
278
1
05/18/22 18:15
TJS
6010D
Chromium
19.3
mg/Kg -
dry
1.31
1.39
1
05/18/22 18:15
TJS
6010D
Copper
366
mg/Kg -
dry
1.72
2.78
1
05/18/22 18:15
TJS
6010D
Iron
17600
mg/Kg -
dry
47.3
55.6
1
05/18/22 18:15
TJS
6010D
Lead
15.7
mg/Kg -
dry
1.00
1.67
1
05/18/22 18:15
TJS
6010D
Magnesium
5070
mg/Kg -
dry
14.3
27.8
1
05/18/22 18:15
TJS
6010D
Manganese
583
mg/Kg -
dry
1.81
2.78
1
05/18/22 18:15
TJS
6010D
Mercury
0.2573
mg/Kg -
dry
0.0339
0.778
1
05/17/22 12:21
JTR
7471A
Molybdenum
15.1
mg/Kg -
dry
0.750
1.39
1
05/18/22 18:15
TJS
6010D
Nickel
15.9
mg/Kg -
dry
0.666
1.39
1
05/18/22 18:15
TJS
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 6 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 05/20/2022
755 Yadkinville Rd
Information :
Received : 05/12/2022
Mocksville , NC 27028
n
Connie Cook
Report Number : 22-132-0037
REPORT OFANALYSIS
Project Manager
Lab No : 90568
Matrix: Solids
Sample ID : South Durham
Sampled: 5/11/2022 10:00
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Potassium
3260
mg/Kg - dry
34.3
55.6 1 05/18/22 18:15 TJS 6010D
Selenium
4.07
mg/Kg - dry
1.78
2.78 1 05/18/22 18:15 TJS 6010D
Sodium
817
mg/Kg - dry
72.2
139 1 05/18/22 18:15 TJS 6010D
Zinc
2520
mg/Kg - dry
4.50
6.94 1 05/18/22 18:15 TJS 6010D
Sulfur
12400
mg/Kg - dry
28.8
55.6 1 05/18/22 18:15 TJS 6010D
Sodium Absorption Ratio
0.57
Ratio
0.01
0.01 1 05/18/22 18:15 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-132-0037
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 05/12/2022 09:51:50
Page 8 of 9

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Page 9 of 9

South 5/11/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 817 147.06 23 6.393913
Calcium 19000 3420 20 171
Magnesium 5070 912.6 12 76.05
Percent Solids 18
SAR 0.58
SAR =
Na+
a (Ca2+ + M;42+ )
6.39391
0.5( 171 2 + 76.05000 2 )

Waypointo
ANALYTICAL
7/25/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-193-0012
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 7/12/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-193-0012
Page 2 of 8

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-193-0012
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97765 South Durham Solids 07/08/2022 08:00 07/12/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-193-0012
Date: 7/25/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 97768 (Brown WTP)
Analyte: Iron
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Manganese
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Selenium
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97765 (South Durham)
Analyte: Mercury
QC Batch No: 1-627730/1-627536
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 97766 (Shelby WTP)
Analyte: Mercury
QC Batch No: 1-627730/1-627536
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Page 4 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 07/25/2022
Received : 07/12/2022
" l.�-
Connie Cook
Report Number : 22-193-0012
REPORT OFANALYSIS
Project
Manager
Lab No : 97765
Matrix:
Solids
Sample ID : South Durham
Sampled:
7/8/2022
8:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
87.0
%
1
07/12/22 15:45
FMM
SW-DRYWT
Ammonia Nitrogen
12500
mg/Kg -
dry
123
769
1
07/25/22 07:37
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
41.0
mg/Kg -
dry
32.3
32.3
1
07/19/22 14:57
ZBD
4500NO3F-2016
Organic N
38620
mg/Kg -
dry
1300
2623
1
07/18/22 14:04
CALCULATION
pH
8.0
S.U.
1
07/18/2215:04
DRS
9045D
Total Solids
13.0
%
0.010
0.010
1
07/12/22 15:45
FMM
2540G-2011
Total Volatile Solids
66.5
%
0.010
0.010
1
07/12/22 15:45
FMM
2540G-2011
Total Kjeldahl Nitrogen
51200
mg/Kg -
dry
2620
1
07/18/22 14:04
CLP 4500NORGD-2011
Phosphorus
39900
mg/Kg -
dry
21.2
38.5
1
07/18/22 20:21
EAL
6010D
Aluminum
33200
mg/Kg -
dry
35.5
38.5
1
07/18/22 20:21
EAL
6010D
Arsenic
6.96
mg/Kg -
dry
1.85
3.85
1
07/18/22 20:21
EAL
6010D
Cadmium
0.969
mg/Kg -
dry
0.154
0.769
1
07/18/22 20:21
EAL
6010D
Calcium
20500
mg/Kg -
dry
298
385
1
07/18/22 20:21
EAL
6010D
Chromium
20.1
mg/Kg -
dry
1.82
1.92
1
07/18/22 20:21
EAL
6010D
Copper
441
mg/Kg -
dry
2.38
3.85
1
07/18/22 20:21
EAL
6010D
Iron
18700
mg/Kg -
dry
65.5
76.9
1
07/18/22 20:21
EAL
6010D
Lead
17.9
mg/Kg -
dry
1.38
2.31
1
07/18/22 20:21
EAL
6010D
Magnesium
5790
mg/Kg -
dry
19.8
38.5
1
07/18/22 20:21
EAL
6010D
Manganese
668
mg/Kg -
dry
2.50
3.85
1
07/18/22 20:21
EAL
6010D
Mercury
0.628 JB
mg/Kg -
dry
0.0479
1.10
1
07/20/22 11:12
JTR
7471A
Molybdenum
23.7
mg/Kg -
dry
1.04
1.92
1
07/18/22 20:21
EAL
6010D
Nickel
16.5
mg/Kg -
dry
0.923
1.92
1
07/18/22 20:21
EAL
6010D
Potassium
3310
mg/Kg -
dry
47.5
76.9
1
07/20/22 18:15
TJS
6010D
Qualifiers/ B
Analyte detected in blank
DF
Dilution Factor
Definitions J
Estimated value
MQL
Method Quantitation Limit
Page 5 of 8

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 07/25/2022
755 Yadkinville Rd
Information :
Received : 07/12/2022
Mocksville , NC 27028
n
Connie Cook
Report Number : 22-193-0012
REPORT OFANALYSIS
Project Manager
Lab No : 97765
Matrix: Solids
Sample ID : South Durham
Sampled: 7/8/2022 8:00
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
5.76
mg/Kg - dry
2.46
3.85 1 07/18/22 20:21 EAL 6010D
Sodium
954
mg/Kg - dry
100
192 1 07/18/22 20:21 EAL 6010D
Zinc
2820
mg/Kg - dry
6.23
9.62 1 07/18/22 20:21 EAL 6010D
Sulfur
13400
mg/Kg - dry
39.8
76.9 1 07/18/22 20:21 EAL 6010D
Sodium Absorption Ratio
0.54
Ratio
0.01
0.01 1 07/18/22 20:21 CALCULATION
Qualifiers/ B Analyte detected in blank
Definitions
DF Dilution Factor
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-193-0012
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 07/12/2022 09:36:17
Page 7 of 8

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Page 8 of 8

South 7/8/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 954 124.02 23 5.392174
Calcium 20500 2665 20 133.25
Magnesium 5790 752.7 12 62.725
Percent Solids 13
SAR 0.54
SAR =
Na+
a (Ca2+ + M;42+ )
5.39217
0.5( 133.25 2 + 62.72500 2 )

Waypointo
ANALYTICAL
10/13/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-277-0023
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 10/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-277-0023
Page 2 of 8

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-277-0023
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
92506 South Durham Solids 10/03/2022 11:45 10/04/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-277-0023
Date: 10/12/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 97015 (Bolster)
Analyte: Potassium
QC Batch No: 1-641846/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Magnesium
QC Batch No: 1-642077/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Manganese
QC Batch No: 1-641846/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Sodium
QC Batch No: 1-641846/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Sulfur
QC Batch No: 1-642077/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Zinc
QC Batch No: 1-642350/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 89992 (September Monthly Comp)
Analyte: Mercury
QC Batch No: 1-641708/1-641289
The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control
acceptance ranges. Matrix interference is suspected
Page 4 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 10/13/2022
nReceived : 10/04/2022
C-�*�-� =
Connie Cook
Report Number : 22-277-0023
REPORT OFANALYSIS
Project
Manager
Lab No : 92506
Matrix:
Solids
Sample ID : South Durham
Sampled:
10/3/2022
11:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
84.2
%
1
10/07/22 15:44
FMM
SW-DRYWT
Ammonia Nitrogen
9810
mg/Kg -
dry
101
633
1
10/12/22 15:20
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
1690
mg/Kg -
dry
31.5
31.5
1
10/08/22 11:28
ZBD
4500NO3F-2016
Organic N
41080
mg/Kg -
dry
1329
2677
1
10/06/22 14:58
CALCULATION
pH
7.7
S.U.
1
10/11/2216:00
SAR
9045D
Total Solids
15.8
%
0.010
0.010
1
10/07/22 15:44
FMM
2540G-2011
Total Volatile Solids
63.3
%
0.010
0.010
1
10/07/22 15:44
FMM
2540G-2011
Total Kjeldahl Nitrogen
50900
mg/Kg -
dry
2680
1
10/06/22 14:58
ANH 4500NORGD-2011
Phosphorus
40800
mg/Kg -
dry
17.5
31.6
1
10/07/22 00:20
JTR
6010D
Aluminum
34400
mg/Kg -
dry
29.2
31.6
1
10/07/22 00:20
JTR
6010D
Arsenic
4.92
mg/Kg -
dry
1.52
3.16
1
10/07/22 00:20
JTR
6010D
Cadmium
0.848
mg/Kg -
dry
0.127
0.633
1
10/07/22 00:20
JTR
6010D
Calcium
20400
mg/Kg -
dry
245
316
1
10/07/22 00:20
JTR
6010D
Chromium
21.8
mg/Kg -
dry
1.49
1.58
1
10/07/22 00:20
JTR
6010D
Copper
465
mg/Kg -
dry
1.96
3.16
1
10/07/22 00:20
JTR
6010D
Iron
18400
mg/Kg -
dry
53.9
63.3
1
10/07/22 00:20
JTR
6010D
Lead
18.3
mg/Kg -
dry
1.14
1.90
1
10/07/22 00:20
JTR
6010D
Magnesium
6030
mg/Kg -
dry
16.3
31.6
1
10/07/22 00:20
EAL
6010D
Manganese
603
mg/Kg -
dry
2.06
3.16
1
10/07/22 00:20
JTR
6010D
Mercury
0.3803
mg/Kg -
dry
0.0408
0.937
1
10/06/22 13:21
TJS
7471A
Molybdenum
21.8
mg/Kg -
dry
0.854
1.58
1
10/07/22 00:20
JTR
6010D
Nickel
18.4
mg/Kg -
dry
0.759
1.58
1
10/07/22 00:20
JTR
6010D
Potassium
3170
mg/Kg -
dry
39.1
63.3
1
10/07/22 00:20
JTR
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 10/13/2022
755 Yadkinville Rd
Information :
Received : 10/04/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-277-0023
REPORT OFANALYSIS
Project Manager
Lab No : 92506
Matrix: Solids
Sample ID : South Durham
Sampled: 10/3/2022 11:45
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
6.65
mg/Kg - dry
2.03
3.16 1 10/07/22 00:20 JTR 6010D
Sodium
968
mg/Kg - dry
82.3
158 1 10/07/22 00:20 JTR 6010D
Zinc
3050
mg/Kg - dry
5.13
7.91 1 10/07/22 00:20 JTR 6010D
Sulfur
14600
mg/Kg - dry
32.8
63.3 1 10/07/22 23:37 TJS 6010D
Sodium Absorption Ratio
0.60
Ratio
0.01
0.01 1 10/07/22 00:20 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-277-0023
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IMakayla Weaver Date & Time: 10/04/2022 09:26:32
Page 7 of 8

0
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Page 8 of 8

South 10/3/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 968 152.944 23 6.649739
Calcium 20400 3223.2 20 161.16
Magnesium 6030 952.74 12 79.395
Percent Solids 15.8
SAR 0.61
SAR — Na
2 (Ca2+ + Mg2- )
6.64974
0.5( 161.16 2 + 79.39500 2 )

Waypointo
ANALYTICAL
11 /16/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-313-0012
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 11/9/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-313-0012
Page 2 of 8

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-313-0012
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
88406 South Durham Solids 11/08/2022 08:45 11/09/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-313-0012
Date: 11 /16/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 88406 (South Durham)
Analyte: Calcium
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88406 (South Durham)
Analyte: Iron
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88406 (South Durham)
Analyte: Phosphorus
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88406 (South Durham)
Analyte: Sulfur
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88406 (South Durham)
Analyte: Zinc
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 11/16/2022
nReceived : 11/09/2022
C-�*�-� =
Connie Cook
Report Number : 22-313-0012
REPORT OFANALYSIS
Project
Manager
Lab No : 88406
Matrix:
Solids
Sample ID : South Durham
Sampled:
11/8/2022
8:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
83.7
%
1
11/10/22 16:03
FMM
SW-DRYWT
Ammonia Nitrogen
6500
mg/Kg -
dry
98.2
613
1
11/15/22 13:30
CLP
4500NH3C-2011
Nitrate+Nitrite-N
150
mg/Kg -
dry
30.4
30.4
1
11/11/22 10:39
ZBD
4500NO3F-2016
Organic N
47180
mg/Kg -
dry
779.1
1571
1
11/15/22 09:09
DH
CALCULATION
pH
6.7
S.U.
1
11/16/2216:36
DRS
9045D
Total Solids
16.3
%
0.010
0.010
1
11/10/22 16:03
FMM
2540G-2011
Total Volatile Solids
68.0
%
0.010
0.010
1
11/10/22 16:03
FMM
2540G-2011
Total Kjeldahl Nitrogen
53700
mg/Kg -
dry
1570
1
11/15/22 09:09
ANH 4500NORGD-2011
Phosphorus
39500
mg/Kg -
dry
16.9
30.7
1
11/10/22 21:39
JTR
6010D
Aluminum
31300
mg/Kg -
dry
28.3
30.7
1
11/10/22 21:39
JTR
6010D
Arsenic
4.29
mg/Kg -
dry
1.47
3.07
1
11/11/22 13:33
TJS
6010D
Cadmium
0.816
mg/Kg -
dry
0.123
0.613
1
11/10/22 21:39
JTR
6010D
Calcium
22300
mg/Kg -
dry
237
307
1
11/10/22 21:39
JTR
6010D
Chromium
19.9
mg/Kg -
dry
1.45
1.53
1
11/10/22 21:39
JTR
6010D
Copper
484
mg/Kg -
dry
1.90
3.07
1
11/10/22 21:39
JTR
6010D
Iron
15300
mg/Kg -
dry
52.3
61.3
1
11/10/22 21:39
JTR
6010D
Lead
15.5
mg/Kg -
dry
1.10
1.84
1
11/10/22 21:39
JTR
6010D
Magnesium
6260
mg/Kg -
dry
15.8
30.7
1
11/10/22 21:39
JTR
6010D
Manganese
530
mg/Kg -
dry
1.99
3.07
1
11/10/22 21:39
JTR
6010D
Mercury
0.7123
mg/Kg -
dry
0.0366
0.840
1
11/11/22 12:03
JTR
7471A
Molybdenum
23.9
mg/Kg -
dry
0.828
1.53
1
11/10/22 21:39
JTR
6010D
Nickel
19.2
mg/Kg -
dry
0.736
1.53
1
11/10/22 21:39
JTR
6010D
Potassium
3100
mg/Kg -
dry
37.9
61.3
1
11/10/22 21:39
JTR
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 11/16/2022
755 Yadkinville Rd
Information :
Received : 11/09/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-313-0012
REPORT OFANALYSIS
Project Manager
Lab No : 88406
Matrix: Solids
Sample ID : South Durham
Sampled: 11/8/2022 8:45
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
6.20
mg/Kg - dry
1.96
3.07 1 11/10/22 21:39 JTR 6010D
Sodium
926
mg/Kg - dry
79.8
153 1 11/10/22 21:39 JTR 6010D
Zinc
3090
mg/Kg - dry
4.97
7.67 1 11/10/22 21:39 JTR 6010D
Sulfur
15200
mg/Kg - dry
31.8
61.3 1 11/10/22 21:39 JTR 6010D
Sodium Absorption Ratio
0.56
Ratio
0.01
0.01 1 11/10/22 21:39 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-313-0012
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 11/09/2022 09:33:58
Page 7 of 8

Ll
-0
c
a-
N
a
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Page 8 of 8

South 11 /8/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 926 150.938 23 6.562522
Calcium 22300 3634.9 20 181.745
Magnesium 6260 1020.38 12 85.03167
Percent Solids 16.3
SAR 0.57
SAR — Na
2 (Ca2+ + Mg2- )
6.56252
0.5( 181.75 2 + 85.03167 2 )

13
ace Analytical ' ANALYTICAL REPORT
March 12, 2022
EMA Resources
Sample Delivery Group: L146285O
Samples Received: 02/17/2022
Project Number:
Description: Sludge
Report To: Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By: z � ��
Cassandra Foster
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy ofthe information provided,
and as the samples are received.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462350 03/12/22 11:41 1 of34

TABLE OF CONTENTS
Cp: Cover Page
u
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
Fss]
SOUTH DURHAM L1462850-01
5
Fn
Qc: Quality Control Summary
7
Wet Chemistry by Method 9012 B
7
Fr
Wet Chemistry by Method 9045D
8
Wet Chemistry by Method D93/1010A
9
Rc
Mercury by Method 7470A
10
F
Metals (ICP) by Method 6010D
11
Volatile Organic Compounds (GC/MS) by Method 8260D
12
[Al
Chlorinated Acid Herbicides (GC) by Method 8151A
14
Pesticides (GC) by Method 8081B
15
RC
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
16
GI: Glossary of Terms
18
Al: Accreditations & Locations
19
Sc: Sample Chain of Custody
20
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:
EMA Resources L1462350
03/12/22 11:41
2 of34

SOUTH DURHAM L1462850-01 Waste
Method
Preparation by Method 1311
Preparation by Method 1311
Wet Chemistry by Method 9012 B
Wet Chemistry by Method 9045D
Wet Chemistry by Method D93/1010A
Mercury by Method 7470A
Metals (ICP) by Method 6010D
Volatile Organic Compounds (GC/MS) by Method 8260D
Chlorinated Acid Herbicides (GC) by Method 8151A
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Subcontracted Analyses
SAMPLE SUMMARY
Collected by
Brent Collins
Batch
WG1821607
WG1822926
WG1821197
WG1819608
WG1822168
WG1823213
WG1823233
WG1824477
WG1825661
WG1821893
WG1828339
WG1828339
WG1822578
Collected date/time Received date/time
02/16/22 09:30 02/17/22 09:30 C
P
Dilution Preparation
Analysis
date/time
date/time
1 02/22/221134
02/22/221134
1 02/24/2210:16
02/24/2210:16
1 02/21/22 2138
02/22/2213:30
1 02/19/22 09:00
02/19/2213:00
1 02/23/22 0100
02/23/22 0100
1 02/24/2212:32
02/25/2212:41
1 02/24/2213:28
02/24/22 2122
1 02/27/2217:21
02/27/22 1721
1 03/02/22 08:02
03/02/2218:27
1 02/25/22 06:54
02/27/22 03:18
1 03/09/22 23:30
03/10/2218:40
1 03/09/22 23:30
03/11/2213:23
1 02/25/22 00:00
02/25/22 00:00
Analyst
JWS
JWS
LDT
GI
WOS
ABL
CCE
BMB
CCW
AMM
JNJ
LEA
ANF
Location
FC
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fn
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fr
Mt. Juliet, TN
Mt. Juliet, TN
Rc
Mt. Juliet, TN
Mt. Juliet, TN
Subcontract
,
F
RC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462350 03/12/22 11:41 3 of34

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the FP
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data. 0
Fr
FQ-cl
GI
Cassandra Foster
Project Manager
RC
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
L1462350 -01 contains subout data that is included after the chain of custody.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462350 03/12/22 11:41 4 of 34

SAMPLE RESULTS - 01
L1462850
SOUTH DURHAM
Collected date/time: 02/16/22 09:30
Preparation by Method 1311
Result Qualifier Prep
Batch
Analyte
date / time
TCLP Extraction
2/22/20221134:34AM
WG1821607
TCLP ZHE Extraction
- 2/24/202210:16:52 AM
WG1822926
Fluid
1 2/22/20221134:34AM
WG1821607
Initial pH
8.27 2/22/20221134:34AM
WG1821607
Final pH
5.28 2/22/20221134:34AM
WG1821607
Wet Chemistry by Method 9012 B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reactive Cyanide 0.424 J3 J6 0.250
Wet Chemistry by Method 9045D
Dilution Analysis Batch
date / time
1 02/22/202213:30 WG1821197
Result Qualifier
Dilution Analysis
Batch
Analyte su
date / time
Corrosivity by pH 7.97 T8
1 02/19/2022 13:00
WG1819608
Sample Narrative:
L1462850-01 WG1819608: 7.97 at19.4C
Wet Chemistry by Method D93/1010A
Result Qualifier
Dilution Analysis
Batch
Analyte Deg. F
date / time
Ignitability DNI at170
1 02/23/2022 0100
WG1822168
Mercury by Method 7470A
Result
Analyte mg/I
Mercury ND
Metals (ICP) by Method 6010D
Qualifier RDL Limit Dilution Analysis Batch
mg/I mg/I date / time
0.0100 0.20 1 02/25/202212:41 WG1823213
Result
Qualifier RDL
Limit
Analyte
mg/I
mg/I
mg/I
Arsenic
ND
0.100
5
Barium
ND
0.100
100
Cadmium
ND
0.100
1
Chromium
ND
0.100
5
Lead
ND
0.100
5
Selenium
ND
0.100
1
Silver
ND
0.100
5
Volatile Organic Compounds (GC/MS) by Method 8260D
Dilution Analysis Batch
date / time
02/24/2022
2122
WG1823233
02/24/2022
2122
WG1823233
02/24/2022
2122
WG1823233
02/24/2022
2122
WG1823233
02/24/2022
2122
WG1823233
02/24/2022
2122
WG1823233
02/24/2022
2122
WG1823233
Result
Qualifier RDL
Limit
Dilution Analysis
Analyte
mg/I
mg/I
mg/I
date/time
Benzene
ND
0.0500
0.50
1 02/27/202217:21
Carbon tetrachloride
ND
0.0500
0.50
1 02/27/202217:21
Chlorobenzene
ND
0.0500
100
1 02/27/202217:21
Chloroform
ND
0.250
6
1 02/27/202217:21
1,2-Dichloroethane
ND
0.0500
0.50
1 02/27/202217:21
1,1-Dichloroethene
ND
0.0500
0.70
1 02/27/202217:21
2-Butanone (MEK)
ND
0.500
200
1 02/27/202217:21
Tetrachloroethene
ND
0.0500
0.70
1 02/27/202217:21
Trichloroethene
ND
0.0500
0.50
1 02/27/202217:21
Vinyl chloride
ND
0.0500
0.20
1 02/27/202217:21
ACCOUNT:
PROJECT:
SDG:
EMA Resources
L1462350
Batch
WG1824477
WG1824477
WG1824477
WG1824477
WG1824477
WG1824477
WG1824477
WG1824477
WG1824477
WG1824477
DATE/TIME: PAGE:
03/12/22 11:41 5 of 34

SOUTH DURHAM SAMPLE RESULTS - 01
Collected date/time: 02/16/22 09:30 L1462850
Volatile Organic Compounds (GC/MS) by Method 8260D
Result Qualifier RDL Limit Dilution Analysis
Analyte mg/I mg/I mg/I date/time
(S) Toluene-dH 112 80.0-120 021271202217:21
(S) 4-Bromofluorobenzene 88.9 77.0-126 021271202217:21
(S) 1,2-Dichloroethone-d4 92.3 70.0-130 021271202217:21
Chlorinated Acid Herbicides (GC) by Method 8151A
Batch
WG1824477
WG1824477
WG1824477
Result Qualifier
RDL Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I mg/I
date/time
2,4,5-TP (Silvex) ND
0.00200 1
1 03/02/2022 18:27
WG1825661
2,4-D ND
0.00200 10
1 03/02/202218:27
WG1825661
(S) Z4-Dichlorophenyl Acetic Acid 74.6
14.0-158
031021202218.27
WG1825661
Pesticides (GC) by Method 8081B
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Chlordane
ND
0.00500
0.03
1 02/27/2022 0318
WG1821893
Endrin
ND
0.00500
0.02
1 02/27/2022 0318
WG1821893
Heptachlor
ND
0.00500
0.0080
1 02/27/2022 0318
WG1821893
Heptachlor epoxide
ND
0.00500
0.0080
1 02/27/2022 0318
WG1821893
Lindane
ND
0.00500
0.40
1 02/27/2022 0318
WG1821893
Methoxychlor
ND
0.00500
10
1 02/27/2022 0318
WG1821893
Toxaphene
ND
0.0100
0.50
1 02/27/2022 0318
WG1821893
(S) Decochlorobiphenyl
31.9
10.0-128
0212712022 03.18
WG1821893
(S) Tetrochloro-m-xylene
42.3
10.0-127
0212712022 03.18
WG1821893
Semi Volatile Organic Compounds
(GC/MS) by Method 8270E
Analyte
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachloroethane
Nitrobenzene
Pyridine
3&4-Methyl Phenol
2-Methylphenol
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
(S) 2-Fluorophenol
(S) 2-Fluorophenol
(S) Phenol-d5
(S) Phenol-d5
(S) Nitrobenzene-d5
(S) Nitrobenzene-d5
(S) 2-Fluorobiphenyl
(S) 2-Fluorobiphenyl
(S) Z4, 6-Tribromophenol
(S) Z4, 6-Tribromophenol
(S) p-Terphenyl-d14
(S) p-Terphenyl-d14
ACCOUNT:
EMA Resources
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
mg/I
mg/I
mg/I
date/time
ND
0.100
7.50
1 03/10/202218:40
WG1828339
ND
0.100
0.13
1 03/10/202218:40
WG1828339
ND
0.100
0.13
1 03/10/202218:40
WG1828339
ND
0.100
0.50
1 03/10/202218:40
WG1828339
ND
0.100
3
1 03/10/202218:40
WG1828339
ND
0.100
2
1 03/10/202218:40
WG1828339
ND
0.100
5
1 03/11/202213:23
WG1828339
ND
0.100
400
1 03/10/202218:40
WG1828339
ND
0.100
200
1 03/10/202218:40
WG1828339
ND
0.100
100
1 03/10/202218:40
WG1828339
ND
0.100
400
1 03/10/202218:40
WG1828339
ND
0.100
2
1 03/10/202218:40
WG1828339
39.1
10.0-120
031101202218.40
WG1828339
37.7
10.0-120
031111202213.23
WG1828339
25.1
10.0-120
031101202218.40
WG1828339
22.6
10.0-120
031111202213.23
WG1828339
64.6
10.0-127
031111202213.23
WG1828339
67.5
10.0-127
031101202218.40
WG1828339
59.3
10.0-130
031101202218.40
WG1828339
59.6
10.0-130
031111202213.23
WG1828339
82.0
10.0-155
031111202213.23
WG1828339
78.5
10.0-155
031101202218.40
WG1828339
78.1
10.0-128
031111202213.23
WG1828339
80.2
10.0-128
031101202218.40
WG1828339
PROJECT:
SDG:
DATE/TIME: PAGE:
L1462350
03/12/22 11:41 6 of34

WG1821197
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3762532-1 02/22/22 1322
MB Result
Analyte mg/kg
Reactive Cyanide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.0390 0.250
L1462850-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1462850-01
(OS) L1462350-01 02/22/22 13:30 • (DUP) R3762532-3 02/22/22 13:31
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide 0.424 0.437 1 3.02 20
L1462872-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1462372-01 02/22/22 13:36 • (DUP) R3762532-6 02/22/22 13:37
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide 0.638 0.583 1 8.98 20
Laboratory Control Sample (LCS)
(LCS) R3762532-2 02/22/22 1323
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Cyanide 2.50 2.52 101
Rec. Limits LCS Qualifier
85.0-115
L1462850-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462350-01 02/22/22 13:30 • (MS) R3762532-4 02/22/22 13:34 • (MSD) R3762532-5 02/22/22 13:35
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec.
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 0.424 0.595 0.438 10.2 0.855
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 75.0-125 J6 J3 J6 30.3 20
L1462970-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462970-01 02/22/22 13:33 • (MS) R3762532-7 02/22/22 13:39 • (MSD) R3762532-8 02/22/22 13:40
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 ND 1.00 1.11 60.0 66.8 1 75.0-125 J6 J6 10.7 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462350 03/12/22 11:41 7 of 34

WG1819608 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9045D L1462850-01
L1462467-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1462467-02 02/19/22 13:00 • (DUP) R3761702-2 02/19/22 13:00
Original Result DUP Result Dilution DUP RPD
Analyte su su
Corrosivity by pH 7.63 7.63 1 0.000
Sample Narrative:
OS: 7.63 at19C
DUP 7.63 at19C
Laboratory Control Sample (LCS)
DUP Qualifier DUP RPD
Limits
(LCS) R3761702-1 02/19/22 13:00
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte su su
Corrosivity by pH 10.0 9.95 99.5 99.0-101
Sample Narrative:
LCS: 9.95 at18.6C
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462350 03/12/22 11:41 3 of 34

WG1822168 QUALITY CONTROL SUMMARY
Wet Chemistry by Method D93/1010A L1462850-01
L1463550-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1463550-01 02/23/22 01:00 • (DUP) R3763170-3 02/23/22 0100
Original Result DUP Result Dilution DUP RPD
Analyte Deg. F Deg. F
Ignitability 155 160 1 3.18
DUP Qualifier DUP RPD
Limits
i
10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3763170-1 02/23/22 01:00 • (LCSD) R3763170-2 02/23/22 0100
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte Deg. F Deg. F Deg. F
Ignitability 126 122 126 96.6 99.7 95.6-104 3.23 10
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462850 03/12/22 11:41 9 of 34

WG1823213 QUALITY CONTROL SUMMARY
Mercury by Method 7470A L1462850-01
Method Blank (MB)
(MB) R3763333-1 02/25/22 12:26
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/I mg/I mg/I
Mercury U 0.00330 0.0100
Laboratory Control Sample (LCS)
(LCS) R3763883-2 02/25/22 12:27
Spike Amount LCS Result LCS Rec.
Analyte mg/I mg/I
Mercury 0.0300 0.0330 110
Rec. Limits LCS Qualifier
80.0-120
L1462462-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462462-06 02/25/22 12:29 • (MS) R3763333-3 02/25/22 12:35 • (MSD) R3763333-4 02/25/22 12:37
Spike Amount
Original Result
MS Result
MSD Result MS Rec. MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Mercury 0.0300
ND
0.0328
0.0322 109 107
1 75.0-125
1.82 20
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
EMA Resources
L1462350
03/12/22 11:41 10 of 34

WG1823233
Metals (ICP) by Method 6010D
Method Blank (MB)
(MB) R3763667-1 02/24/22 20:59
MB Result
MB Qualifier MB MDL
MB RDL
Analyte mg/I
mg/I
mg/I
Arsenic U
0.0333
0.100
Barium U
0.0333
0.100
Cadmium U
0.0333
0.100
Chromium U
0.0333
0.100
Lead U
0.0333
0.100
Selenium U
0.0333
0.100
Silver U
0.0333
0.100
Laboratory Control Sample (LCS)
(LCS) R3763667-2 02/24/22 2102
QUALITY CONTROL SUMMARY
L1462850-01
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
Analyte
mg/I
mg/I
Arsenic
10.0
9.70
97.0
80.0-120
Barium
10.0
9.90
99.0
80.0-120
Cadmium
10.0
9.81
98.1
80.0-120
Chromium
10.0
9.57
95.7
80.0-120
Lead
10.0
9.75
97.5
80.0-120
Selenium
10.0
10.2
102
80.0-120
Silver
2.00
1.76
88.2
80.0-120
LCS Qualifier
L1462431-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462431-01 02/24/22 21:05 • (MS) R3763667-4 02/24/22 21:10 • (MSD) R3763667-5 02/24/22 2113
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Arsenic
10.0
ND
9.65
9.74
96.5
97.4
Barium
10.0
0.210
10.1
10.1
98.6
99.0
Cadmium
10.0
ND
9.77
9.82
97.7
98.2
Chromium
10.0
ND
9.58
9.57
95.8
95.7
Lead
10.0
ND
9.82
9.78
98.2
97.8
Selenium
10.0
ND
10.1
10.1
101
101
Silver
2.00
ND
1.76
1.78
87.8
88.8
Dilution Rec. Limits
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
MS Qualifier MSD Qualifier RPD
0.908
0.399
0.458
0.155
0.341
0.503
1.16
RPD Limits
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG:
EMA Resources L1462350
DATE/TIME:
03/12/22 11:41
PAGE:
11 of 34

WG1824477 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1462850-01
Method Blank (MB)
(MB) R3764355-3 02/27/22 13:43
MB Result
Analyte
mg/I
Benzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chloroform
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
2-Butanone (MEK)
U
Tetrachloroethene
U
Trichloroethene
U
Vinyl chloride
U
(S) Toluene-dH
115
(S) 4-Bromofluorobenzene 91.4
(S) 1,2-Dichloroethane-d4 90.5
MB Qualifier MB MDL
mg/I
MB RDL
mg/I
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
0.0833
0.250
0.0167
0.0500
0.0167
0.0500
0.167
0.500
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
80.0-120
77.0-126
70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3764355-1 02/27/22 10:38 • (LCSD) R3764355-2 02/27/22 12:39
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
Analyte
mg/I
mg/I
mg/I
Benzene
0.250
0.251
0.275
100
110
70.0-123
Carbon tetrachloride
0.250
0.229
0.222
91.6
88.8
68.0-126
Chlorobenzene
0.250
0.260
0.294
104
118
80.0-121
Chloroform
0.250
0.253
0.274
101
110
73.0-120
1,2-Dichloroethane
0.250
0.248
0.274
99.2
110
70.0-128
1,1-Dichloroethene
0.250
0.249
0.258
99.6
103
71.0-124
2-Butanone (MEK)
1.25
1.09
1.21
87.2
96.8
44.0-160
Tetrachloroethene
0.250
0.265
0.266
106
106
72.0-132
Trichloroethene
0.250
0.245
0.261
98.0
104
78.0-124
Vinyl chloride
0.250
0.289
0.291
116
116
67.0-131
(S) Toluene-dH
112
113
80.0-120
(S) 4-Bromofluorobenzene
91.1
90.5
77.0-126
(S) 1,2-Dichloroethane-d4
94.0
94.0
70.0-130
LCS Qualifier
LCSD Qualifier RPD
9.13
3.10
12.3
7.97
9.96
3.55
10.4
0.377
6.32
0.690
RPD Limits
20
20
20
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462350 03/12/22 11:41 12 of 34

WG1824477 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1462850-01
L1464040-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1464040-04 02/27/22 20:50 • (MS) R3764355-4 02/27/22 21:11 • (MSD) R3764355-5 02/27/22 2132
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Benzene 0.250
ND
0.166
0.168
66.4
67.2
1 17.0-158
1.20
27
Carbon tetrachloride 0.250
ND
0.160
0.168
64.0
67.2
1 23.0-159
4.88
28
Chlorobenzene 0.250
ND
0.219
0.219
87.6
87.6
1 33.0-152
0.000
27
Chloroform 0.250
ND
ND
ND
83.6
84.4
1 29.0-154
0.952
28
1,2-Dichloroethane 0.250
ND
0.201
0.196
80.4
78.4
1 29.0-151
2.52
27
1,1-Dichloroethene 0.250
ND
0.119
0.118
47.6
47.2
1 11.0-160
0.844
29
2-Butanone (MEK) 1.25
ND
1.05
1.12
84.0
89.6
1 10.0-160
6.45
32
Tetrachloroethene 0.250
3.96
3.77
3.56
0.000
0.000
1 10.0-160
V_ V_ 5.73
27
Trichloroethene 0.250
ND
0.170
0.173
68.0
69.2
1 10.0-160
1.75
25
Vinyl chloride 0.250
ND
0.130
0.126
52.0
50.4
1 10.0-160
3.12
27
(S) Toluene-dH
110
110
80.0-120
(S) 4-Bromofluorobenzene
97.6
95.1
77.0-126
(S) 1,2-Dichloroethane-d4
94.6
94.0
70.0-130
L1462927-03 Original Sample
(OS) • Matrix Spike (MS)
(OS) L1462927-03 02/27/22 13:45 • (MS) R3764355-6 02/27/22 2152
Spike Amount
Original Result
MS Result
MS Rec.
Dilution
Rec. Limits
MS Qualifier
Analyte mg/I
mg/I
mg/I
Benzene 0.250
ND
0.169
67.6
1
17.0-158
Carbon tetrachloride 0.250
ND
0.165
66.0
1
23.0-159
Chlorobenzene 0.250
ND
0.218
87.2
1
33.0-152
Chloroform 0.250
ND
ND
84.0
1
29.0-154
1,2-Dichloroethane 0.250
ND
0.199
79.6
1
29.0-151
1,1-Dichloroethene 0.250
ND
0.119
47.6
1
11.0-160
2-Butanone (MEK) 1.25
ND
1.05
84.0
1
10.0-160
Tetrachloroethene 0.250
ND
0.202
80.8
1
10.0-160
Trichloroethene 0.250
ND
0.184
73.6
1
10.0-160
Vinyl chloride 0.250
ND
0.131
52.4
1
10.0-160
(S) Toluene-dH
119
80.0-120
(S) 4-Bromofluorobenzene
97.6
77.0-126
(S) 1,2-Dichloroethane-d4
93.9
70.0-130
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
EMA Resources
L1462350
03/12/22 11:41
13 of 34

WG1825661
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
(MB) R3765374-1 03/02/22 16:58
MB Result
Analyte mg/I
2,4,5-TP (Silvex) U
2,4-D U
(S) Z4-Dichlorophenyl Acetic 70.0
Acid
QUALITY CONTROL SUMMARY
L1462850-01
MB Qualifier MB MDL
MB RDL
mg/I
mg/I
0.000667
0.00200
0.000667
0.00200
14.0-158
Laboratory Control Sample (LCS)
(LCS) R3765874-2 03/02/22 1713
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
2,4,5-TP (Silvex) 0.0500
0.0417
83.4
50.0-125
2,4-D 0.0500
0.0451
90.2
50.0-120
(S) Z4-Dichlorophenyl Acetic
74.0
14. 0-158
Acid
L1463588-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1463533-01 03/02/22 20:24 • (MS) R3765874-3 03/02/22 20:38 • (MSD) R3765874-4 03/02/22 20:53
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
2,4,5-TP (Silvex)
0.0500
ND
0.0416
0.0359
83.2
71.8
2,4-D
0.0500
ND
0.0401
0.0407
80.2
81.4
(S) Z4-Dichlorophenyl Acetic
74.4
74.2
Acid
ACCOUNT:
EMA Resources
PROJECT:
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 50.0-125 14.7 20
1 50.0-120 1.49 20
14.0-158
SDG: DATE/TIME: PAGE:
L1462350 03/12/22 11:41 14 of 34

WG1821893
Pesticides (GC) by Method 8081B
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1462850-01
(MB) R3764434-1 02/27/22 00:26
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Chlordane
U
0.00167
0.00500
Endrin
U
0.00167
0.00500
Heptachlor
U
0.00167
0.00500
Heptachlor epoxide
U
0.00167
0.00500
Gamma BHC
U
0.00167
0.00500
Methoxychlor
U
0.00167
0.00500
Toxaphene
U
0.00333
0.0100
(S) Decachlorobiphenyl
69.9
10.0-128
(S) Tetrochloro-m-xylene
84.7
10.0-127
Laboratory Control Sample (LCS)
(LCS) R3764484-2 02/27/22 00:36
Spike Amount
LCS Result
Analyte
mg/I
mg/I
Endrin
0.0100
0.00897
Heptachlor
0.0100
0.00973
Heptachlor epoxide
0.0100
0.00875
Gamma BHC
0.0100
0.00928
Methoxychlor
0.0100
0.00852
(S) Decachlorobiphenyl
(S) Tetrochloro-m-xylene
LCS Rec. Rec. Limits LCS Qualifier
89.7
97.3
87.5
92.8
85.2
58.7
78.5
57.0-134
27.0-132
57.0-130
55.0-129
54.0-155
10.0-128
10.0-127
L1460315-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1460315-01 02/27/22 00:45 • (MS) R3764484-3 02/27/22 00:55 • (MSD) R3764484-4 02/27/22 0104
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Endrin
0.0100
ND
0.00811
0.00829
81.1
82.9
Heptachlor
0.0100
ND
0.00842
0.00834
84.2
83.4
Heptachlor epoxide
0.0100
ND
0.00769
0.00724
76.9
72.4
Gamma BHC
0.0100
ND
0.00902
0.00838
90.2
83.8
Methoxychlor
0.0100
ND
0.00839
0.00752
83.9
75.2
(S) Decachlorobiphenyl
52.0
48.5
(S) Tetrochloro-m-xylene
66.6
68.2
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
1 10.0-160
2.20
1 16.0-136
0.955
1 10.0-160
6.03
1 14.0-141
7.36
1 10.0-160
P 10.9
10.0-128
10.0-127
RPD Limits
39
40
36
40
34
ACCOUNT:
EMA Resources
PROJECT:
SDG: DATE/TIME:
L1462350 03/12/22 11:41
PAGE:
15 of 34

WG1828339 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1462850-01
Method Blank (MB)
(MB) R3768508-2 03/10/22 1337
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
U
0.0333
0.100
2,4-Dinitrotoluene
U
0.0333
0.100
Hexachlorobenzene
U
0.0333
0.100
Hexachloro-1,3-butadiene
U
0.0333
0.100
Hexachloroethane
U
0.0333
0.100
Nitrobenzene
U
0.0333
0.100
Pyridine
U
0.0333
0.100
3&4-Methyl Phenol
U
0.0333
0.100
2-Methylphenol
U
0.0333
0.100
Pentachlorophenol
U
0.0333
0.100
2,4,5-Trichlorophenol
U
0.0333
0.100
2,4,6-Trichlorophenol
U
0.0333
0.100
(S) 2-Fluorophenol
41.4
10.0-120
(S) Phenol-d5
25.6
10.0-120
(S) Nitrobenzene-d5
68.7
10.0-127
(S) 2-Fluorobiphenyl
70.6
10.0-130
(S) 2,4, 6-Tribromophenol
870
10. 0-155
(S) p-Terphenyl-d14
94.3
10.0-128
Laboratory Control Sample (LCS)
(LCS) R3768508-1 03/10/22 1316
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
1,4-Dichlorobenzene 0.500
0.357
71.4
18.0-120
2,4-Dinitrotoluene 0.500
0.513
103
49.0-124
Hexachlorobenzene 0.500
0.436
87.2
44.0-120
Hexachloro-1,3-butadiene 0.500
0.375
75.0
19.0-120
Hexachloroethane 0.500
0.365
73.0
15.0-120
Nitrobenzene 0.500
0.349
69.8
27.0-120
Pyridine 0.500
0.136
27.2
10.0-120
3&4-Methyl Phenol 0.500
0.333
66.6
31.0-120
2-Methylphenol 0.500
0.336
67.2
28.0-120
Pentachlorophenol 0.500
0.408
81.6
23.0-120
2,4,5-Trichlorophenol 0.500
0.438
87.6
44.0-120
2,4,6-Trichlorophenol 0.500
0.415
83.0
42.0-120
(S) 2-Fluorophenol
47.2
10.0-120
(S) Phenol-d5
29.7
10.0-120
(S) Nitrobenzene-d5
69.2
10.0-127
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1462850 03/12/22 11:41 16 of 34

WG1828339 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1462850-01
Laboratory Control Sample (LCS)
(LCS) R3768508-1 03/10/22 1316
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/I mg/I
(S) 2-Fluorobiphenyl 75.6 10.0-130
(S) 2,4, 6-Tribromophenol 91.5 10. 0-155
(S) p-Terphenyl-d14 91.4 10.0-128
L1462850-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462350-01 03/10/22 18:40 • (MS) R3763503-3 03/10/22 19:02 • (MSD) R3763503-4 03/10/22 19:23
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
Analyte
mg/I
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
0.500
ND
0.352
0.380
70.4
76.0
1 17.0-120
2,4-Dinitrotoluene
0.500
ND
0.500
0.528
100
106
1 39.0-125
Hexachlorobenzene
0.500
ND
0.415
0.445
83.0
89.0
1 35.0-122
HexachIaro-1,3-butadiene
0.500
ND
0.374
0.403
74.8
80.6
1 12.0-120
Hexachloroethane
0.500
ND
0.356
0.381
71.2
76.2
1 10.0-120
Nitrobenzene
0.500
ND
0.332
0.356
66.4
71.2
1 12.0-120
Pyridine
0.500
ND
ND
ND
7.36
16.1
1 10.0-120
3&4-Methyl Phenol
0.500
ND
0.291
0.331
58.2
66.2
1 10.0-120
2-Methylphenol
0.500
ND
0.284
0.320
56.8
64.0
1 10.0-120
Pentachlorophenol
0.500
ND
0.291
0.338
58.2
67.6
1 10.0-128
2,4,5-Trichlorophenol
0.500
ND
0.409
0.441
81.8
88.2
1 33.0-120
2,4,6-Trichlorophenol
0.500
ND
0.399
0.427
79.8
85.4
1 26.0-120
(S) 2-Fluorophenol
40.1
43.6
10.0-120
(S) Phenol-d5
26.1
28.5
10.0-120
(S) Nitrobenzene-d5
66.7
69.0
10.0-127
(S) 2-Fluorobiphenyl
70.0
70.9
10.0-130
(S)2,4,6-Tribromophenol
84.5
91.0
10.0-155
(S) p-Terphenyl-d14
92.8
94.3
10.0-128
MS Qualifier MSD Qualifier RPD RPD Limits
J6 J3
7.65 40
5.45 25
6.98 24
7.46 34
6.78 40
6.98 30
74.3 37
12.9 36
11.9 30
14.9 37
7.53 31
6.78 31
ACCOUNT: PROJECT:
EMA Resources
SDG: DATE/TIME: PAGE:
L1462350 03/12/22 11:41 17 of 34

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
u
Fc
Fss]
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
Fn
RDL
Reported Detection Limit.
Rec.
Recovery.
Fr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
F
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
F
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Rc
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe
samples from the time of collection until delivery to the laboratory for analysis.
This section ofyour report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J3
The associated batch QC was outside the established quality control range for precision.
J6
The sample matrix interfered with the ability to make any accurate determination, spike value is low.
P
RPD between the primary and confirmatory analysis exceeded 40%.
T8
Sample(s) received past/too close to holding time expiration.
v
The sample concentration is too high to evaluate accurate spike recoveries.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1462350 03/12/22 11:41 13 of 34

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
N E-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TNO02
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704 _
Georgia
NELAP
North Carolina 3
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky' 6
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee'"
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas5
LABO152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A2 LA
A2LA— ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A2 LA — ISO 17025 5
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
Rc
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1462350 03/12/22 11:41
PAGE:
19 of 34

urofins
Environment Testing
America
ANALYTICAL REPORT
Eurofins Chicago
2417 Bond Street
University Park, IL 60484
Tel: [phone]
Laboratory Job ID: 500-212791-1
Client Project/Site: WG1822578
For
Pace Analytical National
12065 Lebanon Rd
Mt Juliet, Tennessee 37122
Attn: Jimmy Huckaba
Authorized for release by:
212512022 2:45:32 PM
Jim Knapp, Project Manager II
[phone]
[e-mail]
Designee for
Sandie Fredrick, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for
accredited parameters, exceptions are noted in this report. This report may not be reproduced
except in full, and with written approval from the laboratory. For questions please contact the
Project Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
12
13
14

Client: Pace Analytical National
Project/Site: WG1822578
Laboratory Job ID: 500-212791-1
Table of Contents
Cover Page ..............................................
Table of Contents .........................................
2
Case Narrative ...........................................
3
Detection Summary ........................................
4
Method Summary .........................................
5
Sample Summary .........................................
6
Client Sample Results ......................................
7
Definitions ...............................................
8
QC Association ...........................................
9
QC Sample Results ........................................
10
Chronicle ................................................
11
Certification Summary ......................................
12
Chain of Custody ..........................................
13
Receipt Checklists .........................................
14
12
13
14
Eurofins Chicago
Page 2 of 14 2/25/2022

Case Narrative
Client: Pace Analytical National
Project/Site: WG1822578
Job ID: 500-212791-1
Laboratory: Eurofins Chicago
Narrative
Job Narrative
500-212791-1
Comments
No additional comments.
Job I D: 500-212791-1
Receipt
The sample was received on 2/24/2022 10:00 AM. Unless otherwise noted below, the sample arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 1.20 C.
General Chemistry
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
12
13
14
Eurofins Chicago
Page 3 of 14 2/25/2022

Detection Summary
Client: Pace Analytical National Job ID: 500-212791-1
Project/Site: WG1822578
Client Sample ID: SOUTH DURHAM Lab Sample ID: 500-212791-1
�— No Detections.
This Detection Summary does not include radiochemical test results.
F47
12
13
14
Eurofins Chicago
Page 4 of 14 2/25/2022

Method Summary
Client: Pace Analytical National
Project/Site: WG1822578
Method Method Description
9034 Sulfide, Reactive
7.3.4 Sulfide, Reactive
Protocol References:
Job I D: 500-212791-1
Protocol Laboratory
SW846 TAL CHI
SW846 TAL CHI
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL CHI = Eurofins Chicago, 2417 Bond Street, University Park, IL 60484, TEL [phone]
12
13
14
Eurofins Chicago
Page 5 of 14 2/25/2022

Sample Summary
Client: Pace Analytical National
Project/Site: WG1822578
Lab Sample ID Client Sample ID Matrix Collected Received
500-212791-1 SOUTH DURHAM Solid 02/16/22 09:30 02/24/22 10:00
Job I D: 500-212791-1
12
13
14
Page 6 of 14 Eurofins--J?N2922

Client Sample Results
Client: Pace Analytical National
Project/Site: WG1822578
Job I D: 500-212791-1
Client Sample ID: SOUTH DURHAM Lab Sample ID: 500-212791-1
Date Collected: 02/16/22 09:30 Matrix: Solid
Date Received: 02/24/22 10:00
General Chemistry
Analyte Result Qualifier LOQ LOD Unit D Prepared Analyzed Dil Fac
Sulfide, Reactive <3.9 49.5 3.9 mg/Kg 02/24/22 19:03 02/25/22 11:00 1
12
13
14
Eurofins Chicago
Page 7 of 14 2/25/2022

Definitions/Glossary
Client: Pace Analytical National
Project/Site: WG1822578
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
II Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level'
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRIES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Job I D: 500-212791-1
0
12
13
14
Eurofins Chicago
Page 8 of 14 2/25/2022

QC Association Summary
Client: Pace Analytical National
Project/Site: WG1822578
General Chemistry
Prep Batch: 644394
Job I D: 500-212791-1
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
500-212791-1
SOUTH DURHAM
Total/NA
Solid
7.3.4
MB 500-644394/1-A
Method Blank
Total/NA
Solid
7.3.4
LCS 500-644394/2-A
Lab Control Sample
Total/NA
Solid
7.3.4
Analysis Batch: 644530
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
500-212791-1
SOUTH DURHAM
Total/NA
Solid
9034
644394
MB 500-644394/1-A
Method Blank
Total/NA
Solid
9034
644394
LCS 500-644394/2-A
Lab Control Sample
Total/NA
Solid
9034
644394
12
13
14
Eurofins Chicago
Page 9 of 14 2/25/2022

QC Sample Results
Client: Pace Analytical National
Project/Site: WG1822578
Job I D: 500-212791-1
Method: 9034 - Sulfide, Reactive
Lab Sample ID: MB 500-644394/1-A Client Sample ID: Method Blank
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 644530 Prep Batch: 644394
MB MB
Analyte Result Qualifier LOQ LOD Unit D Prepared Analyzed Dil Fac
Sulfide, Reactive <3.9 50.0 3.9 mg/Kg 02/24/22 18:46 02/25/22 10:49 1
Lab Sample ID: LCS 500-644394/2-A Client Sample ID: Lab Control Sample
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 644530 Prep Batch: 644394
Spike LCS LCS %Rec.
Analyte Added Result Qualifier Unit D %Rec Limits
Sulfide, Reactive 198 162.9 mg/Kg 82 80 -120
12
13
14
Eurofins Chicago
Page 10 of 14 2/25/2022

Lab Chronicle
Client: Pace Analytical National
Project/Site: WG1822578
Job I D: 500-212791-1
Client Sample ID: SOUTH DURHAM Lab Sample ID: 500-212791-1
Date Collected: 02/16/22 09:30 Matrix: Solid
Date Received: 02/24/22 10:00
Batch
Batch
Dilution Batch
Prepared
Prep Type Type
Method
Run Factor Number
or Analyzed Analyst Lab
Total/NA Prep
7.3.4
644394
02/24/22 19:03 TMS TAL CHI
Total/NA Analysis
9034
1 644530
02/25/22 11:00 TMS TAL CHI
Laboratory References:
TAL CHI = Eurofins Chicago, 2417
Bond Street, University
Park, IL 60484, TEL [phone]
11
12
13
14
Eurofins Chicago
Page 11 of 14 2/25/2022

Accreditation/Certification Summary
Client: Pace Analytical National
Project/Site: WG1822578
Laboratory: Eurofins Chicago
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority
Program
California
State
Georgia
State
Georgia (DWW)
State
Hawaii
State
Illinois
NELAP
Indiana
State
Iowa
State
Kansas
NELAP
Kentucky (UST)
State
Kentucky (WWW)
State
Louisiana
NELAP
Mississippi
State
North Carolina (WWW/SW)
State
North Dakota
State
Oklahoma
State
South Carolina
State
USDA
US Federal Programs
Wisconsin
State
Wyoming
State
Job I D: 500-212791-1
Identification Number Expiration Date
2903
04-29-22
N/A
04-29-22
939
04-30-21
NA
04-29-22
IL00035
04-29-22
C-1 L-02
04-29-22
082
05-01-22
E-10161
10-31-22
Al # 108083
04-29-22
KY90023
12-31-22
02046
06-30-22
NA
04-30-22
291
12-31-22
R-194
04-29-22
8908
08-31-22
77001003
04-29-22
P330-18-00018
02-11-24
999580010
08-31-22
8TMS-Q
04-30-22
Accreditation/Certification renewal pending - accreditation/certification considered valid.
Eurofins Chicago
Page 12 of 14 2/25/2022

Sub -Contract Chain of Custody
Batch Date/Time: 02/23/22 13 44
Sub -Contract I ab• iAt jPlI
aceAnalytical
Address: 241.7 Bond Street
City/State: University Park, It
60494
12065 Lebanon Rd
Contact.
500-212791 COC
Mt Juhet,'I"N 37122
Sandra.Fredrick -4t1urofinset com
Phone [phone]
Owner Lab: PACLMTJL
WO. WG1922578
Fax [phone]
Address: 12065 Lebanon Rd
Ltuail: M 1,11 SuboutI earn wpacelabs corn
City/State: Mt Juliet, IN 37122
Results Due Date: 03/09/22
Phone: [phone]
LSC Purchase Order 9: 1, I402850
Fax: [phone]
Send Reports to: James C Huckaba
Sample ID
Container ID
Matrix State Collect Date Description
p
SOUTH DURHAM
SS NC 02/16/22 09 30 Miscellaneous Analysis
�� o�f0)l ti a�
Relinquished by:
Recieved by:
per, Date �j
`�;Date
Relinquished by:
Date
Recieved by:
Date
Sample Number Sample Comments
Lab Use Only Lab Use Only
2 L 1462850-01 Reactive Sulfide
Page 13 of 14 2/25/2022

Client: Pace Analytical National
Login Number: 212791
List Number: 1
Creator: Scott, Sherri L
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
True
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
1.2
Job Number: 500-212791-1
List Source: Eurofins Chicago
12
13
14
Eurofins Chicago
Page 14 of 14 2/25/2022

Company Namc/Addres,
Billing Information:
EMA Resources
Mr. Brent Collins Pres
755 Yadkinville Road Chk
755 Yadkinville Road
Mocksville, NC 27028
Mocksville, NC 27028
Report to:
Email To:
Mr. Brent Collins
[e-mail];roy.whitak
Project Description:
City/State
Collected wf �nC
Please Circle,
PT MT CT ET
Sludge
Client Project It
Lab Project ti
Phone,336-751-1441
Collected by (print):
13r�i all., ,
Collected b signature):
Immediately ✓
Packed on tce N Y
Sample ID
* Matrix:
SS - Soil AIR • Air F - Flltcr
GW - Groundwater B - Bioaccay
WW - WasteWater
DW - Drinking Water
OT - Other
Relinquished by : (Signature)
Relinquished by: (Signature)
Relinquished by : (Signature)
R
ite/Facility ID q
P.D. #
a
a
fl
Z
RuSh? (Lab MUST Be Notified) Quote #
Same Day _ Five Day
U
Next Day 5 Day (Rad Only) Date Results Needed
2=
_ _
Two Day _ 10 Day (Rad Only) No.
U
_
Three Day of
r4
Ln
Comp/Grab
Matrix'
Depth
Date Time
ntrs
U
r
/s
/
SS
3,
1r!0/2z-
n
9r�
2
X
x
rks:
Samples returned via: Tracking #
_ UPS FedEx Coutier
Date: Time. Received by. (Signature)
2I/4, /zz- 3,-.:)a
Date: Time: Received by: (Signature)
Date: ITimei I Received for lab by:
:hain of Custody Page ____ of
aceAnaVical
12065 Lebanan Rd Mount Iohm, TN 37122
Submitting a ample na Eftiit [lsain o1 custodq
on[t4wes acknowledgment and acceptance of the
Pace Terms and t:and,Tio. found v:
hnpc_lrnfo, W [elabs.camlhubfslpas-standard
terms pd1
SDG P
1053
Acctnum: EMARES
Template:T11413
Prelogin: P895426
PM: 807 - Justin Carr
PB: 6 1j1 -1-)-
Shipped via: Fed EX Ground
Re—rks Sample It (lab pnly}
di
Samz)le Receipt
h
pH Temp COC Seal PresentlIntact: p _Y _N
COC Signed/Accurate: _N
Flaw Other Battles arrive intact: /f N
Correct bottles used: —N
Sufficient volume sent: 1l _N
7 ]� If Applicable
L VOA Zero Headspace: _Y N
Trip Blank Received: Yes preservation Correct/Checked: _Y �N
p RAD Screen c0.5 tnR/hr: � _N
HCL 1 MeoH
TBR
Tempe '� Bottles Received: 1 if preservation required by Login: Date/Time
mate: Time; ^ Hold: Cond
7/1 V Z-Z� L '3(ya NCF

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 44.3 Acres Permitted: 44.3 Site #: GR05 Field #:
160.41
VaB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
3.62
Arsenic
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
Cadmium
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Copper
3.107
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.107
Chromium
0.143
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.143
Lead
0.234
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.234
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.232
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.232
denum
Nickel
0.141
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.141
Selenium
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.045
Zinc
21.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
21.002
Total
Phos-
303.440
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
303.440
horus
1
1
1
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,_
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Henry Thorpe Jr.
Operator: Henry Thorpe Jr.
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 160.41 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
146
Crop 2 Name:
Acres Utilized:
GR05 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
44.3
44.3
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/1
687
15.6
2.037
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
61.490
NA
Fescue
2/2
534
15.6
1.584
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
47.795
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1221
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
109.285
o.000
Lime A lied
Annuallbs/acre
0.023
0.008
3.107
0.143
0.234
0.002
0.232
0.141
0.045
21.002
303.440
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.23649
0.10632
18.3418
2.03999
1.57613
0.0338
0.53967
1.148
0.41515
99.2916
Current Cumulative lbs/ac
0.260
0.114
21.449
2.183
1.810
0.036
0.772
1.289
0.460
120.293
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
1 146
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 40 Acres Permitted: 40 Site #: GR05 Field #:
118.36
VaB
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.96
Arsenic
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
2.136
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.136
Chromium
0.101
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.101
Lead
0.106
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.106
Mercury
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.092
denum
Nickel
0.097
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.097
Selenium
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Zinc
15.328
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
15.328
Total
Phos-
215.415
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
215.415
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Henry Thorpe Jr.
Operator: Henry Thorpe Jr.
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 118.36 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
146 Crop 2 Name:
2
GR05
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
40
40
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/4
531
12.8
1.431
South Durham
D
<.5"
S
0.5
0.2
53800
9840
39
39.356
NA
Fescue
3/5
453
12.8
1.221
South Durham
D
<.5"
S
0.5
0.2
53800
9840
39
33.575
NA
Fescue
3/7
114
12.8
0.307
South Durham
D
<.5"
S
0.5
0.2
53800
9840
39
8.449
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1098
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
8i.38oT
o.000
Lime Applied
Annuallbs/acre
0.021
0.004
2.136
0.101
0.106
0.003
0.092
0.097
0.017
15.328
215.415
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.23065
0.11217
18.2572
2.80066
1.93352
0.03434
0.69276
1.48175
0.4822
107.912
Current Cumulative lbs/ac
0.252
1 0.116
20.394
2.902
2.039
0.037
0.784
1.579
0.499
123.240
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
146
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 96.9 Acres Permitted: 96.9 Site #: GR05 Field #:
751.36
VaB
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
11
SD
1/3/22
2
Brown
1/3/22
3
SD
3/l/22
4
SD
11/8/22
5
6
7
8
9
10
11
12
% Solids
15.6
21.9
12.8
1 16.3
Arsenic
3.21
16.1
3.56
4.29
Cadmium
1.04
0.913
0.691
0.816
Copper
429
363
361
484
Chromium
19.8
10.8
17.1
19.9
Lead
32.3
11.5
17.9
15.5
Mercury
0.301
0.0316
0.472
0.712
Molyb-
denum
32.1
6.16
15.5
23.9
Nickel
19.5
29.2
16.4
19.2
Selenium
6.22
14.6
2.91
6.2
Zinc
2900
37
2590
3090
Total
Phos-
horus
41900
991
36400
39500
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
0.93
5.47
0.59
0.77
Arsenic
0.006
0.176
0.004
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.193
Cadmium
0.002
0.010
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Copper
0.794
3.968
0.427
0.748
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.936
Chromium
0.037
0.118
0.020
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.206
Lead
0.060
0.126
0.021
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.231
Mercury
0.001
0.000
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.059
0.067
0.018
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.182
denum
Nickel
0.036
0.319
0.019
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.404
Selenium
0.012
0.160
0.003
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.184
Zinc
5.365
0.404
3.061
4.777
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
13.608
Total
Phos-
77.515
10.832
43.025
61.067
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
192.438
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,_
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Henry Thorpe Jr.
Operator: Henry Thorpe Jr.
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 751.36 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
146
Crop 2 Name:
Acres Utilized:
GR05 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
96.9
96.9
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/2
39
15.6
0.053
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
1.596
NA
Fescue
2/10
300
15.6
0.407
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
12.276
NA
Fescue
2/11
343
15.6
0.465
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
14.035
NA
Fescue
2/14
417
21.9
0.794
Brown WTP
D
<.5"
S
0.5
0.4
10300
280
30.9
6.634
NA
Fescue
2/15
567
21.9
1.079
Brown WTP
D
<.5"
S
0.5
0.4
10300
280
30.9
9.020
NA
Fescue
2/16
378
21.9
0.719
Brown WTP
D
<.5"
S
0.5
0.4
10300
280
30.9
6.013
NA
Fescue
2/17
375
21.9
0.714
Brown WTP
D
<.5"
S
0.5
0.4
10300
280
30.9
5.965
NA
Fescue
2/21
234
21.9
0.445
Brown WTP
D
<.5"
S
0.5
0.4
10300
280
30.9
3.722
NA
Fescue
2/22
375
21.9
1 0.714
Brown WTP
D
<.5"
S
0.5
0.4
1 10300
280
30.9
5.965
NA
Fescue
2/23
75
21.9
0.143
Brown WTP
D
<.5"
S
0.5
0.4
10300
280
1 30.9
1.193
NA
Fescue
3/2
450
21.9
0.857
Brown WTP
D
<.5"
S
0.5
0.4
10300
280
30.9
7.159
NA
Fescue
3/3
531
12.8
0.591
South Durham
D
<.5"
S
0.5
0.2
53800
9840
39
16.246
NA
Fescue
546
0
0.773
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
19.863
0.000
TOTALS:
46301
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
iog.688T
o.000
Lime Applied
Annuallbs/acre
0.193
0.014
5.936
0.206
0.231
0.003
0.182
0.404
0.184
13.608
192.438
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.22456
0.08683
14.9047
1.57995
1.05175
0.02898
0.33728
1.06314
0.23292
98.1215
Current Cumulative lbs/ac
0.417
1 0.101
20.841
1.786
1.282
0.032
0.519
1.467
0.417
111.729
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
146
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

Facility Name:
Land Owner:
Operator:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Supplemental Information
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham WQ Permit #: WQ0003504 Field #: 3 Acres Utilized:
Henry Thorpe Jr. Annual Dry Tons Applied: 751.36 Site #: GR05 Acres Permitted:
Henry Thorpe Jr.
Crop 1 Name:
Fescue -Pasture
Predominant Soil Series: VaB
Crop 1 Max. PAN:
146
Crop 2 Name:
Cation Exchange Capacity (non 503):
Crop 2 Max PAN:
96.9
96.9
o
r./o
o
Volume applied (enter
one)
Cu. Yds Gallons
o
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, W #,
Fert., Animal
Waste, etc)
Soil
Cond.
(D
We '
Moist)
Precip.
Past 24
Hrs.
inches
y
a
°o w
°�
o
7� w
N'
o'
7� ?_
CD N•
o,
TKN
mg/kg
Z
o
ua o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
g
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/9
234
16.3
0.331
South Durham
D
<.5"
S
0.5
0.2
53700
6500
150
8.513
NA
Fescue
11/10
312
16.3
0.442
South Durham
D
<.5"
S
0.5
0.2
53700
6500
150
11.350
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
546
0
0.773
19.863
0.000
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (SUPP) (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 48.5 Acres Permitted: 48.5 Site #: GR05 Field #:
190.22
EnB
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.16
1.77
Arsenic
0.014
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Cadmium
0.004
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
1.850
1.709
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.559
Chromium
0.085
0.070
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.156
Lead
0.139
0.055
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.194
Mercury
0.001
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.138
0.084
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.223
denum
Nickel
0.084
0.068
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.152
Selenium
0.027
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.049
Zinc
12.505
10.914
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
23.419
Total
Phos-
180.673
139.514
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
320.187
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,_
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Henry Thorpe Jr.
Operator: Henry Thorpe Jr.
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 190.22 Site #:
Predominant Soil Series: EnB
Crop 1 Max. PAN:
146 Crop 2 Name:
4
GR05
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
48.5
48.5
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/2
114
15.6
0.309
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
9.320
NA
Fescue
2/10
191
15.6
0.517
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
15.615
NA
Fescue
2/11
226
15.6
0.612
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
18.476
NA
Fescue
2/12
265
15.6
0.718
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
21.665
NA
Fescue
11/7
234
16.3
0.662
South Durham
D
<.5"
S
0.5
0.2
53700
6500
150
17.008
NA
Fescue
11/8
390
16.3
1.104
South Durham
D
<.5"
S
0.5
0.2
53700
6500
150
28.347
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
14201
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
110.431
o.000
Lime Applied
Annuallbs/acre
0.029
0.007
3.559
0.156
0.194
0.004
0.223
0.152
0.049
23.419
320.187
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.20482
0.07736
13.6156
1.45098
0.86603
0.02743
0.31601
0.96692
0.21499
101.93
Current Cumulative lbs/ac
0.234
1 0.085
17.175
1.607
1.060
0.031
0.539
1.119
0.264
125.348
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
1 146
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 26.1 Acres Permitted: 26.1 Site #: GR05 Field #:
156.39
HrB
5
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
SD
3/1/22
2
SD
10/3/22
3
SD
11/8/22
4
5
6
7
8
9
10
11
12
% Solids
12.8
15.8
16.3
Arsenic
3.56
4.92
4.29
Cadmium
0.691
0.848
0.816
Copper
361
465
484
Chromium
17.1
21.8
19.9
Lead
17.9
18.3
15.5
Mercury
0.472
0.38
0.712
Molyb-
denum
15.5
21.8
23.9
Nickel
16.4
18.4
19.2
Selenium
2.91
6.65
6.2
Zinc
2590
3050
3090
Total
Phos-
horus
36400
40800
39500
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
1.72
1.19
3.08
Arsenic
1 0.012
0.012
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
Cadmium
0.002
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
1.243
1.109
2.979
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.331
Chromium
0.059
0.052
0.122
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.233
Lead
0.062
0.044
0.095
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.201
Mercury
0.002
0.001
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Molyb-
0.053
0.052
0.147
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.252
denum
Nickel
0.056
0.044
0.118
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.219
Selenium
0.010
0.016
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.064
Zinc
8.920
7.277
19.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
35.213
Total
Phos-
125.362
97.349
243.083
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
465.793
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Henry Thorpe Jr.
Operator: Henry Thorpe Jr.
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 156.39 Site #:
Predominant Soil Series: HrB
Crop 1 Max. PAN:
211
Crop 2 Name:
Acres Utilized:
GR05 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
26.1
26.1
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/7
417
12.8
1.722
South Durham
D
<.5"
S
0.5
0.2
53800
9840
39
47.366
NA
Fescue
10/31
234
15.8
1.193
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
35.343
NA
Fescue
11/1
351
16.3
1.846
South Durham
D
<.5"
S
0.5
0.2
53700
6500
150
47.408
NA
Fescue
11/2
234
16.3
1.231
South Durham
D
<.5"
S
0.5
0.2
53700
6500
150
31.605
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
12361
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
i6i.723T
o.000
Lime Applied
Annuallbs/acre
0.050
0.009
5.331
0.233
0.201
0.007
0.252
0.219
0.064
35.213
465.793
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.31456
0.10303
21.3893
1.88029
1.28335
0.03166
0.43161
1.38191
0.30995
126.832
Current Cumulative lbs/ac
0.365
1 0.112
26.721
2.114
1.484
0.039
0.684
1.600
0.374
162.045
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 9.5 Acres Permitted: 9.5 Site #: GR05 Field #:
51.90
VaB
6
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
5.46
Arsenic
0.054
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.054
Cadmium
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
5.081
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.081
Chromium
0.238
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.238
Lead
0.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.200
Mercury
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.238
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.238
denum
Nickel
0.201
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.201
Selenium
0.073
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.073
Zinc
33.324
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
33.324
Total
Phos-
445.781
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
445.781
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Henry Thorpe Jr.
Operator: Henry Thorpe Jr.
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 51.90 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
194 Crop 2 Name:
6
GR05
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
9.5
9.5
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/27
234
15.8
3.278
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
97.101
NA
Fescue
10/28
156
15.8
2.185
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
64.734
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
390
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
161.835
o.000
Lime A lied
Annuallbs/acre
0.054
0.009
5.081
0.238
0.200
0.004
0.238
0.201
0.073
33.324
445.781
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.22028
0.07193
13.5028
1.22537
0.91615
0.02175
0.29589
0.94616
0.2149
90.8177
Current Cumulative lbs/ac
0.274
0.081
18.583
1.464
1.116
0.026
0.534
1.147
0.288
124.142
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
1 194
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 17.5 Acres Permitted: 17.5 Site #: GR05 Field #:
101.73
CeB2
7
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
5.81
Arsenic
0.050
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
Cadmium
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
5.627
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.627
Chromium
0.231
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.231
Lead
0.180
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.180
Mercury
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Molyb-
0.278
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.278
denum
Nickel
0.223
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.223
Selenium
0.072
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.072
Zinc
35.924
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
35.924
Total
Phos-
459.227
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
459.227
horus
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Henry Thorpe Jr.
Operator: Henry Thorpe Jr.
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 101.73 Site #:
Predominant Soil Series: CeB2
Crop 1 Max. PAN:
216
Crop 2 Name:
Acres Utilized:
GR05 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
17.5
17.5
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/3
507
16.3
3.977
South Durham
D
<.5"
S
0.5
0.2
53700
6500
150
102.130
NA
Fescue
11/4
234
16.3
1.836
South Durham
D
<.5"
S
0.5
0.2
53700
6500
150
47.137
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
7411
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
149,2671
0.000
Lime Applied
Annuallbs/acre
0.050
0.009
5.627
0.231
0.180
0.008
0.278
0.223
0.072
35.924
459.227
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.07772
0.03442
6.69754
0.42568
0.35186
0.00687
0.13567
0.35103
0.08603
43.7954
Current Cumulative lbs/ac
0.128
1 0.044
12.325
0.657
0.532
0.015
0.414
0.574
0.158
79.720
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
89
1 2498
Permit PAN Limit lst/2nd Crop
1 216
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 45.72
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Milton Latta Owner: Milton Latta Predominant Soil Series: HrB
Acres Used: 13 Acres Permitted: 13 Site #: OR01 Field #: 1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
3.52
Arsenic
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
3.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.018
Chromium
0.139
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.139
Lead
0.227
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.227
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.226
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.226
denum
Nickel
0.137
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.137
Selenium
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
Zinc
20.399
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
20.399
Total
Phos-
294.725
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
294.725
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham
Land Owner: Milton Latta
Operator: Milton Latta
Crop 1 Name: Com-Grain
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 45.72 Site #:
Predominant Soil Series: HrB
Crop 1 Max. PAN:
132
Crop 2 Name:
Acres Utilized:
OR01 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
13
13
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/28
348
15.6
3.517
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
106.141
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
3481
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
iw.mT
o.000
Lime Applied
Annuallbs/acre
0.023
0.007
3.018
0.139
0.227
0.002
0.226
0.137
0.044
20.399
294.725
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.20177
0.08876
14.6345
1.46525
0.97605
0.03768
0.41323
0.96186
0.25766
102.902
Current Cumulative lbs/ac
0.224
1 0.096
17.652
1.605
1.203
0.040
0.639
1.099
0.301
123.301
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
132
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 18.26
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Milton Latta Owner: Milton Latta Predominant Soil Series: HrB
Acres Used: 6.5 Acres Permitted: 6.5 Site #: OR01 Field #: 2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.81
Arsenic
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
2.410
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.410
Chromium
0.111
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.111
Lead
0.181
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.181
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.180
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.180
denum
Nickel
0.110
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.110
Selenium
0.035
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Zinc
16.292
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.292
Total
Phos-
235.394
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
235.394
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham
Land Owner: Milton Latta
Operator: Milton Latta
Crop 1 Name: Com-Grain
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 18.26 Site #:
Predominant Soil Series: HrB
Crop 1 Max. PAN:
132 Crop 2 Name:
2
OR01
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
6.5
6.5
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/28
139
15.6
2.809
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
84.791
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1391
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
84,79iT
o.000
Lime Applied
Annuallbs/acre
0.018
0.006
2.410
0.111
0.181
0.002
0.180
0.110
0.035
16.292
235.394
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.30419
0.10043
15.4826
1.89158
1.24401
0.0434
0.42637
1.20741
0.29075
93.6901
Current Cumulative lbs/ac
0.322
1 0.106
17.893
2.003
1.425
0.045
0.607
1.317
0.326
109.982
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
132
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 11.69
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Milton Latta Owner: Milton Latta Predominant Soil Series: GeB
Acres Used: 5.8 Acres Permitted: 5.8 Site #: OR01 Field #: 3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.02
Arsenic
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
1.730
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.730
Chromium
0.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
Lead
0.130
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.130
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.129
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.129
denum
Nickel
0.079
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.079
Selenium
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Zinc
11.693
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.693
Total
Phos-
168.941
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
168.941
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham
Land Owner: Milton Latta
Operator: Milton Latta
Crop 1 Name: Com-Grain
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 11.69 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
132
Crop 2 Name:
Acres Utilized:
OR01 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
5.8
5.8
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/28
89
15.6
2.016
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
60.843
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
891
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
6o.843T
o.000
Lime Applied
Annuallbs/acre
0.013
0.004
1.730
0.080
0.130
0.001
0.129
0.079
0.025
11.693
168.941
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.2708
0.09694
14.4532
1.71186
1.01985
0.03079
0.4054
1.08785
0.27071
93.3717
Current Cumulative lbs/ac
0.284
1 0.101
16.183
1.792
1.150
0.032
0.535
1.166
0.296
105.064
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
132
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 53.34
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Milton Latta Owner: Milton Latta Predominant Soil Series: GeB
Acres Used: 15.3 Acres Permitted: 15.3 Site #: OR01 Field #: 4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
3.49
Arsenic
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
2.991
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.991
Chromium
0.138
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.138
Lead
0.225
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.225
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.224
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.224
denum
Nickel
0.136
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.136
Selenium
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.043
Zinc
20.219
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
20.219
Total
Phos-
292.127
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
292.127
horus
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham
Land Owner: Milton Latta
Operator: Milton Latta
Crop 1 Name: Com-Grain
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 5334 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
132 Crop 2 Name:
4
OR01
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
15.3
15.3
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/27
381
15.6
3.272
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
98.737
NA
Fescue
1/28
25
15.6
0.215
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
6.479
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
4061
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
io5.2mT
o.000
Lime Applied
Annuallbs/acre
0.022
0.007
2.991
0.138
0.225
0.002
0.224
0.136
0.043
20.219
292.127
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.24283
0.10478
18.5453
1.82031
1.10121
0.03888
0.50901
1.2125
0.30988
123.886
Current Cumulative lbs/ac
0.265
0.112
21.536
1.958
1.326
0.041
0.733
1.348
0.353
144.105
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
132
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 40.93
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: David Walker Owner: David Walker Predominant Soil Series: HrB
Acres Used: 5.9 Acres Permitted: 5.9 Site #: OR05 Field #: 2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 01071IN
Com-
posite
Date
E
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
6.94
Arsenic
0.052
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Cadmium
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
5.078
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.078
Chromium
0.268
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.268
Lead
0.218
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.218
Mercury
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.209
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.209
denum
Nickel
0.221
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.221
Selenium
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.056
Zinc
34.962
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
34.962
Total
Phos-
475.878
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
475.878
horus
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
David Walker
Operator: David Walker
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 40.93 Site #:
Predominant Soil Series: HrB
Crop 1 Max. PAN:
211 Crop 2 Name:
2
OR05
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
5.9
5.9
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/2
114
18
2.929
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
88.685
NA
Fescue
6/27
156
18
4.008
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
121.359
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
270
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
210,044
0.000
Lime A lied
Annuallbs/acre
0.052
0.009
5.078
0.268
0.218
0.004
0.209
0.221
0.056
34.962
475.878
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.18046
0.05617
13.6269
1.10429
0.82717
0.02025
0.33775
0.78608
0.17349
78.6143
Current Cumulative lbs/ac
0.232
0.066
18.705
1.372
1.045
0.024
0.547
1.007
0.230
113.577
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 53.21
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: David Walker Owner: David Walker Predominant Soil Series: GeB
Acres Used: 8.6 Acres Permitted: 8.6 Site #: OR05 Field #: 3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 01071IN
Com-
posite
Date
B
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
6.19
Arsenic
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Cadmium
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Copper
4.529
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.529
Chromium
0.239
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.239
Lead
0.194
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.194
Mercury
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.187
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.187
denum
Nickel
0.197
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
1 0.000
0.197
Selenium
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.050
Zinc
31.182
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
31.182
Total
Phos-
424.428
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
424.428
horus
1
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
David Walker
Operator: David Walker
Crop 1 Name: Soybeans
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 53.21 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
190
Crop 2 Name:
Acres Utilized:
OR05 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
8.6
8.6
0
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
( y'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
4
w •,
* N
*�
TKN
mg/kg
Z
o
8
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/27
234
18
4.125
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
124.887
NA
Beans
6/29
117
18
2.062
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
62.443
NA
Beans
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
3511
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
187,3301
0.000
Lime Applied
Annuallbs/acre
0.046
0.008
4.529
0.239
0.194
0.003
0.187
0.197
0.050
31.182
424.428
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.26387
0.07713
22.423
1.46431
1.1407
0.02607
0.40957
1.11884
0.23346
89.6298
Current Cumulative lbs/ac
0.310
1 0.086
26.952
1.703
1.335
0.029
0.596
1.316
0.284
120.812
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
190
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 53.21
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: David Walker Owner: David Walker Predominant Soil Series: HrB
Acres Used: 8.6 Acres Permitted: 8.6 Site #: OR05 Field #: 4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 01071IN
Com-
posite
Date
E
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
6.19
Arsenic
0.046
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Cadmium
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Copper
4.529
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.529
Chromium
0.239
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.239
Lead
0.194
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.194
Mercury
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.187
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.187
denum
Nickel
0.197
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.197
Selenium
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
Zinc
31.182
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
31.182
Total
Phos-
424.428
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
424.428
horus
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
David Walker
Operator: David Walker
Crop 1 Name: Soybeans
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 53.21 Site #:
Predominant Soil Series: HrB
Crop 1 Max. PAN:
190 Crop 2 Name:
4
OR05
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
8.6
8.6
0
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
( y'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
4
w •,
* N
*�
TKN
mg/kg
Z
8
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/29
351
18
6.187
South Durham
D
<.5"
S
0.5
0.2
59400
10600
1 78.9
187.330
NA
Beans
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
351
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
187.330
0.000
Lime Applied
Annuallbs/acre
0.046
0.008
4.529
0.239
0.194
0.003
0.187
0.197
0.050
31.182
424.428
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.23947
0.06701
15.4108
1.29101
0.86874
0.02335
0.34623
0.9448
0.25676
74.3695
Current Cumulative lbs/ac
0.286
1 0.075
19.940
1.530
1.063
0.027
0.533
1.142
0.307
105.552
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
190
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 277.40
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: David Walker Owner: Don Walker Predominant Soil Series: HrB
Acres Used: 57.6 Acres Permitted: 57.6 Site #: OR06 Field #: 1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 01071IN
Com-
posite
Date
E
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
4.82
Arsenic
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
3.525
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.525
Chromium
0.186
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.186
Lead
0.151
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.151
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.145
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.145
denum
Nickel
0.153
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
1 0.000
0.153
Selenium
0.039
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.039
Zinc
24.273
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
24.273
Total
Phos-
330.378
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
330.378
horus
1
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Don Walker
Operator: David Walker
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 277.40 Site #:
Predominant Soil Series: HrB
Crop 1 Max. PAN:
158
Crop 2 Name:
Acres Utilized:
OR06 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
57.6
57.6
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
5/31
350
18
0.921
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
27.890
NA
Fescue
6/1
325
18
0.855
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
25.898
NA
Fescue
6/2
153
18
0.403
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
12.192
NA
Fescue
6/3
534
18
1.405
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
42.552
NA
Fescue
6/30
468
18
1.232
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
37.293
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1830
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
i45,823T
o.000
Lime Applied
Annuallbs/acre
0.036
0.007
3.525
0.186
0.151
0.002
0.145
0.153
0.039
24.273
330.378
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.38492
0.17621
26.2655
2.19489
1.42858
0.04472
0.63601
1.48316
0.44067
130.835
Current Cumulative lbs/ac
0.421
1 0.183
29.791
2.381
1.580
0.047
0.781
1.636
0.480
155.108
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
158
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 61.54
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: David Walker Owner: Don Walker Predominant Soil Series: GeB
Acres Used: 8.9 Acres Permitted: 8.9 Site #: OR06 Field #: 2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 01071IN
Com-
posite
Date
B
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
6.92
Arsenic
0.052
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Cadmium
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
5.062
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.062
Chromium
0.267
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.267
Lead
0.217
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.217
Mercury
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.209
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.209
denum
Nickel
0.220
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.220
Selenium
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.056
Zinc
34.852
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
34.852
Total
Phos-
474.369
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
474.369
horus
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Don Walker
Operator: David Walker
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 61.54 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
211 Crop 2 Name:
2
OR06
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
8.9
8.9
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/1
100
18
1.703
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
51.571
NA
Fescue
6/2
306
18
5.212
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
157.808
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
4061
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
2og.38oT
o.000
Lime Applied
Annuallbs/acre
0.052
0.009
5.062
0.267
0.217
0.004
0.209
0.220
0.056
34.852
474.369
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.56961
0.16385
39.2361
2.78582
2.00329
0.06873
0.69363
2.28895
0.55866
150.144
Current Cumulative lbs/ac
0.621
0.173
44.298
3.053
2.220
0.072
0.902
2.509
0.615
184.996
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
1 211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 135.59
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Richard Vanhook Owner: Charlie Florence Predominant Soil Series: GeB
Acres Used: 41.3 Acres Permitted: 41.3 Site #: OR15 Field #: 1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
3.28
Arsenic
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
2.817
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.817
Chromium
0.130
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.130
Lead
0.212
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.212
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.211
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.211
denum
Nickel
0.128
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.128
Selenium
0.041
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
Zinc
19.041
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
19.041
Total
Phos-
275.115
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
275.115
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Charlie Florence
Operator: Richard Vanhook
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 135.59 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
211
Crop 2 Name:
Acres Utilized:
OR15 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
41.3
41.3
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/11
345
15.6
1.097
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
33.122
NA
Fescue
1/12
687
15.6
2.185
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
65.956
65.956
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
10321
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
99.078
65.956
Lime Applied
Annuallbs/acre
0.021
0.007
2.817
0.130
0.212
0.002
0.211
0.128
0.041
19.041
275.115
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.27445
0.08374
18.4931
1.50127
1.02748
0.02416
0.44627
1.14219
0.28736
108.265
Current Cumulative lbs/ac
0.296
1 0.091
21.310
1.631
1.240
0.026
0.657
1.270
0.328
127.306
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 25.23
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Richard Vanhook Owner: Willie Vanhook Predominant Soil Series: GeB
Acres Used: 8.5 Acres Permitted: 8.5 Site #: OR15 Field #: 3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.97
Arsenic
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
2.547
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.547
Chromium
0.118
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.118
Lead
0.192
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.192
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.191
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.191
denum
Nickel
0.116
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.116
Selenium
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Zinc
17.214
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
17.214
Total
Phos-
248.718
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
248.718
horus
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Willie Vanhook
Operator: Richard Vanhook
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 25.23 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
158
Crop 2 Name:
Acres Utilized:
OR15 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
8.5
8.5
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/11
192
15.6
2.968
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
89.563
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1921
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
89,563T
o.000
Lime Applied
Annuallbs/acre
0.019
0.006
2.547
0.118
0.192
0.002
0.191
0.116
0.037
17.214
248.718
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.20498
0.07352
15.2841
1.39875
0.77923
0.01957
0.3481
0.97234
0.21925
89.4572
Current Cumulative lbs/ac
0.224
1 0.080
17.831
1.516
0.971
0.021
0.539
1.088
0.256
106.672
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
158
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 14.97
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Latta Owner: William Breeze Predominant Soil Series: GeB
Acres Used: 6.7 Acres Permitted: 6.7 Site #: OR76 Field #: 6
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.24
Arsenic
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Cadmium
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
1.918
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.918
Chromium
0.089
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.089
Lead
0.144
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.144
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.143
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.143
denum
Nickel
0.087
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.087
Selenium
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.028
Zinc
12.963
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.963
Total
Phos-
187.293
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
187.293
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
William Breeze
Operator: William Latta
Crop 1 Name: Sorghum -Grain
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 14.97 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
98 Crop 2 Name:
6
OR76
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
6.7
6.7
0
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
( y'
Wet,
Moist)
precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
o
8
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/13
114
15.6
2.235
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
67.465
NA
Sorghum
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1141
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
67.465
0.000
Lime Applied
Annuallbs/acre
0.014
0.005
1.918
0.089
0.144
0.001
0.143
0.087
0.028
12.963
187.293
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.39309
0.1586
25.9216
5.20834
3.1614
0.06069
1.03418
2.84694
0.39825
173.47
Current Cumulative lbs/ac
0.407
0.163
27.839
5.297
3.306
0.062
1.178
2.934
0.426
186.433
Permitted C. P. L. R.****1
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
F 98
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 40.20
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Latta Owner: William Breeze Predominant Soil Series: GeB
Acres Used: 7.6 Acres Permitted: 7.6 Site #: OR76 Field #: 7
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
5.29
Arsenic
0.034
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Cadmium
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Copper
4.539
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.539
Chromium
0.209
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.209
Lead
0.342
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.342
Mercury
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.340
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.340
denum
Nickel
0.206
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.206
Selenium
0.066
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.066
Zinc
30.682
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
30.682
Total
Phos-
443.302
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
443.302
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
William Breeze
Operator: William Latta
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 4020 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
211
Crop 2 Name:
Acres Utilized:
OR76 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
7.6
7.6
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/27
306
15.6
5.290
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
159.645
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
3061
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
i59.645
o.000
Lime Applied
Annuallbs/acre
0.034
0.011
4.539
0.209
0.342
0.003
0.340
0.206
0.066
30.682
443.302
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.33108
0.16292
21.0511
4.11636
2.17914
0.05278
0.82987
2.02004
0.38466
138.586
Current Cumulative lbs/ac
0.365
1 0.174
25.590
4.326
2.521
0.056
1.169
2.226
0.450
169.268
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 29.96
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Latta Owner: William Breeze Predominant Soil Series: GeB
Acres Used: 15.3 Acres Permitted: 15.3 Site #: OR76 Field #: 9
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
21
3
4
5j
6j
7j
81
9
10
ill
12
DT/Ac./
App.
.fir
Event
1.96
Arsenic
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
1.680
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.680
Chromium
0.078
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.078
Lead
0.126
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.126
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.126
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.126
denum
Nickel
0.076
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.076
Selenium
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
Zinc
11.356
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.356
Total
Phos-
164.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
164.080
horus
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
William Breeze
Operator: William Latta
Crop 1 Name: Sorghum -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 29.96 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
223 Crop 2 Name:
OR76
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
15.3
15.3
0
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
( y'
Wet,
Moist)
precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
o
8
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/14
228
15.6
1.958
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
59.087
NA
Sorghum
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
228
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
59.087
0.000
Lime Applied
Annuallbs/acre
0.013
0.004
1.680
0.078
0.126
0.001
0.126
0.076
0.024
11.356
164.080
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.51114
0.16077
29.7335
7.18166
3.74169
0.06745
1.11514
2.82874
0.48466
205.583
Current Cumulative lbs/ac
0.524
0.165
31.414
7.259
3.868
0.069
1.241
2.905
0.509
216.939
Permitted C. P. L. R.****1
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
F 223
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 41.00
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Latta Owner: William Breeze Predominant Soil Series: GeB
Acres Used: 20 Acres Permitted: 20 Site #: OR76 Field #: 10
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.05
Arsenic
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
1.759
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.759
Chromium
0.081
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.081
Lead
0.132
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.132
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.132
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.132
denum
Nickel
0.080
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
Selenium
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Zinc
11.890
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.890
Total
Phos-
171.790
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
171.790
horus
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
William Breeze
Operator: William Latta
Crop 1 Name: Sorghum -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 41.00 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
223 Crop 2 Name:
10
Acres Utilized:
OR76 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
20
20
0
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
( y'
Wet,
Moist)
precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
•;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/15
312
15.6
2.050
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
61.855
NA
Sorghum
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
3121
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
61.855
0.000
Lime Applied
Annuallbs/acre
0.013
0.004
1.759
0.081
0.132
0.001
0.132
0.080
0.026
11.890
171.790
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.56291
0.18416
33.4122
8.836
3.71222
0.07825
1.36116
3.1003
0.55029
237.474
Current Cumulative lbs/ac
0.576
0.188
35.171
8.917
3.845
0.079
1.493
3.180
0.576
249.364
Permitted C. P. L. R.****1
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
F 223
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 45.32
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Latta Owner: William Breeze Predominant Soil Series: GeB
Acres Used: 11.1 Acres Permitted: 11.1 Site #: OR76 Field #: 12
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
4.08
Arsenic
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Copper
3.503
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.503
Chromium
0.162
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.162
Lead
0.264
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.264
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.262
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.262
denum
Nickel
0.159
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.159
Selenium
0.051
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Zinc
23.681
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
23.681
Total
Phos-
342.155
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
342.155
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
William Breeze
Operator: William Latta
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 45.32 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
211 Crop 2 Name:
12
Acres Utilized:
OR76 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
11.1
11.1
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/13
78
15.6
0.923
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
27.862
NA
Fescue
1/14
267
15.6
3.160
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
95.375
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
3451
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
i23,238T
o.000
Lime Applied
Annuallbs/acre
0.026
0.008
3.503
0.162
0.264
0.002
0.262
0.159
0.051
23.681
342.155
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.64839
0.22341
40.5224
10.70172
4.57187
0.1027
1.31911
3.39447
0.46268
222.266
Current Cumulative lbs/ac
0.675
0.232
44.026
10.863
4.836
0.105
1.581
3.554
0.513
245.948
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 29.95
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Latta Owner: William Breeze Predominant Soil Series: GeB
Acres Used: 7.3 Acres Permitted: 7.3 Site #: OR76 Field #: 13
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
4.10
Arsenic
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
3.520
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.520
Chromium
0.162
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.162
Lead
0.265
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.265
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.263
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.263
denum
Nickel
0.160
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.160
Selenium
0.051
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Zinc
23.797
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
23.797
Total
Phos-
343.831
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
343.831
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
William Breeze
Operator: William Latta
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 29.95 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
211 Crop 2 Name:
13
Acres Utilized:
OR76 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
7.3
7.3
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/14
228
15.6
4.103
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
123.840
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
2281
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
i23.84oT
o.000
Lime Applied
Annuallbs/acre
0.026
0.009
3.520
0.162
0.265
0.002
0.263
0.160
0.051
23.797
343.831
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.54345
0.15755
32.3624
8.95587
3.71452
0.07221
1.3719
3.18081
0.51861
195.538
Current Cumulative lbs/ac
0.570
1 0.166
35.883
9.118
3.980
0.075
1.635
3.341
0.570
219.335
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 70.16
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Latta Owner: William Breeze Predominant Soil Series: GeB
Acres Used: 17.2 Acres Permitted: 17.2 Site #: OR76 Field #: 17
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
4.08
Arsenic
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Copper
3.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.500
Chromium
0.162
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.162
Lead
0.264
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.264
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.262
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.262
denum
Nickel
0.159
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.159
Selenium
0.051
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Zinc
23.658
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
23.658
Total
Phos-
341.820
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
341.820
horus
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
William Breeze
Operator: William Latta
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 70.16 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
211 Crop 2 Name:
17
Acres Utilized:
OR76 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
17.2
17.2
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/13
534
15.6
4.079
South Durham
D
<.5"
S
0.5
0.2
62200
8650
55.1
123.101
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
5341
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
mmj
o.000
Lime Applied
Annuallbs/acre
0.026
0.008
3.500
0.162
0.264
0.002
0.262
0.159
0.051
23.658
341.820
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.49506
0.17759
29.2482
7.65493
3.70965
0.06715
1.43637
3.04768
0.51028
187.338
Current Cumulative lbs/ac
0.521
1 0.186
32.748
7.816
3.973
0.070
1.698
3.207
0.561
210.997
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 26.98
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Rogers Owner: Curtis Chandler Predominant Soil Series: HeB
Acres Used: 5.7 Acres Permitted: 5.7 Site #: OR93 Field #: 8A
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 01071IN
Com-
posite
Date
B
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
4.73
Arsenic
0.035
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
3.465
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.465
Chromium
0.183
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.183
Lead
0.149
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.149
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.143
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.143
denum
Nickel
0.151
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
1 0.000
0.151
Selenium
0.039
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.039
Zinc
23.859
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
23.859
Total
Phos-
324.752
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
324.752
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Curtis Chandler
Operator: William Rogers
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 26.98 Site #:
Predominant Soil Series: HeB
Crop 1 Max. PAN:
163 Crop 2 Name:
8A Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
5.7
5.7
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/6
178
18
4.734
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
143.332
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
178
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
143,332
0.000
Lime A lied
Annuallbs/acre
0.035
0.006
3.465
0.183
0.149
0.002
0.143
0.151
0.039
23.859
324.752
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.36683
0.13893
18.5231
12.82884
2.51959
0.16913
1.27345
4.64327
0.25189
150.304
Current Cumulative lbs/ac
0.402
0.145
21.988
13.012
2.668
0.172
1.416
4.794
0.290
174.163
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
1 163
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual): 26.98
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Rogers Owner: Curtis Chandler Predominant Soil Series: HeB
Acres Used: 7.8 Acres Permitted: 7.8 Site #: OR93 Field #: 8B
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 01071IN
Com-
posite
Date
E
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
3.46
Arsenic
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
2.532
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.532
Chromium
0.134
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.134
Lead
0.109
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.109
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.104
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.104
denum
Nickel
0.110
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
1 0.000
0.110
Selenium
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.028
Zinc
17.433
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
17.433
Total
Phos-
237.287
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
237.287
horus
1
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Curtis Chandler
Operator: William Rogers
Crop 1 Name: Com-Silage
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 26.98 Site #:
Predominant Soil Series: HeB
Crop 1 Max. PAN:
163 Crop 2 Name:
Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
7.8
7.8
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/6
178
18
3.459
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
104.743
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
178
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
104,743
0.000
Lime A lied
Annuallbs/acre
0.026
0.005
2.532
0.134
0.109
0.002
0.104
0.110
0.028
17.433
237.287
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.14912
0.05741
9.98555
1.41166
0.71664
0.02287
0.27535
0.68823
0.16196
81.743
Current Cumulative lbs/ac
0.175
0.062
12.518
1.545
0.825
0.025
0.380
0.798
0.190
99.176
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
1 163
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Rogers Owner: Linwood Rogers Predominant Soil Series:
Acres Used: 31.2 Acres Permitted: 31.2 Site #: OR93 Field #:
73.38
HeB
14
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... W1071IN
Com-
posite
Date
B
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
2.35
Arsenic
0.018
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
1.722
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.722
Chromium
0.091
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.091
Lead
0.074
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.074
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.071
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.071
denum
Nickel
0.075
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.075
Selenium
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Zinc
11.854
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.854
Total
Phos-
161.347
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
161.347
horus
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Linwood Rogers
Operator: William Rogers
Crop 1 Name: Soybeans
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 73.38 Site #:
Predominant Soil Series: HeB
Crop 1 Max. PAN:
147 Crop 2 Name:
14
Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
31.2
31.2
0
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
( y'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
4
w •,
* N
*�
TKN
mg/kg
Z
8
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/8
484
18
2.352
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
71.201
NA
Beans
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
484
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
71.201
0.000
Lime Applied
Annuallbs/acre
0.018
0.003
1.722
0.091
0.074
0.001
0.071
0.075
0.019
11.854
161.347
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.03185
0.01169
1.40381
0.19125
0.14862
0.00355
0.04136
0.13776
0.02924
7.44238
Current Cumulative lbs/ac
0.049
0.015
3.125
0.282
0.222
0.005
0.112
0.213
0.048
19.296
Permitted C. P. L. R.****
36
1 34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
147
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Tommy Gentry Owner: Tommy Gentry Predominant Soil Series:
Acres Used: 13.5 Acres Permitted: 13.5 Site #: OR94 Field #:
42.59
HeB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... W1071IN
Com-
posite
Date
W
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
3.16
Arsenic
0.024
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
2.309
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.309
Chromium
0.122
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.122
Lead
0.099
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.099
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.095
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.095
denum
Nickel
0.100
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.100
Selenium
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Zinc
15.901
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
15.901
Total
Phos-
216.433
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
216.433
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Tommy Gentry
Operator: Tommy Gentry
Crop 1 Name: Com-Silage
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 42.59 Site #:
Predominant Soil Series: HeB
Crop 1 Max. PAN:
163
Crop 2 Name:
Acres Utilized:
OR94 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
13.5
13.5
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/7
281
18
3.155
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
95.537
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
2811
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
95,537T
o.000
Lime Applied
Annuallbs/acre
0.024
0.004
2.309
0.122
0.099
0.002
0.095
0.100
0.026
15.901
216.433
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.024
0.004
2.309
0.122
0.099
0.002
0.095
0.100
0.026
15.901
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
163
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Tommy Gentry Owner: Tommy Gentry Predominant Soil Series:
Acres Used: 5.1 Acres Permitted: 5.1 Site #: OR94 Field #:
15.16
HeB
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... W1071IN
Com-
posite
Date
E
1010B
on
OEM
EMBEEM
MEMO
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
2.97
Arsenic
0.022
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
2.176
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.176
Chromium
0.115
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.115
Lead
0.093
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.093
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.090
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.090
denum
Nickel
0.095
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.095
Selenium
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
Zinc
14.979
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
14.979
Total
Phos-
203.879
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
203.879
horus
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Tommy Gentry
Operator: Tommy Gentry
Crop 1 Name: Com-Silage
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 15.16 Site #:
Predominant Soil Series: HeB
Crop 1 Max. PAN:
163 Crop 2 Name:
2
OR94
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
5.1
5.1
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/7
100
18
2.972
South Durham
D
<.5"
S
0.5
0.2
59400
10600
78.9
89.997
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
100
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
89.997
0.000
Lime A lied
Annuallbs/acre
0.022
0.004
2.176
0.115
0.093
0.002
0.090
0.095
0.024
14.979
203.879
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.022
0.004
2.176
0.115
0.093
0.002
0.090
0.095
0.024
14.979
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
1 163
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Alfred Gentry Owner: Alfred Gentry Predominant Soil Series:
Acres Used: 15.6 Acres Permitted: 15.6 Site #: PS03 Field #:
83.04
GeB
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
5.32
Arsenic
0.052
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Cadmium
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
4.950
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.950
Chromium
0.232
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.232
Lead
0.195
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.195
Mercury
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.232
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.232
denum
Nickel
0.196
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.196
Selenium
0.071
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.071
Zinc
32.470
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
32.470
Total
Phos-
434.357
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
434.357
horus
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Alfred Gentry
Operator: Alfred Gentry
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 83.04 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
211
Crop 2 Name:
Acres Utilized:
PS03 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
15.6
15.6
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/11
156
15.8
1.331
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
39.421
NA
Fescue
10/12
468
15.8
3.992
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
118.264
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
6241
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
157.685
o.000
Lime Applied
Annuallbs/acre
0.052
0.009
4.950
0.232
0.195
0.004
0.232
0.196
0.071
32.470
434.357
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.18354
0.07925
13.6638
1.39449
0.78367
0.03172
0.36298
0.86429
0.19828
95.794
Current Cumulative lbs/ac
0.236
1 0.088
18.614
1.627
0.978
0.036
0.595
1.060
0.269
128.264
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
89
2498
Permit PAN Limit lst/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Alfred Gentry Owner: Alfred Gentry Predominant Soil Series:
Acres Used: 15.7 Acres Permitted: 15.7 Site #: PS03 Field #:
72.66
GeB
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
4.63
Arsenic
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Cadmium
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Copper
4.304
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.304
Chromium
0.202
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.202
Lead
0.169
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.169
Mercury
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.202
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.202
denum
Nickel
0.170
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.170
Selenium
0.062
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.062
Zinc
28.231
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
28.231
Total
Phos-
377.645
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
377.645
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Alfred Gentry
Operator: Alfred Gentry
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 72.66 Site #:
Predominant Soil Series: GeB
Crop 1 Max. PAN:
211 Crop 2 Name:
4
PS03
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
15.7
15.7
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/10
234
15.8
1.983
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
58.755
NA
Fescue
10/11
312
15.8
2.644
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
78.341
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
546
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
137,096
0.000
Lime A lied
Annuallbs/acre
0.046
0.008
4.304
0.202
0.169
0.004
0.202
0.170
0.062
28.231
377.645
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.09693
0.03891
7.33348
0.41294
0.3164
0.00778
0.1359
0.33781
0.10092
39.4204
Current Cumulative lbs/ac
0.142
0.047
11.638
0.615
0.486
0.011
0.338
0.508
0.162
67.651
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
1 211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 36.6 Acres Permitted: 36.6 Site #: PS07 Field #:
67.45
OrB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
21
3
4
5j
6j
7j
81
9
10
ill
12
DT/Ac./
App.
.fir
Event
1.84
Arsenic
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
1.714
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.714
Chromium
0.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
Lead
0.067
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.067
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
denum
Nickel
0.068
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.068
Selenium
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Zinc
11.242
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.242
Total
Phos-
150.389
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
150.389
horus
1
1
1
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Roy Carver
Operator: Roy Carver
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 67.45 Site #:
Predominant Soil Series: OrB
Crop 1 Max. PAN:
72.75
Crop 2 Name:
Acres Utilized:
PS07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
36.6
36.6
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
9/28
156
15.8
0.567
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
16.803
NA
Fescue
9/29
351
15.8
1.276
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
37.806
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
5071
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
54.6o8
o.000
Lime Applied
Annuallbs/acre
0.018
0.003
1.714
0.080
0.067
0.001
0.080
0.068
0.025
11.242
150.389
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.13395
0.02677
15.9774
0.45933
0.26075
0.00511
0.10163
0.39364
0.31384
20.2583
Current Cumulative lbs/ac
0.152
1 0.030
17.691
0.540
0.328
0.007
0.182
0.461
0.338
31.501
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
72.75
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 24.4 Acres Permitted: 24.4 Site #: PS07 Field #:
46.70
OnA
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
21
3
4
5j
6j
7j
81
9
10
ill
12
DT/Ac./
App.
.fir
Event
1.91
Arsenic
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
1.780
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.780
Chromium
0.083
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.083
Lead
0.070
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.070
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.083
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.083
denum
Nickel
0.070
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.070
Selenium
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Zinc
11.675
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.675
Total
Phos-
156.182
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
156.182
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Roy Carver
Operator: Roy Carver
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 46.70 Site #:
Predominant Soil Series: OnA
Crop 1 Max. PAN:
77.25 Crop 2 Name:
2
PS07
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
24.4
24.4
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
9/27
156
15.8
0.851
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
25.204
NA
Fescue
9/28
195
15.8
1.063
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
31.505
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
3511
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
56.7ogT
o.000
Lime Applied
Annuallbs/acre
0.019
0.003
1.780
0.083
0.070
0.001
0.083
0.070
0.025
11.675
156.182
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.04601
0.01425
3.57067
0.19566
0.16878
0.00445
0.18512
0.18341
0.05667
26.9018
Current Cumulative lbs/ac
0.065
0.017
5.351
0.279
0.239
0.006
0.269
0.254
0.082
38.577
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
1 77.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 29.5 Acres Permitted: 29.5 Site #: PS07 Field #:
51.77
OnA
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
21
3
4
5j
6j
7j
81
9
10
ill
12
DT/Ac./
App.
.fir
Event
1.76
Arsenic
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
1.548
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.548
Chromium
0.071
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.071
Lead
0.063
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.063
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.083
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.083
denum
Nickel
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
Selenium
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Zinc
9.898
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.898
Total
Phos-
140.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
140.049
horus
1
1
1
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Roy Carver
Operator: Roy Carver
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 51.77 Site #:
Predominant Soil Series: OnA
Crop 1 Max. PAN:
77
Crop 2 Name:
Acres Utilized:
PS07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
29.5
29.5
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/7
128
13
0.475
South Durham
D
<.5"
S
0.5
0.2
51200
12500
41
13.331
NA
Fescue
7/8
345
13
1.280
South Durham
D
<.5"
S
0.5
0.2
51200
12500
41
35.930
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
4731
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
49,26iT
o.000
Lime Applied
Annuallbs/acre
0.024
0.003
1.548
0.071
0.063
0.002
0.083
0.058
0.020
9.898
140.049
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.04296
0.01481
3.40227
0.18536
0.16018
0.00487
0.1544
0.17399
0.0471
20.7229
Current Cumulative lbs/ac
0.067
1 0.018
4.950
0.256
0.223
0.007
0.238
0.232
0.067
30.621
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
77
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 33.8 Acres Permitted: 33.8 Site #: PS07 Field #:
126.11
SmB
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
3.73
Arsenic
0.052
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
3.291
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.291
Chromium
0.150
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.150
Lead
0.134
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.134
Mercury
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.177
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.177
denum
Nickel
0.123
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.123
Selenium
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.043
Zinc
21.043
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
21.043
Total
Phos-
297.734
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
297.734
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Roy Carver
Operator: Roy Carver
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 126.11 Site #:
Predominant Soil Series: SmB
Crop 1 Max. PAN:
190 Crop 2 Name:
4
PS07
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
33.8
33.8
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/5
384
13
1.244
South Durham
D
<.5"
S
0.5
0.2
51200
12500
41
34.904
NA
Fescue
7/6
434
13
1.406
South Durham
D
<.5"
S
0.5
0.2
51200
12500
41
39.449
NA
Fescue
7/7
334
13
1.082
South Durham
D
<.5"
S
0.5
0.2
51200
12500
41
30.359
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
11521
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
iw.7nT
o.000
Lime Applied
Annuallbs/acre
0.052
0.007
3.291
0.150
0.134
0.005
0.177
0.123
0.043
21.043
297.734
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.15638
0.05662
11.9332
0.61737
0.45702
0.00905
0.35024
0.5257
0.25574
54.6424
Current Cumulative lbs/ac
0.208
1 0.064
15.224
0.767
0.591
0.014
0.527
0.649
0.299
75.685
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit lst/2nd Crop
190
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 19.8 Acres Permitted: 19.8 Site #: PS07 Field #:
62.27
RaB
5
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
3.15
Arsenic
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
Cadmium
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
2.925
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.925
Chromium
0.137
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.137
Lead
0.115
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.115
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.137
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.137
denum
Nickel
0.116
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.116
Selenium
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Zinc
19.185
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
19.185
Total
Phos-
256.632
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
256.632
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z: �z 4; 5 1 /�,-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Roy Carver
Operator: Roy Carver
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 62.27 Site #:
Predominant Soil Series: RaB
Crop 1 Max. PAN:
142.5
Crop 2 Name:
Acres Utilized:
PS07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
19.8
19.8
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/5
156
15.8
1.048
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
31.059
NA
Fescue
10/6
312
15.8
2.097
South Durham
D
<.5"
S
0.5
0.2
50900
9810
1690
62.118
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
4681
01
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
93.178
0.000
Lime Applied
Annuallbs/acre
0.031
0.005
2.925
0.137
0.115
0.002
0.137
0.116
0.042
19.185
256.632
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.03042
0.01326
1.99496
0.12792
0.12062
0.00265
0.0458
0.11731
0.03314
14.7799
Current Cumulative lbs/ac
0.061
0.019
4.920
0.265
0.236
0.005
0.183
0.233
0.075
33.964
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
142.5
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham
WWTP Name: South Durham WRF
WQ Permit Number:
NPDES Number:
WQ0003504
NCO047597
Monitoring Period: From l/l/2022
To 2/28/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying
Composting
Aerobic Digestion
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
MinimuniGeo.
Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
472
1476
7317
col/g
0
Quarterly
C
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) r❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
`'❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
Feb 28, 2023 4v2 2/15/2023
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham
WWTP Name: South Durham WRF
WQ Permit Number:
NPDES Number:
WQ0003504
NCO047597
Monitoring Period: From 3/l/2022
To 4/30/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying
Composting
Aerobic Digestion
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
MinimuniGeo.
Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
11029
38075
193780
col/g
0
Quarterly
C
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) r❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
`'❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
Brent Collins; Director of Technical Services
Land Applier Name and Tititll/ee (if applicable)(type or print)
Feb 28, 2023Z4y� 2/15/2023
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham
WWTP Name: South Durham WRF
WQ Permit Number:
NPDES Number:
WQ0003504
NCO047597
Monitoring Period: From 5/l/2022
To 6/30/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying
Composting
Aerobic Digestion
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
MinimuniGeo.
Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
7740
33749
133000
col/g
0
Quarterly
C
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) r❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
`'❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
Feb 28, 2023 4v2 2/15/2023
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham
WWTP Name: South Durham WRF
WQ Permit Number:
NPDES Number:
WQ0003504
NCO047597
Monitoring Period: From 7/l/2022
To 8/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying
Composting
Aerobic Digestion
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
MinimuniGeo.
Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1346
2678
5714
col/g
0
Quarterly
C
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) r❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
`'❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
Feb 28, 2023 4v2 2/15/2023
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham
WWTP Name: South Durham WRF
WQ Permit Number:
NPDES Number:
WQ0003504
NCO047597
Monitoring Period: From 9/l/2022
To 10/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying
Composting
Aerobic Digestion
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
MinimuniGeo.
Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
898
2403
4620
col/g
0
Quarterly
C
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) r❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
`'❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
�1� (�111W-
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
Feb 28, 2023 4y2 2/15/2023
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham
WWTP Name: South Durham WRF
WQ Permit Number:
NPDES Number:
WQ0003504
NCO047597
Monitoring Period: From l l/l/2022
To 12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying
Composting
Aerobic Digestion
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
MinimuniGeo.
Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
2674
4836
9189
col/g
0
Quarterly
C
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) r❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
`'❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
�1� (�111W—
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
Feb 28, 2023 4v2 2/15/2023
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Pages from 2022 Durham Annual Report -
WQ0003504
Final Audit Report 2023-02-28
Created: 2023-02-28
By: Brent Collins ([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAA7dVEFSdQlfp349LhHIG8oizc4sTTEX4B
"Pages from 2022 Durham Annual Report - WQ0003504" Histor
v
Document created by Brent Collins ([e-mail])
2023-02-28 - 8:51:30 PM GMT- IP address: 206.85.202.26
E'71 Document emailed to Charles Cocker ([e-mail]) for signature
2023-02-28 - 8:52:33 PM GMT
Email viewed by Charles Cocker ([e-mail])
2023-02-28 - 8:54:19 PM GMT- IP address: 66.195.223.214
Document e-signed by Charles Cocker ([e-mail])
Signature Date: 2023-02-28 - 8:58:29 PM GMT - Time Source: server- IP address: 66.195.223.214
Agreement completed.
2023-02-28 - 8:58:29 PM GMT
a Adobe Acrobat Sign

North & South Durham Sludge Fecal Coliform Analysis
2022 Summary
North Durham WRF
Sample
Date
Sample Set #1
MPN
f. coliform/g total solids
Sample Set #2
MPN
f coliform/g total solids
Sample Set #3
MPN
f. coliform/g total solids
Sample Set 94
MPN
f. coliform/g total solids
Sample Set #5
MPN
f. coliform/g total solids
Sample Set #6
MPN
f. coliform/g total solids
Sample Set #7
MPN
f conform/g total solids
Geometric Mean
tco1. /g. is
#NUM!
No sampling - Composting
#NUM!
#NUM!
#NUM!
#NUM!
#NUM!
South Durham WRF
Sample
Date
Sample Set #1
MPN
f. coliform/g total solids
Sample Set #2
MPN
f. coliform/g total solids
Sample Set #3
MPN
f. coliform/g total solids
Sample Set #4
MPN
f. colifomr/g total solids
803
Sample Set #5
MPN
f. coliform/g total solids
1,129
Sample Set #6
MPN
f. coliform/g total solids
7,317
Sample Set #7
MPN
f. conform/g total solids
982
Geometric Mean
f. Col. /g. is
2/23/2022
1,705
2,916
472
1,476
4/20/2022
43,269
16,746
20,833
11,029
70,539
50,980
193,780
38,075
6/1/2022
7,740
133,000
47,600
16,200
69,200
36,900
24,600
33,749
8/212022
2,222
2,692
2,241
1,346
5,714
4,194
2,285
2,678
10/5/2022
3,240
2,090
1,720
4,620
4,260
898
2,250
2,403
121512022
2,674
3,571
4,865
5,333
9,189
7,927
3,428
4,836

South Durham Water Reclamation Facility
Sludge Report
January'2022
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
t
244,556
3.6
73,425
83.2
61,090
2
264,662
3.9
86,084
86.1
74,118
3
267,980
3.5
78,223
84.5
66,099
4
391,446
3.4
110,998
89.3
99,122
TOTAL
1,168,644
3.6
348,731
85.8
300,429
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
1,227,800
1.06
108,645
42.8
46,535
145,443
6.5
78,845
75.3
59,370
2
1,227,800
1.00
102,720
75.2
77,248
128,632
6.1
65,389
75.3
49,238
3
1,227,800
0.98
100,760
76.5
77,111
145,727
4.9
59,553
75.4
44,903
4
1,772,000
0.99
146,455
77.4
113,362
162,111
7.1
95,992
77.0
73,914
TOTAL
5,455.400
1.01
458,580
68.0
314,257
581,813
6.2
299,779
75.8
227,425
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry % Vol Ibs VM
1
441,707
2.2
81,044
65.5
53,084
405
15.6
67.9
223.758
4.3 80,244 74.5 59,782
2
429,116
2.2
78,734
66.8
52,594
374
15.4
67.5
197,742
3.0 49,475 74.0 36,612
3
429,850
2.3
82,454
65.2
53,760
438
15.8
67.0
224,195
4.3 80,401 71.4 57,406
4
660,315
2.3
107,480
64.6
69,432
541
16.3
66.4
249,401
4.5 93,600 75.6 70,762
TOTAL
1,860.988
2.3
349,712
65.5
228,870
1,758
15.8
67.2
895,096
4.0 303,720 73.9 224,561
ANAEROBIC SLUDGE TO BEDS
SOLIDS OFF DRYING BEDS
Beds
Yards
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Cleaned
% Solids
Removed
1
165,000
3.6
49,540
85.8
42,505
2
3
4
TOTAL
165,000
3.6
49,540
85.8
42,505
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1,750,457
648,510
527,854
2,025,988
399,252
271,375
58
Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Digester' is 65% of
the 'Gravity Thickener to GBT flow. Bad flow meter.
56 % (VK) 49 % (LBS)
Ibs Polymer $Ilb Poly Cost $IDT
748
$1.75 1,309
2,677
$1.75 4,685 26.79

South Durham Water Reclamation Facility
Sludge Report
February'2022
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
278,524
3.2
74,332
89.4
2
276,046
3.7
85,182
88.3
3
310,076
3.6
93,097
88.1
4
333,159
4.0
111,142
82.7
TOTAL
1,197,805
3.6
363,754
87.1
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
938,880
1.G3
80,495
78.1
2
920,360
1.16
88,831
78.2
3
910,000
1.20
90,780
76.9
4
972,860
1.16
94,362
77.5
TOTAL
3,742,100
1.14
354,468
77.7
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
462,932
2.4
92,660
64.6
2
420,063
2.4
84,080
66.1
3
460,110
2.3
88,258
65.1
4
407,990
2.4
81,663
64.7
TOTAL
1,751,095
2.4
346,662
65.1
ANAEROBIC
SLUDGE
TO BEDS
Ibs VM
66,453
75,216
82,019
91,914
315,602
Ibs VM
62,829
69,433
69,853
73,128
275,244
Ibs VM
59,859
55,577
57,456
52,836
225,728
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Gallons % Solids Lbs Dry % Vol Ibs VM
TWAS GBT TO ANAEROBIC DIGESTED
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
144,828
6.6
79,719
76.7
61,145
145,469
6.5
78,859
78.0
61,510
147,454
7.2
88,543
77.4
68,532
141,395
6.3
74,292
76.4
56,759
579,146
6.7
321,413
77A
247,946
SD SOLIDS OFF PRESS
Yds
% Solids
% Vol
397
16.2
66.6
361
15.3
66.5
440
15.2
66.4
361
15.8
66.8
1,558
15.6
66.6
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK. Gallons % Solids Lbs Dry % Vol Ibs VM Cleaned % Solids Removed
1
2
3
4 104,300 3.6 31,315 87.1 27,275
TOTAL 104,300 3.6 31,315 87.1 27,275
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Prod ucedllb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1.776,951
685,167
563,548
1,855,395
377,977
253,003
52
GRAVITY THICKENER TO GBT
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
222,812
4.1
76,188
75.2
57,294
223,798
3.7
69,060
77.1
53,245
226,853
3.6
68,110
76.5
52,104
217,530
3.4
61,683
74.8
46,139
890,993
3.7
275,041
75.9
208,782
Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Oigestar' is 65% of
the 'Gravity Thickener to GBT' flow. Bad flow meter.
62 % (VK) 55 % (LBS)
Ibs Polymer $11b Poly Cost $IDT
690
$1.75 1,208
2,456
$1.75 4,298 24.80

South Durham Water Reclamation Facility
Sludge Report
March '2422
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
322,373
3.8
102,166
79.1
80,814
2
299,655
3.3
82,471
85.2
70,265
3
283,693
3.3
78,078
82.4
64,336
4
490,865
3.3
133,049
85.9
114,223
TOTAL
1,396,586
3.4
395,764
83.2
329,638
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
863,944
0.87
62,892
122,708
6.7
68,567
76.0
52,111
2
925,594
0.89
68,670
75.0
51,526
110,256
6.6
60,689
73.1
44,364
3
1,018,215
0.95
80,249
73.7
59,126
114,407
6.0
57,249
73.3
41,964
4
1,425,545
0.87
103,601
75.0
77,748
194,648
6.1
98,214
74.0
72,678
TOTAL
4,233,298
0.90
315,412
74.6
188,400
542,019
6.4
284,719
74.1
211,116
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK
Gallons
% Solids
Lbs. Dry
% Vol
Ibs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry % Vol
Ibs VM
1
420,243
2.3
80,611
64.6
52,075
385
16.1
65.9
188,782
3.7
58,254 75.0
43,691
2
394,367
2.3
75,647
63.0
47,658
357
15.7
64.1
169,624
3.8
53,757 72.9
39,189
3
401,783
2.2
73,719
61.8
45,558
379
16.4
64.2
176,010
4.3
63,121 73.1
46,141
4
673,586
2.3
126,398
62.3
78,746
597
17.3
63.9
299,459
4.3
107,392 72.8
78,181
TOTAL
1,889,979
2.3
356,376
62.9
224,037
1,718
16.4
64.5
833,875
4.0
282,524 73.5
207,202
ANAEROBIC
SLUDGE
TO BEDS
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK Gallons % Solids Lbs Dry % Vol Ibs VM Cleaned % Solids Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig,
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Producedllb of VM added
Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1,938,605
680,483
540,754
1,889,979
356,376
224,037
52
Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Digester' is 65% of
the 'Gravity Thickener to GBT' flow. Bad flow meter.
59 % (VK) 59 % (LBS)
Ibs Polymer $Ilb Poly Cost $IDT
780 $175 1,365
3,167 $1.75 5,542 31.10

South Durham Water Reclamation Facility
Sludge Report
April '2022
SD PRIMARY SLUDGE TO DIGESTER
WEFK
Gallons
% Solids
Lbs Dry
% Vol
1
359,725
3.5
105,004
88.0
2
403,196
3.3
110,968
83.7
3
348,940
3.6
104,766
86.4
4
468,295
3.5
136,695
87.2
TOTAL
1,580,156
3.5
457,432
86.3
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,138,550
0.94
88,810
74.9
2
1,138,550
0.78
73,685
73.6
3
1,134,000
0.83
78,498
86.3
4
1,485,570
0.91
113,118
74.7
TOTAL
4,896,670
0.87
354,111
77.4
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% solids
Lbs Dry
% Vol
1
465,489
2.2
85,408
63.0
2
460,478
2.2
84,489
62.8
3
484,683
2.1
84,887
63.7
4
497,083
2.1
87,059
63.7
TOTAL
1,907,733
2.2
341,843
63.3
ANAEROBIC
SLUDGE
TO BEDS
Ibs VM
92,403
92,880
90,518
119,198
394,999
Ibs VM
66,563
54,245
67,723
84,471
273,002
ibs VM
53,807
53,059
54,073
55,457
216,396
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Gallons % Solids Lbs Dry % Vol Ibs VM
TWAS GBT TO ANAEROBIC DIGESTER
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
128,538
5.3
56,816
74.6
42,385
95,830
5.9
47,154
74.2
34,988
127,490
6.1
64,859
74.7
48,450
123,647
7.5
77,341
73.7
57,000
475,505
6.2
246,171
743
182,824
SD SOLIDS OFF PRESS
Yds
% Solids
% Vol
409
17.2
64.0
459
17.2
64.7
430
16.8
64.9
377
16.7
65.7
1,675
17.0
64.8
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK Gallons % Solids Lbs Dry % Vol Ibs VM Cleaned % Solids Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig.
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production F13
Ft3 of Gas Produced/lb of VM added
Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
2,055,661
703,603
577,823
1,907, 733
341,843
216,396
48
GRAVITY THICKENER TO GBT
Gallons
% Solids Lbs Dry
% Vol
Ibs VM
197,750
4.6
75,865
71.9
54,547
147,430
4.6
56,560
73.3
41,459
196,138
4.0
65,432
73.6
48,158
190,226
4.3
68,219
72.5
49,459
731,544
4.4
266,075
72.8
193,622
Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Digester' is 65% of
the 'Gravity Thickener to GBT' flow. Bad flow meter.
66 % (VK) 63 % (LBS)
Ibs Polymer $/lb Poly Cost $IDT
635
$1.75 1,111
3,169
$1.75 5,546 32.45

South Durham Water Reclamation Facility
Sludge Report
May '2022
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
347,189
3.4
98,449
87.9
2
289,074
3.4
81,970
87.5
3
311,483
3.4
88,324
87.2
4
384,323
3.2
102,568
85.5
TOTAL
1,332,069
3.4
371,311
87.0
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,236,397
0.87
89,534
77.1
2
1,261,400
0.80
84,416
74.4
3
1,262,800
0.81
85,676
74.2
4
1,826,663
0.77
117,880
72.8
TOTAL
5,587,260
0.81
377,506
74.6
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
482,068
2.2
88,450
64.6
2
457,381
2.1
80.106
64.5
3
452,970
2.2
83,111
64.7
4
623,346
2.2
114,372
65.3
TOTAL
2,015,765
2.2
366,038
64.8
ANAEROBIC
SLUDGE.
TO BEDS
Ibs VM
86,537
71,724
77,019
87,696
322,975
Ibs VM
68,997
62,810
63,530
85,830
281,168
Ibs VM
57,139
51,668
53,773
74,685
237,264
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Gallons % Solids Lbs Dry % Vol Ibs VM
TWAS GBT TO ANAEROBIC DIGESTE?
Gallons
% Solids
Lbs Dry
% Vol
ibs VM
133,323
6.3
70,051
74.0
51,837
140,602
5.7
66,839
74.5
49,795
113,597
5.8
54,949
74.2
40,772
212,878
6.6
117,177
73.9
86,593
600,400
6.1
309,016
74.2
228,999
SD SOLIDS OFF PRESS
Yds
% Solids
% Vol
458
16.7
65.9
413
16.6
66.8
410
16.6
67.1
623
16.4
66.7
1,903
16.6
66.6
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK Gallons % Solids Lbs Dry % Voi Ibs VM Cleaned % Solids Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig.
Total Pounds of Vol. Solids to Anaerobic Dig,
Total Gallons from Anaerobic Dig.
Total ibs. of Dry Solids from Anaerobic Dig.
Total lbs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1,932,469
680,327
551,973
2,015,765
366,038
237,264
52
GRAVITY THICKENER TO GBT
Galions
% Solids Lbs Dry
% Vol
Ibs VM
205,112
4.4
75,268
72.1
54,268
216,310
3.5
63,141
72.9
46,030
174,764
3.2
46,641
74.1
34,561
327,505
3.2
87,405
73.4
64,155
923,691
3.6
272,454
73.1
199,014
Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Digester' is 65% of
the'Gravity Thickener to GBT' flow. Bad flow meter.
62 % (VK) 57 % (LBS)
Ibs Polymer $fib Poly Cost $/DT
888 $1.75 1,554
3,444 $1.75 6,027 32.93

South Durham Water Reclamation Facility
Sludge Report
June '2022
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
364,290
4.6
139,756
86.6
121,029
2
288,316
2.9
69,732
87.0
60,667
3
355,805
3.4
100,892
89.0
89,794
4
364,219
3.7
110,872
88.0
97,512
TOTAL
1,372,630
3.7
421,252
87.7
369,002
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTE9
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
1,288,026
0.87
92,981
71.1
66,152
147,123
5.6
68,712
71.5
49,129
2
1,282,680
0.73
78,505
73.7
57,873
119,534
5.9
58,818
71.9
42,290
3
1,286,485
0.75
80,883
74.7
60,440
119,686
5.8
57,895
72A
41,916
4
1,694,700
0.67
94,649
72.3
68,461
203,208
6.1
102,533
73.1
74,900
TOTAL
5,551,891
0.76
347,018
73.0
252,926
589,551
5.9
287,957
72.2
208,235
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry % Vol
Ibs VM
1
484,878
2.2
88,965
64.8
57,650
458
16.5
66.4
226,343
3.9
73,620 70.9
52,197
2
452,768
2.2
83.074
64.7
53,749
426
16.4
66.2
183,899
3.3
50,613 70.7
35,783
3
466,921
2.2
85,671
74.5
63,625
458
16.0
66.4
184,132
3.1
47,605 69.4
33,038
4
631,752
2.2
115,914
64.5
74,706
588
16.1
64.0
312,628
3.2
82.131 72.0
59,134
TOTAL
2,036,319
2.2
373,624
67.1
249,930
1,929
16.3
65.8
907,002
3.4
253,969 70.8
180,152
ANAEROBIC
SLUDGE TO BEDS
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK Gallons - % Solids Lbs Dry % Vol Ibs VM Cleaned % Solids Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol, Solids from Anaerobic Dig,
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1,962,181
709,210
577,237
2,036,319
373,624
249,930
50
Weeks 1-4 of 'Ga€Ions TWAS GBT to Anaerohic Digester' is 65 % of
the 'Gravity Thickener to GBT' flow. Bad flow meter.
58 % (VK) 57 % (LBS)
Ibs Polymer $Ilb Poly Cost $IDT
776
$1.75 1,358
3,719 $1.75 6,508 34.84

South Durham Water Reclamation Facility
Sludge Report
July'2022
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
259,497
3.8
82,240
87.8
2
203,542
4.6
77,238
77.4
3
392,839
3.6
117,946
79.5
4
351,931
5.2
152,625
85.0
TOTAL
1,207,809
4.3
430,049
82.4
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,318,800
0.65
71,429
71.9
2
1,317,680
0.71
78,072
71.5
3
1,318,450
0.82
90,433
71.3
4
1,804,623
0.70
105,339
70.8
TOTAL
5,759,553
0.72
345,274
71.4
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
390,185
2.2
71,591
64.6
2
568,763
2.3
106,728
64.8
3
513,612
2.4
102,805
63.4
4
490,115
2.5
102,189
62.3
TOTAL
1,962,675
2.4
383,313
63.8
ANAEROBIC
SLUDGE TO BEDS
lbs VM
72,207
59,782
93,767
129,732
355,487
lbs VM
51,340
55,802
64,434
74,615
246,190
lbs VM
46,248
69,107
65,178
63,664
244,196
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Gallons % Solids Lbs Dry % Vol lbs VM
TWAS GBT TO ANAEROBIC DIGESTER
Gallons
% Solids
Lbs Dry
% Vol
lbs VM
124,844
6.5
67,678
73.7
49,879
129,212
6.3
67,891
72.7
49,322
120,713
6.0
60,405
69.7
42,102
118,150
6.0
59,122
70.6
41,740
492,919
6.2
255,096
71.7
183,044
SD SOLIDS OFF PRESS
Yds
% Solids
% Vol
373
16.0
65.0
512
16.5
64.9
461
16.4
65.2
465
16.5
63.8
1,811
16.4
64.7
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK
Gallons % Solids
Lbs Dry
% Vol
lbs; VM Cleaned % Solids Removed
1
2
280,000
2.3
53,710
64.8
34,804
3
60,000
2.4
12,010
63.4
7,614
4
110,000
2.5
22,935
62.3
14,289
TOTAL
450,000
2.4
88,654
63.5
56,706
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig
Total Gallons from Anaerobic Dig.
Total lbs. of Dry Solids from Anaerobic Dig.
Total lbs, of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1,700,728
685,145
538,531
2,412,675
471,967
300,903
51
GRAVITY THICKENER TO GBT
Gallons
% Solids Lbs Dry
% Vol
lbs VM
192,068
3.0
48,055
72.7
34,936
198,788
3.2
53,053
71.3
37,826
185,713
3.4
52,661
69.8
36,757
181,770
4.7
71,250
67.0
47,738
758,339
3.6
225,019
70.2
157,258
Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Digester' is 65% of
the'Gravlty Thickener to GBT' flow. Bad flow meter.
54 % (VK) 44 % (LBS)
lbs Polymer $/lb Poly Cost $/DT
661
$1.75 1,157
3,774 $1.75 6,605 34.46

South Durham Water Reclamation Facility
Sludge Report
August '2022
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
258,231
3.8
81,839
85.6
2
293,978
5.5
134,848
85.2
3
240,575
4.9
98,313
85.9
4
346,136
3.8
109,697
85.5
TOTAL
1,138,920
4.5
424,697
85.6
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,271,019
0.57
60,195
70.9
2
1,303,875
0.61
66,535
72.8
3
1,399,982
0.71
82,548
72.1
4
2,277,700
0,78
148,910
73A
TOTAL
6,252,576
0.67
358,188
72.3
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
331,356
3.0
82,905
61.9
2
378,979
2.4
75,856
63.0
3
474,304
2.4
94,937
62.9
4
792,943
2.4
158,715
63.7
TOTAL
1,977,582
2.6
412,414
62.9
ANAEROBIC SLUDGE TO BEDS
WEEK
1
2
3
4
TOTAL
Ibs VM
70,054
114,890
84,451
93,791
363,187
Ibs VM
42,695
48,407
59,477
109,369
259,948
ibs VM
51,318
47,790
59,715
101,102
259,925
Gallons % Solids Lbs Dry % Vol Ibs VM
50,000 3.0 12,510 61.9 7,744
50,000 3.0 12,510 61.9 7,744
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig.
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detentson Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1,691,361
677,502
545,409
2,027,582
424,924
267,669
46
GRAVITY THICKENER TO ANAEROBIC DIGESTS
Gallons % Solids Lbs Dry % Vol Ibs VM
TWAS GBT TO ANAEROBIC DIGESTED
Gallons % Solids Lbs Dry % Vol Ibs VM
107,548
6.0
53,817
70.9
38,156
99,049
5.4
44,608
71.9
32,073
124,685
5.8
60,313
72.3
43,606
221,159
5.1
94,068
72.7
68,387
552,441
5.6
262,805
72.0
182,223
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
Yds
% Solids
% Vol
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
291
18.2
60.5
165,458
3.6
49,677
68.7
34,128
362
16.4
64.2
152,383
4.0
50,835
68.7
34,924
454
16.6
62.9
191,823
3.3
52,794
67.6
35,688
739
16.3
64.9
340,244
3.3
93,642
70.6
66,111
1,846
16.9
63.1
849,908
3.6
246,948
68.9
170,851
SOLIDS OFF DRYING BEDS
Beds Yards
Cleaned % Solids Removed
Weeks 1-4 of 'Gallons TWAS GBT to Anaerobic Digester' is 65% of
the 'Gravity Thickener to GBT' flow. Bad flow meter.
61 % (VK) 51 % (LBS)
Ibs Polymer $Ilb Poly Cost $IDT
833
$1.75 1,458
3,608 $1 75 6,314 30.62

South Durham Water Reclamation Facility
Sludge Report
September '2022
SD PRIMARY SLUDGE TO DIGESTER
WFEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
248,388
3.9
80,791
86.5
69,884
2
245,731
4.5
92,223
85.3
78,666
3
257,373
4.2
90,153
84.5
76,179
4
360,481
5.4
156,381
85.0
132,924
TOTAL
1,101,973
4.5
419,547
85.3
357,653
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
1,632,236
0.69
94,065
75.2
70,715
2
1,712,657
0.77
109,330
74.3
81,259
3
1,640.433
0.68
93,189
74.8
69,734
4
1,988,487
0.64
106,064
93.0
98,611
TOTAL
6,973,813
0.70
402,648
79.3
320,319
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
611,087
2.4
122,315
64.0
78,282
2
315,671
2.4
63,185
64.9
41,007
3
512,834
2.4
102,649
65.7
67,440
4
769,081
2.3
147,525
66.4
97,957
TOTAL
2,208,673
2.4
435,674
65.3
284,686
ANAEROBIC
SLUDGE
TO BEDS
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Gallons % Solids Lbs Dry % Vol Ibs VM
TWAS GBT TO ANAEROBIC DIGESTE
Gallons
% Solids
Lbs Dry
% Vol
160,408
6.1
81,606
73.6
99,880
5.6
46,648
73.8
129,087
5.9
63,519
75.1
165,446
6.4
88,308
75.5
554,821
6.0
280,081
74.5
SD SOLIDS OFF PRESS
Yds
% Solids
% Vol
585
15.8
64.8
301
16.0
67.2
471
15.5
67.5
728
15.5
67.1
2,084
15.7
66.7
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK Gallons % Solids Lbs Dry % Vol Ibs VM Cleaned % Solids Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig,
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production F13
Ft3 of Gas Produced/lb of VM added
Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
Ibs VM
60,062
34,426
47,702
66,629
208,819
GRAVITY THICKENER TO GBT
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
246,781
3.5
72,035
71.3
51,361
153,661
3.6
46,135
71.1
32.802
198,595
4.7
77,845
72.6
56,516
254,533
3.7
78,544
73.5
57,730
853,570
3.9
274,560
72.1
198,409
1,656,794
699,628
566,472
Weeks 1-4 of'Gailons TWAS GBT to Anaerobic Digester' is 65% of
2,208,673
the 'Gravity Thickener to GBT' flow. Bad flow meter.
435,674
284,686
°% sofids and % vol for the second week of 'Primary Sludge to Digester' is
46
the average for the month. Sample was not run.
58 % (VK) 50 % (LBS)
Ibs Polymer $Ilb Poly Cost $IDT
917 $1.75 1,605
3,169 $1.75 5,546 25.46

South Durham Water Reclamation Facility
Sludge Report
October '2022
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
lbs VM
1
249,336
5.3
110,211
86.5
95,333
2
257,335
4.3
92,285
89.3
82,411
3
261,088
4.8
104,519
86.7
90,618
4
361,979
4.1
123,775
86.2
106,694
TOTAL
1,129,738
4.6
430,791
87.2
375,056
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
lbs VM
1
1,250,000
0.60
63,012
75.6
47,635
2
1,092,000
0.57
52,107
76.8
40,044
3
1,092,000
0.71
64,818
75.6
49,024
4
1,607,000
0.81
109,149
77.6
84,724
TOTAL
5,041,000
0.67
289,085
76.4
221,426
GRAVITY THICKENER TO ANAEROBIC DIGESTS
Gallons % Solids Lbs Dry % Vol lbs VM
TWAS GBT TO ANAEROBIC DIGESTE
Gallons
% Solids
Lbs Dry
% Vol
113,760
5.8
55,028
74.6
54,867
5.1
23,337
75.1
100,095
6.5
54,261
75.0
132,274
5.8
63,984
76.0
400,996
5.8
196,610
75.2
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
lbs VM
Yds
% Solids
% Vol
1
505,828
2.1
88,591
66.2
58,647
478
15.8
67.4
2
385,765
2.2
70,780
66.9
47,352
331
15.8
66.3
3
482,055
2.0
80,407
66.9
53,792
414
15.9
68A
4
629,795
2.1
110,302
67A
74,344
552
15.8
69.3
TOTAL
2,003,443
2.1
350,080
66.9
234,135
1,774
15.8
67.8
ANAEROBIC
SLUDGE
TO BEDS
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK Gallons % Solids Lbs Dry % Vol lbs VM Cleaned % Solids Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig
Total Gallons from Anaerobic Dig.
Total lbs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1,530,734
627,401
522,956
2,003,443
350,080
234,135
51
lbs VM
41,051
17,526
40,696
48,628
147,901
GRAVITY THICKENER TO GBT
Gallons
% Solids Lbs Dry
% Vol
lbs VM
175,015
5.2
75,901
74.5
56,546
84,410
5.6
39,423
73.0
28,779
153,992
4.2
53,940
74.5
40,186
203,499
3.3
56,007
74.1
41,501
616,916
4.6
225,271
74.0
167,011
Weeks 1-4 of'Gallons TWAS to Anaerobic Digester' is 65% of
the 'Gravity Thickener to GBT' flow. Bad flow meter.
62 % (VK) 55 % (LB5)
lbs Polymer $1lb Poly Cost $1DT
745
$1.75 1,304
2,186 $1.75 3,826 21.86

South Durham Water Reclamation Facility
Sludge Report
November '2022
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
266,270
4.0
88,828
86.7
2
255,998
3.2
68,321
84.7
3
290,727
4.3
104,261
89.3
4
343,306
4.8
137,432
86.7
TOTAL
1,156,301
4.1
398,841
86.9
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,066,000
0.79
70,565
35.7
2
1,330,000
0.70
78,061
78.1
3
1,229,000
0.56
57,619
77.1
4
1,440,000
0.82
98,148
77.7
TOTAL
5,065,000
0.72
304,393
67.2
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Ga}Ions
% Solids
Lbs Dry
% Vol
1
473,848
2.0
79,038
67.6
2
506,423
2.0
84,471
67.0
3
544,260
1.5
68,087
67.0
4
492,502
2.0
82,149
67.4
TOTAL
2,017,033
1.9
313,745
67.3
ANAEROBIC
SLUDGE
TO BEDS
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Ibs VM Gallons % Solids Lbs Dry % Vol Ibs VM
77,014
57,868
93,105
119,154
347,140
TWAS GBT TO ANAEROBIC DIGESTE
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
25,202
104,266
6.7
58,262
76.7
60,960
120,776
6.3
63,458
76.1
44,426
117,922
5.7
56,058
76.6
76,216
123,183
5.7
58,559
76.7
206,803
466,147
6.1
236,336
76.5
SD SOLIDS OFF PRESS
Ibs VM
Yds
% Solids
% Vol
53,430
472
16,0
70.1
56,596
469
15.8
70.1
45,618
503
15.8
70.6
55,369
434
15.8
70A
211,012
1,878
15.9
70.2
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK Gallons % Solids Lbs Dry % Vol Ibs VM Cleaned % Solids Removed
1
2
3
4 70,000 2.0 11,676 67.4 7,870
TOTAL 70,000 2.0 11,676 67.4 7,870
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig,
Total Pounds of Vol. Solids to Anaerobic Qig,
Total Gallons from Anaerobic Dig.
Total lbs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
1,622,448
635,178
527,973
2,087,033
325,421
218,882
47
Ibs VM
44,687
48,292
42,940
44,915
180,833
GRAVITY THICKENER TO GBT
Gallons
% Solids Lbs Dry
% Vol
Ibs VM
160.409
3.7
49,499
75.9
37,570
185,809
2.5
38,741
72.0
27,894
181,419
2.8
42,365
75.2
31,858
189,512
3.7
58,480
75.1
43,918
717,149
3.2
189,085
74.6
141,240
Weeks 1-4 of'Gallons TWAS to Anaerobic Digester' is 65% of
the'Gravity Thickener to GBT' flow. Bad flow meter.
61 % (VK) 59 % (LBS)
Ibs Polymer $/lb Poly Cost $IDT
888
$1.75 1,554
2,126
$1.75 3,721 23.72

South Durham Water Reclamation Facility
Sludge Report
December '2022
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
277,306
5.1
117,949
80.3
94,713
2
305,121
3.6
91,610
90.2
82,632
3
267,308
3.7
82,486
84.8
69,948
4
357,648
3.3
98,432
87.3
85,931
TOTAL
1,207,383
3.9
390,477
85.7
333,224
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
1,026,343
0.73
62,889
78.2
49,203
2
1,010,232
0.74
62,215
77.2
48,049
3
956,400
1.09
86,555
77.4
66,990
4
1,289,512
0.86
92,059
77A
71,261
TOTAL
4,282,487
0.86
303,718
77.6
235,502
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
517,362
2.0
86,296
67.5
58,250
2
464,279
2.2
85,186
67.8
57,756
3
462,164
2.1
80,943
68.4
55,365
4
578,026
2.0
96,415
68.6
66,141
TOTAL
2,021,831
2.1
348,840
68.1
237,512
ANAEROBIC
SLUDGE TO BEDS
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Gallons % Solids Lbs Dry % Vol Ibs VM
TWAS GBT TO ANAEROBIC DIGESTE
Gallons
% Solids
Lbs Dry
% Vol
98,979
5.9
48,704
77.0
111,004
5.9
54,621
77.3
84,020
6.1
42,744
77.5
134,811
6.3
70,270
77.7
428,814
6.1
216,339
77.4
SD SOLIDS OFF PRESS
Yds
% Solids
% Vol
453
15.7
70.4
437
16.8
68.0
393
16.3
70.7
501
15.8
71.4
1,784
16.2
70.1
SOLIDS OFF DRYING BEDS
Beds Yards
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM Cleaned % Solids Removed
1
2
50,000
2.2
9,174
67.8
6,220
3
4
50,000
2.0
8,340
68.6
5,721
TOTAL
100,000
2.1
17,514
68.2
11,941
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BI=P
1,636,197
606,815
500,675
2,121,831
366,354
249,453
48
Ibs VM
37,502
42,222
33,127
54,600
167,450
GRAVITY THICKENER TO GBT
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
152,275
3.4
43,179
75.9
32,773
170,775
3.2
45,576
75.7
34,501
129,261
4.3
46,356
75.4
34,952
207,402
3.9
67,460
75.8
51,101
659,713
3.7
202,571
75.7
153,327
Weeks 1-4 of 'Gallons TWAS to Anaerobic Digester' is 65% of
the 'Gravity Thickener to GBT' Flaw. Bad Flow meter.
58 % (VK) 50 % (LBS)
Ibs Polymer $/lb Poly Cost $1DT
860
$1.75 1,505
2,070 $1.75 3,623 20.77

Page 1 of 1
Report No: 22-048-0677
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Henry Thorpe
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm: GR05
Date Received: 02/17/2022
Date of Report: 02/18/2022
Lab No Field ID
Sample ID
Soil Class
HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
17026
01
MIN
2.0
5.4
1.6
176
32
31
94
0 0
695
695
175
5.7
72
44
24
2.0
0.1
17027
04
MIN
1.8
5.6
1.5
143
38
12
281
0 0
683
683
215
6.6
77
46
27
1.3
0.1
17029
03
MIN
1.2
5.3
1.4
257
28
31
206
0 0
928
928
215
4.5
69
42
22
1.7
0.1
Comment:
Did not receive sample 05
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY22-SL029473
k5i I"14'4+;4
Client:
Henry Thorpe
Advisor: Brent Collins
Predictive
5676 Old Roxboro Rd.
EMA Resources Inc
°± f'
Oxford, NC 27565
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Granville
_1
Links to Helpful Information
Sampled: Received: 03/17/2022 Completed: 03/30/2022 Farm: GR05
Client ID:
279166
Advisor ID: 405413
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.0 120-200 0
80
0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.41 1.04 8.3 81 1.6 5.9 204 27 54 25
33 734
457 1082 1082
245 0.1 1
Sample ID: 00005
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim, M 1.1 120-200 0
100
0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-AI2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.18 1.05 7.0 72 2.0 5.3 150 21 46 24
54 87
69 676 676
209 0.1 1
North Carolina
Tai wLm Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL016425
k5i I"14'4+;4
Client: Henry Thorpe
Advisor: Brent Collins
Predictive
5676 Old Roxboro Rd.
EMA Resources Inc
°± f'
Oxford, NC 27565
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Granville
_1
Links to Helpful Information
Sampled: Received: 11/17/2022 Completed: 12/21/2022 Farm: GRO5
Client ID: 279166
Advisor ID: 405413
Sample ID: 00004
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O Mg S Mn Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim, M 1.0 120-200 0
50 0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.51 1.23 8.0 73 2.1 5.5 112 43 50 20
73 1872 1140 643 643
235 0.1 1
Sample ID: 00005
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O Mg S Mn Zn
Cu B
Information
Lime History:
1 -Fescue/OGrass/Tim, M 0.0 120-200 80
110 0 20 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.13 1.15 6.0 78 1.3 6.0 24 16 46 30
25 94 73 46 46
27 0.1 2
North Carolina
Tai wLm Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY23-SL016425
Henry Thorpe
Page 2 of 3
Sample ID: 00007
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg
S
Mn Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim, M 1.0
120-200 100
120
0
0
0 0
0 0
Note: 12
2- 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg% S-1
Mn-I
Mn-All
Mn-Al2
Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.60 1.15 4.9 61 1.9 5.3 16 12
43 16 38
255
170
119 119
83 0.1 2

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL012935
k5i I"14'4+;4
Client: Henry Thorpe
Advisor: Brent Collins
Predictive
5676 Old Roxboro Rd.
EMA Resources Inc
°± f'
Oxford, NC 27565
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Granville
_1
Links to Helpful Information
Sampled: Received: 11/04/2022 Completed: 11/21/2022 Farm: GR05
Client ID: 279166
Advisor ID: 405413
Sample ID: 00006
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O Mg S Mn Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.9 120-200 0
120 0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.27 1.10 6.6 76 1.6 5.3 93 12 57 18
48 198 136 351 351
564 0.1 2
North Carolina
Tai wLm Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

Page 1 of 1
Report No: 22-025-0824
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Milton Latta
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm: OR01
Date Received:01/25/2022
Date of Report: 01/26/2022
Lab No Field ID
Sample ID
Soil Class
HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
23550
01
MIN
2.3
6.0
1.5
166
46
35
425
0 0
975
975
265
9.8
85
58
24
0.8
0.1
23551
02
MIN
2.0
5.7
1.7
171
37
37
606
0 0
683
683
230
8.1
78
54
22
0.9
0.1
23552
03
MIN
1.8
5.2
1.6
129
69
69
1106
0 0
405
405
150
4.6
66
39
18
1.4
0.1
23554
04
MIN
1.9
6.2
0.7
90
26
42
863
0 0
305
305
120
6.1
88
57
27
1.3
0.1
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-025-0826
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Bettie Harrison
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm: OR04
Date Received:01/25/2022
Date of Report: 01/26/2022
Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-I K-I S-I Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I CEC BS % Ca % Mg % ESP Na
23557 01 MIN 2.5 6.6 0.8 363 25 37 494 0 0 928 928 385 13.4 94 79 13 0.7 0.1
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL000910
kSi l"14'4+;4
Client: David Walker
Advisor:
Brent Collins
Predictive
2909 Walker Road
EMA Resources Inc
°± f'
Hillsborough, NC 27278
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Orange
_1
Links to Helpful Information
Sampled: Received: 07/18/2022 Completed: 07/26/2022 Farm:OR05
Client ID: 526908
Advisor
ID: 405413
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O Mg S Mn
Zn
Cu
B
Information
Lime History:
1-Fescue/OGrass/Tim, M 1.5 120-200 0
80 0 0 0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0 120-200 0
80 0 0 0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.22 0.96 8.7 70 2.6 5.2 249 31 47 21
56 640 401 401 793
793
369
0.1 1
Sample ID: 00003
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O Mg S Mn
Zn
Cu
B
Information
Lime History:
1-Fescue/OGrass/Tim, M 1.7 120-200 0
0 0 0 0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0 120-200 0
0 0 0 0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I Mn-All Mn-AI2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.32 0.98 7.0 61 2.7 5.0 267 82 39 16
69 1034 637 637 994
994
378
0.1 1
North Carolina
Tai wLm Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No.
FY23-SL000910
David Walker
Page 2 of 3
Sample ID: 00004
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg
S
Mn
Zn
Cu B
Information
Lime History:
1 -Fescue/OGrass/Tim, M 0.0
120-200 0
60
0
0
pH$
0
0 0
Note: 12 Note: $
2 - Fescue/OGrass/Tim, M 0.0
120-200 0
60
0
0
pH$
0
0 0
Note: 12 Note: $
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg% S-1
Mn-I
Mn-All
Mn-Al2
Zn-I
Zn-AI
Cu-I Na ESP
SS-1 NO3-N
0.32 1.08 8.1
87 1.0 6.6 152 39
57 28 27
1400
848
848
454
454
242 0.1
1

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL000907
kSi l"14'4+;4
Client:
Ronald Walker
Advisor:
Brent Collins
Predictive
3626 NC 57 N
EMA Resources Inc
°± f'
Hillsborough, NC 27278
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Orange
_1
Links to Helpful Information
Sampled: Received: 07/18/2022 Completed: 07/26/2022 Farm:OR06
Client ID:
69935
Advisor
ID: 405413
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.6 120-200 0
80
0 0 0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0 120-200 0
80
0 0 0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-Al2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.36 1.00 12.7 83 2.2 5.8 515 30 68 13
45 464
295 295 1500
1500
566
0.1 1
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.8 120-200 0
70
0 0 0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0 120-200 0
70
0 0 0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-AI2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.46 1.08 6.9 73 1.8 5.5 95 35 52 19
37 411
264 264 305
305
224
0.2 3
North Carolina
Tai wLm Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

Page 1 of 1
Report No: 22-025-0825
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Richard Vanhook
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm: OR15
Date Received:01/25/2022
Date of Report: 01/26/2022
Lab No Field ID
Sample ID
Soil Class
HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
23555
01
MIN
1.0
6.3
0.5
107
16
33
250
0 0
238
238
105
4.3
89
52
34
2.1
0.1
23556
03
MIN
1.5
6.0
0.9
84
34
54
581
0 0
148
148
100
5.6
84
55
25
1.3
0.1
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-025-0827
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: William Breeze Jr.
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm: OR76
Date Received:01/25/2022
Date of Report: 01/26/2022
Lab No Field ID
Sample ID
Soil Class
HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
23558
06
MIN
1.1
5.9
0.7
369
16
35
263
0
0
1080
1080
230
4.1
83
57
20
4.0
0.2
23559
09
MIN
2.1
5.4
2.0
369
32
60
269
0
0
1368
1368
275
7.0
71
47
18
3.2
0.2
23560
10
MIN
1.8
5.3
2.2
318
32
52
588
0
0
1868
1868
305
7.0
69
49
15
2.7
0.2
23561
12
MIN
2.2
5.4
1.8
167
24
44
850
0
0
1405
1405
240
6.3
71
47
19
3.9
0.2
23562
13
MIN
1.9
5.6
1.5
112
55
56
581
0
0
513
513
170
6.4
76
46
22
4.2
0.3
23563
17
MIN
1.5
5.9
0.9
203
17
33
606
0
0
768
768
210
5.4
83
58
22
1.9
0.1
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-038-1149
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: William Breeze
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm: OR76
Date Received: 02/07/2022
Date of Report: 02/08/2022
Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I CEC BS % Ca % Mg % ESP Na
10090 7 MIN 1.3 6.2 0.7 390 32 31 313 0 0 1120 1120 235 5.8 89 62 22 1.0 0.1
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL000908
kSi l"14'4+;4
Client:
LJ Rogers
Advisor:
Brent Collins
Predictive
7912 NC Hwy 49
EMA Resources Inc
°± f'
Mebane, NC 27302
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Orange
_
Links to Helpful Information
Sampled: Received: 07/18/2022 Completed: 07/26/2022 Farm:OR93
Client ID:
532835
Advisor
ID: 405413
Sample ID: 0008A
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.7 120-200 0
120
0 0 0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0 120-200 0
120
0 0 0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-Al2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.46 1.16 4.5 66 1.5 5.5 253 12 55 10
29 166
117 117 941
941
144
0.1 2
Sample ID: 0008B
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1 -Fescue/OGrass/Tim, M 0.0 120-200 0
50
0 0 pH$
0
0
0
Note: 12 Note: $
2 - Fescue/OGrass/Tim, M 0.0 120-200 0
50
0 0 pH$
0
0
0
Note: 12 Note: $
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-AI2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.27 1.15 9.5 97 0.3 7.3 191 45 77 18
26 371
219 219 599
599
102
0.1 1
North Carolina
Tai wLv Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No.
FY23-SL000908
LJ Rogers
Page 2 of 3
Sample ID: 00014
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg
S
Mn
Zn
Cu B
Information
Lime History:
1 -Fescue/OGrass/Tim, M 0.0
120-200 0
20
0
20
pH$
0
0 0
Note: 12 Note: $
2 - Fescue/OGrass/Tim, M 0.0
120-200 0
20
0
20
pH$
0
0 0
Note: 12 Note: $
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg% S-1
Mn-I
Mn-All
Mn-Al2
Zn-I
Zn-AI
Cu-I Na ESP
SS-1 NO3-N
0.32 1.17 7.2
91 0.6 6.8 112 62
71 15 22
654
397
397
368
368
129 0.1
1

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL000909
k5i I"14'4+;4
Client:
Tommy Gentry
Advisor:
Brent Collins
Predictive
3220 Mt Zion Ch Rd
EMA Resources Inc
°± f'
Mebane, NC 27302
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Orange
_1
Links to Helpful Information
Sampled: Received: 07/18/2022 Completed: 07/26/2022 Farm:OR94
Client ID:
386665
Advisor
ID: 405413
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.0 120-200 0
10
0 0 0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0 120-200 0
10
0 0 0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-Al2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.32 1.14 9.3 89 1.0 6.3 167 78 67 18
124 600
373 373 342
342
165
0.2 2
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1 -Fescue/OGrass/Tim, M 0.0 120-200 0
70
0 25 pH$
0
0
0
Note: 12 Note: $
2 - Fescue/OGrass/Tim, M 0.0 120-200 0
70
0 25 pH$
0
0
0
Note: 12 Note: $
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-AI2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.27 1.32 5.8 89 0.6 6.7 253 35 75 11
20 361
224 224 212
212
80
0.1 2
North Carolina
Tai wLm Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL010622
k5i I"14'4+;4
Client:
Alfred Gentry
Advisor: Brent Collins
Predictive
76 Dennys Store Rd
EMA Resources Inc
°± f'
Roxboro, NC 27574
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Person
_1
Links to Helpful Information
Sampled: Received: 10/24/2022 Completed: 11/03/2022 Farm: PS03
Client ID:
445972
Advisor ID: 405413
Sample ID: 00003
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.9 120-200 30
110
0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.27 1.08 7.9 74 2.0 5.5 46 14 53 20
26 209
142 210 210
124 0.1 1
Sample ID: 00004
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn Zn
Cu B
Information
Lime History:
1 -Fescue/OGrass/Tim, M 0.0 120-200 140
110
0 20 pH$ 0
0 0
Note: 12 Note: $
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-AI2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.32 1.12 8.5 98 0.2 7.2 3 17 83 14
17 992
593 35 35
90 0.1 1
North Carolina
Tai wLm Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008147
k5i I"14'4+;4
Client:
Roy Corver
Advisor:
Brent Collins
Predictive
1220 Morton Pulliam Rd.
EMA Resources Inc
°± f'
Roxboro, NC 27574
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Person
_1
Links to Helpful Information
Sampled: Received: 10/11/2022 Completed: 10/20/2022 Farm: PS07
Client ID:
535588
Advisor
ID: 405413
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S
Mn
Zn
Cu
B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.3 120-200 0
110
0 0
0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0 120-200 0
110
0 0
0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.36 1.26 7.6 83 1.3 5.8 71 17 63 19
41 1275 782 782
331
331
121
0.1 1
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S
Mn
Zn
Cu
B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.3 120-200 100
90
0 0
0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0 120-200 100
90
0 0
0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-AI2
Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.18 1.28 10.4 93 0.8 5.6 16 22 58 33
28 819
508 508
70
70
85
0.1 1
North Carolina
Tcbwim Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL000906
k5i I"14'4+;4
Client:
Roy Carver
Advisor:
Brent Collins
Predictive
1220 Morton Pulliam Rd
EMA Resources Inc
°± f'
Roxboro, NC 27574
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Person
_1
Links to Helpful Information
Sampled: Received: 07/18/2022 Completed: 07/26/2022 Farm: PS07
Client ID:
509635
Advisor
ID: 405413
Sample ID: 00003
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1 -Fescue/OGrass/Tim, M 0.0 120-200 50
80
0 20 pH$
0
0
0
Note: 12 Note: $
2 - Fescue/OGrass/Tim, M 0.0 120-200 50
80
0 20 pH$
0
0
0
Note: 12 Note: $
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-Al2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.27 1.23 9.5 89 1.0 6.5 39 29 62 25
22 498
308 308 101
101
74
0.1 1
Sample ID: 00004
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1 -Fescue/OGrass/Tim, M 0.0 120-200 0
110
0 0 pH$
0
0
0
Note: 12 Note: $
2 - Fescue/OGrass/Tim, M 0.0 120-200 0
110
0 0 pH$
0
0
0
Note: 12 Note: $
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-AI2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.22 1.15 11.2 91 1.0 6.7 87 17 74 17
35 266
166 166 273
273
112
0.1 1
North Carolina
Tcbwim Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL010623
k5i I"14'4+;4
Client: Roy Carver
Advisor: Brent Collins
Predictive
1220 Morton Pulliam Rd
EMA Resources Inc
°± f'
Roxboro, NC 27574
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Person
_1
Links to Helpful Information
Sampled: Received: 10/24/2022 Completed: 11/03/2022 Farm: PS07
Client ID: 509635
Advisor ID: 405413
Sample ID: 00005
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O Mg S Mn Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim, M 0.0 120-200 0
100 0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.46 1.19 9.1 83 1.5 5.9 93 19 57 25
29 410 263 109 109
205 0.1 1
North Carolina
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Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture