WQ0041666_2022 Residual Annual Report_20230228 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0041666
Applicant/Permittee EMA Resources, Inc.
Email Notifications
Does this need review by the hydrogeologist? * Yes U No
Regional Office Winston-Salem
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Brent Collins
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
336-399-3646
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0041666
Has Current Existing permit number
Applicant/Permittee Address*
755 Yadkinville Rd, Mocksville NC 27028
Facility Name*
EMA Resources Class A Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 EMA Resources Inc. Annual Report - WQ0041666.pdf 10.42MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/28/2023

February 28, 2023
DENR/Water Quality Section
Non -Discharge Compliance Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2022 Annual Report — EMA Resources Inc.
Treatment and Land Application of Residuals
Permit No. WQ0041666
Dear Sir or Madam:
Enclosed is the 2022 Annual Report for the above referenced land application permit.
During 2022 EMA Resources, Inc. land applied 2169.1 total dry tons of wastewater
residuals to 338.06 acres of private farmland.
Please contact Brent Collins - Director of Technical Services if you have any further
questions regarding this report.
Sincerely,
Brent Collins
Director of Technical Services
brent.collins2emaresourcesinc.com
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

--Resources, Inc.
EMA Resources Inc. - DCAR
2022 Annual Report
Residuals Land Application
Permit No. WQ0041666
Prepared By:
EMA Resources, Inc.
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0041666 FACILITY NAME:
PHONE: [phone] COUNTY:
Davie
OPERATOR:
EMA Resources Inc.
EMA Resources Inc.
FACILITY TYPE (please check one): 0 Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
® Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes ® No 0 -op- If No skip parts A, B, C and certify form below
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
February
March
April
May
June
July
August
September
October
November
December
Total from FORM DMSDF (sup)
0
2169.1
2169.1
2169.1
Totals:
Annual (dry tons):
0
2169.1
2169.1
1
2169.1
Amendment(s) used: I I Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l 0
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit 0 Yes
(including but not limited to items 1-3 below) issued by the Division of Water Quality: ❑ No 0 If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality.
No contravention of Ground Water Quality Standards occurred at a monitoring well.
"1 certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. 1 am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Erik Blankenship (Feb 9, 2023 09108 EST)
Signature of Permittee
Feb 9, 2023 C011Il1f
Brent Collins (Feb 9, 2023 11:59 EST)
Date Signature of Preparer**
(if different from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Feb 9, 2023
Date
DENR FORM DMSDF (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Supplemental Information
WQ PERMIT #: WQ0041666 FACILITY NAME:
PHONE: [phone] COUNTY: Davie
EMA Resources Inc.
OPERATOR: EMA Resources Inc.
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
❑,► Distribution and Marketing (complete Parts A, and B)
Part A*:
Part Bx:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry
tons)
Intended use(s)
March
Piedmont Water
310.82
310.82
Gene Hiatt
310.82
Soil Amendment
May
Lear Corp.
117.97
117.97
Donnell Kornegay
117.97
Soil Amendment
June
Brown WTP
619.45
619.45
Larry Rogers
619.45
Soil Amendment
July
Piedmont Water
59.65
59.65
Gen Hiatt
59.65
Soil Amendment
August
Brown WTP
246.99
246.99
Roy Carver
246.99
Soil Amendment
August
Piedmont Water
49.9
49.9
Gene Hiatt
49.9
Soil Amendment
September
Lear Corp.
146.17
146.17
Nicholas Edwards
146.17
Soil Amendment
October
Brown WTP
324.83
324.83
Kenny McMahan
324.83
Soil Amendment
October
Brown WTP
70.62
70.62
Ted Oakley
70.62
Soil Amendment
November
Piedmont Water
222.7
222.7
Ryan Hiatt
222.7
Soil Amendment
Totals:
Annual (dry tons):
0
2169.1
2169.1 2169.1
Amendment(s) used:
Bulking Agent(s) used:
(supp)): Total Number of Form DMSDF (Supp)l 1
* If more space is required, attach additional information sheets (FORM DMSDF
DENR FORM DMSDF (Supp) (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WQ0041666
EMA Resources Inc.
NC0332010-PO1
WWTP Name: Wade G Brown WTP
Residual Analvsis Data
Laboratory:
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
(mg/kg)
Conc.
Limit
(mg/kg a
Sample or Composite Date
1/3/22
5/11/22
7/8/22
10/3/22
Percent Solids (%)
NA
21.9
21.1
18.8
21.5
Arsenic
75
16.1
1.26
5.31
38.1
Cadmium
85
0.913
5.21
19.5
0.67
Copper
4,300
363
573
1620
2610
Chromium
NA
10.8
13.6
12
12.7
Lead
840
11.5
13.2
14.2
16.2
Mercury
57
0.0316
0.0502
0.0369
0.0698
Molybdenum
75
6.16
3.1
4.31
4.36
Nickel
420
29.2
58.8
56.4
107
Selenium
100
14.6
30.3
17
7.44
Zinc
7,500
37
67.3
64.9
169
Total Phosphorus
NA
991
986
830
814
TKN
NA
10300
8290
9890
7400
Ammonia -Nitrogen
NA
280
1000
1150
411
Nitrate and Nitrite
NA
30.9
338
34
20.9
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Z�fz 2/8/2023
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
WQ0041666
EMA Resources Inc.
NC0332010-PO1
Wade G Brown WTP
Laboratory:
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
Sample or • • • - Date
• 1
1. 1 1
1
• 1
--------
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
2/8/2023
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

Waypointo
ANALYTICAL
1 /12/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-004-0031
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 1/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2022
Arkansas
State Program
88-0650
02/07/2022
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-004-0031
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-004-0031
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97025 Brown W FP Solids 01/03/2022 12:40 01/04/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-004-0031
Date: 1 /11 /2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 97025 (Brown WTP)
QC Batch No: 1-593850/1-593519
This sample was analyzed at a dilution due to IEC interference/matrix interference.
Analyte: Aluminum
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97328
Analyte: Arsenic
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 97328
Analyte: Calcium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97328
Analyte: Chromium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97328
Analyte: Iron
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Potassium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97328
Analyte: Manganese
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 97025 (Brown WTP)
Analyte: Lead
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Analyte: Mercury
QC Batch No: 1-593529/1-593334
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number : 22-004-0031
Lab No : 97025
Sample ID: Brown WTP
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
REPORT OFANALYSIS
Report Date : 01/12/2022
Received : 01/04/2022
Danyale Love
Project Manager
Matrix: Solids
Sampled: 1/3/2022 12:40
Test
Results
Units
MDL
MQL
DF
Date / Time
Analyzed
By
Analytical
Method
Moisture
78.1
%
0.010
1
01/04/22 16:05
FMM
SW-DRYWT
Ammonia Nitrogen
2803
mg/Kg -
dry
73.1
457
1
01/11/22 13:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
30.9
mg/Kg -
dry
22.7
22.7
1
01/10/22 15:17
ZBD
4500NO3F-2011
Organic N
99953
mg/Kg -
dry
758.0
1
01/11/22 13:30
CALCULATION
pH
5.0
S.U.
1
01/06/2215:16
DRS
9045D
Total Solids
21.9
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Volatile Solids
31.4
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Kjeldahl Nitrogen
10300
mg/Kg -
dry
758
1
01/11/22 14:54
CLP
4500NORGD-2011
Phosphorus
991
mg/Kg -
dry
126
228
10
01/11/22 13:38
EAL
6010D
Aluminum
3670
mg/Kg -
dry
211
228
10
01/11/22 13:38
EAL
6010D
Arsenic
16.13
mg/Kg -
dry
11.0
22.8
10
01/11/22 13:38
EAL
6010D
Cadmium
<0.913
mg/Kg -
dry
0.913
4.57
10
01/11/22 13:38
EAL
6010D
Calcium
<1770
mg/Kg -
dry
1770
2280
10
01/11/22 13:38
EAL
6010D
Chromium
<10.8
mg/Kg -
dry
10.8
11.4
10
01/11/22 13:38
EAL
6010D
Copper
363
mg/Kg -
dry
14.2
22.8
10
01/11/22 13:38
EAL
6010D
Iron
408000
mg/Kg -
dry
389
457
10
01/11/22 13:38
EAL
6010D
Lead
11.53
mg/Kg -
dry
8.22
13.7
10
01/11/22 13:38
EAL
6010D
Magnesium
1933
mg/Kg -
dry
118
228
10
01/11/22 13:38
EAL
6010D
Manganese
3630
mg/Kg -
dry
14.8
22.8
10
01/11/22 13:38
EAL
6010D
Mercury
<0.0316
mg/Kg -
dry
0.0316
0.0726
1
01/07/22 12:43
JW2
7471A
Molybdenum
<6.16
mg/Kg -
dry
6.16
11.4
10
01/11/22 13:38
EAL
6010D
Nickel
29.2
mg/Kg -
dry
5.48
11.4
10
01/11/22 13:38
EAL
6010D
Potassium
<282
mg/Kg -
dry
282
457
10
01/11/22 13:38
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions L
Limit Exceeded
MQL
Method Quantitation Limit
Page 6 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Project Durham, NC
Mr. Brent Collins
755 Yadkinville Rd
Information
Mocksville , NC 27028
Report Number : 22-004-0031
Lab No : 97025
Sample ID: Brown WTP
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
REPORT OFANALYSIS
Report Date : 01/12/2022
Received : 01/04/2022
Danyale Love
Project Manager
Matrix: Solids
Sampled: 1/3/2022 12:40
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Selenium
Sodium
Zinc
Sulfur
Sodium Absorption Ratio
Qualifiers/ DF Dilution Factor
Definitions
<14.6
mg/Kg -
dry
14.6
22.8
10
01/11/22 13:38
EAL
6010D
<594
mg/Kg -
dry
594
1140
10
01/11/22 13:38
EAL
6010D
<37.0
mg/Kg -
dry
37.0
57.1
10
01/11/22 13:38
EAL
6010D
5890
mg/Kg -
dry
237
457
10
01/11/22 13:38
EAL
6010D
<0.01
Ratio
0.01
0.01
10
01/11/22 13:38
CALCULATION
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-004-0031
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 01/04/2022 10:20:14
Page 8 of 9

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Page 9 of 9

Brown WTP 1 /3/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
594
130.086
23 5.655913
Calcium
1770
387.63
20 19.3815
Magnesium
193
42.267
12 3.52225
Percent Solids
21.9
SAR
1.67
SAR =
Na+
a (Ca2+ + M;42+ )
5.65591
0.5( 19.382 2 + 3.52225 2 )

Waypointo
ANALYTICAL
5/19/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-132-0036
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 5/12/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-132-0036
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-132-0036
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
90566 Brown W FP Solids 05/11/2022 10:45 05/12/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-132-0036
Date: 5/19/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 90600 (TB-11-3)
Analyte: Aluminum
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Arsenic
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 90600 (TB-11-3)
Analyte: Calcium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Chromium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Iron
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Potassium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Manganese
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Analyte: Phosphorus
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90566 (Brown WTP)
Analyte: Selenium
QC Batch No: 1-616955/1-616254
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 90600 (TB-11-3)
Analyte: Selenium
QC Batch No: 1-616955/1-616254
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 90600 (TB-11-3)
Analyte: Selenium
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 90592 (TB-7-3)
Analyte: Mercury
QC Batch No: 1-616692/1-615833
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 05/19/2022
//Received : 05/12/2022
C.�.-�,...dJ l.�-
Connie Cook
Report Number : 22-132-0036
REPORT OFANALYSIS
Project
Manager
Lab No : 90566
Matrix:
Solids
Sample ID: Brown WTP
Sampled:
5/11/2022
10:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
78.9
%
1
05/18/22 16:00
FMM
SW-DRYWT
Ammonia Nitrogen
1000
mg/Kg -
dry
75.8
474
1
05/19/22 14:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
338
mg/Kg -
dry
21.8
21.8
1
05/17/22 14:38
ZBD
4500NO3F-2016
Organic N
7294
mg/Kg -
dry
411.4
829.4
1
05/17/22 16:39
CALCULATION
pH
5.1
S.U.
1
05/19/2215:08
DRS
9045D
Total Solids
21.1
%
0.010
0.010
1
05/18/22 16:00
FMM
2540G-2011
Total Volatile Solids
34.4
%
0.010
0.010
1
05/18/22 16:00
FMM
2540G-2011
Total Kjeldahl Nitrogen
8290
mg/Kg -
dry
829
1
05/17/22 16:39
CLP 4500NORGD-2011
Phosphorus
986
mg/Kg -
dry
13.1
23.7
1
05/18/22 18:10
TJS
6010D
Aluminum
10900
mg/Kg -
dry
21.9
23.7
1
05/18/22 18:10
TJS
6010D
Arsenic
1.263
mg/Kg -
dry
1.14
2.37
1
05/18/22 18:10
TJS
6010D
Cadmium
5.21
mg/Kg -
dry
0.0947
0.474
1
05/18/22 18:10
TJS
6010D
Calcium
1170
mg/Kg -
dry
183
237
1
05/18/22 18:10
TJS
6010D
Chromium
13.6
mg/Kg -
dry
1.12
1.18
1
05/18/22 18:10
TJS
6010D
Copper
573
mg/Kg -
dry
1.47
2.37
1
05/18/22 18:10
TJS
6010D
Iron
334000
mg/Kg -
dry
806
948
20
05/19/22 12:01
TJS
6010D
Lead
13.2
mg/Kg -
dry
0.853
1.42
1
05/18/22 18:10
TJS
6010D
Magnesium
332
mg/Kg -
dry
12.2
23.7
1
05/18/22 18:10
TJS
6010D
Manganese
4980
mg/Kg -
dry
7.73
11.8
5
05/19/22 11:56
TJS
6010D
Mercury
0.05023
mg/Kg -
dry
0.0330
0.758
1
05/17/22 12:17
JTR
7471A
Molybdenum
3.10
mg/Kg -
dry
0.639
1.18
1
05/18/22 18:10
TJS
6010D
Nickel
58.8
mg/Kg -
dry
0.568
1.18
1
05/18/22 18:10
TJS
6010D
Potassium
265
mg/Kg -
dry
29.3
47.4
1
05/18/22 18:10
TJS
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 6 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 05/19/2022
755 Yadkinville Rd
Information :
Received : 05/12/2022
Mocksville , NC 27028
/!
Connie Cook
Report Number : 22-132-0036
REPORT OFANALYSIS
Project Manager
Lab No : 90566
Matrix: Solids
Sample ID: Brown WTP
Sampled: 5/11/2022 10:45
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<30.3
mg/Kg - dry
30.3
47.4 20 05/19/22 12:01 TJS 6010D
Sodium
402
mg/Kg - dry
61.6
118 1 05/18/22 18:10 TJS 6010D
Zinc
67.3
mg/Kg - dry
3.84
5.92 1 05/18/22 18:10 TJS 6010D
Sulfur
2550
mg/Kg - dry
24.5
47.4 1 05/18/22 18:10 TJS 6010D
Sodium Absorption Ratio
1.22
Ratio
0.01
0.01 1 05/18/22 18:10 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-132-0036
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 05/12/2022 09:50:18
Page 8 of 9

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Page 9 of 9

Brown WTP 5/11/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
402
84.822
23 3.687913
Calcium
1170
246.87
20 12.3435
Magnesium
332
70.052
12 5.837667
Percent Solids
21.1
SAR
1.22
SAR =
Na+
a (Ca2+ + M;42+ )
3.68791
0.5( 12.344 2 + 5.83767 2 )

Waypointo
ANALYTICAL
7/27/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-193-0015
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 7/12/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-193-0015
Page 2 of 8

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-193-0015
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97768 Brown W FP Solids 07/08/2022 09:00 07/12/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-193-0015
Date: 7/26/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 97768 (Brown WTP)
Analyte: Aluminum
QC Batch No: 1-627396/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Iron
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Manganese
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Selenium
QC Batch No: 1-627396/1-626741
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 97768 (Brown WTP)
Analyte: Selenium
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 98409 (Little Patuxent Class A 1)
Analyte: Mercury
QC Batch No: 1-626964/1-626559
The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control
acceptance ranges. Matrix interference is suspected
Page 4 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 07/27/2022
Received : 07/12/2022
" l.�-
Connie Cook
Report Number : 22-193-0015
REPORT OFANALYSIS
Project
Manager
Lab No : 97768
Matrix:
Solids
Sample ID: Brown WTP
Sampled:
7/8/2022
9:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
81.2
%
1
07/12/22 15:45
FMM
SW-DRYWT
Ammonia Nitrogen
1150
mg/Kg -
dry
85.1
532
1
07/26/22 15:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
34.0
mg/Kg -
dry
26.6
26.6
1
07/19/22 14:59
ZBD
4500NO3F-2016
Organic N
8745
mg/Kg -
dry
590.4
1191
1
07/15/22 13:19
CALCULATION
pH
5.1
S.U.
1
07/18/2215:04
DRS
9045D
Total Solids
18.8
%
0.010
0.010
1
07/12/22 15:45
FMM
2540G-2011
Total Volatile Solids
37.3
%
0.010
0.010
1
07/12/22 15:45
FMM
2540G-2011
Total Kjeldahl Nitrogen
9890
mg/Kg -
dry
1190
1
07/15/22 13:19
CLP 4500NORGD-2011
Phosphorus
830
mg/Kg -
dry
14.7
26.6
1
07/18/22 20:37
EAL
6010D
Aluminum
7870
mg/Kg -
dry
24.6
26.6
1
07/18/22 20:37
EAL
6010D
Arsenic
5.31
mg/Kg -
dry
1.28
2.66
1
07/18/22 20:37
EAL
6010D
Cadmium
19.5
mg/Kg -
dry
0.106
0.532
1
07/18/22 20:37
EAL
6010D
Calcium
1090
mg/Kg -
dry
206
266
1
07/18/22 20:37
EAL
6010D
Chromium
12.0
mg/Kg -
dry
1.26
1.33
1
07/18/22 20:37
EAL
6010D
Copper
1620
mg/Kg -
dry
1.65
2.66
1
07/18/22 20:37
EAL
6010D
Iron
409000
mg/Kg -
dry
453
532
10
07/19/22 20:11
EAL
6010D
Lead
14.2
mg/Kg -
dry
0.957
1.60
1
07/18/22 20:37
EAL
6010D
Magnesium
309
mg/Kg -
dry
13.7
26.6
1
07/18/22 20:37
EAL
6010D
Manganese
5740
mg/Kg -
dry
17.3
26.6
10
07/19/22 20:11
EAL
6010D
Mercury
<0.0369
mg/Kg -
dry
0.0369
0.846
1
07/15/22 14:08
JTR
7471A
Molybdenum
4.31
mg/Kg -
dry
0.718
1.33
1
07/18/22 20:37
EAL
6010D
Nickel
56.4
mg/Kg -
dry
0.638
1.33
1
07/18/22 20:37
EAL
6010D
Potassium
212
mg/Kg -
dry
32.9
53.2
1
07/20/22 18:40
TJS
6010D
Qualifiers/ DF Dilution Factor
MQL
Method Quantitation Limit
Definitions
Page 5 of 8

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Project Durham, NC
Mr. Brent Collins
755 Yadkinville Rd
Information
Mocksville , NC 27028
Report Number : 22-193-0015
Lab No : 97768
Sample ID: Brown WTP
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
REPORT OFANALYSIS
Report Date : 07/27/2022
Received : 07/12/2022
" l.�—
Connie Cook
Project Manager
Matrix: Solids
Sampled: 7/8/2022 9:00
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Selenium
Sodium
Zinc
Sulfur
Sodium Absorption Ratio
Qualifiers/ DF Dilution Factor
Definitions
<17.0
mg/Kg -
dry
17.0
26.6
10
07/19/22 20:11
EAL
6010D
379
mg/Kg -
dry
69.1
133
1
07/18/22 20:37
EAL
6010D
64.9
mg/Kg -
dry
4.31
6.65
1
07/18/22 20:37
EAL
6010D
3530
mg/Kg -
dry
27.6
53.2
1
07/18/22 20:37
EAL
6010D
1.13
Ratio
0.01
0.01
1
07/18/22 20:37
CALCULATION
MQL Method Quantitation Limit
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-193-0015
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 07/12/2022 09:40:31
Page 7 of 8

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Page 8 of 8

Brown WTP 7/8/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
379
71.252
23 3.097913
Calcium
1090
204.92
20 10.246
Magnesium
309
58.092
12 4.841
Percent Solids
18.8
SAR
1.13
SAR =
Na+
a (Ca2+ + M;42+ )
3.09791
0.5( 10.246 2 + 4.84100 2 )

Waypointo
ANALYTICAL
10/13/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-277-0022
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 10/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-277-0022
Page 2 of 9

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 22-277-0022
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
92505 Brown W FP Solids 10/03/2022 10:30 10/04/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-277-0022
Date: 10/12/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 92505 (Brown WTP)
Analyte: Calcium
QC Batch No: 1-641846/1-641319
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 92505 (Brown WTP)
Analyte: Potassium
QC Batch No: 1-641846/1-641319
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 97015 (Bolster)
Analyte: Potassium
QC Batch No: 1-641846/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 92505 (Brown WTP)
Analyte: Magnesium
QC Batch No: 1-641846/1-641319
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 97015 (Bolster)
Analyte: Magnesium
QC Batch No: 1-642077/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 92505 (Brown WTP)
Analyte: Sodium
QC Batch No: 1-641846/1-641319
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 97015 (Bolster)
Analyte: Sodium
QC Batch No: 1-641846/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Durham, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 10/18/2022
nReceived : 10/04/2022
C-�*�-� =
Connie Cook
Report Number : 22-277-0022
REPORT OFANALYSIS
Project
Manager
Lab No : 92505
Matrix:
Solids
Sample ID: Brown WTP
Sampled:
10/3/2022
10:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
78.5
%
1
10/07/2215:44
FMM
SW-DRYWT
Ammonia Nitrogen
4113
mg/Kg -
dry
74.4
465
1
10/12/22 15:20
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<20.9
mg/Kg -
dry
20.9
20.9
1
10/08/22 11:26
ZBD
4500NO3F-2016
Organic N
69863
mg/Kg -
dry
930.2
1874
1
10/06/22 14:57
CALCULATION
pH
4.9
S.U.
1
10/11/2216:00
SAR
9045D
Total Solids
21.5
%
0.010
0.010
1
10/07/22 15:44
FMM
2540G-2011
Total Kjeldahl Nitrogen
7400
mg/Kg -
dry
1870
1
10/06/22 14:57
ANH 4500NORGD-2011
Phosphorus
814
mg/Kg -
dry
64.2
116
5
10/07/22 23:32
EAL
6010D
Aluminum
4160
mg/Kg -
dry
107
116
5
10/14/22 06:07
TJS
6010D
Arsenic
38.1
mg/Kg -
dry
5.58
11.6
5
10/07/22 23:32
EAL
6010D
Cadmium
0.6703
mg/Kg -
dry
0.465
2.33
5
10/07/22 23:32
EAL
6010D
Calcium
1500
mg/Kg -
dry
902
1160
5
10/07/22 23:32
TJS
6010D
Chromium
12.7
mg/Kg -
dry
5.49
5.81
5
10/14/22 06:07
TJS
6010D
Copper
2610
mg/Kg -
dry
7.21
11.6
5
10/07/22 23:32
EAL
6010D
Iron
366000
mg/Kg -
dry
396
465
10
10/14/22 06:02
TJS
6010D
Lead
16.2
mg/Kg -
dry
4.19
6.98
5
10/07/22 23:32
EAL
6010D
Magnesium
221
mg/Kg -
dry
60.0
116
5
10/07/22 23:32
TJS
6010D
Manganese
19400
mg/Kg -
dry
15.1
23.3
10
10/14/22 06:02
TJS
6010D
Mercury
0.06983
mg/Kg -
dry
0.0280
0.642
1
10/14/22 12:39
TJS
7471B
Molybdenum
4.363
mg/Kg -
dry
3.14
5.81
5
10/07/22 23:32
EAL
6010D
Nickel
107
mg/Kg -
dry
2.79
5.81
5
10/07/22 23:32
EAL
6010D
Potassium
<144
mg/Kg -
dry
144
233
5
10/07/22 23:32
TJS
6010D
Selenium
<7.44
mg/Kg -
dry
7.44
11.6
5
10/07/22 23:32
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 9

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 10/18/2022
755 Yadkinville Rd
Information :
Received : 10/04/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-277-0022
REPORT OFANALYSIS
Project Manager
Lab No : 92505
Matrix: Solids
Sample ID: Brown WTP
Sampled: 10/3/2022 10:30
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Sodium
<302
mg/Kg - dry
302
581 5 10/07/22 23:32 TJS 6010D
Zinc
169
mg/Kg - dry
18.8
29.1 5 10/07/22 23:32 EAL 6010D
Sulfur
3400
mg/Kg - dry
120
233 5 10/07/22 23:32 6010D
Sodium Absorption Ratio
<0.01
Ratio
0.01
0.01 5 10/07/22 23:32 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 6 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-277-0022
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IMakayla Weaver Date & Time: 10/04/2022 09:23:46
Page 7 of 9

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Page y of y

Brown WTP 10/3/2022
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 302 64.93 23 2.823043
Calcium 1500 322.5 20 16.125
Magnesium 221 47.515 12 3.959583
Percent Solids 21.5
SAR 0.89
SAR — Na
2 (Ca2+ + Mg2- )
2.82304
0.5( 16.125 2 + 3.95958 2 )

ace Analytical ' ANALYTICAL REPORT
March 07, 2022
EMA Resources
Sample Delivery Group: L1462872
Samples Received: 02/17/2022
Project Number:
Description: Sludge
Report To: Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By: , �-
Justin Carr
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
N
� T
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 1 of34

TABLE OF CONTENTS
Cp: Cover Page
u
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
Fss]
BROWN WTP L1462872-01
5
Fn
Qc: Quality Control Summary
7
Wet Chemistry by Method 9012 B
7
Fr
Wet Chemistry by Method 9045D
8
Wet Chemistry by Method D93/1010A
9
Rc
Mercury by Method 7470A
10
F
Metals (ICP) by Method 6010D
11
Volatile Organic Compounds (GC/MS) by Method 8260D
12
[Al
Chlorinated Acid Herbicides (GC) by Method 8151A
14
Pesticides (GC) by Method 8081B
15
RC
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
16
GI: Glossary of Terms
18
Al: Accreditations & Locations
19
Sc: Sample Chain of Custody
20
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:
EMA Resources L1462372
03/07/22 17:11
2 of34

SAMPLE SUMMARY
Collected by
BROWN WTP L1462872-01 Waste Brent Collins
Collected date/time Received date/time
02/16/22 08:30 02/17/22 09:30 C
P
Method
Batch
Dilution Preparation
Analysis
Analyst
date/time
date/time
Preparation by Method 1311
WG1822047
1 02/23/22 0810
02/23/22 08:10
JAV
Preparation by Method 1311
WG1822926
1 02/24/2210:16
02/24/2210:16
JWS
Wet Chemistry by Method 9012 B
WG1821197
1 02/21/22 2138
02/22/2213:36
LDT
Wet Chemistry by Method 9045D
WG1819608
1 02/19/22 09:00
02/19/2213:00
GI
Wet Chemistry by Method D93/1010A
WG1821036
1 02/21/22 0100
02/21/22 0100
WOS
Mercury by Method 7470A
WG1823061
1 02/24/22 09:45
02/24/2213:43
CLL
Metals (ICP) by Method 6010D
WG1823102
1 02/24/2210:36
02/24/2215:29
KMG
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1824477
1 02/27/2218:03
02/27/22 18:03
BMB
Chlorinated Acid Herbicides (GC) by Method 8151A
WG1825661
1 03/02/22 08:02
03/02/2218:56
CCW
Pesticides (GC) by Method 8081B
WG1825495
1 03/02/22 08:42
03/02/2214:03
AO
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
WG1824791
1 03/04/22 06:25
03/04/2214:52
LEA
Subcontracted Analyses
WG1822593
1 02/25/22 00:00
02/25/22 00:00
ANF
Location
FC
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fn
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fr
Mt. Juliet, TN
Mt. Juliet, TN
Rc
Mt. Juliet, TN
Subcontract
GI
F
RC
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1462372 03/07/22 17:11
PAGE:
3 of34

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the FP
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data. 0
Fr
Rc
GI
Justin Carr [Al
Project Manager
RC
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
L1462372 -01 contains subout data that is included after the chain of custody.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 4 of 34

SAMPLE RESULTS - 01
L1462872
BROWN WTP
Collected date/time: 02/16/22 08:30
Preparation by Method 1311
Result Qualifier Prep
Batch
Analyte
date / time
TCLP Extraction
2/23/2022 8:10:29 AM
WG1822047
TCLP ZHE Extraction
- 2/24/202210:16:52 AM
WG1822926
Fluid
1 2/23/2022 8:10:29 AM
WG1822047
Initial pH
5.75 2/23/2022 8:10:29 AM
WG1822047
Final pH
5.08 2/23/2022 8:10:29 AM
WG1822047
Wet Chemistry by Method 9012 B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reactive Cyanide 0.638 0.250
Wet Chemistry by Method 9045D
Dilution Analysis Batch
date / time
1 02/22/202213:36 WG1821197
Result Qualifier
Dilution Analysis
Batch
Analyte su
date / time
Corrosivity by pH 5.57 T8
1 02/19/2022 13:00
WG1819608
Sample Narrative:
L1462872-01 WG1819608: 5.57 at19.4C
Wet Chemistry by Method D93/1010A
Result Qualifier
Dilution Analysis
Batch
Analyte Deg. F
date / time
Ignitability DNI at170
1 02/21/2022 0100
WG1821036
Mercury by Method 7470A
Result
Analyte mg/I
Mercury ND
Metals (ICP) by Method 6010D
Qualifier RDL Limit Dilution Analysis Batch
mg/I mg/I date / time
0.0100 0.20 1 02/24/202213:43 WG1823061
Result
Qualifier RDL
Limit
Analyte
mg/I
mg/I
mg/I
Arsenic
ND
0.100
5
Barium
0.205
0.100
100
Cadmium
ND
0.100
1
Chromium
ND
0.100
5
Lead
ND
0.100
5
Selenium
ND
0.100
1
Silver
ND
0.100
5
Volatile Organic Compounds (GC/MS) by Method 8260D
Dilution Analysis Batch
date / time
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
02/24/202215:29
WG1823102
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Benzene
ND
0.0500
0.50
1 02/27/202218:03
WG1824477
Carbon tetrachloride
ND
0.0500
0.50
1 02/27/202218:03
WG1824477
Chlorobenzene
ND
0.0500
100
1 02/27/202218:03
WG1824477
Chloroform
ND
0.250
6
1 02/27/202218:03
WG1824477
1,2-Dichloroethane
ND
0.0500
0.50
1 02/27/202218:03
WG1824477
1,1-Dichloroethene
ND
0.0500
0.70
1 02/27/202218:03
WG1824477
2-Butanone (MEK)
ND
0.500
200
1 02/27/202218:03
WG1824477
Tetrachloroethene
ND
0.0500
0.70
1 02/27/202218:03
WG1824477
Trichloroethene
ND
0.0500
0.50
1 02/27/202218:03
WG1824477
Vinyl chloride
ND
0.0500
0.20
1 02/27/202218:03
WG1824477
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
EMA Resources
L1462372
03/07/22 17:11 5 of 34

BROWN WTP SAMPLE RESULTS
- 01
Collected date/time: 02/16/22 08:30 L1462872
Volatile Organic Compounds (GC/MS) by Method 8260D
Result Qualifier RDL Limit Dilution
Analysis
Batch
Analyte mg/I mg/I mg/I
date/time
(S) Toluene-dH 113 80.0-120
021271202218.03
WG1824477
(S) 4-Bromofluorobenzene 89.5 77.0-126
021271202218.03
WG1824477
(S) 1,2-Dichloroethone-d4 94.3 70.0-130
021271202218.03
WG1824477
Chlorinated Acid Herbicides (GC) by Method 8151A
Result Qualifier
RDL Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I mg/I
date/time
2,4,5-TP (Silvex) ND
0.00200 1
1 03/02/2022 18:56
WG1825661
2,4-D ND
0.00200 10
1 03/02/202218:56
WG1825661
(S) Z4-Dichlorophenyl Acetic Acid 83.0
14.0-158
031021202218.56
WG1825661
Pesticides (GC) by Method 8081B
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Chlordane
ND
0.00500
0.03
1 03/02/202214:03
WG1825495
Endrin
ND
0.00500
0.02
1 03/02/202214:03
WG1825495
Heptachlor
ND
0.00500
0.0080
1 03/02/202214:03
WG1825495
Heptachlor epoxide
ND
0.00500
0.0080
1 03/02/2022 14:03
WG1825495
Lindane
ND
0.00500
0.40
1 03/02/202214:03
WG1825495
Methoxychlor
ND
0.00500
10
1 03/02/202214:03
WG1825495
Toxaphene
ND
0.0100
0.50
1 03/02/202214:03
WG1825495
(S) Decochlorobiphenyl
81.5
10.0-128
0310212022 14.03
WG1825495
(S) Tetrochloro-m-xylene
70.0
10.0-127
0310212022 14.03
WG1825495
Semi Volatile Organic Compounds
(GC/MS) by Method 8270E
Analyte
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachloroethane
Nitrobenzene
Pyridine
3&4-Methyl Phenol
2-Methylphenol
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
(S) 2-Fluorophenol
(S) Phenol-d5
(S) Nitrobenzene-d5
(S) 2-Fluorobiphenyl
(S) Z4, 6-Tribromophenol
(S) p-Terphenyl-d14
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
mg/I
mg/I
mg/I
date/time
ND
0.100
7.50
1 03/04/202214:52
WG1824791
ND
0.100
0.13
1 03/04/202214:52
WG1824791
ND
0.100
0.13
1 03/04/202214:52
WG1824791
ND
0.100
0.50
1 03/04/202214:52
WG1824791
ND
0.100
3
1 03/04/202214:52
WG1824791
ND
0.100
2
1 03/04/202214:52
WG1824791
ND
0.100
5
1 03/04/202214:52
WG1824791
ND
0.100
400
1 03/04/202214:52
WG1824791
ND
0.100
200
1 03/04/202214:52
WG1824791
ND
0.100
100
1 03/04/202214:52
WG1824791
ND
0.100
400
1 03/04/202214:52
WG1824791
ND
0.100
2
1 03/04/202214:52
WG1824791
42.4
10.0-120
031041202214.52
WG1824791
27.7
10.0-120
031041202214.52
WG1824791
78.9
10.0-127
031041202214.52
WG1824791
78.9
10.0-130
031041202214.52
WG1824791
83.0
10.0-155
031041202214.52
WG1824791
92.0
10.0-128
0310412022 14.52
WG1824791
ACCOUNT:
EMA Resources
PROJECT: SDG: DATE/TIME: PAGE:
L1462372 03/07/2217:11 6 of34

WG1821197
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3762532-1 02/22/22 1322
MB Result
Analyte mg/kg
Reactive Cyanide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.0390 0.250
L1462850-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1462872-01
(OS) L1462350-01 02/22/22 13:30 • (DUP) R3762532-3 02/22/22 13:31
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide 0.424 0.437 1 3.02 20
L1462872-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1462372-01 02/22/22 13:36 • (DUP) R3762532-6 02/22/22 13:37
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide 0.638 0.583 1 8.98 20
Laboratory Control Sample (LCS)
(LCS) R3762532-2 02/22/22 1323
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Cyanide 2.50 2.52 101
Rec. Limits LCS Qualifier
85.0-115
L1462850-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462350-01 02/22/22 13:30 • (MS) R3762532-4 02/22/22 13:34 • (MSD) R3762532-5 02/22/22 13:35
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec.
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 0.424 0.595 0.438 10.2 0.855
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 75.0-125 J6 J3 J6 30.3 20
L1462970-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462970-01 02/22/22 13:33 • (MS) R3762532-7 02/22/22 13:39 • (MSD) R3762532-8 02/22/22 13:40
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 ND 1.00 1.11 60.0 66.8 1 75.0-125 J6 J6 10.7 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
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WG1819608 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9045D L1462872-01
L1462467-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1462467-02 02/19/22 13:00 • (DUP) R3761702-2 02/19/22 13:00
Original Result DUP Result Dilution DUP RPD
Analyte su su
Corrosivity by pH 7.63 7.63 1 0.000
Sample Narrative:
OS: 7.63 at19C
DUP 7.63 at19C
Laboratory Control Sample (LCS)
DUP Qualifier DUP RPD
Limits
(LCS) R3761702-1 02/19/22 13:00
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte su su
Corrosivity by pH 10.0 9.95 99.5 99.0-101
Sample Narrative:
LCS: 9.95 at18.6C
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 3 of 34

WG1821036 QUALITY CONTROL SUMMARY
Wet Chemistry by Method D93/1010A L1462872-01
L1463101-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1463101-02 02/21/22 01:00 • (DUP) R3762219-3 02/21/22 0100
Original Result DUP Result Dilution DUP RPD
Analyte Deg. F Deg. F
Ignitability 132 140 1 5.90
DUP Qualifier DUP RPD
Limits
i
10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3762219-1 02/21/22 01:00 • (LCSD) R3762219-2 02/21/22 0100
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte Deg. F Deg. F Deg. F
Ignitability 126 128 122 101 96.5 95.6-104 4.82 10
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 9 of 34

WG1823061 QUALITY CONTROL SUMMARY
Mercury by Method 7470A L1462872-01
Method Blank (MB)
(MB) R3763464-1 02/24/22 1313
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/I mg/I mg/I
Mercury U 0.00330 0.0100
Laboratory Control Sample (LCS)
(LCS) R3763464-2 02/24/22 1324
Spike Amount LCS Result LCS Rec.
Analyte mg/I mg/I
Mercury 0.0300 0.0310 103
Rec. Limits LCS Qualifier
80.0-120
L1459816-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1459316-02 02/24/22 13:26 • (MS) R3763464-3 02/24/22 13:29 • (MSD) R3763464-4 02/24/22 13:31
Spike Amount
Original Result
MS Result
MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Mercury 0.0300
ND
0.0326
0.0332 109 111 1 75.0-125 1.70 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
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WG1823102
Metals (ICP) by Method 6010D
Method Blank (MB)
(MB) R3763533-1 02/24/22 1512
MB Result
MB Qualifier MB MDL
MB RDL
Analyte mg/I
mg/I
mg/I
Arsenic U
0.0333
0.100
Barium U
0.0333
0.100
Cadmium U
0.0333
0.100
Chromium U
0.0333
0.100
Lead U
0.0333
0.100
Selenium U
0.0333
0.100
Silver U
0.0333
0.100
Laboratory Control Sample (LCS)
(LCS) R3763588-2 02/24/22 1514
QUALITY CONTROL SUMMARY
L1462872-01
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
Analyte
mg/I
mg/I
Arsenic
10.0
9.46
94.6
80.0-120
Barium
10.0
9.62
96.2
80.0-120
Cadmium
10.0
9.52
95.2
80.0-120
Chromium
10.0
9.93
99.3
80.0-120
Lead
10.0
9.44
94.4
80.0-120
Selenium
10.0
10.3
103
80.0-120
Silver
2.00
1.75
87.7
80.0-120
LCS Qualifier
L1459816-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1459316-02 02/24/22 15:17 • (MS) R3763533-4 02/24/22 15:23 • (MSD) R3763533-5 02/24/22 15:26
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Arsenic
10.0
ND
9.44
9.25
94.4
92.5
Barium
10.0
0.421
9.94
9.88
95.2
94.6
Cadmium
10.0
ND
9.45
9.44
94.5
94.4
Chromium
10.0
ND
9.93
9.84
99.3
98.4
Lead
10.0
ND
9.42
9.32
93.6
92.6
Selenium
10.0
ND
10.2
10.2
102
102
Silver
2.00
ND
1.76
1.74
87.8
87.1
Dilution Rec. Limits
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
MS Qualifier MSD Qualifier RPD
1.95
0.626
0.0823
0.879
1.09
0.465
0.872
RPD Limits
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG:
EMA Resources L1462372
DATE/TIME:
03/07/22 17:11
PAGE:
11 of 34

WG1824477 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1462872-01
Method Blank (MB)
(MB) R3764355-3 02/27/22 13:43
MB Result
Analyte
mg/I
Benzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chloroform
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
2-Butanone (MEK)
U
Tetrachloroethene
U
Trichloroethene
U
Vinyl chloride
U
(S) Toluene-dH
115
(S) 4-Bromofluorobenzene 91.4
(S) 1,2-Dichloroethane-d4 90.5
MB Qualifier MB MDL
mg/I
MB RDL
mg/I
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
0.0833
0.250
0.0167
0.0500
0.0167
0.0500
0.167
0.500
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
80.0-120
77.0-126
70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3764355-1 02/27/22 10:38 • (LCSD) R3764355-2 02/27/22 12:39
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
Analyte
mg/I
mg/I
mg/I
Benzene
0.250
0.251
0.275
100
110
70.0-123
Carbon tetrachloride
0.250
0.229
0.222
91.6
88.8
68.0-126
Chlorobenzene
0.250
0.260
0.294
104
118
80.0-121
Chloroform
0.250
0.253
0.274
101
110
73.0-120
1,2-Dichloroethane
0.250
0.248
0.274
99.2
110
70.0-128
1,1-Dichloroethene
0.250
0.249
0.258
99.6
103
71.0-124
2-Butanone (MEK)
1.25
1.09
1.21
87.2
96.8
44.0-160
Tetrachloroethene
0.250
0.265
0.266
106
106
72.0-132
Trichloroethene
0.250
0.245
0.261
98.0
104
78.0-124
Vinyl chloride
0.250
0.289
0.291
116
116
67.0-131
(S) Toluene-dH
112
113
80.0-120
(S) 4-Bromofluorobenzene
91.1
90.5
77.0-126
(S) 1,2-Dichloroethane-d4
94.0
94.0
70.0-130
LCS Qualifier
LCSD Qualifier RPD
9.13
3.10
12.3
7.97
9.96
3.55
10.4
0.377
6.32
0.690
RPD Limits
20
20
20
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 12 of 34

WG1824477 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1462872-01
L1464040-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1464040-04 02/27/22 20:50 • (MS) R3764355-4 02/27/22 21:11 • (MSD) R3764355-5 02/27/22 2132
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Benzene 0.250
ND
0.166
0.168
66.4
67.2
1 17.0-158
1.20
27
Carbon tetrachloride 0.250
ND
0.160
0.168
64.0
67.2
1 23.0-159
4.88
28
Chlorobenzene 0.250
ND
0.219
0.219
87.6
87.6
1 33.0-152
0.000
27
Chloroform 0.250
ND
ND
ND
83.6
84.4
1 29.0-154
0.952
28
1,2-Dichloroethane 0.250
ND
0.201
0.196
80.4
78.4
1 29.0-151
2.52
27
1,1-Dichloroethene 0.250
ND
0.119
0.118
47.6
47.2
1 11.0-160
0.844
29
2-Butanone (MEK) 1.25
ND
1.05
1.12
84.0
89.6
1 10.0-160
6.45
32
Tetrachloroethene 0.250
3.96
3.77
3.56
0.000
0.000
1 10.0-160
V_ V_ 5.73
27
Trichloroethene 0.250
ND
0.170
0.173
68.0
69.2
1 10.0-160
1.75
25
Vinyl chloride 0.250
ND
0.130
0.126
52.0
50.4
1 10.0-160
3.12
27
(S) Toluene-dH
110
110
80.0-120
(S) 4-Bromofluorobenzene
97.6
95.1
77.0-126
(S) 1,2-Dichloroethane-d4
94.6
94.0
70.0-130
L1462927-03 Original Sample
(OS) • Matrix Spike (MS)
(OS) L1462927-03 02/27/22 13:45 • (MS) R3764355-6 02/27/22 2152
Spike Amount
Original Result
MS Result
MS Rec.
Dilution
Rec. Limits
MS Qualifier
Analyte mg/I
mg/I
mg/I
Benzene 0.250
ND
0.169
67.6
1
17.0-158
Carbon tetrachloride 0.250
ND
0.165
66.0
1
23.0-159
Chlorobenzene 0.250
ND
0.218
87.2
1
33.0-152
Chloroform 0.250
ND
ND
84.0
1
29.0-154
1,2-Dichloroethane 0.250
ND
0.199
79.6
1
29.0-151
1,1-Dichloroethene 0.250
ND
0.119
47.6
1
11.0-160
2-Butanone (MEK) 1.25
ND
1.05
84.0
1
10.0-160
Tetrachloroethene 0.250
ND
0.202
80.8
1
10.0-160
Trichloroethene 0.250
ND
0.184
73.6
1
10.0-160
Vinyl chloride 0.250
ND
0.131
52.4
1
10.0-160
(S) Toluene-dH
119
80.0-120
(S) 4-Bromofluorobenzene
97.6
77.0-126
(S) 1,2-Dichloroethane-d4
93.9
70.0-130
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
EMA Resources
L1462372
03/07/22 17:11
13 of 34

WG1825661
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
(MB) R3765374-1 03/02/22 16:58
MB Result
Analyte mg/I
2,4,5-TP (Silvex) U
2,4-D U
(S) Z4-Dichlorophenyl Acetic 70.0
Acid
QUALITY CONTROL SUMMARY
L1462872-01
MB Qualifier MB MDL
MB RDL
mg/I
mg/I
0.000667
0.00200
0.000667
0.00200
14.0-158
Laboratory Control Sample (LCS)
(LCS) R3765874-2 03/02/22 1713
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
2,4,5-TP (Silvex) 0.0500
0.0417
83.4
50.0-125
2,4-D 0.0500
0.0451
90.2
50.0-120
(S) Z4-Dichlorophenyl Acetic
74.0
14. 0-158
Acid
L1463588-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1463533-01 03/02/22 20:24 • (MS) R3765874-3 03/02/22 20:38 • (MSD) R3765874-4 03/02/22 20:53
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
2,4,5-TP (Silvex)
0.0500
ND
0.0416
0.0359
83.2
71.8
2,4-D
0.0500
ND
0.0401
0.0407
80.2
81.4
(S) Z4-Dichlorophenyl Acetic
74.4
74.2
Acid
ACCOUNT:
EMA Resources
PROJECT:
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 50.0-125 14.7 20
1 50.0-120 1.49 20
14.0-158
SDG: DATE/TIME: PAGE:
L1462372 03/07/22 17:11 14 of 34

WG1825495
Pesticides (GC) by Method 8081B
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1462872-01
(MB) R3765616-1 03/02/22 1337
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Chlordane
U
0.00167
0.00500
Endrin
U
0.00167
0.00500
Heptachlor
U
0.00167
0.00500
Heptachlor epoxide
U
0.00167
0.00500
Gamma BHC
U
0.00167
0.00500
Methoxychlor
U
0.00167
0.00500
Toxaphene
U
0.00333
0.0100
(S) Decachlorobiphenyl
89.0
10.0-128
(S) Tetrochloro-m-xylene
71.5
10.0-127
Laboratory Control Sample (LCS)
(LCS) R3765616-2 03/02/22 13:46
Spike Amount
LCS Result
Analyte
mg/I
mg/I
Endrin
0.0100
0.00938
Heptachlor
0.0100
0.00904
Heptachlor epoxide
0.0100
0.00928
Gamma BHC
0.0100
0.00965
Methoxychlor
0.0100
0.0110
(S) Decachlorobiphenyl
(S) Tetrochloro-m-xylene
LCS Rec. Rec. Limits LCS Qualifier
93.8
90.4
92.8
96.5
110
94.7
81.1
57.0-134
27.0-132
57.0-130
55.0-129
54.0-155
10.0-128
10.0-127
P
L1462872-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462372-01 03/02/22 14:03 • (MS) R3765616-3 03/02/22 14:12 • (MSD) R3765616-4 03/02/22 14:21
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Endrin
0.0100
ND
0.00939
0.00836
93.9
83.6
Heptachlor
0.0100
ND
0.00884
0.00793
88.4
79.3
Heptachlor epoxide
0.0100
ND
0.00942
0.00838
94.2
83.8
Gamma BHC
0.0100
ND
0.00973
0.00856
97.3
85.6
Methoxychlor
0.0100
ND
0.0110
0.00987
110
98.7
(S) Decachlorobiphenyl
96.6
87.2
(S) Tetrochloro-m-xylene
80.2
68.8
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
1 10.0-160
11.6
1 16.0-136
10.9
1 10.0-160
11.7
1 14.0-141
12.8
1 10.0-160
P P 10.8
10.0-128
10.0-127
RPD Limits
39
40
36
40
34
ACCOUNT:
EMA Resources
PROJECT:
SDG: DATE/TIME:
L1462372 03/07/22 17:11
PAGE:
15 of 34

WG1824791 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1462872-01
Method Blank (MB)
(MB) R3766433-2 03/04/22 1141
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
U
0.0333
0.100
2,4-Dinitrotoluene
U
0.0333
0.100
Hexachlorobenzene
U
0.0333
0.100
Hexachloro-1,3-butadiene
U
0.0333
0.100
Hexachloroethane
U
0.0333
0.100
Nitrobenzene
U
0.0333
0.100
Pyridine
U
0.0333
0.100
3&4-Methyl Phenol
U
0.0333
0.100
2-Methylphenol
U
0.0333
0.100
Pentachlorophenol
U
0.0333
0.100
2,4,5-Trichlorophenol
U
0.0333
0.100
2,4,6-Trichlorophenol
U
0.0333
0.100
(S) 2-Fluorophenol
45.8
10.0-120
(S) Phenol-d5
28.0
10.0-120
(S) Nitrobenzene-d5
80.8
10.0-127
(S) 2-Fluorobiphenyl
83.4
10.0-130
(S) 2,4, 6-Tribromophenol
83.5
10. 0-155
(S) p-Terphenyl-d14
93.2
10.0-128
Laboratory Control Sample (LCS)
(LCS) R3766483-1 03/04/22 1120
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
1,4-Dichlorobenzene 0.500
0.443
88.6
18.0-120
2,4-Dinitrotoluene 0.500
0.610
122
49.0-124
Hexachlorobenzene 0.500
0.545
109
44.0-120
Hexachloro-1,3-butadiene 0.500
0.336
67.2
19.0-120
Hexachloroethane 0.500
0.456
91.2
15.0-120
Nitrobenzene 0.500
0.422
84.4
27.0-120
Pyridine 0.500
0.158
31.6
10.0-120
3&4-Methyl Phenol 0.500
0.410
82.0
31.0-120
2-Methylphenol 0.500
0.396
79.2
28.0-120
Pentachlorophenol 0.500
0.422
84.4
23.0-120
2,4,5-Trichlorophenol 0.500
0.498
99.6
44.0-120
2,4,6-Trichlorophenol 0.500
0.452
90.4
42.0-120
(S) 2-Fluorophenol
48.5
10.0-120
(S) Phenol-d5
32.2
10.0-120
(S) Nitrobenzene-d5
80.0
10.0-127
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1462872 03/07/22 17:11 16 of 34

WG1824791 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1462872-01
Laboratory Control Sample (LCS)
(LCS) R3766483-1 03/04/22 1120
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/I mg/I
(S) 2-Fluorobiphenyl 88.4 10.0-130
(S) 2,4, 6-Tribromophenol 99.0 10. 0-155
(S) p-Terphenyl-d14 89.9 10.0-128
L1462338-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462333-02 03/04/22 13:27 • (MS) R3766483-3 03/04/22 13:48 • (MSD) R3766483-4 03/04/22 14:09
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
Analyte
mg/I
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
0.500
ND
0.356
0.346
71.2
69.2
1 17.0-120
2.85
2,4-Dinitrotoluene
0.500
ND
0.505
0.482
101
96.4
1 39.0-125
4.66
Hexachlorobenzene
0.500
ND
0.460
0.441
92.0
88.2
1 35.0-122
4.22
HexachIaro-1,3-butadiene
0.500
ND
0.285
0.299
57.0
59.8
1 12.0-120
4.79
Hexachloroethane
0.500
ND
0.383
0.378
76.6
75.6
1 10.0-120
1.31
Nitrobenzene
0.500
ND
0.381
0.385
76.2
77.0
1 12.0-120
1.04
Pyridine
0.500
ND
0.120
0.127
24.0
25.4
1 10.0-120
5.67
3&4-Methyl Phenol
0.500
ND
0.447
0.445
89.4
89.0
1 10.0-120
0.448
2-Methylphenol
0.500
0.171
0.502
0.501
66.2
66.0
1 10.0-120
0.199
Pentachlorophenol
0.500
ND
0.390
0.378
78.0
75.6
1 10.0-128
3.12
2,4,5-Trichlorophenol
0.500
ND
0.406
0.397
81.2
79.4
1 33.0-120
2.24
2,4,6-Trichlorophenol
0.500
ND
0.381
0.372
76.2
74.4
1 26.0-120
2.39
(S) 2-Fluorophenol
41.3
39.2
10.0-120
(S) Phenol-d5
27.6
26.9
10.0-120
(S) Nitrobenzene-d5
76.1
74.9
10.0-127
(S) 2-Fluorobiphenyl
75.4
72.9
10.0-130
(S)2,4,6-Tribromophenol
89.0
83.0
10.0-155
(S) p-Terphenyl-d14
83.9
80.6
10.0-128
RPD Limits
40
25
24
34
40
30
37
36
30
37
31
31
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462372 03/07/22 17:11 17 of 34

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
u
Fc
Fss]
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
Fn
RDL
Reported Detection Limit.
Rec.
Recovery.
Fr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
F
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
F
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Rc
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe
samples from the time of collection until delivery to the laboratory for analysis.
This section ofyour report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J3
The associated batch QC was outside the established quality control range for precision.
J6
The sample matrix interfered with the ability to make any accurate determination, spike value is low.
P
RPD between the primary and confirmatory analysis exceeded 40%.
T8
Sample(s) received past/too close to holding time expiration.
v
The sample concentration is too high to evaluate accurate spike recoveries.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1462372 03/07/22 17:11 13 of 34

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
N E-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TNO02
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704 _
Georgia
NELAP
North Carolina 3
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky' 6
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee'"
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas5
LABO152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A2 LA
A2LA— ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A2 LA — ISO 17025 5
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
Rc
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1462372 03/07/22 17:11
PAGE:
19 of 34

Company Name/Address:
E MA Resources
Billing Information:
Mr. Brent Collins LChks
An
Iv is /Contall
/ r
s rvative
Chain of Custody Page — of
755 Yadkinviile Road
aCE AnaIytlCa�
755 Yadkinville Road
Mocksville, NC 27028
Mocksville, INC 27028
,
sunm5r `6anon Rdk tta lhn d-n M[,,todv
easamp
SpI51iluln acknowledgmanl and acceptance of [he
i Terms and [nndiliona found al',
httn//info.pattiaM.mm uMslpas-Woodard
ermr.pei
Report to:
Mr. Brent Collins
Email To,
brent.collins ema'esourcesinc.com;ro .wnitak
y
Project Description:
Sludge
city/State llease
Collected: �11r�OM JNG TPT
Circle
MT Cl ET
SDG #
Phone [phone]
Client Project #
Lab Project #
1060
`
a
°
Z
W
J
ry
U
6
Z
U
j
a
V
h-
Acctnum; kMAKkS
Tempiate:T11413
Prelogin: P895405
PM: 807 -Justin Carr
PB;�y—
Collected by (print):
��� ���a
Site/Facility ID #
P.O. #
Collected by (signature),
Immediately
Packed on Ice N _ Y
Rush) (Lab MUST Be Notified) Quote #
Same Day _ Five Day
'_Next Day _ 5 Day (Rad Only) Date Results Needed
_ Two Day _ 10 Day (Rod Only) No.
_ Three Day of
snipped via: FedEX Ground
Sample ID
Comp/Grab
Matrix'
Depth
Date
Time
ntrs
T
Remar6a Sample # (lab or,iy)
�rown YJ'rP
C
s5
3 '
Z1,�lZL
�'3a
2
X
X
' Matrix:Remarks:
SS - Soil AIR - Air F- Filter pH Temp
GW Groundwater B- Bioassa y Flow Other
WW - WasteWater
sar'1` t
COC Seal Present/intact: r [aF t N
CDC Signed/Accurate: /t N
Bottles arrive intact: "e' N
Correct bottles used: Y _N
DW - Drinking Water
OT - Other Samples returned via: Tracking #
UPS FedEx
Sufficient volume sent: _N
If Aonlicable
VCA Zero Headspace: 'f N
_ _ —Courier
_
PAD Screen On Correct/Checked: N
PAD Screen <0.5 mR/hr:
Relinquished by ; (Signature) Date:
q g I
Z%1ZZ
Time
j,7o
Received by: (Signature)
Trip Blank Received: Yes/ o
,leoti
TBR
BR -
Relinquished by: (Signature) Date:
Time:
Received by: (Signature)
Tee�mp: CBottles Rece.
�'f'
1 6 /
If preservation required by Login: Date/Time
Relinquished by: (Signature) Date,
Time
i'ved far I by: (5ignatur)
a e: Time;
�/ v2L 30
Hold:
Condit'
NCF , 0

urofins
Environment Testing
America
ANALYTICAL REPORT
Eurofins Chicago
2417 Bond Street
University Park, IL 60484
Tel: [phone]
Laboratory Job ID: 500-212792-1
Client Project/Site: WG1822593
For
Pace Analytical National
12065 Lebanon Rd
Mt Juliet, Tennessee 37122
Attn: Jimmy Huckaba
Authorized for release by:
212512022 2:46:10 PM
Jim Knapp, Project Manager II
[phone]
[e-mail]
Designee for
Sandie Fredrick, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for
accredited parameters, exceptions are noted in this report. This report may not be reproduced
except in full, and with written approval from the laboratory. For questions please contact the
Project Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
12
13
14

Client: Pace Analytical National
Project/Site: WG1822593
Laboratory Job ID: 500-212792-1
Table of Contents
Cover Page ..............................................
Table of Contents .........................................
2
Case Narrative ...........................................
3
Detection Summary ........................................
4
Method Summary .........................................
5
Sample Summary .........................................
6
Client Sample Results ......................................
7
Definitions ...............................................
8
QC Association ...........................................
9
QC Sample Results ........................................
10
Chronicle ................................................
11
Certification Summary ......................................
12
Chain of Custody ..........................................
13
Receipt Checklists .........................................
14
12
13
14
Eurofins Chicago
Page 2 of 14 2/25/2022

Case Narrative
Client: Pace Analytical National
Project/Site: WG1822593
Job ID: 500-212792-1
Laboratory: Eurofins Chicago
Narrative
Job Narrative
500-212792-1
Comments
No additional comments.
Job ID: 500-212792-1
Receipt
The sample was received on 2/24/2022 10:00 AM. Unless otherwise noted below, the sample arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 1.20 C.
General Chemistry
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
12
13
14
Eurofins Chicago
Page 3 of 14 2/25/2022

Detection Summary
Client: Pace Analytical National Job ID: 500-212792-1
Project/Site: WG1822593
Client Sample ID: BROWN WTP Lab Sample ID: 500-212792-1
ENo Detections.
This Detection Summary does not include radiochemical test results.
F47
12
13
14
Eurofins Chicago
Page 4 of 14 2/25/2022

Method Summary
Client: Pace Analytical National
Project/Site: WG1822593
Method Method Description
9034 Sulfide, Reactive
7.3.4 Sulfide, Reactive
Protocol References:
Job ID: 500-212792-1
Protocol Laboratory
SW846 TAL CHI
SW846 TAL CHI
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL CHI = Eurofins Chicago, 2417 Bond Street, University Park, IL 60484, TEL [phone]
12
13
14
Eurofins Chicago
Page 5 of 14 2/25/2022

Sample Summary
Client: Pace Analytical National
Project/Site: WG1822593
Lab Sample ID Client Sample ID Matrix Collected Received
500-212792-1 BROWN WTP Solid 02/16/22 08:30 02/24/22 10:00
Job ID: 500-212792-1
12
13
14
Page 6 of 14 Eurofins--J?N2922

Client Sample Results
Client: Pace Analytical National
Project/Site: WG1822593
Job ID: 500-212792-1
Client Sample ID: BROWN WTP Lab Sample ID: 500-212792-1
Date Collected: 02/16/22 08:30 Matrix: Solid
Date Received: 02/24/22 10:00
General Chemistry
Analyte Result Qualifier LOQ LOD Unit D Prepared Analyzed Dil Fac
Sulfide, Reactive <3.7 46.9 3.7 mg/Kg 02/24/22 19:05 02/25/22 11:02 1
12
13
14
Eurofins Chicago
Page 7 of 14 2/25/2022

Definitions/Glossary
Client: Pace Analytical National
Project/Site: WG1822593
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
II Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level'
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRIES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Job ID: 500-212792-1
0
12
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Eurofins Chicago
Page 8 of 14 2/25/2022

QC Association Summary
Client: Pace Analytical National
Project/Site: WG1822593
General Chemistry
Prep Batch: 644394
Job ID: 500-212792-1
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
500-212792-1
BROWN WTP
Total/NA
Solid
7.3.4
MB 500-644394/1-A
Method Blank
Total/NA
Solid
7.3.4
LCS 500-644394/2-A
Lab Control Sample
Total/NA
Solid
7.3.4
Analysis Batch: 644530
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
500-212792-1
BROWN WTP
Total/NA
Solid
9034
644394
MB 500-644394/1-A
Method Blank
Total/NA
Solid
9034
644394
LCS 500-644394/2-A
Lab Control Sample
Total/NA
Solid
9034
644394
12
13
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Eurofins Chicago
Page 9 of 14 2/25/2022

QC Sample Results
Client: Pace Analytical National
Project/Site: WG1822593
Job I D: 500-212792-1
Method: 9034 - Sulfide, Reactive
Lab Sample ID: MB 500-644394/1-A Client Sample ID: Method Blank
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 644530 Prep Batch: 644394
MB MB
Analyte Result Qualifier LOQ LOD Unit D Prepared Analyzed Dil Fac
Sulfide, Reactive <3.9 50.0 3.9 mg/Kg 02/24/22 18:46 02/25/22 10:49 1
Lab Sample ID: LCS 500-644394/2-A Client Sample ID: Lab Control Sample
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 644530 Prep Batch: 644394
Spike LCS LCS %Rec.
Analyte Added Result Qualifier Unit D %Rec Limits
Sulfide, Reactive 198 162.9 mg/Kg 82 80 -120
12
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Eurofins Chicago
Page 10 of 14 2/25/2022

Lab Chronicle
Client: Pace Analytical National
Project/Site: WG1822593
Job ID: 500-212792-1
Client Sample ID: BROWN WTP Lab Sample ID: 500-212792-1
Date Collected: 02/16/22 08:30 Matrix: Solid
Date Received: 02/24/22 10:00
Batch
Batch
Dilution Batch
Prepared
Prep Type Type
Method
Run Factor Number
or Analyzed Analyst Lab
Total/NA Prep
7.3.4
644394
02/24/22 19:05 TMS TAL CHI
Total/NA Analysis
9034
1 644530
02/25/22 11:02 TMS TAL CHI
Laboratory References:
TAL CHI = Eurofins Chicago, 2417
Bond Street, University
Park, IL 60484, TEL [phone]
11
12
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14
Eurofins Chicago
Page 11 of 14 2/25/2022

Accreditation/Certification Summary
Client: Pace Analytical National
Project/Site: WG1822593
Laboratory: Eurofins Chicago
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority
Program
California
State
Georgia
State
Georgia (DWW)
State
Hawaii
State
Illinois
NELAP
Indiana
State
Iowa
State
Kansas
NELAP
Kentucky (UST)
State
Kentucky (WWW)
State
Louisiana
NELAP
Mississippi
State
North Carolina (WWW/SW)
State
North Dakota
State
Oklahoma
State
South Carolina
State
USDA
US Federal Programs
Wisconsin
State
Wyoming
State
Job ID: 500-212792-1
Identification Number Expiration Date
2903
04-29-22
N/A
04-29-22
939
04-30-21
NA
04-29-22
IL00035
04-29-22
C-1 L-02
04-29-22
082
05-01-22
E-10161
10-31-22
Al # 108083
04-29-22
KY90023
12-31-22
02046
06-30-22
NA
04-30-22
291
12-31-22
R-194
04-29-22
8908
08-31-22
77001003
04-29-22
P330-18-00018
02-11-24
999580010
08-31-22
8TMS-Q
04-30-22
Accreditation/Certification renewal pending - accreditation/certification considered valid.
Eurofins Chicago
Page 12 of 14 2/25/2022

Batch Date/Time. 02/23/22 13 47
Sub -Contract Lab IACIPR
Address: 2417 Bond Street
City/State: University Park, 1I
60484
Contact:
San dra. Fredrrcktd Eurofinset. com
Owner Lab: PACLMTJL
kddress: 12065I ebanon Rd
City/State: Mt, Joliet, TN 37122
Phone: [phone]
Fax: [phone]
a—
WO.VvG 18225500-212792 COC
Lntad: M1;TI SuboutI'evn(&pacelabs corri
Results Due Date: 03/09/22
LSC. Purchase Order #: 1 1462872
Send Reports to: James C 1Juckaba
12065 Lebanon Rd
Mt Juliet, TN 37122
Phone [phone]
Fax [phone]
Sample ID Sample Number Sample Comments
Container ID Matrix State Collect Date Description Lab Use Only Lab Use Only
BROWN WTP SS NC 02/16/22 08 30 Miscellaneous Analysis 2 L1462872-01 Reactive Sulfide
Relinquished by: 4 Date a -al -C)vd.
Recre,�ed by: � Date LIP
Relinquished by
Recieved by: Date
Page 13 of 14 2/25/2022

Client: Pace Analytical National
Login Number: 212792
List Number: 1
Creator: Scott, Sherri L
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
True
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
1.2
Job Number: 500-212792-1
List Source: Eurofins Chicago
12
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Eurofins Chicago
Page 14 of 14 2/25/2022

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WQ0041666
EMA Resources Inc.
NC0002305
WWTP Name: Lear Corporation WWTP
Residual Analysis Data
Laboratory:
1)
2)
3)
4)
5)
Envirochem
Waypoint Analytical
Parameter
(mg/kg)
Conc.
Limit
(mg/kg a
Sample or Composite Date
2/17/22
9/27/22
10/6/22
11/1/22
Percent Solids (%)
NA
4.68
2.52
2.5
3.98
Arsenic
75
20.5
9.6
9.6
17
Cadmium
85
20.5
0.8
0.8
14.3
Copper
4,300
42.7
39
43.2
51.3
Chromium
NA
20.5
9.44
9.44
14.3
Lead
840
20.5
7.2
7.2
14.3
Mercury
57
0.372
0.305
0.396
0.457
Molybdenum
75
20.5
5.4
6.32
14.3
Nickel
420
20.5
4.8
4.8
14.3
Selenium
100
20.5
12.8
12.8
14.3
Zinc
7,500
66
32.4
35.3
93.5
Total Phosphorus
NA
14600
19800
20600
21200
TKN
NA
33600
31000
21800
34100
Ammonia -Nitrogen
NA
581
5560
3770
4970
Nitrate and Nitrite
NA
5.61
199
188
131
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Z�fz 2/8/2023
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
WQ0041666
EMA Resources Inc.
NC0002305
Lear Corporation WWTP
Laboratory: 1) Envirochem
2) Waypoint Analytical
3)
4)
5)
Parameter
Sample or • • • - Date
• •11
••:11
1:11
' 11
--------
11
11
11
11
--------
• •
1 1
1 1
' 1
1 1
--------
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
2/8/2023
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

]Mvironmental Chemists,
Inc.
f
6602 Windmill Way,
Wilmington, NC 28405 e 910.392.0223 Lab . 910.392.4424 Fax
-
710 Bowsertown Road, Manteo, NC 27954 • 252A73.5702 Lab/x ax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
ANALYTICAL & CONSULTING CHEMISTS
infoCaenvironmentalchemists.com
Guilford East
Date of Report: Mar 15, 2022
1754 NC HWY 903
Customer PO #:
Kenansville NC 28349
Customer ID: 11030018
Attention: George Yankay
Report #: 2022-03049
Project ID: Sludge
Lab ID Sample ID:
Collect Date/Time Matrix Sampled by
22-07209 Site: Sludge
2/17/2022
10.45 AM Solid/Sludge Dale Johnson
Test
Method
Results Date Analyzed
Chlordane (TCLP)
SW-846 8081 B
<0.02 mg/L
02/28/2022
Endrin (TCLP)
SW-8468081B
<0.0005mg/L
02128/2022
Heptachlor (TCLP)
SW-846 8031 B
<0.0005 mg/L
02/28/2022
Heptachlor epoxide (TCLP)
SW-846 8081 B
<0.0005 mg1L
02/28/2022
Lindane (TCLP)
SW-846 8081 a
<0.0005 mg/L
02/28/2022
Methoxychlor (TCLP)
SW-846 Bost B
<0.0005 mg/L
02/28/2022
- Toxaphene (TCLP)
sW-B468081 B
<0-05mg/L
02/2812022
2,4,5-TP (TCLP)
SW-846 8151 A
<0.003 mg/L
03102/2022
2,4-D (TCLP)
SW-8468151A
<0.003mg/L
03/02/2022
1,4-Dichlorobenzene (TCLP)
SW-846 $270 E
<0.050 mg/L
03/01/2022
2,4,5-Trichlorophenol (TCLP)
SW-846 8270 E
<0.050 mg/L
03101 /2022
2,4,6-Trichlorophenol (TCLP)
SW-a46 8270 a
<0.050 mg/L
03/01/2022
2,4-Dinitrotoluene (TCLP)
SW-846 8270 E
<0.050 mg/L
03/01/2022
Cresol (TCLP)
SW-846 8270 E
<0.050 mg/L
03/01/2022
Hexachloro-1,3-butadiene (TCLP)
SW-646 8270 E
<0.050 mg/L
03/01/2022
Hexachlorobenzene (TCLP)
SW-846 8270 E
<0.050 mg/L
03/01/2022
Hexachloroethane (TCLP)
SW-846 8270 E
<0,050 mg/L
03/0112022
m + p-Cresol (TCLP)
SW-845 8270 E
<0.050 mg/L
03/01/2022
Nitrobenzene (TCLP)
SW-846 8270 E
<0.050 mg/L
03/01/2022
o-cresol (TCLP)
SW-846 8270 a
<0.050 mg/L
03/01/2022
Pentachlorophenol (TCLP)
SW-846 8270 E
<0.250 mg/L
03/01/2022
Pyridine (TCLP)
SW-846 8270 S
<0.050 mg/L
03/01/2022
1, 1 -Dichloroethylene (TCLP)
SW-846 Method8260D
<0.01 mg/L
03/01/2022
1,2-Dichloroethane (TCLP)
SW-840 Method 8260D
<0.01 mg/L
03/01/2022
Benzene (TCLP)
5W B46 Method B260❑
<0-01 mg/L
03/01/2022
Carbon Tetrachloride (TCLP)
SW-846 Method 82601)
<0.01 mg/L
03101/2022
Report#., 2022-o3049
Pagel of4

Guilford East
Date of Report: Mar 15, 2022
1754 NC HWY 903
Customer PO #:
Kenansville NC
28349
Customer ID: 11030018
Attention: George Yankay
Report #: 2022-03049
Project ID: Sludge
Chlorobenzene (TCLP)
SW-646 Method 8260D
<0.01 mg/L
03/01/2022
Chloroform (TCLP)
SW-146 Method 82800
<0.01 mg/L
03/01/2022
Methyl ethyl ketone (TCLP)
SW-846 Method 82500
<0.05 mg/L
03/0112022
Tetrachloroethylene (TCLP)
SW 646 Method 62600
<0.01 mg1L
03/01/2022
Trichloroethylene (TCLP)
SW-846 Method 926oD
<0.01 mg/L
03/01/2022
Vinyl Chloride (TCLP)
SW-846 Method 8260D
<0.01 mg/L
03/01/2022
:T41
Cyanide
SM 4500 CN 0-2016
1.60 mg/kg
03/01/2022
Sulfide
SM 4500 S D
8.50 mg/kg
03/03/2022
lgnitability
SW 646 method 1010
>158 OF
02/26/2022
Sludge Residuals
Aluminum
EPA 200.7, Rev.4,4, 1994
63900mglkg
02/22/2022
Arsenic
EPA 200.7, Rev. 4.4,1994
<20.5 mglkg
02/22/2022
Cadmium
EPA2007. Rev. 4A,1994
<20.5mglkg
02/22/2022
Calcium
EPA 200,7. Rev. 4.4,1994
11500 mglkg
02/2212022
Chromium
EPA 200 7, Rev. 4A, 1994
<20.5 mglkg
02/22/2022
Copper
EPA 200.7. Rev, 4.4, 1994
42.7 mg/kg
02/22/2022
Lead
EPA 200,7, Rev. 4.4, 1994
<20.5 mglkg
02/22/2022
Magnesium
EPA 200.7, Rev. 4.4, 1994
2740 mg/kg
02/22/2022
Molybdenum
EPA 200.7, Rev_ 4,4, 1994
<20.5 mglkg
02/2212022
Nickel
EPA 200.7. Rev. 4.4, 1994
<20.5 mglkg
02/22/2022
Potassium
EPA 200.7, Rev. 4.4, 1994
2090 mg/kg
02/22/2022
Selenium
EPA 200.7, Rev. 4.4, 1994
<20.5 mg/kg
02/22/2022
Sodium
EPA 200.7, Rev_ 4.4, 1994
2500 mg/kg
02/22/2022
Zinc
EPA2007, Rev. 4.4, 1994
66.0 mg/kg
02/22/2022
Nitrate+Nitrite-Nitrogen
EPA353.2
5.61 mglkg
02/21/2022
-- Total Solids (%)
SM 2540 B
4.68 %
02/1812022
Ammonia Nitrogen
SM 4500 NH3 C-2011
581 mg/kg
02/22/2022
Total Kjeldahl Nitrogen (TKN)
SM 4500 Norg B-2011
33600 mg/kg
02/22/2022
Total Phosphorus
SM 4500 P (F-H)-2011
14600 mg/kg
02/23/2022
Report0t: 2022-03049
Page 2 of 4

A Ai
ANALYTICAL & CONSULTING CHEMISTS
Guilford East
1754 NC HWY 903
Kenansville NC
Attention: George Yankay
Environmental Chfists, Inc.
6602 Windmill Way, Wilmington, NC 28405 ° 910-392.OM Lab • 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 a 252.473.3702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
info@environmen to lchemists.corn
Date of Report: Mar 15, 2022
Customer PO #:
28349 Customer ID: 11030018
Report #: 2022-03049
Project ID: Sludge
pH SW 846 Method 90450
Result estimated. Anaiyzed out of 15 minutes hold time.
Mercury
TCLP Metals
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Mercury
Lab ID Sample ID:
22-07210 Site: Sample 1
SW-846 7471 B
EPA 200.7, Rev. 4.4, 1994
EPA 200.7, Rev. 4.4, 1994
EPA 200.7, Rev. 4.4, 1994
EPA 200.7, Rev. 4.4, 1994
EPA 200.7. Rev 4.4, 1994
EPA 200.7. Rev. 4.4, 1994
EPA 2007. Rev 4.4, 1994
EPA 245.1
Collect Date/Time
2/17/2022 9:00 AM
6.98 units 03/14/2022
<0.372 mg/kg 02118/2022
<1.0 mg/L
02/2812022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<0.0002 mg/L
02/28/2022
Matrix Sampled by
Solid/Sludge Dale Johnson
Test Method Results Date Analyzes!
Total Solids (°!n) Sin 254€ B 2.50 % 02/18/2022
Fecal Density SM 9221C E-2014 80 MPN/g 02/17/2022
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-07211 Site: Sample 2 2/1712022 9:15 AM Solid/Sludge Dale Johnson
Test Method Results Date Analyzed
Total Solids {%) SM 2540 B 2.34 % 02/18/2022
Fecal Density SM 9221C E-2014 193 MPN/g 02/17/2022
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-07212 Site: Sample 3 2/17/2022 9.30 AM Solid/Sludge Dale Johnson
Test Method Results Date Analyzes)
Total Solids (%)
Fecal Density
SM 2540 B
SM 9221 C E-2014
2.43 % 02/18/2022
83 MPNIg 02/17/2022
Report : 2022-03049 Page 3 of 4

Guilford East
Date of Report: Mar 15, 2022
1754 NC HWY 903
Customer PO #:
Kenansville NC
28349 Customer ID: 11030018
Attention: George Yankay
Report 9: 2022-03049
Project ID: Sludge
Lab ID Sample ID:
Collect Date/Time Matrix Sampled by
22-07213 Site: Sample 4
2/17/2022 9:45 AM Solid/Sludge Dale Johnson
Test
Method Results Date Analyzed
Total Solids {p/p)
SM 2540 B 2.12 % 02/18/2022
Fecal Density
SM 9221C E-2014 213 MPN/g 02/17/2022
Lab ID Sample ID:
Collect Date/Time Matrix Sampled by
22-07214 Site: Sample 5
2/17/2022 10:00 AM Solid/Sludge Dale Johnson
Test
Method Results Date Analyzed
Total Solids (%)
SM 2540 B 2.28 % 02/18/2022
Fecal Density
SM 9221C E-2014 198 MPN/g 02/17/2022
Lab ID Sample ID:
Collect DateMme Matrix Sampled by
22-07215 Site: Sample 6
2/17/2022 10:15 AM Solid/Sludge Dale Johnson
Test
Method Results Date Analyzed
Total Solids (%)
SM 2W s 2.30 a/o 02118/2022
Fecal Density
SM 9221 C E-2014 B7MPN/g 02/17/2022
Lab ID Sample 1D:
Collect Date/Time Matrix Sampled by
22-07216 Site: Sample 7
2/17/2022 10:30 AM Solid/Sludge Dale Johnson
Test
Method Results Date Analyzed
Total Solids (%)
SM 2540 B 2.60 % 02/18/2022
Fecal Density
SM 9221C E-2014 77 MPN/g 02/17/2022
Comment: Sludge residual,
except pH, reported on a dry weight basis. pH reported on an as received basis.
Reviewed by:
Report #.' 2022-03049
Page 4 of 4

Lear Corp 2/17/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 2500 117 23 5.086957
Calcium 11500 538.2 20 26.91
Magnesium 2740 128.232 12 10.686
Percent Solids 4.68
SAR 1.17
SAR =
Na+
a (Ca2+ + M;42+ )
5.08696
0.5( 26.91 2 + 10.68600 2 )

Waypointo
ANALYTICAL
10/12/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-271-0063
Client Project Description: Kenanville, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 9/28/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 11

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-271-0063
Page 2 of 11

Waypoint
ANALYTICAL
Report Number: 22-271-0063
Client Project Description: Kenanville, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Lab No Client Sample ID Matrix
88939 Guilford Mills
Solids
Date Collected
09/27/2022 08:00
Date Received
09/28/2022
Page 3 of 11

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Kenanville, NC
Lab Report Number: 22-271-0063
Date: 10/12/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 88974
Analyte: Aluminum
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Arsenic
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Calcium
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Cadmium
QC Batch No: 1-641833/1-640939
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance
ranges. Matrix interference is suspected.
Sample 88974
Analyte: Cadmium
QC Batch No: 1-641833/1-640939
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance
ranges. Matrix interference is suspected.
Sample 88974
Analyte: Chromium
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Copper
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Iron
Page 4 of 11

Waypoint".0
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
QC Batch No: 1-642077/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Potassium
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 88974
Analyte: Magnesium
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Manganese
QC Batch No: 1-642077/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Molybdenum
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Sodium
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 88974
Analyte: Nickel
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Phosphorus
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Lead
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 5 of 11

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 88974
Analyte: Sulfur
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88974
Analyte: Selenium
QC Batch No: 1-641833/1-640939
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 88974
Analyte: Selenium
QC Batch No: 1-642077/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 88974
Analyte: Zinc
QC Batch No: 1-641833/1-640939
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93878 (Curt East Yard)
Analyte: Aluminum
QC Batch No: 1-642674/1-642280
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93878 (Curt East Yard)
Analyte: Iron
QC Batch No: 1-642674/1-642280
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93878 (Curt East Yard)
Analyte: Potassium
QC Batch No: 1-642674/1-642280
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 93878 (Curt East Yard)
Analyte: Magnesium
QC Batch No: 1-642674/1-642280
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93878 (Curt East Yard)
Analyte: Manganese
QC Batch No: 1-642674/1-642280
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 6 of 11

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 93878 (Curt East Yard)
Analyte: Sodium
QC Batch No: 1-642674/1-642280
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93878 (Curt East Yard)
Analyte: Phosphorus
QC Batch No: 1-642674/1-642280
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93878 (Curt East Yard)
Analyte: Sulfur
QC Batch No: 1-642674/1-642280
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 93878 (Curt East Yard)
Analyte: Zinc
QC Batch No: 1-642674/1-642280
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 7 of 11

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Kenanville, NC
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Report Date : 10/12/2022
nReceived : 09/28/2022
C-�*�-� =
Connie Cook
Report Number : 22-271-0063
REPORT OFANALYSIS
Project
Manager
Lab No : 88939
Matrix:
Solids
Sample ID : Guilford Mills
Sampled:
9/27/2022
8:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
97.5
%
1
09/30/22 15:53
FMM
SW-DRYWT
Ammonia Nitrogen
5560
mg/Kg -
dry
640
4000
1
10/05/22 13:45
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<199
mg/Kg -
dry
199
199
1
09/30/22 14:57
CLP
4500NO3F-2016
Organic N
25440
mg/Kg -
dry
640.0
4000
1
10/04/22 10:00
DH
CALCULATION
pH
6.5
S.U.
1
10/05/2213:32
SAR
9045D
Total Solids
2.52
%
0.010
0.010
1
09/30/22 15:53
FMM
2540G-2011
Total Volatile Solids
75.1
%
0.010
0.010
1
09/30/22 15:53
FMM
2540G-2011
Total Kjeldahl Nitrogen
31000
mg/Kg -
dry
400
10000
1
10/04/22 10:00
JPJ ;M-4500-NH3C-TKI`
Phosphorus
19800
mg/Kg -
dry
110
200
1
10/07/22 02:58
EAL
6010D
Aluminum
66800
mg/Kg -
dry
185
200
1
10/07/22 02:58
EAL
6010D
Arsenic
<9.60
mg/Kg -
dry
9.60
20.0
1
10/07/22 02:58
EAL
6010D
Cadmium
<0.800
mg/Kg -
dry
0.800
4.00
1
10/07/22 02:58
EAL
6010D
Calcium
11100
mg/Kg -
dry
1550
2000
1
10/07/22 02:58
EAL
6010D
Chromium
<9.44
mg/Kg -
dry
9.44
10.0
1
10/07/22 02:58
EAL
6010D
Copper
39.0
mg/Kg -
dry
12.4
20.0
1
10/07/22 02:58
EAL
6010D
Iron
3883
mg/Kg -
dry
341
400
1
10/12/22 00:24
EAL
6010D
Lead
<7.20
mg/Kg -
dry
7.20
12.0
1
10/07/22 02:58
EAL
6010D
Magnesium
2980
mg/Kg -
dry
103
200
1
10/07/22 02:58
EAL
6010D
Manganese
38.7
mg/Kg -
dry
13.0
20.0
1
10/07/22 02:58
EAL
6010D
Mercury
0.3053
mg/Kg -
dry
0.258
5.92
1
09/30/22 11:41
TJS
7471A
Molybdenum
<5.40
mg/Kg -
dry
5.40
10.0
1
10/07/22 02:58
EAL
6010D
Nickel
<4.80
mg/Kg -
dry
4.80
10.0
1
10/07/22 02:58
EAL
6010D
Potassium
2600
mg/Kg -
dry
247
400
1
10/07/22 02:58
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 8 of 11

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Kenanville, NC
Mr. Brent Collins
Report Date : 10/12/2022
755 Yadkinville Rd
Information :
Received : 09/28/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-271-0063
REPORT OFANALYSIS
Project Manager
Lab No : 88939
Matrix: Solids
Sample ID : Guilford Mills
Sampled: 9/27/2022 8:00
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
< 12.8
mg/Kg - dry
12.8
20.0 1 10/07/22 02:58 EAL 6010D
Sodium
3020
mg/Kg - dry
520
1000 1 10/07/22 02:58 EAL 6010D
Zinc
<32.4
mg/Kg - dry
32.4
50.0 1 10/07/22 02:58 EAL 6010D
Sulfur
13800
mg/Kg - dry
207
400 1 10/07/22 17:27 TJS 6010D
Sodium Absorption Ratio
1.03
Ratio
0.01
0.01 1 10/07/22 02:58 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 9 of 11

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-271-0063
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT99
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: Summer Harrison Date & Time: 09/28/2022 11:55:15
Page 10 of 11

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Page 11 of 11

Lear Corp 9/27/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
3020
76.104
23 3.30887
Calcium
11100
279.72
20 13.986
Magnesium
2980
75.096
12 6.258
Percent Solids
2.52
SAR
1.04
SAR =
Na+
a (Ca2+ + M;42+ )
3.30887
0.5( 13.986 2 + 6.25800 2 )

Waypointo
ANALYTICAL
10/18/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-280-0161
Client Project Description: Kenansville, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 10/7/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-280-0161
Page 2 of 8

Waypoint
ANALYTICAL
Report Number: 22-280-0161
Client Project Description: Kenansville, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Lab No Client Sample ID Matrix
94424 Guilford Performance Textiles
Solids
Date Collected
10/06/2022 06:00
Date Received
10/07/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Kenansville, NC
Lab Report Number: 22-280-0161
Date: 10/18/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 94251 (SW Cake)
Analyte: Aluminum
QC Batch No: 1-643164/1-642701
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 94251 (SW Cake)
Analyte: Iron
QC Batch No: 1-643299/1-642701
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 94251 (SW Cake)
Analyte: Potassium
QC Batch No: 1-643164/1-642701
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 94251 (SW Cake)
Analyte: Sulfur
QC Batch No: 1-643566/1-642701
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 8

•
27090 Whitten Road, Memphis, TN 38133
Waypoint
Main 901.213.2400 ° Fax [phone]
ANALYTICAL www.waypointanalyiical.com
46245
EMA Resources Inc Project Kenansville, NC
Mr. Brent Collins Report Date : 10/18/2022
755 Yadkinville Rd Information : Received : 10/07/2022
Mocksville , NC 27028
Report Number : 22-280-0161 REPOR T OF ANAL YSIS Danyale Love
Project Manager
Lab No : 94424
Matrix: Solids
Sample ID : Guilford Performance Textiles
Sampled:
10/6/2022
6:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
97.5
%
1
10/12/22 15:33
FMM
SW-DRYWT
Ammonia Nitrogen
37703
mg/Kg -
dry
640
4000
1
10/17/22 15:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<188
mg/Kg -
dry
188
188
1
10/11/22 15:17
ZBD
4500NO3F-2016
Organic N
180703
mg/Kg -
dry
6000
12120
1
10/11/22 16:02
CALCULATION
pH
6.8
s.u.
1
10/14/2215:03
SAR
9045D
Total Solids
2.50
%
0.010
0.010
1
10/12/22 15:33
FMM
2540G-2011
Total Volatile Solids
74.8
%
0.010
0.010
1
10/12/22 15:33
FMM
2540G-2011
Total Kjeldahl Nitrogen
21800
mg/Kg -
dry
12100
1
10/11/22 16:02
ANH 4500NORGD-2011
Phosphorus
20600
mg/Kg -
dry
110
200
1
10/14/22 03:56
TJS
6010D
Aluminum
70800
mg/Kg -
dry
185
200
1
10/14/22 03:56
TJS
6010D
Arsenic
<9.60
mg/Kg -
dry
9.60
20.0
1
10/14/22 18:48
EAL
6010D
Cadmium
<0.800
mg/Kg -
dry
0.800
4.00
1
10/14/22 03:56
TJS
6010D
Calcium
11200
mg/Kg -
dry
1550
2000
1
10/14/22 03:56
TJS
6010D
Chromium
<9.44
mg/Kg -
dry
9.44
10.0
1
10/14/22 03:56
TJS
6010D
Copper
43.2
mg/Kg -
dry
12.4
20.0
1
10/14/22 03:56
TJS
6010D
Iron
584
mg/Kg -
dry
341
400
1
10/14/22 03:56
TJS
6010D
Lead
<7.20
mg/Kg -
dry
7.20
12.0
1
10/14/22 03:56
TJS
6010D
Magnesium
3050
mg/Kg -
dry
103
200
1
10/14/22 03:56
TJS
6010D
Manganese
42.8
mg/Kg -
dry
13.0
20.0
1
10/14/22 03:56
TJS
6010D
Mercury
0.3963
mg/Kg -
dry
0.240
5.52
1
10/11/22 13:00
TJS
7471A
Molybdenum
6.323
mg/Kg -
dry
5.40
10.0
1
10/14/22 03:56
TJS
6010D
Nickel
<4.80
mg/Kg -
dry
4.80
10.0
1
10/14/22 03:56
TJS
6010D
Potassium
2950
mg/Kg -
dry
247
400
1
10/14/22 03:56
TJS
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

•
Waypoint
27090 Whitten
Road, Memphis, TN 38133
Main
901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Kenansville, NC
Mr. Brent Collins
Report Date : 10/18/2022
755 Yadkinville Rd
Information :
Received : 10/07/2022
Mocksville , NC 27028
Danyale Love
Report Number : 22-280-0161
REPOR T OF ANAL YSIS
Project Manager
Lab No : 94424
Matrix: Solids
Sample ID : Guilford Performance Textiles
Sampled: 10/6/2022 6:00
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
< 12.8
mg/Kg - dry
12.8
20.0 1 10/14/22 18:48 EAL 6010D
Sodium
3140
mg/Kg - dry
520
1000 1 10/14/22 03:56 TJS 6010D
Zinc
35.33
mg/Kg - dry
32.4
50.0 1 10/14/22 03:56 TJS 6010D
Sulfur
14000
mg/Kg - dry
207
400 1 10/18/22 00:09 EAL 6010D
Sodium Absorption Ratio
1.07
Ratio
0.01
0.01 1 10/14/22 03:56 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-280-0161
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IMakayla Weaver Date & Time: 10/07/2022 13:56:32
Page 7 of 8

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Page 8 of 8

Lear Corp 10/6/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 3140 78.5 23 3.413043
Calcium 11200 280 20 14
Magnesium 3050 76.25 12 6.354167
Percent Solids 2.5
SAR 1.07
SAR =
Na+
a (Ca2+ + M;42+ )
3.41304
0.5( 14 2 + 6.35417 2 )

Guilford East
1754 NC HWY 903
Kenansville NC 28349
Attention: George Yankay
EinvironmentO Chemists,
6602 Windmill Way, Wilmington, NC 28405 ® 910.392.0773 Lab 8 910,392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 @ 910.347.5843 Lab/Fax
[e-mail]
Date of Report: Dec 14, 2022
Customer PO #:
Customer ID: 11030018
Report M 2022-21693
Project ID: Wastewater/Effluent
Lab ID Sample ID:
Collect Date/Time
Matrix Sampled by
22.53165 Site: Effluent
11/1/2022 9:00 AM
Water Dale Johnson
Test
Method
Results Date Analyzed
Residue Suspended (TSS)
SM 2540 0-2015
5.5 mg/L 11/02/2022
SOD
5M 5210 B-2016
4 mg/L 11/01/2022
COD
SM 5220 D12011
84.0 mg/L 11 /02/2022
Lab ID Sample ID:
Collect DatelTime
Matrix Sampled by
22-53166 Site: Sludge}'>
11/1/2022 10.00 AM
Solid/Sludge Dale Johnson
Test
Method
Results Date Analyzed
Total Solids (%}
SM 254D 6
6.00 % 11/02/2022
Fecal Density
SM 9221C E-2D14
75 MPN/g 11/0112022
Lab ID Sample ID:
Collect Date/Time
Matrix Sampled by
22-53167 Site: Sludge::
11/1/2022 10:01 AM
Solid/Sludge Dale Johnson
Test
Method
Results Date Analyzed
Total Solids (%)
8M 2540 e
5.10 % 1 '1102/2022
Fecal Density
sM 9221C E-2014
89 MPN/g 11/01/2022
Lab ID Sample ID:
Collect DatetTime
Matrix Sampled by
22-53168 Site: Sludge
11/1/2022 10:02 AM
Solid/Sludge Dale Johnson
Test
Method
Results Date Analyzed
Total Solids (%)
SM 2540 8
5.15 % 11/02/2022
Fecal Density
SM 9221 C E-2014
78MPNIg 11/01/2022
Lab ID Sample ID:
Collect DatelTime
Matrix Sampled by
22-53169 Site: Sludge;:.
11/1/2022 10:03 AM
Solid/Sludge Dale Johnson
Test
Method
Results Date Analyzed
Total Solids (%)
SM 2540 a
5.20 % 11/02/2022
Fecal Density
SM 9221C E-2014
39 MPN/g 11/01/2022
Report# 2022-21693
Page 1 of

Guilford East Date of Report: Dec 14, 2022
1754 NC HWY 903 Customer PO #:
Kenansville NC 28349 Customer ID: 11030018
Attention: George Yankay Report #: 2022-21693
Project ID: Wastewater/Effluent
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-53170 Site: Sludge: 11/1/2022 10:04 AM Solid/Sludge Dale Johnson
Test Method Results Date Analyzed
Total Solids (%) SM 2540 B 5.22 % 11/02/2022
Fecal Density SM 9221C E-2014 39 MPN/g 11/01/2022
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-53171 Site: S.ludge.. 11/1/2022 10:05 AM Solid/Sludge Dale Johnson
Test Method Results Date Analyzed
Total Solids (%)
Fecal Density
Lab ID Sample ID:
22-53172 Site: Sludge.;
Test
Total Solids (%)
Fecal Density
SM 2540 B
SM 9221 C E-2014
5.65 % 11/02/2022
36 MPN/g 1 IJ0112022
Collect Date/Time Matrix Sampled by
11/1/2022 10:06 AM Solid/Sludge Dale Johnson
Method Results Date Analyzed
SM 2540 B 5.44 % 11 /02/2022
SM 9221C E-2014 37 MPN/g 11 /0112022
Report# 2022.21693 Page 2 of 5

Guilford East Date of Report: Dec 14, 2022
1754 NC HWY 903 Customer PO #:
Kenansville NC 28349 Customer ID: 11030018
Attention: George Yankay Report #: 2022-21693
Project ID: Wastewater/Effluent
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-53173 Site:.:Sludge 11/1/2022 10.07 AM Solid/Sludge Dale Johnson
Test Method Results Date Analyzed
Chlordane (TCLP)
SW-8468081 B
<0.02 mg/L
11/09/2022
Endrin(TCLP)
SW-8468081E
<0.0005mg/L
11/09/2022
Heptachlor (TCLP)
SW-8468081 B
<0.0005mg/L
11/09/2022
Heptachlor epoxide (TCLP)
SW8468061 B
<0.0005mgIL
11/09/2022
Lindane (TCLP)
SW-846 S081 B
<0.0005 mg/L
11109/2022
Methoxychlor (TCLP)
SW-846 5081 B
<0.0005 mg/L
11/09/2022
Toxaphene (TCLP)
SW-8468081 B
<0.05mg/L
11/09/2022
2,4,5-TP (TCLP)
SW-84e 8151 A
<0.003 mg/L
11/09/2022
2,4-D (TCLP)
SW-846 6151 A
<0.003 mg/L
11/0912022
1,4-Dichlorobenzene (TCLP)
SW-846 8270 E
<0.050 mg/L
11/22/2022
2,4,5-Trichlorophenol (TCLP)
SW-846 8270 E
<0.050 rng/L
11/22/2022
2,4,6-Trichlorophenol (TCLP)
SW-846 8270 E
<0.050 mg/L
11/22/2022
2,4-Dinitrotoluene (TCLP)
SW-846 8270 E
<0.050 mg/L
11/2212022
Cresol (TCLP)
8W-846 3270 E
<0.050 mg/L
11/22/2022
Hexachloro-1,3-butadiene (TCLP)
SW-a468270E
<0.050mg/L
11/22/2022
Hexachlorobenzene (TCLP)
SW-8468270E
<0.050mg/L
11/22/2022
Hexachloroethane (TCLP)
SW-8468270E
<0.050mg/L
11/2212022
m + p-Creso[ (TCLP)
SW-846 8270 E
<0.050 mg1L
11/22/2022
Nitrobenzene (TCLP)
SW-846 8270 E
<0.050 mg/L
11/22/2022
o-Cresol (TCLP)
SW-846 8270 E
<0.050 mg/L
11/22/2022
Pentachlorophenol (TCLP)
SW-8468270E
<0.250mg/L
II/22/2022
Pyridine (TCLP)
SW-846 8270 E
<0.050 mg/L
11122/2022
1, 1 -Dich loroethylene (TCLP)
SW-846 Method 8260D
<0.01 mg/L
11/10/2022
1,2-Dichloroethane (TCLP)
SW-846 Method 82e0D
<0.01 mg/L
11/1012022
Benzene (TCLP)
SW-846 Method 8260D
<0.01 mg/L
11/10/2022
Carbon Tetrachloride (TCLP)
SW-845 Method 8260D
<0.01 mg/L
11/10/2022
Report # 2022-21593
Page 3 of 5

ANALYTICAL & CONSULTING CHEMISTS
tot
6602 Windmill Way, Wilmington, NC 28405 1 910,392.0223 Lab 9 910.392.4424 Fax
710 Bowsertown load, Manteo, NC 27954 ° 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Pax
[e-mail]
Guilford East
Date of Report: Dec 14, 2022
1754 NC HWY 903
Customer PO #:
Kenansville NC 28349
Customer ID: 11030018
Attention: George Yankay
Report #: 2022-21693
Project ID: Wastewater/Effluent
Chlorobenzene (TCLP)
SW-845 Method 8260D
<0.01 mg/L
11110/2022
Chloroform (TCLP)
SW-846 Method82601)
<0.01 mg/L
11/10/2022
Methyl ethyl ketone (TCLP)
SW-646 Method 8260D
<0.05 mg/L
11/10/2022
Tetrachloroethylene (TCLP)
5W-846 Method 8260D
<0.01 mg/L
11/10/2022
Trichloroethylene (TCLP)
SW-846 Method 8260D
<0.01 mg/L
11110/2022
Vinyl Chloride (TCLP)
SW646 Method 8260D
<0.01 mg/L
11/10/2022
RCI
Cyanide
SM 4500 CN D-2016
<1,0 mg/kg
11/17/2022
Sulfide
SM 4500 S D
1.56 mg/kg
11128/2022
Ignitability
SW 846 method 1010
> 157'F
11/28/2022
Sludge Residuals
Aluminum
EPA 200-7. Rev 44. 1994
74200mglkg
12/06/2022
Arsenic
EPA 200.7, Rev 4.4, 1994
17.0 mg/kg
11/16/2022
Cadmium
EPA 200.7, Rev 4.4. 1994
<14.3 mg/kg
11/16/2022
Calcium
EPA 200 7, Rev 4 4. 1994
11500 mg/kg
11/16/2022
Chromium
5PA2007,Rev 4.4, 1994
<14.3mg/kg
11/1612022
Copper
EPA 200 7, Rev. 4 4, 1994
51.3 mglkg
11/16/2022
Lead
EPA 2a0 7, Rev, 4 4, 1994
<14.3 mg/kg
11116/2022
Magnesium
EPA 200.7,Rev..44.1994
2540mg/kg
11/1612022
Molybdenum
EPA 200.7, Rev 44, 1994
<14.3mglkg
11/16/2022
Nickel
EPA 200.7, Rev 4.4, 1994
<14.3 mglkg
11/16/2022
Potassium
EPA 2007, Rev 4.4, 1994
1570mglkg
11/1612022
Selenium
EPA 2007,Rev 4 4, 1994
<14.3mglkg
11/16/2022
Sodium
EPA 2007,Rev 4 4. 1994
2300mg/kg
12/06/2022
Zinc
EPA 200 7. Rev 4.4. 1994
93.5 mg/kg
11116/2022
Nitrate+Nitrite-Nitrogen
EPA 3532
131 mg/kg
11/02/2022
Total Solids (%)
SM 2540 s
3.98 %
11/0212022
Ammonia Nitrogen
SM 4500 NH3 C-2011
4970 mg/kg
11/0212022
Total Kjeldahl Nitrogen (TKN)
SM 4500 Norg 5-2011
34100 mg/kg
11 /02/2022
Report # 2022-21693 Page 4 of 5

ANALYTICAL & CONSULTING CHEMISTS
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 9 910.392.0223 Lab a 910.392.=1424 Fax
710 Bowsertown Road., Nlanteo, NC 27954 1 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 ® 910.347.5843 Lab/Fax
in foCa environmentalchemists.com
Guilford East Date of Report: Dec 14, 2022
1754 NC HWY 903 Customer PO #:
Kenansville NC 28349 Customer ID: 11030018
Attention: George Yankay Report #: 2022-21693
Project ID: Wastewater/Effluent
Total Phosphorus SM 4500 P (F-H)-2011 21200 mg/kg 11/04/2022
pH SW 646 Method 9045D 7.37 units 11/14/2022
Result estimated. Analyzed out of 15 minutes hold time.
Mercury
SW-946 7471 a
<0.457 mg/kg
11/14/2022
TCLP Metals
Arsenic (TCLP)
EPA 200.7. Rev 44.1994
<1.0 mg1L
11/14/2022
Barium (TCLP)
EPA 200.7. Rev 4.4, 1994
<1.Omg/L
11/14/2022
Cadmium (TCLP)
EPA 200.7, Rev 4.4,1994
<1.Omg/L
11/14/2022
Chromium (TCLP)
EPA 2007, Rev.4.4, 1994
<1.0mg1L
11/14/2022
Lead (TCLP)
EPA 200.7, Rev. 4 4, 1994
<1.O mg/L
11/14/2022
Selenium (TCLP)
EPA200.7, Rev 44.1994
<1,0rng/L
11/14/2022
Silver (TCLP)
EPA 200.7, Rev 44,1994
<1.0 mg/L
11/14/2022
Mercury (TCLP)
EPA245,1
<0.0002 mg/L
1 If14/2022
Comment: Leachate extraction for the 8270E analysis was performed outside of holding time. Sludge
residuals, except pH, reports on a dry weight basis. pH reported on an as received basis.
Reviewed by:
Report * 2022-21693 Page 5 of 5

Analytical Envirantnental Services, Inc
Date: 23-Nov-22
CE Bent: Environmental Chemists. Inc,
Client Sample ID:
22-53I73
Project Name, 2022-21693
Collection Date:
11i1/202210:07:00AM
Lab ID: 2211050-001
Matrix.
Solid
Reporting
Dilution
Analyses Result
Qual Units BatchlD
DatcAual}zed Analyst
Limit
Factor
Total Organic Carbon in Sail SW9060
(SW9060 Modified)
Total Organic Carbon (TOC) 424000
999 mW g-dry 346861
1 11:22.7022 13 00 NM
Qunlir[ers; Yatue eAcceds maximum mntammant Icy at E Esnmated €value abos a cl-nation range)
9n 9cl0w repurnnu llmlt S Spike Recovey outside limits due to matnx
H Holding nines for preparation or analysis exceeded Narr Sec case narmn'e
N Analyze not NELAC caniGed F Analyzed in the lab which is a dc,aacn from the method
H Analyre dt, emrd ra Ehe assocaaEed method hlunk Less dean Result value
Grater thau Result ,alae 1 Esnrnaled value detected beta, lieponmg 1--t
Page 3 of 6

vt � fi3i
T AL' l'
.\ R a$ 1€ t A L
w
66002 Windmill Way
Wilmington, NC 28405
Client Project: 2022-21693
Sample .Received: 11 / 14/22
1122-743
.isotope Dilution Method
PFAS — Draft M 163 3 List (40)
L: MUM
� r �
Mark Hager
0: 910-876-68941 F. 910-212-6886
mark.hager@_enthalj2y.com I www.enthalpy.com
2714 Exchange Drive, Wilmington, NC 28405

I certify that to the best of my knowledge all analytical data presented in this report;
0 Have been checked for completeness
• Are accurate, error -free, and legible
• Have been conducted in accordance with approved protocol, and that all deviations and
analytical problems are summarized in the appropriate narrative(s)
This analytical report was prepared in Portable Document Format (.PDF) and contains 21
pages.
ENTHALPY
f
f
C� Revi w Performed by: Laura K. 8oivin
1211f2Q22
Report Issued Date:
EU 1122-743 Page 2 of 21

ENTHALPY
A N A L Y T I L I L
Summary of Results
EU 1122-743 Page 3 of 21

Enthalpy Analytical
Job No.: 1122-743-1 PFAS by Isotope Dilution (soils/solids)
Environmental Chemist Client Project: 2022-21693
Compound
CAS
22-53173
ngtg
Acids
PFBA
375-22-4
11.5
PFPeA
2706-90-3
58.6
PFHxA
307-24-4
54.7
PFHpA
375-85-9
31,0
PFOA
335-67-1
49.5
PFNA
375-95-1
22.4
PFDA
335-76-2
76A
PFUnDA
2058-94-8
56.7
PFDoDA
307-55-1
7.58
PFTrDA
72629-94-8
11.7
PFTeDA
PFBS
376-06-7
375-73-5
1.49 J
<LOD (0.460) U
Sulfonates
PFPeS
2706-91-4
<LOD (0.312) U
PFHxS
355-46-4
1,97 J
PFHpS
375-92-8
<LOD (0.492) U
PFOS
1763-23-1
139
PFNS
68259-12-1
<LOD (0.405) U
PFDS
335-77-3
<LOD (0.344) U
4:2 FTS
757124-72-4
<LOD (0.294) U
6:2 FTS
27619-97-2
<LOD (0.178) U
8:2 FTS
PFOSA
39108-34-4
754-91-6
<LOD (0.341) U
37.1
Other
N-McFOSAA
2355-31-9
49.5
N-EtFOSAA
2991-50-6
0.912 J
HFPO-DA
13252-13-6
<LOD (0.449) U
PFMOPrA
377-73-1
<LOD (0.757) U
ADONA
919005-14-4
CLOD (1.52) U
9CI-PF30NS
756426-58-1
<LOD (1.52) U
11CI-PF3OUdS
763051-92-9
<LOD (1.52) U
3:3 FTCA
356-02-5
<LOD (55.5) U
5:3 FTCA
91463749-3
18.5
7:3 FTCA
812-70-4
22.1
N-EtFOSA
4151-50-2
<LOD (0.757) U
N-EtFOSE
1691-99-2
<LOD (22.7) U
NFDHA
151772-58-6
<LOD (0.757) U
N-McFOSA
31506-32-8
2.42 J
N-McFOSE
24448-09-7
34.7
PFDoS
79780-39-5
<LOD (7.07) U
PFEESA
113507-82-7
<LOD (0.757) U
PFMOBA
863090-89-5
<LOD (4.54) U
EU 1122-743 Page 4 of 21

NTHALPY
.11A L': I FLh L
EU 1 122 743 Page 7 of 21

Enthalpy Analytical
Job No. 1122-743A PFAS by lsolopa Dilultun (soffslsvilds)
Erlvlmnma tal Chemise Clleat PrajocL 2022-21893
Enthalpy 10 M13-14315-PFAS
Prep Belch
EU14315
Exlraclod Mesa(g)
1
Sample Name MS-14315-PFAS
Prop Date
2022-11-15 14,05
Entract Vol (M)
0.6
Matnx solid
Analysis Dale
i 11172022 7:11.14 AM
Split Faclar
N1A
SampllaO Daly
Aael7al
aybAarhtbraofcer
%Sotlds
100.0%
Received Date
Iaet vrmrM
K Mpippi.
Dry Weight Equal. (0)
1.00
Compound
CAS
Extract
Sample
Fonlraited
LOD
LOG
Aacovery
RaWvery
Flags
Cancontruftn
Concanlratlon
R-.k
nwg
I
n919
Limns
ao7l-
R91P
hglii
Arid.
PFEA
375�22d
ND
NO
<LOD
0.288
0.540
N
PFPeA
2705-SU-3
ND
N
-LOD
D.0424
0.54D
U
PPHxA
301-24-4
NO
ND
<LOD
0,0245
C.540
u
PFHpA
37585-9
No
NO
CLOD
0.0497
M40
u
PFOA
335-67-1
NO
ND
eLOD
OA312
MAD
u
PFNA
375-95-1
NO
N
-LOD
0.0155
Ui40
u
PFOA
335-78-2
ND
ND
'LOD
C.0330
0,540
u
PFUnDA
2058-84-8
NO
ND
-LOD
0.0298
0,540
U
FFOoDA
307.55.1
No
NO
<LOO
0.034E
0,540
u
PFTr0A
7262SA4-8
ND
NO
<WD
OAM
0.540
u
PFTeDA
PFh7S
376-05-7
375-73-5
NO
NO
ND
ND
-LOD
<LOD
0.6500
D.0547
D-540
OA79
U
u
$u3fpnates
PFPcS
2706,91-4
NO
NO
<LOD
0.0371
0.508
u
PFHxS
355.4B-4
ND
NO
-LOD
0.0503
DA94
u
PFHpS
375.42-8
N D
NO
<LOD
0.0505
0.515
u
PFOS
1763-23-1
ND
ND
CLOD
0.0300
0.501
u
PFNS
68259-12-1
ND
ND
-LOD
0.0481
0.520
u
PFOS
335-77-3
ND
ND
-LOD
0,0409
0.521
u
4 2 FTS
757124-72-4
NO
ND
rLOD
0.0349
0.500
u
a2F7S
27SIS-97-2
ND
NO
CLOD
0A21Y
(1414
u
5 2 FTS
PFOSA
39108-34-4
754.91-6
NO
NO
NO
NO
<LOD
<LQD
0.0405
0.0622
0.518
D.540
u
u
Other
N Ma$'OSAA
2345.M4
NO
ND
<1.00
M297
D.540
u
N.EIFQSAA
2991-50-6
49.01
0.0294
<LOO
0.0603
11_540
u
HFPQ-QA
13252.13.6
NO
No
<OD
0,0534
0.540
u
PFMOPrA
377-73-1
ND
ND
<LOD
0.0900
0.540
L!
ADONA
$19005-14-4
NO
ND
<LOD
0.160
0.511
It
9Ci-PF30NS
756426-58-1
NO
NO
CLOD
0.160
0.504
u
11CWF30ud5
763051-92-9
NO
ND
<LOD
0.180
0,509
u
3 3 FICA
356-02.5
NO
ND
<11_00
6.60
6.60
u
5.3 FTrA
91463749-3
ND
NO
-LOD
0.7a0
0.78D
u
7.3 FTCA
812-70.4
NO
NO
-LOD
0.940
0.940
U
N-CIFOSA
4151-50-2
NO
NO
<L00
0.0900
0.540
t1
N-EIFOSE
1691-ES-2
No
NO
<LOO
2,70
2.70
11
NFDHA
151772-58-6
ND
NO
<LOO
B.D900
0.540
u
N-McFOSA
31506-32-8
No
NO
-LOD
0.09D0
0.540
u
N-MCFOSE
24445-037
ND
ND
<LOD
2.70
2.7D
V
PFOc5
79780.39-5
NO
ND
<LOD
0.B40
0.840
u
PFEESA
114567-82-7
NO
ND
<LOO
0.0900
0.540
u
PPM09A
MPFSA
663090-89-5
NO
4199.03
NO
7.52
<LOD
0.540
0,540
20-1 SD%
64.0%
u
E5
MSPFPeA
4505.95
2,70
20-159%
90.1%
M3PF6S
4023.28
2.41
20.150%
80.5%
M2.42 FTS
4618.73
2,77
2V 50%
92.4%
MSPFHxA
4198.14
2.64
20-150%
B7.9%
M3HFPO-DA
3486.71
2.09
20-1 WrA
69.7%
M4PFHpA
4467.71
2.66
20-150%
69,4%
M3PPHxS
3639.37
2.18
211-150:G
72.8%
M2-62 FTS
4398.81
2.64
20-1501h
68.0%
MIIPFOA
4444.6a
2.87
20-150%
WEI%
M9PFNA
4791.56
2.B8
20-150%
95.8%
MBPFOS
4672.05
2,74
20-150%
91,4%
M2.82 F7S
4603.8J
2,06
20.lw%
96A%
M8FOSA4
4671,94
2,80
20-1 fpo%
93a%
FA6PFDA
4266,10
2,56
20.150%
85A%
d3-N-McFOSAA
3881.84
2.33
20-160%
77-6%
dS-N-EIF05AA
4088.25
2.45
20-150h
81.8%
WPFUdA
4334.49
2.60
20-150%
06.7%
MPFDoA
3746.05
2.25
20-160;i
74,9%
M2PFTCDA
3653.56
2.13
20-15044
71,1%
d3-NAWOSA
2447.31
1.47
10-200%
24,5%
dS-N-EIFOSA
2330A4
1.40
10-200%
23.3%
d7-N-McFQSE
7895.59
4.74
10-200
78.0%
dg-N-FIFOSE
7283.32
4.37
1(1.200%
EU 1122-743 Page 8 of 21

Enthalpy Analytical
Job No.: 1122-743-1 PFAS by Isotope Dilution (sakslsolids)
Environmental Chemist Client Project: 2022-21693
Enthalpy ID OPR-14315-PFAS
Prep Batch
EU14315
Extracted Mass (g)
1
Sample Name OPR-14315-PFAS
Prep Date
2022-11-15 14:05
Extract Val (inL)
0.6
Matrix solid
Analysis Date
1111712022 7:33:53 AM
Split Factor
NIA
Sampling Date
Analyst
eybakerltbroaker
%Solids
100.D%
Received Date
Instrument
is lPlppin
Dry Welght Equiv. (g)
1-00
Compound
CAS
Ex ract
Concenttetion
ng/L
Sample
Concentration'
ng/g
Formatted
Result
nglg
LOD
nglg
Loci
mg/9
Recovery
Limits
Recovery
Flags
Acids
PFSA
37S 22-4
10443.111
6,27
627
0.288
0.546
71-135%
83.5%
PFPsA
2705-90-3
987""
5.92
5.92
0.0424
0.540
69-132%
79-0%
PFHxA
307-244-4
11S69.07
6.94
6.94
0-0245
0.540
70-132%
926°%
PFHpA
375-B5.9
11634-73
6.38
8,38
0.0497
0.540
71-131%
85.1 %
PFOA
335-67-1
10416.94
6.25
6.25
0.0312
0-540
69-133%
8313%
PFNA
376-95-1
10453.81
6.27
6.27
0.0156
0.540
72-129%
83.6%
PFDA
335-76-2
11327,14
6-80
6.80
0.0330
0.540
69-133%
90.6%
PFUnDA
2058-94-8
11038.41
6.82
6-62
0.0296
0-540
64-136%
89.3%
PFDoDA
307-55.1
10117,0
6.07
6,07
0.0349
0.54o
69-135%
80.9%
PFTrOA
72629-94-8
11691.28
7.D1
7.01
0,105
0.540
66-i39%
53.5%
PFTeDA
376-06-7
12457.17
7.47
7.47
0-0500
0.540
69-1331A
99.7%
SuAonales
PFBS
375-73-5
10154.9
6.09
6.09
0.0547
0.479
72-128%
91.6%
PFPeS
2706-91-4
11670.6
7.00
7.OD
0.0371
0.508
73-123%
992%
PFHXS
355-46-4
7778.65
4.67
4.67
0.0603
OA94
67-130%
68.1 %
PFHpS
375.92-B
9112.57
5-47
5.47
0.0585
OZ15
70-132%
76-5%
PFOS
1763-23-1
9425.51
5.66
5.66
0.0300
0.501
66-136%
81.3%
PFNS
68259-12-1
9491.34
5-69
5.69
0.0481
0.520
69-125%
78.9%
PFDS
335-77-3
10124.7
6.07
6.07
0.0409
0,521
59-134%
83,9%
4:2 FTS
757124-724
9219.31
5.53
5.53
0.0349
0.506
62-145 %
78.7%
6:2 FTS
27619.97--2
9071,71
5.44
5-44
0.0212
0,514
64-140 %
76.31%
8:2 FTS
39108-34-4
15107.11
9.06
9.06
0-0405
0.518
65-137%
125.91%
Other PFOSA
754-91.6
10340.2
6.20
620
0-0622
0.540
67-137%
82.7°%
N-McFOSAA
2355-31-9
10521.9
6.31
6.31
0,0297
0.540
63-144 %
84.2°%
N-EIFOSAA
299159-6
10521.
6,31
6.31
0,06D3
0.540
61-139%
84,2°A
HFPO-DA
13252-13-5
12055,16
7.23
7.23
0.0534
0.540
70-1su%
96.4°Aa
ES MPFHA
4336.62
2-60
20-150%
86,7%
M6PFPeA
4187.87
251
20-150%
83-8'%
M3PF9S
3631.47
2.18
20-150%
72.6°%
M2-41 FTS
4897.9
244
20-150%
98.0 %
MSPFHxA
3923.61
2.35
20-150%
78.5°%
M3HFPO-DA
3101.01
1.91
20-150%
63.6%
M4PFl !pA
4431.2
2-66
20 150%
88.8%
M3PFHxS
4515.95
2-71
20-150%
90.3°%
M2.6:2FTS
4416.91
2.65
20-150%
88,3%
MBPFOA
4474.40
7-68
20-150%
89.5%
M9PFNA
4849.8
2.91
20-150%
97,0°%
MSPFOS
4955.40
2-97
20-150%
99.1%
M2-8:2 FTS
4881.o1
293
20-150°%
97.61A
MSFOSA 1
4740.7
264
20-150%
94.a-%
M6PFDA
4564.26
2.74
20-150°%
91.3%
d3-N-MaPOSAA
4119.34
2A7
20-153%
82.4%
d5-N-EtFOSAA
4314.33
2.59
20-150%
86.3%
M7PFUdA
4378.91
2.63
20-1501A
87-6%
MPFDoA
4895.37
294
20-150%
97.91%
M2PFTeDA
4274.03
2.56
20-150%
65.5%
EU 1122-743 Page 9 of 21

Loma
ENTHALPY
A N,A Lt 11t, AI
EU 1122-743 Page 10 of 21

Enthalpy Analytical Narrative Summary
Company Environmental Chemist
.lob No. 1122-743-1 PFAS by Isotope Dilution (soils/solids)
Client ID. 2022-21693
6. Reporting Notes, continued
Enthalpy Analytical, LLC in Wilmington NC is accredited by the Louisiana Department of
Environmental Quality to the 2009 TNI Standard under certificate number 05075.
EU 1122-743 Page 13 of 21

NI General Reporting Notes -- Data Qualifiers
`' 1 T IH A U Y
The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC -
Wilmington, NC data reports, unless specifically noted otherwise.
General Data Qualifiers
a B — The analyte was found in the method blank, at a concentration that was at least 10% of the
amount in the sample.
Cxx — Two or more congeners co -elute. In EDDs, C denotes the lowest IUPAC congener in a co -
elution group and additional co-eluters for the group (`xx') are shown with the number of the
lowest 1TJPAC co-eluter.
® E -- The reported concentration exceeds the calibration range (upper point of the calibration
curve). For HRMS data, this condition does not imply additional measurement uncertainty. For
LC-MS/MS data, these values should be considered as having measurement uncertainty higher
than values within the calibration range.
® EDL — Estimated Detection Level: The EDL is unique to isotope dilution methods and reflects
the conditions of analysis at the time of analysis, including the equipment used. Where the MDL
is a static value, the EDL is a dynamic value.
® EMPC — Estimated Maximum Possible Concentration: EMPC is specific to Dioxin/Furan tests to
indicate the determined ion -abundance ratio was outside the allowed theoretical range (usually
due to being near the detection limit, although it can very rarely be caused by a co -eluting
interference). The EMPC concentration is adjusted to reflect the value at the theoretical ion -
abundance ratio.
IR — The ion ratio between the primary and secondary ions was observed to be outside the
method criteria. The analyte concentration may be inaccurate due to interference.
w J — The analyte has a concentration below the minimum calibration level (LOQ value) but greater
than the LOD. These values should be considered as having measurement uncertainty higher than
values within the calibration range
® L - Indicates that an analyte has a concentration below the Minimum Detection Limit (MDL).
The reported concentration is not recommended for regulatory use as the analyte signal may have
a signal-to-noise ratio less than the criteria deemed necessary to be considered a detected analyte.
LOD — Limit of Detection: For reports conforming to the DOD ELAP QSM, this is the QSM-
defined LOD. For reports conforming to TNI requirements (but not DOD FLAP QSM
requirements), this value is the minimum detection limit (MDL). The LOD is adjusted for sample
weight or volume.
® LOQ — Limit of Quantitation; For reports conforming to the DOD ELAP QSM, this is the QSM-
defined LOQ. For reports conforming to TNI requirements (but not DOD ELAP QSM
requirements), this value is the reporting limit (RL). The LOQ is adjusted for sample weight or
volume.
EU 116—v6 (General Reporting Notes -Data Qualifiers) Enthalpy Analytical, LLC — Wilmington, NC
EU 1122-743 Page 14 of 21

Enthalpy Analytical Narrative Summary
Company Environmental Chemist
Job No. 1122-743-1 PFAS by Isotope Dilution (soils/solids)
Client ID. 2022-21693
1. Custody
Megan Holden received the sample on November 14, 2022 at 14.8 °C after being relinquished
by Environmental Chemist. The sample was received in good condition.
Prior to, during, and after analysis, the sample was kept under lock with access only to
authorized personnel by EnthafpyAnalytical, LLC.
Table 'I - Sample Inventory
EU Lab Sam le ID Client Sample ID Matrix
1122-743-001-2 22-53173 Solid/Stud e
Table 2 - Sample Inventory — not reported
EU Lab Sample ID Client Sample ID
1122-743-001-1 53173
2. Methods and Analytes
A list of analytes of interest and corresponding methods of analysis is shown in Table 3.
Abbreviations are defined in the listed Appendices.
Table 3 - Methods and Anaiytes
EU Method Anal tes Cleanup Method
.,._.__..,. ) t EN
- PFAS Draft M1633 (40LisVI-Caro
..,,..,...__ .............__...
3. Analysis
The sample was analyzed using Waters Acquity UPLC equipped with Xevo TQ MS (LCIMS/MS
"Kill" and "Pippin").
For solid chemical material (SCM) samples, a 1-2g nominal aliquot was weighed and spiked with
Extraction Standard (ES). The sample was then sonicated and centrifuged.
Cleanup procedures were performed on the supernatant and then extracted via SPE. Each final
sample extract was transferred to an autosampler vial and spiked with 150 pL of Injection
Standard (IS), prior to analysis_
The sample was analyzed on more than one instrument sequence in order to include all of the
analytes of interest and to meet method acceptance criteria.
Enthalpy's SOP method differed from EPA 1633 as follows:
1. The reagents used to prepare elute solutions for SPE, standards and sample diluent were
ammonium acetate in water and methanol instead of ammonium hydroxide in methanol, water
and acidic acid. Acetic acid was not used.
EU 1122-743 Page 11 of 21

Enthalpy Analytical Narrative Summary
Company Environmental Chemist
Job No. 1122-743-1 PFAS by Isotope Dilution (soils/solids)
Client ID. 2022-21693
3. Analysis, continued
2. The OPR may be spiked at the upper end of the calibration range as well as the low and mid-
range concentrations as indicated in the method.
3. Class wool is not used during extraction as indicated in the method.
4. The bile salt interference check is not performed as indicated in the method.
4. Calibration
In the initial calibration, the reported analytes exhibited R^2 of 2 0.99. Except where noted
below, the reported analyses in the calibration standards, continuing calibration (concal) and
Initial Calibration Verification (ICV) met the 30% accuracy criterion for native anayytes.
8:2 FTS fell above method control limits in the concals. This analyte was not detected in the
sample; therefore, the data is reportable without adverse impact.
5. QC Notes
The QC sample analyses passed all method criteria.
The samples were extracted within the 28-day from collection holding time and analyzed within
the 28-day from extraction to analysis holding time required by the method.
Samples received above 6 °C, client notified in order acknowledgement documentation.
6. Reporting dotes
The results presented in this report are representative of the samples as provided to the
laboratory.
Solid results are reported on a dry weight basis. To achieve nominal 1-2g sample aliquot, a
percent solid analysis was performed to determine dry weight. "As Is" results are available upon
3
request.
Manual integrations were performed on anayytes in the ICAL, controls, and samples to correct
baseline -to -baseline integration as well as integrate all isomers for compounds that have both
linear and branched isomers.
Enthalpy Analytical, LLC in Wilmington NC not accredited to perform EPA Draft Method 1633.
However, Enthalpy is accredited by the ANAB to the DoD QSM 5.4 for SOP method EU047 and
by the LDEQ to the TNI 2016 Standard for SOP method EU047.
Differences between SOP EU047 (the method used) and US EPA Draft 1633 are not expected
to impact the quality of the data nor compariability.
These analyses met the requirements of the TNI Standard. Any deviations from the
requirements of the reference method or TNI Standard have been stated above.
EU 1122-743 Page 12 of 21

General Reporting Notes — Data Qualifiers
ENT1-IALPY
• CLOD() — Analyte was not found at a concentration high enough to be reported as detected. It is
reported as Iess than the LOD, and the LOD is given in the parentheses.
• <LOQQ — Analyte was not found at a concentration high enough to be reported as above the
QSM-defined LOQ or TNI defined Reporting Limit. It is reported as less than the LOQ, and the
LOQ is given in the parentheses.
• ND — Indicates a non -detect.
• NR — Indicates a value that is not reportable due to issues observed in sample preparation or
analysis.
• PR — The associated congener(s) is(are) poorly resolved.
* QI — Indicates the presence of a quantitative interference.
• RL — Reporting Limit. Lowest reportable value. The level is higher than the MDL.
• SI — Denotes "Single .Ion Mode" and is utilized for PCBs where the secondary ion trace has a
significantly elevated noise level due to background PFK. Responses for such peaks are
calculated using an EMPC approach based solely on the primary ion area(s) and may be
considered estimates.
• U — The analyte was not detected.
• V / Q — The labeled standard recovery is not within method control limits.
• X — Indicates the result is from re-injection/repeat/second-column analysis.
Lab Identifiers/ Data Attributes
• AR — Indicates use of the archived portion of the sample extract.
• CU — Indicates a sample that required additional clean-up prior to E RMS injection/processing.
• D — Dilution Data. Result was obtained from the analysis of a dilution. The number that follows
the "D" indicates the dilution factor.
• DE — Indicates a dilution performed with the addition of ES (Extraction Standard) solution.
• DUP — Designation for a duplicate sample.
• MS —Designation for a matrix spike.
• MSD — Designation for a matrix spike duplicate.
• R — Indicates a re -extraction of the sample_
• RI — Indicates a reinjection of the sample extract.
EUI I6_v6 (General Reporting Notes -Data Qualifiers) Enthalpy Analytical, LLC — Wilmington, NC
EU 1122-743 Page 15 of 21

r
General Reporting Notes -- Data Qualifiers
ENTHALPY
a S — Indicates a sample split. The number that follows the "S" indicates the split factor.
® SAT — Indicates an analyte saturated the detector.
EU1 t 6—v6 (General Reporting Notes -Data Qualifiers) Enthalpy Analytical, LLC — Wilmington, NC
EU 1122-743 Page 16 of 21

PFAS Compound Acronym list
Acronym
CAS #
Compound Name
. :....: i.: r,. ,i>1
, i z,
* Analyte is not accredited
PFBA
375-22-4
Perfluorobutanoic Acid
PFPeA
2706-90-3
PerfluoropentanoicAcid
PFHxA
PrwlA
307-24-4
27c..cc...0
Perfluorohexanoic Acid
h....Fl....... L......r.......:- A-'J
PFOA
335-67-1
PerfluorooctanoicAcid^
PFNA
375-95-1
Perfluorononanoic Acid
PFDA
335-76-2
Perfluorodecanoic acid
PFUnA (PFUnDA)
2058-94-8
Perfluaroundecanoic acid
PFDoA (PFDoDA)
307-55-1
Perfluorododecanoic acid
PFTrDA (PFTriA)
72629-94-8
Perfluorotridecanoic acid
PFTeDA (PFTA)
376-06-7
Perfluorotetradecanoic acid
PFBS
375-73-5
Perfluorobutene sulfonic acid
PFPeS
2706-91-4
Perfluoropentane sulfonic acid
PFHxS
355-46-4
Perfluorohexane sulfonic acid
PFHpS
375-92-8
Perfluoroheptane sulfonic acid
PFOS
1763-23-1
Perfluoroactane sulfonic acid
PFNS
68259-12-1
Perfluorononane sulfonic acid
PFDS
335-77-3
Perfluorodecane sulfonic acid
4:2 FTS
757124-72-4
4:2 fluorotelomer sulfonic acid
6:2 FTS
27619-97-2
1754-91-6
6:2 fluorotelomer sulfonic acid
8:2 FTS
39108-34-4
8:2 fluorotelomer sulfonic acid
PFOSA (FOSA)
Perfluorooctane sulfonamide
N-McFOSAA
2355-31-9
N-methyl perfluorooctane sulfonamide acetic acid
N-EtFOSAA
2991-50-6
N-ethyl perfluorooctane sulfonamido acetic acid
HFPO-DA
13252-13-6
2,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropro poxy)-propan oic acid (Gen-X)
11CI-PF30Ud5
763051-92-9
11-chloroeicosafluoro-3-oxaundecane-l-sulfonic acid
90-PF30NS
756426-58-1
9-chlorohexadecafiuoro-3-oxanon ane-l-sulfonic acid
ADONA
919005-14-4
4,8-dioxa-31-i-perfluorononanofc acid
PFEESA
113507-82-7
Perfluoro(2-ethoxyethane)sulphonic acid
PFMOBA(PFMBA)
863090-89-5
Perfluoro-4-methoxybutanicacid
NFDHA
151772-58-6
Nonafluoro-3,6-dioxaheptanoic acid
PFMOPrA (PFMPA)
377-73-1
Perfluoro-3-methoxypropanoic acid
PFMOAA
674-13-5
Perfluora-2-methoxyaceticacid
PF02HxA
39492-88-1
Perfluoro (3,5-dicxahexanoic) acid
PF030A
39492-89-2
Perfluoro (3,5,7-trioxaoctanoic) acid
* PF04DA
39492-90-5
Perfluoro (3,5,7,9-tetraoxadecanoic) acid
* PFOSOA
39492-91-6
Perfluoro(3,5,7,9,11-pentaoxadodecanoic) acid
* Nafion Byproduct 1
29311-67-9
Won Byproduct 1
* Naffon Byproduct 2
749836-20-2
Nafion Byproduct 2
* PEPA
267239-61-2
Perfluoro-2-ethoxypropanoicacid
* PMPA
13140-29-9
Perfluoro-2-methoxypropanoic acid
* 10:2 FTS
120226-60-0
Fluorotelamersulfonate 10:2
* N-EtFOSA
4151-50-2
N-ethylperfluero-l-octanesulfonamide
* N-EtFOSE
1691-99-2
2-(N-methylperfluoro-l-octanesuffonamido)-ethanof
* N-McFOSA
31505-32-8
N-methylperfluoro-l-octanesulfonamide
* N-McFOSE
24448-09-7
2-(N-methylperfluoro-l-octanesulfonamido)-ethanol
* PFECA-G
801212-59-9
4-(Heptafluoroisopropoxy)hexafluorobutanoicacid
* PFHxDA 67905-19-5 Perfluorohexadecanoic acid
R-PSDA (Nafian Byproduct
* 4) 12416366-18-0 Perfluoro-4-(2-sulfoethoxV)pentanoic acid
EU 1122-743 Page 17 of 21

PFAS Compound Acronym List
Acronym CAS # Compound Name
� e.
o Analyte is not accredited
Hydrolyzed PSDA (Nafion
Byproduct 5)
2416366-19-1
2-fluorc-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,7,2-tetrafluoro-2-suifoethoxy)propoxyj-acetic acid
R-PSDCA (Nafion Byproduct
6)
2416366-21-5
1,1,2,2-tetrafluoro-2-[1,2,2,3,3-pentafIuoro-1-(trifluoromethyl) propoxy] ethanesulfonic
acid
EVE Acid
69087-46-3
2,2,3,3-tetrafluoro-3-({1,1,1,2,3,3-hexafluoro-3-[(1,2,2-trifluoroethenyl)oxy] pro pan-2-
y0ox0proplonic acid
FBSA
30334-69-1
Perfluorobutylsulfonamide
Hydro-EVE Acid
773804-62-9
2,2,3,3-Tetrafluoro-3-{[1,1,1, 2,3,3-hexafiuoro-3-(1,2,2,2-tetrafIuoroethoxy) prop an-2-
yl]oxy)propanoic acid
R-EVE Acid
2416366-22-6
4-(2-carhoxy-1,1,2,2-tetrafluoroethoxy)-2,2,3,3,4,5,5,5-octafluoro-pentanoicacid
NVHOS
1132933-86-8
Perfluoroethoxysulfonic acid
PFDoS
79780-39-5
Perfiuorododecane sulfonic acid
PFODA
16517-11-6
Perfluorooctadecanoic acid
3:3 FTCA
356-02-5
2H,2H,3H,3H-Perfluorohexanoic acid
5:3 FTCA
914637-49-3
2H,2H,3H,3H-Perfluorooctanoic acid
7:3 FTCA
812-70-4
2H,2H,3H,3H-Perfluorodecanolc acid
N-AP-FHxSA
50598-28-2
N-(3-fDimethylamino)propyl)tridecafluoro-l-hexanesulfonamide
N-C MArnP-6:2 FOSA
34455-29-3
N-(Ca rboxymethyl)-N,N-dimethy1-3-(((3,3,4,4,5,5,6,6,7,7, 8,8,8-
tridecafluorooctyl)suIfonyl)amino) 1-propanamini um
EU 1122-743 Page 18 of 21

Sample
Custody
EU 1122-743 Page 19 of 21

This Is The Last Page
Of This Report.
EU 1122-743 Page 21 of 21

Environmental Chemist, Inc., Wilmington, NC Late #94
Sample Receipt Checklist
6602 Windmill Way
Wilmington, NC 28405
910.392.0223
Client: G2Ui� Date: Ji�o 22
Report Number. 2022- 2- 9
Receipt of sample: ECHfiVI Pickup Client Delivery ©
UPS ❑ FedEx © her ❑
❑ YES
10 NO
Ik N/A
1. Were custody seals present on the cooler?
❑ YES 10
NO
I NE N/A 12..
If custody seals were present, were they intact/unbroken?
Original temperature upon receipt �,t-f t °C Corrected temperature upon receipt °C
How temperature taken:
❑ Temperature Blank Against Bottles
IR Gun ID: Thomas Traceable S/N 192511657 IR Gun Correction Factor °C: 0.0
YES
❑ NO
3. If temperature of cooler exceeded 6'C, was Project Mgr./QA notified?
❑ NO
4. Were proper custody procedures (relinquished/received) followed?
YES
❑ NO
5. Were sample ID's listed on the COC?
IYES
YES
❑ NO
6. Were samples ID's listed on sample containers?
YES
❑ NO
7. Were collection date and time listed on the COC?
gut YES
❑ NO
8. Were tests to be performed listed on the COC?
YES
❑ NO
9. Did samples arrive in proper containers for each test?
YES
❑ NO
10. Did samples arrive in good condition for each test?
YES
❑ NO
11. Was adequate sample volume available?'
YES
❑ NO
12. Were samples received within proper holding time for requested tests?
YES
❑ NO
13. Were acid preserved samples received at a pH of <2?
❑ YES
❑ NO
14. Were cyanide samples received at a pH >12?
❑ YES
❑ NO
15. Were sulfide samples received at a pH >9?
❑ YES
❑ NO
16, Were NH3/TKN/Phenol received at a chlorine residual of <0,5 m/L? **
❑ YES
❑ NO
27, Were Sulfide/Cyanide received at a chlorine residual of <0.5 m/L?
❑ YES I0
NO
18. Were orthophosphate samples filtered in the field within 15 minutes?
TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet.
** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet.
Sample Preservation:
Samples)
by adding (circle one):
Time of preservation:
(Must be completed for any sample(s) incorrectly preserved or with headspace)
were received incorrectly preserved and were adjusted accordingly
H7SO4 HNO3 HCI NaOH
If more than one preservative is needed, notate in comments below
Mote: Notify customer service immediately for incorrectly preserved samples. Obtain a new sample or
notify the state lab if directed to analyzed by the customer. who was noticed, date and time:
Volatiles Sample(s) _
were received with headspace
COMMENTS:
DOC. QA,002 Rev 1

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Lear Corp 11 /1 /22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 2300 91.54 23 3.98
Calcium 11500 457.7 20 22.885
Magnesium 2540 101.092 12 8.424333
Percent Solids 3.98
SAR 1.01
SAR =
Na+
a (Ca2+ + M;42+ )
c •M
0.5( 22.885 2 + 8.42433 2 )

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Analysis Data
WQ0041666
EMA Resources Inc.
NCO087866
Piedmont Water
Laboratory:
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
(mg/kg)
Conc.
Limit
(mg/kg a
Sample or Composite Date
1/19/22
6/2/22
7/5/22
10/18/22
Percent Solids (%)
NA
24.2
24.4
22.7
22.6
Arsenic
75
0.991
3.61
1.61
9.51
Cadmium
85
25.2
36.5
37.5
33.2
Copper
4,300
87.2
159
133
142
Chromium
NA
2.62
14.1
13.4
7.65
Lead
840
14
17.6
13.3
20.3
Mercury
57
0.0283
0.0246
0.0678
0.0633
Molybdenum
75
12.6
16.8
20.9
16.2
Nickel
420
0.495
6.84
4.07
17.8
Selenium
100
1.32
66.8
14.1
1.42
Zinc
7,500
5.37
18.2
17.7
21.9
Total Phosphorus
NA
860
1000
736
761
TKN
NA
8640
8890
4100
7080
Ammonia -Nitrogen
NA
115
387
564
345
Nitrate and Nitrite
NA
19.8
19.3
75.8
20.4
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Z�fz 2/8/2023
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
WQ0041666
EMA Resources Inc.
NCO087866
Piedmont Water
Laboratory:
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
Sample or • •• Date
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
2/8/2023
Date
DENR FORM RSSF - B (12/2006)

Waypointo
ANALYTICAL
1 /27/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-020-0063
Client Project Description: Randleman, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 1/20/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2022
Arkansas
State Program
88-0650
02/07/2022
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-020-0063
Page 2 of 8

Waypoint
ANALYTICAL
Report Number: 22-020-0063
Client Project Description: Randleman, NC
Lab No Client Sample ID
87503 Piedmont Water
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Matrix Date Collected Date Received
Solids 01/19/2022 13:30 01/20/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Randleman, NC
Lab Report Number: 22-020-0063
Date: 1 /27/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 87528
Analyte: Molybdenum
QC Batch No: 1-596093/1-595742
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 56356
Analyte: Mercury
QC Batch No: 1-595981/1-595746
The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control
acceptance ranges. Matrix interference is suspected.
Page 4 of 8

waypANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number : 22-020-0063
Lab No : 87503
Sample ID : Piedmont Water
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Project Randleman, NC
Information :
REPORT OFANALYSIS
Report Date : 01/27/2022
Received : 01/20/2022
Danyale Love
Project Manager
Matrix: Solids
Sampled: 1/19/2022 13:30
Test
Results
Units
MDL
MQL
DF
Date / Time
Analyzed
By
Analytical
Method
Moisture
75.8
%
0.010
1
01/20/2215:55
FMM
SW-DRYWT
Ammonia Nitrogen
1153
mg/Kg -
dry
66.1
413
1
01/27/22 14:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<19.8
mg/Kg -
dry
19.8
19.8
1
01/27/22 14:06
ZBD
4500NO3F-2011
Organic N
85213
mg/Kg -
dry
311.6
628.1
1
01/25/22 15:24
CALCULATION
pH
4.7
S.U.
1
01/26/2216:05
DRS
9045D
Total Solids
24.2
%
0.010
0.010
1
01/20/22 15:55
FMM
2540G-2011
Total Volatile Solids
27.6
%
0.010
0.010
1
01/20/22 15:55
FMM
2540G-2011
Total Kjeldahl Nitrogen
8640
mg/Kg -
dry
628
1
01/25/22 15:24
CLP
4500NORGD-2011
Phosphorus
860
mg/Kg -
dry
11.4
20.7
1
01/25/22 06:25
JTR
6010D
Aluminum
6400
mg/Kg -
dry
19.1
20.7
1
01/25/22 06:25
JTR
6010D
Arsenic
<0.991
mg/Kg -
dry
0.991
2.07
1
01/25/22 06:25
JTR
6010D
Cadmium
25.2
mg/Kg -
dry
0.0826
0.413
1
01/25/22 06:25
JTR
6010D
Calcium
996
mg/Kg -
dry
160
207
1
01/25/22 06:25
JTR
6010D
Chromium
2.62
mg/Kg -
dry
0.975
1.03
1
01/25/22 06:25
JTR
6010D
Copper
87.2
mg/Kg -
dry
1.28
2.07
1
01/25/22 06:25
JTR
6010D
Iron
430000
mg/Kg -
dry
3520
4130
100
01/25/22 21:17
EAL
6010D
Lead
14.0
mg/Kg -
dry
0.743
1.24
1
01/25/22 06:25
JTR
6010D
Magnesium
318
mg/Kg -
dry
10.7
20.7
1
01/25/22 06:25
JTR
6010D
Manganese
955
mg/Kg -
dry
1.34
2.07
1
01/25/22 06:25
JTR
6010D
Mercury
<0.0283
mg/Kg -
dry
0.0283
0.0649
1
01/24/22 14:23
TJS
7471A
Molybdenum
12.6
mg/Kg -
dry
0.557
1.03
1
01/25/22 06:25
JTR
6010D
Nickel
<0.495
mg/Kg -
dry
0.495
1.03
1
01/25/22 06:25
JTR
6010D
Potassium
147
mg/Kg -
dry
25.5
41.3
1
01/25/22 06:25
JTR
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

WayP�'��'
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400
° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Randleman, NC
Mr. Brent Collins
Report Date : 01/27/2022
755 Yadkinville Rd
Information :
Received : 01/20/2022
Mocksville , NC 27028
Danyale Love
Report Number : 22-020-0063
REPORT OFANALYSIS
Project Manager
Lab No : 87503
Matrix: Solids
Sample ID : Piedmont Water
Sampled: 1/19/2022 13:30
Test
Results
Units
MDL
MQL
DF Date / Time By Analytical
Analyzed Method
Selenium
<1.32
mg/Kg - dry
1.32
2.07
1 01/25/22 06:25 JTR 6010D
Sodium
<53.7
mg/Kg - dry
53.7
103
1 01/25/22 06:25 JTR 6010D
Zinc
5.37
mg/Kg - dry
3.35
5.17
1 01/25/22 06:25 JTR 6010D
Sulfur
9920
mg/Kg - dry
21.4
41.3
1 01/25/22 06:25 JTR 6010D
Sodium Absorption Ratio
<0.01
Ratio
0.01
0.01
1 01/25/22 06:25 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-020-0063
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
1#137
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lKristinaA. McAdams Date & Time: 01/20/2022 12:33:47
Page 7 of 8

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Page 8 of 8

Piedmont Water 1/19/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 53.7 12.9954 23 0.565017
Calcium 996 241.032 20 12.0516
Magnesium 318 76.956 12 6.413
Percent Solids 24.2
SAR 0.19
SAR — Na
2 (Ca2+ + Mg2- )
0.56502
0.5( 12.052 2 + 6.41300 2 )

Waypointo
ANALYTICAL
6/16/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-154-0040
Client Project Description: Randleman, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 6/3/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-154-0040
Page 2 of 9

Waypoint
ANALYTICAL
Report Number: 22-154-0040
Client Project Description: Randleman, NC
Lab No Client Sample ID
89864 Piedmont Water
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Matrix Date Collected Date Received
Solids 06/02/2022 08:30 06/03/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Randleman, NC
Lab Report Number: 22-154-0040
Date: 6/16/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 90192 (WRC Topsoil (June))
Analyte: Aluminum
QC Batch No: 1-620235/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90192 (WRC Topsoil (June))
Analyte: Aluminum
QC Batch No: 1-620618/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90192 (WRC Topsoil (June))
Analyte: Calcium
QC Batch No: 1-620618/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90192 (WRC Topsoil (June))
Analyte: Iron
QC Batch No: 1-620618/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90192 (WRC Topsoil (June))
Analyte: Potassium
QC Batch No: 1-620618/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 90192 (WRC Topsoil (June))
Analyte: Magnesium
QC Batch No: 1-620235/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90192 (WRC Topsoil (June))
Analyte: Manganese
QC Batch No: 1-620235/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90192 (WRC Topsoil (June))
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Analyte: Phosphorus
QC Batch No: 1-620235/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90192 (WRC Topsoil (June))
Analyte: Lead
QC Batch No: 1-620235/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90192 (WRC Topsoil (June))
Analyte: Sulfur
QC Batch No: 1-620235/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 89864 (Piedmont Water)
Analyte: Selenium
QC Batch No: 1-620235/1-619916
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 90192 (WRC Topsoil (June))
Analyte: Selenium
QC Batch No: 1-620235/1-619916
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

waypANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Project Randleman, NC
Information :
Report Date : 06/16/2022
nReceived : 06/03/2022
C-�*�-� =
Connie Cook
Report Number : 22-154-0040
REPORT OFANALYSIS
Project
Manager
Lab No : 89864
Matrix:
Solids
Sample ID : Piedmont Water
Sampled:
6/2/2022
8:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
75.6
%
0.010
0.010
1
06/03/22 16:27
FMM
SW-DRYWT
Ammonia Nitrogen
3873
mg/Kg -
dry
65.6
410
1
06/16/22 14:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<19.3
mg/Kg -
dry
19.3
19.3
1
06/07/22 14:58
ZBD
4500NO3F-2016
Organic N
85083
mg/Kg -
dry
541.0
1094
1
06/13/22 10:13
CALCULATION
pH
4.9
S.U.
1
06/10/2216:00
DRS
9045D
Total Solids
24.4
%
0.010
0.010
1
06/03/22 16:27
FMM
2540G-2011
Total Volatile Solids
30.0
%
0.010
0.010
1
06/03/22 16:27
FMM
2540G-2011
Total Kjeldahl Nitrogen
8890
mg/Kg -
dry
1090
1
06/13/22 10:13
CLP 4500NORGD-2011
Phosphorus
1000
mg/Kg -
dry
11.3
20.5
1
06/07/22 19:39
EAL
6010D
Aluminum
8240
mg/Kg -
dry
18.9
20.5
1
06/07/22 19:39
EAL
6010D
Arsenic
3.61
mg/Kg -
dry
0.983
2.05
1
06/07/22 19:39
EAL
6010D
Cadmium
36.5
mg/Kg -
dry
0.0819
0.410
1
06/07/22 19:39
EAL
6010D
Calcium
1520
mg/Kg -
dry
159
205
1
06/07/22 19:39
TJS
6010D
Chromium
14.1
mg/Kg -
dry
0.967
1.02
1
06/07/22 19:39
EAL
6010D
Copper
159
mg/Kg -
dry
1.27
2.05
1
06/07/22 19:39
EAL
6010D
Iron
418000
mg/Kg -
dry
1750
2050
50
06/09/22 03:45
EAL
6010D
Lead
17.6
mg/Kg -
dry
0.737
1.23
1
06/07/22 19:39
EAL
6010D
Magnesium
496
mg/Kg -
dry
10.6
20.5
1
06/07/22 19:39
EAL
6010D
Manganese
832
mg/Kg -
dry
1.33
2.05
1
06/07/22 19:39
EAL
6010D
Mercury
<0.0246
mg/Kg -
dry
0.0246
0.566
1
06/08/22 11:45
ZMT
7471A
Molybdenum
16.8
mg/Kg -
dry
0.553
1.02
1
06/07/22 19:39
EAL
6010D
Nickel
6.84
mg/Kg -
dry
0.491
1.02
1
06/07/22 19:39
EAL
6010D
Potassium
204
mg/Kg -
dry
25.3
41.0
1
06/07/22 19:39
TJS
6010D
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 6 of 9

waypANALYTICAL
46245
EMA Resources Inc
Project
Mr. Brent Collins
755 Yadkinville Rd
Information
Mocksville , NC 27028
Report Number : 22-154-0040
Lab No : 89864
Sample ID : Piedmont Water
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Randleman, NC
REPORT OFANALYSIS
Report Date : 06/16/2022
nReceived : 06/03/2022
C-�*�-� =
Connie Cook
Project Manager
Matrix: Solids
Sampled: 6/2/2022 8:30
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Selenium
Sodium
Zinc
Sulfur
Sodium Absorption Ratio
Qualifiers/ DF Dilution Factor
Definitions
66.83
mg/Kg -
dry
65.6
102
50
06/09/22 03:45
EAL
6010D
220
mg/Kg -
dry
53.3
102
1
06/07/22 19:39
EAL
6010D
18.2
mg/Kg -
dry
3.32
5.12
1
06/07/22 19:39
EAL
6010D
6390
mg/Kg -
dry
21.2
41.0
1
06/07/22 19:39
EAL
6010D
0.61
Ratio
0.01
0.01
1
06/07/22 19:39
CALCULATION
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-154-0040
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT137
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: Summer Harrison Date & Time: 06/03/2022 10:12:00
Page 8 of 9

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Piedmont Water 6/2/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 220 53.68 23 2.333913
Calcium 1520 370.88 20 18.544
Magnesium 496 121.024 12 10.08533
Percent Solids 24.4
SAR 0.62
SAR — Na
2 (Ca2+ + Mg2- )
2.33391
0.5( 18.544 2 + 10.08533 2 )

Waypointo
ANALYTICAL
7/15/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-187-0032
Client Project Description: Randleman, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 7/6/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-187-0032
Page 2 of 9

Waypoint
ANALYTICAL
Report Number: 22-187-0032
Client Project Description: Randleman, NC
Lab No Client Sample ID
88272 Piedmont Water
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Matrix Date Collected Date Received
Solids 07/05/2022 09:15 07/06/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Randleman, NC
Lab Report Number: 22-187-0032
Date: 7/15/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 88781 (Grant Creek)
Analyte: Aluminum
QC Batch No: 1-626480/1-626043
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88781 (Grant Creek)
Analyte: Calcium
QC Batch No: 1-626480/1-626043
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88781 (Grant Creek)
Analyte: Iron
QC Batch No: 1-626480/1-626043
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88781 (Grant Creek)
Analyte: Potassium
QC Batch No: 1-626955/1-626043
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88781 (Grant Creek)
Analyte: Manganese
QC Batch No: 1-626480/1-626043
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88781 (Grant Creek)
Analyte: Phosphorus
QC Batch No: 1-626480/1-626043
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88781 (Grant Creek)
Analyte: Sulfur
QC Batch No: 1-626480/1-626043
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 88272 (Piedmont Water)
Analyte: Selenium
QC Batch No: 1-626480/1-626043
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 88781 (Grant Creek)
Analyte: Zinc
QC Batch No: 1-626480/1-626043
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 88272 (Piedmont Water)
QC Batch No: 1-626150/1-625869
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Page 5 of 9

waypANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Project Randleman, NC
Information :
Report Date : 07/15/2022
nReceived : 07/06/2022
C-�*�-� =
Connie Cook
Report Number : 22-187-0032
REPORT OFANALYSIS
Project
Manager
Lab No : 88272
Matrix:
Solids
Sample ID : Piedmont Water
Sampled:
7/5/2022
9:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
77.3
%
1
07/08/22 15:43
FMM
SW-DRYWT
Ammonia Nitrogen
564
mg/Kg -
dry
70.5
441
1
07/14/22 13:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
75.8
mg/Kg -
dry
22.0
22.0
1
07/14/22 16:29
ZBD
4500NO3F-2016
Organic N
3537
mg/Kg -
dry
506.6
1022
1
07/07/22 14:14
CALCULATION
pH
6.1
S.U.
1
07/12/2215:07
DRS
9045D
Total Solids
22.7
%
0.010
0.010
1
07/08/22 15:43
FMM
2540G-2011
Total Volatile Solids
28.7
%
0.010
0.010
1
07/08/22 15:43
FMM
2540G-2011
Total Kjeldahl Nitrogen
4100
mg/Kg -
dry
1020
1
07/07/22 14:14
ANH 4500NORGD-2011
Phosphorus
736
mg/Kg -
dry
12.2
22.0
1
07/12/22 21:50
EAL
6010D
Aluminum
7090
mg/Kg -
dry
20.4
22.0
1
07/12/22 21:50
EAL
6010D
Arsenic
1.613
mg/Kg -
dry
1.06
2.20
1
07/12/22 21:50
EAL
6010D
Cadmium
37.5
mg/Kg -
dry
0.0881
0.441
1
07/12/22 21:50
EAL
6010D
Calcium
2750
mg/Kg -
dry
170
220
1
07/12/22 21:50
EAL
6010D
Chromium
13.4
mg/Kg -
dry
1.04
1.10
1
07/12/22 21:50
EAL
6010D
Copper
133
mg/Kg -
dry
1.37
2.20
1
07/12/22 21:50
EAL
6010D
Iron
404000
mg/Kg -
dry
749
881
20
07/14/22 15:08
TJS
6010D
Lead
13.3
mg/Kg -
dry
0.792
1.32
1
07/12/22 21:50
EAL
6010D
Magnesium
546
mg/Kg -
dry
11.4
22.0
1
07/12/22 21:50
EAL
6010D
Manganese
881
mg/Kg -
dry
1.43
2.20
1
07/12/22 21:50
EAL
6010D
Mercury
0.0678 JB
mg/Kg -
dry
0.0294
0.674
1
07/11/22 14:12
ZMT
7471A
Molybdenum
20.9
mg/Kg -
dry
0.594
1.10
1
07/12/22 21:50
EAL
6010D
Nickel
4.07
mg/Kg -
dry
0.528
1.10
1
07/12/22 21:50
EAL
6010D
Potassium
189
mg/Kg -
dry
27.2
44.1
1
07/12/22 21:50
EAL
6010D
Qualifiers/ B Analyte detected in blank
DF
Dilution Factor
Definitions J Estimated value
MQL
Method Quantitation Limit
Page 6 of 9

waypANALYTICAL
46245
EMA Resources Inc
Project
Mr. Brent Collins
755 Yadkinville Rd
Information
Mocksville , NC 27028
Report Number : 22-187-0032
Lab No : 88272
Sample ID : Piedmont Water
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Randleman, NC
REPORT OFANALYSIS
Report Date : 07/15/2022
nReceived : 07/06/2022
C-�*�-� =
Connie Cook
Project Manager
Matrix: Solids
Sampled: 7/5/2022 9:15
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Selenium
Sodium
Zinc
Sulfur
Sodium Absorption Ratio
<14.1
mg/Kg -
dry
14.1
22.0
10
07/14/22 15:13
TJS
6010D
266
mg/Kg -
dry
57.3
110
1
07/12/22 21:50
EAL
6010D
17.7
mg/Kg -
dry
3.57
5.51
1
07/12/22 21:50
EAL
6010D
4110
mg/Kg -
dry
22.8
44.1
1
07/12/22 21:50
EAL
6010D
0.57
Ratio
0.01
0.01
1
07/12/22 21:50
CALCULATION
Qualifiers/ B Analyte detected in blank
Definitions
DF Dilution Factor
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-187-0032
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 07/06/2022 09:42:08
Page 8 of 9

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Piedmont Water 7/5/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 266 60.382 23 2.625304
Calcium 2750 624.25 20 31.2125
Magnesium 546 123.942 12 10.3285
Percent Solids 22.7
SAR 0.58
SAR — Na
2 (Ca2+ + Mg2- )
2.62530
0.5( 31.213 2 + 10.32850 2 )

Waypointo
ANALYTICAL
10/27/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-292-0018
Client Project Description: Piedmont Water
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 10/19/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-292-0018
Page 2 of 9

Waypoint
ANALYTICAL
Report Number: 22-292-0018
Client Project Description: Piedmont Water
Lab No Client Sample ID
98721 Piedmont Water
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Matrix Date Collected Date Received
Solids 10/18/2022 11:35 10/19/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Piedmont Water
Lab Report Number: 22-292-0018
Date: 10/26/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 98992 (DG-1)
Analyte: Aluminum
QC Batch No: L645267/L644464
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 98992 (DG-1)
Analyte: Arsenic
QC Batch No: L644946/L644464
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 98992 (DG-1)
Analyte: Calcium
QC Batch No: L644946/L644464
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance
ranges. Matrix interference is suspected.
Sample 98992 (DG-1)
Analyte: Calcium
QC Batch No: L644946/L644464
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance
ranges. Matrix interference is suspected.
Sample 98992 (DG-1)
Analyte: Iron
QC Batch No: L645267/L644464
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 98992 (DG-1)
Analyte: Potassium
QC Batch No: L645267/L644464
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 98992 (DG-1)
Analyte: Manganese
QC Batch No: L645267/L644464
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 98992 (DG-1)
Analyte: Lead
QC Batch No: L644946/L644464
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 5 of 9

waypANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Project Piedmont Water
Information :
Report Date : 10/27/2022
nReceived : 10/19/2022
C-�*�-� =
Connie Cook
Report Number : 22-292-0018
REPORT OFANALYSIS
Project
Manager
Lab No : 98721
Matrix:
Solids
Sample ID : Piedmont Water
Sampled:
10/18/2022
11:35
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
77.4
%
1
10/21/2215:42
FMM
SW-DRYWT
Ammonia Nitrogen
3453
mg/Kg -
dry
70.8
442
1
10/26/22 15:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<20.4
mg/Kg -
dry
20.4
20.4
1
10/25/22 14:30
ZBD
4500NO3F-2016
Organic N
67353
mg/Kg -
dry
557.5
1128
1
10/24/22 16:00
DH
CALCULATION
pH
5.5
S.U.
1
10/26/2216:25
DRS
9045D
Total Solids
22.6
%
0.010
0.010
1
10/21/22 15:42
FMM
2540G-2011
Total Volatile Solids
28.6
%
0.010
0.010
1
10/21/22 15:42
FMM
2540G-2011
Total Kjeldahl Nitrogen
7080
mg/Kg -
dry
1130
1
10/24/22 16:00
ANH 4500NORGD-2011
Phosphorus
761
mg/Kg -
dry
12.2
22.1
1
10/24/22 20:41
TJS
6010D
Aluminum
6280
mg/Kg -
dry
20.4
22.1
1
10/24/22 20:41
TJS
6010D
Arsenic
9.51
mg/Kg -
dry
1.06
2.21
1
10/24/22 20:41
TJS
6010D
Cadmium
33.2
mg/Kg -
dry
0.0884
0.442
1
10/24/22 20:41
TJS
6010D
Calcium
1750
mg/Kg -
dry
171
221
1
10/24/22 20:41
TJS
6010D
Chromium
7.65
mg/Kg -
dry
1.04
1.11
1
10/24/22 20:41
TJS
6010D
Copper
142
mg/Kg -
dry
1.37
2.21
1
10/24/22 20:41
TJS
6010D
Iron
427000
mg/Kg -
dry
752
885
20
10/25/22 18:00
EAL
6010D
Lead
20.3
mg/Kg -
dry
0.796
1.33
1
10/24/22 20:41
TJS
6010D
Magnesium
387
mg/Kg -
dry
11.4
22.1
1
10/24/22 20:41
TJS
6010D
Manganese
7920
mg/Kg -
dry
14.4
22.1
10
10/25/22 17:55
EAL
6010D
Mercury
0.06333
mg/Kg -
dry
0.0268
0.615
1
10/20/22 15:02
TJS
7471A
Molybdenum
16.2
mg/Kg -
dry
0.597
1.11
1
10/24/22 20:41
TJS
6010D
Nickel
17.8
mg/Kg -
dry
0.530
1.11
1
10/24/22 20:41
TJS
6010D
Potassium
173
mg/Kg -
dry
27.3
44.2
1
10/24/22 20:41
TJS
6010D
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 6 of 9

WayP�'��'
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Piedmont Water
Mr. Brent Collins
Report Date : 10/27/2022
755 Yadkinville Rd
Information :
Received : 10/19/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-292-0018
REPORT OFANALYSIS
Project Manager
Lab No : 98721
Matrix: Solids
Sample ID : Piedmont Water
Sampled: 10/18/2022 11:35
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<1.42
mg/Kg - dry
1.42
2.21 1 10/24/22 20:41 TJS 6010D
Sodium
827
mg/Kg - dry
57.5
111 1 10/24/22 20:41 TJS 6010D
Zinc
21.9
mg/Kg - dry
3.58
5.53 1 10/24/22 20:41 TJS 6010D
Sulfur
7790
mg/Kg - dry
22.9
44.2 1 10/24/22 20:41 TJS 6010D
Sodium Absorption Ratio
2.21
Ratio
0.01
0.01 1 10/24/22 20:41 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-292-0018
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: lEmily M. Peterson Date & Time: 10/19/2022 09:14:14
Page 8 of 9

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Page 9 of 9

Piedmont Water 10/18/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 827 186.902 23 8.126174
Calcium 1750 395.5 20 19.775
Magnesium 387 87.462 12 7.2885
Percent Solids 22.6
SAR 2.21
SAR — Na
2 (Ca2+ + Mg2- )
8.12617
0.5( 19.775 2 + 7.28850 2 )

ace Analytical ' ANALYTICAL REPORT
February 04, 2022
EMA Resources
Sample Delivery Group: L1453296
Samples Received: 01/20/2022
Project Number:
Description: Sludge
Report To: Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By: , �-
Justin Carr
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
N
� T
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 1 of 22

TABLE OF CONTENTS
Cp: Cover Page
u
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
Fss]
PIEDMONT WATER L1453296-01
5
Fn
PIEDMONT WATER L1453296-02
6
Qc: Quality Control Summary
8
Fr
Wet Chemistry by Method 9012 B
8
Wet Chemistry by Method 9034-9030B
9
Rc
Wet Chemistry by Method 9045D
10
F
Wet Chemistry by Method D93/1010A
11
Mercury by Method 7470A
12
[Al
Metals (ICP) by Method 6010D
13
Volatile Organic Compounds (GC/MS) by Method 8260D
14
RC
Chlorinated Acid Herbicides (GC) by Method 8151A
16
Pesticides (GC) by Method 8081B
17
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
18
GI: Glossary of Terms
20
Al: Accreditations & Locations
21
Sc: Sample Chain of Custody
22
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:
EMA Resources L1453296
02/04/22 11:16
2 of 22

SAMPLE SUMMARY
Collected by Collected date/time Received date/time
PIEDMONT WATER L1453296-01 Solid Roy Whittaker 01/19/2213:30 01/20/2209:00 , C
P
Method
Wet Chemistry by Method 9012 B
Wet Chemistry by Method 9034-9030B
Wet Chemistry by Method 9045D
Wet Chemistry by Method D93/1010A
PIEDMONT WATER L1453296-02 Waste
Method
Preparation by Method 1311
Preparation by Method 1311
Mercury by Method 7470A
Metals (ICP) by Method 6010D
Volatile Organic Compounds (GC/MS) by Method 8260D
Chlorinated Acid Herbicides (GC) by Method 8151A
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Batch
Dilution Preparation
Analysis
Analyst
Location
�J
_
date/time
date/time
FWG1808071
1 01/27/221147
01/27/2218:32
CAT
Mt. Juliet, TN
WG1806992
1 01/24/2216:00
01/25/22 2100
SAC
Mt. Juliet, TN
WG1806056
1 01/21/2214:14
01/22/22 07:18
GI
Mt. Juliet, TN
WG1806787
1 01/24/22 02:00
01/24/22 02:00
WOS
Mt. Juliet, TN
Fn
Collected by
Collected date/time
Received date/time
Roy Whittaker
01/19/2213:30
01/20/22 09:00
5
Sr
Batch
Dilution Preparation
Analysis
Analyst
Location
LJ
date/time
date/time
aOC
WG1807134
1 01/25/22 06:41
01/25/22 06:41
JWS
Mt. Juliet, TN
WG1809852
1 01/31/2212:03
01/31/2212:03
CJW
Mt. Juliet, TN
WG1808205
1 01/26/2210:06
01/27/2210:22
ABL
Mt. Juliet, TN
GI
WG1808315
1 02/01/2216:33
02/02/2213:43
KMG
Mt. Juliet, TN
WG1811489
1 02/02/22 00:52
02/02/22 00:52
ADM
Mt. Juliet, TN
SAI
WG1806269
1 01/28/22 09:17
01/31/22 08:32
JMB
Mt. Juliet, TN
WG1809205
1 02/03/22 06:33
02/03/2213:53
AO
Mt. Juliet, TN
WG1809535
1 01/30/2216:30
01/31/22 02:37
JNJ
Mt. Juliet, TN
RC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 3 of 22

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the FP
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data. 0
Fr
Rc
GI
Justin Carr [Al
Project Manager
RC
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-903013.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 4 of 22

SAMPLE RESULTS - 01
L1453296
PIEDMONT WATER
Collected date/time: 01/19/22 13:30
Wet Chemistry by Method 9012 B
Result Qualifier
RDL
Analyte mg/kg
mg/kg
Reactive Cyanide 0.463
0.250
Wet Chemistry by Method 9034-9030B
Result Qualifier
RDL
Analyte mg/kg
mg/kg
Reactive Sulfide 62.0
25.0
Wet Chemistry by Method 9045D
Dilution Analysis Batch
date / time
1 01/27/202218:32 WG1808071
Dilution Analysis Batch
date / time
1 01/25/2022 2100 WG1806992
Result Qualifier
Dilution Analysis
Batch
Analyte su
date / time
Corrosivity by pH 6.20 T8
1 01/22/2022 07:18
WG180605E
Sample Narrative:
L1453296-01 WG1806056: 6.2 at17.5C
Wet Chemistry by Method D93/1010A
Result Qualifier
Dilution Analysis
Batch
Analyte Deg. F
date / time
Ignitability DNI at170
1 01/24/2022 02:00
WG1806787
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 5 of 22

SAMPLE RESULTS - 02
L1453296
PIEDMONT WATER
Collected date/time: 01/19/22 13:30
Preparation by Method 1311
Result
Qualifier Prep
Batch
Analyte
date / time
TCLP Extraction
1/25/2022 6:4123 AM
WG1807134
TCLP ZHE Extraction -
1/31/202212:03:16 PM
WG1809852
Fluid 1
1/25/2022 6:4123 AM
WG1807134
Initial pH 6.45
1/25/2022 6:4123 AM
WG1807134
Final pH 5.07
1/25/2022 6:4123 AM
WG1807134
Mercury by Method 7470A
Result
Qualifier RDL Limit
Dilution Analysis Batch
Analyte mg/I
mg/I mg/I
date/time
Mercury ND
0.0100 0.20
1 01/27/202210:22 WG1808205
Metals (ICP) by Method 6010D
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Arsenic
ND
0.100
5
1 02/02/202213:43
WG1808315
Barium
0.216
0.100
100
1 02/02/202213:43
WG1808315
Cadmium
ND
0.100
1
1 02/02/202213:43
WG1808315
Chromium
ND
0.100
5
1 02/02/202213:43
WG1808315
Lead
ND
0.100
5
1 02/02/202213:43
WG1808315
Selenium
ND
0.100
1
1 02/02/202213:43
WG1808315
Silver
ND
0.100
5
1 02/02/202213:43
WG1808315
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Benzene
ND
J3
0.0500
0.50
1 02/02/2022 0052
WG1811489
Carbon tetrachloride
ND
J3 J4
0.0500
0.50
1 02/02/2022 0052
WG1811489
Chlorobenzene
ND
J3
0.0500
100
1 02/02/2022 0052
WG1811489
Chloroform
ND
J3 J4
0.250
6
1 02/02/2022 0052
WG1811489
1,2-Dichloroethane
ND
0.0500
0.50
1 02/02/2022 0052
WG1811489
1,1-Dichloroethene
ND
J3 J4
0.0500
0.70
1 02/02/2022 0052
WG1811489
2-Butanone (MEK)
ND
0.500
200
1 02/02/2022 0052
WG1811489
Tetrachloroethene
ND
J3
0.0500
0.70
1 02/02/2022 0052
WG1811489
Trichloroethene
ND
J3
0.0500
0.50
1 02/02/2022 0052
WG1811489
Vinyl chloride
ND
J3
0.0500
0.20
1 02/02/2022 0052
WG1811489
(S) Toluene-dH
93.9
80.0-120
0210212022 00.52
WG1811489
(S) 4-Bromofluorobenzene
96.7
77.0-126
0210212022 00.52
WG1811489
(S) 1,2-Dichloroethane-d4
98.2
70.0-130
0210212022 00.52
WG1811489
Chlorinated Acid Herbicides (GC)
by Method
8151A
Result Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
2,4,5-TP (Silvex)
ND
0.00200
1
1 01/31/2022 08:32
WG1806269
2,4-D
ND
0.00200
10
1 01/31/2022 08:32
WG1806269
(S) Z4-Dichlorophenyl Acetic Acid
57.2
14.0-158
0113112022 08.32
WG1806269
Pesticides (GC) by Method 8081B
Result Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Chlordane
ND
0.00500
0.03
1 02/03/202213:53
WG1809205
Endrin
ND
0.00500
0.02
1 02/03/202213:53
WG1809205
Heptachlor
ND
0.00500
0.0080
1 02/03/202213:53
WG1809205
Heptachlor epoxide
ND
0.00500
0.0080
1 02/03/2022 13:53
WG1809205
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
EMA Resources
L1453296
02/04/22 11:16 6 of 22

PIEDMONT WATER
Collected date/time: 01/19/22 13:30
Pesticides (GC) by Method 8081B
Result
Analyte mg/I
Lindane ND
Methoxychlor ND
Toxaphene ND
(S) Decochlorobiphenyl 84.1
(S) Tetrochloro-m-xylene 876
Semi Volatile Organic Compounds
SAMPLE RESULTS
L1453296
Qualifier RDL Limit Dilution
mg/I mg/I
0.00500 0.40 1
0.00500 10 1
0.0100 0.50 1
10.0-128
10.0-127
(GC/MS) by Method 8270E
- 02
Analysis
date/time
02/03/202213:53
02/03/202213:53
02/03/202213:53
0210312022 13.53
0210312022 13.53
Batch
WG1809205
WG1809205
WG1809205
WG1809205
WG1809205
Result
Qualifier RDL
Limit Dilution
Analysis
Batch
Analyte
mg/I _
mg/I
mg/I
date/time
1,4-Dichlorobenzene
ND
0.100
7.50 1
01/31/2022 0237
WG1809535
2,4-Dinitrotoluene
ND
0.100
0.13 1
01/31/2022 0237
WG1809535
Hexachlorobenzene
ND
0.100
0.13 1
01/31/2022 0237
WG1809535
Hexachloro-1,3-butadiene
ND
0.100
0.50 1
01/31/2022 0237
WG1809535
Hexachloroethane
ND
0.100
3 1
01/31/2022 0237
WG1809535
Nitrobenzene
ND
0.100
2 1
01/31/2022 0237
WG1809535
Pyridine
ND
0.100
5 1
01/31/2022 0237
WG1809535
3&4-Methyl Phenol
ND
0.100
400 1
01/31/2022 0237
WG1809535
2-Methylphenol
ND
0.100
200 1
01/31/2022 0237
WG1809535
Pentachlorophenol
ND
0.100
100 1
01/31/2022 0237
WG1809535
2,4,5-Trichlorophenol
ND
0.100
400 1
01/31/2022 0237
WG1809535
2,4,6-Trichlorophenol
ND
0.100
2 1
01/31/2022 0237
WG1809535
(S) 2-Fluorophenol
50.0
10.0-120
0113112022 02.37
WG1809535
(S) Phenol-d5
32.0
10.0-120
0113112022 02.37
WG1809535
(S) Nitrobenzene-d5
80.9
10.0-127
0113112022 02.37
WG1809535
(S) 2-Fluorobiphenyl
77.6
10.0-130
0113112022 02.37
WG1809535
(S) 2,4, 6-Tribromophenol
73.5
10.0-155
0113112022 02.37
WG1809535
(S) p-Terphenyl-d14
85.8
10.0-128
0113112022 02.37
WG1809535
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
EMA Resources
L1453296
02/04/22 11:16 7 of 22

WG1808071
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3754357-1 01/27/22 1826
MB Result
Analyte mg/kg
Reactive Cyanide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.0390 0.250
L1454296-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1453296-01
(OS) L1454296-01 01/27/22 18:34 • (DUP) R3754357-3 01/27/22 18:35
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide ND ND 1 2.80 20
L1454504-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1454504-01 01/27/22 18:45 • (DUP) R3754357-8 01/27/22 18:46
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Cyanide ND ND 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3754357-2 01/27/22 18:27
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Cyanide 2.50 2.38 95.3
Rec. Limits LCS Qualifier
85.0-115
L1454296-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1454296-01 01/27/22 18:34 • (MS) R3754357-6 01/27/22 18:38 • (MSD) R3754357-7 01/27/22 18:39
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 ND 1.59 3.13 83.2 176 1 75.0-125 J3 J5 65.3 20
L1454504-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1454504-01 01/27/22 18:45 • (MS) R3754357-9 01/27/22 18:47 • (MSD) R3754357-10 01/27/22 18:50
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 ND 0.773 0.798 46.4 47.9 1 75.0-125 J6 J6 3.16 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 3 of 22

WG1806992
Wet Chemistry by Method 9034-9030B
Method Blank (MB)
(MB) R3753430-1 01/25/22 2100
MB Result MB Qualifier MB MDL
Analyte mg/kg mg/kg
Reactive Sulfide U 7.63
Laboratory Control Sample (LCS)
(LCS) R3753480-2 01/25/22 2100
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Sulfide 100 128 128
QUALITY CONTROL SUMMARY
L1453296-01
MB RDL
mg/kg
25.0
Rec. Limits LCS Qualifier
70.0-130
L1452840-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1452340-01 01/25/22 21:00 • (MS) R3753430-3 01/25/22 21:00 • (MSD) R3753430-4 01/25/22 2100
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Sulfide 100 42.3 60.1 56.1 17.8 13.8 1 70.0-130 J6 J6 6.90 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 9 of 22

WG1806056 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9045D L1453296-01
L1453260-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1453260-01 01/22/22 07:18 • (DUP) R3752514-2 01/22/22 0718
Original Result DUP Result Dilution DUP RPD
Analyte su su
Corrosivity by pH 7.19 7.19 1 0.000
Sample Narrative:
OS: 7.19 at17.6C
DUP 7.19 at17.6C
Laboratory Control Sample (LCS)
DUP Qualifier DUP RPD
Limits
(LCS) R3752514-1 01/22/22 0718
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte su su
Corrosivity by pH 10.0 9.93 99.3 99.0-101
Sample Narrative:
LCS: 9.93 at15.6C
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 10 of 22

WG1806787
Wet Chemistry by Method D93/1010A
L1451363-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1451363-01 01/24/22 02:00 • (DUP) R3753039-3 01/24/22 02:00
Original Result DUP Result Dilution DUP RPD
Analyte Deg. F Deg. F
Ignitability DNI at200 DNI at200 1 0.000
L1453335-02 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1453296-01
DUP Qualifier DUP RPD
Limits
i
10
(OS) L1453335-02 01/24/22 02:00 • (DUP) R3753039-4 01/24/22 02:00
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F
Ignitability DNI at170 DNI at170 1 0.000 10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3753039-1 01/24/22 02:00 • (LCSD) R3753039-2 01/24/22 02:00
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte Deg. F Deg. F Deg. F
Ignitability 126 130 128 103 101 95.6-104 1.55 10
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 11 of 22

WG1808205 QUALITY CONTROL SUMMARY
Mercury by Method 7470A L1453296-02
Method Blank (MB)
(MB) R3754125-1 01/27/22 0923
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/I mg/I mg/I
Mercury U 0.00330 0.0100
Laboratory Control Sample (LCS)
(LCS) R3754125-2 01/27/22 09:26
Spike Amount LCS Result LCS Rec.
Analyte mg/I mg/I
Mercury 0.0300 0.0332 111
Rec. Limits LCS Qualifier
80.0-120
L1450954-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1450954-01 01/27/22 09:23 • (MS) R3754125-3 01/27/22 09:30 • (MSD) R3754125-4 01/27/22 09:33
Spike Amount
Original Result
MS Result
MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Mercury 0.0300
ND
0.0329
0.0327 110 109 1 75.0-125 0.610 20
L1452746-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1452746-02 01/27/22 09:42 • (MS) R3754125-5 01/27/22 09:45 • (MSD) R3754125-6 01/27/22 09:47
Spike Amount
Original Result
MS Result
MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Mercury 0.0300
ND
0.0391
0.0317 130 106 1 75.0-125 J5 J3 20.9 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 12 of 22

WG1808315
Metals (ICP) by Method 6010D
Method Blank (MB)
(MB) R3756347-1 02/02/22 1323
MB Result
MB Qualifier MB MDL
Analyte mg/I
mg/I
Arsenic U
0.0333
Barium U
0.0333
Cadmium U
0.0333
Chromium U
0.0333
Lead U
0.0333
Selenium U
0.0333
Silver U
0.0333
Laboratory Control Sample (LCS)
(LCS) R3756347-2 02/02/22 1325
Spike Amount
LCS Result
Analyte
mg/I
mg/I
Arsenic
10.0
9.75
Barium
10.0
9.88
Cadmium
10.0
9.46
Chromium
10.0
9.51
Lead
10.0
10.1
Selenium
10.0
10.0
Silver
2.00
1.73
LCS Rec.
97.5
98.8
94.6
95.1
101
100
86.5
QUALITY CONTROL SUMMARY
L1453296-02
MB RDL
mg/I
0.100
0.100
0.100
0.100
0.100
0.100
0.100
Rec. Limits
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
LCS Qualifier
L1452764-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1452764-03 02/02/22 13:23 • (MS) R3756347-4 02/02/22 13:33 • (MSD) R3756347-5 02/02/22 13:35
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
Analyte
mg/I
mg/I
mg/I
mg/I
Arsenic
10.0
ND
9.84
9.64
98.4
96.4
1 75.0-125
Barium
10.0
0.213
10.1
9.93
98.9
97.2
1 75.0-125
Cadmium
10.0
ND
9.37
9.21
93.7
92.1
1 75.0-125
Chromium
10.0
ND
9.51
9.35
95.1
93.5
1 75.0-125
Lead
10.0
ND
10.1
9.89
101
98.9
1 75.0-125
Selenium
10.0
ND
10.0
9.86
100
98.6
1 75.0-125
Silver
2.00
ND
1.73
1.69
86.6
84.4
1 75.0-125
MS Qualifier MSD Qualifier RPD
2.12
1.79
1.76
1.70
2.15
1.88
2.60
RPD Limits
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 13 of 22

WG1811489 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1453296-02
Method Blank (MB)
(MB) R3755939-3 02/01/22 23:03
MB Result
Analyte
mg/I
Benzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chloroform
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
2-Butanone (MEK)
U
Tetrachloroethene
U
Trichloroethene
U
Vinyl chloride
U
(S) Toluene-dH
91.1
(S) 4-Bromofluorobenzene 96.8
(S) 1,2-Dichloroethane-d4 100
MB Qualifier MB MDL
mg/I
MB RDL
mg/I
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
0.0833
0.250
0.0167
0.0500
0.0167
0.0500
0.167
0.500
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
80.0-120
77.0-126
70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3755939-1 02/01/22 21:36 • (LCSD) R3755939-2 02/01/22 2158
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
Analyte
mg/I
mg/I
mg/I
Benzene
0.250
0.264
0.276
106
110
70.0-123
Carbon tetrachloride
0.250
0.294
0.329
118
132
68.0-126
Chlorobenzene
0.250
0.240
0.259
96.0
104
80.0-121
Chloroform
0.250
0.311
0.315
124
126
73.0-120
1,2-Dichloroethane
0.250
0.279
0.302
112
121
70.0-128
1,1-Dichloroethene
0.250
0.283
0.322
113
129
71.0-124
2-Butanone (MEK)
1.25
1.31
1.30
105
104
44.0-160
Tetrachloroethene
0.250
0.269
0.287
108
115
72.0-132
Trichloroethene
0.250
0.286
0.308
114
123
78.0-124
Vinyl chloride
0.250
0.224
0.242
89.6
96.8
67.0-131
(S) Toluene-dH
92.2
93.8
80.0-120
(S) 4-Bromofluorobenzene
101
101
77.0-126
(S) 1,2-Dichloroethane-d4
100
105
70.0-130
LCS Qualifier
J4
LCSD Qualifier RPD
4.44
J4 11.2
7.62
J4 1.28
7.92
J4 12.9
0.766
6.47
7.41
7.73
RPD Limits
20
20
20
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 14 of 22

WG1811489 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1453296-02
L1453296-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1453296-02 02/02/22 00:52 • (MS) R3755939-4 02/02/22 07:23 • (MSD) R3755939-5 02/02/22 07:45
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier
RPD
RPD Limits
Analyte
mg/I
mg/I
mg/I
mg/I
Benzene
0.250
ND
0.157
0.279
62.8
112
1 17.0-158
J3
56.0
27
Carbon tetrachloride
0.250
ND
0.156
0.335
62.4
134
1 23.0-159
J3
72.9
28
Chlorobenzene
0.250
ND
0.161
0.262
64.4
105
1 33.0-152
J3
47.8
27
Chloroform
0.250
ND
ND
0.314
83.6
126
1 29.0-154
J3
40.2
28
1,2-Dichloroethane
0.250
ND
0.237
0.295
94.8
118
1 29.0-151
21.8
27
1,1-Dichloroethene
0.250
ND
0.157
0.328
62.8
131
1 11.0-160
J3
70.5
29
2-Butanone (MEK)
1.25
ND
1.28
1.29
102
103
1 10.0-160
0.778
32
Tetrachloroethene
0.250
ND
0.132
0.291
52.8
116
1 10.0-160
J3
75.2
27
Trichloroethene
0.250
ND
0.156
0.306
62.4
122
1 10.0-160
J3
64.9
25
Vinyl chloride
0.250
ND
0.107
0.222
42.8
88.8
1 10.0-160
J3
69.9
27
(S) Toluene-dH
88.5
89.4
80.0-120
(S) 4-Bromofluorobenzene
96.8
98.3
77.0-126
(S) 1,2-Dichloroethane-d4
98.3
100
70.0-130
L1454497-02 Original Sample (OS) • Matrix Spike (MS)
(OS) L1454497-02 02/02/22 02:19 • (MS) R3755939-6 02/02/22 03 06
Spike Amount
Original Result
MS Result
MS Rec. Dilution
Rec. Limits MS Qualifier
Analyte mg/I
mg/I
mg/I
Benzene 0.250
10.9
11.7
320 1
17.0-158 E V
Carbon tetrachloride 0.250
ND
0.290
116 1
23.0-159
Chlorobenzene 0.250
ND
0.243
97.2 1
33.0-152
Chloroform 0.250
ND
0.282
113 1
29.0-154
1,2-Dichloroethane 0.250
ND
0.269
108 1
29.0-151
1,1-Dichloroethene 0.250
ND
0.293
117 1
11.0-160
2-Butanone (MEK) 1.25
ND
1.11
88.8 1
10.0-160
Tetrachloroethene 0.250
ND
0.260
104 1
10.0-160
Trichloroethene 0.250
ND
0.266
106 1
10.0-160
Vinyl chloride 0.250
ND
0.214
85.6 1
10.0-160
(S) Toluene-dH
90.3
80.0-120
(S) 4-Bromofluorobenzene
100
77.0-126
(S) 1,2-Dichloroethane-d4
94.3
70.0-130
ACCOUNT:
PROJECT:
SDG: DATE/TIME: PAGE:
EMA Resources
L1453296 02/04/22 11:16 15 of 22

WG1806269
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
(MB) R3755450-1 01/31/22 02:57
MB Result
Analyte mg/I
2,4-D U
2,4,5-TP (Silvex) U
(S) Z4-Dichlorophenyl Acetic 62.4
Acid
QUALITY CONTROL SUMMARY
L1453296-02
MB Qualifier MB MDL
MB RDL
mg/I
mg/I
0.000667
0.00200
0.000667
0.00200
14.0-158
Laboratory Control Sample (LCS)
(LCS) R3755450-2 01/31/22 03:11
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
2,4-D 0.0500
0.0370
74.0
50.0-120
2,4,5-TP (Silvex) 0.0500
0.0351
70.2
50.0-125
(S) Z4-Dichlorophenyl Acetic
58.0
14. 0-158
Acid
L1452051-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1452051-01 01/31/22 04:39 • (MS) R3755450-3 01/31/22 04:54 • (MSD) R3755450-4 01/31/22 05:03
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
2,4-D
0.0500
ND
0.0382
0.0387
76.4
77.4
2,4,5-TP (Silvex)
0.0500
ND
0.0339
0.0340
67.8
68.0
(S) Z4-Dichlorophenyl Acetic
55.2
64.0
Acid
ACCOUNT:
EMA Resources
PROJECT:
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 50.0-120 1.30 20
1 50.0-125 0.295 20
14.0-158
SDG: DATE/TIME: PAGE:
L1453296 02/04/22 11:16 16 of 22

WG1809205
Pesticides (GC) by Method 8081B
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1453296-02
(MB) R3756557-1 02/03/22 1150
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Gamma BHC
U
0.00167
0.00500
Endrin
U
0.00167
0.00500
Heptachlor
U
0.00167
0.00500
Heptachlor epoxide
U
0.00167
0.00500
Methoxychlor
U
0.00167
0.00500
Chlordane
U
0.00167
0.00500
Toxaphene
U
0.00333
0.0100
(S) Decachlorobiphenyl
80.8
10.0-128
(S) Tetrochloro-m-xylene
89.9
10.0-127
Laboratory Control Sample (LCS)
(LCS) R3756557-2 02/03/22 1159
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
Analyte
mg/I
mg/I
Gamma BHC
0.0100
0.0108
108
55.0-129
Endrin
0.0100
0.0109
109
57.0-134
Heptachlor
0.0100
0.0114
114
27.0-132
Heptachlor epoxide
0.0100
0.0104
104
57.0-130
Methoxychlor
0.0100
0.0109
109
54.0-155
(S) Decachlorobiphenyl
88.9
10.0-128
(S) Tetrochloro-m-xylene
96.0
10.0-127
LCS Qualifier
L1451418-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1451413-02 02/03/22 12:17 • (MS) R3756557-3 02/03/22 12:25 • (MSD) R3756557-4 02/03/22 12:34
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Gamma BHC
0.0100
ND
0.00967
0.0103
96.7
103
Endrin
0.0100
ND
0.00961
0.0104
96.1
104
Heptachlor
0.0100
ND
0.0102
0.0110
102
110
Heptachlor epoxide
0.0100
ND
0.00921
0.0100
92.1
100
Methoxychlor
0.0100
ND
0.00969
0.0105
96.9
105
(S) Decachlorobiphenyl
81.9
89.2
(S) Tetrochloro-m-xylene
85.5
92.5
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
1 14.0-141
6.31
40
1 10.0-160
7.90
39
1 16.0-136
7.55
40
1 10.0-160
8.22
36
1 10.0-160
8.02
34
10.0-128
10.0-127
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 17 of 22

WG1809535 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1453296-02
Method Blank (MB)
(MB) R3755335-2 01/31/22 00:07
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
U
0.0333
0.100
2,4-Dinitrotoluene
U
0.0333
0.100
Hexachlorobenzene
U
0.0333
0.100
Hexachloro-1,3-butadiene
U
0.0333
0.100
Hexachloroethane
U
0.0333
0.100
Nitrobenzene
U
0.0333
0.100
Pyridine
U
0.0333
0.100
2-Methylphenol
U
0.0333
0.100
3&4-Methyl Phenol
U
0.0333
0.100
Pentachlorophenol
U
0.0333
0.100
2,4,5-Trichlorophenol
U
0.0333
0.100
2,4,6-Trichlorophenol
U
0.0333
0.100
(S) Nitrobenzene-d5
82.9
10.0-127
(S) 2-Fluorobiphenyl
79.5
10.0-130
(S) p-Terphenyl-d14
88.0
10.0-128
(S) Phenol-d5
32.0
10.0-120
(S) 2-Fluorophenol
51.5
10.0-120
(S) 2,4, 6-Tribromophenol
77.0
10. 0-155
Laboratory Control Sample (LCS)
(LCS) R3755335-1 01/30/22 23:45
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
1,4-Dichlorobenzene 0.500
0.376
75.2
18.0-120
2,4-Dinitrotoluene 0.500
0.420
84.0
49.0-124
Hexachlorobenzene 0.500
0.367
73.4
44.0-120
Hexachloro-1,3-butadiene 0.500
0.343
68.6
19.0-120
Hexachloroethane 0.500
0.391
78.2
15.0-120
Nitrobenzene 0.500
0.373
74.6
27.0-120
Pyridine 0.500
0.282
56.4
10.0-120
2-Methylphenol 0.500
0.336
67.2
28.0-120
3&4-Methyl Phenol 0.500
0.381
76.2
31.0-120
Pentachlorophenol 0.500
0.390
78.0
23.0-120
2,4,5-Trichlorophenol 0.500
0.420
84.0
44.0-120
2,4,6-Trichlorophenol 0.500
0.408
81.6
42.0-120
(S) Nitrobenzene-d5
72.5
10.0-127
(S) 2-Fluorobiphenyl
74.1
10.0-130
(S) p-Terphenyl-d14
83.6
10.0-128
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1453296 02/04/22 11:16 18 of 22

WG1809535
QUALITY
CONTROL
SUMMARY
Semi Volatile Organic Compounds
(GC/MS) by Method 8270E
L1453296-02
Laboratory Control Sample (LCS)
(LCS) R3755335-1 01/30/22 23:45
Spike Amount
LCS Result
LCS Rec.
Rec. Limits
LCS Qualifier
Analyte mg/I
mg/I
(S) Phenol-d5
34.8
10.0-120
(S) 2-Fluorophenol
55.5
10.0-120
(S) 2,4, 6-Tribromophenol
74.0
10. 0-155
L1452714-01 Original Sample (OS) • Matrix Spike (MS)
• Matrix
Spike Duplicate (MSD)
(OS) L1452714-01 01/31/22 00:23 • (MS) R3755335-3 01/31/22 00:49 • (MSD) R3755335-4 01/31/22 0111
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec. Dilution Rec. Limits MS Qualifier
MSD Qualifier RPD
RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
1,4-Dichlorobenzene 0.500
ND
0.363
0.373
72.6
74.6 1
17.0-120
2.72
40
2,4-Dinitrotoluene 0.500
ND
0.426
0.443
85.2
88.6 1
39.0-125
3.91
25
Hexachlorobenzene 0.500
ND
0.375
0.390
75.0
78.0 1
35.0-122
3.92
24
HexachIaro-1,3-butadiene 0.500
ND
0.345
0.347
69.0
69.4 1
12.0-120
0.578
34
Hexachloroethane 0.500
ND
0.389
0.394
77.8
78.8 1
10.0-120
1.28
40
Nitrobenzene 0.500
ND
0.376
0.375
75.2
75.0 1
12.0-120
0.266
30
Pyridine 0.500
ND
0.265
0.282
53.0
56.4 1
10.0-120
6.22
37
2-Methylphenol 0.500
ND
0.322
0.327
64.4
65.4 1
10.0-120
1.54
30
3&4-Methyl Phenol 0.500
ND
0.350
0.371
70.0
74.2 1
10.0-120
5.83
36
Pentachlorophenol 0.500
ND
0.420
0.434
84.0
86.8 1
10.0-128
3.28
37
2,4,5-Trichlorophenol 0.500
ND
0.426
0.446
85.2
89.2 1
33.0-120
4.59
31
2,4,6-Trichlorophenol 0.500
ND
0.419
0.431
83.8
86.2 1
26.0-120
2.82
31
(S) Nitrobenzene-d5
73.2
76.5
10.0-127
(S) 2-Fluorobiphenyl
72.4
76.5
10.0-130
(S) p-Terphenyl-d14
88.2
88.3
10.0-128
(S) Phenol-d5
32.0
32.7
10.0-120
(S) 2-Fluorophenol
52.0
52.0
10.0-120
(S)2,4,6-Tribromophenol
81.0
80.0
10.0-155
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1453296 02/04/22 11:16 19 of 22

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
u
Fc
Fss]
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
Fn
RDL
Reported Detection Limit.
Rec.
Recovery.
Fr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
F
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
F
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Rc
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe
samples from the time of collection until delivery to the laboratory for analysis.
This section ofyour report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
E
The analyte concentration exceeds the upper limit ofthe calibration range ofthe instrument established by the initial
calibration (ICAL).
J3
The associated batch QC was outside the established quality control range for precision.
J4
The associated batch QC was outside the established quality control range for accuracy.
J5
The sample matrix interfered with the ability to make any accurate determination, spike value is high.
J6
The sample matrix interfered with the ability to make any accurate determination, spike value is low.
T8
Sample(s) received past/too close to holding time expiration.
v
The sample concentration is too high to evaluate accurate spike recoveries.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1453296 02/04/22 11:16 20 of 22

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
N E-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TNO02
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704 _
Georgia
NELAP
North Carolina 3
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky' 6
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee'"
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas5
LABO152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A2 LA
A2LA— ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A2 LA — ISO 17025 5
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
Rc
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1453296 02/04/22 11:16
PAGE:
21 of 22

Company Name/Address:
Billing information,
Analvsr
/
Container
/ Pr
servative
j'
Chain of Custody Page of
EMA Resources
Mr. Brent Collins Lhk'
755 Yadkinville Road
755 Yadkinville Road
Mocksville, NC 2702$
aCeAl?allial
11�m
Mocksville, NC 27028
I2065 rebanon Rd Mo,ol Aii e. TN 37122
s emin�n"„�e„etnacnainor �,iody
consHt�­6M 4dii Ind xce9t— f tM
P.. Terns and CoMdwns (pond al:
+ rnn+o.w eas omn�m.rPs-atanda,a-
.—pot
Report to:
Mr. Brent Collins
iTOE
brent.coltins@em a re sourcesinc.com;roy.whitak
Project Description:
Sludge
City/State /I �t
Collected: go/10+L^�► ii //uc-
Nease Circie
PT MT C-1 EI
SDG # 32 `Z
Phone [phone]
Client Project #
Lab Project k
a
a
p
Z
I
`'
1-4
a
z
U
J
+
d
!
E091
Acctnum: EMARES
Template:T11413
7
Prelogin: P895414
PM: 807 -Justin Carr
PB.
C ed by41"IZE4L_
o
Site/Facility ID #
Collette (signa ur
Imme rely
Packed on Ice N _ Y
Rosh? {Lab MUST Be Notified) Quote #
Same Day _Five Day
Next Day _5 Day{Rad Orfy) Date Results Needed
Two Day 30 Day Iliad Only) No.
_ Three Day of
Shipped Via: FedEX Ground
Re arts
Sample ID
Camp/Grab
Matrix *
Depth
Date
Time
ntrs
—
�
C
SS
3`
d191212-
f
2
X
X
P 4tvi W ai er LL
Sample Receipt Chec! 'S-g
COC Seal Present/Tntact: —NF N
COC Signed/Accurate: 1 —N
Bottles arrive intact: Y _N
Correct bottles used: N
* Matrix: Remarks:
SS - Soil AIR - Air F- Filter pH Temp
GW- Groundwater B- Bioassay
WW - WasteWatet Flow Other
DW -Drinking Water
Samples returned via: T�
OT- Other _UPS Fed Ex Courier Tracking # Sy� 4[D 13 V pL 1 �
— —
Sufficient volume sent: N
—
If Applicable
VOA 2erp Headspace: Y N
Preservation Correct/Checked: _N
PAD Screen <0.5 mRlhr: vY —N
Reli IF Date
/l/glZZ
Time
7 o0
Received by: (Signature)
Trip Blank Received: Yes DC
HC eaH
rBR
Relinquis ed y (Signature Date:
JIJW2,2-
T>me:
3.30
Received by: (Signature)
Temp-VAii Battles Received:
A b,11--o -:!- l,cf c�
If preservation required by Login: Date/Time
Relinquished by : (Signature) Date:
Time:
Reived for lab by: (Signature)
Datte: Time:
Hold:
Conditi n. ,

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 117.97
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Donnell Komegay Owner: Donnell Kornegay Predominant Soil Series: FoA
Acres Used: 16.56 Acres Permitted: 16.56 Site #: DU07 Field #: 9
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
3
4
5j
6j
7j
8j
9
10
11
12
DT/Ac./
App.
.fir
Event
7.12
Arsenic
0.292
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.292
Cadmium
0.292
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.292
Copper
0.608
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.608
Chromium
0.292
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.292
Lead
0.292
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.292
Mercury
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.292
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.292
denum
Nickel
0.292
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.292
Selenium
0.292
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.292
Zinc
0.940
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.940
Total
Phos-
208.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
208.021
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Donnell Kornegay
Operator: Donnell Kornegay
Crop 1 Name: Soybeans
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 117.97 Site #:
Predominant Soil Series: FoA
Crop 1 Max. PAN:
156 Crop 2 Name:
9
DU07
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
16.56
16.56
0
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
F ,'tea
c�
w
*o•
o
,•d
�,
#
4
w •,
* N
*�
TKN
mg/kg
Z
8
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
5/9
91000
4.68
1.072
Guilford Mills
Dry
<.5"
S
0.5
1 0.3
33600
581
5.61
21.881
NA
Beans
5110
136500
4.68
1.609
Guilford Mills
Dry
<.5"
S
0.5
0.3
33600
581
5.61
32.822
NA
Beans
5111
149500
4.68
1.762
Guilford Mills
Dry
<.5"
S
0.5
0.3
33600
581
5.61
35.948
NA
Beans
5/12
162500
4.68
1.915
Guilford Mills
Dry
<.5"
S
0.5
0.3
33600
581
5.61
39.073
NA
Beans
5/13
65000
4.68
0.766
Guilford Mills
Dry
<.5"
S
0.5
0.3
33600
581
5.61
15.629
NA
Beans
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
0
604500
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
145.7
0.000
Lime App lied
Annuallbs/acre
0.292
0.292
0.608
0.292
0.292
0.005
0.292
0.292
0.292
0.940
208.021
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.292
0.292
0.608
0.292
0.292
0.005
0.292
0.292
0.292
0.940
Permitted C. P. L. R.****1
36
1 34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
1 156
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
EMA Resources Inc.
Total Dry Tons Applied (Annual):
WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Donnell Komegay Owner: Donnell Kornegay Predominant Soil Series:
Acres Used: 55 Acres Permitted: 55 Site #: DU07 Field #:
81.95
10
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
1.49
Arsenic
0.029
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Cadmium
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Copper
0.116
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.116
Chromium
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.028
Lead
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
denum
Nickel
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Selenium
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.038
Zinc
0.097
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.097
Total
Phos-
59.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
59.004
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: EMA Resources Inc.
Land Owner: Donnell Kornegay
Operator: Donnell Kornegay
Crop 1 Name: Wheat
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 81.95 Site #:
Predominant Soil Series
Crop 1 Max. PAN:
156 Crop 2 Name:
10
Acres Utilized:
DU07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
55
55
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
9/26
234000
2.52
0.447
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
9.488
NA
Wheat
9/27
260000
2.52
0.497
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
10.542
NA
Wheat
9/28
286000
2.52
0.546
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
11.596
NA
Wheat
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
780000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
3 i.627T
o.000
Lime Applied
Annuallbs/acre
0.029
0.002
0.116
0.028
0.021
0.001
0.016
0.014
0.038
0.097
59.004
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.029
1 0.002
0.116
0.028
0.021
0.001
0.016
0.014
0.038
0.097
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
1
1 156
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 133.62
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Ryan Hiatt Owner: Ryan Hiatt Predominant Soil Series: EnC
Acres Used: 25.95 Acres Permitted: 25.95 Site #: GU28 Field #: 2X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
5.15
Arsenic
0.098
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.098
Cadmium
0.342
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.342
Copper
1.462
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.462
Chromium
0.079
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.079
Lead
0.209
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.209
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.167
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.167
denum
Nickel
0.183
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.183
Selenium
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Zinc
0.226
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.226
Total
Phos-
7.837
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
7.837
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Ryan Hiatt
Operator: Ryan Hiatt
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 133.62 Site #:
Predominant Soil Series: EnC
Crop 1 Max. PAN:
136.5 Crop 2 Name:
2X Acres Utilized:
GU28 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
25.95
25.95
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/18
234
22.6
1.716
Piedmont Water
Dry
<.5"
S
0.5
0.4
7080
345
20.4
9.909
NA
Fescue
11/21
468
22.6
3.433
Piedmont Water
Dry
<.5"
S
0.5
0.4
7080
345
20.4
19.819
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
702
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
29.728
0.00o
Lime A lied
Annuallbs/acre
0.098
0.342
1.462
0.079
0.209
0.001
0.167
0.183
0.015
0.226
7.837
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.098
1 0.342
1.462
0.079
0.209
0.001
0.167
0.183
0.015
0.226
Permitted C. P. L. R.****1
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
1
1 136.5
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 66.81
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Ryan Hiatt Owner: Ryan Hiatt Predominant Soil Series: HhB
Acres Used: 17.13 Acres Permitted: 17.13 Site #: GU28 Field #: 5X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
3
4
5j
6j
7j
8j
9
10
11
12
DT/Ac./
App.
.fir
Event
3.90
Arsenic
0.074
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.074
Cadmium
0.259
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.259
Copper
1.108
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.108
Chromium
0.060
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
Lead
0.158
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.158
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.126
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.126
denum
Nickel
0.139
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.139
Selenium
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Zinc
0.171
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.171
Total
Phos-
5.936
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.936
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Ryan Hiatt
Operator: Ryan Hiatt
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 66.81 Site #:
Predominant Soil Series: HhB
Crop 1 Max. PAN:
114.75 Crop 2 Name:
5X Acres Utilized:
GU28 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
17.13
17.13
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/22
351
22.6
3.900
Piedmont Water
Dry
<.5"
S
0.5
0.4
7080
345
20.4
22.518
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
3511
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
22.5 1 8T
o.000
Lime Applied
Annuallbs/acre
0.074
0.259
1.108
0.060
0.158
0.000
0.126
0.139
0.011
0.171
5.936
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.074
0.259
1.108
0.060
0.158
0.000
0.126
0.139
0.011
0.171
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
114.75
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 22.27
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Ryan Hiatt Owner: Ryan Hiatt Predominant Soil Series: EnC
Acres Used: 3 Acres Permitted: 3 Site #: GU28 Field #: 7X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
3
4
5j
6j
7j
8j
9
10
11
12
DT/Ac./
App.
.fir
Event
7.42
Arsenic
0.141
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.141
Cadmium
0.493
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.493
Copper
2.108
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.108
Chromium
0.114
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.114
Lead
0.301
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.301
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.241
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.241
denum
Nickel
0.264
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.264
Selenium
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
Zinc
0.325
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.325
Total
Phos-
11.298
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.298
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Ryan Hiatt
Operator: Ryan Hiatt
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 2227 Site #:
Predominant Soil Series: EnC
Crop 1 Max. PAN:
182
Crop 2 Name:
7X Acres Utilized:
GU28 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Q
Volume applied
enter one Solids/
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
c�
w
*o•
o
,•d
�
#
w ,
* N
*�
TKN
mg/kg
Z
;
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/18
117
22.6
7.423
Piedmont Water
Dry
<.5"
S
0.5
1 0.4
7080
345
20.4
42.858
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
1171
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
42.858
1 0.000
Lime Applied
Annuallbs/acre
0.141
0.493
2.108
0.114
0.301
0.001
0.241
0.264
0.021
0.325
11.298
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.141
1 0.493
2.108
0.114
0.301
0.001
0.241
0.264
0.021
0.325
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
89
2498
Permit PAN Limit Ist/2nd Crop
182
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc
WQ0041666
Nicholas Edwards Owner:
10 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Nicholas Edwards Predominant Soil Series:
10 Site #: NE Field #:
21.86
AuB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
2.19
Arsenic
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
0.171
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.171
Chromium
0.041
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
Lead
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
denum
Nickel
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
Selenium
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.056
Zinc
0.142
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.142
Total
Phos-
86.566
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
86.566
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Nicholas Edwards
Operator: Nicholas Edwards
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 21.86 Site #:
Predominant Soil Series: AuB
Crop 1 Max. PAN:
196
Crop 2 Name:
Acres Utilized:
NE Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
10
10
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
F �a
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
9/6
143000
2.52
1.503
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
31.890
NA
Bermuda
9/7
65000
2.52
0.683
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
14.496
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
208000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
46,786T
0.000
Lime Applied
Annuallbs/acre
0.042
0.003
0.171
0.041
0.031
0.001
0.024
0.021
0.056
0.142
86.566
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.042
0.003
0.171
0.041
0.031
0.001
0.024
0.021
0.056
0.142
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
196
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc
WQ0041666
Nicholas Edwards Owner:
4.3 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Nicholas Edwards Predominant Soil Series:
4.3 Site #: NE Field #:
8.20
We
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
1.91
Arsenic
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
0.149
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.149
Chromium
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Lead
0.027
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
denum
Nickel
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Selenium
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.049
Zinc
0.124
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.124
Total
Phos-
75.478
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
75.478
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Nicholas Edwards
Operator: Nicholas Edwards
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 820 Site #:
Predominant Soil Series: We
Crop 1 Max. PAN:
180 Crop 2 Name:
2
NE
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
4.3
4.3
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
9/7
78000
2.52
1.906
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
40.453
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4-0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
78000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
40.45
00.000
Lime Applied
Annuallbs/acre
0.037
0.003
0.149
0.036
0.027
0.001
0.021
0.018
0.049
0.124
75.478
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.037
0.003
0.149
0.036
0.027
0.001
0.021
0.018
0.049
0.124
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
180
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc
WQ0041666
Nicholas Edwards Owner:
7 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Nicholas Edwards Predominant Soil Series:
7 Site #: NE Field #:
15.71
We
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
2.24
Arsenic
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.043
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
0.175
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.175
Chromium
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Lead
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
denum
Nickel
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
Selenium
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.057
Zinc
0.145
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.145
Total
Phos-
88.862
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
88.862
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Nicholas Edwards
Operator: Nicholas Edwards
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 15.71 Site #:
Predominant Soil Series: We
Crop 1 Max. PAN:
180
Crop 2 Name:
4
Acres Utilized:
NE Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Q
Volume applied
enter one Solids/
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
#
w ,
* N
*�
TKN
mg/kg
Z
;
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
9/7
32500
2.52
0.488
Guilford Mills
Dry
<.5"
S
0.5
1 0.3
31000
5560
199
10.354
NA
Bermuda
9/8
117000
2.52
1.756
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
37.274
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4-0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
149500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
47.628
0.000
Lime Applied
Annuallbs/acre
0.043
0.004
0.175
0.042
0.032
0.001
0.024
0.022
0.057
0.145
88.862
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.043
0.004
0.175
0.042
0.032
0.001
0.024
0.022
0.057
0.145
Permitted C. P. L. R.****
1 36
1 34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
1 180
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc
WQ0041666
Nicholas Edwards Owner:
18 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Nicholas Edwards Predominant Soil Series:
18 Site #: NE Field #:
18.45
Po
5
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
1.03
Arsenic
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Cadmium
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Copper
0.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
Chromium
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Lead
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
denum
Nickel
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Selenium
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Zinc
0.066
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.066
Total
Phos-
40.590
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
40.590
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Nicholas Edwards
Operator: Nicholas Edwards
Crop 1 Name: Bermuda -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 18.45 Site #:
Predominant Soil Series: PO
Crop 1 Max. PAN:
184
Crop 2 Name:
Acres Utilized:
NE Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
18
18
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
9/8
32500
2.52
0.190
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
4.027
NA
Bermuda
9/9
143000
2.52
0.835
Guilford Mills
Dry
<.5"
S
0.5
0.3
31000
5560
199
17.717
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
01
175500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
21,74-7
0.000
Lime Applied
Annuallbs/acre
0.020
0.002
0.080
0.019
0.015
0.001
0.011
0.010
0.026
0.066
40.590
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.020
0.002
0.080
0.019
0.015
0.001
0.011
0.010
0.026
0.066
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
184
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 80.14
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Larry Rogers Owner: Larry Rogers Predominant Soil Series: HeB
Acres Used: 6.1 Acres Permitted: 6.1 Site #: OR93 Field #: 2X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
Brown
5/11/22
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
13.14
Arsenic
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.033
Cadmium
0.137
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.137
Copper
15.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
15.056
Chromium
0.357
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.357
Lead
0.347
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.347
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.081
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.081
denum
Nickel
1.545
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.545
Selenium
0.796
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.796
Zinc
1.768
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.768
Total
Phos-
25.908
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
25.908
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Larry Rogers
Operator: Larry Rogers
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 80.14 Site #:
Predominant Soil Series: HeB
Crop 1 Max. PAN:
163 Crop 2 Name:
2X Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
6.1
6.1
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
as o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/9
451
21.1
13.138
Brown WTP
Dry
<.5"
S
0.5
0.4
8290
1000
338
98.640
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
4511
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
98.64oT
o.000
Lime Applied
Annuallbs/acre
0.033
0.137
15.056
0.357
0.347
0.001
0.081
1.545
0.796
1.768
25.908
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.033
1 0.137
15.056
0.357
0.347
0.001
0.081
1.545
0.796
1.768
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
I
F-163
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 101.83
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Larry Rogers Owner: Larry Rogers Predominant Soil Series: HeB
Acres Used: 15.05 Acres Permitted: 15.05 Site #: OR93 Field #: 03X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
Brown
5/11/22
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
6.77
Arsenic
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Cadmium
0.071
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.071
Copper
7.754
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
7.754
Chromium
0.184
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.184
Lead
0.179
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.179
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
denum
Nickel
0.796
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.796
Selenium
0.410
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.410
Zinc
0.911
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.911
Total
Phos-
13.343
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
13.343
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Larry Rogers
Operator: Larry Rogers
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 101.83 Site #:
Predominant Soil Series: HeB
Crop 1 Max. PAN:
163 Crop 2 Name:
03X Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
15.05
15.05
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/16
573
21.1
6.766
Brown WTP
Dry
<.5"
S
0.5
0.4
8290
1000
338
50.796
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
5731
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
so.796
0.000
Lime A lied
Annuallbs/acre
0.017
0.071
7.754
0.184
0.179
0.001
0.042
0.796
0.410
0.911
13.343
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.017
1 0.071
7.754
0.184
0.179
0.001
0.042
0.796
0.410
0.911
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
163
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 104.84
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Larry Rogers Owner: Larry Rogers Predominant Soil Series: VaB
Acres Used: 10.01 Acres Permitted: 10.01 Site #: OR93 Field #: 4X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
E
Monona
Com-
Brown
5/11/22
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
3
4
5j
6j
7j
8j
9
10
11
12
DT/Ac./
App.
.fir
Event
10.47
Arsenic
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.109
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.109
Copper
12.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.003
Chromium
0.285
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.285
Lead
0.277
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.277
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.065
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.065
denum
Nickel
1.232
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 1.232
Selenium
0.635
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.635
Zinc
1.410
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.410
Total
Phos-
20.655
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
20.655
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Larry Rogers
Operator: Larry Rogers
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 104.84 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
188 Crop 2 Name:
4X Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
10.01
10.01
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/10
590
21.1
10.474
Brown WTP
Dry
<.5"
S
0.5
0.4
8290
1000
338
78.637
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
5901
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
78.637
0.000
Lime A lied
Annuallbs/acre
0.026
0.109
12.003
0.285
0.277
0.001
0.065
1.232
0.635
1.410
20.655
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.026
1 0.109
12.003
0.285
0.277
0.001
0.065
1.232
0.635
1.410
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
188
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 44.42
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Larry Rogers Owner: Larry Rogers Predominant Soil Series: VaB
Acres Used: 10.2 Acres Permitted: 10.2 Site #: OR93 Field #: 6X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
Brown
5/11/22
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
4.36
Arsenic
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Cadmium
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.045
Copper
4.991
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.991
Chromium
0.118
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.118
Lead
0.115
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.115
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.027
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
denum
Nickel
0.512
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.512
Selenium
0.264
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.264
Zinc
0.586
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.586
Total
Phos-
8.588
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
8.588
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Larry Rogers
Operator: Larry Rogers
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 44.42 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
188 Crop 2 Name:
6X Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
10.2
10.2
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/13
250
21.1
4.355
Brown WTP
Dry
<.5"
S
0.5
0.4
8290
1000
338
32.700
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
2501
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
32.700
0.000
Lime Applied
Annuallbs/acre
0.011
0.045
4.991
0.118
0.115
0.000
0.027
0.512
0.264
0.586
8.588
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.011
1 0.045
4.991
0.118
0.115
0.000
0.027
0.512
0.264
0.586
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
188
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 76.23
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Larry Rogers Owner: Larry Rogers Predominant Soil Series: HeB
Acres Used: 4.8 Acres Permitted: 4.8 Site #: OR93 Field #: 07X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
Brown
5/11/22
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
15.88
Arsenic
0.040
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
Cadmium
0.165
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.165
Copper
18.201
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
18.201
Chromium
0.432
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.432
Lead
0.419
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.419
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.098
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.098
denum
Nickel
1.868
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.868
Selenium
0.962
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.962
Zinc
2.138
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.138
Total
Phos-
31.319
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
31.319
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Larry Rogers
Operator: Larry Rogers
Crop 1 Name: Com-Silage
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 76.23 Site #:
Predominant Soil Series: HeB
Crop 1 Max. PAN:
163 Crop 2 Name:
07X Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
4.8
4.8
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu_ Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/20
273
21.1
10.107
Brown WTP
Dry
<.5"
S
0.5
0.4
8290
1000
338
75.880
NA
Fescue
6/21
156
21.1
5.775
Brown WTP
Dry
<.5"
S
0.5
0.4
8290
1000
338
43.360
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
4291
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
119.241
0.000
Lime A lied
Annuallbs/acre
0.040
0.165
18.201
0.432
0.419
0.002
0.098
1.868
0.962
2.138
31.319
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.040
1 0.165
18.201
0.432
0.419
0.002
0.098
1.868
0.962
2.138
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
I
F-163
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: EMA Resources Inc. Total Dry Tons Applied (Annual): 211.99
Permit #: WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Larry Rogers Owner: Larry Rogers Predominant Soil Series: VaB
Acres Used: 14.81 Acres Permitted: 14.81 Site #: OR93 Field #: 21X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
Brown
5/11/22
Date
Total
Phos-
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
14.31
Arsenic
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Cadmium
0.149
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.149
Copper
16.404
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.404
Chromium
0.389
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.389
Lead
0.378
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.378
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.089
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.089
denum
Nickel
1.683
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.683
Selenium
0.867
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.867
Zinc
1.927
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.927
Total
Phos-
28.227
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
28.227
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Larry Rogers
Operator: Larry Rogers
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 211.99 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
188 Crop 2 Name:
21X Acres Utilized:
OR93 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
14.81
14.81
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
6/14
545
21.1
6.539
Brown WTP
Dry
<.5"
S
0.5
0.4
8290
1000
338
49.096
NA
Fescue
6/15
648
21.1
7.775
Brown WTP
Dry
<.5"
S
0.5
0.4
8290
1000
338
58.375
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
11931
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
107.472
0.000
Lime A lied
Annuallbs/acre
0.036
0.149
16.404
0.389
0.378
0.001
0.089
1.683
0.867
1.927
28.227
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.036
1 0.149
16.404
0.389
0.378
0.001
0.089
1.683
0.867
1.927
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
188
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
EMA Resources Inc.
Total Dry Tons Applied (Annual):
WQ0041666 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 30 Acres Permitted: 30 Site #: PS07 Field #:
246.99
3X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
Brown
7/8/22
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
8.23
Arsenic
0.087
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.087
Cadmium
0.321
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.321
Copper
26.675
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
26.675
Chromium
0.224
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.224
Lead
0.217
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.217
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.051
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
denum
Nickel
0.968
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.968
Selenium
0.499
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.499
Zinc
1.108
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.108
Total
Phos-
16.235
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.235
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Roy Carver
Operator: Roy Carver
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 246.99 Site #:
Predominant Soil Series
Crop 1 Max. PAN:
163 Crop 2 Name:
3X Acres Utilized:
PS07 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
30
30
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
8/4
195
18.8
1.029
Brown WTP
Dry
<.5"
S
0.5
0.4
9890
1150
34
8.449
NA
Fescue
8/5
312
18.8
1.647
Brown WTP
Dry
<.5"
S
0.5
0.4
9890
1150
34
13.519
NA
Fescue
8/8
273
18.8
1.441
Brown WTP
Dry
<.5"
S
0.5
0.4
9890
1150
34
11.829
NA
Fescue
8/9
468
18.8
2.470
Brown WTP
Dry
<.5"
S
0.5
0.4
9890
1150
34
20.278
NA
Fescue
8/10
1 312
18.8
1.647
Brown WTP
Dry
<.5"
S
1 0.5
0.4
9890
1150
34
13.519
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
15601
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
67.s94
o.000
Lime Applied
Annuallbs/acre
0.087
0.321
26.675
0.224
0.217
0.001
0.051
0.968
0.499
1.108
16.235
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.087
1 0.321
26.675
0.224
0.217
0.001
0.051
0.968
0.499
1.108
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
163
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc.
Total Dry Tons Applied (Annual):
WQ0041666 Cation Exchange Capacity (non 503 only):
Kenny McMahan Owner: Kenny McMahan Predominant Soil Series:
16 Acres Permitted: 16 Site #: PS30 Field #:
148.29
GeC
1X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
9.27
Arsenic
0.706
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.706
Cadmium
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Copper
48.379
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
48.379
Chromium
0.235
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.235
Lead
0.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.300
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.081
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.081
denum
Nickel
1.983
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.983
Selenium
0.138
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.138
Zinc
3.133
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.133
Total
Phos-
15.088
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
15.088
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Kenny McMahan
Operator: Kenny McMahan
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 14829 Site #:
Predominant Soil Series: GeC
Crop 1 Max. PAN:
198 Crop 2 Name:
1X Acres Utilized:
PS30 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
16
16
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/14
546
21.5
6.179
Brown WTP
Dry
<.5"
S
0.5
0.4
7400
411
20.9
37.345
NA
Fescue
10/20
273
21.5
3.089
Brown WTP
Dry
<.5"
S
0.5
0.4
7400
411
20.9
18.673
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
8191
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
56.018
0.000
Lime Applied
Annuallbs/acre
0.706
0.012
48.379
0.235
0.300
0.001
0.081
1.983
0.138
3.133
15.088
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.706
0.012
48.379
0.235
0.300
0.001
0.081
1.983
0.138
3.133
Permitted C. P. L. R.****
36
34
1 1338
1
267
1 15
374
1 89
2498
Permit PAN Limit Ist/2nd Crop
i
F-198
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc.
Total Dry Tons Applied (Annual):
WQ0041666 Cation Exchange Capacity (non 503 only):
Kenny McMahan Owner: Kenny McMahan Predominant Soil Series:
7 Acres Permitted: 7 Site #: PS30 Field #:
84.74
HrC
2X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
12.11
Arsenic
0.922
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.922
Cadmium
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Copper
63.193
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
63.193
Chromium
0.307
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.307
Lead
0.392
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.392
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.106
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.106
denum
Nickel
2.591
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.591
Selenium
0.180
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.180
Zinc
4.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.092
Total
Phos-
19.709
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
19.709
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Kenny McMahan
Operator: Kenny McMahan
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 84.74 Site #:
Predominant Soil Series: HrC
Crop 1 Max. PAN:
198
Crop 2 Name:
2X Acres Utilized:
PS30 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Q
Volume applied
enter one Solids/
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
c�
w
*o•
o
,•d
�
#
w ,
* N
*�
TKN
mg/kg
Z
;
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/20
234
21.5
6.053
Brown WTP
Dry
<.5"
S
0.5
1 0.4
7400
411
20.9
36.583
NA
Fescue
10/21
234
21.5
6.053
Brown WTP
Dry
<.5"
S
0.5
0.4
7400
411
20.9
36.583
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF so
pp to this form):
TOTALS:
468
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
73.166
0.000
Lime Applied
Annuallbs/acre
0.922
0.016
63.193
0.307
0.392
0.002
0.106
2.591
0.180
4.092
19.709
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.922
0.016
63.193
0.307
0.392
0.002
0.106
2.591
0.180
4.092
Permitted C. P. L. R.****
36
1 34
1 1338
1
1 267
1 15
1
1 374
89
2498
Permit PAN Limit Ist/2nd Crop
198
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc.
Total Dry Tons Applied (Annual):
WQ0041666 Cation Exchange Capacity (non 503 only):
Kenny McMahan Owner: Kenny McMahan Predominant Soil Series:
7 Acres Permitted: 7 Site #: PS30 Field #:
91.80
GeC
3X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
13.11
Arsenic
0.999
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.999
Cadmium
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Copper
68.455
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
68.455
Chromium
0.333
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.333
Lead
0.425
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.425
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.114
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.114
denum
Nickel
2.806
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.806
Selenium
0.195
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.195
Zinc
4.433
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.433
Total
Phos-
21.350
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
21.350
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Kenny McMahan
Operator: Kenny McMahan
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 91.80 Site #:
Predominant Soil Series: GeC
Crop 1 Max. PAN:
198
Crop 2 Name:
3X Acres Utilized:
PS30 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Q
Volume applied
enter one Solids/
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
c�
w
*o•
o
,•d
�
#
w ,
* N
*�
TKN
mg/kg
Z
;
o
as o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/21
117
21.5
3.026
Brown WTP
Dry
<.5"
S
0.5
1 0.4
7400
411
20.9
18.292
NA
Fescue
10/24
390
21.5
10.088
Brown WTP
Dry
<.5"
S
0.5
0.4
7400
411
20.9
60.972
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF so
pp to this form):
TOTALS:
5071
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
79.264
0.000
Lime Applied
Annuallbs/acre
0.999
0.018
68.455
0.333
0.425
0.002
0.114
2.806
0.195
4.433
21.350
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.999
0.018
68.455
0.333
0.425
0.002
0.114
2.806
0.195
4.433
Permitted C. P. L. R.****
36
1 34
1 1338
1
1 267
1 15
1
1 374
89
2498
Permit PAN Limit Ist/2nd Crop
198
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc.
Total Dry Tons Applied (Annual):
WQ0041666 Cation Exchange Capacity (non 503 only):
Ted Oakley Owner: Ted Oakley Predominant Soil Series:
16 Acres Permitted: 16 Site #: PS31 Field #:
70.62
VaB
1X
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
Brown
10/3/22
Date
Total
Phos-
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
4.41
Arsenic
0.336
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.336
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
23.041
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
23.041
Chromium
0.112
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.112
Lead
0.143
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.143
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.038
denum
Nickel
0.945
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.945
Selenium
0.066
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.066
Zinc
1.492
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.492
Total
Phos-
7.186
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
7.186
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/6/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Ted Oakley
Operator: Ted Oakley
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 70.62 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
194 Crop 2 Name:
1X Acres Utilized:
PS31 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
16
16
0
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/25
156
21.5
1.765
Brown WTP
Dry
<.5"
S
0.5
0.4
7400
411
20.9
10.670
NA
Fescue
10/26
234
21.5
2.648
Brown WTP
Dry
<.5"
S
0.5
0.4
7400
411
20.9
16.005
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
3901
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
26.675
0.000
Lime A lied
Annuallbs/acre
0.336
0.006
23.041
0.112
0.143
0.001
0.038
0.945
0.066
1.492
7.186
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.336
1 0.006
23.041
0.112
0.143
0.001
0.038
0.945
0.066
1.492
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
I
F-194
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc
WQ0041666
Gene Hiatt Owner:
11 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Gene Hiatt Predominant Soil Series:
11 Site #: RD43 Field #:
176.30
BtB2
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
16.03
Arsenic
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Cadmium
0.808
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.808
Copper
2.795
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.795
Chromium
0.084
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.084
Lead
0.449
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.449
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.404
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.404
denum
Nickel
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Selenium
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Zinc
0.172
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.172
Total
Phos-
27.566
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
27.566
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Gene Hiatt
Operator: Gene Hiatt
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 176.30 Site #:
Predominant Soil Series: BtB2
Crop 1 Max. PAN:
128.25
Crop 2 Name:
Acres Utilized:
RD43 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
o �
N
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
-
w •,
* N
*�
TKN
mg/kg
Z
;
o
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/21
240
24.2
4.447
Piedmont Water
Dry
<.5"
S
0.5
0.4
8640
115
19.8
31.014
NA
Fescue
3/22
300
24.2
5.558
Piedmont Water
Dry
<.5"
S
0.5
0.4
8640
115
19.8
38.767
NA
Fescue
3/23
75
24.2
1.390
Piedmont Water
Dry
<.5"
S
0.5
0.4
8640
115
19.8
9.692
NA
Fescue
3/28
250
24.2
4.632
Piedmont Water
Dry
<.5"
S
0.5
0.4
8640
115
19.8
32.306
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
8651
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
111.779
0.000
Lime A lied
Annuallbs/acre
0.032
0.808
2.795
0.084
0.449
0.001
0.404
0.016
0.042
0.172
27.566
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.032
1 0.808
2.795
0.084
0.449
0.001
0.404
0.016
0.042
0.172
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
128.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc
WQ0041666
Gene Hiatt Owner:
16.2 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Gene Hiatt Predominant Soil Series:
16.2 Site #: RD34 Field #:
166.60
GbC
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
1
2
3
4
5
6
7
8
9
10
11
12
COm-
Piedmont
Asheboro
pOSlte
Water
7/5/22
7�5�22
Date
% Solids
1 22.7
19.3
Arsenic
1.61
7.2
Cadmium
37.5
0.808
Copper
133
293
Chromium
13.4
67.9
Lead
13.3
24.2
Mercury
0.0678
1.59
Molyb-
20.9
55.4
denum
Nickel
4.07
17.7
Selenium
14.1
2.83
Zinc
17.7
746
Total
Phos-
736
26200
horus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8
9 1
10
11
12
DT/Ac./
App.
.fir
Event
6.76
3.52
Arsenic
1 0.022
0.051
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.072
Cadmium
0.507
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.513
Copper
1.799
2.064
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.863
Chromium
0.181
0.478
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.660
Lead
0.180
0.170
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.350
Mercury
0.001
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Molyb-
0.283
0.390
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.673
denum
Nickel
0.055
0.125
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.180
Selenium
0.191
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.211
Zinc
0.239
5.255
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.494
Total
Phos-
9.954
184.553
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
194.506
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Gene Hiatt
Operator: Gene Hiatt
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 166.60 Site #:
Predominant Soil Series: GbC
Crop 1 Max. PAN:
140.25 Crop 2 Name:
2
RD34
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
16.2
16.2
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/25
234
22.7
2.761
Piedmont Water
Dry
<.5"
S
0.5
0.4
4100
564
75.8
9.787
NA
Fescue
7/28
78
22.7
0.920
Piedmont Water
Dry
<.5"
S
0.5
0.4
4100
564
75.8
3.262
NA
Fescue
8/1
27
22.7
0.319
Piedmont Water
Dry
<.5"
S
0.5
0.4
4100
564
75.8
1.129
NA
Fescue
8/2
234
22.7
2.761
Piedmont Water
Dry
<.5"
S
0.5
0.4
4100
564
75.8
9.787
NA
Fescue
9/20
1 312
19.3
3.130
Asheboro WWTP
Dry
<.5"
S
0.5
0.2
45100
9640
61.1
74.961
NA
Fescue
9/21
39
19.3
0.391
Asheboro WWTP
Dry
<.5"
S
0.5
0.2
45100
9640
61.1
9.370
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
9241
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
1oS.29S
0.000
Lime Applied
Annuallbs/acre
0.072
0.513
3.863
0.660
0.350
0.012
0.673
0.180
0.211
5.494
194.506
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.072
1 0.513
3.863
0.660
0.350
0.012
0.673
0.180
0.211
5.494
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
140.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc
WQ0041666
Gene Hiatt Owner:
11.92 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Gene Hiatt Predominant Soil Series:
11.92 Site #: RD43 Field #:
111.75
BtC2
3b
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
1 1
2
3
4
5
6
7
8
9 j
10 J11
12
COm-
Piedmont
Asheboro
pOSlte
Water
7/5/22
7�5�22
Date
% Solids
1 22.7
19.3
Arsenic
1.61
7.2
Cadmium
37.5
0.808
Copper
133
293
Chromium
13.4
67.9
Lead
13.3
24.2
Mercury
0.0678
1.59
Molyb-
209
55.4
denum
Nickel
4.07
17.7
Selenium
14.1
2.83
Zinc
17.7
746
Total
Phos-
736
26200
horus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9
10
11
12
DT/Ac./
App.
.fir
Event
7.78
1.60
Arsenic
1 0.025
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
Cadmium
0.584
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.586
Copper
2.069
0.935
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.004
Chromium
0.209
0.217
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.425
Lead
0.207
0.077
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.284
Mercury
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Molyb-
0.325
0.177
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.502
denum
Nickel
0.063
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.120
Selenium
0.219
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.228
Zinc
0.275
2.380
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.655
Total
Phos-
11.452
83.578
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
95.030
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Gene Hiatt
Operator: Gene Hiatt
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 111.75 Site #:
Predominant Soil Series: BtC2
Crop 1 Max. PAN:
107.25 Crop 2 Name:
3b
Acres Utilized:
RD43 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
11.92
11.92
0
o �
N
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
F
w
*o•
o
,•d
�,
#
w •,
* N
*�
TKN
mg/kg
Z
;
o
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/15
315
24.2
5.386
Piedmont Water
Dry
<.5"
S
0.5
0.4
8640
115
19.8
37.564
NA
Fescue
3/16
140
24.2
2.394
Piedmont Water
Dry
<.5"
S
0.5
0.4
8640
115
19.8
16.695
NA
Fescue
9/21
117
19.3
1.595
Asheboro WWTP
Dry
<.5"
S
0.5
0.2
45100
9640
61.1
38.204
38.204
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
572
o
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
92.463
38.204
Lime A lied
Annuallbs/acre
0.048
0.586
3.004
0.425
0.284
0.006
0.502
0.120
0.228
2.655
95.030
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.048
0.586
3.004
0.425
0.284
0.006
0.502
0.120
0.228
2.655
Permitted C. P. L. R.****
36
34
1 1338
267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit Ist/2nd Crop
I 107.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
EMA Resources Inc
WQ0041666
Gene Hiatt Owner:
5 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Gene Hiatt Predominant Soil Series:
5 Site #: RD34 Field #:
41.78
BtC2
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5j
6j
7j
8j
9j
10
11
12
DT/Ac./
App.
.fir
Event
8.36
Arsenic
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Cadmium
0.421
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.421
Copper
1.457
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.457
Chromium
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
Lead
0.234
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.234
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.211
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.211
denum
Nickel
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Selenium
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
Zinc
0.090
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.090
Total
Phos-
14.372
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
14.372
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 2/6/2023
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
EMA Resources Inc.
Gene Hiatt
Operator: Gene Hiatt
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0041666 Field #:
Annual Dry Tons Applied: 41.78 Site #:
Predominant Soil Series: BtC2
Crop 1 Max. PAN:
107
Crop 2 Name:
4
Acres Utilized:
RD34 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
Q
Volume applied
enter one Solids/
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied er
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
�a
c�
w
*o•
o
,•d
�
#
w ,
* N
*�
TKN
mg/kg
Z
;
o
oa o
�•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/21
205
24.2
8.356
Piedmont Water
Dry
<.5"
S
0.5
1 0.4
8640
115
19.8
58.280
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
TOTALS:
2051
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
58.280
1 0.000
Lime Applied
Annuallbs/acre
0.017
0.421
1.457
0.044
0.234
0.000
0.211
0.008
0.022
0.090
14.372
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.017
1 0.421
1.457
0.044
0.234
0.000
0.211
0.008
0.022
0.090
Permitted C. P. L. R.****
36
34
1 1338
267
1 15
1
1 374
89
1 2498
Permit PAN Limit Ist/2nd Crop
1 107
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/6/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: EMA Resources Inc. WQ Permit Number: WQ0041666
WWTP Name: Lear Corporation WWTP
Monitoring Period: From l/l/2022
NPDES Number: NC0002305
To 12/31/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
T Alt B (Alk Treatment) ❑ 7
Alt. C (Prior Testing) ❑
Alt.D (No Prior Test) ❑
F Process to Further Reduce Pathogengs 0
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density ❑
1 Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
Composting ❑
jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
Number ot
Excee-
deuces
Frequency
of Analysis
Sample
Type
Analytical
Tech-nique
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
77
120
213
MPN/g
0
Annually
G
SM92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.1 (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed 0
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Brent Collins - Director of Technical Services Brent Collins; Director of Technical Services
Preparer Name and Title (tvpe or print)
Signature of Preparer*
Land Applier Name and Title (if applicable)(type or print)
2/8/2023 G;ii-r.`"e(�2/8/2023
Date Signature of Land Applier (if applicable)
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

]Mvironmental Chemists,
Inc.
f
6602 Windmill Way,
Wilmington, NC 28405 e 910.392.0223 Lab . 910.392.4424 Fax
-
710 Bowsertown Road, Manteo, NC 27954 • 252A73.5702 Lab/x ax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
ANALYTICAL & CONSULTING CHEMISTS
infoCaenvironmentalchemists.com
Guilford East
Date of Report: Mar 15, 2022
1754 NC HWY 903
Customer PO #:
Kenansville NC 28349
Customer ID: 11030018
Attention: George Yankay
Report #: 2022-03049
Project ID: Sludge
Lab ID Sample ID:
Collect Date/Time Matrix Sampled by
22-07209 Site: Sludge
2/17/2022
10.45 AM Solid/Sludge Dale Johnson
Test
Method
Results Date Analyzed
Chlordane (TCLP)
SW-846 8081 B
<0.02 mg/L
02/28/2022
Endrin (TCLP)
SW-8468081B
<0.0005mg/L
02128/2022
Heptachlor (TCLP)
SW-846 8031 B
<0.0005 mg/L
02/28/2022
Heptachlor epoxide (TCLP)
SW-846 8081 B
<0.0005 mg1L
02/28/2022
Lindane (TCLP)
SW-846 8081 a
<0.0005 mg/L
02/28/2022
Methoxychlor (TCLP)
SW-846 Bost B
<0.0005 mg/L
02/28/2022
- Toxaphene (TCLP)
sW-B468081 B
<0-05mg/L
02/2812022
2,4,5-TP (TCLP)
SW-846 8151 A
<0.003 mg/L
03102/2022
2,4-D (TCLP)
SW-8468151A
<0.003mg/L
03/02/2022
1,4-Dichlorobenzene (TCLP)
SW-846 $270 E
<0.050 mg/L
03/01/2022
2,4,5-Trichlorophenol (TCLP)
SW-846 8270 E
<0.050 mg/L
03101 /2022
2,4,6-Trichlorophenol (TCLP)
SW-a46 8270 a
<0.050 mg/L
03/01/2022
2,4-Dinitrotoluene (TCLP)
SW-846 8270 E
<0.050 mg/L
03/01/2022
Cresol (TCLP)
SW-846 8270 E
<0.050 mg/L
03/01/2022
Hexachloro-1,3-butadiene (TCLP)
SW-646 8270 E
<0.050 mg/L
03/01/2022
Hexachlorobenzene (TCLP)
SW-846 8270 E
<0.050 mg/L
03/01/2022
Hexachloroethane (TCLP)
SW-846 8270 E
<0,050 mg/L
03/0112022
m + p-Cresol (TCLP)
SW-845 8270 E
<0.050 mg/L
03/01/2022
Nitrobenzene (TCLP)
SW-846 8270 E
<0.050 mg/L
03/01/2022
o-cresol (TCLP)
SW-846 8270 a
<0.050 mg/L
03/01/2022
Pentachlorophenol (TCLP)
SW-846 8270 E
<0.250 mg/L
03/01/2022
Pyridine (TCLP)
SW-846 8270 S
<0.050 mg/L
03/01/2022
1, 1 -Dichloroethylene (TCLP)
SW-846 Method8260D
<0.01 mg/L
03/01/2022
1,2-Dichloroethane (TCLP)
SW-840 Method 8260D
<0.01 mg/L
03/01/2022
Benzene (TCLP)
5W B46 Method B260❑
<0-01 mg/L
03/01/2022
Carbon Tetrachloride (TCLP)
SW-846 Method 82601)
<0.01 mg/L
03101/2022
Report#., 2022-o3049
Pagel of4

Guilford East
Date of Report: Mar 15, 2022
1754 NC HWY 903
Customer PO #:
Kenansville NC
28349
Customer ID: 11030018
Attention: George Yankay
Report #: 2022-03049
Project ID: Sludge
Chlorobenzene (TCLP)
SW-646 Method 8260D
<0.01 mg/L
03/01/2022
Chloroform (TCLP)
SW-146 Method 82800
<0.01 mg/L
03/01/2022
Methyl ethyl ketone (TCLP)
SW-846 Method 82500
<0.05 mg/L
03/0112022
Tetrachloroethylene (TCLP)
SW 646 Method 62600
<0.01 mg1L
03/01/2022
Trichloroethylene (TCLP)
SW-846 Method 926oD
<0.01 mg/L
03/01/2022
Vinyl Chloride (TCLP)
SW-846 Method 8260D
<0.01 mg/L
03/01/2022
:T41
Cyanide
SM 4500 CN 0-2016
1.60 mg/kg
03/01/2022
Sulfide
SM 4500 S D
8.50 mg/kg
03/03/2022
lgnitability
SW 646 method 1010
>158 OF
02/26/2022
Sludge Residuals
Aluminum
EPA 200.7, Rev.4,4, 1994
63900mglkg
02/22/2022
Arsenic
EPA 200.7, Rev. 4.4,1994
<20.5 mglkg
02/22/2022
Cadmium
EPA2007. Rev. 4A,1994
<20.5mglkg
02/22/2022
Calcium
EPA 200,7. Rev. 4.4,1994
11500 mglkg
02/2212022
Chromium
EPA 200 7, Rev. 4A, 1994
<20.5 mglkg
02/22/2022
Copper
EPA 200.7. Rev, 4.4, 1994
42.7 mg/kg
02/22/2022
Lead
EPA 200,7, Rev. 4.4, 1994
<20.5 mglkg
02/22/2022
Magnesium
EPA 200.7, Rev. 4.4, 1994
2740 mg/kg
02/22/2022
Molybdenum
EPA 200.7, Rev_ 4,4, 1994
<20.5 mglkg
02/2212022
Nickel
EPA 200.7. Rev. 4.4, 1994
<20.5 mglkg
02/22/2022
Potassium
EPA 200.7, Rev. 4.4, 1994
2090 mg/kg
02/22/2022
Selenium
EPA 200.7, Rev. 4.4, 1994
<20.5 mg/kg
02/22/2022
Sodium
EPA 200.7, Rev_ 4.4, 1994
2500 mg/kg
02/22/2022
Zinc
EPA2007, Rev. 4.4, 1994
66.0 mg/kg
02/22/2022
Nitrate+Nitrite-Nitrogen
EPA353.2
5.61 mglkg
02/21/2022
-- Total Solids (%)
SM 2540 B
4.68 %
02/1812022
Ammonia Nitrogen
SM 4500 NH3 C-2011
581 mg/kg
02/22/2022
Total Kjeldahl Nitrogen (TKN)
SM 4500 Norg B-2011
33600 mg/kg
02/22/2022
Total Phosphorus
SM 4500 P (F-H)-2011
14600 mg/kg
02/23/2022
Report0t: 2022-03049
Page 2 of 4

A Ai
ANALYTICAL & CONSULTING CHEMISTS
Guilford East
1754 NC HWY 903
Kenansville NC
Attention: George Yankay
Environmental Chfists, Inc.
6602 Windmill Way, Wilmington, NC 28405 ° 910-392.OM Lab • 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 a 252.473.3702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
info@environmen to lchemists.corn
Date of Report: Mar 15, 2022
Customer PO #:
28349 Customer ID: 11030018
Report #: 2022-03049
Project ID: Sludge
pH SW 846 Method 90450
Result estimated. Anaiyzed out of 15 minutes hold time.
Mercury
TCLP Metals
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Mercury
Lab ID Sample ID:
22-07210 Site: Sample 1
SW-846 7471 B
EPA 200.7, Rev. 4.4, 1994
EPA 200.7, Rev. 4.4, 1994
EPA 200.7, Rev. 4.4, 1994
EPA 200.7, Rev. 4.4, 1994
EPA 200.7. Rev 4.4, 1994
EPA 200.7. Rev. 4.4, 1994
EPA 2007. Rev 4.4, 1994
EPA 245.1
Collect Date/Time
2/17/2022 9:00 AM
6.98 units 03/14/2022
<0.372 mg/kg 02118/2022
<1.0 mg/L
02/2812022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<1.0 mg/L
02/28/2022
<0.0002 mg/L
02/28/2022
Matrix Sampled by
Solid/Sludge Dale Johnson
Test Method Results Date Analyzes!
Total Solids (°!n) Sin 254€ B 2.50 % 02/18/2022
Fecal Density SM 9221C E-2014 80 MPN/g 02/17/2022
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-07211 Site: Sample 2 2/1712022 9:15 AM Solid/Sludge Dale Johnson
Test Method Results Date Analyzed
Total Solids {%) SM 2540 B 2.34 % 02/18/2022
Fecal Density SM 9221C E-2014 193 MPN/g 02/17/2022
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-07212 Site: Sample 3 2/17/2022 9.30 AM Solid/Sludge Dale Johnson
Test Method Results Date Analyzes)
Total Solids (%)
Fecal Density
SM 2540 B
SM 9221 C E-2014
2.43 % 02/18/2022
83 MPNIg 02/17/2022
Report : 2022-03049 Page 3 of 4

Guilford East
Date of Report: Mar 15, 2022
1754 NC HWY 903
Customer PO #:
Kenansville NC
28349 Customer ID: 11030018
Attention: George Yankay
Report 9: 2022-03049
Project ID: Sludge
Lab ID Sample ID:
Collect Date/Time Matrix Sampled by
22-07213 Site: Sample 4
2/17/2022 9:45 AM Solid/Sludge Dale Johnson
Test
Method Results Date Analyzed
Total Solids {p/p)
SM 2540 B 2.12 % 02/18/2022
Fecal Density
SM 9221C E-2014 213 MPN/g 02/17/2022
Lab ID Sample ID:
Collect Date/Time Matrix Sampled by
22-07214 Site: Sample 5
2/17/2022 10:00 AM Solid/Sludge Dale Johnson
Test
Method Results Date Analyzed
Total Solids (%)
SM 2540 B 2.28 % 02/18/2022
Fecal Density
SM 9221C E-2014 198 MPN/g 02/17/2022
Lab ID Sample ID:
Collect DateMme Matrix Sampled by
22-07215 Site: Sample 6
2/17/2022 10:15 AM Solid/Sludge Dale Johnson
Test
Method Results Date Analyzed
Total Solids (%)
SM 2W s 2.30 a/o 02118/2022
Fecal Density
SM 9221 C E-2014 B7MPN/g 02/17/2022
Lab ID Sample 1D:
Collect Date/Time Matrix Sampled by
22-07216 Site: Sample 7
2/17/2022 10:30 AM Solid/Sludge Dale Johnson
Test
Method Results Date Analyzed
Total Solids (%)
SM 2540 B 2.60 % 02/18/2022
Fecal Density
SM 9221C E-2014 77 MPN/g 02/17/2022
Comment: Sludge residual,
except pH, reported on a dry weight basis. pH reported on an as received basis.
Reviewed by:
Report #.' 2022-03049
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