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HomeMy WebLinkAboutWQ0007349_2022 Residual Annual Report_20230224 (2)Initial Review Reviewer Nathaniel.Thornburg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2022 Permit Number (IR) * WQ0007349 Applicant/Permittee Yadkin Valley Sewer Authority Email Notifications Does this need review by the hydrogeologist? * Yes U No Regional Office Winston-Salem CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Zach Key Email Address* zachkey@usbiosolids.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 3367776909 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0007349 Has Current Existing permit number Applicant/Permittee Address* 500 North Carolina 268 W, Elkin, NC 28621 Facility Name* Yadkin Valley Sewer Authority Class B Residuals Program Please provide comments/notes on your current submittal below. Land Application Report for the Yadkin Valley Sewer Authority, Permit No. WQ0007349 At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) 2022 Annual Report YVSA.pdf 1.94MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/24/2023 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0007349 County: SLIM Year: 2022 Facility Name (as shown on permit): Land Application Operator: Yadkin Valicy Sayer Authority Phone: 336-777-6909 Land application of residuals as allowed by the permit occurred during the past calendar year'' R) Yes LJ No - If No, skip Part A, and Part B anti proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summarv: Total nunlhcr ol*application fields in the ermil: t0 Total number of fields utilized for land application during the ycar:1 3 Total amount of dry tons applied dUring the year for all application sites: $3,17 Total number of acres utilires for land application during the year: 26.3 Part B - Annual Comniance Statement: US Biosolids. file. Facility was compliant during calendar year 2022 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. Ll Yes J No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. I ) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pf I was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH ofat least 6.0 or the limit specified in the permit. 3) Annual soils analysis were perl'ormed on each site receiving residuals during the past calendar year and three (3) copies oflaboratory results are attached. 4) Annual TCI.P analysis (ifrequired) was performed and three (3) copies ofeertilied laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) 'The facility did not exceed any of'the Pollutant Concentration Limits in 15A NCAC 02T .1 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .I 105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring.; and reporting requirements in I5A NCAC 02T .I I I I %+cre complied with (applicable to 40 CFR Part 503 regulated facilities). 9) AIi operations and maintenance requirements in the permit were complied with or. in the case ofa deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to inelude appropriate: actions and remcdiations. 1 1) Vegetative cover was maintained and proper crop management was performed on each site receing residuals. as specified in the permit. 12) No runoffofresiduals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application ofresiduals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the Possibility of fines and imprisonment for knowing violations." J&f rCs IL rJ 0 Y111-S�aI�ttreive. �rreCTaY Perm' tcc Name and Title (type or print) Signature oi'Pernlrttee Date //a&lad (- /� Signature of Preparer* Date 01'different from Permittee) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T 1"7b'=3 Signature of l.an Applier Date (if'different from Permittee and Preparer) .1 102 (26) DENR FORM ACF (12/2006) m Q. Cd R 3 O CC L O AZ m m >1 M O O O I t� Q O O C..J O n [G C/} CA -- rr N N r- N OO M 00 c t `4 v _ 5 F— a u S CV 7 I z a, M O O O L� O 0 U O a3 N i f.� �p O CN nO O 00 _q frI O F%1 o_ CV �O M ON O CS fn, Ile _fJ ^ a O Q u cC ^ 0 i Iz�'A ^4 -,ar O Q 0. C� Q V/ a O N (_V 77, LL U) U) QC 2i Of O LL ly Z W 0 ANNUAL. METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Yadkin Valley Sewer Authority Total Dry Tons Applied (Annual): Permit #: WQ0007349 Cation Exchange Capacity (non 50.3 only): Operator: Bill Ilinson Owner: Bill Hinson Predominant Soil Series: Acres Used: 9.3 Acres Permitted: 9.3 Site #: 131101 Field #: 45.58 FcB2 131401 Residual Analvsis Data (Heavy Metals and Tntal Phncnhnrns imp ma/lra °/ .Cnlirle m.vP 12-a , Pae•. -* "1. Sample or Com- posite Date 1... 3114/22 2 3.i 4._ 56.. 7.' & ` 9. 10 11 12 ' Solids 2.95 Arsenic 16.7 Cadmium 3.33 Copper 205 Chromium 24.4 Lead 17.7 Mercury 2.91 Molyb denum 833 Nickel 17.7 Selenium 16.7 Zinc 517 Total Phos- horus 31100 txnnuai ileavv tvietai riew t,oaatngs tt.alculated In lbc/acrol- Total 2 3.: a 5 6 7; 8 9 10 11 12 DT/Ac./ c App. Event 4.90 y Arsenic 0.164 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.164 Cadmium 0.033 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.033 Copper 2.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.009 Chromium 0.239 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.239 Lead 1 0.173 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.173 Mercury 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Molvb- denum 0.082 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.082 Nickel 0.173 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.173 Selenium 0.164 0.000 0.000 1 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.164 Zinc 5.068 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5.068 Total Phos- 304,842 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 304.842 horus e,-.eI--. _I_ - ---.,,, �,�..u.., .,, ."TV, . Nat III, P t MAIuIrIn wa, pr-cparru unuer my uireenon or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of land Applier Date DENR FORM MFLSF (12/2006) a M C a N a u Ed N u O O i N a C: E 2 z � �• CCI [T] — f a L L O V 3 � O O :1 — C` •^ � 1 r f, CQ N 7 oz c o O 'J C f In C-1 Cl c� W M Ammonia �' oc t r-' a Nitrogen F e n n N^ o N a } m Mineralization In ^ ^00a ri M r In W �- Volatilization �n �n �n O N oc M. ,p n -� C Raw* o o a o o M 7 0 c Applicution fy N C ,n Melhod" - V O G. ul Li. N M M f r u . — 0 O — N f 5 7:3 73 o U N M �, •J aY- •7 r^ oc rt h In 4 N N N .o rn r_ o M a -.-- L N C N M P P P O 0 0 0 0 0 '� P Q 'J` � � i _ _ r•i � � M C r] v. ~ O o b O v-, o n aJ M 'O C ro cU7DQ > t.l j U O W N �1 ^1 a0 Ile(] N N N C O L E L U a a a !C s y aJ L � v� s� �Q aJ C � OL � � L � O rn +•" � C tQ a y Q' '3 C to U tU t. c •_ fj -a o a cp r-. L C.J D GJ G i 3 ; L � C � C E17 CIO O -- DL � a 3 0 C r 'LJ E e CC i- OJ qj L C C S v E R ca es u y � o c �. 6J CIO 7 qj � � c L^ C a � c u Q :C � tr c � m ANNUAL, METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Yadkin Valley Sewer Authority Total Dry Tons Applied (Annual): 15.99 Permit #: WQ0007349 Cation Exchange Capacity (non 503 only): Operator: Hill Hinson Owner: Bill Hinson Predominant Soil Series: FcB2 Acres Used: 10.1 Acres Permitted: 10.1 Site #: B1102 Field #: BH02 Residual Analysis Data (Heavy Metals and "Total Phncnhorw> ttcr mo/Lo °/ Cnlirtc iirN +li. Sample or COn1- posite Date 1.. 3/ 14/22 2_ 3_; 4 12' % Solids 2.95 Arsenic 16.7 Cadmium 3.33 Copper 205 Chromium 24.4 Lead 17.7 Mercury 2.91 Molyb- denum 8.33 Nickel 17.7 Selenium 16.7 Zinc 517 Total Phos- horus 31100 r.uuuat rrieavy MUM rie►u imauintis it aicuiatea in inslacrel: -total ? 3` 4' 5 6 7l 8' 9 10 11 12' D-r/Ac) - c App- f.:vcnt 1.58 Arsenic 0,053 0.000 0,000 0.000 0,000 0.000 0.000 0.000 0.000 1 0.000 0.000 0,000 1 0.053 Cadmium 0,011 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Copper 0.649 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.649 Chromium 0.077 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.077 Lead 0,056 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 Mercury 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Molyb denulrr 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Nickel 0.056 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 Selenium 0,053 0.000 0.000 0.000 0.000 0,000 1 0.000 0.000 0.000 1 0,000 0.000 0.000 0.053 zinc 1.637 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1,637 Total Phos- 98.463 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 98.463 horus .o. . «.... , -It Vi F,ruartj in 14", ulai uns uoCu111e11t Was prepares unuer my uireetion or supervision In accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of band Applier Date DENR FORM MFLSF (12/2006) U F5 M rL, 75 _ J i f K+ fl 'J v .... a cz Q d O O O O O C O R M M Allifillllia Nilrogen � �� � N � rr ri C. O Ol '•' Lz Mineralization hate*** ` 7. c o n a ee •� Volatilization ��, f, .:r f2 ilEe#* C. 5o p N ry 7 Application Method* J• �l ti L O p kn -,T C n cC 5 U 0 oc C ✓ < J _� _ C C 4 _ ry a 3 3 a U o c o U — �. O -p �n c f fi U ca 0. C 6 0 >73 ^� o J = = j = c U -� w a LJJUOw N _ y rr ¢ O c O L E 10 ��pC1 Qa Uric a 0 0 N N LL U- O LL Z W ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to he submitted in Annual Report Facility Name: Yadkin Valley Sewer Authority Total Dry Tons Applied (Annual): 21.59 Permit #: WQ0007349 Cation Exchange Capacity (non 503 only): Operator: Bill Hinson Owner: Bill I linson Predominant Soil Series: FcB2 Acres Used: 6.9 Acres Permitted: 6.9 Site #: 13115 Field #: B115 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/leg, Solids use Raw percent #): Sample or 2^ 3 4. 6_ 7_..' 10 11 12 Com- __.... posite Date 3/14!22 %Solids F2.95 Arsenic6.7 Cadmium 3.33 Copper 205 =hromium 24.4 Lead 17.7 Mercury 2.91 Molvb- 19 denum Nickel 17.7 Selcniunl 16.7 "Zinc 517 Total Phos- 31100 Annual heavy Metal Field Loadings (Calculated in Ibs/acre): Total.. z_. 3.; 4$ 6 7 8 9 10 11 1 112 --T UrAc. fl App. m I'ycnt 3.13 1 1 1 Arsenic 0.105 0.000 0.000 0.000 Cadmium 0.021 0.000 0.000 0.000 Copper 1.283 0.000 0.000 0,000 hromium 0.153 0.000 0.000 0.000 Lead 0.111 0.000 0.000 0.000 Mercury 0.018 0.000 0.000 1 0.000 Molyb- demim 0.052 0.000 0.000 0.000 Nickel 0.111 0,000 0.000 0,000 Selenium 0.105 0.000 0.000 0.000 Zinc 3.235 0.000 0.000 0.000 Total 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.105 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.283 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.153 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.111 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.111 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.105 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 3.235 Phos- 194.624 0.000 0.000 O.I o.000 1 0.000 1 0.000 10.000 10.000 10.000 10.000 0.000 194.6 _1_ _.. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of and Applier Date DENR FORM MFLSF (12/2006) v -- B75 N U n p n n G j O L J Q f`I c o c o o 0 0 G c o Q a J M x Q o c o 0 o ca a P° pp u c Im n n E m y p_ Ammonia x Nitrogen E- N e-i a 7 5_ Mineralization z r x n Rate*** s 0 3 0 r `0 '-' Volatilization +n �n C n r�{ x Ratc** c S n [- c fi c Application � C-4 Method* — m L t r 4? n — C :1: v 7:3 u_ M r7 7 i3 �n •-- x G o o o _ �2 M r C O C G C^ G G C O Q- — C o f 0 fS"I N U � � O J x {� r > p# N r n (-I 0 K y^ > Lj t _R —may U Q ttlUO[N o r { o L .to olecl y 7� ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Yadkin Valley Sewer Authority WQ Permit Number: WWTP Name: Yadkin Valley Sewer Authority NPDES Number: Monitoring Period: From Ill/2022 To 12/31/2023 WQ0007349 NCO020567 Pathogen Reduction f 15A NCAC 021' .1106) - Please indiente level nehieverl and altvrnatwn nPrfnvmoA- Class A: Alt. A (tine' temp) - Alt B (Alk Treatnent) Alt. C (Prior Testing)'D Alt.D (No Prior Test) Ll Process to Further Reduce Pathogengs Ll If applicable to alternative performed) (Class A on[-,,) indicate "Process to Further Reduce Pathogens': Compost ❑ Heat Drying 0 Iieat Treatment $,..J Thertnopliilic D Beta Ray Ll (;anima Ray Ll Pasteurization 0 Class B: JAIL (1) Fecal Density Alt. (2) Process to Sigtiilicantly Reduce Pathogens LJ If applicable to alternative performed ((lass B only) indicate "Process to Significant) Reduce Pathogens": Lime Stabilization LJ Air Drying Ll Composting J jAcroblic Digestion iJ Anaerobic Digestior Ll If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g Number o Excee- clences Frequency of Analysis Sample Type na ytica -11ech nioue Mimmurn Geo. Mean MaxiMLIM Units Fecal Colilorm 2 x 10 to the 6th power per gram of total solids MPN 1 b340 42978 162338 MPN/g 0 7 grab sm9221 C1=U 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 Ygrams total solid (dry Weight) vector AtIracnon rceuucnon t 1-�A NIL AIL- VL 1 .I 111 /1 - I lease indlente alternative nerfnrmod- Alt.I (VS reduction) Lj Alt. 2 (40-day bench) LJ Alt. 3 (30-day bench) WAR. 4 (Spec. O, uptake) Alt. 5 (14-Day Aerobic) ®I Alt. 6 (Alk. Stabilization L] Alt 7 (Drying - Stable) �J Alt. S (Drying - Unstable) F1 Alt. 9 (Injection) Lj Alt. 10 (incorporation) Lj No vector attraction reduction alternatives were performed �r.tc t IV 1fLA t 1CJtr 51 A 1 LIV1P.IV l (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02117 .1107 have been met." ii "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." �GL Dennis Key US Biosolids. Inc. Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 21-.1 102 (26) DENR FORM PVRF 02T (12/2006) Waypointo ANALYTICAL 46381 US Biosolids Inc Dennis Key 958 Hoots Road Roaring River , NC 28669 Report Number : 22-074-0003 Lab No : 57146 Sample ID : Yusa Project Yusa Information : 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271.6446 www.waypointanalytical.com REPORT OFANALYSIS Report Date: 03/23/2022 Received : 03/15/2022 44 1AWI( 6/0"I i Pauric Mc Groary MD., CPA Agronomist Matrix: Solids Sampled: 3/ 14/ 2022 13:00 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 97.0 % 0.010 1 03/16/2216:04 FMM 5M-2540G Sulfur 6630 mg/Kg - dry 333 1 03/19/22 11:13 EAL 6010D Calcium 7670 mg/Kg - dry 1670 1 03/19/22 11:13 EAL 6010D Aluminum 59700 mg/Kg - dry 167 1 03/19/22 11:13 EAL 6010D Manganese 483 mg/Kg - dry 16.7 1 03/22/22 04:00 EAL 6010D Organic N 37830 mg/Kg - dry 8333 1 03/21/22 11:30 CALCULATION Nickel 17.7 mg/Kg - dry 8.33 1 03/19/22 11:13 EAL 6010D Lead 17.7 mg/Kg - dry 10.0 1 03/19/22 11:13 EAL 6010D Arsenic <16.7 mg/Kg - dry 16.7 1 03/19/22 11:13 EAL 6010D Selenium <16.7 mg/Kg - dry 16.7 1 03/19/22 11:13 EAL 6010D Test Results Units MQL DF Date 1 Time By Analytical Analyzed Method Total Solids 2.95 % 0.010 1 03/16/2216:04 FMM SM-2540G Phosphorus 31100 mg/Kg - dry 167 1 03/19/22 11:13 EAL 6010D Copper 205 mg/Kg - dry 16.7 1 03/19/22 11:13 EAL 6010D Total Kjeldahl Nitrogen 43000 mg/Kg - dry 8330 1 03/21/22 11:30 ]P] ;M-4500-NH3C-TKP Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit Definitions Waypointo ANALYTICAL 46381 US Biosolids Inc Project yusa Dennis Key 958 Hoots Road Information Roaring River , NC 28669 Report Number: 22-074-0003 Lab No : 57146 Sample ID : Yusa 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waVpoiiitanalytical.com REPORT OFANAL YSIS Report Date : 03/23/2022 Received : 03/15/2022 To.wil 01 &/0-W� Pauric Mc Groary Ph.D., CPA Agronomist Matrix: Solids Sampled: 3 / 14/ 2022 13:00 Potassium 5400 mg/Kg - dry 333 1 03/19/22 11:13 EAL 6010D Magnesium 3170 mg/Kg - dry 167 1 03/19/22 11:13 EAL 6010D Sodium 2170 mg/Kg - dry 833 1 03/19/22 11:13 EAL 6010D Iron 20500 mg/Kg - dry 333 1 03/22/22 04:00 EAL 6010D Zinc 517 mg/Kg - dry 41.7 1 03/19/22 11:13 EAL 6010D Ammonia Nitrogen 5170 mg/Kg - dry 3330 1 03/22/22 09:30 JPJ SM-4500-NH3C Nitrate+Nitrite-N < 159 mg/Kg - dry 159 1 03/22/22 14:29 ZBD 4500NO3F-2011 Cadmium <3.33 mg/Kg - dry 3.33 1 03/19/22 11:13 EAL 6010D Chromium 24.4 mg/Kg - dry 8.33 1 03/19/22 11:13 EAL 6010D Mercury 2.91 mg/Kg - dry 0,473 1 03/21/22 14:45 ZMT SW-7471B pH 6.0 S.U. 1 03/22/2215:55 DRS 9045D Molybdenum <8,33 mg/Kg - dry 8.33 1 03/19/22 11:13 EAL 6010D Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit Definitions SAR Sodium Absorption Ratio Na M /L Ca M /L WaLIM /L Na: Sodium (Mg/L) Equivalent weight: 23 64.015 226.265 1 64.015 Ca'. Calcium (Mg/L) Equivalent weight: 20 Mg : Magnesium (MgIL) Equivalent weight. 12 Na_(ME) Ca_PE). MglM.E,) 2.783261 11.31325 5.334583 Milli Equivalent = MgIL / Equivalent weight The amour amount of E SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power Permitting ; SAR = 0.964695 (From MgIL entered above) SAR= 0.971894 (From ME entered below) Na (M.0 Ca (ME) Ma (ME} 2.8 1 11.3 1 5.3 \\ / f x cn / / E / 0 i i N 7 T + 2 � � k x 0) � AM I � CL .0 a k � S � ) t2 t� k 2 k� Analytical Results U.S. Biosolids Inc 958 Hoots Road Roaring River, NC 28669 Receive Date: 09/22/2022 Reported: 10131 /2022 For: YVSA Comments: Sample Number Parameter Sample ID Result 220922-28-01 30 Day Benchscaie YVSA 5.4 Respectfully submitted, Melissa Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 STATESVILLE ANALYTICAL Unit Method Analyzed Analyst % EPA625-R 9210 09/22/2022 MD PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 5 30 Day Bench Worksheet Sample 1D # 220922-28-01 WEEK 1 Samples Total Solids Volatile Solids % Volatile Fraction 1 1.07 0.58 2 1.07 0.58 3 1.07 0.57 Average: 1.07 0.58 0.5421 WEEK 2 Samples Total Solids Volatile Solids % Volatile Fraction 1 1.10 0.59 2 1.08 0.58 3 1.06 9.57 Average: 1.08 0.58 0.5370 WEEK 2 Samples Total Solids Volatile Solids % Volatile Fraction 1 1.08 0.58 2 1.08 0.58 3 1.07 0.57 Average: 1.08 0.58 0.5370 WEEK 4 Samples Total Solids Volatile Solids % Volatile Fraction 1 1.08 0.58 2 1.05 0.57 3 1.08 0.58 Average: 1.07 0.58 0.5421 WEEK 5 Samples Total Solids Volatile Solids % Volatile Fraction 1 1.12 0.60 2 1.12 0.60 3 1.12 0.60 Average; 1.12 0.60 0.5357 WEEK 6 Samples Total Solids Volatile Solids "/o Volatile Fraction 1 1.05 0.55 2 1.06 0.57 3 1.06 0.57 Average: 1.06 0.56 0.5283 Van Kleeck Reduction: 0.5421 - 0.5283 X 100 = 5.40 % 0.5421 - ( 0.5421 X 0.5283) Final Result: 5.4% PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 5 of 5 Analytical Results U.S. Biosolids Inc 958 Hoots Road Roaring River, NC 28669 Receive Date: 03/03/2022 Reported: 03/07/2022 For: YVSA Comments: Geometric Mean: 42,978 MPN/g (Most probable number) STATESVI LLF ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 220303-21-01 Fecal Coliforms 1 162338 MPN/g SM92210E-2006 03/03/2022 MD 220303-21-01 Percent Solids 1 3.08 % SM25406.2011 03/03/2022 MD 220303-21-02 Fecal Coliforms 2 115512 MPNIg SM92210E-2006 03/03/2022 MD 220303-21-02 Percent Solids 2 3.03 % SM25406-2011 03/03/2022 MD 220303-21-03 Fecal Coliforms 3 34810 MPNIg SM92210E•2006 03/03/2022 MD 220303-21-03 Percent Solids 3 316 % SM25406.2011 03/03/2022 MD 220303-21-04 Fecal Coliforms 4 26490 MPNIg SM92210E-2006 03/03/2022 MD 220303-21-04 Percent Solids 4 3.02 % SM26406-2011 03/03/2022 MD 220303-21-05 Fecal Coliforms 5 26667 MPNIg SM92210E-2006 03/03/2022 MD 220303-21-05 Percent Solids 5 3.00 % sM,Z!40-2011 03/03/2022 MD 220303-21-06 Fecal Coliforms 6 16340 MPNIg SM92210E-2006 03/03/2022 MD 220303-21-06 Percent Solids 6 3.06 % SM25406-2011 03/03/2022 MD 220303-21-07 Fecal Coliforms 7 35948 MPNIg SM92210E-2006 03/03/2022 MD 220303-21-07 Percent Solids 7 3.06 % SM25409.2011 03/03/2022 MD Respectfully submitted, Melissa Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 ll�ace Analytical rww.ptcfla UGM i ANALYTICAL RESULTS Pace Ana"cal Services, LLC 9800KinceyAve. Suite too Huntensvllle. NC 28078 (704)875.9092 Project: US BIOSOLIDS YVSA Pace Project No.: 92591527 Semple: US BIOSOLIDS NSA Lab ID: 92591527001 Collected: 03/03/22 08:15 Received: 03104/22 10:15 Matrix: Solid Results reported on a 'dry weight' basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8081 TCLP Pesticides RVE Analytical Method: EPA 8081B Preparation Method: EPA3510C Leachate Method/Date: EPA 1311: 03/07122 14:30 Initial pH: 5.46; Final pH: 5 Pace Analytical Services - Charlotte gamma-BHC (Lindane) NO ug1L 0.50 1 03/10/22 12:29 03/11/22 14:47 58-89-9 Chlordane (Technical) NO ug1L 3.0 1 03/10/22 12:29 03/11/22 14:47 57-74-9 Endrin NO ug/L 0.50 1 03i1012212:29 03111/2214:47 72-20-8 Heptachlor NO uglL 0.50 1 03110122 12:29 03H112214:47 76-44-8 Heptachlor epoxide NO ug/L 0,50 1 03/10/22 12:29 03/11122 14:47 1024-57-3 Methoxychlor NO ug/L 1000 1 03/10/2212:29 0311112214:47 72-43-5 Toxaphene ND ug1L 3,0 1 03110122 12:29 03/11/221447 8001-35-2 Surrogates Decachloroblphenyl (S) 102 % 10-154 1 03/10122 12:29 03111t22 14:47 2051.24-3 Tetrachloro-m-xylene (S) 83 % 10-184 1 03110122 12:29 03111/22 14:47 877-09-8 8082 GCS PCB Analytical Method: EPA 8082A Preparation Method: EPA 3546 Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) NO ug/kg 66700 1 03109/22 16:24 03/10/22 10:43 12674-11-2 PCB-1221 (Aroclor 1221) NO ug/kg 66700 1 03/09/22 15:24 03/10/22 10:43 11104-28-2 PCB-1232 (Aroclor 1232) ND uglkg 66700 1 03/09/22 16:24 03/10122 10:43 11141-16-5 PCB-1242 (Aroclor 1242) NO ugikg 66700 1 03/09122 16:24 03110122 10:43 53469-21-9 PCB-1248 (Aroclor 1248) NO ug/kg 66700 1 03/09t22 16:24 03/10122 10:43 12672-2" PCB-1254 (Aroclor 1254) NO uglkg 66700 1 03/09122 16:24 03110122 10:43 11097-69-1 PCB-1260 (Aroclor 1260) NO uglkg 66700 1 03/09/22 16:24 03/10/22 10:43 11096-82.5 Surrogates Deeachlorobiphenyl (S) 21 % 10-160 1 03/09122 16:24 03110/22 10:43 2051-24-3 8082 TCLP PCBs RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Leachate Method/Date: EPA 1311; 03/07/22 14:30 Initial pH: 5.46: Final pH: 5 Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) NO ug1L 1000 1 03110122 12:29 03/11/22 17:06 12674-11-2 PCB-1221 (Aroclor 1221) NO ug1L 1000 1 03110/22 12:29 03/11/22 17:06 11104-28-2 PCB-1232 (Aroclor 1232) NO ug1L 1000 1 03/10/22 12:29 03/11/22 17:06 11141-16-5 PCB-1242 (Aroclor 1242) NO ug1L 1000 1 03110/22 12:29 03/11/22 17:06 53469-21-9 PCB-1248 (Aroclor 1248) NO ug1L 1000 1 03/10/22 12:29 03/11/22 17:06 12672-29-6 PCB-1254 (Aroclor 1254) NO ug1L 1000 1 03110/22 12:29 03111/22 17:06 11097.69-1 PCB-1260 (Aroclor 1260) NO ug/L 1000 1 03/10/22 12:29 03111122 17:06 11096-82-5 Surrogates Decachlorobiphenyl (S) 94 % 10-181 1 03/10122 12:29 03/11122 17:06 2051-24-3 6010D ATL ICP, TCLP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Leachate Method/Date: EPA 1311: 03114/22 15:00 Initial pH: 8.24; Final pH: 5.41 Pace Analytical Services - Peachtree Comers, GA Arsenic NO mg/L 0.30 1 03/15122 15:30 03/16/22 00:31 7440-38.2 Barium ND mg/L 0-50 1 03115122 15:30 03116122 00:31 7440-39-3 Cadmium ND mg/L 0.10 1 03115/22 15:30 03/16122 00:31 744043-9 Chromium ND mg1L 0.10 1 03/15122 15:30 03/16122 00:31 7440-47-3 Lead NO mg/L 0.25 1 03/15/22 15:30 03/16/22 00:31 7439-92.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, excapi In lull. Date: 03/1812022 04:55 PM without Me written consent of Pace Analytical Services, LLC. Page 5 of 33 PO Box 228 a Statesville, NC 28687 e 704/872/4F Page 9 of aceAnalytical l wrryeale4s.com I ANALYTICAL RESULTS Project: US BIOSOLIDS YVSA Pace Project No.: 92591527 Pau Ana"cal Services, LLC 9800 Klncey Ave. Suite 1011 Hunterevitle, NC 20078 1704►875.9092 Sample: US BIOSOLIDS TVSA Lab ID; 92591527001 Collected: 03103122 08:15 Received: 03104/22 10:15 Matrix: Solid Results reported on a 'dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 00100 ATL ICP, TCLP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Leachate MelhodlDale: EPA 1311; 03114/22 15:00 Initial pH: 8.24; Final pH: 5.41 Pace Analytical Services - Peachtree Comers, GA Selenium ND mg/L 0A0 1 03/15122 15:30 03/16122 00:31 778249-2 Silver NO mg1L 0.10 1 03115/22 15:30 03/16122 00:31 7"0-22-4 7470 Mercury, TCLP Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1311; 03/14122 15:00 Initial pH: 8.24; Final pH: 5.41 Pace Analytical Services - Peachtree Comers, GA Mercury NO mg/L 0,0050 1 03/16/22 07:45 03116122 13:09 7439-97-6 M1 8270E TCLP RVE 1,4-Dlchtorobanzene 2,4-Dinitrotoluene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachloroethans 2-M et hyl pheno I (o-Cresol ) 3&4-Methy1phenol(m&p Cresol) Nitrobenzene Pentachlorophenol Pyridine 2,4,5-TdchlorophenoI 2,4,6-Tnch I orophe nol Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Terphenyl-d14 (S) Phenol-d6 (S) 2-Fluorophenof (S) 2,4,6-Tdbromophenol(S) 8260D MSV TCLP Benzene 2-Butanone (MEK) Carbon tetrachloride Chlorobenzene Chloroform 1,4-Oichlorobenzene 1,2-Oichloroethane 1,1-Oichloroethene Tetrachloroethene Trichtaroethene Date: 0311 t112022 04:55 PM Analytical Method: EPA 8270E Preparation Method: EPA 3510C Leachate MeftdlDatw EPA 1311; 03107/22 14:30 initial pH: 5.46; Final pH: 5 Pace Analytical Services - Charlotte ND ug1L 50.0 1 0310912216:34 03110/2212:03 106-46-7 ND ug1L 50.0 1 0310912216:34 03110/2212:03 121-14-2 ND ug1L 50.0 1 03/0912216:34 03110/2212:03 87-68-3 ND ug)L 50.0 1 03/0912216:34 03110/2212:03 116-74.1 ND ug1L 50.0 1 03/09122 1634 03110M 12:03 67-72-1 NO ug1L 50.0 1 03/0912216:34 03110/2212:03 95-48-7 NO ug1L 50.0 1 03109/2216:34 03/1012212:03 15831-10-4 ND ug1L 50.0 1 0310912216:34 0311012212:03 98-95-3 ND ug1L 100 1 0310912216:34 03/1012212:03 87-86-5 ND ug1L 50.0 1 03109/2216:34 03/1012212:03 1W86-1 NO ug1L 50.0 1 03/09/2216:34 03/10/2212:03 95-95A ND ug1L 50.0 1 03f0912216:34 03110/2212:03 884)&2 92 % 10-144 1 03109/2216:34 03/10/2212:03 4165.60-0 84 % 10-130 1 03109/22 16:34 03/10/22 12:03 321-60-8 i50 % 34-163 1 03109/2216:34 03110/2212:03 1718-51-0 57 % 10-130 1 0310912216:34 0311012212:03 13127-88-3 75 % 10-130 1 03/09/22 16:34 03/10122 12:03 367.12-4 96 % 10-144 1 03/09/22 16:34 03/10/22 12:03 118-79-6 Analytical Method: EPA 82600 Leachate MethodlDate: EPA 1311: 03109/22 13:25 Pace Analytical Services - Charlotte ND t4l. 100 20 03/1012214:39 71-43-2 NO ug1L 200 20 03/10/2214:39 78-93-3 NO uglL 100 20 03110/22 14:39 56-23-5 NO uglL 100 20 03110/2214:39 108-90-7 NO uglL 100 20 0311012214:39 67-66-3 NO ug1L 100 20 0311012214:39 106-46-7 NO uglL 100 20 0311012214:39 107-06-2 NO uglL 100 20 031101221439 75-35.4 NO uglL 100 20 0311012214:39 127-18� NO ug1L 100 20 0311012214:39 79-01-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services. LLC. Page 6 of 33 PO Box 228 a Statesville, NC 28687 e 704/872/4697 Page 10 of 39 aceAnalXkal e tew.yscfdsls.catt ANALYTICAL RESULTS Project: US BIOSOLIDS YVSA Pace Project No.: 92591527 Pace Analytical Services, LLC 9600 Mncey Ave. Suite 14D Hunteravipe, NC 28078 (704)875.9092 Sample: US BIOSOLIDS NSA Lab ID: 92591527001 Collected: 03/03/22 08:15 Received: 03104/22 10:15 Matrix: Solid Results reported on a 'dry weight' basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 8260D MSV TCLP Analytical Method: EPA B260D Leachate MethodlDate: EPA 1311: 03/09122 13:25 Pace Analytical Services - Charlotte Vinyl chloride ND u91L 100 20 03/10/22 14:39 75-01.4 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 70-130 20 03/10/22 14:39 1706M7-0 Toluene-d8 (S) 102 % 67-135 20 03/10122 14:39 2037-26-5 4-Bromofluorobenzene (S) 100 % 70-130 20 03/10/22 14:39 460-00-4 Percent Moisture Analytical Method: SW-846 Pace Analytical Services - Charlotte Percent Moisture 97.0 % 0.10 1 03108122 16:19 N2 1010 Flashpoint,Ciosed Cup Analytical Method: EPA 10108 Pace Analytical Services - Asheville Flashpoint 3-200 dog F 70.0 1 03117/22 13:05 9045 PH Soil Analytical Method: EPA 9045D Pace Analytical Services - Asheville pH at 25 Degrees C 6.6 Sid. Units 0.10 1 03107/22 14:48 H3 9095 Paint Filter Liquid Test Analytical Method: EPA9095B Pace Analytical Services -Asheville Free Liquids FAIL 1.0 1 03108/22 09:42 Percent Moisture Analytical Method: Moisture Pace Analytical Services - New Orleans Percent Moisture 97.1 % 0.50 1 03/15122 11:16 733C S Reactive Cyanide Analytical Method: SW-846 7.3.3.2 Preparation Method: SW-646 7.3.3.2 Pace Analytical Services - New Orleans Cyanide, Reactive ND mg/kg 25.0 1 03/17122 09:34 03118122 08:52 734S Reactive Sulfide Analytical Method: SM 4500-S2-F-2011 Preparation Method: SW-846 7.3.4.2 Pace Analytical Services - Greensburg Sulfide, Reactive ND mg/kg 338 1 03/10122 19:38 03110/22 19:59 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 04:55 PM without the written consent of Pace Analytical Services. LLC. Page 7 of 33 PO Box 228 e Statesville, NC 28687 e 704/872/4697 Page 11 of 39 Analytical Environmental Services, Inc Date: 14-Mar-22 Client: Pace Analytical Client Sample ID: US BIOSOLIDS TVSA Project Name: 92591527 Collection Date: 3/3/2022 8:15:00 AM Lab ID: 2203A21-001 Matrix: Solid Analyses Result Reporting Limit Qua] Units Batc61D Dilution Factor Date Analyzed Analyst HERBICIDES, TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.20 mg1L 332444 1 03/1 U2022 17:50 KH 2,4-D HRL 0.20 mglL 332444 1 031111202217:5o KH Sam DCAA 66.6 5M-120 %l2BC 332444 1 03/11/2022 17:50 KH Qualirters: ' Wte cxccedx maximum romaminaat level BRL Below, rcporn,, limit H Holding limes for preparation or analysis exceeded N Anulytc nm NFL.AC eenificd B Analyte dtactcd in the associated melho l blank Greater than Rewlr valve p Fstimated(v,hue above quantilalion range) S Spike Recovery outside limits dan In matrix Nam See csu narreave F Aiuly,d in the lab whVrh is a daviaPor fivm the method < Le. than Rasolr'.i- ] Estimated value detected below Aeperum, Limht Page 30 of 33 Page 3 of 6 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 34 of 39 N N >- LL p cn co U n7 Z t Q O ( Y(D O O _ ._ M LO N a E w 0 CZ Z O 2 — N N a W a p 0 E r ,. ci O C Z z p z — co fn W M Z V co CD m Q a N U) w� p Z p CD L: O G 0 > L) U CD Q a a o 0) c� U i N Q Q N o Q o N N N (0 O c_ N O m C N m N fV Y co [00CN N m N N 1° N U Z d (n O ._ C U- N �O f+ C U) '� •� O OD 3 oC CL C7 O ti z a7 O C CO C _ m rL co u1 of (n 0 0 °' 00 rL � CIA 6: tm V U m C — ui co w — (n n 00 ,� 0 0 e a a a T U _ -E a1 CD 2 N a � o o o o ro X z N o CI E N N Z o G1 E W u° 0 � � c V �n z z U5 U m N oN ` a cv o z — X N a o o A Z — Y co kn N E y r p J E N O O E N C U J C 2 U � d !D O 01 m c o> o E E ° " E E c E E e Q1 0 0 w o V) z = Q r `n N O cn iq z z u V Lci o r N m [j Q m m(� O r Lu a E a m W a~ _ o cn U m �+ o CL LL s M' o a) 0 Y V ■� C a ce U r N u e y Ix U r N J .� L m 0) co I� ♦�/O 0. 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