WQ0008008_2022 Residual Annual Report_20230215 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0008008
Applicant/Permittee Pasquotank County
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Washington
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Drew Matthews
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
2528839301
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* Wastewater Irrigation High -Rate Infiltration
Other Wastewater Reclaimed Water
Closed -Loop Recycle Residuals
Single -Family Residence Wastewater Other
Irrigation
Permit Number:* WQ0008008
Has Current Existing permit number
Applicant/Permittee Address* PO Box 2245 Elizabeth City, NC 27909
Facility Name* Pasquotank County Class A Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Pasquotank County Annual Report.pdf 5AMB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
01f1 i �4e*A~
Submission Date 2/15/2023

PASQUOTANK COUNTY
2022 ANNUAL LAND APPLICATION OF
RESIDUAL BIOSOLIDS REPORT
CLASS A WTP RESIDUALS PROGRAM
WQ0008008
Submitted by:
Soil Plus
PO Box 1396
Oxford, NC 27565
February 15, 2023
SOIL PLUS

SOIL PLUS
February 15, 2023
NCDEQ-DWR
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Re: 2022 LAND APPLICATION ANNUAL REPORT
Pasquotank County DCAR
NC Permit No: WQ0008008
Soil Plus Project No: 201007.B11
Information Processing Unit:
Soil Plus, LLC (Soil Plus) is submitting all monitoring and reporting requirements as
specified in the above referenced permit for Pasquotank County. Soil Plus compiled this
report using data gathered during the compliance year. This data includes (1) a certification
form, (2) residual sampling summary, & (3) distribution & marketing summary form.
Pasquotank County prepared approximately 290,000 Gallons or 162.53 Dry Tons of Class
A Water Treatment Plant residuals from the Pasquotank County Regional WTP for land
application by Atlantic OBX during 2022. The residuals were distributed to farms in
Pasquotank County for agricultural uses.
If there is any further information required or questions regarding this annual report, please
do not hesitate to contact me or Pasquotank County (252-335-2240) for further assistance.
Respectfully,
Drew Matthews, Soil Plus
cc: David Smithson, Pasquotank County
J. Bryan Smith, Atlantic OBX
PO Box 1396
Oxford, NC 27565
[phone]
dmatthewsgsoilplus. ne t
www.soilplusuc.com

Pasquotank County
2022 Annual Land
Application of
Residual Bio s olid s
Report
Elizabeth City, NC
ANNUAL LAND
APPLICATION
CERTIFICATION FORM
ANNUAL RESIDUAL
SAMPLING SUMMARY
FORM
Nutrients
503 Metals
TCLP
ANNUAL
DISTRIBUTION AND
MARKETING
CERTIFICATION AND
SUMMARY FORM

PASQUOTANK COUNTY
2022 Class A WTP Annual Report
WQ Permit# WQ0008008
Annual Certification Form
Source Summary

ANNUAL LAND APPLICATION CERTIFICATION FORM
PermitNumber FacilityName Land Application Operator County Phone Number
WQ0008008 Pasquotank County DCAR David Smithson Pasquotank [phone]
Year: 2022
Land application of residuals as allowed by the permit occurred during the past calendar year? If No, skip Part A, and Yes No
Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how
the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit: N/A
Total number of fields utilized for land application during the year: N/A
Total amount of dry tons applied during the year for all application sites: 162.53
Total number of acres utilizes for land application during the year: N/A
Part B - Annual Compliance Statement:
Facility was compliant during calendar year with all conditions of the land application permit? Yes No
Including but not limited to items 1-13 below) issued by the Division of Water Quality 0 ❑
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory
results are attached
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of
certified laboratory results are attached
6.The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T
7. All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated
facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated
facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was
received from the Division of Water Quality
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to
include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations."
David Smithson, Utilities Director
Permittee Name and Title (type or print): Sign ture of a ee Date
Same as Permittee a. 2/15/23
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)

Source Summary Report
WWTP
Pasquotank County Regional WTP
VolumeApplied tal Dry Tons
290,000 Gallons 162.53
Total 162.53

PASQUOTANK COUNTY
2022 Class A WTP Annual Report
WQ Permit# WQ0008008
Residual Sampling Summary Form — Pasduotank County Regional WTP
Field Loading Calculations
2022 Analytical
2022 TCLP

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&AGMAN FIELD LOADING ESTIMATES
Facility Pasquotank County Regional WTP
Sampling Date 2/2/2022
Solids 13.44
Mineralization Rate 0
Gallons per DT 1,784.29
pH 8.4
Sodium Absorpotion 0.79 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 1,930 lbs./1,000 gal 2.16
Ammonia Nitrogen (mg/Kg) 41.90 lbs./1,000 gal 0.05
Nitrate -Nitrite (mg/Kg) 19.95 lbs./1,000 gal 0.02
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 41 lbs./1,000 gal 0.05
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 62 lbs./1,000 gal 0.07
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
K20 lbs./1,000 gal 0.67
P205 lbs./1,000 gal 16.50
Calcium lbs./1,000 gal 24.56
Magnesium lbs./1,000 gal 2.34
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.01
HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.50
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
11.00
Copper lbs./1,000 gal
0.01
Lead (mg/Kg)
5.20
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.04
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
5.00
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.00
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
19.00
Zinc lbs./1,000 gal
0.02
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
1,930
41 0.08
1,889
1,930
62 0.12
1,868
1,889
0 0.00
1,889
1,868
0 0.00
1,868
1,889
0 0.00
1,889
1,868
0 0.00
1,868
1,889
0 0.00
1,889
1,868
0 0.00
1,868
1,889
0 0.00
1,889
1,868
0 0.00
1,868
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 41 0.08
Total 62 0.12

EmAnDERM % WOO TpumA
114 OAKMONT DRIVE
GREENVILL E, N.C. 2785€3
PASQUOTANK CO. WATER (SLUDGE)
MR. MICHAEL L. HARRIS
1.466 WEVKSVILLE ROAD
ELIZABETH CITY, NC 27909
PARAMETERS
PH (not to be used for reporting)
Aluminum, (dry wt. basis), mg/kg
Arsenic (dry wt. basis), mg/!cg
Calcium (dry wt. basis), mg/kg
Cadmium (dry wt. basis), mg/kg
Copper (dry wt. basis), mg/lcg
Chromium, T.(dry wt. basis),mg/Icg
Lead (dry weight basis), mg/kg
Magnesium (dry wt. basis), mg/kg
Mercury (dry wt. basis), mg/kg
Nickel (dry wt. basis), mg/kg
Potassium (dry wt, basis), mg/kg
Selenium (dry wt. basis), mg/kg
Sodium (dry wt. basis), mg/lcg
Zinc (dry wt. basis), mg/kg
Total Solids,
TKN (dry wt.), mg/lcg
Ammonia Nitrogen (dry wt.),mg/Icg
Phosphorus, T. (dry wt.), mg/kg
Nitrate+Nitrite (dry wt.), mg/kg
Plant Available Nitrogen, mg/kg
Molybdenum (dry wt. basis), mg/lcg
Water Plant Analysis Method
Sludge Date Analyst Code
8.4
02/02/22
CAW
4500HB-11
4593
02/08/22
LFJ
EPA200.7
<2.5
02/10122
MTM
311313r04
21911
02/08/22
LFJ
EPA200.7
<0.5
02/08/22
MTM
3113E-04
11
02/08/22
LFJ
EPA200.7
10
02/08/22
LFJ
EPA200.7
5.2
02/09/22
MTM
3113B-04
2092
02/08/22
LFJ
EPA200.7
<0.04
02/10/22
MTM
EPA7471B
<5.0
02/08/22
LFJ
EPA200.7
<500
02109/22
LFJ
EPA200.7
<5.0
02/11/22
MTM
3113B-04
< 1250
02108/22
LFJ
EPA200.7
19
02/08/22
LFJ
EPA200.7
13.44
02/03/22
BLV
2540G-15
c 1930
02/08/22
TRJ
351.2 R2-93
c 41.90
02/08/22
KES
350.1 R2-93
c 6427
02/08/22
BMD
365.4-74
c 19.95
02/09/22
TRJ
353.2 R2-93
796
02/15/22
MAO
<5.0
02/08/22
LFJ
EPA200.7
Drinking water iD: 37715
wastewater ID: 10
PHONE [phone]
FAX [phone]
ID#: 149
DATE COLLECTED: 02/02/22
DATE REPORTED : 03/01/22
REVIEWED BY:
c Uncertified data. DWR does not offer non -aqueous certification for this analytical procedure.

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SGS,
Orlando, FL
The results set fortis herein are provided by SGS North Atnerieti lnc. e- ardcojq 2' d
Aut(niia€ed Repo1.2
Technical Deport for
Environment 1, Inc
Pasquotank Co Water; 1466 Weeksville Rd, Elizabeth City, NC
ME
SGS Job Number: FA92936
Sampling Date: 02/02/22
Report to:
Environment 1, Inc
PO Box 7085
Greenville, NC 27835
[e-mail]
TTN: Ann. Brown
Total number of pages in report: 1.4
e
'rest results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Norm Farmer
Technical Director
Client Service contact: Jean Dent -Smith 407-425-6700
Certifications; FL(E83510), G.A(03051), KS(E-10327), NC(573), N7(FL002), NY(12022), SC(96038001)
DoD FLAP(ANAS L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(65-03573), VA(460177),
AL, AK, Ail, CT, W KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, Wl, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGs,
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32911 • tel: [phone] - fax: [phone]
SGS it the sole :authority Col. authorizi€1g calits nr nmdifloatiaw., to this tlocutneat. Ncasc share gout i6eas abllut i of i+
Umiuthorizcd moditiration of this report is strictly lirnhibited. how tvt: t'an serve you Kett". at: _.. --

Sections:
1, ble or' Contents
Section1: Sample Summary................................................................................................... 3
Section2: Summary of Hits.................................................................................................... 4
Section 3: Sample, Rena lts...........>.,a............s............... ............
3.1. FA92936-1: WATER PLANT SLUDGE.... ............................ ...... .................... ......... 6
3.2. FA92936-1L: WATER PLANT SLUDGE ............................................ ............... 7
Section4: Misc. Forms ............................................................................................................ 12
4.1: Chain of Custody........................................................................................................... 13

SGS North America Inc.
Sample Summary
Environment 1, Inc
Soh No: F'A92936
Pasquotank Co Water; 1466 Weeksville Rd, Elizabeth City, NC
Project No: 149
Sample
Collected
Matrix
Client
Number
Date Time By
Received Code Type
Sample ID
if i$ re'por contains results iepoxied as -ND - Not doected„The following applies:
Organics ND = Not detected above the MDL
FA92936-1 02/02/22 09:00 AW 02/07/22 SO Sludge WATER PLANT SLUDGE
FA92936-IL 02/02/22 09:0.0 AW 02/07/22 SO Sludge WATER PLANT SLUDGE
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
H
" 3 of 1�
.. vim. _...

Summary of Hits
Job Number:
FA92936
Account:
Environment 1, Inc
Project:
Pasquotank Co Water; 1466 Weeksville Rd, Elizabeth City, NC
Collected-
02/02/22
Lab Sample ID Client Sample Tl7 Result/
Aualyte Qual RL MDL Units Method
FA92936-1 'WATER PLANT SLUDGE
Corrosivity as pH 8.3
Ignitability (Flashpoint) a > 200
F'A92936-IL WATER PLAINT SLUDGE
No hits reported in this sample.
(a) Not ignitable.
Page l of 1
su SW846 CHAP7
Deg. F SW846 1020C MOD
4 of 1,
_ ._

Orlando, FL
Sample Results
Report of Analysis
�. .._..q ..._ .
. ml�
tF

SGS North America Inc.
Report of Analysis
Client Sample ID: WAFER PLANT SLUDGE
Lab Sample ID: FA92936-1 Date Sampled: 02/02/22
Matrix: SO - Sludge Date Received: 02/07/22
Percent Solids: 25.6
Project: Pasquotank Co Water; 1466 Weeksville Rd, Elizabeth City, NC
General Chemistry
Analyte
Corrosivity as pH
Cyanide Reactivity
Ignitability (Flashpoint) a
Solids, Percent
Sulfide Reactivity
(a) Not ignitable
RL = Reporting Limit
Page 1 of 1`
Result
RL Units DF
Analyzed
By
Method
8.3
su 1
02/11/22 09:58
n
SW846 CHAP7
< 5.9
5.9 mg/kg 1
02/28/22 10:24
AC
SW846 CHAP7
> 200
Deg. F 1
02/10/22 14:30
RA
SW846 1020C MOD
25.6
% 1
02/16/22 19:14
AK
SM19 2540G
< 19
19 mg/kg I
02116/22 15:10
is
SW846 CHAP7
6ofi�

SGS North America Inc.
Report of Analysis
Client Sample TD: WATER PLANT SLUDGE
Lab Sample 1D: FA92936-IL Date Sampled: 02/02/22
Matrix: SO - Sludge Date Received: 02/07/22
Method: SW846 8260D SW846 1311 Percent Solids: 25.6
Project: Pasquotank Co Water; 1466 Weeksville Rd, Elizabeth City, NC
Page L of I P
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run 91 2P8553I.D 10 02/09/22 19:52 CF 02/08/22 13:00 OP89629 V2P3394
Run ##2
Purge Volume
Run ##1 5.0 tnt
Run 02
VOA TCLP List
CAS No.
Compound
Result
HW##
MCL RL
71-43-2
Benzene
ND
D018
0.50 0.010
78-93-3
2-Butanone (MEK)
ND
D035
200 0.050
56-23-5
Carbon Tetrachloride
ND
DO19
0.50 0,010
108-90-7
Chlorobenzene
ND
D021
100 0.010
67-66-3
Chloroform
ND
D022
6.0 0.010
106-46-7
114-Dichlorobenzene
ND
D027
7.5 0.010
107-06-2
1,2-Dichloroethane
ND
D028
0.50 0.010
75-35-4
1,1-Dichloroethylene
ND
D029
0.70 0.010
L27-18-4
Tetrachloroethylene
ND
D039
0.70 0.010
79-01-6
Trichloroethylene
ND
D040
0.50 0.010
75-01-4
Vinyl Chloride
ND
D043
0.20 0.010
CAS No.
Surrogate Recoveries
Rung i
Run# 2
Limits
1868-53-7
Dibromofluoromethane
99%
83-118%
17060-07-0
1,2-Dicbloroethane-D4
103%
79-125%
2037-26-5
Toluene-D8
94%
85-112%
460-00-4
4-Bromofluorobenzene
100%
83-118%
TCLP Leachate method SW846 1311
MDL
Units Q
0.0031
mg/1
0.020
mg/l
0.0036
mg/1
0.0020
mg/1
0.0030
mg/1
0.0026
mg/1
0.0031
mg/i
0.0032
rng/l
0.0022
mg/1
0.0035
rng/I
0.0041
mg/i
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
MCL = Maximum Contamination Level (40 CFR 261 7/1/11) B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7af1=
_..,

SGS North America Inc.
Report of Analysis
,lient Sample ID: WATER PLANT SLUDGE
,alb Sample ID: FA92936-IL Date Sampled: 02/02/22
Matrix: SO - Sludge Date Received: 02/07/22
Method: SW846 82701, SW846 3510C Percent Solids: 25.6
"rof ect: Pascluotank Co Water; 1466 Weeksville Rd, Elizabeth City, NC
Page 1 of 1
Tile ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F13315.D 1 02/18/22 22:52 WH 02/18/22 12:00 OP89832 S6F496
Run #2
Initial Volume Final Volume
Run #1 10,O ml 1.0 m1
Run #2
ABN TCLP List
CAS No.
Compound
Result
HW#
MCL
RL
95-48-7
2-Metbylphenol
ND
D023
200
0.50
3&4-Mothylphenol
ND
D024
200
0.50
87-86-5
Pentachlorophenol
ND
D037
100
2.5
95-95-4
2,4,5-Trichlorophenol
ND
D041
400
0.50
88-06-2
2,4,6-Trichlorophenol
ND
D042
2.0
0.50
106-46-7
1,4-Dichlorobenzene
ND
D027
7.5
0.50
121-14-2
2,4-Dinitrotoluene
ND
D030
0.13 0.50
118-74-1
Hexachlorobenzene
ND
D032
0.13 0.50
87-68-3
Hexachlorobutadiene
ND
D033
0.50 0.50
67-72-1
Hexachloroethane
ND
D034
3.0
0.50
98-95-3
Nitrobenzene
ND
D036
2.0
0.50
110-96-1
Pyridine
ND
D038
5.0
1.0
CAS No.
Surrogate Recoveries
Run# I
Run# 2
Limits
367-12-4
2-Fluorophen01
34%
14-67%
4165-62-2
Phenol-d5
24%
10-50%
118-79-6
2,4,6-Tribromophenol
75%
33-118%
4165-60-0
Nitrobenzene-d5
69%
42-108%
321-60-8
2-Fluorobiphenyl
72%
40-106%
1718-51-0
Terphenyi-d14
84%
39-121%
T'CLP Leaehate method SW846 1311
MDL
Units Q
0.056
mg/l
0.098
mg/l
0.50
mgll
0.074
mg/1
0.075
mg/l
0.050
mg/l
0.081
mg/I
0.069
mg/I
0.050
mg/1
0.16
mg/l
0.093
Ong/1
0.20
rng/l
ND = Not detected MVL = Method Detection Limit J = Indicates an estimated value
MCL = Maximum Contamination Level (40 CFR 261 7/1/11) B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
CAM 1 -.. 8of1,

SGS North America Inc.
Report of Analysis
Client Sample ID; WATER PLANT SLUDGE
Lab Sample ID: FA92936-1I, Date Sampled: 02/02/22
Matrix: SO - Sludge Date Received: 02/07/22
Method: SW846 9151A SW846 3510C Percent Solids: 25.6
Project: Pasgvotank Co Water; 1466 Weeksville Rd, Elizabeth City, NC
Page I of 1
Rile Ill DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 CCO80211.1) 1 02/20/22 2152 NJ 02/18/22 12:00 OP99827 GCC2022
Run 42
Initial Volume Final Volume
Run 91 10.0 ml 5.0 ml
Run #2
Herbicide TCLP List
TCLP Leachate method SW846 011
CAS No,
Compound
Result
HW#
MCL RL
MDL Units Q
94-75-7
2,4-D
ND
D016
10 0.050
0.017 mg/1
93-72-1
2,4,5-TP (Silvex)
ND
D017
1.0 0,0050
0.0013 :ng/l
CAS No.
Surrogate Recoveries
Run,# 1
Run# 2
Limits
19719-28-9
2,4-DCAA
95%
39-135%
ND — Not detected MDL = Method Detection Limit J = Indicates an estimated value
MCL — Maximum Contamination Level (40 CFR 261 7/1It 1) B — Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N — Indicates presumptive evidence of a compound
0 of 1•
--

SGS North America Inc.
Report of Analysis
Client Sample ID: WATER PLANT SLUDGE
Lab Sample ID: 1;A92936-1L Date Sampled: 02/02/22
Matrix: SO - Sludge Date Received: 02/07/22
Method: SW846 8081B SW846 3510C Percent Solids: 25.6
Project: Pasquotank Co Water; 1466 Weeksvilie Rd, Elizabeth City, NC
Page 1 of I
Pile 1D Di< Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 ST159863.D l 02118/22 19.38 WH 02/18/22 13:30 OP89833 GST3889
Run 92
Initial Volume Final Volume
Run #1 [00 mI 5.0 ml
Run #2
Pesticide TCLP List
TCLP Leachate method SW846 1311
CAS No.
Compound
Result
HW#
MCL RL
MDL
Units Q
58-89-9
gamma-BHC (Lindane)
ND
D013
0.40 0.00010
0.000022
►ng/1
12789-03-6
Chlordane
ND
D020
0.030 0,0010
0.00038
mg/1
72-20-8
Endrin
ND
D012
0.020 0.00020
0.000021
mg/1
76-44-8
Heptachlor
ND
D031
0.0080 0.00010
0.000026
mg/l
1024-57-3
Heptachlor epoxide
ND
D031
0.0080 0..00010
0.000020
mg/1
72-43-5
Methoxychlor
ND
D014
10 0.00020
0.000050
mg/1
8001-35-2
Toxaplrene
ND
D015
0.50 0.0050
0.0021
mg/1
CAS No,
Surrogate Recoveries
Run# 1
Run# 2
Limits
977-09-8
Tetrachloro-m-xylene
125%
42-127%
2051-24-3
Decachlorobiphenyl
115%
27-127%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated valuo
MCL = Maximum Contamination Level (40 Cl"R 261 7/1/11) B Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 1,

SGS North America Inc.
Report of Analysis Page 1 of 1
'lient Sample ID: WATER PLANT SLUDGE
,ab Sample 1D: FA92936- IL Date Sampled: 02/02/22
Matrix: SO - Sludge Date Received: 02/07/22
Percent Solids: 25.6
'roject: Pasquotank Co Water; 1466 Weeksville Rd, Elizabeth City, NC
Metals Analysis, TCLP Leachate SW846 1311
Analyte
Result
HW##
MCL
RL
Units
DF
Prep
Analyzed By
Method
Prep Method
Arsenic
< 0.10
D004
5.0
0.10
mg/I
1
02/15/22
02/16/22
LM
SW846 601OD 2
SW846 3010A 4
Barium
<2.0
D005
100
2.0
mg/1
1
02/15/22
02/16/22
LM
SW8466010D2
SW8463010A4
Cadmium
<0,050
D006
1.0
0.050
mg/1
1
02/15/22
02/16/22
Lm
SW946 6010D 2
SW846 301OA 4
Chromium
<0.10
D007
5.0
0.10
mg/l
1
02/15/22
02/16/22
LM
SW846 6010D 2
SW846 3010A 4
Lead
< 0.050 .
D008
5.0
0.050
mg/1
1
02/15/22
02/16122
LM
SW846 6010D 2
SW846 3010A 4
Mercury
< 0-0050
D009
0.20
0.0050
mg/1
1
02/16/22
02/16/22
JC
SW846 7470A t
SW846 7470A 5
Selenium
< 0.50
D010
1.0
0.50
mg/1
5
02/15/22
02117/22
LM
SW846 6010D 3
SW846 301OA 4
Silver
<0.10
D011
5.0
0.10
txm/1
1
02/15/22
02/16/22
T-m
SW846 6010D 2
SW846 3010A 4
(1) Instrument QC Batch: MAI8461
(2) Instrument QC Batch: MA18463
(3) Instrument QC Batch: MA18466
(4) Prep QC Batch: MP40294
(5) Prep QC Batch: MP40301
RL = Reporting Limit
MCL = Maximum Contamination Level (40 CFR 261 711/11)
---. 1._.. 11 of 1

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Orlando FL
Section 4
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
C
12of1,

Ed
Environment 1, Inc. CHAIN OF CUSTODY RECORD
P.O. Box 7085, 114 Oakmont Dr. 1 I
Greenvil.lc, NC 27853 Page __ of _
I
enviromnent l ine .cam
Phone [phone] •Fax [phone]
DISIN FECf1OhI
Cit CRINE NEUTRAUZEDA7 =LECT6IN
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ASQUOTANK CO. WATFR (SLUDGE)
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CHEMICAL PRESERVATION
166 WESKSVILLE ROAD
LIZABRTJRCITYNC. 27409
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157)330-4e06
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DATE
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PLEASE RE140 instrlrclicns for GOD)ptat{t1g this corm an the reverse s1de. Na 8998�44 1
znRse �s Grab sample in the blocks shave {or each parameter Eeaussted.
FA92936: Chain of Custody
Page ! of 2
r 13 of 1.

Job Number: PA92936
SGS Sample Receipt Summary
Client: ENVIRONMENT 1. INC
Project: PASQUOTANK CO. WATER (SLUDGE)
Data/ Time Received: 217/2022 9:15:00 AM Delivery Method: FEDEX Airbill Ws: 5230 2508 4527
Therm ID: IR4;
Therm CF: 0.5;
�
# of Coolers: 1
Cooler Temps (Raw Measured) "C:
Cooler 1: (4.2):
Coofer Temps (Corrected) `C;
Cooler 1: (4.8);
Cooler informatian Y
or N
amnle Information
_
Y or N_
N1A
1. Custody Seals Present ©
1. Sample labeis present an betties
©
❑
2. Custody Seals Intact 0
©
2. Samples preserved properly
❑
3. Temp criteria achieved
❑
3. Sufficient volumelcontainers recvd for analysis;
®
[
4. Cooler terng verification IR Gun
4. Condition of sample
lntaes
5. Cooler media Ica iBao)
5. Sample recvd within HT
❑W
❑
8_ DatesfrimesllDs on COG match Sample Lahel
©
❑
E min Stank Information _ --
or N -N(A
7. VOCs have headspaca
❑
©
[]y
1. Trip Blank present! cooler ❑
❑ []
8. Bottles received for unspecified tests
❑
2. Trip Blank Wed an COG ❑
© ©
9. Composiling instructions clear
❑
W
or S N1A
10. We Sal KitWars received past 48hrs?
ID
❑
3. Type Of TB Received ❑
[]
11. % Solids Jar received?
❑
©
0
12. Residual Chlorine present?
❑
©
�
Misc. Information
Number of Encores: 25-Gram 5-Gram Number of 5035 Field lets:
Test Strip Lot tis: pH 0-3 230315 pH 10.12 2t9813A
Residual Chlorine Test Strip Lot M
Comments
stsot
Rev. Data 551311}7 Technician: SAMUELM Date: 2A12022 9:15:00 AM Revier we.
Number of Lab Filtered Metals:
Other: (Specify)
Hate:
Fr-92936; Chain of Custodv
Page 2 of 2
'__ 14 of 1•

PASQUOTANK COUNTY
2022 Class A WTP Annual Report
WQ Permit# WQ0008008
Annual Distribution and Marketing Certification Summary Form

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