WQ0031314_2022 Residual Annual Report_20230227 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0031314
Applicant/Permittee Winston-Salem/Forsyth County Utilities Commission
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Winston-Salem
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Alan Fowler
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
3363977727
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0031314
Has Current Existing permit number
Applicant/Permittee Address*
2800 River Ridge Road, Pfafftown NC 27040
Facility Name*
Winston-Salem/Forsyth County Utilities Commission Class A Residuals
Program
Please provide comments/notes on your current submittal below.
Attached, please find the 2022 Land Application Annual Report for Winston-Salem/Forsyth County Utilities (WQ 0031314).
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
Land Application Annual Report 2022(signed).pdf 5.42MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/27/2023

Winston-Salem / Forsyth County
Date February 15,2023
North Carolina Division of Environmental Quality
Aquifer Protection -Land Application Section
1636 Mail Service Center
Raleigh, NC 27699-1636
Dear Sir or Madam,
Attached is our 2022 Residuals Land Application Annual Report and supporting documentation for the
City of Winston-Salem's Swann, Thomas and Neilson Water Treatment Plants for permit WQ0031314.
Swann Water Treatment Plant
The Swann Water Treatment Plant operated in compliance with all parameters of its pert -nit during the
2022 calendar year. The Swann WTP operates one equalization basin and two residuals lagoons that
produces a Class A Residual, which is 503 exempt. Residuals generated by filter washes flow through an
equalization basin, whereas solids removed from the plant's sedimentation basins flow by gravity directly
to the residuals lagoon in service. The lagoons are operated such that one lagoon accepts residuals while
the other lagoon is cleaned or in reserve. During the 2022 calendar year, the Swann WTP contracted with
EMA Resources, Inc. to land apply 129.39 dry tons of residuals to farmland in Yadkin County. Listed
below are documents associated with this land application event.
Section 1
• DEQ Form DMSDF - Class A Annual Distribution and Marketing/Surface Disposal Certification
and Summary Form
• DEQ Form RSSF - Annual Residual Sampling Summary Form
• DEQ Form RSSF B - Annual Residual Sampling Summary Form
Section 2
• DEQ Form MFLSF - Annual Metals Field Loading Summary Form
• DEQ Form FSF - Annual Land Application Field Summary Form
Section 3
• Lab data sheets from Waypoint Analytical (nutrient metal analysis data sheets)
• Lab data sheets from Summit Environmental Technologies, Inc. (TCLP, reactivity, ignitability,
and cyanide)
• Copies of our SAR/PAN calculations
Section 4
• Maps of the residuals disposal sites
Section 5
• Field soil sampling results
=.EDncil: Mayor Alien Jolnes; Denise D. Adams, Mayor Pro Tempore, North Ward; Barbara Hanes Burke, Northeast Ward; Robert C. Clark, West Ward;
Jahn C. LarsonSouth Ward; Jeff Macintosh, Northwest Ward; Kevin Mundy, Southwest Ward; Annette Scippio, East Ward; James Taylor, Jr., Southeast Ward;
City Manager: Lee D. Garrity
t ry C Y nnnCounty Commissioners: Don Martin, Chair; Gloria D. Whisenhunt, Vice Chair; Dan Besse; Richard V. Htrvl€te; Tonya D. McDanlel; David R. Plyler, Malishai
Cai1311 ar ! uuVn U Woodbury; County Manager: Dudley Watts, Jr,
CitylrrEk@Cit Ofw$.arg Winton-Salem/Forsyth County Utility Commission: L. Wesley Curtis, Jr., Chair; Chris Parker, Vice Chair; Simpson O. Brown, }r.; Harold Eustache; Tom Griffin;
y Yvonne H. Hines; Hugh W. )emigan; Duane Long; Calvht McRae; Charles Wilson; Allan Younger

Thomas Water Treatment Plant
The Thomas Water Treatment Plant operated in compliance with all parameters of its permit during the
2022 calendar year. During the 2022 calendar year the Thomas WTP hauled 475.54 day tons to the I -lanes
Mill Road Landfill located at 325 W. Hanes Mill Road, Winston-Salem, NC 27105.
Neilson Water Treatment Plant
The Neilson Plant operated in compliance with all parameters of its permit during the 2022 calendar year.
The Neilson Water Treatment Plant operates three residuals lagoons and produces a Class A Residual,
which is 503 exempt. Solids from the sedimentation basins flow directly to the residual lagoon in service.
The lagoons are in a rotation so one is in service, one is drying and one is empty and ready to be placed
into service. During the 2022 calendar year EMA Resources, Inc. removed and applied 645.5 dry tons of
residuals on land owned by Frank Small. Based on the soil results, approximately 65 tons of lime were
applied. Listed below are documents associated with this land application event.
Section l
• DEQ Form DMSDF - Class A Annual Distribution and Marketing/Surface Disposal Certification
and Summary Form
• DEQ Form DMSDF (Sapp) - Class A Annual Distribution and Marketing/Surface Disposal
Certification and Summary Form (Supplemental Information)
• DEQ Form RSSF - Annual Residual Sampling Summary Form
• DEQ Form RSSFB - Annual Residual Sampling Summary Form
Section 2
• DEQ Form MFLSF - Annual Metals Field Loading Summary Form
• DEQ Form FSF - Annual Land Application Field Summary Form
Section 3
• Lab data sheets from Waypoint (nutrient metal analysis data sheets)
• Lab data sheets from Waypoint (TCLP, reactivity, ignitability, and cyanide)
• Copies of our SAR/PAN calculations
Section 9
• Maps of the residuals disposal sites
Section 5
• Field soil sampling results
If you have any questions or require additional information regarding our 2022 Annual Report, please
call Alan Fowler, Water Treatment Superintendent, at [phone].
Alan S. Fowler
Permittee: Preparer of Annual Report:
Courtney L. Driver Alan S.Fowler
Director of Utilities Water Treatment
Utilities Administration Superintendent
P.O. Box 2511 Swann Water Treatment Plant
Winston-Salem, NC 27102 2800 River Ridge Road

Winston-Salem/Forsyth County Utilities
WQ0031314
2022 Residuals Land Application Report
P.W. Swann Water Treatment Plant
TABLE OF CONTENTS
Section 1
• DEQ Form DMSDF - Class A Annual Distribution and Marketing/Surface Disposal
Certification and Summary Form
• DEQ Form RSSF - Annual Residual Sampling Summary Form
• DEQ Form RSSF B - Annual Residual Sampling Summary Form
Section 2
• DEQ Form MFLSF - Annual Metals Field Loading Summary Form
• DEQ Form FSF - Annual Land Application Field Summary Form
Section 3
• Lab data sheets from Waypoint Analytical, LLC (nutrient, nutrient metal sampling data
and chain of custody's)
• Lab data sheets from Summit Environmental Technologies, INC (TCLP, Reactivity,
Ignitability Analysis for this Permit Cycle)
• Copies of our SARIPAN calculations
Section 4
• Maps of the residuals disposal sites
• Field soil sampling results
• Agricultural Lime Application Logs
Section 5
3

Section 1
• DEQ Form DMSDF -Class A Annual Distribution and
Marketing/Surface Disposal Certification and Summary Form
• DEQ Form RSSF - Annual Residual Sampling Summary Form
• DEQ Form RSSF B - Annual Residual Sampling Summary Form
4

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
%VQ PERM IT #: W00031314 FACILITY NANIE: Winston Salem - Swann Water Treatment Plant
PHONE: COUNTY: Forsyth OPERATOR: City of Winston Salem
FACILITY TYPE (please check one): © Surface Disposal (complete Part A (Source(&) and "Residual In" Volume only) and Part C)
R Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes 0 No © —► If No skip parts A, B, C and certify form below
Part Ar: Part 13*:
Sources s ( include NPDES # if Volume (dry tons) Recipient Information
Month Amendment!
applicable) Bulking Agent I
Residual In Product Out Name(s) Volume (dry tons) Intended use(s)
arch
space
Total Number of Form DMSDF 1
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit 0 Yes
(including but not limited to items 1-3 below) issued by the Division of Water Quality: © No —; If No, Explain in Narrifive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"1 certify, under penalty of , hat the above information is, to the best of my knowledge and belief, trite, accurate and complete. I am aware that there are significant
penalties f submitting f se inf rntation, including the possibility of fines and imprisonment fork nlin violations."
a�av 1-7
Signatureo Permittee aL7 to Signature ofPreparer* Date
Py (ifdifferent from Permittee)
"Preparer is defined in 40 CFR Part 503.9(r) and I SA NCAC 2T .l 102 (26)
DENR FORM DMSDF (12/2006)

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Section 2
• DEQ Form MFLSF W Annual Metals Field Loading Summary Form
• DEQ Form FSF - Annual Land Application Field Summary Form
5

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Winston Salem - Swann WTI' Total Dry `foes Applied (Annual): 72.10
Permit ##: WQ0031314 Cation Exchange Capacity (non 503 only): 0
Operator: Forrest Breedtove Owner: Forrest Breedlove Predominant Soil Series: NaB
Acres Used: 28 Acres Permitted: 28 Site #: DV33 Field 0: 1
Residual Anatvsls Data fHeavv Metals and Total Phomhorus use nie/kv-, % Solids use Raw Percent 4):
Sample 4r
Com-
posite
Date
-11
Fall Avg
2
3
41
5
6
7
8
9
IQJ
jjj
12
% Solids
3.41
Arsenic
9.1
Cadmium
0,6
Copper
48.6
Chromium
27.6
Lead
20.8
Mercury
0.2
Molyb-
denum
4
Nickel
14,6
Selenium
9.5
Zinc
380.8
Total
Phos-
horus
3322.5
Annual Heavy Metal Field Loadings (Ualculated in im/acre):
Total
L2J
3
4
Gj
0
11
12
DT/Ac./
-jJ
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App.
Event
2.58
Arscoic
0.047
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0,000
0.000
0.000
0,000
0.047
Cadmium
0.003
0.000
0.000
0,000
0,000
0,000
0,000
0,000
0,000
0.000
0,000
0.000
0.003
Copper
0.250
0.000
0,000
0,000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.250
Chromium
0.142
0,000
0.000
0.000.
0A00
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.142
Lead
0.107
0.000
0,000
OA00
0,000
0.000
0.000
0.000
0.000
0,000
0.006
0.000
0.107.
Mercury
0,001 ;
1 0.000
0.000
0.000
0,000
0.000
0,000
A000 .
0.000
0.000
0.000
0,000
0.001
Molyb
0,021 c
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0,000
0,000
0.000
0.021
denum
Nickel
0.075
0,000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0,000
0.000
0,000
0,075
Selenium
0,049
0.000
0,000
0.000
0,000
0.000
0.000
0.000
.0,000
0.000
0.000
0,000.
0,049
Zinc
1,961 �
0,000
0,000
0.000
0.000
0.000
0,000
0.000
0,000
0.000
0.000
0.000
1961
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17.111.
0.000
0.000.
0A00
0.000
0.000
0.000
0,000
0,000
0,000
0,000
0.000
17.111
"1 Certify, nuclei, penalty of law, that tnts aocument was prepared unaer my airection or supervision in accornance witil
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
G� 2/15/2023
Signature of Land Applier Date
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ANNUAL METALS FIELD LOADING SUMMARY FORM`
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit 4-
Operator*
Acres Used:
Winston Salem - Swann WTP Total Dry Tons Applied (Annual):
WQ0031314 Cation Exchange Capacity (non 503 only):
Forrest Breedlove Owner: Forrest Breedlove Predominant Soil Series:
14.5 Acres Permitted: 14.5 Site 4: DV33 Field #t
12,93
NaB
2
Residual Analvsis Data (Heavv Metals and Total PhostAorus use mgllit;, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
!
Fall Avg
2
s
_4j
s
7
8
9
10
11
12
% Solids
1 3.41
Arsenic
M
Cadmium
0,6
Copper
48.6
Chromium
27,6
Lead
20.8
Mercury
0.2
Molyb-
de"1u"n
4
Nickel
14.6
Selenium
9.5
Zinn.
390.8
Total
Phos-
horus
3322,5
Annual Heavv Metal Field Loadinus (Calculated in lbs/acrel:
Total
2
3
4
6
7
LSJ
9
10
Lij
12
-Si
H
DT/AG./
0
APP.
Event
0,89
Arsenic
0.016
0.000
0,000
0.000
0A00
0.000
0,000
0,000
0.000
0.000
0.000
0,000
0.016
Cadmium
0.001
0.000
0.000
0,000
0,000
0,000
0.000
0.000
0.000
0,000
0,000
0,000
.0,001
Copper
0.087
0.000
0,000
0.000
0.000
0.000 '
0.000
0.000
0,000
0.000
0.006
0.000
0,087
Chromium
0.049
0.000
0,000
0.000
0.000
0,000
0.000
0,000
0.000
0.000
0,000
0.000
0.049
Lead
0.037
0.000
0,000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0,000
0.600
0.037
Mercury
0.000
0,000.
0.000
0.000
0,000
U00
0,000
0,000
0.000
0.000
0.000
0,000
0.000:
Molyb-
0.007 :
-0.000
0.000
0.000 .
0,000 ;
0,000
.0.000
0,000
0.000
0,000
01000
0.000.
0.007
denum
Nickel
0,026
0.000
0,000
0,000
0.000
0,000
0.000
0.000
0,000
0.000
0.000
0,000
0.026
Selenium
0,017
'0,000
0,000
0.000
0,000
0,000
0.000
0.000
0,000
0.000
0,000
0.000
0.017
Zinc
0.679
0,000
0,000
0,000
0,000
0,000
0.000
0.000
0.000
0,000
0,000
0,000
0,679
Total
Phos-
5,927
0.©00.
0.000.
0.000.
0.00.0
0.000.
0.000
0,000:
0.000.
0.000.
0,000
a.000
5.927.
�hnrus
"t certify, under penalty of taw, that tnis uocument was preparea under my nurection or super vision in accoraance wiul
a system designed to assure that qualified personnel property gathered and evaluated the information submitted. I am
arvare that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
�� 2/15/2023
Date
DENR FORM MFLSF (1212006)

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tY
0
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tL
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0

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Winston Salem _ Swaim WTP 'Total Dry Tons Applied (Annual): 35.12
Permit 4: WQ0031314 Cation Exchange Capacity (non 503 only): 0
Operator: Edsel Wooten Owner: Edsel Wooten Predominant Soil Series: CcB2
Acres Used: 22.5 Acres Permitted: 22.5 Site 4: YK43 Field #: 1
Residual Analvsis Data fHeavv Metals and Total Phosphorus use me/ku, % Solids use Rave Percent #):
Sample or
Com-
posite
Date
Fall Avg
2
4
5
_sj
7
81
9
10
11
12
Solids
1 3.41
Arsenic
9.1
Cadmium
0.6
Copper
48.6
Chromium
27.6
Lead
20.8
Mercury
0,2
Mo[yb-
denum
4
Nickel
14.6
Selenium
9.5
Zinc
380.8
Total
Phos-
liorus
3322.5
Annual Heavv Metal Field LnafltnoS tualeuiatefl in ins/acre):
Total
1
2
3 j
4
5
S
7
8
9
14
11
12
H
DT/Ac,/
0
App.
4
Event
1.56
Arsenic
0.028
0.000
0,000
0,000
0,000
0,000
0.000
0.000
0,000.
0.000
0.000
0,000
0.028
Cadmium
'UO2
0,000
0,000
0,000.
0.000
0.000
0,000
U00
0.000
0.000
0,000
0,000
0.002
Copper
0:152
0.000
0,000
0.600
0.000
0M00
0.000
0.000
0.000
0.000
0.000
Q000
0,152
Cluomiun
0.086
0.000
6,000
U00
0.000
0.000
0.000
0.000
0.000
0.000
0,0o0
0,0o0
0.086
Lead
0.065
0.000
0,000
0.000
0.000
0.000.
0.000
0.000
0.000
0,000
0.000
0,000
0:065
Mercury
0.001
0.000
0,000
0.000,1
0.000
0.000 .1
`0.000
0.000
0.000
1 0,000
0.000 :
0.000
:0,001 .:
MolyU
0.012
0.000
0.000
0,000
0.000.
0.000
0.000
0A00
0.000
0,000
0.000
0,000.
0,012
denum
Nickel
0.046
0,000.
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.046
Selenium
0,030
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0,000
0.000
0.000
0.000.
0.030
Zinc
1,189
0,000
0,000
0.000
0.000
0.000
0,000
0,000.
0.000
0,000
0.000
0,000
1,189
Total
Phos-
10.373
6.000.
0M00
0.000
0,000.
0.000
0.000
0.000
0,000
0,000
0.000
0.000..
10,373.
lxorus
^i certity, under penatty of taw, coat. tilts aocumen€ was prepares under my airection or supervision III accuruance WRIA
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations",
Signature of Land Applier
4� 2/15/2023
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to he submitted in Annual Report
Facility Name: Winston ,Salem -- Swatui WTP Total Dry Tons Applied (Annual): 9.24
Permit #: WQ0031314 Cation Exchange Capacity (non 503 only): 0
Operator: Edsel Wooten Owner: Edsel Wooten. Predominant Soil Series: CcB2
Acres Used: 6.5 Acres Permitted: 6.5 Site #: YK43 Field #: 2
Rrsidnnl Annlvsis Data tllenvv Metals and Total Phosnhorus use meft& % Solids use Raw Percent #)r
Sample or
Com-
posite
Date
1
Fa l[ Avg
z
3
4
5
s
7
B
s
10
11
12
% Solids
3.41
Arsenic
9.1
Cadmium
0.6
Copper
48.6
Chromium
27.6
Lead
20.8
Mercury
0.2
Molyh-
denum
4
Nickel
14.6
Selenium
9.5
Zinc
380.8
Total
Phos-
horus
3322.5
Avtrkiiqi HPnvv MPtai iiim t i,nn[iinfys it-'aieniaie❑ to ins/acr"et:
Total
1
2
3
A v
5
ti
2j
8
9
10
111
12
DT/Ac,/
APp-
;4
Event
1,42
Arsenic
0.026
0.000
0.000
0.000
0,000
0,000
0,000
0.000
0.000
0,000
0.000
0.000
0,026
Cadmium
0,002
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.002
Copper
0,139
0.000
0,000
0.000
0.000
0.000
0.000
0,000
0,000
0.000
0.000
0,000
.0.138
Chromium
0.078
0,000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0,000
0.078
Lead
0,059
0.000 ,
.0.000
0,000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0,059
Mercury
0.001.
0.000
0.000
0.000..
.0.000
0,000
0.000
0.000,
0,000
0,000
0,000
0.000
0,001
Molyh-
0.01i .
0.000
0.000
0.000
0A00
0.000 ::
0.000
0,000
0.000
0.000
Q000.
0.000
0.011
denurn
Nickel
0.042
0.000
0,000
0,000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,042
Selenium
0.027
0,000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0,000
0-000
0.027
Zinc
1.083
0.000
0,000
0,000
0.000
0.000
0.000
0,000
0,000
0.000.
0,000
0,000
1.083
Total
Phos,
9.449
0,000
0,000
0.000
0,000.
0.000
0,000.
0.000
0X0
0.000
0,000.
0,000
9,4491
hoius
"1 certity, unuer penar[y Or iaW, LnaC Curs oocumenC was prepnreu miuec guy uif Gt.►xuRm ul aup- YA.7lull Aid .a�Vk u"l- VA. -
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted, I ant
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
` e 2/15/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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Section 3
• Lab data sheets from Waypoint Analytical Services, LLC (nutrient,
nutrient metal sampling data and chain of custody's)
• Lab data sheets from Summit Environmental Technologies, INC
(TCLP, Reactivity, Ignitability Analysis for this Permit Cycle)
• Copies of our SAR/PAN calculations
rl

doo
r
Waypoint
ANALYTICAL
12/212022
,EMA Resources Inc
Breant Callins
755 YadkinviIle Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-326-OO94
Client Project Description: Swann VVTP
21N Whitten lioad, Memphis; IN 38133
Main 901.223.2400 ° Fax [phone]
www,waypointa nalytical.eom
Dear Brent Collins:
VVaypoint Analytical, LLC, received samples) on 1. 1122/2022 for the analyses presented in the following report,
The above referenced project has been analyzed peryour instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. quality Assurance, method validations; instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 10 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—' symbol. These are not included in
the scope because NEILAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicably:.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sarn piing. Usually; but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time: compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated, This report shall not be reproduced except in frill and relates only to
the samples included in this report.
Please do not hesitate to cvnteact me or client services it you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laborawry s llablllty In any claim relating to analyses performed shall be liiriltad to, ar labamtdrys option, repeating the
analysts In question at laboratory's expense, or the refund of the char}2es paid fbr parformance o/ sald analysls.
0
Fagg I rf 6

Waypointle
ANALYTICAL
2100 Whitten Road, Memphis, TN 38133
Main 901.213.2400 a Fax [phone]
www:way�alnta naly11ca1, com
Certification Summary
Laboratory ID: WP MTN: Waypofnt Analytical, LLC., Memphis, TN
State _
— Program - - -- _
Alabama
Slate Program
Arkansas
State Program
California
Slate Program
Florida
Slate Program - NELAP
Georgia
Slate Program
Georgia
Slate Program
Illinois
State Program a NELAP
Kentucky
State Program
Kentucky
State Program
Louisiana
State Program - NELAP
Loulslarla
State Program - NELAP
MlsslssIPPI
State Program
North CaroWa
State Program
North Carolina
State Program
PQnngl,rar)la
State Program - NELAP
South Carolina
State Program
Tennessee
State Program
Texas
State Program - NELAP
Virginia
State Program
Virginia
State Program - NELAP
Lair ID _ _._
Expiration Date
_
40750
02/2812023
88-0850
0210712023
2904
0613012023
E8A167
06130120.23
13044
02/1812023
04016
0613012023
200078
10/1012023
80215
06/3012023
KY9Q047
12131.12022
LA037
12/3112022
04016
0613012023
MS
02/1112023
47701
07/3112023
a 15
12/3l 12022
68-03196
06/3112023
84002
06/3012023
02027
02111 f2o23
T1047041 e0
0913012022
00106
06130=23
46r1181
09/1412023
Pape 1 of t
P€qe 2 of 0
100001/22-326-0094

TN
Waypoint 279U n 901.2 Road, Nie Fox
Main BQ1.Z1$.Z4U0 °Fax 9Ui,223.2AdQ
ANALYTICAL www.waypolntanalocal.com
Sample summary Table
Report Numben 22-326,0094
Client Project nescription: Swann WTP
Lab No Client Sample It) Matrix Date Collected Date Received
93946 SWatin Wih Sol& 11/21/2022 10,45 111242022
Page 3 of a

Waypoint.
ANALYTICAL
2790 Whitten Hoaci, Mernph Is, 7N 38133
Main 901.213.2400 ° Fax 901,213.2440
wwwmaypoInta n slytical.com
Client: EMA Resources Inc CASE NARRATIVE
Project; Swann WTp
Lab Report Number: 22-326.0094
Date; 12/2/2022
Block Digestion and FIA Method 4600NORGD-2011
QC Batch No. L6514111L650987
The MSlM513 recoveries are outside QC limits due to the level of analyte present in the parent sample relative to
the spike level, RPD is based an the MS/MSC results and should be evaluated as laboratory duplicates,
Metals Analysis Method 6010D
Sample 93046 (Swann WTP)
Ahalyte; Aluminum
QC Batch No: L661373/L651058
The matrix spike andfor the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of

Waypoint.0
ANALYTICAL
46245
EMA Resotlr[es Inc
Brent Collins
755 Yadkin]fle Rd
Motksvflle , NC 27028
Report Number : 22-326.0094
Project Swann WTP
Information :
279D Whitten Road, Memphis, TN 38133
Main 901..219.2400 ° Fox 901,2112440
uvww.way pointanalyt€cai.com
REPORTOFANALYBIS
Report Date: 12/02/2022
iteceivedl 11/22/2022
Cctnle Cook
Project Manager
tab No 93946 Matrix; Solids
Sample 10 : Swann WTP Sampled: 11/21/2022 10.45
Test Results Units MDL MOL OF pale l Time By Analytical
Analyzed Method
Moisture
96.8
%
1.
11/28/2216:33
FMM
SW-DRYWT
Ammonia Nitrogen
6090
feSJKg ` dry
Soo
3130
1
12/01/22 16:10
1p.7
4500MF13Cr2011
Nitrate+Nitrite•N
c154
mg/Kg - dry
154
154
1
11/ZW/ 1.1:37
?OR
4504NO3F-2016
Organic N
3156
mg/Kg - dry
3125
1
12/01/22 16:10
CALCUL{iTION
PH
7.2
S.U.
1
11/30/2715:59
I1R5
904SD
Total Solids
3AS
96
0.010
0.010
1
11/28/22 16:33
FMM
254DG-2011
Total Volatile Sands
37.0
°A
0.010
0.010
1
11/28/22 16:33
FMM
2540G-2011.
Total KJeldahl Nbogen
9250
MWK9 a dry
1560
1
12102/2210:59
AN14
4500NQRG13-2011
Phosphorus
3470
nV/KtJ - dry
86,3
156
1
12/01/22 01.16
JrR
60101)
Aluminum
146000
(m/Kg - dry
144
156
1
12101/22 01:16
JTR
6010D
Arsenic
<7.50
► 09 - dry
7.50
15.6
1
12/01/22 01:16
JTR
15010D
Cadmium
<0A25
mgft = dry
0.625
3.13
1
12/01/22 01.16
JTR
6010D
Calcium
3120
mg/Kg - (fry
1210
i560
1
12101/22 01:16
JTR
6010D
Chromium
27.2
mg/K9 w drY
7.3A
7.81
1
12/01P? 01:16
JTR
60101)
Copper
43.8
mak - dry
9.60
15.6
1
12/01/22 01:16
JTR
6010D
Iron
31300
m9/Kg -dry
265
31.3
1
12/01/22 0106
JTR
60101)
Lead
i6.8
ntg/Kg - dry
5.63
938
1
1210//22 01:16
JTR
60101)
Magnesium
1360
mNKg - dry
8M6
156
1
12/01/22 01.16
011
6010D
Manganese
1350
mg/Kg - dry
10,2
15.6
1
12/01/22 01,16
JTR
6619D
Mercury
e0,210
mg/Kg - dry
ano
4.81.
1
11/28122 13:00
FDS
7471A
Molybdenum
<9.22
mg/Kg - dry
4.22
7181
1
12/01/22 01:16
JTR
6010D
Nickel
14.3
mg/Kg - dry
3,75
7.81
1
12/01/22 01:16
JTR
60100
Potassium
1360
nag/Kg - dry
193
313
1
12101122111116
JTR
60100
Qualifiers/ DF
Dilution Fartor
MQi-
Method Quant€tation Limit
Definitions
Page 5 of 8

4r
Waypointv
2790 Wltitten ftas.d, Memphis, 7N 38133
Main 901.213,2400 0 Fax [phone]
ANALYTICAL
www.waypolnlanalOW.cam
46245
FMA Resources Inc
Prolect
Swann wfP
Brent Collins
Report Date: 12/02/2022
755 Yadkiwille lid
Information r
Rocelved : 11/22/2022
Moct svllle , NC 2.7028
Coirltle CO
Report Numher : 22-326.0094
IREPORT4PMALYS!"S`
Prbleck Mann ager
Lab No: 93946
Mawr: Solids
Sample ID : Swann tl TP
Sampled: 11/21/2022 10:45
Test
Results
Units
MPL
MOL OF €iatelTlms By Analytical
Analyzed Method
Selenium
e10.o
mg/x9 - dry
10.0
15:6 1 12/01/22 01:16 IfR 60101)
Sodium
<40G
rncl/K9 - dry
406
781 1 12/01122 01:16 3fR 6010D
Zlnc
38i
m9ft - dry
25.3
39.1 1 12/01122 01:16 JTR 60100
Sulfur
4030
mg/Kg - dry
162
313 1 12/O1/22 01:16 IfR 6010D
Sodlum Absorption Ratio
-40.01
Ratio
0.01
0.01 1 12/01122 01:16 CALCULATION
Qualifiers/ DF Dilution Factor
pefinluons
MQl- Method Quantitation Urnit
Page 6 of 9

111 (D
Wayndint.
ANALYTICAL
�79Q 1Nh�tte I Road, Memphts, TN 38133
Ma1n 901,213,2400 0 Fax [phone]
WWW.WAVpointanatyti cai.cant
Shipment Receipt Form
Customer Number: 46245
Customer Name; EMA Resources Inc
Report Number: 22-326-0094
Shipping Method
Fed Ex us Postal 0 Lab Other: F"�'"�
-
0 UPS 0 Client 0 Courier Thermometer lie: S9
Shipping cdntalnerlcooler uncomprornised?
Yes
0 No
Number of coolers/boxes received
F 1
Custody seats Intact on shipping container/cooler?
0 Yes
0 No Q Not Present
Custody seats intact on sample. battles?
0 Yes
C) No Not Present
Chain of Custody (COO) present?
Q Yes
0 No
CDC agrees with sample label(s)?
Yes
0 No
CDC properly completed
Yes
(f No
Samples in proper containers?
0 Yes
( No
Sample containers Intact?
[ Yes
0 No
...............
Sufficient sample volume for indicated test(s)7 Yes 0 No
All samples received within holding time? Q Yes C No
Cooler temperature. Incompliance?
Yes
C,: j No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
No
Water - Sample containers properly preserved
0 Yes
0 No
NIA
Water - VOA dials free of headspace
0 Yes
0 No
NIA
Trip Blanks "received avid► VOAs
Q Yes
0 No
NIA
Soil VOA method 6035 µ compliance criteria met
0 Yes
O No
NIA
f_... H oh concentration container (48 hr)
F High concentration pre-welghed (methanol -14 d)
�— Low concentration EnCore samplers (48 hr)
Low conc pro-woighed vials (Sod Sis -14 ci)
Sped al precautions or instructions included?
Yes
Q No
Comments .
Signature: umme►„Harrison mate & Time.. [ 1/221202214 f
Page 7 of R

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Wayp � nr.
I�ALYTICAL
12/7/2022
BMA Resources Inc
Mr. Brent Collins
755 Yadtihville Road
Mocksville, NC, 27028.
Ref; Analytical Testing
Lab Report Number: 22-333.0013
Client Project Description: Swann 1NTP
2190 Whitten Road, Memphis, TN 38133
Main 901.213.2Q0 ° Fax 901.213,2440
wwwmaypolmanaly tical,com
bear Mr. Brent Collins:
Waypotnt Analytical, 41-C, received sarnple(s) on 11/2912022 for the analyses presented in the following report..
The above referenced project has been analyzed per your Instructions. The analyses were perforriled in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
Para' ieters (NEI AP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a' -'symbol, These are not included in
the scope because NEI..AP accreditation is either not available or has not been applied for. Additlonal
certificallons may be heldiare available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is a.Vallable upon request,
Certain parameters (chlorine, pit, dissolved oxygen, sulfite...) are required to be analyzed vrithin 15 minutes of
saris"Ting, Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(§). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's 11abil11y in any claim relating to analyses performed shall be fimired to, at laboratory's option, repeating the
analysts An quesilon at laboratory's expense, or the refund of the charges paid lot performance of said analysis:
0
Page 1 of 8

Waypoinic.,
ANALYTICAL
2190 Whitten Road, rvlamphis, TN 39133.
Main 901.213,2400 6 Fax 901;-213.2440
www.waypalntana1v*gl.rom
Certification Summary
Laboratory!!). WP MTN.. Waypolnt Analytical, LLC., Memphis, TN
State
i'r ram ,
Lab 11
i xRrOon ai�at _._:... ,_.
Alabama
State Program
40760
02/2812023
Arkansas
State Program
MOW
0210712023
California
State Program
2904
06/3012023
Florida
State Program - NELAP
E871157
06/3012023
Georgia
State Program
C044
0211812023
Georgia
Stale Program
04015
0613012023
Illinois
State Program - NELAP
200078
1011012023
Kentucky
State Program
80215
06J30t2023
kentuchy
State Program
KY90047
1213112022
Louisiana
State Program - NELAP
LA037
1213112022
Loufslarla
State Program - NELAP
04016
06130/2023
MISSISSIPPI
Slate Program
MS
02111/2023
North Carolina
Slate Program
47701
07131=23
North Carol#na
Slate Program
415
12/31/2022
Pennsylvanla
State Program - NELAP
66-03195
0513112023
South Carolina
State Program
84002
06/3W2023
Tennessee
Slate Program
02027
62111R023
Texa&
Slate Program - NELAP
T104704180
091302022
Virginia
State Program
00106
06/30,2023
Virginia
State Program - NELAP
460181
09/1412023
Rage 1 of I 00001122-333-0013
Page 2 of A

Wayp nv
A,g,ICAL
Report Number: 22.-333-0013
Client Project Description: Swann WTP
2790 Whitten Road, MarnpWs, TN 38133
Main 901.213.2400 0 Fax 901,213.2440
www.waypolntanalytical.com
Sample Summary Table
Lab No Client Sample ID Matrix Date Collected Date Received
95179 Swann WrP Solids 11129/2022 09.95 11/29/2022
...........................
Page 3 of 8

0
way o0tnt.
ANALYTICAL
Client: EMA Resources Inc
Project: Swann W P
Lab Report Number: 22-333-0013
Pate: 1217/2022
2790 Whitten (load, Memphis, 7N 38133
Main 901.213.2400 6 Fax [phone]
www,waypainka rlalyttcal.cdm
CASE NARRATIVE
Metals Analysts Method 60100
Sample 95179 (Swann WfP)
Analyte: Aluminum
QC Such No: L65.21041L661599
The matrix spike andlor the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 95170 (Swann WTI )
Analyte: Iron
QC Batch No: L662104IL651599
The matrix spike andlor the matrix spike duplicate was outside quality control acceptance ranges, A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 95179 (Swann WTP)
Ahalyte: Potassium
QC Batch No: L6521041051599
The matrix spike acidlor the matrix spike duplicate was outside quality control acceptance ranges. A past
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 96179 (Swann WTP)
Analyte: Manganese
QC Batch No: M21041L661699
The matrix spike andlor the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
P�90 4 of 8

Wayoint,
ANALYTICAL
46245
EMA Resources Inc project Swann W1P
Mri Pront Collins
755 yadkinvlllu dead Information
Macksville , NC 27028
Deport Number :22-333-0013
2790 W1111tten Road, Memphis,14 391B
Moln 901.2134460 0 Fax 901,213.2440
voww,woVpolntanalVtfical.tom
IMPORT OF ANAL WiS
Repixt Date, 12/07/2022
Recelved : 11/29/2022
Untie Cook
Project Manager
Lab No; 95179 Matrix: Solids
5arnple 11); Stniarin WTP Sampler]: 11/2812022 9.45
Test Results !units MDL Mt2t_ DF Data 1 Time By Analytical
Analyzed Method
Moisture
96.1
"/a
1
11/3012216:00
FMM
SW-ARYWT
Ammonia Nitrogen
5260
mg/K9 - dry
410
2560
1
12106/27 14:5-S
PJ
4500MC--2011
NitrnW+Nltrite-N
<126
mg/Kg � dry
126
126
1
12/62/22 15:12
ZBD
46CONO3F-2016
Organic N
16820
mg/Kg - dry
5946
1
12/06122 14:55
CALCULATION
pR
6.5
9.u.
1
12106/2216.40
MS
9045D
Total Solids
3.91
16
0.010
0.010
1
11/30122 16:00
FMM
251OG-2011
Total Volatile Solids
37.4
%
0.010
0.010
1
11130/22 16,00
FMM
251115-2011
Total WOW Nitrogen
22100
mg/Ko -dry
5850
1
12/07/22 14:02
ANH
4500NORGO-2011
Phosphorus
2790
mg/Kg - dry
70.8
128
1
12/06/22 00:02
BKN
6010D
Aluminum
114000
mg/K9 - dry
118
128
1
12/06/22 00:02
8KN
60100
Arsenic
9.313
mg/Kg - dry
6.15
l2,8
1
12J06/22 00,02
BKN
6010D
Cadmium
<0,513
mg/Kg - dry
0.513
2.56
1
12106/22 00:02
WN
6010D
cats "M
2640
rng/Kg - dry
992
12BO
1
12106/22 00:02
OKh
6010D
Chromium
23.0
mg/Kg - dry
6.05
6.41
1
12/06/22 00:02
80
6010D
Caliper
42.81
m9/K9 - drY
7.95
12.8
1
12/06/22 00:02
WN
6010d
Iron
25900
mg/Kg - dry
218
256
1
12/05/22 06:02
BKN
60ibb
Lead
26.2
mg/Kq - dry
4.62
7.69
1
12/06/22 00:02
6KN
60100
Mgnesium
1240
mg/Kg - dry
66.2
128
1
12106/22 00:02
BKN
6010E)
Manganese
1070
mg/Kg - dry
8.33
12.5
1
12/05/22 00:02
8KN
60100
Mercury
<0.170
mg/Kg - dry
coo
3.90
1
12/05/22 11:52
FDS
7471A
Molybdenum
t146
mglKg - dry
146
6.4.1
1
12/06/22, a0:02
BKN
6010D
Nickel
120
mg!/Kg - dry
3108
6.41
1
12/06122 00:02
BKN
6010D
potassium
1180
in9/Kg - dry
158
256
1
12106122 00:02
9KN
6010D
Quriliflersl OF
Dilution Factor
J
Wmated value
De tltions MQL
Method Quantitation Wit
Page 5 of 0

Waypointo
ANALYTICAL
46245
ENA Resources Inc Project Swann WTP
Mr, Brent Collins
755 Yadklnville Road Information
Moeksville , f1C 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.219,2400 0 Fax [phone]
wwwwaypoirntanalyticai,com
Report Date ; 12/07/20Z2
Recelved : 11/29/2022
Connie Cook
Report Number : 22-333.0013 REPORT OFANALYSTS
Project Manager'
Lab No: 95179 Matrix: solids
Sample. Its : Swann WTP Sampled; 11/2912022 9:49
Test Results units MDL MOL OF Bate I Time By Analytical
Analyzed Method
Selenium
t8.21
mg/Kg -dry
8.21
1218
1
12/06122 00:02
BKN
6010D
Sodium
<333
my/Kg -dry
333
641
1
12/06/22 00:02
BKN
6010D
Zinc
328
mg/Kg -dry
20.8
3211
1
12/(16/22 00;02
WN
6010D
Sulfur
3460
mg/Kg -dry
133
256
1
12/06/22 00:02
VKN
60101)
Sodium Absorption Ratio
. 0.01
Ratio
0.01
0,01
1
12/06/22 00,02
CALCULATION
............ .
Qualifiers/ OF Dilution Factor ) Estimated value
Definitions
Page 6 ot 8

0
point
ANALYTICAL
2791) Willuen Road, Meniphls, ilu 38133
Main 992.213.240.0' Fax 9D1.213.2440
www.w�iypointenaiyUcbl.co rn
Shipment Recelpt Norm
Customor Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-333-0013
Shipping Method
* Fed Ex 0 US Postal 0 Lab 0 Other
0 UPS () Client C) Courier Thermometer IC: T135
Shipping container/cooler uncompromised? Yes U No
Number of coolersiboxes received
Custody seals intact on shipping container/cooler?
0 Yes
ONO
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
C) No
COC agrees with sample label(s)?
0 Yes
C) No
COC properly completed
Yes
0 No
Samples in proper containers?
(* Yss
Q No
Sample containers intact?
Yes
F
0 No
Sufficient sample volume for indicated test(s)?
( Yes
0 No
All samples received within holding time?
Q Yes
0 No
Cooler temperature in compliance?
Yes
No
CoolerlSamples arrived at the laboratory on ice,
Samples were considered acceptable as coaling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
......................................
0 Yes
.0 No
00 Nils
Water - VOA vials free of headspace
0 Yes
No
NIA
Trip Blanks received wilh VOAs
0 Yes
C) No
00 NIA
;'aofl VQA method 5035 — compliance criteria met
0 Yes
O No
NIA
High concentration container (48 lir)
F HQl7 coricenlrsrtion pre -weighed (methanot -14 d)
Low concentration EnCore samplers (48 hr)
I ..:. Low conc prp-weighed vials (Sod Bis -14 d)
$pedal precautions or insiruciions included? (D Yes Of No
GoMrnentS; . _.___..__.___.
Signature: Emily M. eterson Date & Time: 1112'312022 09:38 12
Page 7 of 0

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Page 8 of 8

- Suufftaf hJil'1f`61iiJl�i►frdd I'eehtlulo�iea,hJc,
J3/0 IVIIf 31,
! 1;VIIIa1#I1LI�iF�{- 7 ! {I1tilfih ]Cl14 fi� inrr t;Ffyphago Falls, DIt a 44223
775M., (3311) 253.8211 F.U. (M) 253-'l189
Il'rhske., liM.Ai inv sendco—
Dccel ber 18, 2020
Alex 1�ux
Synagre
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
RIB: Winston. WTt'
Dear AIex Fox -
Order No.: 20120299
Summit Environmental Techno logics, Inc. received I saimple(s) on 12I412020 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report Hitless rioted
In the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
ewept where noted.
If yoti have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
ejp,W� WWOf
Minifer Woolf
t'fujee,t. Mangy ger
3310 win St.
Cuyahoga tails, Ohio 44223
Atkausns984W3S, C.allfn fda INS, C olnrnda, [:metlicxt Pimof4, fin la mA.AC i-Wfi81i, IdallaOFMO2.3,111610is Z00061;I>aAvu C4311.13I Kpnyys
L•1U317, iCetuucky (L'tldtx rrituW Storage TMk) 3, Kcalcaky 9014b, klwyland JP, hlichiSm $Stkd, Mintwsaia IM279, New
ns�"Ilite 2996, Not Jersey 011000, New York I I i?7, NnA Orblifm 39105 and 631, NoA Del:gtrl R-20t, Ohio OW, ()hip \'AP C=I.002, 0011iolm
2gi4.15S,t7vrPuggll3qqOD1, Prrl,layl�alpn0ll,1ZfKldtlslxnJLRGDQ.i17.5ix��4['art�41fsa4241GOd11.TCzxs7'1417gd�IG6.19.1G.1,1taltglfQp�d277g34-k7,
YiijiWa VELAP 10111, Neal Vi4ala 9937C
Page 1 of 34

Stiur,7ift rpovironweurnl Teeklo%ies. b)t.
MMSUMMNT MO.1ri;1'1l, Case Narrative
OdYl. 1lti�NrA�-i[�JI@!(71t3[sl45,rF?G. C10,11hugaF014,ON0,1441 yytj#: 20tZU2?�J
� dig rle 4 t ar rr 7'F.1,; / 31)J 2$3.84 11
IJ'ebstle; h1fn;Iima��j�,.tellek earl I)uE4: 12118/2020
Project: Winstoo W`rn
WorkOrder Narrative:
20120299:1'his report in its entirety Consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accrcclitatlbn Information, Chairs-ofCustody,
Cooler Receipt Forin, and other opplic;ablc forms as necossary. All documents contain the Summit
.Environmental Technologies, Inc., Work Order Number assigned to this report.
Surnmit EnvIron mental Technologies, Inc., holds the listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to die "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
`I'ecitnologies, Inc. and that of the customer. It cannot be reproduced in ally form without the consent of
Summit Environmental Technologies, Inc: or the customer for which this report was issued. The results
contained in this report arc only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies; Inc. is not responsible
ib.r use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" dcsignation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the Analytical events associated with this report are noted below.
Analytical Sequence QC Notes:
40PPM SVOC-MSTR�S(8270): 8270 CCV exhibits high recovery for Pyridine; Associated samples are
N.D, for this analyte.
LCS-46757 SVOC-BNA_TCLP(8270): Possible high Bias for Pyridine due; to high recovery in CCV.
Originat
Page 2 of 34

airitrxtlt Grrvirr�nruerllrtl'f'kh wlogl&s. ht QualiRer5 and kcrol< yms
MSUMMIT3310 lt'Irr.'.
IErt!11i1QWAFW4 toot+Rol,.t OJES, Ifir, C voijagarats, (ahl*442; WO#; 20120299
AnaM ' ei L vrjwii mils: (J30) 2534211 E.4X 13 30) 25344A Date: 1208020
11,04 W ltllrr:/hi ww'smek.se
These commonly used Qualifiers and Acronyms may or niay riot bt; preselit in this report,
QlralMers
11 The cot-aptioild lugs rinailyzed For but vas riot detected.
J The rcporled v{ilua is t?r�atcr tlrati rlrii Mnlhod Diilecliori I,itiiiE hcd less Man ills Repurtitig l,inril,
11 'T'he Itnitl lithe t'or xtinlple preparntioa andlcr nlialysis +vies exceeded.
1) i lie result is mporled If -am u dilulida,
is 'flic result exceeded the linear range of the r alilil ailon w is eslininted due to interference.
Me The result Is Wow Ilse htirilmum Compound Lholi_
'111e result exceeds the Regulatory Limit or Maximum Conttilnimilon Utah,
r1i Manual integration was used to determine the area response.
d Manual iolcgration in. which peal: was deleted
N Tiie result is presumptive based on a Mqss Spectral 11brary senrch assuming a I: I response.
P `i'lie stoond eMutrtri 04imm(10ri exceeded 25%diffetenee,
C 'Tiie rLsuI[ hus ikon coem ud by OCIMS.
X The result was not confirmed When UPOMS Antrlysis wits pet'rormcd.
D111M+ The analyte ivas delccled trillte assoeratcd birl►rk.
G bite ICB or CCD contained rcportable amourilsol'annlyte,
QC -A- Ilie CCV recuvery trailed low (-) or 111gh (+).
RIQI:)lt 'rhe RPD vvgq otitside orrtccepted igi:ovety Ihrlits.
Ql,]+ 111e LCS or LCSD recovery roiled love (-) or high M.
Ql,lt Tire LCSILCSD RI'D Has ootsideoraccepted recovery limits,
QM-0 '11rc MS or MSD recovoy failed iniv (-) or high (-F).
QMR The Msllvlslu APD was outside of aceepled recovery limits.
QV Fr 'tile IC:N' recovery failed lo%y (.) or. high (1)
S '11ie spike t-sult Wat outside of accepted recovery lirnhs.
Z Dovintiop; A deviation from the rliethod vvag per�formcd; Naasc refer io the C a-e Narrative far
addhionl itii'oimminu
Acrunyins
ND
Not Detected
Itl.
Rap ping Lintil
QC
Quality CoMM
MDL
MOW 041cclim Limit
chill
MC11101 at"oh
Lot)
Level OrIMCCtton
VS
Laboralaiy C0111rol Sarrrplc
LCIQ
t. Ve or'Quatiiltation
LCSD
Labornlory COMM Sarilple t)upllcntc
P()I.
l'raetirnl Qnanlitation Unlit
QC5
Quality Control Saritplc
t,ltal.
Conhact Required Qwkilathui Lhiiit
DUP
011plicatc
Pl.
Niinil Limit
1FIS
ivlarrix Spike
ttcat.il
Regtdatory 1_imit
%j$J)
Mairk Spikt t7ap11,CWt
NJe%
i1InAni nii Con(ainhiblion Uinit
RFD
Itclailve Percent Difrsrent
MIMCIa
Miaintuai C)utnpeund Liuil
ICY
initial C'alibralion Vedlicalinn
It'1
Reanalysis
Ick
initial Culibra lion 131ank
lit'.
Rrunlraeliorl
CcV
Coulinuing Calibration Vcailicalioa
TIC
"tentallwly lderititicd Conipoalald
CCn
Cotilln'uing C'alibralion Blaiik
ttT
iteieiuion Time
R11C
Reporting Limit Clleck
CR
Calibration Factor
Or
Dilulinn Factor
RF
iiesgoPSO rlictnr
This.list of Qualifiers and Acronyms reflects the most eotnttionly utilized Qualificirs and Acronyms for rppot'ling.
Please refer to the Analyfieat Dotes in the Case Narrative for any Qusatillers or Acronyms that do not al)peav in tfris
list or to), additional information regarding the use of These Qualifiers on reported data.
original
Page 3 of 34

SrruuuN ls'nvlrnrunerual Tedinnlogles, lire,
SUMM11- 33101Wm &
EAV111DIVACNTAL U1MN01,001M, INC C'n)whol a Falls, Uklo 44223
Arr lyrkal tab&btot'lo TEL: [phone] FAX. [phone]
IVebs!!e: w r xOj1e&CQUJ
CLIENT: Synagro
ero*Oct., Winston WTP
Lab SamplelD Clieni Sample ll)
20120299.001 Winstasi 1rJTP
'Tag No Orate Collccicrl
12/2/2020 11:15:OCI AM
Workorder
Sample Summary
Wool: 20120291
1"VO-20
Date Received mairir
12/,112020 I0,55:00 AM Sludge
Page 4 of 34

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srrrrrrrril Ent'lmnrrwnial Techoolagles, hie,m9summill
Analytical Report
3310 h7o Sr,
P
WIFIO IMW11t_ TJCCi!?JPLC 01F5, INC
rujullogd Falls, 011to 40�1
(base mparl)
At
Okml tob T €dtler
TV-- [phone] F.,11 ": (J' 30) 253.4499
w0y; 20170299
i1`�Gs1tr.: lrrr;,:lRtyli tt..rex�k.eair:
,Dato Rcportcd: 12/18/2020
CL1CN11.
5ynpy-o
Tag Number:
Matrix,
SLUDGE
C911ecliatl Date:
12/21202.0 11:15:00 AM
Lab ID,
20120299.00 I A
Project:
Winston W T'P
C1is,n1 Sanilile ID Winston WTP
Analyses Resin.`! RL QUal U1111s DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERS -SOLID
SW7470A
SW7470A Analyst, EPA
TCLP MERCURY ANALYSIS (SIN131117470)
TCLP mmury
ND
0.00200
mg(L
1
1211612020105:00 PM
TCLP METALS, VOC, BNA, PEST, HERS-801-lb
SW6010D
SW3010A Analyst: EAM
TCLP METALS ANALYSIS (SW131116010)
TCLP Prserric(As)
ND
0.500
MOIL.
1
121012020 6,2341 PM
TCLP Earlum(Oa)
ND
5.00
n101L
1
121912020 6:23:41 PM
TCLP Cadmlum{cd)
Na
0.100
MOIL
1
121012021)6:23:41 PM
TCLP Chmmlum(Cr)
Na
0-200
MOIL
i
12t1112020 6:23:41 PM
TCLP Wad(Pb)
NO
0.b00
mg/L
1
1219120200:23,41 PM
TCLP Selenluw(Se)
NO
0.0500
M91L
1
120112020 6:23:41 PM
TCLP Silver ft)
ND
0.500
Ing1L.
1
121012020 6:23:A1 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SWB270
SW3510C A001ysl: SFG
TCLP SEMI VOL;ATILES ANALYSIS (SVVI31118270)
1,4-pl01orobenrene
ND
0,200
mg1L
2
1211112020 10:30 00 PM
2,4,5-TrlchiorophenO
NO
0.500
MOIL
2
120202010:30:00 PM
2,4,0-Trlchloraphenbl
No
6-500
mglL
2
12t01202010:30:00 PM
2,40nOrotoluene
Wb
0.100
M91
2
IZO202010:30:00 PM
Cresols, Total.
ND
10.0
mg1L
2
121i1120201030:00 PM
itexachtora-1,3-buledlene
14D
0.0400
Mgllm
2
120202010:30;00 PM
Nexachlorobenzene
NO
0.100
Mg1L
2
1219120201010:00 PM
"ef(achlomethane
Nil
0.200
mg1L
2
1219/2020 1D;3D:04 PM
Nitrobenzene
Nil
0100
11MgIL
2
IM/2020 16:30:00 PM
Pamaehibrophenol
NO
0.500
mg1L
2
121012020 W:36,00 PM
Pyrldinl?
NO
0,500
QC* m911
?
t21012020 10:30.00 PM
Slim'2-Fluorophenol
41,2
10 -157
%Rec
2
V101202010:30:00 PM
Sure PheribW6
46.6
10 -169
%R.ec
2
1211112020.10:30:00 PM
Surf: Nltrobenzene-d5
46.2
32.1 - 120
%Rec
2
VM12020 10:30:110 PM
Burr: 2,4,64flbrumophenot
$0.0
46A - US
%Rec
2
QW202010.3D:00 PM
Sum 2-Fluorohlphanyl
57,0
35,7 - 130
%Rea
2
121912020 10.30:00 PM
Burr p-Terphanyl-d14
116
74,7-145
%Roo
2
i21912020 10:311:00 Pm
(Nlalitielx: 13
A mlylu dcteuted In 111e: asst Q`tetl "' —00v):l 1110A
-C
Valuo Auve quantitstion range
14
11Wing litnes foT prepanillon nr analysis aeceeded
M
Monwil Integral ion lased to dclermine area re5tvI nse
NIC
'Valpc is below Minimum Compound Limit.
N
Tootalivply idemified pampowAs
NO
i101 Doema
1'
Secnndculumn confirmation exceeds
pi,
Permit Limit
It
11P13 pgtshle accep(ed wovery limits Qri inul
R1,
Rwiiing lictection limit
U
Samples wab C-rilcYal t MDL
Page 6 of 34

SUMMITI�.
5'1111100il 1"nWronmental 1�eluiaingles, lire,
Analytical. Report
3310rr'fn8r,
Srtivil
0NM6NTAI- aril} O nGI ;, WC
Ctav2ltaga 1 �111r, 010 4a22.1
Gatsc rc art
� )
Awilyodw
l a"rat? ew
TEL [330J 2$34211 I,-W' (130) 2.i3-1,189
1V011: 20120299
1i' hsrra: 1Nrii:/�re►ru scrr�k c�aur
Dille Reporled: 12/1812020
CLIT;Ni':
Synagro
Tag Number,
mairlx:
SLUDGE
Collection Date:
12l212020 11:15:00 AM
Lob 111:
20120299-00 1 A
Project:
Winston WTI}
d liettl sample ID witisloh WTV
1lnnlyks result RL Q1101 Units Di+ Date, Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8081
SW3510C Analyst. CS3
TCLP PESTICIDES ANALYSIS ($W131118061)
Cluorda►e otal
ND
0.0250
mglL
1
WIV20201:03:00 AM
Toxapticne
ND
0.0500
ti WL
1
121121202.01:03:00 AM
Endfiih
ND
0.002511
mg1L
1
12112120201;0100 AAA
gamma-RHe
ND
0.0025o
VVIL
1
1211020201:0100 AM
Hoptachlot
Na
0,002b0
MG&
1
12/1212020 1:03:00 AM
Hcplaehlor epoxide
Alp
0.00250
►ncg1L
1
12112i2020 1:03;00 AM
Methoxychlor
NO
0.00260
nigh
1
12(12i20201:03:00 AM
5urr. TOW
7311
10.119
%Rec
1
12112120201:03:00 AM
Sum 1X13
71.3
10 -119
%Rec
1
12112J2.0201:03:00 AM
TCLP HERBICIDES BY EPA 8321B
SW8321A
Analyst: TM
2,4-D
ND
0,500
mg1L
50
1211W0206:47;Q0 PM
2,4,6-TP
ND
0.600
MIL
50
1211612020 6:47:00 PM
Surr: 2.4•Dichlorophanylacetic ark
83.2
70 -130
%Aec
50
1211612020 6:47'00 PM
TCLP METALS, VOG, BNA, PEST, HERB -SOLID
SW8260
SW1311M Analyst: SLV
TCLP VOLATILES ANALYSIS
1,1-DipllloromWe
ND
0.250
mg1L
50
121912020 6:03100 PM
1,2-C91c111oroethane
NO
0,250
mglL
50
121912020 6[08:00 PM
MEK
NIA
5.00
mg1L
50
121912020 6.1060 PM
Benzene
Nil
6,250
MOIL
60
121912020 6:00:00 PM
Carbon letrachloOde
N❑
0.250
mg1L
50
1 WW2020 6:08:00 PM
Chlornhanzone
Nil
2.50
mglL
50
1219/2020 6;08;00 PM
r hlomWm
ND
0.250
mg11.
60
121012020 6.08:00 PM
Teirachtaroaihene
ND
0.250
MWL
a0
121912020 &118:00 PM
fewhimethene
ND
0.250
mg1L
$0
i210120206;08:00PM
Vinyl chloride
No
0,1100
niglL
so
12IW2020 6:0500 PM
Sum 4-Browfluombenzene
90.5
70 - i34
%Ilec
50
121912020 6:080 PM
Sum 014renionuotamethane
98.8
iU - 13o
%Rec
5o
121WP2020 6,08:00 PM
SUrt; Toluehu,d8
96.9
70.130
%Rec
50
121912020 6:08;D0 PM
Qualifiers: 0
Annlyle deleeled in the =66alyd Method 13Lid
E
Value above rlrlantilation range
H
Holding time I'ur nrepawflan or nnalysis exceeded
M
M4110111ftgrulion p-wd to deiermine errx response
MC
Vnllic 16 Wow Minimum Compolind Limit
Al
'Tentatively idendfied compounds
ND
Noj Denoted
P
Second column cootimpation uxcecds
1'1-
PlrWt Moil
It
lu'D grliside accepted temmy linllts Origtrtal
RI_
Iteporting Detect" Limit
Ll
Sat,lpla iNith C 11leVal
'age 7 of 34

SPndl rilwhYil+ladwal reclunlog;as, hie.
Analytical Report
gym"
II"N $
`3310
Citrahosa /-ally, Ohio 44223
(tzc report)N
►1s
4 tiv # 1; r r«:
ML. (330) 25.3.8211 PAX.- (330) 233-440
A10A. 2.0120299
ff �1xF1(e: h1lp:IfFi �r r�.sulrlr.c¢i11
Dnw, Repor'1ed: 12/18/2020
CLIENT:
Synng►`o
'ung Number,
Mnlrix:
SLUDGE
Collection Date:
12/212020 1 1,15:U0 AM
Lab I.D:
20120299-001 A
Projeet:
Winston WTI'
Client Ssnlple ID Winston WIT
Analyses Result
RL Qual Units D1+
Date Aunlyzed
RCI
SW9014
Analyst: MS
REACTIVE CYANIDE (901417.3.3.2)-SOLID
Cyanide, Reaullve ND
0.400 MglKg 1
12/13120211112:46;00 PM
IGNITASILITY OF SOLIDS (SW-845:1030)
SWI030
Analyst: CXS
Ignilablfity tmnflammAle
rrrnrlsao 1
121101202U 5:30.16 VIA
RCI
SW9045D
Analyst: VVK
PH (SW9045D)
PH 7.2
s.U,2U_RC 9
121712026 12:13:39 I'M
RCI
SW9034
Analyst: MS
REACME SULFIDE: (9034)17.3.4.2
Sulfide, Reactive ND
25:0 MfjtKg I
121131202012.46.00 PM
Quallliers: B
Anal)le deteeted In tile > zonated Method Blank
If
IWding liras for preparation orarmlysis exceeded
MC
Valet& is be€oivMin€mum Cumpound Hrnit.
ND
Not DOwed
P1,
Moll I Limit
RL
Rteparlirrg Deicetwn Lim€t
E Value atruve quantilation range
M Mandal Integration used to determine nrm tespume
N Tenta3 holy identified compounds
V See(n!d MUM cnnfomgtfnn eccends
R € PD outside accepted iecrvciy Iimits 0riginail
U Samples with Calc-Val <MDL
Page 8 of 34

Srrnnnlil Environmentalhrhnralogiex Me, Accreditation Program
11 33101vinsr. Anal tes Re ort
RIAUM0M"ri�11 ' ItNoLaatln, �r� cny�r, oqa Malls, Oldo 44223 Y [�
Ai^tf%t k 1 L4I: i' 041vt TEL [phone] F.l.Y. [phone] W011. 20120299
Webslre: hrnm-&-irir„relrek. not
IS-Dee-20
Client: Synagro
Stt#ic: NW
Pr6ject: Wilislon WTP
Program Na1ne: NC—W W-SCM
Sample ID Matrix
Test Nwe
diinla'1C
S#a#us
20120299-001A Sludgy
IgnilabililyorSolids (SW84671030)
Igrrltabllity
A
Sludge
[III (SW90451))
Hydrogen lost (PI l)
A
Sludge
RearuveCyanide(90MR,3,32)-Solid
Cyanide, Reactive
i`t
Sludge
Reactive Sulfide(00341)f73,41
Sulfide, Iterative
N
Sludge
1'CI,P l letbicides k%Y BWA $3218
2,4,5 ]'P
A
Studre
'170LI' 1lcnbieides by HIA $32113
2,4.D
A
Sludge
TCIYMercury Analysis (S1v1.111/7470)
Mercury
A
Sludge
TCLP Metais Analysis (SW1311i6010)
Arscnic
A
Sludge
V13' M Cis15 Analysis (SW I 3 I IM010)
Barium
A
Sludge
TCLP dvlcIals Arai ysis (SW 13t 1/6010)
Cadinlrtm
A
Shtdgc
TCLP Wtals Analysis (SW 1311160 10)
Chromium
A
Sludge
11VI--P Metals Analysis (SWI31114010)
Lend
A
Sludge
TCLP Metals Analysis (SW 1311160 10)
Selenium
A
Sludge
TCLP Metals Analysis (SW 1311/6010)
silver
A
Sludge
`I'Cl P pesticides Analy-w (SW 131118081)
Clibirdane, total
A
Mudge
'1 UP Pesticides Analysis (SW 131 V8081)
Endrin
A
Sludge
TCLP Ptsticides Analysis (SW13111808 1)
gamma-171M
A
Sludge
TCLP PralicidesAnalysis (SW13111808))
Iteplachlot
A
Sludge
'IUI'PesticidesAnal ysis(SW131118081j
Hep#achlori-ImKitic
A
Sludge
TCLP Pesticides Analysis (Ml 311180811
Methovoldor
A
Sludge
TCLP Pesticides Analysis (SW 1a1118081)
1'asapluGic
A
Sludge
'FVLIISemi-VoletilesAnalysis (SW131l/8270)
1,40eblorobe ,"w
A
Sludge.
M-P Semi-Volatiles. Analysis (SW 131118270)
7,4,3-TiMilamplienul
A
Sludge
TCLP Semi-Volaliles Analysis (SW 131 NM70)
44,6•1'riidilairophenoi
A
Sludge
TCLPSemi-Volati#es AnalysislSW131118270)
2A-1)ini1r0t01ue1te
A
Sludge
T[ -P Seri-Volatiiec Analysis (SW I 3 11/82701
Cresols, Total
A
Sludg;
TOY Semi-Volatdei Analysis (SW 1311182711)
(lcnachlgrobenzene
A
Sludge
TCLP Semi-VoWilesAnalysis (SWI3II/s270)
Flrxiicliiclrobuladlertc
A
Sludge
'1'0..l' Semi-Volaules Analysis (SW I31 118270)
11exaclilarwAbone
A
Sludge
TlL LV Seri-Volatiles Analysis (SW 131118270)
N06benxrxlc
A
Sludgy
fCI..P 4cmi-Valotilrs Armlysis (SW131118110)
peatachlurnphcnal
A
Sludge
TCIX Scini-Volaldcs Arotysis (SW1311(8270)
Pyridirw
A
Y Y
NC_WW SCM A Accredited NC—WW SCM 14 Not AcerMitt d
Original 4 I
Page 9 of 34

lor Srtovilttlrttlrnrurrcural7cGM0.1agtas.lrrc Accreditation Program
33101VOS1. Anal tes Report
C-AVI ONMONTA Tt:C( Il I tall 5� INC rujwlroga rant, dlrlo 44223
rtit iy►t ! L Y t #1 TEL: [phone] E,4X' (33D) 253- 439 WOti: 20120299
i!`tahsllc; lrrlrr;fht�tet,.yrtrek,com ISpDec�2U
Client: Synagro State: NW
Project: Winstolr WTP Program Name: NC_WW—SCM
sample ID 14l8firix 'I't.St Nnuie 'Anplyle MAWS
20120299-OD I A 916dge TCLP Valatilcs Analysis 1,1,Dicldoroclhctie A
Sludge TCLP Volatilcs Analysis 1,2-Dichloroclhnnc A
Sindgc TCLP Volatilcs Anwtysis 2-Uutaimic A
Stiutgc 'TCLP Volidles Arrnlysis BcovCne A
Sludge
TCLP Volatilcs Analysis
evirbun Ictraclfloride A
Sludge
TzLPVoIndIcsAnnlysis
Chioroknzenc A
Sludge
TOY Volatilcs Analysis
Chloroform A
Slrtdgc
TUIT Volatile, Arrnlysis
Twachlormtheflu A
Sludge
WIT Volatilcs Analysis
Tridhloroellienc A
Sludge
11CL11 Volatilcs Analysis
Vinyl chloride A
t -MV $CM A AccreditM NC WW_SCM A Not Accredited
Original Ill
Page 10 of 34

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Simunr1 knitlramirmnrrrl Teehnologles, hrc.
331 R ii'iTr sr,
P�vlllQtthiCr�T�L.Tr MSUMMT
11Vr. C"u)ydrog,Rarls, Ohio 442-23 Sample Log -in Check List
AnMylfoaf Lobo toff !'lsl.: (3311} �5i-8211 Rz)Xt (330)W4,189
li'eLsiTe; IrlTi�_lhrn�,r,sellokcarrr
Client Name: SYN•NC47029 Work OrdetNurriber: 20120299 RcptNo: 1
Logged by: Jacquollne Rosite
Completed 13y: Jacquellno Restle
Reviewed ay, Jonnifer Woolf
12102020 10:55;O0 AM
1216f2620.3:47;22 PM
121712b20 2:04:11 PSI
�rf
Chain of C"fadv
1. is Chain of Custody complete? Yes 17.1 No ,+ Not Present lw)
2. How was the sample delivered? FedEx
Loo In
3. Coolers are present? Yes LV7 No NA D
4, Shipping contalnerlcooler In good condition? Yes d No E)
Custody seals Inlact on shipping conlainericooler? Yes No 11 Not Present EV.1
No, seal Date: Signed By;
5, Was an attempt made to cool the samples? Yes 101 No LJ NA
s, Were all samples received at a temperaltare of }0' C to 8,0T Yes No CAI NA 171
7; 5amplels) In proper conialner(s)? Yes L7 No 1-1
8, Sufficient sample volume for Indicated tosl(s)? Yes No 13
g, Are samples (except VOA and ONCE) property preserved? Yes FIZ Na CI
10. Was preservative added to dollies? Yes U No 11 l NA 11
11. Is the headspace In the VOA vials less than 114 Inch or 6 nim?
Yes E1
No 1-.1 No VOA Vials WJ
12, Were any sample contalnets received broken?
Yes L.!
No d
13, Does paperwork match bottle labels?
Yes (
No
(Note discrepancies on chain of custody)
14. Are matrices correctly Idenllfled on Chain of Custody?
Yes B
No
16. Is It dear what analyses Mre requested?
Yes kd
No U
16, Were all holding times able to be met?
Yes k?,
No 0
(If no, Tiollty crrsiomer for solhorizetion,)
Specil3! Hatd__i_1ng. lit appifcat�lei
17, Was client notified of et1 discrepancies with ails order?
Yes W1
No NA
Person NotlRed: /2920
Alex Fox 1217
f}ale:
By Whom: 3erPritler V+lonif Ma: Jt!1 eElAail 0 Phone rj Fax 1: 1 In Person
Regarding: sample date hated as 9122120. time as 1t3115120.
Clleni Instructions: I It tivas sePgpied on 1212120 anq time collected he II1:15 shloped el 1:00
1$, AddllOnal rarpargs:
sample date Incorrect
Coalar Inf0rrltat100
Page 34 of 34

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Swann 9/21/22
rnglkg
mg/L
Equiv Weight Milli Equiv
Sodium
384
13.0414
23 0,6137017
Calcium
2690
U039
20 4A5195
Magnesium
1330
44.023
12 3,668503
Percenl Solids
3.31
SAR
0;28
,S AR
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0,56702
i;::i 0,5( 4.452 z + 3,66858 )

Swann 10/6/22
mg/kg mq/L. Equiv Weight Milli Equiv
Sodium 406 13,0732 23 0.5884
Calcium 3410 109,802 20 5A901
Magnesium 1550 49.91 12 4.159167
Percent Solids 3.22
SAR 0.26
0.56840
Nay
5AR. - � (G`r���' -I- M�2;) 1,::1 [f,5{ a.490'1 2 + 4.15917 � )

Swann 11 /21 /22
rig/i(g mg/L
Sodium 406 12,9108
Calcium 3120 99,216
Mognasium 1360 43.248
Percent SoIlds 3.18
SAR 0.27
Na
l.
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Equiv Weight Milli EgvIV
23 0.661339
20 4.9608
12 3,604
0,W134
€,�;i 0.6( 4,9608 2 + 3.60400 z )

Swann 11/28/22
mg/kq mg/L
Sodium 333 13,0203
Calcium 2640 103.224
Magnesium 1240 48,484
Perceni Solids 3,91
Equiv Weight Milli Equiv
4 0.5661
20 5.'1612
12 4.040333
SAR 0,26
U.5G810
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)

Section 4
Maps of the residuals disposal sites

11
r

Section 5
Field soil sampling results
• Agricultural Lime Application Logs

Winston-Salem/Forsyth County Utilities
WQ0031314
2022 Residuals Land Application Report
R.W. Neilson Water Treatment Plant
140111 V
Section 1
• DEQ Form DMSDF - Class A Annual Distribution and Marketing/Surface Disposal Certification
and Summary Form
• DEQ Form DMSDF(Supp) - Class A Annual Distribution and Marketing/Surface Disposal
Certification and Summary Form (Supplemental Information)
• DEQ Form RSSF - Annual Residual Sampling Summary Form
• DEQ Form RSSF B - Annual Residual Sampling Summary Form
Section 2
• DEQ Form MFLSF - Annual Metals Field Loading Summary Form
• DEQ Form FSF - Annual Land Application Field Summary Form
Section 3
• Lab data sheets from Waypoint (nutrient, nutrient metal sampling data and chain of custody's)
• Lab data sheets from Waypoint for this permit cycle (TCLP, Corrosivity, Ignitability and Cyanide)
• Copies of our SAR/PAN calculations
Section 4
• Maps of the residuals disposal sites
Section 5
• Field soil sampling results

Section 1
• DEQ Form DMSDF - Class A Annual Distribution and Marketing/Surface
Disposal Certification and Summary Form
• DEQ Form DMSDF(Supp) -Class A Annual Distribution and
Marketing/Surface Disposal Certification and Summary Form (Supplementa
Information)
DEQ Form RSSF -Annual Residual Sampling Summary Form
• DEQ Form RSSF B -Annual Residual Sampling Summary Form

CLASS A ANNUAL DISTRIBUTION AND MARKETIIN) GI SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0031314 FACILITY NAME: Winston Salem - Neilson 1Vater Treatment Plant
Pi 01W: COITNTy: Forsyth OPERATOR: City of Winston Salem
FACILITY TYPE (please check one); El Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
E l Distribution and Markeftng (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes El No © ---r If No slip parts A, B, C and certify form helow
Part A*:
PartB*:
Month
Sources(s) (include NPDFS 4 if
applicable)
ry Winme (dtons)
Recipient Information
Amendment)
Bulling Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
February
March
April
May
NCO086011
645.5
645.5
Roger Spillman
645.5
soilamendment
June
July
August
September
October
November
December
Total from FORM DMSDF (sup)
0
0
0
D
Totals: LAnnual dry tans):
0 _
645.5 ..
645.5
645.5 .
Amendmen s) used:
Bulking Agent(s) used:
* If mare space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)0 �
Part C.
Facility was compliant during the past calendar year with all conditions of the land application permit E Yes
(including but not limlted to items 1-3 below) issued by the Dlvislon of Water Quality: 0 No --- - ► it No, Explain in Narritive
1_ All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Wafer Quality.
3_ No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under pe law, that the above information is, to the best of my knowledge and belief, true accurate and complete. I am aware that there are significant
naities for sob fats information, including the possibility of fines and imprisonment for knowing violations."
t rc X ce Dat Siguaturereparcr** Date
Rdifferent from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
OENR FORM DMSDF (1212006)

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Section 2
DEQ Form MFLSF - Annual Metals Field Loading Summary Form
® DEQ Form FSF - Annual Land Application Field Summary Form

ANNUAL METALS FDFLD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Winston Salem - Neilson WTP Total Dry Tons Applied (Annual):
Permit 0: WQ0031314 Cation Exchange Capacity (non 503 only):
Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series:
Acres Used: 22.98 Acres Permitted: 22.98 Site : DV8 Field 4:
389.97
0
WeC
10
Residual Analvsis Data (Heavv Metals and Total Phose)hoirus wise m2/ke. % Solids use Raw Percent 4l:
Sample or
Com-
posite
Date
1
Spring
Average
2
S
6
7
a
9
10
11
12
% Solids
29.4
.Arsenic
5.1
Cadmium
0,6
Copper
40.9
Chromium
52.5
Lead
26.4
Merciuy
0.1
Molyb-
denum
1.4
Nickel
23.3
Selenium
1.1
Zinc
AK8
Total
Phos-
horus
1787.5
Annual Heavy Metal Field Loadings (C lculated in lbs/acre):
Total
1
2
3
4
5
6
7
S
9
iD
11
12
Dx1Ac,/
App.
r".
Event
16.97
Arsenic
0.173
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0,000
0,000
.0.000
0,000
0.173
Cadmium
0.020
0,000
0.000
0.000
0.000,
0,000.
0,000
0,000
o.0oo
0.000
0.000
0.000
0.020
Copper
1,388
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000.
0,000
1,388
Chromium
1,782
0.000
0,000
0,000
0.000
0.000
0.000
0.000
6,000
0.000
.0,000
.0.000
1.782
Lead
0.896
0.000
.0.000
0.000
0,000
0.000
0,000
0.000
0,000
0,000
0,000
0,000
0,896
Mercury
0.003
1 0.000
0,000.
0,000
0.000
0,000 1
0,000.
0,000
0.000
0,000
0,000
0.000
0.003
Molyb-
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000.
0.048.
denum
Nickel
0,791
.6.000
0.000
0,000
0.000
0.000
0.000
0.000
'0.000
0.000
0.000
0.000
0.791
Selenium
0.037:
0,000
0.000
0.000
0.000
0.000.
'0.000
0.000
0,000
0,000
0,000
0.000
0.037
Zinc
3,625
0,000
0,000
0,000
0,000
0,000
0,000
0.000
0.000
0.000
0,000
0.000
3.625
Total
Phos-
60,668
0.000
0,000
6,000
0.000,
0.000
0,000
0,000 ;
0.000
0.000
0.000 ..
0 000
60.668
1IQrr1S
"I certtty, under penalty of law, that this uocument was prepares uncle], my direction or supervision in accoraance tivrtn
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and.
imprisonment (or lzuowing violations".
Signature of Land Applier
2/15/2023
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Winston Salem - Neilson WTP Total Dry Tons Applied (Annual): 114.39
Permit #: WQ0031314 ^ Cation Exchange Capacity (non 503 only):
Operator; Roger Spillman Owner: Roger Spillman Predominant Soil Series: RnC
Acres Used: 7.21 Acres Permitted: 7.21 Site #: DV8 Field 4: 11
Residual Analvsis Data (Heavy Metals and Total Phosphorus use xrl2llrg, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
Spring
Average
2
3
4
5
6
7
8
9
i D
] 1
12
%Solids
29.4
Arsenic
5.1
Cadmium
0.6
Copper
40.9
C11romiulp
52.5
Lead
26,4
Mercury
0.1
Molyb-
denum
1.4
Nickel
23.3
Selenium
1.1
Zinc
106.8
Total
Phos-
hOITIS
1787.5
Annual Heavy Metal Vield L,oatims (Ualculated in tbslacrel:
Total
1
2
3
4
5j
6 j
2
o
DTIAc.I
App.
R.
Event
15,87
Arsenic
0.162
0.000
0.000
0.000
0.000
0.000
0.000
0,000
OA00
0.000.
0.000
0,000
0.162
Cadmium
0,019
0,000
0.000
0,000
0.000
0,000.
0,000
0,000
0.000
0.000
0,000
0.000
0.019
Copper
1,298
0.000
0.000
0.000
0.000.
0.000
0.000
0.000..
0.000
0.000
0,000
0.000
1.298
Chromium
1.666
0.000
0.000
0,000
0.000
0,000
0,000
0,000
0,000
0,000
0.000
0.000
1.666
Lead
0.838
0,000
0.000
0,000
0,000
0,000
0.000
0,000
0.000
0.000
0,000
0,000
0,8.39
Mercury
0.003
0.000
0.000
0.000
0.000
0,000
'0.000
0.000
1 0.000
0.000..
0.000
0.000
0,003.
Molyb
0.044
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000.
0,000
0,000
0.000
0,044
denum
Nickel
0.739
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0,000
0,000
0,000
0,739
Selenium
0.035
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0,000
0,035
Zinc
3,389
0,000
0,000
OA00
0.000
0,000
0.000.,
0.000
0.000
O,000
0,000
0,000
3,389
"Total
-
-.
Phos-
56.721
0,000.
0.000
0.000
0.000..
0.000
0.000
0,000.
0.000.
0,000
0.000
0,000
56.721
horus
"l certify, under penalty of law, that this document was preparett under my direction or supervision in accornance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
z' 1)I1 Sl1(11)1
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this farm to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Winston Salem - Neilson WTP Total Dry Tons Applied (Annual): 14L14
Permit #- WQ0031314 Cation Exchange Capacity (non 503 only): 0
Operator; Roger Spillman Owner: Roger Spillman Predominant Soil Series: ChA
Acres Used: 16.26 Acres Permitted; 16.26 Site 4: DV8 Field 4: I2
Residual Analvsis Data (Heavy Metals and Total Pliosphorus use pia/k1j, % Solids use Raw Percent #):
Sa:nple or
Com-
posite
Date
1
Spring
Average
2
3
4
5
B
7
a
9
10
11
12
% Solids
29.4
Arsenic
5.1
Cadmium
0.6
Copper
40.9
Chromium
52.5
Lead
26A
Mercury
0.1
Molyb-
denum
1A
Nickel
23.3
Selenium
1.1
Zinc
106.8
Total
Phos-
hoius
1787.5
Annual Heavy Metal Field Loadinas (Calculated in lbs/acrel:
Total
11
1213
4
5 1
6
7
II
9j
LOJ
III
12
DT/Ac./
H
h
App.
Event
8.68
.
Arsenic
0.089
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.089
Cadmium
.0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.010
Copper
0.710
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0M00
0.000
0.710,
Chroir:iiurn
0.911
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.911
Lead
0.458
0.000
0.000
:0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.458
Mercury
0.002
1 0.0.00
0.000
0.000
0.000
0,000
0.000
0.000
1 0.000.
0,000.
0.000
1 0.000
.0.002
Motyb
0.024
0.000,
0.000
0A00
0.000
0.000
U00
0.000
0.000
0.000.
0.000
6.000
0.024.
denum
Nickel
0.404
0.000
0,000
0.000
0,000
0,000
0.000.
0.000
0.000
0,000
'0.000
0.000
0.404
Selenium
0:019
.0.000
0.000
0.000
0.000
0.000
0:000
0.000
0.000
0.000
0.000
0.000
0.019
Zinc
1.854
0.000
0.000
0.000
0.000
0.000
0.000.
0.000
0,000:
0,000
0,000
0.000
1,854
Total
Phos-
31.031
0,000
0.000
0.000
0.000
0.000.
0.000
0.000.
0.000
0.000:
:0.000
0.000
31,031
horns
"1 certify, under penalty or law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
�� 2/i5l2023
Date
DE NR FORM MFLSF (12/2006)

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46

Section 3
a Lab data sheets from Waypoint (nutrient, nutrient metal sampling data and
chain of custody's)
• Lab data sheets from Waypoint for this permit cycle (TCLP, Corrosivity,
Ignitability and Cyanide)
s Copies of our SAR/PAN calculations

Waypointo
ANALYTICAL
4/18/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-096-0018
Client Project Description: Winston Salem, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 4/6/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a'—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable,
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 15

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.vvaypointanatyticat.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Pro roam _
Lab Ifs
Expiration ©ate
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program - NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program - NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program - NELAP
LA037
12/31/2022
Louisiana
State Program - NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program - NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program - NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program - NELAP
460181
09/14/2022
Page 1 of 1 00001/22-096-0018
Page 2 of 15

�� ��„ 2790 Whitten Road, Memphis; TN 38133
Main 901.213.2400 °Fax [phone]
ANALYTICAL www.waypolritanalytical.com
Sample Summary Table
Report Number: 22-096-0018
Client Project Description: Winston Salem, NC
Lab No Client Sample ID Matrix Date Collected Date Received
88972
Neilson WTP 1
Solids
04/05/2022
10;00
04/06/2022
88973
Neilson WTP 2
Solids
04/05/2022
10:00
04/06/2022
88974
Neilson WfP 3
solids
04/05/2022
10:00
04/06/2022
88975
Neilson WTP 4
Solids
04/05/2022
10:00
04/06/2022
Page 3 of 15

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Winston Salem, NC
Lab Report Number: 22-096-0018
Date: 4/18/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 89453 (GP-2)
Analyte: Aluminum
QC Batch No: L610485/1-609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 89453 (GP-2)
Analyte: Arsenic
QC Batch No: L610213/1-609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 89453 (GP-2)
Analyte; Calcium
QC Batch No: L610213IL609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 89453 (GP-2)
Analyte: Iron
QC Batch No: 1-6104851609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges, No matrix interference is suspected.
Sample 89453 (GP-2)
Analyte: Potassium
QC Batch No: 1-610213/1-609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 89453 (GP-2)
Analyte: Magnesium
QC Batch No: 1-610213/1-609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 89453 (GP-2)
Analyte: Manganese
QC Batch No: L610485/1-609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges, A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 89453 (GP-2)
Page 4 of 15

0
Waypoinv.
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213,2400 ° Fax 901.213,2440
www.waypointanalytical.com
Analyte: Lead
QC Batch No: L610213/1-609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88972 (Neilson WTP 1)
Analyte: Selenium
QC Batch No: L610213/L609725
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 89453 (GP-2)
Analyte: Selenium
QC Batch No: 1-610213/1-609725
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges, A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 86807 (MW-1-4)
Analyte: Magnesium
QC Batch No: L611277/L610815
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 89062 (Mills)
Analyte: Mercury
QC Batch No: 1-610707/1-610405
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected,
Page 5 of 15

0
Waypoint
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213,2400 o Fax [phone]
www.waypointanalytical.com
Project Winston Salem, NC
Information
Report Date ; 04/18/2022
Received : 04/06/2022
Connie Cook
Report Number : 22-096-0018 REPORT OF ANALYSIS Project Manager
Lab No : 88972 Matrix: Solids
Sample ID : Neilson WTP 1 Sampled: 4/5/2022 10.00
Test Results Units MDL MQL DF Date ITime By Analytical
Analyzed Method
Moisture
71.7
%
1
04/07/22 16:58
FMM
SW-DRYWT
Ammonia Nitrogen
2953
mg/Kg - dry
56.5
353
1
04/12/22 16:15
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
38.5
mg/Kg - dry
173
17.3
1
04/12/2215:18
ZBD
4500NO3F-2016
Organic N
64883
mg/Kg - dry
56,54
353A
1
04/12/22 09:00
DH
CALCULATION
pH
5.9
S.U.
1
04/13/2215:11
DRS
9045D
Total Solids
28.3
%
0.010
0.010
1
04/07/22 16:58
FMM
2540G-2011
Total Volatile Solids
22.2
%
0.010
0.010
1
04/07/22 16:58
FMM
2540G-2011
Total Kjeldahl Nitrogen
6780
mg/Kg - dry
35.3
883
1
04/12/22 09:00
JPJ iM-4500-141-13C-TKP
Phosphorus
1830
mg/Kg - dry
9.75
17.7
1
04/12/22 01:17
TJS
6010D
Aluminum
102000
mg/Kg - dry
81.6
88.3
5
04/13/22 01:29
TJS
6010D
Arsenic
5.90
mg/Kg - dry
0.848
1.77
1
04/12/22 01:17
TJS
6010D
Cadmium
0.678
mg/Kg - dry
0.0706
0.353
1
04/12/22 01:17
TJS
6010D
Calcium
675
mg/Kg - dry
137
177
1
04/12/22 01:17
TJS
6010D
Chromium
55.8
mg/Kg - dry
0.833
0.883
1
04/12/22 01:17
TJS
6010D
Copper
42.8
mg/Kg - dry
1.10
1.77
1
04/12/22 01:17
TJS
6010D
Iron
55100
mg/Kg - dry
151
177
5
04/13/22 01:29
TJS
6010D
Lead
28.0
mg/Kg - dry
0.636
1.06
1
04/12/22 01:17
TJS
6010D
Magnesium
2530
mg/Kg - dry
9.12
17.7
1
04/12/22 01:17
TJS
6010D
Manganese
587
mg/Kg - dry
1.15
1.77
1
04/12/22 01:17
TJS
6010D
Mercury
0.0883
mg/Kg - dry
0.0234
0.0537
1
04/13/22 17:20
JTR
7471A
Molybdenum
1.51
mg/Kg - dry
0.477
0.883
1
04/12/22 01:17
TJS
6010D
Nickel
24.5
mg/Kg - dry
0.424
0.883
1
04/12/22 01:17
TJS
6010D
Potassium
2350
mg/Kg - dry
21.8
35.3
1
04/15/22 23:37
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 6 of 15

0
Waypoint,
2790 Whitten Road, Memphis, TN 38M
Main 901.213.2400 0.Fax [phone]
ANALYTICAL
www.waypointarialyticaLeom
46245
EMA Resources Inc
Project
Winston Salem, NC
Mr. Brent Collins
Report Date : 04/18/2022
755 Yadkinville Rd
Information :
Received : 04/06/2022
Mocksvilie , NC 27028
Connie Cook
Report Number : 22-096-0018
REPORT OFANALYSIS
Project Manager
Lab No : 88972
Matrix: Solids
Sample ID: Neilson WTP 1
Sampled: 4/5/2022 10.00
Test
Results
Units
MDL
MQL OF Date I Time By Analytical
Analyzed Method
Selenium
<1.13
mg/Kg - dry
1.13
1.77 1 04/13/22 01:34 TJS 6010D
Sodium
120
mg/Kg - dry
45.9
88.3 1 04/12/22 01:17 TJS 6010D
Zinc
110
mg/Kg - dry
2.86
4.42 1 04/12/22 01:17 TJS 6010D
Sulfur
2330
mg/Kg - dry
18.3
35.3 1 04/12/22 01:17 TJS 6010D
Sodium Absorption Ratio
0.25
Ratio
0.01
0.01 1 04/12/22 01:17 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
7 Estimated value
Page 7 of 15

Wayposinto
ANALYTICAL
46245
HMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number: 22-096-0018
Lab No : 88973
Sample ID : Neilson WTP 2
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax 901,213.2440
www.waypointanalytical.com
Project Winston Salem, NC
Information :
REPORT OF ANALYSTS
Report Date : 04/18/2022
Received0410612OR
4600--
Connie Cook
Project Manager
Matrix: Solids
Sampled: 4/5/ 2022 10:00
Test
Results
Units
MDL
MQL
DF
Date ITime
Analyzed
By
Analytical
Method
Moisture
71.0
111/0
1
04/07/22 16:58
FMM
SW-DRYWT-
Ammonia Nitrogen
2883
mg/Kg - dry
55,2
345
1
04/12/22 16:15
3131
4500NH3C-2011
Nitrate+Nitrite-N
26.7
mg/Kg - dry
17.2
17.2
1
04/12/22 15:20
ZBD
4500NO3F-2016
Organic N
67833
mg/Kg - dry
55.17
344.8
1
04/12/22 09:00
DH
CALCULATION
pH
5.1
S.U.
1
04/13/2215:11
DRS
9045D
Total Solids
29.0
%
0,010
0.010
1
04/07/22 16:58
FMM
254OG-2011
Total Volatile Solids
21.9
%
0.010
0.010
1
04/07/22 16:58
FMM
254OG-2011
Total Kjeldahl Nitrogen
7070
mg/Kg - dry
34.5
862
1
04/12/22 09:00
JPJ
;M-4500-NH3C-T0
Phosphorus
1870
mg/Kg - dry
9.52
17,2
1
04/12/22 01:22
TJS
6010D
Aluminum
98600
mg/Kg - dry
79.7
86.2
5
04/13/22 01:40
TJS
6010D
Arsenic
5.31
mg/Kg - dry
0.827
1.72
1
04/12/22 01:22
TJS
6010D
Cadmium
0.548
mg/Kg - dry
0.0689
0.345
1
04/12/22 01:22
TJS
6010D
Calcium
721
mg/Kg - dry
133
172
1
04/12/22 01:22
TJS
6010D
Chromium
52.8
mg/Kg - dry
0.813
0.862
1
04/12/22 01:22
TJS
6010D
Copper
42.8
mg/Kg - dry
1.07
1.72
1
04/12/22 01:22
TJS
6010D
Iron
52100
mg/Kg - dry
147
172
5
04/13/22 01:40
TJS
6010D
Lead
26.9
mg/Kg - dry
0.620
1.03
1
04/12/22 01:22
TJS
6010D
Magnesium
2430
mg/Kg - dry
8.90
17.2
1
04/12/22 01:22
TJS
6010D
Manganese
890
mg/Kg - dry
1.12
1.72
1
04/12/22 01:22
TJS
6010D
Mercury
0.0921
mg/Kg - dry
0.0209
0.0479
1
04/13/22 17:21
JTR
7471A
Molybdenum
1.47
mg/Kg - dry
0.465
0.862
1
04/12/22 01:22
TJS
6010D
Nickel
23.7
mg/Kg - dry
0.413
0.862
1
04/12/22 01:22
TJS
6010D
Potassium
2420
mg/Kg - dry
21.3
34.5
1
04/15/22 23:43
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 8 of 15

0
Waypoint,
2790 Whitten Road, Memphis, TN 38133
Main 901:213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalytical.corn
46245
EMA Resources Inc
Project
Winston Salem, NC
Mr. Brent Collins
Report Date ; 04/18/2022
755 Yadkinville Rd
Information :
Received : 04/06/2022
Mocksville , NC 27028
Connie Cook
Report Number: 22-096-0018
RFPORTOFANALYSTS
Project Manager
Lab No : 88973
Matrix: Solids
Sample ID : Neilson WTP 2
Sampled: 4/5/2022 10:00
Test
Results
Units
MDL
MQL DF Date I Time By Analytical
Analyzed Method
Selenium
<1.10
mg/Kg - dry
1.10
1,72 1 04/12/22 01:22 T3S 6010D
Sodium
130
mg/Kg - dry
44.8
86.2 1 04/12/22 01:22 T3S 6010D
Zinc
111
mg/Kg - dry
2.79
431 1 04/12/22 01:22 T3S 6010D
Sulfur
2310
mg/Kg - dry
17.9
34.5 1 04/12/22 01:22 T3S 6010D
Sodium Absorption Ratio
0.27
Ratio
0.01
0,01 1 04/12/22 01:22 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
3 Estimated value
Page 9 of 15

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
279D Whitten. Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.wayoointa nalytical. corn
Project Winston Salem, NC
Information :
Report Date ; 04/18/2022
nnReceived�� 0bb4/06/2022
L C��
Connie Cook
Report Number: 22-096-0018
REPORTOFAIMALYSIS
Project
Manager
Lab No : 88974
Matrix;
Solids
Sample ID : Neilson WTP 3
Sampled; 4/5/2022 10:00
Test
Results
Units
MDL
MQL
AF
Date I Time
By
Analytical
Analyzed
Method
Moisture
68.9
%
1
04/07/22 16:58
FMM
SW-DRYWT
Ammonia Nitrogen
1073
mg/Kg - dry
51.4
322
1
04/12/22 16:15
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
27,0
mg/Kg - dry
14.0
14.0
1
04/12/22 15:20
ZBD
4500NO3F-2016
Organic N
50063
mg/Kg - dry
51.45
321.5
1
04/12/22 09:00
DH
CALCULATION
pH
6.2
s.u.
1
04/13/2215:11
DRS
9045D
Total Solids
3ILJ
%
0.010
0.010
1
04/07/22 16:58
FMM
2540G-2011
Total Volatile Solids
21,8
%
0.010
0.010
1
04/07/22 16:58
FMM
2540G-2011
Total Kjeldahl Nitrogen
5110
mg/Kg - dry
32.2
804
1
04/12/22 09:00
JPJ iM-4500-NH3C TKP
Phosphorus
1690
mg/Kg - dry
8.87
16.1
1
04/12/22 01:27
TJS
6010D
Aluminum
93600
mg/Kg - dry
743
80.4
5
04/13/22 02:00
TJS
6010D
Arsenic
4.44
mg/Kg - dry
0,771
1.61
1
04/12/22 01:27
TJS
6010D
Cadmium
0.502
mg/Kg - dry
0.0643
0.322
1
04/12/22 01:27
TJS
6010D
Calcium
627
mg/Kg - dry
124
161
1
04/12/22 01:27
TJS
6010D
Chromium
49.5
mg/Kg - dry
0.758
0,803
1
04/12/22 01:27
TJS
6010D
Copper
38.6
mg/Kg - dry
0.997
1,61
1
04/12/22 01:27
TJS
6010D
Iron
45700
mg/Kg - dry
137
161
5
04/13/22 02:00
TJS
6010D
Lead
24.8
mg/Kg - dry
0.578
0.964
1
04/12/22 01:27
TJS
6010D
Magnesium
2280
mg/Kg - dry
8.30
16.1
1
04/12/22 01:27
TJS
6010D
Manganese
447
mg/Kg - dry
1.05
1.61
1
04/12/22 01:27
TJS
6010D
Mercury
0.0920
mg/Kg - dry
0.0210
0.0482
1
04/13/22 17:23
JTR
7471A
Molybdenum
1.27
mg/Kg - dry
0.434
0,803
1
04/12/22 01:27
TJS
6010D
Nickel
22.1
mg/Kg - dry
0.385
0.803
1
04/12/22 01:27
TJS
6010D
Potassium
2150
mg/Kg - dry
19.9
32.2
1
04/15/22 23:58
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 10 of 15

0
Waypoe
2790 Whitten
Road, Memphis, TN 38133
�T
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalytical.com
46245
EMA Resources Inc
Project
Winston Salem, NC
Mr. Brent Collins
Report Date : 04/18/2022
755 Yadkinville Rd
Information
:
Received ; 04/06/2022
Mocksville , NC 27028
Connie Cook
Report Number: 22-096-0018
REPORT OF.
NALYSTS
Project Manager
Lab No : 88974
Matrix: Solids
Sample ID : Neilson WTP 3
Sampled: 4/5/2022 10:00
Test
Results
Units
MDL
MQL DF Date 1 Time By Analytical
Analyzed Method
Selenium
<1.03
mg/Kg - dry
1.03
1.61 1 04/12/22 01:27 TJS 6010D
Sodium
105
mg/Kg - dry
41.8
80.4 1 04/12/22 01:27 TJS 6010D
Zinc
101
mg/Kg - dry
2.60
4.02 1 04/12/22 01:27 TJS 6010D
Sulfur
2120
mg/Kg - dry
16.7
32.2 1 04/12/22 01:27 TJS 6010D
Sodium Absorption Ratio
0.24
Ratio
0.01
0.01 1 04/12/22 01:27 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Estimated value
Page 11 of 15

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 G Fax [phone]
www.waypointanalyticall.com
Project Winston Salem, NC
Information :
Report Date : 04/18/2022
Received
AA 04/06/2022
6�OL
Connie Cook
Report Number : 22-096-0018
REPORT OPANALYSIS
Project
Manager
Lab No : 88975
Matrix:
Solids
Sample ID : Neilson WTP 4
Sampled:
4/5/2022 10:00
Test
Results
Units
MAL
MQL
DF
Date ITime
By
Analytical
Analyzed
Method
Moisture
70.9
%
1
04/07/22 16:58
FMM
SW-DRYWT
Ammonia Nitrogen
1903
mg/Kg - dry
55.0
344
1
04/12/22 16:15
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
32.6
mg/Kg - dry
16.5
16.5
1
04/12/22 15:21
ZBD
4500NO3F-2016
Organic N
5000 3
mg/Kg - dry
54.98
343.6
1
04/12/22 09:00
bH
CALCULATION
pH
5.6
s.u,
1
04/13/2215:11
DRS
9045D
Total Solids
29.1
%
0.010
0.010
1
04/07/22 16:58
FMM
2540G-2011
Total Volatile Solids
22.3
%
0.010
0.010
1
04/07/22 16:58
FMM
254OG-2011
Total Kjeldahl Nitrogen
5190
mg/Kg - dry
34.4
859
1
04/12/22 09:00
JPJ iM-4500-NH3C-TKP
Phosphorus
1760
mg/Kg - dry
9.48
17.2
1
04/12/22 01:32
TJS
6010D
Aluminum
96900
mg/Kg - dry
79.4
85.9
5
04/13/22 02:10
TJS
6010D
Arsenic
4.78
mg/Kg - dry
0.824
1.72
1
04/12/22 01:32
TJS
6010D
Cadmium
0.522
mg/Kg - dry
0.0687
0.344
1
04/12/22 01:32
TJS
6010D
Calcium
656
mg/Kg - dry
133
172
1
04/12/22 01:32
TJS
6010D
Chromium
51,9
mg/Kg - dry
0.810
0.859
1
04/12/22 01:32
TJS
6010D
Capper
39.2
mg/Kg - dry
1,07
1.72
1
04/12/22 01:32
TJS
6010D
Iron
52200
mg/Kg - dry
146
172
5
04/13/22 02:10
TJS
6010D
Lead
25.9
rng/Kg - dry
0,618
1.03
1
04/12/22 01:32
TJS
6010D
Magnesium
2360
mg/Kg - dry
8,87
17.2
1
04/12/22 01:32
TJS
6010D
Manganese
570
mg/Kg - dry
1.12
1.72
1
04/12/22 01:32
TJS
6010D
Mercury
0.0332
mg/Kg - dry
0.0201
0,0460
1
04/13/22 17:24
JTR
7471A
Molybdenum
1.38
mg/Kg - dry
0.463
0,859
1
04/12/22 01:32
TJS
6010D
Nickel
23.0
mg/Kg - dry
0.412
0,859
1
04/12/22 01:32
TJS
6010D
Potassium
2240
mg/Kg - dry
21.2
34.4
1
04/16/22 00:04
EAL
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 12 of 15

0
Waypoint,
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax 901.213,2440
ANALYTICAL
www.waypointenalytical.com
46245
EMA Resources Inc
Project
Winston Salem, NC
Mr. Brent Collins
Report Date : 04/18/2022
755 Yadkinville Rd
Information :
Received : 04/06/2022
Mocksville , NC 27028
Connie Cook
Report Number: 22-096-0018
REPORTOFANALYSIS
Project Manager
Lab No : 88975
Matrix: Solids
Sample ID : Neilson WTP 4
Sampled: 4/5/2022 10:00
Test
Results
Units
MDL
MOL ©F Date I Time By Analytical
Analyzed Method
Selenium
<1,10
mg/Kg - dry
1,10
1.72 1 04/12/22 01:32 TJS 6010D
Sodium
108
mg/Kg - dry
44.7
85.9 1 04/12/22 01:32 TJS 6010D
Zinc
105
mg/Kg - dry
2,78
4.30 1 04/12/22 01:32 TJS 6010D
Sulfur
2220
mg/Kg - dry
17.8
34.4 1 04/12/22 01:32 TJS 6010D
Sodium Absorption Ratio
0.23
Ratio
0,01
0.01 1 04/12/22 01:32 CALCULATION
Qualifiers/ DF Dilution Factor J Estimated value
Deflnitions
Page 13 of 15

Wavgo go nt 2790 Whitten Road, Memphis, TN 38133
P0Main 901.213.2400 o Fax [phone]
ANALYTICAL www.wavpointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-096-0018
Shipping Method
Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
r102
Shipping container/cooler uncompromised?
Yes
0 No
Number of coolers/boxes received
F1
Custody seals intact on shipping container/cooler?
0 Yes
0 No
0 Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
Yes
0 No
COC properly completed
0 Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
DO Yes
No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
N/A
F_ High concentration container (48 hr)
F Low concentration
EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low conc
pre -weighed
vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes (#) No
Comments:
Signature: Imakayla Weaver Date & Time: 04/06/2022 10:20:20
Page 14 of 15

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Neilson #1
mg/kg mg/L Equiv Weight Milli E;quiv
Sodium 120 33.96 23 1.476522
Calcium 675 191.025 20 9.55126
Magnesium 2530 715.99 12 59.66583
Percent Solids 28.3
SAR
0,25
SAR = NQ+
2(C,9,++Mfl2 ))
1.47652
0.5( 9.5513 z + 59.66583 z )

3ca r t
_3...31M-
L 6 7S-m .._X_._ _.a g f L m5f /L - 4 �. �s_ IL
7k5� 9PL
f � I Li
3 LI
PA /V
f:m. R. x-C-aclv - ,v)q a J- Alo
Al
38s- M a, 7 S'O

Neilson #2
mg/kg mglL Equiv Weight Milli Equiv
Sodium 130 37.7 23 1.63913
Calcium 721 209,09 20 10.4545
Magnesium 2430 704.7 12 58.725
Percent Solids 29
SAR 0.28
SAR =
Na+
z (Caz+ + Mg2+ )
1.63913
0.5( 10.455 x + 58.72500 : )

S
C6 �?� 9)
-

Neilson #3
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
105
32.655
23 1.419783
Calcium
627
194.997
20 9,74985
Magnesium
2280
709.08
12 59.09
Percent Solids
31.1
SAR 0.24
SAR Na+
a (0a2+ + Mg2+
1.41978
0.5( 9.7499 z + 59,09000 )

- SAl
6 '7)]
PAN = a;0cR1`1

Neilson #4
mgtkg mg1L Equiv Weight Milli Equiv
Sodium 131 38.121 23 1,657435
Calcium 761 221.451 20 11.07255
Magnesium 3760 1094.16 12 91.18
Percent Solids 29.1
SAR 0.23
1.65743
Na+
SAR — 0.5( 11.073 z + 91.18000 z )
z(Caz+ + Mgzi-

a v1
4 __ 9 42-----

SAR and PAN Verifications for 2021
Dry Tans 129.39
Gallons Hauled 910,000
Solids = MI
mg/kg Mg/I meq
Sodium 394 13.041 0.5670
Calcium 200 89_039 4.4520
Magnesium 1330 44.Q2.3 3.6686
Sodium Adsorbtion Ratio 02$14:
SAR = Na meq/sq rt((Ga meq + Mg rneg)/2)
Mineral€ration Rate
0.4
TKN
33600
Arnmonia-Nitrogen
ME)
Nitrate + Nitrite
143
Plant Available Nitrogen = 1 .
RAN = (Miry Rate * (TKN - NH4)) + (0,5 NH4) + Nitrate + Nitrite

10166 Z%-
SAR and PAN Verifications for 2021
Ory Tons 129.39
Gallons Mauled 910,000
% Solids = 3.22
mglkg mg/l meq
Sodium 406 13.073 0.5684
Calcium 1410 109,802 S.4901
Magnesium 1550 49.910 4.1592
Sodium Adsorbtion Ratio `: 0 2 ,
SAR = Na meq/sq rt((Ca meq M8 meq)/2)
Mineralization Rate 0.4
TO 30900
Ammonia -Nitrogen 4840
Nitrate * Nitrite 152
Plant Available Nitrogen = 1299,6
PAN = (Min Rate * (TKN • NH4)) + (0,5 * NH4) + Nitrate + Nitrite

/n-
SAR and PAN Verifications for 2021
Dry Tans 129.39
Gallons Hauled 5io,000
ve Solids = 3.18
mg/kg mg/i meq
Sodium 406 12,911 0.5613
Calciurn 3120 99.216 4.9608
Magnesium 1360 43.248 3,6040
Sodium Adsorbtion Ratio
SAR = Na meglsq rt((Ca meq + Mg meq)/2)
MlOralization Rate o.4
TO 9250
Amrrtonia-Nitrogen 6090
Nitrate+ Nitrite 154
PlantAvailabie Nitrogen= 4463'
PAN = (Min Rate * (TKN - NH4)) + (0.5 * NH4) + Nitrate + Nitrite

SAR and PAN Verifications for 2021
11ryT6ns 12939
Gallons Hauled 910,000
Solids = 3.91
mg/kg mg/I meq
Sodium 333 11020 0,5661
CalCiklm 2640 103.224 5,1612
Magnesium 1240 48,484 4,0403
Sodium Adsorbtion Ratio; ; �}
5AR = Na meq/sq rt((Ca meq + Mg meq)/2)
Mineraiization Rate 0.4
TKN 22100
Ammonia -Nitrogen 5260
Nitrate + Nitrite 126
Plant Available Nitrogen ^ 9492
PAN = Win Rate * (TKN - NH4)) + (0.5 * N114) + Nitrate + Nitrite

Section 4
® Maps of the residuals disposal sites

P-M 671
® Field soil sampling results

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9

EMh Resources, Inc,
755 Yadkinvi Ile Rd
Mocicsville, NC 27029
Bill TO
City of Winston Satan, NC
PO 110x 2511
Winston SAW1, NC 27102
Alin: Accpxjnts Payable
-Rr °r�tr1-res, Lac
Invoice
Date Invoice #
5f31/2022 7614
P.C. No,
Terms
Projoct
Quantity
Description
Rate
Amount
2,591
65
Und Application 5M22 - 5119122
103 Ids @� 2,591 C'.Y @ S I SAS
Agrlcultutal Lime - 65 ton G S74
18.45
74.00
47,80.1.95
4,810.00
Total $52,613.95
i'IV lfW JJV'IJ.7PI-PI ^--a-nn a,u'I.i1'J4-4
755 Yadkinvillc Road — Mocksville; NC 27028