WQ0035720_2022 Residual Annual Report_20230201 (2)

Initial Review
Reviewer
Thornburg, Nathaniel D
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0035720
Applicant/Permittee Denali Water Solutions LLC
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Jeff Retzke
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
2565034300
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* Wastewater Irrigation High -Rate Infiltration
Other Wastewater Reclaimed Water
Closed -Loop Recycle Residuals
Single -Family Residence Wastewater Other
Irrigation
Permit Number:* WQ0035720
Has Current Existing permit number
Applicant/Permittee Address* 3308 Bernice Avenue, Russellville, AR 72802
Facility Name* Denali Water Solutions Class A Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Lake Kilby WTP annual report.pdf 2.33MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/1/2023

0
Denali
WATER SOLUTIONS
February 1, 2023
3308 Bernice Avenue
Russellville, AR 72802
PO Box 3036 • Russellville, AR 72811
Phone: [phone]
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: 2022 Annual Report - Distribution of Class A Residuals: Denali Water
Solutions (Lake Kilby Water Treatment Plant) Permit No. WQ0035720
To Whom it May Concern:
Denali Water Solutions is submitting the required 2022 Annual Report for Permit No.
WQ0035720. This permit is associated with the distribution of water treatment residuals
produced at the City of Portsmouth - Lake Kilby Water Treatment Plant located in Suffolk,
Virginia, with distribution in Gates County, North Carolina.
This Annual Report contains the following information:
• Form DMSDF
• Form RSSF
• Lab Reports
If you have any questions, or need any additional information, please do not hesitate to
contact me at [phone] or via email at ieff.retzke0denaliwater.com.
Sincerely,
Jeff Retzke
Director of Environmental Services, Southeast
cc: Richard Hurr (Water Plant Manager, City of Portsmouth, Virginia)

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Waypointo
ANALYTICAL
10/11 /2022
Denali Water
Jeff Retzke
1001 Fraser Ave
Huntsville, AL, 35801
Ref: Analytical Testing
Report Number: 22-271-0004
Project Description: Lake Kirby WTP 2022 1 &2
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Dear Jeff Retzke:
Waypoint Analytical Virginia, Inc. received sample(s) on 9/28/2022 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information
Sincerely,
�aw,'c MC G19"./
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

•
7621 Whitepine Road, Richmond, VA 23237
Waypoint
Main 804-743-9401 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-271-0004
Client Project Description: Lake Kirby WTP 2022 1&2
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
59522
1
Solids
59522
1
Solids
59522
1
Solids
59522
1
Solids
59522
1
Solids
59522
1
Solids
59522
1
Solids
59522
1
Solids
59522
1
Solids
59523
2
Solids
59523
2
Solids
59523
2
Solids
59523
2
Solids
59523
2
Solids
59523
2
Solids
59523
2
Solids
59523
2
Solids
59523
2
Solids
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
09/26/2022
11:00
09/28/2022
4500NO3F-2011
WP MTN
SW-7471B
WP MTN
SM-4500-NH3C
WP MTN
6010D
WP MTN
SM-2540G
WP MTN
AOAC 955.01
WP MTN
9045D
WP MTN
SM-4500-NH3C-TKN
WP MTN
SM-4500-NH3C-TKN
WP MTN
SM-4500-NH3C
WP MTN
SM-2540G
WP MTN
4500NO3F-2011
WP MTN
AOAC 955.01
WP MTN
9045D
WP MTN
SW-7471B
WP MTN
6010D
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 2 of 8

Waypointo
ANALYTICAL
07274
Denali Water
Project
Jeff Retzke
1001 Fraser Ave
Information
Huntsville , AL 35801
Report Number : 22-271-0004
Lab No : 59522
Sample ID : 1
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Lake Kirby WTP 2022 1&2
REPORT OFANALYSIS
Report Date : 10/11/2022
Received : 09/28/2022
0Awl[ � Grow
Pauric Mc Groary Ph.D., CPA
Agronomist
Matrix: Solids
Sampled: 9 / 26/ 2022 11:00
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Total Solids
17.0
%
0.010
Calcium
1040
mg/Kg -
dry
294
Iron
17400
mg/Kg -
dry
58.8
Aluminum
194000
mg/Kg -
dry
294
Zinc
50.9
mg/Kg -
dry
7.35
Chromium
101
mg/Kg -
dry
1.47
Arsenic
11.9
mg/Kg -
dry
2.94
Mercury
<0.829
mg/Kg -
dry
0.829
Test
Sodium Absorption Ratio
Ammonia Nitrogen
Organic N
Phosphorus
Cadmium
Copper
Lead
Manganese
Nickel
Selenium
Qualifiers/ DF Dilution Factor
Definitions
Results Units
<5.88
747
15310
900
<0.588
46.6
14.4
1080
9.12
5.64
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
MQL
5.88
588
1471
29.4
0.588
2.94
1.76
2.94
1.47
2.94
1
10/03/2215:26
FMM
SM-2540G
1
10/07/22 01:35
EAL
6010D
1
10/07/22 01:35
EAL
6010D
10
10/10/22 23:07
EAL
6010D
1
10/07/22 01:35
EAL
6010D
1
10/07/22 01:35
EAL
6010D
1
10/07/22 01:35
EAL
6010D
1
10/04/22 13:13
TJS
SW-7471B
DF
Date / Time
By
Analytical
Analyzed
Method
1 10/07/22 01:35 CALCULATION
1 10/05/22 13:45 JPJ SM-4500-NH3C
1 10/04/22 10:00
CALCULATION
1 10/07/22 01:35
EAL
6010D
1 10/07/22 01:35
EAL
6010D
1 10/07/22 01:35
EAL
6010D
1 10/07/22 01:35
EAL
6010D
1 10/07/22 01:35
6010D
1 10/07/22 01:35
EAL
6010D
1 10/07/22 01:35
EAL
6010D
MQL Method Quantitation Limit
Page 3 of 8

•
0
Waypoint
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
ANALYTICAL
www.waypointanalytical.com
07274
Denali Water
Project
Lake Kirby WTP 2022 1&2
Jeff Retzke
Report Date : 10/11/2022
1001 Fraser Ave
Information : Received : 09/28/2022
Huntsville , AL 35801
�oau� �� Grow
Pauric Mc Groary Ph.D., CPA
Report Number : 22-271-0004
REPORT OFANALYSIS
Agronomist
Lab No : 59522
Matrix: Solids
Sample ID : 1
Sampled: 9/26/2022 11:00
Test
Results
Units MQL DF Date / Time By Analytical
Analyzed Method
Sulfur
22500
mg/Kg - dry 588 10 10/07/22 16:19 TJS 6010D
Analytical Method: SM-2540G
Test
Results
Units MQL DF Date / Time By Analytical
Analyzed Batch
Moisture
83.0
% 0.010 1 10/03/2215:26 FMM L641008
Total Kjeldahl Nitrogen
16100
mg/Kg -
dry
1470
1
10/04/22 10:00
JPJ
;M-4500-NH3C-TKI`
Potassium
126
mg/Kg -
dry
58.8
1
10/07/22 01:35
EAL
6010D
Magnesium
771
mg/Kg -
dry
29.4
1
10/07/22 01:35
EAL
6010D
Sodium
217
mg/Kg -
dry
147
1
10/07/22 01:35
EAL
6010D
Nitrate+Nitrite-N
<25.6
mg/Kg -
dry
25.6
1
09/30/22 14:55
CLP
4500NO3F-2011
pH
6.7
S.U.
1
10/03/2214:19
SAR
9045D
Calcium Carbonate Equivalent
19.1
%
0.1
1
10/05/22 13:00
DXT
AOAC 955.01
Total Volatile Solids
46.2
%
0.010
1
10/03/22 15:26
FMM
SM-2540G
Molybdenum
1.61
mg/Kg -
dry
1.47
1
10/07/22 01:35
EAL
6010D
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 4 of 8

•
7621 0 Whitepine Road, Richmond, VA 23237
Waypoint
Main 804-743-9401 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
07274
Denali Water Project Lake Kirby WTP 2022 1&2
Jeff Retzke
Report Date : 10/11/2022
1001 Fraser Ave
Information
:
Received : 09/28/2022
Huntsville , AL 35801
�oau� �� Grow
Pauric Mc Groary Ph.D., CPA
Report Number : 22-271-0004
REPORT OFANALYSIS
Agronomist
Lab No : 59523
Matrix:
Solids
Sample ID : 2
Sampled:
9/26/2022 11:00
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Method
Total Kjeldahl Nitrogen
9430
mg/Kg - dry
1420
1
10/04/22 10:00
JPJ ;M-4500-NH3C-TKI`
Aluminum
184000
mg/Kg - dry
284
10
10/10/22 23:12
EAL 6010D
Manganese
835
mg/Kg - dry
2.84
1
10/07/22 01:40
EAL 6010D
Copper
35.4
mg/Kg - dry
2.84
1
10/07/22 01:40
EAL 6010D
Cadmium
<0.568
mg/Kg - dry
0.568
1
10/07/22 01:40
EAL 6010D
Lead
13.1
mg/Kg - dry
1.70
1
10/07/22 01:40
EAL 6010D
Calcium Carbonate Equivalent
17.7
%
0.1
1
10/05/22 13:00
DXT AOAC 955.01
Total Volatile Solids
46.6
%
0.010
1
10/03/22 15:26
FMM SM-2540G
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Method
Sodium Absorption Ratio
<5.68
mg/Kg -
dry
5.68
1
10/07/22 01:40
CALCULATION
Ammonia Nitrogen
631
mg/Kg -
dry
568
1
10/05/22 13:45
JPJ
SM-4500-NH3C
Nitrate+Nitrite-N
<27.0
mg/Kg -
dry
27.0
1
09/30/22 14:56
CLP
4500NO3F-2011
pH
6.3
S.U.
1
10/03/2214:19
SAR
9045D
Molybdenum
1.63
mg/Kg -
dry
1.42
1
10/07/22 01:40
EAL
6010D
Potassium
112
mg/Kg -
dry
56.8
1
10/07/22 01:40
EAL
6010D
Sodium
212
mg/Kg -
dry
142
1
10/07/22 01:40
EAL
6010D
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 5 of 8

•
7621 0 Whitepine Road, Richmond, VA 23237
Waypoint
Main 804-743-9401 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
07274
Denali Water Project Lake Kirby WTP 2022 1&2
Jeff Retzke Report Date : 10/11/2022
1001 Fraser Ave Information : Received : 09/28/2022
Huntsville , AL 35801
�oau� �� Grow
Report Number : 22-271-0004 REPORT OFANALYSIS Pauric Mc Groary Ph.D., CPA
Agronomist
Lab No : 59523
Sample ID : 2
Matrix: Solids
Sampled: 9/26/2022 11:00
Total Solids
17.6
%
0.010
1
10/03/22 15:26
FMM
SM-2540G
Moisture
82.4
%
0.010
1
10/03/2215:26
FMM
SM-2540G
Phosphorus
881
mg/Kg -
dry
28.4
1
10/07/22 01:40
EAL
6010D
Sulfur
21100
mg/Kg -
dry
568
10
10/07/22 16:25
TJS
6010D
Calcium
1010
mg/Kg -
dry
284
1
10/07/22 01:40
EAL
6010D
Magnesium
676
mg/Kg -
dry
28.4
1
10/07/22 01:40
EAL
6010D
Iron
18100
mg/Kg -
dry
56.8
1
10/07/22 01:40
EAL
6010D
Zinc
47.4
mg/Kg -
dry
7.10
1
10/07/22 01:40
EAL
6010D
Organic N
8801
mg/Kg -
dry
1420
1
10/04/22 10:00
CALCULATION
Chromium
111
mg/Kg -
dry
1.42
1
10/07/22 01:40
EAL
6010D
Nickel
8.69
mg/Kg -
dry
1.42
1
10/07/22 01:40
EAL
6010D
Arsenic
12.0
mg/Kg -
dry
2.84
1
10/07/22 01:40
EAL
6010D
Mercury
<0.852
mg/Kg -
dry
0.852
1
10/04/22 13:17
TJS
SW-7471B
Selenium
5.80
mg/Kg -
dry
2.84
1
10/07/22 01:40
EAL
6010D
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 6 of 8

WayPAoInt..
NALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 07274
Customer Name: Denali Water
Report Number: 22-271-0004
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IDavid Lennon Date & Time: 09/28/2022 08:50:41
Page 7 of 8

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Waypointo
ANALYTICAL
10/20/2022
Denali Water
Jeff Retzke
1001 Fraser Ave
Huntsville, AL, 35801
Ref: Analytical Testing
Report Number: 22-285-0002
Project Description: Lake Kilby WTP 2022 1 &2
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Dear Jeff Retzke:
Waypoint Analytical Virginia, Inc. received sample(s) on 10/12/2022 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information
Sincerely,
�aw,'c MC G19"./
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

•
7621 Whitepine Road, Richmond, VA 23237
Waypoint
Main 804-743-9401 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-285-0002
Client Project Description: Lake Kilby WTP 2022 1&2
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
59623
3
Solids
10/11/2022
11:00
10/12/2022
59623
3
Solids
10/11/2022
11:00
10/12/2022
59623
3
Solids
10/11/2022
11:00
10/12/2022
59623
3
Solids
10/11/2022
11:00
10/12/2022
59623
3
Solids
10/11/2022
11:00
10/12/2022
59623
3
Solids
10/11/2022
11:00
10/12/2022
59623
3
Solids
10/11/2022
11:00
10/12/2022
59623
3
Solids
10/11/2022
11:00
10/12/2022
59623
3
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
59624
4
Solids
10/11/2022
11:00
10/12/2022
4500NO3F-2011
WP MTN
SW-7471B
WP MTN
SM-4500-NH3C
WP MTN
6010D
WP MTN
SM-2540G
WP MTN
AOAC 955.01
WP MTN
9045D
WP MTN
SM-4500-NH3C-TKN
WP MTN
SM-4500-NH3C-TKN
WP MTN
SM-4500-NH3C
WP MTN
SM-2540G
WP MTN
4500NO3F-2011
WP MTN
AOAC 955.01
WP MTN
9045D
WP MTN
SW-7471B
WP MTN
6010D
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 2 of 9

Waypointo
ANALYTICAL
07274
Denali Water
Project
Jeff Retzke
1001 Fraser Ave
Information
Huntsville , AL 35801
Report Number : 22-285-0002
Lab No : 59623
Sample ID : 3
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Lake Kilby WTP 2022 1&2
REPORT OFANALYSIS
Report Date : 10/20/2022
Received : 10/12/2022
0Awl[ Grow
Pauric Mc Groary Ph.D., CPA
Agronomist
Matrix: Solids
Sampled: 10/ 11/2022 11:00
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Total Solids
16.6
%
0.010
Calcium
946
mg/Kg -
dry
301
Iron
19200
mg/Kg -
dry
60.2
Aluminum
187000
mg/Kg -
dry
301
Zinc
45.8
mg/Kg -
dry
7.53
Chromium
99.4
mg/Kg -
dry
1.51
Arsenic
9.82
mg/Kg -
dry
3.01
Mercury
<0.819
mg/Kg -
dry
0.819
Test
Sodium Absorption Ratio
Ammonia Nitrogen
Organic N
Phosphorus
Cadmium
Copper
Lead
Manganese
Nickel
Selenium
Qualifiers/ DF Dilution Factor
Definitions
Results Units
<6.02
<602
21140
867
<0.602
37.7
5.08
861
8.86
5.26
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
mg/Kg - dry
MQL
6.02
602
1506
30.1
0.602
3.01
1.81
3.01
1.51
3.01
1
10/13/2215:57
FMM
SM-2540G
1
10/17/22 22:19
EAL
6010D
1
10/17/22 22:19
EAL
6010D
10
10/18/22 13:02
EAL
6010D
1
10/17/22 22:19
EAL
6010D
1
10/17/22 22:19
EAL
6010D
1
10/17/22 22:19
EAL
6010D
1
10/14/22 12:09
TJS
SW-7471B
DF
Date / Time
By
Analytical
Analyzed
Method
1 10/17/22 22:19 CALCULATION
1 10/19/22 15:30 JPJ SM-4500-NH3C
1 10/19/22 11:15
CALCULATION
1 10/17/22 22:19
EAL
6010D
1 10/17/22 22:19
EAL
6010D
1 10/17/22 22:19
EAL
6010D
1 10/17/22 22:19
EAL
6010D
1 10/17/22 22:19
EAL
6010D
1 10/17/22 22:19
EAL
6010D
1 10/17/22 22:19
EAL
6010D
MQL Method Quantitation Limit
Page 3 of 9

•
0
Waypoint
7621 Whitepine
Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
ANALYTICAL
www.waypointanalytical.com
07274
Denali Water
Project
Lake Kilby WTP 2022 1&2
Jeff Retzke
Report Date : 10/20/2022
1001 Fraser Ave
Information :
Received : 10/12/2022
Huntsville , AL 35801
�oau� �� Grow
Pauric Mc Groary Ph.D., CPA
Report Number : 22-285-0002
REPORT OFANALYSIS
Agronomist
Lab No : 59623
Matrix: Solids
Sample ID : 3
Sampled: 10/11/2022 11:00
Test
Results
Units MQL
DF Date / Time By Analytical
Analyzed Method
Sulfur
19300
mg/Kg - dry 60.2
1 10/17/22 22:19 EAL 6010D
Analytical Method: SM-2540G
Test
Results
Units MQL
DF Date / Time By Analytical
Analyzed Batch
Moisture
83.4
% 0.010
1 10/13/2215:57 FMM L643032
Total Kjeldahl Nitrogen
21100
mg/Kg -
dry
1510
1
10/19/22 11:15
JPJ
;M-4500-NH3C-TKI`
Potassium
135
mg/Kg -
dry
60.2
1
10/17/22 22:19
EAL
6010D
Magnesium
570
mg/Kg -
dry
30.1
1
10/17/22 22:19
EAL
6010D
Sodium
227
mg/Kg -
dry
151
1
10/17/22 22:19
EAL
6010D
Nitrate+Nitrite-N
<25.5
mg/Kg -
dry
25.5
1
10/17/22 15:26
CLP
4500NO3F-2011
pH
6.1
S.U.
1
10/19/2210:39
SAR
9045D
Calcium Carbonate Equivalent
1.5
%
0.1
1
10/17/22 11:15
DXT
AOAC 955.01
Total Volatile Solids
48.2
%
0.010
1
10/13/22 15:57
FMM
SM-2540G
Molybdenum
1.97
mg/Kg -
dry
1.51
1
10/17/22 22:19
EAL
6010D
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 4 of 9

•
7621 0 Whitepine Road, Richmond, VA 23237
Waypoint
Main 804-743-9401 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
07274
Denali Water Project Lake Kilby WTP 2022 1&2
Jeff Retzke
Report Date : 10/20/2022
1001 Fraser Ave
Information
:
Received : 10/12/2022
Huntsville , AL 35801
�oau� �� Grow
Pauric Mc Groary Ph.D., CPA
Report Number : 22-285-0002
REPORT OFANALYSIS
Agronomist
Lab No : 59624
Matrix:
Solids
Sample ID : 4
Sampled:
10/11/2022 11:00
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Method
Total Kjeldahl Nitrogen
9710
mg/Kg - dry
1460
1
10/19/22 11:15
JPJ ;M-4500-NH3C-TKI`
Aluminum
191000
mg/Kg - dry
292
10
10/18/22 13:07
EAL 6010D
Manganese
877
mg/Kg - dry
2.92
1
10/17/22 22:25
EAL 6010D
Copper
39.9
mg/Kg - dry
2.92
1
10/17/22 22:25
EAL 6010D
Cadmium
<0.585
mg/Kg - dry
0.585
1
10/17/22 22:25
EAL 6010D
Lead
4.63
mg/Kg - dry
1.75
1
10/17/22 22:25
EAL 6010D
Calcium Carbonate Equivalent
3.2
%
0.1
1
10/17/22 11:15
DXT AOAC 955.01
Total Volatile Solids
47.3
%
0.010
1
10/13/22 15:57
FMM SM-2540G
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Method
Sodium Absorption Ratio
<5.85
mg/Kg -
dry
5.85
1
10/17/22 22:25
CALCULATION
Ammonia Nitrogen
807
mg/Kg -
dry
585
1
10/19/22 15:30
JPJ
SM-4500-NH3C
Nitrate+Nitrite-N
<29.1
mg/Kg -
dry
29.1
1
10/17/22 15:27
CLP
4500NO3F-2011
pH
5.9
S.U.
1
10/19/2210:39
SAR
9045D
Molybdenum
1.90
mg/Kg -
dry
1.46
1
10/17/22 22:25
EAL
6010D
Potassium
135
mg/Kg -
dry
58.5
1
10/17/22 22:25
EAL
6010D
Sodium
235
mg/Kg -
dry
146
1
10/17/22 22:25
EAL
6010D
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 5 of 9

•
7621 0 Whitepine Road, Richmond, VA 23237
Waypoint
Main 804-743-9401 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
07274
Denali Water Project Lake Kilby WTP 2022 1&2
Jeff Retzke Report Date : 10/20/2022
1001 Fraser Ave Information : Received : 10/12/2022
Huntsville , AL 35801
�oau� �� Grow
Report Number : 22-285-0002 REPORT OFANALYSIS Pauric Mc Groary Ph.D., CPA
Agronomist
Lab No : 59624
Sample ID : 4
Matrix: Solids
Sampled: 10/11/2022 11:00
Total Solids
17.1
%
0.010
1
10/13/22 15:57
FMM
SM-2540G
Moisture
82.9
%
0.010
1
10/13/2215:57
FMM
SM-2540G
Phosphorus
889
mg/Kg -
dry
29.2
1
10/17/22 22:25
EAL
6010D
Sulfur
21200
mg/Kg -
dry
58.5
1
10/17/22 22:25
EAL
6010D
Calcium
988
mg/Kg -
dry
292
1
10/17/22 22:25
EAL
6010D
Magnesium
608
mg/Kg -
dry
29.2
1
10/17/22 22:25
EAL
6010D
Iron
18500
mg/Kg -
dry
58.5
1
10/17/22 22:25
EAL
6010D
Zinc
49.7
mg/Kg -
dry
7.31
1
10/17/22 22:25
EAL
6010D
Organic N
8901
mg/Kg -
dry
1462
1
10/19/22 11:15
CALCULATION
Chromium
105
mg/Kg -
dry
1.46
1
10/17/22 22:25
EAL
6010D
Nickel
9.06
mg/Kg -
dry
1.46
1
10/17/22 22:25
EAL
6010D
Arsenic
9.01
mg/Kg -
dry
2.92
1
10/17/22 22:25
EAL
6010D
Mercury
<0.784
mg/Kg -
dry
0.784
1
10/14/22 12:13
TJS
SW-7471B
Selenium
<2.92
mg/Kg -
dry
2.92
1
10/17/22 22:25
EAL
6010D
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 6 of 9

Waypointo
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Client: Denali Water CASE NARRATIVE
Project: Lake Kilby WTP 2022 1 &2
Lab Report Number: 22-285-0002
Date: 10/19/2022
Metals Analysis Method 601 OD
Sample 59624 (4)
Analyte: Aluminum
QC Batch No: 1-643884/1-643140
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 59624 (4)
Analyte: Iron
QC Batch No: 1-643695/1-643140
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 59624 (4)
Analyte: Sulfur
QC Batch No: 1-643695/1-643140
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 7 of 9

WayPAoInt..
NALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 07274
Customer Name: Denali Water
Report Number: 22-285-0002
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IDavid Lennon Date & Time: 10/12/2022 08:00:08
Page 8 of 9

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REPORT OF ANALYSIS
CLIENT:
Pancopia
REPORT NO: 22-16407 1 1:03
ATTN:
Bill Cumbie
GRAB COLLECTION:
ADDRESS:
1100 Exploration Way, Suite 302
Date: 9/28/2022 Time: 0750
.REED,,,
Hampton, VA 23666
COMPOSITE COLLECTION:
�sdCtA��v
PHONE:
757-344-8607
Start Date: Time:
EMAIL:
[e-mail]
End Date: Time:
Special Notes:
RE: PORTSMOUTH LAGOON
SAMPLE ID: DEW SOLIDS
SAMPLE NO: 22-16407
SAMPLE RECEIPT:
Date: 9/29/2022 Time: 0800
Method
JRA
Parameter
Number
QL
Result
Unit
Analyst
Date
Time
% TS
*2540G
0.1
16.8
%
JAM
9/30/2022
1600
Benzene
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
Carbon Tetrachloride
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
Chlorobenzene
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
Chloroform
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
1,4-Dichlorobenzene
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
1,2-Dichloroethane
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
1, 1 -Dichloroethylene
8260D
5
<5
ug/L
ARP
10/14/2022
0022
Methyl ethyl Ketone
8260D
10
< 10
ug/L
ARP
10/14/2022
0022
Tetrachloroethylene
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
Trichloroethylene
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
Vinyl Chloride
8260D
5
< 5
ug/L
ARP
10/14/2022
0022
o-Cresol
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
m/p-Cresol
8270E
20
<20
ug/L
CLH
10/11/2022
1835
Cresol
8270E
20
< 20
ug/L
CLH
10/11/2022
1835
2,4-Dinitrotoluene
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
Hexachlorobenzene
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
Hexachloro-1,3-butadiene
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
Hexachloroethane
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
Nitrobenzene
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
Pentachlorophenol
8270E
100
< 100
ug/L
CLH
10/11/2022
1835
Pyridine
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
2,4,5-Trichlorophenol
8270E
25
<25
ug/L
CLH
10/11/2022
1835
James R. Reed & Associates
VELAP# 460013
770 Pilot House Drive, Newport News, VA 23606
EPA# VA00015
[phone] 0 Fax: [phone]
_s
Page 1 of 3

�.s:
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REPORT OF ANALYSIS
SAMPLE ID: DEW SOLIDS
SAMPLE NO: 22-16407
Method
JRA
Parameter
Number
QL
Result
Unit
Analyst
Date
Time
2,4,6-Trichlorophenol
8270E
25
<25
ug/L
CLH
10/11/2022
1835
Lindane
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
Heptachlor (+epoxide)
8270E
5
< 5
ug/L
CLH
10/11/2022
1835
Endrin
8270E
5
< 5
ug/L
CLH
10/11/2022
1835
Methoxychlor
8270E
25
< 25
ug/L
CLH
10/11/2022
1835
Chlordane
8270E
25
<25
ug/L
CLH
10/11/2022
1835
Toxaphene
8270E
100
< 100
ug/L
CLH
10/11/2022
1835
2,4-D
8151A
4
<4
ug/L
MJD
10/12/2022
0137
2,4,5-TP
8151A
4
<4
ug/L
MJD
10/12/2022
0137
Silver
6010D
0.010
< 0.010
mg/L
JMH
10/17/2022
1145
Arsenic
6010D
0.050
< 0.050
mg/L
JMH
10/17/2022
1145
Barium
6010D
0.500
< 0.500
mg/L
JMH
10/17/2022
1145
Cadmium
6010D
0.005
< 0.005
mg/L
JMH
10/17/2022
1145
Chromium
6010D
0.010
0.018
mg/L
JMH
10/17/2022
1145
Mercury
7470A
0.0002
< 0.0002
mg/L
JAM
10/18/2022
1004
Lead
6010D
0.050
< 0.050
mg/L
JMH
10/17/2022
1145
Selenium
6010D
0.050
< 0.050
mg/L
JMH
I0/17/2022
1145
Organic Nitrogen
351.2/4500NH
148
6067
mg/Kg
JMH
10/18/2022
1557
Ammonia
*4500NH3D
592
<592M
mg/Kg
JAM
10/11/2022
1230
Total Nitrogen
351.2/353.2
148
6067
mg/Kg
JMH
10/18/2022
1557
Nitrate/Nitrite
353.2
0.29
< 0.29
mg/Kg
AAH
10/5/2022
1417
Total Kjeldahl Nitrogen
351.2
148
6067
mg/Kg
ACS
10/14/2022
0928
Total Aluminum
6010D
27.1
201487
mg/Kg
JMH
10/13/2022
1508
Total Arsenic
6010D
2.71
< 2.71
mg/Kg
JMH
10/13/2022
1348
Total Cadmium
6010D
0.271
1.03
mg/Kg
JMH
10/13/2022
1348
Total Copper
6010D
0.543
35.0
mg/Kg
JMH
10/13/2022
1348
Total Lead
6010D
2.71
< 2.71
mg/Kg
JMH
10/13/2022
1348
Mercury
7471B
0.058
< 0.058
mg/kg
JAM
10/12/2022
1242
Total Molybdenum
6010D
2.71
< 2.71
mg/Kg
JMH
10/13/2022
1348
Total Nickel
6010D
2.71
7.58
mg/Kg
JMH
I0/13/2022
1348
Total Selenium
6010D
2.71
< 2.71
mg/Kg
JMH
10/13/2022
1348
Total Zinc
6010D
2.71
30.6
mg/Kg
JMH
10/13/2022
1348
% TVS
*2540G
0.1
47.3
%
JAM
9/30/2022
1600
James R. Reed & Associates
770 Pilot House Drive, Newport News, VA 23606
[phone] 0 Fax: [phone]
Page 2 of 3
VELAP# 460013
EPA# VA00015

REPORT OF ANALYSIS
SAMPLE ID: DEW SOLIDS
SAMPLE NO: 22-16407
Method JRA
Parameter Number QL Result Unit Analyst Date Time
NOTES:
JRA Quantification Level is the concentration of the lowest calibration standard above zero with a reliable signal.
Reproduction of this report is not permitted, except in full, without written approval from James R Reed & Associates.
The results on this report relate only to the sample(s) provided for analysis and conform to TNl standards unless otherwise indicated.
Chain of Custody attached.
*SM 2011
M- Matrix spike % recovery outside QC acceptance range
James R. Reed & Associates
770 Pilot House Drive, Newport News, VA 23606
[phone] 0 Fax: [phone]
Page 3 of 3
RESPECTFULLY SUBMITTED
P"l Elaine Claiborne
Laboratory Director
Date: 19-Oct-22
VELAP# 460013
EPA# VA00015