WQ0037094_2022 Residual Annual Report_20230221 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0037094
Applicant/Permittee Howard Fertilizer Company, Inc.
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Rob Willcox
Email Address*
[e-mail]
Project Information
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
3363399128
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0037094
Has Current Existing permit number
Applicant/Permittee Address*
8306 South Orange Avenue; Orlando, FL 32809
Facility Name*
Howard Fertilizer Company Class A Residuals Program
Please provide comments/notes on your current submittal below.
2022 Annual Report for Howard Fertilizer Company - Non -Discharge Permit No. WQ0037094
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Distribution of Class A Residuals Annual Report- 47.51MB
Howard Fertilizer-WQ0037094.pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/21/2023

2022 ANNUAL REPORT
HOWARD FERTILIZER COMPANY, INC.
DISTRIBUTION OF CLASS A MUNICIPAL
WASTEWATER TREATMENT PLANT RESIDUALS
NON -DISCHARGE PERMIT #WQ0037094
Prepared For:
Howard Fertilizer Company, Inc.
8306 South Orange Avenue
Orlando, Florida 32809
Compiled By:
Willcox & Mabe Soil Solutions, PLLC
723113 Summerfield Road
Summerfield, North Carolina 27358
February 2023

willcox&mate
SO I L SOL U T I ON S
February 20, 2023
N.C. Department of Environmental Quality
Division of Water Resources — Non -Discharge Branch
512 N. Salisbury Street, 9 h Floor, Office 9 942X
Raleigh, North Carolina 27604
Attention: Non -Discharge Branch
Reference: 2022 ANNUAL REPORT
Howard Fertilizer Company, Inc.
Non -Discharge Permit No. WQ0037094
Willcox & Mabe Soil Solutions, PLLC Project No. 15-07, Phase: 09
Willcox & Mabe Soil Solutions, PLLC (WMSS) is submitting all monitoring and reporting
requirements as specified in the above referenced permit for Howard Fertilizer Company,
Inc. (Howard Fertilizer) on behalf of Howard Fertilizer. WMSS compiled this report using
data provided by Howard Fertilizer. This data includes: 1) Class A Annual Distribution of
Marketing / Surface Disposal Certification and Summary Form, 2) Annual Residual
Sampling Summary Form, 3) Annual Pathogen and Vector Attraction Reduction Form
(503), and 4) Analytical Data.
Howard Fertilizer distributed 802.51 Total Dry Tons of blended fertilizer and South Cross
Bayou WRF pellets in North Carolina under Permit No. WQ0037094 during the 2022
calendar year.
If there is any further information required or questions regarding this distribution program
please do not hesitate to contact Ms. Carry Feliciano, Corporate Compliance Officer (352)
405-1008 for further assistance.
Sincerely,
Willcox & Mabe Soil Solutions, PLLC
_��Z 414&_Z�
Rob Willcox, L.S.S.
Partner / Soil Scientist
Enclosure(s)
cc: Howard Fertilizer Company, Inc.
Shared\WMSS Projects\2015\15-07 Howard Fertilizer\Phase 09 -2022 Annual Report\2022 ANNUAL REPO RT.doc
Willcox & Mabe Soil Solutions, PLLC / 7231 B Summerfield Road / Summerfield, NC 27358 / Rob 336.339.9128 or
Martin 336.312.1396 / www.willcoxmabesoil.com

TABLE OF CONTENTS
SECTION NO. TITLE
Class A Distribution and Marketing / Surface Disposal
Certification Summary Form
Form DMSDF
H Annual Residual Sampling Summary Form
Form RSSF
III Annual Pathogen and Vector Attraction Reduction Form
(503 Rules)
Form PVRF 503
IV Lab Sheets
Analytical Data

Class A Distribution and Marketing / Surface Disposal Certification
Summary Form
FORM DMSDF

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FORM RSSF

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Annual Pathogen and Vector Attraction Reduction Form - (503 Rules)
FORM PVRF 503

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Howard Fertilzer Company, Inc. (Permittee) WQ Permit Number: WQ0037094
WWTP Name: South Cross Bayou WRF Pelletizing Facility NPDES Number:
Monitoring Period: From l/l/2022 To 3/31/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative nerformed:
Class A:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 ❑
Alternative 4 ❑
Alternative 5 El
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying El
Heat Treatment ❑
Thermo hilic [-
Beta Ra ❑
1 Gamma Ray ❑
Pasteurization ❑
Class B:
I Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑ Air Drying[] Composting ❑ Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
Number o
Excee-
Pr P�
Frequency
of Analysis
Sample
Type
na ytica
Tech -
%4inimurr
Geo. Mean
MaximL
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weieht)
Salmonella bacteria
(in lieu of fecal
colifonn) I
3 MPN per 4 grams
total solid (dry
weight)
vecwr Ateraetion Reduction (40 4-1711503.33) - Please indicate option Derformed:
Alt.1 (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
JAIL 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
JAIL 8 (Drying - Unstable) El
Alt. 9 (Iniection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ( 1
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
* Permitte (Howard Fertilizer) N/A
Prepare me anti T-Etl (type or print) Land Applier Name and Title (if applicable)(type or print)
N/A
Signature of P eparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Howard Fertilzer Company, Inc. (Permittee) WQ Permit Number: WQ0037094
WWTP Name: South Cross Bayou WRF Pelletizing Facility NPDES Number:
Monitoring Period: From 4/1/2022 To 6/30/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative nhrfnrn1PA-
Class A:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 ❑
Alternative 4 ❑
Alternative 5 El
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying El
Heat Treatment ❑
Thermophilic ❑
Beta Ray 01
Gamma Ray ❑
Pasteurization ❑
Class B:
Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑ Air Drying❑ Composting ❑ Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in
in Sludge
Pathogen Density
Ex Number o
Excee-
P„„P
Frequency
of Anal
Analysis
Sample
Type
na ch-
Tech -
11P
Minimu
Geo. Mean
Maximu
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
1-.-L--.
3 MPN per 4 grams
total solid (dry
weight)
r ecwr :.xr .e.ron Reduction (14u C1, Ft 503.33) - Please indicate option performed:
Alt.I (VS reduction) ❑
It. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. OZ uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
Alt. 8 (Drying - Unstable)
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
C ERTIFIC:ATION STATEMENT (please check the appropriate statement)
<] "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements) _
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
* Permitte (Howard Fertilizer) N/A
Prepar l�latne •a`nd Tpc or print) Land Applier Name and Title (if applicable)(type or print)
��
fl itle JC1 v� N/A
Signature parer* Datc Signature of Land Applier (if applicable) Date
pP )
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (1212006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Howard Fertilzer Company, Inc. (Permittee) WQ Permit Number: WQ0037094
WWTP Name: South Cross Bayou WRF Pelletizing Facility NPDES Number:
Monitoring Period: From 7/1/2022 To 9/30/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
Alternative 1 ❑
T
Alternative 2 ❑
Alternative 3 ❑
__+
Alternative 4 ❑
Alternative 5 El
I Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying H
Heat Treatment ❑
Thermophilic D
Beta Ray 01
Gamma Ray ❑
Pasteurization ❑
Class B:
I Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑ Air Drying❑ Composting ❑ jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
g
Pathogen Density
g �'
1 um er °
Excee-
Frequency
of Analysis
Sample
Type
Analytical
Tech-
„�,,. P
Minimu
Geo. Mean
Maximo
Units
Fecal Coliform
2x10tothe
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform) I
3 MPN per 4 grams
total solid (dry
weiehtl
Vector Attraction Reduction (40 CFR 503.33) - Please indicate ontion performed:
All. ) (VS reduction) L__l
Alt. 2 (40-day bench) Cl
Alt. 3 (30-day bench) ❑Alt.
4 (Spec. OZ uptake) i i
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) 0
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CER IFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
* Perini tt - oward Fertilizer) N/A
Prep .er Xi"ame and T tic (type or print) Land Applier Name and Title (if applicable)(type or print)
_ w ==� N/A
SignatiirqPreparer* ate Signature of Land A lier if applicable) Date
PP ( ppble)
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Howard Fertilzer Company, Inc. (Permittee) WQ Permit Number: WQ0037094
WWTP Name: South Cross Bayou WRF Pelletizing Facility NPDES Number:
Monitoring Period: From 10/1/2022 To 12/31/2022
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternativp nerfnrmnrl-
Class A:
Alternative 1 ❑
Alternative 2 ❑
Alternative 3 ❑
— —+Alternative
4 ❑
Alternative 5 0
Alternative 6 ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying B
Heat Treatment ❑
Thermophilic I]
Beta Ray 01
Gamma Ray ❑
Pasteurization ❑
Class B:
I Alternative 1 ❑
Alternative 2 ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑ Air Drying❑ Composting ❑ jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
PathogenDensity Densi
Number o
Frequency
Sample
nay ica
in Sludge
E xcxc ee-
of Analysis
Type
Tech-
nione
Minimtl..
Geo. Mean
Maximutr
Units
2x 10tothe
6th power
MPN
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
3 MPN per 4 grams
(in lieu of fecal
total solid (dry
cotiform) I
weight)
VCCtpl Attraction Reduction (40 ChR 503.331 - Please indicate option performed:
Alt.1 (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. OZ uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
Alt. 8 (Drying - Unstable) 0
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
* Permitte (Howard Fertilizer) N/A
Prepa dine"ancl Title pe or print) Land Applier Name and Title (if applicable)(type or print)
N/A
Signature of : •eparcr* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

Lab Sheets
ANALYTICAL DATA

HOWARD FERTILIZER
CLASS A
BIOSOLIDS ANALYSIS
Residual Type: Wastewater Treatment Plant (Pinellas)
Date Sampled: January 4, 2022
Date Reported: January 27, 2022
South Cross Bayou WRF (1st Quarter 2022) Permit No. WQ0037094
Mineralization Rate 0.30 92.60 % Solids
6.9 pH
Parameter
%
Mg/Kg Dry Weight
(% x 10,000)
Pounds/Dry Ton
(Mg/Kg x 0.002)
Nitrogen (TKN)
4.930
49,300,000
98.600
Phosphorus
3.240
32,400.000
64.800
Potassium
0.310
3,100.000
6.200
PAN (injected)*
1.658
16,581.400
33.163
PAN (surface)*
1.531
15,306.400
30.613
Ammonia Nitrogen
0.255
2,550.000
5.100
Calcium
3.490
34,900.000
69.800
Calcium Carbonate Eq.
---
---
Magnesium
---
6,200.000
12.400
Sodium
---
1,500.000
3.000
Sulfur
---
---
Nitrate N / Nitrite N
---
6.400
0.013
Barium
---
---
Chloride
---
---
Iron
---
---
---
Aluminum
---
21,900.000
43.800
Arsenic
---
6.000
0.012
Cadmium
---
0.900
0.002
Chromium
---
---
---
Copper
---
526.000
1.052
Lead
---
15.700
0.031
Mercury
---
0.520
0.001
Molybdenum
---
11.300
0.023
Nickel
---
29.400
0.059
Selenium
---
6.400
0.013
Zinc
---
730.000
1.460
Pace Analytical 35687996
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N) + Ammonia N + Nitrate N + Nitrite N = % PAN
Surface Application:
(Mineralization Rate)(TKN-Ammonia N) + (0.5)(Ammonia N) + Nitrate N + Nitrite N = % PAN
Note: Constituents N.D. (Not Detected) or < detection limits are listed as detection limits
for calculation purposes.
SAR
1.87
Ceiling Concen.
(Mg/Kg)
75
85
4,300
840
57
75
420
100
7,500

aceAnalytical
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January 27, 2022
William Reyes
Synagro
RE: Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Dear William Reyes:
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on January 04, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Cameron Meynardie
[e-mail]
813-855-1844
Project Manager
Enclosures
cc: Robert Ervin, Synagro
/Q PCCgF��
9e0RASpQ�
REPORT OF LABORATORY ANALYSIS
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Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
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Delaware Certification: FL NELAC Reciprocity
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Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
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Maine Certification #: FLO1264
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
CERTIFICATIONS
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
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Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
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West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
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[phone]
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SAMPLE SUMMARY
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Lab ID Sample ID Matrix Date Collected Date Received
35687996001 Pellet Solid 01/04/2215:50 01/04/2219:00
REPORT OF LABORATORY ANALYSIS
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Oldsmar, FL 34677
[phone]
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SAMPLE ANALYTE COUNT
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
35687996001 Pellet EPA 6010
EMG
18
PASI-O
EPA 7471
JNK
1
PASI-O
ASTM D2974-87
NLC
1
PASI-O
SM 2540G
RAK
1
PASI-O
SM 2540G
RAK
1
PASI-O
EPA 9045
SWB
1
PASI-O
SM271OF
AGS
1
PASI-O
TKN-NH3 Calculation
TLK
1
PASI-O
EPA 350.1
RRB
1
PASI-O
EPA 351.2
AVW
1
PASI-O
EPA 353.2
KW1
2
PASI-O
PASI-O = Pace Analytical Services - Ormond Beach
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Sample: Pellet
Lab ID: 35687996001 Collected: 01/04/22 15:50
Received: 01/04/22 19:00 Matrix: Solid
Results reported on a "dry weight'
basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units PQL MDL
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA
3050
Pace Analytical Services - Ormond Beach
Aluminum
21900 mg/kg 82.1 50.1
1
01/13/22 23:49
01/14/22 11:29
7429-90-5
Arsenic
6.0 mg/kg 4.1 2.1
1
01/13/22 23:49
01/14/22 11:29
7440-38-2
Boron
58.9 mg/kg 20.5 3.4
1
01/13/22 23:49
01/14/22 11:29
7440-42-8
Cadmium
0.90 mg/kg 0.41 0.21
1
01/13/22 23:49
01/14/22 11:29
7440-43-9
Calcium
34900 mg/kg 410 295
1
01/13/22 23:49
01/14/22 11:29
7440-70-2
Copper
526 mg/kg 10.3 5.1
5
01/13/22 23:49
01/14/22 14:21
7440-50-8
Iron
18300 mg/kg 410 123
5
01/13/22 23:49
01/14/22 14:21
7439-89-6
Lead
15.7 mg/kg 4.1 2.1
1
01/13/22 23:49
01/14/22 11:29
7439-92-1
Magnesium
6200 mg/kg 205 103
1
01/13/22 23:49
01/14/22 11:29
7439-95-4
Manganese
158 mg/kg 2.1 1.0
1
01/13/22 23:49
01/14/22 11:29
7439-96-5
Molybdenum
11.3 mg/kg 4.1 2.1
1
01/13/22 23:49
01/14/22 11:29
7439-98-7
Nickel
29.4 mg/kg 2.1 1.0
1
01/13/22 23:49
01/14/22 11:29
7440-02-0
Phosphorus
32400 mg/kg 8210 443
20
01/13/22 23:49
01/14/22 14:36
7723-14-0
Potassium
3100 mg/kg 410 205
1
01113/22 23:49
01/14/22 11:29
7440-09-7
Selenium
6.4 mg/kg 6.2 3.1
1
01/13/22 23:49
01/14/22 11:29
7782-49-2
Sodium
1500 mg/kg 410 205
1
01/13/22 23:49
01/14/22 11:29
7440-23-5
Sulfur
11600 mg/kg 410 41.9
1
01/13/22 23:49
01/14/22 11:29
Zinc
730 mg/kg 41.0 14.8
1
01/13/22 23:49
01/14/22 11:29
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA
7471
Pace Analytical Services - Ormond Beach
Mercury
0.52 mg/kg 0.075 0.038
1
01/11/22 08:37
01/12/22 09:51
7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Ormond Beach
Percent Moisture
6.5 % 0.10 0.10
1
01/13/22 06:44
254OG Total Solids
Analytical Method: SM 254OG
Pace Analytical Services - Ormond Beach
Total Solids
92.6 % 0.0010 0.0010
1
01/10/22 19:31
254OG Total Volatile Solids
Analytical Method: SM 2540G
Pace Analytical Services - Ormond Beach
Total Volatile Solids
72.2 % 0.0010 0.0010
1
01/10/22 19:31
9045 pH Soil
Analytical Method: EPA 9045
Pace Analytical Services - Ormond Beach
pH at 25 Degrees C
6.9 Std. Units 0.10 0.10
1
01/11/22 17:27
Q
Specific Gravity/Bulk Density
Analytical Method: SM271OF
Pace Analytical Services - Ormond Beach
Specific Gravity
0.620
1
01/14/22 14:15
N2
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Sample: Pellet Lab ID: 35687996001 Collected: 01/04/22 15:50 Received: 01/04/22 19:00 Matrix: Solid
Results reported on a "dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
Total Organic Nitrogen Soil
Total Organic Nitrogen
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, N021NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Date: 01/27/2022 08:04 AM
Analytical Method: TKN-NH3 Calculation
Pace Analytical Services - Ormond Beach
46800 mg/kg 21.4 11.8 1 01/19/22 08:50
Analytical Method: EPA 350.1 Preparation Method: EPA 350.1
Pace Analytical Services - Ormond Beach
2550 mg/kg 45.2 15.0 50 01/13/2213:01 01/13/2215:27 7664-41-7 J(M1)
Analytical Method: EPA 351.2 Preparation Method: EPA 351.2
Pace Analytical Services - Ormond Beach
49300 mg/kg 5310 2920 50 01/1512216:31 01/18/2215:49 7727-37-9
Analytical Method: EPA 353.2 Preparation Method: EPA 353.2
Pace Analytical Services - Ormond Beach
3.6 mg/kg 0.54 0.27 1 01/12/2215:00 01/12/2217:44 Q
2.8 mg/kg 0.54 0.27 1 01/12/2215:00 01/12/2217:44 14797-55-8 Q
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
QC Batch: 791233
Analysis Method:
EPA 7471
QC Batch Method: EPA 7471
Analysis Description:
7471 Mercury
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
METHOD BLANK: 4342378
Matrix: Solid
Associated Lab Samples: 35687996001
Blank Reporting
Parameter Units
Result Limit
MDL Analyzed Qualifiers
Mercury mg/kg
0.0046 U 0.0092 0.0046 01/12/22 09:47
LABORATORY CONTROL SAMPLE: 4342379
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
0.096 0.095
99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4342380
4342381
MS MSD
35688772011
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.026
0.11 0.11 0.12
0.13 89 93 80-120 6 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 791946 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
METHOD BLANK: 4347650
Associated Lab Samples: 35687996001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
MDL
Analyzed Qualifiers
Aluminum
mg/kg
7.3 U
11.9
7.3
01/14/2216:01
Arsenic
mg/kg
0.30 U
0.59
0.30
01/14/2216:01
Boron
mg/kg
0.49 U
3.0
0.49
01/14/2216:01
Cadmium
mg/kg
0.030 U
0.059
0.030
01/14/2214:13
Calcium
mg/kg
42.8 U
59.5
42.8
01/14/2216:01
Copper
mg/kg
0.15 U
0.30
0.15
01/14/2216:01
Iron
mg/kg
3.6 U
11.9
3.6
01/14/2216:01
Lead
mg/kg
0.30 U
0.59
0.30
01/14/2216:01
Magnesium
mg/kg
14.9 U
29.7
14.9
01/14/2216:01
Manganese
mg/kg
0.15 U
0.30
0.15
01/1412216:01
Molybdenum
mg/kg
0.30 U
0.59
0.30
01/14/2216:01
Nickel
mg/kg
0.15 U
0.30
0.15
01/14/2216:01
Phosphorus
mg/kg
3.2 U
59.5
3.2
01/14/2216:01
Potassium
mg/kg
29.7 U
59.5
29.7
01/1412216:01
Selenium
mg/kg
0.45 U
0.89
0.45
01/14/2216:01
Sodium
mg/kg
29.7 U
59.5
29.7
01/14/2216:01
Sulfur
mg/kg
6.1 U
59.5
6.1
01/1412216:01
Zinc
mg/kg
2.1 U
5.9
2.1
01/14/2216:01
LABORATORY CONTROL SAMPLE:
4347651
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Aluminum
mg/kg
151
150
99
80-120
Arsenic
mg/kg
15.1
15.0
99
80-120
Boron
mg/kg
75.5
69.5
92
80-120
Cadmium
mg/kg
1.5
1.6
105
80-120
Calcium
mg/kg
755
829
110
80-120
Copper
mg/kg
15.1
16.3
108
80-120
Iron
mg/kg
151
151
100
80-120
Lead
mg/kg
15.1
15.8
105
80-120
Magnesium
mg/kg
755
805
107
80-120
Manganese
mg/kg
15.1
15.2
101
80-120
Molybdenum
mg/kg
15.1
16.0
106
80-120
Nickel
mg/kg
15.1
15.7
104
80-120
Phosphorus
mg/kg
15.1
16.4 1
109
80-120
Potassium
mg/kg
755
732
97
80-120
Selenium
mg/kg
15.1
13.8
91
80-120
Sodium
mg/kg
755
762
101
80-120
Sulfur
mg/kg
151
140
92
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pinellas County Pelletizer
Pace Project No.:
35687996
LABORATORY CONTROL
SAMPLE:
4347651
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Zinc
mg/kg
75.5
78.0
103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4347652
4347653
MS
MSD
35687847002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
1640
385
379
2210
2190
150
144
75-125
1
20 J(M1)
Arsenic
mg/kg
4.5
38.5
37.9
45.4
44.8
106
106
75-125
1
20
Boron
mg/kg
20.9
192
190
209
217
98
103
75-125
4
20
Cadmium
mg/kg
0.075 U
3.8
3.8
3.7
3.7
95
97
75-125
1
20
Calcium
mg/kg
283000
1920
1900
346000
284000
3330
61
75-125
20
20 J(M1),
L
Copper
mg/kg
73.7
38.5
37.9
119
123
117
130
75-125
4
20 J(M1)
Iron
mglkg
1560
385
379
1890
2010
86
119
75-125
6
20
Lead
mg/kg
3.2
38.5
37.9
41.3
41.1
99
100
75-125
0
20
Magnesium
mg/kg
7940
1920
1900
9670
10600
90
138
75-125
9
20 J(M1)
Manganese
mg/kg
23.4
38.5
37.9
61.9
63.0
100
104
75-125
2
20
Molybdenum
mg/kg
3.3
38.5
37.9
43.3
42.6
104
103
75-125
2
20
Nickel
mg/kg
5.8
38.5
37.9
42.2
42.6
95
97
75-125
1
20
Phosphorus
mg/kg
6470
38.5
37.9
6280
6540
-482
185
75-125
4
20 J(M1),
L
Potassium
mg/kg
0.39 %
1920
1900
6110
6110
317
321
75-125
0
20 J(M1)
(w/w)
Selenium
mg/kg
2.8
38.5
37.9
39.9
38.6
97
94
75-125
3
20
Sodium
mg/kg
2130
1920
1900
4280
4290
112
113
75-125
0
20
Sulfur
mg/kg
4610
385
379
4910
5030
78
109
75-125
2
20
Zinc
mg/kg
236
192
190
400
418
85
95
75-125
4
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd,
Oldsmar, FL34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
QC Batch: 791871
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
SAMPLE DUPLICATE: 4347142
35687996001
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
6.5
6.7 4
10
SAMPLE DUPLICATE: 4347143
35688044010
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
4.1
4.1 1
10
SAMPLE DUPLICATE: 4347144
35688044020
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
17.0
18.5 8
10
SAMPLE DUPLICATE: 4347145
35688044030
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
17.8
17.4 2
10
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 791156 Analysis Method: SM 2540G
QC Batch Method: SM 2540G Analysis Description: 2540G Total Solids
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
SAMPLE DUPLICATE: 4341528
35687996001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Solids % 92.6 92.6 0 10
SAMPLE DUPLICATE: 4341529
35688604001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Solids % 13.4 13.4 0 10
Results presented on this page are in the units indicated by the "units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/27/2022 08:04 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 20

aceAnalytical
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1
QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 791158 Analysis Method: SM 2540G
QC Batch Method: SM 2540G Analysis Description: 2540G Total Volatile Solids
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
METHOD BLANK: 4341540 Matrix: Solid
Associated Lab Samples: 35687996001
Blank Reporting
Parameter Units Result Limit
Total Volatile Solids % 0.0010 U 0.0010
SAMPLE DUPLICATE: 4341541
35687996001 Dup
Parameter Units Result Result
Total Volatile Solids % 72.2 72.0
MDL Analyzed Qualifiers
0.0010 01/10/2219:31
Max
RPD RPD Qualifiers
0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/27/2022 08:04 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 20

aceAnalXical
www.pacelabs.com
E
QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
QC Batch: 792367 Analysis Method: SM271OF
QC Batch Method: SM271 OF Analysis Description: Spec.Gravity SM271 OF
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
SAMPLE DUPLICATE: 4351006
Parameter Units
Specific Gravity
35687280003 Dup Max
Result Result RPD RPD Qualifiers
1.02 1.02 0 20 N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/27/2022 08:04 AM without the written consent of Pace Analytical Services, LLC.
Page 13 of 20

aceAnalytical
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f
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
QC Batch: 792011
Analysis Method:
EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description:
350.1 Ammonia
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
METHOD BLANK: 4348098
Matrix: Solid
Associated Lab Samples: 35687996001
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Nitrogen, Ammonia mg/kg
0.28 U 0.86
0.28 01/13/22 15:20
LABORATORY CONTROL SAMPLE: 4348099
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia mg/kg
9.9 10.3
104
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4348101
4348100
MS MSD
35687996001
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Nitrogen, Ammonia mg/kg 2550
10.7 10.8 2490
2520
-521 -284 90-110 1 20 J(M1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/27/2022 08:04 AM without the written consent of Pace Analytical Services, LLC.
Page 14 of 20

aceAnalytical
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f
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar. FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
QC Batch: 792516
Analysis Method:
EPA 351.2
QC Batch Method: EPA 351.2
Analysis Description:
351.2 TKN
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
METHOD BLANK: 4352412
Matrix: Solid
Associated Lab Samples: 35687996001
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
31.6 U 57.5
31.6 01/18/22 09:57
LABORATORY CONTROL SAMPLE: 4352413
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
3270 3140
96
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4352415
4352414
MS MSD
35687923001
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 6.3 %
28100 28200 87900
88400
88 89 90-110 1 20 J(M1)
(w/w)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/27/2022 08:04 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 20

aceAnalj cal
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t
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
QC Batch: 791716 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35687996001
METHOD BLANK: 4345532 Matrix: Solid
Associated Lab Samples: 35687996001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Nitrate mg/kg 0.25 U 0.50 0.25 01/12/22 17:42
Nitrogen, NO2 plus NO3 mg/kg 0.25 U 0.50 0.25 01/12/22 17:42
LABORATORY CONTROL SAMPLE: 4345533
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/kg 20.2 19.4 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4345535 4345534
MS MSD
35687996001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/kg 3.6 21.6 21.6 21.0 21.5 81 83 80-120 2 20 Q
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /27/2022 08:04 AM without the written consent of Pace Analytical Services, LLC.
Page 16 of 20

Pace Analytical Services, LLC
aceAnalytical 110 South Bayview Blvd.
Oldsmar, FL 34677
www.pacelabs.tom [phone]
QUALIFIERS
Project: Pinellas County Pelletizer
Pace Project No.: 35687996
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
U Compound was analyzed for but not detected.
i(MI) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)
recovery.
L Off -scale high. Actual value is known to be greater than value given.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditation s/certifications is available upon request.
Q Sample held beyond the accepted holding time.
Q Sample held beyond the accepted holding time. Analysis initiated more than 15 minutes after sample collection.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/27/2022 08:04 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 20

aceAnalytical
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pace Project No.:
Pinellas County Pelletizer
35687996
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
36687996001
Pellet
EPA 3050
791946
EPA 6010
792165
35687996001
Pellet
EPA 7471
791233
EPA 7471
791297
35687996001
Pellet
ASTM D2974-87
791871
35687996001
Pellet
SM 2540G
791156
35687996001
Pellet
SM 2540G
791158
35687996001
Pellet
EPA 9045
791349
35687996001
Pellet
SM271OF
792367
35687996001
Pellet
TKN-NH3 Calculation
793390
35687996001
Pellet
EPA 350.1
792011
EPA 350.1
792050
35687996001
Pellet
EPA 351.2
792516
EPA 351.2
793016
35687996001
Pellet
EPA 353.2
791716
EPA 353.2
791797
Date: 01/27/2022 08:04 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 20

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DC#_Title: ENV-FRM-ORB1-0093 Sample Condition Upon Receipt Form
Version: 2 1 Effective Date: 11/30/2021 1 Issued bv: Ormond Beach
Project it WSJ# : 35687996
Due Date: 01/14/22 Date and Initials of pet• n.
Project Manager: PM: CEM Examining conten s:
CLIENT: 37-SYNAGRO Label: _
Client: Deliver: r
PH:
Thermometer Used. ✓ `� Date: 'I ��/�� Time: ���
Initials:
State of Origin:
❑ For WV projects, all containers verified to s6 °C
Cooler #1 Temp.°C (Visual) --"
(Correction Factor) _
• ,✓ (Actual)
❑
Samples on Ice, cooling process has begun
Cooler #2 Temp."C
(Visual}
(Correction Factor)
(Actual)
❑
Samples on ice, cooling process has begun
Cooler #3 Temp."C
(Visual)
(Correction Factor) _
(Actual)
❑
Samples on ice, cooling process has begun
Cooler #4 Temp.'C
(Visual)
(Correction Factor)
(Actual)
❑
Samples on ice, cooling process has begun
Cooler #5 Temp. °C
(Visual)
(Correction Factor)
(Actual)
❑
Samples on ice, cooling process has begun
Cooler #6 Temp.°C
(Visual)
(Correction Factor)
(Actual)
❑
Samples on ice, cooling process has begun
Courier: ❑ Fed Ex
❑ UPS
❑ USPS ❑ Client /
Commercial ❑ Pace
❑ Other --
Shipping Method: ❑ First Overnight ❑ Priority Overnight ❑ Standard Overnight ❑ Ground ❑ International Priority
❑ Other
Billing: ❑ Recipient ❑ Sender ❑ Third Party ❑ Credit Card ❑ Unknown
Tracking #
Custody Seal on Cooler/Box Present: ❑ Yes JCS No Seals intact: ❑ Yes ❑ No Ice: Blue Dry None
Packing Material: ❑ Bubble Wrap ❑ Bubble Bags ❑ None ❑ Other
Samples shorted to lab (If Yes, complete) Shorted Date: Shorted Time: Qty:
.- t
Chain of Custody Present
Yes
❑ No El N/A
Chain of Custody Filled Out
'&Ls
❑ No ❑N/A
Relinquished Signature & Sampler Name COC
,eYes
❑ No ❑N/A
Samples Arrived within Hold Time
/Yes
❑ No El N/A
Rush TAT requested on COC
❑Yes
/No ❑N/A
Sufficient Volume
Jr'es
❑ No ❑N/A
Correct Containers Used
/yes
❑ No ❑N/A
Containers Intact
,Yes
❑ No El N/A
Sample Labels match COG (sample Us & date/time of
collection)
❑Yes
No ❑N/A
All containers needing acid/base preservation have been
checked. ❑Yes
All Containers needing preservation are found to be in
compliance with EPA recommendation: ❑Yes
Exceptions: VOA, Coliform, TOC, O&G, Carbamates
I
❑ No C;",/A
/
❑ No ❑/N/A
/
Preservation Information:
Preservative: _
Lot #/Trace #: _
Date: Time: _
Initials:
Headspace in VOA Vials? ( >6mm):
—[]Yes
❑ No /A
Trip Blank Present:
❑Yes
❑ No XN/A
Client Notification/ Resolution:
Person Contacted:
Comments/ Resolution (use back for additional comments):
Project Manager Review:
Qualtrax Document ID: 33786
Date/Time:
Pace Analytical Services, LLC
Date:
Page 1 of 1
Page 20 of 20

NELAC Certification #E84167
BENCHMARK
En viroA n alytical Inc.
ANALYTICAL TEST REPORT
THESE RESULTS MEET NELAC STANDARDS
Submission Number: 22010075
:2
Synagro
Project Name:
PINELLAS COUNTY PELLETIZER
P.O. Box 3227
Date Received :
01/04/2022
Pinellas Park, FL 33780
Time Received :
1354
Jennifer Amonica
Submission Number:
22010075
Sample Date: 01/04/2022
Sample Number:
001
Sample Time: 1315
Sample Description:
Pellets
Sample Method: Grab
Parameter
Result
Units MDL
Procedure Analysis
Date/Time
Analyst
TOTAL SOLIDS
94.5
MG/L 0.1
SM254DG 01/06/2022 14:22
MN
PH
6,47 Q
UNITS
SM4500H+B 01/0512022 D9:52
TG
FECAL COLIFORM BY MPN
0.190 U
#1100 ML 0,19D
SM9221 E 01/04/2022 15:25
LG
All values reported in UG1KG, MGIKG #!GRAM and MPN/GRAM are on a dry weight basis
Dale D. Dixon / borat
TOlay Ta risever echnicl
Kara Peterson - QA Officer
y vu'ector
Director= Officer
DATA QUALIFIERS THAT MAY APPLY:
I = Reported value is between the laboratory MDL and the PQL.
J2 = Estimated value. No control criteria exists for this component.
J3 = Estimated value. Quality control criteria for precision or aocuracy not met.
J4 = Estimaled value. Sample matrix Inlerrerence suspected.
L = Off -scale high. Value Is known to be > the value reported.
Q = Sample held beyond accepted hold time.
U = Analyte analyzed but not detected at the value Indicated.
V = Analyte detected In sample and malhod blank.
Y = Analysis perrormed on an Improperly preserved sample. Data may be Inaccurate.
Z = Too many colonies were present (MC). The numeric value represents the filtration volume.
For questions and comments regardina these results please contact us at [phone]
Resuffs relate only to Ilia samples.
01/14/2022
Date
NOTES:
2: SOUR calculations are based on Total Solids.
PQL = 4xMDL.
COMMENTS:
2201CO70 1711 12th Street East * Palmetto, FL 34221 * Phone [phone] * Fax [phone] PACT: i OF 2

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CERTIFICATION
I certify, under penalty of law, that the information that will be used to determine compliance with the
Class A pathogen requirements in §503.32(a) and the vector attraction reduction requirement in
§503.33(b)(8) was prepared under my direction and supervision in accordance with the system designed
to ensure that qualified personnel properly gather and evaluate this information. I am aware that there
are significant penalties for false certification including the possibility of fine and imprisonment."
Project(s): South Cross Bayou WRF Pelletizing Facility
Reporting Period: January 2022
Name: William Reyes — Plant Manager----\ Synagro
Signature: f__----' Date: 1-February-2022
The Class A pathogen requirements were met through §503.32(a)(7). The Process to Further Reduce
Pathogens was Heat Drying (Appendix B, B.2.). The biosolids were dried by direct or indirect contact with
hot gases to reduce the moisture content to 10% or lower. The temperature of the biosolids particles
exceeded 80 degrees Celsius. Fecal coliform testing was performed and the density of fecal coliform in
the biosolids was <1000 MPN per gram of total solids (dry weight basis).
The vector attraction reduction requirement was met through §503.33(b)(8). The percent solids of the
biosolids that contain unstabilized solids generated in a primary wastewater treatment process shall be
>90% based on the moisture content and total solids prior to mixing with other materials,
NTYPE 29: CA5 PR PELL PT VAR 90

HOWARD FERTILIZER
CLASS A
BIOSOLIDS ANALYSIS
Residual Type: Wastewater Treatment Plant (Pinellas)
Date Sampled: April 5, 2022
Date Reported: April 17, 2022
South Cross Bayou WRF (2nd Quarter 2022) Permit No. WQ0037094
Mineralization Rate 0.30 93.60 % Solids
6.9 pH
Parameter
%
Mg/Kg Dry Weight
(% x 10,000)
Pounds/Dry Ton
(Nlg/Kg x 0.002)
Nitrogen (TKN)
5.540
55,400.000
110.800
Phosphorus
3.190
31,900.000
63.800
Potassium
0.227
2,270.000
4.540
PAN (injected)*
1.854
18,538.800
37.078
PAN (surface)*
1.718
17,178.800
34.358
Ammonia Nitrogen
0.272
2,720.000
5.440
Calcium
3.520
35,200.000
70.400
Calcium Carbonate Eq.
---
---
---
Magnesium
---
5,350.000
10.700
Sodium
---
1,430.000
2.860
Sulfur
---
___
Nitrate N / Nitrite N
---
14.800
0.030
Barium
---
---
Chloride
---
--_
Iron
---
---
Aluminum
---
21,100.000
42.200
Arsenic
---
2.500
0.005
Cadmium
---
1.100
0.002
Chromium
---
___
Copper
---
469.000
0.938
Lead
---
14.500
0.029
Mercury
---
0.270
0.001
Molybdenum
---
10.300
0.021
Nickel
---
26.700
0.053
Selenium
---
7.300
0.015
Zinc
---
719.000
1.438
Pace Analytical 35707861
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N) + Ammonia N + Nitrate N + Nitrite N = % PAN
Surface Application:
(Mineralization Rate)(TKN-Ammonia N) + (0.5)(Ammonia N) + Nitrate N + Nitrite N = % PAN
Note: Constituents N.D. (Not Detected) or < detection limits are listed as detection limits
for calculation purposes.
SAR
1.81
Ceiling Concen.
(Mg/Kg)
75
85
4,300
840
57
75
420
100
7,500

aceAnalytical "
www.pacelabs.cem
I
April 17, 2022
William Reyes
Synagro
RE: Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Dear William Reyes:
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar. FL 34677
Enclosed are the analytical results for sample(s) received by the laboratory on April 05, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
oh-J—
Cameron Meynardie
[e-mail]
813-855-1844
Project Manager
Enclosures
cc: Robert Ervin, Synagro
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
[phone]
Page 1 of 20

aceAnalytical
www.pacelabs.com
j
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FL01264
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
CERTIFICATIONS
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Lab ID Sample ID
35707861001 Pellet
SAMPLE SUMMARY
Matrix Date Collected Date Received
Solid 04/05/2210:30 04/05/2211:16
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
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Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Lab ID Sample ID
35707861001 Pellet
PASI-O = Pace Analytical Services - Ormond Beach
SAMPLE ANALYTE COUNT
Method
EPA 6010
EPA 7471
ASTM D2974-87
SM 2540G
SM 254OG
EPA 9045
SM271 OF
TKN-NH3 Calculation
EPA 350.1
EPA 351.2
EPA 353.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Analytes
Analysts Reported Laboratory
EMG
18
PASI-O
JNK
1
PASI-O
AF
1
PASI-O
DDM
1
PASI-O
DDM
1
PASI-O
SWB
1
PASI-O
AGS
1
PASI-O
NMT
1
PASI-O
RMB
1
PASI-O
AVW
1
PASI-O
MRC
2
PASI-O
Page 4 of 20

aceAnalytical
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ANALYTICAL RESULTS
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Sample: Pellet Lab ID: 35707861001 Collected: 04/05/22 10:30 Received: 04/05/22 11:16 Matrix: Solid
Results reported on a "dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Pace Analytical Services - Ormond Beach
Aluminum
21100 mg/kg 99.0 60.4
1
04/08/2213:43
04/11/2216:38
7429-90-5
Arsenic
2.5 U mg/kg 5.0 2.5
1
04/0812213:43
04/11/2216:38
7440-38-2
Boron
57.5 mg/kg 24.8 4.1
1
04/08/2213:43
04111/2216:38
7440-42-8
Cadmium
1.1 mg/kg 0.50 0.25
1
04/08/2213:43
04/11/2216:38
7440-43-9
Calcium
35200 mg/kg 495 357
1
04/08/2213:43
04/11/2216:38
7440-70-2
Copper
469 mg/kg 2.5 1.2
1
04/08/2213:43
04/11/2216:38
7440-50-8
Iron
19700 mg/kg 99.0 29.7
1
04/08/2213:43
04/11/2216:38
7439-89-6
Lead
14.5 mg/kg 5.0 2.5
1
04/08/2213:43
04/11/2216:38
7439-92-1
Magnesium
5350 mg/kg 248 124
1
04/08/2213:43
04/11/2216:38
7439-95-4
Manganese
163 mg/kg 2.5 1.2
1
04/08/2213:43
04/11/2216:38
7439-96-5
Molybdenum
10.3 mg/kg 5.0 2.5
1
04/08/22 13:43
04/09/22 20:08
7439-98-7
Nickel
26.7 mg/kg 2.5 1.2
1
04/08/2213:43
04111/2216:38
7440-02-0
Phosphorus
31900 mg/kg 24800 1340
50
04/08/2213:43
04/11/2216:42
7723-14-0
Potassium
2270 mg/kg 495 248
1
04108/2213:43
04/11/2216:38
7440-09-7
Selenium
7.3 1 mg/kg 7.4 3.7
1
04/08/2213:43
04/11/2216:38
7782-49-2
Sodium
1430 mg/kg 495 248
1
04/08/2213:43
04/11/2216:38
7440-23-5
Sulfur
12600 mg/kg 495 50.5
1
04/08/2213:43
04/11/2216:38
Zinc
719 mg/kg 49.5 17.8
1
04/08/2213:43
04/11/2216:38
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method:
EPA 7471
Pace Analytical Services - Ormond Beach
Mercury
0.27 mg/kg 0.072 0.036
1
04/11/22 09:11
04/11/22 13:05
7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Ormond Beach
Percent Moisture
6.1 % 0.10 0.10
1
04/11/22 10:47
254OG Total Solids
Analytical Method: SM 2540G
Pace Analytical Services - Ormond Beach
Total Solids
93.6 % 0.0010 0.0010
1
04/08/22 16:39
254OG Total Volatile Solids
Analytical Method: SM 254OG
Pace Analytical Services - Ormond Beach
Total Volatile Solids
69.6 % 0.0010 0.0010
1
04/08/22 16:39
9045 pH Soil
Analytical Method: EPA 9045
Pace Analytical Services - Ormond Beach
pH at 25 Degrees C
6.9 Std. Units 0.10 0.10
1
04/08/22 16:16
Q
Specific Gravity/Bulk Density
Analytical Method: SM271 OF
Pace Analytical Services - Ormond Beach
Specific Gravity
0.620
1
04/11/22 15:26
N2
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Sample: Pellet Lab ID: 35707861001 Collected: 04/05/22 10:30 Received: 04/05/22 11:16 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
Total Organic Nitrogen Soil
Total Organic Nitrogen
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, N021NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Date: 04/17/2022 02:57 PM
Analytical Method: TKN-NH3 Calculation
Pace Analytical Services - Ormond Beach
52700 mg/kg 21.3 11.7 1
04/17/2214:42
Analytical Method: EPA 350.1 Preparation Method: EPA 350.1
Pace Analytical Services - Ormond Beach
2720 mg/kg 45.3 15.0 50 04/12/2216:52
04/1212217:41 7664-41-7 J(M1)
Analytical Method: EPA 351.2 Preparation Method: EPA 351.2
Pace Analytical Services - Ormond Beach
55400 mg/kg 1060 584 10 04/14/2214:04
04/15/2213:01 7727-37-9 J(M1)
Analytical Method: EPA 353.2 Preparation Method: EPA 353.2
Pace Analytical Services - Ormond Beach
7.4 1 mg/kg 13.2 6.6 25 04/06/22 08:59
04/06/22 15:36
7.4 1 mg/kg 13.2 6.6 25 04/06/22 08:59
04/06/22 15:36 14797-55-8
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
QC Batch: 814911
Analysis Method:
EPA 7471
QC Batch Method: EPA 7471
Analysis Description:
7471 Mercury
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35707861001
METHOD BLANK: 4473989
Matrix: Solid
Associated Lab Samples: 35707861001
Blank Reporting
Parameter Units
Result Limit
MDL Analyzed Qualifiers
Mercury mg/kg
0.0048 U 0.0096 0.0048 04/11/2212:55
LABORATORY CONTROL SAMPLE: 4473990
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
0.095 0.094
99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4473991 4473992
MS MSD
35708772001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.010 1
0.099 0.1 0.11
0.11 98 97 80-120 0 20
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/17/2022 02:57 PM without the written consent of Pace Analytical Services, LLC.
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Project:
Pinellas County Pelletizer
Pace Project No.:
35707861
QC Batch:
814502
QC Batch Method:
EPA 3050
Associated Lab Samples: 35707861001
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 6010
Analysis Description: 6010 MET Solid
Laboratory: Pace Analytical Services - Ormond Beach
METHOD BLANK: 4471598
Associated Lab Samples: 35707861001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
MDL
Analyzed Qualifiers
Aluminum
mg/kg
6.9 U
11.3
6.9
04/09/2218:26
Arsenic
mg/kg
0.28 U
0.57
0.28
04/09/2218:26
Boron
mg/kg
0.46 U
2.8
0.46
04/1112216:51
Cadmium
mg/kg
0.028 U
0.057
0.028
04/09/2218:26
Calcium
mg/kg
40.7 U
56.5
40.7
04/0912218:26
Copper
mg/kg
0.14 U
0.28
0.14
04/09/2218:26
Iron
mg/kg
3.4 U
11.3
3.4
04109/2218:26
Lead
mg/kg
0.28 U
0.57
0.28
04/09/2218:26
Magnesium
mg/kg
14.1 U
28.3
14.1
04/09/2218:26
Manganese
mg/kg
0.14 U
0.28
0.14
04/09/2218:26
Molybdenum
mg/kg
0.28 U
0.57
0.28
04/09/2218:26
Nickel
mg/kg
0.14 U
0.28
0.14
04/09/2218:26
Phosphorus
mg/kg
3.1 U
56.5
3.1
04/09/2218:26
Potassium
mg/kg
28.3 U
56.5
28.3
04/09/2218:26
Selenium
mg/kg
0.42 U
0.85
0.42
04/09/2218:26
Sodium
mg/kg
28.3 U
56.5
28.3
04/09/2218:26
Sulfur
mg/kg
5.8 U
56.5
5.8
04/09/2218:26
Zinc
mg/kg
2.0 U
5.7
2.0
04/09/2218:26
LABORATORY CONTROL SAMPLE:
Parameter
4471599
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
141
141
100
80-120
Arsenic
mg/kg
14.1
13.3
94
80-120
Boron
mg/kg
70.6
63.6
90
80-120
Cadmium
mg/kg
1.4
1.5
103
80-120
Calcium
mg/kg
706
748
106
80-120
Copper
mg/kg
14.1
14.2
100
80-120
Iron
mg/kg
141
147
104
80-120
Lead
mg/kg
14.1
14.8
105
80-120
Magnesium
mg/kg
706
706
100
80-120
Manganese
mg/kg
14.1
14.5
102
80-120
Molybdenum
mg/kg
14.1
14.6
103
80-120
Nickel
mg/kg
14.1
14.7
104
80-120
Phosphorus
mg/kg
14.1
14.6 1
103
80-120
Potassium
mg/kg
706
687
97
80-120
Selenium
mg/kg
14.1
12.9
91
80-120
Sodium
mg/kg
706
706
100
80-120
Sulfur
mg/kg
141
131
92
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pinellas County Pelletizer
Pace Project No.:
35707861
LABORATORY CONTROL SAMPLE:
4471599
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Zinc
mg/kg
70.6
74.5
105
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4471600
4471601
MS
MSD
35707255003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
75.1
159
153
265
254
119
117
75-125
4
20
Arsenic
mg/kg
0.34 U
15.9
15.3
14.1
13.7
88
89
75-125
3
20
Boron
mg/kg
0.56 U
79.8
76.6
70.5
68.8
88
90
75-125
2
20
Cadmium
mg/kg
0.034 U
1.6
1.5
1.6
1.6
100
101
75-125
3
20
Calcium
mg/kg
49.4 U
798
766
834
800
101
101
75-125
4
20
Copper
mg/kg
0.24 1
15.9
15.3
15.8
15.2
97
98
75-125
4
20
Iron
mg/kg
100
159
153
243
236
90
89
75-125
3
20
Lead
mg/kg
0.34 U
15.9
15.3
16.6
16.0
102
103
75-125
3
20
Magnesium
mg/kg
17.2 U
798
766
784
753
98
98
75-125
4
20
Manganese
mg/kg
0.62
15.9
15.3
16.4
15.8
99
99
75-125
4
20
Molybdenum
mg/kg
0.34 U
15.9
15.3
15.7
15.1
98
98
75-125
4
20
Nickel
mg/kg
0.17 U
15.9
15.3
16.2
15.6
101
101
75-125
4
20
Phosphorus
mg/kg
16.7 1
15.9
15.3
31.0 1
30.5 1
89
90
75-125
20
Potassium
mg/kg
34.3 U
798
766
772
740
96
96
75-125
4
20
Selenium
mg/kg
0.51 U
15.9
15.3
13.8
13.3
85
85
75-125
4
20
Sodium
mg/kg
34.3 U
798
766
795
762
98
97
75-125
4
20
Sulfur
mg/kg
7.5 1
159
153
150
143
89
89
75-125
5
20
Zinc
mg/kg
2.5 U
79.8
76.6
80.0
76.9
100
100
75-125
4
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/17/2022 02:57 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
QC Batch: 815019
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35707861001
SAMPLE DUPLICATE: 4474306
35707861001
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
6.1
6.3 3
10
SAMPLE DUPLICATE: 4474307
35709274002
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
2.9
3.1 9
10
SAMPLE DUPLICATE: 4474308
35709276002
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
4.8
4.7 2
10
SAMPLE DUPLICATE: 4474309
35709277006
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
16.4
16.3 1
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/17/2022 02:57 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 20

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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 814648 Analysis Method: SM 2540G
QC Batch Method: SM 2540G Analysis Description: 2540G Total Solids
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35707861001
SAMPLE DUPLICATE: 4472331
35708523001
Dup
Max
Parameter
Units
Result
Result
RPD RPD Qualifiers
Total Solids
%
2.5
2.5
1 10
SAMPLE DUPLICATE: 4472332
35708523003
Dup
Max
Parameter
Units
Result
Result
RPD RPD Qualifiers
Total Solids
%
18.0
19.1
6 10
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
QC Batch: 814649
Analysis Method:
SM 2540G
QC Batch Method: SM 254OG
Analysis Description:
2540G Total Volatile Solids
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35707861001
METHOD BLANK: 4472333
Matrix:
Solid
Associated Lab Samples: 35707861001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Total Volatile Solids
%
0.0010 U
0.0010 0.0010
04/08/22 16:39
SAMPLE DUPLICATE: 4472334
35708523001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Volatile Solids
%
66.4
66.8 1
10
SAMPLE DUPLICATE: 4472335
35708523003
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Volatile Solids
%
68.3
68.0 1
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 815094 Analysis Method: SM271OF
QC Batch Method: SM271OF Analysis Description: Spec.Gravity SM271OF
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35707861001
SAMPLE DUPLICATE: 4474789
Parameter
Specific Gravity
35705679003 Dup
Units Result Result
1.03 1.03
Max
RPD RPD Qualifiers
0 20 N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
QC Batch: 815472
Analysis Method:
EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description:
350.1 Ammonia
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35707861001
METHOD BLANK: 4477327
Matrix: Solid
Associated Lab Samples: 35707861001
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Nitrogen, Ammonia mg/kg
0.28 U 0.85
0.28 04/12/22 17:24
LABORATORY CONTROL SAMPLE: 4477328
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia mg/kg
9.9 10.6
107
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4477330
4477329
MS MSD
35707861001
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Nitrogen, Ammonia mg/kg 2720
10.5 10.5 2650
2680
-607 -317 90-110 1 20 J(M1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/17/2022 02:57 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 20

aceAnalyiical
www.pacelabs.com
r
I
QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, Fl- 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
QC Batch: 816155 Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35707861001
METHOD BLANK: 4481419 Matrix: Solid
Associated Lab Samples: 35707861001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/kg 49.3 U 89.7 49.3 04/15/22 12:58
LABORATORY CONTROL SAMPLE: 4481420
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/kg 2850 2690 95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4481422 4481421
MS MSD
35707861001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 55400 4250 4220 57000 56700 39 31 90-110 1 20 J(M1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/17/2022 02:57 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 20

aceAnalytical
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I
QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
QC Batch: 813823
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate
+ Nitrite
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35707861001
METHOD BLANK: 4467137
Matrix: Solid
Associated Lab Samples: 35707861001
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed Qualifiers
Nitrogen, Nitrate mg/kg
0.25 U 0.50
0.25 04/06/22 15:37
Nitrogen, NO2 plus NO3 mg/kg
0.25 U 0.50
0.25 04/06/22 15:37
LABORATORY CONTROL SAMPLE: 4467138
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/kg
20.2 21.7 107
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4467140
4467139
MS MSD
35707861001
Spike Spike MS MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/kg 7.4 1
21.3 21.3 29.3 28.3
103 99 80-120 4 20
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/17/2022 02:57 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 20

Pace Analytical Services, LLC
aceAnalytical ® 110 South FIw Blvd.
Oldsmar,
FL 34677
www.pacelabs.com [phone]
I
QUALIFIERS
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D} - Laboratory Control Sample (Duplicate)
Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
'Total' may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
U Compound was analyzed for but not detected.
J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (i
recovery.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
Q Sample held beyond the accepted holding time. Analysis initiated more than 15 minutes after sample collection.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/17/2022 02:57 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 20

aceAnalytical
www.patelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Pinellas County Pelletizer
Pace Project No.: 35707861
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
35707861001
Pellet
EPA3050
814502
EPA6010
814687
35707861001
Pellet
EPA 7471
814911
EPA 7471
815011
35707861001
Pellet
ASTM D2974-87
815019
35707861001
Pellet
SM 2540G
814648
35707861001
Pellet
SM 2540G
814649
35707861001
Pellet
EPA 9045
814485
35707861001
Pellet
SM2710F
815094
35707861001
Pellet
TKN-NH3 Calculation
816741
35707861001
Pellet
EPA 350.1
815472
EPA 350.1
815489
35707861001
Pellet
EPA 351.2
816155
EPA 351.2
816363
35707861001
Pellet
EPA 353.2
813823
EPA 353.2
813833
Date: 04/17/2022 02:57 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 20

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DC# Title: ENV-FRM-ORB1-0093 Sample Condition Upon Receipt Form
Version: 3 1 Effective Date: 12/29/2021 1 Issued by: Ormond Beach
Wc/� a �5 ., .' ' "�^n Receipt Form (SCUR) ,. ace
861
Projec PM: CEM I ---- Date and Initials Of person:
Project Manag CLZENT: 37_SYNRGRO Da Date
04/14/22 Examining contentss
Label;
C I i e m. De liver'__.q�_
pH:_ '
Thermometer Used: T202 Date:4 • S• ZrL Time: I(; r!p Initials, D-1
H"
State of Origin: FL For WV projects, all containers verified to <6 °C
Cooler #1 Temp.°C Visual +0.2 ) j 7- a� (Actual) p g process has begun
C%• �( ) (Correction Factor Actual Samples on ice, cooling
Cooler #2 Temp.°C (Visual) (Correction Factor) ez
(Actual) ❑ Samples on ice, cooling process has begun
Cooler #3 Temp.•C (Visual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun
Cooler #4 Temp.°C (Visual) (Correction Factor)
(Actual) ❑ Samples on ice, cooling process has begun
Cooler 95 Temp.°C (Visual) (Correction Factor) (Actual) Samples on ice, cooling process has begun
Cooler #6 Temp.°C (Visual) (Correction Factor) (Actual) Ej Samples on ice, cooling process has begun
Recheck for OOT °C (Visual) (Correction Factor) (Actual) Time: Initials:
Courier: ❑ Fed Ex ❑ UPS ❑ USPS r Client ❑ Commercial ❑ Pace 7 Other_
Shipping Method: ❑ First Overnight ❑ Priority Overnight ❑ Standard Overnight ❑ Ground ❑ International Priority
❑ Other
Billing: ❑ Recipient ❑ Sender ❑ Third Party ❑ Credit Card ❑ Unknown
Tracking #
Custody Seal on Cooler/Box Present: ❑ Yes -No Seals intact: ❑ Yes ❑ No Ice: et Blue Melted None
Packing Material: ❑Bubble Wrap Bubble Bags Slone ❑Other
Samples shorted to lab (If Yes, compl /te) Shorted Date: Shorted Time: Oty:
Chain of Custody Present
K'es
❑ No ❑N/A
Chain of Custody Filled Out
es
❑ No ❑N/A
Relinquished Signature & Sampler Name COC
[Pes
❑ No ❑N/A
Samples Arrived within Hold Time
Yes
❑ No El N/A
Rush TAT requested on COC
❑Yes
o ❑N/A
Sufficient Volume
es
❑ No ❑N/A
Correct Containers Used
%Yes
❑ No ❑N/A
Containers Intact
es
❑ No ❑N/A
Sampld Labels match C C (sample l " % & date/t me a
collection) es
-acid/base
❑ No ❑N/A
All containais needing preservation have
been checked, ❑Yes
All Containers needing preservation are found to be in
compliance with EPA recommendation. ❑Yes
Exceptinns Vials, MicroNobgy, O&G, PFAS
❑ No t/A
❑ No WI/A
Preservation Information:
Preservative:
Lot#/Trace #:
Date; Time:— w_
Initials: d._
Headspace in VOA Vials? (>6mm):
❑Yes
❑ No /A
Trip Blank Present:
❑Yes
❑ No*/A
Uommentsl Resolution (use back for additional comments):
Qualtrax Document ID: 33786 Page 1 of 1
° Page 20 of 20

BENCHMARK
EnviroAnulyticar Inc.
NELAC Certification #E84167
Synagro
P.0, Box 3227
Pinellas Park, FL 33780
Jennifer Amonica
ANALYTICAL TEST REPORT
THESE RESULTS MEET NELAC STANDARDS
Submission Number: 22040127
Project Name : PINELLAS COUNTY PELLETIZER
Date Received : 04/04/2022
Time Received : 1533
Submission Number:
22040127
Sample Date: 04/04/2022
Sample Number:
001
Sample Time: 1430
Sample Description:
Pellet - Final Bin
Sample Method: Grab
Parameter
Result
Units MDL
Procedure Analysts
Date/Time
Analyst
PH
6.57 Q
UNITS
9045 04/04/2022 16:51
EG
TOTAL SOLIDS
94.7
% DRY WT 0.1
SM2540G 04/0512022 15:19
TG
FECAL COLIFORM BY MPN
0,190 U
#/GRAM 0.190
SM9221 E 04/04/2022 16:10
CW
All values reported in UG/KG, MG/KG
WGRAM and MPNlGRAM are on a dry weight basis
V 04/12/2022
Dale D. ffixonLabordory Director Date
Tiilay Tanrisever -Technical Director/QC Officer
Kara Peterson - QA Officer
DATA QUALIFIERS THAT MAY APPLY: NOTES:
I = Reported value Is between the laboratory MDL and the PQL. 2: SOUR calculations are based on Total Solids.
J2 = Esllmaled value. No control criteria exists for this component. PQL = 4xMDL.
J3 = Estimated value. Quality control criteria for precision or accuracy not met.
J4 = Estimated value. Sample matrix Interference suspected. COMMENTS:
L = Off -scale high. Value Is known to be > the value reported.
Q = Sample held beyond accepted hold time.
U = Analyte analyzed but not detected at the value indicated.
V = Analyte detected In sample and method blank.
Y = Analysis performed on an improperly preserved sample. Date may be inaccurate,
Z = Too many colonies were present (TNTC). The numeric value represents the filtration volume.
For questions and comments regarding these results Please contact us at [phone]
Results relate only to the samples.
22040127 1711 12th Street East * Palmetto, FL 34221 * Phone [phone] * Fax [phone] PAGE 1 OF 2

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CERTIFICATION
"I certify, under penalty of law, that the information that will be used to determine compliance with the
Class A pathogen requirements in §503.32(a) and the vector attraction reduction requirement in
§503.33(b)(8) was prepared under my direction and supervision in accordance with the system designed
to ensure that qualified personnel properly gather and evaluate this information. I am aware that there
are significant penalties for false certification including the possibility of fine and imprisonment."
Project(s): South Cross Bayou WRF Pelletizing Facility
Reporting Period: April 2022
Name: William Reyes — Plant Manager----"'`. Synagro
Signature: / t Date: 1-May-2022
The Class A pathogen requirements were met through §503.32(a)(7). The Process to Further Reduce
Pathogens was Heat Drying (Appendix B, B.2.). The biosolids were dried by director indirect contact with
hot gases to reduce the moisture content to 10% or lower. The temperature of the biosolids particles
exceeded 80 degrees Celsius. Fecal coliform testing was performed and the density of fecal coliform in
the biosolids was <1000 MPN per gram of total solids (dry weight basis).
The vector attraction reduction requirement was met through §503.33(b)(8). The percent solids of the
biosolids that contain unstabilized solids generated in a primary wastewater treatment process shall be
>90% based on the moisture content and total solids prior to mixing with other materials.
NTYPE 29: CA5 PR PELL PT VAR 90

HOWARD FERTILIZER
CLASS A
BIOSOLIDS ANALYSIS
Residual Type: Wastewater Treatment Plant (Pinellas)
Date Sampled: July 6, 2022
Date Reported: July 13, 2022
South Cross Bayou WRF Ord Ouarter 2022) Permit No. WQ0037094
Mineralization Rate 0.30 87.50 % Solids
7.1 pH
Parameter
%
Mg/Kg Dry Weight
(% x 10,000)
Pounds/Dry Ton
(Mg/Kg x 0.002)
Nitrogen (TKN)
4.620
46,200.000
92.400
Phosphorus
3.630
36,300.000
72.600
Potassium
0.233
2,330.000
4.660
PAN (injected)*
1.560
15,602.600
31.205
PAN (surface)*
1.436
14,362.600
28.725
Ammonia Nitrogen
0.248
2,480.000
4.960
Calcium
3.820
38,200.000
76.400
Calcium Carbonate Eq.
---
---
---
Magnesium
---
6,460.000
12.920
Sodium
---
1,600.000
3.200
Sulfur
___
___
Nitrate N / Nitrite N
---
6.600
0.013
Barium
---
---
Chloride
---
___
Iron
---
___
Aluminum
---
32,600.000
65.200
Arsenic
---
3.900
0.008
Cadmium
---
1.200
0.002
Chromium
---
---
Copper
---
568.000
1.136
Lead
---
15.900
0.032
Mercury
---
0.340
0.001
Molybdenum
---
11.300
0.023
Nickel
---
26.800
0.054
Selenium
---
4.500
0.009
Zinc
---
821.000
1.642
Pace Analytical 35729485
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N) + Ammonia N + Nitrate N + Nitrite N = % PAN
Surface Application:
(Mineralization Rate)(TKN-Ammonia N) + (0.5)(Ammonia N) + Nitrate N + Nitrite N = % PAN
Note: Constituents N.D. (Not Detected) or < detection limits are listed as detection limits
for calculation purposes.
SAR
1.86
Ceiling Concen.
(MglKg)
75
85
4,300
840
57
75
420
100
7,500

a ce Analytical
www.pacelabs.com
July 13, 2022
William Reyes
Synagro
RE: Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Dear William Reyes:
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on July 06, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
oh-j—
Cameron Meynardie
[e-mail]
813-855-1844
Project Manager
Enclosures
cc: Robert Ervin, Synagro
9BORAiO��
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 20

aceAnalytical
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I
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
CERTIFICATIONS
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Missouri Certification #: 236
Alaska DEC- CS/UST/LUST
Montana Certification #: Cert 0074
Alabama Certification #: 41320
Nebraska Certification: NE-OS-28-14
Colorado Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
Connecticut Certification #: PH-0216
New Jersey Certification #: FL022
Delaware Certification: FL NELAC Reciprocity
New York Certification #: 11608
Florida Certification #: E83079
North Carolina Environmental Certificate #: 667
Georgia Certification #: 955
North Carolina Certification #: 12710
Guam Certification: FL NELAC Reciprocity
North Dakota Certification #: R-216
Hawaii Certification: FL NELAC Reciprocity
Ohio DEP 87780
Illinois Certification #: 200068
Oklahoma Certification #: D9947
Indiana Certification: FL NELAC Reciprocity
Pennsylvania Certification #: 68-00547
Kansas Certification #: E-10383
Puerto Rico Certification #: FLO1264
Kentucky Certification #: 90050
South Carolina Certification: #96042001
Louisiana Certification #: FL NELAC Reciprocity
Tennessee Certification #: TN02974
Louisiana Environmental Certificate #: 05007
Texas Certification: FL NELAC Reciprocity
Maine Certification #: FL01264
US Virgin Islands Certification: FL NELAC Reciprocity
Maryland Certification: #346
Virginia Environmental Certification #: 460165
Massachusetts Certification #: M-FL1264
West Virginia Certification #: 9962C
Michigan Certification #: 9911
Wisconsin Certification #: 399079670
Mississippi Certification: FL NELAC Reciprocity
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 20

aceAnalytical
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i
SAMPLE SUMMARY
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Lab ID Sample ID Matrix Date Collected Date Received
35729485001 Pellet Solid 07/06/2213:30 07/06/2216:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Page 3 of 20

aceAnalytical
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r
i
i
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pace Project No.:
Pinellas County Pelletizer
35729485
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
35729485001
Pellet
EPA6010
AME
18
PASI-O
EPA 7471
JNK
1
PASI-O
ASTM D2974-87
AF
1
PASI-O
SM 2540G
RAK
1
PASI-O
SM 2540G
RAK
1
PASI-O
EPA 9045
SWB
1
PASI-O
SM271OF
AGS
1
PASI-O
TKN-NH3 Calculation
AVW
1
PASI-O
EPA 350.1
RMB
1
PASI-O
EPA 351.2
AVW
1
PASI-O
EPA 353.2
MRC
2
PASI-O
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar. FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Sample: Pellet
Lab ID: 35729485001 Collected: 07/06/22 13:30
Received: 07/06/22 16:09 Matrix: Solid
Results reported on a "dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units PQL MDL
DF
Prepared
Analyzed
CAS No. Qua[
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Pace Analytical Services - Ormond Beach
Aluminum
32600 mg/kg 103 63.1
1
07/07/22 09:41
07/08/22 06:07
7429-90-5
Arsenic
3.9 1 mg/kg 5.2 2.6
1
07/07/22 09:41
07/08/22 06:07
7440-38-2
Boron
66.0 mg/kg 25.9 4.2
1
07/07/22 09:41
07/08/22 06:07
7440-42-8
Cadmium
1.2 mg/kg 0.52 0.26
1
07/07/22 09:41
07/08/22 06:07
7440-43-9
Calcium
38200 mg/kg 517 372
1
07/07/22 09:41
07/08/22 06:07
7440-70-2
Copper
568 mg/kg 12.9 6.5
5
07/07/22 09:41
07/11/22 11:01
7440-50-8
Iron
13700 mg/kg 103 31.0
1
07/07/22 09:41
07/08/22 06:07
7439-89-6
Lead
15.9 mg/kg 5.2 2.6
1
07/07/22 09:41
07/08/22 06:07
7439-92-1
Magnesium
6460 mg/kg 259 129
1
07/07/22 09:41
07/08/22 06:07
7439-95-4
Manganese
208 mg/kg 2.6 1.3
1
07/07/22 09:41
07/08/22 06:07
7439-96-5
Molybdenum
11.3 mg/kg 5.2 2.6
1
07/07/22 09:41
07/08/22 06:07
7439-98-7
Nickel
26.8 mg/kg 2.6 1.3
1
07/07/22 09:41
07/08/22 06:07
7440-02-0
Phosphorus
36300 mg/kg 25900 1400
50
07/07/22 09:41
07/11/22 11:05
7723-14-0
Potassium
2330 mg/kg 517 259
1
07/07/22 09:41
07/08/22 06:07
7440-09-7
Selenium
4.5 1 mg/kg 7.8 3.9
1
07/07/22 09:41
07/08/22 06:07
7782-49-2
Sodium
1600 mg/kg 517 259
1
07/07/22 09:41
07/08/22 06:07
7440-23-5
Sulfur
13300 mg/kg 517 52.8
1
07/07/22 09:41
07/08/22 06:07
Zinc
821 mg/kg 51.7 18.6
1
07/07/22 09:41
07/08/22 06:07
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Pace Analytical Services - Ormond Beach
Mercury
0.34 mg/kg 0.073 0.037
1
07/07/22 07:37
07/11/22 14:18
7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Ormond Beach
Percent Moisture
8.5 % 0.10 0.10
1
07/08/22 14:26
2540G Total Solids
Analytical Method: SM 254OG
Pace Analytical Services - Ormond Beach
Total Solids
87.5 % 0.0010 0.0010
1
07/10/22 17:02
2540G Total Volatile Solids
Analytical Method: SM 2540G
Pace Analytical Services - Ormond Beach
Total Volatile Solids
66.7 % 0.0010 0.0010
1
07/10/22 17:02
9045 pH Soil
Analytical Method: EPA 9045
Pace Analytical Services - Ormond Beach
pH at 25 Degrees C
7.1 Std. Units 0.10 0.10
1
07/07/22 15:57
Q
Specific Gravity/Bulk Density
Analytical Method: SM271 OF
Pace Analytical Services - Ormond Beach
Specific Gravity
0.630
1
07/11/22 09:03
N2
REPORT OF LABORATORY ANALYSIS
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Date: 07/13/2022 10:18 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 20

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ANALYTICAL RESULTS
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Sample: Pellet Lab ID: 35729485001 Collected: 07/06/22 13:30 Received: 07/06/22 16:09 Matrix: Solid
Results reported on a "dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No.
Total Organic Nitrogen Soil
Total Organic Nitrogen
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Date: 07/13/2022 10:18 AM
Analytical Method: TKN-NH3 Calculation
Pace Analytical Services - Ormond Beach
43700 mg/kg 21.9 12.0 1
07/12/2214:41
Analytical Method: EPA 350.1 Preparation Method: EPA 350.1
Pace Analytical Services - Ormond Beach
2480 mg/kg 46.4 15.4 50 07/08/22 16:53
07/08/22 20:56 7664-41-7
Analytical Method: EPA 351.2 Preparation Method: EPA 351.2
Pace Analytical Services - Ormond Beach
46200 mg/kg 1080 595 10 07/09/2212:40
07/12/2212:11 7727-37-9
Analytical Method: EPA 353.2 Preparation Method: EPA 353.2
Pace Analytical Services - Ormond Beach
3.9 mg/kg 0.55 0.27 1 07/07/22 08:55
07/07/22 11:10
2.7 mg/kg 0.55 0.27 1 07/07/22 08:55
07/07/22 11:10 14797-55-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Qual
J(M1)
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
QC Batch: 837604
Analysis Method:
EPA 7471
QC Batch Method: EPA 7471
Analysis Description:
7471 Mercury
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
METHOD BLANK: 4603616
Matrix: Solid
Associated Lab Samples: 35729485001
Blank Reporting
Parameter Units
Result Limit
MDL Analyzed Qualifiers
Mercury mg/kg
0.0043 U 0.0087 0.0043 07/11/2214:21
LABORATORY CONTROL SAMPLE: 4603617
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
0.089 0.082
92 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4603618 4603619
MS MSD
35728762005
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.0089 1
0.11 0.11 0.10
0.10 86 84 80-120 2 20
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 07/13/2022 10:18 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 837655 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
METHOD BLANK: 4603753
Associated Lab Samples: 35729485001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
MDL
Analyzed Qualifiers
Aluminum
mg/kg
7.0 U
11.4
7.0
07/08/22 05:03
Arsenic
mg/kg
0.29 U
0.57
0.29
07/08/22 05:03
Boron
mg/kg
0.47 U
2.9
0.47
07/08/22 05:03
Cadmium
mg/kg
0.029 U
0.057
0.029
07/08/22 05:03
Calcium
mg/kg
41.2 U
57.2
41.2
07/08/22 05:03
Copper
mg/kg
0.14 U
0.29
0.14
07/08/22 05:03
Iron
mg/kg
3.4 U
11.4
3.4
07/08/22 05:03
Lead
mg/kg
0.29 U
0.57
0.29
07/08/22 05:03
Magnesium
mg/kg
14.3 U
28.6
14.3
07/08/22 05:03
Manganese
mg/kg
0.14 U
0.29
0.14
07/08/22 05:03
Molybdenum
mg/kg
0.29 U
0.57
0.29
07/08/22 05:03
Nickel
mg/kg
0.14 U
0.29
0.14
07/08/22 05:03
Phosphorus
mg/kg
3.1 U
57.2
3.1
07/08/22 05:03
Potassium
mg/kg
28.6 U
57.2
28.6
07/08/22 05:03
Selenium
mg/kg
0.43 U
0.86
0.43
07/08/22 05:03
Sodium
mg/kg
28.6 U
57.2
28.6
07/08/22 05:03
Sulfur
mg/kg
5.8 U
57.2
5.8
07/08/22 05:03
Zinc
mg/kg
2.1 U
5.7
2.1
07/08/22 05:03
LABORATORY CONTROL SAMPLE:
Parameter
4603754
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
126
127
101
80-120
Arsenic
mg/kg
12.6
11.7
93
80-120
Boron
mg/kg
63
57.8
92
80-120
Cadmium
mg/kg
1.3
1.2
99
80-120
Calcium
mg/kg
630
683
108
80-120
Copper
mg/kg
12.6
13.1
104
80-120
Iron
mg/kg
126
134
106
80-120
Lead
mg/kg
12.6
12.8
101
80-120
Magnesium
mg/kg
630
652
103
80-120
Manganese
mg/kg
12.6
12.9
102
80-120
Molybdenum
mg/kg
12.6
12.7
101
80-120
Nickel
mg/kg
12.6
12.9
102
80-120
Phosphorus
mg/kg
12.6
12.6 1
100
80-120
Potassium
mg/kg
630
641
102
80-120
Selenium
mg/kg
12.6
11.7
93
80-120
Sodium
mg/kg
630
665
106
80-120
Sulfur
mg/kg
126
119
95
80-120
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
LABORATORY CONTROL SAMPLE: 4603754
Spike LCS LCS
Parameter Units Conc. Result % Rec
Zinc mg/kg 63 66.0 105
Pace Analytical Services, LLC
110 South Sayview Blvd.
Oldsmar, FL 34677
[phone]
% Rec
Limits Qualifiers
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4603755
MS
35729112001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
4603756
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Aluminum
mg/kg
2230
1180
1320
4020
4130
151
145
75-125
3
20 J(M1)
Arsenic
mg/kg
2.6 U
118
132
115
127
95
95
75-125
10
20
Boron
mg/kg
38.7
593
657
594
645
94
92
75-125
8
20
Cadmium
mg/kg
1.1
11.8
13.2
13.1
14.3
101
100
75-125
9
20
Calcium
mg/kg
26900
5930
6570
32700
35000
98
123
75-125
7
20
Copper
mg/kg
373
118
132
511
511
117
105
75-125
0
20 L
Iron
mg/kg
31600
1180
1320
26700
33300
-407
129
75-125
22
20 J(M1),
J(R1),
L
Lead
mg/kg
15.7
118
132
137
151
102
103
75-125
10
20
Magnesium
mg/kg
6800
5930
6570
12900
13600
104
104
75-125
5
20
Manganese
mg/kg
74.6
118
132
203
214
109
106
75-125
5
20
Molybdenum
mg/kg
7.9
118
132
128
142
101
102
75-125
10
20
Nickel
mg/kg
16.7
118
132
141
154
105
104
75-125
9
20
Phosphorus
mg/kg
30000
118
132
29000
30600
-773
484
75-125
5
20 J(M1),
L
Potassium
mg/kg
0.32 %
5930
6570
9440
9930
159
151
75-125
199
20 J(M1)
(w/w)
Selenium
mg/kg
3.9 U
118
132
118
130
97
97
75-125
10
20
Sodium
mg/kg
1070
5930
6570
7370
7960
106
105
75-125
8
20
Sulfur
mg/kg
11600
1180
1320
12500
13300
75
127
75-125
6
20 J(M1)
Zinc
mg/kg
911
593
657
1520
1570
103
101
75-125
3
20
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/13/2022 10:18 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
QC Batch: 838103
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
SAMPLE DUPLICATE: 4606713
35729485001
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
8.5
8.7 3
10
SAMPLE DUPLICATE: 4606714
35729964001
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
2.8
3.6 23
10 J(D6)
SAMPLE DUPLICATE: 4606715
35730021005
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
20.8
21.2 2
10
SAMPLE DUPLICATE: 4606716
35730021015
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
20.0
19.0 5
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 838308 Analysis Method: SM 2540G
QC Batch Method: SM 2540G Analysis Description: 2540G Total Solids
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
SAMPLE DUPLICATE: 4607934
35729855003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Solids % 19.0 18.6 2 10
SAMPLE DUPLICATE: 4607935
35729909002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Solids % 17.3 23.0 29 10 J(D6)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
QC Batch: 838311
Analysis Method: SM 2540G
QC Batch Method: SM 2540G
Analysis Description: 2540G Total Volatile Solids
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
METHOD BLANK: 4607936
Matrix:
Solid
Associated Lab Samples: 35729485001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Total Volatile Solids
%
0.0010 U
0.0010 0.0010
07/10/22 17:04
SAMPLE DUPLICATE: 4607938
35729855003
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Volatile Solids
%
64.5
64.5 0
10
SAMPLE DUPLICATE: 4607939
35729909002
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Volatile Solids
%
74.2
73.3 1
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 838399 Analysis Method: SM271OF
QC Batch Method: SM271OF Analysis Description: Spec.Gravity SM271OF
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
SAMPLE DUPLICATE: 4608145
Parameter
Specific Gravity
35727704003 Dup
Units Result Result
1.02 1.02
Max
RPD RPD Qualifiers
0 20 N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
QC Batch: 837847 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
METHOD BLANK: 4604781 Matrix: Solid
Associated Lab Samples: 35729485001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Ammonia mg/kg 0.28 U 0.86 0.28 07/08/22 20:46
LABORATORY CONTROL SAMPLE: 4604782
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/kg 10 10.6 106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4604784 4604783
MS MSD
35729485001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Ammonia mg/kg 2480 10.9 10.9 2550 2500 676 212 90-110 2 20 J(M1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/13/2022 10:18 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
QC Batch: 838098
Analysis Method:
EPA 351.2
QC Batch Method: EPA 351.2
Analysis Description:
351.2 TKN
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
METHOD BLANK: 4606615
Matrix: Solid
Associated Lab Samples: 35729485001
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
47.5 U 86.4
47.5 07/12/22 11:59
LABORATORY CONTROL SAMPLE: 4606616
Spike LCS
LCS
% Rec
Parameter Units
Cone. Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
2860 2770
97
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4606618 4606617
MS MSD
35729112001
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Cone. Cone. Result
Result
% Rec % Rec Limits RPD RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 5.9 %
4200 4180 61200
60900
60 55 90-110 0 20 J(M1)
(W/W)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/13/2022 10:18 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 837659 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35729485001
METHOD BLANK: 4603767 Matrix: Solid
Associated Lab Samples: 35729485001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Nitrate mg/kg 0.25 U 0.50 0.25 07/07/22 11:08
Nitrogen, NO2 plus NO3 mg/kg 0.25 U 0.50 0.25 07/07/22 11:08
LABORATORY CONTROL SAMPLE: 4603768
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/kg 19.9 21.6 109 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4603770 4603769
MS MSD
35729485001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/kg 3.9 21.9 21.9 22.7 25.4 86 99 80-120 11 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07113/2022 10:18 AM without the written consent of Pace Analytical Services, LLC.
Page 16 of 20

Pace Analytical Services, LLC
110 South Bayview Blvd.
aceAnalytical
Oldsmar, FL 34677
www.pacelabs.com [phone]
QUALIFIERS
Project: Pinellas County Pelletizer
Pace Project No.: 35729485
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
'Total' may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
U Compound was analyzed for but not detected.
J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory
control limits.
J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)
recovery.
J(R1) Estimated Value. RPD value was outside control limits.
L Off -scale high. Actual value is known to be greater than value given.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
Q Sample held beyond the accepted holding time. Analysis initiated more than 15 minutes after sample collection.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/13/2022 10:18 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 20

aceAnalytical
www.pacelabs.com
t
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pace Project No.:
Pinellas County Pelletizer
35729485
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical
Method
Batch
35729485001
Pellet
EPA 3050
837655
EPA
6010
837783
35729485001
Pellet
EPA 7471
837604
EPA
7471
837657
35729485001
Pellet
ASTM D2974-87
838103
35729485001
Pellet
SM 2540G
838308
35729485001
Pellet
SM 254OG
838311
35729485001
Pellet
EPA 9045
837676
35729485001
Pellet
SM271OF
838399
35729485001
Pellet
TKN-NH3 Calculation
838798
35729485001
Pellet
EPA 350.1
837847
EPA
350.1
838148
35729485001
Pellet
EPA 351.2
838098
EPA
351.2
838601
35729485001
Pellet
EPA 353.2
837659
EPA
353.2
837684
Date: 07/13/2022 10:18 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 20

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DC#_Title: ENV-FRM-ORB1-0093 Sample Condition Upon Receipt Form
Version: 3 � Effective Date: 12/29/2021 1 Issued by: Ormond Beach
WOE : 35729435 R) ace
Project# PM: CEM Due Date: 07/15/22
CLIENT: 37-SYNAGRO Date and Initials of person:
Project Manager: Examining contents.__
Label:
Client: Deliver:.
/(//�' /� �pH:
Thermometer Used T202 Date: ` Time: Initials:
State of rlgin: FL ❑ For WV projects, all containers verified to <6 °C
p.°� (Visu0Cooler #1 Tern .2 (Correction Factor) q1 45 (Actual) 1Y� Samples on ice, cooling process has begun
Cooler #2 Temp.°C (Visual) (Correction Factor) (Actual) �❑ Samples on ice, cooling process has begun
Cooler #3 Temp °C (Visual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun
Cooler #4 Temp."C (Visual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun
Cooler 95 Temp-'C (Visual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun
Cooler#6 Temp.`C VVssual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun
Recheck for OOT °C (Visual) (Correction Factor) (Actual) Time: Initials:
Courier: ❑ Fed Ex ❑ UPS ❑ USPS Client ❑ Commercial ❑ Pace El Other
Shipping Method: ❑ First Overnight ❑ Priority Overnight ❑ Standard Overnight ❑ Ground ❑ International Priority
❑ Other
Billing: ❑ Recipient ❑ Sender ❑ Third Party ❑ Credit Card ❑ Unknown
Tracking #
Custody Seal on CoolerlBox Present: ❑ Yes A Seals intact: ❑ Yes ❑
Packing Material: OBubble Wrap 1/1ubble Bags ❑lone ❑Other
Samples shorted to lab (If Yes, complete) Shorted Date
f' -a
Blue Melted None
Shorted Time: Oty: -_
Chain of Custody Present
rz
_ Xe s
❑ No ❑N/A
Chain of Custody Filled Out
es
❑ No ❑N/A
Relinquished Signature & Sampler Name COC
�1 es
❑ No ❑N/A
Samples Arrived within Hold Time
4�9-Yes
❑ No El N/A
Rush TAT requested on COC
❑Yes No ❑N/A
Sufficient Volume
'Ayes
❑ No ❑N/A
Correct Containers Used
rOYes
❑ No ❑N/A
Containers Intact
—bOes
❑ No El N/A
ample Labe s match (sample I s date time o
collection)
❑Yes
�1,(`,l o ❑N/A
AA) I -f�
t (/a1
All containers needing acid/base preservation have
been checked ❑Yes
All Containers needing preservation are found to be in
compliance with EPA recommendation: ❑Yes
Exceptions: Vials, Microbiology, O&G, PFAS
❑ No 0,N/A
❑ No A/A
Preservation Information:
Preservative:
Lot #/Trace #;
Date: Time.
Initials:
Headspace in VOA Vials? ( >6mm): ❑Yes
❑ No, INN/A
Trip Blank Present:
❑Yes
❑ No-i!�N/A
Comments/ Resolution (use back for additional comments):
Qualtrax Document ID: 33786 Page 1 of 1
Page 20 of 20

FDOH Certification 9E84167 BENCHMARK
EnviroAnalytical, ,Inc.
ANALYTICAL TEST REPORT
THESE RESULTS MEET NELAC STANDARDS
Submission Number, 22070237
Synagro
P.O, Box 3227
Pinellas Park, FL 33780
Jennifer Arnonica
Project Name : PINELLAS COUNTY PELLETIZER
Date Received : 07/06/2022
Time Received : 16:00
Submission Number:
22070237
Sample Date:
07/06/2022
Sample Number:
001
Sample Time:
14:50
Sample Description:
Final Elevator
Sample Method:
Grab
Parameter
Result
Units MDL
Procedure
Analysis
Date/Time
Analyst
PH
6.89 0
UNITS
9046
07/06/2022 17:00
EG
TOTAL SOLIDS
94.8
% DRY WT 0.1
SM254OG
07/081202215:50
TG
FECAL COLIFORM BY MPN
0.190 U
#/GRAM 0.190
SM9221 E
07126/2022 16:15
LG
All values reported in UG/KG, MG1KG WGRAM and MPN/GRAM are on a dry weight basis
08/05/2022
Dale D. D xon / Labora ry Director
Date
TUlay Tanrisever- echnl al Director= Officer
Kara Peterson - QA Officer
DATA QUALIFIERS THAT MAY APPLY: NOTES:
I = Reported value Is between the laboratory MDL and the PQL. 2: SOUR calculations are based on Total Solids
J2 = Estimated value. Me control criteria exists for this component. PQL - 4xMDL.
J3 = Estimated value. Quality control criteria for precision or accuracy not met.
d4 = Estimated value. Sample matrix Interference suspected. COMMENTS:
L = Off -scale high. Value Is known to be > the Value reported. �—
Q = Sample held beyond accepted hold time.
U = Anslyte analyzed but not detected al the value Indicated.
V=Analyle detected in sample and method blank.
Y = Analysis performed on an Improperly preserved sample, Data may be inaccurate.
Z = Too many colonies were present (TNTC). The numeric value represents the filtration volume.
For questions and comments regardine these results please contact us at [phone]
Results relate only to the samples.
22070237 1711 12th Street East * Palmetto, FL 34221 * Phone [phone] * Fax [phone] PAGE r OF 2

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CERTIFICATION
"I certify, under penalty of law, that the information that will be used to determine compliance with the
Class A pathogen requirements in §503.32(a) and the vector attraction reduction requirement in
§503.33(b)(8) was prepared under my direction and supervision in accordance with the system designed
to ensure that qualified personnel properly gather and evaluate this information. I am aware that there
are significant penalties for false certification including the possibility of fine and imprisonment."
Project(s): South Cross Bayou WRF Pelletizing Facility
Reporting Period: July 2022
Name: William Reyes — Plant Vangger Synagro
Signature: _.
g Date: 1-Aug ust-2022
The Class A pathogen requirements were met through §503.32(a)(7). The Process to Further Reduce
Pathogens was Heat Drying (Appendix 6, B.2.). The biosolids were dried by direct or indirect contact with
hot gases to reduce the moisture content to 10% or lower. The temperature of the biosolids particles
exceeded 80 degrees Celsius. Fecal coliform testing was performed and the density of fecal coliform in
the biosolids was <1000 MPN per gram of total solids (dry weight basis).
The vector attraction reduction requirement was met through §503.33(b)(8). The percent solids of the
biosolids that contain unstabilized solids generated in a primary wastewater treatment process shall be
>90% based on the moisture content and total solids prior to mixing with other materials.
NTYPE 29: CA5 PR PELL PT VAR 90

HOWARD FERTILIZER
CLASS A
BIOSOLIDS ANALYSIS
Residual Type: Wastewater Treatment Plant (Pinellas)
Date Sampled: October 4, 2022
Date Reported: October 21, 2022
South Cross Bayou WRF (4th Ouarter 2022) Permit No. WQ0037094
Mineralization Rate 0.30 92.90 % Solids
7.5 pH
Parameter
%
Mg/Kg Dry Weight
(% x 10,000)
Pounds/Dry Ton
(Mg/Kg x 0.002)
Nitrogen (TKN)
4.330
43,300.000
86.600
Phosphorus
2.030
20,300.000
40.600
Potassium
0.074
739.000
1.478
PAN (injected)*
1.412
14,117.300
28.235
PAN (surface)*
1.332
13,317.300
26.635
Ammonia Nitrogen
0.160
1,600.000
3.200
Calcium
2.110
21,100.000
42.200
Calcium Carbonate Eq.
---
___
---
Magnesium
---
4,750.000
9.500
Sodium
---
1,220.000
2.440
Sulfur
---
___
Nitrate N / Nitrite N
---
7.300
0.015
Barium
Chloride
---
---
---
---
---
SAR
1.90
Iron
---
---
---
Ceiling Concen.
Aluminum
---
26,400.000
52.800
(Mg/Kg)
Arsenic
---
5.200
0.010
75
Cadmium
---
0.880
0.002
85
Chromium
---
--_
___
Copper
---
328.000
0.656
4,300
Lead
---
11.500
0.023
840
Mercury
---
0.340
0.001
57
Molybdenum
---
12.300
0.025
75
Nickel
---
18.800
0.038
420
Selenium
---
3.700
0.007
100
Zinc
---
775.000
1.550
7,500
Pace Analytical 35750478
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N) + Ammonia N + Nitrate N + Nitrite N = % PAN
Surface Application:
(Mineralization Rate)(TKN-Ammonia N) + (0.5)(Ammonia N) + Nitrate N + Nitrite N = % PAN
Note: Constituents N.D. (Not Detected) or < detection limits are listed as detection limits
for calculation purposes.

aceAnalj4ical
www.pacelabs.com
October 21, 2022
William Reyes
Synagro
RE: Project: Pinellas County Pelletizer
Pace Project No.: 35750478
Dear William Reyes:
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on October 04, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Cameron Meynardie
[e-mail]
813-855-1844
Project Manager
Enclosures
cc: Robert Ervin, Synagro
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 21

aceAnalytical
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t
CERTIFICATIONS
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Missouri Certification #: 236
Alaska DEC- CS/UST/LUST
Montana Certification #: Cert 0074
Alabama Certification #: 41320
Nebraska Certification: NE-OS-28-14
Colorado Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
Connecticut Certification #: PH-0216
New Jersey Certification #: FL022
Delaware Certification: FL NELAC Reciprocity
New York Certification #: 11608
Florida Certification #: E83079
North Carolina Environmental Certificate #: 667
Georgia Certification #: 955
North Carolina Certification #: 12710
Guam Certification: FL NELAC Reciprocity
North Dakota Certification #: R-216
Hawaii Certification: FL NELAC Reciprocity
Ohio DEP 87780
Illinois Certification #: 200068
Oklahoma Certification #: D9947
Indiana Certification: FL NELAC Reciprocity
Pennsylvania Certification #: 68-00547
Kansas Certification #: E-10383
Puerto Rico Certification #: FL01264
Kentucky Certification #: 90050
South Carolina Certification: #96042001
Louisiana Certification #: FL NELAC Reciprocity
Tennessee Certification #: TN02974
Louisiana Environmental Certificate #: 05007
Texas Certification: FL NELAC Reciprocity
Maine Certification #: FLO1264
US Virgin Islands Certification: FL NELAC Reciprocity
Maryland Certification: #346
Virginia Environmental Certification #: 460165
Massachusetts Certification #: M-FL1264
West Virginia Certification #: 9962C
Michigan Certification #: 9911
Wisconsin Certification #: 399079670
Mississippi Certification: FL NELAC Reciprocity
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 21

aceAnaiytical
www.pacelabs.com
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
Lab ID Sample ID
SAMPLE SUMMARY
Matrix Date Collected Date Received
35750478001 Pellet Solid 10/04/2215:20 10/04/2216:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Page 3 of 21

aceAnalytical
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SAMPLE ANALYTE COUNT
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
35750478001 Pellet EPA6010
AME, KC2
18
PASI-O
EPA 7471
JNK
1
PASI-O
ASTM D2974-87
BMA
1
PASI-O
SM 254OG
JJB
1
PASI-O
SM 2540G
JJB
1
PASI-O
EPA 9045
SWB
1
PASI-O
SM271OF
AGS
1
PASI-O
TKN-NH3 Calculation
AGS
1
PASI-O
EPA 350.1
RMB
1
PASI-O
EPA 351.2
NMT
1
PASI-O
EPA 353.2
KW1
2
PASI-O
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 21

aceAnalytical
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
Sample: Pellet
Lab ID: 35750478001 Collected: 10/04/22 15:20
Received: 10/04/22 16:20 Matrix: Solid
Results reported on a "dry weight'
basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units PQL MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Pace Analytical Services - Ormond Beach
Aluminum
26400 mg/kg 262 160
20
10/05/22 19:13
10/10/2210:01
7429-90-5
J(M1)
Arsenic
5.2 mg/kg 0.65 0.33
1
10/05/22 19:13
10/10/22 09:57
7440-38-2
J(M1)
Boron
57.1 mg/kg 19.6 3.2
1
10/13/2219:19
10/17/2214:31
7440-42-8
J(M1),
J(R1)
Cadmium
0.88 mg/kg 0.065 0.033
1
10/05/22 19:13
10/10/22 09:57
7440-43-9
J(M1)
Calcium
21100 mg/kg 65.4 47.1
1
10/05/22 19:13
10/07/2212:31
7440-70-2
J(M1)
Copper
328 mg/kg 6.5 3.3
20
10/05/22 19:13
10/10/2210:01
7440-50-8
J(M1)
Iron
15600 mg/kg 262 78.5
20
10/05/22 19:13
10/10/2210:01
7439-89-6
J(M1)
Lead
11.5 mg/kg 0.65 0.33
1
10/05/22 19:13
10/10/22 09:57
7439-92-1
J(M1)
Magnesium
4750 mg/kg 196 97.9
1
10113/2219:19
10/17/2214:31
7439-95-4
J(M1)
Manganese
275 mg/kg 6.5 5.2
20
10/05/22 19:13
10/10/2210:01
7439-96-5
J(M1)
Molybdenum
12.3 mg/kg 3.9 2.0
1
10/13/2219:19
10/17/2214:31
7439-98-7
J(M1),
J(R1)
Nickel
18.8 mg/kg 0.33 0.16
1
10/05/22 19:13
10/10/22 09:57
7440-02-0
J(M1)
Phosphorus
20300 mg/kg 13100 706
200
10/05/22 19:13
10/11/22 09:59
7723-14-0
Potassium
739 mg/kg 391 196
1
10/13/2219:19
10/17/2214:31
7440-09-7
J(M1),
J(R1)
Selenium
3.7 1 mg/kg 5.9 2.9
1
10/13/2219:19
10/17/2214:31
7782-49-2
J(M1),
J(R1)
Sodium
1220 mg/kg 391 196
1
10/13/2219:19
10117/2214:31
7440-23-5
J(M1),
J(R1)
Sulfur
13900 mg/kg 391 39.9
1
10/13/2219:19
10/17/2214:31
J(M1)
Zinc
775 mg/kg 39.1 14.1
1
10/13/2219:19
10/17/2214:31
7440-66-6
i(MI)
7471 Mercury
Analytical Method: EPA7471 Preparation Method: EPA7471
Pace Analytical Services - Ormond Beach
Mercury
0.34 mg/kg 0.047 0.024
1
10/10/22 07:51
10/10/22 11:27
7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Ormond Beach
Percent Moisture
7.6 % 0.10 0.10
1
10/07/22 13:22
254OG Total Solids
Analytical Method: SM 254OG
Pace Analytical Services - Ormond Beach
Total Solids
92.9 % 0.0010 0.0010
1
10/08/22 12:27
254OG Total Volatile Solids
Analytical Method: SM 2540G
Pace Analytical Services - Ormond Beach
Total Volatile Solids
60.3 % 0.0010 0.0010
1
10/08/22 12:27
9045 pH Soil
Analytical Method: EPA 9045
Pace Analytical Services - Ormond Beach
pH at 25 Degrees C
7.5 Std. Units 0.10 0.10
1
10/05/22 16:01
Q
REPORT OF LABORATORY ANALYSIS
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Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 21

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ANALYTICAL RESULTS
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Sample: Pellet Lab ID: 35750478001 Collected: 10/04/22 15:20 Received: 10/04/22 16:20 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted forpercent moisture, sample size and any dilutions.
Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual
Specific Gravity/Bulk Density
Analytical Method: SM271OF
Pace Analytical Services - Ormond Beach
Specific Gravity
0.630 1
10/13/22 12:43 N2
Total Organic Nitrogen Soil
Analytical Method: TKN-NH3 Calculation
Pace Analytical Services - Ormond Beach
Total Organic Nitrogen
41700 mg/kg 21.6 11.9 1
10/14/22 08:35
350.1 Ammonia
Analytical Method: EPA 350.1 Preparation Method: EPA 350.1
Pace Analytical Services - Ormond Beach
Nitrogen, Ammonia
1600 mg/kg 13.8 4.6 15 10/05/22 18:29
10/06/22 20:47 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Preparation Method: EPA 351.2
Pace Analytical Services - Ormond Beach
Nitrogen, Kjeldahl, Total
43300 mg/kg 1080 593 10 10/08/22 13:38
10/11/22 16:34 7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Preparation Method: EPA 353.2
Pace Analytical Services - Ormond Beach
Nitrogen, NO2 plus NO3
4.3 mg/kg 0.54 0.27 1 10/05/22 19:46
10/05/22 21:26
Nitrogen, Nitrate
3.0 mg/kg 0.54 0.27 1 10/05/22 19:46
10/05/22 21:26 14797-55-8
Date: 10/21/2022 11:51 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar. FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
QC Batch: 862139 Analysis Method: EPA 7471
QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35750478001
METHOD BLANK: 4745361 Matrix: Solid
Associated Lab Samples: 35750478001
Blank Reporting
Parameter Units Result Limit
Mercury mg/kg 0.0049 U 0.0098
LABORATORY CONTROL SAMPLE: 4745362
Spike LCS
Parameter Units Conc. Result
Mercury mg/kg 0.096 0.097
MDL Analyzed Qualifiers
0.0049 10/10/22 11:22
LCS % Rec
% Rec Limits Qualifiers
101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4745363 4745364
MS MSD
35751276001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.025 0.13 0.12 0.13 0.12 84 82 80-120 6 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/21 /2022 11:51 AM without the written consent of Pace Analytical Services, LLC.
Page 7 of 21

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Project: Pinellas County Pelletizer
Pace Project No.: 35750478
QC Batch: 861087
QC Batch Method: EPA 3050
Associated Lab Samples: 35750478001
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 6010
Analysis Description: 6010 MET Solid
Laboratory: Pace Analytical Services - Ormond Beach
METHOD BLANK: 4739315
Associated Lab Samples: 35750478001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
MDL
Analyzed Qualifiers
Aluminum
mg/kg
6.9 U
11.3
6.9
10/10/2210:09
Arsenic
mg/kg
0.28 U
0.56
0.28
10/10/2210:09
Cadmium
mg/kg
0.028 U
0.056
0.028
10/10/2210:09
Calcium
mg/kg
40.5 U
56.3
40.5
10110/2210:09
Copper
mg/kg
0.14 U
0.28
0.14
10/10/2210:09
Iron
mg/kg
3.4 U
11.3
3.4
10/10/2210:09
Lead
mg/kg
0.28 U
0.56
0.28
10/1012210:09
Manganese
mg/kg
0.22 U
0.28
0.22
10/10/2210:09
Nickel
mg/kg
0.14 U
0.28
0.14
10/10/2210:09
Phosphorus
mg/kg
3.0 U
56.3
3.0
10/1012210:09
LABORATORY CONTROL SAMPLE:
Parameter
4739316
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
120
118
98
80-120
Arsenic
mg/kg
12
11.4
95
80-120
Cadmium
mg/kg
1.2
1.2
102
80-120
Calcium
mg/kg
602
622
103
80-120
Copper
mg/kg
12
12.1
100
80-120
Iron
mg/kg
120
126
104
80-120
Lead
mg/kg
12
12.5
104
80-120
Manganese
mg/kg
12
12.3
102
80-120
Nickel
mg/kg
12
12.5
104
80-120
Phosphorus
mg/kg
12
12.6 1
105
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4739317
4739318
MS
MSD
35750478001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
41300
159
160
30500
25100
2570
-777
75-125
19
20 J(M1),
L
Arsenic
mg/kg
13.2
15.9
16
17.1
14.8
75
60
75-125
14
20 J(M1)
Cadmium
mg/kg
1.6
1.6
1.6
2.1
1.8
79
59
75-125
15
20 J(M1)
Calcium
mg/kg
38900
793
801
27900
23100
858
250
75-125
19
20 J(M1)
Copper
mg/kg
578
15.9
16
419
351
576
149
75-125
18
20 J(M1)
Iron
mg/kg
24900
159
160
16100
13500
332
-1310
75-125
18
20 J(M1),
L
Lead
mg/kg
17.8
15.9
16
24.7
21.1
83
60
75-125
16
20 J(M1)
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pace Project No.:
Pinellas County Pelletizer
35750478
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4739317
4739318
MS
MSD
35750478001
Spike
Spike MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc. Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Manganese
mg/kg 437
15.9
16 316
262
257
-79
75-125
18
20 J(M1),
L
Nickel
mg/kg 31.4
15.9
16 32.9
29.0
89
64
75-125
12
20 J(M1)
Phosphorus
mg/kg 31800
15.9
16 24000
20900
23200
3470
75-125
14
20 L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC.
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aceAnalyiical
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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 863486 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35750478001
METHOD BLANK: 4752422
Matrix:
Solid
Associated Lab Samples: 35750478001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Boron
mg/kg
1.4 1
3.1
0.51
10/17/22 09:40
Magnesium
mg/kg
15.5 U
30.9
15.5
10/17/22 09:40
Molybdenum
mg/kg
0.31 U
0.62
0.31
10/17/22 09:40
Potassium
mg/kg
30.9 U
61.9
30.9
10/17/22 09:40
Selenium
mg/kg
0.46 U
0.93
0.46
10/17/22 09:40
Sodium
mg/kg
30.9 U
61.9
30.9
10/17/22 09:40
Sulfur
mg/kg
6.3 U
61.9
6.3
10/17/22 09:40
Zinc
mg/kg
2.2 U
6.2
2.2
10/17/22 09:40
LABORATORY CONTROL SAMPLE:
4752423
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Boron
mg/kg
61.8
59.7
97
80-120
Magnesium
mg/kg
618
602
97
80-120
Molybdenum
mg/kg
12.4
12.4
100
80-120
Potassium
mg/kg
618
597
97
80-120
Selenium
mg/kg
12.4
11.4
92
80-120
Sodium
mg/kg
618
606
98
80-120
Sulfur
mg/kg
124
114
92
80-120
Zinc
mg/kg
61.8
62.0
100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4752424
4752425
MS
MSD
35750478001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Boron
mg/kg
57.1
405
537
413
565
88
95
75-125
31
20 J(R1)
Magnesium
mg/kg
4750
4050
5370
8680
10500
97
107
75-125
19
20
Molybdenum
mg/kg
12.3
81
107
88.2
118
94
99
75-125
29
20 J(R1)
Potassium
mg/kg
739
4050
5370
4560
6120
94
100
75-125
29
20 J(R1)
Selenium
mg/kg
3.7 1
81
107
76.9
105
90
94
75-125
31
20 J(R1)
Sodium
mg/kg
1220
4050
5370
5180
6830
98
104
75-125
27
20 J(R1)
Sulfur
mg/kg
13900
810
1070
14900
15800
122
176
75-125
6
20 J(M1),
L
Zinc
mg/kg
775
405
537
1120
1300
84
98
75-125
15
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
QC Batch: 861697
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35750478001
SAMPLE DUPLICATE: 4742787
35750478001
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
7.6
7.8 3
10
SAMPLE DUPLICATE: 4742788
35750672002
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
78.8
78.7 0
10
SAMPLE DUPLICATE: 4742789
35750710072
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
17.6
18.0 2
10
SAMPLE DUPLICATE: 4742790
35751005001
Dup
Max
Parameter
Units
Result
Result
RPD RPD
Qualifiers
Percent Moisture
%
2.1
2.7 26
10 J(D6)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 21

aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
QC Batch: 861980 Analysis Method: SM 2540G
QC Batch Method: SM 2540G Analysis Description: 2540G Total Solids
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35750478001
SAMPLE DUPLICATE: 4744739
35751692001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Solids % 4.0 4.0 0 10
SAMPLE DUPLICATE: 4744740
35751340001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Solids % 4.3 4.3 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 21

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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
QC Batch: 861981
Analysis Method: SM 2540G
QC Batch Method: SM 2540G
Analysis Description: 254OG Total Volatile Solids
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35750478001
METHOD BLANK: 4744743
Matrix:
Solid
Associated Lab Samples: 35750478001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Total Volatile Solids
%
0.25
0.0010 0.0010
10/08/22 12:34
SAMPLE DUPLICATE: 4744744
35751692001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Volatile Solids
%
84.6
84.7 0
10
SAMPLE DUPLICATE: 4744745
35751340001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Volatile Solids
%
85.1
85.3 0
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/21 /2022 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 21

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QUALITY CONTROL DATA
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QC Batch: 863321 Analysis Method: SM271OF
QC Batch Method: SM271OF Analysis Description: Spec.Gravity SM271OF
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35750478001
SAMPLE DUPLICATE: 4751461
Parameter
Specific Gravity
35750478001
Units Result
0.630
Dup Max
Result RPD RPD Qualifiers
0.630 0 20 N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
QC Batch: 861080 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35750478001
METHOD BLANK: 4739216
Associated Lab Samples: 35750478001
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 4739217
Parameter Units
Nitrogen, Ammonia mg/kg
Matrix: Solid
Blank Reporting
Result Limit
0.28 U 0.85
Spike LCS
Conc. Result
10 10.5
MDL Analyzed Qualifiers
0.28 10/06/22 20:26
LCS % Rec
% Rec Limits Qualifiers
105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4739219 4739218
MS MSD
35750199001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Ammonia mg/kg 11300 42.6 42.1 11300 10800 48 -1060 90-110 4 20 J(M1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC.
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aceAnalyiical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
QC Batch: 861839
Analysis Method:
EPA 351.2
QC Batch Method: EPA 351.2
Analysis Description:
351.2 TKN
Laboratory:
Pace Analytical Services - Ormond Beach
Associated Lab Samples: 35750478001
METHOD BLANK: 4743652
Matrix: Solid
Associated Lab Samples: 35750478001
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
47.2 U 85.8
47.2 10/11/22 10:27
LABORATORY CONTROL SAMPLE: 4743653
Spike LCS
LCS
% Rec
Parameter Units
Cone. Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
3860 3670
95
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4743655 4743654
MS MSD
35750992002
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Cone. Cone. Result
Result
% Rec % Rec Limits RPD RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 57100
25200 25000 87700
87000
122 120 90-110 1 20 J(M1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC.
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Project: Pinellas County Pelletizer
Pace Project No.: 35750478
QC Batch: 861084
QC Batch Method: EPA 353.2
Associated Lab Samples: 35750478001
METHOD BLANK: 4739240
Associated Lab Samples: 35750478001
Parameter
Nitrogen, Nitrate
Nitrogen, NO2 plus NO3
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Ormond Beach
Matrix: Solid
Blank Reporting
Units Result Limit MDL Analyzed Qualifiers
mg/kg 0.25 U 0.50 0.25 10105/22 21:23
mg/kg 0.25 U 0.50 0.25 10/05/22 21:23
LABORATORY CONTROL SAMPLE: 4739241
Parameter Units
Nitrogen, NO2 plus NO3 mg/kg
Spike LCS
Cone. Result
19.9 21.1
LCS % Rec
% Rec Limits Qualifiers
106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4739243 4739242
MS MSD
35750478001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/kg 4.3 21.5 21.6 23.3 26.6 88 103 80-120 13 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/21 /2022 11:51 AM without the written consent of Pace Analytical Services, LLC.
Page 17 of 21

Pace Analytical Services, LLC
aceMalytical o 110 South Bayview Blvd.
Oldsmar, FL 34677
www.pacelabs.com [phone]
i
i
QUALIFIERS
Project: Pinellas County Pelletizer
Pace Project No.: 35750478
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
U Compound was analyzed for but not detected.
J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory
control limits.
J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)
recovery.
J(R1) Estimated Value. RPD value was outside control limits.
L Off -scale high. Actual value is known to be greater than value given.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
Q Sample held beyond the accepted holding time. Analysis initiated more than 15 minutes after sample collection.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/21/2022 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 21

aceAnalytical
( www.pacelabs.com
i
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
110 South Bayview Blvd.
Oldsmar, FL 34677
[phone]
Project:
Pace Project No.:
Pinellas County Pelletizer
35750478
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
35750478001
Pellet
EPA 3050
861087
EPA 6010
861127
35750478001
Pellet
EPA 3050
863486
EPA 6010
863507
35750478001
Pellet
EPA 7471
862139
EPA 7471
862200
35750478001
Pellet
ASTM D2974-87
861697
35750478001
Pellet
SM 2540G
861980
35750478001
Pellet
SM 2540G
861981
35750478001
Pellet
EPA 9045
860913
35750478001
Pellet
SM271OF
863321
35750478001
Pellet
TKN-NH3 Calculation
863617
35750478001
Pellet
EPA 350.1
861080
EPA 350.1
861094
35750478001
Pellet
EPA 351.2
861839
EPA 351.2
862493
35750478001
Pellet
EPA 353.2
861084
EPA 353.2
861113
Date: 10/21/2022 11:51 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 21

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DC#_Title: ENV-FRM-ORBl-0093 Sample Condition Upon Receipt Form
Version: 3 1 Effective Date: 12/7 ��lIssued bv: Ormond Beach
y
35?5o4?s UR) J ace
PM: CEM Due Date: 10/13/22
Project # CLIENT: 37-SYNAGRO Date and Initials ofperson:
Project Manager: Examining contents:
Label:
Client: Deliver:
'7 /` pH:
Thermometer Used: T202 Date: ( Time. /1W Initials, t 17
State of Origin: FL ❑ For WV projects, all containers verified to <_6 °C
Cooler #1 Temp :C,�_u
(Visal) +0.2 (Correction Factor) —tC2, 3(Actual) l Samples on ice, cooling process has begun
Cooler #2 Temp.°C (Visual) (Correction Factor) (Actual) EJ Samples on ice, cooling process has begun
Cooler #3 Temp "C (Visual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun
Cooler #4 Temp.°C (Visual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun
Cooler #5 Temp.°C (Visual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun
Cooler #6 Temp.°C (Visual) (Correction Factor) (Actual) Samples on ice, coolin ❑ P g process has begun
Recheck for OOT °C (Visual) (Correction Factor) (Actual) Time: Initials:
Courier: ❑ Fed Ex ❑ UPS ❑ USPS /In Client ❑ Commercial ❑ Pace l7 Other
Shipping Method: ❑ First Overnight ❑ Priority Overnight ❑ Standard Overnight ❑ Ground ❑ International Priority
❑ Other .
Billing: ❑ Recipient ❑ Sender ❑ Third Party ❑ Credit Card ❑ Unknown
Tracking # �,
Custody Seal on CoolerlBox Present: ❑ Yes No Seals intact: ❑ Yes ❑ No Ice: Wet i lue Melted None
Packing Material: RIBubble Wrap Y,ubble Bags done ❑Other
Samples shorted to lab (If Yes, complete) Shorted Date: Shorted Time: Qty_
Chain of Custody Present
es
11 No ❑NIA
Chain of Custody Filled Out
rlYes
❑ No ❑NIA
Relinquished Signature & Sampler Name COC
Yes
❑ No ❑N/A
Samples Arrived within Hold Time
. Yes
❑ No ❑N/A
Rush TAT requested on COC
❑Yes
eNo ❑N/A
Sufficient Volume
f4Yes
❑ No ❑N/A
Correct Containers Used
h6YeS
❑ No ❑N/A
Containers Intact
Yes
❑ No El N/A
ample La els match : (Sample Es & dateltllne of
collection) NJ 1 Yes
II containers needing acidl ese preservation ave
been checked. ❑Yes
All Containers needing preservation are found to be in
compliance with EPA recommendation: ❑Yes
Exceplidns: Vials. Mtcrotiwtogy. OBC, PFAS
❑ No ❑N/A
❑ No .I?rN/A
❑ No .6N/A
Preservation Information:
Preservative:
Lot #/Trace #:
Date: Time:
Initials:
Headspace in VOA Vials? ( >6mm):
❑Yes
❑ No
Trip Blank Present:
❑Yes
❑ No A/A
�WI-11-11­1 "VJuuvn tune oacx Tor aaa¢ronal comments):
Qualtrax Document ID: 33786 Page 1 of 1
Page 21 of 21

FDOH Certification 4E84167
I
BENCHMARK
EnviroAnalytical, Inc.
ANALYTICAL TEST REPORT
THESE RESULTS MEET NELAC STANDARDS
Submission Number : 22100121
Synagro
P.O. Box 3227
Pinellas Park, FL 33780
Project Name : PINELLAS COUNTY PELLETIZER
Date Received : 10/04/2022
Time Received : 14:30
Jennifer Amonica
Submission Number: 22100121 Sample Date: 10/04/2022
Sample Number: 001 Sample Time: 15:30
Sample Description: Pellets - #28-0750 Sample Method: Grab
Parameter
Result
Units MDL
Procedure
Analysis
Analyst
Date/Time
PH
8.74 Q
UNITS
9045
1012MO2211:10
TG
TOTAL SOLIDS
90.4
% DRY WT 0.1
SM254OG
1010612022 14:40
MN
FECAL COLIFORM BY MPN
0.190 U
WGRAM 0.19D
SM9221E
10/04/2622 16:13
DJ
All values reported in UG/KG, MG/KG WGRAM and MPNIGRAM are on a dry weight basis
TOlay Tanrisever - Technical Director/QC Officer
Haley Richardson- QA Officer
DATA QUALIFIERS THAT MAY APPLY:
1= Reported value Is between the laboratory MD(- and the PQL.
J2 = Estimated value. No control criteria exists for this component.
J3 = Estimated value. Quality control criteria for precision or accuracy not met.
J4 = Estimated value. Sampla matrix Interference suspected.
L = Off -scale high. Value Is known to be > the value {sported-
0 = Sample held beyond accepted hold time.
U = Analyte analyzed but not detected at the value indicated.
V = Analyte detected In sample and method blank
Y = Analysis performed on an improperly preserved sample. Data may be inaccurate.
Z = Too many ootonles were present (TNTC). The numeric value represents the filtration volume.
For questions and comments renardina these results please contact us at (9411723-9986
Results relate only to the samples.
NOTES:
2. SOUR calculations are based on Total Solids.
PQL = 4XMDL.
COMMENTS:
22100121 171 t 12th Street Fast * Palmetto, FL 34221 * Plione [phone] * Fax [phone] PAGE 9 OF 2

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CERTIFICATION
"I certify, under penalty of law, that the information that will be used to determine compliance with the
Class A pathogen requirements in §503.32(a) and the vector attraction reduction requirement in
§503.33(b)(8) was prepared under my direction and supervision in accordance with the system designed
to ensure that qualified personnel properly gather and evaluate this information. I am aware that there
are significant penalties for false certification including the possibility of fine and imprisonment."
Project(s): South Cross Bayou WRF Pelletizing Facility
Reporting Period: October 2022
Name: William Reyes — Ian an er Synagro
Signature: Date: 1-November-2022
The Class A pathogen requirements were met through §503.32(a)(7). The Process to Further Reduce
Pathogens was Heat Drying (Appendix B, B.2.). The biosolids were dried by direct or indirect contact with
hot gases to reduce the moisture content to 10% or lower. The temperature of the biosolids particles
exceeded 80 degrees Celsius. Fecal coliform testing was performed and the density of fecal coliform in
the biosolids was <1000 MPN per gram of total solids (dry weight basis).
The vector attraction reduction requirement was met through §503.33(b)(8). The percent solids of the
biosolids that contain unstabilized solids generated in a primary wastewater treatment process shall be
>90% based on the moisture content and total solids prior to mixing with other materials.
NTYPE 29: CA5 PR PELL PT VAR 90