WQ0003902_2022 Residual Annual Report_20230223 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0003902
Applicant/Permittee City of Newton
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Mooresville
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Lysa Finnerty
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
4105376150
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* Wastewater Irrigation High -Rate Infiltration
Other Wastewater Reclaimed Water
Closed -Loop Recycle Residuals
Single -Family Residence Wastewater Other
Irrigation
Permit Number:* WQ0003902
Has Current Existing permit number
Applicant/Permittee Address* 435 Williams Court, Ste. 100, Baltimore, MD 21220
Facility Name* City of Newton Class B Residuals Program
Please provide comments/notes on your current submittal below.
2022 Annual Report for City of Newton, NC
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
Newton NC 2022 Annual Report FINAL.pdf 15.45MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/23/2023

435 Williams Court, Suite 100
Baltimore, MD 21220
www.synagro.com
FEBRUARY 23, 2023
NCDEQ
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2022 Annual Report for Permit No. WQ0003902
Dear NCDEQ:
SYNAGRO
Synagro is submitting one electronic copy of the above referenced report on behalf of the City
of Newton, NC.
If you have any questions or need additional information, please do not hesitate to contact Eric
Jones at [phone] or Alex Fox at [phone].
Sincerely,
De1U & skkc"
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: Eric Jones — City of Newton
Alex Fox, Synagro
YOUR PARTNER FORA CLEANER, GREENERWORLD

CITY OF NEWTON, NC
RESIDUALS LAND APPLICATION PROGRAM
Permit No. WQ0003902
2022 ANNUAL REPORT

City of Newton, NC
Residuals Land Application Program
2022 Annual Report
TABLE OF CONTENTS
1. Certification Form and Annual Operations Summary
2. Annual Residual Sampling Summary Forms and Residuals
Analyses
3. Annual Land Application Field Summary Forms
4. TCLP Analysis
5. Pathogen ReductionNector Attraction Reduction
6. Soil pH & Lime Application Records
7. Soil Analyses

SECTION 1

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0003902 County Catawba Year 2022
Facility Name (as shown on permit) City of Newton, Clark Creek WWTP NPDES No. NCO036196
Land Application Operator Synagm Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied
please attach an explanation on how the residuals were handled.
Part A — Residuals Annlication Summa
Total number of application fields in the permit: 50
Total number of fields utilized for land application during the year: 9
Total amount of dry tons applied during the year for all application sites: 616.23
Total number of acres utilized for land application during the year: 268.20
Part B — Annual Compliance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit (including but not limited to items
1-13 below) issued by the Division of Water Quality X_YES NO.
If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading
Rates in 15A NCAC 02T, I 105(b) (Applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503
regulated facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations,
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified
in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
B. All buffer requirements as specified on the pen -nit were maintained during each application of residuals.
Part C — Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete.
-
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations." T 1),)11 R11)(V711
Wentz
Public
James entz: u c Works Director
Permittee Name and Title (type or print)
Signature of Preparer* Date
(if different from Permittee)
Signature of Permittee Date
1/31/2023
SIARWan' ipplier Date
(if different in Permittee and Preparer)
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T.1102 (26) DENR FORM ACF (12/2006)

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 2/22/2022 - 6/21/2022
NEWTON, NC
NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID
MONTH/YEAR
AMOUNT
UNIT
DRY TONS
UNIT
DRY METRIC TONS
February 2022
156,000.00
G
39.94
D
36.23
March 2022
468,000.00
G
119.83
D
108.68
April2022
540,000.00
G
74.53
D
67.60
May 2022
558,000.00
G
77.02
D
69.86
TOTAL
Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards
Report Date: 2/3/2023 5:01:49 PM
1,722,000.00 G 311.32 D 282.37

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 7/27/2022 - 7/28/2022
NEWTON, NC
NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID
MONTH/YEAR
July 2022
TOTAL
Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards
Report Date: 2/3/2023 5:07:06 PM
AMOUNT
UNIT
DRY TONS
UNIT
DRY METRIC TONS
216,000.00
G
48.64
D
44.12
216,000.00
G
48.64
D
44.12

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 9/26/2022 - 11/28/2022
NEWTON, NC
NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID
MONTH/YEAR
September 2022
November 2022
IEel /_1I
Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards
Report Date: 2/3/2023 5:09:19 PM
AMOUNT
UNIT
DRY TONS
UNIT
DRY METRIC TONS
570,000.00
G
128.35
D
116.42
498,000.00
G
127.92
D
116.03
1,068,000.00
G
256.27
D
232.44

SECTION 2

ri,w
y
w
(N Z w
0 rY
0) L)
co
0 Cl)
0 0
Lu () 0
o -j
z z
L
E
z E 0
E
Z mZ
to Z' a.
L W
cy U)
LL it z
ts
C
0
u
= E
0:0
t6 0 C, .2
O co
v
0 "Zt 00 C) m r-� ;: Co 0 0 0 0 cq
',: N Lq ?2 10 Cl) cq m 0 0 0
LO CD 0 0 N
CN
Lq r CD M W (0 "t "r 0 0 0 0 M
N Cl)
O� (q CD 0 'lz� c; 14: �2 ll� MOO
0 0 "t
co C'4 w co m m 0 0
C*4 C) co to 0
v 00 N
C) C.
Zr-lr mZWLoI—N t0 —r--ZZZZ
to 0 e :L-
Ez z
CL
0 =3 U)
E E 0
= 2 m E
E 2 0 to
E 2 M 0 C
P(D-OCLEM 2�3400�§ZEE
pemo.cwoo.oz�q �eE--
m < 0 0 0 _5 2 2 Z Cn N 9 F- < z
mY
O
, cr 75
2.0
1
I
to E
ca —0
.2
rn
07
U) 0)
(D
-0
E
2 E
1.0
>, =3
U)
—0
CD
0 C:
r- a)
M 'R a-� Cl)
0 cc 04
0 0
0 C)
M
LO
.0
04
Q C)
Z5
.2 p
E
E
E
M cn
CL c U)
LD .0 c:
CL
U)
E A
.2
>
E
=1 0
0-
-a cn
>
m Q) Q)
-C -0 E
C: c
ca L0
EQ
0 Q) E
Z� = .—
M
(D CL_
CL
2
CL _0
:3 21
0. O.
I
.11

00000ot-Lo
N CN
N 0
OC)OOOO[I--
0 0 0 cq 0 0 M
0 �2 �2 1
0 1,
v C)
0 0 co
C4 'r 0 r-
m CD C5
,It
000,�Oog'D
o 0 0 m m m (D
CD
C:)
N 0
E
4 E E E E
4) E E 2
6 E
E :3
z w
ioL CL CLU) < o CL 4 co
m
CN
0
N
LO
T-
CN
0

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Newton
Lot Number:XA04057
Date Completed:01/20/2022
NIM�� Mr�
01/20/2022 3:46 PM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: XA04057
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to low % solids the initial amount of these samples was 3 times the standard procedure amount. The
LOQ has been adjusted accordingly.
Inorganic Non -Metals
The pH of sample XA04057-001 came to 12.15 which is outside the range of the pH meter. Therefore a
pH 12 Buffer Standard was read but failed to meet its temperature corrected value. Results will be
reported.
All samples analyzed with batch 28656 were analyzed using expired ascorbic acid reagent. This run was
a re -analysis of a previous run that was analyzed using a linear calibration range that was slightly greater
than 6 months old, per SOP criteria. The instrument was re -calibrated and the samples were re-
analyzed, using the new calibration, and similar results were obtained. Thus, re-ananlysis is not required
for samples that were within calibration range. All instrumentation check standards and method criteria
were met.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Synagro
Lot Number: XA04057
Sample Number Sample ID Matrix Date Sampled Date Received
001 Newton Solid 01/04/2022 0730 01/04/2022
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

Inorganic non-metals
Client:Synagro Laboratory ID:XA04057-001
Description: Newton Matrix: Solid
Date Sampled:01/04/2022 0730 % Solids: 6.14 01/12/2022 0029
Date Received:01/04/2022
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date
Batch
1 350.1
(Ammonia - N ) 350.1
2
01/12/2022 2155 DAK
28095
1
(Nitrate - N ) 9056A
1
01/06/2022 0146 AAB
27594
1
(Nitrite - N ) 9056A
1
01/06/2022 0146 AAB
27595
2
(Phosphorus) 365.1
20
01/13/2022 1249 DMA
01/06/2022 1459
27588
1
(Soil pH meas) 9045D
1
01/11/2022 2038 NBW
28081
1 351.4
(TKN) 351.2
1
01/05/2022 1741 DMA
01/05/2022 1000
27443
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Ammonia - N (gas diffusion)
350.1
1100
33
17
mg/kg
1
Nitrate - N (soluble)
9056A
140
8.1
1.6
mg/kg
1
Nitrite - N (soluble)
9056A
24
3.3
1.6
mg/kg
1
Phosphorus
7723-14-0 365.1
8600
1600
330
mg/kg
2
Soil pH measured in water @
19.9 ° C
9045D
12.1
su
1
TKN
351.2
21000
810
410
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 9

CVAA
Client:Synagro Laboratory ID:XA04057-001
Description: Newton Matrix: Solid
Date Sampled:01/04/2022 0730 % Solids: 6.14 01/12/2022 0029
Date Received:01/04/2022
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7471B 7471B 1 01/10/2022 0744 JAB2 01/10/2022 0116 27833
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury
7439-97-6 7471B ND 1.3 0.31 mg/kg 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

ICP-AES
Client:Synagro Laboratory ID:XA04057-001
Description: Newton Matrix: Solid
Date Sampled:01/04/2022 0730 % Solids: 6.14 01/12/2022 0029
Date Received:01/04/2022
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 01/06/2022 1126 JMH 01/06/2022 0311 27531
2 3050B 6010D 5 01/06/2022 1149 JMH 01/06/2022 0311 27531
Parameter
CAS
Number
Analytical
Method
Result
Q
LOQ
DL
Units
Run
Aluminum
7429-90-5
6010D
14000
110
41
mg/kg
1
Arsenic
7440-38-2
6010D
2.9
J
4.1
1.4
mg/kg
1
Cadmium
7440-43-9
6010D
0.60
J
1.4
0.34
mg/kg
1
Calcium
7440-70-2
6010D
200000
6800
850
mg/kg
2
Chromium
7440-47-3
6010D
25
2.7
0.68
mg/kg
1
Copper
7440-50-8
6010D
230
14
6.1
mg/kg
2
Iron
7439-89-6
6010D
9000
27
12
mg/kg
1
Lead
7439-92-1
6010D
8.4
2.7
1.2
mg/kg
1
Magnesium
7439-95-4
6010D
4500
1400
170
mg/kg
1
Manganese
7439-96-5
6010D
450
4.1
1.6
mg/kg
1
Molybdenum
7439-98-7
6010D
3.4
J
11
2.7
mg/kg
1
Nickel
7440-02-0
6010D
10
J
11
2.8
mg/kg
1
Potassium
7440-09-7
6010D
990
J
1400
170
mg/kg
1
Selenium
7782-49-2
6010D
3.4
J
5.4
2.2
mg/kg
1
Sodium
7440-23-5
6010D
980
J
1400
170
mg/kg
1
Zinc
7440-66-6
6010D
830
14
3.4
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 9

PACE ANALYTICAL SERVICES, LLC
00
I �a
+L
N
ly �
.yi
FS
h
W �
£3 'E
0
LU
to
LU
42
-d' V
�r s-bn
w
4
CUaIIY
Y➢L�Q}
;r
4
t
I
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.corr
Page 8 of 9

PACE ANALYTICAL SERVICES, LLC
�.. - �..
i7licint� SYNA6RU
Fai`c
Samples Receipt Checklist (SRC (ME001,C-15J rtL±visr_d_9PS/2020
IssulrLg Authority: Pacv ENV • LN:QL Rage 1 of 3
Sample Receipt Cheekfiqt (SRC)
Cooler ins rcud . !datn: 14W / UU2D22 Lrt �7 a asp
liurA n ilPS I I FecE)T(Amer- " I
rm
%F Iwo 1.
we nAiody seals pre-,,CLtl un the ronlW?
Yes
MCI [Z 12. E�custoci
seals wcrc rcSMI, were they :uLWGL and IIFS a_o-sea?
Ipl{ Strip
IJD. N,�
Chlorine Strip 1D_ NA Te!jlad by. HA
UrJgJnal
i:mperature upon rea
iptr`Dcrived (ClanvCted) ternp4xAtuir upiwn i-ccipt %SuRd Snap
1,_3 13.3 uC NA f V fi
C NA r NA aC NA j NA cC
lte(hod.
EJ TCmparatuM $Ian
L kt-�nst Bc4lita Tit CMIn ID: C;Itn C Iv eetiLm Ft
lethal ofcanlz�rn: 0 Wet
_ _tit
oc L,I lc P�r.�;s 0 ice lVolse
ElYES
0 NLr �rNA
r mperature of any snniL�r rx zejed 6,saC, 4vas Prpjcct rlaitp, r t4
hd was Nocificd by: phor_e i gnrail / rE1LX-t0-fa(e 16-r,'X one).
Ycs
No ' d NA _ I
$ the rrnrunemial courier':s pscki ig Slip a=:: cj 10 }cis Farm4
erc: Esraperca9tady prci�edures (relDbqulshLdh%ceeiverl) followed?
IL Ves 10 5.
V Y �15
L NI) 6.
ert sum ple lDF 1i stcd On lhtr COC"'
N T.
ere h�lrn}rlc ins hitrxl an all Sample c#11aLin4 s,'
a-, collections datc & time Jistcci on Che COC?Ta
#CZ,
'No l3_
9.
Was collectiou L]atC LY- tune listed on all samlyia co11t7it]Crs?
2 n
❑ No 14,
id all ccurtaiuer Iabc-. inforwalon (ID, dalo, time) :Igrrc wifli 11LV CC
v V,:s
NEp$rC
`.t= tl} 11C p2rfdL'mL'.d listed on lira CCMC?
❑Noi 12,
id a]I ii. Vqs arrive in the ps'c"r ; antainer� for each trot and/or in
II+ (iwi
%61tdn, lids an, eit_P —
x �ti u rva i�, x.s adnL{Lrato sample vaiorse ava�llblc3?
Yes No H. ea'a all HAT] ]pies re-c-N-ed %vii7iin V� tha holding Eirne or 48 3nurs, vl l
Ycs + lid 15_ Tcre any sampies corib4incrs misg1rlglex L:ss rcircic one) sAlnpies NLsl
16 Yes []Nu ONA Or l'Qh �wd RSIi�-175 samples, w, rc :Albbieb prosait lxa-si a"
Irr a o; the VOA vials'?
gYes iy NA J 7. = all DR( rnet,ls.{a� 1Aent �aMPJ6s l+eezi uad at a hH of<
Yes Na 7 INlA 1 ere. Al cyan ii& AMIes reMM—d at a pH ] 12 and 5_J Li dr SUMPIes n
Yes 0 f Na ENA ]4, ere all UL plicaWe N Nkyan &d M� Cno ffi2_. J;6U8.3 fC_ Q,Sing,�
ETKol 7NA
_Yro IJNo,' �7T.
LnLlrie Prmerv.96Un b ra (
Tilpie(s) NA
sample rexciving wi�tL NA
ma of nrescrvation N.4 - -
116
3ccoirJirLgh' in san'ipia
�ancode IahelS applied by.
cornmunts:
C client MrnxrksrregLLr3t5 {Le. rey in- dilatit ns, Tr1SWSi de:
ly tM11.3arihcd fro,u Its COC into the cprnsrt.ntsecti0n ii LIMS?
s the gLrorc 7umbvr IA an toe ronzaLiner lah217 If yes. Qaate lr
aomplctcd f-nr any WInpl Zj) inDwrertly pi%FLserq,d or with heads
Were reae,ved incarrectiy pri;Ecrved and W
L af-circ% one' 1­12SN., I-N<)3, HCI,L silig SR 4 NA
11`rrlom than L)n- preservative is rleeded, phew note in TILL•. corn
EI}_ 21,2ri61
lod -condition
revLw comer first?
sited 0C COC-7
or 6rui Er. dknieter)
eived at a PH "JF
ump.es frcoo
Abn.R, ec ... )
i;s;r:sted aecordis]gly
is below,
..—_were receNW with bubbles 4 Rhin of d'amcrer_
—� WITe receivtd with 7Rc> 0.5rugrl. (Ifµl i is rra) anid w,ro
vivhumuith 5odiTu7T d1iusulfate (Li1l125,0z) with'51muly ID- KA
[}ate: Lr�1Lfi�'z
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 9

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
2025-01-LSLIQ-NC NEWTON, NC CLARK CREEK LIME STABILIZED
LIQUID
Na mg/I = (Na mg/kg x % Solids) = 100 = (980 x 6.1400) = 100 = 60.172
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (200000 x 6.1400) = 100 = 12280
Mg mg/I = (mg mg/kg x % Solids) = 100 = (4500 x 6.1400) = 100 = 276.3
Na meq = Na mg/I = Molec.Wgt.Na = 60.172 = 23 = 2.61617
Ca meq = Ca mg/I = Molec.Wgt.Ca = 12280 = 20 = 614
Mg meq = Mg mg/I = Molec.Wgt.Mg = 276.3 = 12 = 23.025
Sample Date Report Range Ratio
1 /4/2022 1 /1 /2022 - 3/31 /2022 0.1466
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.61617 = SgrRoot[0.5(614+23.025)] = 0.14659

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Newton
Lot Number:XD07084
Date Completed:06/02/2022
NIM�� Mr�
06/03/2022 9:31 AM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 7

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: XD07084
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
The following samples were classified as a biosolid therefore they were weighed out at around 3.0 grams
to 4.0 grams to ensure proper digestion: -001. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
Due to multiple QC failures, sample -001 required additional runs. The best run has been reported.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 7

Client: Synagro Laboratory ID: XD07084-001
Description: Newton Matrix: Solid
Date Sampled: 04/06/2022 0815 % Solids: 3.31 04/16/2022 1428
Date Received:04/07/2022
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 04/16/2022 1428 CVR
38384
1 350.1
(Ammonia - N ) 350.1
10 04/20/2022 1402 DRD
38502
3
(Nitrate - N ) 9056A
5 05/19/2022 2146 CAW
42428
3
(Nitrite - N ) 9056A
1 05/19/2022 1450 CAW
42431
1
(Phosphorus) 365.1
25 04/12/2022 1150 DMA
04/08/2022 1221 37480
2
(Soil pH meas) 9045D
1 04/21/2022 1442 NBW
39017
1 351.4
(TKN) 351.2
1 04/11/2022 1912 DMA
04/08/2022 1143 37479
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
3.31
%
1
Ammonia - N (gas diffusion)
350.1
7000 S
300
160
mg/kg
1
Nitrate - N (soluble)
9056A
32 HJ
76
15
mg/kg
3
Nitrite - N (soluble)
9056A
4.5 HJ
6.0
3.0
mg/kg
3
Phosphorus
7723-14-0 365.1
20000
3800
760
mg/kg
1
Soil pH measured in water C)
25 ° C
9045D
11.7
su
2
TKN
351.2
34000
1500
760
mg/kg
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 04/13/2022 0536 JAB2
04/13/2022 0232 37587
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7471 B
ND
2.3
0.56
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
6010D
1 04/13/2022 0225 KSH2
04/08/2022 1202 37530
2 3050B
6010D
5 04/13/2022 1709 KSH2
04/08/2022 1202 37530
3 3050B
6010D
5 04/15/2022 0221 JMH
04/08/2022 1202 37530
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6010D
34000
190
71
mg/kg
1
Arsenic
7440-38-2 6010D
4.5 J
7.1
2.4
mg/kg
1
Cadmium
7440-43-9 6010D
1.4 J
2.4
0.60
mg/kg
1
Calcium
7440-70-2 6010D
400000
12000
1500
mg/kg
2
Chromium
7440-47-3 6010D
78
4.8
1.2
mg/kg
1
Copper
7440-50-8 6010D
450
24
11
mg/kg
3
Iron
7439-89-6 6010D
21000
48
22
mg/kg
1
Lead
7439-92-1 6010D
28
4.8
2.1
mg/kg
1
Magnesium
7439-95-4 6010D
7800
2400
300
mg/kg
1
Manganese
7439-96-5 6010D
690
7.1
2.8
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 7

Client: Synagro Laboratory ID: XD07084-001
Description: Newton Matrix: Solid
Date Sampled: 04/06/2022 0815 % Solids: 3.31 04/16/2022 1428
Date Received:04/07/2022
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date Batch
1 3050B
6010D
1 04/13/2022 0225 KSH2
04/08/2022 1202 37530
2 3050B
6010D
5 04/13/2022 1709 KSH2
04/08/2022 1202 37530
3 3050B
6010D
5 04/15/2022 0221 JMH
04/08/2022 1202 37530
CAS Analytical
Parameter
Number Method
Result Q LOQ
DL
Units
Run
Molybdenum
7439-98-7 6010D
14 J 19
4.8
mg/kg
1
Nickel
7440-02-0 6010D
34 19
5.0
mg/kg
1
Potassium
7440-09-7 6010D
2200 J 2400
300
mg/kg
1
Selenium
7782-49-2 6010D
8.4 J 9.5
3.9
mg/kg
1
Sodium
7440-23-5 6010D
1700 J 2400
300
mg/kg
1
Zinc
7440-66-6 6010D
1600 24
5.9
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 7

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 7

PACE ANALYTICAL SERVICES, LLC
Ujg
4�
4
2
'b13.CL
a`
x OX
5 1 47
G7 :;: 'Q I
j
rJQMuUMCCi
+5
du
S]
2 2
~
yo
S
F
n. tJ
iE
a
�L
S
PS
1
Y a
a
�
N
o �
2�,3
m
u
E n
6
m
.
L
{r
y
U
16
h
F
—
".}
d
a
f] F3
r
R
4
N
a
r
L V
E
y 5g A;?
i.
dx
rr. to
u C4
{
LL
2
L
'
z a
c
iF
2
El
r
C]
u
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 7

PACE ANALYTICAL SERVICES, LLC
Samples Receipt Checklist(SAC)(MEt?DISC-t5j
Is so ng Authorityr: mace hNV - WCOL
Sample. Reeeipt Checklist ( RQ
Client: �1�10f11' Cool& RtsteeLed hy{didn: 9'�-C: { t4 C ,xC=7 ] {, �- XV074164
ReVIse19j2920
Page 1 of 1
14fcarl4 0f IMVi-l1: P.gcL'
:Iicni 71 lips Fv.dFx 0 Oilier:
Yes
Vf N
i_ WM mistod*- sealssLals
jMV=j ors tho cooler?
Yml
F N 0
WINA
12. if custn seals wej%e re%en were th - inffiot and unhroken7
pH Strip Ili: ";A —._-- Chlorine Strip Testwd by,14�1
Origlinal t,-lnpCr�tt3rc i1pon receipt s J7eri.ed (Coiiocred) tenrperature upon receipt °ltiSol:r Sru�p-Cup LD: '-
-.1 r 4.7 r.0 h?i +NA AC NA jNA oC NA {K, 0C
M,-Lh,pa:[ 1k;mpmture Bl�.nk L3kpinstBordrr, IRGurt ID: s IR Gun Cam -.rim fact, cc
rwfethod of coalatit: ❑ wet lee ❑ Ica Jkmka ❑ Djj lee ❑ None
Yes
N
❑ 11A
Tf ir_xnlume of xhl-ny con1cr oxcee W &O'C, was P:-4,jcef Manwr Kotified7
PM w.44Mi6florl by, phona+'emgil ?fare fr i�se$ ;circle one).
Ycs
No
PEA
4. Is the r-ammcroiel aeuri`r-spacking slip attachod to dlis farm'?
d
1'ns0
5. l'ene 1"" custody pr; ccdtnts (ttltntit5ied,'rcceivcd) iollay.d r
Yck
X
6. WL:-c swple IDs Ii-ded on the COC7
L+'J
1'cs
I Nol
T we-v' sample IDls listed on a115amplc cvjaWiicrs?
J
Yes
U No
8. Was collcetiom dale tfrnr lisierl on Ihr.. CO('?
❑
Yee
x❑ No
19.
Was CQ1led-on ftw 0111a ligod ore all sample MR4,,ill ?
d
Yes
No
10. L}d -]I container label infw-natian(ID, date, ti71e)dg-4:c wJTh ft COC?
2
Yes
1 Tr}
1 1 . Were C".d% 10 frC P}C forC1J0d I ixtad CM t11C ff)M
i Yr
❑ Na
J-. L7irJ F11 samples arrivo in the proper containers for each test andlor in good condition
(unbrokeii, lids on, a c.)F
?jjyGSj
LJND
1" War, adc umm sane :c volume available?
Ldyesl
LJNO
141 Were all satnplai received within r� dse holding tinse & 48 huurt, wbichevcr rabmcS rlrSt?
Ycs
J Nr;
iS, +Mare any sari lcs containers missin€lexcess (circle une) swn les Not listed on CDC?
[]Yes
❑s 10
J N.4
if. For ��OA and RSK-175 =plus, were Bubbles present >"pea-she(r1*'Dr6mm in diuir�ctcr',
in any of [he VOA vials?
Yes
No
d NA4 I
17_ Wer2 al l DRC)lm -aLiin utriont sam lcs received at a pH of < 27
YesITNu
MN4
18_ Vcrc trlI c 'pnictc snmplcs rcecirtd Elt c pH = 12 and sulfide sutnplcs rocchrcd at a pH > 9?
Yes
ONO
0NA
19. Were a1€ app][cable1l6M.� (40._�mg!L) 6amples free of
residual rMorine?
YC5
[I No
❑N.
20_ 601- alre,3L 1t1rLurkVrttqu yes (ix. Ivc:'uu cd dilutions, I.'1s MSD dvsigaaliunH. CLU.,,
carrectly lraf s2ribed frc m Lht! COC inLo the confMCRtSecti'ar to 1,4.b1S?
Yes
No
21 Wim Tic 11{ Pee Mimhnr Iitil eel on the uonl a innr 1Nbw_: if ki ok� 4
oQple i*rese�•v� lion �foita[ �e curr�pl4'�d Cor tug}�tnpjc(f) incurresi ly pr�h�rvcd or uril>� hearl�pace.)
Same lec(s) N�1 won roc-,,ivod 1mmouy preuelaea ena were Atli uSted a morclingly
in saniole receiving wkh I`A roL, of circle ore: 142SO4, HNO3, HGI. NaOH us ing SR 9 A ---
rime nfpreseryatiott HA Urr.[xt ih&rt one preAu-vat-Nu is nwdcd, plcasc now in tat kaniments biAg-ev.
Sitrrtp:e(s) NAware rec i�efl xvidt bubbles G rtltn iu digtr ter_
SAnp=es(f) NA wage re; eived wi*h TR C > 7.� m81J . (f f 4 t 9 iS no) and were
adjusted accardinglu it %atnple receiving with sodium dhirwoliate (Nm2S O,) with SheaPy 10,
Sst InamW l7b]CJS rl-3psied by: r.aRW late: (1447MM
(_;Cmnen:y
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 7

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
2025-01-LSLIQ-NC NEWTON, NC CLARK CREEK LIME STABILIZED
LIQUID
Na mg/I = (Na mg/kg x % Solids) = 100 = (1700 x 3.3100) = 100 = 56.27
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (400000 x 3.3100) = 100 = 13240
Mg mg/I = (mg mg/kg x % Solids) = 100 = (7800 x 3.3100) = 100 = 258.18
Na meq = Na mg/I = Molec.Wgt.Na = 56.27 = 23 = 2.44652
Ca meq = Ca mg/I = Molec.Wgt.Ca = 13240 = 20 = 662
Mg meq = Mg mg/I = Molec.Wgt.Mg = 258.18 = 12 = 21.515
Sample Date Report Range Ratio
4/6/2022 4/1 /2022 - 6/30/2022 0.1323
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.44652 = SgrRoot[0.5(662+21.515)] = 0.13234

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Newton
Lot Number:XG07084
Date Completed:07/22/2022
NIM�� Mr�
07/22/2022 3:39 PM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 7

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: XG07084
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
Due to low percent solids, sample -001 has been prepped at approximately three times the standard
procedure. The LOQs have been adjusted to accomodate the additional mass.
Inorganic Non -Metals
The method blank for prep batch 47664 contained the analyte total phosphate greater than the method
acceptance criteria. The associated samples contained detections for this analyte at concentrations
greater than 1 OX the value found in the method blank; therefore sample results are not impacted. The
data has been reported.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 7

Client: Synagro Laboratory ID: XG07084-001
Description: Newton Matrix: Solid
Date Sampled: 07/06/2022 0900 % Solids: 5.40 07/10/2022 1650
Date Received:07/07/2022
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 07/10/2022 1650 TAD
47512
1 350.1
(Ammonia - N ) 350.1
5 07/19/2022 1114 CMM
47976
1
(Nitrate - N ) 353.2
1 07/20/2022 1255 KKP
47766
1
(Nitrite - N ) 353.2
1 07/20/2022 1255 KKP
47768
1
(Phosphorus) 365.1
25 07/18/2022 1558 DMA
07/12/2022 1324
47664
1
(Soil pH meas) 9045D
1 07/11/2022 1344 KKP
47566
2 351.4
(TKN) 351.2
1 07/20/2022 1218 DMA
07/16/2022 1320
48198
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
5.40
%
1
Ammonia - N (gas diffusion)
350.1
2200
93
48
mg/kg
1
Nitrate - N (soluble)
353.2
45
3.7
0.50
mg/kg
1
Nitrite - N (soluble)
353.2
2.3 J
3.7
0.49
mg/kg
1
Phosphorus
7723-14-0 365.1
10000
2300
460
mg/kg
1
Soil pH measured in water C)
16.3 ° C
9045D
7.3
su
1
TKN
351.2
22000
930
460
mg/kg
2
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 07/10/2022 1043 MRW2
07/10/2022 0654
47419
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7471 B
0.51 J
1.4
0.34
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 07/13/2022 0745 JMH
07/11/2022 1541
47423
2 3050B
601OD
5 07/13/2022 0802 JMH
07/11/2022 1541
47423
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6010D
18000
110
42
mg/kg
1
Arsenic
7440-38-2 6010D
2.4 J
4.2
1.4
mg/kg
1
Cadmium
7440-43-9 6010D
0.58 J
1.4
0.35
mg/kg
1
Calcium
7440-70-2 6010D
180000
7000
870
mg/kg
2
Chromium
7440-47-3 6010D
39
2.8
0.70
mg/kg
1
Copper
7440-50-8 6010D
180
14
6.3
mg/kg
2
Iron
7439-89-6 6010D
13000
28
13
mg/kg
1
Lead
7439-92-1 6010D
10
2.8
1.3
mg/kg
1
Magnesium
7439-95-4 6010D
5400
1400
170
mg/kg
1
Manganese
7439-96-5 6010D
530
4.2
1.6
mg/kg
1
Molybdenum
7439-98-7 6010D
3.7 J
11
2.8
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 7

Client: Synagro Laboratory ID: XG07084-001
Description: Newton Matrix: Solid
Date Sampled: 07/06/2022 0900 % Solids: 5.40 07/10/2022 1650
Date Received:07/07/2022
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 07/13/2022 0745 JMH 07/11/2022 1541 47423
2 3050B 6010D 5 07/13/2022 0802 JMH 07/11/2022 1541 47423
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Nickel
7440-02-0
6010D
11
11
2.9
mg/kg
1
Potassium
7440-09-7
6010D
1300
J
1400
170
mg/kg
1
Selenium
7782-49-2
6010D
2.9
J
5.6
2.3
mg/kg
1
Sodium
7440-23-5
6010D
1300
J
1400
170
mg/kg
1
Zinc
7440-66-6
6010D
690
14
3.5
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 7

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 7

PACE ANALYTICAL SERVICES, LLC
a
d�
F.
"'
W
€� f
f]
COO : y
T
�
m
� NSA paguuo�.q .
3, duel gd—,
�
uglAal'c0
_ _
1CL.-_
N 73
L
C
O
0
4
a,
Cl
�
S
�
A
C
JI
a `
U
Z
i
�
a
a
w
2
LL
e
Le
sE❑
G
22 .n
4
E
R
3
'L
C�
a
i5
_
F
M
t9
�
s
- ,
1
s
6
21
a
yy
a
F
M
F A.
IQ
� P
ee ❑
a
I
N
ac
n
P'
H
�
C
L.r
C
Q
C_
2 r
Qa
0
fC
tC
ri
A
Y
4
Q
0
E5
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 7

PACE ANALYTICAL SERVICES, LLC
Samples Reeeipt Checkiist PRO (tdIE0018C-15) 11PASen:912`JI2U20
- �3:�Ars3�7r�•w
lssuing Atithoriry: Pace ENV - LUC L Pagel of 1
.2xnpie Remipt C;heekiist (SRC)
8vani, Coulry lnq-ected rrlatd' KD�w i u?,1C7�'sG; Lot W:
Cliaolt: Tu
t�i,�O.rsofireecipF ,f P&W Clict'It 1TP5 PedCx -tsar;
1'cs V No i. Were wstody sd7iis present uti the cnoter7
Yes No / NA . TF seals wCie rrt, Were t'nc int.ict ar.d u«braken7
PH strip ID: tan �T'ktlorinc Strip ]JJ: NA_ Tested bp': �
Original iteuuperature upon reee' pt ? ( rived (Corrected) tom -am-a � TKm rye 60 °1oS+�tid Snap -Cop [I}; I � 3
.3.4 OA • c NA I NA off+ hfA [NA aC 14A eNA - aC
14iathod= fer,�ricranuc H ink gainirC 13a4.1es IR Csur. IT): IiZ Cavn Comccrirtn factor. 4 _"G
atihociofcrrnTrufL Vb'eticc ©L aFaC4s D Tie Nnne _. _.
3, if tieinp�rx�,�rc oF�tt}' ono'er �•:cueded 6.0°C, �vaa PmjLcl i1+]a.uagrr l�l��ti�cd?
❑ y Lb 71 blo (ZINA RM w•" Niitified by: phone/ email J fac o-face rcirr lc
Ves No VNA4.Islilt! CpmrtierciaTcourier'spwkin$slipatl3chCd6othirtpTrn?
yes 7 0 5. Vrerc prupCr mtAv Mcadures (ieiin uishtAWcciVcd) fullowzr-'-'
Yes No 6. Were sample ID3 liseCd pn the CQC?
Yes ❑ No 7, Were sample 1Ds listed on all sample uoriai iMrV
Yes V No 8, lVaq coil"4i0dt date & time liswd an iixe C?
J Yin No 9, Was coliaction date & !JmE: listed m all sample containen"
l Yea No 10, Did all corhrner label inf wmation UD, date, iirnej Were xsta to be t miormod listed orL The Cf XC-i rcc with t13e CAC?
Y I —I Nv
J Y NO
1-1 IT *Z Nn
yes Q Na
}'ot he
5as 1*[
O Yosl ❑N(
12. 1.3A all Swnp' aR wrriye in th4 proper oantainers for Cwh Lest and or in a-ooc! cxmdit1011
(ur_broken, lids an, 0-)4 _ —
Ia. WUS sample Voinmc �VDil3bl6
14. T]4'era �I] sart l�srix:eiv,�riv�'ithfn'�thc hal�lin�,tim$ oT'I$ k�aura, y,+l,�cliever camel: rst'1
l5. W'ere sn}'sam�leS cont8inCFS iitiSsil1giQMi eSS (eitTlc c1r4 santp1CS NoT. listed on COO
l6_ F+m' VOA AndRSK-1;5 sample:,wr;rnlaul�LlcsprCseiit7"prx�aiae" f i''arfimm indium ter)
ut arr
yar_a VC)A visal5"
J NA ]7, %Vare all DRO.mrtah
,{ NA 118, �VC C 4111 f.}'Mide SALT
l . Were a a5, ]WaLi e
❑i`lA
_ �.. rt,r.,_:..,1dj
lent samOlos rece_vcd at A PH
reuea wad At a hT T > 12 End Sillfide sarnpleP received at a 'JH > 2''
Mem client r=ar6m!reaLies" (i.e. rcquc5t diliitionx, TaTS�I+dSD dr};�nations, etc
❑ Yes N° �NA correcliy transcribed Cmna tho Coe into the. "n1ment sccljom in LlNfSF
I —I IANM 121 _ Was the gUota number listed [m the ContaiD er lalAe If yc.5, QuobC i
rnple Preservation [Must be rani,l,eted far iLtlu savtple(s) incoTec#ly prt*erved qr with licadfpRut.)
trple(s) were i ccivod'.rconwly Meset­Yed and Were adj��wt�1 acoorclingl�
sample receiving will N+ _mG of circle one. HZS04, T IN03, HCl. ;*laOh u5ir g ';Rd NA
me u` preser Etion A J_. 1f more than one pr�eswvateue is rlc&dml, IyIease nofa in -lie eommcr is below.
NA
vvers rrce-ved bubbles >6 mm iri dialrctcr.
-o WA were receiva4 wiLh'T"RC > D4 mg+L (fi'NO ) and were
accordingly iri sample ra eivu with soe_ium tltKa ill�a4e {1wa�SA)') With 5hoply 1I1, "41`
harcndc 1ub41s Tipplied by_ Ni�u•
Ccr.15rnents' Dorm oDt k0r.C4 7n C OC
D M aim711U ?.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 7

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
2025-01-LSLIQ-NC NEWTON, NC CLARK CREEK LIME STABILIZED
LIQUID
Na mg/I = (Na mg/kg x % Solids) = 100 = (1300 x 5.4000) = 100 = 70.2
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (180000 x 5.4000) = 100 = 9720
Mg mg/I = (mg mg/kg x % Solids) = 100 = (5400 x 5.4000) = 100 = 291.6
Na meq = Na mg/I = Molec.Wgt.Na = 70.2 = 23 = 3.05217
Ca meq = Ca mg/I = Molec.Wgt.Ca = 9720 = 20 = 486
Mg meq = Mg mg/I = Molec.Wgt.Mg = 291.6 = 12 = 24.3
Sample Date Report Range Ratio
7/6/2022 7/1 /2022 - 9/30/2022 0.1911
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 3.05217 = SgrRoot[0.5(486+24.3)] = 0.191078

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Adam Brigman
Project Name: Newton
Lot Number:XJ20074
Date Completed:11/17/2022
11/18/2022 1:48 PM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 7

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: XJ20074
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
Due to the matrix and low percent solid, the following sample has an initial weight that is 3x greater than
standard procedure: XJ20074-001. The LOQ has been adjusted to reflect this change.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 7

Client:Synagro Laboratory I D: XJ 20074-001
Description: NEWTON Matrix: Solid
Date Sampled:10/20/2022 0900 % Solids: 6.16 10/26/2022 0048
Date Received:10/20/2022
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 10/26/2022 0048 CBP
58141
1 350.1
(Ammonia - N ) 350.1
5 11/04/2022 1428 CMM
58714
1
(Nitrate - N ) 353.2
1 11/01/2022 1934 KKP
58858
1
(Nitrite - N ) 353.2
1 11/01/2022 1934 KKP
58860
1
(Phosphorus) 365.1
5 10/31/2022 1203 DMA
10/28/2022 1636 58634
1
(Soil pH meas) 9045D
1 10/24/2022 1624 KKP
58105
1 351.4
(TKN) 351.2
1 10/31/2022 1824 DMA
10/28/2022 1553 58630
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 2540G
6.16
%
1
Ammonia - N (gas diffusion)
350.1
1300 S
81
42
mg/kg
1
Nitrate - N (soluble)
353.2
120 S
3.2
0.43
mg/kg
1
Nitrite - N (soluble)
353.2
17
3.2
0.43
mg/kg
1
Phosphorus
7723-14-0 365.1
1800
410
81
mg/kg
1
Soil pH measured in water C)
19.6 ° C
9045D
11.9
su
1
TKN
351.2
8000
810
410
mg/kg
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 10/25/2022 1303 MRW2
10/22/2022 1211 57844
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7471B
ND
0.077
0.019
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
6010D
1 10/25/2022 1020 JMH
10/23/2022 1830 57881
2 3050B
6010D
1 10/31/2022 0012 JMH
10/23/2022 1830 57881
3 3050B
6010D
5 10/31/2022 0016 JMH
10/23/2022 1830 57881
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6010D
26000
100
39
mg/kg
1
Arsenic
7440-38-2 6010D
4.0
3.9
1.3
mg/kg
1
Cadmium
7440-43-9 6010D
0.49 J
1.3
0.32
mg/kg
1
Calcium
7440-70-2 6010D 220000
6400
810
mg/kg
3
Chromium
7440-47-3 6010D
49
2.6
0.64
mg/kg
1
Copper
7440-50-8 6010D
210
13
5.8
mg/kg
3
Iron
7439-89-6 601OD
15000
26
12
mg/kg
1
Lead
7439-92-1 601OD
11
2.6
1.2
mg/kg
1
Magnesium
7439-95-4 601OD
6100
1300
160
mg/kg
1
Manganese
7439-96-5 6010D
610
3.9
1.5
mg/kg
1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 7

Client:Synagro Laboratory I D: XJ 20074-001
Description: NEWTON Matrix: Solid
Date Sampled:10/20/2022 0900 % Solids: 6.16 10/26/2022 0048
Date Received:10/20/2022
ICP-AES
Run
Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
3050B
6010D
1
10/25/2022 1020 JMH
10/23/2022 1830 57881
2
3050B
6010D
1
10/31/2022 0012 JMH
10/23/2022 1830 57881
3
3050B
6010D
5
10/31/2022 0016 JMH
10/23/2022 1830 57881
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Molybdenum
7439-98-7
Nickel
7440-02-0
Potassium
7440-09-7
Selenium
7782-49-2
Sodium
7440-23-5
Zinc
7440-66-6
601OD
4.4 J
10
2.6
mg/kg 1
601OD
13
10
2.7
mg/kg 1
601OD
1300
1300
160
mg/kg 2
601OD
2.9 J
5.2
2.1
mg/kg 1
601OD
1100 J
1300
160
mg/kg 2
601OD
710
13
3.2
mg/kg 1
LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure
ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure
H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 7

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 7

PACE ANALYTICAL SERVICES, LLC
4
�y
_u
Cq
[C
C
©
i
C
a
C �
G
N
4 {3
V
y(
�
a
a
G
7
r�o
z
w q
p.
S
L
W U °4 - .
C4 4 a
Z
cc
Q a� del lE,JWeS
ejjii +� ent,lalla
—
C
m
J
r
z
Elf
cr
6
o
v
ci
�
y
i
t
L
'Y a O Ur�[J
on
+
i
i
m
f
� r s�i ra
'
L
^�
'R
^
Z
d.
£� }
f/p
LL
L'
V}
LL
O tli
0 W O
p
TL
u0
:x
�
F
o
a
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 7
R
A
s pp G
I�
It
Lj
m � v

PACE ANALYTICAL SERVICES, LLC
DC#_TitlL-: ENk'-FRPA-�VCDL-0256vD2_Saripli3s Rece;p` ChecN;liat (SRC)
Effective Date, S/?12022
Sample Receipt Cheeklia (RQ
k.n�n; - taoiciJ11a]7eC[ ;.UpcLaLU; f L8TIF: "•""'r,
Iuieam offeccio , FZ Parr ffil T=t UPS F,,Fx i7thcr-
Yes
ti/ Tea
1, W= r_uslody seals preseal %I r e coolet?
eS
ATa
. NA
Z_ If cEr3to seals e1 esenl: were tlse ' iulcr aid lrnhrof vn?
iH 5tilp 1D. chlorine 5inp ID` NA Tes:ed by NIL
Dl�gival to pdatttre ttpori receilrt. Daii eA (CuiTmord) LCnrpLTaftxo upon rece ipt. %SOlid Si pdtlp 11D: 22.15
2.1 KA / NA or Nh I NA oC NA i NA oc
Ietlwd; ❑TeuTurature Blank gaimt Bottles aC-autIL)_� IR Gun Cuimu&la Faulur-
rdetht)dref«xx, ilul- WIWelIcT. LllceFachEl Dry Ice I_..T None
❑ Yes
3, Alrere AIr.oalcrs rocci,,T l a[ x bt:low 6,0`C? Xmu, was I)-aject %fanagmu.ticd`' , ❑ o ❑? FM was Noil=ied >t : hulr- f Lauail 1 face-to-face {ciizle oite).
Y$S -N0 � �_1. 1, Is the m miercial cataer'S ackiu� shp atfathed to this fano
,I Yes No . Vi+ere }�ropcl rrrstodyprooc4iu[es (relizx�ru�l�clhacri��cd) l�ollo�v�d7
Yet -NO er-e Sturlple Rhi listed rm t1w COC'and aU sniliple r_ombincrs?
Yts l0 7_ Wn collec�iou [la*e& thux lis; 001 llle COC we all sInpit cautainers?
�f Y�; NL, 8. Did ail c;onbiari label iufommbwl (II], dare, Line) ngmc willi tide COO.
v ;I I No 9. Wefc tests to be paknued listed on the CDC"?
[ZIYQS U m 10. Did all samples rwh,,v is the gaper mmincrs far ea di rest audfo€ in good cauditioit
(UwXVkan, lidSon. Mj7
EyCS
Na 11, Wasparlcquale satuple wAmiac avaiiaWe
Na 12_ WcTc all sans les received unth rd ? t file holding lime rn' 48 Lam. am. xilichever comes first?
d❑Ye-, ❑ N0 15 _ WeEc. A s."P1es 0ontainets accowilcd far? 0 mis�in&Kc ess)
[-]Yes ❑Nu WINA I4. WtLr. VOA. 3015C and RSK-175 sa Tlcs iioe ofbubbles
diai=,,r) in auyofIflic VOA vtals'i`
JYM No ,� A 15. crc all f]I�Cl,'tnetalsiatu icut samples received v l: a H of':' r
Yes No ,{ 1 16. Were all �niide s les rcecivcd a[ a pH > 1 "c sulfide saipplcN � cerivcd al a {3 > 97
�T 17. crc , app c� � l`i�IylIT��}��tidc l+�lo-l•'6�5.I1b{15.3 ;� __ ri Salll�7lC5 fret of
❑�,� ❑ Ago MN r...�!___1
I❑Nol CNAI18, Was the quoreninnher listed on t ie container lag}cl? if yes. Quow
triple riv,1erWOu tMwt be conmpleted for au}' snwple(s) tucoo-sec-dy pret ,erved rrl-wit1rL-ajs?acc.)
wle(s) wel-c fcceived ulcuuwtly }+rr;mwd and were. ndjimc�d accordittgly
-u satnitle vice1VM1 g)A1 , axL ofCif cle 0rrc-112 01, KNO3, HCI, NaDH using SIB i din V
true 0iFki!5M anon NA _ ifUMC &M oboe 11+eservMti%'0 i9 tieeded, pleas: note in #w cntLrre m below.
NA
were rKeived VrAh Lu bbi}s 36 turn in diantcia.
La;%gnt}alcS(S) NA 'Rm fceived with TRC � I'15 m�'I. { I ' as 11o) �Ird ,tee
`ed acrtWxlftlglY in SLWle reC4iVb1g wilh sidium H}ilosttifote [1wf yC}s) with Unique ID; "�A
t upltrox ID' Str`35D Pie Analytitiel SeF r ees, L plan 1 of 4
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 7

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
2025-01-LSLIQ-NC NEWTON, NC CLARK CREEK LIME STABILIZED
LIQUID
Na mg/I = (Na mg/kg x % Solids) = 100 = (1100 x 6.1600) = 100 = 67.76
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (220000 x 6.1600) = 100 = 13552
Mg mg/I = (mg mg/kg x % Solids) = 100 = (6100 x 6.1600) = 100 = 375.76
Na meq = Na mg/I = Molec.Wgt.Na = 67.76 = 23 = 2.94609
Ca meq = Ca mg/I = Molec.Wgt.Ca = 13552 = 20 = 677.6
Mg meq = Mg mg/I = Molec.Wgt.Mg = 375.76 = 12 = 31.3133
Sample Date
10/20/2022
Report Range Ratio
10/1 /2022 - 0.1565
12/31 /2022
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.94609 = SgrRoot[0.5(677.6+31.3133)] = 0.156482

SECTION 3

2
CL
O
<
2(nu)
womw
E
LL
LL
U- LL
LL
U-
m
z
C2
N
a)
2
CL
<
z
to
0
LO
0
2
rn
OR
q
Oo
Z
-M
4
4
0
E
EgE�R
F
0
CD
C5
0
6 6
0 0
6
0
6
0
E
c�
Ci Ci
C�
C�
tl
c
0
a
0
0 0
0
0
m
0
0
0 C)
CD
o
Of
Q�
of cr
x
cc
:D
D D
Z)
Ui
CLco
CD
Fo
M
U)
C0
0 0
0
0
.0(.)L)
0000
❑
Z
z
z z
z
z
I--
co
m
0
o
cc!
t'17 h
n
P-❑
"a
o
C)
. .
.
.
Cl)
(o
w
tD m
0
(D
(D
(D
Q
(D 0
(D
(D
(D
0
0
Q
o
0
0.
C�C,
ci
Ci
C�
0
0C�
o
ci
C)
C�
0
C�
N
-1
to
CI co
LO
N N
N
LO
N
N
N
N
C'I
C14
N
N
W.,500
Z,
N
1%4
000OC4
0
m
C'I
N
2�j
�L
td
O
co
N
0
N
C',

2
2C:
CL
Cl)
a
C<"Mmmm
>
Lou)
m
E
owwww
6
LL
LL
LL
Lo 't
z
0
m
Z
(D
Ix
Lu
z
04
ui
N
-o
w
2
t- uj
<
Ln
m
wm
U) w Lu
Z
uj w
(D n-
Z o
o
q
CO
c6
xU
cl
C�
cl
C?
E
E
N
cN!
N
N
o)
<
.... ........................
Z
N
N
c1l
N
9
z
m
-
0
o
6
c
c
6
c
0
6
0
0
6
Lu
Z
2
<
z
z
N
o
Lu
0
0
0
C)
C,
w t
w
E co
u
o
., o
o
CL
(D
c6
p
d
y
G
Lu
Lu
w
CD M
0) a.
E2
w
u)
0
u)
0 Z
0
0
u) <
Z
<
K
w <
0
o
mnaa-
z
w 0
z
z
z
z
z
w x
<
6- C.)
to
cq
o
o
o
o
o
16
E
.2
16
U
Z wLL
>-
o
0
a)
c
o
o
CD
P
0 uj
CD
CD
0
C�
0
0
0
Q
CD
C)
0
C)
0
E
Ci
N
0
Ci
N
ci
to
R
0
W
z <
uj
LU
0
c)
o
(D
N
LL
0
LU
U)
Z< z
Q
0 z
<
N
N
o
N
N
o
N
N
c
N
N
0
0
o
,
,
�.�!
cL
z
C—L
uj 0
0
u)
CD
,Nd
clj
izz
m
Q)
<
, w
uj
LL
0 0
m
-a
O
2 1

V
C\l
a
2
(D
2
<
0 .>
Cf)
U)
cn
U)
E
2
LL
LL
U-
U.
z 12
C14
"a
<
z
<
2
C�
C�
c6
(�=
z
co
.Cuc
0000
a
0
0
m
0)
C�
E
2
E
=
E
C
c
C!
o
<
Z
z
M
0
c
0
CD
E
c�
c�
o
M
0
o
0
0
0
U?
Lq
U�
U?
............
o
o
D
D
D
D
E2
v
v
6
6
6
6
0-
i7 0
UL�-,00clo
0
0
L)
0�
u)
0
z
0
z
0
z
zL)
zt
(D
C)
CN
0
cq
u
't
CD
2:1
c)
(i
ch
C?
U)
co
m
co
co
0
0
Ci
C0
0
C�
0
C�
0
0
N
i
m
0
(D
R
0
E
r-
<
IN
N
cq
N
N
0
0 N
C, N
0 N
cli
0
2
�
O
O
(D
E
0
co
U)
F-
CL
co
Z
CO
0
U)
0) m
C� q
(5 10' 1 l'O
:2 C�
0 1:0�
C.
q C�
'C"), co"
00
N
co
(N
LO
m
Cl)
N
0
to
<
O
0
2
O
CD
9
rr

C� z
N 0
w z
0
w F-
w
D a_ 0
U) cn w
LLI Lu 0
Z 0
x
w
Z
0
F-
6
0.
2
76
2
CL
<
E
(D
0
2
LPL
LL
IllLL
0
Z
(2
a)
CL
C)
Z
-0
co
m
cn
m
fi
0
0
0
0
0
E
cD
0
E
E
Ci
<
0
0
o
0
z
m
E
c�
c�
c�
OO
co
=0
q
LQ
q
>
a)
CL
05
(0
cn
V)
O
K
z
z
z
z
rn
0
N
cl
cl
COO,
CM
C?
C?
C?
co
0
m
CD
C)
C�
0
0
0
C�
0
C�
co
'T
w
w
O
O
E
Cl)
to
It
m
("i
N
cli
N
t
ro
E
-00
00
O

E
cc)
LL
LL
ILL
ILL
Z
m
p
L)
CL
CL
Z
2
cj
�
Z
UJ
U)
Lq
U�
O
E
co
m
(o
m
w
m
co
m
0
C)
0
0
E21�)253
6
C5
65
0
E
E
c�
q
q
q
<
Z
r-
I,.
r-
I-
0
0
0
0
a
0
0
0
0
z
E
o
c�0
'71
«0
oc
m
m
m
co
cs
ci
6
ci
D
Z)
>
D
a
CL
75
U)
Cn
V)
a)
N
CN
cq
N
73
v
-ja
J
J
0
0
C)
Of
cn
0
z
L)
z
Q
z
L)
z
o
N
Ci
C?
Ci
Ci
0
0
C
0�
C�
C�
0
0
E
<
N
N
N
N
C615
N
m
0
—
LO
iV
O

v
0
16
E
i
Co
CL
E
wo
LL LL
LL
z
(2
0
rn
Lq
N
Cl)
0
E
E
<
0)
2
E
C) 0
0
c! n
0
C)
c!
z
-
0 CD
C�
c
E
O c�
co 00
O
co
. 2c000
"Z6
0
o
=
D Z)
D
=CL
CL
15
ui
C,
v
v
IL
0
❑
2
cq co
U)
72
S
0
U)
L) 0
z z
z
co
m
c
C-4
M
❑
o
CD
(6 6
(6
2
0
=
. 2
0
M
o
0
CD 0
0 0
C� cl
0
C>
cl
0
0
C�
'M*
E
<
cwo 00)
!0�O?
04
0
N
N N
N
2�4
N
�14 m
fV
>
0
Z
0

0
O
0
.00
C'4
ID CL
2
-o Q
in-
C)
2
CL
a
16 < m m
ID U) V)
E 2
LL LL
U
Z (2
04
.1 — a
N
'a
<
z
<
2 of cR
z 0 0
t-�
�2 a2
c 0 C,
a) 0) O O
0 0)
E 2
E rt' E c'� c!
< Z
0 CD Z
E O O
W co
oc
0
0
v V
(L
IL
FOO 2�500
()
O
U) C")
0
V)
z z
jo
0 0
O
>l!
0
0 0 0
0
0
E C'zto 'O;To w
<
. . ..............
N N
Cq IN N0 >
o
Z
O
O
ob
0)
li 112
0
U)
(D
Cc
2' a -2
Ir
0
_J
O
— C
in c
0
ca.
O
E
0 0
bl)
a
<
E
75 --
w
E _j
<
G 1:
cl
ro
c
0
to
0
0
Z

m
q:
�T
z
E
LL
LL
0
m
z
Of
Lu
Lu z
F-
LLI t-
11 15
Zi M
g
=CL
Q-
P: ui
<
D a_
co U)
w
z
w LU
rl�
(D a-
Z 0
C6
x
(D
w
Z
0
z
F-
<
0
E
m
2
cp
m
q
0
5
5
O
E
<
=
Z
E
"I
c!
aj
9
E
c�
0
0
<
C) 0
ui
2
co
co
Z
z
z
IL
uj
LL
m
d
>
So
w
co
0
0
O
vi
z
0
ID
(0
EL
CL
'i
C'j
CL
LU
w
rn a-
a-
W
U)
<
0
co
-j N
0
:E
U)
Z a
0 2
0
<
'It r
Z
F-
<
U)
(n
Lli
0
IL
0
0
0
0
L)
0
CL D
z
0
w 0
z
z
0 z
x
<
0- L)X
Ln
to
0
=0
0
0
O
U)
E
0
!E
0
a
(D
a
Z
0
,
U)
z
Z
0
<
>.
to,
0
0
0
F- Yj
3: z
r5 M w
LLI Z
LL, C)
u)
LU
0
<
ran
o)
Z 0
w
Q
. . ly
LU
LL
0
Of
0� W
0
W
2E
U)
N
N
Z z
<
Z
< ,
a
"0
"0
N
C�
0
zj ,
L) z
w 0
0
U)
M
0
>
Qi
CL w
5�
0 L)
w
I

v
0
0
E
0
0 CO QM
0 o w
>-
w W
z 0 U
. . 0 LL
w
w 0 ..
0 w 0
LU
Z
3: 0 Z <
0
z w 0 a)
u< g o
CL C) 0-1
L=L,
.0
2
ca
CL
o
g
E
LL
LL
LL
m
z
Q�
cli
0
a2
co
Cl)
w
<D
Q)
Z
tii
0
E
0)
2
m
C�
0 C,
0
E
cl !
<
Z
0
c
C)
Z
E
0
,
,.:
0
0
(Il
0
0
Ncli
o
0
0
o
C)
0
r1l
76
o
D
D
D
0
0
L)
U
0
L)
a)
0
u)
L)
L)
Z
z
zL)
0
C?
C?
O
N
O
(D
LO
LO
(D
(D
(D
0
0
CD
Q
Q
0
0
0
0
0
C)
C�
Ct
0
E
co
10
cli
0O
<
N
cli
CIJ
04
N
04
WtONOCC4
0
Cl)
O
0
O
Lo
fl
O.
0
0
0
U-
U) LL
0
z
LU
0
I

SECTION 4

SUMM111
ENVIRONMENTAL TECHN❑LOMZ3. INC
Arraly0ca1 Laboralorfas
January 14, 2022
Alex Fox
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL:
FAX:
RE: Newton
Dear Alex Fox:
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
Order No.: 22010196
Summit Environmental Technologies, Inc. received 1 sample(s) on 1/5/2022 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas
E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada OH009232020-1, New
Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma
2019-155, Oregon OH2O0001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah OH009232020-12,
Virginia VELAP 10381, West Virginia 9957C
Page 1 of 35

MM' Y Summit Environmental Technologies, Inc. Case Narrative
SU3310 Win St.
ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 22010196
Arralyi9cal Laboralorlas TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com Date: 1/14/2022
CLIENT: Synagro
Project: Newton
WorkOrder Narrative:
22010196: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Sequence Sample Notes:
22010196-OOIA MTL-TCLP-7(6010D): LCS-54221 exhibits high recovery for Silver. Sample is ND
for this analyte.
Analytical Sequence QC Notes:
LCS-54221 Mtl-TCLP-7(6010): LCS-54221 exhibits high recovery for Silver. Associated samples are
ND for this analyte.
LCS-54264 TCLP-SVOC-CPEST(8081B): P: RPD between confirmation column is greater than 40%.
Original
Page 2 of 35

MM' Summit Environmental Technologies, In Qualifiers and Acronyms
SU3310 Win S
EkiwllOMM@NTALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 22010196
Arraly0cal Laboralorlas TEL: [phone] FAX.- (330) 253-44E
Wehsite: httn:11www.settek.co Date: 1/14/2022
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
in Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25% difference.
C The result has been confirmed by GC/MS.
X The result was not confirmed when GUMS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low (-) or high (+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low (-) or high (+).
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low (-) or high (+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low (-) or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected
RL
Reporting Limit
QC
Quality Control
MDL
Method Detection Limit
MB
Method Blank
LOD
Level of Detection
LCS
Laboratory Control Sample
LOQ
Level of Quantitation
LCSD
Laboratory Control Sample Duplicate
PQL
Practical Quantitation Limit
QCS
Quality Control Sample
CRQL
Contract Required Quantitation Limit
DUP
Duplicate
PL
Permit Limit
MS
Matrix Spike
RegLvl
Regulatory Limit
MSD
Matrix Spike Duplicate
MCL
Maximum Contamination Limit
RPD
Relative Percent Different
MinCL
Minimum Compound Limit
ICV
Initial Calibration Verification
RA
Reanalysis
ICB
Initial Calibration Blank
RE
Reextraction
CCV
Continuing Calibration Verification
TIC
Tentatively Identified Compound
CCB
Continuing Calibration Blank
RT
Retention Time
PLC
Reporting Limit Check
CF
Calibration Factor
DF
Dilution Factor
RF
Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 35

�� 1 � Summit Environmental Technologies, Inc.
SU3310 Win St.
ENVIROMMEWAL YECHNO WULES, JNGG Cuyahoga Falls, Ohio 44223
Analytical Laboralorlas TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
CLIENT: Synagro
Project: Newton
Lab SampleID Client Sample ID
22010196-001 Newton
Tag No Date Collected
1/4/2022 7:45:00 AM
Workorder
Sample Summary
WO#: 22010196
l4 Jan-22
Date Received Matrix
1/5/2022 12:50:00 PM Sludge
Page 4 of 35

LO
co
4-
0
LO
m
m
ca
a_
A
Or
a
z
H

SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223
Arralyt9cal Laboralorfas TEL: [phone] FAX. [phone]
Website: http://�i,-"-m,.settek.coin
Analytical Report
(base report)
WO#: 22010196
Date Reported: 1/14/2022
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/4/2022 7:45:00 AM
Lab ID: 22010196-OOIA
Project: Newton
Client Sample ID Newton
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury
ND 0.00200 mg/L
SW7470A SW7470A Analyst: KLC
1 1/7/2022 5:30:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW6010
SW301OA Analyst: MSK
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As)
ND
0.500
mg/L
1
1/10/2022 11:52:00 AM
TCLP Barium(Ba)
ND
5.00
mg/L
1
1/10/2022 11:52:00 AM
TCLP Cadmium(Cd)
ND
0.100
mg/L
1
1/10/2022 11:52:00 AM
TCLP Chromium(Cr)
ND
0.200
mg/L
1
1/10/2022 11:52:00 AM
TCLP Lead(Pb)
ND
0.500
mg/L
1
1/10/2022 11:52:00 AM
TCLP Selenium(Se)
ND
0.0500
mg/L
1
1/10/2022 11:52:00 AM
TCLP Silver(Ag)
ND
0.500
QL+ mg/L
1
1/10/2022 11:52:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8270
SW351OC Analyst: SFG
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene
ND
0.200
mg/L
2
1/10/2022 8:30:00 PM
2,4,5-Trichlorophenol
ND
0.500
mg/L
2
1/10/2022 8:30:00 PM
2,4,6-Trichlorophenol
ND
0.500
mg/L
2
1/10/2022 8:30:00 PM
2,4-Dinitrotoluene
ND
0.100
mg/L
2
1/10/2022 8:30:00 PM
Cresols, Total
ND
10.0
mg/L
2
1/10/2022 8:30:00 PM
Hexachloro-1,3-butadiene
ND
0.0400
mg/L
2
1/10/2022 8:30:00 PM
Hexachlorobenzene
ND
0.100
mg/L
2
1/10/2022 8:30:00 PM
Hexachloroethane
ND
0.200
mg/L
2
1/10/2022 8:30:00 PM
Nitrobenzene
ND
0.200
mg/L
2
1/10/2022 8:30:00 PM
Pentachlorophenol
ND
0.500
mg/L
2
1/10/2022 8:30:00 PM
Pyridine
ND
0.500
mg/L
2
1/10/2022 8:30:00 PM
Surr: 2-Fluorophenol
58.4
10 - 157
%Rec
2
1/10/2022 8:30:00 PM
Surr: Phenol-d6
65.5
10 - 169
%Rec
2
1/10/2022 8:30:00 PM
Surr: Nitrobenzene-d5
57.0
32.1 - 130
%Rec
2
1/10/2022 8:30:00 PM
Surr: 2,4,6-Tribromophenol
77.3
45.4 - 166
%Rec
2
1/10/2022 8:30:00 PM
Surr: 2-Fluorobiphenyl
56.4
35.7 - 130
%Rec
2
1/10/2022 8:30:00 PM
Surr: p-Terphenyl-d14
103
70 - 145
%Rec
2
1/10/2022 8:30:00 PM
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H Holding times for preparation or
analysis exceeded
M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified
compounds
ND Not Detected
OG1
P Second column confirmation exceeds
PL Permit Limit
Original
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 6 of 35

SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223
Arrafyt9caf Laboralorfas TEL: [phone] FAX. [phone]
Website: http://�i,-"-m,.settek.coin
Analytical Report
(base report)
WO#: 22010196
Date Reported: 1/14/2022
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/4/2022 7:45:00 AM
Lab ID: 22010196-OOIA
Project: Newton
Client Sample ID Newton
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP PESTICIDES ANALYSIS (SW1311/8081)
Chlordane, total
ND
Toxaphene
ND
Endrin
ND
gamma-BHC
ND
Heptachlor
ND
Heptachlor epoxide
ND
Methoxychlor
ND
Surr: TCMX
55.8
Surr: DCB
84.7
TCLP HERBICIDES BY EPA 8321B
2,4-D ND
2,4,5-TP ND
Surr: 2,4-Dichlorophenylacetic aci 95.2
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene
ND
1,2-Dichloroethane
ND
MEK
ND
Benzene
ND
Carbon tetrachloride
ND
Chlorobenzene
ND
Chloroform
ND
Tetrachloroethene
ND
Trichloroethene
ND
Vinyl chloride
ND
Surr: 4-Bromofluorobenzene
97.4
Surr: Di brom ofl uorom ethane
102
Surr: Toluene-d8
101
SW8081 SW351OC Analyst: CSS
0.0250
mg/L
10
1/13/2022 2:07:00 AM
0.0500
mg/L
10
1/13/2022 2:07:00 AM
0.00500
mg/L
10
1/13/2022 2:07:00 AM
0.00500
mg/L
10
1/13/2022 2:07:00 AM
0.00500
mg/L
10
1/13/2022 2:07:00 AM
0.00500
mg/L
10
1/13/2022 2:07:00 AM
0.00500
mg/L
10
1/13/2022 2:07:00 AM
10 - 119
%Rec
10
1/13/2022 2:07:00 AM
10 - 119
%Rec
10
1/13/2022 2:07:00 AM
S W 8321
Analyst: RIS
0.500
mg/L
50
1/12/2022 4:43:00 AM
0.500
mg/L
50
1/12/2022 4:43:00 AM
70 - 130
%Rec
50
1/12/2022 4:43:00 AM
SW8260
SW1311M Analyst: NAW
0.250
mg/L
50
1/7/2022 6:56:00 PM
0.250
mg/L
50
1/7/2022 6:56:00 PM
5.00
mg/L
50
1/7/2022 6:56:00 PM
0.250
mg/L
50
1/7/2022 6:56:00 PM
0.250
mg/L
50
1/7/2022 6:56:00 PM
2.50
mg/L
50
1/7/2022 6:56:00 PM
0.250
mg/L
50
1/7/2022 6:56:00 PM
0.250
mg/L
50
1/7/2022 6:56:00 PM
0.250
mg/L
50
1/7/2022 6:56:00 PM
0.100
mg/L
50
1/7/2022 6:56:00 PM
70 - 130
%Rec
50
1/7/2022 6:56:00 PM
70 - 130
%Rec
50
1/7/2022 6:56:00 PM
70 - 130
%Rec
50
1/7/2022 6:56:00 PM
Qualifiers: B
Analyte detected in the associated Method Blank
H
Holding times for preparation or analysis exceeded
MC
Value is below Minimum Compound Limit.
ND
Not Detected
P
Second column confirmation exceeds
R
RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
OG 1
PL Permit Limit Original
RL Reporting Detection Limit
Page 7 of 35

MMIT
Summit Environmental Technologies, Inc. Analytical Report
SU3310 Win St.
ENVIRONMENTAL TECHNOLOGIE-3, IRC Cuyahoga Falls, Ohio 44223 (base report)
Arralyt9cal Laboralorfas TEL: [phone] FAX.- [phone] WO#: 22010196
Website: http://www.settek.com Date Reported: 1/14/2022
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/4/2022 7:45:00 AM
Lab ID: 22010196-OOIA
Project: Newton
Client Sample ID Newton
Analyses Result
RL Qual Units
DF
Date Analyzed
RCI
SW9014
Analyst: MS
REACTIVE CYANIDE (9014/7.3.3.2)-SOLID
Cyanide, Reactive ND
0.495 mg/Kg
1
1/10/2022 11:41:00 AM
IGNITABILITY OF SOLIDS (SW-846: 1030)
SW1030
Analyst: ALT
Ignitability nonflammable
mm/sec
1
1/7/2022 2:56:08 PM
RCI
SW9045D
Analyst: ALT
PH (SW9045D)
pH 12.2
s.u.@19.7C
1
1/7/20224:13:17 PM
RCI
SW9034
Analyst: MS
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive ND
25.0 mg/Kg
1
1/10/2022 11:41:00 AM
Qualifiers: B
Analyte detected in the associated Method Blank
H
Holding times for preparation or analysis exceeded
MC
Value is below Minimum Compound Limit.
ND
Not Detected
P
Second column confirmation exceeds
R
RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
OG 1
PL Permit Limit Original
RL Reporting Detection Limit
Page 8 of 35

Summit Environmental Technologies, Inc.
Accreditation
Program
SUMMIEF
fr3310 Win St.
Analv n tes Report
ENwIROMMEWALYECHNOL.OG{r,S,INC
Cuyahoga Falls, Ohio44223
J
Y
Arraly0cal Laboralorlas
TEL: [phone] FAX.- [phone]
WO#:
22010196
Wehsite: http://www.settek.com
14 Jan-22
Client: Synagro
State: NW
Project: Newton
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
22010196-OOIA Sludge
Ignitability of Solids (SW-846: 1030)
Ignitability
A
Sludge
pH (SW9045D)
Hydrogen Ion (pH)
A
Sludge
Reactive Cyanide (9014/7.3.3.2)-Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/7.3.4.2
Sulfide, Reactive
U
Sludge
TCLP Herbicides by EPA 8321B
2,4,5-TP
A
Sludge
TCLP Herbicides by EPA 8321B
2,4-D
A
Sludge
TCLP Mercury Analysis (SW1311/7470)
Mercury
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Arsenic
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Barium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Cadmium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Chromium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Lead
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Selenium
A
Sludge
TCLP Metals Analysis (SW1311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Endrin
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
gamma-BHC
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Methoxychlor
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Toxaphene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
1,4-Dichlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,5-Trichlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,6-Trichlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4-Dinitrotoluene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Cresols, Total
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachlorobutadiene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachloroethane
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Nitrobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Pentachlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
Pyridine
A
Original #1
Page 9 of 35

Summit Environmental Technologies, Inc.
Accreditation
Program
SUMMIEF
fr3310 Win St.
Analv n tes Report
ENVIROMMEWAL YECHHOL.OG{r,S,
INC Cuyahoga Falls, Ohio 44223
J
Y
Arraly0cal Laboralorlas
TEL: [phone] FAX.- [phone]
WO#:
22010196
Wehsite: http://www.settek.com
14 Jan-22
Client: Synagro
State: NW
Project: Newton
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
22010196-OOIA Sludge
TCLP Volatiles Analysis
1, 1 -Dichloroethene
A
Sludge
TCLP Volatiles Analysis
1,2-Dichloroethane
A
Sludge
TCLP Volatiles Analysis
2-Butanone
A
Sludge
TCLP Volatiles Analysis
Benzene
A
Sludge
TCLP Volatiles Analysis
Carbon tetrachloride
A
Sludge
TCLP Volatiles Analysis
Chlorobenzene
A
Sludge
TCLP Volatiles Analysis
Chloroform
A
Sludge
TCLP Volatiles Analysis
Tetrachloroethene
A
Sludge
TCLP Volatiles Analysis
Trichloroethene
A
Sludge
TCLP Volatiles Analysis
Vinyl chloride
A
Original #1
Page 10 of 35

0
0
N
Fi
c�
0
E
J
O d
M LOT ry
f� CDao to
to r)
M d
rK
z z
0-
of �
0
d
N N
00
N N
J
� � L
N N
C6 ) _
Q fn E
Q) 'N J
d T
� J
Q
U
W
0
J
E m
r >
M w
O � �
� Y
IL
U)
O
a co
co >
Y
H CO IL
0
U wIL
J
Ci
0
0
a
COm
� a
N � N
E _O co
cn U Q
O O O
O O O
r— r— r—
LO N
C6 O O
rn
U') U') U')
0 0 o 0 0 0 0 0 0
U') U') l0 l0 L6 U0 U0 U0 N
0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 o 0 0
Z Z Z Z Z Z Z Z Z Z m `) `)
C C
C
00
N O p
00
o 00
o 0
EEC
N N U O O N Oi OO N
0 0 c o m
0 0 o m o o 0 o v i
U U N 00 O O U O U i i i
Q Q Y C O O U U) (n (n
N W a) (O L :EO
2 m 0 0 0 H H
LO
M
O
O
CD
co

75
N
N _
O
N E
n J
� L
_D
O N =
cl cl
Q N
E .N 3
a '•
co J
Q
LU
U
J
E N
Uj M
� N Y
a
Cn
U
O O o
> o
a � co
U ? Y
H CO q-
-0 Z
0
U (D J
U H a
(D a
N U
L
N
a
a .U.
E m
co Co
U
CO
Q
O
O
o U
00 O
o
R
N m
Q) O
E o �o
i/ U Q
CO�� � CO CO O O
� �
CO I- M N I- r— U) N V M I- U')
cli Uf Uf 6 O c'(7 N 6 Or-� LP7 V
U') CO -,I-N M -,I-M N I- CY)
N CO N CO O CO V V O V N � O
O O O
O O O O O O O O O O
0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0
�f7 N N N
0 0 0 0 0 0 0 0 0 0
cn cn o cn cn cn cn cn cn o
N N Lj N N N N N N
O O O O O O O O
N CO0 co Z M NN Z � I- N I- U) ON O
�� CR� CR CR r— N N N
00 00 O O O O
Nco
L
C �
N
O p
0 0 o m
0 0 70 o 00
c c C
o co o o 0
E E
N N N N O O N
O O C E O m �_ 2
O O N �
U U_ O O U O U
Y N O O c6 L T
U Cn Cn Cn
Doo U U U H
m
a
E
J
Cl) 0
Im
a
M � a
Z Z o
c �
in
a
N
N _
O
N E
� J
� L
_D
N O =
co C6 _
cl cl
Q N E
.N 3a '•
co J
Q
LU
U
J
E N
y M
N Y
a
Cn
U
O O o
> o
a � co
Y
H N q-
-0 Z
0
U (D J
al
H Cl
N N
L
N
a
a .U.
E m
co Co
U
0
CO
Q
O
O
o U
o O
o 2
R
N m
0
� � O
E o co
i/) U Q
N N C�
O
c2 co O rn
rn rn o
6 0 0
O m �2
CO
CO I- m N
0 0 0 0
cn cn o cn
N N Lj N
O O O
CR CC) CR
O O O
M
4-
0
N
ca
0-

0
0
N
A
U
:C
a
N
N _
O
N
n J
� L
_D
O N =
cl cl
Q U)E
E .N 3
a '•
c J
Q
U
W
J
E N
y M
� N Y
a
CO
U
O O
a co
� m
Y
H N q-
Z
O
U J
H CJ
� a
N N Q)
L
N
a
a .V.
E m
m Co
U
0
CO
Q
O
O
o U
00 O
o
R
N m
O O
E Q) m
c n a
N N N N N N N N N
O O � O �� 0 0 0
co N N 6 0 co
O o Cj r- Oro r-
rn rn o o �
0 0 0 0 0
I- r- U) N V m I- U)
N CCJ V 6 C6
N O N u') N I- N n O
m m m m r-:
r�
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
N N N
0 0 0 0 0 0
N � N N N O
N
O O O O O
N Z N N N r- V Uf)
O O O O O N N N
M
4-
0
cr)
m
0
0-

75
a
E
J
L
a
Cl) to 0�
to Im
M � a
zo zo
c �
in
75
N N
N N
O E
n � J
� � L
_D
U N =
cl cl
a U E
E .N 3
a '•
c J
Q
LU
U
J
C1
E O_
CO
M
� N Y
a
n
d
J O �
H cO >
Y
co a-
Z
0
U (D J
H CJ
� a
Y
m N N
L
N
a
a .U.
E m
m Co
U
N
v
00 Cl)
� a
0
o o
0- T
E o Flo
U Q
0 0 0 0 0 0 0
0 0 0 0 0 0 0
�t
O O O O O O
0 0 0 0 0 0 0
z z z z z z z
75
a
E
J
O
a
to to 0�
to Im
M t a
zo zo
c 0-
� (n
75
N N
N N
O E
n � J
� � L
_D
U N =
cl cl
a U) E
` >
a , 3
co J
Q
U
LU
O �
M
� � Y
a
n
d
J O Q)
cO >
Y
co
Z
0
U J
Q CJ
� a
U v o
J L
U
a
a .U.
E m
m Co
U
N
N
J J
0
o o
0- C T
E o m
i/ U Q
O O O O O O O
O O O O O O O
O O O O O O O
O O O O O O O
O O O O O O O
O O O O O O O
N N N N N N N
0 0 0 0 0 0 0
0 0 0 0 0 0 0
O O O O O O
o z 7 7 7 7�
N z N N N N N
M
4-
0
m
0
0-

75
N N
N N
O E
n J
D
ib
0 0
a
E .N 3
a '•
c J
Q
U
u1
J
E O_
Ui O i
Cl)
� N Y
a
CO
n
d
J O �
H >
Y
m co a-
Z
0
U U J
H CJ
� a
coN Q)
L
N
a
a .U.
E m
m Co
U
CO
Q
O
O
Q1 U
n d
o �
R
N m
47 N
E o m
i/ U Q
O O O O O O O
�2 �2 �2 �2 10 10 10
o N v m m v
rn rn� rn rn rn
O O O O O O O
N
O O
O
O O O O O O O
O O O O O O O
O O O O O O O
N N N N N N N
0 0 0 0 0 0 0
0 0 0 0 0 0 0
O O O O O O
N z� N N C) V
� U o
U U
Q m E = E
U 2 a 7 Q
E O O N
i N (6 L co N
Q co U U J cn c/)
a a a a a a a
J J J J J J J
U U U U U U U
75
E
J
a-
M t a
zo zo
c 0-
� CO
N N
N N
O E
D
0 0
a U E
` .55
>
a , 3
co J
Q
U
u1
J
O �
U O i
M
Cl) Y
a
n
d
J O Q)
H >
Y
m co a-
Z
0
U Q J
Q CJ
� a
�
N Q)
L
U
a
a .0
E m
m Co
U
0
CO
Q
O
O
Q1 U
n U,
o �
R
N m
6
47 N
Cl >,
E o m
i/5 E)Q
J
O
O
O
O
O
O O
N
N
N
N
N
N N
m o � m � v) 00
0
N O m N (Dr-
N I� O O O) V
O O O O O O O
�2 �2 �2 �2 �2 �2 �2
o- v v I- o co
6 N m uf7 V �
O m O O O m
O O O O O O O
CY) O
N
O O
O
O O O O O O O
O O O O O O O
O O O O O O O
N N N N N N N
0 0 0 0 0 0 0
0 0 0 0 0 0 0
O O O O O O
z m � coo, rn m
� U o
U U
Q m E = E
U 2 a 7 Q
E O -O N N
i N (6 L N N
Q co U U J Cl) c/)
a a a a a a a
J J J J J J J
U U U U U U U
M
4-
0
m
cu
0-

75
a
E
J
O a-
a
LO N
to Im
M CO d
zo zo
c zT
in
n
75
N N _
N N E
n n
D
ib
0 0
a
E .N 3
a '•
c J
Q
U
u1
a a
a O 5
_ v >
� N Y
a
a
J O (D
H� n co
2 CO a-
Z
0
U (D J
U H a
(D a
m N N
L
N
a
a .U.
E m
m Co
U
N
N
v
an
00 Cl)
� a
U U
fl >,
E o m
i/ U Q
O
O
N
O
O
1.
ii
U
U
2
a
75
a
E
J
a-
a
LO N
to Im
M CO d
zo zo
c zT
[If in
n
75
N N _
N N E
n n
D
ib
0 0
a
.N 3a '•
c J
Q
U
u1
a a
a O 5
_ v >
Cl) Y
a
a
J O �
H� n m
2 CO a-
-0 Z
0
U (D J
H CJ
� a
U v (D
Of
J to
U
a
a .U.
E m
m Co
CO
N
N
N
cb co
J J
47 N
0- >,
E o m
i/) U Q
O
O
0
co
O
O
co
a
E
J
a 0
LO N
to Im
M CO d
zo zo
c 0-
� CO
n
a
N N _
N N E
D
0 0
a
2 .N 3
a
c J
Q
U
u1
a a
a O 5
_ v >
n
� � Y
a
a
J O Q)
2 CO a-
Z
0
U Q) J
Q CJ
� a
y v Q)
to
U
a
a .0
E m
m Co
U
CO
Q
O
O
O1 U
n u,
o �
R
N m
L
47 N
E o m
i/) U Q
a
CO
0
N
O
i1
co
a
E
J
Cn
LO N
to Im
M CO d
zo zo
c zT
in
n
Flo
N N _
N N E
D
co co
0 0
a U E
E .N 3
a
c J
Q
U
u1
a a
a O m
v >
y_ n
� N Y
a
a
J O (3)
H� n co
(� Y
2 m �
Z
0
U � J
H CJ
� a
N N Q)
L
N
a
a .0
E m
m Co
U
0
CO
Q
O
O
O1 U
n u,
o �
R
N m
b
U U
Cl >,
E o m
i/ U Q
O
N
O
O
26
U
U
2
a
J
U
P
M
0
� m
o ca
0-

N
N
N
Fi
c�
0
E
J
to r)
cn 'IT d
LO ry
is m
00 to
to r)
M d
Z
ry
z
>
ry
ry
0
d
N N
00
N N E
� � J
� � L
N N
N ) _
Q N E
Q) 'N J
d T
� J
Q
U
LU
0
N N N
N
a
Q U
E t6
(6 CO
0
N
¢
0
n V
Ci
N to
N CO
Q �
E _� (a
cn U Q
LO
co
0
ti
m

N
7
N
A
U
:C
a
E
J
N
a
n00 to
o
M to
') d
zo zo
c �
in
75
N N
a a
N N
O O E
� � J
� � L
_D
O N =
cl cl
a U) E
E .N 3
a '•
c J
Q
U
W
J
C1
O �
ri L >
M
� N Y
i a
U CO
N n
a co
� m
U ? Y
H N a-
� z
0
U � J
U H a
� a
(n N
L
ai p
a
a .U.
E m
m Co
U
CO
Q
O
O
Q1 U
rn 0
O U
R
N m
N N
E o m
cn a
V N O N N coN U') V O Cfl O com m n N C2 L2 v m m L2 v- m m m v m CC) C2 C2
N co co N m (fl O m N V O I'- � Ci m V C%
Lx� O I-� U') (fl r-� - V C� N � O m I-- -,I-
CO N N N U) - M N N N U')
m II- N V N V O V N V m V CP) - U') N N N_
O V Cfl C6 Uf O 6 V C6 I-� Cfl C6 N C6 6 Cfl �
O O O O O N O O O O O O
m_
O
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 o m o 0 0 0 0 0 0 0 0 0 0 0
O O O O O O O O O O O
0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 C� o 0 0 0 0
O
N O m I- N 0 N CP) Cf7 O v p Cf7 U') N N N
O I- O O O Z m I- M N M Z N C%7 Ci) CO
V co co r- co m co m co co r- r- co m r-
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
O
C=
N
N -O it C
NC NE N O
0 0 C o
N L L C C 0 'O N:N
C 0- 0- N CJ N N O N� Q
O O O L O Q O O
O-� O O O OL LL -0�_ LL H
C o O O O N O N d Z N N C1
U H I7 � rn U U U ) 0 C
Cf7 co0 to N N (6 O 'O
V V V V U O N N N T (n (n (n (n (n (n
N N N O U 2 2 2 2 d d
M
4-
0
co
m
0
0-

N
7
N
A
U
:C
75
a
E
J
Cl)
a
n00 to
o
M CO
CS d
Z Z o
C 0-
Tf in
N N
a a
N N
O O E
� � J
� � L
_D
O N =
cl cl
a U) E
E .N 3
a '•
c J
Q
U
W
J
C1
O �
N L >
M
� N Y
i a
U U
N n 2
a co m
U ? Y
H N a-
� Z
0
U � J
U H a
� a
N N N
ai p
a
a .U.
E m
m Co
U
0
C0
Q
O
O
Q1 U
M C3
O U
R
N m
O O
E N co
Con a
E
O O O O O O O O O O O O
m m m m m m m m m m m m
o cl� cl� O r-� O (fl
O N N
O O N N O O O O N O V O
O I- O O O CY) r- OCY)
v, co co co m co m co co
0 0 0 0 0 0 0 0 0 0
V N O N N co N U') V O (fl O co m m n
N �2 Lf2 v m m Ln v m c2 c2 c2 v c2 �2 m �2
N co co O m (fl O m N V O I'- � O) m y Cv
Lx� O I-� U') (fl r-� - V C� N � O m I-- -,I-
CO N N N U) - M N N N U')
N V- M Cfl - V V V- Cfl O CO O (fl M M M
m zi Cfl 6 Cfl 6 m 6 O m N I-� m N Uf
V I- co r- co co V I- V co O co co co UP) N co m
O O O O O N O O O O O O
m_
O
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 o co 0 0 0 0 0 0 0 0 0 0 0 0
m------
O O O O O O O O O O O
0 0 0 0 0 0 0 0 0 0 0 0
O
Cl? Ln Ln Co Ln cm Cfl m Ln Co m co Ln m co rn
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
O
C
N
O Q C
,I-
.0 C N O N O
0 0 C o
co N L L O LL 'O NCC
0 O O 5 CO LOL Q
O O O O
i N N Z HN
N N Q
U H I- C N O U U U 0 C i i i i i i
O 'O � � � � � �
V V V V U O O O N T Cn Cn Cn Cn Cn Cn
N N N 0
U 2 2 2 Z d d
M
4-
0
rn
m
0
0-

N
N
Fi
U
F�
0
E
J
V d
N f- r'
f- CDao to
to r)
M d
rK
z z
0-
of �
J cm �
N
a
Q U
E ca
co CO
Cn
N
N
m m
� a
_N cl N
E am m
co n C) a
M CO M M M M
0 0 00 Lo'T 00
Cfl M M C)
00 O O CD O N
M V Lo C)
I- r- CD 00 CD
O O O Cl Cl Cl
Cl Cl Cl Cl Cl Cl
Cl Cl Cl O O O
O O O O O O O O O O O O
NNN C) CD C) C) NN LO O
0 0 0 CD 0 0 CD 0 0 0 0
O C) O
p p p p p p p p p p p p w O m Co O N
Z Z Z Z Z Z Z Z Z Z Z Z�(D M M
O O O O O
O
C
A 0 0�
O
O L N
C 0- 0-O N (0 N 2� C O
O (6 O N Q 7 C am~ 7 Q
o
L L 0 0 O O O N O LE =-. ..,i4H
U U O O O N N d Z N N Q
L L C.)i i i i i i
l0 CO i5 N O (0 (6 co Q (0 .o O O O O O O
V , V V C)N N N N .O N >. U) U) U) U) U) U)
r N N N 6 6 2 2 2 2 a a
co
O
0
N
Q)
ca
d

N
7
N
A
U
:C
m
a
E
J
M
a
n o
M 00 to
CO
CM d
zo zo
C 0-
in
75
N N
N N
O O E
� � J
� � L
_D
O N =
cl cl
a U) E
E .N 3
a '•
c J
Q
U
LU
J
tm
E O
N Lo >
M
� N Y
a
Qi cn
Z
U ci m
� � Y
N �
� z
0
U � J
U H a
� a
U v N
J M
N
a
a .U.
E m
m Co
U
N
U co
J J
N cl N
fl >,
E N c5
cn a
E
O CO N O O O O O m 0 �f7 O� m m
m m m m m cm cm cm cm cm cm cm co 2 m co
c i I-� of Lxi I-� C6 of co C,i o — — — co c i m o
co U') co U') U') m co m U') co CO co
V O V N I- r— O m M m V O� V U) — I- N
c0 m 6 Or-� O U7 c0 m 6 m zi c0 N N N co I�:
V I� Cc r-- co co V r— V co I- m co r— co m (D m
O O O O O O O O O O O O
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 o co 0 0 0 0 0 0 0 0 0 0 0 0
m------
O O O O O O O O O O O
0 0 0 0 0 0 0 0 0 0 0 0
O N N U) N O O O O_ O N N
�f7
O O O
V U) co N 0 U) U) I- r— � V U) I- N
co O U7 N V Z Co co N
m �f7 �f7 c0 UP m CO m UP UP N c0 I� CO N CO O1
O O O O O O O O O O O O O O O O O
O
C
N
Co NC N Q
N c EC
p
ON L N N
N NNN
0 O NLNQO C OQp
OO O O LL 2_ LL H
i i O O O N O N d Z N N Q
U H I7 C N U U U C i i i i i i
N N N O 0 2 2 2 2 d d
M
4-
0
N
ca
0-

m
a
E
J
l
Im a
00 Cl)
M � a
zo zo
c �
in
75
n
N N
N N
N E
� � J
� � L
_D
O N =
cl cl
a U E
E .N 3
a '•
c J
Q
U
W
J
C1
O �
N L >
M
N Y
a
U U
N c
a a co
m
—i coU ? Y
H N a-
Z
0
U � J
U H a
� a
U v o
J L
N
a
a .V
E m
m Co
U
to
N
Cl) CO
J J
o o
fl >,
E o m
Co n a
a
O O O O O N O O
�2 �2 �2 �2 �2 �: �2 �2
O O O O O O O O
N O U') — CO O U) O
I- m co co I- V CO
O O O O O O O O
0 0 0 0 0 0 0
CON 0 0 0 0 0 0 0
0 0 0 0 0 0
0
0 0
0
0
0
N
�f7 �f7
�f7
�f7
�f7
O
O O
O
O
O
O
O O
O
O
O
O
O O
O
O
O
O O
O
O
O
O
co
o�
U)
r-
rn
ry
0
O
0 0
O
0
0
0 OC)
0
O O
O
O
0
O O
O
O
N
X
U o o m
m
-o c m m o
O n
L C E N N 47
U W o1 2 2
m
a
E
J
O
Im Cl)
00 L
M 00 to
to
M a
zo zo
c
[if in
75
n
N N
N N
N E
� � J
� � L
_D
O N =
co (
0 cl
a U E
E .N 3
a
c J
Q
U
W
ly-
C1
O �
N L >
M
Cl) Y
a
U U
C9 co �
a co m
Y
H N a-
-0 Z
0
U Q) J
Q al
H CJ
co N Q)
L
O
a
a .V.
E m
m Co
CO
to
e
LO
m m
a
o o
fl- � T
E o m
Co n a
m
O N
O co
0 0 0 0 0 0 0
N �f7 �f7 �f7 �f7 �f7 �f7
O O O O O O O
O O O O O O O
O O O O O O O
O O O O O
Z Z Z Z Z Z Z
N
X
U o o m
Qco m U H
E m m 0
L x0 C N N N 47 CO CO
U H W 0) 2 2

IV
Iz
Fi
U
F�
0
E
to r)
a_W LO ry
co LO
co to
to
r)
M d
Z
rK
z
75
0
N N
CD
N N
N E
0 0
U E
Q) 'N J
d T
� J
Q
U
LU
0
J_
E m
r >
M
� Y
IL
U U)
c
a co co
>
Y
H CO IL
�o Z
0
U � J
m IL
Ci
m N N
N
a
Q U
E ca
co CO
co
a
CO m
� a
0
m � m
E _o m
cn U Q
LO
co
O
co
N
Q)
ca
d

m
a
E
J
Cl)
Im a
N CO 0'
co LO
M CO
� M d
o o z z
C ZT
75
N
N _
O
N
M J
� L
O N =
cl cl
Q to
E .N 3
a '•
c J
Q
U
u1
a
e N
N >
C D
� Y
a
�I U
co 2
fA O
U 00 co
y a
U
Z
0
U � J
U H a
� a
CM
N
co
in Cl) N
J �
N
a
a .V.
E m
m Co
U
r- O
o � o
rn
O O O
Uf7 N O
6 C6 O
Nco
L
c 0
N
O p
O p 00
0 0 0
E E
0 0
O
C/) C/) C/)
m
a
E
J
l
N CO 0'
M CO
f") d
zo zo
C �
[If C/)
75
N
N _
O
N E
M J
� L
_D
co C6 _
0 cl
a U) E
2 .N 3
a '•
c J
Q
U
u1
a
e co
N >
C )
� Y
a
�I U
H
fA O Q)
U 00 >
O> y a
U
Z
0
U � J
H CJ
m
N
J M N
Q
a
a .V.
E m
m Co
CO
O co rn
r-� 6 6
rn rn rn
U') o rn
Nco
L
c 0
N
O o
O 0
0 0 0
E E
0 0
m
V i5 H
7 7 7
C/) C/) C/)

V a
0
E
J
d
N LO ry
'o 00
co LO
to r)
M d
Z
rK
z
ry
ry
0
d
ry
N _
O
N E
� J
L
N N
C6 ) _
Q fn E
Q) 'N J
d T 3
� J
Q
U
LU
v
a
CV!
E
E
C
Y
IL
U)
O �
w r >
� 3 Y
y a
� Z
0
U J
IL
N
co
co
M
co
U U
J J
E m Flo(6 — C
cn U Q
O
co
O
r-
r-
0
O
O
V
N
T
21
LO
co
O
LO
N
Q)
ca
d

m
a
E
J
Im
to a
to 00
n
M � a
o o z z
C �
n
75
N
N _
O
N
n J
ai ib =
m m _
cl cl
a U
E .N 3
a '•
c J
Q
U
w
U
L
CW
V
7
N 75
N >
C D
� Y
a
LO
O(DQj � 7
N > Im
I Y
C N a-
� z
0
U (D J
H CJ
� a
cn
O �
in 00 M N
J �
N
a
a .V.
E m
m Co
U
to
cn
O
00
M_
13; N
Cl) CO
J J
47 N
0- >,
E o co
i/ U Q
O
O
rn
O
O
O
O
O
r-
m
a
E
J
a-
co 00
i
M � a
zo z75
C �
n
a
N
N _
O
N E
_D
ai ai =
m m _
cl cl
a U
.N 3a '•
c J
Q
U
w
U
v
Q1
V
7
y N
N >
C D
� Y
a
LO
(Da-e 7
I Y
C a-
� z
0
U (D J
H CJ
� a
cn
00
O
d m N
0 � �
a
a .V.
E m
m 00
a
D
Q
O
O
CD U
0
O U
C.jR
N CO
L
47 N
0- C T
E o m
i� U Q
rn
r-
O
O
O
m
a
E
J
Cl) 0
a
ali n 0�
co 00
M c a
zo zo
C 0-
0� CO
75
a
N
N _
O
N E
n
_D
ai ai =
m m _
cl cl
a U
2 .N 3
a
c J
Q
U
w
U
cn
Q1
V
7
y N
N >
C )
� Y
a
0 CO
LO
QOj LO 7
I Y
C N a-
� z
0
U Q) J
Q CJ
� a
O
Cl) —
O
00
d f) Q)
0
a
a .V.
E m
m Co
U
a
D
Q
O
O
U
O m C.jR
N CO
6
Q Q)
0- >,
E o co
i/) U Q
v
O
O
lf7
M
0
�
N
own
�
O
c6
0-

0
E
J
d
M f- ry
'o 00
co LO
to
r)
M IL
Z
Ir
z
C �
Cn
V a
m
IN
m
O
O
O
2
a
LO
co
O
ti
N
Q)
ca
d

m
a
E
J
Im
n 00
to Im
M � a
o zo z
c �
in
75
O _
N
O E
� J
� L
_D
N =
cl cl
a U E
E .N 3
a >
c J
Q
U
w
Y
C1
E 75
N >
C D
� Y
a
t5 Cl)
� � N
7
a O (6
w 01 >
y y a
U
70 Z
0
U (D J
U H a
(D a
n
J M N
N
a
a .V.
E m
m 00
U
00
00
M_
m Cl)
� a
Q Q)
fl- � T
E o m
Con a
O
Ut
N
cl
z
m
a
E
J
O a-
i 0000
co Im
M LO
to d
zo zo
c �
[If in
75
O _
N
O E
� J
� L
_D
N N =
cl cl
a U E
E .N 3
a >•
c J
Q
U
w
Y
tm
E 75
N >
C (D
� Y
a
R Cl)
� � N
7
a O (6
w 01 >
y y a
U
70 Z
0
U (D J
H CJ
00
n ..
0
Cl) Cl) N
J �
a
a .V.
E m
m 00
U
00
M_
U co
J J
47 N
E o m
i/) U Q
00
O
O
Ut
rn
O
O
O
N
N
O
Ut
N
O
O
O
N
m
a
E
J
a-
n 00
to Im
M t a
zo zo
C 0-
� (n
75
O _
N
O E
J
� L
_D
N N =
(6 ( _
cl cl
a U E
2 .N 3
a >
c J
Q
U
w
Y
C1
E 75
N >
C )
� Y
a
t5 Cl)
Q)
7
a O (6
w G1 >
y y a
U
Z
0
U Q) J
Q CJ
n ..
0
W N
M_ Q)
of
a
a .V.
E m
m Co
U
CO
Q
O
O
U O1
01 0
O V
R
N m
6
Q) L
E o m
i/) U Q
O
O
N
N
O
Ut
N
O
N
O
N
m
a
E
J
N 0
n 00
to Im
M � a
zo zo
c �
in
75
O _
N
O E
� J
� L
_D
N � _
(6 (6 _
cl cl
a U) E
E .N 3
a >
c J
Q
U
w
Y
C1
E 75
N >
C D
� Y
a
t5 Cl)
� � N
7
a O (6
w 01 >
Cl) CO a
U
70 Z
0
U (D J
H CJ
00
n ..
0 Cl)_ N
N
a
a .V.
E m
m Co
U
0
CO
Q
O
O
U O1
01 0
O V
R
N m
b
Q) L
E o co
i/) U Q
O
cam
cam
00
V
O
N
O
N
O
N
O
O
v
co
rn
O
O
O
N
N
O
Ut
N
O
N
K
0
U
co
CO
M
0
co
�
N
own
�
c6
O
0-

M
.-I
u
Fi
U
F�
Z3
0
E
N r)
co ry
co d
t0 m
co to
to
r)
M d
Z
rK
z
ry
ry
0
N
O _
N
O E
J
� L
2)
N N =
C6 ) _
Q N E
Q) 'N J
d T
� J
Q
U
LU
0
r
co
� M �
N
a
Q U
E ca
(6 CO
0
N
Q
0
� U
Ci
N R
N CO
Q �
E _o m
cn U Q
LO
co
0
rn
N
Q)
ca
d

75
a
E
J
Im
a
n Cl)�
M � a
o o z z
c �
in
n
75
O _
N
O E
� J
� L
_D
N =
cl cl
a U E
E .N 3
a
c J
Q
U
u1
Y
C1
E 75
N >
C D
� Y
a
N Cl)
�a co
� 7
cU CO a-
zo
0
U (D J
U H a
(D a
01
n
J M N
N
a
a .V.
E m
m 00
U
0
V
0
cl
z
0. ri
it
0
a
m
(D
�+
L" Qj
Q)
C
N
C
Co
C
co
75
a
E
J
L
n rn a
0�
to Im
M LO
to d
zo zo
c �
[If in
n
75
O _
N
O E
� J
� L
_D
N N =
(6 ( _
cl cl
a U E
E .N 3
a '•
c J
Q
U
u1
Y
C1
E 75
N >
C D
� Y
a
N Cl)
�Q co
� 7
cU CO a-
-0 zo
0
U (D J
H CJ
01
n ..
00 U)
M_ N
a
a .V.
E m
m 00
U
CO
Q
O
O
Q1 U
am U,
o �
R
N m
4) c N
E o co
i/ U Q
m
00
0
O
O
O
O
rn
V
0
co
U')
O
75
a
E
J
to 0
n rn a-
M t a
zo zo
c 0-
� (n
N
O _
N
O E
J
� L
_D
N N 2
cl cl
a U E
2 .N 3
a
c J
Q
U
u1
Y
C1
E 75
N >
C )
� Y
a
N Cl)
a) >
cU cA a-
zo
0
U Q) J
Q CJ
am
n
00
Cl)
0 Q)
a
a .V.
E m
m Co
U
0
CO
Q
O
O
U O1
rn d
o �
R
N m
E o m
i/) U Q
0
co
O
O
O
00
V
0
co
O
O
75
a
E
J
O �
n rn
to Im
M t a
zo zo
c �
in
N
O _
N
O E
� J
� L
_D
N � _
(6 (6 _
cl cl
a U) E
E .N 3
a '•
c J
Q
U
u1
Y
C1
E 75
N >
C D
� Y
a
N C/)
a co
� � 7
U N Y
a
70 zo
0
U � J
H CJ
00
01
n ..
0
Cl) Cl) N
J �
N
a
a .V.
E m
m 00
U
00
O
00
0
O
CO
CO
t
U
co
J
J
co
0�
of
Q)
Q
Q
m
E
Q)
c
co
>,
Co
Q)
co
co
>1
U
cn
U
Q
U
M
0
0
� m
O co
0-

75
a
E
J
O �
LO a
n rn 0�
to Im
M � a
o o z z
c �
in
n
75
O _
N
O E
� J
� L
_D
N =
cl cl
a U E
E .N 3
a
c J
Q
U
w
Y
C1
E 75
N >
C D
� Y
a
N Cl)
�a co
� 7
cU CO a-
Z
0
U (D J
U H a
(D a
CO
CO CO
J J
Q Q)
0- >,
E o m
it U Q
75
a
E
J
Cl)
LO a
n rn 0�
to Im
M � a
o o z z
c �
in
n
75
O _
N
O E
� J
� L
_D
N � _
cl cl
a U E
E .N 3
a
c J
Q
U
w
Y
C1
E 75
N >
C D
� Y
a
N Cl)
�Q co
� 7
cU CO a-
-0 Z
0
U (D J
H CJ
x U
t �
J 10
� m
Q Q)
E o m
i/) U Q
O
6
rn
O
O

kr,
N
00
00
M
A
U
:C
m
a
E
J
M a
N
M CO
� SO to
M a
o o z z
c zT
in
n
75
a
� J
� L
U ib _
cl cl
a U
E .N 3
a >
c J
Q
U
w
J
a)
E 75
N >
C D
� Y
a
U U
CO N
d CM (6
00 >
U �: Y
H N a-
� z
0
U � J
Cn
N
00
J M N
a
a .U.
E m
m Co
U
O
C6
rn
O
O
O
s
cl cl O
Z z rn
O
0 6
V cl)V
N N
m
a
E
J
N r-)
LO a
N M
M 00 m
00 to
CO
f") a
zo zo
c �
in
n
75
a
� J
� L
_2)
co (6 _
0 cl
a U) E
2 .N 3
a >•
c J
Q
U
w
J
a)
E 75
N >
C
� Y
a
U U
Ct? N =5
d M 75
00 >
U �: Y
H N a-
0 z
0
U J
Cn
N
00
00
M U)
J �
0)
a
a .U.
E m
m Co
CO
U
U co
CO CO
J J
0) cl 0)
0- >,
E o —co
i/ U Q
m
rn 00 00
M
0
N
own �
O c6
0-

Q
. itvsl
�
r.
a u;ynay sv �°ex�d �07 I�dS =�InO MQ ,aff
8
U
—
G
L
x
❑
y
Y
1V�
Fs
.S
a
O
C
El
U
2.1
dilo-_L oif5euAS
Bid IttB y ,ad s�ameah0� �8 1�[JlO R�
(�ma.moa al JCynods} taglw ($ •ruo° {L �YQ'3 t9 �fld■or
�
E
'��.
Y
Y
is tua�uv aura (n :nx ra=rnsrrr rx �catim [� :°�a•a
[�
�
�
,ueM�hl�Hd-.MO x+f�M�l9�"d�°A:maea�a
$
}'
�dmxg ayrod�ifGYj
�
a
4
.p
aEdusrggs,e�
�
� `$
a
�
E
°
G _
a
� w
—
ct
�-
e
�
w
Ix
�
x
_
8
is
a o
x
LL
wnuv�
Z yCy
}C
iA
m
a
pp S
e
�
e
3 s
a
0
a�
0)
ca
0-
Page 33 of 35

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMENTAL TECHNOLOQH�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List
Arrafocaf Laboralorias TEL: [phone] FAX.- [phone]
Website: http://`h,,",m,.settek.coin
Client Name: SYN-NC-27028 Work Order Number: 22010196 RcptNo: 1
Logged by: 1/5/2022 12:50:00 PM
Completed By: Christina N. Jager 1/6/2022 1:44:53 PMdrx
Reviewed By: Jennifer Woolf 1/6/2022 2:53:02 PM
Chain of Custody
1. Is Chain of Custody complete? Yes ❑ No ❑d Not Present ❑
2. How was the sample delivered? FedEx
Lop In
3. Coolers are present? Yes ❑d No ❑ NA ❑
4. Shipping container/cooler in good condition?
Yes
d❑
No
❑
Custody seals intact on shipping container/cooler?
Yes
❑
No
❑
Not Present V
No. Seal Date:
Signed By:
5. Was an attempt made to cool the samples?
Yes
❑d
No
❑
NA ❑
6. Were all samples received at a temperature of >0° C to 6.0°C
Yes
❑d
No
❑
NA ❑
7. Sample(s) in proper container(s)?
Yes
❑d
No
❑
8. Sufficient sample volume for indicated test(s)?
Yes
❑d
No
❑
9. Are samples (except VOA and ONG) properly preserved?
Yes
❑d
No
❑
10. Was preservative added to bottles?
Yes
❑
No
❑d
NA ❑
11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm?
Yes
❑
No
❑ No VOA Vials ❑�
12. Were any sample containers received broken?
Yes
❑
No
❑d
13. Does paperwork match bottle labels?
Yes
No
❑
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody?
Yes
❑d
No
❑
15. Is it clear what analyses were requested?
Yes
❑d
No
❑
16. Were all holding times able to be met?
Yes
No
❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17. Was client notified of all discrepancies with this order?
Yes
❑
No
❑ NA V
Person Notified: Date:
By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
18. Additional remarks:
1/4/22 per email
Received by Tegan Richards
sample date 1/4/21 on coc
Page 34 of 35

summly Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHHQL4Ga1�23.INC Cuyahoga Falls, Ohio44223
�trrafyt�caf iaboralorJas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
Client Name: SYN-NC-27028
Cooler Information
Work Order Number: 22010196
Sample Log -In Check List
Cooler No
Temp °C
Condition
I Seal Intact
Seal No
Seal Date
Signed By
1
14.0
Goodl
Not Present
RcptNo: 1
Page 35 of 35

SECTION 5

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Newton WQ Permit Number: WQ 0003902
WWTP Name: Newton Clark Creek WWTP NPDES Number: NC 0036196
Monitoring Period: From 01/01/22 To 3/31/22
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1 /A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens x
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization X Air Drying Composting Aerobic Digestion
Anaerobic Digestion
If annli—hl. to —f--] A — Cl... R1 --l.+. +hf-11-4— --+-- A-+-.
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
deuces
Analysis
Fecal
2x 10 to the 6t'
MPN
MPN/g
Coliforin
power per gram
of total solids
CFU
CFU/g
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliforin)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1 107) - Please indicate option/alternative performed:
Option/Alt. I
Option/Alt. 2
Option/Alt. 3 Option/Alt, 4
(VS reduction)
(40-day bench)
(3 0-day bench) (Spec. 02 uptake)
Option/Alt, 5
Option/Alt. 6
Option/Alt. 7 Option/Alt. 8
(14-Day Aerobic)
(Alk Stabilization) x
(Drying — Stable) (Drying — Unstable)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T. 1106 and the vector attraction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T. 1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T. 1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T. 1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to deterri-iine that the pathogen and vector attraction reduction requirements have
been met. I am aware that there are significant penalties for false certification including fine and imprisonment."
James Wentz PWU Director
Preparer Name and Title ( type or print)
02/15/2023
Land Applier Name and Title (if applicable) (type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T. 1102 (26)

>1 , ,
co
ai
co
Ln
a) Ln
C14
<
v CD
C,
E rq
CD
OL
w
E
D
0
Qj
7K
'Y
0 zz�-
77
tx� -�L
co
C)
Ln
C:)
co V)
A, 'F—
co
fu (3j
Qj
CL
E
CL CL c:
4-J V) CL
E q7 5-
<
C)
t)n a)
b�
CL
0
u
--
Iri I
C'4
(2
e4
N.
0
E vo
Lor)
co
bib Ub
Z- Z-
0 0 0
E w
�7- O'D
IN
71
1� 0
>. Ln
a)
(U
ru
tx
Ln
ra fl;
u
z,
F4 N
j 0 0
ci .>
\V) -a -a t:
E E E
eN
0 m ro ro
E
cc
—0
tj U U cn
Li S2 u u L" Li u
YLju5uuuuuu'UU"ukl
u u
LU
!!! LA q--Fr�-
r%
Ln

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Newton WQ Permit Number: WQ 0003902
WWTP Name: Newton Clark Creek WWTP NPDES Number: NC 0036196
Monitoring Period: From 04/01/22 To 6/30/2022
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1 106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1 /A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens x
It applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization X Air Drying _ Composting _ Aerobic Digestion
Anaerobic Digestion
If annficable fn n1fPrnnflvP nprfarmpd (Class A nr Clqvv R1 rnmnlpfa fht fallawinff ma—f—Ina data-
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dences
Analysis
Fecal
2x 10 to the 6111
MPN
MPN/g
Coliform
power per gram
of total solids
CFU
CFU/g
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed:
Option/Alt. I
Option/Alt. 2
Option/Alt. 3 Option/Alt. 4
(VS reduction)
(40-day bench)
(30-day bench) (Spec. 02 uptake)
Option/Alt. 5
Option/Alt. 6
Option/Alt. 7 Option/Alt. 8
(14-Day Aerobic)
(Alk Stabilization) x
(Drying — Stable) (Drying — Unstable)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T. 1106 and the vector attraction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15MAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
1:
been met. I am aware that there are significant penalties for false certification including fine and imprisonment."
James Wentz PWU Director
Preparer Name and Title ( type or print)
— 1--: �- - - I- - 02/15/2023
Land Applier Name and Title (if applicable) (type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T. 1102 (26)

>1 , ,
co
ai
co
Ln
a) Ln
C14
<
v CD
C,
E rq
CD
OL
w
E
D
0
Qj
7K
'Y
0 zz�-
77
tx� -�L
co
C)
Ln
C:)
co V)
A, 'F—
co
fu (3j
Qj
CL
E
CL CL c:
4-J V) CL
E q7 5-
<
C)
t)n a)
b�
CL
0
u
--
Iri I
C'4
(2
e4
N.
0
E vo
Lor)
co
bib Ub
Z- Z-
0 0 0
E w
�7- O'D
IN
71
1� 0
>. Ln
a)
(U
ru
tx
Ln
ra fl;
u
z,
F4 N
j 0 0
ci .>
\V) -a -a t:
E E E
eN
0 m ro ro
E
cc
—0
tj U U cn
Li S2 u u L" Li u
YLju5uuuuuu'UU"ukl
u u
LU
!!! LA q--Fr�-
r%
Ln

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Newton WQ Permit Number: WQ 0003902
WWTP Name: Newton Clark Creek WWTP NPDES Number: NC 0036196
Monitoring Period: From 07/01/22 To 9/30/2022
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt, l/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens x
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization X Air Drying Composting Aerobic Digestion
Anaerobic Digestion
If annlirahle to alternative nrrfnrmM Wince A nr f lace Rl rmm�lnto thr fnlln..�inn mnn;tnr;,,n A�t�.
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
deuces
Analysis
Fecal
2x10to the 61h
MPN
MPN/g
Coliform
power per gram
of total solids
CFU
CFU/g
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed:
Option/Alt. I
Option/Alt. 2
Option/Alt. 3 Option/Alt. 4
(VS reduction)
(40-day bench)
(30-day bench) (Spec. 02 uptake)
Option/Alt. 5
Option/Alt. 6
9ption/A1t. 7 Option/Alt. 8
(14-Day Aerobic)
(Alk Stabilization) x
(Drying — Stable) (Drying — Unstable)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
cen met. I am aware that there are significant penalties for false certification including fine and imprisonment."
James Wentz PWU Director
Preparer Name and Title ( tvpe or print)
02/15/2023
Signature of Preparer*
Land Applier Name and Title (if applicable) (type or print)
Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and I5A NCAC 2T.1102 (26)

>1 , ,
co
ai
co
Ln
a) Ln
C14
<
v CD
C,
E rq
CD
OL
w
E
D
0
Qj
7K
'Y
0 zz�-
77
tx� -�L
co
C)
Ln
C:)
co V)
A, 'F—
co
fu (3j
Qj
CL
E
CL CL c:
4-J V) CL
E q7 5-
<
C)
t)n a)
b�
CL
0
u
--
Iri I
C'4
(2
e4
N.
0
E vo
Lor)
co
bib Ub
Z- Z-
0 0 0
E w
�7- O'D
IN
71
1� 0
>. Ln
a)
(U
ru
tx
Ln
ra fl;
u
z,
F4 N
j 0 0
ci .>
\V) -a -a t:
E E E
eN
0 m ro ro
E
cc
—0
tj U U cn
Li S2 u u L" Li u
YLju5uuuuuu'UU"ukl
u u
LU
!!! LA q--Fr�-
r%
Ln

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Newton WQ Permit Number:
WWTP Name: Newton Clark Creek WWTP NPDES Number:
Monitoring Period: From 10/01/22 To 12/31/2022
WQ 0003902
NC 0036196
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1 106) - Please indicate level achieved and alternative performed:
Class A:
Alt. l/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma, Ray Pasteurization
Class B:
Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens X
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization X Air Drying _ composting — Aerobic Digestion
Anaerobic Digestion
If annfivAlp fn n1fPrnntivPnPrfhrmPd U"Ince A — Cl... R1 the fnllnwinn —4—.. A .+a -
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dences
Analysis
Fecal
2xI 0 to the 61
MPN
MPN/g
Coliforin
power per grain
of total solids
CFU
CFU/g
1000 MPN per grain of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed:
Option/Alt. I
Option/Alt. 2
Option/Alt. 3 Option/Alt. 4
(VS reduction)
(40-day bench)
(30-day bench) (Spec. 02 uptake)
Option/Alt, 5
Option/Alt. 6
Option/Alt. 7 Option/Alt. 8
(14-Day Aerobic)
(Alk Stabilization) x
(Drying — Stable) (Drying — Unstable)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 5 03.3 2/15A NCAC 02T. 1106 and the vector attraction
X reduction requirement in 40 CFR 5 03.33/15A NCAC 02T. 1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 5 03.3 2/1 5A NCAC 02T. 1106 and the vector attraction
reduction requirement in 40 CFR 503.3 3/15A NCAC 02T. 1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
been met. I am aware that there are significant penalties for false certification including fine and imprisonment."
James Wentz PWU Director
Preparer Name and Title ( type or print)
02/15/2023
Signature of Preparer*
Land Applier Name and Title (if applicable) (type or print)
Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1 102 (26)

>1 , ,
co
ai
co
Ln
a) Ln
C14
<
v CD
C,
E rq
CD
OL
w
E
D
0
Qj
7K
'Y
0 zz�-
77
tx� -�L
co
C)
Ln
C:)
co V)
A, 'F—
co
fu (3j
Qj
CL
E
CL CL c:
4-J V) CL
E q7 5-
<
C)
t)n a)
b�
CL
0
u
--
Iri I
C'4
(2
e4
N.
0
E vo
Lor)
co
bib Ub
Z- Z-
0 0 0
E w
�7- O'D
IN
71
1� 0
>. Ln
a)
(U
ru
tx
Ln
ra fl;
u
z,
F4 N
j 0 0
ci .>
\V) -a -a t:
E E E
eN
0 m ro ro
E
cc
—0
tj U U cn
Li S2 u u L" Li u
YLju5uuuuuu'UU"ukl
u u
LU
!!! LA q--Fr�-
r%
Ln

SECTION 6

Agricultural Lime Application Log
Year: 2022
Project: Newton
Field
Soil
Lime Requirement
Tons/Acre
Date Applied
(state -county -site -field)
pH
(from soil analysis)
Applied(CCE Eq.)
CA-20-9
6.5
O.OT/Ac.
CA-20-3
5.8
O.OT/Ac.
CA-25-2
6.3
0.0 T/AC
CA-21-2
6.4
O.OT/Ac.
CA-20-12
5.6
O.OT/Ac.
CA-20-13
5.6
O.OT/Ac.
CA-32-1
7.1
O.OT/Ac.
CA-32-2
7.3
O.OT/Ac.
LT-119-5
6.9
O.OT/Ac.
They get their lime in the sludge since Newton is Lime stabalized.

SECTION 7

O
Cl)
CD M
N
}
LL
00
N
U
C)f z
a) 6'
x 0 a,= o
0 0 > Ln
co
C
O
0 — r r
CC
O O O
- z zi
Z
O
z
—
cn
a
cn
W
C O O
O
CN
y r r
CO M
E
O O O
z z
Z
0
z
cn
cn
a
cn
W
Z
x N COV
co 0 0
co 0 0
O
C
Q U) N 0
R CD
fC N
C.
—
Z O
Z O
N
i
0 O
Mn
>
V CD CD—
V CD 0
Q
7 M
7 M
Q
U
U N
N o o
o
N CD CD0000
ch
N
N
m
m
N
N
cu
C o o
c o
C==
c 000
N
Q- a
N M
�
N
N
cu
U
to
R N
�j
to
R N
L00
O
U Q co
U Q 00
co
0 v) O O
— r rn
0 v) o o
—_r
m � �
w O U O Ln
c
a�
c
a�cn
O
z U �
� LO
z �Oo
rn
z �Oo
00
co
0
0
o
E
m a� m
tm
cn z cn
o
—
0
C C
D O O
M
0 O O
C LO
tm
Y rn rn
Y
tm
U U
R
V
—
cn co
— N
cn Ln
C
0 O O
N N
0
0 CD
3
o
N
a
o
N
a
o
O
Q
M� Cal N
C
M Cal r-
C
}
U U
(B
CD CD
O O
CD CDto
O O
=
j
L
x
N N
Z CD
01 L
o
N N
Z O
cm 0
E
>
R
W 'L
CD
c U
O
U
ce)
I
z
z
N
M
M
U CD
i
Z — (
i
Z — 00
N
d 0 M CDY
N
y 0 0 CDY
W)
N CD
E Noo
Noo
N
Ln
J C
U
J C
U
CD
O
(0
a m
C N
o f
E E
E
E E
E
U
t/! '� '�
C = 00
t/! '� '�
C =
C
O O
O M M
Z C. Ln
O N M
Z
C
R C� C�
C
a
Q. CDc
00
R
c 00
R
m a� a�
E
U 0 cy
W Q
0 a) a)
E
U q 0
W Q O
N O
= Ln
U U
ECL
U
U U
E
U
% O O
a)
O 0 LL LL
U Q
ME
O 0
U Q
ME
O
V ■� y
U N
V N
tm
U N
V 0) O
O)
Mn
_ >
O J W
00
C m
C m
0
L
�?r
_ a
9 L)
U 00
O
N
N
W
r U
W M
r U
C
;ti x5k'k l, CD
N
ry;
co
C
O
C
Q
k
y�.
U
O
I-
N
O
N
to
to
0
p'�
y C
y
TI51N57.
CD
z
V1
cn J
H
cn J
H
N0
C �
w C
E
O
� U
N �
LL
(on 2
H
O
O U
Q U
N �
CO 0
N �
Y O
m �
� U
m
`o
E z
N N
CO
0 E
O
N w
E
N �p
N O
c �
E �
E o
c M
O o
o

C)
M
CD M
c�
N
}
LL
Cl)
O
N
d
C
O O
i= N N
O M
E N N
O O O
C Z Z
Z
M
Z
—
fA
cn
a
fA
W
C
y 0
i= N N
O M
E N N
O O O
C Z Z
Z
A
Z
cn
cn
a
I fA N
W
O
Z
m o O
m o O
i
O
C.
R
Z O
R
Z O
N
VCD CD
CD CD-
o
-
Ln
U N
U
N CD CDQ
rn
N CD o
Q
C `�
C 00
N
N
m
m
N
N
�O O
c —
c Lo
�O o
c —
c 00
N
N
N
N
U
N
R N
U
N
R N
U Q °°
U Q N
fA CD CD—
C
(/� C) C)—
C M
N
—
cn
N
—
c
OZ
7
CD CDZ
Q 00
4:5
CD CDM
Q N
C
O
O1
C Ln
N
O
CD
Ln
O
�
0 0
Y
CD O
Y
tm
m—
co
fA
— co
fA co
C
O O C)O
0 0
N Ln Ln
a
N COCO
a
3
o
o
ME N
Cl)
ME N
�=
N
O CD
CD CD
CDCD O
CDO
-a
=
j
N N
Z O O
01 o
E
N N
Z O O
tm 0
E 'o
>
m
c U
�
U
Z
Z
M
O -
Z Y M
M
O co
Z Y 00
i°Noo
ENoo
E
N
J C
C)
J C
U
y
O
0
O
M
M
—
O a1
d M
—
O
E
E
v
C
C
N
to in in
2 co
v! � �
u� u�
= co
M C Ln
C
O �p �p
Z
O �p �p
Z
R (D (D
R U'(
a
O O
R
c O O
R
N N N
U U I-_
N N N
U U
E ��
W Q
E L L
w Q
E co co
U
E co co
U
O C. O O
O LL �
ME
O C. O O
O �` �`
"
ME
CO
U N
V 07
U N
V (O
Mn
O) m I�
O) m I�
C
C
0
2
U rn
U
E
O
r U
r U LU Ln
C
O
i
w
CO
C
N
C
tm
'—
'--' > N
> (o
O
CD
U
N
to
N
N
Q
E
Q =
w o (o
Q =
N .1 N
o
o
U
E
y= o
E
N= o
Z
tC
fA J
d
H
R
fA J
d
H

O
co
co
O
(n
N
LL
o
co
0 w
co
a)
y
C
i
QN
i
O
N
w
(n
C
O _ E _
N C 0 Q Q
U E a) a) O O
y U U U co
Q N co
O O
U mE E 0 X
>, >, O- M >, X X — a)
a) a)
U U N y : N N co N a)
a� a� a) (onE N m m X )
cUi cUi N a) a)T
w co O ON -
O O X O N N O .—C
O) - jC�L6 N Nc
C 0 U N " �ymWWCM w0)M 0 �Q Q C
o X
0 CO CO X
66UO 6O_ OO U w.�Q U 'OX O O2)� ziOO o E E E E C co CO U a EL (n coN a) o aQ Q Q
N—
U
C
N Z
o e \ Q Q
Z Q M — >
CCC CaO CC
U U UW`1 ZZ Z O . d d 0) 0)Q
N N
C
O m
U) (B
U)
(B N
a) Q
N o
�_
m
O O
0
OU�
OLi
N (B a-C
U) :5
y p o N
7 "O Lo Lo a)
U
i
C
U
(B O
E
~
y C_
Q
p a) p=
C a) n p
C
C
CD
may) p p 7
-O L a) �. i
4
�j
0+
p
C
U Zi OY
� a) y
N C N �
O (B U)
N
=
O y
(B r)CY
O �\
I
E a+
_
C i
Z>
O
O
C Lo O
E
a) a) O
.y
a) --I:- CY
> O a)
E U 'N
0 C y a)
O C
M U)
a) O
y
O
O
E
a) (n m
O U
R
N m
-p M C Q
vi
. C a)
O
ch O
) a
O
C L
a) 0 0
a) O U)
y E U
CD
Q
O W
O)
C
N Lo a)
U) E .Z'
a) L
N
-Q
C
m
7
i—
L U
i —
O
E
— Z
O O
E
U y U)
N m N
N a)
E
O
U) i
(4
a
. >,
Lo
cn
3
c
rz U) m
Lo o a) M
E 73
o c E
a—
y
> U)=
�_ U)o
cA U)
N
d
V a0 E�
"O
.O "O
N
(6
U C
a O p y—
Q E N M
C co m
m
z N
a)
m
O CO C .E
N N a)
o O
fA
C
Q Q N
(I
o Q N
N a)
rz
a
is
N N
C
(B O L O
in (B a) N
(B z
a
E
(B
T a)
a) 0_
_
a) Z �
_ _
O
M
p
QU N
C E
Mv�i
U) Q
co mU)U)
(U o 0
3
'� a)
—
d
C E Q M
; Q
> N U
O
ry�� C
—
O L
C O E
Q (n
a)
O
U L
[�
Q c c)
Y> a) N
p i .�
C
L
a) O
W
O
O N C C
L X O
a C +y CD p
(o a) E
C O m
o z
,�
LL
a)
U Q O
L
O
n} `)
E w a)
w� w
�
> o
o
a)
L E
w E .o a) �
O U D
o
i C
'
O L
>
>
a
C
Q
a)
L L O—
O
yt. U U) (�
O m
N
L
a) a) .O
( L
V
y
_- C
O a)
O C C
x
N
2� N 2� U)m
C:
O a) Q O
"O L
y
M
a)
_
a)
N
O
N
N
lN
CD
p�
Q O
m
m
n
� (B
CQ
C
O
O
O U
m a)_
My
Mn
Q a) E
'y0—�
E U) t
C
L D
p M y
Q
o
p C N u� C
(1) m
y
a)
w U a)
cn
o�� o
o
o -0-0�o
m a)
- aa))
C
,
Cl a) C7
O .0 C
m U O
o
N U
> d U_
_
C
(4
U) a)
"�
0 U)_
(B () a) U)
"C
O Q O O
"C
M—
"C
C
n
a) u O
Q
0
LO
N Q O C Q
U"
N
> C
(B
od
L
E
O a) O
E a) U U C
L p o 0
O
E
(B a)
a)
C
E
( O
— U Q .N
a)
OI
L O O O
C N>
N
X L
a) >
(B
U
m
N L
E C o E a)
a) L °� C C
n3 o a) U
a)
a) n3
y
y
a) (B
E>
Z
J .O LL — .N LL
m m 0
LL C C C
E
H
F— N M

a
\
»
/
co>-7z
z
20a
o a
E a
z
0
z
cn
k
IL
w^
z
=o
k
J
§
Mn
0
��
>
>
$
«
u
NC CD
#
_
N00
2
N
3
/
2�
F
/
\
/
§
m
eq
C14
`
cn C)
\
C
7
\\
\
m
�
_
k§
e 0>
2 7
/�
2
/ 2 2
±r
2
�
It
\ \
E
\
/
§
_
g
2
00
)
%
u
u
/
c
\
t
R o
§
E
\
'
\
�
u
/
2
E
2
tm
EM
2
/
,
u
/
n
z
/CD
0
\
.qoo
k
CD
§
\
2
k
>
t
/
0
6
C
6
\
§
C
E
§
)
\
z
_
&
_
2
)
C
G
\
0
CD
�
W
0
\
u
«
9
)
/
E
¥
q
$
o0\
.2
m§
7
r
3
�
Cl)
CL
7
u
L
0
` �`
0
©
C
a
2
}
^
>
o
k
w
a
a
_
u
.
k
©
E
7
=CD
9
z
¥_y«
2
m
z
w
f

N
0')
O
(n
co
N
LL
pm
0
C
N
N
0
N
a)
y
C
y
fC
N
i
QN
i
o
N
y
C E
O _ _
Q Q
U E O a) O O
y U U U co
N co
O O
U N E U X
>, >, CL >, X X — a)
a) a)
N N 0) y N a) N U O O
m cUi cUi N C) a) N co O — y X
O O O X O O w N N O = O N- O .— O)
C 0 U N � C �y L 0 (6 N>> N" a) E N .0 � L L .c O Q- j
m W W CO Q M U (CO CO 6 (6 (LU O 0) (6 (6 0 O Z_ a) O Q Q �p X
U `..' `..' Q U `..' c c 'O O O w .— C 'O
X O O o N O X a) 0 0 O N C C N ++ O- 2)� L L zi O
a) o o U U a) Q Q Q o C y C O U Q Q y y N—
U
C
N Z
o e \ Q Q
m W 7 fA 1 al Z C C C C Q M O — Q
U fA CC
Q M M U U U W 2 `1 `1 2 2 2 2 2 2 Z Z Z O C. d d 0) 0) �i N N
C
O
y >,.— U) (B
(B N
a) Q
Q
N 0
�_
m
O O
0
O UL
OL i
N (B a-C
U) :5
y O o N
7 "O Lo Lo a)
U
i
i
U
(B O
~
y C_
Q
p O p=
C a) n p
4C:
p
CD
U) p p 7
-O L a) �. i
�j
�,
C
U Zi OY
(B r)CY
a) y
�
a) C)-0 N U
O (B U)
N
=
O y
O ff\
E
U)a)
I
co
a+
0_
C i
Z>
o
o
C Lo O
E
a) a) O
.y
a) --I:-
> O a)
U 'N
0 C U)a)
`� M U)
U)O
O
a) (n m
N m
O
-p M C Q
y a) O
. C a)
O
ch O
O U
) a
o
L
a) 0 0
a) a) U)
y E U
w C
QQ
O W
O)
C
a)
-0 U) E Z
L
yr N
-0
Q
C
m mO
fC
7
N
i— ay+
O 0Lo
L U
i —
— Z
O O
U y U)
N m
O
U) i
(�
O
a
.N >,
i
(A
3
C
rz U) m U
O O O N M
E 73
O
a—
y
C L
> U)=
V U U)N
O
(n U)
d
CO
Va
�
(mN
U C
p
N
M
m
m
N
zO
a)
m
O CO C .�
N N � N
0
o� O
415
r
o Q N
N a)
rz
a
is
N N
C
N L
N (B a) N
(B z
a
(B
a) 0_
+� a) -0
_
a) Z> U) t
i O
p
U C
Q N
M
N Q
m U) U)
w 0 0
3
'� a)
—
�Q
d
C Q
; C: mO
Q
>, N U
O
ry��
co a)
C
—c
L
0-
OE
LL
,-
M
a)YN OL
LUU>U
O
O N
CD p
O m
LL
Oo
Q
XO
)
w aw�
zwO
-
>
o
a
o a-0
O U D
ow
L C
=
O L
>
a
Q
a)
'U
O
U)m
O N
a) a) .O
� L
_V
w
�
_' C
O N
O C L
N
N U) m
C:
O 0
Q
73 L
-0N
M
a)
O N
lN
p�
Q O
m
m
CCx
n �
C
O
O
O U
m a)_
MN fl-Q
0
U)
73
Q
Q E
N
U)
DM
p M
o
N
a) m
y
w U
ay)�
o
o -0-0
om
a)o
aa))o�
Y
Or
(B O 'N
C L 0) a) U p
aa)) OL N
O
a)
M
Eo a)(�
0 0.—-
� m Uo
o
N U
>a U_
C
0 U)OU) U) a)�i
Q O O
M
_
—
aL)
O -0
O
QO U
O
r
>
U
O
.p
C Ofn a) a)
UL
�
B
a)
Q
n
x
N
OO
B a)oi
d
N Q N
a)I M N
aO p
pU C N>
N
x LC
a) >
y
U
C
()
L
E_ O a)
a) m L C C
m O a) U
a)
a) M
y
a) (B
L >
Z
0 LL — .N LL
Q' �o (B (B 0
LL c
Q'
E E
H
H M

o
\
»
/
co
y
z
2 0
o # r
E a
-
7z
z
3
z
cn
k
w
z
co CD
k
J
§
Mn
0
CD
L)
J
k
«
-
k
r
3
N�
S
N
_
_
2
22
\
/
N
F
/
\
/
§
m
04
-
`
cn CD
\
C
7
\\
\
m
¥
_
/ƒ\
/
�t
�o
}
\ƒ\
�
It\
E\
\/
§
\
0
C
C
0=
R
§
§
/
cn
2
t
a
ko
\
§
\
m
®
\
/
E
� �
E
M
2
,
u
7
n
z
/
j
2
a
.uoo
z
k
CD
§
\
2
k
§
-
Cl)
p
2
k0.
C
§
a)§
0
F
§
z
k
/
\
$
2C
G
\
m
/
/
]
�
}
@
)
/
E
u
$
00\
f
0
f
J
u \
t
2
2
f
3
6
2
C
¥
CL
w
L
/
0
^}
C
tm «
2
a
>
a
k
2
z
2
m
w
f

O
0')
O
(n
co
N
LL
pm
0
C
N
N
0
N
a)
O
y
C
y
fC
N
i
QN
i
o
N
y
C E
O _ _
Q Q
U E O a) O O
y U O U U co
N co
O O
U N E U X
>, >, CL >, X X — a)
a) a)
N N 0) y N a) N U O O
m cUi cUi N C) a) O O O — y X
O O O X a) O w N N O = `o m- u�6i a) .—
O O
C 0 U N � C �y L 0 (6 N>> N" a) E N .0 � L L .c O Q- j
m W W CO Q M U (CO CO 6 (6 (LU O 0) (6 (6 0 O Z_ a) O Q Q �p X
U `..' `..' Q U `..' c c 'O O O w .— C 'O
X O O o N O X a) 0 0 O N C C N ++ O- 2)� L L zi O
a) o o U U a) Q Q Q o C y C O U Q Q y y N—
U
C
N Z
o e \ Q Q
m W 7 fA 1 al Z C C C C Q M O — Q
U fA CC
Q M M U U U W 2 `1 `1 2 2 2 2 2 2 Z Z Z O C. d d 0) 0) �i N N
C
O
y >,.— U) (B
(B N
a) Q
Q
N 0
�_
m
O O
0
O UL
OL i
N (B a-C
U) :5
y O o N
7 "O Lo Lo a)
U
i
i
U
(B O
~
y C_
Q
p O p=
C a) n p
4C:
p
CD
U) p p 7
-O L a) �. i
�j
�,
C
U Zi OY
(B r)CY
a) y
�
a) C)-0 N U
O (B U)
N
=
O y
O ff\
E
U)a)
I
co
a+
0_
C i
Z>
o
o
C Lo O
E
a) a) O
.y
a) --I:-
> O a)
U 'N
0 C U)a)
`� M U)
U)O
O
a) (n m
N m
O
-p M C Q
y a) O
. C a)
O
ch O
O U
) a
o
L
a) 0 0
a) a) U)
y E U
w C
QQ
O W
O)
C
a)
-0 U) E Z
L
yr N
-0
Q
C
m mO
fC
7
N
i— ay+
O 0Lo
L U
i —
— Z
O O
U y U)
N m
O
U) i
(�
O
a
.N >,
i
(A
3
C
rz U) m U
O O O N M
E 73
O
a—
y
C L
> U)=
V U U)N
O
(n U)
d
CO
Va
�
(mN
U C
p
N
M
m
m
N
zO
a)
m
O CO C .�
N N � N
0
o� O
415
r
o Q N
N a)
rz
a
is
N N
C
N L
N (B a) N
(B z
a
(B
a) 0_
+� a) -0
_
a) Z> U) t
i O
p
U C
Q N
M
N Q
m U) U)
w 0 0
3
'� a)
—
�Q
d
C Q
; C: mO
Q
>, N U
O
ry��
co a)
C
—c
L
0-
OC�
OE
LL
,-
M
a)YN OL
LUU>U
O
O N
CD p
O m
LL
Oo
Q
XO
)
w aw�
zwO
-
>
o
a
o a-0
O U D
ow
L C
=
O L
>
a
Q
a)
'U
O
U) m
O N
a) a) .O
� L
_V
w
�
_' C
O N
O C L
N
N U) m
C:
O 0
Q
73 L
-0N
M
a)
O N
lN
p�
Q O
m
m
CCx
n �
C
O
O
O U
m a)_
MN fl-Q
0
U)
73
Q
Q E
N
U)
DM
p M
o
N
a) m
y
w U
ay)�
o
o -0-0
om
a)o
aa))o�
Y
Or
(B O 'N
C L 0) a) U p
aa)) OL N
O
a)
M
Eo a)(�
0 0.—-
� m Uo
o
N U
>a U_
C
0 U)OU) U) a)�i
Q O O
M
_
—
aL)
O -0
O
QO U
O
r
>
U
O
.p
C Ofn a) a)
UL
�
B
a)
Q
n
x
N
OO
B a)oi
d
N Q N
a)l M N
aO p
pU C N>
N
x LC
a) >
y
U
C
()
L
E_ O a)
a) m L C C
m O a) U
a)
a) M
y
a) (B
L >
Z
0 LL — .N LL
Q' �o (B (B 0
LL c
Q'
E E
H
H M

\
/
\
y
LL
a
k
02
2 = a
o _
.2 E¥
05
7z
z
Cl)
z
_
cn
m
IL
w
a
k
00 2
2 - a
o M
2 E a
oe
7z
z
A
z
cn
m
IL
w
zco
CD
co CD
k
k
Mn
B0
� �
L) CD
$
J
k
-
k
w
©
-
k
n
®
N�
4
N CD
@
_
N
_
N
2
2
®
_
C ?
\
7
4
?
\
a
%
=
N
=
N
\
\
%
)
%
m
04
/
-
m o
=
C
m o
=/
= G
±
=
0\
�
2
m_
�
2
m_
k
§
�mco
e 0 >
2 7
/
�
\
/ �
\
�®
��
2
��
2
�
\
It
\
E
\
/
§
_
coQ/
_
$
0
C
C
Q/
)
)
R
©
©
tm
§
§
c
\
cn
/
kg
kg
�
t
m
§
/
\
�
'
o
�
u
g
g
2
x
E
z/
E$%
z/
E$%
2
)
2
r-
u
u
m
z
z
\
/�
/
2
CD C)
©moo
§
ƒ
/
\
2 6 6
E
§ 2 6 6
E
C
u
C
u
e
n
$
-
w
$
-
_
t
t
2
-
E
/
E
/
E
)
6
§
_
�
\
\
=
e
§
C
)
o
0)\
co
)
z
k
% )
z
w
§
/
\
/
\
)^
§
E
\
u
u
m
o
§ \
u
w«
u
9
o
ƒ/
¥
q«
¥
u
>
2
2
E/
.,
E
o C/
0
.,
�
§
'
m
.
.
,
u a
t%\
,
J u a
t%\
�
Q
k
F
=
ECL
_
3
2 Cl)
\
w
\
w
\
u
a
u
\
0
k
C
a
^
\
ca
w
a\
§
w
a/
§
K
7§
6
K
7§
6
z
y«
2
m
w
0)
w
k 'j
� k
= E
{ /
.! 7
§ 2
(on\
E&
t o
\k
/ \
} 0
E /
/ y
\ \
�CO
E
\ \
E k
§ /
E a
/
f

m
O
(n
co
N
LL
pm
0
C
N
N
0
N
a)
y
C
y
fC
N
i
QN
i
o
N
y
C E
O _ _
Q Q
U E O a) O O
y U U U co
N co
O O
U N E U X
>, >, CL >, X X — a)
a) a)
N N 0) y N a) N U O O
m cUi cUi N C) a) N co O — y X
O O O X O O w N N O = O N- O .— O)
C 0 U N � C �y L 0 (6 N>> N" a) E N .0 � L L .c O Q- j
m W W CO Q M U (CO CO 6 (6 (LU O 0) (6 (6 0 O Z_ a) O Q Q �p X
U `..' `..' Q U `..' c c 'O O O w .— C 'O
X O O o N O X a) 0 0 O N C C N ++ O- 2)� L L zi O
a) o o U U a) Q Q Q o C y C O U Q Q y y N—
U
C
N Z
o e \ Q Q
m W 7 fA 1 al Z C C C C Q M O — Q
U fA CC
Q M M U U U W 2 `1 `1 2 2 2 2 2 2 Z Z Z O C. d d 0) 0) �i N N
C
O
y >,.— U) (B
(B N
a) Q
Q
N 0
�_
m
O O
0
O UL
OL i
N (B a-C
U) :5
y O o N
7 "O Lo Lo a)
U
i
i
U
(B O
~
y C_
Q
p O p=
C a) n p
4C:
p
CD
may) p p 7
-O L a) �. i
�j
�,
C
U Zi OY
(B r)CY
a) y
�
a) C)-0 N U
O (B U)
N
=
O y
O ff\
E
U)a)
I
co
a+
0_
C i
Z>
o
o
C Lo O
E
a) a) O
.y
a) --I:-
> O a)
U 'N
0 C U)a)
`� M U)
U)O
O
a) (n m
N m
O
-p M C Q
y a) O
. C a)
O
ch O
O U
) a
o
L
a) 0 0
a) a) U)
y E U
w C
QQ
O W
O)
C
a)
-0 U) E Z
L
yr N
-0
Q
C
m mO
fC
7
N
i— ay+
O 0Lo
L U
i —
— Z
O O
U y U)
N m
O
U) i
(�
O
a
.N >,
i
(A
3
C
rz U) m U
O O O N M
E 73
O
a—
y
C L
> U)=
V U U)N
O
(n U)
d
CO
Va
�
(mN
U C
p
N
M
m
m
N
zO
a)
m
O CO C .�
N N � N
0
o� O
415
r
o Q N
N a)
rz
a
is
N N
C
N L
N (B a) N
(B z
a
(B
a) 0_
+� a) -0
_
a) Z> U) t
i O
p
U C
Q N
M
N Q
m U) U)
w 0 0
3
'� a)
—
�Q
d
C Q
; C: mO
Q
>, N U
O
ry��
co a)
C
—c
L
0-
OE
LL
,-
M
a)YN OL
LUU>U
O
O N
CD p
O m
LL
Oo
Q
XO
)
w aw�
zwO
-
>
o
a
o a-0
O U D
ow
L C
=
O L
>
a
Q
a)
'U
O
U)m
O N
a) a) .O
� L
_V
w
�
_' C
O N
O C L
N
N U) m
C:
O 0
Q
73 L
-0N
M
a)
O N
lN
p�
Q O
m
m
CCx
n �
C
O
O
O U
m a)_
MN fl-Q
0
U)
73
Q
Q E
N
U)
DM
p M
o
N
a) m
y
w U
ay)�
o
o -0-0
om
a)o
aa))o�
Y
Or
(B O 'N
C L 0) a) U p
aa)) OL N
O
a)
M
Eo a)(�
0 0.—-
� m Uo
o
N U
>a U_
C
0 U)OU) U) a)�i
Q O O
M
_
—
aL)
O -0
O
QO U
O
r
>
U
O
.p
C Ofn a) a)
UL
�
B
a)
Q
n
x
N
OO
B a)oi
d
N Q N
a)I M N
aO p
pU C N>
N
x LC
a) >
y
U
C
()
L
E_ O a)
a) m L C C
m O a) U
a)
a) M
y
a) (B
L >
Z
0 LL — .N LL
Q' �o (B (B 0
LL c
Q'
E E
H
H M

_
\
c
\
coa
K
z
00
=G
± z
e
w
#
/
C2
2 = CN
0{
2z
2
z
m
L\§k
mz x
co CD
0
\ U \ \
§
zCL
\
J
§
Mn
0
��
J
>
-
k
m
®
Co
a
2
LU
a
\
_
2
\
2 61)
N
2
ry
=
\
F
2
2
`��
@ /
\ CD
a)
2
cn
2
a)\
f\\
/
7
z
2/
t �
g
o
C
� # .� *
a^
E
2
2
a f
/
/%e/
/§
_
g
2
00
)
�
%
±
±
��
u
u
\
/
t0
t
§
\
©
)
\
o
C
2
@
E
�
zm
%
LU
2
/
, 2
u
2
n
z
/
\
\
.qoo
�
Q
E
2 6 6
§
\
0
2
->
y
_
%
/
0
6
6
\
§
0
E
§
)
\
z
=
R
_
2
)
G
2
\
0
C
CD
m
0
\
L)
u
R
o
f
7
E
¥
q«
$0
CD
�0\coE
.2
%
f
)
J
u \
t
§
\
0
3
6
2
C
¥
°
CL
f
u
=
)
q
6
` �`
m
°
2
0
°
^\
2
>
CD«
/
k
=
§
k
k
n
§
CD
z
my«
2
m
w
k 'j
E
= E
{ /
�} 7
Co
0
\k
/ %
\ /
E \
/ y
\ \
�E
\ £
\k
E k
.§ /
E a
/
f

ONOCD
O
O
(n
co
N
LL
p
C
N
N
0
N
(U
y
C
y
MC
N
i
QN
i
O
N
w
y
O _ E _
Q Q
U E O (U O O
y U U U co
Q m O O
U mE U X
>, >, CL >, X X — (U
(U 0
U U N y : N co co N X (U
N N (onN N U N O O
cUi cUi N N N co O — y X TD
O O O X O O w N N O = w w O N- O .— O)
C 0 U N � C �y L 0 (6 (6 j j (6 " N E B .0 � L L .c O Q j
m W W CO Q M U MCO CO O (6 (wU O 0) M (6 0 O �_ O Q Q �p X
U `..' `..' iz U `..' c c 'O O O w .� C 'O
X O O o (6 O X (U 0 0 O (6 C C (6 ++ O- 2)� L L zi O
a) o o U U N Q Q Q o C y C O U Q Q y y N —
U
C
N Z
o e \ Q Q
m W 7 fA al — C C C C Q M O — Q
M) fA CC
Q m m U U U W 2 Y `1 Z Z Z O C. d d 0) 0) N N
C
O m
U) (B
U)
(B N
a) Q
N o
�_
m
O O
0
OU�
OLi
N (B a-
U) :5
C y p o N
7 "O Lo Lo a)
U
i
C
U
(B O
~
y C_
Q
p a) CD =
C a) n p
C
C
CD
maU) p p 7
-O L a) �. i
4
�j
0+
p
C
U Zi OY
� a) y
a) C N �
O (B U)
N
=
O y
(B MCY
O ff\
I
a+
_
C i
Z>
O
O
C Lo O
x
a) a) O
.y
a) --I:- CY
t
> O a)
U 'N
0 C y a)
O C
M U)
a) O
y
O
O
a) (n m
M7 U
N m
-p M C Q
y
. C a)
O
ch O
) a
O
C L
a) 0 0
a) O U)
y U
CD
Q
O W
O)
C
N Lo a)
U) E .Z'
a) L
N
-Q
C
R
7
i— ay+
L U
i —
O
— Z
O O
U y U)
N m N
O
U) i
M4
a
. >,
Lo
cn
3
c
rz U) m
Lo o a) M
E 73
o c E
a—
y
> Mn =
�_ Mn
o
cA U)
N
d
V 00
"O
.O "O
N
N
U C
a O p y—
Q N M
C m m
m
z N
a)
m
O CO C .�
N N a)
o O
fA
C
Q Q N
(I
o Q N
N a)
rz
a
is
N N
C
N L
N (B a) N
(B z
a
m
(B
T a)
a) 0_
_
a) Z �
_ _
O
M
p
QU N
C E
Mv�i
U) Q
co mU) � U)
MU o 0
3
'� a)
—
d
C Q M
; Q
> N U
O
ry�� C
—
O L
C O C
Q (n
O
O
U L
[�
Q c U
Y> N N
p i .�
C
L
a) O
W
O
O N C C
L X O
a C +y CD p
MO a) E
C O m
o z
,�
LL
a)
U Q O
L
O
n} `)
E w a)
w� w
�
> o
o
a)
L
w E .o a) �
O U D
o
L C
'
>
a
C
Q
ay+ a)
L L O—
O
yt. U y m
O N
L
a) a) .O
( L
V
y
_- C
O a)
O C C
x
N
2� N 2� U)m
:
O a) Q O
"O L
y
M
a)
_
a)
N
O
O N
N
lN
CD
p�
Q O
m
m
N
CD
CQ
C
O
O
O U
m a)
M
Mn
Q N E
U) t
C
L D
p M y
Q
o
N C N C
(1) m
Mn
a)
w U a)
cn
o�� o
o
o -0-0�o
m a)
- aa))
ioN
`
) a) p
a)
°=
o
M
Cl a)
O CC
m U O
N
>C
dU
0 U)O a) i
O O
M
"a_OC)o
a)
-a
O
a) Q
Q U
C
L
0C
>O
U
O
Q
+
U
CC
a(B
cla
>
-2
L
a) >
L
aOOU
O0
p
_
B a)E
La)
0U
p N
Oa)
N
C NO
>
X LQ>
a)(D
y
B)
C
u
a)
CL
E O
L
C C
m O a) U
a) B
>
Z
w
0
JI� L .—
�m O
LL C C
E
H
F MB