WQ0021828_2022 Residual Annual Report_20230228 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * W00021828
Applicant/Permittee Orange Water And Sewer Authority
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Raleigh
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Wilmer Lawson
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
9195374351
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0021828
Has Current Existing permit number
Applicant/Permittee Address*
400 Jones Ferry rd, Carrboro NC 27510
Facility Name*
OWASA Class A Residuals Program
Please provide comments/notes on your current submittal below.
Attached is the 2022 OWASA Class A annual land application biosolids report. Permit number WQ0021828
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Class A Biosolids Annual Report.pdf 8.74MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
JUl�rrt ,,�irroN
Submission Date 2/28/2023

Orange Water and Sewer Authority
OWASA is Carrboro-Chapel Hill's not -for -profit public service agency
delivering high quality water, wastewater, and reclaimed water services.
February 27, 2023
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
SUBJECT: ANNUAL LAND APPLICATION — BIOSOLIDS REPORT 2022
NON -DISCHARGE PERMIT NO. WQ0021828
MASON FARM WASTEWATER TREATMENT PLANT
ORANGE WATER & SEWER AUTHORITY - CHAPEL HILL, NC
The Orange Water and Sewer Authority (OWASA) owns and operates the Mason Farm
Wastewater Treatment Plant located in Chapel Hill, North Carolina (NC). This facility serves
the Chapel Hill, Carrboro communities including the University of North Carolina at Chapel
Hill; all of which are located in southeastern Orange County. The plant discharge is regulated by
NPDES Permit NC0025241. The Class A land application program is regulated by Non -
Discharge (Permit No. WQ0021828) issued by the State of North Carolina Department of
Environmental Quality - Division of Water Resources.
This report documents that the biosolids generated during calendar year 2022 are in compliance
with 40 CFR Part 503 Federal Regulations, 15A NCAC 2T rules. All biosolids produced during
the 2022 calendar year were of Class A quality, therefore no Class B was land applied.
If there are any questions regarding this submittal, please contact me at your convenience.
Sincerely,
Wilmer Lawson
Wastewater Treatment and Biosolids Recycling Manager
cc: file
400 Jones Ferry Road, Carrboro, NC 275 10 0 919-968-4421 (D [e-mail] 0 @OWASAI a www.owasa.org

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0021828 County: Orange Year:
2022
Facility Name (as shown on permit): Orange Water & Sewer Authority
Land Application Operator: Dylan Bowers Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
M Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in thepermit:
91
Total number of fields utilized for land application during the year:
41
Total amount of dry tons applied during the year for all application sites:
536.13
Total number of acres utilizes for land application during the year:
1724.18
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. a Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Wastewater Treatment &
Wilmer Lawson Biosolids Recycling Manager
Permittee Name and Title (type or print)
Signature of Preparer*
Date
02/27/2023
Signature of Pennittee Date
of Land Applier
02/28/2023
Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ORANGE WATER & SEWER
AUTHORITY
Mason Farm Wastewater Treatment Plant
NPDES Permit # NCO025241
2022 Annual Land Application Report
Land Application Permit
Class -A Permit # WQ0021828

OWASA Mason Farm Wastewater Treatment Plant
Anaerobic Digestion Process
Summary Information Calendar Year 2022
The Mason Farm Wastewater Treatment Plant Anaerobic Digestion Process provides treatment for both
primary and waste activated sludges in a four -stage digestion process. The four anaerobic digestion tanks
provide approximately 1,800,000 gallons of digestion capacity and are operated in series. Normally the first
three anaerobic digesters are maintained in the thermophilic temperature range, in excess of 1250 F and the
fourth anaerobic digester is operated in the mesophilic temperature range, less then 115' Fahrenheit. For the
2022 calendar year, the average temperature and time for biosolids processed through the Class A
thermophilic process was 139.61 F and 11 hours. The digester operation -temperatures, recirculation and
mixing rates are monitored continuously, in addition to gas production. Process control testing (VA/ALK
ratios, pH and alkalinity, etc.) is checked routinely. Transfers into and out of the various digester tanks are
monitored and recorded.
The Mason Farm Wastewater Treatment Plant anaerobic digestion operating conditions have been carefully
monitored for the period of January 1, 2022 through December 31, 2022. The review confirms the following:
Average daily wastewater flow 7.2 MGD
Average daily dry tons biosolids recycled 3.0 Dry Tons
Average volatile solids reduction thru anaerobic digestion 60.1%
Average anaerobic (total) digestion time 40 Days
FECAL COLIFORM
JAN-FEB
MAR -APR
MAY-JUN
JUL-AUG
SEP-OCT
NOV-DEC
Class A max
93
107
89
81
87
98
Class A avg
21
36
29
27
49
21
PARAMETER
JAN-FEB
MAR -APR
MAY-JUN
JUL-AUG
SEP-OCT
NOV-DEC
Percent Solids (%)
2.03
1.6
1.95
2.20
2.60
2.01
Arsenic (As)
<2.46
3.43
15.4
<4.55
4.27
<4.98
Cadmium (Cd)
1.13
0.94
5.13
1.09
1.02
0.0891
Copper(Cu)
223
251
166
163
302
257
Lead (Pb)
<2.46
20.5
13.3
12
11.7
11.6
Mercury (Hg)
.00985
0.01
0.108
<0.0182
0.0231
0.0383
Molybdenum (Mo)
5.12
5.84
20.5
<2.27
5.27
<2.49
Nickel (Ni)
11.4
14.4
10.3
10.0
14
15.1
Selenium (Se)
5.37
3.93
20.5
<4.55
6
<4.98
Zinc (Zn)
788
756
518
750
781
990
Aluminum
87700
49,500
31,800
44,000
52,700
56,200
Calcium
17389
19,400
13,700
17,500
17,700
24,900
Magnesium
5172
5,750
3,910
4,860
4,920
7,010
Potassium
8966
8,000
6,140
7,180
7,620
10,700
Sodium
5420
7,000
4,250
5,680
5,460
7,960
SAR
1.321
1.435
1.151
1.452
1.509
1.628

ORANGE WATER AND SEWER AUTHORITY (OWASA)
MASON FARM WASTEWATER TREATMENT PLANT
SIMPLIFIED ANAEROBIC DIGESTION PROCESS FLOW SCHEMATIC
Primary Sludge & Waste Activated Sludge
RDT = ROTARY DRUM THICKENER
RDT RDT
#1 #2
(COLD, THICKENED SLUDGE TO DIGESTION)
n
1 ST STAGE TEMPERATURE RANGE
(THERMOPHILIC TEMPERATURE) ANAEROBIC 135 F - 140 F
[DIGESTER #4 CONTINUOUS OR BATCH FEED,
HEAT EXCHANGER & BATCH DISCHARGE
RECIRCULATION PUP M
2nd STAGE TEMPERATURE RANGE
(THERMOPHILIC TEMPERATURE) ANAEROBIC 135 F - 140 F
DIGESTER #3 BATCH FEED & DISCHARGE,
HEAT EXCHANGER & HOLD BATCH - REQ'D. HOURS
RECIRCULATION PUMP
EPA 503 TIME & TEMPERATURE
REQUIREMENTS MET IN THIS TANK
40 CFR Part 503.32-3ii.D.
3rd STAGE TEMPERATURE RANGE
(THERMOPHILIC TEMPERATURE) ANAEROBIC 115 F - 125 F
DIGESTER #2 BATCH FEED, NEAR
HEAT EXCHANGER & CONTINUOUS DISCHARGE
RECIRCULATION PUMP
4th STAGE
(MESOPHILIC TEMPERATURE) ANAEROBIC TEMPERATURE RANGE
DIGESTER #1 < 115 F
HEAT EXCHANGER & CONTINUOUS FEED,
RECIRCULATION PUMP BATCH DISCHARGE STORAGE
TANK
#1
STORAGE
BIOSOLIDS TO IN -PLANT TANK
STORAGE TANKS #2
LIQUID BIOSOLIDS TO:
LAND APPLICATION or
OFFSITE STORAGE
DEWATERED BIOSOLIDS TO:
COMMERCIAL COMPOST FACILITY

TABLE OF CONTENTS
SECTION NO. TITLE
Class A Distribution and Marketing / Surface
Disposal Certification Forms
Form DMSDF
II Annual Residual Sampling Summary Forms
Form RSSF
III Annual Pathogen and Vector Attraction
Reduction Form (503) Rules
Form PVRF 503
IV Lab Sheets
Analytical Data

Section I
Class A Distribution and Marketing /
Surface Disposal Certification Forms

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0021828 FACILITY NAME: Orange Water & Sewer Authority
PHONE: [phone] COUNTY: ORANGE OPERATOR: Dylan Bowers
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
0 Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes 0 No ❑ 0 If No skip parts A, B, C and certify form below
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
Mason Farm WWTP NCO025241
48.58
McGill Environmental Inc
48.58
Composting
February
Mason Farm WWTP NCO025241
58.1
McGill Environmental Inc
58.1
Composting
March
Mason Farm WWTP NCO025241
66.66
McGill Environmental Inc
66.66
Composting
April
Mason Farm WWTP NCO025241
33.36
McGill Environmental Inc
33.36
Composting
May
Mason Farm WWTP NCO025241
23.11
McGill Environmental Inc
23.11
Composting
June
Mason Farm WWTP NCO025241
16.22
McGill Environmental Inc
16.22
Composting
July
Mason Farm WWTP NCO025241
46.76
McGill Environmental Inc
46.76
Composting
August
Mason Farm WWTP NCO025241
50.7
McGill Environmental Inc
50.7
Composting
September
Mason Farm WWTP NCO025241
50.75
McGill Environmental Inc
50.75
Composting
October
Mason Farm WWTP NCO025241
58.66
McGill Environmental Inc
58.66
Composting
November
Mason Farm WWTP NCO025241
51.1
McGill Environmental Inc
51.1
Composting
December
Mason Farm WWTP NCO025241
69.46
McGill Environmental Inc
69.46
Composting
Total from FORM DMSDF (sup)
Totals:
Annual (dry tons):
0
0
573.46
573.46
Amendments used: I I Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit p Yes
(including but not limited to items 1-3 below) issued by the Division of Water Resources: ❑ No lo If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
WG��`YLQ , x. 02/27/2023
Signature of Pennittee Date
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Signature of Preparer**
(if different from Permittee)
Date
DENR FORM DMSDF (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0021828 FACILITY NAME: Orange Water & Sewer Authority
PHONE: [phone] COUNTY: ORANGE OPERATOR: Dylan Bowers
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
❑ Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes 0 No ❑ 0 If No skip parts A, B, C and certify form below
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
Mason Farm WWTP NCO025241
2.39
Phillips
2.39
Land Applied
February
Mason Farm WWTP NCO025241
10.54
Phillips
10.54
Land Applied
March
Mason Farm WWTP NCO025241
27.8
OWASA 11
27.8
Land Applied
April
Mason Farm WWTP NCO025241
30.3
Lemons
30.3
Land Applied
May
Mason Farm WWTP NCO025241
20.6
Pope
20.6
Land Applied
June
Mason Farm WWTP NCO025241
66
Pope
66
Land Applied
July
Mason Farm WWTP NCO025241
41.8
OWASA 11
41.8
Land Applied
August
Mason Farm WWTP NCO025241
12.6
OWASA 11
12.6
Land Applied
September
Mason Farm WWTP NCO025241
16.2
OWASA 5
16.2
Land Applied
October
Mason Farm WWTP NCO025241
21.1
Phillips
21.1
Land Applied
November
Mason Farm WWTP NCO025241
26.7
Phillips
26.7
Land Applied
December
Mason Farm WWTP NCO025241
Total from FORM DMSDF (sup)
0
0
260.1
260.1
Totals:
Annual (dry tons):
0
0
536.13
536.13
Amendments used: I I Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit p Yes
(including but not limited to items 1-3 below) issued by the Division of Water Resources: ❑ No lo If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
U)Z&Z/Z.02/27/2023
Signature of Pennittee Date
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Signature of Preparer**
(if different from Permittee)
Date
DENR FORM DMSDF (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Supplemental Information
WQ PERMIT #: WQ0021828 FACILITY NAME: Orange Water & Sewer Authority
PHONE: [phone] COUNTY: Orange OPERATOR: Dylan Bowers
FACILITY TYPE (please check one): 0 Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
❑ Distribution and Marketing (complete Parts A, and B)
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry
tons)
Intended use(s)
FebaLLry
Mason Farm WWTP NCO025241
5.5
OWASA 11
5.5
Land Applied
March
Mason Farm WWTP NCO025241
17.4
OWASA 5
17.4
Land Applied
March
Mason Farm WWTP NCO025241
4.8
Warren Ray
4.8
Land Applied
March
Mason Farm WWTP NCO025241
23.9
Phillips
23.9
Land Applied
April
Mason Farm WWTP NCO025241
10.8
Strayhorn
10.8
Land Applied
April
Mason Farm WWTP NCO025241
1.7
Warren Ray
1.7
Land Applied
April
Mason Farm WWTP NCO025241
15.7
Sockwell
15.7
Land Applied
April
Mason Farm WWTP NCO025241
10
Andrews
10
Land Applied
May
Mason Farm WWTP NCO025241
36
Strayhorn
36
Land Applied
June
Mason Farm WWTP NCO025241
9.5
Strayhorn
9.5
Land Applied
July
Mason Farm WWTP NCO025241
4.8
Strayhorn
4.8
Land Applied
August
Mason Farm WWTP NCO025241
9.6
OWASA 5
9.6
Land Applied
August
Mason Farm WWTP NCO025241
22.1
Phillips
22.1
Land Applied
September
Mason Farm WWTP NCO025241
62.7
Phillips
62.7
Land Applied
November
Mason Farm WWTP NCO025241
20.7
OWASA 11
20.7
Land Applied
November
Mason Farm WWTP NCO025241
4.9
Thompson
4.9
Land Applied
Mason Farm WWTP NCO025241
Totals:
Annual (dry tons):
0
0
260.1 260.1
Amendment(s) used-7 Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)
DENR FORM DMSDF (Supp) (12/2006)

Section II
Annual Residual Sampling Summary
Forms

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0001169 (B) and WQ0021828 (A)
Facility Name: Orange Water & Sewer Authority
Residual Source WQ # or
NPDES #:
NCO025241
WWTP Name: Mason Farm WWTP
Residual Analysis Data
Laboratory: 1) Pace Analytical
2) OWASA WWTP Lab
3) Meritech, Inc
4)
5)
Parameter
aramet)
Conc.
Limit
m /k a
Sample or Composite Date
01/18/22
03/07/22
05/09/22
07/18/22
09/12/22
11/07/22
Percent Solids (%)
NA
2.03
1.6
1.95
2.2
2.6
2.01
Arsenic
75
<2.46
3.43
15.4
<4.55
4.27
<4.98
Cadmium
85
1.13
0.94
5.13
1.09
1.02
0.0891
Copper
4,300
223
251
166
163
302
257
Chromium
NA
NA
NA
NA
NA
I NA
NA
Lead
840
<2.46
20.5
13.3
12
11.7
11.6
Mercury
57
0.06
0.01
0.108
<0.0182
0.0231
0.0383
Molybdenum
75
5.12
5.84
20.5
<2.27
5.27
<2.49
Nickel
420
11.4
14.4
10.3
10
14
15.1
Selenium
100
5.27
3.93
20.5
<4.55
6
<4.98
Zinc
7,500
788
756
518
750
781
990
Total Phosphorus
NA
75,862
227,000
47,100
44,500
44,200
58,200
TKN
NA
93,103
85,900
135,000
81,400
94,600
125,000
Ammonia -Nitrogen
NA
42,562
62,800
122,000
51,400
58,800
103,000
Nitrate and Nitrite
NA
493
241
40
77
54
33
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer
02/27/2023
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0001169 (B) WQ0021828 (A)
Facility Name: Orange Water & Sewer Authority
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analysis Data
NCO025241
Mason Farm WWTP
Laboratory: 1) Pace Analytical
2) Meritech
3) OWASA Lab
4)
5)
Parameter
(mg/kg)
Sample or Composite Date
01/18/22
03/07/22
05/09/22
07/18/22
09/12/22
11/07/22
Aluminum
87,700
49,500
31,800
44,000
52,700
56,200
Calcium
17,389
19,400
13,700
17,500
17,700
24,900
Magnesium
5,172
5,750
3,910
4,860
4,920
7,010
Potassium
8,966
8,000
6,140
7,180
7,620
10,700
Sodium
5,420
7,000
4,250
5,680
5,460
1 7,960
SAR
1.321
1.435
1.151
1.452
1.509
1.628
PAN
64
73
127
64
73
112
pH
*See Lab
Sheets for
pH Results*
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
(i( )AW,V 2. x. )y 02/27/2023
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

Section III
Annual Pathogen and Vector Attraction
Reduction Form (503) Rules

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Orange Water & Sewer Authority WQ Permit Number: WQ0021828
WWTP Name: Mason Farm Wastewater Treatment Plant
NPDES Number: NCO025241
Monitoring Period: From l/l/2022 To 2/28/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 El
Alternative 2 ❑
Alternative 3 ❑
Alternative 4 ❑
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
F Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly
Reduce Pathogens":
Lime Stabilization ❑
Air Drying❑ I Composting ❑ jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the
following monitoring data:
Allowable Level
Pathogen Density
Number of
Frequency
Sample
Analytical
Parameter
in Sludge
g
Excee-
of Analysis
y
Type
Tech-
Minimu
Geo. Mean
aximu
Units
deuces
ni ue
2 x 10 to the
MPN
6th power
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
MPN/
Bi-
SM
of total solid (dry
6
13
93
0
Grab
weight)
FC/G
Monthly
9221 E
Salmonella bacteria
3 MPN per 4 grams
(in lieu of fecal
total solid (dry
coliform)
weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Alt.1 (VS reduction) El
Alt. 2 (47day bench) ❑
Alt. 3 (30-day bench) ❑Alt.
4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Wilmer Lawson- WWTPBR Manager Dylan Bowers-Biosolids Recycling Supervisor
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
02/27/2023 D 5&t,� 02/28/2023
Signature of Preparer* Date Si ature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Orange Water & Sewer Authority WQ Permit Number: WQ0021828
WWTP Name: Mason Farm Wastewater Treatment Plant
NPDES Number: NCO025241
Monitoring Period: From 3/l/2022 To 4/30/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 El
Alternative 2 ❑
Alternative 3 ❑
Alternative 4 ❑
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
F Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly
Reduce Pathogens":
Lime Stabilization ❑
Air Drying❑ I Composting ❑ jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the
following monitoring data:
Allowable Level
Pathogen Density
Number of
Frequency
Sample
Analytical
Parameter
in Sludge
g
Excee-
of Analysis
y
Type
Tech-
Minimu
Geo. Mean
aximu
Units
deuces
ni ue
2 x 10 to the
MPN
6th power
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
MPN/
Bi-
SM
of total solid (dry
<8
21
107
0
Grab
weight)
FC/G
Monthly
9221 E
Salmonella bacteria
3 MPN per 4 grams
(in lieu of fecal
total solid (dry
coliform)
weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Alt.1 (VS reduction) El
Alt. 2 (47day bench) ❑
Alt. 3 (30-day bench) ❑Alt.
4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Wilmer Lawson- WWTPBR Manager Dylan Bowers- Biosolids Recycling Supervisor
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
02/27/2023 02/28/2023
Signature of Preparer* Date SignAure of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Orange Water & Sewer Authority WQ Permit Number: WQ0021828
WWTP Name: Mason Farm Wastewater Treatment Plant
NPDES Number: NCO025241
Monitoring Period: From 5/l/2022 To 6/30/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 El
Alternative 2 ❑
Alternative 3 ❑
Alternative 4 ❑
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
F Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly
Reduce Pathogens":
Lime Stabilization ❑
Air Drying❑ I Composting ❑ jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the
following monitoring data:
Allowable Level
Pathogen Density
Number of
Frequency
Sample
Analytical
Parameter
in Sludge
g
Excee-
of Analysis
y
Type
Tech-
Minimu
Geo. Mean
aximu
Units
deuces
ni ue
2 x 10 to the
MPN
6th power
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
MPN/
Bi-
SM
of total solid (dry
<8
19
gg
0
Grab
weight)
FC/G
Monthly
9221 E
Salmonella bacteria
3 MPN per 4 grams
(in lieu of fecal
total solid (dry
coliform)
weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Alt.1 (VS reduction) El
Alt. 2 (47day bench) ❑
Alt. 3 (30-day bench) ❑Alt.
4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Wilmer Lawson- WWTPBR Manager Dylan Bowers- Biosolids Recycling Supervisor
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
a)4&Q,& 4•Z-G-Gt/, e" 02/27/2023 D�1 a� � 02/28/2023
Signature of Preparer* Date Sign ure of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Orange Water & Sewer Authority WQ Permit Number: WQ0021828
WWTP Name: Mason Farm Wastewater Treatment Plant
NPDES Number: NCO025241
Monitoring Period: From 7/l/2022 To 8/31/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 El
Alternative 2 ❑
Alternative 3 ❑
Alternative 4 ❑
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
F Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly
Reduce Pathogens":
Lime Stabilization ❑
Air Drying❑ I Composting ❑ jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the
following monitoring data:
Allowable Level
Pathogen Density
Number of
Frequency
Sample
Analytical
Parameter
in Sludge
g
Excee-
of Analysis
y
Type
Tech-
Minimu
Geo. Mean
aximu
Units
deuces
ni ue
2 x 10 to the
MPN
6th power
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
MPN/
Bi-
SM
of total solid (dry
<7
16
81
0
Grab
weight)
FC/G
Monthly
9221 E
Salmonella bacteria
3 MPN per 4 grams
(in lieu of fecal
total solid (dry
coliform)
weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Alt.1 (VS reduction) El
Alt. 2 (47day bench) ❑
Alt. 3 (30-day bench) ❑Alt.
4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Wilmer Lawson- WWTPBR Manager
Preparer Name and Title (type or print)
Signature of Preparer*
02/27/2023
Date
Dylan Bowers- Biosolids Recycling Supervisor
Land Applier Name and Title (if applicable)(type or print)
Sig ture of Land Applier (if applicable)
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM PVRF 503 (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Orange Water & Sewer Authority WQ Permit Number: WQ0021828
WWTP Name: Mason Farm Wastewater Treatment Plant
NPDES Number: NCO025241
Monitoring Period: From 9/l/2022 To 10/31/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 El
Alternative 2 ❑
Alternative 3 ❑
Alternative 4 ❑
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
F Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly
Reduce Pathogens":
Lime Stabilization ❑
Air Drying❑ I Composting ❑ jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the
following monitoring data:
Allowable Level
Pathogen Density
Number of
Frequency
Sample
Analytical
Parameter
in Sludge
g
Excee-
of Analysis
y
Type
Tech-
Minimu
Geo. Mean
aximu
Units
deuces
ni ue
2 x 10 to the
MPN
6th power
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
MPN/
Bi-
SM
of total solid (dry
<7
32
87
0
Grab
weight)
FC/G
Monthly
9221 E
Salmonella bacteria
3 MPN per 4 grams
(in lieu of fecal
total solid (dry
coliform)
weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Alt.1 (VS reduction) El
Alt. 2 (47day bench) ❑
Alt. 3 (30-day bench) ❑Alt.
4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Wilmer Lawson- WWTPBR Manager Dylan Bowers- Biosolids Recycling Supervisor
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
u)4&Z'& 4- L—,u � e, 02/27/2023 T71 Udury�t� 02/28/2023
Signature of Preparer* Date Sig ture of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Orange Water & Sewer Authority WQ Permit Number: WQ0021828
WWTP Name: Mason Farm Wastewater Treatment Plant
NPDES Number: NCO025241
Monitoring Period: From l l/l/2022 To 12/31/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 El
Alternative 2 ❑
Alternative 3 ❑
Alternative 4 ❑
Alternative 5 ❑
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
F Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly
Reduce Pathogens":
Lime Stabilization ❑
Air Drying❑ I Composting ❑ jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the
following monitoring data:
Allowable Level
Pathogen Density
Number of
Frequency
Sample
Analytical
Parameter
in Sludge
g
Excee-
of Analysis
y
Type
Tech-
Minimu
Geo. Mean
aximu
Units
deuces
ni ue
2 x 10 to the
MPN
6th power
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
MPN/
Bi-
SM
of total solid (dry
<8
13
98
0
Grab
weight)
FC/G
Monthly
9221 E
Salmonella bacteria
3 MPN per 4 grams
(in lieu of fecal
total solid (dry
coliform)
weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Alt.1 (VS reduction) El
Alt. 2 (47day bench) ❑
Alt. 3 (30-day bench) ❑Alt.
4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Wilmer Lawson- WWTPBR Manager Dylan Bowers- Biosolids Recycling Supervisor
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
02/27/2023 5e64,t� 02/28/2023
Signature of Preparer* Date Sign re of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

Section IV
Lab Sheets

OWASA MASON FARM WWTP - DIGESTION PROCESS OPERATING SUMMARY
AVERAGE MONTHLY OPERATING TEMPERATURES & RETENTION TIMES
CALENDAR YEAR 2022
DIGESTER 4
DIGESTER 3
DIGESTER 2
DIGESTER 1
COMBINED
AVG TEMP
HRT
AVG TEMP
HRT
AVG TEMP
HRT
AVG TEMP
HRT
AVG TEMP
HRT
F°
DAYS
F°
DAYS
F°
DAYS
F°
DAYS
F°
DAYS
2022
Jan-22
138.9
8.2
138.9
7.9
124.7
7.6
108.1
16.1
127.7
39.8
Feb-22
139.4
9.9
139.4
7.0
125.8
6.7
111.7
14.3
129.1
37.9
Mar-22
139.5
14.6
138.6
8.6
128.1
6.3
114.6
13.7
130.2
43.1
Apr-22
139.8
18.1
123.9
6.2
114.6
13.7
126.1
37.9
May-22
139.7
14.0
128.3
11.9
115.2
21.4
127.7
47.2
Jun-22
139.8
12.7
131.6
7.1
118.5
17.9
130.0
37.7
Jul-22
139.8
15.9
130.5
8.9
120.8
19.1
150.0
43.9
Aug-22
139.9
12.9
129.4
8.5
120.6
17.8
130.0
39.2
Sep-22
139.8
12.0
128.6
7.6
120.3
17.1
134.2
36.8
Oct-22
139.7
16.1
126.7
8.8
115.0
18.9
127.4
43.8
Nov-22
140.0
15.5
126.9
7.8
113.2
16.7
126.6
40.0
Dec-22
139.8
14.4
125.8
7.8
110.3
17.8
125.1
40.1
AVG
139.7
13.7
139.0
7.8
127.5
8.1
115.2
17.0
130.3
40.6
MAX
140.0
18.1
139.4
8.6
131.6
8.9
120.8
21.4
150.0
47.2
MIN
138.9
8.2
138.6
7.0
123.9
7.1
108.1
13.7
125.1
36.8
*Digester 3 was taken out of service for cleaning and rehab mid -March*

Jan-22
Feb-22
Mar-22
Apr-22
May-22
Jun-22
J u I-22
Aug-22
Sep-22
Oct-22
Nov-22
Dec-22
FWAXWO
MAX
MIN
OWASA MASON FARM WWTP - DIGESTER RETENTION TIME
DIGESTER 4
Cap. = 570,000 GALS.
(Esti Use 85%Cap.)
IN \ OUT RETENTION
GALS. DAYS
59,003
8.2
49,179
9.9
33,274
14.6
26,827
18.1
34,680
14.0
38,072
12.7
30,379
15.9
37,663
12.9
40,429
12.0
30,099
16.1
31,330
15.5
33,606
14.4
37,045
13.7
59,003
18.1
26,827
8.2
Dig4 out
*Digester 3 was
DIGESTER 3
Cap. = 310,000 GALS.
(Esti Use 85%Cap.)
IN \ OUT RETENTION
GALS. DAYS
33,509 7.9
37,621 7.0
30,609 8.6
33,913 7.8
37,621 8.6
30,609 7.0
Dig3 out
taken out of service for cIE
DIGESTER 2
Cap. = 310,000
GALS.
(Esti Use 85%Cap.)
IN \ OUT
RETENTION
GALS.
DAYS
34,773
7.6
39,213
6.7
42,156
6.3
42,682
6.2
22,187
11.9
36,942
7.1
29,635
8.9
30,907
8.5
34,533
7.6
29,838
8.8
33,664
7.8
33,569
7.8
32,727 8.1
36,942 8.9
29,635 7.1
Dig2 out
caning and rehab mid -Marc
DIGESTER 1
Cap. = 690,000
GALS.
(Esti Use 85%Cap.)
IN \ OUT
RETENTION
GALS.
DAYS
36,337
16.1
40,928
14.3
42,755
13.7
42,771
13.7
27,465
21.4
32,788
17.9
30,783
19.1
32,982
17.8
34,226
17.1
31,114
18.9
35,027
16.7
32,870
17.8
35,004
17.0
42,771
21.4
27,465
13.7
Dig1 out
:h*

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
JANUARY 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO RDT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
01 /01 /22
01 /02/22
01 /03/22
01 /04/22
2.01
65.30
7.6
01 /05/22
3.28
40.09
7.6
01 /06/22
0.17
80.69
0.74
74.28
12.53
79.05
2.04
65.15
7.6
01 /07/22
01 /08/22
01 /09/22
01 /10/22
2.02
65.13
7.4
01 /11 /22
2.46
62.82
7.6
01 /12/22
1.93
90.53
3.30
85.43
1.39
78.68
2.00
65.17
7.6
01 /13/22
2.00
65.38
7.7
01/14/22
01 /15/22
01 /16/22
01 /17/22
01 /18/22
7.1
01 /19/22
1.38
80.54
3.58
81.77
11.61
97.69
2.01
65.73
7.5
01 /20/22
01 /21 /22
01 /22/22
01 /23/22
01 /24/22
01 /25/22
1.57
90.32
6.12
84.88
1.06
75.32
2.01
65.20
7.5
01 /26/22
01 /27/22
01 /28/22
01 /29/22
01 /30/22
01 /31 /22
AVERAGE
1.26
85.52
3.44
81.59
6.65
82.69
2.20
62.22
7.51

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
FEBRUARY 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO RDT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
02/01 /22
02/02/22
1.56
90.05
1.23
76.07
6.32
85.15
1.58
65.00
7.5
02/03/22
02/04/22
02/05/22
02/06/22
02/07/22
02/08/22
02/09/22
1.92
91.95
1.05
75.66
1.49
84.53
1.79
63.98
7.5
02/10/22
02/11 /22
02/12/22
02/13/22
02/14/22
02/15/22
02/16/22
1.68
92.08
1.43
75.33
4.90
84.51
1.65
64.31
7.5
02/17/22
02/18/22
02/19/22
02/20/22
02/21 /22
02/22/22
02/23/22
0.06
50.30
1.23
75.73
6.03
85.71
1.75
65.06
7.5
02/24/22
02/25/22
02/26/22
02/27/22
02/28/22
JAVERAGE.1
1.31
81.10
1.24
75.70
4.69
84.98
1.69
64.59
7.52

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
MARCH 2O22
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO RDT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
03/01 /22
03/02/22
1.99
89.63
2.60
75.66
8.73
85.07
2.03
64.25
7.5
03/03/22
03/04/22
03/05/22
03/06/22
03/07/22
1.68
63.14
7.6
03/08/22
2.80
62.56
7.5
03/09/22
2.33
86.28
0.97
73.65
6.93
83.30
2.15
64.12
7.7
03/10/22
2.15
64.34
8.4
03/11 /22
03/12/22
03/13/22
03/14/22
2.38
61.45
8.1
03/15/22
7.9
03/16/22
1.48
90.70
0.84
74.17
6.98
83.88
1.78
62.89
7.8
03/17/22
1.94
62.97
7.7
03/18/22
03/19/22
03/20/22
03/21 /22
03/22/22
03/23/22
1.98
91.33
0.91
73.16
6.18
79.77
1.54
62.49
7.6
03/24/22
03/25/22
03/26/22
03/27/22
03/28/22
03/29/22
03/30/22
1.60
92.38
0.95
74.89
8.82
85.07
1.65
65.05
7.5
03/31 /22
,AVERAGE,,
1.88
90.06
1.25
74.31
7.53
-8-3.4-2-7
2.01
63.33
7.77

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
APRIL 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO RDT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
04/01 /22
04/02/22
04/03/22
04/04/22
04/05/22
04/06/22
1.68
91.09
1.65
75.12
6.81
84.13
1.56
65.04
7.4
04/07/22
04/08/22
04/09/22
04/10/22
04/11 /22
04/12/22
04/13/22
0.79
88.34
1.32
74.81
9.09
85.28
2.00
64.54
7.4
04/14/22
04/15/22
04/16/22
04/17/22
04/18/22
04/19/22
04/20/22
0.05
71.60
0.55
74.57
7.65
81.95
1.37
65.23
7.5
04/21 /22
04/22/22
04/23/22
04/24/22
04/25/22
04/26/22
04/27/22
0.21
80.50
1.53
75.24
8.80
83.28
2.17
67.35
7.0
04/28/22
04/29/22
04/30/22
AVE RAGE
0. 88
82.88
1.26
74.94
8.09
83.66
1.78
65.54
7.34

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
MAY 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO RDT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
05/01 /22
05/02/22
05/03/22
05/04/22
2.08
90.25
1.45
74.49
7.64
83.24
2.19
64.93
7.5
05/05/22
05/06/22
05/07/22
05/08/22
05/09/22
1.80
64.31
7.5
05/10/22
2.41
64.69
7.5
05/11 /22
0.18
70.97
0.58
72.73
4.62
76.02
1.88
63.75
7.5
05/12/22
2.43
64.73
7.5
05/13/22
05/14/22
05/15/22
05/16/22
2.58
65.04
7.6
05/17/22
1.95
64.58
7.3
05/18/22
1.85
92.32
1.11
74.76
8.67
83.95
7.5
05/19/22
2.24
64.35
7.6
05/20/22
05/21 /22
05/22/22
05/23/22
05/24/22
05/25/22
0.76
86.58
0.94
74.62
7.68
80.35
2.70
65.76
7.4
05/26/22
05/27/22
05/28/22
05/29/22
05/30/22
05/31 /22
AVERAGE
1.22
85.03
1.02
74.15 17
7. 55
80.89
2.24
64.68
7.47

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
JUNE 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO RDT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
06/01 /22
2.33
81.81
1.09
74.37
7.82
81.47
2.80
65.65
7.4
06/02/22
06/03/22
06/04/22
06/05/22
06/06/22
06/07/22
06/08/22
2.16
88.28
1.03
72.36
6.51
75.96
2.93
62.56
7.6
06/09/22
06/10/22
06/11 /22
06/12/22
06/13/22
06/14/22
06/15/22
0.20
79.28
0.94
71.72
4.15
74.62
2.80
64.00
7.5
06/16/22
06/17/22
06/18/22
06/19/22
06/20/22
06/21 /22
06/22/22
1.95
81.85
0.97
73.39
5.36
76.66
2.91
63.47
06/23/22
06/24/22
06/25/22
06/26/22
06/27/22
06/28/22
06/29/22
1.92
76.61
1.15
70.38
5.65
74.38
2.36
62.17
7.4
06/30/22
AVERAGE,j
1.71
81.57
1.04
72.44
5.90
76.62
2.76
63.57
7.47

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
J U LY 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO GBT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
07/01 /22
07/02/22
07/03/22
07/04/22
07/05/22
07/06/22
0.97
88.87
0.71
68.87
5.93
80.07
2.85
63.34
7.4
07/07/22
07/08/22
07/09/22
07/10/22
07/11 /22
2.88
63.28
7.5
07/12/22
2.84
63.25
7.5
07/13/22
2.28
91.09
0.13
58.38
8.10
80.87
2.11
61.61
7.6
07/14/22
2.12
62.03
7.5
07/15/22
07/16/22
07/17/22
07/18/22
2.18
63.08
7.7
07/19/22
1.97
62.99
7.7
07/20/22
1.81
90.98
0.89
70.14
5.58
80.82
2.83
63.39
7.5
07/21 /22
1.92
62.57
7.7
07/22/22
07/23/22
07/24/22
07/25/22
07/26/22
07/27/22
0.99
86.75
0.84
68.24
4.50
78.33
2.83
62.87
7.5
07/28/22
07/29/22
07/30/22
07/31 /22
AVE RAGE
1.51
89.42
0.64
66.41
6.03
80.02
2.45
62.84
7.55

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
AUGUST 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO GBT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
08/01 /22
08/02/22
08/03/22
0.66
88.10
0.85
70.00
4.48
77.71
2.85
62.84
7.4
08/04/22
08/05/22
08/06/22
08/07/22
08/08/22
08/09/22
08/10/22
1.34
87.86
0.82
68.76
3.78
76.82
2.93
62.29
7.4
08/11 /22
08/12/22
08/13/22
08/14/22
08/15/22
08/16/22
08/17/22
1.88
89.60
0.73
69.52
4.33
81.82
2.61
61.09
08/18/22
08/19/22
08/20/22
08/21 /22
08/22/22
08/23/22
08/24/22
1.42
89.20
0.63
69.18
5.80
81.20
2.65
61.26
7.6
08/25/22
08/26/22
08/27/22
08/28/22
08/29/22
08/30/22
08/31 /22
1.88
90.02
0.94
71.23
7.30
82.27
2.67
61.27
7.6
AVERAGE1
1.44
88.96
0.79
69.74
5.14
79.96
2.74
61.75
7.54

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
SEPTEMBER 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO GBT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
09/01 /22
09/02/22
09/03/22
09/04/22
09/05/22
09/06/22
09/07/22
1.99
89.60
0.71
71.96
4.42
82.60
2.15
61.92
7.5
09/08/22
09/09/22
09/10/22
09/11 /22
09/12/22
2.70
63.87
7.4
09/13/22
1.69
61.90
7.7
09/14/22
1.82
89.23
0.81
70.94
5.64
82.57
2.73
63.48
7.4
09/15/22
2.00
62.37
7.6
09/16/22
09/17/22
09/18/22
09/19/22
2.43
61.98
7.5
09/20/22
2.12
61.88
7.5
09/21 /22
1.72
90.33
0.78
70.83
5.67
97.45
2.69
63.48
7.5
09/22/22
2.64
63.18
7.4
09/23/22
09/24/22
09/25/22
09/26/22
09/27/22
09/28/22
1.99
91.66
0.78
71.15
6.52
83.42
1.92
62.31
7.5
09/29/22
09/30/22
JAVERAGE1
1.88
90.21
0.77
1 71.22
5.56
1 86.51
2.31
62.64
7.49

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
OCTOBER 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO GBT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
10/1 /2022
10/1 /2023
10/1 /2024
10/1 /2025
10/1 /2026
1.93
63.29
7.7
10/1 /2027
0.34
80.89
0.82
72.01
8.14
84.64
10/1 /2028
10/1 /2029
10/1 /2030
10/1 /2031
10/1 /2032
10/1 /2033
1.89
91.09
0.87
71.84
6.27
84.15
1.89
63.14
7.6
10/1 /2034
10/1 /2035
10/1 /2036
10/1 /2037
10/1 /2038
10/1 /2039
10/1 /2040
0.87
89.04
0.78
72.55
6.74
84.48
1.93
63.67
10/1 /2041
10/1 /2042
10/1 /2043
10/1 /2044
10/1 /2045
10/1 /2046
10/1 /2047
10/1 /2048
2.00
91.72
0.91
71.63
5.81
85.01
1.83
64.00
7.5
10/1 /2049
10/1 /2050
10/1 /2051
10/1 /2052
AVE RAGE
1.28
88.19
0.85
72.01
6.74
84.57
1.90
63.53
7.61

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
NOVEMBER 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO GBT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
11 /01 /22
11 /02/22
0.12
78.92
0.65
72.37
74.69
0.32
2.67
66.66
7.5
11 /03/22
11 /04/22
11 /05/22
11 /06/22
11 /07/22
2.34
63.31
7.7
11 /08/22
1.99
63.32
7.7
11 /09/22
1.93
91.24
0.74
70.84
82.27
0.63
1.90
63.16
1 7.7
11 /10/22
1.95
63.66
7.8
11/11/22
11 /12/22
11/13/22
11 /14/22
1.77
64.25
8.0
11 /15/22
2.53
64.96
7.5
11 /16/22
2.13
84.56
0.72
72.19
81.69
0.58
2.55
65.27
7.5
11 /17/22
1.56
64.01
7.8
11/18/22
11/19/22
11 /20/22
11/21/22
11 /22/22
11 /23/22
7.6
11 /24/22
11 /25/22
11 /26/22
11 /27/22
11 /28/22
11 /29/22
11 /30/22
AVERAGE
1.39
84.91
0.70
71.80
79.55
0.51
2.14
64.29
7.66

ORANGE WATER AND SEWER AUTHORITY
MASON FARM WASTEWATER TREATMENT PLANT
TOTAL SOLIDS AND pH WORKSHEET
DECEMBER 2022
SAMPLE
DATE
PRIMARY
SLUDGE TO RDT
WASTE ACTIVATED
SLUDGE TO GBT
COMBINED PS +
WAS TO DIGESTION
BIOSOLIDS TO
LAND APPLICATION
%TS
%TVS
%TS
%TVS
%TS
%TVS
%TS
%TVS
pH
12/01/22
12/02/22
12/03/22
12/04/22
12/05/22
12/06/22
12/07/22
2.12
89.81
0.80
73.07
5.87
84.27
2.07
64.72
12/08/22
12/09/22
12/10/22
12/11/22
12/12/22
12/13/22
12/14/22
12/15/22
0.05
65.97
1.02
71.52
2.95
75.93
1.98
63.72
12/16/22
12/17/22
12/18/22
12/19/22
12/20/22
12/21/22
12/22/22
2.35
88.63
1.11
73.26
6.13
83.35
2.02
64.67
12/23/22
12/24/22
12/25/22
12/26/22
12/27/22
12/28/22
0.55
87.91
0.80
73.55
4.08
76.12
1.86
64.99
12/29/22
12/30/22
12/31 /22
E1.27
7.4
AVERAGE
83.08
0.93
72.85 11
4.76
79.92 11
1.98
1 64.53
7.40

OWASA
Digested Sl udge Anal ysi s for Fecal Col iform
Reported MPN fecal coliform/g = 13 (geometric mean for Class B)
MAX 93 (single value, Class A)
MIN 6
Average MPN fecal coliform/g= 21
Date
MPN Index / 100mis
TS (%)
Largest Volume Used (mL)
MPN FC/g
01 /04/22
<2
2.01
1
<10
01 /05/22
2
3.28
1
6
01 /06/22
2
2.04
1
10
01 /10/22
<2
2.02
1
<10
01 /11 /22
23
2.46
1
93
01 /12/22
<2
2
1
<10
01 /13/22
2
2
1
10
1
Using EPA 503 rules for ClassA Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Each reported value must be <1000 MPN per gram total solids (dry wt basis)
Using EPA 503 rules for Class B Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10* (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Reported value is geometric mean of all samples
-Reported val ue must be <2 mi I I i on M PN per gram total sol i ds (dry wt basi s)

OWASA
Digested Sl udge Anal ysi s for Fecal Col iform
Reported MPN fecal coliform/g = 21 (geometric mean for Class B)
MAX 107 (single value, Class A)
MIN <8
Average MPN fecal coliform/g= 36
Date
MPN Index / 100mis
TS (%)
Largest Volume Used (mL)
MPN FC/g
03/07/22
<2
1.68
1
<12
03/08/22
23
2.8
1
82
03/09/22
2
2.15
1
9
03/10/22
23
2.15
1
107
03/14/22
<2
2.38
1
<8
03/16/22
<2
1.78
1
<11
03/17/22
4
1.94
1
21
Using EPA 503 rules for Class A Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Each reported value must be <1000 MPN per gram total solids (dry wt basis)
Using EPA 503 rules for Class B Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Reported value is geometric mean of all samples
-Reported val ue must be <2 mi I I i on M PN per gram total sol i ds (dry wt basi s)

OWASA
Digested Sl udge Anal ysi s for Fecal Col iform
Reported MPN fecal coliform/g = 19 (geometric mean for Class B)
MAX 89 (single value, Class A)
MIN <8
Average MPN fecal coliform/g= 29
Date
MPN Index / 100mis
TS (%)
Largest Volume Used (mL)
MPN FC/g
05/09/22
<2
1.80
1
<11
05/10/22
4.5
2.41
1
19
05/11 /22
<2
1.88
1
<11
05/12/22
<2
2.43
1
<8
05/16/22
23
2.58
1
89
05/17/22
<2
1.95
1
<10
05/19/22
13
2.24
1
58
1
Using EPA 503 rules for Class A Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Each reported value must be <1000 MPN per gram total solids (dry wt basis)
Using EPA 503 rules for Class B Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Reported value is geometric mean of all samples
-Reported val ue must be <2 mi I I i on M PN per gram total sol i ds (dry wt basi s)

OWASA
Digested Sl udge Anal ysi s for Fecal Col iform
Reported MPN fecal coliform/g = 16 (geometric mean for Class B)
MAX 81 (single value, Class A)
MIN <7
Average MPN fecal coliform/g= 27
Date
MPN Index / 100mis
TS (%)
Largest Volume Used (mL)
MPN FC/g
07/11 /22
<2
2.88
1
<7
07/12/22
23
2.84
1
81
07/13/22
<2
2.11
1
<9
07/14/22
<2
2.12
1
<9
07/18/22
<2
2.18
1
<9
07/19/22
<2
1.97
1
<10
07/20/22
23
2.83
1
81
07/21 /22
<2
1.92
1
<10
Using EPA 503 rules for ClassA Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Each reported value must be <1000 MPN per gram total solids (dry wt basis)
Using EPA 503 rules for Class B Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Reported value is geometric mean of all samples
-Reported val ue must be <2 mi I I i on M PN per gram total sol i ds (dry wt basi s)

OWASA
Digested Sl udge Anal ysi s for Fecal Col iform
Reported MPN fecal coliform/g = 32 (geometric mean for Class B)
MAX 87 (single value, Class A)
MIN <7
Average MPN fecal coliform/ = 49
Date
MPN Index / 100mis
TS (%)
Largest Volume Used (mL)
M PN FC/g
09/12/22
<2
2.70
1
<7
09/13/22
13
1
77
1.69
09/14/22
23
2.73
1
84
09/15/22
<2
2
1
<10
09/19/22
8
2.43
1
33
09/20/22
<2
2.12
1
<9
09/21 /22
23
2.69
1
86
09/22/22
23
2.64
1
87
Using EPA 503 rules for Class Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Each reported value must be <1000 MPN per gram total solids (dry wt basis)
Using EPA 503 rules for Class B Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Reported value is geometric mean of all samples
-Reported val ue must be <2 mi I I i on M PN per gram total sol i ds (dry wt basi s)

OWASA
Digested Sl udge Anal ysi s for Fecal Col iform
Reported MPN fecal coliform/g = 13 (geometric mean for Class B)
MAX 98 (single value, Class A)
MIN <8
Average MPN fecal coliform/g= 21
Date
MPN Index / 100mis
TS (%)
Largest Volume Used (mL)
MPN FC/g
11 /07/22
23
2.34
1
98
11 /08/22
<2
1
<10
1.99
11 /09/22
2
1.9
1
11
11 /10/22
<2
1.95
1
<10
11 /14/22
<2
1.77
1
<11
11 /15/22
<2
2.53
1
<8
11 /16/22
<2
2.55
1
<8
11 /17/22
<2
1.56
1
<13
Using EPA 503 rules for ClassA Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Each reported value must be <1000 MPN per gram total solids (dry wt basis)
Using EPA 503 rules for Class B Sludge, Appendix F:
-follow SM 9221 E (Al Media)-2006, SM 9221 C Table9221:IV-2006
-Report as M PN Fecal Col iforni/gram
-Calculation(EPA) _ (10 * (MPN Index/100 mis))/(largest volume*% dry solids)
where: MPN I ndex/100mis is read from MPN table,
-Reported value is geometric mean of all samples
-Reported val ue must be <2 mi I I i on M PN per gram total sol i ds (dry wt basi s)

Meritech, Inc.
Environmental Laboratory
' • Laboratory Certification No.165
}
RECEIVED
Contact: Stephanie Knott By Jennifer Hunter at 5:05 pm, Mar 03, 2022 Revised Date:
Report Date:
Client: Pace Analytical
1377 South Park Drive
Kernersville, NC 27284
Project:
P.O. #:
Date Sample Rcvd:
211012022
2/4/2022
92583083
SJK011822
1/18/2022
Meritech Work Order #
01182222
Sample: OWASA -Digested Sludge
1/18/22
Parameters
Result
Analysis Date Reporting Limit
Method
Ammonia, Nitrogen
864 mg/L
1/20/22
0.1 mg/L
EPA 350.1
TKN
1890 mg/L
1/25/22
0.20 mg/L
EPA 351.1
Nitrate, Nitrogen
<10.0 mg/L
1/20/22
10.0 mg/L
EPA 353.2
Nitrite, Nitrogen
<10.0 mg/L
1/20/22
10.0 mg/L
EPA 353.2
Nitrate/Nitrite, Nitrogen
<10.0 mg/L
1/21/22
10.0 mg/L
EPA 353.2
Total Solids
20300 mg/L
1/21/22
10 mg/L
SM 2540B
Aluminum, total*
1780 mg/L
219122
0.050 mg/L
EPA 200.7
Arsenic, total
<0.050 mg/L
1/31/22
0.050 mg/L
EPA 200.7
Cadmium, total
0.023 mg/L
1/31/22
0.002 mg/L
EPA 200.7
Calcium, total
353 mg/L
1/31/22
0.100 mg/L
EPA 200.7
Copper, total
4.53 mg/L
1/31/22
0.002 mg/L
EPA 200.7
Lead, total
<0.050 mg/L
219122
0.050 mg/L
EPA 200.7
Magnesium, total
105 mg/L
1/31/22
0.005 mg/L
EPA 200.7
Mercury, total
0.0012 mg/L
1/25/22
0.0002 mg/L
EPA 245.1
Molybdenum, total
0.104 mg/L
1/31/22
0.005 mg/L
EPA 200.7
Nickel, total
0.231 mg/L
1/31/22
0.010 mg/L
EPA 200.7
Phosphorus, total
1540 mg/L
1/31/22
0.020 mg/L
EPA 200.7
Potassium, total
182 mg/L
1/31/22
1.00 mg/L
EPA 200.7
Selenium, total*
0.109 mg/L
219122
0.010 mg/L
EPA 200.7
Sodium, total
110 mg/L
1/31/22
0.100 mg/L
EPA 200.7
Zinc, total
16.0 mg/L
1/31/22
0.010 mg/L
EPA 200.7
* Denotes Average
I hereby certify that I have reviewed and approve these data.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

\
a
D
O
to
o
M
0
�
M
O
ro
�
n
m
�
r�D
C
v
3
3
s
.ry
m
rD
0
o
o
m
d
(�
�
_ J
Z
3
•3F
�F
fD
70
r"F
Z]
(D
[/1
C
r--h
Ln
aJ
LA
r
n
rD �o
m
0
a
0
ry
No
L
o
ru
n
Mr_
n
o
m
o.
�
zCL
n
Q
O_
C
N
fD
<
d
m
(D
m
rD
n
C
o
�
m
Ln
a'
n
O
Q
C7
(D
�
P-
Z
cn
�
N
9
c
fD
v
O
O
eD
Ln
2
o
a
v
m
0
3D
r,
zr
O
l J
n
�
O
r
3
ui
n
w
=
F+
r+
rn
D
N
m
�'
o
N
�
O
CD
H
N
:0
N
rri
Nco
O
o
�
m
3
�
g
n
n n
U 6
0
!D
Q CD
0
n
7
1-' H
q
O
p Z
D
3
w
rt
rt
X
n
1 m
3
OrD
�'
m
rr
D
n
rD
cn
r.
o Q
V
-rA
Z
v'
v
'R -C
314
Ln
C
n
fD
S
Z
(/)CD
7r rD
C
b O
1. C
a
_
+
9 ro
CD
DQ
(D
m
X 3
ry
O
-D
-0
m
O
o
,.
ID
-
X
lD
JI7t
CL
v
o
�
a
�
x
a
w
-I
Q
w
O
N W
rD
Ort
O
ILfb'
o
0
r
n 5
z M
'o d
O N
H
`I
O
W *
a
rD
Da
O
f 1 112=
a
o
a
X •C
.-i
ems,
n
M
-V Z
x 0
O d
= m
rD
I�
V
0
V
V
O
lD
W

aceAnalXical
www.pacelabs.com
Wilmer Lawson
OWASA
400 Jones Ferry Road
Carrboro, NC 27510
Project: OWASA- Digested Sludge
Pace Project No.: 92591752
Sample: Digested Sludge
RECEIVED
By Jennifer Hunter at 8:04 am, Mar 16, 2022
Laboratory Report
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 1 of 1
Report Date: 03/15/2022
Date Received: 03/07/2022
Lab ID: 92591752001 Collected: 03/07/22 10:08 Matrix: Water
Method
Parameters
Results
Units
Report Limit
Analyzed Qualifiers
EPA 200.7
Aluminum
792000
ug/L
1000
03/10/22 15:25
EPA 200.7
Arsenic
54.8
ug/L
30.0
03/10/22 15:20
EPA 200.7
Cadmium
15.0
ug/L
10.0
03/09/22 23:44
EPA 200.7
Calcium
311000
ug/L
10000
03/10/22 15:25
EPA 200.7
Copper
4010
ug/L
20.0
03/10/22 15:20
EPA 200.7
Lead
328
ug/L
25.0
03/09/22 23:44
EPA 200.7
Magnesium
92000
ug/L
50.0
03/09/22 23:44
EPA 200.7
Molybdenum
93.5
ug/L
40.0
03/09/22 23:44
EPA 200.7
Nickel
230
ug/L
20.0
03/09/22 23:44
EPA 200.7
Potassium
128000
ug/L
200
03/09/22 23:44
EPA 200.7
Selenium
62.8
ug/L
40.0
03/09/22 23:44
EPA 200.7
Sodium
112000
ug/L
1000
03/09/22 23:44
EPA 200.7
Zinc
12100
ug/L
20.0
03/09/22 23:44
EPA245.1
Mercury
ND
ug/L
0.20
03/14/2216:11
Reviewed by:�
Stephanie Knott
704-977-0981
[e-mail]
Pace Analytical Services Peachtree Corners
110 Technology Pkwy, Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
North Carolina Certification #: 381
South Carolina Certification #: 98011001
Page 1 of 4

z
(NIA)
U m
10e;u1
6
saIdweS
U Y
z
2
A
Ja!o0O
U z
F
a
=
pa!eas
4 =
O
U
R o sn
{NNJ
a
a
a0I
c
y
g a N
0o paA! a0aa
J
(NIA)aup01y0 lenp!saa
m
o
0 u! dN31
a
z
N
�
m
•?wL
o
W
Z
G
U
Z
F
Z
}
r.
6
`m
sP!IoS !eloF
x
�
m
sruugdsNd IzPci
x
�
J
m
U050JIlN ZON+EON
x
r
m
U050JIlN @1u1!N
x
.�3
G
ua6o„!N 91LA N
x
o
a
qi
m
13a6oiliN U!UUWILb•
x
fq
C.
Z
Q
¢
aJ
o
N711
x
�
Q
U
z
�
m
e
0
y s!e;any
x
a
NIA
;sal. saslleuy
Y
JOWO
U
.(D
@
t
d
louey;aN
@
a
9L
r
2 a>
w
(0
m
EOZSZeN
U
L
HOeN
IOH
G C 0
N
E
li
EONH
patuasadu0
N
o ca+ 3 n
�
d
a`
i
S}J3NIV1N0330#
y° Q U¢
a
ri
a
N0113311031V dIN3131dWVS
J
4
w
w
a
EL
o-
�
a
m
y
Z
0
z
C
o
a
o
,
U
w
LU
Lu
a
¢
'
z
w
w
1a
m
a
O
C
¢LU
m
(dAcz)-3 8V210-0) 3dA13"1dWVS
C)
J.
c
_
O
y ti
Z
o
EL
a
O
ti
a
�
�q
10 o o
H
a
Z
Z
o
4�
_
U T
Un
U
N
O
N
O
d a U
% 0
Uf K D: U
7
a
a
a
T
�o3
C
o
•�
O
L
y
a
a
Q 13
a
Z
z
a)
Y
7
iL
r]
LL
°
�.�..� 2 .o
O
U
C
la
o2S C
N
_
J
N
m°
U
y
�
so
J ,a; m�
o E
Q
z
�
G
p
N
a`
a
F
2
2
U
`o c
N
Q
C
(n C
7
m
a a o a
U1 K U Q
E
w
s
a_
e:
0
C7
Page 2 of 4

Document Name:
Document Revised: November 15, 2021
Sample Condition Upon Receipt (SCUR)
Page 1 of 2
Document No..
Issuing Authority:
i aceAnalytical
F-CAR-CS-033-Rev.OB
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville
SampleCandition Client Name:
Upon Receipt
DS Project f#
Courier: ❑Fed Ex L� ❑UPS ❑USPS ❑Client
❑ Commercial [�Jp�ce ❑Other:
Custody Seal Present? ❑Yes L3ixo Seals Intact? ❑Yes ❑No
Packing Material: ❑Bubble Wrap ❑Bubble Bags EVone ❑ Other
Thermometer: AD000
❑yv�et ❑slue
IR Gun ID:
Type of Ice:
Correction Factor:
Cooler Temp: -0 Add/Subtract (°C} 0
Cooler Temp Corrected (° ): U
USDA Regulated Soil (N/A, water sample)
Did samples on ate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
F
Date/Initials Person Examining Contents:
Biological Tissue ;Fen?
❑None
[]Yess ❑No /A
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (interna ignally,
Comments/Discrepancy:
Chain of Custody Present?
es
ON.
❑N/A
1.
Samples Arrived within Hold Time?
[9/Ye
ONO
❑N/A
2.
Short Hold Time Analysis (<72 hr,)?
es
ONO
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
a
[-]N/A
4.
Sufficient Volume?
[1 vs
❑No
[-]N/A
5.
Correct Containers Used?
-Pace Containers Used?
09e5
FeKes
❑No
❑No
El N/A
❑N/A
6.
Containers Intact?
❑6'i'es
ONO
ON/A,
7.
Dissolved analysis: Samples Field Filtered? ❑Yes
[-]NO
/A
H.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis
es
Matrix:
ONO
❑N/A
9.
Headspace in VOAVials (>5-6mm)?
❑Yes
ONO
PI/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
Oyes
❑Yes
❑No
❑No
�/V
11. '
COMMENTS/SAMPLE DISCREPANCY
Lot 1D of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Field Data Required? ❑Yes ❑Nc
Page 3 of 4

Document Name:
Document Issued: November 15, 2021
z,
aceAnalytica!
Bottle Identification Form (B[F)
Page 1 of 1
Document No.:
Issuing Authority:
!
F-CAR-CS-043-Rev.01
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
Project #
ao L<3
`9
E
w
Z
a
m
d
_
M
a
E
N
v
a
Com
Z
a
m
v
°c
Z
a
E
C
V�
7
m
a
Z
a
a
d
a
u
a
E
CDof
4
7
N
a
Cc
z
Z
a
c
N
a-
v
p
N
=
m
a
E
Vf
a
m
v
2
a
m0
z
2
a.
E
Z
M
n.
m
Z
W
4
N
;�
a
E
N
a
m
fV
_
a
2
z
a
E
rN-I
m
a
a
m
Q
m
M
L
°
E
-0
3
z
a
m
a
`m
9
E
¢
a+
J
.--I
7
r+
l7
a
_
v
n.
2
a
.c
E
¢
a`,
-
H
S
l7
a
v
v
c
=
E
¢
ut
N
m
t7
a
w
N
a
0
N
v
a
E
¢
v
.1
Vl
N
U
a
V
N
T
E
a
.-,
E
N
N
m
tD
a I
U
v
E
a
E
o
n�i
�
M
l7
❑
6
m
LD
a
z
-
U
T
¢
0
>
E
O
2
m
Q
❑
N
N
m
z
a
O
>
p
Q
H
rn
Q
>
Z
a
n
c
4
0
J
E
O
a
CD
>
Z
m
T
4
0
J
E
O
l
a
Q+
Q
a
m
o
L
Y
`m
a
�n
.}
y
st
6
0
>
=
a
s
a
a
N
�
fYl
y
l7
>
T
a
a
v
E
Ln
,--�
ui
am
v,
w
a
n
E
O
N
F
N
LM
z
?
m
d
E
N
Q
m
a
m
z
c
n
E
¢
a
O
r-I
7
o
C7
a
a
o
-
=
c
'u
�
O
N
a
l7
vti
>\\N
a
-a
c
a
E
¢
E
0
lY
7
0)
t9
a
1
z
\\N1
4
6
\NN\
N
7
8
9
1Q
11
12
N�NNLLL
pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot H
adjusted added
i
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 4 of 4

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
01
RECEIVED
By Jennifer Hunter at 2:14 pm, Mar 22, 2022
March 19, 2022
Wilmer Lawson
OWASA
400 Jones Ferry Road
Carrboro, NC 27510
RE: Project: OWASA- Digested Sludge
Pace Project No.: 92592208
Dear Wilmer Lawson:
Enclosed are the analytical results for sample(s) received by the laboratory on March 07, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Stephanie Knott
[e-mail]
704-977-0981
Project Manager
Enclosures
cc: Jennifer Hunter
REPORT OF LABORATORY ANALYSIS
TNI
\l,9eORATOQQ�
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 15

aceAnalytical
www.pacelabs.cem
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water#: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 15

aceAnalytical
www.pacelabs.cem
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
SAMPLE SUMMARY
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
Lab ID Sample ID Matrix Date Collected Date Received
92592208001 Digested Sludge Solid 03/07/22 10:08 03/07/22 13:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 15

aceAnalytical
www.pacelabs.cem
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
OWASA- Digested Sludge
92592208
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92592208001
Digested Sludge
SM 254OG-2011
KDF
1
PASI-C
SW-846
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
SMS
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
SMT
3
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 15

aceAnalytical
www.pacelabs.cem
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
ANALYTICAL RESULTS
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
Sample: Digested Sludge
Lab ID: 92592208001 Collected: 03/07/22 10:08 Received: 03/07/22 13:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
254OG Total Percent Solids
Analytical Method: SM 254OG-2011
Pace Analytical Services - Charlotte
Total Solids
1.6 % 0.10 1 03/10/22 18:14
Percent Moisture
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
98.4 % 0.10 1 03/10/22 18:06 N2
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod. Preparation Method: EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services - Asheville
Nitrogen, Ammonia
62800 mg/kg 1790 3 03/16/22 12:26 03/16/22 14:50 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
85900 mg/kg 2770 1 03/18/22 19:31 03/19/22 04:05 7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
ND mg/kg 241 1 03/09/22 07:25 03/09/22 08:25
Nitrogen, Nitrate
ND mg/kg 241 1 03/09/22 07:25 03/09/22 08:25 14797-55-8
Nitrogen, Nitrite
ND mg/kg 241 1 03/09/22 07:25 03/09/22 08:25 14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
227000 mg/kg 7320 125 03/16/22 11:45 03/17/22 09:15 7723-14-0 M1,R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/19/2022 04:02 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 15

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
QUALITY CONTROL DATA
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
QC Batch: 683963 Analysis Method: SW-846
QC Batch Method: SW-846 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92592208001
SAMPLE DUPLICATE: 3577432
Parameter
Percent Moisture
SAMPLE DUPLICATE: 3577433
Parameter
Percent Moisture
92591773001 Dup
Units Result Result
13.5 13.6
92592746002 Dup
Units Result Result
% 16.0 16.0
Max
RPD RPD Qualifiers
1 25 N2
Max
RPD RPD Qualifiers
0 25 N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/19/2022 04:02 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 15

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
QUALITY CONTROL DATA
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
QC Batch: 685130 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92592208001
METHOD BLANK: 3582536
Associated Lab Samples: 92592208001
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 3582537
Parameter Units
Nitrogen, Ammonia mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 9.8 03/16/2214:28
Spike LCS LCS % Rec
Cone. Result % Rec Limits Qualifiers
490 485 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3582538 3582539
MS MSD
92591071001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Ammonia mg/kg 266 542 636 780 869 95 95 90-110 11 10 R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3582540 3582541
MS MSD
92591071002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Ammonia mg/kg 341 662 615 985 848 97 82 90-110 15 10 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/19/2022 04:02 PM without the written consent of Pace Analytical Services, LLC.
Page 7 of 15

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
QUALITY CONTROL DATA
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
QC Batch: 685791 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92592208001
METHOD BLANK: 3586018
Associated Lab Samples: 92592208001
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 3586019
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.0 03/19/22 04:00
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1000 959 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3586020 3586021
MS MSD
92591749001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 55000 4550 4550 63300 59400 183 98 90-110 6 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/19/2022 04:02 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 15

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
QUALITY CONTROL DATA
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
QC Batch: 683345 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92592208001
METHOD BLANK: 3574279
Matrix: Solid
Associated Lab Samples: 92592208001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
03/09/22 08:18
Nitrogen, Nitrite
mg/kg
ND 4.0
03/09/22 08:18
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
03/09/22 08:18
LABORATORY CONTROL SAMPLE: 3574280
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 15.0 100 90-110
Nitrogen, Nitrite mg/kg 10 10.2 102 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 25.2 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3574281
3574282
MS
MSD
92592037001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Nitrogen, Nitrate
mg/kg
ND
92.8
93.4
116
107
125
115
90-110
7 10
Nitrogen, Nitrite
mg/kg
ND
61.7
62.3
52.2
48.3
85
78
90-110
8 10 M1
Nitrogen, NO2 plus NO3
mg/kg
ND
154
156
168
156
103
95
90-110
8 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/19/2022 04:02 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 15

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
QUALITY CONTROL DATA
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
QC Batch: 684858 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92592208001
METHOD BLANK: 3581315
Associated Lab Samples: 92592208001
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 3581316
Parameter Units
Phosphorus mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.96 03/17/22 09:12
Spike LCS LCS % Rec
Cone. Result % Rec Limits Qualifiers
45.5 47.3 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3581317 3581318
MS MSD
92591749001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual
Phosphorus mg/kg 218000 187 219 197000 208000 -11500 -4830 90-110 5 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3581319 3581320
MS MSD
92592208001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual
Phosphorus mg/kg 227000 2980 2580 75800 63300 -5070 -6350 90-110 18 10 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/19/2022 04:02 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 15

aceAnalytical
www.pacelabs.cem
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
QUALIFIERS
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/19/2022 04:02 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 15

aceAnalytical
www.pacelabs.cem
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: OWASA- Digested Sludge
Pace Project No.: 92592208
Analytical
Lab ID
Sample ID
QC Batch
Method
QC Batch
Analytical
Method
Batch
92592208001
Digested
Sludge
SM 2540G-2011
683882
92592208001
Digested
Sludge
SW-846
683963
92592208001
Digested
Sludge
EPA 350.1
Rev 2.0
1993
685130
EPA 350.1
Rev 2.0
1993
685153
Mod.
Mod.
92592208001
Digested
Sludge
EPA 351.2
Rev 2.0
1993
685791
EPA 351.2
Rev 2.0
1993
685921
92592208001
Digested
Sludge
EPA 353.2
Rev 2.0
1993
683345
EPA 353.2
Rev 2.0
1993
683346
92592208001
Digested
Sludge
EPA 365.1
Rev 2.0
1993
684858
EPA 365.1
Rev 2.0
1993
685157
Date: 03/19/2022 04:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 15

OD
49
N
/
N�
'a)
r/ �
N
�m
�m
_ N
N
OOl
3 �N
N
Gl
z
iN1A)
qn
saldweg
Y
2
N1A
w
v z
O
O
o
FZ
Ja!003
a
z
Paleas
a z
Rpolsn
(NIA)
lu
u
d
m
m
aul
cr
2
e
`m
CC
? a N
¢
uo pan!aaaa
Q
R
o
c
a
iN1A) au!jo143 �enpisa0
�
a
�
F
r
m
?
G
_
m
0
2
n
m
r
sp!I0S lelul
x
LL
G
sruo4dso4d lelol
x
H
�
O
uabO&N ZONIEON
x
¢
uaB04N WAN
x
v
UABOI_N 81BAIN
x
o
m
0
u,
a
c
y
uaB0J1!N e'uowwV
xcc
z
LLI
U
N711
x
F
a
Q
A
o
sle;aW
xLL
-e
a
NIA
Isa1 sasAlBud
a)
m
A8410LU
.6
U
.�
,
!oueylaW
c
`m
a
v
EOZSZUN
aN7
HOeN
a,
ie
¢
t
L
o
'c
O
vOi
10H
EONH
d
Z
°�
m
°
VOSZH
pardasaidu0
N
o u
0
a
m
a
2
o
SZn-
wul
¢
U
a
a
a
a
5213NIV1NO3 do ix
_
a
N01133-11QQ id dW313ldWtl5
F
S
ti
Ww
J
a
J
V7
�
a.
m
g
C,
H
C1
Z
N
y
Z
6
O
O
aLI
LU
Lu
❑
¢
'
}a
E
Ua
O
TJ'
Z
z
w
C
J
Z
J
w
OO
P
a
y
❑
.s-
c
o
uj
9V21 =e) 3d A13ldINV5
C9
#
)pal of sapoo piEen aasl 3Q0� XI211VW
m
Nut
a
- -
a
z�S'
ut
o
IL
D
m
E
by
o
~
Z
Z
o
OUaam0
t
O
u
V
u
�i�OH
U cr
Cl
a
O
f!1 Ir
!Y
U
d
n_
d
T
�oya�,o a
o
U
L
T
A
d
7
5
a
y
`)
d
Q
W
U
LL
❑ 00 a
O'
U)
m
LL
f—
O
W o. ?
Ci
�6
N
J
a)
oU
mc0
J mm E
4
0
�
�Z
o�
1°nf .
o�
F
a
Q C7 a1
=
0
2
U
E
U}
Q
-
ma
O
a)
3
O
L
L
rn
ru
c m
4�
m
�'
�
�
v
c
E
v
�'°
o�
# W311
�
r%1 C
U
4
w
aI
-
Page 13 of 15

Document Name: Document Revised: November 15, 2021
1� - Sample Condition Upon Receipt (SCUR) Page 1 of 2
.- 3C�'Aic3l'ft1Cc7,r Document No.: Issuing Authority:
F-CAR-CS-033-Rev.
08 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville
Client Name:
%� m \ f�� �� ,PS
Project #:
Courier: ❑Fed Ex ,l❑oU}P5 ❑U5P5 ❑Client
❑ Commercial [�/ace ❑Other:
Custody Seal Present? ❑Yes L 11ao Seals Intact? [—]Yes ❑No
Date/initials Person Examining Contents:
Packing Material: ❑Bubble Wrap ❑Bubbie Bags EVOne ❑ Other Biological Tissue Fr en?
Thermometer. a ] r�% ❑Yes []No ❑i0/A
❑ IR Gun ID:et ❑Blue ❑N❑ne
Type of Ice:
<
Correction Factor: o
Cooler Temp: Add/Subtract ("C) Temp should be above freezing to VC
C�
Cooler Temp Corrected❑Samples out of temp criteria. Samples an ice, cooling process
): has begun
U5DA Regulated Sail { N/A, water sample)
Did samples on ' ate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internatignady,
❑Yes No inducing Hawaii and Puerto Rico)? ❑Yes ❑
Comments/Di sere p ancv:
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (a72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/5AMPtE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
❑No
❑N/A
1.
❑N❑
[]N/A
2.
❑N❑
❑N/A
3.
❑
❑N/A
4.
❑No
❑N/A
5.
[]No
❑N/A
6.
[:]No ❑N/A
❑No El N/A 7.
❑N❑ /A 8.
[:]No ❑N/A 4.
IJYes ❑No LAN/A 1D.
❑Yes ❑No V 11.
❑Yes nNo jt]NLF�
Date/Time:
Lot ID of split containers:
Date:
Date:
Field Data Required? ❑Yes ❑No
Page 14 of 15

Document Name:
Document Issued: November 15, 2021
aceAnalytical'
Bottle Identification Form (BIF)
Page 1 of 1
Document No.:
issuing Authority:
F-CAR-CS-043-Rev.01
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
Project #
ao ,
U
G
?
E
z
c
7
u
7
m
z
c
7
u
o
7
m
z
c
7
u
a2
E
o
7
m
a
Z
a
c
H
m
N
`^
=
u
y
m
ry
Z
z
u
°
Z
m
o
z
�
N
4
N
u
N
m
p_
Oro
Z
u
m
m
v
n
C7
E¢CL
�
z
a
E
`
.-�
l7
a
v
2
E
2
rl
t7
a
z
vW
c
`a
¢
E
i
M
M
4(
a
ry
Y
OL.J0
=
E
-o
v1
rl
C7
a
—
N
a
ry
E
a
EE
M
M
C7
a
z
U
z
E
Q
7
❑
a
M
C7
¢
z
U
o
M
QS
l7
❑
z
N
OO
¢
>
J
E
�
T
>
>
a
Z
W
v
a
c
¢
V
a,
U
>
>
=
d
m
O
>
Q1
M
a
in
_
4
;X
o
.�^,
MyN
Y
a
p
>
z
+-�
N
LD
'a
'5
0
>
>
o
I
z
-
n_
Y
Ln
[P1
�
R
I
z
«.
a
E
F
N
,a
n
2
a
❑
a
M
m
S
N
c
=
E
¢
EE
o
O
a
c
o
✓cam
1
EN
7
U,
7
—"
�
J
L
a
aE
E
V
m
a
1
I
2
3
4
5
6
7
8
9
14
\
NN,
11
12
pH Adjustment Log for Preserved Samples
Sample iD
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot tf
1
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form wilt he sent to the North Carolina DEHNR Certification office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 15 of 15

aceAnalXical
www.pacelabs.com
Wilmer Lawson
OWASA
400 Jones Ferry Road
Carrboro, NC 27510
Project: OWASA Digested Sludge
Pace Project No.: 92603423
Sample: Digested Sludge
Oo
RECEIVED
By Jennifer Hunter at 8:48 am, Jun 07, 2022
Laboratory Report
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 1 of 1
Report Date: 06/03/2022
Date Received: 05/09/2022
Lab ID: 92603423001 Collected: 05/09/22 08:10 Matrix: Water
Method
Parameters
Results
Units
Report Limit
EPA 200.7
Aluminum
620000
ug/L
1000
EPA 200.7
Arsenic
ND
ug/L
300
EPA 200.7
Cadmium
ND
ug/L
100
EPA 200.7
Calcium
267000
ug/L
10000
EPA 200.7
Copper
3240
ug/L
200
EPA 200.7
Lead
260
ug/L
250
EPA 200.7
Magnesium
76200
ug/L
500
EPA 200.7
Molybdenum
ND
ug/L
400
EPA 200.7
Nickel
ND
ug/L
200
EPA 200.7
Potassium
135000
ug/L
2000
EPA 200.7
Selenium
ND
ug/L
400
EPA 200.7
Sodium
82900
ug/L
10000
EPA 200.7
Zinc
10100
ug/L
200
EPA 245.1 Rev 3.0 1994
Mercury
2.1
ug/L
0.20
SM 254OB-2015
Total Solids
19500
mg/L
2500
EPA 350.1 Rev 2.0 1993
Nitrogen, Ammonia
2380
mg/L
25.0
EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
2640
mg/L
100
EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
0.77
mg/L
0.040
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
0.70
mg/L
0.040
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrite
0.070
mg/L
0.040
EPA 365.1 Rev 2.0 1993
Phosphorus
919
mg/L
12.5
ANALYTE QUALIFIERS
Analyzed
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
06/01 /22 19:47
05/19/22 13:00
05/13/22 09:38
05/13/22 12:59
05/19/22 07:55
05/11/22 02:55
05/11/22 02:55
05/11/22 02:55
05/13/22 19:58
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
Reviewed by
Stephanie Knott
704-977-0981
[e-mail]
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Peachtree Corners
110 Technology Pkwy, Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Certification #: 381
South Carolina Certification #: 98011001
D3
D3
D3
D3
D3
Qualifiers
Page 1 of 4

N
lD
A
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accur,.
WO#:92603423
IIIIII IIIIIIIIIIIII III
Section A
Section B
Section C
Required Client Information:
Required Project information:
Invoice Information:
Page : 1 Of 1
Company Orange Water & Sewer Authority
Report To:
Jennifer Hunter
Attention Jennifer Hunter
Address:
170 Old Mason Farm Rd
Copy To:
Company Name: Orange Water & Sewer Authority
Chapel Hill, NC 27517
Address 400 Jones Ferry Rd, Carrboro, NC 27510
Regulatory Agency
Email To: 'hUrltef OWaSa.Or
Purchase Order#:
Pace Quote:
NC Division of WaterQuali
Phoney
919-537-4206 jFaK
Project Name:
Pace Project Manager Stephanie Knott
Stale I Location
Requested Due Date:
Project Number:
Pace Profile #:
North Carolina I Ralei h
Re
uested
Anal
le
Filtered
1N
�
d
Z
MATRIX
coos
°
o
U
COLLECTED
Z
Preservatives
❑rinkmg water Dw
V
O
Weter
WT
o
V
Waste Water WW
_
Product
SOVS.Id
P
SL
SAMPLE ID
�_
START
END
¢
oil
CL
One Character per box. W,Pe WF
m
w
a
Ip
at
m
m
t
L
[A,Z, 0-91, -j
nor
AR
o
o
a
MU
a
a
m
2
"
z
o
o
z
`�
n
o
w
a
U
Sample Ids must be unique
cther
Tissue
oT
Ts
x
a
O
H
a
o
m
C
m
m
—
z
Oz
c
¢
a
a
o
c
O
z
0
m
m
L
a
N
m
o
E
O
n-
r
m
DATE
TIME
DATE
TIME
w
a__=
z
z
O
g
y
r¢
z
'z'
z
o
t-
o
H
1
Digested Sludge
WT
G
-qV
0WO
5
2
2
1
X
X
X
X
X
X
X
x
Pb. Mg, Hg, Mo, Ni, K. Se. Na,
zn
2
3
4
5
6
7
B
e
10
11
12
ADDITIONAL COMMENTS
RELINQUISHED BY I AFFILIA110N
DATE
TIME
ACCEPTED BY I AFFILIATION
DATE
TIME
SAMPLE CONDITIONS
Cooler packed with crushed ice and picked up by courier
f r a 'i y'
nA
0,710
�L
SAMPLER NAME AND SIGNATURE
U
o
m
PRINT Name of SAMPLER:
0 pry',
i C►'
V>
SIGNATURE of SAMPLER:
DATE Signed:
[K
W
L

Document Name: Document Revised: November 15, 2021
Sample Condition Upon Receipt (SCUR) Page 1 of Z
�_. ace Aralffiica!'
Document No.: Issuing Authority:
F-CAR-CS-033-Rev.08 Pace Carolinas QualitV Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[7] Atlanta[] Kernersvillei�,r
Client Name:
Project 4$
Courier: ❑�F�e�d Ex ❑UPS ❑USPS ❑Client
❑ Commercial t1r�°ce ❑Other:
Custody Seal Present? ❑Yes No Seals Intact? ❑Yes FIND
Date/Initials Person Examining Contents:
Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: ❑Yes ❑No [—]N/A
❑ IR Gun ID: ❑Wet ❑Blue ❑None
Type of Ice:
Correction Factor:
Cooler Temp: 3 ' E* Add/Subtract (°C) U Temp should be above freezing to 6"C
Cooler Temp Corrected (°C): 2f ❑Samples out of temp criteria. Samples on ice, cooling process
r has begun
USDA Regulated Soil (,water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check mansl? nisi --io° r,
COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑No
Lot ID of split containers:
CLIENT NCPTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review:
Project Manager SRF Review:
Date:
Date:
Page 3 of 4

Cr- cp h 3 ' f c h,x i; a r.- %ar cccr.ler;ratioa is Fro ,-2 -
- I
ra'i7C fo.'
Soi'IrI�5.
tst r cr, 4'Z-. C- T C;. a - c7_c, C'-. F-`5
`Y6,—"cm h2. 1 cf bc:c is tc list num'--er of co:t'es i
7
v
}
`J
�
K
Li
C
—_
^'
V
i
jjlE � I
I <!
-
� I
i� II I
2-
i
—
-
—
—
-
I �_
u
{
G
_
i C
C
I
}
I <_
7 I 7 I 7 C
C I .. I L C
— -
C
I C
l7
C
C
<
l:
C
4'
C
iI t:
I G
C
l: ff C' f}j C:. ` C
G
I } E 7 I f 7
IIIIII 11
7 I.•. I �n f I C }
III III - I
XK i\
I NN
I
? \
,
L
NIN
3 \
I" IN I
NI N- -1 I
1
NN\N
N!
1�\NNNI
N
\. N
N NI I
A
N\1
�\
N
I
\
�1,,N
\�
1 lZ \J
NN
PH Adjustrnent Log for Preserved Samples
ample IC Ty?e of Pre serv3tive pH upon r=_ceigt Data pceser•Jation adjustzd Time praservatioc
adjusted
A,rnount of Praser'43 t:v=_ i Let n
added i
'P. is a d'scrzpere'r a^ect!r.o P<cr.^ Carclir.a cc, p-ran[e sarrlcle5, a ca cy tr.i5 of F� .. • -- - W;I: be 5e-;t'c tFe ox'r Ca-ci;r.a
cF hoic, irccrrect pre52r'ia',ve, out of terrp, incarrec' conrainers.
Page 4 of 4

acmnalytical
www.pacelabs.com
Wilmer Lawson
OWASA
400 Jones Ferry Road
Carrboro, NC 27510
Project: OWASA Digested Sludge
Pace Project No.: 92615356
Sample: Digested Sludge
RECEIVED
By Jennifer Hunter at 10:04 am, Aug 27, 2022
Laboratory Report
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 1 of 1
Report Date: 08/08/2022
Date Received: 07/18/2022
Lab ID: 92615356001 Collected: 07/18/22 09:50 Matrix: Water
Method
Parameters
Results
Units
Report Limit
EPA 200.7 Rev 4.4 1994
Aluminum
967000
ug/L
1000
EPA 200.7 Rev 4.4 1994
Arsenic
ND
ug/L
100
EPA 200.7 Rev 4.4 1994
Cadmium
23.9
ug/L
10.0
EPA 200.7 Rev 4.4 1994
Calcium
386000
ug/L
1000
EPA 200.7 Rev 4.4 1994
Copper
3580
ug/L
50.0
EPA 200.7 Rev 4.4 1994
Lead
264
ug/L
50.0
EPA 200.7 Rev 4.4 1994
Magnesium
107000
ug/L
1000
EPA 200.7 Rev 4.4 1994
Molybdenum
ND
ug/L
50.0
EPA 200.7 Rev 4.4 1994
Nickel
220
ug/L
50.0
EPA 200.7 Rev 4.4 1994
Potassium
158000
ug/L
50000
EPA 200.7 Rev 4.4 1994
Selenium
ND
ug/L
100
EPA 200.7 Rev 4.4 1994
Sodium
125000
ug/L
50000
EPA 200.7 Rev 4.4 1994
Zinc
16500
ug/L
100
EPA245.1 Rev 3.0 1994
Mercury
ND
ug/L
0.40
SM 254OB-2015
Total Solids
22000
mg/L
2500
EPA 350.1 Rev 2.0 1993
Nitrogen, Ammonia
1130
mg/L
25.0
EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
1790
mg/L
100
EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
1.7
mg/L
0.040
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
1.6
mg/L
0.040
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrite
0.12
mg/L
0.040
EPA 365.1 Rev 2.0 1993
Phosphorus
978
mg/L
12.5
ANALYTE QUALIFIERS
Analyzed
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
07/29/22 15:03
08/05/22 09:25
07/23/22 10:11
07/26/22 13:14
07/26/22 04:49
07/20/22 01:19
07/20/22 01:19
07/20/22 01:19
07/21 /22 18:18
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
Reviewed by:
Stephanie Knott
704-977-0981
[e-mail]
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
D3
M1
Qualifiers
Page 1 of 4

/.C�CHAIN-OF-CUSTODY 1 Analytical Request C
/V aCie The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields ml
f(( Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at http0iinfo,pac
Section A Section B Section C
Required client information: Required Project Information: Invoice Information:
WO#:92615356
1111111111111111111111
92615356
Company: OWASA
Report To, Jennifer Hunter
Attention:
Company Name
Address: 170 Old Mason Farm Road
Copy To:
Chapel Hill, NC 27517
Address:
Regulatory Agency
Emai[ jhunter owasa_org
Purchase Order #.
Pace Ouote:
Phone: [phone] Fax',
Project Name', Digested Sludge
Pace Project Manager stephanie.knottpacelads,com,
State I Location
Requested Due Date:
Project #:
Pace Profile #', 12793
Requested
Anel
sie
Mitered
YIN
a
Z
o
COLLECTED
Preservatives
>'
rm.4rRlx cooE
❑'inking Water Ow
Wale' WT
V
Z
~
Waste Wa[et WIN
Product P
SAMPLE ID S.115oud SL
—
Q
$TART
END
n
m
tv
�
Z
}
OII OL
One Character per box. Wipe W
�'.
_-
U
Q
�
W
z
�
01
ry
y
%O
O
z
C
L
nP
other oT
o
+-
M
S
w
ii
m
Sample Ids must be unique tissue Ts
C
x
r
w
J
z
o
v
O
tti
M
O
'o
O
Z
C)
oZ
0
tC
v?
a
U
m
p
MO
=
L
d
C
Q
E
NTIAT11111
DATE
TIME
x
_
_
=
Z
Z
U
¢
�'
Of
1
i � C'S
w
���,
eFpSa
�j
✓
�/
✓
�
2
3
4
b
6
7
8
16
11
12
ADDITIONAL COMMENTS
RELINQUISHED BY I AFFILIATION
DATE
TIME
ACCEPTED BY I AFFILIATION
DATE
T]ME
SAMPLE CONDITIONS
�]
1'; �
P
20031245.1- A1, As, Cd, Ca, Cu, Pb, Mg, Hg, M., Ni, K. Se, Na, Zn
%LC7
r
SAMPLER NAME AND SIGNATURE
c
>,
m
—
PRINT Name of SAMPLER: SIC f�
N
a
w
U
m m Z
o m
m$}co
SIGNATURE of SAMPLER:
DATE Signed:
Cn
Viv

DCrr_Title: ENV-FRM-HUNJ-0034 v01 Tech Spec Sample Condition
Upon Receipt
f u•rcxhras Effective Data: 05,12.2722
a'nnratnry r¢roivin� � ..I��.
. ." ,.-. ,.r
Asheville ❑ Eden ❑ Greenwood ❑ Huntersv;lle ❑ Raleigh❑ P�1�_hanicsvilie❑ A:1a i,aKern ,
y ] K�rR_r;�ill�
L7 � � C112Rt t113'1"le:
�/V ti IA Project ;
Courier: ❑Fad Ex L,lups ❑USPS ❑Client
❑ Commercial Q/ l ce ❑Othzr: f 1 f
Carrier Tracking Number: d
Custody Sea! Present? ❑Yas ZI0 SeaisIntact? ❑Yes ❑No
Pack:ng Material: ❑Sub! !a wrap ❑Bubble Bags urlone ❑ czhar
Thermometer: ❑ IRGun ID; �T 0 0 Type aflc [ 'Wet ❑Blue
Cooler Temp ('C): 2 • Correction Factor: Add / Subtract ('C) —
Corrected Cooler Temp ('C ): 2- • 6
USDA Regulatad Soil ( E2 N/A, water sample)
Did samples cr;ginate in a quarantine zone within the Unitz:t States: CA, tly, or SC (check maps)?
❑Yes ❑Pia
Chain of Custody Present?
Samples Arrived within Ncld Time?
Short Hold Time Analysis (c72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Contairers Intact?
Dissolved analysis: Samples Feld Filtered?
Sample Labels klatch C0C?
-Includas Date/Time/ID/Anafvsis Ma
Headsoace in VOA Vials (>S-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCRa�ANCY
Temp Log: Temp must be maintained
at<6 C during login, record temp
Every 2D minutes.
Time opened:/ b Q 0 temp: 2, b
Time: ! b a put in cooler
Time: Tema:
Na ❑N/A
No ❑N/A
No MN/A
Lres
L INa
INN/A
6
1�3yes
[IN.❑N/A
6,
tires
❑No
❑N/A
Yas
❑No
7.
❑'la
,,❑]�N/A
ETM/A
18.
Yes
❑No
❑N/A
9.
w w
Eye'
❑No
(25i/A
10.
❑Yas
ONO
(Z-WA
111.
Date/Initials Person Examining Contznts: 'h.f
Biological Tissue Fro'en?
Oyes ❑Pla N/A
❑ iyone
Tamp should be above freezing to E'C
❑Sarnples out of temp criteria. Samples en ice, cooling process
has begun
Cid samples origlnat=_ from a foreign source (internationally,
including Ha:vaii and Puerto Ricz)? ❑yes ❑pia
Comments/Ci4cronamr,..
Lot ID of snit containers:
ULIC+vt 1'4viirlt_AJIUN/RE50LUTl0N
Person Contactzd: Date/Time:
Project Manager SCURF Review: Date:
Protect Manager SRF Review; Date:
Qualtrax Document 1D: 70677
Field Data Required? ❑Yas
Page I of 2
Page 3 of 4

LIL�_11110: tNV-FKM-HUN1-0034 v01 Tech Spec Sample Condition
aCe• Upon Receipt
Effective bate: 05112!2022
*Cher'( mark top half of box if pH and/or dechlorination
is verified and within the acceptance range for
preservation samples.
Excep^ors: VOA, Colif=rm, TOC, Oil and Grease, CrRO/30I5 (water) CCC, LP-H.7
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Project iY
I
1
7
tl
_u
J
G
u
J
G
L
?.i
iJ
-
.`_'
E:J
G7
77n
u
Z
T
O
r�
G
tl
u
—_
n
C
L`
2
v
a
E
U
C
Q
v
U
t7
Q
U
J
t7
C
V
ry
E
¢
_
0
Q
V
-
C
ry
l7
C
Z
LJ
Z
J
ri
L-
G
?
ZZ
Q
a
0
C,
N
(�^a
7
41
V
c
0O
7
E
c
Gil
l7
7
O
?
E
Gl
l^
C
O
0
>G
G�'�
t'7
C]
Zn
]
Cl
_
^-
Q
�
7
d
in
E
•"
LF'1
4
v
m
d
to
E
ry
N
a
vI
n
C�
c
2C
G
E
ry
C
m
_
U
Z_
'-
Z
Q
E
�
Q
E
z
C
E
rCv
C7
7
3
w
Z
E
E
�c
ci
G
�
l
l i2
e�
��
a
5
r
9N\1 I I I I
1 11
1 12
PH Adjustment Lag for Preserved Samples
Sample 10 Type of Preservative pH upon receipt pate preservation adjusted Time preservation Amount of Preservative
adjusted I added
Lot #
Ncte: Whenever there is a discrepancy affecting North Carolina comp(ianc samples, a copy of this form will 6e sent to the North Carolina CENN i Certif cation Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers]
Qualtrax Document ID: 70677
Page 2 of 2
Page 4 of 4

Pace Analytical Services, LLC
ceAnalytical ® 1 South Park Drive
Kernrnersville, NC 27284
www.pacolahs.com [phone]
Page 1 of 2
Laboratory Report
Wilmer Lawson Report Date: 10/06/2022
OWASA Date Received: 09/12/2022
400 Jones Ferry Road
Carrboro, NC 27510
Project: OWASA- Digested Sludge
Pace Project No.: 92624978
Sample: Digested Sludge Lab ID:
Method Parameters
92624978001 Collected: 09/12/22 08:35 Matrix:
Results Units Report Limit
Water
Analyzed Qualifiers
EPA 8081 B
gamma-BHC (Lindane)
ND
ug/L
0.50
09/22/22 13:38 R1
EPA 8081 B
Chlordane (Technical)
ND
ug/L
3.0
09/22/22 13:38
EPA 8081 B
Endrin
ND
ug/L
0.50
09/22/22 13:38
EPA 8081 B
Heptachlor
ND
ug/L
0.50
09/22/22 13:38
EPA 8081 B
Heptachlor epoxide
ND
ug/L
0.50
09/22/22 13:38
EPA 8081 B
Methoxychlor
ND
ug/L
1000
09/22/22 13:38
EPA 8081 B
Toxaphene
ND
ug/L
3.0
09/22/22 13:38
EPA 601OD
Arsenic
ND
mg/L
0.30
09/30/2212:29
EPA 601OD
Barium
ND
mg/L
0.50
09/30/2212:29
EPA 601OD
Cadmium
ND
mg/L
0.10
09/30/2212:29
EPA 601OD
Chromium
ND
mg/L
0.10
09/30/2212:29
EPA 601OD
Lead
ND
mg/L
0.25
09/30/2212:29
EPA 601OD
Selenium
ND
mg/L
0.40
09/30/2212:29
EPA 601OD
Silver
ND
mg/L
0.10
09/30/2212:29
EPA 7470A
Mercury
ND
mg/L
0.0050
09/30/22 13:20
EPA 200.7 Rev 4.4 1994
Aluminum
1370000
ug/L
2500
09/21/22 13:18
EPA 200.7 Rev 4.4 1994
Arsenic
111
ug/L
50.0
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Cadmium
26.6
ug/L
5.0
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Calcium
459000
ug/L
500
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Copper
7840
ug/L
25.0
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Lead
304
ug/L
25.0
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Magnesium
128000
ug/L
500
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Molybdenum
137
ug/L
25.0
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Nickel
364
ug/L
25.0
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Potassium
198000
ug/L
25000
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Selenium
156
ug/L
50.0
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Sodium
142000
ug/L
25000
09/19/22 15:30
EPA 200.7 Rev 4.4 1994
Zinc
20300
ug/L
50.0
09/19/22 15:30
EPA 245.1 Rev 3.0 1994
Mercury
0.60
ug/L
0.20
10/06/22 09:24
EPA 8270E
1,4-Dichlorobenzene
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
2,4-Dinitrotoluene
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
Hexachloro-1,3-butadiene
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
Hexachlorobenzene
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
Hexachloroethane
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
2-Methyl phenol(o-Cresol)
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
3&4-Methylphenol (m&p Cresol)
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
Nitrobenzene
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
Pentachlorophenol
ND
ug/L
100
09/22/22 20:02
EPA 8270E
Pyridine
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
2,4,5-Trichlorophenol
ND
ug/L
50.0
09/22/22 20:02
EPA 8270E
2,4,6-Trichlorophenol
ND
ug/L
50.0
09/22/22 20:02
EPA 8260D
Benzene
ND
ug/L
100
09/22/22 08:36 Page 1 of 11

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Sample: Digested Sludge
Lab ID: 92624978001 Collected: 09/12/22 08:35 Matrix: Water
Method
Parameters
Results
Units
Report Limit
EPA 8260D
2-Butanone (MEK)
ND
ug/L
200
EPA 8260D
Carbon tetrachloride
ND
ug/L
100
EPA 8260D
Chlorobenzene
ND
ug/L
100
EPA 8260D
Chloroform
ND
ug/L
100
EPA 8260D
1,4-Dichlorobenzene
ND
ug/L
100
EPA 8260D
1,2-Dichloroethane
ND
ug/L
100
EPA 8260D
1,1-Dichloroethene
ND
ug/L
100
EPA 8260D
Tetrachloroethene
ND
ug/L
100
EPA 8260D
Trichloroethene
ND
ug/L
100
EPA 8260D
Vinyl chloride
ND
ug/L
100
SM 2540B-2015
Total Solids
26000
mg/L
500
EPA 350.1 Rev 2.0 1993
Nitrogen, Ammonia
1530
mg/L
25.0
EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
2460
mg/L
100
EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
1.4
mg/L
0.040
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
1.1
mg/L
0.040
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrite
0.29
mg/L
0.040
EPA 365.1 Rev 2.0 1993
Phosphorus
1150
mg/L
25.0
ANALYTE QUALIFIERS
R1 RPD value was outside control limits.
Reviewed by:� "
Stephanie Knott
704-977-0981
[e-mail]
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Peachtree Corners
110 Technology Pkwy, Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
Analyzed
09/22/22 08:36
09/22/22 08:36
09/22/22 08:36
09/22/22 08:36
09/22/22 08:36
09/22/22 08:36
09/22/22 08:36
09/22/22 08:36
09/22/22 08:36
09/22/22 08:36
09/14/22 17:18
09/30/22 13:05
09/30/22 06:39
09/14/22 01:46
09/14/22 01:46
09/14/22 01:46
09/30/22 19:23
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water#: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Certification #: 381
South Carolina Certification #: 98011001
Page 2 of 2
Qualifiers
Page 2 of 11

U
= I
L) a
❑ U
N
a
E
c4 ga
U 2
R
�. F
aw
O
0 ❑
LLU
J
LL $
O�
Z c�
VL
U
H
�
V m
yaeyul
N
saldweS
U Y
U Z
p
w
¢ 0
E
i
J
�`1
�B00 J
paleaS
Q T
a
U
Lam-)
(N1Ai
�
m
.4
a
a n`i
4
O1
uo paniaoald
(NIA) auuoWC) lenp!saa
is
�
0)\
_
�
�
o
�
O U! dW31
a
�
y
■
�
o
°
Z
z
F
i
d101
x
=�
a
g
sP!io51elo1
x
sruoydsoyd lefol
x
¢
ry
a
.1
ua6oJ41N ZON+EON
x
ti
e
G�
v
ua5a4!N 0117!N
x
m
a
ua50AIN OMAIN
x
o
a
a
a)
cy
u05WI!N z!IuDw V
X
U
Q
NA1
x
o
s!e2aya
x
Q
Z
�
m
o
O
�
1EiA
39��i��tl
a
U
}
m
v
,6
c
ja41O
e
m
o
a
IOULLpvj
SOZSZRN
ym
7
V
1
HORN
J
m
c
Z
w
�L1
IOH
o
O
o
ro
`7
I,L
ELE
BONH
_
LU
\V
O
O
pamesaadun
m
a`
0-
ni
u
w
E
n.
U.
F
en
¢
U¢
a
d
d
Sa3NIV1N00 d0 �Y
m
NaiD311001V dVY31711dWVS
s�
Z
Q
a
a
2
LL,
a
Q
z°
sn
`°
rn
z
w
It
a
O
Q
N
Q
E
cl
2
Z
Z
Ln
p
C
LL
Q
C
m
.:�yx
G
�
S
a
- ti
(d Nf6a=0 9Vi1J=01 3dAi 31dWV5
�
y
�
it
�
6
2
J
(yak of sapo� piles aesy 3400 XILIltlW
�
m��
Hui
3
U C'
0
a
s
N
O
N
O
110� 0. �IOQ O F
m0:
Of
v
I
1a
s
a`
v
_
as a ✓4i a¢ a r
O
o
O
w
9
Q
�
�
Q
�
a
W
U
m
0
° a
Q
cc
LO
`o
,
a
LL
N
LU 0.~
cd
N
J
¢
u
9�?oN
d
F
4
t
a�
g
a�
giE
c
N
OI��
O
m
Arno
m
p
(n
ur
0
C
f
n
# wall
w
�
U
Page 3 of 11

DC'M_Titfe: ENV-FR,M-HLJN1-0084 V01 Tech Spec Sample Condition
Upon Receipt
I Effective Date: 05,1Z.'2�22
Laboratory receiving samples:
Asheville ❑ Eden Greenwood 0 HuntersvHle Ralaigh� Machanicsv'slle] % 3anta� Karnersville%f
- Client `fame:
�- 19 W a f Q Project" :
�iy eJ f
Courier, ❑red Ex IJU?5 ❑ US?5
❑ Commercial lzpace ❑Client
❑Other, �' �
Carrier Tracking Number:
Custody Seal Present? ❑Yes P!c Seals Intact? ❑Yes ❑Na
Packing Rilaterial: Elsubble wrap yubble flags ❑rfene
❑ Cthar
Thermometer: ❑ IR Gun ID:
`1 Type of ICE!: ki wat ElP!ue El?Jona
Cooler Temp ('C ): 7 ' l Correction Factor. Add / Subtract (°C)
Temp should be ahcve freezing to 6°C
Corrected Cooler Temp (°C ): (• ❑Samples out of tamp cr!taria. Samples en ica, tooling
USDA Regulated Soil ( ❑ N/A, water sample)
has be -Tin prccass
Did samples iginat in a quarantine zone within the Unitad States: CA, NY, or SC (check maps)? Did samples orig!nate- from a foreign sour -,a (intern nal}
❑Yes / No
indudirg Ha.vaii and Puerto Ricap ❑yes No
I Comments/Discra-pancv:
Chain of Custody Prsent?
Elves
❑ND
❑N/A
1.
Samples Arrived within Hold Time?
Snort Hold Time Analysis (<72 hr.)?
{}jres
❑Yes
nNo
ffJN❑
❑NIA
❑N/A
2.
I R,
Rush Turn Around Time Requested?
❑Yes
&0
❑N/A
14.
Sufficient Volume?
[KY,s
❑NO
❑N/A
Correct Containers Used?
-Pace_ Containers Used?
Oyes
15Yes
[]No
❑No
❑N/A
❑N/A
15.
6
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Klatch COC?
QYes
❑Yes
Zryes
ONO
ON,
❑Nv
❑rl/A
NIA I
❑n/A
7.
S.
9.
-[riciudes Date/Time/ID/Analysis Matrix:
p
V 1
Headscace in VOA Vials (>S-Gmm)?
Trip Blank Present?
Trio Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
Dyes
Oyes
Dyes
❑No
❑No
ONO
NIA 110,
�N(A
[?N/A
11.
Temp Log: Temp must be maintained
at <5 C.during login, record temp
every 20 minutes.
Time opened:/ / Q Temp: . p
Time- ILI2D put in cooler
Time: Temp:
Person Contacted
0
Project Manager SCURF Review:
Project Manager SRF Review:
Qualtrax Document ID: 70677
Date/Initials Person Examining Contents:
8iciegical Tissue Frozen? �y
❑Yes ON' Z7I/A
Field Data Raquired?
Lot ID of crlit
CLIENT NOTiFICAT]ON/RESOLUTIOPJ
Date/Time:
Date:
Date:
Page 1 Of 2
Page 4 of 11

_ ;acekalytical
Document Name:
Bottle Identification Form (BIF)
Document Issued: November 15, 2021
Page 1 of 1
Document No.:
F-CAR-CS-043-Rev.01
Issuing Authority:
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
Project #
0wftll�
cj1C� ¢fie d fjv��{y2
n
U
U
U
z
q
X
•�
m
E
Z
U1
>
J
E
n�i
.a
7
m
Z
a
c
>
J
E
Ln
N
m
Z
N
>
_
J
E
o
N
7
ro
Z
,
a
a
=
..y
m
N
V
O
2
E
rev
ti
L"
m
V
Z
z
u
E
N
Z
m
_
CD
Z
°6
a
z
u
E
ry
�.y
N
m
n
O
Z
J
E
N
e-1
m
m
Q-
7
N
t7
�_
6
j
Z
-o
Q
E
a
m
Y
'i
7
.-�
0
¢
¢
S
E
¢
w
=
.-1
=
,1
C7
d
a
Z
--�
d
NT
c
a
J
E
N
7
M
l7
d
—
V
n
V
O
N
2
E
¢
v
=
.-[
vs
.i
l7
d
_
N
V
O
x
¢
E
o
N
LA
rn
0
d
¢
Z
V
Z
E
a
E
I
m
d
e*f
0
¢
Z
_
U
2
>
E
o
2
of
V)
O
Z
O
Z
O
>
J
r
s
C7
>
¢
N
Q
v
c-
a
>
E
o
q
7
m
l7
>
¢
c
o
,art
p
>
of
V
a
m
W
d
a
ate+
0
a
�.
sc
d
O
>
Z
=
a
ate.
y
G
•i
m
Y
l7
>
'—°
Z
W
_�
a
l%1
E
ry
F-
Fn
N
j2
N
z
a
t/1
E
In
FL
H
Ln
M
Z
"
a
E
o
�'
d
m
Ca
w
5
c
d
E
a
r-1
Z
c
o
•�
.p
E
"
7
j
z
W
N
a
E
¢
E
�
o
1
N
X
\�
\\\�
T
2
\\N
4
5
6
7
1\\��9
10
11
12
�LNN
N��:��
N�J
PH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot tt
i
Note: Whenever there is a discrepancy atfecting North Carolina compliance samples, a copy of this form wilf be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 5 of 11

ANALYTICAL ENVIRONMENTAL SERVICES, INC.
AES
September 22, 2022
Stephanie Knott
Pace Analytical
1377 South Park Dr
Kernsville NC 27284
RE: 92624978
Dear Stephanie Knott: Order No: 2209E26
Analytical Environmental Services, Inc. received 1 samples on 9/14/2022 9:56:00 AM
for the analyses presented in following report.
"No problems were encountered during the analyses except as noted in the Case Narrative or by qualifiers in
the report or QC Summary. Additionally, all results for the associated Quality Control samples were within
EPA and/or AES established limits.
AES' certifications are as follows:
-NELAP/Florida State Laboratory ID E87582 for analysis of Non -Potable Water, Solid & Chemical Materials,
Air & Emissions for Organics, and Drinking Water Microbiology & Metals, effective 07/01/22-06/30/23.
-North Carolina Certification number 562 for analysis of Surface Water, Groundwater, Effluent, effective until
12/31/22.
-South Carolina Environmental Laboratory Certification number 98016003 effective until 6/30/23.
These results relate only to the items tested as received. This report may only be reproduced in full and with
written permission from the laboratory.
If you have any questions regarding these test results, please feel free to call.
Sincerely,
Harts Bejdic
Project Manager
3080 Prev,;Lniial Atlanta, Georgia S0340 - Tel: [phone] - Fax: [phone] • Toll Fretie.800.972.4389
www.aesatlanta.com Page 6 of 11
Page 1 of 6

Chain of Custody
PASI Charlotte Laboratory
Workorder Name: OWASA - Digested Sludge
Stephanie Knott
Pace Analytical Kernersville
1377 South Park Drive
Kernersville, NC 27284
Phone [phone]
Email: [e-mail]
State of Sample Origin: NC
Monday, September 12, 2022 6:40:10 PM
AES
3080 Presidential Dr.
Atlanta, GA 30340
9/12/2022 08:35 192624978001 1 Water
P.O. SJK92624978
Date/Time R cei ed By
f� a
°C Custody Seal Y or N Reci
z W9 eIZ (0 - -..dft
aceAnaljftal
www.pacelab$.com
Results Requested By: 9/26/2022
Y or N
FMT-ALL-C-002rev.00 24March2009
LAB USE ONLY I
Intact Y
Page 1 of 1
Page 7 of 11
Page 2 of 6

Analytical Environmental Services, Inc
Date: 22-Sep-22
Client:
Pace Analytical
Client Sample ID:
DIGESTED SLUDGE
Project Name:
92624978
Collection Date:
9/12/2022 8:35:00 AM
Lab ID:
2209E26-001
Matrix:
Aqueous
Reporting
Dilution
Analyses
Result
Qual
Units BatchID
Date Analyzed Analyst
Limit
Factor
HERBICIDES, TCLP SW1311/8151A
(SW3510C)
2,4,5-TP (Silvex)
BRL
0.20
mg/L 343155
1
09/16/2022 21:15 TB
2,4-D
BRL
0.20
mg/L 343155
1
09/16/2022 21:15 TB
Surr: DCAA
68.4
48-120
%REC 343155
1
09/16/2022 21:15 TB
Qualifiers: a
value exceeds maximum contaminant level
BRL
Belowreporting limit
H
Holding times for preparation or analysis exceeded
N
Analyte not NELAC certified
B
Analyte detected in the associated method blank
>
Greater than Result value
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
Nan Seecasenanative
F Analyzed in the lab which is a deviation from the method
< Less than Result value
J Estimated value detected below Reporting Limit
Page 8 of 11
Page 3 of 6

m
L.
V
ka
N
W
01
O
N
N
a
Z
N
0
CA
a
a
z
O
z
N
U U
v' v'
m m
N N
E E
v 00
N N
O O
U U
0 0
U U
o o
L1 N
7 7
m m
0. 0.
N �
N N
0 0
U U
o o
N
v v
N N
O. 0.
♦- ♦- N
u7 d
N N £
U U U
ni m y u'i 6 r; o0 of o 4 ry mi v u'i
a
t
N
C
C
N
L
3 ❑
0
c
a
� N
u C
O
t c
3 0
U
ai o2S
C N
n0 £
in
N N
u n
a
N F
0.
m �
❑ N C
� N
0
Elc °1
ai u
c o
�C p•
a1Oi o -a
a �
❑ u
m
+= ❑ c
� c '
c
0o a�i c
a U O w
0
cc .03s-*Iscc
• • • O • • -
C,C,
u
o v
v a
� c
m
a a
c �
M N_
n• £ o'
C C
O •U1
N
C ai ai
ou n. �• 3 �
cn• U
N a op
0 ro � ai n• c
c £ 0
o 0
u c a L
C OD E ++ 0 -
_ +_
u n c v� 3
N a G a-� H a-� ++
H C L N m m a
ai n•
v U
C E U d u U
C ¢ v a gap w
N w
ad
c � �
m 0. m 'L v o o ai 0 0
N N N W }, }a
C N
. L1 N N m
0 N N = £
O7 7 m Vl Y
N I ++ N a., U U C_
OD
O. O O O. Ul ❑• C C O.
p N N
+� +� £ 75 a£i m m £ F
H U U F U ++ U U V,
a
z
O
z
❑ ❑ ❑
U
El El
Ou O
C c
v 0 >
o —
0 0 0
C C c
El El O
O j 0
S U
y 0
ai —
o ai a�i a�i o
0 0. n a
C C N N N
.O 0*3*
0 O cflo(�o
• 0 • 0 *a�
n•
N N
ai a
c �
m -
a 4
n• ai 14
a m H
n F U c c
m L n U n 0.
U UU U O m
u N Ou a2 0 O v u ai
Ll C N U C £ O L
C. up O L 0 +' £ 0 0
N u +u+ N C N O 75
u ❑. 0) m mCL 0. 3
ai
m i= o. E u 0) m£ 0. a �•.
C N £ Mn a
m N C N C
p N C
O C p '—° aai ai o v ai aLui E
s C 0 y o v u> a
N 7
C N y C 7 m uu
O C +m+ rr
u N N L1 ❑• N
n C ai ai o. v Y
N 0 N +L+ N m m
m m U N
a
to to H H 0. i H 01 m 0.
C m t N N i ++
N 0 0 H ,p N H 3 N w N
ai ai ai m a w ai ai
U U ❑ a ❑
r
N
V
ei
m
2
U
a
z
O
z
CN
N
m
2
U
w
N
w
= w
a o,
c
u
H
m12 W
06 c d
O
0 u
c t O
J
m
U
d
O u
t6 r; o0 . of o 4 ry mi v m ,o r; 00 of c 9e
ei 14 a -I N N N N N N N N N N
1
PC
G
f11 u
a
z
O
z
❑ ❑ ❑
U
El El
Ou O
C c
v 0 >
o —
0 0 0
C C c
El El O
O j 0
S U
y 0
ai —
o ai a�i a�i o
0 0. n a
C C N N N
.O 0*3*
0 O cflo(�o
• 0 • 0 *a�
n•
N N
ai a
c �
m -
a 4
n• ai 14
a m H
n F U c c
m L n U n 0.
U UU U O m
u N Ou a2 0 O v u ai
Ll C N U C £ O L
C. up O L 0 +' £ 0 0
N u +u+ N C N O 75
u ❑. 0) m mCL 0. 3
ai
m i= o. E u 0) m£ 0. a �•.
C N £ Mn a
m N C N C
p N C
O C p '—° aai ai o v ai aLui E
s C 0 y o v u> a
N 7
C N y C 7 m uu
O C +m+ rr
u N N L1 ❑• N
n C ai ai o. v Y
N 0 N +L+ N m m
m m U N
a
to to H H 0. i H 01 m 0.
C m t N N i ++
N 0 0 H ,p N H 3 N w N
ai ai ai m a w ai ai
U U ❑ a ❑
r
N
V
ei
m
2
U
a
z
O
z
CN
N
m
2
U
w
N
w
= w
a o,
c
u
H
m12 W
06 c d
O
0 u
c t O
J
m
U
d
O u
t6 r; o0 . of o 4 ry mi v m ,o r; 00 of c 9e
ei 14 a -I N N N N N N N N N N
1
PC
G
f11 u
N
V
ei
m
2
U
a
z
O
z
CN
N
m
2
U
w
N
w
= w
a o,
c
u
H
m12 W
06 c d
O
0 u
c t O
J
m
U
d
O u
t6 r; o0 . of o 4 ry mi v m ,o r; 00 of c 9e
ei 14 a -I N N N N N N N N N N
1
PC
G
f11 u

Analytical Environmental Services, Inc
Date: 22-Sep-22
Client: Pace Analytical ANALYTICAL QC SUMMARY REPORT
Project Name: 92624978
Workorder: 2209E26 BatchID: 343155
Sample ID: MB-343155
Client ID:
Units: mg/L
Prep Date: 09/15/2022
Run No: 496630
SampleType: MBLK
TestCode: HERBICIDES, TCLP SW I31I/815IA
BatchID: 343155
Analysis Date: 09/16/2022
Seq No: 11604827
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
2,4,5-TP (Silvex) BRL 0.20
2,4-D BRL 0.20
Surr: DCAA 0.3154 0 0.5000 63.1 48 120
Sample ID: LCS-343155
Client ID:
Units: mg/L
Prep Date: 09/15/2022
Run No: 496630
SampleType: LCS
TestCode: HERBICIDES, TCLP SW I31I/815IA
BatchID: 343155
Analysis Date: 09/16/2022
Seq No: 11604826
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
2,4,5-TP (Silvex)
0.3177
0.20
0.5000
63.5
50.8
120
2,4-D
0.3039
0.20
0.5000
60.8
50
120
Surr: DCAA
0.3027
0
0.5000
60.5
48
120
Sample ID: 2209B57-008AMS
Client ID:
Units: mg/L
Prep Date: 09/15/2022
Run No: 496630
SampleType: MS
TestCode: HERBICIDES, TCLP SW I31I/815IA
BatchID: 343155
Analysis Date: 09/16/2022
Seq No: 11604819
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
2,4,5-TP (Silvex)
0.3567
0.20
0.5000
71.3
50.5
120
2,4-D
0.3584
0.20
0.5000
71.7
47.1
120
Surr: DCAA
0.3517
0
0.5000
70.3
48
120
Qualifiers: > Greater than Result value
BRL Below reporting limit
J Estimated value detected below Reporting Limit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitation range)
N Analyte not NELAC certified
S Spike Recovery outside limits due to matrix
B Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 10 of 11
Page 5 of 6

End of Report
Page 11 of 11
Page 6 of 6

aceAnalytical
www.pacolahs.com
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Wilmer Lawson
OWASA
400 Jones Ferry Road
Carrboro, NC 27510
Project: OWASA- Digested Sludge
Pace Project No.: 92635063
Sample: Digested Sludge
Method
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
EPA 245.1 Rev 3.0 1994
SM 254OB-2015
EPA 350.1 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
ANALYTE QUALIFIERS
Laboratory Report
Page 1 of 1
Report Date: 12/14/2022
Date Received: 11/07/2022
Lab ID: 92635063001 Collected: 11/07/22 09:45 Matrix: Water
Parameters
Results
Units
Report Limit
Aluminum
1130000
ug/L
2000
Arsenic
ND
ug/L
100
Cadmium
17.9
ug/L
10.0
Calcium
500000
ug/L
1000
Copper
5160
ug/L
50.0
Lead
234
ug/L
50.0
Magnesium
141000
ug/L
1000
Molybdenum
ND
ug/L
50.0
Nickel
304
ug/L
50.0
Potassium
215000
ug/L
50000
Selenium
ND
ug/L
100
Sodium
160000
ug/L
50000
Zinc
19900
ug/L
100
Mercury
0.77
ug/L
0.40
Total Solids
20100
mg/L
2500
Nitrogen, Ammonia
2080
mg/L
25.0
Nitrogen, Kjeldahl, Total
2520
mg/L
100
Nitrogen, NO2 plus NO3
0.66
mg/L
0.040
Nitrogen, Nitrate
0.61
mg/L
0.040
Nitrogen, Nitrite
0.046
mg/L
0.040
Phosphorus
1170
mg/L
25.0
Analyzed
12/12/22 21:06
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
12/08/22 12:34
11 /28/22 10:27
11 /09/22 16:12
11/14/22 16:12
11/18/22 06:34
11 /09/22 01:18
11 /09/22 01:18
11 /09/22 01:18
11/18/22 20:32
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
Reviewed by:
Y
Stephanie Knott
704-977-0981
[e-mail]
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
D3
D3
D3
Qualifiers
Page 1 of 4

N
ca
co
O
0 U
.A
N m
E
W �
7
C)
> Q
Z
aZ
00
0
H Q
N w
J
� N
LL T
oB
1 N
a
2 C
U�
U
N
L
z
(NIA)
U ai
13e101
m
to
saldweS
U 1
Z
N!A
F
O
N o
jaloPO
¢
2
papas
V
R Plsn
(N/A)
u
o
m
'mom
CL
aOl
�,
o
a
2L 1
<
uo PaApoab
e
�
�
(N/A) aUPONO lenPisay
d
O Ol dW31
a
2
LU
U
x
V
F
~,
2
SP11Os lelal
x
's
a.l
"v
snloydsoydelol
X
Q
O
uOf3-;'N ZON+£ON
x
m
ua6a1!N a;uRN
x
a
e
m
uA0A!N 81e41N
x
a
u08011EN e!uowwy
x
Z
N
j
NNI
x
4
Q
Z
J_
tv
O`
0
slelaA
x
u
NIA
ISO.l sas BUV
m
c)
E
Aa410
a`�
c
in
o
m
ani
aueylaVj
F
�
£4ZSZeN
m
�
67
a,wy
L
7
U
HOeN
C
(
Q)
O
IOH
o
E
O
m
�+
m
a
d
1
£ONH
T
E
N
m
Z
U c
CO
w
o
W
.�
V
panjasaiduN
N
Va
O
E
-o
m
m
m
f
sa3NivlNaO do a
U3 S
a
0
a
a
d
a
NOil1V dW3i a-16wvs
l
r
a
a
�
z
rn
z
a
`o
0
o
7
w
z
i
w
U
z
O
4
ui
w
O
r
4
y
C
4
GEnal
m
(dwOO-O evaO-01 3dA13ldWtl5
U
w
N
E
H
`
m
7 ?
a z
J
(URl oy sapw WW aas) 3000xla1VW
a`
o
E
F
LU
lD p
C d
W
o
~
N
z
z
rr
PUO$a w0 �¢OF
m a
�
a
a
o
c)
ld
T
o33amo3aOF
o
U
D
L_
a
�
Q-
C
O
a
z
�
Y
4
z
w
V
~
_
Q
LL
'G
r
='
Q.
ca
otf
n�i
i
W a
u
c
mo
ca
U
ca
�y
J �`a m
a u o E
a
O
N
a=
CO
r
L? a
a�
7
O
a
Or
T
ca
30
0
U)
CD
3
a
U
N
y
U
Q a
''
cm
u
o
0
# INUI
r
ev
M
v
rn-
{O
r.
ea
O1
p
a'
1
E
'I
U
4
w
a
w
�j
Page 2 of 4

I vuoSam to C
_ 4 VU _I ec Spec � ondition
�Ce' U{aon Receipt
I I ..•�K,,,: 1 E-ec�i`re C3:a: C3,12.�.�„
d.aboratory receiving samples:
AShevifi_ e Gre-3,n voa e
E� n � d [� 1--lt:rt rs'rille Ralei�hl P?� „�r.itsri, F,tla�
t3J Ker,ar•rill��Vr
M7 I �22 -- C) �—J )&A Praj-2ct 4-1
Courier: C; d EX ❑U?5 EIUSrs ❑CIi2r;
❑ Cccrne: oaf `3c ❑other:
Carrier Tracking ,Number;
Custody Seal Present? Se315 Jntact? ❑Y25 ❑^Jc
Pac:c r,; blot=rial: 03uL'Zfe V,'rar ❑Bu�Je Bats ❑
Thermcmeter: Elm, m
Ca",�; Initials Person Examining Contents
Bicicgical Tis3ue Frozen?
❑Yes ❑ IO Vjr'A
j��
un TINa a ;lce: Prat ❑ =lue
❑ }
y ��``
CcelerTemp I°C ): - i Correction Factor: Add / Subtract (-C) —^-V
�( T2mp should be a�eve freeing kc 6'C
Corn_c zd Ccalzr Tamp ('C ): Tf ❑Sar plzs cut eF tap p critzrid. Samples en ice. cooling process
USDA Regulated Soil ( Vl/A, watarsample) has
(aid sampl. or: --irate in a quarntina zone witi`in the Unitad Sta`=_s: CA, NYS4
❑Y2s , er(che=!k r maps )?
Cid samples ori&at FrCm a Far=_i,n sour-- (',nt=maa nil ,
inc!udir, Havrsil and Puer<c Rica)? ❑ya5 ?
I
CCmn',e Rts/I:ils[r2'3anCV]
Chain of Custody Present?
w'fes
❑No
I]N/a
Samples Arrived within Hole T-ime?
d=5
i�rao
❑r„a
Short Held T;me Analysis (<72 hr,)?
L'fes
❑r!o
❑N/a
Rush Turn Around Time Req-Les`2d?
❑Y=s
tSerJo
❑N,'A
SufficentVolume?
Lv�'l-s
ONO
C3N/A
Correct Containers Used?
2�es
ONO
❑N/A
-Pace CRrtainers Used?
❑No
N/
❑A.
Cantairersintact?
--//,s
EZ-KEs
❑;la
❑N;s
Cissa!v=_' analysis: Samples Field FiIt?r2d?
❑'r`es
❑Nod
Sample La�;s (Match COC?
��r::
❑N,'
-IncludesDaterFTme/ID/Anafwis
iI❑No
H'-- space it VOA Vials f>5-6mm)?
❑Yes
I-1No
p s,
Trip Mani Present?
❑Yas
❑Na
/A
Trio Blank Custody Seals Present?
❑Yas
❑rlos
CONIMENT51SA,MPLE DISCREPANCY
Tamp Log: Tamp must be maintained
at <6 C during login, record temp
every 26 minutes.
Time opened: emp:
Time: put in cooler l
Time: Temp:
Person Contacted: ,
j
Project Manager SCURF Review:
Project Nlana,er SRF Review:
—QUa(trax Document ID: 70677
Lot ID of Split containers:
—Ll4i Ivvllr)LA[IUN/RESOLLiTION
031-- me:
Date:
Date:
Field Data Raquired? ❑Yes ❑No
Page 1 of 2
Page 3 of 4

---------------------
CC: I'jme
K�aeSC3nen Se
Reme:re
m £2 C-h3!7c.b2« 2 pH �:2/eza= a 2 6. gone
»e 7,land wi\ in Ae.3 s n:: en;! for R Sa&3S:n
s; m ales.
2'if-rrn,r C, Cil 7 D G25{ :2CCC, ;
.�aee:m h3fcfbcxb to btnu meJ Q Boa g
P,c)e=t %
\
\
\
\
\
\
\
\
—I,- N
�3 \
NN
( ^
` N I I
N���
—jo N F�
I |
1 !! NI I
NN
I2N I I
.
3c\ w\ay
Ea Gy>=2>Efa
pH Adjustment Log for Praserve am /eG
arR»e Typeca.rin we PewereGr esPrL=menadjusted zmePresemen Amount am m
mmw I added
Lot
. .� I | —
No": Wheneverm R,a 3a. ,a±g wad Ca , oEna complianrz samples, a of w<»m +e,sa to m,«� Carolina ee 9 R< 2no , .
Out Re m,m=,ez out a @mrmom = ens ,e
Page 4of4