WQ0004095_2022 Residual Annual Report_20230227 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0004095
Applicant/Permittee PCS Phosphate Company, Inc.
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Washington
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* James Chandler Stroud
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
2524026044
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0004095
Has Current Existing permit number
Applicant/Permittee Address*
1530 NC Highway 306 South
Facility Name*
PCS Phosphate Class B Residuals Program
Please provide comments/notes on your current submittal below.
Please see annual residuals report for 2022 calendar year.
Thank you!
Chandler Stroud
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Annual Report_Residuals Land Application
1.49MB
Program_WQ0004095 Final_Feb 2023.pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617

Signature
Submission Date 2/27/2023

,4utrien-
CERTIFIED MAIL
February 27, 2023
Division of Water Resources
Information Processing Unit/Non-Discharge Branch
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Subject: Permit #WQ0004095
PCS Phosphate Company, Inc.l
Residual Land Application Program
2022 Annual Report
Dear Mr. Thornburg,
As required by Condition IV.8 - Monitoring and Reporting Requirements, of the above
reference permit, attached is the Annual Residual Land Application Report for the 2022 calendar
year.
Please do not hesitate to contact me at (252)-402-6044 if I can answer any questions or provide
any additional information.
Sincerely,
James Char[dler Stroud
Supervisor, Environmental Affairs & Technical Services
Nutrien — Aurora
Attachments
PC: 12-04-01
ec: Lauren Raup-Plummer — DWR, NDB (w/attachments)
K.A. Alnandy (w/attachments)
B.S. Curtis (w/attachments)
L. D. Davis (w/attachments)
1530 NC Hwy 306 South, Aurora, NC USA 27806
1 Effective January 1, 2018, PCS Phosphate Company, Inc. is an indirect subsidiary of Nutrien Ltd. PCS Phosphate Company, Inc.
remains the legal operating entity and permittee.
nutrien.com

Residual Land Application Program
PCS Phosphate Company, Inc.
Aurora, NC
Permit No. WQ0004095
2022 Annual Report

Table Of Contents
1. Annual Land Application Certification Form (ACF)
2. Annual Residual Sampling Summary Form (RSSF) — A &B
3. Annual Metals Field Loading Summary Form (MFLSF)
4. Annual Land Application Field Summary Form (FSF)
5. Annual Pathogen & Vector Attraction Reduction Form (PVRF)
6. PVRF Records — Sludge Stabilization Form
7. Residuals Analysis Report — Element One, Inc.
8. Soil Analysis Results — NCDA&CS
9. Realistic yield Expectations Summary - NCSU
10. Monitoring & Reporting Requirements (Annual)

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0004095 County:
Beaufort
Year: 2022
Facility Name (as shown on permit): PCS Phosphate Company, Inc.
Land Application Operator: PCS Phosphate Company, Inc. Phone: [phone] x8391
Land application of residuals as allowed by the permit occurred during the past calendar year?
0 Yes ❑No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of ap2lication fields in the ermit: Two
Total number of fields utilized for land application during the year: One
Total amount of dry tons applied during the year for all application sites: 4.9994964
Total number of acres utilizes for land application during the year: 5.5
Part B - Annual Com fiance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. © Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied '(if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three
(3) copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T . 1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T. 1 105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
William M. Ponton, General Manager
Permittee Name and Title (type or print)
f
Signature of Permittee Date
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: PCs Phosphate Company, Inc. Total Dry Tons Applied (Annual): 5.00
Permit #: WQ0004095 Cation Exchange Capacity (non 503 only):
Operator: CS Phosphate Company, In Owner: Reserveco, Inc. Predominant Soil Series:
Acres Used: 5.5 Acres Permitted: 9.9 Site #: PCs Field #: PCs 01
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
fee -
Total
Phos-
phorusEENEMENEEMEN
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
ff 111
1 111
1 111 1 111
1 111
1 11
1 tl
1 11
1 111
1 111
1 111
1 111
1 111
1 111
111I
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1 1 1
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1 111
1 1
1 111
1 1
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1 111
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1 111
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1 111
MY, 11
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1 111
1 111
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1 111
1 111 1 111
1 11
1 111
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1 IltI
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1 111
1 11
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1 111
1 111
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1 111
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Total
Phos-
phorus
"i certify, uncler penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

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ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: PCS Phosphate Company, Inc.
WWTP Name: PCS Phosphate Company, Inc.
Monitoring Period: From l/1/2022 To
WQ Permit Number:
NPDES Number:
12/31/2022
WQ0004095
Non Discharge
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
1 Alt B (Alk Treatment) ❑
Alt. C (Prior Testing) ❑
Alt.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
d...........
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost [31
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray L31
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density [3Alt.
(2) Process to Significantly Reduce Pathogens [3..........,
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization p
Air Drying ❑ Composting ❑
jAerobic Digestion ❑
Anaerobic Dig estion
If applicable to alternative performed (Class A or Class B) complete the following
monitoring
data:
Parameter
Allowable Level
in Sludge
Pathogen Density
Number ot
Excee-
s
Frequency
of Analysis
Sample
Type
• na ytica
Tech -
niaue
MinimumGeo.
Mean
aximu
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform) I
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) -Please indicate alternative performed:
Alt.1 (VS reduction) ❑Alt. 2 (40-day bench) ❑klt. 3 (30-day bench) ❑�lt. 4 (Spec. 02 uptake) C
Alt. 5 (14-Day Aerobic) ❑Alt. 6 (Alk. Stabilization r❑klt 7 (Drying - Stable) ❑Alt. 8 (Drying - Unstable) C
Alt. 9 (Injection) ❑Alt. 10 (Incorporation) ❑Jo vector attraction reduction alternatives were performed C
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
William M. Ponton, General Manager
Pr arer N me and TiZ(tor print)
Signature of Preparer* Date
Land Applier Name and Title (if applicable)(type or print)
Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

lutrien-
Waste Water Treatment Plant (W`WTP)
Sludge Stabilization Form zDzz
*pH Is read in SU. Instrument ID- Oakton 300 serial # 459794 (temp and pH combo meter)
PH Meter Cal.
Date/ Time
Starting pH
Buff PH
*pH in SU
1.0= p t
pH Temp in °C
pH Meter Cal.
Date/ Time
After Lime
*pH in SU
4.0 =
pH Temp in 'C
7 0 = �j %� l
f 9
q-ZS
7.0=
12.45=7.0=
70Up1:lt'
Meter
1000= to•oy
19
Zozz
09'1�Meer
Buff H
Mfl
7ak
�9
7.0=
PH Acceptance Criteria +/- 0.1 su at 25 *C
Basin
Date
*pH in SU
starmig pH
Added �oixrd5
or Lime
After Lime pH
(Siud(jo)
Time
r< ti*pH in� rSU
� at+r.
Date ,
Z fl ,�.�
Tema "C
ql 9( 11
Temp C
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Signature &
Date �-
w

Chandler Stroud
Nutrien
1530 Hwy 306 South
Aurora, NC 27806
Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number e38349
April 15, 2022
Client Project Name: Bio Solids
Client PO Number. 2101171980
E1 Project Number e38349
Sample ID: Bio Solids
Sample Matrix SS
Sample Type
Grab
Date Received 03/31/2022
Date Sampled 03/30/2022
Time Sampled
0930
Time Received 1245
Delivered by FedEx
Sampler
Received by LLB
Extraction Begun 04/12/22 1600
Extraction
Ended
04/13/22 0900 E1 Sample # 38349 TCLP
Parameter
Result
Unit
Calc. RL Dilution
DL Method
Date
Chromium, TCLP digested
< 0.05
mg/L
0.05
50
0.001 EPA 131116020B
04/15/22
Arsenic, TCLP digested
< 0.05
mg/L
0.05
50
0.001 EPA 1311/6020B
04/15/22
Selenium, TCLP digested
< 0.05
mg/L
0.05
50
0.001 EPA 1311/6020B
04/15/22
Silver, TCLP digested
< 0.05
mg/L
0.05
50
0.001 EPA 1311/6020B
04/15/22
Cadmium, TCLP digested
< 0.05
mg/L
0.05
50
0.001 EPA 1311/6020B
04/15/22
Barium, TCLP digested
0.092
mg/L
0.05
50
0.001 EPA 1311/6020B
04/15/22
Lead, TCLP digested
< 0.05
mg/L
0.05
50
0.001 EPA 1311/60208
04/15/22
Mercury, TCLP digested < 0.0004
mg/L
0.0004
2
0.0002 EPA 1311/7470A
04/13/22
Solids
4.85
%
SM2540G
04/12/22
pH, Initial
11.80
SU
EPA 1311
04/12/22
Fluid Determination pH
3.05
SU
EPA 1311
04/12/22
TCLP pH, Final'
5.97
SU
EPA 1311
04/13/22
pH, Extraction Fluid ##1
4.92
SU
EPA 1311
04/12/22
Ken Smith, Laboratory Director
38349 Nutrien Report Packet Compiled by W11
Certifications: NJ NELAP NCO09 and NC DWQ DENR 604
Page 1 of 3

6319-D Carolina Beach Rd.
ell
Wilmington, NC 28412
Phone: [phone]
Pax: 910 792-6863
[e-mail]
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number e38349
Chandler Stroud April 15, 2022
Nutrien Client Project Name: Bio Solids
1530 Hwy 306 South Client PO Number. 2101171980
Aurora, NC 27806 Ell Project Number e38349
Sample ID: Bio Solids
Sample Matrix
SS
Sample Type
Grab
Date Received 03/31/2022
Date Sampled
03/30/2022
Time Sampled 0930
Time Received 1245
Delivered by
FedEx
Sampler
Received by LLB
E1 Sample # 38349 TOT
Parameter
Result
Result
Unit
Dilution
DL
Method
Date
As Received
Dry Basis
Sodium, Total
71.5
1474
mg/kg
100
0.2
EPA 3010/6020B
04/15/22
Magnesium, Total
176
3629
mg/kg
100
0.2
EPA 3010/6020B
04/15/22
Aluminum, Total
53.9
1111
mg/kg
100
0.01
EPA 301016020B
04/15/22
Phosphors, Total
455
9381
mg/kg
100
0.2
EPA 3010/6020B
04/15/22
Potassium, Total
89.7
1849
mg/kg
100
0.2
EPA 3010/6020B
04/15/22
Calcium, Total
11735
241959
mg/kg
1000
0.5
EPA 301016020E
04/15/22
Chromium, Total
0.805
1.75
mg/kg
10
0.01
EPA 301016020B
04/15/22
Nickel, Total
0.395
8.14
mg/kg
10
0.01
EPA 3010/6020B
04/15/22
Copper, Total
10.1
208
mg/kg
10
0.01
EPA 3010/6020B
04/15/22
Zinc, Total
82.3
1697
mg/kg
100
0.01
EPA 301016020E
04/15/22
Arsenic, Total
< 0.01
< 0.206
mg/kg
1
0.01
EPA 3010/6020B
04/15/22
Selenium, Total
0.025
0.515
mg/kg
1
0.01
EPA 3010/6020B
04/15122
Molybdenum, Total
0.327
6.74
mg/kg
1
0.01
EPA 3010/6020B
04/15122
Cadmium, Total
0.081
1.67
mg/kg
1
0.01
EPA 3010/6020B
04/15/22
Lead, Total
0.334
6.89
mg/kg
10
0.01
EPA 301016020B
04/15122
Mercury, Total
< 0.008
< 0.165
mg/kg
1
0.008
EPA 7471 B
04/12122
Solids
4.85
%
SM254OG
04/12/22
pH, as received
11.88
SU
EPA 9045D
04/14/22
-- V�L��
Ken it , Caboratory Director
Page 2 of
3
38349 Nutrien Report
Packet Compiled by—Vt
Certifications:
NJ NELAP NCO09 and NC DWQ
DENR 604
'I a fV71J ,, a riRUNUE L.ornp1rea oy Ayr
Certifications: NJ NELAP NCO09 and NC DWQ DENR 604

el,
elementOne
Chandler Stroud
Nutrien
1530 Hwy 306 South
Aurora, NC 27806
Sample Matrix
Date Sampled
Delivered by
Parameter
SS
03/30/2022
FedEx
Total Nitrogen-N
Nitrate+Nitrite-N
Kjeldahl Nitrogen, TKN
Ammonia as N
Organic Nitrogen-N
Solids
-PR !J (" I,-v)
Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number 938349
April 15, 2022
Client Project Name: Bio Solids
Client PO Number: 2101171980
E1 Project Number e38349
Sample ID: Bio Solids
Sample Type Grab Date Received 03/31/2022
Time Sampled 0930 Time Received 1245
Sampler Received by LLB
E1 Sample # 38349 TOT
Result
Result
Unit
Dilution
DL
Method
Date
As Received
Dry Basis
960
19794
mg/kg
5
5.5
EPA 300.0+4500NH3C
04/13/22
103
2124
mg/kg
5
0.5
EPA 300.0
04/04/22
857
17670
mg/kg
1
5.0
SM 4500 Nag C/NH3 D
04/13/22
78.4
1616
mg/kg
1
0.5
SM 4500 NH3 B&D
04/13/22
779
16054
mg/kg
1
0.5
calculation
04/13/22
4.85
%
SM2540G
04/12/22
3 Nos
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0. 00 ©'+ti
� I (r ?�N d r� -�
4��
Ken Smith, Laboratory Director Page 3 of 3
38349 Nutrien Report Packet Compiled by&LA
Certifications: NJ NELAP NCO09 and NC DWQ DEN 604

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IV.
MONITORING AND REPORTING REQUIREMENTS
I. The Permittee shall conduct and report any Division required monitoring necessary to evaluate this
program's impact on groundwater and surface water. [ 15A NCAC 02T .0108(c)]
2. The residuals from each source generating facility shall be analyzed to demonstrate they are non-
hazardous under the Resource Conservation and Recovery Act (RCRA). Residuals that test or are
classified as a hazardous or toxic waste under 40 CFR Part 261 shall not be land applied. The analyses
(i.e., corrosivity, ignitability, reactivity, and toxicity characteristic leaching procedure (TCLP)) shall be
performed at the frequency specified in Attachment A, and the Permittee shall maintain these results
for five years. Any exemptions from the requirements in this condition shall be specified in Attachment
A. The TCLP analysis shall include the following parameters, and the Federal regulatory level (ma)
is in parentheses:
Arsenic 1,4-Dichlorobenzene (7.5) Nitrobenzene (2.0)
Barium
Benzene
1,2-Dichloroethane (0.5)
1,1 Drichloroethylene (0.7)
Cadmium I 2,4-Dinitrotoluene (0.13)
Carbon tetrachloride (0.5)
Chlordane (0.03)
Chlorobenzene (100.0)
Chloroform (6.0)
Chromium (5.0)
m-Cresol (200.0)
o-Cresol (200.0)
p-Cresol (200.0)
Cresol (200.0)
Endrin (0.02)
Heptachlor (and its epoxide)
r0.008)
Hexachlorobenzene (0.13)
Hexachlorobutadiene (0.5)
Hexachloroethane (3.0) l
Lead (5.0)
Lindane (0.4)
Mercury (0.2)
Methoxychlor (10.0)
2,4-D (10.0) Methyl ethyl ketone (200.0)
Pentachlorophenol (100.0)
Pyridine (5.0)
Selenium (1.0)
Silver (5.0)
Tetrachloroethylene (0.7)
Toxaphene (0.5)
Trichloroethylene (0.5)
2,4,5-Trichlorophenol (400.0)
2,4,6-Trichlorophenol (2.0)
2,4,5-TP (Silvex) (1.0)
Vinyl chloride (0.2)
Croce the residuals have been monitored for two years at the frequency specified in Attachment A, the
Permittee may submit a permit modification request to reduce the frequency of this monitoring
requirement. In no case shall the monitoring frequency be less than once per permit cycle.
[15A NCAC 13A .0102(b), 02T .1101, 02T .1105]
WQ0004095 Version 4.0 Shell Version 190618 Page 8 of 12

3. The residuals from each source generating facility shall be analyzed at the frequency specified in
Attachment A, and the Permittee shall maintain the results for a minimum of five years. Each analysis
shall include the following parameters:
Aluminum
Ammonia -Nitrogen
Arsenic
Cadmium
Calcium
Copper
Lead — —
Magnesium
[15A NCAC 02T. 1101]
Mercury
Molybdenum
Nickel
Nitrate -Nitrite Nitrogen
Percent Total Solids
pH
Phosphorus
Plant Available Nitrogen
(by calculation)
Potassium
Selenium
Sodium
Sodium Adsorption Ratio
(SAR)
TKN
Zinc
4. Residuals shall be monitored for compliance with pathogen and vector attraction reduction
requirements at the frequency specified in Attachment A. The monitoring results shall specify the
stabilization process utilized, and demonstrate compliance with the Class B pathogen reduction
requirements in 15A NCAC 02T .1106(b), and one vector attraction reduction requirement in 15A
NCAC 02T .1107(a) shall be met. Any exemptions from the requirements in this condition shall be
specified in Attachment A. [15A NCAC 02T .1106(b), 02T .1107(a), 02T .1111(c)]
5. An annual representative soils analysis (i.e., Standard Soil Fertility Analysis) shall be conducted on
each land application site listed in Attachment B that received residuals during the calendar year. This
analysis shall be in accordance with the soil sampling guidance located in the Sampling Instructions
section of the NC Department of Agriculture & Consumer Services' website
(http://www.nr,agr.goy/agronomilgubs.html. The Permittee shall maintain these results for a period of
no less than five years, and these results shall be made available to the Division upon request. Each
Standard Soil Fertility Analysis shall include the following parameters:
Aciditv
Sodium
Base Saturation (by calculation) Magnesium
Calcium Manganese
Cation Exchange Capacity Percent Humic Matter
Copper pH
[15A NCAC 02T .0108(c), 15A NCAC 02T .1 I I l(d)]
Phosphorus
Potassium
Sodium
Zinc
6. Representative samples of residuals that are prepared for land application shall be collected and
analyzed. [ 15A NCAC 02T .11 l 1(a)]
WQ0004095 Version 4.0 Shell Version 1906I8 Page 9 of 12

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