WQ0014868_2022 Residual Annual Report_20230228 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0014868
Applicant/Permittee Smithfield Fresh Meats Corp.
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Fayetteville
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Brent Collins
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
336-399-3646
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0014868
Has Current Existing permit number
Applicant/Permittee Address*
PO Box 99, Tarheel, NC 28392
Facility Name*
Smithfield Fresh Meats Corp. Class B Residuals
Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Smithfield Fresh Meats Annual Report -
7.98MB
WQ0014868.pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
�r�rrt�ot�ly r
Submission Date 2/28/2023

February 28, 2023
DENR/Water Quality Section
Non -Discharge Compliance Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2022 Annual Report — Smithfield Fresh Meats Corp.
Treatment and Land Application of Residuals
Permit No. WQ0014868
Dear Sir or Madam:
Enclosed is the 2022 Annual Report for the above referenced land application permit.
During 2022 EMA Resources, Inc. land applied 1042.04 dry tons of wastewater residuals
to 374.7 acres of private farmland. Please contact Brent Collins - Director of Technical
Services if you have any further questions regarding this report.
Sincerely,
Z.-e4:241-
Brent Collins
Director of Technical Services
brent.collins&emaresourcesinc.com
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

--Resources, Inc.
Smithfield Fresh Meats
Tar Heel Facility
2022 Annual Report
Residuals Land Application
Permit No. WQ0014868
Prepared By:
EMA Resources, Inc.
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0014868 County: Bladen Year:
2022
Facility Name (as shown on permit):
Land Application Operator:
Smithfield Fresh Meats Corp.
EMA Resources Inc.
Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
El Yes 0 No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in thepermit:
37
Total number of fields utilized for land application during the year:
17
Total amount of dry tons applied during the year for all application sites:
1042.04
Total number of acres utilizes for land application during the year:
374..7
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Quality. R1 Yes 0 No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Andrea Tucker - Complex Plant Manager
Permittee Name and Title (type or print)
✓�Gi�G Bgff
Dwayne uss (Feb 10, 2023 07:26 EST)
Feb 10, 2023
AWIea Txlrel-
Andrea Tucker (Feb 13, 2023 18:02 EST)
Signature of Permittee
Z�fz
Feb 13, 2023
Date
1/26/2023
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WQ0014868 Laboratory:
Smithfield Fresh Meats Corp.
NCO078344
WWTP Name: Tarheel Plant WWTP
Recidnal AnAvcic Data
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
(mg/kg)
Conc.
Limit
(mg/kg a
Sample or Composite Date
North
1/3/22
South
1/3/22
North
2/21/22
South
2/21/22
Percent Solids (%)
NA
4.2
4.63
4
4.05
Arsenic
75
5.71
5.22
6
5.45
Cadmium
85
0.669
0.522
0.713
0.743
Copper
4,300
1250
1180
1230
1110
Chromium
NA
69.3
62.4
66.3
56.8
Lead
840
11
10.9
10.60
9.66
Mercury
57
0.16
0.146
0.169
0.153
Molybdenum
75
15.7
15.8
15.4
13.8
Nickel
420
61
55.9
59
50.7
Selenium
100
7.62
6.96
8.0
7.27
Zinc
7,500
2900
2780
2800
2590
Total Phosphorus
NA
21500
23900
27500
20400
TKN
NA
80500
81100
70500
63000
Ammonia -Nitrogen
NA
11400
12400
14300
13000
Nitrate and Nitrite
NA
181
140
116
125
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
✓�wa��re ,��rr
�:2ti ES�� Feb 10, 2023
arync uss (Feb 111, 211230
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name: Smithfield Fresh Meats Corp.
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
NCO078344
Tarheel Plant WWTP
Laboratory: 1) Waypoint Analytical
2)
3)
4)
5)
Parameter
Sample or Composite Date
South
111
1 11
11
• 1
--------
11
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Feb 10, 2023
Date
DENR FORM RSSF - B (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 49.18
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only):
Operator: Steve Dunham Owner: Steve Dunham Predominant Soil Series: LaB
Acres Used: 21.6 Acres Permitted: 21.6 Site #: SF03 Field #: 1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.28
Arsenic
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
5.431
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.431
Chromium
0.290
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.290
Lead
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.069
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.069
denum
Nickel
0.258
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.258
Selenium
0.034
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Zinc
12.603
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.603
Total
Phos-
106.222
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
106.222
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Steve Dunham
Operator: Steve Dunham
Crop 1 Name: Bermuda -Pasture
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 49.18 Site #:
Predominant Soil Series: LaB
Crop 1 Max. PAN:
110.25
Crop 2 Name:
Acres Utilized:
SF03 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
21.6
21.6
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/14
162500
4.22
1.324
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
49.587
NA
Bermuda
2/15
117000
4.22
0.953
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
35.703
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
279500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
85.290
o.000
Lime Applied
Annuallbs/acre
0.026
0.003
5.431
0.290
0.048
0.001
0.069
0.258
0.034
12.603
106.222
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.29
0.096
41.325
2.35
0.655
0.022
1.243
3.633
0.388
169.61
Current Cumulative lbs/ac
0.316
0.099
46.756
2.640
0.703
0.023
1.312
3.891
0.422
182.213
Permitted C. P. L. R.****
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
110.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Fresh Meats Total Dry Tons Applied (Annual): 36.60
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): 8.3
Operator: Steve Dunham Owner: Steve Dunham Predominant Soil Series: Cc
Acres Used: 13.3 Acres Permitted: 13.3 Site #: SF03 Field #: 2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.75
Arsenic
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
6.564
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.564
Chromium
0.351
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.351
Lead
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.084
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.084
denum
Nickel
0.312
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.312
Selenium
0.041
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
Zinc
15.232
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
15.232
Total
Phos-
128.381
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
128.381
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Smithfield Fresh Meats
Steve Dunham
Operator: Steve Dunham
Crop 1 Name: Bermuda Pasture
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 36.60 Site #:
Predominant Soil Series: Ce
Crop 1 Max. PAN:
131.25 Crop 2 Name:
2
SF03
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
13.3
13.3
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/14
71500
4.22
0.946
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
35.434
NA
Bermuda
1/15
136500
4.22
1.806
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
67.647
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
208000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
103.082
o.000
Lime Applied
Annuallbs/acre
0.031
0.004
6.564
0.351
0.058
0.001
0.084
0.312
0.041
15.232
128.381
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.401
0.095
48.231
2.198
0.835
0.023
1.208
4.225
0.497
179.011
Current Cumulative lbs/ac
0.432
0.099
54.795
2.549
0.893
0.024
1.292
4.537
0.538
194.243
Permitted C. P. L. R. * * * *
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
i
F-131.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 61.77
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only):
Operator: Steve Dunham Owner: Steve Dunham Predominant Soil Series: Cc
Acres Used: 21.3 Acres Permitted: 21.3 Site #: SF03 Field #: 3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.90
Arsenic
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
6.917
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.917
Chromium
0.369
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.369
Lead
0.061
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.061
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.088
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.088
denum
Nickel
0.329
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.329
Selenium
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.043
Zinc
16.052
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.052
Total
Phos-
135.285
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
135.285
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Steve Dunham
Operator: Steve Dunham
Crop 1 Name: Bermuda Pasture
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 61.77 Site #:
Predominant Soil Series: Ce
Crop 1 Max. PAN:
131.25
Crop 2 Name:
Acres Utilized:
SF03 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
21.3
21.3
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/12
97500
4.22
0.806
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
30.171
NA
Bermuda
1/13
149500
4.22
1.235
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
46.263
NA
Bermuda
1/14
97500
4.22
0.806
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
30.171
NA
Bermuda
1/26
6500
4.22
0.054
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
2.011
NA
Bermuda
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
3510001
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
108.617
o.000
Lime Applied
Annuallbs/acre
0.032
0.004
6.917
0.369
0.061
0.001
0.088
0.329
0.043
16.052
135.285
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.411
0.109
41.601
1.821
0.71
0.019
1.005
3.398
0.501
152.055
Current Cumulative lbs/ac
0.443
0.113
48.518
2.190
0.771
0.020
1.093
3.727
0.544
168.107
Permitted C. P. L. R.****
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
i
F-131.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 59.47
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): 9.8
Operator: Steve Dunham Owner: Steve Dunham Predominant Soil Series: Wh
Acres Used: 19 Acres Permitted: 19 Site #: SF03 Field #: 4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
3.13
Arsenic
0.035
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
7.465
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
7.465
Chromium
0.399
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.399
Lead
0.066
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.066
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.095
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.095
denum
Nickel
0.355
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.355
Selenium
0.047
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.047
Zinc
17.325
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
17.325
Total
Phos-
146.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
146.015
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Steve Dunham
Operator: Steve Dunham
Crop 1 Name: Corn
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 59.47 Site #:
Predominant Soil Series: Wh
Crop 1 Max. PAN:
150 Crop 2 Name:
4
SF03
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
19
19
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/27
143000
4.22
1.324
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
49.608
NA
Corn
2/15
52000
4.22
0.482
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
18.039
NA
Corn
2/16
130000
4.22
1.204
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
45.098
NA
Corn
2/26
13000
4.22
0.120
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
4.510
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
338000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
117.255
0.000
Lime Applied
Annuallbs/acre
0.035
0.004
7.465
0.399
0.066
0.001
0.095
0.355
0.047
17.325
146.015
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.193
0.059
17.984
1.681
0.365
0.012
0.674
2.029
0.242
90.766
Current Cumulative lbs/ac
0.228
1 0.063
25.449
2.080
0.431
0.013
0.769
2.384
0.289
108.091
Permitted C. P. L. R.****1
9
1 250
1
1 1000
1
1
1 250
1
1 500
Permit PAN Limit lst/2nd Crop
1
1 150
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 22.88
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): 7.8
Operator: Steve Dunham Owner: Steve Dunham Predominant Soil Series: LaB
Acres Used: 8 Acres Permitted: 8 Site #: SF03 Field #: 5
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.86
Arsenic
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
6.821
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.821
Chromium
0.364
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.364
Lead
0.060
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.087
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.087
denum
Nickel
0.324
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.324
Selenium
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.043
Zinc
15.830
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
15.830
Total
Phos-
133.419
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
133.419
horus
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Steve Dunham
Operator: Steve Dunham
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 22.88 Site #:
Predominant Soil Series: LaB
Crop 1 Max. PAN:
147
Crop 2 Name:
Acres Utilized:
SF03 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Q
Volume applied
enter one Solids/
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A hed er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
4 �
F
w
*o•
o
,•d 2
#
4
w ,
* N
*�
TKN
mg/kg
Z
;
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/26
130000
4.22
2.860
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
1 73775
12775
140.5
107.108
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
130000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
107.1081
0.000
Lime Applied
Annuallbs/acre
0.032
0.004
6.821
0.364
0.060
0.001
0.087
0.324
0.043
15.830
133.419
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.297
0.083
29.827
1.504
0.452
0.014
0.738
2.396
0.371
112.414
Current Cumulative lbs/ac
0.329
0.087
36.648
1.868
0.512
0.015
0.825
2.720
0.414
128.244
Permitted C. P. L. R.****
1 9
1 250
1
1 1000
1
250
500
Permit PAN Limit lst/2nd Crop
1 147
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 67.49
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): 4.9
Operator: Steve Dunham Owner: Steve & John Dunham Predominant Soil Series: LaB
Acres Used: 16.5 Acres Permitted: 16.5 Site #: SF03 Field #: 6
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
4.09
Arsenic
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Cadmium
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
9.755
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.755
Chromium
0.521
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.521
Lead
0.086
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.086
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.124
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.124
denum
Nickel
0.463
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.463
Selenium
0.061
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.061
Zinc
22.638
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
22.638
Total
Phos-
190.799
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
190.799
horus
1
1
1
1
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Steve & John Dunham
Operator: Steve Dunham
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 67.49 Site #:
Predominant Soil Series: LaB
Crop 1 Max. PAN:
196 Crop 2 Name:
6
SF03
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
16.5
16.5
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1/28
156000
4.22
1.664
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
62.318
NA
Bermuda
1/31
149500
4.22
1.594
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
59.721
NA
Bermuda
2/4
78000
4.22
0.832
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
31.159
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
383500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
153.197
o.000
Lime Applied
Annuallbs/acre
0.046
0.005
9.755
0.521
0.086
0.001
0.124
0.463
0.061
22.638
190.799
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.228
0.077
25.781
1.357
0.471
0.016
0.924
2.736
0.296
124.49
Current Cumulative lbs/ac
0.274
0.082
35.536
1.878
0.557
0.017
1.048
3.199
0.357
147.128
Permitted C. P. L. R.****
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
i
F 196
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Smithfield Farmland Corp. Total Dry Tons Applied (Annual):
WQ0014868 Cation Exchange Capacity (non 503 only):
Steve Dunham Owner: Steve Dunham Predominant Soil Series:
37.2 Acres Permitted: 37.2 Site #: SF03 Field #
162.42
WmB
7
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
4.37
Arsenic
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.049
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
10.413
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
10.413
Chromium
0.556
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.556
Lead
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.092
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.133
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.133
denum
Nickel
0.495
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.495
Selenium
0.065
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.065
Zinc
24.166
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
24.166
Total
Phos-
203.674
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
203.674
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4;�r-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Steve Dunham
Operator: Steve Dunham
Crop 1 Name: Rye Grass - Hay
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 162.42 Site #:
Predominant Soil Series: WmB
Crop 1 Max. PAN:
210
Crop 2 Name:
Acres Utilized:
SF03 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
37.2
37.2
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A hed er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
4 �
F
w
*o•
o
,•d 2
#
4
w ,
* N
*�
TKN
mg/kg
Z
;
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/17
175500
4.22
0.830
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
1 140.5
31.096
NA
Rye
2/21
117000
4.22
0.553
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
20.731
NA
Rye
2/22
117000
4.22
0.553
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
20.731
NA
Rye
2/23
136500
4.22
0.646
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
24.186
NA
Rye
2/24
117000
4.22
0.553
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
20.731
NA
Rye
2/25
136500
4.22
0.646
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
1 140.5
24.186
NA
Rye
2/26
123500
4.22
0.584
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
21.882
NA
Rye
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
923000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
163.5421
0.000
Lime Applied
Annuallbs/acre
0.049
0.006
10.413
0.556
0.092
0.001
0.133
0.495
0.065
24.166
203.674
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.107
0.056
24.118
3.501
0.655
0.013
0.678
2.506
0.152
107.128
Current Cumulative lbs/ac
0.156
1 0.062
34.531
4.057
0.747
0.014
0.811
3.001
0.217
131.294
Permitted C. P. L. R.****
9
1 250
1
1 1000
1
250
500
Permit PAN Limit lst/2nd Crop
1 210
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual):
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only):
Operator: Vance Tyson Owner: Vance Tyson Predominant Soil Series:
Acres Used: 77 Acres Permitted: 77 Site #: SF06 Field #:
188.73
5.3
De
7
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.45
Arsenic
0.027
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
5.846
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.846
Chromium
0.312
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.312
Lead
0.052
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.074
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.074
denum
Nickel
0.278
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.278
Selenium
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Zinc
13.566
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
13.566
Total
Phos-
114.339
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
114.339
horus
1
1
1
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4;�r-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Vance Tyson
Operator: Vance Tyson
Crop 1 Name: Corn
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 188.73 Site #:
Predominant Soil Series: De
Crop 1 Max. PAN:
120
Crop 2 Name:
Acres Utilized:
SF06 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
77
77
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/8
97500
4.22
0.223
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
8.346
NA
Corn
3/9
117000
4.22
0.267
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
10.015
NA
Corn
3/15
130000
4.22
0.297
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
11.128
NA
Corn
3/16
149500
4.22
0.342
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
12.797
NA
Corn
3/18
1
136500
4.22
0.312
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
11.685
NA
Corn
3/19
130000
4.22
0.297
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
11.128
NA
Corn
3/20
136500
4.22
0.312
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
11.685
NA
Corn
3/21
104000
4.22
0.238
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
8.903
NA
I Corn
3/22
71500
4.22
1 0.163
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
1 73775
12775
1 140.5
6.120
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
1072500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
91.807
o.000
Lime Applied
Annuallbs/acre
0.027
0.003
5.846
0.312
0.052
0.001
0.074
0.278
0.037
13.566
114.339
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.044
0.014
3.051
0.431
0.079
0.002
0.124
0.399
0.059
16.104
Current Cumulative lbs/ac
0.071
1 0.017
8.897
0.743
0.131
0.003
0.198
0.677
0.096
29.670
Permitted C. P. L. R.****
9
1 250
1
1 1000
1
1
1 250
1
1 500
Permit PAN Limit lst/2nd Crop
1 120
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Smithfield Farmland Corp. Total Dry Tons Applied (Annual):
WQ0014868 Cation Exchange Capacity (non 503 only):
Steve Dunham
Owner: JW Burney Predominant Soil Series:
21.8 Acres Permitted: 21.8 Site #: SF07 Field #:
57.18
Aa
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
OEM
MEMO
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
.fir
Event
2.62
Arsenic
0.029
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
6.256
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.256
Chromium
0.334
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.334
Lead
0.055
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.055
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
denum
Nickel
0.297
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.297
Selenium
0.039
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.039
Zinc
14.518
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
14.518
Total
Phos-
122.363
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
122.363
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4;�r-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: JW Burney
Operator: Steve Dunham
Crop 1 Name: Bermuda -Pasture
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 57.18 Site #:
Predominant Soil Series: Aa
Crop 1 Max. PAN:
155
Crop 2 Name:
Acres Utilized:
SF07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
21.8
21.8
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/12
52000
4.22
0.420
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
15.722
NA
Bermuda
3/3
110500
4.22
0.892
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
33.410
NA
Bermuda
3/4
136500
4.22
1.102
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
41.271
NA
Bermuda
3/5
26000
4.22
0.210
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
7.861
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
325000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
98.265
o.000
Lime Applied
Annuallbs/acre
0.029
0.003
6.256
0.334
0.055
0.001
0.080
0.297
0.039
14.518
122.363
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.285
0.245
102.053
1.459
1.365
0.022
1.164
2.657
0.416
303.982
Current Cumulative lbs/ac
0.314
0.248
108.309
1.793
1.420
0.023
1.244
2.954
0.455
318.500
Permitted C. P. L. R.****
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
i
F-155
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Smithfield Farmland Corp. Total Dry Tons Applied (Annual):
WQ0014868 Cation Exchange Capacity (non 503 only):
Steve Dunham
Owner: JW Burney Predominant Soil Series:
12.3 Acres Permitted: 12.3 Site #: SF07 Field #:
28.60
Aa
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.33
Arsenic
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
5.545
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.545
Chromium
0.296
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.296
Lead
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.049
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.071
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.071
denum
Nickel
0.263
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.263
Selenium
0.035
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Zinc
12.869
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.869
Total
Phos-
108.461
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
108.461
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4;�r-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: JW Burney
Operator: Steve Dunham
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 28.60 Site #:
Predominant Soil Series: Aa
Crop 1 Max. PAN:
138
Crop 2 Name:
Acres Utilized:
SF07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
12.3
12.3
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/2
26000
4.22
0.372
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
13.933
NA
Fescue
3/5
136500
4.22
1.953
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
73.147
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
162500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
87.080
o.000
Lime Applied
Annuallbs/acre
0.026
0.003
5.545
0.296
0.049
0.001
0.071
0.263
0.035
12.869
108.461
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.074
0.034
13.353
2.414
0.516
0.009
0.516
1.725
0.125
81.015
Current Cumulative lbs/ac
0.100
0.037
18.898
2.710
0.565
0.010
0.587
1.988
0.160
93.884
Permitted C. P. L. R. * * * *
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
i
Fl-38
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Smithfield Farmland Corp. Total Dry Tons Applied (Annual):
WQ0014868 Cation Exchange Capacity (non 503 only):
Steve Dunham
Owner: JW Burney Predominant Soil Series:
19.3 Acres Permitted: 19.3 Site #: SF07 Field #:
51.47
WmB
6
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.67
Arsenic
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
6.361
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.361
Chromium
0.340
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.340
Lead
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.056
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.081
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.081
denum
Nickel
0.302
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.302
Selenium
0.040
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
Zinc
14.762
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
14.762
Total
Phos-
124.416
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
124.416
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4;�r-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: JW Burney
Operator: Steve Dunham
Crop 1 Name: Bermuda -Pasture
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 51.47 Site #:
Predominant Soil Series: WmB
Crop 1 Max. PAN:
162 Crop 2 Name:
6
SF07
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
19.3
19.3
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/1
6500
4.22
0.059
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
2.220
NA
Bermuda
2'2
188500
4.22
1.719
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
64.376
NA
Bermuda
2'3
97500
4.22
0.889
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
33.298
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
292500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
99.894
o.000
Lime Applied
Annuallbs/acre
0.030
0.004
6.361
0.340
0.056
0.001
0.081
0.302
0.040
14.762
124.416
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.364
0.262
113.045
6.567
1.885
0.03
1.734
15.161
0.484
384.576
Current Cumulative lbs/ac
0.394
0.266
119.406
6.907
1.941
0.031
1.815
15.463
0.524
399.338
Permitted C. P. L. R.****
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
i
Fl-62
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Smithfield Farmland Corp. Total Dry Tons Applied (Annual):
WQ0014868 Cation Exchange Capacity (non 503 only):
Steve Dunham
Owner: JW Burney Predominant Soil Series:
12.1 Acres Permitted: 12.1 Site #: SF07 Field #:
29.74
Aa
8
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.46
Arsenic
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.028
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
5.862
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.862
Chromium
0.313
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.313
Lead
0.052
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.075
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.075
denum
Nickel
0.278
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.278
Selenium
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Zinc
13.605
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
13.605
Total
Phos-
114.666
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
114.666
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4;�r-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: JW Burney
Operator: Steve Dunham
Crop 1 Name: Bermuda -Pasture
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 29.74 Site #:
Predominant Soil Series: Aa
Crop 1 Max. PAN:
155.25
Crop 2 Name:
Acres Utilized:
SF07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
12.1
12.1
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/1
162500
4.22
2.363
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
88.519
NA
Bermuda
2/4
6500
4.22
0.095
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
3.541
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
169000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
92.060
o.000
Lime Applied
Annuallbs/acre
0.028
0.003
5.862
0.313
0.052
0.001
0.075
0.278
0.037
13.605
114.666
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.273
0.081
34.717
4.544
0.778
0.02
1.06
3.018
0.378
137.617
Current Cumulative lbs/ac
0.301
0.084
40.579
4.857
0.830
0.021
1.135
3.296
0.415
151.222
Permitted C. P. L. R.****
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
i
F-155.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 46.90
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only):
Operator: Richard Dunham Owner: Bonnie Meeker Predominant Soil Series: WmB
Acres Used: 21.3 Acres Permitted: 21.3 Site #: SF07 Field #: 9
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.20
Arsenic
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
5.252
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.252
Chromium
0.281
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.281
Lead
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.067
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.067
denum
Nickel
0.249
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.249
Selenium
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.033
Zinc
12.188
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.188
Total
Phos-
102.723
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
102.723
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Bonnie Meeker
Operator: Richard Dunham
Crop 1 Name: Corn
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 46.90 Site #:
Predominant Soil Series: WmB
Crop 1 Max. PAN:
278 Crop 2 Name:
9
SF07
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
21.3
21.3
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/1
156000
4.22
1.289
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
48.274
NA
Corn
3/2
110500
4.22
0.913
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
34.194
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
266500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
82.468
o.000
Lime Applied
Annuallbs/acre
0.025
0.003
5.252
0.281
0.046
0.001
0.067
0.249
0.033
12.188
102.723
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.344
0.119
36.295
4.185
0.868
0.02
1.12
3.463
0.423
158.586
Current Cumulative lbs/ac
0.369
0.122
41.547
4.466
0.914
0.021
1.187
3.712
0.456
170.774
Permitted C. P. L. R.****
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
i
F-278
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 3.44
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only):
Operator: Richard Dunham Owner: Bonnie Meeker Predominant Soil Series: LaB
Acres Used: 7.5 Acres Permitted: 7.5 Site #: SF07 Field #: 14
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 010711RENWINEME
Com-
posite
Date
OEM
MEMEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
2 1
3
4
5j
6j
7
8
9
10
11
12
-1J
DT/Ac./
App.
.fir
Event
0.46
Arsenic
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Cadmium
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Copper
1.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.092
Chromium
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
Lead
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
denum
Nickel
0.052
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Selenium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Zinc
2.535
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.535
Total
Phos-
21.366
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
21.366
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Bonnie Meeker
Operator: Richard Dunham
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 3.44 Site #:
Predominant Soil Series: LaB
Crop 1 Max. PAN:
147 Crop 2 Name:
14
Acres Utilized:
SF07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
7.5
7.5
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/4
19500
4.22
0.458
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
17.137
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
19500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
17.137
o.000
Lime Applied
Annuallbs/acre
0.005
0.001
1.092
0.058
0.010
0.000
0.014
0.052
0.007
2.535
21.366
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.27
0.086
42.262
2.693
0.724
0.02
1.099
3.317
0.371
151.684
Current Cumulative lbs/ac
0.275
0.087
43.354
2.751
0.734
0.020
1.113
3.369
0.378
154.219
Permitted C. P. L. R.****
9
250
1
1000
1
250
500
Permit PAN Limit lst/2nd Crop
147
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 9.15
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only):
Operator: Richard Dunham Owner: Bonnie Meeker Predominant Soil Series: At
Acres Used: 3 Acres Permitted: 3 Site #: SF07 Field #: 15
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
... 010711RENWINEME
Com-
posite
Date
OEM
MEMEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
.fir
Event
3.05
Arsenic
0.034
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
7.274
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
7.274
Chromium
0.389
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.389
Lead
0.064
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.064
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.093
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.093
denum
Nickel
0.346
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.346
Selenium
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Zinc
16.882
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.882
Total
Phos-
142.283
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
142.283
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4; 1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Bonnie Meeker
Operator: Richard Dunham
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 9.15 Site #:
Predominant Soil Series: At
Crop 1 Max. PAN:
237
Crop 2 Name:
15
Acres Utilized:
SF07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Q
Volume applied
enter one Solids/
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
A hed er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
4 �
F
w
*o•
o
,•d 2
#
4
w ,
* N
*�
TKN
mg/kg
Z
;
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
2/3
45500
4.22
2.669
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
1 73775
12775
140.5
99.968
NA
Bermuda
2/4
6500
4.22
0.381
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
14.281
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
52000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
114.2491
0.000
Lime Applied
Annuallbs/acre
0.034
0.004
7.274
0.389
0.064
0.001
0.093
0.346
0.046
16.882
142.283
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.034
0.004
7.274
0.389
0.064
0.001
0.093
0.346
0.046
16.882
Permitted C. P. L. R. * * * *
1 9
1 250
1
1 1000
1
250
500
Permit PAN Limit lst/2nd Crop
1 237
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual):
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only):
Operator: Hinton King Owner: Musselwhite Trust Predominant Soil Series:
Acres Used: 36 Acres Permitted: 36 Site #: SF09 Field #:
86.94
WaB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.42
Arsenic
0.027
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
5.760
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.760
Chromium
0.308
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.308
Lead
0.051
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.073
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.073
denum
Nickel
0.274
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.274
Selenium
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Zinc
13.367
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
13.367
Total
Phos-
112.660
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
112.660
horus
1
1
1
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4;�r-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Musselwhite Trust
Operator: Hinton King
Crop 1 Name: Soybeans
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 86.94 Site #:
Predominant Soil Series: WaB
Crop 1 Max. PAN:
109
Crop 2 Name:
Acres Utilized:
SF09 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
36
36
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
4
w •,
* N
*�
TKN
mg/kg
Z
8
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/23
32500
4.22
0.159
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
1 140.5
5.950
NA
Beans
3/25
110500
4.22
0.540
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
20.232
NA
Beans
3/28
71500
4.22
0.350
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
13.091
NA
Beans
3/29
117000
4.22
0.572
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
21.422
NA
Beans
3/30
162500
4.22
0.794
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
29.752
NA
Beans
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
494000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
90,4471
0.000
Lime Applied
Annuallbs/acre
0.027
0.003
5.760
0.308
0.051
0.001
0.073
0.274
0.036
13.367
112.660
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.0113
0.0075
1.795
0.2785
0.0395
0.0015
0.0818
0.254
0.0188
10.066
Current Cumulative lbs/ac
0.038
0.011
7.555
0.586
0.090
0.002
0.155
0.528
0.055
23.433
Permitted C. P. L. R.****1
9
1 250
1
1 1000
1
1
1 250
1
1 500
Permit PAN Limit lst/2nd Crop
1 109
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual):
Permit #: WQ0014868 Cation Exchange Capacity (non 503 only):
Operator: Hinton King Owner: Musselwhite Trust Predominant Soil Series:
Acres Used: 27.5 Acres Permitted: 27.5 Site #: SF09 Field #:
80.08
GoA
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.91
Arsenic
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.033
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
6.945
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.945
Chromium
0.371
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.371
Lead
0.061
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.061
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.088
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.088
denum
Nickel
0.330
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.330
Selenium
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.043
Zinc
16.118
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.118
Total
Phos-
135.845
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
135.845
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Z�fz 4;�r-
1/26/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Smithfield Farmland Corp
Land Owner: Musselwhite Trust
Operator: Hinton King
Crop 1 Name: Soybeans
WQ Permit #: WQ0014868 Field #:
Annual Dry Tons Applied: 80.08 Site #:
Predominant Soil Series: GoA
Crop 1 Max. PAN:
176 Crop 2 Name:
2
SF09
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
27.5
27.5
4.0
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
4
w •,
* N
*�
TKN
mg/kg
Z
8
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/22
78000
4.22
0.499
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
1 140.5
18.695
NA
Beans
3/23
169000
4.22
1.081
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
40.506
NA
Beans
3/28
130000
4.22
0.832
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
31.159
NA
Beans
3/31
78000
4.22
0.499
Tarheel WWTP
Dry
<.5"
S
0.5
0.2
73775
12775
140.5
18.695
NA
Beans
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
455000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
109,056T
0.000
Lime Applied
Annuallbs/acre
0.033
0.004
6.945
0.371
0.061
0.001
0.088
0.330
0.043
16.118
135.845
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.033
0.004
6.945
0.371
0.061
0.001
0.088
0.330
0.043
16.118
Permitted C. P. L. R.****
9
1 250
1
1 1000
1
1
1 250
1
1 500
Permit PAN Limit lst/2nd Crop
176
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
1/26/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

Waypointo
ANALYTICAL
1 /11 /2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-004-0033
Client Project Description: Tar Heel, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 1/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2022
Arkansas
State Program
88-0650
02/07/2022
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-004-0033
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-004-0033
Client Project Description: Tar Heel, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97041 Smithfield North Solids 01/03/2022 08:00 01/04/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Tar Heel, NC
Lab Report Number: 22-004-0033
Date: 1 /11 /2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 97328
Analyte: Aluminum
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Arsenic
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Analyte: Calcium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Chromium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Iron
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Potassium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Manganese
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Lead
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypoint".0 -
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97329
Analyte: Mercury
QC Batch No: 1-593529/1-593334
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number : 22-004-0033
Lab No : 97041
Sample ID : Smithfield North
Project Tar Heel, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
REPORT OFANALYSIS
Report Date : 01/11/2022
Received : 01/04/2022
Danyale Love
Project Manager
Matrix: Solids
Sampled: 1/3/2022 8:00
Test
Results
Units
MDL
MQL
DF
Date / Time
Analyzed
By
Analytical
Method
Moisture
95.8
%
0.010
1
01/04/22 16:05
FMM
SW-DRYWT
Ammonia Nitrogen
11400
mg/Kg -
dry
381
2380
1
01/11/22 13:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
181
mg/Kg -
dry
110
110
1
01/10/22 15:18
ZBD
4500NO3F-2011
Organic N
69120
mg/Kg -
dry
381.0
2381
1
01/11/22 09:00
CALCULATION
pH
7.2
S.U.
1
01/06/2215:16
DRS
9045D
Total Solids
4.20
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Volatile Solids
77.8
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Kjeldahl Nitrogen
80500
mg/Kg -
dry
238
5950
1
01/11/22 09:00
JPJ
;M-4500-NH3C-TKI`
Phosphorus
21500
mg/Kg -
dry
65.7
119
1
01/11/22 01:18
EAL
6010D
Aluminum
11000
mg/Kg -
dry
110
119
1
01/11/22 01:18
EAL
6010D
Arsenic
<5.71
mg/Kg -
dry
5.71
11.9
1
01/11/22 01:18
EAL
6010D
Cadmium
0.6693
mg/Kg -
dry
0.476
2.38
1
01/11/22 01:18
EAL
6010D
Calcium
25500
mg/Kg -
dry
921
1190
1
01/11/22 01:18
EAL
6010D
Chromium
69.3
mg/Kg -
dry
5.62
5.95
1
01/11/22 01:18
EAL
6010D
Copper
1250
mg/Kg -
dry
7.38
11.9
1
01/11/22 01:18
EAL
6010D
Iron
13100
mg/Kg -
dry
203
238
1
01/11/22 01:18
EAL
6010D
Lead
11.0
mg/Kg -
dry
4.29
7.14
1
01/11/22 01:18
EAL
6010D
Magnesium
2150
mg/Kg -
dry
61.4
119
1
01/11/22 01:18
EAL
6010D
Manganese
479
mg/Kg -
dry
7.74
11.9
1
01/11/22 01:18
EAL
6010D
Mercury
<0.160
mg/Kg -
dry
0.160
0.367
1
01/07/22 12:46
JW2
7471A
Molybdenum
15.7
mg/Kg -
dry
3.21
5.95
1
01/11/22 01:18
EAL
6010D
Nickel
61.0
mg/Kg -
dry
2.86
5.95
1
01/11/22 01:18
EAL
6010D
Potassium
4900
mg/Kg -
dry
147
238
1
01/11/22 01:18
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions L
Limit Exceeded
MQL
Method Quantitation Limit
Page 6 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Tar Heel, NC
Mr. Brent Collins
Report Date : 01/11/2022
755 Yadkinville Rd
Information :
Received : 01/04/2022
Mocksville , NC 27028
Danyale Love
Report Number : 22-004-0033
REPORT OFANALYSIS
Project Manager
Lab No : 97041
Matrix: Solids
Sample ID : Smithfield North
Sampled: 1/3/2022 8:00
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<7.62
mg/Kg - dry
7.62
11.9 1 01/11/22 01:18 EAL 6010D
Sodium
12300
mg/Kg - dry
310
595 1 01/11/22 01:18 EAL 6010D
Zinc
2900
mg/Kg - dry
19.3
29.8 1 01/11/22 01:18 EAL 6010D
Sulfur
19700
mg/Kg - dry
123
238 1 01/11/22 01:18 EAL 6010D
Sodium Absorption Ratio
4.05
Ratio
0.01
0.01 1 01/11/22 01:18 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-004-0033
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 01/04/2022 10:24:36
Page 8 of 9

a
N
-0
6
LL
Y
a
U�
E
£
a
M
C7 N
0
2+
N
� a a
L
�
❑
IG
tt
CL
V Y n M 2 C"
a
0
V
Q
2
Q}
y
3
y
❑
a o c 0 0 Q o
❑❑ N o M z M❑
u u x 2 Z x z x u
6
ti
L
.T.
Q
❑
7
Z
N
^
CL
L^
x A a
LL
iu
2
Q
a
NQy�
7
❑
0
i
S
` c
E
d
v
E "Mx
E CO
E
OFF
z Z
7
-w
—0
d
=may
�®l]
a
co
splo51e}ol
a
c
T
N
rn
a
�i
N o3ue5j0�@jeJIIN
ov0
N
eiuOWW HIN }#1
a
F
p o
v�
E
Q ❑ N
)
C
oG
Y
o
�001 �9) Simona
w
z
z
O
a m
C7
C
❑
[[ N ❑
pt
a
N
N
= U
Q
° as
a;isodwa[�} �o qe�{�1
a
a
a
m
a
a _
Q
�
a
(Aa)l 01 is;a4) x»3pwcr
3
a
saauie;uo:);o AagwON
OC
c
a
=
cro
N
C
u
a
H
v r
m
W
_
❑ 1
cc[
c
N
❑ `
a �
❑ u
� o
cr)
U
U
9 u
r
M
`.Il
❑m
w
v
o
@
�
O
s
p
�-
_
C C
d a]
u
°
a
r
S
❑
N
c °
w
'7
O
v
-G m
it
a` (Y)
❑
a
v
w
n
J
E
o
m
co
r
a
Uti
Ci iy
■�} n`:
-� _.
m
�
°�
E(V
c:
p
� N
tl] U
jZ
c
0
a
c
Z �Q vz.=
v�i �
o
IDN
❑
2
C a
Z �'
Y�
uEl
M
y 2
c
-1
wn�
Page 9 of 9

North 1 /3/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 12300 516.6 23 22.46087
Calcium 25500 1071 20 53.55
Magnesium 2150 90.3 12 7.525
Percent Solids 4.2
SAR 4.06
SAR
Na+
a (Ca2+ + M92+)
22.46087
0.5( 53.55 2 + 7.52500 2 )

Waypointo
ANALYTICAL
1 /11 /2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-004-0032
Client Project Description: Tar Heel, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 1/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2022
Arkansas
State Program
88-0650
02/07/2022
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-004-0032
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-004-0032
Client Project Description: Tar Heel, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97026 Smithfield South Solids 01/03/2022 08:00 01/04/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Tar Heel, NC
Lab Report Number: 22-004-0032
Date: 1 /11 /2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 97328
Analyte: Aluminum
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Arsenic
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Analyte: Calcium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Chromium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Iron
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Potassium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Manganese
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Lead
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypoint".0 -
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97329
Analyte: Mercury
QC Batch No: 1-593529/1-593334
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number : 22-004-0032
Lab No : 97026
Sample ID : Smithfield South
Project Tar Heel, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
REPORT OFANALYSIS
Report Date : 01/11/2022
Received : 01/04/2022
Danyale Love
Project Manager
Matrix: Solids
Sampled: 1/3/2022 8:00
Test
Results
Units
MDL
MQL
DF
Date / Time
Analyzed
By
Analytical
Method
Moisture
95.4
%
0.010
1
01/04/22 16:05
FMM
SW-DRYWT
Ammonia Nitrogen
12400
mg/Kg -
dry
348
2170
1
01/11/22 13:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
140
mg/Kg -
dry
103
103
1
01/10/22 15:18
ZBD
4500NO3F-2011
Organic N
68650
mg/Kg -
dry
347.8
2174
1
01/11/22 09:00
CALCULATION
pH
7.4
S.U.
1
01/06/2215:16
DRS
9045D
Total Solids
4.63
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Volatile Solids
76.5
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Kjeldahl Nitrogen
81100
mg/Kg -
dry
217
5430
1
01/11/22 09:00
JPJ
;M-4500-NH3C-TKI`
Phosphorus
23900
mg/Kg -
dry
60.0
109
1
01/11/22 01:13
EAL
6010D
Aluminum
10300
mg/Kg -
dry
100
109
1
01/11/22 01:13
EAL
6010D
Arsenic
<5.22
mg/Kg -
dry
5.22
10.9
1
01/11/22 01:13
EAL
6010D
Cadmium
0.5223
mg/Kg -
dry
0.435
2.17
1
01/11/22 01:13
EAL
6010D
Calcium
38300
mg/Kg -
dry
841
1090
1
01/11/22 01:13
EAL
6010D
Chromium
62.4
mg/Kg -
dry
5.13
5.43
1
01/11/22 01:13
EAL
6010D
Copper
1180
mg/Kg -
dry
6.74
10.9
1
01/11/22 01:13
EAL
6010D
Iron
13700
mg/Kg -
dry
185
217
1
01/11/22 01:13
EAL
6010D
Lead
10.9
mg/Kg -
dry
3.91
6.52
1
01/11/22 01:13
EAL
6010D
Magnesium
2390
mg/Kg -
dry
56.1
109
1
01/11/22 01:13
EAL
6010D
Manganese
557
mg/Kg -
dry
7.07
10.9
1
01/11/22 01:13
EAL
6010D
Mercury
<0.146
mg/Kg -
dry
0.146
0.335
1
01/07/22 12:45
JW2
7471A
Molybdenum
15.8
mg/Kg -
dry
2.93
5.43
1
01/11/22 01:13
EAL
6010D
Nickel
55.9
mg/Kg -
dry
2.61
5.43
1
01/11/22 01:13
EAL
6010D
Potassium
4570
mg/Kg -
dry
134
217
1
01/11/22 01:13
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions L
Limit Exceeded
MQL
Method Quantitation Limit
Page 6 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Tar Heel, NC
Mr. Brent Collins
Report Date : 01/11/2022
755 Yadkinville Rd
Information :
Received : 01/04/2022
Mocksville , NC 27028
Danyale Love
Report Number : 22-004-0032
REPORT OFANALYSIS
Project Manager
Lab No : 97026
Matrix: Solids
Sample ID : Smithfield South
Sampled: 1/3/2022 8:00
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<6.96
mg/Kg - dry
6.96
10.9 1 01/11/22 01:13 EAL 6010D
Sodium
11400
mg/Kg - dry
283
543 1 01/11/22 01:13 EAL 6010D
Zinc
2780
mg/Kg - dry
17.6
27.2 1 01/11/22 01:13 EAL 6010D
Sulfur
19200
mg/Kg - dry
113
217 1 01/11/22 01:13 EAL 6010D
Sodium Absorption Ratio
3.28
Ratio
0.01
0.01 1 01/11/22 01:13 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-004-0032
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 01/04/2022 10:21:28
Page 8 of 9

cm
a-
N
4
v
U
F
a
C]
c
N
d
d
o
r,
o
❑
C
�ry
°
rn
o
z
U
aj
U)
N
n r-
i
0
°7°
7
R
V g d= '^ a
N°_
° = 0 2= x r
L
T p Y
u° uu
Q
x3oo
Q
c
E
r
L
�i o a
TGix
in
a mu❑ W LLt7r_
x
N
z
o
a w
s
Q>
r
l7
kn
^
s. L
a
a
a
El
C
M Z
N
J
U
�!
0.
E
E
�pn
i N G1
0
w
2
I
u
H
a
SAi
a
w�
W
�]
E
E
E
a w g+
= LL! V �
-mac
t
0.
Hd
NO
5P!IOS Ielol
A
d
U
L
S"
u
N
cJ.
a
n
�v
U
o
N Oiue
ccfiAp[all?A!N
]
Li7
m
OIUOWWV/N>li
IIN^
w
a 4
C W
W
O
yy y
4J
a
E
�
r
t091a9) SimeN
z
z
z
_
�
°
a
aaisodtuo��J �a ge�[91
L}
- i.
m Q
a`
tAa7i oa as;ay) ><u;eyy
L
�
r
r
QW
uaureiuo:j;o-jagwnry
u
m
�y
c
co
o d
m
C \
❑
u
o u
ou LJ
ro 'D
y
m
a U
o a
o�
d
a a`
t Cfl
'
E
rtrt,,
CO
d
c
w
�v
a
co
V �
A
•
� W �
a
N M N
m U
C
g
� C ^'
�Z
c
o
E �+ -Y —_
m
a
� r •a
o
i m
❑
a
N LO❑
cc
ry .G
L_��'
i+ urr-2
G
S
ps
Page 9 of 9

South 1 /3/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
11400
527.82
23 22.9487
Calcium
38300
1773.29
20 88.6645
Magnesium
2390
110.657
12 9.221417
Percent Solids
4.63
SAR
3.28
SAR
Na+
a (Ca2+ + M92+)
22.94870
0.5( 88.665 2 + 9.22142 2 )

Waypointo
ANALYTICAL
3/8/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-054-0037
Client Project Description: Tar Heel, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 2/23/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-054-0037
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-054-0037
Client Project Description: Tar Heel, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97405 Smithfield North Solids 02/21/2022 06:30 02/23/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Tar Heel, NC
Lab Report Number: 22-054-0037
Date: 3/8/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 56819
Analyte: Aluminum
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 56819
Analyte: Iron
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 56819
Analyte: Potassium
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 56819
Analyte: Magnesium
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 56819
Analyte: Sodium
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Aluminum
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Iron
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 99632 (KGO-CP 3795)
Analyte: Potassium
QC Batch No: 1-603249/1-602867
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 99632 (KGO-CP 3795)
Analyte: Potassium
QC Batch No: 1-603457/1-602867
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 99632 (KGO-CP 3795)
Analyte: Manganese
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Sodium
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Phosphorus
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Lead
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Sulfur
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Zinc
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97405 (Smithfield North)
Analyte: Mercury
QC Batch No: 1-601502/1-601274
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Tar Heel, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 03/08/2022
Received : 02/23/2022
" l.�—
Connie Cook
Report Number : 22-054-0037
REPORT OFANALYSIS
Project
Manager
Lab No : 97405
Matrix:
Solids
Sample ID : Smithfield North
Sampled:
2/21/2022
6:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
96.0
%
1
02/24/22 15:49
FMM
SW-DRYWT
Ammonia Nitrogen
14300
mg/Kg -
dry
400
2500
1
03/02/22 14:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
116
mg/Kg -
dry
115
115
1
03/02/22 15:15
ZBD
4500NO3F-2011
Organic N
56250
mg/Kg -
dry
400.0
2500
1
03/02/22 10:00
DH
CALCULATION
pH
7.0
S.U.
1
03/01/2215:28
DRS
9045D
Total Solids
4.00
%
0.010
0.010
1
02/24/22 15:49
FMM
2540G-2011
Total Volatile Solids
76.8
%
0.010
0.010
1
02/24/22 15:49
FMM
2540G-2011
Total Kjeldahl Nitrogen
70500
mg/Kg -
dry
250
6250
1
03/02/22 10:00
JPJ ;M-4500-NH3C-TKI`
Phosphorus
27500
mg/Kg -
dry
69.0
125
1
03/02/22 00:42
EAL
6010D
Aluminum
11400
mg/Kg -
dry
116
125
1
03/02/22 20:48
EAL
6010D
Arsenic
<6.00
mg/Kg -
dry
6.00
12.5
1
03/02/22 00:42
EAL
6010D
Cadmium
0.7133
mg/Kg -
dry
0.500
2.50
1
03/02/22 00:42
EAL
6010D
Calcium
34000
mg/Kg -
dry
968
1250
1
03/02/22 20:48
EAL
6010D
Chromium
66.3
mg/Kg -
dry
5.90
6.25
1
03/02/22 00:42
EAL
6010D
Copper
1230
mg/Kg -
dry
7.75
12.5
1
03/02/22 00:42
EAL
6010D
Iron
13900
mg/Kg -
dry
213
250
1
03/02/22 00:42
EAL
6010D
Lead
10.6
mg/Kg -
dry
4.50
7.50
1
03/02/22 00:42
EAL
6010D
Magnesium
2070
mg/Kg -
dry
64.5
125
1
03/02/22 00:42
EAL
6010D
Manganese
600
mg/Kg -
dry
8.13
12.5
1
03/02/22 00:42
EAL
6010D
Mercury
<0.169
mg/Kg -
dry
0.169
0.388
1
02/24/22 13:26
JW2
7471A
Molybdenum
15.4
mg/Kg -
dry
3.38
6.25
1
03/02/22 00:42
EAL
6010D
Nickel
59.0
mg/Kg -
dry
3.00
6.25
1
03/02/22 00:42
EAL
6010D
Potassium
5800
mg/Kg -
dry
155
250
1
03/07/22 17:05
EAL
6010D
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 6 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Tar Heel, NC
Mr. Brent Collins
Report Date : 03/08/2022
755 Yadkinville Rd
Information :
Received : 02/23/2022
Mocksville , NC 27028
n
Connie Cook
Report Number : 22-054-0037
REPORT OFANALYSIS
Project Manager
Lab No : 97405
Matrix: Solids
Sample ID : Smithfield North
Sampled: 2/21/2022 6:30
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<8.00
mg/Kg - dry
8.00
12.5 1 03/02/22 00:42 EAL 6010D
Sodium
11400
mg/Kg - dry
325
625 1 03/02/22 20:48 EAL 6010D
Zinc
2800
mg/Kg - dry
20.3
31.3 1 03/02/22 00:42 EAL 6010D
Sulfur
20200
mg/Kg - dry
130
250 1 03/02/22 00:42 EAL 6010D
Sodium Absorption Ratio
3.23
Ratio
0.01
0.01 1 03/02/22 00:42 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-054-0037
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 02/23/2022 09:45:31
Page 8 of 9

o
ai
t
LL
v y
�n
a 'a
O
o
'
lr
r
V
a�-i
L
U
N 1��
N
T
m
d O
v u
Z ti wdN N
m
(�
Z
L
�•
❑
is
xt
v a m J �
O x
O
CI]
Q
_
can
c
za
o°� a� v$
�y=zz===U
a
0
L
T Y
C
�
�`�
Y
U)
CCU1
�
LL
0
m a
OJ
C
rf 1
W
L.
a
a m V 0 u� C7 x_
_
v
a
a
T
2
C7
a
C
Q]
�n
w
L.Ln
`
a
❑
❑
__ g y
'^ �
a
7
v
7
I
7
= �
C
d
a
a
c��
E
�wF-
V{�J]
ci u i
'
R
V
Y
ow.�
a
SIl1
E
£aF
F
a
a
y
HST
c:
r
kl
N
�
�
o
SPHOS Iulal
U)
01
y
T
a
a
N
Q)
j
N :)iue6a0/aleA!N
�Y
a
LO
Ecc
r COo
o z
W
eiuowwy1N>11
o
m
�y
a y a
m cn
A
rc
rc
cc
m
L
cry y a�
U
a �'
L7
0C
u
a H p
N
6� r
ti.
m ¢
a
a;{sedwo{�] ie qe�{91
a
.�
IV
T
(AaN o1 )a�agj xla;evv
c
c
o
c
CD
s.iauie;uo:);o aagtunN
m
s
u
m
r
S
r
m a
CI1
O `
L
O V
o
m C))
m m
a
m
C'']
a 0 ~
s
.7
=
rra,
O V
y
r6 {
❑
d c
N
t; tr
N
t;
H F
[�
E
V
lam,
O
C
C
T
V m
S
a t- 1
ILa
cu
v
a
E
11
7
u7
`a
•
0
a
00fu
a
Q
v
C
a '^
rV}
O7
O
q C
L'i
'a C>
a j'>z
a
r°0,.,
�Q Yz
E
O
�7
0
y O = pj
N
E
r�
2 }
a ,_�
_
LS)
a
c� e�c1
a
Page 9 of 9

North 2/21 /22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 11400 456 23 19.82609
Calcium 34000 1360 20 68
Magnesium 2070 82.8 12 6.9
Percent Solids 4
SAR
3.24
SAR Na+
a (Ca2+ + M92+)
19.82609
0.5( 68 2 + 6.90000 2 )

Waypointo
ANALYTICAL
3/8/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-054-0036
Client Project Description: Tar Heel, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 2/23/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-054-0036
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-054-0036
Client Project Description: Tar Heel, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97404 Smithfield South Solids 02/21/2022 06:45 02/23/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Tar Heel, NC
Lab Report Number: 22-054-0036
Date: 3/8/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 56819
Analyte: Aluminum
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 56819
Analyte: Iron
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 56819
Analyte: Potassium
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 56819
Analyte: Magnesium
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 56819
Analyte: Sodium
QC Batch No: 1-602356/1-601780
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Aluminum
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Iron
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 99632 (KGO-CP 3795)
Analyte: Potassium
QC Batch No: 1-603249/1-602867
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 99632 (KGO-CP 3795)
Analyte: Potassium
QC Batch No: 1-603457/1-602867
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 99632 (KGO-CP 3795)
Analyte: Manganese
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Sodium
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Phosphorus
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Lead
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Sulfur
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99632 (KGO-CP 3795)
Analyte: Zinc
QC Batch No: 1-603249/1-602867
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97405 (Smithfield North)
Analyte: Mercury
QC Batch No: 1-601502/1-601274
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Tar Heel, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 03/08/2022
Received : 02/23/2022
" l.�—
Connie Cook
Report Number : 22-054-0036
REPORT OFANALYSIS
Project
Manager
Lab No : 97404
Matrix:
Solids
Sample ID : Smithfield South
Sampled:
2/21/2022
6:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
95.6
%
1
02/24/22 15:49
FMM
SW-DRYWT
Ammonia Nitrogen
13000
mg/Kg -
dry
364
2270
1
03/02/22 14:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
125
mg/Kg -
dry
107
107
1
03/02/22 15:15
ZBD
4500NO3F-2011
Organic N
49980
mg/Kg -
dry
363.6
2273
1
03/02/22 10:00
DH
CALCULATION
pH
7.1
S.U.
1
03/01/2215:28
DRS
9045D
Total Solids
4.05
%
0.010
0.010
1
02/24/22 15:49
FMM
2540G-2011
Total Volatile Solids
76.1
%
0.010
0.010
1
02/24/22 15:49
FMM
2540G-2011
Total Kjeldahl Nitrogen
63000
mg/Kg -
dry
227
5680
1
03/02/22 10:00
JPJ ;M-4500-NH3C-TKI`
Phosphorus
20400
mg/Kg -
dry
62.7
114
1
03/02/22 00:37
EAL
6010D
Aluminum
9520
mg/Kg -
dry
105
114
1
03/02/22 20:43
EAL
6010D
Arsenic
<5.45
mg/Kg -
dry
5.45
11.4
1
03/02/22 00:37
EAL
6010D
Cadmium
0.7433
mg/Kg -
dry
0.455
2.27
1
03/02/22 00:37
EAL
6010D
Calcium
25200
mg/Kg -
dry
880
1140
1
03/02/22 20:43
EAL
6010D
Chromium
56.8
mg/Kg -
dry
5.36
5.68
1
03/02/22 00:37
EAL
6010D
Copper
1110
mg/Kg -
dry
7.05
11.4
1
03/02/22 00:37
EAL
6010D
Iron
12600
mg/Kg -
dry
194
227
1
03/02/22 00:37
EAL
6010D
Lead
9.66
mg/Kg -
dry
4.09
6.82
1
03/02/22 00:37
EAL
6010D
Magnesium
1750
mg/Kg -
dry
58.6
114
1
03/02/22 00:37
EAL
6010D
Manganese
482
mg/Kg -
dry
7.39
11.4
1
03/02/22 00:37
EAL
6010D
Mercury
<0.153
mg/Kg -
dry
0.153
0.350
1
02/24/22 13:25
JW2
7471A
Molybdenum
13.8
mg/Kg -
dry
3.07
5.68
1
03/02/22 00:37
EAL
6010D
Nickel
50.7
mg/Kg -
dry
2.73
5.68
1
03/02/22 00:37
EAL
6010D
Potassium
4160
mg/Kg -
dry
140
227
1
03/07/22 17:00
EAL
6010D
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 6 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Tar Heel, NC
Mr. Brent Collins
Report Date : 03/08/2022
755 Yadkinville Rd
Information :
Received : 02/23/2022
Mocksville , NC 27028
n
Connie Cook
Report Number : 22-054-0036
REPORT OFANALYSIS
Project Manager
Lab No : 97404
Matrix: Solids
Sample ID : Smithfield South
Sampled: 2/21/2022 6:45
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<7.27
mg/Kg - dry
7.27
11.4 1 03/02/22 00:37 EAL 6010D
Sodium
9610
mg/Kg - dry
295
568 1 03/02/22 20:43 EAL 6010D
Zinc
2590
mg/Kg - dry
18.4
28.4 1 03/02/22 00:37 EAL 6010D
Sulfur
18100
mg/Kg - dry
118
227 1 03/02/22 00:37 EAL 6010D
Sodium Absorption Ratio
3.30
Ratio
0.01
0.01 1 03/02/22 00:37 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-054-0036
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 02/23/2022 09:44:13
Page 8 of 9

a
N
4
CD
d�
❑
o
E 1
E
C3 Qj
❑
❑
C7 po
I N
p
N ^�
Z
�
!}
aj
C Jhh
o v
iD N
2 N G d ry V x
Q1
Z
C�II
C
y �i-' C
O b : crS z N 0.
E
N
C37
n1 44
R 3 C
iG
V V O a x M J V
Q
'
u3
.
$$ ry O m z d A °a
uuxxxxxx0
Q
t
Q
C)
[tC
� � ❑ C
in
am V o wtiL7z
�
�
�
�
w
,i,
0
~
J
N
z
z
C7
L
0
0.
of r
C
y1
w
W
N
._.
2
._.
j.
❑ a
= i]
N
$
a
(LP
a
s
41
CCL
V
E
7
�/f
E ®
y
~LUF
L,
a
Tsnl
Ln
0
m
E
E!
E
E
7 t
-C u O
w
t
a
q
cc
F
r�
.T
cou
m
a
m
5P! loS I elol
a
(�
a
CL a
Ln
QS
di
tin s
o
N :)iue6JQ/a;eJI!N
u7
U
\j
y'
�
a ,4 z
W
�uawwdlN�ll7-1
P
..
@) j
W
W
w
MoLog) S�LjaW
�
4 W
0
c
i
i
N
CL
2
a`
c C 7
d' Ln 6
d
y
Vl
y
m ¢
a
a�isodwa[�} �o gel[cy]
m
z
a
n �
v
-0
N
[Ra)l of aajaa] xiJ3ew
�
a
c
3
a
3
a
�
E
c
c
c
sjau�e4uo:);o2agwnN
aj
Y,
m
�
c
D
a_T
�
ro
m
c
Q I
5
o
4
C p
° �+
m
CIO
o
m
o, U
�'
I
p G.
O�7
1V�'[�
E
S
-irN_
Qo
R
N H
u
E
0
>ti
P
CY)
O L•
[�
❑ Q
d
�_
�
E
�
v
c
v
M
m
a
1
00
u hl
V
7
v Jl �N
�^
rd
E.
r
�` 93 6] t.7
2
a
a
� d Mx.•
C;�
u
o
E N Y—
di
E
3
]ia
ry
'F �
O P
2 t�l�
e QC L)
❑
d
2
a
A. ^�
a, m o
2
u
c
ma
C ❑
O
❑
N
f]
lr~1,� \
`�]
r
mr
r Jy ' u i

South 2/21 /22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
9610
389.205
23 16.92196
Calcium
25200
1020.6
20 51.03
Magnesium
1750
70.875
12 5.90625
Percent Solids
4.05
SAR
3.17
SAR
Na+
a (Ca2+ + M92+)
16.92196
0.5( 51.03 2 + 5.90625 2 )

ace Analytical ' ANALYTICAL REPORT
January 21, 2022
EMA Resources
Sample Delivery Group: L1447726
Samples Received: 01/04/2022
Project Number:
Description: Sludge
Report To: Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By: , �-
Justin Carr
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
N
� T
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 1 of 21

TABLE OF CONTENTS
Cp: Cover Page
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
SMITHFIELD L1447726-01
5
Qc: Quality Control Summary
7
Wet Chemistry by Method 9012 B
7
Wet Chemistry by Method 9034-9030B
8
Wet Chemistry by Method 9045D
9
Wet Chemistry by Method D93/1010A
10
Mercury by Method 7470A
11
Metals (ICP) by Method 6010D
12
Volatile Organic Compounds (GC/MS) by Method 8260D
13
Chlorinated Acid Herbicides (GC) by Method 8151A
15
Pesticides (GC) by Method 8081B
16
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
17
GI: Glossary of Terms
19
al: Accreditations & Locations
20
Sc: Sample Chain of Custody
21
ACCOUNT: PROJECT: SDG:
DATE/TIME: PAGE:
EMA Resources L1447726
01/21/22 14:57 2 of 21

SMITHFIELD L1447726-01 Waste
SAMPLE SUMMARY
Collected by
Roy Whitaker
Collected date/time Received date/time
01/03/22 08:00 01/04/22 09:15 C
P
Method
Batch
Dilution Preparation
Analysis
Analyst
date/time
date/time
Preparation by Method 1311
WG1799743
1 01/10/2210:59
01/10/2210:59
CJW
Preparation by Method 1311
WG1799807
1 01/10/2215:00
01/10/2215:00
MLB
Wet Chemistry by Method 9012 B
WG1799974
1 01/12/22 02:22
01/13/2216:38
JER
Wet Chemistry by Method 9034-9030B
WG1798632
1 01/09/2217:00
01/09/22 22:00
ARID
Wet Chemistry by Method 9045D
WG1798313
1 01/05/221137
01/05/22 14:00
BMD
Wet Chemistry by Method D93/1010A
WG1799366
1 01/09/2216:00
01/09/22 16:00
BMD
Mercury by Method 7470A
WG1800260
1 01/11/22 1108
01/12/22 08:24
ABL
Metals (ICP) by Method 6010D
WG1800417
1 01/11/22 17:28
01/11/22 23:57
CCE
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1800226
1 01/11/22 15:56
01/11/2215:56
JHH
Chlorinated Acid Herbicides (GC) by Method 8151A
WG1800468
1 01/11/22 18:34
01/14/22 0101
HMH
Pesticides (GC) by Method 8081B
WG1802137
1 01/14/22 06:35
01/14/2214:16
AMM
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
WG1804747
1 01/20/22 07:16
01/20/22 16:42
JNJ
Location
FC
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fn
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fr
Mt. Juliet, TN
Mt. Juliet, TN
Rc
Mt. Juliet, TN
Mt. Juliet, TN
GI
SAI
RC
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1447726 01/21/22 14:57
PAGE:
3 of 21

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the FP
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data. 0
Fr
Rc
GI
Justin Carr [Al
Project Manager
RC
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-903013.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 4 of 21

SAMPLE RESULTS - 01
L1447726
SMITHFIELD
Collected date/time: 01/03/22 08:00
Preparation by Method 1311
Result Qualifier Prep
Batch
Analyte
date / time
TCLP Extraction
1/10/2022 3:00:13 PM
WG1799807
TCLP ZHE Extraction
- 1/10/2022 10:59:38 AM
WG1799743
Fluid
1 1/10/2022 3:00:13 PM
WG1799807
Initial pH
7.69 1/10/2022 3:00:13 PM
WG1799807
Final pH
5.12 1/10/2022 3:00:13 PM
WG1799807
Wet Chemistry by Method 9012 B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reactive Cyanide ND 0.250
Wet Chemistry by Method 9034-9030B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reactive Sulfide 139 25.0
Wet Chemistry by Method 9045D
Dilution Analysis Batch
date / time
1 01/13/202216:38 WG1799974
Dilution Analysis Batch
date / time
1 01/09/2022 22:00 WG1798632
Result Qualifier Dilution Analysis Batch
Analyte su date / time
Corrosivity by pH 7.67 T8 1 01/05/202214:00 WG1798313
Sample Narrative:
L1447726-01 WG1798313: 7.67 at20C
Wet Chemistry by Method D93/1010A
Result
Analyte Deg. F
Ignitability DNI at170
Mercury by Method 7470A
Qualifier Dilution Analysis Batch
date / time
1 01/09/202216:00 WG1799366
Result Qualifier RDL Limit
Analyte mg/I mg/I mg/I
Mercury ND 0.0100 0.20
Metals (ICP) by Method 6010D
Result
Qualifier RDL
Limit
Analyte
mg/I
mg/I
mg/I
Arsenic
ND
0.100
5
Barium
ND
0.100
100
Cadmium
ND
0.100
1
Chromium
ND
0.100
5
Lead
ND
0.100
5
Selenium
ND
0.100
1
Silver
ND
0.100
5
Volatile Organic
Compounds (GC/MS) by Method
8260D
Result
Qualifier RDL
Limit
Analyte
mg/I
mg/I
mg/I
Benzene
ND
0.0500
0.50
Carbon tetrachloride
ND
0.0500
0.50
Chlorobenzene
ND
0.0500
100
Chloroform
ND
0.250
6
ACCOUNT:
PROJECT:
EMA Resources
Dilution Analysis Batch
date / time
1 01/12/2022 08:24 WG1800260
Dilution Analysis
Batch
date / time
1 01/11/2022 23:57
WG1800417
1 01/11/2022 23:57
WG1800417
1 01/11/2022 23:57
WG1800417
1 01/11/2022 23:57
WG1800417
1 01/11/2022 23:57
WG1800417
1 01/11/2022 23:57
WG1800417
1 01/11/2022 23:57
WG1800417
Dilution Analysis
Batch
date / time
1 01/11/202215:56
WG1800226
1 01/11/202215:56
WG1800226
1 01/11/202215:56
WG1800226
1 01/11/202215:56
WG1800226
SDG:
DATE/TIME: PAGE:
L1447726
01/21/22 14:57 5 of 21

SMITHFIELD SAMPLE RESULTS
Collected date/time: 01/03/22 08:00 L1447726
Volatile Organic Compounds (GC/MS) by Method 8260D
- 01
Result
Qualifier RDL Limit Dilution
Analysis
Batch
Analyte
mg/I
mg/I mg/I
date/time
1,2-Dichloroethane
ND
0.0500 0.50 1
01/11/202215:56
WG1800226
1,1-Dichloroethene
ND
0.0500 0.70 1
01/11/202215:56
WG1800226
2-Butanone (MEK)
ND
0.500 200 1
01/11/2022 15:56
WG1800226
Tetrachloroethene
ND
0.0500 0.70 1
01/11/202215:56
WG1800226
Trichloroethene
ND
0.0500 0.50 1
01/11/202215:56
WG1800226
Vinyl chloride
ND
0.0500 0.20 1
01/11/2022 15:56
WG1800226
(S) Toluene-dH
105
80.0-120
0111112022 15.56
WG1800226
(S) 4-Bromofluorobenzene
101
77.0-126
0111112022 15.56
WG1800226
(S) 1,2-Dichloroethane-d4
102
70.0-130
011111202215.56
WG1800226
Chlorinated Acid Herbicides (GC) by Method 8151A
Result Qualifier RDL
Analyte mg/I mg/I
2,4,5-TP (Silvex) ND 0.00200
2,4-D ND 0.00200
(S) Z4-Dichlorophenyl Acetic Acid 68.8 14.0-158
Pesticides (GC) by Method 8081B
Limit Dilution Analysis
Batch
mg/I date / time
1 1 01/14/2022 0101
WG1800468
10 1 01/14/2022 0101
WG1800468
0111412022 01.01
WG1800468
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Chlordane
ND
0.00500
0.03
1 01/14/202214:16
WG1802137
Endrin
ND
0.00500
0.02
1 01/14/202214:16
WG1802137
Heptachlor
ND
0.00500
0.0080
1 01/14/202214:16
WG1802137
Heptachlor epoxide
ND
0.00500
0.0080
1 01/14/2022 14:16
WG1802137
Lindane
ND
0.00500
0.40
1 01/14/202214:16
WG1802137
Methoxychlor
ND
0.00500
10
1 01/14/202214:16
WG1802137
Toxaphene
ND
0.0100
0.50
1 01/14/202214:16
WG1802137
(S) Decochlorobiphenyl
60.5
10.0-128
0111412022 14.16
WG1802137
(S) Tetrochloro-m-xylene
76.0
10.0-127
0111412022 14.16
WG1802137
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Result
Analyte
mg/I
1,4-Dichlorobenzene
ND
2,4-Dinitrotoluene
ND
Hexachlorobenzene
ND
HexachIoro-1,3-butadiene
ND
Hexachloroethane
ND
Nitrobenzene
ND
Pyridine
ND
3&4-Methyl Phenol
ND
2-Methylphenol
ND
Pentachlorophenol
ND
2,4,5-Trichlorophenol
ND
2,4,6-Trichlorophenol
ND
(S) 2-Fluorophenol
472
(S) Phenol-d5
29.5
(S) Nitrobenzene-d5
63.4
(S) 2-Fluorobiphenyl
66.4
(S) Z4, 6-Tribromophenol
69.0
(S) p-Terphenyl-d14
80.2
Qualifier
RDL
mg/I
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
10.0-120
10.0-120
10.0-127
10.0-130
10.0-155
10.0-128
Limit
mg/I
7.50
0.13
0.13
0.50
3
2
5
400
200
100
400
2
Dilution Analysis Batch
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
01/20/202216:42
0112012022 16.42
0112012022 16.42
0112012022 16.42
0112012022 16.42
0112012022 16.42
0112012022 16.42
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
WG1804747
ACCOUNT: PROJECT: SDG:
EMA Resources L1447726
DATE/TIME: PAGE:
01/21/22 14:57 6 of 21

WG1799974
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3749791-1 01/13/22 1634
MB Result
Analyte mg/kg
Reactive Cyanide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.0390 0.250
L1449017-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1447726-01
(OS) L1449017-01 01/13/22 16:43 • (DUP) R3749791-3 01/13/22 16:46
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg %_
Reactive Cyanide ND ND 1 0.000 20
L1449146-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1449146-01 01/13/22 16:53 • (DUP) R3749791-6 01/13/22 16:54
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide ND ND 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3749791-2 01/13/22 16:35
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Cyanide 2.50 2.50 100
Rec. Limits LCS Qualifier
85.0-115
L1449054-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1449054-02 01/13/22 16:47 • (MS) R3749791-4 01/13/22 16:43 • (MSD) R3749791-5 01/13/22 16:49
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 0.257 0.533 0.929 16.6 40.3 1 75.0-125 J6 J3 J6 54.1 20
L1449146-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1449146-01 01/13/22 16:53 • (MS) R3749791-7 01/13/22 16:55 • (MSD) R3749791-8 01/13/22 16:56
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 ND 0.552 0.549 33.1 33.0 1 75.0-125 J6 J6 0.494 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 7 of 21

--------------
WG1798632
Wet Chemistry by Method 9034-9030B
Method Blank (MB)
(MB) R3743299-1 01/09/22 22:00
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/kg mg/kg mg/kg
Reactive Sulfide U 7.63 25.0
QUALITY CONTROL SUMMARY
L1447726-01
Laboratory Control Sample (LCS)
(LCS) R3743299-2 01/09/22 22:00
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg
Reactive Sulfide 100 122 122 70.0-130
L1447635-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1447635-02 01/09/22 22:00 • (MS) R3743299-3 01/09/22 22:00 • (MSD) R3743299-4 01/09/22 22:00
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Sulfide 100 ND 125 122 125 122 1 70.0-130 2.77
RPD Limits
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 3 of 21

WG1798313 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9045D L1447726-01
Laboratory Control Sample (LCS) C
(LCS) R3743204-1 01/05/22 14:00 p
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier ITC]
Analyte su su % %
Corrosivity by pH 10.0 10.0 100 99.0-101
F
Sample Narrative: SS
LCS:10 at18.8C
[Cn]
5
Sr
�GI
FAI
FSC1
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 9 of 21

WG1799366 QUALITY CONTROL SUMMARY
Wet Chemistry by Method D93/1010A L1447726-01
L1447726-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1447726-01 01/09/22 16:00 • (DUP) R3743276-3 01/09/22 16:00
Original Result DUP Result Dilution DUP RPD
Analyte Deg. F Deg. F
Ignitability DNI at170 DNI at170 1 0.000
DUP Qualifier DUP RPD
Limits
i
10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3748276-1 01/09/22 16:00 • (LCSD) R3748276-2 01/09/22 16:00
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte Deg. F Deg. F Deg. F
Ignitability 126 123 123 97.9 97.9 95.6-104 0.000 10
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 10 of 21

WG1800260 QUALITY CONTROL SUMMARY
Mercury by Method 7470A L1447726-01
Method Blank (MB)
(MB) R3749164-1 01/12/22 0812
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/I mg/I mg/I
Mercury U 0.00330 0.0100
Laboratory Control Sample (LCS)
(LCS) R3749164-2 01/12/22 08:14
Spike Amount LCS Result LCS Rec.
Analyte mg/I mg/I
Mercury 0.0300 0.0313 104
Rec. Limits LCS Qualifier
80.0-120
L1442497-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1442497-04 01/12/22 08:16 • (MS) R3749164-3 01/12/22 08:18 • (MSD) R3749164-4 01/12/22 08:20
Spike Amount
Original Result
MS Result
MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Mercury 0.0300
ND
0.0330
0.0312 110 104 1 75.0-125 5.70 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 11 of 21

WG1800417
Metals (ICP) by Method 6010D
Method Blank (MB)
(MB) R3749075-1 01/11/22 2325
MB Result
MB Qualifier MB MDL
MB RDL
Analyte mg/I
mg/I
mg/I
Arsenic U
0.0333
0.100
Barium U
0.0333
0.100
Cadmium U
0.0333
0.100
Chromium U
0.0333
0.100
Lead U
0.0333
0.100
Selenium U
0.0333
0.100
Silver U
0.0333
0.100
Laboratory Control Sample (LCS)
(LCS) R3749075-2 01/11/22 23:28
QUALITY CONTROL SUMMARY
L1447726-01
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
Analyte
mg/I
mg/I
Arsenic
10.0
9.27
92.7
80.0-120
Barium
10.0
9.34
93.4
80.0-120
Cadmium
10.0
9.64
96.4
80.0-120
Chromium
10.0
9.46
94.6
80.0-120
Lead
10.0
9.71
97.1
80.0-120
Selenium
10.0
9.76
97.6
80.0-120
Silver
2.00
1.90
94.9
80.0-120
LCS Qualifier
L1442497-16 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1442497-16 01/11/22 23:30 • (MS) R3749075-4 01/11/22 23:36 • (MSD) R3749075-5 01/11/22 23:38
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Arsenic
10.0
ND
9.39
9.37
93.3
93.1
Barium
10.0
6.07
15.6
15.1
94.9
90.1
Cadmium
10.0
0.155
9.87
9.85
97.1
97.0
Chromium
10.0
ND
9.45
9.53
94.5
95.3
Lead
10.0
2.00
11.8
11.7
98.0
96.6
Selenium
10.0
ND
9.81
9.95
98.1
99.5
Silver
2.00
ND
1.93
1.93
96.6
96.4
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
1 75.0-125
0.262
20
1 75.0-125
3.14
20
1 75.0-125
0.189
20
1 75.0-125
0.799
20
1 75.0-125
1.18
20
1 75.0-125
1.38
20
1 75.0-125
0.258
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 12 of 21

WG1800226 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1447726-01
Method Blank (MB)
(MB) R3743973-2 01/11/22 1113
MB Result
Analyte
mg/I
Benzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chloroform
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
2-Butanone (MEK)
U
Tetrachloroethene
U
Trichloroethene
U
Vinyl chloride
U
(S) Toluene-dH
104
(S) 4-Bromofluorobenzene
103
(S) 1,2-Dichloroethane-d4
100
MB Qualifier MB MDL
mg/I
MB RDL
mg/I
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
0.0833
0.250
0.0167
0.0500
0.0167
0.0500
0.167
0.500
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
80.0-120
77.0-126
70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3748973-1 01/11/22 08:55 • (LCSD) R3748973-3 01/11/22 1152
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
Analyte
mg/I
mg/I
mg/I
Benzene
0.250
0.255
0.237
102
94.8
70.0-123
Carbon tetrachloride
0.250
0.255
0.230
102
92.0
68.0-126
Chlorobenzene
0.250
0.258
0.260
103
104
80.0-121
Chloroform
0.250
0.243
0.241
97.2
96.4
73.0-120
1,2-Dichloroethane
0.250
0.235
0.245
94.0
98.0
70.0-128
1,1-Dichloroethene
0.250
0.239
0.205
95.6
82.0
71.0-124
2-Butanone (MEK)
1.25
1.59
1.56
127
125
44.0-160
Tetrachloroethene
0.250
0.255
0.247
102
98.8
72.0-132
Trichloroethene
0.250
0.267
0.245
107
98.0
78.0-124
Vinyl chloride
0.250
0.272
0.236
109
94.4
67.0-131
(S) Toluene-dH
101
103
80.0-120
(S) 4-Bromofluorobenzene
102
101
77.0-126
(S) 1,2-Dichloroethane-d4
94.6
96.8
70.0-130
LCS Qualifier
LCSD Qualifier RPD
7.32
10.3
0.772
0.826
4.17
15.3
1.90
3.19
8.59
14.2
RPD Limits
20
20
20
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 13 of 21

WG1800226 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1447726-01
L1448913-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1443913-02 01/11/22 17:33 • (MS) R3743973-4 01/11/22 1919 • (MSD) R3743973-5 01/11/22 19:40
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Benzene
0.250
ND
0.175
0.212
70.0
84.8
Carbon tetrachloride
0.250
ND
0.121
0.169
48.4
67.6
Chlorobenzene
0.250
ND
0.213
0.244
85.2
97.6
Chloroform
0.250
ND
ND
ND
80.4
91.6
1,2-Dichloroethane
0.250
ND
0.236
0.258
94.4
103
1,1-Dichloroethene
0.250
ND
0.117
0.153
46.8
61.2
2-Butanone (MEK)
1.25
ND
2.04
2.03
163
162
Tetrachloroethene
0.250
ND
0.149
0.188
59.6
75.2
Trichloroethene
0.250
ND
0.167
0.207
66.8
82.8
Vinyl chloride
0.250
ND
0.118
0.0698
47.2
27.9
(S) Toluene-dH
105
102
(S) 4-Bromofluorobenzene
107
109
(S) 1,2-Dichloroethane-d4
105
105
Dilution Rec. Limits
MS Qualifier MSD Qualifier
RPD
RPD Limits
1 17.0-158
19.1
27
1 23.0-159
J3
33.1
28
1 33.0-152
13.6
27
1 29.0-154
13.0
28
1 29.0-151
8.91
27
1 11.0-160
26.7
29
1 10.0-160
J5 J5
0.491
32
1 10.0-160
23.1
27
1 10.0-160
21.4
25
1 10.0-160
J3
51.3
27
80.0-120
77.0-126
70.0-130
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 14 of 21

WG1800468
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
(MB) R3749844-1 01/13/22 1610
MB Result
Analyte mg/I
2,4-D U
2,4,5-TP (Silvex) U
(S) Z4-Dichlorophenyl Acetic 70.2
Acid
QUALITY CONTROL SUMMARY
L1447726-01
MB Qualifier MB MDL
MB RDL
mg/I
mg/I
0.000667
0.00200
0.000667
0.00200
14.0-158
Laboratory Control Sample (LCS)
(LCS) R3749844-2 01/13/22 16:26
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
2,4-D 0.0500
0.0367
73.4
50.0-120
2,4,5-TP (Silvex) 0.0500
0.0390
78.0
50.0-125
(S) Z4-Dichlorophenyl Acetic
71.4
14. 0-158
Acid
L1446529-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1446529-01 01/13/22 23:58 • (MS) R3749844-3 01/14/22 00:14 • (MSD) R3749844-4 01/14/22 00:29
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
2,4-D
0.0500
ND
0.0356
0.0368
71.2
73.6
2,4,5-TP (Silvex)
0.0500
ND
0.0375
0.0395
75.0
79.0
(S)Z4-Dichlorophenyl Acetic
73.6
74.4
Acid
ACCOUNT:
EMA Resources
PROJECT:
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 50.0-120 3.31 20
1 50.0-125 5.19 20
14.0-158
SDG: DATE/TIME: PAGE:
L1447726 01/21/22 14:57 15 of 21

WG1802137
Pesticides (GC) by Method 8081B
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1447726-01
(MB) R3750132-1 01/14/22 12:49
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Gamma BHC
U
0.00167
0.00500
Endrin
U
0.00167
0.00500
Heptachlor
U
0.00167
0.00500
Heptachlor epoxide
U
0.00167
0.00500
Methoxychlor
U
0.00167
0.00500
Chlordane
U
0.00167
0.00500
Toxaphene
U
0.00333
0.0100
(S) Decachlorobiphenyl
71.2
10.0-128
(S) Tetrochloro-m-xylene
78.1
10.0-127
Laboratory Control Sample (LCS)
(LCS) R3750132-2 01/14/22 12:57
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
Analyte
mg/I
mg/I
Gamma BHC
0.0100
0.0106
106
55.0-129
Endrin
0.0100
0.0113
113
57.0-134
Heptachlor
0.0100
0.00974
97.4
27.0-132
Heptachlor epoxide
0.0100
0.0112
112
57.0-130
Methoxychlor
0.0100
0.0119
119
54.0-155
(S) Decachlorobiphenyl
68.8
10.0-128
(S) Tetrochloro-m-xylene
82.7
10.0-127
LCS Qualifier
L1446529-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1446529-01 01/14/22 13:15 • (MS) R3750132-3 01/14/22 13:24 • (MSD) R3750132-4 01/14/22 13:32
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Gamma BHC
0.0100
ND
0.00873
0.0102
87.3
102
Endrin
0.0100
ND
0.0101
0.0113
101
113
Heptachlor
0.0100
ND
0.00801
0.00944
80.1
94.4
Heptachlor epoxide
0.0100
ND
0.00950
0.0108
95.0
108
Methoxychlor
0.0100
ND
0.00850
0.0110
85.0
110
(S) Decachlorobiphenyl
75.1
83.5
(S) Tetrochloro-m-xylene
64.4
79.6
Dilution Rec. Limits
1 14.0-141
1 10.0-160
1 16.0-136
1 10.0-160
1 10.0-160
10.0-128
10.0-127
MS Qualifier MSD Qualifier RPD
15.5
11.2
16.4
12.8
25.6
RPD Limits
40
39
40
36
34
ACCOUNT: PROJECT: SDG:
EMA Resources L1447726
DATE/TIME:
01/21/22 14:57
PAGE:
16 of 21

WG1804747 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1447726-01
Method Blank (MB)
(MB) R3751992-2 01/20/22 1515
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
U
0.0333
0.100
2,4-Dinitrotoluene
U
0.0333
0.100
Hexachlorobenzene
U
0.0333
0.100
Hexachloro-1,3-butadiene
U
0.0333
0.100
Hexachloroethane
U
0.0333
0.100
Nitrobenzene
U
0.0333
0.100
Pyridine
U
0.0333
0.100
2-Methylphenol
U
0.0333
0.100
3&4-Methyl Phenol
U
0.0333
0.100
Pentachlorophenol
U
0.0333
0.100
2,4,5-Trichlorophenol
U
0.0333
0.100
2,4,6-Trichlorophenol
U
0.0333
0.100
(S) Nitrobenzene-d5
59.4
10.0-127
(S) 2-Fluorobiphenyl
64.3
10.0-130
(S) p-Terphenyl-d14
83.1
10.0-128
(S) Phenol-d5
28.8
10.0-120
(S) 2-Fluorophenol
45.4
10.0-120
(S) 2,4, 6-Tribromophenol
61.0
10. 0-155
Laboratory Control Sample (LCS)
(LCS) R3751992-1 01/20/22 1453
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
1,4-Dichlorobenzene 0.500
0.338
67.6
18.0-120
2,4-Dinitrotoluene 0.500
0.413
82.6
49.0-124
Hexachlorobenzene 0.500
0.367
73.4
44.0-120
Hexachloro-1,3-butadiene 0.500
0.274
54.8
19.0-120
Hexachloroethane 0.500
0.335
67.0
15.0-120
Nitrobenzene 0.500
0.309
61.8
27.0-120
Pyridine 0.500
0.0950
19.0
10.0-120
2-Methylphenol 0.500
0.303
60.6
28.0-120
3&4-Methyl Phenol 0.500
0.334
66.8
31.0-120
Pentachlorophenol 0.500
0.349
69.8
23.0-120
2,4,5-Trichlorophenol 0.500
0.376
75.2
44.0-120
2,4,6-Trichlorophenol 0.500
0.372
74.4
42.0-120
(S) Nitrobenzene-d5
57.3
10.0-127
(S) 2-Fluorobiphenyl
71.2
10.0-130
(S) p-Terphenyl-d14
80.3
10.0-128
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1447726 01/21/22 14:57 17 of 21

WG1804747 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1447726-01
Laboratory Control Sample (LCS)
(LCS) R3751992-1 01/20/22 1453
Spike Amount LCS Result LCS Rec.
Analyte mg/I_ mg/I
Rec. Limits LCS Qualifier
(S) Phenol-d5 33.6 10.0-120
(S) 2-Fluorophenol 50.5 10.0-120
(S) 2,4, 6-Tribromophenol 74.0 10. 0-155
L1447055-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1447055-02 01/20/22 17:47 • (MS) R3751992-3 01/20/22 13:09 • (MSD) R3751992-4 01/20/22 13 30
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
Analyte
mg/I
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
0.500
ND
0.343
0.325
68.6
65.0
1 17.0-120
5.39
2,4-Dinitrotoluene
0.500
ND
0.415
0.415
83.0
83.0
1 39.0-125
0.000
Hexachlorobenzene
0.500
ND
0.359
0.347
71.8
69.4
1 35.0-122
3.40
HexachIaro-1,3-butadiene
0.500
ND
0.279
0.272
55.8
54.4
1 12.0-120
2.54
Hexachloroethane
0.500
ND
0.333
0.319
66.6
63.8
1 10.0-120
4.29
Nitrobenzene
0.500
ND
0.313
0.312
62.6
62.4
1 12.0-120
0.320
Pyridine
0.500
ND
ND
0.105
9.88
21.0
1 10.0-120
J6 J3 72.0
2-Methylphenol
0.500
ND
0.311
0.291
62.2
58.2
1 10.0-120
6.64
3&4-Methyl Phenol
0.500
ND
0.346
0.327
69.2
65.4
1 10.0-120
5.65
Pentachlorophenol
0.500
ND
0.373
0.362
74.6
72.4
1 10.0-128
2.99
2,4,5-Trichlorophenol
0.500
ND
0.376
0.380
75.2
76.0
1 33.0-120
1.06
2,4,6-Trichlorophenol
0.500
ND
0.363
0.370
72.6
74.0
1 26.0-120
1.91
(S) Nitrobenzene-d5
60.2
57.6
10.0-127
(S) 2-Fluorobiphenyl
68.1
678
10.0-130
(S) p-Terphenyl-d14
85.0
79.7
10.0-128
(S) Phenol-d5
32.1
31.9
10.0-120
(S) 2-Fluorophenol
50.0
48.8
10.0-120
(S)2,4,6-Tribromophenol
71.5
72.5
10.0-155
RPD Limits
40
25
24
34
40
30
37
30
36
37
31
31
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1447726 01/21/22 14:57 13 of 21

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
u
Fc
Fss]
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
Fn
RDL
Reported Detection Limit.
Rec.
Recovery.
Fr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
F
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
F
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Rc
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe
samples from the time of collection until delivery to the laboratory for analysis.
This section ofyour report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J3
The associated batch QC was outside the established quality control range for precision.
J5
The sample matrix interfered with the ability to make any accurate determination, spike value is high.
J6
The sample matrix interfered with the ability to make any accurate determination, spike value is low.
T8
Sample(s) received past/too close to holding time expiration.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1447726 01/21/22 14:57 19 of 21

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
N E-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TNO02
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704 _
Georgia
NELAP
North Carolina 3
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky' 6
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee'"
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas5
LABO152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A2 LA
A2LA— ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A2 LA — ISO 17025 5
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
Rc
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1447726 01/21/22 14:57
PAGE:
20 of 21

Company Name/Address:
Billing Information:
EMA Resources
Mr. Brent Collins Pres
755 Yadkinville Road Chk
755 Yadkinville Road
Mocksville, NC 27028
Mocksville, NC 27028
Report to:
Email To:
Mr. Brent Collins
[e-mail];roy.whitak
Project Description_
City/State y �
)Ot qee i C
Please Circle
PT MT CT
Sludge
Collected: /V
Client Project #
Lab Project s
Phone: [phone]
a�
Coll d by (prin
Site/Facility ID #
P.O. #
a
O �'f r C
L1
Z
Collected gnarl
Rush? (Lab MUST Be Notified) Quote 8
a
O
6=
Same Day _ Five Day I
V
J
Next Day 5 Day (Rod oniyj Date Results Needed
'-
Immll!cliatfly
_
�_ Two Day 10 Day (Rad only) No.
J
Packed on Ice N _ Y
Three Day of
ri
Sample ID
Comp/Grab Matrix'
Depth
Date 7E
Time
ntrs
C
55
3'
113JZZ
J:no
2
x
X
mi+hi'4114
Matrix:
i - Soil AIR - Air F - Filter
IN - Groundwater B - Bioassay
'W - Wastewater
W - Drinking Water
T - Other
elingv.9hgd by )SAri�lurey
inquisjxd by :
Relinquished by : (Signature)
Samples returned via:
UPS Fedlx Courier
Date:
113/22
Date:
YJ32Z
Date:
Tracking #
Time:
Received by: (Signature)
19 4/0
Time
Received by: (Signature)
Time
I Received fo bv' {
Chain of Custody Page of
(��a?eAnaVical"
12065 Lebanon Rd Mount lullet, TN 17122
Sobmittme a sample ria this chain 0-1rody
_11*uter a owledemeM and x "Un[e Of the
Pace Terms and Cmditlansfound at:
http 1/In0o.p—labs com/hulls/parstandard
I.— pol
SDG # ( I I r ' 0 Y
J1g5
Acctnum: EMARES
Template:T11413
Prelogin: P895411
PM: 807 - Justin Carr
Shipped Via: Fed EX Ground
Rema,ws I `:ample p (lab only)
- { i
Sample Receipt Ch.:-._.
pH
Temp
COC Seal Present/Intact: P
N
�
CCC Signed/Accurate:
N
Flow
Other
Bottles arrive intact:
_X' N
Correct bottles used:
Sufficient volume sent:
j( Acalicable
VOA Zero Readspace:
N
Y N
sriq 61 roc
Preservation Correct/Checked:
�Y �N
Trip Blank Received: Yes/No
RAD Screen <0.5 mR/hr:_N
HCt / MeoH
TBR
-C Bottles Received:
if preservation required by Login: Datei
1- E*-"45 ^-f'
Date: TimeHold: Cnndit
d Q:1 Fl s I
NCF /

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Smithfield Fresh Meats Corp. WQ Permit Number: WQ0014868
WWTP Name: Tarheel WWTP
NPDES Number: NCO078344
Monitoring Period: From l/l/2022 To 12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
Alt.D (No Prior Test) ❑
I Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
I Heat Drying ❑
1 Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑
1 Pasteurization ❑
Class B:
I Alt. (1) Fecal Density 0
I Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
1;xcee-
ences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
83333
111637
152174
CFU/ g
0
l
Quarterly
G
SM9222D
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable)
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
❑`' "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Dwayne Russ - ORC Brent Collins; Director of Technical Services
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
✓�GdGIuss(Fee 1,2023 Feb 10, 2023 G 1/26/2023
Dwayne uss (Feb 13, 2023 07:26 EST) '�"�
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No. 165
A `.
Page 1
Contact: Brent Collins Report Date: 1/26/2022
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028 Date Sample Rcvd: 1/19/2022
Meritech Work Order # 01192235 Sample: Smithfield North 1 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.60 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 152,174 col/gdry wt 1/19/22 130 col/gdry wt SM 9222D
Meritech Work Order # 01192236 Sample: Smithfield North 2 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.67 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 107,066 col/g dry wt 1/19/22 130 col/g dry wt SM 9222D
Meritech Work Order # 01192237 Sample: Smithfield North 3 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.37 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (SIudge) 102,975 col/g dry wt 1/19/22 130 col/g dry wt SM 9222D
Meritech Work Order # 01192238 Sample: Smithfield North 4 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.56 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 83,333 col/g dry wt 1/19/22 130 col/gdry wt SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
AMP
r
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
MocksvilIe, NC 27028
Page 2
Report Date: 1/26/2022
Date Sample Rcvd: 1/19/2022
Meritech Work Order # 01192239 Sample: Smithfield North 5 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.52 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 112,832 col/g dry wt 1/19/22 130 col/g dry wt SM 9222D
Meritech Work Order # 01192240 Sample: Smithfield North 6 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.73 % 1/20/22 0-100 % SM 2540E
Fecal Coliform (Sludge) 105,708 col/g drywt 1/19/22 130 col/g dry wt SM 9222D
Meritech Work Order # 01192241 Sample: Smithfield North 7 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids
4.63 %
1/20/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
129,590 col/g dry wt
1/19/22
130 col/g dry wt
SM 9222D
I hereby certify that have reviewed and approve these data. JmuiQLa kafu Qom.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

x`
Y
ECL
v�
=
U
c
�
N
L
❑
Itl
Q1 Z
Nl
4
Q
F "a
i1
i i
O
•�
J
�
°
Uzi
m
-' �
° a
CL
:
E
E
v c v
=
ri rl
q
H }:
U
1
Ln Ln —
2
to
tw
-19
~
�
O
n V
rJ]
�
O
ry
�
�
u
!a
ti
R
m m
1
f
Ln
Lu —
Qy
•,
J
a °
0
m
E
a� L� Lt
a
��
i
°
,�c+(T�
�
X
r
N
VI LL
/�{
C
�1
Q �'
cu L
G
L
Q
U'I
v
U 00
C O
O
a
�r
�,
�CL
r�,
y 1
`�
,
C
a
v U
U
v
(U
L ] Z
C
�^
�
0
a
V
p
Q
Ln Y =
=
QJ
J
Q U
`i�
7
_Ln
7_
Ln
Lu r,
ca
CL
x
s
ce
n
Ln
o
m
u
Z
cuc
o
❑
a
CL
c
ti
ti
ai
co
i
>
, ,
VLn N
F-,
Lu
u
i
0
0�
w
^�
M1vi
O N N
tp
O
Q
V
(Mrl M fO
O M
T m w
Q
O
E
o
V
L X i Ln
V a
'�.
�`
[p
LL
W a
o
L
o
z
E
�,
L
ce
UA Q 0
C (}
N
O
m
N
M
N
o
O cr u
4-1
W z L
V
"'
Z
N
^�j
T
4l
o
v
}
uw H
v
d
C
ai
[B
Nei.
c
Q
c
_
O
�
«
L
C6
°N
}
_
�
Q
LL
=
C
N
N
❑
❑
❑
❑

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Smithfield Fresh Meats Corp. WQ Permit Number: WQ0014868
WWTP Name: Tarheel WWTP
NPDES Number: NCO078344
Monitoring Period: From l/l/2022 To 12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
Alt.D (No Prior Test) ❑
I Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
I Heat Drying ❑
1 Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑
1 Pasteurization ❑
Class B:
I Alt. (1) Fecal Density 0
I Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
1;xcee-
ences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
57592
71206
83117
CFU/ g
0
l
Quarterly
G
SM9222D
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable)
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
❑`' "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Dwayne Russ - ORC Brent Collins; Director of Technical Services
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
L14Wayne, LIl1l nYk20 Feb lo, 2023 1/26/2023
Dwayne Muss (Feb 10, 2023 07:26 EST) '�"" �
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Page 1
Report Date: 1/29/2022
Mocksville, INC. 27028 Date Sample Revd: 1/19/2022
Meritech Work Order # 01192242 Sample: Smithfield South 1 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids
Fecal Coliform (Sludge)
3.96 %
75,758 cal/g dry wt
1/20/22
1/19/22
0-100 %
130 col/g dry wt
SM 2540B
SM 9222D
Meritech Work Order #
01192243 Sample: Smithfield South 2 Grab
1/19/22
Parameters
Result
Analysis Date Reporting Limit
Method
% Total Solids
3.81 %
1/20/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
74,803 col/g dry wt
1/19/22
130 col/g dry wt
SM 9222D
Meritech Work Order # 01192244 Sample: Smithfield South 3 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.08 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 68,627 col/g dry wt 1/19/22 130 col/g dry wt SM 9222D
Meritech Work Order # 01192245 Sample: Smithfield South 4 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 3.82 % 1/20/22 0-100 % SM 2540E
Fecal Coliform (Sludge) 57,592 col/g dry wt 1/19/22 130 col/g dry wt SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
drr•
Page 2
Contact: Brent Collins Report Date: 1/26/2022
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028 Date Sample Rcvd: 1/19/2022
Meritech Work Order # 01192246 Sample: Smithfield South 5 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.16 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 67,308 col/g dry wt 1/19/22 130 col/g dry wt SM 9222D
Meritech Work Order # 01192247 Sample: Smithfield South 6 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.05 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 74,074 col/g dry wt 1/19/22 130 col/g dry wt SM 9222D
Meritech Work Order # 01192248 Sample: Smithfield South 7 Grab 1/19/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 3.85 % 1/20/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 83,117 col/g dry wt 1/19/22 130 col/g dry wt SM 9222D
I hereby certify that I have reviewed and approve these data. HM-1C +
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

c
=❑
T
Y Y
D
v
=
O
0
o
cL
2
c
`�
* cL
Q
E o
.
?
? �
O
\
N
o
l
r•
E
o
��
��
a
a
m
E
-1 N m
aj
J
Q1
cai
~�
~
_—
~
G
m
H
u
to
Ln Ln
tA
tD c
�
O
m m m
a
Z Q. lL W
a-
Q.
y
V
cr
w
tA
T
T
uS-
o
o
�Q)
o
1
v)
.v
m
00
_
+s
41 [o I
/y
a
Col
C
U (..j
Y t�
c
(w
W
c
cli
rL
m )
u
} U
a.+
C
o
a
cQ
C Ln
ai
3:mo
2 N
C
O c
ro
`
Y
It
N
N
++ IU
Z;
�
u
H
=
Y
h
❑
Q
M
p
a
a
a
o
-
..
v
E
a�Qj
L
cob
V N
I
V
`
C
y
C
ro
m
zss
O v N O
M u
d
Q
n
n
O
Z C+"1
Q Ln
E
ko tp
m m E
4j
Q
o ri
0
❑
o
6
0
= Q P
to
o
_
acL
u-
E
�
o
v
c,
`
o
W c�
u
z , —
H iLl O O
vq
a
m C}
m
N
¢
m
c
—
z N_
O
o 'r u
vi
W 25 O
�?
j w au
v1
.�
a
z m
¢
C
a m
p
C
v
a
-r-
°1
c
L
rD
E
Q
c
c
c
0
u
o
i
U
o 4
}
O
J
4
=
O OJ
Ln
x
LU
v
aLs
N
Li
O
Ln
❑
❑
❑
❑

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Smithfield Fresh Meats Corp. WQ Permit Number: WQ0014868
WWTP Name: Tarheel WWTP
NPDES Number: NCO078344
Monitoring Period: From l/l/2022 To 12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
Alt.D (No Prior Test) ❑
I Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
I Heat Drying ❑
1 Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑
1 Pasteurization ❑
Class B:
I Alt. (1) Fecal Density 0
I Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
1;xcee-
ences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
39801
53528
69479
CFU/ g
0
l
Quarterly
G
SM9222D
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable)
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
❑`' "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Dwayne Russ - ORC Brent Collins; Director of Technical Services
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
LWqu1he 70G2LI Feb lo, 2023 1/26/2023
Dwayne Muss (Feb 10, 2023 07:26 EST)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No. 165
Contact: Brent Collins
Client: EMA Resources, Inc
755 YadkinviIle Road
Mocksville, NC 27028
Page 1
Report Date: 3/3/2022
Date Sample Rcvd: 2/21/2022
Meritech Work Order # 02212207 Sample: Smithfield North 1 Grab 2/21/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.00 % 2/22/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 55,000 col/g dry wt 2/21/22 130 col/g dry wt SM 9222D
Meritech Work Order # 02212208 Sample: Smithfield North 2 Grab 2/21/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids
4.02 %
2/22/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
39,801 col/g dry wt
2/21/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
02212209 Sample: Smithfield North 3 Grab
2/21/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
4.02 % 2/22/22 0-100
%
SM 2540B
Fecal Coliform (Sludge)
62,189 col/g dry wt 2/21/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
02212210 Sample: Smithfield North 4 Grab
2/21/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
3.96 % 2/22/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
65,657 col/g dry wt 2/21/22
130 col/g dry wt
SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental. Laboratory
Laboratory Certification No.165
Page 2
Contact: Brent Collins Report Date: 3/3/2022
Client: EMA Resources, Inc
755 YadkinviIle Road
Mocksville, NC 27028 Date Sample Rcvd: 2/21/2022
Meritech Work Order # 02212211 Sample: Smithfield North 5 Grab 2/21/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 3.85 % 2/22/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 44,156 col/g dry wt 2/21/22 130 col/g dry wt SM 9222D
Meritech Work Order # 02212212 Sample: Smithfield North 6 Grab 2/21/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 3.92 % 2/22/22 0-100 % SM 2540E
Fecal Coliform (Sludge) 45,918 col/g dry wt 2/21/22 130 col/g dry wt SM 9222D
Meritech Work Order # 02212213 Sample: Smithfield North 7 Grab 2/21/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.03 % 2/22/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 69,479 col/g dry wt 2/21/22 130 col/g dry wt SM 9222D
I hereby certify that i have reviewed and approve these data.y�p�� �pc1�j
Laboratory Representative
642 Tarnco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

M1• ft,
E
0
-4
O
o
a
n
a
N
0
_�
2
IL
c�
at
O
4
H
m
Z
`—'
a n
CL
E_
N
Cu
J
O 0))
E v
O
1-1 r`a
't I;T m
c x
N
ri rl
� O
LLLJJJ
�
n Ln
$
M
cc
t-I
mN
m M a
*
ro
a—
M M c
W
O Xcs
Z d u
m
ep
LE
+
�
a�
C
X
�CL
U-
v
o
i
o
—
O
V)
_0
0
L
V)
v
v
�
3
`WO
Y
s
V) C:� r
v U
Y
cu
cU
O
—
R1
J
-a Qelf
°G
j
Y
�-
to 0
Q } U
c
O
�/
q1
n
}
v
L U n C
m
}, _
al
cc
el
5
a1
BC
O
m
E
of
O
2 �
C
rYp
0
O
# U
Z
ai
Y
o
C:
ci
r
U Q
Q
d
u l7
D
�
Z
ai
Gi
ti
d7
1—
>-
\
co
N
~
O N
f6
O
of
d
d
d
Qm
y
E
a
to
CC m m m
¢
a
fth m
O m
Q
o
Co 6
v
�
I
o
V o X_
_
o
E
a
U
W
E
to
P
N
Z
W+-
�'
O
n N
Z -a N _
p
5
O
N
�J
O W u
'L
s
W 0 z E
Vj
E w w
d
a,
}
;
Zuj En
�
V N �
0
C
Q
V
�
G
6
Q
c
c
c
'U
O
> �
J
�
Ln
u
`
E
a
o
v
LL
a
O
d
N
❑
❑
❑
❑
t

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Smithfield Fresh Meats Corp. WQ Permit Number: WQ0014868
WWTP Name: Tarheel WWTP
NPDES Number: NCO078344
Monitoring Period: From l/l/2022 To 12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
Alt.D (No Prior Test) ❑
I Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
I Heat Drying ❑
1 Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑
1 Pasteurization ❑
Class B:
I Alt. (1) Fecal Density 0
I Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
1;xcee-
ences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
39627
58473
73350
CFU/ g
0
l
Quarterly
G
SM9222D
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable)
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
❑`' "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Dwayne Russ - ORC Brent Collins; Director of Technical Services
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
✓�WGl'1/9G 1yG�� Feb lo, 2023 1/26/2023
Dwayne uss (Feb 10, 2423 D7:26 EST)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Meritech, Inc.
Environmental. Laboratory
Laboratory Certification No.165
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Page 1
Report Date: 3/3/2022
Date Sample Rcvd: 2/21/2022
Meritech Work Order #
Parameters
% Total Solids
Fecal Coliform (Sludge)
02212214 Sample: Smithfield South 1 Grab
Result Analysis Date Reporting Limit
4.09 % 2/22/22 0-100 %
73,350 cal/g dry wt 2/21/22 130 col/g dry wt
2/21/22
Method
SM 254013
SM 9222D
Meritech Work Order #
02212215 Sample: Smithfield South 2 Grab
2/21/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
4.10 % 2/22/22 0-100
%
SM 2540B
Fecal Coliform (Sludge)
53,659 col/g dry wt 2/21/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
02212216 Sample: Smithfield South 3 Grab
2/21/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
4.19 % 2/22/22 0-100
%
SM 2540B
Fecal Coliform (Sludge)
52,506 col/g dry wt 2/21/22
130 col/g dry wt
SM 9222D
Meritech Work Order # 02212217 Sample: Smithfield South 4 Grab 2/21/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 4.18 % 2/22/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 71,770 col/g dry wt 2/21/22 130 col/g dry wt SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Asa
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Page 2
Report Date: 3/3/2022
Date Sample Rcvd: 2/21/2022
Meritech Work Order #
Parameters
% TotaI Solids
Fecal Coliform (Sludge)
02212218 Sample: Smithfield South S Grab
Result Analysis Date Reporting Limit
4.29 % 2/22/22 0-100 %
39,627 col/g dry wt 2/21/22 130 col/g dry wt
2/21/22
Method
SM 2S40B
SM 9222D
Meritech Work Order #
02212219 Sample: Smithfield. South 6 Grab
2/21/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
4.38 % 2/22/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
63,927 col/g dry wt 2/21/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
02212220 Sample: Smithfield South 7 Grab
2/21/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
4.18 % 2/22/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
62,201 col/g dry wt 2/21/22
130 col/g dry wt
SM 9222D
I hereby certify that I have reviewed and approve these data. _ _ _ . HUV)CP U
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

ra
E
o
co
d
_
° °
e
on
o
.� Q
c7' V
a
u
v cod1
a
❑
O
Q
a
o
a
o
w a
p
CL
tw
a;
E
°'
E
y
i
c-I N m
01
CL
Q
N
`M
J
H
O>
C' 'm
W
E
Ll
H
H
•
In Ln
M
f'+'1 M
rn M
N
W
uj
W
+
c
Ca O X C°
4
Q
m
o
�-
Z a LL Lu
a
a
i X
�7
v1 U-
I`cl
/ {
�dJ
O
o
N
v l
N
N
`lam
U N
p
O Q
?
'~
�L
ai
+'
O
v (N
p
V)
s
Q
a1 V
c
vN
�+
Z
a
�•
vQ
:2 Q
} Y
Y
:3
-(7}1
7•
LLl
m
}> _
CL
Q ro
-
s �
o C
p
L
0
u\1
N
+, m
F-
F
❑
L
4J
r_
-
Y
7v
O ''
m
U Q
Q
n
u p
o
C
al
Z
E
E
E
N
Q
F
F
F
E
V
V N
LJJ
U
ti
LLI
aJ
O N N
r
Q
�
m m YCL
4
6 c
rn M
w
a
fth O m m
0
o
y
ti
b
ECL
o
Qm
.J0 X z
•�
•Q
Qd LL
i
q
o
W
E
�,
z
o
Q
w
c U
c/]
-o
rn
Z N -_
N
o
a O u 'ta
'�
L
W E
ai
u
j °' �' cv
N
�
?
.4
Y
4-
Z m ?
W
0
O
W
7
p
-o
M
-c
C
Kt
Lo t[
O
n
a�
d
N
v
r
v
m
.
p
Q
V
i
(
LU
m
a
C_
U-
°
a
N
Lr)
�`s`'❑❑❑❑

Land App ANL Volatile Solids In
DAFE c
TSS mg/1
DAFEc
TvSS mg/1
..
Jan 2022
58900.00
54250.00
92.11
Feb 2022
63650.00
58850.00
92.46
Mar 2022
73550.00
68900.00
93.68
Apr 2022
56650.001
50300.00
88.79
May 2022
58350.00
54050.00
92.63
Jun 2022
64750.00
60750.00
93.82
Ju12022
63850.00
59600.00
93.34
Aug 2022
56750.00
53100.00
93.57
Sep 2022N721240.00
54300.00
90.42
Oct 2022
43400.00
92.74
Nov 2022
54450.00
92.60
Dec 20220
55000.00
93.00
Minimum
0
43400.00
Maximum0
68900.00
Total
0
666950.00
Average
0
55579.00
92.43

Volatile Solids Out
Volatile Solids IN average
% Reduction
1/9/22 North
77.8
92.43
71.30
1/3/2022 South
76.5
92.43
73.34
2/21/22 North
76.8
92.43
72.89
2/21/22 South
1 76.10
92.43
73.92

Page 1 of 1
Report No: 22-312-9646
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Steve Dunham
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:SF03
Date Received: 11/08/2022
Date of Report: 12/28/2022
Lab No Field ID
Sample ID
Soil Class HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
18615
1
MIN
5.4
2.9
596
90
33
56
0 0
2483
2483
695
10.2
72
54
13
0.7
0.1
18616
4
M-0
5.8
2.7
120
32
21
19
0 0
705
881
140
14.1
81
55
24
1.1
0.2
18617
6
MIN
7.2
0.0
240
14
44
81
0 0
900
900
450
14.4
100
91
8
0.6
0.1
18618
7
MIN
6.0
1.0
35
29
29
63
0 0
175
175
80
6.5
85
53
28
1.7
0.1
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-038-1154
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Steve Dunham
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:SF03
Date Received: 02/07/2022
Date of Report: 02/08/2022
Lab No Field ID
Sample ID
Soil Class
HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
10113
2
MIN
1.0
6.4
0.7
367
15
27
56
0 0
1625
1625
450
7.8
91
71
18
0.8
0.1
10114
3
MIN
1.1
6.4
0.7
394
18
27
56
0 0
1763
1763
495
8.1
91
70
19
0.9
0.1
10116
5
MIN
1.1
6.4
0.7
412
18
25
56
0 0
1845
1845
495
8.0
91
70
19
0.8
0.1
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-312-9689
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Vance Tyson
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:SF06
Date Received:11/08/2022
Date of Report: 12/28/2022
Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-1 Mn-All Mn-Al2 Zn-1 Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na
18732 7 MIN 1.9 5.8 2.1 183 59 104 25 0 0 188 188 75 11.1 81 51 27 0.6 0.1
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-312-9647
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: J.W. Burney
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:SF07
Date Received: 11/08/2022
Date of Report: 12/28/2022
Lab No Field ID
Sample ID
Soil Class HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
18619
1
MIN
7.1
0.0
125
19
35
256
0 0
1008
1008
785
12.0
100
69
28
1.4
0.2
18621
3
MIN
5.9
1.2
59
14
17
981
0 0
433
433
380
7.1
83
60
21
1.5
0.1
18622
6
MIN
4.8
6.0
802
42
54
113
0 0
4138
4138
1540
12.9
53
42
9
0.9
0.1
18623
8
MIN
5.2
3.8
655
63
40
375
0 0
3530
3530
1035
11.0
66
51
12
0.8
0.1
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-312-9688
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Bonnie Meeker
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:SF07
Date Received: 11/08/2022
Date of Report: 12/28/2022
Lab No Field ID
Sample ID
Soil Class
HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
18728
9
MIN
0.9
4.4
3.3
612
34
37
131
0 0
998
998
1035
5.3
38
29
4
1.1
0.1
18730
14
MIN
1.5
6.6
0.6
298
16
33
50
0 0
1160
1160
545
9.8
94
72
20
0.8
0.1
18731
15
MIN
1.2
5.4
1.2
183
18
29
38
0 0
305
305
85
4.2
71
50
18
1.1
0
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-089-0918
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Mack King
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:SF08
Date Received: 03/30/2022
Date of Report: 04/01 /2022
Lab No Field ID
Sample ID
Soil Class
HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
23353
01
MIN
0.8
6.2
0.6
204
30
17
219
0 0
250
250
125
4.7
87
63
19
1.6
0.1
23354
02
MIN
0.8
6.2
0.5
201
26
17
200
0 0
250
250
130
4.2
88
64
19
1.8
0.1
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-312-9648
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Musselwhite Family Trust
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:SF09
Date Received: 11/08/2022
Date of Report: 12/28/2022
Lab No Field ID
Sample ID
Soil Class HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
18624
1
MIN
4.7
3.8
424
71
62
206
0 0
723
723
475
7.6
50
37
7
1.2
0.1
18625
2
MIN
5.0
1.5
367
20
12
256
0 0
255
255
175
3.6
58
47
7
1.6
0.1
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

2T Annual Report Forms
Final Audit Report 2023-02-10
Created: 2023-02-06
By: Brent Collins ([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAABdybkBaK111V46-GfubHWslNegOvk86U
"2T Annual Report Forms" History
Document created by Brent Collins ([e-mail])
2023-02-06 - 4:33:43 PM GMT- IP address: 206.85.202.26
P-► Document emailed to [e-mail] for signature
2023-02-06 - 4:35:56 PM GMT
Email viewed by [e-mail]
2023-02-10 - 12:23:21 PM GMT- IP address: 50.225.252.4
dp Signer [e-mail] entered name at signing as Dwayne Russ
2023-02-10 - 12:26:33 PM GMT- IP address: 50.225.252.4
Gip Document e-signed by Dwayne Russ ([e-mail])
Signature Date: 2023-02-10 - 12:26:35 PM GMT - Time Source: server- IP address: 50.225.252.4
Q Agreement completed.
2023-02-10 - 12:26:35 PM GMT
0 Adobe Acrobat Sign

Smithfield Signature Page
Final Audit Report 2023-02-13
Created: 2023-02-13
By: Brent Collins ([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAA6sn8fO54bKgkeBfoOHZg79Nj7CefSyh5
"Smithfield Signature Page" History
Document created by Brent Collins ([e-mail])
2023-02-13 - 9:37:12 PM GMT- IP address: 206.85.202.26
P-► Document emailed to [e-mail] for signature
2023-02-13 - 9:38:06 PM GMT
Email viewed by [e-mail]
2023-02-13 - 11:01:45 PM GMT- IP address: 50.225.252.6
dp Signer [e-mail] entered name at signing as Andrea Tucker
2023-02-13 - 11:02:21 PM GMT- IP address: 50.225.252.6
Gip Document e-signed by Andrea Tucker ([e-mail])
Signature Date: 2023-02-13 - 11:02:23 PM GMT - Time Source: server- IP address: 50.225.252.6
Q Agreement completed.
2023-02-13 - 11:02:23 PM GMT
0 Adobe Acrobat Sign