WQ0023181_Monitoring - 10-2022_20230123

Monitoring Report Submittal
Permit Number #*
Name of Facility:*
Month: * October
Report Information
WQ0023181
International Paper - Ridgeway Chip Mill
Year:* 2022
Type* Upload Document*
GW-59 International Paper Ridgeway 900.19KB
WQ0023181 GW-59 2022
v3.pdf
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
Confirmation Email Address:* [e-mail]
Name of Submitter: * Benjamin Burger
Signature:
0 mcclw &
Date of submittal: 1/23/2023
This will be filled in automatically
Initial Review

Reviewer: Wanda.Gerald
Is the project number correct?* WQ0023181
Is the monitoring report accepted?* Yes NO
Regional Office* Raleigh
Reviewer: _anonymous
Review Date: 2/14/2023

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
r1EPAIR MENT OF ENVIRONMENTAL QUALITY - OIV, of WATER RESOURCES
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
' `
IBIT MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phorts: 9i19-e074306
FACILITY INFORMATION
P1easePrint ClearfyorType
PERMIT Numbeiiita-44 r , Expiration Date:
Facility Name: International Paper- Mdge.vay
Chip Mill
Non -Discharge UIC
NPDES NCG220000 Other
Permit Name (if different):
Facility Address: ` ✓l
TYPE OF PERMITTED OPERATION BEING MONITORED
/'
--
County (t l ^(/'C' t�
❑ Lagoon ❑ Remedlatlon: Infiltration Gallery
❑ Spray Field ❑ Remedlation:
Contact Person: Ben Burger
Telephone#: [phone]
ElRotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:nla
No. of wells to be sampled: n/a
❑ Water Source Heat Pump 0 Other: Recycled and other wastewater
r iriFr;ir
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit}:
Date sample collected: 10/25/2022
FIELD ANALYSES:
WAS
Well Depth: ft.
Well Diameter; in.
pH omao: 7.7 units Temp. 000to: 16 oC
DRY at
Depth to Water Leval 82546: ft. below measuring point
Screened Interval: ft. to
ft. Spec. Cond. 00094; µMhos
time of
samplsampl
sampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation: ft.
Odor 000es-
check
Volume of water pumped/bailed before sampling:
gallons
Appearance
here.,
Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:1012712022
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335 28
mg/L
Nitrite (NO2) as N o0815
ni Pb - Lead o1051 ug1L
Coliform: MF Fecal 31616
1100ml-
Nitrate (NO3) as N 00620
mg1L Zn - zinc 01092 mg1L
Collform: MF Total 31s04
/100ml- Phosphorus:
Total as P 000m
mg1L
(Nola: use MRN method for hieNy turbid samptaa)
Orthophosphate 70507
mg1L Other (Specify Compounds and Concentration Units).
issolved Solids:Total To300 193
mg/L
AI - Aluminum 01105
mi
PH (Lab) 00403
units
Ba - Barium 01007
ugi
TOC oo6eo
mg1L
Ca - Calcium 00916
mg11
Chloride 00940 15
mg/L
Cd - Cadmium 01027
ug1L
Arsenic wom
ug1L
Chromium: Total 01034
ug1L
Grease and Oils ooss2
mgli.
Cu - Capper 01042
ni ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 <i
uglL
Fe - Iron 01045
ug1L
(Specify test and method A ATTACH LAB REPORT.)
Sulfate 00946
mi
Hg - Mercury 71900
ui
Lab Report Attached? ❑ Yes (1) ❑ No (0)
Pacific Conductance 00096
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia 00610
mg/L
Mg - Magnesium 00927
ni method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese o1 ass
ug1L
method #
TKN as N 00625
mg1L
Ni - Nickel olo67
ui
, method #
For Remediation Systems Only (Attach Lab Reports): Innuent Total VOCs: mg1L Effluent Total VOCs: mg/L VOC Removal%
Benjamin W Burger 01i I 'a 1
Permittee (or Authorized Agent) Name and Title - Please print or type Signatu Permit, r Authariz Agent) ( at )
GW-59 Rev. 3-1-2016

CHAIN OF CUSTODY
Company Name: International Paper Norlina, NC)
Company Contact: Ben Burger _
Results To: Ben Bur er
Address: 247 Collins Road
Norlina, NG 27563
Phone: [phone]
Email: 2e_n.&rgerA i RaRMSOM
4A IDl
ZZ-
Project ID: NPDES Annual
Storage Pond Ridgeway Chip Mill Site
North Carolina Certication #289
Sample Location I Start I Start j End I End
Date Time I Date Date
`WW= Wastewater, GW = Groundwater. DW =
XXXX I xxxx I XXXX I XXxx
sV90P
ANALYSES REQUESTED
Bottle 0:1 q 1 g 1 C I D
�f Preserved with: 1 3,1 311 1
Of Pmstrnrawns Checked:
A Chloilne Checked: Yej or NN (ff applicable circle one)
0
�
us
m
0
.c
Grab
Total # of
a
0
C)
Time containers
G}
U
t
o_
}-
12 1 i 2-0'5 4 Ix
X1
X
I X
Water, SW = Stormwater, HW = Hazardous Waste, OTHERS
Sampled B .
JIRA Datemme: IO Z 5 z �20
Relinquished By:
DatefTime:
Received By:
DaEeTme: LoZZ
Relinquished By.
Daterrime:
Received By:
Datef rime:
do
n
x
PMWV2ffws &- C,hbrim i40.5PPrni for TKN, NOX. NH,,TN, NNnif
1=0.M 8=N*A203 9-NH+CI
2=HNO3(<2) 6-N%80.*HC1 10=A%wrbiCACid+HCI
3=H180+(4) 7-NOOH+ZnOAc 11=HCl (42)
14 -N&OH(>12) 3■N1e0,+rAe1e21 12 - &W AMIN* + NaOH
_7L _for Compliance *TDS - subcontract to Pace: (9800 Kincey Ave., Suite 100, Huntersville, NC 28078
Not for Compliance (using Pace paid ship ing abel)
pH(field)� 1. 6oL ^Date a Z 2-L Time 12D8 Analyst D IM
Page 9 of 9 Arrival Temp: C. q °C
JAMES R. REED & ASSOCIATES [phone]; FAX [phone]
770 Pilot House Drive, Newport News, VA 23606
Dlr�

REPORT OF ANALYSIS
CLIENT: International Paper (Norlina, NC)
REPORT NO: 22-1796415:59
ATTN: Ben Burger
GRAB COLLECTION:
ADDRESS: 247 Collins Road
Date: 10/25/2022 Time: 1205
�„ REED h
Norlina, NC 27563
COMPOSITE COLLECTION:
s�c►l►�
PHONE: [phone]
Start Date: Time:
EMAIL: [e-mail]
End Date: Time:
Special Notes:
SAMPLE RECEIPT:
RE: NPDES ANNUAL
Date: 10/25/2022 Time: 1520
STORAGE POND RIDGEWAY CHIP MILL SITE
NORTH CAROLINA CERTIFICATION 9289
SAMPLE ID: POND
SAMPLE NO: 22-17964
Method
.IRA
Parameter
Number
QL
Result
Unit
Analyst
Date
Time
COD
HACH8000
10
28
mg/L
TNT
10/28/2022
1406
Phenols
420.4
0.02
< 0.02
mg/L
ACS
11/1/2022
1118
Total Dissolved Solids
*2540C
25
193
mg/L
PAC
10/30/2022
0948
pH (Field)
*4500H+B
7.7Q16oC
S.U.
DKH
10C1512022
1208
Chloride
*4500CI C
1
I5
mg/L
JMH
11/I 1/2022
1645
NOTES:
IRA Quantification Level is the concentration of the lowest calibration standard above zero with a reliable signal.
Reproduction of this report is not permitted, except in full, without written approval from James R Reed dt Associates.
The results on Ihis report relate only to the sample(s) provided for analysis and conform to TNI standards unless otherwise indicated.
Chain of Custody attached.
*SM 2011 (pH, Chloride), *SM 2015 (TDS)
TDS Subcontracted to Pace Analytical Services, Inc.
Ashville, NC, see attached Report
RESPECTFULLY SUBMITTED
Elaine Claiborne
Laboratory Director
Date: 15 Nov-22
James R. Reed & Associates
v wccRe _
VELAP# 460013 �.� —" 770 Pilot House Drive, Newport News, VA 23606
£PA# VAOOOlS
[phone] 0Fax: [phone]
�Qo�r
Page I of 1

/�alwmpaclllksxamceAnaljftal'
{
November 01, 2022
Elaine Claiborne
,lames R. Reed & Associates
770 Pilot House Drive
Newport News, VA 23606
RE: Project: P22-17964/POND-TDS
Pace Project No.: 92633321
Dear Elaine Claiborne:
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh. NC 2707
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on October 27, 2022. The results relate only to
the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless
otherwise footnoted.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
st-
Erick Hanna
erick. [e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full.
without the written consent of Pace Analytical Services. LLC.
Page 1 of 10

+ Paco Analytical Servlcas, LLC
aceAnalj cal 6701 Conference Drive
taa www.ptc111b5m Raleigh. NC 27607
(919)tt34.4884
CERTIFICATIONS
Project: 022-17964/POND-TDS
Pace Project No.: 92633321
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Noi lh Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification M 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fun,
wnhoul the written consent of Pace Analytical Services, LLC.
Page 2 of 10

Pace Analytical Services, LLC
e�a'i�cal a 6701 Conference Drive
j`!L 1 Raleigh, NC 27607
/�W81cewww.packlabLeam {919}834-
4984
SAMPLE ANALYTE COUNT
Project: P22-17964/POND-TDS
Pace Project No.- 92633321
Lab ID Sample ID Method Analysts
92633321001 22-179641POND
PASI-A= Pace Analytical Services -Asheville
SM 254-3-2015
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Without the written consent of Pace Analytical Services, LLC.
MAB2
Atialytes
Reported Laboratory
1 PASI-A
Page 3 of 10

Pace Analytical Services, LLC
��aoeAnayjcal* 6701 conference Drive
Raleigh, NC 27607
www.pa pilots coat [phone]
ANALYTICAL RESULTS
Project: P22-17964/POND-TDS
Pace Project No.: 92633321
Sample: 22479641POND Lab ID: 92633321001 Collected: 10/25/22 12,05 Received: 10127122 09:53 Matrix: Water
Parameters
2640C Total Dissolved Solids
Total Dissolved Solids
Results Units Report Limit DP Prepared Analyzed CAS No. Qual
Analytical Method: SM 2540G2015
Pace Analytical Services -Asheville
193 mg1L 25.0 1
REPORT OF LABORATORY ANALYSIS
10/30/22 09:48
This report shalt not be reproduced, except in full,
Date: 11/01/2022 09:47 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 10

01�
YaceAnalj&al
wwapacatais cm
QUALITY CONTROL DATA
Project: P22-17964/POND-TDS
Pace Project No.: 92633321
QC Batch: 733614 Analysis Method: SM 2540C-2015
QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92633321001
METHOD BLANK: 3818538 Matrix: Water
Associated Lab Samples: 92633321001
Blank Reporting
Parameter Units Result Limit Analyzed qualifiers
Total Dissolved Solids mg/L ND 25.0 10130122 09:48
Pace Analytical Servic _ , LLC
6701 Conference Drive
Raleigh, NC 27607
f919j8344984
LABORATORY CONTROL SAMPLE: 3818539
Spike LCS LCS % Rec
Parameter Units Cone. Result % Roe Limits Qualifiers
Total Dissolved Solids mg/L 250 246 98 90-110
SAMPLE DUPLICATE: 3818541
92633429007 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 219 215 2
SAMPLE DUPLICATE: 3818663
92633429D06 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 178 175 2
Results presented an this page an In the units Indcated by the "UnW column except where an allemate unit is presented to the right of the resulL
REPORT OF LABORATORY ANALYSIS
This report shag not he reproduced, except in full,
Date: 11/0112022 09:47 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 10

WceAnaoical'
wwrr p#cellimem
QUALIFIERS
Project: P22-17964/POND-TDS
Pace Project No.: 92633321
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported aata due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh. NC 27607
[phone]
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. Thes result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample tbuplicate
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitriie ny EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylai 1ne using Method 8270, The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 11/01/2022 09.47 AM without the written consent of Pace Analytical Services, LLC_ Page 6 of 10

�� Pace Analytical Services, LLC
ccAnalX cal' 6701 Conference Drive
Raleigh, NC 27607
www.p4eela6a.e®e (919)8344984
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: P22-179641POND-TDS
Pace Project No.: 92633321
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92633321001 22.179641POND SM 254OC-2015 'rd3614
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fall.
Date: 11/01/2022 09:47 AM Wthout the written consent of Pace Analytical Services, LLC. Page 7 of 10

Effective Elate: 05/112/2022o5/12/2022:
Laboratory receiving samples;
Asheville ❑ EdenQ Greenwood Q Huntersviile'0 Raleigho MechanicsvilleE] Atlanta❑ Kernersville[]
Sarnple Condition Client Name:
, �[]USPS�O�Clp
jett ff:Wog#:92633321
Courier: FedEx ❑UP5 ❑ Commercial Paceient
❑Other• iii i
Custody Seat present? ❑yes (Pilo Seals intact? []yes /dNo
Packing Material: E]Bubble Wrap ❑8ubbte Bags one
❑ Other
Thermometer:
Gun ID: PK
...f 2T(� -7(�
Correction Factor:
Type of ce: 121Wet ❑Blue
Cooler Temp: Aed/Subtract lecJ Cooler Temp Corrected ('C): D . -7
USDA Regulated Soil ( N/A, water sample!
Did samples origin .rlte In a quarantine zone within the United States: CA, NY, or SC
(check maps)? ❑Yes FINa
Chain of Custody Present?
Yes
❑No
N/A
1.
Samples Arrived within Hold Time?
Short Hold Time Anal sls <72 hr.)T
Yes
I]Yes
ONO
❑NJA
$_
Rush Turn Around Time Requested?
o
N/A
3.
❑Yes
Na
❑N/A
A.
Sufficient Volume?
Yes
❑No
❑N/A
5.
Correct Containers Used?
Yes
ONO
❑N/A
S•
Pace Containers Used?
Yes
ONO
N/A
Containers Intact?
11 les
❑No
❑N/A
T.
Dissolved analysis: Samples Field Filtered?
❑Yes
2INo
©NJA
S.
Sample Labels Match COC?
0Yes
ON.
❑N/A
9.
includes Date/Time/ID/Analysis Matrix: iLui
Headspace In VOA Vials (>5.6mrrl)? ❑Yes 16
Trip Blank present? ❑N/A 10.
❑Yes Na ❑N/A lI,
Trip Blank Custody Seals present?
COMMENTS/SA&QLEDrSCREPANCY ©Yes I Wyo ❑N/A
Elate/inllials Person Examining Contents: dJ �)
810
10811cal Tissue row?
1, �s
Des ONO Z/A
❑None
Temp should be above freezing to 6'C
❑Samples aut of temp criteria. Samples on Ice, cooling process
has begun
Did samples originate from a foreign source (interne) tonally,
including HiWall and Puerto Rico)? 11YPs r1
Field Data Required? Des
CLIENT NpTiFiCATION/fIE50LUTION Lot i©Uf SplltLOrltdlneFs:
Person contacted:
Project Manager SCURF Review:
_Pf!PJPct.Marlager.SRf. Aeview:-
Date/Time:
Date:
Date: -
Quiaitr'ax ID: 69614
Page 1 of 2 Page 8 of 10

Effective fate:
*Check mark top half of box if pH and/or dechlorination Is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, TOC, Olt and Greasa, ORO/SD15 (water) DOC, LLH9
"Bottom half of box Is to list number of bottles
* "Check all unpreserved Nitrates for chlorine
Project W0 # ' 92.6333f21
PH: EJH Due Date: 11/20122
CLIENT: 91-JRRE.ED
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pH Adjustment log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Tyne preserniton Amount of PreservaEive tQt
adjusted added
—Note: Wh�rleveTlhefe is a isaepancy affecting North Cafollna compliance samples, a copy of this form will be sent to the North Carolina DENRCertiFlcation Office (Le
Out Of hold, incorrect preservative, out of temp, incorrect containers,
Qualtrax ID: 69614 Page 2 of 2 Page 9 of 10

CHAIN OF CUSTODY
ANALYSES REQUESTED
Company Name: James R. Reed & Assat;iates Bottle ID
Company Contact: Elaine Claiborne Telephone: [phone] [Present.
Results To: Elaine Claiborne email: claibome rceed,com
Address: 770 Pilot House Drive
Newport News, VA 23606
Project ID:
Sample Z~oca#iort Start Start End End Date ! - Time Total # w
Date Time Date Time of Cont,lull
n�
22-179641POND X) xxx xxxxx xxxm I= 10-25-22 1205 1 X Q(
`WW= Wastewater, GW =Groundwater, DW - Drinking Water, HW - Hazardous Waste. OTHERS
Sampled By:
Relinquished BY:
Received By:
Relinquished By:
Received By:
___y_for Compliance
--Not for Compliance
Q
Client _ DateTme: see above
DateMme:
DateTme: 22i 6-273
Daterrime:
Date/Time.
Page 1 of 'I
JAMES R. REED and ASSOCIATES [phone],
770 Pilot House Drive, Newport hews, VA 23606
EmamlignK
1 = ce°C 5 = NazS203 8 = NH,CI
2 = HNO3 B = Na2SO3 + HCi 1 D=Ascorbic Acid + HCi
3 = H2SO4 7 = NaOH + ZnOAc 11=HCl
4 = Na0H 8 = H2S0, + FAS 12=2inc Acetate + NaOH
Arrival Temp: °C
FAX [phone]