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HomeMy WebLinkAboutWQ0000601_Inspection_20080725I County: RICHMOND River Basin Report To FROAP Collector: B TODD Region: FRO Sample Matrix: GROUNDWATER Loc. Type: WATER SUPPLY Emergency Yes/No - COC Yes/No Yes Location ID: 6P077WQ0000601 NC DWQ Laboratory Section Wesufts Sample ID: AB38176 �F. WArFy ¢G� PO Number # Date Received: 8G1551 11/26/2008 � � �� � Ct�l : Time Received: 08:20 �u o Y Labworks LoginlD HPARKER g� DEC .' J Zoos 1. 1� Date Reported: 12/17/08 Report Generated: 12/17/2008 OENR-FAYEMILLEREGIONALOFFlCE VisitlD Loc. Descr.: CSX TRANSPORTATION INC ' rl� / j l V a Collect Date: 11/25/2008 Collect Time:: 11:15 Sample Depth Sample Qualifiers and Comments Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwqlab.org under Staff Access A -Value reported is the average of two or more determinations N3-Estimated concentration is < PQL and >MDL B1-Countable membranes with <20 colonies; Estimated NE -No established PQL B2- Counts from all filters were zero. P-Elevated PQL due to matrix interference and/or sample dilution - B3- Countable membranes with more than 60 or 80 colonies; Estimated Q1-Holding time exceeded prior to receipt at lab. B4-Filters have counts of both >60 or 80 and < 20; Estimated 85-Too many colonies were present; too numerous to count (TNTC) Q2- Holding time exceeded following receipt by lab PQL- Practical Quantitation Limit -subject to change due. to instrument sensitivity J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated U- Samples'analyzed for this compound but not detected J3-The sample matrix interfered with the ability to make any accurate determination; Estimated XI- Sample not analyzed for this compound J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated NI -The component has been tentatively identified based on mass spectral library search and has an estimated value I AR Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 5 - - NC WQQ .Laboratory Section Resultsoau�Nioiv H6J8-1/C Location ID: 6PO77W00000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:15 Visit ID CAS # Analyte Name PQL Result Qualifier Units Analyst/Date Approved By /Date LAB Sample temperature at receipt by lab 1.7 °C DSAUNDERS HPARKER Method Reference 11/26/08 11/26/08 Me. TOC in liquid 2.0 2 U J8 mg/L BSWANSON CGREEN Method Reference APHA5310B-20th 12/4108 12/9/08 WET Total Dissolved Solids in liquid 12 47 mg/L AWILLIAMS CGREEN Method Reference APHA254OC-18TH 11/26/08 12/3/08 MET 7440-38-2 As by ICPMS 5.0 2.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7440-38-3 Ba by ICP 10 10 U ug/L DSTANLEY ESTAFFORD Method Reference EPA 200.7 12/1/08 12/17/08 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/2/08 12/17/08 7440-47-3 Cr by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7439-92-1 Pb by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 VOL Volatile Organics in liquid TITLE_ ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-78-1 Dichlorodifluoromethane 1.0 - Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/09 1211/08 74-87-3 Chloromethane 0.50 Not detected ug/L ATERRY WELLING Method, Reference EPA5030/62418260 11/26/08 12/1108 75-01-4 Vinyl Chloride 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 74-83-9 Bromomethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-00-3 Chloroethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-69-4 Trichlorofluoromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-35-4 1,1-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 5 XC DWQQ Laboratory Section ResultsSample ID AB38175 Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:15 Visit ID 75-09-2 Methylene Chloride 10 Not detected ug/L ATEKKY KKELLINU Method Reference EPA5030/624/8260 11/26/08 1211/08 156-60-5 trans-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 1211/08 1634-04-4 Methyl Tert-Butyl Ether 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 75-34-3 1,1-Dichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 156-59-4 cis-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1108 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 67-66-3 Chloroform 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 590-20-7 .2,2-Dlchloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 107-06-2 1,2-Dichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 71-55-6 1,1,1-Tiichloroethane - 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11%26/08 12/1/08 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08. 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 71-43-2 Benzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 74-95-3 Dibromomethane 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11126/08. 1211/08 78-87-5 1,2-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 79-01-6 Trichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1/08 75-27-4 Bromodichloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 10061-01-5 cis-1,3-Dichloropropehe 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 Laboratory. Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 . Page 3 of 5 XC DWQ Laboratory Section Results Sample lD aB38175 Location ID: 6PO77W00000601 Collect Date: 11/26/2008 Loc. Descr.: CSX-TRANSPORTATION INC Collect Time:: 11:15 Visit ID CAS # Analyte Name POL Result Qualifier Units Anarysvuate Approves i3y /uate 10061-02-6 trans-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 79-00-5 1,1,2-Trichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 . 108-88-3 . Toluene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 142-28-9 1,3-Dichloropropane 0.25 Not detected ug/L _ ATERRY RKELLING Method Reference ` EPA5030/624/8260 11/26/08 1211/08 124-48-1 Dibromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 106-93-4 (EDB)1,2-Dibromoethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 127-18-4 Tetrachloroethene 0.25 Not detected ug/L . ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 108-90-7 Chlorobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 100-41-4 Ethylbenzene 0.25 Not detected ug/L ATERRY RKELLING - Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-25-2 Bromoform 1.0 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 . 108-38-3 . m,p-Xylene 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08. 12/1/08 100-42-5 Styrene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 630-20-6 1,1,1,2-Tetrachloroethane 0.25 Not detected ug/L - ATERRY RKELLING Method Reference EPA50301624/8260 11/26/08 1211/08 95-47-6 o-Xylene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA8030/624/8260 11/26/08 12/1/08 96-18-4 1,2,3-Trichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 _ . 98-82-8 Isopropylbenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 108-86-1 Bromobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC-27699-1623 (919) 733-3908 . Page 4 of 5 NC (DWQ Laboratory Section Results Sample D AB38175 Location ID: 6PO77WQ0000601 Collect Date: 11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:15 Visit ID 103-65-1- , n-Propylbenzene 0.25. Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 95-49-8 2-Chlorotoluene 0.25 Not detected ug/L . ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1/08 106-43-4 4-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 108-67-8 1,3,5-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 1211/08 98-06-6 tert-Butylbenzene 0.25 Not detected. ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 95-63-6 . •1,2,4-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 135-98-8 sec-Burylbenzene 0.25 Not detected ug/L - ATERRY WELLING Method Reference EPA5030/624/8266 11/26/08 12/1108 543-7.3-1 m-Dichlorobenzene (1,3) 0.25 Not detected. ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 106-46-7. p-Dichlorobenzene (1,4) 0.25 Not detected , ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 95-50-1 o-Dichlorobenzene (1;2) 0.25 Not detected ug/L ATERRY -WELLING Method Reference EPA50301624/8260 11/26/08 1211/08 99-87-6. p-Isopropyltoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 104-51-8 n-Burylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 1211/08 96-12-8 1,2-Dibromo-3-Chloropropane 2.0 , Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 120-82-1 1,2,4-Trichlorobenzene 0.50 Not detected : ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211108 91-20-3 . Naphthalene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 1211/08 87-68-3 Hexachlorobutadiene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 87-61-6 1,2,3-Trichlorobenzene 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 VOC'S BY GC/MS Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 North Carolina I GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY -GROUNDWATER SECTION Location code 6P077W00000601 County_Rich Quad No Serial No Lat. Long._ Report To: ARCED MRO, RRO, WaRO, WiRO, -WSRO, Kinston FO. Fed. Trust, Central Off., Other: Shipped by: Bus, ourle Hand Del., Other: Purpose: Collector(s): Date 27/ ' Time I IIS Baseline, Cor FIELD ANALYSES / / Owner C JX 4 pH 400 = 33 Spec. Cond.94 t,G . at 25°C Location or Site Temp.lo t °C Odor Pac ,� Description of sampling poi Appearance Sampling Method SAMPLE TYPE ® Water ❑ Soil El Other ® Chain of Custodv SAMPLE PRIORITY K Routine ❑ Emergency Field Analysis By: I ARnRATnRY ANALYS S BOD 310 mg/L COD High 340 mg/L COD Low 335 mg/L Coliform: MF Fecal 31616 /100mI Coliform: MF Total 31504 /1oom1 X TOC 680 mg/L Turbidity 76 NTU Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 mg/L Carbonate 445 mg/L Bicarbonate 440 mg/L Carbon dioxide.405 mg/L Chloride 940 mg/L Chromium: Hex 1032 ug/L Color: True 80 Cu Cyanide 720 mg/L 11 Lab Comments X Diss. Solids 70300 mg/L Fluoride 951 mg/L Hardness: Total 900 mg/L Hardness (non-carb) 902 mg/L Phenols 32730 ug/I Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Grease mg/L NH3 as N 610 mg/L TKN as N 625 mg/L NO2 + NO3 as N 630 mg/L P: Total as P 665 mg/L Nitrate (NO3as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7103 For Dissolved Analysis -submit filtered sample and write "DIS" in block. mW Lab Number �G J��� l JU t3617� d Date Received Time: 0 .l Rec'd By: From:Bus, ourier Hand Del., Other: Data Entry By: Ck: Date Reported: ;omplianpe LUST,_ Pesticide Study, Federal Trust, Other: Sample Interval (Pumping time, air temp., etc.) Ag-Silver 46566 u /L AI -Aluminum 46557 u /L X As -Arsenic 46551 u /L X Ba-Barium 46558 u /L Ca -Calcium 46552 m /L X Cd-Cadmium 46559 u /L X Cr-Chromium 46559 u /L Cu-Copper 46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 m /L Mg -Magnesium 46554 m /L Mn-Manganese 46566 u /L Na-Sodium 46556 m /L Ni-Nickel u /L X Pb-Lead 46564 u /L Se -Selenium u /L Zn-Zinc 46567 u /L Or anochlorine Pesticides Or ano hos horus Pesticides Nitrogen Pesticides Acid Herbicides PCBs Semivolatile Organics TPH-Diesel Range Volatile Organics(VOA bottle TPH-Gasoline Range TPH-BTEX Gasoline Range LAB USE ONLY Temperature on arrival (°C): '- Report to: —FROAP Lab Number: AB38175 Station Location: CSX TRANSPORT- ATION INC NC DENR/DWQ Laboratory Sample Anomaly Report (SAR) Sample ID: 6PO77WQ0000601 County: RICHMOND Region: FAYETTEVILLE Sample Type: WATER SUPPLY Priority: Collector: B TODD Date collected: 11/25/08 Date received: 11/26/08 Date analyzed: 12/04/08 Affected Parameter(s): $AE— MC, Analytical Area (check one): ❑WCH ❑META LS ❑NUT ®MICRO The following anomalies occurred (check all that apply): ❑Samples ❑Improper container used ❑VOA vials with headspace ❑Sulfide samples with headspace ❑Samples not received, but listed on fieldsheet ❑Samples received, but not listed on fieldsheet ❑Mislabeled as to tests, preservatives, etc. ❑Holding time expired ❑Prior to receipt in lab ❑After receipt in lab ❑Insufficient.quantity for analysis ❑Sample exhibits gross non -homogeneity ❑Sample not chemically preserved properly ❑pH out of range (record pH):. ❑Improper chemical ❑Residual chlorine present in sample ❑Color interference ❑Heavy emulsion formed during extraction ❑Sample bottle broken in lab - no reportable results ❑VOA ❑SVOA ❑PEST ❑Quality Control ❑Instrument failure — no reportable results ❑Analyst error— no reportable results ❑Surrogates ❑None added ❑Recovery outside acceptance limits ❑Spike recovery ❑None added ❑Recovery outside acceptance limits ❑Failed to meet criteria for precision ❑Internal standards ❑Blank contamination ❑QC data reported outside of controls (e.g., QCS, LCS) ❑Incorrect procedure used ❑SOP intentionally modified with QA and Branch Head approval ❑Invalid instrument calibration ❑Elevated detection limits due to: ❑Insufficient sample volume ®Other (specify):Temperature limit exceeded during storage, the data may not be accurate: Comments: The cooler used to store samples malfunctioned during the night of 12/3/08. This sample registered a below freezing temperature. Corrective Action:The samples were removed from storage and the cooler maintenanced ❑Samples were rejected by DWQ Lab. Authorized by: Date: ❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured. ❑S'arnple(s) on Bold until: ®Sample reported with qualification. Data qualification code used:J8 ❑Other (explain): Notification Required? ❑ Yes ❑ No Person Contacted: Date: Form completed by: jBeth Swanso Date: 12/8/2008 Lead Chemist Revie (initial): ❑BIOCHEM ❑PEST ❑METALS ❑VOA Branch Head Review (initial • 1 2A/QC Review (ini ' QA\Fonns\Laboratory\SAR ❑SVOA Logged into database by (initial):_ IZlo9/2�>Y 10/23/01 dbs .,, 9VC DM Laboratory Section c esults County ' RICHMOND Sample ID: AB38176 River Basin' W AT OFh> O� PO Number # Received: 8G1552 Report To FROAP� . Date 11/26/2008 ���� Imo, Time Received: 08:20 Collector: B TODD i� �y - Labworks LoginlD HPARKER Region: FRO 9 ZQQg EE Date Reported: 12/17/08 Sample Matrix: GROUNDWATER Loc. Type: WATER SUPPLY Report Generated: 12/17/2008 Emergency Yes/No LREGICTIALOWE visitlD COC Yes/No Yes / Loc. Descr.: CSX TRANSPORTATION INC Location ID: 6PO77W00000601 Collect Date: 11/26/2008 Collect Time:: 11:55 Sample Depth Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwglab.org under StaffAccess A -Value reported is the average of two or more determinations B1-Countable membranes with <20 colonies; Estimated N3-Estimated concentration is < PQL and >MDL NE -No established PQL . B2- Counts, from all filters were zero. 63- Countable membranes with more than 60 or 80 colonies; Estimated P-Elevated PQL due to matrix interference and/or sample dilution B4-Filters have counts of both>60 or 80 and < 20; Estimated Q1-Holding time exceeded prior to receipt at lab. 135-7r6o many colonies were present; too numerous.to count (TNTC) Q2- Holding time exceeded following receipt by lab PQL-'Practical Quantitation Limit -subject to change due to instrument sensitivity J2- Reported, value failed to meet QC criteria for either precision or accuracy; Estimated U- Samples analyzed for this compound but not detected . J3-The sample matrix interfered with the ability to make any accurate determination; Estimated X1-Sample not analyzed for this compound J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated. N1-The component has been tentatively identified based on mass spectral library search and has an estimated value AR Laboratory Section»`1623 Mail Service Center, Raleigh, NC 27699-1623 (919) n3-3908 Page 1 of 6 Sample ID AB38176 NC DWQQ .Laboratory Section Results Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:55 Visit ID CAS # Analyte Name PQL Result Qualifier Units Analyst/Date Approved By /Date LAB Sample temperature at receipt by lab 1.7 °C DSAUNDERS HPARKER Method Reference 11/26/08 11/26/08 MIC TOC in liquid 2.0 2.6 J8 mg/L BSWANSON CGREEN Method Reference APHA53106-20th 12/11/08 12/16/08 WET Total Dissolved Solids in liquid 12 82 mg/L AWILLIAMS CGREEN Method Reference APHA254OC-18TH 11/26/08 12/3/08 MET 7440-38-2 As by ICPMS 5.0 3.4 ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7440-38-3 Be by ICP 10 10 U ug/L DSTANLEY ESTAFFORD Method Reference EPA200.7 12/1/08 '12117/08 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/2/08 12/17/08 7440-47-3 Cr by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7439-92-1 Pb by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 1213/08 12/17/08 VOL Volatile Organics in liquid TITLE_ ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 1211/08 75-78-1 Dichlorodifluoromethane 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 74-87-3 Chloromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 1211/08 75-01-4 ' Vinyl Chloride 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 74-83-9 Bromomethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 75-00-3 Chloroethane 0.50 Not detected. ug/L ATERRY RKELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 75-69-4 Trichlorofluoromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 75-35-4 1,1-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 5 PVC WQ .Laboratory Section ResultsSample ID AB38176 Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:65 Visit ID 75-09-2 Methylene Chloride 10 Not detected ug/L A I hHHY KKELLING , Method Reference EPA5030/624/8260 11/26/08 1211/08 . 156-60=5 •trans-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 1634-04-4 Methyl Tert-Butyl Ether 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1/08 75-34-3 1,1-Dichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 �11126108 1211/08 156-59-4 cis-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING' Method Reference EPA5030/624/8260 11/26/08 12/1/08 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 67-66-3 Chloroform 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 _ 12/1108 590-20-7 2,2-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 . 12/1/08 107-06-2 1,2-Dichloroethane 0.25 Not detected ug/L ATERRY WELLINGMethod Reference EPA5030/624/8260 - 11/26/08 12/1/08 71-55-6 1,1,1-Trichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY. WELLING . Method Reference EPA5030/624/8260 11/26/08 12/1/08 71-43-2 Benzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 74-95-3 Dibromomethane 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1108 78-87-5 1,2-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1/08 79-01-6 . Trichloroethene 0.25 Not detected ug/L ATERRY --RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 75-27-4 Bromodichloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 10061-01-5 cis-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 5 � . PVC DSample ID AB38176WQ Laboratory Section results . Location ID: 6P077WQ0000601 Collect Date: 11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:65 Visit ID - 10061-02-6 trans-1,3-Dichloropropene 0.25 Not detected ug/L AI EKRY HKELLINU Method Reference EPA5030162418260 11/26/08 12/1108 . 79--00-5 1,1,2-Tdchloroethane 0.25 -Not detected... ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 108-88-3 Toluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26108, 1211/08 142-28-9 1,3-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING. Method Reference EPA50301624/8260 11/26/08 1211/08 124-48-1 Dibromochloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 106-93-4 (EDB)1,2-Dibromoethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 127-18-4 Tetrachloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 1211/08 108-90-7 Chlorobenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/68 12/1/08 100-41-4 Ethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 .11/26/08 '12/1/08 75-25-2 Bromoform 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 108-38-3 m,p-Xylene 0.50 .. Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 100-42-5 Styrene 0.25 Not detected ug/L ATERRY ' WELLING Method Reference EPA5030/624/8260 11/26/08 1211108 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08, 630-20-6 1,1,1,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 11/26/08 1211/08 95-47-6 o-Xylene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030162418260 11/26/08 1211/08 ' 96-18-4 1,2,3-Trichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 98-82-8 Isopropylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 108-86A Bramobenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624M260 11/26/08 1211/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 4 of 5 Sample ID AB38176 NC (DWQQ Laboratory Section Results Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:55 Visit ID 103-65-1 n-Propylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 95-49-8 2-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 106-43-4 4-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 108-67-8 1,3,5-Trimethyibenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 98-06-6 tert-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 95-63-6 1,2,4-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 135-98-8 sec-Burylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 1211/08 543-73-1 m-Dichlorobenzene (1,3) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 106-46-7 p-Dichlorobenzene (1,4) 0.25 Not detected ug/L ATERRY WELLING . Method Reference EPA5030/624/8260 11/26/08 12/1/08 95-50-1 o-Dichlorobenzene(1,2) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 99-87-6 p-Isopropyltoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211108 104-51-8 n-Burylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1/08 96-12-8 1,2-Dibromo-3-Chloropropane 2.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 120-82-1 1,2,4-Trichlorobenzene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 91-20-3 Naphthalene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 87-68-3 Hexachlorobutediene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 87-61-6 1,2,3-Trichlorobenzene 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 VOC'S BY GUMS Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 North Carolina GROUNDWATER FIELD/LAB FORM U �'� Department of Environment and Natural Resources DIVISION OF WATER QUALITY -GROUNDWATER SECTION Location code_6P077WQ0000601 SAMPLE TYPE SAMPLE PRIORITY /J,,� County_Richmond ® Water Routine W Lab Number Q ASS 148Q3 p 1 �6 ❑ Soil Emergency ❑ / Time: Quad No Serial No. El Date Received j�-o�(p'��i 'b O Lat. Long. Rec'd By: 'From:Bus Auner,and Del., ® Chain of Custody Other: Report To: ARO(ED MRO, RRO, WaRO, WiRO, Data Entry By: Ck: WSRO, Kinston FO d. Trust, Central Off., Other: Date Reported: Shipped by: Bus,(Couriea Hand Del., Other: Purpose: Collector(s): t Date Time 5 Baseline, Complaint Complian e LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYS S 1.Owner �)( 1je 4 �s 7715 e -Ld pH 400 P+80 Spec. Cond.94 131 at 25°C Location or Site 4- Temp.lo -'k 0 .0 °C Odor i ':;)ry0- Description of sampling point WeL e.4 Appearance C_L ­r -Sampling Method A3.4i le Sample Interval FieldAnalysis_By: : c 4 Remarks umo, aier.ec. LABORATORY ANALYSES (Pumping time, air temp., etc.) BOD 310 mg/L COD High 340 mg/L COD Low 335 mg/L Coliform: MF Fecal 31616 /loom] Coliform: MF Total 31504 /loom] X TOC 680 mg/L Turbidity 76 NTU Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 mg/L Carbonate 445 mg/L Bicarbonate 440 mg/L Carbon dioxide 405 mg/L Chloride 940 mg/L Chromium: Hex 1032 ug/L Color: True 80 Cu Cyanide 720 mg/L Lab Comme X Diss. Solids 70300 mg/L Fluoride 951 mg/L Hardness: Total 900 . mg/L Hardness (non-carb) 902 mg/L Phenols 32730 ug/I Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Grease mg/L NH, as N 610 mg/L KNas N 625 mg/L Oz + NO3 asN 630 mg/L : Total as P 665 mg/L tP itrate (NO3as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block. Ag-Silver 46566 u /L AI -Aluminum 46557 u /L X As -Arsenic 46551 u /L X Ba-Barium 46558 u /L Ca -Calcium 46552 m /L X Cd-Cadmium 46559 u /L X Cr-Chromium 46559 u /L Cu-Copper46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 m /L Mg -Magnesium 46554 m /L Mn-Manganese 46565 u /L Na-Sodium 46556 m /L Ni-Nickel u /L X Pb-Lead 46564 u /L Se -Selenium u /L Zn-Zinc 46567 u /L Or anochlorine Pesticides Or ano hos horus Pesticides Nitrogen Pesticides Acid Herbicides PCBs Semivolatile Organics TPH-Diesel Range Volatile Or anics(VOA bottle TPH-Gasoline Range TPH-BTEX Gasoline Range LAB USE ONLY Temperature on arrival (IC): County: RICHMOND River Basin Report To FROAP Collector: B TODD Region: FRO Sample Matrix: GROUNDWATER Loc. Type: WATER SUPPLY 1 EIVED DEC 19 2000 DENR - FAYMLLE REGIONAL OFFICE Sample ID: AB38177 PO Number# 8G1553 Date Received: 11/26/2008 Time Received: 08:20 Labworks LoginlD HPARKER Date Reported: 12/17/08 Report Generated: 12/17/2008 Emergency Yes/No �J] VisitlD COC Yes/No Yes 7 Loc. Descr.: CSX TRANSPORTATION INC Location ID: 6PO77W00000601 Collect Date: 11/25/2008 Collect Time:: 11:35 Sample Depth Sample Qualifiers and Comments Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwqlab.org under Staff Access /OS A -Value reported is the average of two or more determinations N3-Estimated concentration is < PQL and >MDL B1-Countable membranes with <20 colonies; Estimated NE -No established PQL . B2- Counts from all filters were zero. P-Elevated PQL due to matrix interference and/or sample dilution B3- Countable membranes with more than 60 or 80 colonies; Estimated • Q1-Holding time exceeded prior to receipt at lab. B4-Filters have counts of both >60 or 80 and < 20; Estimated Q2- Holding time exceeded following receipt by lab B5-Too many colonies were present; too numerous to count (TNTC) PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated U- Samples analyzed for this compound but not detected J3-The sample matrix interfered with the ability to make any accurate determination; Estimated X1- Sample not analyzed for this compound J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated N1-The component has been tentatively identified based on mass spectral library search and has an estimated value I AR Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 5 NC ��VQ Laboratory Section Results Collect "' H6.fif"1 / / Location ID: 6P077WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:35 Visit ID CAS # Analyte Name PQL Result Qualifier Units Analyst/Date Approved By /Date LAB Sample temperature at receipt by lab 1.7 'C DSAUNDERS HPARKER Method Reference 11/26/08 11/26/08 MIC TOC in liquid 2.0., 2 U J8 mg/L BSWANSON CGREEN Method Reference APHA5310B-20th 12/4/08 12/9/08 WET Total Dissolved Solids in liquid 12 54 mg/L AWILLIAMS CGREEN Method Reference APHA254OC-18TH 11/26/08 12/3108 MET 7440-38-2 As by ICPMS 5.0 2.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7440-38-3 Be by ICP 10 10 U ug/L DSTANLEY ESTAFFORD Method Reference EPA 200.7 12/1/08 12/17/08 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 .12/2/08 12/17/08 7440-47-3 Cr by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7439-92-1 Pb by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference ' EPA 200.8 12/3/08 12/17/08 VOL Volatile Organics in liquid TITLE_ ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 75-78-1 Dichlorodifiuoromethane 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 74-87-3 Chloromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-01-4 Vinyl Chloride 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 74-83-9 Bromomethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-00-3 Chloroethane 0.50 Not detected ug/L ATERRY RKELLING, Method Reference EPA5030/624/8260 11/26/08 1211/08 75-69-4 Trichlorofluoromethane 0.50 Not detected ug/L ATERRY .RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-35-4 1,1-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 5 oarnpiC w AI:33S'I l7 Jr C DWQ ,Laboratory Section Results Location ID: 6P077WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 11:35 Visit ID AEKKY KKELLING Method Reference EPA50301624/8260 11/26/08 1211/08 156-60-5 trans-l;2-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 1634-04� Methyl Tert-Butyl Ether 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-34-3 1,1-Dichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 156-59-4 cis-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 67-66-3 Chloroform 0.25 Not detected ug/L ATERRY: RKELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 590-20-7 2,2-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 107-06-2 1,2-Dichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 71-55-6 1,1,1-Trichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08. 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L' ATERRY RKELLING: Method Reference EPA5030/624/8260 11/26/08 12/1/08 . 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 71-43-2 Benzene - 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 74-95-3 Dibromomethane 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5630/624/8260 11/26/08 12/1/08 78-87-5 1,2-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08' 12/1/08 79-01-6. Trichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 75-27-4 Bromodichloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 10061-01-5 cis-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING. Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 5 �ampie iu A538177 NC DWQ La6oratory Section Results Location ID: 6PO77WO0000601 Collect Date: 11/25/2008 Loc. Descr.:" CSX"TRANSPORTATION INC Collect Time:: 11:35 Visit ID 10061-02-6 trans-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 79-00-5 1,1,2-Tnchloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 108-88-3 Toluene 0.25 Not detected ug/L ATERRY WELLING Method Reference . EPA5030/624/8260 11/26/08 1211/08 142-28-9 1,3-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08` 12/1/08 12448-1 Dibromochloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260. 11/26/08 12/1/08 106-93-4 (EDB)1,2-Dibromoethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 127-184 Tetrachloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211108 108-90-7• Chlorobenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 100-41-4 Ethylbenzene 0.25 Not detected- ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 1211/08 75-25-2 Bromoform 1.0 Not detected ug/L ATERRY WELLING. Method Reference EPA5030/624/8260 11/26/08 12/1/08 108-38-3 - m,p-Xylene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 100-42-5 Styrene 0.25 Not detected ug/L ATERRY. WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 - 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY WELLING Method'Reference EPA50301624/8260 11/26/08 1211/08 630-20-6 1,1,1,2-Tetrachloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 1211/08 95-47-6 o-Xylene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260-, 11/26/08 12/1/08 96-184. 1,2,3-Trichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 98-82-8. Isopropylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 108-86-1 Bromobenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 4 of 5 NC DWQ Laboratory Section Results Sample ID A638177 Location ID: 6PO77W00000601 Collect Date: 11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC. Collect Time:: 11:35 Visit ID 0.25 Not detected Method Reference EPA5030/624/8260 11/26/08- 1211/08 95-49-8 2-Chiorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 . 11/26/08 12/1/08 106-43-4 4-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1/08 108-67-8 1,3,5-Trimethyibenzene 0.25 Not detected ug/L ATERRY . WELLING Methlod Reference EPA5030/62418260 11/26/08 12/1108 98-06-6 tert-Butyibenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1/08 95-63-6 1,2,4-Trimethyibenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08. .135-98-8 sec-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 643-73-1 m-Dichlorobenzene (1,3) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211108 106-46-7 p-Dichlorobenzene (1,4) 0.25 Not detected ug/L ATERRY WELLING Method Reference • EPA5030/624/8260 11/26/08 1211108 95-50-1 o-Dichiorobenzene (1,2) 0.25 Not detected ug/L ATERRY WELLING Method Reference EOA5030/624/8260 11/26/08 12/1/08 99-87-6 p-Isopropyltoluene 0.25 Not detected ug/L ATERRY. WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 104-51-8 n-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260' 11/26/08 12/1/08 96-12-8 .1,2-Dibromo-3-Chioropropane 2.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 120-82-1 1,2,4-Trichlorobenzene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 ' 11/26/08 12/1108 91-20-3 Naphthalene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 87-68-3 Hexachlorobutadiene 0.50 . Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 87-61-6 1,2,3-Ticchoorobenzene . 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 VOC'S BY GC/MS Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY -GROUNDWATER SECTION Location code 6P077WQ0000601 Cou Quad No Serial No. Lat. Long. SAMPLE TYPE SAMPLE PRIORITY ® Water Routine /YJ (j 1 Lab Number g13' �5 3v5 /71a3� ��T ❑ Soil ❑ Emergency Date Received - — V Time: b ❑ Other Rec'd By: ii���� From:Bus, ouner Hand Del., ® Chain of Custody Other: tw Report To: ARCED MRO, RRO, WaRO, WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, ourle Han DPI/, Other: Pur ose: Collector(s):QD¢ Date Time ►i �Baseline, Complaint Complian e LUST, Pesticide Study, Federal Trust, Other: —� ( cle one -� FIELD ANALYSES Owner A5 X l �2.or�•x rie rlr i . PH 400 -•qrj Spec. Cond.94 at 25°C Location or Site 4 Temp.lo eC Odor e- Description of sampling poi We- Ale -Ad Appearance . JI Sampling Method Ai a Sample Interval Field Analysis By: S i Remarks I umo. Dailer. a c. LABORATORY ANALYSES (Pumping time, air temp., etc.)' BOD 310 mg/L COD High 340 mg/L COD Low 335 mg/L Coliform: MF Fecal 31616 /100ml Coliform: MF Total 31504 /100ml X TOC 680 mg/L Turbidity 76 NTU Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 mg/L Carbonate 445 mg/L Bicarbonate 440 mg/L Carbon dioxide 405 mg/L Chloride 940 mg/L Chromium: Hex 1032 ug/L Color: True 80 Cu Cyanide 720 mg/L Lab X Diss. Solids 70300 mg/L Fluoride 951 mg/L Hardness: Total 900 mg/L Hardness (non-carb) 902 mg/L Phenols 32730 ug/I Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Grease mg/L NH3 as N 610 mg/L TKN as N 625 mg/L NO2 + NO3 as N 630 mg/L P: Total as P 665 mg/L Nitrate (NO3as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block. Ag-Silver 46566 u /L AI -Aluminum 46557 u /L X As -Arsenic 46551 u /L X Ba-Barium.46558 u /L Ca -Calcium 46552 m /L X Cd-Cadmium 46559 u /L X Cr-Chromium'46559 u /L Cu-Copper46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 m jL Mg -Magnesium 46554 m /L Mn-Manganese 46565 u /L Na-Sodium 46556 m /L Ni-Nickel u /L X Pb-Lead 46564 u /L Se -Selenium u /L Zn-Zinc 46567 u /L' Or anochlorine Pesticides Or ano hos horus Pesticides Nitrogen Pesticides Acid Herbicides PCBs Semivolatile Organics TPH-Diesel Range Volatile Organics(VOA bottle TPH-Gasoline Range TPH-BTEX Gasoline Range LAB USE ONLY Temperature on arrival (IC): / I Report to: _FROAP Lab Number: Station Location: AB38177 CSX - TRANSPORT- ATION INC Sample Type: WATER SUPPLY Date collected: 11/25/08 Affected Parameter(s): TOC NC DENR/DWQ Laboratory Sample Anomaly Report (SAR) Sample ID: 6PO77WQ0000601 County: RICU MOND Region: FAYETTEVILLE Priority: Collector: Date received: 11/26/08 " Date analyzed Analytical Area (check one): ❑ WCH ❑METALS ❑NUT ®MICRO The following anomalies occurred (check all that apply): ❑Samples ❑Improper container used ❑VOA vials with headspace ❑Sulfide samples with headspace ❑Samples not received, but listed on fieldsheet ❑Samples received, but not listed on fieldsheet ❑Mislabeled as to tests, preservatives, etc. ❑Holding time expired ❑Prior to receipt in lab ❑After receipt in lab ❑Insufficient quantity for analysis ❑Sample exhibits gross non -homogeneity ❑Sample not chemically preserved properly ❑pH out of range (record pH): ❑Improper chemical ❑Residual chlorine present iri sample ❑Color interference ❑Heavy emulsion formed during extraction ❑Sample bottle broken in lab,- no reportable results B TODD 12/04/08 ❑VOA ❑SVOA ❑PEST ❑Quality Control ❑Instrument failure — no reportable results ❑Analyst error — no reportable results [:]Surrogates ❑None added ❑Recovery outside acceptance limits ❑Spike recovery ❑None added ❑Recovery outside acceptance limits ❑Failed to meet criteria for precision ❑Internal standards ' ❑Blank contamination ❑QC data reported outside of controls (e.g., QCS, LCS) ❑Incorrect procedure used ❑SOP intentionally modified with QA and Branch Head approval ❑Invalid instrument calibration ❑Elevated detection limits due to: ❑Insufficient sample volume ®Other (specify):Temperature limit exceeded during storage, the data may not be accurate. Comments: The cooler used to store samples malfunctioned during the night of 12/3/08. This sample registered a below freezing temperature. Corrective Action:Tlie samples were removed from storage and the cooler maintenanced ❑Samples were rejected by DWQ Lab. Authorized by: Date: ❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured. ❑Sample(s) on hold until: ®Sample reported with qualification. Data qualification code used:J8 ❑Other (explain): Notification Required? ❑ Yes ❑ No Person Contacted: Date: Form completed by: JBeth Swanson g Aj___ ^\— Date: 12/8/2008 Lead Chemist eve (initial): ❑BIOCHE—]PEST ❑METALS [_]VOA Branch Head Review (initial): QA/QC Review (in' ' — QA\Forms\Laboratory\SAR ❑SVOA Logged into database by (initial): �v _ 12/067/.2-40$, I0/23/Oldbs NC OM LaboratorySection Wesults County: RICHMOND Sample ID: AB38178 River Basin �QF W ATF,gQ PO Number # 8G1554 Report To FROAP Date Received: 11/26/2008 ����� , r Time Received: 08:20 Collector: B TODD p Labworks LoginlD HPARKER REC Region: FRO # ry�y� Sample Matrix: GROUNDWATER DEC 1 9 •LUU® Date Reported: 12/17/08 Loc. Type: WATER SUPPLY Report Generated: 12/17/2008 Emergency Yes/No DENR-FAYETULLEREGiONALOWE , VisitlD �� COC Yes/No Yes Loc. Descn: CSX TRANSPORTATION INC C/ Y ! Location ID: 6PO77WQ0000601 Collect Date: 11/26/2008 Collect Time:: 12:15 Sample Depth Sample Qualifiers and Comments Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwqlab.org under Staff Access A -Value reported is the average of two or more determinations N3-Estimated concentrationi is < PQL and >MDL B1-Countable membranes with <20 colonies; Estimated NE -No established PQL B2- Counts from all filters were zero. P-Elevated PQL due to matrix interference and/or sample dilution B3- Countable membranes with more than 60 or 80 colonies; Estimated Q1-Holding time exceeded prior to receipt at lab. . 84-Filters have counts of both >60 or 80 and < 20; Estimated Q2- Holding time exceeded following receipt by lab B5-Too many colonies were present; too numerous to count (TNTC) PQL-Practical Quantitation Limit -subject to change due to instrument sensitivity J2- Reported value failed to meet. QC criteria for either precision or accuracy; Estimated U- Samples analyzed for this compound but not detected J3-The sample, matrix in with the ability to make any accurate determination; Estimated X1- Sample not analyzed for this compound J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated N1-The component has been tentatively identified based on mass spectral library search and has an estimated value 1 AR Laboratory Section>> 1623 Mall Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 6 Sample ID AB38178 NC (DWQ Laboratory Section Resufts Locatiod ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 12:16 Visit ID CAS # Analyte Name PQL Result Qualifier Units Analyst/Date Approved By /Date LAB Sample temperature at receipt by lab 1.7 °C DSAUNDERS HPARKER Method Reference 11/26/08 11/26/08 MIC TOC in liquid 2.0 2 U J8 mg/L BSWANSON CGREEN Method Reference APHA53108-20th 12/4/08 1219/08 WET Total Dissolved Solids in liquid 12 79 mg/L AWILLIAMS CGREEN Method Reference APHA254OC-18TH 11/26/08 12/3108 MET 7440-38-2 As by ICPMS 5.0 2.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7440-38-3 Ba by ICP 10 10 U ug/L - DSTANLEY ESTAFFORD Method Reference EPA200.7 12/1/08 12/11/08 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/2/08 12/17/08 7440-47-3 Cr by ICPMS 10 10 U' ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7439-92-1 Pb by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 Tm Volatile Organics in liquid _TITLE_ ug/L ATERRY WELLING Method Reference ' EPA5030/624/8260 12/1/08 12/2/08 75-78-1 Dichlorodifluoromethane Method Reference EPA5030/624/8260 1.0 Not detected ug/L ATERRY 12/1/08 WELLING 12/2/08 74-87-3 Chloromethane Method Reference EPA5030/62418260 0.50 Not detected ug/L ATERRY 12/11/08 WELLING 12/2/08 75-01-4 Vinyl Chloride Method Reference EPA5030/624/8260 0.50 Not detected ug/L ATERRY 1211/08 WELLING 12/2/08 74-83-9 Bromomethane Method Reference EPA5030/624/8260 0.50 Not detected ug/L ATERRY 1211/08 WELLING 12/2/08 75-00-3 Chloroethane Method Reference EPA5030/624/8260 0.50 Not detected ug/L ATERRY 12/1/08 WELLING 12/2108 75-69-4 Trichlorofluoromethane Method Reference EPA5030/624/8260 0.50 Not detected ug/L ATERRY 1211/08 WELLING 12/2/08 75-35-4 1,1-Dichloroethene Method Reference EPA5030/624/8260 0.25 Not detected ug/L ATERRY 1211/08 WELLING 1212/08 .Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 5 NC DWQ, Laboratory Section Results""'"" "' HW01'U Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 12:15 Visit.ID Chloride 10 Not detected Method Reference EPA5030/624/8260 1211/08 12/2/08 156-60-5 trans-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING - Method Reference EPA5030/624/8260 12/1108 .12/2/08 1634-04-4 Methyl Tert-Butyl Ether 0.25 Not detected ug/L :, ATERRY RKELLING. Method Reference EPA5030/624/8260 12/1/08 1212/08 75-34-3 1,1-Dichloroethane 0.25 Not detected ug/L ATERRY. RKELLING Method Reference EPA5030/624/8260 12/1/08 12IN08 156-59-4 cis-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08' 12/2/0S 67-66-3 Chloroform 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 1212/08 590-20-7 2,2-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 107-06-2 1,2-Dichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1108 . 12/2108 71-55-6 1,1,1-Trichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/2108 71-43-2 Benzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 12/2/08 74-95-3 Dibromomethane 1.0 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 78-87-5 112-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/2108 79-01-6 Trichloroethene 0..25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 75-27-4 Bromodichloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 10061-01-5 cis-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 1212/08 J Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733=3908 Page 3 of 5 5 C DWQ Laboratory Section -Results �Q"'"l—. "C5150,110 Location ID: 6PO77WQ0000601 Collect Date: 11/26/2608 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 12:15 Visit ID Not detected ug/L A I tKKT KMtLUNU Method Reference EPA5030/624/8260 12/1108 12/2/08 79-00-5 1,1,2-Trichloroethane 0.25 Not detected ug/L ATERRY RKELLING. Method Reference EPA5030/624/8260 1211/08 12/2/08 108-88-3 Toluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 142-28-9 1,3-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 124-48-1 Dibromochloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12008 106-93-4 (EDB)1,2-Dibromoethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 127-18-4 Tetrachloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 108-90-7 Chlorobenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1/08 12/2108 100-41-4 Ethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 75-25-2 Bromoform 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 108-38-3 m,p-Xylene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1/08 12/2/08 100-42-5 Styrene 0.25 Not detected ug/L . ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/2108 630-20-6 1,1,1,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2108 95-47-6 o-Xylene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 96-18-4 1,2,3-Trichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 1211/08 12/2108 98-82-8 Isopropylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 108-86-1 Bromobenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 . 12/1/08 12/2/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 4 of 5 NC 0WQ Laboratory Section Results Location ID: 6PO77W00000601 Collect Date: 11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 12:15 Visit ID 0.25 Not detected ug/L A Method Reference EPA5030/624/8260 12/1/08 1212/08 95-49-8 2-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 12/1/08 12/2108 106-43-4 4-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 .1211/08 12/2/08 108-67-8 1,3,5-Trmethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1/08 1212108 98-06-6 tert-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 1211/08 1212/08 95-63-6 1,2,4-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 1212/08 135-98-8 sec-Burylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 543-73-1 m-Dichlorobenzene (1,3) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 1212/08 106-46-7 p-Dichlorobenzene (1,4) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 95-50-1 o-Dichlorobenzene (1,2) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 1211/08 1212108 99-87-6 p-Isopropyitoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 104-51-8 n-Burylbenzene 0.25 Not detected ug/L ATERRY WELLING Method'Reference EPA5030/624/8260 12/1/08 12/2/08 96-12-8 1,2-Dibromo-3-Chloropropane . 2.0 Not detected. ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 120-82-1 1,2,4-Trichlorobenzene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 91-20-3 Naphthalene 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 87-68-3 Hexachlorobutadiene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 87-61-6 1,2,3-Trichlorobenzene 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 VOC'S BY GC/MS Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY -GROUNDWATER SECTION, Location code 6P077W00000601 County_Richm Quad No . Serial No. Long SAMPLE TYPE SAMPLE PRIORITY G ® Water Routine Lab Number & i �J�� rJ/c738 j 0 ❑ Soil Emergency ! Date Received -02 -- Time: `0 -❑ Other Lf• Rec'd By: From: Bus, ourier, and Del., ® Chain of Custody Other: M Report To: ARO, FRO MRO, RRO, WaRO, WiRO, Data Entry By: Ck: WSRO, Kinston FO. Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, ourle Hand Del., Other: Pur ose: Collector(s): Date IAnm Time Baseline, Complaint Complian e LUST, Pesticide Study, Federal.Trust, Other: FIELD ANALYSES Owner eSX 1CI ne ;� pH 400 • ,GY© Spec. Cond. -1D at 25°C Location or Site 4 Temp.lo M ,0 ° or C Odor i�Jei Description of sampling poi toe- e-,4 Appearance O'C4 Sampling Method fig n 4 Sample Interval Field Analysis By: 1. Remarks umo, batier. a c. LABORATORY ANALYSES (Pumping time, air temp., etc.) BOD 310 mg/L COD High 340 mg/L COD Low 335 mg/L Coliform: MF Fecal 31616 /100ml Coliform: MF Total 31504 /100ml X TOC 680 mg/L Turbidity 76 NTU Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 ' mg/L Carbonate 445 mg/L Bicarbonate 440 mg/L ' Carbon dioxide 405 mg/L Chloride 940 mg/L Chromium: Hex 1032 ug/L Color: True 80 CU Cyanide 720 mg/L Lab X Diss. Solids 70300 mg/L Fluoride 951 mg/L Hardness: Total 900 mg/L Hardness (non-carb) 902 mg/L Phenols 32730 ug/I Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Grease mg/L NH3 as N 610 mg/L TKN as N 625 mg/L NO2 + NO3 as N 630 mg/L P: Total as P 665 mg/L Nitrate (NO3as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block. Ag-Silver 46566 u /L AI -Aluminum 46557 u /L X As -Arsenic 46551 u /L X Ba-Barium 46558 u /L Ca -Calcium 46552 m /L X Cd-Cadmium 46559 u /L X Cr-Chromium 46559 u /L Cu-Copper 46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 m /L Mg -Magnesium 46554 m /L Mn-Manganese 46565 u /L Na-Sodium 46556 m /L Ni-Nickel u /L X Pb-Lead 46564 u /L Se -Selenium u /L Zn-Zinc 46567 u /L t Report to: _FROAP NC DENR/DWQ Laboratory Sample Anomaly Report (SAR) Lab Number: AB38178 Station Location: CSX TRANSPORT- ATION INC Sample Type: WATER SUPPLY Date collected: 11/25/08 Affected Parameter(s): TOC Sample ID: 6PO77WQ0000601 County: RICHMOND _ Region: FAYETTEVILLE Priority: Collector: Date received: 11/26/08 Date analyzed: Analytical Area (check one): ❑ WCH ❑METALS ❑NUT NMICRO The following anomalies occurred (check all that apply): ❑Samples ❑Improper container used ❑VOA vials with headspace ❑Sulfide samples with headspace ❑Samples not received, but listed on fieldsheet ❑Samples received, but not listed on fieldsheet ❑Mislabeled as to tests, preservatives, etc. ❑Holding time expired ❑Prior to receipt in lab []After receipt in lab ❑Insufficient quantity for analysis ❑Sample exhibits gross non -homogeneity ❑Sample not chemically preserved properly ❑pH out of range (record pH): ❑Improper chemical ❑Residual chlorine present in sample ❑Color interference ❑Heavy emulsion formed during extraction ❑Sample bottle broken in lab - no reportable results B TODD 12/04/08 ❑VOA ❑SVGA ❑PEST ❑Quality Control ❑Instrument failure — no reportable results ❑Analyst error _ no reportable results ❑Surrogates ❑None added ❑Recovery outside acceptance limits ❑Spike recovery ❑None added ❑Recovery outside acceptance limits ❑Failed to meet criteria for precision ❑Internal standards ❑Blank contamination ❑QC data reported outside of controls (e.g., QCS, LCS) ❑Incorrect procedure used ❑SOP intentionally modified with QA and Branch Head approval ❑Invalid instrument calibration ❑Elevated detection limits due to: ❑Insufficient sample volume ®Other (specify):Temperature limit exceeded during storage, the data may not be accurate. Comments: The cooler used to store samples malfunctioned during the night of 12/3/08. This sample registered a below freezing temperature. Corrective Action:The samples were removed from storage and the cooler maintenanced ❑Samples were rejected by DWQ Lab. Authorized by: Date: ❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured. ❑Sample(s) on hold until: . ®Sample reported with qualification. Data qualification code used:J8 ❑Other (explain): Notification Required? ❑ Yes ❑ No Person Contacted: Date: Form completed by: 113eth Swafiso ���- Date: 12/8/2008 z Lead Chemist vie Initial): 1­1131OCHEM ❑PEST ❑METALS ❑VOA Branch Head Review (id' QA/QC Review (i itial): QA\Fomis\tabomtorykSAR ❑SVOA Logged into database by (initial): &0 10/23/Oldbs e R. N 1�ZV Laborato ection esuits County: RICHMOND _ Sample ID: AB38179 River Basin =_ �Q� WArF9Q PO Number# 8G1555 Report To FROAP RE��d'6�} i Date Received: 11/26/2008 I � _ _ Time Received: 08:20 Collector: B TODD FRO �pilpp-J DEC 201J� y o Y Labworks LoginlD HPARKER Region: Date Reported: 12/17/08 Sample Matrix: GROUNDWATER f Loc.Type: WATER SUPPLY DES_II-FAYCffklflLLEREGIOi9LURCE! Report Generated: 12/17/2008 Emer enc Yes/No —_ -_'l g y VisitlD COC Yes/No Yes ' Loc. Descr.: CSX TRANSPORTATION INC Location ID: 6PO77WQ0000601 Collect Date: 11/26/2008 Collect Time:: 10:25 Sample Depth Sample Qualifiers and Comments / Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access A -Value reported is the average of two or more determinations N3-Estimated concentration is < PQL and >MDL B1-Countable membranes with <20 colonies; Estimated NE -No established PQL B2- Counts from all filters were zero. P-Elevated PQL due to matrix interference and/or sample dilution B3- Countable membranes with more than 60 or 80 colonies; Estimated Q1-Holding time exceeded prior to receipt at lab. B4-Filters have counts of both >60 or 80 and < 20; Estimated Q2-Holding time exceeded following receipt by lab B5-Too many colonies were present; too numerous to count (TNTC) PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated U- Samples analyzed for this compound but not detected J3-The sample matrix interfered with the ability to make any accurate determination; Estimated X1-Sample not analyzed for this compound J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated N1-The component has been tentatively identified based on mass spectral library search and has an estimated value IAR Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919).733-3908 Page 1 of 5 �arnPin w At33tf'17y NC WQ.Laboratory Section W§sufts Location ID: 6PO77WQ0000601 Collect Date: 11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 10:25 Visit ID AS # Analyte Name PQL Result Qualifier Units Analyst/Date Approved By /Date LAB Sample temperature at receipt by lab 1.7 °C DSAUNDERS HPARKER Method Reference 11/26/08 11/26/08 MIC TOC In liquid 2.0 2 U J8 mg/L BSWANSON CGREEN Method Reference APHA5310B-20th 12/4/08 12/9/08 WET Total Dissolved Solids in liquid 12 103 mg/L AWILLIAMS CGREEN Method Reference APHA254OC-18TH 11/26/08 12/3108 MET 7440-38-2 As by ICPMS 5.0 2.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7440-38-3 ' Baby ICP 10 31 ug/L DSTANLEY ESTAFFORD Method Reference EPA200.7 12/1/08 12/17/08 7440-43-9 Cd by ICPMS 1.0 • 1.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/2/08 12/17/08 7440-47-3 Cr by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD -y - Method Reference EPA 200.8 12/3/08 12/17/08 7439-92-1 Pb by ICPMS 10 10- U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 VOL Volatile Organics in liquid TITLE_ ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1/08 12/2/08 75-78-1 Dichlorodifluoromethane 110 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 12/1/08 .12/2/08 74-87-3 Chloromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1212/08 75-01-4 Vinyl Chloride 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 1212108 74-83-9 Bromomethane 0.50 Not detected ug/L, ATERRY. WELLING Method Reference EPA5030/624/8260 1211/08 12/2108 75-00-3 Chloroethane 0.50 Not detected ug/L ATERRY RKELLING, Method Reference EPA50301624/8260 1211108 12/2/08 75-69-4 Trichlorofluoromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 .12/2/08 75-35-4 , 1,1-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08' 12/2/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 5 Sample ID AB38179 NC IDWQQ Laboratory Section Results Location ID: 6P077WQ0000601 Collect Date: - 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 10:25 Visit ID 75-09-2 Methylene Chloride 10 Not detected ug/L A I LKKY KKLLLIN(3 • Method Reference EPA5030/624/8260 1211108 1212/08 156-60-5 trans-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211108 12/2/08 1634-04-4 Methyl Tert-Butyl Ether 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 75-34-3 1,1-Dichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 156-59-4 cis-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1212/08 ' 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference - EPA5030/624/8260 1211/08 12/2/08 67-66-3 Chloroform 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211108 12/2/08 590-20-7 2,2-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 107-06-2 1,2-Dichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 71-55-6 1,1,1-Trichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 •12/2/08 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY RKELLING • Method Reference EPA50301624/8260 1211/08 12/2/08 71-43-2 Benzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 1212/08 74-95-3 Dibromomethane 1.0 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 1212/08 78-87-5 1,2-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 79-01-6 Trichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 12/2108 75-27-4 Bromodichloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 10061-01-5 cis-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 5 Sample ID AB38179 NC (DWQ Laboratory Section ResuCts Location ID: 6PO77WO0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 10:26 Visit ID trans-1.3-Dichloroorooene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 1212/08 .79-00-5 1,1,2-Tdchloroethane 0.25 Not detected ug/L ATERRY , RKELLING Method Reference EPA5030/62418260 1211/08 12/2/08 108-88=3 Toluene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211108, 12/2/08, 142-28-9 1,3-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 , 12/2/08 12448-1 'Dibromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 106-93-4 (EDB)1,2-Dibromoethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 127-18-4 Tetrachloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1212/08 108-90-7 Chlorobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 - 12/2/08 100-41-4 Ethylbenzene ' 0.25 Not detected ug/L ATERRY ; 'RKELLING Method ReferenceEPA5030%624/8260 1211/08 12/2108 75-25-2 Bromoform 1.0 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 12/2/08 108-38-3 m,p-Xylene 0.50 " Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 - 1211/08 12/2/08 100-42-5 Styrene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211108 12/2/08 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 630-20-6 1,1,1,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING' Method Reference EPA5030/624/8260 - 12/1/08 12/2/08' 95-47-6 o-Xylene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 96-18-4 1,2,3-Trichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 98-82-8 Isopropylbenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 108-86-1 Bromobenzene 0.25 Not detected ug/L ATERRY RKELLING . Method Reference EPA5030/624/8260 12/1/08 12/2/08 Laboratory. Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 4 of 5 NC DWQ Laboratory Section 12esurts Sample ID AB38179 Location ID: 6PO77WO0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 10:25 Visit ID 103-65-1 n-Propylbenzene 0.25 Not detected ug/L AI tKKY KKtLLINU Method Reference EPA5030/624/8260 12/1/08 1212/08 95-49-8 2-Chiorotoluene 0.25 Not detected ug/L- ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 106-43-4 4-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 1212/08 108-67-8 1,3,5-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2108 98-06-6 tert-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 95-63-6 1,2,4-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 135-98-8 sec-Butylbenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 12/2/08 543-73-1 m-Dichlorobenzene (1,3) . 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 106-46-7 p-Dichlorobenzene (1,4) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 1211/08 12/2/08 95-50-1 o-Dichlorobenzene (1,2) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 99-87-6 p-Isopropyltoluene 0.25 Not detected ug/L ATERRY WELLING - Method Reference EPA50301624/8260 12/1/08 12/2/08 104-51-8 n-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 96-12-8 1,2-Dibromo-3-Chloropropane 2.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 120-82-1. 1,2,4-Trichlorobenzene 0.50 Not detected. ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1212108 91-20-3 Naphthalene 0.50 Not detected ug/L ATERRY RKELLING- Method Reference EPA5030/624/8260 12/1/08 12/2/08 87-68-3 Hexachlorobutadiene 0.50 Not detected ug/L ATERRY- WELLING Method Reference EPA5030/624/8260 12/1108 1212108 87-61-6 1,2,3-Trichlorobenzene 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 VOC'S BY GC/MS Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 North Carolina GROUNDWATER FIELD/LAB FORML�u Department of Environment and Natural Resources DIVISION OF WATER QUALITY -GROUNDWATER SECTION .Location code_6P077WQ0000601 SAMPLE TYPE SAMPLE PRIORITY (- / p County_Richmond ® Water Routine Lab Number' l J!j5 ! ❑ Soil El Emergency Quad No Serial No. � Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ® Chain of Custody Other: Report To: ARO, FRO MRO, RRO, WaRO, WiRO, Data Entry By: Ck: WSRO, Kinston FO. Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, ourle Hand Del., Other: Pur ose: Collector(s): Date 2S Winne AS Baseline, Complaint ��A LUST, Pesticide Study, Federal Trust, Other: �� ( clt? one -� �9 FIELD ANALYS S q .Owner SX lj2.4d f'.1cf ,til' d f PH 400 Spec. Cond.94 i at 250C Location or Site 4 Temp.lo 19, Q °C Odor Kiag— Description'of sampling poirA,[ve/ eA Appearance Sampling Method A3Ai a d Sample Interval Field Analysis By: I Remarks umo. ai er, a c. LABORATORY ANALYSES (Pumping time, air temp., etc.) BOD 310 mg/L COD High 340 mg/L COD Low 335 mg/L Coliform: MF Fecal 31616 /100ml Coliform: MF Total 31504 /1ooml X TOC 680 mg/L Turbidity 76 NTU Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 mg/L Carbonate 445 mg/L Bicarbonate 440 mg/L Carbon dioxide 405 mg/L Chloride 940 mg/L Chromium: Hex 1032. ug/L Color: True 80 Cu Cyanide 720 mg/L Lab X Diss. Solids 70300 mg/L Fluoride 951 mg/L Hardness: Total 900 mg/L Hardness (non-carb) 902 mg/L Phenols 32730 ug/l Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Grease mg/L NH3 as N 610 mg/L TKN as N 625 mg/L NO2. + NO3 as N 630 mg/L P: Total as P 665 mg/L Nitrate (NO3 as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block. Ag-Silver 46566 u /L AI -Aluminum 46557 u /L X As -Arsenic 46551 u /L X Ba-Barium 46558 u /L Ca -Calcium 46552 m /L X Cd-Cadmium 46559 u /L X Cr-Chromium 46559 u /L Cu-Copper 46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 m /L Mg -Magnesium 46554 m /L Mn-Manganese 46565 u /L Na-Sodium 46556 m /L Ni-Nickel u /L X Pb-Lead 46564 u /L Se -Selenium u /L Zn-Zinc 46567 u /L ri- Or anochlorine Pesticides Or ano hos horus Pesticides Nitrogen Pesticides Acid Herbicides PCBs Semivolatile Organics TPH-Diesel Range Volatile Organics OA bottle TPH-Gasoline Range TPH-BTEX Gasoline Ran e LAB USE ONLY Temperature on arrival (°C): 1 Report to:—FROAP= NC DENR/DWQ Laboratory Sample Anomaly Report (SAR) Lab Number: Station Location: AB38179 CSX TRANSPORT- ATION INC Sample Type: WATER SUPPLY Date collected: 11/25/08 Affected Parameter(s): TOC Sample ID: 6PO17WQ0000601 County: RICHMOND Region: FAYETTEVILLE Priority: Date received: 11/26/08 Analytical Area (check one): ❑ WCH ❑METALS ❑NUT ®MICRO The following anomalies occurred (check all that apply): ❑Samples ❑Improper container used ❑VOA vials with headspace ❑Sulfide samples with headspace ❑Samples not received, but listed on fieldsheet ❑Samples received, but not listed on fieldsheet ❑Mislabeled as to tests, preservatives, etc. ❑Holding time expired ❑Prior to receipt in lab ❑After receipt in lab ❑Insufficient quantity -for analysis ❑Sample exhibits gross non -homogeneity ❑Sample not chemically preserved properly ❑pH out of range (record pH): ❑Improper chemical ❑Residual chlorine present in sample ❑Color interference ❑Heavy emulsion formed during extraction ❑Sample bottle broken in lab - no reportable results Collector: Date .analyzed: B TODD 12/04/08 ❑VOA ❑SVOA ❑PEST ❑Quality Control ❑Instrument failure— no reportable results ❑Analyst error— no reportable results ❑Surrogates ❑None added ❑Recovery outside acceptance limits ❑Spike recovery ❑None added ❑Recovery outside acceptance limits ❑Failed to meet criteria for precision ❑Internal, standards ❑Blank contamination []QC data reported outside of controls (e.g., QCS, LCS) ❑Inco'rrect procedure used ❑SOP intentionally modified with QA and Branch Head approval ❑Invalid instrument calibration ❑Elevated detection limits due to: ❑Insufficient sample volume ®Other (specify):Temperature limit exceeded during storage, the data may not be accurate. Comments: The cooler, used to store samples malfunctioned during the night of 12/3/08. This sample registered a below freezing temperature. Corrective Action:The samples were removed from storage and the cooler maintenanced ❑Samples were rejected by DWQ Lab. Authorized by: Date: ❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured. ❑Sample(s) on hold until: ®Sample reported with qualification. Data qualification code used:J8 ❑Other (explain): Notification Required? ❑ Yes ❑ No Person Contacted: Date: Form completed by: Beth Swanson Date: 12/8/2008 Lead Chemist R few nlal): ❑BIOCHEM ❑PEST ❑ METALS ❑ VOA Branch Head Review (in' •a QA/QC Review (in tial): %o1�cZ/U" QATonns\Laboratory\SAR - ❑SVOA Logged into database by (initial):_ 10/23/Oldbs f• r `ection County: RICHMOND River Basin Report To FROAP Collector: B TODD Region: FRO Sample Matrix: GROUNDWATER Loc. Type: WATER SUPPLY Emergency Yes/No COC Yes/No Yes I Location ID: 6PO77WQ0000601 RECEIVED DEC 19 2000 DENR- FAT tT I -LE REGIONAL OFRCE I VisitlD Loc. Descr.: CSX TRANSPORTATION INC Collect Date: 11/25/2008 Collect Time::. 10:00 Sample Qualifiers and Comments Sample ID: PO Number # Date Received: Time Received: Labworks LoginlD Date Reported: Report Generated: Sample Depth AB38180 8G1556 11 /26/2008 08:20 HPARKER 12/17/08 12/17/2008 Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwglab. org-under Staff Access A -Value reported is the average of two or more determinations N3-Estimated concentration is < PQL and >MDL B1-Countable membranes -with <20 colonies; Estimated NE -No established PQL 62-Counts from all filters were zero. P-Elevated PQL due to matrix interference and/or sample dilution B3- Countable membranes with more than 60 or 80 colonies; Estimated 64-Filters have counts of both >60 or 80 and < 20; Estimated Q1-Holding time exceeded prior to receipt at lab. Q2- Holding time exceeded following receipt by lab B5-Too many colonies were present; too numerous to count (TNTC) J2- Reported value failed to meet QC criteria, for either precision or accuracy; Estimated PQL- Practical Quantitation Limit -subject to change due to. instrument sensitivity U- Samples analyzed for this compound but not detected J3-The sample matrix interfered with the ability to make any accurate determination; Estimated X1- Sample not analyzed for this compound J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated N1-The component has been tentatively identified based on mass spectral library search and has an estimated value I AR Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Pagel of 5 5VC DWQ La6oratory Section Results Sample ID AB38180 Location ID: 6P077WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC, Collect Time:: 10:00 Visit ID — CAS # Analyte Name PQL Result Qualifier Units Ana yst/Date Approved By /Date LAB Sample temperature at receipt by lab 1.7 °C DSAUNDERS HPARKER Method Reference 11/26/08 11/26/08- MIC TOG in liquid 2.0 2 'U J8 mg/L BSWANSON. CGREEN Method Reference APHA53106-20th 1214/08 12/9/08 MET . 7440-38-2 As by ICPMS 5.0 2.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08. 7440-38-3 . Ba by.ICP 10 16 ug/L DSTANLEY ESTAFFORD Method Reference EPA 200.7 12/1/08 12/17/08 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 1212/08 12/17/08 7440-47-3 Cr by ICPMS 10 27 ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 7439-92-1 . Pb by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference. EPA 200.8, 12/3/08 12/17/08 VOL Volatile Organics In liquid _TITLE_ ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 -' 12/2/08 75-78-1 - Dichlorodifluoromethane 1.0 Not detected ug/L ATERRY WELLING . Method Reference EPA5030/624/8260 12/1108 12/2/08 74-87-3 Chloromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 12/1/08 1212/08 75-01-4 Vinyl Chloride 0.50 Not detected ug/L - ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08, 74-83-9 Bromomethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1212108 75-00-3 Chloroethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 75-69-4 Trichlorofluoromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 12/1/08 1212108 75-35-4 1,1-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211108 12/2/08 75-09-2 Methylene Chloride 10 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC, 27699-1623 (919) 733-3908 Page 2 of 5 PVC WQ La6oratory Section I�esulCts Sample ID AB38180 Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 10:00 Visit ID 156-60-5 trans-1,2-Dichloroethene 0.25 Not detected ug/L A I tKKT KKCLLINC9 Method Reference EPA5030/624/8260 1211/08 12/2/08 1634-04-4 Methyl Tert-Butyl Ether 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 75-34-3 1,1-Dichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 156-59-4 cis-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211108 12/2108 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 67-66-3 Chloroform 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1212/08 590-20-7 2,2-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2108 107-06-2 1,2-Dichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 71-55-6 1,1,1-Tdchloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2108 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2108 71-43-2 Benzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 1211/08. 12/2/08 74-95-3 Dibromomethane 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 78-87-5 1,2-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1 12/1/08 1212/06 79-01-6 Trichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 75-27-4 Bromodichloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 1211/08 12/2/08 10061-01-5 cis-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 1212/08 10061-02-6 trans-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-16.23 (919) 733-3908 Page 3 of 5 XC (DWQ Laboratory Section ResultsSample ID AB38180 Location ID: 6P077WQ0000601 Collect Date: 11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 10:00 Visit ID 79-00-5 1,1,2-Trichloroethane , 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 108-88-3 Toluene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 12/2/08 142-28-9 1,3-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference . EPA5030/624/8260 12/1/08 12/2/08 124-48-1 Dibromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 106-93-4 (EDB)1,2-Dibromoethane . 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 127-18-4 Tetrachloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 108-90-7 Chlorobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 12/2108 100-41-4 Ethylbenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 75-25-2 Bromoform 1.0 Not detected. ug/L ATERRY RKELLING Method Reference EPA5030/62418260 1211/08 12/2/08 108-38-3 in,p-Xylene 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/2108 100-42-5 Styrene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA503b/624/8260 12/1/08 1212/08 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 630-20-6 1,1,1,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 12/2108 95-47-6 o-Xylene 0.25. Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 1212/08 96-18-4 1,2,3-Trichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1212/08 98-82-8 Isopropylbenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 12/2/08 108-86-1 Bromobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 103-65-1 _ n-Propylbenzene' 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1108 12/2/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 4 of 5 Sample ID AB38180 XC DWQ Laboratory Section Results Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 10:00 Visit ID Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 12/2108 106-43-4 4-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 108-67-8 1,3,5-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 98-06-6 tert-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EOA5030/624/8260 12/1/08 1212/08 95-63-6 1,2,4-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 135-98-8 sec-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1/08 12/2108 543-73-1 m-Dichlorobenzene (1,3) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1212108 106-46-7 p-Dichlorobenzene (1,4) 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624_/8260 12/1/08 12/2/08 95-50-1 . o-Dichlorobenzene (1,2) 0.25 -Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 99-87-6 p-isopropyltoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 104-51-8 n-Butylbenzene 0.25 Not detected. ug/L ATERRY WELLING Method Reference EPA5030/62418260 12/1/08 12/2/08 96-12-8 1,2-Dibromo-3-Chlorop_ropane 2.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/2/08 120-82-1 1,2,4 Tdchlorobenzene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2/08 91-20-3 Naphthalene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 12/1/08 12/2108 87-68-3 Hexachlorobutadiene 0.50 Not detected ug/L. ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1212108, 87-61-6 1,2,3-Tdchlorobenzene , 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624]8260 1211/08 12/2108 VOC'S BY GUMS Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/2108 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 GROUNDWATER FIELD/LAB FORM Location code 6PO77WQ0000601 County Quad No Serial No. Lat. Long. SAMPLE TYPE SAMPLE PRIORITY ® Water Routine ❑ Soil ❑ Emergency ❑ Other III ®Chain of Custody Report To: ARO, FRO MRO, RRO, WaRO, WiRO, l WSRO, Kinston FO d. Trust, Central Off., Other: Shipped by: Bus, ourie Hand Del., Other: Purpose: Collector(s): Date Time i 0b0 Baseline, Complai FIELD ANALYSES Owner JESX 1je.4r PH 400 Spec. Cond.94 71, at 25°C Location or Site Temp.10 Odor yy,�nJ >� Description of sampling poi Appearance_ Li.i2 Sampling Method mil/ Field Analysis By: Remarks_ LABORATORY ANALYSES BOD 310 mg/L COD High 340 mg/L COD Low 335 mg/L Coliform: MF Fecal 31616 /100ml Coliform: MF Total 31504 /loom] X TOC 680 mg/L Turbidity 76 NTU Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 mg/L Carbonate 445 mg/L Bicarbonate 440 mg/L' Carbon dioxide 405 mg/L Chloride 940 mg/L Chromium: Hex 1032 ug/L Color: True 80 Cu Cyanide 720 mg/L Lab Comments mg/L Fluoride 951 mg/L, Hardness: Total 900 mg/L Hardness (non-carb) 902 mg/L Phenols 32730 ug/I Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Greate mg/L e NH3 as N 610 mg/L TKN as N 625 mg/L NO2 + NO3 as N 630 mg/L P: Total as P 665 mg/L Nitrate (NO3as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block. North Carolina Department of Environment and Natural Resources DIVISION OF WATER QUALITY -GROUNDWATER SECTION Lab Number *336 b Date Received �r-a% ��� Time: O� Rec'd By: From:Bus, ourie , Hand Del., Other: Data Entry By: Ck: Date Reported: ;omplian e LUST, Pesticide Study, Federal Trust, Other: A ( ,%one . 1 �;te . (Pumping time, air temp., etc.) Ag-Silver 46566 u /L AI -Aluminum 46557 u /L X As -Arsenic 46551 u /L X Ba-Barium 46558 u /L Ca -Calcium 46552 m /L X Cd-Cadmium 46559 u /L X Cr-Chromium'46559 u /L Cu-Copper 46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 / m /L Mg -Magnesium 46554 m /L Mn-Manganese 46565 u /L Na-Sodium 46556 m /L Ni-Nickel u /L X Pb-Lead 46564 u /L Se=Selenium u /L Zn-Zinc 46567 u /L ple Interval Or anochlorine Pesticides Or ano hos horus Pesticides Nitrogen Pesticides Acid Herbicides PCBs Semivolatile Organics TPH-Diesel Range X Volatile Organics(VOA bottle TPH-Gasoline Range TPH-BTEX Gasoline Range LAB USE ONLY Temperature on arrival (°C): ) �� Er Report to: _FROAP. NC DENR/DWQ Laboratory Sample Anomaly Report (SAR) Lab Number: AB38180 Station Location: CSX TRANSPORT- ATION INC- Sample Type: WATER SUPPLY Date collected: 11/25/08 Affected Parameter(s): TOC Sample ID: 6PO77WQ0000601 County: RICHMOND Region: FAYETTEVILLE Priority: Collector:, Date received: 11/26/08 Date analyzed: Analytical Area (check one): ❑ WCH ❑METALS ❑NUT NMICRO The following anomalies occurred (check all that apply): ❑Samples El Improper container used ❑VOA vials with headspace ❑Sulfide samples with headspace ❑Samples not received, but listed on fieldsheet ❑Samples received, but not listed on fieldsheet ❑Mislabeled as to tests, preservatives, etc. ❑Holding time expired ❑Prior to receipt in lab ❑After receipt in lab ❑Insufficient quantity for analysis . ❑Sample exhibits gross non -homogeneity ❑Sample not chemically preserved properly ❑pH out of range (record.pH): ❑Improper chemical - ❑Residual chlorine present in sample ❑Color interference ❑Heavy emulsion formed during extraction ❑Sample bottle broken in lab - no reportable results B TODD 12/04/08 ❑VOA ❑SVOA ❑PEST ❑Quality Control ❑Instrument failure — no reportable results ❑Analyst error — no reportable results ❑Surrogates ❑None added ❑Recovery outside acceptance limits ❑Spike recovery ❑None added ❑Recovery outside acceptance limits ❑Failed to meet criteria for precision ❑Internal standards ❑Blank contamination ❑QC data reported outside of controls (e.g., QCS, LCS) ❑Incorrect procedure used ❑SOP intentionally modified with QA and Branch Head approval ❑Invalid instrument calibration ❑Elevated detection limits due to: ❑Insufficient sample volume ®Other (specify):Temperature limit exceeded during storage, the data may not be accurate. Comments: The cooler used to store samples malfunctioned during the night of 12/3/08. This sample registered a below freezing temperature. Corrective Action:The samples were removed from storage and the cooler maintenanced ❑Samples were rejected by DWQ Lab. Authorized by: Date: ❑Accepted and analyzed after notifying the. collector or contact person and determining that another sample could not be secured. ❑Sample(s) on hold until: ZSample reported with qualification. Data qualification code used:J8 ❑Other (explain): Notification Required? ❑ Yes ❑ No Person Contacted: Date: Form completed by: Beth Swanson `— Date: 12/8/2008 Lead Chemist R v1e- (initial): ❑BIOCHEM ❑METALS Branch Head Review (initial): QA/QC Review (initi J� ❑PEST ❑VOA ❑SVOA Logged into database by (initial): RA4�—di-2a.� QA\Forms\UboralorylSAR 10/23/01 dbs r, County: RICHMOND River Basin Report To FROAP Collector: B TODD Region: FRO Sample Matrix: GROUNDWATER Loc. Type: . WATER SUPPLY Emergency Yes/No COC Yes/No Yes I Location ID: 6PO77WQ0000601 REUE" D DEC 19 2008 `O�pF W AT�RQG � r K- DENR-FAYE7RLLEREGIONAL O VisitlD Loc. Descr.: CSX TRANSPORTATION INC Collect Date: 11/26/2008 Collect Time:: 12:30 Sample Qualifiers and Comments Sample ID: PO Number # Date Received: Time Received: Labworks LoginlD Date Reported: Report Generated: Sample Depth AB38181 8G1557 11/26/2008 08:20 HPARKER 12/17/08 12/17/2008 Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwqlab.org under Staff Access A -Value reported is the average of two or more determinations N3-Estimated concentration is < PQL and >MDL B1-Countable membranes with <20 colonies; Estimated NE -No established PQL 62- Counts from all filters were zero. P-Elevated PQL due to matrix interference and/or sample dilution B3- Countable membranes with more than 60 or 80 colonies; Estimated Q1-Holding time exceeded prior to receipt at lab. B4-Filters have -counts of both >60 or 80 and < 20; Estimated Q2- Holding time exceeded following receipt by lab B5-Too many colonies were present; too numerous to count (TNTC) PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity J2- Reported value'failed to meet QC criteria for either precision or accuracy; Estimated U- Samples analyzed for this compound but not detected J3-The sample matrix interfered with the ability to make any accurate determination; Estimated X1- Sample not analyzed for this compound J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated N1-The component has been tentatively identified based on mass spectral library search and has an estimated value AR Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 5 �- Sample ID AB38181 NC (DWQQ Laboratory Section Results ID: 6PO77WO0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 12:30 Visit ID CAS # Analyte Name PQL Result Qualifier Units Analyst/Date Approved By /Date LAB Sample temperature at receipt by lab 1.7 LISAUNUEKS HNAHKER Method Reference 11/26/08 11/26/08 =. MIC WET TOC in liquid 2.0 Method Reference APHA5310B-20th 2.1 mg/L BSWANSON CGREEN 12/11/08 12/16/.08 Total Dissolved Solids in liquid 12 70 mg/L AWILLIAMS CGREEN Method Reference APHA254OC-18TH 11/26/08- 12/3108 MET 7440-38-2 As by ICPMS 5.0 2.0 U ug/L JJURGEVICH ESTAFFORD Method Reference . EPA 200.8 12/3108 12/17/08 7440-38-3 Ba by ICP 10 36 ug/L DSTANLEY ESTAFFORD Method Reference EPA200.7 12/1/08 12/17/08 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/2108 12/17/68 7440-47-3 - Cr by ICPMS 10 (43 / ug/L JJURGEVICH Lb I A- -UHU Method Reference EPA 200.8 12/3/08 12/17/08 7439-92-1 Pb by ICPMS 10 10 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3/08 12/17/08 VOL Volatile Organics in liquid _TITLE_ ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1214/08' 75-78-1 Dichlorodifluoromethane 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 74-87-3 Chloromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1108 12/4/08 75-01-4 Vinyl Chloride 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 74-83-9 Bromomethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/l/08 12/4/08 75-00-3 Chloroethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 75-69-4 Trichlorofluoromethane 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 1214/08 75-36-4 1,1-Dichloroethene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/l/OS 1214108 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of Sample ID AB38181 XC DWQ Laboratory Section Results Location ID: 6PO77WQ0000601 Collect.Date:11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 12:30 Visit ID 75-09-2 . Methylene Chloride 10 Not detected ug/L A I tKKY KKtLLINU Method Reference EPA5030/62418260 12/1/08 12/4/08 156-60-5 trans-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 1634-04-4 Methyl Tert-Butyl Ether - 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 75-34-3 1,1-Dichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference, EPA5030/624/8260 12/1108. 12/4/08 156-59-4 cis-1,2-Dichloroethene 0.25 'Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 67-66-3 Chloroform 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5.030/624/8260 12/1/08 1214/08 590-20-7 2,2-Dichloropropane 0.25 Not detected ug/L 'ATERRY WELLING , Method Reference EPA5030/624/8266 1211/08 12/4/08 107-06-2 1,2-Dichloroethane . 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/OR 1214/08 71-55-6 1,1,1-Trichloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1108 12/4108 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 1214/08 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 12/4/08 71-43-2 Benzene 0.25 Not detected ug/L ATERRY WELLING. Method Reference EPA5030/624/8260 12/1/08 12/4/08 74-95-3 Dibromomethane 1.0 Not detected ug/L ATERRY WELLING - Method Reference EPA50361624/8260 1211/08 12/4108 78-87-5 1,2-Dichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211108 12/4108 79-01-6 Trichloroethene 0.25 0.23' N3 ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 75-27-4 Bromodichloromethane 0.25 Not detec ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08. 12/4/08 10061-01-5 cis-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5036/62418260 1211/08 1214/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 5 Sample ID AB38181 PVC wVQ Laboratory Section Results Location ID: 6PO77WQ0000601 Collect Date: 11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 12:30 Visit ID ,3-Dichloropropene . 0.25 Method Reference EPA5030/624/8260 12/1/08 1214/08 79-00-5 1,12-Trichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 12/4/08' 108-88-3 Toluene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1108 12/4/08 142-28-9 1,3-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference ' EPA5030/624/8260 1211/08 1214108 124-48-1 Dibromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 106-93-4 ' (EDB)1,2-Dibromoethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EP,A5030/624/8260 12/1/08 -12/4/08 127-18-4 Tetrachloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference. EPA5030/624/8260 12/1108 12/4108 108-90-7 Chlorobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 .12/4/08 100-41-4 Ethylbenzene. 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 75-25-2 Bromoform M Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/4/08 108-3873 m,p-Xylene 0.50 Not detected ug1L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 100-42-5- Styrene 0.25 Not detected ug/L ATERRY . RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING - Method Reference EPA5030/624/8260 12/1/08 12/4/08 630-20-6 1,1,1,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1108 12/4/08 95-47-6 o-Xylene 0.25 Not detected ug/L ATERRY RKELLING Method Reference • EPA5030/624/8260 1211108 12/4/08 96-18-4 1,2,3-Trichloropr9pane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 98-82-8 Isopropylbenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1108 12/4/08 108-86-1 Bromobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/4/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NO 27699-1623 (919) 733-3908 Page 4 of 5 ' Sample ID A638181 NC 1D VQ Laboratory -Section 1§sufts Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time::, 12:30 Visit ID iu;s-bb-i n-Nropylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08, 1214/08 95-49-8 2-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1/08 12/4/08 106-43-4 . 4-Chlorotoluene 0.25 Not detected ug/L. ATERRY WELLING Method Reference. EPA5030/624/8260 12/1/08 1214/08 108-67-8 1,3,5-Tnmethylbenzene 0.25 Not detected ug/L. ATERRY WELLING Method'Reference EPA5030/624/8260 12/1/08 12/4/08 98-06-6 tert-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260, 12/1/08 12/4/08 95-6376 1,2,4-Tnmethylbenzene _0.25 Not detected ug/L. ATERRY WELLING Method Reference , EPA5030/624/8260 12/1108 '12/4/08. 135-98-8 sec-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 543-73-1 m-Dichlorobenzene (1,3) 0.25 Not -detected ug/L ATERRY• WELLING Method Reference EPA5030/624/8260 12/1108 1214/08 106-46-7 p-Dichlorobenzene (1,4) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 1214/08 95-50-1 o-Dichlorobenzene (1,2) 0.25 Not detected ug/L ATERRY RKELLING- Method Reference EPA5030/624/8260 12/1/08 12/4/08 99-87-6 p4sopropyltoluene 0.25 Not detected ug/L ATERRY WELLING Method. Reference EPA5030/624/8260 12/1/08 12/4/08 104-51-8 n-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 - Iva lwlul1 IwIuNwNaIV, ��.V� ) rvo[ae[ec[eu ug/L AItKKY RKELLING Method Reference EPA5030/624/8260 \X 12/1108 12/4/08 120-82-1. 1,2,4-Tdchlorobenzene Ot50 Not detected ug/L ATERRY WELLING. Method Reference EPA5030/624/8260 - 12/1/08 12/4/08 91-20-3 Naphthalene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 12/4/08 87-68-3 Hexachlorobutadiene 0.50 Not detected ug/L •ATERRY WELLING Method Reference , EPA5030/624/8260 12/1/08 12/4/08 , 87-61-6 1,2,3-Tnchlorobenzene 1.0 Not detected ug/L ATERRY. WELLING Method Reference EPA50301624/8260 .12/1/08- 1214/08 Laboratory Section>> 1623 Mail Service Center; Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 GROUNDWATER FIELD/LAB FORM Location code_6P077WQ0000601 SAMPLE TYPE SAMPLE PRIORITY County_Richmond ® Water Routine Quad No Serial No. ❑ Soil ❑ Emergency Lat. Long. El Other ® Chain of Custody Report To: ARO(FRO MRO, RRO, WaRO, WiRO, WSRO, Kinston FO d. Trust, Central Off., Other: Shipped .by: Bus, ourie Hand Del., Other: Pur ose: Collector(s): Date I Time _ Baseline, Complain FIELD ANALYSES Owrier J)C li2.4r . pH 400 Spec. Cond.94 at 25°C. Location or Site Temp.10 . a °C Odor Description of sampling poi Appearance L �.�r — Q 0 E Sampling Method �l A Field Analysis By: . f Csrl Remarks BOD 310 mg/L COD High 340 mg/L COD Low 335 mg1L Coliform: MF Fecal 31616 /100ml Coliform: MF Total 31504 /100ml X TOC 680 mg/L Turbidity 76 NTU Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 mg/L Carbonate 445 mg/L Bicarbonate 440 mg/L Carbon dioxide 405 mg/L Chloride 940 mg/L Chromium: Hex 1032 ug/L Color: True 80 CU Cyanide 720 mg/L Lab Comments X Diss. Solids 70300 mg/L Fluoride 951 mg/L Hardness: Total 900 mg/L Hardness (non-carb) 902 mg/L Phenols 32730 ug/I Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Grease . mg/L NH3 as N 610 1 mg/L TKN as N 625 mg1L NO2 + NO3 as N 630 mg/L P: Total as P 665 mg/L Nitrate (NO3as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write, "DIS" in block. North Carolina Department of Environment and Natural Resources DIVISION OF WATER QUALITY -GROUNDWATER SECTION Al Lab Number Date,Received Rec'd By: From:Bus, ourier, Hand Del., Other: Data Entry 6y,:v Ck. • Date Reported: ;omplianpe .LUST, Pesticide Study, Federal Trust, Other: u I rG Samplelnterval (Pumping time, air temp., etc.) Ag-Silver 46566 u /L AI -Aluminum 46557 u /L X As -Arsenic 46551 u /L X Ba-Barium 46558 u /L Ca -Calcium 46552 m /L X Cd-Cadmium 46559 u /L X Cr-Chromium 46559 u /L Cu-Copper 46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 m /L Mg -Magnesium 46554 m /L Mn-Manganese 46565 u /L Na-Sodium 46556 m /L Ni-Nickel u /L X Pb-Lead 46564 u /L Se -Selenium u /L Zn-Zinc 46567 u /L Nitrogen Pesticides Acid Herbicides PCBs Semivolatile Organics TPH-Diesel Range Volatile Organics(VOA bottle)' TPH-Gasoline Range TPH-BTEX Gasoline Range LAB USE ONLY Temperature on arrival (°C): i County: RICHMOND River Basin Report To FROAP Collector: B TODD Region: FRO Sample Matrix: GROUNDWATER Loc. Type:. WATER SUPPLY Emergency Yes/No COC Yes/No Yes Location ID: 6PO77WQ0000601 Sample ID: AB38182 RECEIVED pF WAr�Cig 11 QGy PO Number# 8G1568 DEC 19 2008 > Date Received: Time Received: 11/26/2008 08:20 y Labworks LoginlD HPARKER DENR—FAYLLEREGIOKAALOMGE EfiEVI Date Reported: 12/17/08 Report Generated: 12/17/2008 VisitlD Loc. Descr.: CSX TRANSPORTATION INC / O� Collect Date: ' 11/25/2008 1 Collect Time:: 09:48 .. Sample Depth Sample Qualifiers and Comments Q v Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwqlab.org under Staff Access A -Value reported is the average of two or more determinations B1-Countable membranes with <20 colonies; Estimated N3-Estimated concentration is < PQL and >MDL' B2-Counts from all filters were zero. NE -No established PQL B3- Countable membranes with more than 60 or 80 colonies; Estimated P-Elevated PQL due to matrix interference and/or sample dilution B4-Filters have counts of both >60 or 80 and < 20; Estimated Q1-Holding time exceeded prior to receipt at lab. Q2- Holding time exceeded following receipt by lab B5 Too many colonies were present; too numerous to count (TNTC) PQL­ Practical Quantitation Limit -subject to change due to instrument sensitivity J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated J3-The sample matrix interfered with the ability to make any accurate determination; Estimated U-Samples analyzed'for this compound but not detected J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated X1- Sample not analyzed for this compound NI -The component has been tentatively identified based on mass spectral library search and has an estimated value I AR Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 5 Location ID: 6PO77WQ0000601 Loc. Descr.: CSX TRANSPORTATION INC Visit ID LAB MIC WET XC DWQ Laboratory Section Results Collect Date: Collect Time: 11/25/2608 09:48 � Sample temperature at receipt by lab 1.7 °C DSAUNDERS HPARKER Method Reference 11/26/08 11/26/08 TOC in liquid 2.0 2 U mg/L BSWANSON CGREEN Method Reference APHA531bB-20th 12/11/08 12/16/08 Total Dissolved Solids in liquid 12 136 mg/L AWILLIAMS CGREE_N Method Reference APHA254OC-18TH 11/261b8 12/3/08 MET 7440-38-2 As by ICPMS 5.0 2.0 U ug/L JJURGEVICH ESTAFFO�D Method Reference EPA 200.8 1213108 12/17/08 7440-38-3 Be by ICP 10 50 ug/L DSTANLEY ESTAFFORD Method Reference EPA 200.7 12/1/08 12/17/08 7440-43-9 Cd by ICPMS 1.0 .19 U ug/L JJURGEVICH ESTAFFORD Method Reference EPA200.8 1 12/2/08 12/17/08 7440-47-3 Cr by ICPMS 10 26 ug/L JJURGEVICH ESTAFFORD Method Reference EPA 200.8 12/3108 12/17/08 Method Reference EPA 200.8 12/3108 12/17/08 VOL Volatile Organics in liquid TITLE_ ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 12/4/08 75-78-1 Dichlorodifluoromethane 1.0 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 74-87-3 Chloromethane 0.50 Not detected ug/L ATERRY RKELLING Method Reference . EPA5030/624/8260 12/1/08 1214/08 75-01-4 Vinyl Chloride 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 12/4/08 74-83-9 Bromomethane 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 75-00-3 Chloroethane 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 1214/08 75-69-4 Trichlorofluoromethane 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 12/1/08 1214/08 75-35-4 1,1-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 5 NC DWQ .Laboratory Section Results "Q"'"'"`" "0130'U` Location ID: 6P077WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time::. 09:48 Visit.ID 75-09-2 Methylene Chloride 10 Not detected ug/L A i tKKY hKtLLINU - Method.Reference EPA5030/624/8260 12/1/08 1214/08 156-60-5 trans-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 1634-04-4 Methyl Tert-Butyl Ether 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 75-34-3 1,17Dichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214108 156-59-4 cis-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211108 .12/4/08 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference . EPA5030/624/8260 12/1/08 12/4108 67-66-3 Chloroform 0.25 3.5 ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 .12/1/08 12/4/08 590-20-7 2,2-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4108 107-06-2r .1,2-Dichloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08, 71-55-6 1,1,1-Trcchloroethane 0.25 Not detected. ug/L ATERRY RKELLING 'Method Reference EPA5030/624/8260 12/1/08 12/4/08 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 1211/08 12/4/08 . 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY RKELLING - Method Reference EPA5030/624/8260 1211/08 1214/08 71-43-2 Benzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/4/08 74-95-3 Dibromomethane 1,0 Not detected_ ug/L ATERRY RKELLING Method Reference . EPA5030/624/8260 12/1/08 12/4/08- 78-87-5 1,2-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1108 12/4/08 79-01-6 Trichioroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 75-27-4 Bromodichloromethane 0.25 Not detected ug/,L ATERRY RKELLING. Method Reference EPA5030/624/8260 12/1/08 12/4/08 10061-01-5 cis-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 12/4/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 5 NC' WQ Laboratory Section Results Sample ID AB38182 Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 09:48 Visit ID 10061-02-6 trans-1,3-Dichloropropene 0.25 Not detected Ug/L AI LMY NKtLLINU Method Reference. EPA50301624/8260 12/1/08 1214/08 79-00-5 1,1,2-Tdchloroethane .0.25 • Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 12/4/08 108-88-3 Toluene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1108 12/4/08 142-28-9 1,3-Dlchloropropane 0.25 Not detected ug/L' ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/4/08 124-48-1 Dibromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 106-93-4 (EDB)1,2-Dibromoethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 127-18-4 Tetrachloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 1211/08 12/4/08 108-90-7 Chlorobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 . 100=41-4 Ethylbenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 75-25-2 Bromoform 1.0 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 12/1/08 1214/08 108-38-3 m,p-Xylene 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 1211/08 12/4/08 100-42-5 Styrene 0.25 Not detected ug/L ATERRY RKELLING . Method Reference EPA5030/624/8260 1211/08 12/4/08 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference, EPA50301624/8260 12/1108 12/4/08 630-20-6 1,1,1,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING " Method Reference EPA5030/624/8260 12/1/08 12/4/08 95-47-6 o-Xylene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 96-18-4 1,2,3-Trichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference, EPA5030/62418260 12/1/08 1214/08 98782-8 Isopropylbenzene 0.25 Not detected ug/L ATERRY RKELLING. Method Reference EPA5030/624/8260 1211/08 12/4/08 108-86-1 Bromobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 4 of 5 Sample ID AB38182 kN NC DWQ La6oratory Section Results Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC - Collect Time:: 09:48 Visit ID 103-65-1 n-Propylbenzene 0.25 Not detected Ug/L AI tKKY KKtLLINU Method Reference EPA5030/62418260 12/1/08 12/4/08 95-49-8 2-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4108 106-43-4 4-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4108 108-67-8 1,3,5-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 1211/08 .12/4108 98-06-6 tert-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 95-63-6 1,2,4-Trmethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1214108 135-98-8 sec-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 1211/08 1214/08 543-73-1 m-Dichlorobenzene (1,3) -0.25 Not detected ug/L ATERRY WELLING Methbd'Reference EPA5030/624/8260 12/1/08 12/4/08 106-46-7 p-Dichlorobenzene (1,4) 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 95-50-1 o-Dichlorobenzene (1,2) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 99-87-6 p-Isopropyltoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 1211/08 12/4108 104-51-8 n-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1/08 1214108 96-12-8 1,2-Dibromo-3-Chloropropane 2.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 1214/08 120-82-1 1,2,4-Trichlorobenzene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1/08 12/4/08 91-20-3 Naphthalene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 12/1/08 12/4/08 87-68-3 Hexachlorobutadiene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 12/1108 ' 1214/08 87-61-6 1,2,3-7richlorobenzene 1.0 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 12/1/08 12/4108 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 ,• v North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources ( 2( ) (. � DIVISION OF WATER QUALITY -GROUNDWATER SECTION Location code -6P077.WQ0000601 County_Rich Quad No Serial No. Lat. Long. SAMPLE TYPE SAMPLE PRIORITY �(r r l ® Water Routine uJ Lab Number O15/1 J �� � 3 31$ 2 ElSoil ❑ Emergency Date Received I— a9b '� Time: 7) El Other Rec'd By: From: Bus, ourier, Hand Del., JIL® Chain of Custody Other: IHO Report To: ARCED MRO, RRO, WaRO, WiRO, Data Entry B : Ck: WSRO, Kinston FO,Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, oune Hand Del., Other: 4 F Purppse: Collector(s): Date_Ll JZ Time Oq q& Baseline, Complaint Complian e LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES � Owner dS j( %,>e,,Q,�.t (�a ne pH 400 Spec. Cond.94 5 at 25°C Location or Site ,F Temp.lo °C Odor Description of sampling poiri4 to C-A Appearance Sampling Method 4Ai le Sample Interval Field Analysis By: Remarks 1HUMD. bailer. etc.] LABORATORY ANALYSES (Pumping time, air temp., etc.) BOD 310 mg/L COD High 340 mg/L COD Low 335 mg/L Coliform: MF Fecal 31616 /100ml Coliform: MF Total 31504 /loom! X TOC 680 mg/L Turbidity 76 NTLI Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 mg/L Carbonate 445 mg/L Bicarbonate 440 mglL- Carbon dioxide 405 mg/L Chloride. 940 mg/L Chromium: Hex 1032 ug/L Color: True 80 Cu Cyanide 720 mg/L Lab X Diss. Solids 70300 mg/L Fluoride 951 mg/L Hardness: Total 900 mg/L Hardness (non-carb) 902 mg/L Phenols 32730 ug/I Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Grease mg/L NH3 as N 610 mg/L TKN as N 625 mg/L NO2 + NO, as N 630 mg/L P: Total as P 665 mg/L Nitrate (NO3as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block. Ag-Silver 46566 u /L AI -Aluminum 46557 u /L X As -Arsenic 46551 u /L X Ba-Barium 46558 u /L Ca -Calcium 46552 m /L X Cd-Cadmium 46559 u /L X Cr-Chromium'46559 u /L Cu-Copper 46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 m /L Mg -Magnesium 46554 m /L Mn-Manganese 46565 u /L Na-Sodium 46556 m /L Ni-Nickel u /L X Pb-Lead 46564 u /L Se -Selenium u /L Zn-Zinc 46567 u /L Or anochlorine Pesticides Or ano hos horus Pesticides Nitrogen Pesticides Acid Herbicides PCBs Semivolatile Organics TPH-Diesel Range Volatile Organics(VOA bottle TPH-Gasoline Range TPH-BTEX Gasoline Range LAB USE ONLY / Temperature on arrival (°C): i County: RICHMOND River Basin Report To FROAP Collector: B TODD Region: FRO Sample Matrix: GROUNDWATER Loc. Type: TRIP BLANK Emergency Yes/No COC Yes/No Yes II Location ID: 6PO77W00000601 'ection RECEIVED DEC 0 4 2008 DENR-FAYEMILLEREGIONAL OFRCE I VisitlD Loc. Descr.: CSX TRANSPORTATION INC Collect Date: 11/25/2008 Collect Time:: 09:45 Sample Qualifiers and Comments Sample ID: AB38183 PO Number# 8G1559 Date Received: 11/26/2008 Time Received: 08:20 Labworks LoginlD HPARKER Date Reported: 12/1/08 Report Generated: 12/01/2008 1C)da Sample Depth Routine Qualifiers For a more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access A -Value reported is the average of two or more determinations N3-Estimated concentration is < PQL and >MDL B1-Countable membranes with <20 colonies; Estimated NE -No established PQL B2- Counts from all filters were zero. P-Elevated PQL due to matrix interference and/or sample dilution B3- Countable membranes with more than 60 or 80 colonies; Estimated B4-Filters have counts of both >60 or 80 and < 20; Estimated Q1-Holding time exceeded prior to receipt at lab. Q2- Holding time exceeded following receipt by lab B5-Too many colonies were present; too numerous to count (TNTC) PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated U- Samples analyzed for this compound but not.detected _J3-The sample matrix interfered with the ability to make any accurate determination; Estimated X1- Sample not analyzed for this compound J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated N1-The component has been tentatively identified based on mass spectral library search and has an estimated value AR Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 5 Sample ID AB38183 XC DWQ .Laboratory Section Results Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 09:45 Visit ID CAS # Analyte Name PQL Result Qualifier Units Analyst/Date Approved By /Date LAB Sample temperature at receipt by lab 1.7 °C DSAUNDERS HPARKER Method Reference 11/26/08 11/26/08 VOL Volatile. Organics in liquid _TITLE_ ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 .11/26/08 12/1/08 75-78-1 Dichlorodifluoromethane 1.0 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08. 74-87-3. Chloromethane 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-01-4 Vinyl Chloride 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 74-83-9 Bromomethane 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-00-3 Chloroethane 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-69-4 Trichlorofluoromethane 0.50 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-35-4 1,1-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 1211108 75-09-2 Methylene Chloride 10. Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 156-60-5 trans-1,2-Dichloroethene, 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1108 1634-04-4 Methyl Ter[ -Butyl Ether 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-34-3 1,1-Dichloroethane 0:25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 156-59-4 cis-1,2-Dichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 11/26/08 1211/08 74-97-5 Bromochloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 67-66-3 Chloroform 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 590-20-7 2,2-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 5 Sample ID AB38183 NC (DWQQ Laboratory Section Results Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 09:45 Visit ID 107-06-2 1,2-Dichloroethane 0.25 Not detected ug/L A I LKKY KKtLLINU Method Reference EPA5030/624/8260 11/26/08 1211/08 71-55-6 1,1,1-Trichloroethane 0.25 Not detected tig/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 563-58-6 1,1-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 56-23-5 Carbon Tetrachloride 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 71-43-2 Benzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 74-95-3 Dibromomethane 1.01 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 78-87-5 1,2-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 79-01-6 Trichloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 75-27-4 Bromodichloromethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/62418260 11/26/08 1211108 10061-01-5 cis-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 10061-02-6 trans-1,3-Dichloropropene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 79-00-5 1,1,2-Trichloroethane 0.25 Not detected ug/.L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 108-88-3 Toluene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 142-28-9 1,3-Dichloropropane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08, 12/1/08 124-48-1 Dibromochloromethane 0.25 Not detected ug/L. ATERRY RKELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 106-93-4 (EDB)1,2-Dibromoethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08. 127-18-4 Tetrachloroethene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 108-90-7 Chlorobenzene 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center,' Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 5 NC DWQ Laboratory Section ResultsSample ID AB38183 Location ID: 6PO77WQ0000601 Collect Date: 11/25/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 09:45 Visit ID Method Reference EPA5030/62418260 11/26/08 12/1/08 75-25-2 Bromoform 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 108-38-3 m,p-Xylene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1/08 100-42-5 Styrene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 1211/08 79-34-5 1,1,2,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY RKELLING Method Reference EPA5030/624/8260 11/26/08. 12/1/08 630-20-6 1,1,1,2-Tetrachloroethane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 95-47-6 o-Xylene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 96-18-4 1,2,3-Trichloropropane 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 98-82-8 Isopropylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 108-86-1 Bromobenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211108 103-65-1 n-Propylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211/08 95-49-8 2-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 106-43-4 4-Chlorotoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 108-67-8 1,3,5-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 98-06-6 tert-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/62418260 11/26/08 12/1108 95-63-6 1,2,4-Trimethylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 135-98-8 sec-Butylbenzene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 543-73-1 m-Dichlorobenzene (1,3) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 4 of 5 jr\rC DWQQ Laboratory Section Resufts Sample ID AB38183 Location ID: 6PO77WQ0000601 Collect Date: 11/26/2008 Loc. Descr.: CSX TRANSPORTATION INC Collect Time:: 09:45 " Visit ID IUb-4b-/ p-uicnlorooenzene(1,4)- U.Zb Not cetectea Ug/L AIEHHY RKELLING Method Reference - EPA5030/624/8260 11/26/08 12/1/08 - 95-50-1 o-Dichlorobenzene (1,2) 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 99-87-6 p-Isopropyltoluene 0.25 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08' 104-51-8 n-Butylbenzene 0.25• Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 96-12-8 1,2-Dibromo-3-Chloropropane 2.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/1/08 120-82-1 1,2,4-Trichlorobenzene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 _ 11/26/08 12/1/08 91-20-3 Naphthalene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 12/1/08 87-68-3 Hexachlorobutadiene 0.50 Not detected ug/L ATERRY WELLING Method Reference EPA50301624/8260 11/26/08 1211/08 87-61-6 1,2,3-Trichlorobenzene 1.0 Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 1211108 VOC'S BY GC/MS Not detected ug/L ATERRY WELLING Method Reference EPA5030/624/8260 11/26/08 12/l/0$ Laboratory Section>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 5 of 5 North Carolina GROUNDWATER FIELD/LAB FORM TRIP BLAN Department of Environment and Natural Resources DIVISION OF WATER QUALITY -GROUNDWATER SECTION Location code_6P077WQ0000601 SAMPLE TYPE SAMPLE PRIORITY C�/` County_Richmond LX Water la Routine . Lab Number UV (sS9 M 3 O ffl3 El Soil El Emergency gO Quad No Serial No. Other Date Received ❑ Lat. Long. 2 Rec'd By: From:Bus, ourie , Hand Del., ® Chain of Custody Other: Report To: ARO, RO RO, RRO, WaRO, WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, GR Hand Del —Other: Purpose: Collector(s): Date : Time S Baseline, Complaint Complianc , LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner C 05 4 S p (°f`ie pH 400 - A 1,_ Spec. Cond.9a at 250C Location or Site e Temp.lo cC Odor1Z Description of sampling point 1- A Appearance Sampling Method Sample Interval Field Analysis By: Remarks umo. ai er. etc.) LABORATORY ANALYSES (Pumping time, air temp., etc.) BOD 310 mg/L COD High 340 mg/L COD Low 335 mg/L Coliform: MF Fecal 31616 /loom( Coliform: MF Total 31504 /loom( TOC 680 mg/L Turbidity 76 NTU Residue, Suspended 530 mg/L pH 403 units Alkalinity to pH 4.5 410 mg/L Alkalinity to pH 8.3 415 mg/L Carbonate 445 mg/L Bicarbonate 440 mg/L Carbon dioxide 405 mg/L Chloride 940 mg/L Chromium: Hex 1032 ug/L Color: True 80 Cu Cyanide 720 mg/L Lab Diss. Solids 70300 mg/L Fluoride 951 mg/L Hardness: Total 900 mg/L Hardness (non-carb) 902• mg/L Phenols 32730 ug/I Specific Cond. 95 uMhos/cm Sulfate 945 mg/L Sulfide 745 mg/L Oil and Grease mg/L NH3 as N 610 mg/L TKN as N 625 mg/L NO2 + NO3 as N 630 mg/L P: Total as P 665 mg/L Nitrate (NO3 as N) 620 mg/L Nitrite (NO2 as N) 615 mg/L GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block. Ag-Silver 46566 u /L AI -Aluminum 46557 u /L As -Arsenic 46551 u /L Ba-Barium 46558 u /L Ca -Calcium 46552 m /L Cd-Cadmium 46559 u /L Cr-Chromium 46559 u /L Cu-Copper 46562 u /L Fe -Iron 46563 u /L Hg-Mercury 71900 u /L K-Potassium 46555 m /L Mg -Magnesium 46554 m /L Mn-Manganese 46565 u /L Na-Sodium 46556 m /L Ni-Nickel u /L Pb-Lead 46564 u /L Se -Selenium u /L Zn-Zinc 46567 u /L Or anochlorine Pesticides Or ano hos horus Pesticides Nitrogen Pesticides Acid Herbicides PCBs Semivolatile Organics TPH-Diesel'Ran e X TRIP BLANK Volatile Organics(VOA bottle TPH-Gasoline Range TPH-BTEX Gasoline Range LAB USE ONLY Temperature on arrival (°C): 4 i 77f• ,�� `y I? ,Zliy 2 i 5-. k'iS' YJ' .,3v `F S.'- ='.lit, '�. ; S Y f' _ ) V ID#: 4 B CSX TRANSPORTATION (HAMLET) MIKE GREGORY 173 CSX DRIVE DATE COLLECTED: 12/16/08 HAMLET ,NC 28345 DATE REPORTED 12/30/08 REVIEWED BY. PARAMETERS Nitrate Nitrogen, mg/l Total Organic Carbon, mg/l Total Dissolved Residue, mg/1 Arsenic, mg/l Barium, mg/l Cadmium, mg/1 Total Chromium, mg/l Lead, mg/l DAF Analysis Method Date Analyst Code 0.88 12/17/08 TWA EPA353.2 6.90 12/22/08 SEJ SM5310C 195 12/22/08 TRB SM2540C <0.005 12/23/08 CMF SM3113B 0.015 12/18/08 LFJ EPA200.7 <0.001 12/24/08 CMF SM3113B <0.005 12/18/08 LFJ EPA200.7 <0.005 12/19/08 CMF SM3113B I;nvi"onmbxat 1, Inc. ICHANT1,1 OF SC+U51rI'lC'DY IR, ECORD P.O. Box 7085, 114 Oakinont Dr. Page 1 of Greenville, NC 27858 - Phone (252) 756-6208 o Fax (252) 756-0633 DISINFEiCTIUN � CHLORI!\!cNEUTRALIZED ATCOLLECTION CtILORINE CLIENT. 4 B Week: 1 - pH CHECK (LAB) P P P P I COIN-TAINER TYPE, P/G CSX TRANSPORTATION (HAMLET) NONE MIKE GREGORY UJI _ A _ - C ___ A A (;HErrl!CAl_f'RESEf1VATI0P! 173 CSX DRIVE HAMLET NC 28345 - _- -- (910) 205-6379 L Lij o`nc Z i UJ Z LU 1 l i-!NO E - F ICL CL O p[ O (0 I 1,SO, F - ZINC ACETATE -xLu COLLECTION 5z LL E) o0 LL ¢ ¢ 0E � y z U (n ( G-!NATHIOSULFATE ^� SAMPLE LOCATION DAT TIME DAF C) • 4 i z; - CLASSIFICATION: WASTEWATER (INPDES) DRINKINGWATER I— X a DWQ/GiP! SOLID WASTE SECTION -�� CHAIN OF CUSTODY MAINTAINED DURING SHIP JENTiDELIVERY n! -- - - -— F I SAMPLES COLLECTED BY: 1 _. (Please//Print) r-._._._ --- � lam- l�✓,�(___-�� �� -- SAMPLES RECEIVED IN LAB AT ' _'r'� °C RELIN IS BY (SIG.) (S' LER) DATFJTIME RECEIVED ( (SIB : �, DATETTINIE COfvIIVIENTS: UIINIE DATEMME - — ------ ELIP SHED BY (S1U.) RECEIVED BY (. ! .) RELINQUIS14ED BY (SIG.) DATEMME RECEIVED BY (SIG.) DATEMME Instructions for completing this form are on the reverse side. Sampler must place a "C for composite sample or a "G" for N o 1 7 6 � t6;, _-- Groh can,nln in thn,hlnckc.nhrrnrQ fnr anrh nni -.tr,r raruJnsted. 3 __. CSX QA/QC DATA SUMMARY FACILITY: Hamlet SAMPLE DATE: 12/16/08 SAMPLE LOCATION: DAF PARAMETER: Nitrate Nitrogen Duplicates RPD =1.5 % (acceptable value is < 14.75%) Quality Control'Standard Recovery =108.0 % (acceptable value is 85-115%) Blank Value = 0.00 mg/1 PARAMETER: Total Organic Carbon Duplicates RPD = 0.5% (acceptable value is <10.84%) Quality Control Standard Recovery = 94.0% (acceptable value is 85-115%) Blank Value = 0.00 mg/1 PARAMETER: Total Dissolved Residue Duplicates RPD = 0.3 % (acceptable value is <6.15%) *Quality Control Standard Recovery =102.6 % (acceptable value is 90-100%) Blank Value=1.5mg/l * Value reported for required quarterly QC standard. RPD (Relative Percent Difference) Quality control data for individual metals analyses is attached on the following pages. TEST:-. A - GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: (Z / ?, /y 9 Analyst Initials: -- „, Blank Check Value, ug/l ( 0.0 1 Result, ug/l O rem Sequence # L- RL ( S Acceptance Pass ---Fail ( ) < RL Initial Calibration Verification Value, ug/1 L22 o Result, ug/l ( Z7-a,?) Sequence # 1U % Recovery 6r_k Acceptance +10% Pass ---Fail ( :�'( ) Detection Limit Standard Value, ug/l Result, ug/l S. ZG 3- Sequence # _V % Recovery / O Acceptance +10% Pass --Fail Initial Calibration Levels Value, ug/l 2. v Value, ug/l S",O Value, ug/l ( 1p.-O Value, ug/l ems; d ) Value, ug/l 52;1111) Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank Md a -le ( 0.0 ) U. Uv�) t� ! Z ) ; < RL a' /- /--/�< Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail LCS (Second Source mid -point) ( ZS;O _ ( z � ( ( IUl+15%—) Digested Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail +20% Matrix Spike Z S D Z S G y ( t f ) 163 C_�Ir (� Sample Name: #1 f _,/ Client ID# ( 3Ga Sample Result, ug/l Sequence # Location Code: Date: !Z-/ 5 Digested MS Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail +20% Duplicate 91 (Z j�� l�) (� ; G l(_�) !O RPD Acceptance Pass-- Fail Spike Duplicate Results (� RPD <20% (__ } (_� Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail ! Digested Method Blank ( 0.0 ) ( ) ) < RL j LCS (Second Source mid -point) Value, ug/l Result, ug/l Sequence # % Recovery Acceptance +15% Pass- -=Fail lr"gested i�,iatrir• Spike Spike Amount, ug/l (_� Spike Result, ug/l L_� Sequence # (� % Recovery (� Acceptance Pass ---Fail +20% Sample Name: #2 Client 1D9 Sample Result, ug/l Sequence # Location Code: Date: _ Digested MS Duplicate #1 Spike Amount, ug/l ( Spike Result, ug/] ( Sequence # % Recovery ) Acceptance Pass ---Fail +_20% RPD Acceptance Pass ---Fail Duplicate Results ( ) RPD <20% (_) (_) ISpike i Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank 0.0 .--) . ( ) < RL () ( ) Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail LCS (Second Source mid -point) ( +15% O ( ) Digested Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail +20% Matrix Spike . Sample Name: #3 Client ID# _ Sample Result, ug/l Sequence # Location Code: Date: Digested MS Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail +20% Duplicate #1 )() (_) RPD Acceptance Pass ---Fail Spike Duplicate Results ( ) RPD <20% (_) L_) . TES'': N GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: ' )z / !' / of Analyst Initials: z1-:�PkC Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail < RL Blank Check Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail Initial Calibration. Verification (z C' el—) /a r +10% Jj ( Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail . Detection Limit Standard S o 5 -I fV +`� +_10% Value, ug/l Value, ug/l Value, ug/1 Value, ug/l Value, ug/l Initial Calibration Levels -G, G S• U Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank ./n� !l-/9 ( 0.0 ) -0. dG y f� ) _) < RL Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail LCS (Second Source mid -point) (7 s"- ) ( Z `� >' ! / (_q � +15% Digested Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail +_20% Matrix Spike ZS" U �. W) Sample Name: Client ID# 1 Sample Result, ug/l Sequence # Location Code: Date: ! 2 - /9 Digested MS Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail # 1 ( 2 s' d ( ZG. iG / �( ) r'a -' +20% (✓Y( ) _Duplicate RPD Acceptance Pass ---Fail / Spike Duplicate Results RPD <20% ' Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail L Digested Method Blank ( 0.0 < RL O I Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail LCS (Second Source mid -point) ) +15% ) (__) Digested k'atrix Spike Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail (_) (j +20% Sample Name: #2 ` Client ID# ' Sample Result, ug/l Sequence # Location Code: I Date: Digested MS Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail +20% Duplicate#1 ( ( ( ( ) ( ( ) RPD Acceptance Pass ---Fail Spike Duplicate Results ( ) RPD <20% U (_) Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail t Digested Method Blank L 0.0 _L) ( < RL Value; ug/I Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail LCS (Second Source mid -point) ( ) ( ( +15% ( ( ) Digested Matrix Spike Spike Amount, ug/1 �� Spike Result, ug/l �� Sequence # �� % Recovery () Acceptance Pass= --Fail (_j (j -+20% Sample Name: #3 Client ID# _ Sample Result, ug/l Sequence # Location Code: Date: Digested MS Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail +20% Du licate #1 _) L ( (_) RPD Acceptance Pass ---Fail Spike Duplicate Results (__) RPD <20% Date of Analysis 12/18/2008 Ba :Digested Method Blank I Second Source Digested LCS jested Matrix Spike — — i Spike Amount, ug/I 500 _ Bottle # ; Sample Name 369 Client ID # Location Code Date _ jested Matrix Spike Dup _ ug/L 500 TAR PAMLICO ICP Ongoing Quality Control Analyst Initials LET Value Result, ug/L Sequence # RL 0.0000 1.4000 16 10 Value Result, ug/L Sequence # % Recovery 500 456 1 91 Spike Results, up/L Sequence # % Recovery — 498.2— 3 95 1300 Sample Result, Ug/L Sequence # ST01 21.7 2 12/15/2008 Acceptance Pass/Fail <= RL LXj U _ Acceptance Pass/Fail +/- 15% t_X,_ (_j Acceptance +/- 20 % (WW) Pass/Fail +/- 30% (DWI ; L)_) U Spike Results, ug/L Sequence # - % Recovery ' Pass/Fail 481.91 4 92 LX-) L_ RPD Acceptance <20% Pass/Fail 3 (_X_) L -r . Digested Method Blank Value Result, ug/L Sequence # RL Acceptance Pass/Fail 0.0000 0.9000 16 -- —= 5.0 --- -- <= RL -- - LX, (� - )— --- _ — Second Source Digested LCS —... Value --- ..—. Result, ug/L Sequence # % Recovery Acceptance Pass/Fail 500 466.4 1 93 +/- 15% LXJ U _ --�'----` — -' Spike Results, i _ Acceptance Digested Matrix Spike ue/L Sequence # /° Recovery +1- 20 % (WW) Pass/Fail Spike mo nt, ug/l i 490.4 3.. 98 -- - +1-,30%JDW) Bottle # iSample Name TAR PAMLICO 369 Client ID # 1300 -Sample Result, Ug/L Sequence # Location Code STOS �s�+�� _-;.�.;L;� 3.7' 2 !Date - 12/15/2008 Digested Matrix Spike Dup ': —_ ug/L I Spike Results, ug/L Sequence # % Recovery i Pass/Fail 500 f " ` 472.4 4 9_4 - -- — LXJ L-) RPD Acceptance <20% Pass/Fail 4 LX-) (—) �- BEST:- GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: l2 / 2 V/ O Analyst Initials: e>ts41 Blank Check Value, ug/I Result, ua/l 0: �� � Sequence # RL . Acceptance Pass ---Fail L v)'( � < RL Initial Calibration Verification Value, ug/1 1_ 5 0 Result, ug/I ( 2. S 9y) Sequence # % Recovery /G `� % Recovery Acceptance ±10%-( Pass ---Fail ) Detection Limit Standard Value, ug/I Result', ug/l Sequence # Acceptance ±10% Pass- Fail Initial Calibration Levels Value, ug/1 Value, ug/I Value, ug/I Value, ug/I Value, ug/1 Digested Method Blank //1P 12-le Value, ug/I 0.0 Result, uJl : U: Sequence # ! ) RL I _) Acceptance < RL Pass ---Fail ( �'( ) d6 i 2.-/y LCS (Second Source mid -point) Value, ug/I ( Z, SU) Result, ug/I (� • 535- Sequence # 6 % Recovery lc� / ) Acceptance +15% Pass ---Fail Digested Matrix Spike Spike Amount, ug/I Spike Result, ug/I Z..Y7y Sequence # ( i 7 ) % Recovery ( 7 ) Acceptance Pass --Fail L (_) +20% 91 Sample Name: •%G1%1.411 3�`l Client 1D# /3 oG Location Code: t%o / Sample Result, ug/1 Sequence # Date: z - I f Digested MS 1 Duplicate 41 Spike Amount, ug/l ( Z• sD) Spike Result, ug/I (-� Y�? Sequence # % Recovery `T'7 Acceptance Pass ---Fail +20% RPD ( G� _) Acceptance RPD < 0% Pass ---Fail — . Spike Duplicate Results Value, ug/I Result, ug/I Sequence # RL Acceptance Pass ---Fail Dif ested Method Blank f'/'!Z i7-27y 0.0 -U, e_1_1 _) ( ) < RL L 0 C, / Z-;( Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail Value, ug/I LCS (Second Source mid -point) �. s D ) Z. q d ( �j ) ( 17 ) ±15% Digested Spike Amount, ug/1 Spike Result, ug/I Sequence # % Recovery Acceptance Pass ---Fail +20% i'Vistrix Spike i vo Sample Name: #2 T� ,� l �d u16 Client ID# / D 0). Sample Result, ug/I Sequence # Location Code: - • l2 Date: 1 z-/s Digested MS Spike Amount, ug/l Spike Result, ug/I Sequence # % Recovery Acceptance Pass ---Fail +20% Dup licate#1 RPD Acceptance Pass ---Fail Spike Duplicate Results RPD <20% � ) Value, ug/I Result, ug/I Sequence # RL Acceptance Pass ---Fail Digested Method Blank ( 0.0 < RL ( ( ) Result, ug/I Sequence # % Recovery Acceptance Pass ---Fail Value, ug/I LCS (Second Source mid -point) ( ) ( ) ( Spike Result, ug/I Sequence # ) % Recovery +15% ( -). ( ) Digested Spike Amount, ug/I Acceptance Pass ---Fail +20% Matrix Spike U (�� L� ( � Sample Name: ♦ T.7 i Client ID# _ Sample Result, ug/I Sequence # I Location Code: Date: Digested MS ' Spike Amount, ug/I Spike Result, ug/I Sequence # % Recovery Acceptance Pass ---Fail RPD Acceptance Pass ---Fail Spike Duplicate Results (__) RPD <20% (__) (_) Report to: FRO GROUNDWATER SECTION CHAIN OF CUSTODY (COC) RECORD NC DENR/DWQ LABORATORY (check one): I® 1 CENTRAL [❑ 1 ARO I❑ 1 WaRO Page 1 of 1 For Investigation of: CSX Transportation Inc. Incident No. WQ0000601 Sample collector (print name) and GW-54 forms completed by: Sample collector's signature: Field storage conditions and location (when applicable): Lab_ Use Only LAB NO. SAMPLE ID QUAD. NO. LOCATION r zJ� D`AtL LE �L TID�1rr /I S U� NUMBER OF CONTAINERS MW-1 CSX Transportation Inc. Hamlet, NC i 490 "7 MW-2 Same as above i ­:5— ZY/^� �V .Az MW-3 Same as above 1 �� �f MW-4 Same as above , I" MW-5 Same as above I O f S j I .W 7 MW-6 Same as above O0,ry VV I/Z� -9 ` MW-7 Same as above�� MW- 8 Same as above �,9 ,; qg / c7 TB-1 same as above t 1 �z 3 Relinquished by (signature): Date Time Received by (signature): Date Time Relinquished by (signature): Date Time Received by (signature): Date Time Relinquished by (signature): Date Time Received by (signature): Date Time Method of Shipment (check one): State Courier® Hand -delivered❑ Federal Express❑ UPS❑ Other: Security Type and Conditions: Sealed by: Broken by: , , 1NTECALADURA1'UKY UHAIN UY UUNIUDY - Lab Use Only LAB NUMBERS ,"" NUMBER ANALYSES, RELINQUISHED RECEIVED. DATE TIME- _: FROM THROUGII' BOTTLESREQUESTED BY ;"' BY: Report to: FRO GROUNDWATER SECTION CHAIN OF CUSTODY (COC) RECORD NC DENRIDWQ LABORATORY (check one): JE1 I CENTRAL [E] I ARO IE1 I WaRO Page I of I RECE[VUE? For Investigation of. CSX . Transportation Inc. WQ0000601. DEC -012008 Incident No. 11 Sample collector (print name) and GW-54 forms completed by:. Bill Todd Sample collector's signature: 46ca nFNR—FAYETULLE REGIONAL OFM Field storage conditions and location (when applicable): -,Lab Use Only, NUMBER DATE TIME OF SAMPLE ID QUAD. NO. LOCATION SAMPLED SAMPLED CONTAINERS MW=l cjea.4 1101** CSX Transportation Inc. 11/25/08 7 Hamlet NC f MW-2 cl"i d I/V.4 Same as above 11/25/08 7 Mw Same as above 11/25/08 7 MW-4 C, (,—A, 4 Same as above 11/25/08 7 MW-5 Same as above 11/25/08 7 d1AV )/z3fl -Z -r,-I& MW-6 Same as above 11/25/08 Rat 6 lb MW-7 Same as above 11/25/08 7 6 Ben MW-8 Same as above 11/25/08 I -YAM 7 TB- I Same as above 11/25/08 3 Relinquished by (signature): Date TimepxRe ve-d si t re): Date Time % 4:6 0 17 11 Do Relinquished by (signature): Date! Time - Received by (signktu-rj). Date Time Relinquished by (signature): Date Time Received by (signature): Date Time Method of Shipment (check one): State Courier® Hand-deliveredEl Federal ExpressEl UPSEI Other: Security Type and Conditions: Sealed by: Benibiy 0 A' K ti v - IIN'I'IKALABUI<,AL(JKYUHAIINUk'UUN'I'UDY,- LabUseUnly NUMBERti ANALYSES'--"", 'RELINQUISHED ll���'��,��-.---'-* TIME FROMt4ln-�J-a-- THROUGH B REQER'Y. BY: 7 rA win, on 0 MR-0,1110-0.52 I I 'ems: v I LM wI d IJ %) LU r d- ji l lip lvl d pS Digital Map Store Home Aerial Photos National Geographic. De'Lorme Topo USA; 'Road- Maps - GPS Coordinates Zip Code Topo - Instructions: �1.) -Zoom in to, your location,;.,.-2:) .click _the ."MyTopo"`:button for topo' n `��.�`•�� x' - ,.»+�"'� - x ..Y �. a.�� _ _ 'r�lii- �+I.r N.,,d'T� �� :� rt i :4r � �L i C s ,t -� $��.. .r� .r �C'6'• k i�f rr� ,•f^ t"t _ �'�� �i ,y� - � t ''t � --_-��aj,�nrx„+' - . � � . t� a - tF- i .r t sa•- � iy � d~ �� I ,i • r- 0 r '� ell 5 —�-,, l r ... ram. �z_v .n M. as?- ,s.+ ..._ _ r _ ` r '; �' . P , -UNTY Printed On: RICHMOND, CO 8/26/2008 J. �•. f". ram,.+ t i _ �� � 1 .�-'. „�'� ' . ��. �R�� � � � � • � �:u� '�P� � �\ art .. � #'.�„ ����+j� I t T W I� 1' t i qC �. i f ilu Disclaimer: All information on this map is prepared for the inventory of real property found within Richmond County. All data, including maps, is compiled from recorded deeds, plats, and other public records and data. Users of this data are hereby notified that the aforementioned public primary information sources should be consulted for verification of the information. All information contained herein was created for the County +s internal use. Richmond County, its agents and employees make no warranty as to the correctness or accuracy of the information set forth on this media whether express or implied, in fact or in law, including without limitation the implied warranties of merchantability and fitness for a particular use. Any resale of this data is strictly prohibited in accordance with North Carolina General Statute 132-10. Grid is based on North Carolina State Plane NAD83. lb 1 - . - �dr � ir. r KLr v rr• 9i ,�}"-"� x �. 1. � f .Yr � , ♦ u'";. [ s• f »rya"1""' ]IC"„�t^':.[43 • �` a 4 [ ICI :�' - .J . •w "- ��`q. } "�.°,'�r !. '�`ki �,�� "r._�`� ex • 4 � y .M r i, A•f K 1 ;L c � 5[ m ...�°"=Cr" '�s, � +.-` "�1 i` '" �'�n I �"- 1 Syr ' �k -' rws��a' � r. ax,�'l sly,7 AL- f 06. h zyrk +y. P.v'j y t 'L/-: �. ,r r+T y• k �}�� +�'1,•.�1 a .� "tCC k . .�` }y. f r, 1 �r s. A % Z y OL °�g'i. 1 hey'. _y � Yr�a. a - �'N �'��, ,�s �a?,ri 4� r �f` ,} « s v 4C • l 1 " b �"� �''rt� e r^ J,r,r �'�ryi" si �, �I. `. � i r 1 ' tK [ ; i � � , t n - �' ' �`•.xl� ° � k.T, 7 f R _ ,r i rC ,1 1 1' L. A +�' 4f k � t i* j1� � • • a^ � W � �i .. x r '�� f' 4 �� L _ T f� L r` � � Yw� " `••-ter e'4 ��.ly'��� ' T l M tQ LV raft r Lf ; r`-' T'�L� r r '� Jr,'a S °`_ 7 Q _ I -C intedo­rr Or JI J.,j 8/26/2008, el L4, -wt A 'Ilk or.4 Of A't i�,, 4 ti �jj Tt Ito, Printed On: RICHMOND 8/26/2008 !tom 0. R T H C A IR O L. I N A �._..� =DENR-FAWM TRANSPORTATION Carl A: Gerhardstein, P.E. 500 Water'Street, J275 Director -Environmental Systems Jacksonville, 32202 (904)366. 4303 FAX (904) 245-2828 Carl_ Gerhardstein@CSX.com July 25, 2008 Joel S, Shields... North Carolina Division:of,Water Quality 225 . Green ,.Street,' •Suite. 714 .Fayetteville, NC.._ 28301 Dear Mr. Shields: I am in receipt of your June' 10,:2008 letter.regarding• the Compliance Evaluation Inspection form from the inspection conducted.on June 6, 2008 at o_ur_faci-lity.in Richmond -.County, Hamlet,: NC. I am pleased to: hear the facility 'was found to be sin -•Compliance with permit WQ00.00601': CSXT is committed -to -'maintaining the highest standards of environmental - compliance. -If you. Piave -any questions I can be reached at 9.04-366-- 4303 Sincerely CC: Mike Gregory Tony Bellamy Jerry Cato.