WQ0002712_2022 Residual Annual Report_20230228 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0002712
Applicant/Permittee City of Lincolnton
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Mooresville
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Lysa Finnerty
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
4105376150
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0002712
Has Current Existing permit number
Applicant/Permittee Address*
435 Williams Court, Ste 100, Baltimore, MD 21220
Facility Name*
City of Lincolnton Class B Residuals Program
Please provide comments/notes on your current submittal below.
2022 Annual Report for City of Lincolnton, NC
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
Lincolnton NC 2022 Annual Report FINAL.pdf 17.74MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Alva �Cit'wt%tt,
Submission Date 2/28/2023

435 Williams Court, Suite 100
Baltimore, MD 21220
www.synagro.com
FEBRUARY 28, 2023
NCDEQ
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2022 Annual Report for Permit No. WQ0002712
Dear NCDEQ:
SYNAGRO
Synagro is submitting one electronic copy of the above referenced report on behalf of the City
of Lincolnton, NC.
If you have any questions or need additional information, please do not hesitate to contact
Richey Haynes at [phone] or Alex Fox at [phone].
Sincerely,
De1U & skkc"
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: Richey Haynes, City of Lincolnton
Alex Fox, Synagro
YOUR PARTNER FORA CLEANER, GREENERWORLD

CITY OF LINCOLNTON, NC
RESIDUALS LAND APPLICATION PROGRAM
Permit No. WQ0002712
2022 ANNUAL REPORT

City of Lincolnton, NC
Residuals Land Application Program
2022 Annual Report
TABLE OF CONTENTS
1. Certification Form and Annual Operations Summary
2. Annual Residual Sampling Summary Forms and Residuals
Analyses
3. Annual Land Application Field Summary Forms
4. TCLP Analysis
5. Pathogen ReductionNector Attraction Reduction
6. Soil pH & Lime Application Records
7. Soil Analyses

SECTION 1

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit #: WQ0002712 County Lincoln Year 2022
Facility Name (as shown on permit) City of Lincolnton WWTP and WTP NPDES No. NC0025496 & 0085588
Land Application Operator Synagro Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. If NO, skip PartA, and PartB and proceed to Part C, Also, if residuals were generated but not land applied,
please attach an explanation on how the residuals were handled.
Part A — Residuals Application Summary;
Total number of application fields in the permit: 33
Total number of fields utilized for land application during the year; 9
Total amount of dry tons applied during the year for all application sites: 526.08
Total number of acres utilized for land application during the year: 283.88
Part B — Annual Compliance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit (including but not limited to items
1-13 below) issued by the Division of Water QualityX YES NO.
If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this pen -nit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I105(a) or the Pollutant Loading
Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities),
7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503
regulated facilities).
S. All monitoring and reporting requirements in 15A NCAC 02T. 1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9, All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified
in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C — Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations."
i
Ritchie Haynes, City Manager 0'
Pe7mgt' (type or print) igtiati re of Pe ' cc Date
~off $"a1 2/20/2023
Signature of Preparer* U Date Signa and A er Date
(if different from Pemnittee) (if different from ermittee and Preparer)
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T A 102 (26) DENR FORM ACF (1212006)

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 1/1/2022 - 4/10/2022
LINCOLNTON, NC
LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID
MONTH/YEAR
January 2022
February 2022
March 2022
TOTAL
Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards
Report Date: 2/9/2023 3:59:15 PM
AMOUNT
UNIT
DRY TONS
UNIT
DRY METRIC TONS
155,000.00
G
34.64
D
31.42
223,200.00
G
49.89
D
45.25
589,000.00
G
131.65
D
119.41
967,200.00
G
216.18
D
196.08

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 5/23/2022 - 6/14/2022
LINCOLNTON, NC
LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID
MONTH/YEAR
May 2022
TOTAL
Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards
Report Date: 2/9/2023 4:03:00 PM
AMOUNT
UNIT
DRY TONS
UNIT
DRY METRIC TONS
564,200.00
G
112.69
D
102.21
564,200.00
G
112.69
D
102.21

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 7/26/2022 - 8/13/2022
LINCOLNTON, NC
LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID
MONTH/YEAR
July 2022
TOTAL
Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards
Report Date: 2/9/2023 4:05:04 PM
AMOUNT
UNIT
DRY TONS
UNIT
DRY METRIC TONS
167,400.00
G
38.25
D
34.70
167,400.00
G
38.25
D
34.70

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 9/8/2022 - 12/31/2022
LINCOLNTON, NC
LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID
MONTH/YEAR
September 2022
October 2022
November 2022
TOTAL
Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards
Report Date: 2/9/2023 4:07:22 PM
AMOUNT
UNIT
DRY TONS
UNIT
DRY METRIC TONS
465,000.00
G
106.26
D
96.38
99,200.00
G
15.06
D
13.66
248,000.00
G
37.64
D
34.14
812,200.00
G
158.96
D
144.18

SECTION 2

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PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Lincolnton
Lot Number:XA04056
Date Completed:01/20/2022
NIM�� Mr�
01/20/2022 10:22 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
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ANSI NdmlAccre00- Board
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A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: XA04056
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to low % solids the initial amount of sample of sample -001 was 3 times the standard procedure
amount. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
All samples analyzed with batch 28656 were analyzed using expired ascorbic acid reagent. This run was
a re -analysis of a previous run that was analyzed using a linear calibration range that was slightly greater
than 6 months old, per SOP criteria. The instrument was re -calibrated and the samples were re-
analyzed, using the new calibration, and similar results were obtained. Thus, re-ananlysis is not required
for samples that were within calibration range. All instrumentation check standards and method criteria
were met.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Synagro
Lot Number: XA04056
Sample Number Sample ID Matrix Date Sampled Date Received
001 Lincolnton Solid 01/04/20221000 01/04/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

Inorganic non-metals
Client:Synagro Laboratory ID:XA04056-001
Description: Lincolnton Matrix: Solid
Date Sampled:01/04/2022 1000 % Solids: 5.36 01/12/2022 0029
Date Received:01/04/2022
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date
Batch
1 350.1
(Ammonia - N ) 350.1
25
01/12/2022 2113 DAK
28095
1
(Nitrate - N ) 9056A
5
01/06/2022 0043 AAB
27594
1
(Nitrite - N ) 9056A
5
01/06/2022 0043 AAB
27595
2
(Phosphorus) 365.1
20
01/13/2022 1249 DMA
01/06/2022 1459
27588
1
(Soil pH meas) 9045D
1
01/11/2022 2036 NBW
28081
1 351.4
(TKN) 351.2
2
01/05/2022 1749 DMA
01/05/2022 1000
27443
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Ammonia - N (gas diffusion)
350.1
17000
470
240
mg/kg
1
Nitrate - N (soluble)
9056A
9.6 J
47
9.3
mg/kg
1
Nitrite - N (soluble)
9056A
32
19
9.3
mg/kg
1
Phosphorus
7723-14-0 365.1
14000
1900
370
mg/kg
2
Soil pH measured in water @
20 ° C
9045D
7.2
su
1
TKN
351.2
44000
1900
930
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 9

CVAA
Client:Synagro Laboratory ID:XA04056-001
Description: Lincolnton Matrix: Solid
Date Sampled:01/04/2022 1000 % Solids: 5.36 01/12/2022 0029
Date Received:01/04/2022
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7471B 7471B 1 01/10/2022 0741 JAB2 01/10/2022 0116 27833
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury
7439-97-6 7471B ND 1.4 0.34 mg/kg 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

ICP-AES
Client:Synagro Laboratory ID:XA04056-001
Description: Lincolnton Matrix: Solid
Date Sampled:01/04/2022 1000 % Solids: 5.36 01/12/2022 0029
Date Received:01/04/2022
Run Prep Method
1 3050B
Analytical Method Dilution Analysis Date Analyst
6010D 1 01/06/2022 1122 JMH
Prep Date Batch
01/06/2022 0311 27531
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Aluminum
7429-90-5
6010D
12000
120
45
mg/kg
1
Arsenic
7440-38-2
6010D
5.6
4.5
1.5
mg/kg
1
Cadmium
7440-43-9
6010D
0.45
J
1.5
0.38
mg/kg
1
Calcium
7440-70-2
6010D
7700
1500
190
mg/kg
1
Chromium
7440-47-3
6010D
85
3.0
0.76
mg/kg
1
Copper
7440-50-8
6010D
290
3.0
1.4
mg/kg
1
Iron
7439-89-6
6010D
11000
30
14
mg/kg
1
Lead
7439-92-1
6010D
11
3.0
1.4
mg/kg
1
Magnesium
7439-95-4
6010D
2800
1500
190
mg/kg
1
Manganese
7439-96-5
6010D
250
4.5
1.8
mg/kg
1
Molybdenum
7439-98-7
6010D
5.0
J
12
3.0
mg/kg
1
Nickel
7440-02-0
6010D
10
J
12
3.2
mg/kg
1
Potassium
7440-09-7
6010D
3700
1500
190
mg/kg
1
Selenium
7782-49-2
6010D
5.0
J
6.0
2.5
mg/kg
1
Sodium
7440-23-5
6010D
1000
J
1500
190
mg/kg
1
Zinc
7440-66-6
6010D
250
15
3.8
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 9

PACE ANALYTICAL SERVICES. LLC
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 9

PACE ANALYTICAL SERVICES, LLC
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J Yesl NO 14, ore all sarnptcs receiv��j tbo hoidin time or 4? hours_ whi tkwrs xsmes Erse
Yt ; + Tti4 15. 'CM any sau1PIQ oartral:iors Inis�rin exopss (circle rite] Samples Not lister! on CC]{ I
Dyts Qlyv' ONA 16_ n vo.a aad3t51{-175s�unpt w lntf?blcSpre lGs •pea sir,C' rer&tt°n ire r]'aroe crJ
it3 an, of the VOA vials?
F Yes Nu NA 17. 'cre all OROlrnetalslnutrimt sum pics received at ii pA of <??
Yes NO A M Wcm ati Cy aifi+.tcsam ies received Erta pld > 1'' ae¢] stittidesarap:eni r+ebtived at a III> 9?
Yes [I No E A 19. ere id] app=ieable lvF�f E K[�f nt elpi7nnol 5��.1! S.3 (� .Sn samP Ics free of
r�sid I ohtlal•:E_o7
UYet ❑Na DNS. 30_ � ere client n�a�tarks•riaeqursls{i_e4 i�ucstaddiluFions, hf5,'MSf} I}�Sp�n r�o-ns, etc.,_)
torre dvtmnscribec fr�rrn theCOC 1DWthe connmun[ siuWcntl'r T. Msi
Ye; +' Nn 2 l- as tte trata rlltbcr :irrcl ooi tJtc eunrlfirrer ]alrel? IFycs, tote �! —
5arrrplo preser vturn (Must b c m�lG#vd ii�r any s8lriPie-'3) iwca irrectly pr ed o- wi%Jiead�pa le. s
"ll:) ESA _ucrc received i110wu only 1xz;seirved nOrd u"er adjUSW aacrordingly
in sauiplu receiving with ' L of circle one: H2SO4, H LN03, K L Zr ao H ttsiltg slt g NA
firoe ufpre eEVa!oil PA If 3ni}rC Than one praqawtive is all Please nil in tho COMMis belffw,
'arr�pla(s) KA
T �wcre reooived W:1h buhhlra >6 mm in diamoter.
Sant plc (.s}MA
wx'CrC —received with TRC > 0.5 Ir.g+L (If # ] 9 is 110 1 and were
adjusl accordingly in saniple r1mciviJ19 with wkliwn 11103alfate (Na135 3) with Shealy JD; NA
fi(£ bUQWc labels applied by, t' I' irate= 1!4J24)4
Cornm:n[s;
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 9

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
2161-01-LIQ-NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED
LIQUID
Na mg/I = (Na mg/kg x % Solids) = 100 = (1000 x 5.3600) = 100 = 53.6
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (7700 x 5.3600) = 100 = 412.72
Mg mg/I = (mg mg/kg x % Solids) = 100 = (2800 x 5.3600) = 100 = 150.08
Na meq = Na mg/I = Molec.Wgt.Na = 53.6 = 23 = 2.33043
Ca meq = Ca mg/I = Molec.Wgt.Ca = 412.72 = 20 = 20.636
Mg meq = Mg mg/I = Molec.Wgt.Mg = 150.08 = 12 = 12.5067
Sample Date Report Range Ratio
1 /4/2022 1 /1 /2022 - 3/31 /2022 0.5725
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.33043 = SgrRoot[0.5(20.636+12.5067)] = 0.572477

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Lincolnton
Lot Number:XD07083
Date Completed:06/02/2022
NIM�� Mr�
06/03/2022 9:28 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 7

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: XD07083
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
The following samples were classified as a biosolid therefore they were weighed out at around 3.0 grams
to 4.0 grams to ensure proper digestion: -001. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
Due to multiple QC failures, sample -001 required additional runs. The best run has been reported.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 7

Client: Synagro Laboratory ID: XD07083-001
Description: Lincolnton Matrix: Solid
Date Sampled: 04/06/2022 1030 % Solids: 4.79 04/16/2022 1428
Date Received:04/07/2022
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 04/16/2022 1428 CVR
38384
1 350.1
(Ammonia - N ) 350.1
50 04/20/2022 1400 DRD
38502
3
(Nitrate - N ) 9056A
5 05/19/2022 2127 CAW
42428
3
(Nitrite - N ) 9056A
1 05/19/2022 1431 CAW
42431
1
(Phosphorus) 365.1
25 04/12/2022 1150 DMA
04/08/2022 1221
37480
2
(Soil pH meas) 9045D
1 04/21/2022 1438 NEW
39017
1 351.4
(TKN) 351.2
5 04/11/2022 1919 DMA
04/08/2022 1143
37479
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
4.79
%
1
Ammonia - N (gas diffusion)
350.1
11000
1000
540
mg/kg
1
Nitrate - N (soluble)
9056A
19 HJ
52
10
mg/kg
3
Nitrite - N (soluble)
9056A
100 H
4.2
2.1
mg/kg
3
Phosphorus
7723-14-0 365.1
16000
2600
520
mg/kg
1
Soil pH measured in water C)
25 ° C
9045D
7.1
su
2
TKN
351.2
57000
5200
2600
mg/kg
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 04/13/2022 0533 JAB2
04/13/2022 0232
37587
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7471 B
ND
1.6
0.40
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601 OD
1 04/13/2022 0144 KSH2
04/08/2022 1202 37530
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6010D
15000
120
46
mg/kg
1
Arsenic
7440-38-2 6010D
6.8
4.6
1.5
mg/kg
1
Cadmium
7440-43-9 6010D
0.58 J
1.5
0.38
mg/kg
1
Calcium
7440-70-2 6010D
11000
1500
190
mg/kg
1
Chromium
7440-47-3 6010D
110
3.0
0.76
mg/kg
1
Copper
7440-50-8 6010D
400
3.0
1.4
mg/kg
1
Iron
7439-89-6 6010D
15000
30
14
mg/kg
1
Lead
7439-92-1 6010D
17
3.0
1.4
mg/kg
1
Magnesium
7439-95-4 6010D
5100
1500
190
mg/kg
1
Manganese
7439-96-5 6010D
380
4.6
1.8
mg/kg
1
Molybdenum
7439-98-7 6010D
6.9 J
12
3.0
mg/kg
1
Nickel
7440-02-0 6010D
14
12
3.2
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 7

Client: Synagro Laboratory ID: XD07083-001
Description: Lincolnton Matrix: Solid
Date Sampled: 04/06/2022 1030 % Solids: 4.79 04/16/2022 1428
Date Received:04/07/2022
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
6010D 1 04/13/2022 0144 KSH2
04/08/2022 1202 37530
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Potassium
7440-09-7 6010D
5300
1500
190
mg/kg
1
Selenium
7782-49-2 6010D
4.0 J
6.1
2.5
mg/kg
1
Sodium
7440-23-5 6010D
1500
1500
190
mg/kg
1
Zinc
7440-66-6 6010D
320
15
3.8
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 7

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 7

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 7

PACE ANALYTICAL SERVICES, LLC
Samples FLecelpt Cheddist (SRC) (ME004C-lei ReVISed;9/29M20
d!�. AtlylifxLr ScaiingAuthoflity: Nac-2 ENV •WFOL Page 11y�1
Sample Receipt Checklist (} (:)
C',icnt: 5}r.3gn Cooler inspect�-dhy+idate� ,'L:c ; t4G7fM2 J-014; x.'nPOKl
f44eaiis ufrerr ipl: 01 face
Oient I I U?S I 1F&iEx Cklter-
Yw5 No
I 11. W'cm cumo ' seaf& pirtnent cm the cool er?
Yes Mn
I J NA 11 1f CarLnd %eals were present, were they irkLu 1. mad ur_brukurl?
F1 Strip ID- ailor=ne SlAp 1D NA Tesred by__
ll?rii n;ti .rempacnt5i Ire• uponr6mipt l Derived (Corfe,;Led) terc-IM rl utt: r.pon Tucmipt IN Solid Snap-C-up ID-oC
l
Mathod: ETnTLPL:MjUre ]31amk ❑fi Aaafria nales 1R CT1m ]D; SIII Gwi ComgC t]on Factor: 'c
Arlvthod of 000lzr_t; Net Ice ❑ Ice ftCki ❑ DU I rc 0 None
❑Yes
ONO
❑✓ NA
3, [f ternjerzture of any 0o-ole€ exm- eded 6.O°C, was Vrgject KmRgGr Notifii?d?
PM was N6af"jcd LTy- pbor c 1 ci ai I / f Lee-uo-fay (6rclr- quo).
YesI
Lj No
J : ]A
4. is the Dear mercia] caur=or's pack ing slip attached to this f6=9
,! Yes
I LJ NO
5- LVcre proper custody procedures; (r:elitkqui<hcAgT&aeived) followed?
J
Y vs
Lj Ti o
U Nol
6- Wtrc s xrnpie ID& listed an the COO
+
Yms
17. Werp 9= Pic, ID& 11=d on al &ample CDrLL1inCr5?
i [ZlYol
V1,
LJ No
No
_
S. Was co11ddion{f"&finc listed on Like COC? _.
19, Was c011ecd. lrl014 & LITOc h3l;don all Sam 1ffcontairkey¢?
Y*
No
1 10. Uid ali container IaWl in%nniatioa (ID, daw, liu,e) agron wiih Itre COC•?
i Yes
7 Ycs
N0
❑ N6
I I. M:rr- teLjti I Nk erfonned listex ol: the COOT
f 2. Did al ] ramp]es arrive in tlw proper corkaki wF❑r cac:h tcsf andkw in pod condition
funbrokcn, I:ds on, etc.)
Ycs
No
11 Wa.w adwylate Sample vo'urne: vailabW
J Yes
, NO
' -
14_ Worc 0f samples received wLfhj , I, the holding CTnc er. 48 ]fours, wMehever crm,a5 fir5V
'Yrs
+� N o
15. Woe anv sa,n les cc) tkaincrs missiugfex esR (circle one) zrlrp1m; Not listed on COCf?
❑ fob
[:]No
ZINA
1-6' i`ar VOA and R41C- 175 sample-R, wend M,bbler� present °pea -Sipe" (W w 6nwrk in diamctcr)
n1 Lu y of she VOA vials?
Yes
No
+� NA
1-7. Were all DRC WmotadSrnutrient samples received at a H ck` < 27
Y os
No
N'�
1.0. Were al' CS anidM 5amplos rcoci wcd at a I I > 12 aryl mi Ifi de mm les received Al a pl-1 > 9?
Ycs
El
2NA
:9, emal; .appTicableNH�i'Kt+icyanidLVphenoli625,1r608,5(= ,5rngL samplesflue: of y
ayes id ua, ChIckrine4
❑ YeSI
OItio
d A
20, Wrrw elic-it remarkslrequWs (i.e. requested dilutions, MS,' ED do rigrkati , cap,,,)
conrcctly transcribed ftm the COC into the cmume]tt section in ].JfvW,
LJ Yrs
No
21. Was dse quote recrrei»-li:Lvd un the kontainer label? Ify", Quotc :qI-S-
ample Presocrv?Woii OAust be completed f[rr any Sawple(s) incotractly pmsa-%red or %ViLh I1ead9PM=. j
5aniple(s) `A _ WCM. roreived incomwty hrenruc-d and were adiustedaccowdikrgl,
In sample rmCC[vittg with mI, iofOrde unv; H2SO4, HNW, .110, NaCk] I iisin SR �2 KA
Time ofprewintkis h'A V mitre (ban ono prc9cry d67 13 needed, fleaw ntltc in the cnmmmr below.
Sa_mple(s) r:n wcrnrecui%pcdwith bubbler >6rnm in diameter,
SaLtLpl s} N.4 — -were received with TKC > 0.5 rngiL (If #19 is nip) and wore
adjusnedaecordit'lGly in sar_t�Ic receiving •ids sodium t}'kit7�ttltiakr: (�a�5�0a}•�iih Shc�ly 113�a.
5R L•,arcode I;3be]S aplied by; KDRW - Date- carn7.12027.
C131111nellt;_
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 7

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
2161-01-LIQ-NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED
LIQUID
Na mg/I = (Na mg/kg x % Solids) = 100 = (1500 x 4.7900) = 100 = 71.85
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (11000 x 4.7900) = 100 = 526.9
Mg mg/I = (mg mg/kg x % Solids) = 100 = (5100 x 4.7900) = 100 = 244.29
Na meq = Na mg/I = Molec.Wgt.Na = 71.85 = 23 = 3.12391
Ca meq = Ca mg/I = Molec.Wgt.Ca = 526.9 = 20 = 26.345
Mg meq = Mg mg/I = Molec.Wgt.Mg = 244.29 = 12 = 20.3575
Sample Date Report Range Ratio
4/6/2022 4/1 /2022 - 6/30/2022 0.6465
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 3.12391 = SgrRoot[0.5(26.345+20.3575)] = 0.646463

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Lincolnton
Lot Number:XG07083
Date Completed:07/22/2022
NIM�� Mr�
07/22/2022 3:38 PM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 7

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: XG07083
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
Due to low percent solids, sample -001 has been prepped at approximately three times the standard
procedure. The LOQs have been adjusted to accomodate the additional mass.
Inorganic Non -Metals
The method blank for prep batch 47664 contained the analyte total phosphate greater than the method
acceptance criteria. The associated samples contained detections for this analyte at concentrations
greater than 1 OX the value found in the method blank; therefore sample results are not impacted. The
data has been reported.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 7

Client: Synagro Laboratory ID: XG07083-001
Description: Lincolnton Matrix: Solid
Date Sampled: 07/06/2022 1100 % Solids: 5.48 07/10/2022 1650
Date Received:07/07/2022
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 07/10/2022 1650 TAD
47512
1 350.1
(Ammonia - N ) 350.1
50 07/19/2022 1154 CMM
47976
1
(Nitrate - N ) 353.2
1 07/20/2022 1252 KKP
47766
1
(Nitrite - N ) 353.2
1 07/20/2022 1252 KKP
47768
1
(Phosphorus) 365.1
25 07/18/2022 1558 DMA
07/12/2022 1324
47664
1
(Soil pH meas) 9045D
1 07/11/2022 1342 KKP
47566
1 351.4
(TKN) 351.2
5 07/19/2022 2048 DMA
07/16/2022 1320
48198
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
5.48
%
1
Ammonia - N (gas diffusion)
350.1
23000
910
470
mg/kg
1
Nitrate - N (soluble)
353.2
82
3.6
0.49
mg/kg
1
Nitrite - N (soluble)
353.2
9.7
3.6
0.48
mg/kg
1
Phosphorus
7723-14-0 365.1
17000
2300
460
mg/kg
1
Soil pH measured in water C)
15.8 ° C
9045D
7.2
su
1
TKN
351.2
63000
4600
2300
mg/kg
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 07/10/2022 1040 MRW2
07/10/2022 0654
47419
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7471 B
ND
1.4
0.34
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 07/13/2022 0742 JMH
07/11/2022 1541
47423
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6010D
13000
110
41
mg/kg
1
Arsenic
7440-38-2 6010D
6.3
4.1
1.4
mg/kg
1
Cadmium
7440-43-9 6010D
0.66 J
1.4
0.35
mg/kg
1
Calcium
7440-70-2 6010D
11000
1400
170
mg/kg
1
Chromium
7440-47-3 6010D
100
2.8
0.69
mg/kg
1
Copper
7440-50-8 6010D
380
2.8
1.2
mg/kg
1
Iron
7439-89-6 6010D
13000
28
13
mg/kg
1
Lead
7439-92-1 6010D
11
2.8
1.2
mg/kg
1
Magnesium
7439-95-4 6010D
4500
1400
170
mg/kg
1
Manganese
7439-96-5 6010D
310
4.1
1.6
mg/kg
1
Molybdenum
7439-98-7 6010D
6.8 J
11
2.8
mg/kg
1
Nickel
7440-02-0 6010D
12
11
2.9
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 7

Client: Synagro Laboratory ID: XG07083-001
Description: Lincolnton Matrix: Solid
Date Sampled: 07/06/2022 1100 % Solids: 5.48 07/10/2022 1650
Date Received:07/07/2022
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
6010D 1 07/13/2022 0742 JMH
07/11/2022 1541
47423
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Potassium
7440-09-7 6010D
5300
1400
170
mg/kg
1
Selenium
7782-49-2 6010D
4.2 J
5.5
2.2
mg/kg
1
Sodium
7440-23-5 6010D
1300 J
1400
170
mg/kg
1
Zinc
7440-66-6 6010D
310
14
3.4
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 7

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 7

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 7

PACE ANALYTICAL SERVICES, LLC
samples Iteceipt ChLcldist (SRC) IMCOO 1,8r,35j HcN isod:9/291202D
f� .#� IybCaJ Issuing AvLhorlty,' Pare ENV - WCOL page 1 of 1
Sample Receipt Checklist (SRC)
Ciit5nt: Ya"gf° Caal,-r Inspected by+date; KDRW I o7ra7raoax Lot A X{301153
Fuieansul'rc v4PL_ - P-�Ce
C,-, lt1'S LJ FcdE 0JW1-LJ -
Yur.1
Ld 7wla L- Were oistody seais present or Lhr-, cooler?
Lyesl
LJNDINA 2, if qus�Ldy seals wpm resent, wcirC klwy iui.4u, and u,lbrokgm?
PH stp p fill; NA _. CbIr rinc SLr3l ID- NA TebLrd by_
ri&pI t-j!mperfture upon receipt f tw:vc�l (C(irrected) ❑emperature upo-n rc44ipL VSolid Snap -Cup ID= 22-19.53
3-4 }3_4 ae NA fMA oC NA INA eC N-A /NA oC
ethod: �Tcrtiprrmura Blank Lrst 13otdks I Gur. I1D; 6 )R C tan C;amcotian wortor_ o aD
Method ofcooju,iL. ❑, Wet Ice 0 toe PackE Q Dry lee Koiie
Ycs
El No
Y�ln
OI A
3. If temperaturo of P-ty weler exceeded 6.011C, wa: "out Mwi agar Notified?
PM was Not-fied by. ph -me f email r' face -to -;ace (circle one). �
Yee
NA
4. is the own,nerciei eouricr s netting s=ip altarhed m this fmm
Yes
No
5. Wan proper cuau_kly pnr Lrdu, s (relinquislieofremiiwd) fallnw A9.
Ycs
LIN4i
6. %%rare samplo CDs lisivl on the CDC?
,r yes
Q Na
7, Were s9ml,lc ID,; Iistad LNi all sample cantainera?
} cSLj3ve
8. W., oollcc[ion date & lithe listed an the { OC7
Waa collection date & time listed an all sarnpk -uunlainets?
I,,' Yee
C No
10- Did all etditainer label infarmatiaL (Ii_}, datr, tirrr] agree wi 1 th-aCOC I
11. Were tests to be erfbtroe listed on the i;i)O
12. Did 611 samples arrivo it tlyc� proper cnmtainers to_ each test andfar in good oo-nditiun
(tmbrnken, NIS an, etc.)?
13. Was adequate samp levWuNme av;,if;1bla? _
Ycs
No
d Yes
❑ No
:U Yes
LJ No
Yes
No
14. 11kere al samples mccivcd within rr, the holding tirr.0 yr 48 I�ou~s, u11Aevei ooanes first?
yCS
J w
15. Werc arty sampim containers nrissin excesq (circle are) sam Jcs NO; ligncd nn COO?
Yes
ldu
❑ 1A
16- For VQA aiid RSK-175 samPkE, were bubbles pret sent>;'Pr-size" (!,"iw Gram in diainew)
in any of the Yc7A vials?
ycc!
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17. Wen all 13ROlmOal6tintriemt satn les racei ved at a p1 I of < 72
ycs
Alo
-lA
18. %Veoe all cyanide satnpics rcceivcd at a pH � I? and sulride sam icR received at a 1 I> 97
Ycs
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[711
19.%Veneall applicableNH,1'rKN1ayer.ide;phennlrfi25.ii6N._t (<0-5n�WL)sar-tpes freeot
residualchlurine?
Vca
❑ Nv
❑ lA
20. Were C1Len*. temar�rs, -Nue� (i-e. requested dilutions, M�'NISD dc3'g"atioris, utc...)
onu-rectiy trFInSC: iovd freest too COC into tl1Y comrr,errt -.�acdnn in L.IMS'?
Yr'
INN
2'-, Was the ua.e nurn ~u listed on the container ]abYl? If Yes, Quore
Samply Prusrrvatioi, (MList be cam pleted for any tamp le(s) ifteo GGtly presar td of wish head€'pace-)
�tmftlG(t) t'h were :waived iiiearrcctly preserved and wrzo Adjusted accordingly
in sample receiving with Nrr mL of circle one. 8ZS04, HF Off, HC], NaOR lasing SR 4 114A
Time of prac,ervarir%n + I more dlau ❑nc preservative is neaded, please note in th4 ccxomsnls aciow,
amplr(s) NA _-_-- wm romi-nd With ou"le. >> inn in diameter-
amples(s) Na — — - _ wzro rcacivcd with 'I KC �, 0-5 mg/h (ff;ll n is rru) nrd were
jusredaecordingty iusaraplereceiving with 5odium1hi95uJfatc (Na�S20;) wAb Shealy lu; t:A
R baixode labels applied by, KDRW Dote; 07 ml.
Ccunlrents=
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 7

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
2161-01-LIQ-NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED
LIQUID
Na mg/I = (Na mg/kg x % Solids) = 100 = (1300 x 5.4800) = 100 = 71.24
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (11000 x 5.4800) = 100 = 602.8
Mg mg/I = (mg mg/kg x % Solids) = 100 = (4500 x 5.4800) = 100 = 246.6
Na meq = Na mg/I = Molec.Wgt.Na = 71.24 = 23 = 3.09739
Ca meq = Ca mg/I = Molec.Wgt.Ca = 602.8 = 20 = 30.14
Mg meq = Mg mg/I = Molec.Wgt.Mg = 246.6 = 12 = 20.55
Sample Date Report Range Ratio
7/6/2022 7/1 /2022 - 9/30/2022 0.6152
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 3.09739 = SgrRoot[0.5(30.14+20.55)] = 0.615248

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Lincolnton
Lot Number:XJ04091
Date Completed:10/26/2022
NIM�� Mr�
10/27/2022 11:17 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
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ANSI NdmlAccre00- Board
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Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 7

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: XJ04091
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to the matrix and low percent solid, sample -001 has an initial weight that is 3x greater than standard
procedure. The LOQ has been adjusted accordingly.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 7

Client: Synagro Laboratory ID: XJ04091-001
Description: Lincolnton Matrix: Solid
Date Sampled:10/04/2022 1000 % Solids: 3.64 10/11/2022 2200
Date Received:10/04/2022
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 10/11/2022 2200 MJS2
56709
1 350.1
(Ammonia - N ) 350.1
50 10/19/2022 1658 CMM
57366
1
(Nitrate - N ) 353.2
1 10/19/2022 1524 KKP
57569
1
(Nitrite - N ) 353.2
1 10/19/2022 1524 KKP
57570
1
(Phosphorus) 365.1
25 10/08/2022 1523 DMA
10/07/2022 1400 56358
1
(Soil pH meas) 9045D
1 10/12/2022 1521 KKP
56841
1 351.4
(TKN) 351.2
5 10/07/2022 1808 DMA
10/06/2022 1447
56231
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 2540G
3.64
%
1
Ammonia - N (gas diffusion)
350.1
37000
1400
710
mg/kg
1
Nitrate - N (soluble)
353.2
190
5.5
0.74
mg/kg
1
Nitrite - N (soluble)
353.2
12
5.5
0.72
mg/kg
1
Phosphorus
7723-14-0 365.1
24000
3400
690
mg/kg
1
Soil pH measured in water C)
21.3 ° C
9045D
7.4
su
1
TKN
351.2
90000 S
6900
3400
mg/kg
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 10/07/2022 1524 MRW2
10/07/2022 1138
55609
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7471B
ND
2.1
0.50
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601 OD
1 10/18/2022 0116 JMH
10/07/2022 0714
56157
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 601OD
9300
170
64
mg/kg
1
Arsenic
7440-38-2 601OD
8.8
6.4
2.1
mg/kg
1
Cadmium
7440-43-9 601OD
0.81 J
2.1
0.54
mg/kg
1
Calcium
7440-70-2 601OD
11000
2100
270
mg/kg
1
Chromium
7440-47-3 601OD
120
4.2
1.1
mg/kg
1
Copper
7440-50-8 601OD
310
4.2
1.9
mg/kg
1
Iron
7439-89-6 601OD
14000
42
19
mg/kg
1
Lead
7439-92-1 601OD
12
4.2
1.9
mg/kg
1
Magnesium
7439-95-4 601OD
4800
2100
270
mg/kg
1
Manganese
7439-96-5 6010D
220
6.4
2.5
mg/kg
1
Molybdenum
7439-98-7 6010D
9.2 J
17
4.2
mg/kg
1
Nickel
7440-02-0 6010D
16 J
17
4.5
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 7

Client: Synagro Laboratory ID: XJ04091-001
Description: Lincolnton Matrix: Solid
Date Sampled:10/04/2022 1000 % Solids: 3.64 10/11/2022 2200
Date Received:10/04/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 10/18/2022 0116 JMH 10/07/2022 0714 56157
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Potassium
7440-09-7
Selenium
7782-49-2
Sodium
7440-23-5
Zinc
7440-66-6
601OD
7300
2100
270
mg/kg 1
601OD
3.9 J
8.5
3.5
mg/kg 1
601OD
1800 J
2100
270
mg/kg 1
601OD
360
21
5.3
mg/kg 1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 7

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 7

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 7

PACE ANALYTICAL SERVICES, LLC
LIC.4 ItIQ= ENV-FKM-VVC3!_-OM6 v02_Samp)es Receipt Cfieddist (31
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Sample Receipt Checklist (SRQ
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Oii2ln d teluPeril lire uP,gl receipt.' Derives[ (Cmiiccoedl icnlpcl ait]ic upon retieipr °,GiSafid Sl1a1l�C qk ]I?. 22-1$8s
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yes
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Yes
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9_ Were Celts to be P erEATUCd lulled on Zbe COI
WIVics
Q No
10. iW aU sm"Pies mrzi%r. iu rite paper tout[d[iers for each tort arldlcti in good 05ndi[iiaax
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Page 7 of 7

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
2161-01-LIQ-NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED
LIQUID
Na mg/I = (Na mg/kg x % Solids) = 100 = (1800 x 3.6400) = 100 = 65.52
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (11000 x 3.6400) = 100 = 400.4
Mg mg/I = (mg mg/kg x % Solids) = 100 = (4800 x 3.6400) = 100 = 174.72
Na meq = Na mg/I = Molec.Wgt.Na = 65.52 = 23 = 2.8487
Ca meq = Ca mg/I = Molec.Wgt.Ca = 400.4 = 20 = 20.02
Mg meq = Mg mg/I = Molec.Wgt.Mg = 174.72 = 12 = 14.56
Sample Date Report Range Ratio
10/4/2022 10/1 /2022 - 0.6851
12/31 /2022
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.8487 = SgrRoot[0.5(20.02+14.56)] = 0.685091

SECTION 3

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SECTION 4

SUMM111
ENVIRONMENTAL TECHN❑LOMZ3. INC
Arraly0ca1 Laboralorfas
January 14, 2022
Alex Fox
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL:
FAX:
RE: Lincolnton
Dear Alex Fox:
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
Order No.: 22010195
Summit Environmental Technologies, Inc. received 1 sample(s) on 1/5/2022 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas
E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada OH009232020-1, New
Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma
2019-155, Oregon OH2O0001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah OH009232020-12,
Virginia VELAP 10381, West Virginia 9957C
Page 1 of 35

MM' Y Summit Environmental Technologies, Inc. Case Narrative
SU3310 Win St.
ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 22010195
Arralyi9cal Laboralorlas TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com Date: 1/14/2022
CLIENT: Synagro
Project: Lincolnton
WorkOrder Narrative:
22010195: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Sequence Sample Notes:
22010195-OOIA MTL-TCLP-7(6010D): LCS-54221 exhibits high recovery for Silver. Sample is ND
for this analyte.
Analytical Sequence QC Notes:
LCS-54221 Mtl-TCLP-7(6010): LCS-54221 exhibits high recovery for Silver. Associated samples are
ND for this analyte.
LCS-54264 TCLP-SVOC-CPEST(8081B): P: RPD between confirmation column is greater than 40%.
Original
Page 2 of 35

MM' Summit Environmental Technologies, In Qualifiers and Acronyms
SU3310 Win S
EkiwllOMM@NTALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 22010195
Arraly0cal Laboralorlas TEL: [phone] FAX.- (330) 253-44E
Wehsite: httn:11www.settek.co Date: 1/14/2022
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
in Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25% difference.
C The result has been confirmed by GC/MS.
X The result was not confirmed when GUMS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low (-) or high (+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low (-) or high (+).
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low (-) or high (+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low (-) or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected
RL
Reporting Limit
QC
Quality Control
MDL
Method Detection Limit
MB
Method Blank
LOD
Level of Detection
LCS
Laboratory Control Sample
LOQ
Level of Quantitation
LCSD
Laboratory Control Sample Duplicate
PQL
Practical Quantitation Limit
QCS
Quality Control Sample
CRQL
Contract Required Quantitation Limit
DUP
Duplicate
PL
Permit Limit
MS
Matrix Spike
RegLvl
Regulatory Limit
MSD
Matrix Spike Duplicate
MCL
Maximum Contamination Limit
RPD
Relative Percent Different
MinCL
Minimum Compound Limit
ICV
Initial Calibration Verification
RA
Reanalysis
ICB
Initial Calibration Blank
RE
Reextraction
CCV
Continuing Calibration Verification
TIC
Tentatively Identified Compound
CCB
Continuing Calibration Blank
RT
Retention Time
PLC
Reporting Limit Check
CF
Calibration Factor
DF
Dilution Factor
RF
Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 35

�� 1 � Summit Environmental Technologies, Inc.
SU3310 Win St.
ENVIROMMEWAL YECHNO ijULES. JNG, Cuyahoga Falls, Ohio 44223
Analytical Laboralorlas TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
CLIENT: Synagro
Project: Lincolnton
Lab SamplelD Client Sample ID
22010195-001 Lincolnton
Tag No Date Collected
1/4/2022 10:00:00 AM
Workorder
Sample Summary
WO#: 22010195
14 Jan-22
Date Received Matrix
1/5/2022 12:50:00 PM Sludge
Page 4 of 35

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SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223
Arralyt9cal Laboralorfas TEL: [phone] FAX. [phone]
Website: http://�i,-"-m,.settek.coin
Analytical Report
(base report)
WO#: 22010195
Date Reported: 1/14/2022
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/4/2022 10:00:00 AM
Lab ID: 22010195-OOIA
Project: Lincolnton
Client Sample ID Lincolnton
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury
ND 0.00200 mg/L
SW7470A SW7470A Analyst: KLC
1 1/7/2022 5:27:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW6010
SW301OA Analyst: MSK
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As)
ND
0.500
mg/L
1
1/10/2022 11:50:00 AM
TCLP Barium(Ba)
ND
5.00
mg/L
1
1/10/2022 11:50:00 AM
TCLP Cadmium(Cd)
ND
0.100
mg/L
1
1/10/2022 11:50:00 AM
TCLP Chromium(Cr)
ND
0.200
mg/L
1
1/10/2022 11:50:00 AM
TCLP Lead(Pb)
ND
0.500
mg/L
1
1/10/2022 11:50:00 AM
TCLP Selenium(Se)
ND
0.0500
mg/L
1
1/10/2022 11:50:00 AM
TCLP Silver(Ag)
ND
0.500
QL+ mg/L
1
1/10/2022 11:50:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8270
SW351OC Analyst: SFG
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene
ND
0.200
mg/L
2
1/10/2022 7:57:00 PM
2,4,5-Trichlorophenol
ND
0.500
mg/L
2
1/10/2022 7:57:00 PM
2,4,6-Trichlorophenol
ND
0.500
mg/L
2
1/10/2022 7:57:00 PM
2,4-Dinitrotoluene
ND
0.100
mg/L
2
1/10/2022 7:57:00 PM
Cresols, Total
ND
10.0
mg/L
2
1/10/2022 7:57:00 PM
Hexachloro-1,3-butadiene
ND
0.0400
mg/L
2
1/10/2022 7:57:00 PM
Hexachlorobenzene
ND
0.100
mg/L
2
1/10/2022 7:57:00 PM
Hexachloroethane
ND
0.200
mg/L
2
1/10/2022 7:57:00 PM
Nitrobenzene
ND
0.200
mg/L
2
1/10/2022 7:57:00 PM
Pentachlorophenol
ND
0.500
mg/L
2
1/10/2022 7:57:00 PM
Pyridine
ND
0.500
mg/L
2
1/10/2022 7:57:00 PM
Surr: 2-Fluorophenol
62.4
10 - 157
%Rec
2
1/10/2022 7:57:00 PM
Surr: Phenol-d6
66.1
10 - 169
%Rec
2
1/10/2022 7:57:00 PM
Surr: Nitrobenzene-d5
69.3
32.1 - 130
%Rec
2
1/10/2022 7:57:00 PM
Surr: 2,4,6-Tribromophenol
92.3
45.4 - 166
%Rec
2
1/10/2022 7:57:00 PM
Surr: 2-Fluorobiphenyl
65.6
35.7 - 130
%Rec
2
1/10/2022 7:57:00 PM
Surr: p-Terphenyl-dl4
ill
70 - 145
%Rec
2
1/10/2022 7:57:00 PM
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H Holding times for preparation or
analysis exceeded
M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified
compounds
ND Not Detected
OG1
P Second column confirmation exceeds
PL Permit Limit
Original
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 6 of 35

SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223
Arrafyt9caf Laboralorfas TEL: [phone] FAX. [phone]
Website: http://�i,-"-m,.settek.coin
Analytical Report
(base report)
WO#: 22010195
Date Reported: 1/14/2022
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/4/2022 10:00:00 AM
Lab ID: 22010195-OOIA
Project: Lincolnton
Client Sample ID Lincolnton
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP PESTICIDES ANALYSIS (SW1311/8081)
Chlordane, total
ND
Toxaphene
ND
Endrin
ND
gamma-BHC
ND
Heptachlor
ND
Heptachlor epoxide
ND
Methoxychlor
ND
Surr: TCMX
40.8
Surr: DCB
79.7
TCLP HERBICIDES BY EPA 8321B
2,4-D ND
2,4,5-TP ND
Surr: 2,4-Dichlorophenylacetic aci 99.0
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene
ND
1,2-Dichloroethane
ND
MEK
ND
Benzene
ND
Carbon tetrachloride
ND
Chlorobenzene
ND
Chloroform
ND
Tetrachloroethene
ND
Trichloroethene
ND
Vinyl chloride
ND
Surr: 4-Bromofluorobenzene
97.9
Surr: Di brom ofl uorom ethane
98.3
Surr: Toluene-d8
102
SW8081 SW351OC Analyst: CSS
0.0250
mg/L
10
1/13/2022 1:42:00 AM
0.0500
mg/L
10
1/13/2022 1:42:00 AM
0.00500
mg/L
10
1/13/2022 1:42:00 AM
0.00500
mg/L
10
1/13/2022 1:42:00 AM
0.00500
mg/L
10
1/13/2022 1:42:00 AM
0.00500
mg/L
10
1/13/2022 1:42:00 AM
0.00500
mg/L
10
1/13/2022 1:42:00 AM
10 - 119
%Rec
10
1/13/2022 1:42:00 AM
10 - 119
%Rec
10
1/13/2022 1:42:00 AM
S W 8321
Analyst: RIS
0.500
mg/L
50
1/12/2022 3:51:00 AM
0.500
mg/L
50
1/12/2022 3:51:00 AM
70 - 130
%Rec
50
1/12/2022 3:51:00 AM
SW8260
SW1311M Analyst: NAW
0.250
mg/L
50
1/7/2022 6:26:00 PM
0.250
mg/L
50
1/7/2022 6:26:00 PM
5.00
mg/L
50
1/7/2022 6:26:00 PM
0.250
mg/L
50
1/7/2022 6:26:00 PM
0.250
mg/L
50
1/7/2022 6:26:00 PM
2.50
mg/L
50
1/7/2022 6:26:00 PM
0.250
mg/L
50
1/7/2022 6:26:00 PM
0.250
mg/L
50
1/7/2022 6:26:00 PM
0.250
mg/L
50
1/7/2022 6:26:00 PM
0.100
mg/L
50
1/7/2022 6:26:00 PM
70 - 130
%Rec
50
1/7/2022 6:26:00 PM
70 - 130
%Rec
50
1/7/2022 6:26:00 PM
70 - 130
%Rec
50
1/7/2022 6:26:00 PM
Qualifiers: B
Analyte detected in the associated Method Blank
H
Holding times for preparation or analysis exceeded
MC
Value is below Minimum Compound Limit.
ND
Not Detected
P
Second column confirmation exceeds
R
RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
OG 1
PL Permit Limit Original
RL Reporting Detection Limit
Page 7 of 35

MMIT
Summit Environmental Technologies, Inc. Analytical Report
SU3310 Win St.
ENVIRONMENTAL TECHNOLOGIE-3, IRC Cuyahoga Falls, Ohio 44223 (base report)
Arralyt9cal Laboralorfas TEL: [phone] FAX.- [phone] WO#: 22010195
Website: http://www.settek.com Date Reported: 1/14/2022
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/4/2022 10:00:00 AM
Lab ID: 22010195-OOIA
Project: Lincolnton
Client Sample ID Lincolnton
Analyses Result
RL Qual Units
DF
Date Analyzed
RCI
SW9014
Analyst: MS
REACTIVE CYANIDE (9014/7.3.3.2)-SOLID
Cyanide, Reactive ND
0.481 mg/Kg
1
1/10/2022 11:41:00 AM
IGNITABILITY OF SOLIDS (SW-846: 1030)
SW1030
Analyst: ALT
Ignitability nonflammable
mm/sec
1
1/7/2022 2:56:08 PM
RCI
SW9045D
Analyst: ALT
PH (SW9045D)
pH 7.1
s.u.@20.00
1
1/7/20224:13:17 PM
RCI
SW9034
Analyst: MS
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive 30.0
25.0 mg/Kg
1
1/10/2022 11:41:00 AM
Qualifiers: B
Analyte detected in the associated Method Blank
H
Holding times for preparation or analysis exceeded
MC
Value is below Minimum Compound Limit.
ND
Not Detected
P
Second column confirmation exceeds
R
RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
OG 1
PL Permit Limit Original
RL Reporting Detection Limit
Page 8 of 35

Summit Environmental Technologies, Inc.
Accreditation
Program
SUMMIEF
fr3310 Win St.
Analv n tes Report
ENwIROMMEWALYECHNOL.OG{r,S,INC
Cuyahoga Falls, Ohio44223
J
Y
Arraly0cal Laboralorlas
TEL: [phone] FAX.- [phone]
WO#:
22010195
Wehsite: http://www.settek.com
14 Jan-22
Client: Synagro
State: NW
Project: Lincolnton
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
22010195-OOIA Sludge
Ignitability of Solids (SW-846: 1030)
Ignitability
A
Sludge
pH (SW9045D)
Hydrogen Ion (pH)
A
Sludge
Reactive Cyanide (9014/7.3.3.2)-Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/7.3.4.2
Sulfide, Reactive
U
Sludge
TCLP Herbicides by EPA 8321B
2,4,5-TP
A
Sludge
TCLP Herbicides by EPA 8321B
2,4-D
A
Sludge
TCLP Mercury Analysis (SW1311/7470)
Mercury
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Barium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Cadmium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Chromium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Lead
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Endrin
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
gamma-BHC
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Methoxychlor
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Toxaphene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
1,4-Dichlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,5-Trichlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,6-Trichlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4-Dinitrotoluene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Cresols, Total
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachlorobutadiene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachloroethane
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Nitrobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Pentachlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Pyridine
A
Original #1
Page 9 of 35

Summit Environmental Technologies, Inc.
Accreditation
Program
SUMMIEF
fr3310 Win St.
Analv n tes Report
ENVIROMMEWAL YECHHOL.OG{r,S,
INC Cuyahoga Falls, Ohio 44223
J
Y
Arraly0cal Laboralorlas
TEL: [phone] FAX.- [phone]
WO#:
22010195
Wehsite: http://www.settek.com
14 Jan-22
Client: Synagro
State: NW
Project: Lincolnton
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
22010195-OOIA Sludge
TCLP Volatiles Analysis
1, 1 -Dichloroethene
A
Sludge
TCLP Volatiles Analysis
1,2-Dichloroethane
A
Sludge
TCLP Volatiles Analysis
2-Butanone
A
Sludge
TCLP Volatiles Analysis
Benzene
A
Sludge
TCLP Volatiles Analysis
Carbon tetrachloride
A
Sludge
TCLP Volatiles Analysis
Chlorobenzene
A
Sludge
TCLP Volatiles Analysis
Chloroform
A
Sludge
TCLP Volatiles Analysis
Tetrachloroethene
A
Sludge
TCLP Volatiles Analysis
Trichloroethene
A
Sludge
TCLP Volatiles Analysis
Vinyl chloride
A
Original #1
Page 10 of 35

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Page 33 of 35

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMENTAL TECHNOLOQH�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List
Arrafocaf Laboralorias TEL: [phone] FAX.- [phone]
Website: http://`h,,",m,.settek.coin
Client Name: SYN-NC-27028 Work Order Number: 22010195 RcptNo: 1
Logged by: 1/5/2022 12:50:00 PM
Completed By: Christina N. Jager 1/6/2022 1:43:13 PMdrx
Reviewed By: Jennifer Woolf 1/6/2022 2:48:09 PM
Chain of Custody
1. Is Chain of Custody complete? Yes ❑ No ❑d Not Present ❑
2. How was the sample delivered? FedEx
Lop In
3. Coolers are present? Yes ❑d No ❑ NA ❑
4. Shipping container/cooler in good condition?
Yes
d❑
No
❑
Custody seals intact on shipping container/cooler?
Yes
❑
No
❑
Not Present V
No. Seal Date:
Signed By:
5. Was an attempt made to cool the samples?
Yes
❑d
No
❑
NA ❑
6. Were all samples received at a temperature of >0° C to 6.0°C
Yes
❑d
No
❑
NA ❑
7. Sample(s) in proper container(s)?
Yes
❑d
No
❑
8. Sufficient sample volume for indicated test(s)?
Yes
❑d
No
❑
9. Are samples (except VOA and ONG) properly preserved?
Yes
❑d
No
❑
10. Was preservative added to bottles?
Yes
❑
No
❑d
NA ❑
11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm?
Yes
❑
No
❑ No VOA Vials ❑�
12. Were any sample containers received broken?
Yes
❑
No
❑d
13. Does paperwork match bottle labels?
Yes
No
❑
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody?
Yes
❑d
No
❑
15. Is it clear what analyses were requested?
Yes
❑d
No
❑
16. Were all holding times able to be met?
Yes
No
❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17. Was client notified of all discrepancies with this order?
Yes
❑
No
❑ NA V
Person Notified: Date:
By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
18. Additional remarks:
1/4/22 per email
Received by Tegan Richards
sample date on coc 1/4/21
Page 34 of 35

summly Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHHQL4Ga1�23.INC Cuyahoga Falls, Ohio44223
�trrafyt�caf iaboralorJas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
Client Name: SYN-NC-27028
Cooler Information
Work Order Number: 22010195
Sample Log -In Check List
Cooler No
Temp °C
Condition
I Seal Intact
Seal No
Seal Date
Signed By
1
14.0
Goodl
Not Present
RcptNo: 1
Page 35 of 35

SECTION 5

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
FacilityName: City of Lincolnton WWTP WQ Permit Number: WQ 0002712
WWTP Name: Lincolnton WWTP NPDES Number: NC 0025496
Monitoring Period: From 01/01/22 To 03/31/2022
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) -Please indicate level achieved and alternative performed:
Class A:
Alt. I/A (time/temp) Alt. 2B (Alk Treatment) Alt. 31C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion
Anaerobic Digestion
If *., .4--fi— n—f .r.. A frl... A — Cl­ 11141 th.. r"u..wCr.a ­;r..r rlot9•
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dences
Analysis
Fecal
2x10 to the 6'
MPN
MPN/g
Coliform
power per gram
of total solids
2 t 3
249
459
CF1F/g
0
Quarterly
Grab
9222D
CFU
SM
1000 MPN per gram of
rv1PN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate optionlalternative performed:
0 tion/Alt. 1
Option/Alt.2
Option/Alt.3 Option/Alt.4
(VS reduction) X
(40-day bench)
(30-day bench) (Spec. 02 uptake)
Option/Alt. 5
Option/Alt. 6
Option/Alt. 7 Option/Alt. 8
(14-Day Aerobic)
(Alk Stabilization)
(Drying — Stable) (Drying — Unstable)
Option/Alt, 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32115A NCAC 02T.1106 and the vector attraction
X reduction requirement to 40 CFR 503.33115A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the ppathogen requirements in 40 CFR 503,32/15A NCAC 02T.1106 and the vector attraction
reduction requirement m 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
been met. I am aware that there are significant penalties for false certification including fine and imprisonment."
Ritchie Haynes City Manager
Prep me Witle (type or print)
a a-a3
Signature ofPreparer* U Date
Land Applier Name and Title (if applicable) (type or print)
Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1 t02 (26)

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
r
Page 1
Contact: Alex Fox Report Date: 1/18/2022
Client: Synagro
284 Boger Road Project: Lincolnton
Mocksville, NC 27028 Date Sample Rcvd: 1/4/2022
Meritech Work Order # 01042275 Sample: L1-71 Grab 1/4/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 4.05 % 1/5/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <224 col/g dry wt 1/4/22 224 cal/g dry wt SM 9222D
Meritech Work Order #
01042275 Sample: L1-7 2 Grab
1/4/22
Parameters
Results
Analysis Date
Reporting Limit
Method
% Total Solids
3.96 %
1/5/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
459 col/g dry wt
1/4/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
01042276 Sample: L1-7 3 Grab
1/4/22
Parameters
Results
Analysis Date
Reporting Limit
Method
% Total Solids
4.03 %
1/5/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
226 col/g dry wt
1/4/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
01042277 Sample:
L1-7 4 Grab
1/4/22
Parameters
Results
Analysis Date
Reporting Limit
Method
% Total Solids
4.27 %
1/5/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
213 col/g dry wt
1/4/22
130 col/g dry wt
SM 9222D
Meritech Work Order # 01042278 Sample: L1-7 5 Grab 1/4/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 3.97 % 1/5/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 229 col/g dry wt 1/4/22 130 col/g dry wt SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Page 2
Contact: Alex Fox Report Date:
Client: Synagro
284 Boger Road Project: Lincolnton
Mocksville, NC 27028 Date Sample Rcvd: 1/4/2022
Meritech Work Order # 01042279 Sample: L1-7 6 Grab 1/4/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 3.88 % 1/5/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 234 col/g dry wt 1/4/22 130 col/g dry wt SM 9222D
Meritech Work Order # 01042280 Sample: Ll-7 7 Grab 1/4/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids
4.08 %
1/5/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
223 col/g dry wt
1/4/22
130 col/g dry wt
SM 9222D
I hereby certify that I have reviewed and approve these data. i2Y,
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

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ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION )CORM (02T Rules)
Facility Name: City of Lincolmon WWTP WQ Permit Number:
WWTP Name: Lincolmon WWTP NPDES Number;
Monitoring Period: From 04/01/22 To 06/30/2022
WQ 0002712
NC 0025496
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1 /A (time/temp) _ Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment ThermopI lic
Seta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class S only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion
Anaerobic Digestion
Tf ennlirahla !Fn nlfnrna4iva —f--A fr lonr A nr f lace TA the
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Minimum Gco. Mean Maximum Units
Excee-
dences
of
Analysis
Type
Technique
Fecal
2x10to the 61"
MPN
MPN/g
Coliform
power per gram of
total solids
CFU
CFU/g
1000 MPN per gram of total
245
307
514
MPN/g
0
Quarterly
Grab
9222D SM
solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed:
Option/Alt. 1
Option/Alt. 2
Option/Alt. 3 Option/Alt. 4
(VS reduction) X
(40-day bench)
(30-day bench) (Spec. 02 uptake)
Option/Alt. 5
Option/Alt. 6
Option/Alt. 7 Option/Alt. 8
(14-Day Aerobic)
(Alk Stabilization)
(Drying — Stable) (Drying — Unstable)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel
properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met, I am
aware that there are significant penalties for false certification including fine and imprisonment,"
s 11 1,
CC
Preparer Name 60d Title ( type or print) Land Applier Name and Title (if applicable) (type or print)
3
Signature of Preparer* V Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26)

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
OT,
.-.
Page 1
Contact: Alex Fox
Report Date:
4/14/2022
Client: Synagro
284 Boger Road
Project:
Lincolnton
Mocksville, NC 27028
Date Sample Rcvd:
4/6/2022
Meritech Work Order #
04062277 Sample: L 1 Grab
4/6/22
Parameters
Results Analysis Date
Reporting Limit
Method
% Total Solids
3.54 % 4/7/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
514 col/g dry wt 4/6/22
224 col/g dry wt
SM 9222D
Meritech Work Order #
04062278 Sample: L 2 Grab
4/6/22
Parameters
Results Analysis Date
Reporting Limit
Method
% Total Solids
3.55 % 4/7/22
0-100 %
SM 2540B
Fecal CoIiform (Sludge)
256 col/g dry wt 4/6/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
04062279 Sample: L 3 Grab
4/6/22
Parameters
Results Analysis Date
Reporting Limit
Method
% Total Solids
3.64 % 4/7/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
250 col/g dry wt 4/6/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
04062280 Sample: L 4 Grab
4/6/22
Parameters
Results Analysis Date
Reporting Limit
Method
% Total Solids
3.71 % 4/7/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
245 col/g dry wt 4/6/22
130 col/g dry wt
SM 9222D
Meritech Work Order #
04062281 Sample: L 5 Grab
4/6/22
Parameters
Results Analysis Date
Reporting Limit
Method
% Total Solids
3.60 % 4/7/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
<253 col/g dry wt 4/6/22
253 cal/g dry wt
SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact: Alex Fox
Client: Synagro
284 Boger Road
Mocksville, NC 27028
Meritech Work Order # 04062282 Sample: L 6 Grab
Parameters Results Analysis Date
% Total Solids 3.60 % 4/7/22
Fecal Coliform (Sludge) 505 col/g dry wt 4/6/22
Page 2
Report Date: 4/14/2022
Project: Lincolnton
Date Sample Rcvd: 4/6/2022
4/6/22
Reporting Limit Method
0-100 % SM 2540B
130 col/g dry wt SM 9222D
Meritech Work Order # 04062283 Sample: L 7 Grab
Parameters Results Analysis Date Reporting Limit
% Total Solids 3.65 % 4/7/22 0-100 %
Fecal Coliform (Sludge) 249 col/g dry wt 4/6/22 130 col/g dry wt
4/6/22
Method
SM 2540B
SM 9222D
I hereby certify that I have reviewed and approve these data. '" nicL,4^tO'aL �[ )
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

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SM 2540 B-2011, 2540 D -2011 NC0025496
All weighings are done in grams
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Time Collected
0
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Wet Solids Wgt
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Dried Solids Wgt
% Reduction = (VS DAF -VS Sludge) _X100 q
VS DAF - (VS DAF)(VS Sludge) I- %

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Lincolnton WWTP_ WQ Permit Number: WQ 0002712
WWTP Name, Lincolnton WWTP NPDES Number: NC 0025496
Monitoring Period: From 07/01/22 To 09/30/2022
Pathogen Reduction (40 CFR 503.32115A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp) Alt. 21B (Alk Treatment) Alt, WC (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying
Anaerobic Digestion
Composting Aerobic Digestion
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dences
Analysis
Fecal
WO to the 61h
MPN
MPNIg
Coliform
power per gram
of total solids
CFU
CFU/g
1000 MPN per gram of
198
216
225
MPN/g
Quarterly
Grab
9222DSM
total solids (dry weight)
,Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coli foam
Vector Attraction Reduction (40 CFR 503.33115A NCAC 02T.1107) - Please indicate optionlalternative performed:
Option/Alt. 1
Option/Alt. 2
(V5 reduction) X
(40-day bench)
Option/Alt. 5
Option/Alt. 6
(14-Day Aerobic)
(Alk Stabilization)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
CERTIFICATION STATEMENT (please check the appropriate statement)
Option/Alt. 3 Option/Aft. 4
(30-daybench) (Spec. 02 uptake)
Option/Alt, 7 Option/Alt. 8
(Drying — Stable) (Drying —Unstable)
No vector attraction reduction alternatives were performed
"I certify, under penalty of law, that the pathogen re uirements in 40 CFR 503,32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement an 40 CFR 503.33/15A NCAC 02T,1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement an 40 CFR 503.33/15A NCAC 02T,1107 have not been met," (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
et, been mI am awarg that there are significant p nalties-for fal*e certification including fine and imprisonment."
or+Ald 16%,01e),JR ww � ,Y,n rrrlen�
�s
Prep rer Name t
T T
pe or print) Land Applier Name and Title (if applicable) (type or print)
a _3
Signature of Preparer* U Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26)

Meritech, Inc.
Environmental Laboratory
AMP,, Laboratory Certification No.165
Contact: Alex Fox Page 1Report Date: 7/14/2022
Client: Synagro
284 Boger Road Project: Lincolnton
Mocksville, NC 27028 Date Sample Rcvd: 7/7/2022
Meritech Work Order # 070722100 Sample: L 1 Grab 7/7/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 4.20 % 7/8/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <216 CFU/g dry wt 7/7/22 216 CFU/g dry wt SM 9222D
Meritech Work Order #
070722101 Sample: L 2 Grab
7/7/22
Parameters
Results Analysis Date
Reporting Limit
Method
% Total Solids
4.12 % 7/8/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
<221 CFU/g drywt 7/7/22
221 CFU/g dry wt
SM 9222D
Meritech Work Order #
070722102 Sample: L 3 Grab
7/7/22
Parameters
Results Analysis Date
RepQrtingLimit
Method
% Total Solids
4.22 % 7/8/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
<215 CFU/g dry wt 7/7/22
215 CFU/g dry wt
SM 9222D
Meritech Work Order #
070722103 Sample: L 4 Grab
7/7/22
Parameters
Results Analysis Date
,Reporting Limit
Method
% Total Solids
4.09 % 7/8/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
<222 CFU/g dry wt 7/7/22
222 CFU/g dry wt
SM 9222D
Meritech Work Order #
070722104 Sample: L 5 Grab
7/7/22
Parameters
Results Analysis Date
ReportingLimit
Method
% Total Solids
4.04 % 7/8/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
<225 CFU/g dry wt 7/7/22
225 CFU/g dry wt
SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No. 165
Contact: Alex Fox
Client: Synagro
284 Boger Road
MocksvilIe, NC 27028
Page 2
Report Date: 7/14/2022
Project: Lincolnton
Date Sample Rcvd: 7/7/2022
Meritech Work Order # 070722105 Sample: L 6 Grab 7/7/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 4.24 % 7/8/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <214 CFU/g dry wt 7/7/22 214 CFU/g dry wt SM 9222D
Meritech Work Order # 070722106 Sample: L 7 Grab 7/7/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 4.58 % 7/8/22 0-100 SM 2540E
Fecal Coliform (Sludge) <198 CFU/g dry wt 7/7/22 198 CFU/g dry wt SM 9222D
I hereby certify that I have reviewed and approve these data.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

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SM 2640 8-2011, 2640 n -2011 NG0025496 All weighings are done In grams
Time Collected
Date Gollected
Date 1 Time In
Date 1 Time Out
Total Wet Wgt
Dish
Wet Sludge Wgt
(103-1050C) Dried
Wgt'—
Dish
Dry Solids Wgt
% Solids
-Z(/- Zz
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t
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i� 1
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10 _
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<, r 7j
% Volatile Solids
AVG
% Volatile Solids
% TS DAF
%p TS Sludge
%VSDAF=
% VS Slud e =
c
% Total Solids = Dry Solids Wgt x 1100
Wet Solids Wgt
% Volatile Solids r (Volatile solids Mgt) - ___._-x 100
Cried Solids Wgt
% Reduction « (V S DAF - VS sludge)._ =-x 100
VS DAF - (VS DAF)(V5 Sludge)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Lincolnton WWTP WQ Permit Number: WQ 0002712
WWTP Name: Lincolnton WWTP NPDES Number: NC 0025496
Monitoring Period: From 10/01/22 To 12/31/22
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1 /A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying
Anaerobic Digestion
Composting Aerobic Digestion
If applicable to alternative performed (Class A or Class B) complete the followine uionitorine data:
Parameter
Allowable Level in Sludge
Pathogen Density
No, of
Frequency
Samplc
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
denies
Analysis
Fecal
200 to the 6`
MPN
MPN/g
Coliform
power per gram
of total solids
CFU
CFU/g
1000 MPN per grain of
1483
1522
1576
MPN/g
0
Quarterly
Grab
9222D
total solids (dry weight)
SM
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lien of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed:
0 tion/Alt, I
Option/Alt. 2
(VS reduction) X
(40-day bench)
Option/Alt. 5
Option/Alt. 6
(i4-Day Aerobic)
(Alk Stabilization)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
CERTIFICATION STATEMENT (please check the appropriate statement)
Option/Alt. 3 Option/Alt. 4
(30-day bench) (Spec. 02 uptake)
Option/Alt. 7 Option/Alt. 8
(Drying -- Stable) (Drying — Unstable)
No vector attraction reduction alternatives were performed
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X_ reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the ppathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met," (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
beggrr��met. I am ware that there are significant penalties for false gertification including fine and imprisonment."
1�on 1 uP11ef Jc. W�p `o tP'r`�r�]e n
Pr arer N Mend �Ie ( type or print) Land Applier Name and Title (if applicable) (type or print)
Signature of Preparer Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503,9(r) and 15A NCAC 2T.1102 (26)

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact: A. Fox Page 1Report Date: 10/13/2022
Client: Synagro
284 Boger Road Project: Lincolnton
Mocksville, NC 27028 Date Sample Rcvd: 10/4/2022
Meritech Work Order # 100422242 Sample: L 1 Grab 10/4/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 6.13 % 10/6/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <1483 CFU/g dry wt 10/4/22 1483 CFU/g dry wt SM 9222D
Meritech Work Order # 100422243 Sample: L 2 Grab 10/4/22
Parameters
Results
Analysis Date
Reporting Limit
Method
% Total Solids
5.77 %
10/6/22
0-100 %
SM 2540E
Fecal Coliform (Sludge)
1,576 CFU/g dry wt
10/4/22
130 CFU/g dry wt
SM 9222D
Meritech Work Order # 100422244 Sample: L 3 Grab 10/4/22
Parameters
Results
Analysis Date
Reporting Limit
Method
% Total Solids
6.07 %
10/6/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
<1498 CFU/g dry wt
10/4/22
1498 CFU/g dry wt
SM 9222D
Meritech Work Order # 100422245 Sample: L 4 Grab 10/4/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 6.07 % 10/6/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <1498 CFU/g dry wt 10/4/22 1498 CFU/g dry wt SM 9222D
Meritech Work Order # 100422246 Sample: L 5 Grab 10/4/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 5.90 % 10/6/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <1541 CFU/g dry wt 10/4/22 1541 CFU/g dry wt SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Page 2
Contact: Ryan Copeland Report Date: 10/13/2022
Client: Synagro
284 Boger Road Project: Lincolnton
Mocksville, NC 27028 Date Sample Rcvd: 10/4/2022
Meritech Work Order # 100422247 Sample: L 6 Grab 10/4/22
Parameters Results Analysis Date Reporting Limit Method
% Total Solids 6.03 % 10/6/22 0-100 % SM 2540B
Fecal CoIiform (Sludge) <1508 CFU/g dry wt 10/4/22 1508 CFU/g dry wt SM 9222D
Meritech Work Order # 100422248 Sample: L 7 Grab 10/4/22
Parameters Results Analysis Date Reporting Limit Method
% TotaI Solids 5.86 % 10/6/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <1551 CFU/g drywt 10/4/22 1551 CFU/g dry wt SM 9222D
1 hereby certify that have reviewed and approve these data. (�- -'0
Labora bry Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

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VS DAF - (VS DAF)(VS Sludge)
0/0

SECTION 6

Agricultural Lime Application Log
Year: 2022
Project: Lincolnton
Field
Soil
Lime Requirement
Tons/Acre
Date Applied
(state -county -site -field)
pH
(from soil analysis)
Applied(CCE Eq.)
L I -4 /-b
b.9
U.0 I /AC
U.0
LT-1 9-1
5.8
1 T/Ac
1 T/Ac
10/08/22
LT-1 9-2
6.2
0.0 T/Ac
0.0
LT-1 9-3
6.0
0.0 T/Ac
0.0
LT-47-2
6.0
0.0 T/Ac
0.0
LT-49-1
5.8
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1 T/AC
10/01 /22
LT-49-2
5.8
.5T/Ac
1 T/Ac
10/01 /11
LT-55-1
5.4
.7T/AC
1 T/AC
10/12/22
LT-55-2
5.5
.8T/Ac
1 T/AC
10/13/22
* Lime is ordered waiting for Vendor to spread it

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