WQ0032723_2022 Residual Annual Report_20230228 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0032723
Applicant/Permittee City of Reidsville
Email Notifications
Does this need review by the hydrogeologist? * Yes U No
Regional Office Winston-Salem
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Brent Collins
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
336-399-3646
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0032723
Has Current Existing permit number
Applicant/Permittee Address*
1100 Vance Street, Reidsville, NC 27320
Facility Name*
City of Reidsville Class A Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Reidsville WTP Annual Report - WQ0032723.pdf 5.16MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/28/2023

February 28, 2023
DENR/Water Quality Section
Non -Discharge Compliance Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2022 Annual Report — Reidsville WTP
Treatment and Land Application of Residuals
Permit No. WQ0032723
Dear Sir or Madam:
Enclosed is the 2022 Annual Report for the above referenced land application permit.
During 2022 EMA Resources, Inc. land applied 58.03 dry tons of wastewater residuals to
39.68 acres of private farmland. Please contact Brent Collins - Director of Technical
Services if you have any further questions regarding this report.
Sincerely,
Z.-e4:241-
Brent Collins
Director of Technical Services
brent.collins&emaresourcesinc.com
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

t
esources, Inc.
City of Reidsville WTP
2022 Annual Report
Residuals Land Application
Permit No. WQ0032723
Prepared By:
EMA Resources, Inc.
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

1011►A&MV.1\1►111.1a0R411R1: 0I1119F191120MRNONI19IM111RV.TejBe0 0I1-1-T.1Irol04t 1Y111[91:vY[119F.191M111u10M:AldWQmad I
WQ PERMIT #: WQ0032723 FACILITY NAME:
Reidsville WTP
Rockingham OPERATOR: City of Reidsville
❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
E Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes 10 No ❑ —1o. If No skip parts A, B, C and certify form below
PHONE:
COUNTY
FACILITY TYPE (please check one)
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
February
March
April
May
June
July
August
September
October
November
December
Total from FORM DMSDF (sup)
0
58.03
58.03
58.03
Totals: Annual (dry tons):
0
58.03
58.03
58.03
Amendments used:
Bulkin Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)):
Part C:
Total Number of Form DMSDF 0 1
Facility was compliant during the past calendar year with all conditions of the land application permit p Yes
(including but not limited to items 1-3 below) issued by the Division of Water Quality: ❑ No 0 If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
c)AWN101- WODA��YG�_
Summer Woodard (Feb 10, 202316:24 EST)
Signature of Permittee
Feb 10,2023
W. Blake Slaughter (Feb 10, 02312:48 EST)
Date Signature of Preparer**
(if different from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Feb 10, 2023
Date
DENR FORM DMSDF (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Supplemental Information
WQ PERMIT #: WQ0032723 FACILITY NAME: City of Reidsville WTP
PHONE: COUNTY: Rockingham OPERATOR: City of Reidsville
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
© Distribution and Marketing (complete Parts A, and B)
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry
tons)
Intended use(s)
August
City of Reidsville WTP
58.03
58.03
Russell Purdue
58.03
Soil Amendment
Totals:
Annual (dry tons):
0
58.03
58.03 58.03
Amendment(s) used: I
Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)):
Total Number of Form DMSDF (Supp)L
DENR FORM DMSDF (Supp) (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Analysis Data
WQ0032723
Reidsville WTP
NCO046345
Reidsville WTP
Laboratory:
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
(mg/kg)
Conc.
Limit
(mg/kg a
Sample or Composite Date
113122
Percent Solids (%)
NA
0.892
Arsenic
75
26.7
Cadmium
85
2.22
Copper
4,300
40.7
Chromium
NA
26.2
Lead
840
20
Mercury
57
0.721
Molybdenum
75
15
Nickel
420
13.3
Selenium
100
35.6
Zinc
7,500
90
Total Phosphorus
NA
394
TKN
NA
42700
Ammonia -Nitrogen
NA
8660
Nitrate and Nitrite
NA
548
'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
W $ (Feb 10.
Feb10 2023
W. Blake Slauehter 112311,. 11 7
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
WQ0032723
Laboratory: 1)
Facility Name:
Reidsville WTP
2)
Residual Source
NCO046345
3)
NPDES # or WQ#:
4)
WWTP Name:
Reidsville WTP
5)
Residual Analvsis Data
Waypoint Analytical
Parameter
Sample or Com osite Date
Magnesium
--
--
--
Potassium
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
W XW(E2 T, Feb 10, 2023
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Reidsville - WTP Total Dry Tons Applied (Annual):
WQ0032723 Cation Exchange Capacity (non 503 only):
Russell Perdue Owner: Russell Perdue Predominant Soil Series:
6.34 Acres Permitted: 6.34 Site #: RC 131 Field #:
8.22
FrD2
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
8/3/22
2
_3j
4j
5j
U
U
8
9j
0
11
12
% Solids
0.892
Arsenic
26.7
Cadmium
2.22
Copper
40.7
Chromium
26.2
Lead
20
Mercury
0.721
Molyb-
denum
15
Nickel
13.3
Selenium
35.6
Zinc
90
Total
Phos-
horus
394
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3j
4j
5j
6j
7j
8
9
10
11
12
DT/Ac./
App.
-
Event
1.30
Arsenic
0.069
0.000
0.000
1 0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
1 0.069
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
0.106
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.106
Chromium
0.068
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.068
Lead
0.052
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.039
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.039
denum
Nickel
0.035
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Selenium
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.092
Zinc
0.233
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.233
Total
Phos-
1.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.022
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/8/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Reidsville - WTP WQ Permit #: WQ0032723 Field #: 1 Acres Utilized: 6.34
Land Owner: Russell Perdue Annual Dry Tons Applied: 8.22 Site #: RC131 Acres Permitted: 6.34
Operator: Russell Perdue Predominant Soil Series: FrD2 Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Hay Crop 1 Max. PAN: 154 Crop 2 Name: Crop 2 Max. PAN:
$..,
Q
Volume applied
PP
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
WetHrs.
Moist)
Preci p•
Past 24
inches
>
,.�
0 w
*
o
* �:
4
�
PZ =
w
* w
,
TKN
mg/kg
Z 8
o 0
w.
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
pp
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
8/4
78000
0.892
0.458
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
7.580
NA
Fescue
8/5
78000
0.892
0.458
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
7.580
NA
Fescue
8/26
65000
0.892
0.381
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
6.317
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM
FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
01
221000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
I P
21.477
0.000
Lime Applied
Annuallbs/acre
0.069
0.006
0.106
0.068
0.052
0.002
0.039
0.035
0.092
0.233
1.022
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.069
0.006
0.106
0.068
0.052
0.002
0.039
0.035
0.092
0.233
Permitted C. P. L. R.****
36
34
1 1338
267
1 15
1
1 374
1 89
2498
Permit PAN Limit 1 st/2nd Crop
F 154
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/8/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Reidsville - WTP Total Dry Tons Applied (Annual):
WQ0032723 Cation Exchange Capacity (non 503 only):
Russell Perdue Owner: Russell Perdue Predominant Soil Series:
15.12 Acres Permitted: 15.12 Site #: RC131 Field #:
20.31
CsA
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
8/3/22
2
_3j
4j
5j
U
U
8
9
10
11
12
% Solids
0.892
Arsenic
26.7
Cadmium
2.22
Copper
40.7
Chromium
26.2
Lead
20
Mercury
0.721
Molyb-
denum
15
Nickel
13.3
Selenium
35.6
Zinc
90
Total
Phos-
horus
394
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3j
4j
5j
6j
7j
8
9
10
11
12
DT/Ac./
App.
-
Event
1.34
Arsenic
0.072
0.000
0.000
1 0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
1 0.072
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
0.109
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.109
Chromium
0.070
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.070
Lead
0.054
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.054
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.040
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
denum
Nickel
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Selenium
0.096
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.096
Zinc
0.242
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.242
Total
Phos-
1.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.058
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/8/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Reidsville - WTP WQ Permit #: WQ0032723 Field #: 2 Acres Utilized: 15.12
Land Owner: Russell Perdue Annual Dry Tons Applied: 20.31 Site #: RC 131 Acres Permitted: 15.12
Operator: Russell Perdue Predominant Soil Series: CsA Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 141.75 Crop 2 Name: Crop 2 Max. PAN:
$
Q
Volume applied
PP
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NpDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Preci p•
Past 24
Hrs.
inches
>
4 '`�
c,
a w
5.
* o
o
* w.
--
7y �
w
* K.
TKN
mg/kg
z 8
4
o
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
8/8
123500
0.892
0.304
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
5.032
NA
Fescue
8/9
162500
0.892
0.400
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
6.622
NA
Fescue
8/17
149500
0.892
0.368
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
6.092
NA
Fescue
8/18
110500
0.892
0.272
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
4.503
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM
FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
01
546000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
22.249
0.000
Lime Applied
Annuallbs/acre
0.072
0.006
0.109
0.070
0.054
0.002
0.040
0.036
0.096
0.242
1.058
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.072
0.006
0.109
0.070
0.054
0.002
0.040
0.036
0.096
0.242
Permitted C. P. L. R.****
36
34
1338
2671
15
1
374
89
2498
Permit PAN Limit 1 st/2nd Crop
141.75
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/8/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Reidsville - WTP Total Dry Tons Applied (Annual):
WQ0032723 Cation Exchange Capacity (non 503 only):
Russell Perdue Owner: Russell Perdue Predominant Soil Series:
12.72 Acres Permitted: 12.72 Site #: RC 131 Field #:
18.86
DoA
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
8/3/22
2
_3j
4j
5j
U
U
8
9j
0
11
12
% Solids
0.892
Arsenic
26.7
Cadmium
2.22
Copper
40.7
Chromium
26.2
Lead
20
Mercury
0.721
Molyb-
denum
15
Nickel
13.3
Selenium
35.6
Zinc
90
Total
Phos-
horus
394
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3j
4j
5j
6j
7j
8
9
10
11
12
DT/Ac./
App.
-
Event
1.48
Arsenic
0.079
0.000
0.000
1 0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
1 0.079
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
0.121
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.121
Chromium
0.078
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.078
Lead
0.059
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.059
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
denum
Nickel
0.039
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.039
Selenium
0.106
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.106
Zinc
0.267
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.267
Total
Phos-
1.169
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.169
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/8/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Reidsville - WTP WQ Permit #: WQ0032723 Field #: 3 Acres Utilized: 12.72
Land Owner: Russell Perdue Annual Dry Tons Applied: 18.86 Site #: RC 131 Acres Permitted: 12.72
Operator: Russell Perdue Predominant Soil Series: DoA Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 148.5 Crop 2 Name: Crop 2 Max. PAN:
o
o
Q
Volume applied
(enter one) Solids/
Liquid
q
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
fin'
Wet
Moist)
Precip.
Past 24
Hrs.
inches
�
o w
* o
C
�,
K'
*
4.
W
' ,
* w'
TKN
mg/kg
Z a
� �
o �
c°°o °
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
lbs/acre
( )
Name of CropType
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
8/10
1
123500
0.892
0.361
Reidsville WTP
Dry
<.5"
S
0.5
0.1
1 42700
8660
1 548
5.982
NA
Fescue
8/11
1
52000
0.892
0.152
Reidsville WTP
Dry
<.5"
S
0.5
0.1
1 42700
8660
1 548
2.519
NA
Fescue
8/19
1
97500
0.892
0.285
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
4.723
NA
Fescue
8/24
1
104000
0.892
0.304
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
5.037
NA
Fescue
8/25
1
130000
0.892
0.380
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
6.297
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM
FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
01
507000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
24.558
0.000
Lime Applied
Annuallbs/acre
0.079
0.007
0.121
0.078
0.059
0.002
0.044
0.039
0.106
0.267
1.169
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
1 0.079
0.007
0.121
0.078
0.059
0.002
0.044
0.039
0.106
0.267
Permitted C. P. L. R.****
1 36
1 34
1338
267
1 15
1
374
89
2498
Permit PAN Limit lst/2nd Crop
I
F 148.5
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/8/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Reidsville - WTP Total Dry Tons Applied (Annual):
WQ0032723 Cation Exchange Capacity (non 503 only):
Russell Perdue Owner: Russell Perdue Predominant Soil Series:
5.5 Acres Permitted: 5.5 Site #: RC 131 Field #:
10.64
FrD2
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
1
8/3/22
2
_3j
4j
5j
U
U
8
9j
0
11
12
% Solids
0.892
Arsenic
26.7
Cadmium
2.22
Copper
40.7
Chromium
26.2
Lead
20
Mercury
0.721
Molyb-
denum
15
Nickel
13.3
Selenium
35.6
Zinc
90
Total
Phos-
horus
394
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3j
4j
5j
6j
7j
8
9
10
11
12
DT/Ac./
App.
-
Event
1.93
Arsenic
0.103
0.000
0.000
1 0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
1 0.103
Cadmium
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Copper
0.157
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.157
Chromium
0.101
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.101
Lead
0.077
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.077
Mercury
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
denum
Nickel
0.051
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Selenium
0.138
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.138
Zinc
0.348
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.348
Total
Phos-
1.524
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.524
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/8/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Reidsville - WTP WQ Permit #: WQ0032723 Field #: 4 Acres Utilized: 5.5
Land Owner: Russell Perdue Annual Dry Tons Applied: 10.64 Site #: RC131 Acres Permitted: 5.5
Operator: Russell Perdue Predominant Soil Series: FrD2 Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Hay Crop 1 Max. PAN: 154 Crop 2 Name: Crop 2 Max. PAN:
o
� O
Q
Volume applied
(enter one) Solids/
Li uid
9
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
�
0
o w
* °
C
7d R.
�,
K'
*
=
'
� �
,
TKN
mg/kg
Z
0
o 0
c°°o °
R.
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
lbs/acre
( )
Name of Crop Type
p
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
8/11
26000
0.892
0.176
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
2.913
NA
Fescue
8/12
104000
0.892
0.703
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
11.650
NA
Fescue
8/15
32500
0.892
0.220
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
3.641
NA
Fescue
8/16
123500
0.892
0.835
Reidsville WTP
Dry
<.5"
S
0.5
0.1
42700
8660
548
13.835
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0 A
0
0.000
Residuals Applications totals on FORM
FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
01
286000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
32.038
0.000
Lime Applied
Annuallbs/acre
0.103
0.009
0.157
0.101
0.077
0.003
0.058
0.051
0.138
0.348
1.524
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.103
0.009
0.157
0.101
0.077
0.003
0.058
0.051
0.138
0.348
Permitted C. P. L. R.****
36
34
i 1338
267
15
374
89
2498
Permit PAN Limit lst/2nd Crop
154
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/8/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

Waypointo
ANALYTICAL
8/11/2022
EMA Resources Inc
Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-216-0026
Client Project Description: Reidsville, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 8/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a'—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
"J-
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-216-0026
Page 2 of 8

0OWaYPOInt
. 2790 Whitten Road, Memphis, 21.2440
Main 901.213.2400 "Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-216-0026
Client Project Description: Reidsville, NC
Lab No Client Sample ID
94981 Reidsville WTP
Matrix Date Collected
Solids 08/03/202211:10
Date Received
08/04/2022
Page 3 of 8

Waypoint
ANALYTICAL
Client: EMA Resources Inc
Project: Reidsville, NC
Lab Report Number: 22-216-0026
Date: 8/11 /2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 99623 (Sludge Vector 1 Dup.)
Analyte: Aluminum
QC Batch No: 1-630653/1-630360
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 99623 (Sludge Vector 1 Dup.)
Analyte: Potassium
QC Batch No: 1-630653/1-630360
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 99623 (Sludge Vector 1 Dup.)
Analyte: Sulfur
QC Batch No: 1-630653/1-630360
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 94983 (Mocksville)
Analyte: Mercury
QC Batch No: 1-630902/1-630456
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 4 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Reidsville, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Report Date : 08/11/2022
Received : 08/04/2022
Connie Cook
Report Number : 22-216-0026
REPORT OFANALYSIS
Project
Manager
Lab No : 94981
Matrix:
Solids
Sample ID : Reidsville WTP
Sampled:
8/3/2022
11:10
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
99.1
%
1
08/08/22 16:08
FMM
SW-DRYWT
Ammonia Nitrogen
86603
mg/Kg - dry
1780
11100
1
08/11/22 12:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<548
mg/Kg - dry
548
548
1
08/09/22 14:33
ZBD
4500NO3F-2016
Organic N
340103
mg/Kg - dry
1778
11110
1
08/11/22 09:00
CALCULATION
pH
6.7
S.U.
1
08/11/2215:11
DRS
9045D
Total Solids
0.892
%
0.010
0.010
1
08/08/22 16:08
FMM
2540G-2011
Total Volatile Solids
25.5
%
0.010
0.010
1
08/08/22 16:08
FMM
2540G-2011
Total Kjeldahl Nitrogen
42700
mg/Kg - dry
1110
27800
1
08/11/22 09:00
JPJ iM-4500-NH3C-TKP
Phosphorus
3943
mg/Kg - dry
307
556
1
08/05/22 19:59
EAL
6010D
Aluminum
26000
mg/Kg - dry
513
556
1
08/05/22 19:59
EAL
6010D
Arsenic
<26.7
mg/Kg - dry
26.7
55.6
1
08/05/22 19:59
EAL
6010D
Cadmium
<2.22
mg/Kg - dry
2.22
11.1
1
08/05/22 19:59
EAL
6010D
Calcium
<4300
mg/Kg - dry
4300
5560
1
08/05/22 19:59
EAL
6010D
Chromium
<26.2
mg/Kg - dry
26.2
27.8
1
08/05/22 19:59
EAL
6010D
Copper
40.73
mg/Kg - dry
34.4
55.6
1
08/05/22 19:59
EAL
6010D
Iron
8420
mg/Kg - dry
947
1110
1
08/05/22 19:59
EAL
6010D
Lead
<20.0
mg/Kg - dry
20.0
33.3
1
08/05/22 19:59
EAL
6010D
Magnesium
761
mg/Kg - dry
287
556
1
08/05/22 19:59
EAL
6010D
Manganese
3660
mg/Kg - dry
36.1
55.6
1
08/05/22 19:59
EAL
6010D
Mercury
<0.721
mg/Kg - dry
0.721
16.6
1
08/08/22 12:10
TJS
7471A
Molybdenum
<15.0
mg/Kg - dry
15.0
27.8
1
08/05/22 19:59
EAL
6010D
Nickel
<13.3
mg/Kg - dry
13.3
27.8
1
08/05/22 19:59
EAL
6010D
Potassium
8193
mg/Kg - dry
687
1110
1
08/05/22 19:59
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

WavDointo
ANALYTICAL
46245
EMA Resources Inc
Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number : 22-216-0026
Lab No : 94981
Sample ID : Reidsville WTP
Project Reidsville, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
REPORT OFANAL YSIS
Report Date : 08/11/2022
Received : 08/04/2022
l-e4-
Connie Cook
Project Manager
Matrix: Solids
Sampled: 8/3/2022 11:10
Test
Results
Units
MDL
MQL
DF
Date / Time
Analyzed
By
Analytical
Method
Selenium
<35.6
mg/Kg - dry
35.6
55.6
1
08/05/22 19:59
EAL
6010D
Sodium
<1440
mg/Kg - dry
1440
2780
1
08/05/22 19:59
EAL
6010D
Zinc
<90.0
mg/Kg - dry
90.0
139
1
08/05/22 19:59
EAL
6010D
Sulfur
1400
mg/Kg - dry
576
1110
1
08/05/22 19:59
EAL
6010D
Sodium Absorption Ratio
<0.01
Ratio
0.01
0.01
1
08/05/22 19:59
CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

Waypoint
279D Whitten Road, Memphis,
33
Main 901.213.2400 °Fax [phone]
ANALYTICAL
www.waypointanalytical.com
Shipment
Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-216-0026
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 Other:
0 UPS 0 Client 0 Courier
Thermometer ID:
T102
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
0 Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
0 Not Present
Chain of Custody (COC) present?
0 Yes
0 No
COC agrees with sample label(s)?
0 Yes
0 No
COC properly completed
0 Yes
0 No
Samples in proper containers?
0 Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
0 Yes
0 No
All samples received within holding time?
0 Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
0 Yes
0 No
Samples were considered acceptable as cooling
process had begun.
Water - Sample containers properly preserved
0 Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
0 N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes
Comments:
0 No
Signature: Makayla Weaver Date & Time: 08/04/2022 09:51:44
Page 7 of 8

Client s
Client Project
ling Information#46245
zs
I111111�I�III�IIIII����IIIIIIII����IIIPf IIIIII'lllll�
EMA ResouArcessInc
Bent COIljnsger/contact
Aiccount
�s
755 Yadklnvjl(e Rd
EM Resources Inc 2022
Mocksville, NC 27028
Reidsmile, NC 09 51 32
Method of ShiId me
Project Description
Project/Site Location (City/State)
RUSH - Additional charges apply
Speclai Detection Urnit(s)
E-Fed Ex UPS UUSPS ww
I
l+ s-A L-1N
Date Results Needed
Courier Client Drop Off DW - Drinking Water S -Soil /Solid D - Oil
P - Product M - Misc
Other
Project Number
Project Manager Phone #
Project Manager Email
Purchase Order Number
Site/Facility ID #
336-399-3646
brent.colijns@emaresources com
T
Z
fn
A Cool < 20C Na2S203 (Micro Only)
Waypotnt-
d
OIs
0
_
Cool e- 6C
C H2SO4pH<2
ANALYTICAL
ro
c
o.
E
a
O
E
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CD
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UJ
D None Required
E NaoH PH�10
790 Whitten Road
Unless noted, all containers
_v
m
s
v
N
Q
0
u
V J
F HNO3 pHc2
G HCLpH<2
Memphis. IN 38133
C
Z
H
[phone]
per Table II of AO CFR Part
E
H
_
Z
O
Q
H3Po4 pH<2
I Cool <= 6C NA2SZ03
136.
,
c?
Date
Time
Sample Identification
Required
Analysis / Preservative
Comments/Notes
IW3
I
St,#e
Vol'
✓
Metals AI,As,Ca,Cd,Cr,Cu,Fe,Pb
Mn,Mg,Mo,Hg,Ni,Se,Na,P,S,K,Zn
t7
For laboratory Use Only
Sampled by (Name - Print)
3��,, �- G//-,•f
Client Remarks/Comments
Sludge Samples - Report Dry Weight
Ice
Custody
Seals
Lab Comments
�N
Relinquished by: (SIGNATURE)
Date Time
Received by: (SIGNATURE)
Date Time
f�
y 1
J�
b1l 3. 3 o
"Cooler Temp
Relinquished by: (SIGNATURE)
Date Time
Received by: (SIGNATURE)
Date Time
Cr
-i�cs
t
Relinquished by: (SIGNATURE)
Date Time
Re
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AMI
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to Tim e
V
i,�/1

aceAnalytical ° ANALYTICAL REPORT
August 23, 2022
EMA Resources
Sample Delivery Group: L1522454
Samples Received: 08/05/2022
Project Number:
Description: Sludge
Report To: Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By
Reagan Johnson
• Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval ofthe laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
A0
M
6
!�� t Amp,
I
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 1 of 22

I RUN we] 3oZe7►IIiI►11601
Cp: Cover Page
Tc: Table of Contents
Ss: Sample Summary
Cn: Case Narrative
Sr: Sample Results
REIDSVILLE WTP L1522454-01
Qc: Quality Control Summary
Wet Chemistry by Method 9012 B
Wet Chemistry by Method 9034-9030B
Wet Chemistry by Method 9045D
Wet Chemistry by Method D93/1010A
Mercury by Method 7470A
Metals (ICP) by Method 6010D
Volatile Organic Compounds (GC/MS) by Method 8260D
Semi -Volatile Organic Compounds (LCMS) by Method SW-846 8321
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
GI: Glossary of Terms
Al: Accreditations & Locations
Sc: Sample Chain of Custody
2
3
4
5
5
7
7
8
9
10
12
13
14
16
17
18
20
21
22
F_CP1
FF,
rCn]
r
Sr
rG1
rAl
FC
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 2 of 22

SAMPLE SUMMARY
Collected by Collected date/time Received date/time
REIDSVILLE WTP L1522454-01 Waste Brent Collins 08/03/2211:15 08/05/2208:45
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Preparation by Method 1311
Preparation by Method 1311
Wet Chemistry by Method 9012 B
Wet Chemistry by Method 9034-9030B
Wet Chemistry by Method 9045D
Wet Chemistry by Method D93/1010A
Mercury by Method 7470A
Metals (ICP) by Method 6010D
Volatile Organic Compounds (GC/MS) by Method 8260D
Semi -Volatile Organic Compounds (1-CMS) by Method SW-846 8321
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
WOIyUb4J2
1
Ud/Ud/22 Uy:Jb
Ud/Ud/22 Uy:Jb
JW)
Mt. Juliet, IN
WG1906972
1
08/08/2210:58
08/08/2210:58
JTM
Mt. Juliet, TN
WG1906868
30
08/12/22 09:15
08/13/2211:34
LDT
Mt. Juliet, TN
WG1910308
1
08/13/2210:00
08/14/2217:00
RMR
Mt. Juliet, TN
WG1911547
1
08/16/2214:00
08/16/2216:00
NTG
Mt. Juliet, TN
WG1907662
1
08/09/22 02:59
08/09/22 02:59
WOS
Mt. Juliet, TN
WG1907830
1
08/09/2210:22
08/10/2210:19
MRW
Mt. Juliet, TN
WG1908142
1
08/09/2216:04
08/09/22 20:56
ZSA
Mt. Juliet, TN
WG1907935
1
08/09/2217:32
08/09/2217:32
ACG
Mt. Juliet, TN
WG1909068
1
08/11/22 08:58
08/11/2219:49
GKM
Mt. Juliet, TN
WG1908936
1
08/11/22 08:10
08/11/2213:11
HMH
Mt. Juliet, TN
WG1908107
7
08/10/2216:07
08/11/2216:00
JNJ
Mt. Juliet, TN
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 3 of 22

CASE NARRATIVE
RP
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples IT C
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my r
SS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
r
Sr
FC]
rG1
Reagan Johnson $AI
Project Manager
E
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-903013.
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 4 of 22

SAMPLE RESULTS - 01
L1522454
REIDSVILLE WTP
Collected date/time: 08/03/22 11:15
Preparation by Method 1311
Result Qualifier
Prep
Batch
Analyte
date / ti me
TCLP Extraction -
8/8/202210:58:35 AM
WG1906972
TCLP ZHE Extraction -
8/8/2022 9:35:17 AM
WG1906432
Flui d 1
8/8/202210:58:35 AM
WG1906972
Ini tal pH 6.86
8/8/202210:58:35 AM
WG1906972
Final pH 4.90
8/8/202210:58:35 AM
WG1906972
Wet Chemistry by Method 9012 B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reacti veCyani de ND 7.50
Sample Narrati ve:
L1522454-01 WG1906868: Di lutbn due to matri x
Wet Chemistry by Method 9034-9030B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reacti veSulfi de ND Q 75.0
Wet Chemistry by Method 9045D
Di luti on Analysi s Batch
date / ti me
30 08/13/202211:34 WG1906868
Di luti on Analysi s Batch
date / ti me
1 08/14/202217:00 WG1910308
Result Qualifier Di luti on Analysi s Batch
Analyte su date / ti me
Corrosi vi t�by pH 7.21 T8 1 08/16/202216:00 WG1911547
Sample Narrati ve:
L1522454-01 WG1911547: 7.21 at 23.4C
Wet Chemistry by Method D93/1010A
Result
Analyte Deg. F
Igni tabi Ii ty DNI at 170
Mercury by Method 7470A
Qualifier Di luti on
1
Analysi s
date / ti me
08/09/2022 02:59
Batch
WG1907662
Result
Qualifier RDL
Li mi t
Di luti on Analysi s
Batch
Analyte mg/I
mg/1
mg/1
date / ti me
Mercury ND
0.0100
0.20
1 08/10/202210:19
WG1907830
Metals (ICP) by Method 6010D
Result
Qualifier RDL
Li mi t
Di luti on Analysi s
Batch
Analyte mg/I
mg/1
mg/1
date / ti me
Arseni c ND
0.100
5
1 08/09/2022 20:56
WG1908142
Bari um ND
0.100
100
1 08/09/2022 20:56
WG1908142
Cadmi um ND
0.100
1
1 08/09/2022 20:56
WG1908142
Chromi um ND
0.100
5
1 08/09/2022 20:56
WG1908142
Lead ND
0.100
5
1 08/09/2022 20:56
WG1908142
Seleni um ND
0.100
1
1 08/09/2022 20:56
WG1908142
Si Iver ND
0.100
5
1 08/09/2022 20:56
WG1908142
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
EMA Resources
L1522454
08/23/22 17:04 5 of 22

REIDSVILLE WTP SAMPLE RESULTS - 01
Collected date/time: 08/03/22 11:15 L1522454
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mgA
mg/1
mg/1
date / time
Benzene
ND
0.0500
0.50
1 08/09/202217:32
WG1907935
Carbon tetrachloride
ND
0.0500
0.50
1 08/09/202217:32
WG1907935
Chlorobenzene
ND
0.0500
100
1 08/09/202217:32
WG1907935
Chloroform
ND
0.250
6
1 08/09/202217:32
WG1907935
1,2-Dichloroethane
ND
0.0500
0.50
1 08/09/202217:32
WG1907935
1,1-Dichloroethene
ND
0.0500
0.70
1 08/09/202217:32
WG1907935
2-Butanone (MEK)
ND
0.500
200
1 08/09/202217:32
WG1907935
Tetrachloroethene
ND
0.0500
0.70
1 08/09/202217:32
WG1907935
Trichloroethene
ND
0.0500
0.50
1 08/09/202217:32
WG1907935
Vinyl chloride
ND
0.0500
0.20
1 08/09/202217:32
WG1907935
(S) Toluene-d8
116
80.0-120
08109120221732
WG1907935
(S) 4-Bromofluorobenzene
99.0
77.0-126
08109120221732
WG1907935
(S)1,2-Dichloroethane-d4
97.6
70.0-130
08109120221732
WG1907935
Semi -Volatile Organic Compounds (LCMS) by Method SW-846 8321
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mgA
mg/1
mg/1
date / time
2,4-D
ND
0.0200
10
1 08/11/202219:49
WG1909068
2,4,5-TP (Silvex)
ND
0.0200
1
1 08/11/202219:49
WG1909068
(S)2,4-DB-D3
133
J1 70.0-130
081111202219.49
WG1909068
Pesticides (GC) by Method 8081B
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mgA
mg/1
mg/1
date / time
Chlordane
ND
0.00500
0.03
1 08/11/202213:11
WG1908936
Endrin
ND
0.00500
0.02
1 08/11/202213:11
WG1908936
Heptachlor
ND
0.00500
0.0080
1 08/11/202213:11
WG1908936
Heptachlor epoxide
ND
0.00500
0.0080
1 08/11/202213:11
WG1908936
Lindane
ND
0.00500
0.40
1 08/11/202213:11
WG1908936
Methoxychlor
ND
0.00500
10
1 08/11/202213:11
WG1908936
Toxaphene
ND
0.0100
0.50
1 08/11/202213:11
WG1908936
(S)Decochlorobiphenyl
39.3
10.0-128
081111202213:11
WG1908936
(S) Tetrochloro-m-xylene
41.2
10.0-127
081111202213:11
WG1908936
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
Analyte
mgA
mg/1
mg/1
date / time
1,4-Dichlorobenzene
ND
0.100
7.50
1
08/11/202216:00
WG1908107
2,4-Dinitrotoluene
ND
0.100
0.13
1
08/11/202216:00
WG1908107
Hexachlorobenzene
ND
0.100
0.13
1
08/11/202216:00
WG1908107
Hexachloro-1,3-butadiene
ND
0.100
0.50
1
08/11/202216:00
WG1908107
Hexachloroethane
ND
0.100
3
1
08/11/202216:00
WG1908107
Nitrobenzene
ND
0.100
2
1
08/11/202216:00
WG1908107
Pyridine
ND
J4 0.100
5
1
08/11/202216:00
WG1908107
3&4-Methyl Phenol
ND
0.100
400
1
08/11/202216:00
WG1908107
2-Methylphenol
ND
0.100
200
1
08/11/202216:00
WG1908107
Pentachlorophenol
ND
0.100
100
1
08/11/202216:00
WG1908107
2,4,5-Trichlorophenol
ND
0.100
400
1
08/11/202216:00
WG1908107
2,4,6-Trichlorophenol
ND
0.100
2
1
08/11/202216:00
WG1908107
(S)2-Fluorophenol
29.3
10.0-120
081111202216:00
WG1908107
(S) Phenol-d5
22.5
10.0-120
081111202216:00
WG1908107
(S) Nitrobenzene-d5
55.9
10.0-127
081111202216:00
WG1908107
(S)2-Fluorobiphenyl
46.4
10.0-130
081111202216:00
WG1908107
(S)2,4,6-Tribromophenol
60.0
10.0-155
081111202216:00
WG1908107
(S) p-Terphenyl-d14
67.3
10.0-128
081111202216:00
WG1908107
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 6 of 22

WG1906868
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3825908-1 08/13/2211:19
MB Result
Analyte mg/kg
Reactive Cyanide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.0390 0.250
L1520927-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1522454-01
(OS) L1520927-01 08/13/2211:23 • (DUP) R3825908-3 08/13/2211:24
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg % %
Reactive Cyanide NO NO 1 0.000 20
L1523218-04 Original Sample (OS) • Duplicate (DUP)
(OS) L1523218-04 08/13/2211:46 • (DUP) R3825908-6 08/13/2211:47
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg % %
Reactive Cyanide NO NO 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3825908-2 08/13/22 11:20
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg % %
Reactive Cyanide 2.50 2.40 96.0 85.0-115
L1522736-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1522736-01 08/13/2211:36 • (MS) R3825908-4 08/13/2211:37 • (MSD) R3825908-5 08/13/2211:38
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg % % % % %
Reactive Cyanide 1.67 NO 1.72 1.67 103 100 1 75.0-125 2.96 20
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 7 of 22

WG1910308
Wet Chemistry by Method 9034-9030B
Method Blank (MB)
(MB) R3826086-1 08/14/22 17:00
MB Result
Analyte mg/kg
Reactive Sulfide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
30.0 75.0
Laboratory Control Sample (LCS)
QUALITY CONTROL SUMMARY
L1522454-01
(LCS) R3826086-2 08/14/22 17:00
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg % %
Reactive Sulfide 100 55.2 55.2 53.8-124
L1523875-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1523875-01 08/14/22 17:00 • (MS) R3826086-3 08/14/22 17:00 • (MSD) R3826086-4 08/14/22 17:00
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte mg/kg mg/kg mg/kg mg/kg % % % %
Reactive Sulfide 100 ND ND ND 0.000 0.000 1 10.0-136 J6 J6 0.000
Sample Narrative:
MS: Matrix spike failure due to matrix.
MSD: Matrix spike failure due to matrix.
RPD Limits
20
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/2217:04 8 of 22

WG1911547 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9045D L1522454-01
Laboratory Control Sample (LCS)
(LCS) R3826919-1 08/16/2216:00
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte su su % %
Corrosivity by pH 10.0 9.91 99.1 99.0-101
Sample Narrative:
LCS: 9.91 at 22.6C
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 9 of 22

WG1907662 QUALITY CONTROL SUMMARY
Wet Chemistry by Method D93/1010A L1522454-01
L1520837-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1520837-01 08/09/22 02:59 • (DUP) R3823959-3 08/09/22 02:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F % %
Ignitability DNIat170 DNIat170 1 10
L1521198-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1521198-01 08/09/22 02:59 • (DUP) R3823959-4 08/09/22 02:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F % %
Ignitability 148 150 1 1.34 10
L1521198-03 Original Sample (OS) • Duplicate (DUP)
(OS) L1521198-03 08/09/22 02:59 • (DUP) R3823959-5 08/09/22 02:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F % %
Ignitability 154 146 1 5.34 10
L1521198-05 Original Sample (OS) • Duplicate (DUP)
(OS) L1521198-05 08/09/22 02:59 • (DUP) R3823959-6 08/09/22 02:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F % %
Ignitability 150 152 1 1.33 10
L1521198-07 Original Sample (OS) • Duplicate (DUP)
(OS) L1521198-07 08/09/22 02:59 • (DUP) R3823959-7 08/09/22 02:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F % %
Ignitability 150 154 1 2.64 10
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/2217:04 10 of 22

WG1907662 QUALITY CONTROL SUMMARY
Wet Chemistry by Method D93/1010A L1522454-01
L1522347-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1522347-01 08/09/22 02:59 • (DUP) R3823959-8 08/09/22 02:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F % %
Ignitability 166 160 1 3.69 10
L1522454-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1522454-01 08/09/22 02:59 • (DUP) R3823959-9 08/09/22 02:59
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F % %
Ignitability DNIat170 DNIat170 1 0.000 10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3823959-1 08/09/22 02:59 • (LCSD) R3823959-2 08/09/22 02:59
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte Deg. F Deg. F Deg. F % % % % %
Ignitability 126 124 128 98.2 101 95.6-104 3.18 10
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 11 of 22

WG1907830
Mercury by Method 7470A
Method Blank (MB)
(MB) R3824604-1 08/10/22 09:45
MB Result
Analyte mg/1
Mercury U
MB Qualifier MB MDL
MB RDL
mg/1
mg/1
0.00333
0.0100
Laboratory Control Sample (LCS)
QUALITY CONTROL SUMMARY
L1522454-01
(LCS) R3824604-2 08/10/22 09:51
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/1 mg/1 % %
Mercury 0.0300 0.0312 104 80.0-120
L1522235-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1522235-02 08/10/22 09:53 • (MS) R3824604-3 08/10/22 09:55 • (MSD) R3824604-4 08/10/22 09:57
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/1 mg/1 mg/1 mg/1 % % % % %
Mercury 0.0300 ND 0.0328 0.0326 109 109 1 75.0-125 0.685 20
ACCOUNT: PROJECT:
EMA Resources
SDG: DATE/TIME: PAGE:
L1522454 08/23/22 17:04 12 of 22

WG1908142
Metals (ICP) by Method 6010D
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1522454-01
(MB) R3824410-1 08/09/22 20:09
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte mg/1
mg/1
mg/1
Arsenic U
0.0333
0.100
Barium U
0.0333
0.100
Cadmium U
0.0333
0.100
Chromium U
0.0333
0.100
Lead U
0.0333
0.100
Selenium U
0.0333
0.100
Silver U
0.0333
0.100
Laboratory Control Sample (LCS)
(LCS) R3824410-2 08/09/22 20:12
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
Analyte mg/1
mg/1
%
%
Arsenic 10.0
9.64
96.4
80.0-120
Barium 10.0
9.98
99.8
80.0-120
Cadmium 10.0
9.91
99.1
80.0-120
Chromium 10.0
9.76
97.6
80.0-120
Lead 10.0
9.86
98.6
80.0-120
Selenium 10.0
10.0
100
80.0-120
Silver 2.00
1.91
95.5
80.0-120
LCS Qualifier
L1522227-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1522227-01 08/09/22 20:15 • (MS) R3824410-4 08/09/22 20:21 • (MSD) R3824410-5 08/09/22 20:23
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/1
mg/1
mg/1
mg/1
%
%
Arsenic
10.0
ND
9.72
9.56
96.7
95.1
Barium
10.0
0.403
10.4
10.2
99.5
98.2
Cadmium
10.0
ND
9.94
9.80
99.4
98.0
Chromium
10.0
ND
9.80
9.66
98.0
96.6
Lead
10.0
0.108
9.95
9.84
98.4
97.3
Selenium
10.0
ND
9.96
9.88
98.8
98.0
Silver
2.00
ND
1.92
1.90
96.2
95.1
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
1 75.0-125
1.66
20
1 75.0-125
1.26
20
1 75.0-125
1.37
20
1 75.0-125
1.43
20
1 75.0-125
1.13
20
1 75.0-125
0.824
20
1 75.0-125
1.16
20
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 13 of 22

WG1907935 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1522454-01
Method Blank (MB)
(MB) R3824763-3 08/09/2213:27
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Benzene
U
0.0167
0.0500
Carbon tetrachloride
U
0.0167
0.0500
Chlorobenzene
U
0.0167
0.0500
Chloroform
U
0.0833
0.250
1,2-Dichloroethane
U
0.0167
0.0500
1,1-Dichloroethene
U
0.0167
0.0500
2-Butanone (MEK)
U
0.167
0.500
Tetra chloroethene
U
0.0167
0.0500
Trichloroethene
U
0.0167
0.0500
Vinyl chloride
U
0.0167
0.0500
(S) Toluene-d8
110
80.0-120
(S) 4-Bromofluorobenzene
101
77.0-126
(S) 1,2-Dichloroethone-d4
92.5
70.0-130
Laboratory Control
Sample (LCS) • Laboratory
Control Sample
Duplicate (LCSD)
(LCS) R3824763-1 08/09/2210:51 • (LCSD) R3824763-2 08/09/22 11:11
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
mg/I
mg/I
mg/I
%
%
%
%
%
Benzene
0.250
0.257
0.259
103
104
70.0-123
0.775
20
Carbon tetrachloride
0.250
0.255
0.228
102
91.2
68.0-126
11.2
20
Chlorobenzene
0.250
0.286
0.285
114
114
80.0-121
0.350
20
Chloroform
0.250
0.253
0.258
101
103
73.0-120
1.96
20
1,2-Dichloroethane
0.250
0.248
0.248
99.2
99.2
70.0-128
0.000
20
1,1-Dichloroethene
0.250
0.293
0.271
117
108
71.0-124
7.80
20
2-Butanone (MEK)
1.25
1.25
1.15
100
92.0
44.0-160
8.33
20
Tetrachloroethene
0.250
0.319
0.313
128
125
72.0-132
1.90
20
Trichloroethene
0.250
0.271
0.265
108
106
78.0-124
2.24
20
Vinyl chloride
0.250
0.238
0.235
95.2
94.0
67.0-131
1.27
20
(S) Toluene-d8
112
115
80.0-120
(S) 4-Bromofluorobenzene
100
102
77.0-126
(S)1,2-Dichloroethone-d4
91.8
93.4
70.0-130
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 14 of 22

WG1907935 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1522454-01
L1522736-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1522736-01 08/09/22 20:15 • (MS) R3824763-4 08/09/22 20:35 • (MSD) R3824763-5 08/09/22 20:55
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
%
%
%
%
%
Benzene 0.250
NO
0.283
0.284
113
114
1 17.0-158
0.353
27
Carbon tetrachloride 0.250
NO
0.249
0.256
99.6
102
1 23.0-159
2.77
28
Chlorobenzene 0.250
NO
0.297
0.301
119
120
1 33.0-152
1.34
27
Chloroform 0.250
NO
0.279
0.286
112
114
1 29.0-154
2.48
28
1,2-Dichloroethane 0.250
NO
0.262
0.263
105
105
1 29.0-151
0.381
27
1,1-Dichloroethene 0.250
NO
0.281
0.303
112
121
1 11.0-160
7.53
29
2-Butanone (MEK) 1.25
NO
1.19
1.17
95.2
93.6
1 10.0-160
1.69
32
Tetrachloroethene 0.250
NO
0.340
0.344
136
138
1 10.0-160
1.17
27
Trichloroethene 0.250
NO
0.289
0.293
116
117
1 10.0-160
1.37
25
Vinyl chloride 0.250
NO
0.268
0.270
107
108
1 10.0-160
0.743
27
(S) Toluene -dB
113
110
80.0-120
(S) 4-Bromofluorobenzene
103
101
77.0-126
(S)1,2-Dichloroethane-d4
94.6
92.6
70.0-130
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
EMA Resources
L1522454
08/23/22 17:04
15 of 22

WG1909068 QUALITY CONTROL SUMMARY
Semi -Volatile Organic Compounds (LCMS) by Method SW-846 8321 L1522454-01
Method Blank (MB)
(MB) R3825545-2 08/11/22 17:26
MB Result
Analyte
mg/1
2,4-D
U
2,4,5-TP (Silvex)
U
(S) 2,4-DB-D3
130
MB Qualifier MB MDL
MB RDL
mg/1
mg/1
0.00667
0.0200
0.00667
0.0200
70.0-130
Laboratory Control Sample (LCS)
(LCS) R3825545-1 08/11/22 17:08
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/1
mg/1
%
%
2,4-D 0.200
0.180
90.0
70.0-130
2,4,5-TP (Silvex) 0.200
0.178
89.0
70.0-130
(S)2,4-DB-D3
120
70.0-130
L1522684-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1522684-01 08/11/22 21:01 • (MS) R3825545-3 08/11/22 17:44 • (MSD) R3825545-4 08/11/22 18:02
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
Analyte
mg/1
mg/1
mg/1
mg/1
%
%
%
2,4-D
0.200
NO
0.195
0.218
97.5
109
1 70.0-130
2,4,5-TP (Silvex)
0.200
NO
0.192
0.228
96.0
114
1 70.0-130
(S) 2,4-DB-D3
120
139
70.0-130
MS Qualifier MSD Qualifier RPD RPD Limits
11.1 30
17.1 30
J1
ACCOUNT: PROJECT: SDG:
EMA Resources L1522454
DATE/TIME:
08/23/22 17:04
PAGE:
16 of 22

WG1908936
Pesticides (GC) by Method 8081B
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1522454-01
(MB) R3825283-1 08/11/22 11:34
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/1
mg/1
mg/1
Chlordane
U
0.00167
0.00500
Endrin
U
0.00167
0.00500
Heptachlor
U
0.00167
0.00500
Heptachlor epoxide
U
0.00167
0.00500
Gamma BHC
U
0.00167
0.00500
Methoxychlor
U
0.00167
0.00500
Toxaphene
U
0.00333
0.0100
(S) Decachlorobipheny/
63.6
10.0-128
(S) Tetrachloro-m-xylene
60.1
10.0-127
Laboratory Control Sample (LCS)
(LCS) R3825283-2 08/11/22 11:44
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
Analyte
mg/1
mg/1
%
%
Endrin
0.0100
0.00884
88.4
57.0-134
Heptachlor
0.0100
0.00763
76.3
27.0-132
Heptachlor epoxide
0.0100
0.00875
87.5
57.0-130
Gamma BHC
0.0100
0.00822
82.2
55.0-129
Methoxychlor
0.0100
0.00857
85.7
54.0-155
(S) Decachlorobipheny/
69.8
10.0-128
(S) Tetrachloro-m-xylene
55.8
10.0-127
LCS Qualifier
L1522736-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1522736-01 08/11/22 13:50 • (MS) R3825283-6 08/11/22 14:00 • (MSD) R3825283-7 08/11/22 14:10
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/1
mg/1
mg/1
mg/1
%
%
Endrin
0.0100
NO
0.00857
0.00795
85.7
79.5
Heptachlor
0.0100
NO
0.00723
0.00677
72.3
67.7
Heptachlor epoxide
0.0100
NO
0.00842
0.00790
84.2
79.0
Gamma BHC
0.0100
NO
0.00824
0.00768
82.4
76.8
Methoxychlor
0.0100
NO
0.00882
0.00804
88.2
80.4
(S) Decachlorobipheny/
63.5
59.9
(S) Tetrachloro-m-xylene
58.9
51.4
Dilution Rec. Limits
MS Qualifier
MSD Qualifier RPD
RPD Limits
1 10.0-160
P
7.51
39
1 16.0-136
P
6.57
40
1 10.0-160
P
6.37
36
1 14.0-141
P
7.04
40
1 10.0-160
P
9.25
34
10.0-128
10.0-127
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1522454 08/23/22 17:04 17 of 22

WG1908107
QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds
(GC/MS) by
Method 8270E
L1522454-01
Method Blank (MB)
(MB) R3825387-2 0 8/11/2 2 12:2 4
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte mg/1
mg/1
mg/1
1,4-Dichlorobenzene U
0.0333
0.100
2,4-Dinitrotoluene U
0.0333
0.100
FSS
Hexachlorobenzene U
0.0333
0.100
Hexachloro-1,3-butadiene U
0.0333
0.100
Hexachloroethane U
0.0333
0.100
rcn]
Nitrobenzene U
0.0333
0.100
Pyridine U
0.0333
0.100
FSr
3&4-Methyl Phenol U
0.0333
0.100
2-Methylphenol U
0.0333
0.100
Pentachlorophenol U
0.0333
0.100
2,4,5-Trichlorophenol U
0.0333
0.100
2,4,6-Trichlorophenol U
0.0333
0.100
7G�
(S) 2-Fluorophenol 33.3
10.0-120
(S) Phenol-d5 24.5
10.0-120
(S) Nitrobenzene-d5 54.8
10.0-127
FAI
(S) 2-Fluorobiphenyl 50.2
10.0-130
(S) 2,4, 6-Tribromophenol 68.0
10.0-155
ISCI
(S) p-Terphenyl-d14 62.2
10.0-128
Laboratory Control Sample (LCS)
(LCS) R3825387-1 08/11/22 12:02
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/1
mg/1
%
%
1,4-Dichlorobenzene 0.500
0.209
41.8
18.0-120
2,4-Dinitrotoluene 0.500
0.352
70.4
49.0-124
Hexachlorobenzene 0.500
0.318
63.6
44.0-120
Hexachloro-1,3-butadiene 0.500
0.273
54.6
19.0-120
Hexachloroethane 0.500
0.221
44.2
15.0-120
Nitrobenzene 0.500
0.279
55.8
27.0-120
Pyridine 0.500
0.0312
6.24
10.0-120 J4
3&4-Methyl Phenol 0.500
0.247
49.4
31.0-120
2-Methylphenol 0.500
0.221
44.2
28.0-120
Pentachlorophenol 0.500
0.306
61.2
23.0-120
2,4,5-Trichlorophenol 0.500
0.335
67.0
44.0-120
2,4,6-Trichlorophenol 0.500
0.324
64.8
42.0-120
(S) 2-Fluorophenol
30.5
10.0-120
(S) Phenol-d5
28.5
10.0-120
(S) Nitrobenzene-d5
57.5
10.0-127
ACCOUNT:
PROJECT: SDG: DATE/TIME:
PAGE:
EMA Resources
L1522454 08/23/22 17:04
18 of 22

WG1908107 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1522454-01
Laboratory Control Sample (LCS)
(LCS) R3825387-1 08/11/22 12:02
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/I mg/I % %
(S) 2-Fluorobiphenyl 54.8 10.0-130
(S) 2,4,6-Tribromophenol 73.5 10.0-155
(S) p-Terphenyl-dM 64.9 10.0-128
L1522736-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1522736-01 08/11/22 17:06 • (MS) R3825387-3 08/11/2217:28 • (MSD) R3825387-4 08/11/22 17:50
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte
mg/I
mg/I
mg/I
mg/I
%
%
%
%
%
1,4-Dichlorobenzene
0.500
NO
0.151
0.173
30.2
34.6
1 17.0-120
13.6
40
2,4-Dinitrotoluene
0.500
NO
0.282
0.315
56.4
63.0
1 39.0-125
11.1
25
Hexachlorobenzene
0.500
NO
0.240
0.257
48.0
51.4
1 35.0-122
6.84
24
Hexachloro-1,3-butadiene
0.500
NO
0.193
0.233
38.6
46.6
1 12.0-120
18.8
34
Hexachloroethane
0.500
NO
0.161
0.188
32.2
37.6
1 10.0-120
15.5
40
Nitrobenzene
0.500
NO
0.221
0.240
44.2
48.0
1 12.0-120
8.24
30
Pyridine
0.500
NO
NO
ND
0.000
0.000
1 10.0-120
J6 J6 0.000
37
3&4-Methyl Phenol
0.500
NO
0.185
0.223
37.0
44.6
1 10.0-120
18.6
36
2-Methylphenol
0.500
NO
0.160
0.198
32.0
39.6
1 10.0-120
21.2
30
Pentachlorophenol
0.500
NO
0.255
0.277
51.0
55.4
1 10.0-128
8.27
37
2,4,5-Trichlorophenol
0.500
NO
0.251
0.289
50.2
57.8
1 33.0-120
14.1
31
2,4,6-Trichlorophenol
0.500
NO
0.245
0.275
49.0
55.0
1 26.0-120
11.5
31
(S) 2-Fluorophenol
22.0
26.6
10.0-120
(S) Phenobd5
20.2
24.7
10.0-120
(S) Nitrobenzene-d5
43.0
49.5
10.0-127
(S) 2-Fluorobiphenyl
40.3
47.5
10.0-130
(S)2,4,6-Tribromophenol
57.0
61.5
10.0-155
(S) p-Terphenyl-dM
50.2
55.5
10.0-128
ACCOUNT: PROJECT:
EMA Resources
SDG: DATE/TIME: PAGE:
L1522454 08/23/22 17:04 19 of 22

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND Not detected at the Reporting Limit (or MDL where applicable).
RDL Reported Detection Limit.
Rec. Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
(S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J1
Surrogate recovery limits have been exceeded; values are outside upper control limits.
J4
The associated batch QC was outside the established quality control range for accuracy.
J6
The sample matrix interfered with the ability to make any accurate determination; spike value is low.
P
RPD between the primary and confirmatory analysis exceeded 40%.
Q
Sample was prepared and/or analyzed past holding time as defined in the method. Concentrations should be
considered minimum values.
T8
Sample(s) received past/too close to holding time expiration.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1522454 08/23/22 17:04 20 of 22

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
NE-05-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey —NE LAP
TNO02
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704
Georgia
NELAP
North Carolina'
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhodelsland
LA000356
Kentucky''
KY90010
South Carolina
84004002
Kentucky'
16
South Dakota
n/a
Louisiana
A130792
Tennessee' °
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas'
1-AB0152_
Maryland
324
Utah
TNO_00032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A21-A
A21-A— 150 17025
1461.01
AIHA-LAP,LLC EM LAP
100789
A21-A — IS017025'
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
' Drinking Water ' Underground Storage Tanks 3 Aquatic Toxicity ° Chemical/Microbiological 'Mold 'Wastewater n/a Accreditation not applicable
*Not all certifications held by the laboratory are applicable to the results reported in the attached report.
*Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
ACCOUNT: PROJECT: S DG: DATE/TIME:
EMA Resources L1522454 08/23/22 17:04
PAGE:
21 of 22

Company Name/Address:
Billing Information:
EMA Resources
Mr. Brent Collins Pres
755 Yadkinville Road Chk
755 Yadkinville Road
Mocksville, NC 27028
Mocksville, NC 27028
Report to:
Email To:
Mr. Brent Collins
[e-mail];roy.whit ak
^
Project Description
City/State
//
Re.
Please Circle:
PT MT CT ET
Sludge
Collected: ¢svdile�XVG
Phone [phone]
Client Project It
lab Prolect4
Collected by (print
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Packed on Ice N _ Y
Sample ID
` Matrix:
SS - Soil AIR - Air F - Filter
GW - Groundwater B - Bioassay
WW - WasteWater
DW - Drinking Water
OT - Other
Relinquished by : (Signature)
Relinquished by : (Signature)
a
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P.O. N
in Oil
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Date: Time- Received by: (5 gnature)
5d hz'
Date: Time. Received by (Signature)
Relinquished by : (Signature) JDate: (Time IReceived for lab by -
Chain of Custody Page _ of
ace Analytical
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Acctnum: EMARES
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ICOC Signed'Accurate:
NP 64,14
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arrive :t€ta-t:
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Su€€:C_er,E 'volume sent:
iJY' N
N
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1 l5 1VCA
Zero Y N
'=eeervat4nn -:o:rFcl:JChackrd: Y N
Trip Blank Received Yes
fNleoN
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RAD 8cre2n 0.5 rr.R; hr:
t� N
TBR
Temp:Q jrVeC Bottles Receved
if preservation required by login: Date/Time
w
Date
Hold-
Conditi?'
(+Time
e// </7� ;.' 4c,
NCF / V
I

8/3/2022
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 1440 12.8448 23 0.55847
Calcium 4300 38.356 20 1.9178
Magnesium 761 6.78812 12 0.565677
Percent Solids 0.892
SAR 0.50
SAR = Na+
a (Ca2+ + Mg2+)
0.55847
0.5( 1.9178 2 + 0.56568 2 )

2022 Reidsville WTP Annual Report -
WQ0032723
Final Audit Report
Created: 2023-02-08
By: Brent Collins ([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAAvthBBV1p7pYTfHDjW1Sk9f9hnG1gdmFd
2023-02-10
"2022 Reidsville WTP Annual Report - WQ0032723" History
Document created by Brent Collins ([e-mail])
2023-02-08 - 4:28:18 PM GMT- IP address: 206.85.202.26
P+ Document emailed to [e-mail] for signature
2023-02-08 - 4:29:23 PM GMT
Email viewed by [e-mail]
2023-02-08 - 4:47:34 PM GMT- IP address: 174.210.68.109
Signer [e-mail] entered name at signing as W. Blake Slaughter
2023-02-10 - 5:48:21 PM GMT- IP address: 12.234.212.82
-0u Document e-signed by W. Blake Slaughter ([e-mail])
Signature Date: 2023-02-10 - 5:48:23 PM GMT - Time Source: server- IP address: 12.234.212.82
Agreement completed.
2023-02-10 - 5:48:23 PM GMT
0 Adobe Acrobat Sign

2022 Reidsville WTP Annual Report -
WQ0032723
Final Audit Report
Created: 2023-02-10
By: Brent Collins([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAAbvYs10sU-Xjk5xYJ5a8kLNUZ6gV8dgFM
2023-02-10
"2022 Reidsville WTP Annual Report - WQ0032723" History
Document created by Brent Collins([e-mail])
2023-02-10 - 5:55:20 PM GMT- IP address: 206.85.202.26
2+ Document emailed to [e-mail] for signature
2023-02-10 - 5:56:10 PM GMT
Email viewed by [e-mail]
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&0 Signer [e-mail] entered name at signing as Summer Woodard
2023-02-10 - 9:24:42 PM GMT- IP address: 12.234.212.82
&0 Document e-signed by Summer Woodard ([e-mail])
Signature Date: 2023-02-10 - 9:24:44 PM GMT - Time Source: server- IP address: 12.234.212.82
0 Agreement completed.
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