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Home My WebLink AboutWQ0002503_Monitoring - 07-2022_20230113 (2)Monitoring Report Submittal Permit Number #* Name of Facility:* Month: * July Report Information WQ0002503 FRIT CAR, INC. Type * NDMR, NDAR-1, NDAR-2, NDMLR G W-59 Confirmation Email Address:* Name of Submitter: * Signature: Date of submittal: Initial Review cpettis@fritcar.com Connie Pettis O Year:* 2022 Upload Document* NDAR-NDMR JULY 2022.pdf 4.09MB PDF Only 2022-07 GW59.pdf 4.88MB PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-7, NDAR-2, NDMLR, GW-59). 1 /13/2023 This will be filled in automatically Reviewer: Gerald, Wanda Is the project number correct?* WQ0002503 Is the monitoring report accepted?* Yes No Regional Office* Washington Reviewer: _anonymous Review Date: 2/6/2023 GW-59A COMPLIANCE REPORT FORM Permit # WQ0002503 (Submit one each monitoring period with GW-59 forms.) 1 Enter date monitoring results were due. 8/30/2022 Will this monitoring report(GIN-59 and GW-59A YES NO be submitted after the established due date? X 2 Was any required information missing on the GW-59 report forms? YES 1:IQ n IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Office for guidance. X 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below. Mw•1) MW-5,MW-Lo MW-9 IRON 01045 5 For the constituents identified in question 4 above, have standards been exceeded previously for YES NO the same constituent(s) in the same well(s) in the last two years? �p If the answer to question 5 is NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving YES NO this groundwater quality problem? v If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. 3uCK8r0VM EYalual-iON/ g The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby qqknowledge that the above information was evaluated, and the information submitted in this rep Compliance Report GIN-59A) is true and complete to the best of my knowledge. / Signature of Per ee (or Authorized Agent) Date GW-59A 12/8/2003 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Ft s.l�tc,t'iarse�-1las� _ FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 2/28/2029 Facility Name: FRIT CAR, INC. Non -Discharge UIC Permit Name (if different): SAME AS ABOVE NPDES WQ0002503 Other Facility Address: 2012 HIGHWAY 17 NORTH TYPE OF PERMITTED OPERATION BEING MONITORED BRIDGETON NC 28519 County CRAVEN ❑ Lagoon ❑ Remediation: Infiltration Gallery 0 Spray Field ❑ Remediation: Contact Person: MICHAEL NEWBY Telephone#: 251-867-7752 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: FRIT CAR SPRAYFIELD No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from Permit): MW-1 Date sample collected: 7/27/2022 Well Depth: 15.65 ft. Well Diameter: 2 in. Depth to Water Level 82546: 7.35 ft. below measuring point Screened Interval: 1.8 ft. to 11•8 ft. Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: 7.97 gallons Samples for metals were collected unfiltered: X YES ❑ NO and field acidified: ❑■ YES ❑ NO FIELD ANALYSES: pH ooaoo: 6.33 units Temp. 000lo: 24.8 °C Spec. Cond. 00094: µ Mhos Odor 000m: NONE Appearance CLOUDY WAS DRY at time of sampling, check here:❑ LABORATORY INFORMATION Date sample analyzed: 8/12/2022 Laboratory Name: PACE ANALYTICAL Certification No. EnV375 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb -Lead 01051 <2.0 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 .451 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <• 10 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 182 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 5.16 mg/L Ca - Calcium oo916 mg/L Chloride 0094o 2.31 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 <2.0 ug/L Grease and Oils 00552 mg/L Cu -Copper 01042 <.005 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 704 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 17 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <•25 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen: NH3as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 <2.0 ug/L method # I -or Remediation Systems Unly (Attach Lab Reports): Influent Total VOGs: mg/L Effluent Total VOCs: mg/L VOC Removal% Michael Newby, Senior Vice President I'/o(ZZ Permittee (or Authorized Agent) Name and Title - Please print or type 5ignalfure of Permittee (o nt) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Please Print Clearly or Facility Name: FRIT CAR, INC Permit Name (if different): SAME AS ABOVE Facility Address: 2012 HIGHWAY 17 NORTH BRIDGETON NC 28519 County CRAVEN Contact Person: MICHAEL NEWBY Telephone#: 251-867-7752 JVell Location/Site Name: FRIT CAR SPRAYFIELD No. of wells to be sampled: 4 PERMIT Number: Expiration Date: 2/28/2029 Non -Discharge UIC NPDES WQ0002503 Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: SAMPLING INFORMATION WELL ID NUMBER (from Permit): MW-5 Date sample collected: 7/27/2022 Well Depth: 15.25 ft. Well Diameter: 2 in. Depth to Water Level 82546: 7.28 ft. below measuring point Screened Interval: 2 ft. to 12 ft. Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: 7.66 gallons Samples for metals were collected unfiltered: 9 YES ❑ NO and field acidified: ❑■ YES ❑ NO Date sample analyzed: 8/12/2022 Laboratory Name: PACE ANALYTICAL PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 <.10 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.1 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Dissolved Solids:Total 703oo 82 mg/L Al - Aluminum oilo5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 4.03 mg/L Ca - Calcium 00916 mg/L Chloride 00940 15.6 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium. Total 01034 5.68 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 <.005 mg/L Phenol 32730 ug/L Fe - Iron 01045 2260 ug/L Sulfate 00945 17.5 mg/L Hg - Mercury 71900 ug/L Specific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 00610 <.25 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen, NH3as N: Ammonia Nitrogen, Total) Mn - Manganese 01055 u9 /L TKN as N 00625 mg/L Ni - Nickel 01067 <2.0 ug/L FIELD ANALYSES: pH 00400: 5.21 units Temp. 000lo: 20.2 OC Spec. Cond. 00094: µMhos Odor00085: NONE Appearance CLEAR WAS DRY at time of sampling, check here:❑ Certification No. EnV375 Pb -Lead 01051 3.45 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? X Yes (1) ❑ No (0) VOC 7873 method # method # method # method # �• •-�•••�u•a�•�••..r Willy "au RCNVrLbt. nrnuem Iotal vvus. mg/L tttluent Total VOCs: mg/L VOC Removal% Michael Newby, Senior Vice President Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Please Print Clearly or Facility Name: FRIT CAR, INC Permit Name (if different): SAME AS ABOVE Facility Address: 2012 HIGHWAY 17 NORTH BRIDGETON " NC 28519 County CRAVEN Contact Person: MICHAEL NEWBY Telephone#: 251-867-7752 Well Location/site Name: FRIT CAR SPRAYFIELD No. of wells to be sampled: 4 PERMIT Number: Expiration Date: 2/28/2029 Non -Discharge UIC NPDES WQ0002503 Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 9 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: afamrt_trvu iNrvmmA i tvry WELL ID NUMBER (from Permit): MW-6 Date sample collected: 7/27/2022 Well Depth: 19.68 ft. Well Diameter: 2 in. Depth to Water Level 82546: 11.45 ft. below measuring point Screened Interval: 5 ft. to 15 ft. Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: 13 gallons ❑� for metals were collected unfiltered: YES ❑ NO and field acidified: AYES ❑ NO FIELD ANALYSES: pH ooaoo: 5.03 units Temp. 000lo: 22.1 oC Spec. Cond. 00094: µMhos Odor 00085: NONE Appearance CLEAR If WELL WAS DRY at time of sampling,check here: ❑Samples LABORATORY INFORMATION Date sample analyzed: 8/12/2022 Laboratory Name: PACE ANALYTICAL Certification No. EnV375 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 2.34 u9 /L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 <.10 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <• 10 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 86 mg/L Al - Aluminum oilo5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 3.07 mg/L Ca - Calcium 00916 mg/L Chloride 00940 15 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total olo34 3.97 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 <.005 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 6180 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 13.1 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <•25 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 <2.0 ug/L method # For Remealation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Michael Newby, Senior Vice President Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: - . . . IDEPARTMENT OF ENVIRONMENTAL OUAIUTY - DIY. OF WATER RESOURCES COMPLIANCE REPORT FORM INt=c»uTIONIaRocEsrrUNIT lflE7rIYIlULSERYIGECENT6R,li6Elctt,NCzi6'T_1s1Y ; FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 2/28/2029 Facility Name: FRIT CAR, INC. Non -Discharge UIC Permit Name (if different): SAME AS ABOVE NPDES W00002503 Other Facility Address: 2012 HIGHWAY 17 NORTH TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery BRIDGETON "`'" ` NC 28519 County CRAVEN 0 Spray Field ❑ Remediation: Contact Person: MICHAEL NEWBY Telephone#: 251-867-7752 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: FRIT CAR SPRAYFIELD No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-7 Date sample collected: 7/27/2022 p FIELD ANALYSES: WAS Well Depth: 16.18 ft. Well Diameter: 2 in. pH ooaoo: 5.05 units Temp. 00010: 24.4 °C DRY at Depth to Water Level 82546: 8.26 ft. below measuring point Screened Interval: 2 ft. to 12 ft. Spec. Cond. 000ga: µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 000as: NONE sampling, check Volume of water pumped/bailed before sampling: 7.6 gallons Appearance CLEAR here:❑ Samples for metals were collected unfiltered: X YES ❑ NO and field acidified: X YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 8/12/2022 Laboratory Name: PACE ANALYTICAL Certification No. EnV375 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Pb -Lead 01051 3.6 u9 /L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 <_ 10 mg/L Zn - Zinc 01092 m9 /L Coliform: MF Total 31504 /100mL Phosphorus: Total as P oosss .438 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total7030o 414 mg/L AI - Aluminum oilo5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC oosso 16.7 mg/L Ca - Calcium oogls mg/L Chloride oogao 112 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 7.74 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 <.005 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 7070 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 122 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oosso <.25 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3asN. Ammonia Nitrogen, Total) Mn -Manganese 000ss ug/L ,method # TKN as N 00625 mg/L Ni - Nickel 01067 2.19 ug/L method # I -or Remematton Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L ^ Effluent Total VOCs: mg/L VOC Removal% (i W-by Rev. 06-07-2018 (� ace Analytical 11 ANALYTICAL REPORT August 30, 2022 Frit Car Inc. Sample Delivery Group: L1519627 Samples Received: 07/28/2022 Project Number: 8522054 Description: Bridgeton Facility Report To: Connie Pettis 2012 US Hwy 17N New Bern, NC 28560 Entire Report Reviewed By: q�"h Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 1 of 20 TABLE OF CONTENTS Cp: Cover Page u Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results ,i Fss] MW-1 L1519627-01 5 Fn MW-5 L1519627-02 6 MW-6 L1519627-03 7 Fr MW-7 L1519627-04 8 Qc: Quality Control Summary 9 Rc Gravimetric Analysis by Method 2540 C-2011 F Wet Chemistry by Method 350.1 10 Wet Chemistry by Method 365.4 11 [Al Wet Chemistry by Method 9056A 12 Wet Chemistry by Method 9060A 14 RC Metals (ICPMS) by Method 6020B 16 GI: Glossary of Terms 18 Al: Accreditations & Locations 19 Sc: Sample Chain of Custody 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 2 of 20 SAMPLE SUMMARY Collected by Collected date/time Received date/time MW-1 L1519627-01 GW Brent Heard 07/27/221130 07/28/2209:00 FP Method Batch Dilution Preparation Analysis Analyst Location date/time date/time F Gravimetric Analysis by Method 2540 C-2011 WG1905119 1 08/03/2217:46 08/03/2218:00 SLP Mt. Juliet, TN Wet Chemistry by Method 350.1 WG1904045 1 08/03/2215:56 08/03/2215:56 SL Mt. Juliet, TN Wet Chemistry by Method 365.4 WG1907864 1 08/03/22 09:10 08/09/22 1125 LDT Mt. Juliet, TN Wet Chemistry by Method 9056A WG1902443 1 07/29/22 03:55 07/29/22 03:55 LBR Mt. Juliet, TN Wet Chemistry by Method 9060A WG1909545 1 08/22/2218:49 08/22/2218:49 BGM Mt. Juliet, TN Fn Metals (ICPMS) by Method 6020B WG1903521 1 08/01/2215:05 08/02/22 14:33 JPD Mt. Juliet, TN Metals (ICPMS) by Method 6020B WG1905934 1 08/09/2210:35 08/12/2217:21 JPD Mt. Juliet, TN Fr Collected by Collected date/time Received date/time MW-5 L1519627-02 GW Brent Heard 07/27/2212:45 07/28/2209:00 Rc Method Batch Dilution Preparation Analysis Analyst Location date/time Fdate/time Gravimetric Analysis by Method 2540 C-2011 WG1905119 1 08/03/2217:46 08/03/2218:00 SLP Mt. Juliet, TN Wet Chemistry by Method 350.1 WG1904045 1 08/03/2215:57 08/03/2215:57 SL Mt. Juliet, TN F Wet Chemistry by Method 365.4 WG1907864 1 08/03/22 09:10 08/09/22 1128 LDT Mt. Juliet, TN Wet Chemistry by Method 9056A WG1902443 1 07/29/22 04:10 07/29/22 04:10 LBR Mt. Juliet, TN Wet Chemistry by Method 9060A WG1909545 1 08/22/2219:03 08/22/2219:03 BGM Mt. Juliet, TN RC Metals (ICPMS) by Method 6020B WG1903521 1 08/01/2215:05 08/02/22 14:37 JPD Mt. Juliet, TN Metals (ICPMS) by Method 6020B WG1905934 1 08/09/2210:35 08/12/2217:24 JPD Mt. Juliet, TN Collected by Collected date/time Received date/time MW-6 L1519627-03 GW Brent Heard 07/27/2214:55 07/28/2209:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Gravimetric Analysis by Method 2540 C-2011 WG1905119 1 08/03/2217:46 08/03/2218:00 SLP Mt. Juliet, TN Wet Chemistry by Method 350.1 WG1904045 1 08/03/2216:03 08/03/2216:03 SL Mt. Juliet, TN Wet Chemistry by Method 365.4 WG1907864 1 08/03/22 09:10 08/09/22 1130 LDT Mt. Juliet, TN Wet Chemistry by Method 9056A WG1902443 1 07/29/22 04:25 07/29/22 04:25 LBR Mt. Juliet, TN Wet Chemistry by Method 9060A WG1909545 1 08/23/22 1140 08/23/221140 SJF Mt. Juliet, TN Metals (ICPMS) by Method 6020B WG1903521 1 08/01/2215:05 08/02/22 14:40 JPD Mt. Juliet, TN Metals (ICPMS) by Method 6020B WG1905934 1 08/09/2210:35 08/12/2217:28 JPD Mt. Juliet, TN Collected by Collected date/time Received date/time MW-7 L1519627-04 GW Brent Heard 07/27/2216:10 07/28/2209:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Gravimetric Analysis by Method 2540 C-2011 WG1905119 1 08/03/2217:46 08/03/2218:00 SLP Mt. Juliet, TN Wet Chemistry by Method 350.1 WG1904045 1 08/03/2216:05 08/03/2216:05 SL Mt. Juliet, TN Wet Chemistry by Method 365.4 WG1907864 1 08/03/22 09:10 08/09/22 1131 LDT Mt. Juliet, TN Wet Chemistry by Method 9056A WG1902443 1 07/29/22 04:40 07/29/22 04:40 LBR Mt. Juliet, TN Wet Chemistry by Method 9060A WG1909545 1 08/23/22 12:03 08/23/2212:03 SJF Mt. Juliet, TN Metals (ICPMS) by Method 6020B WG1903521 1 08/01/2215:05 08/02/22 14:43 JPD Mt. Juliet, TN Metals (ICPMS) by Method 6020B WG1905934 1 08/09/2210:35 08/12/2217:31 JPD Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 3 of 20 CASE NARRATIVE FP All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. 0 Fr Rc 4�z F, Heather J Wagner F Project Manager RC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 4 of 20 MW-1 SAMPLE RESULTS - 01 Collected date/time: 07/27/22 11:30 L1519627 Gravimetric Analysis by Method 2540 C-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Dissolved Solids 182000 10000 1 08/03/202218:00 WG1905119 Wet Chemistry by Method 350.1 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Ammonia Nitrogen ND 250 1 08/03/202215:56 WG1904045 Wet Chemistry by Method 365.4 Result Qualifier RDL Analyte ug/I ug/I Phosphorus, Total ND 100 Wet Chemistry by Method 9056A Dilution Analysis Batch date / time 1 08/09/20221125 WG1907864 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Chloride 2310 1000 1 07/29/2022 03:55 WG1902443 Nitrate as (N) 451 B 100 1 07/29/2022 03:55 WG1902443 Sulfate 17000 5000 1 07/29/2022 03:55 WG1902443 Wet Chemistry by Method 9060A — FP - FC FS - Fn- - Rc F, [Al RC Result Qualifier Analyte ug/I TOC (Total Organic Carbon) 5160 Metals (ICPMS) by Method 6020B RDL ug/I 1000 Dilution Analysis date / time 1 08/22/202218:49 Batch WG1909545 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Chromium ND 2.00 1 08/12/202217:21 WG1905934 Chromium, Dissolved ND 2.00 1 08/02/202214:33 WG1903521 Copper ND 5.00 1 08/12/202217:21 WG1905934 Copper, Dissolved ND 5.00 1 08/02/202214:33 WG1903521 Iron 704 100 1 08/12/202217:21 WG1905934 Iron,Dissolved ND 100 1 08/02/202214:33 WG1903521 Lead ND 2.00 1 08/12/202217:21 WG1905934 Lead,Dissolved ND 2.00 1 08/02/202214:33 WG1903521 Nickel ND 2.00 1 08/12/202217:21 WG1905934 Nickel, Dissolved ND 2.00 1 08/02/202214:33 WG1903521 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 5 of 20 MW-5 SAMPLE RESULTS - 02 Collected date/time: 07/27/22 12:45 L1519627 Gravimetric Analysis by Method 2540 C-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Dissolved Solids 82000 10000 1 08/03/202218:00 WG1905119 Wet Chemistry by Method 350.1 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Ammonia Nitrogen ND 250 1 08/03/202215:57 WG1904045 Wet Chemistry by Method 365.4 Result Qualifier RDL Analyte ug/I ug/I Phosphorus, Total 100 100 Wet Chemistry by Method 9056A Dilution Analysis Batch date / time 1 08/09/20221128 WG1907864 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Chloride 15600 1000 1 07/29/2022 04:10 WG1902443 Nitrate as (N) ND 100 1 07/29/2022 04:10 WG1902443 Sulfate 17500 5000 1 07/29/2022 04:10 WG1902443 Wet Chemistry by Method 9060A — FP - FC FS - Fn- - Rc F, [Al RC Result Qualifier Analyte ug/I TOC (Total Organic Carbon) 4030 Metals (ICPMS) by Method 6020B RDL ug/I 1000 Dilution Analysis date / time 1 08/22/202219:03 Batch WG1909545 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Chromium 5.68 2.00 1 08/12/202217:24 WG1905934 Chromium, Dissolved ND 2.00 1 08/02/202214:37 WG1903521 Copper ND 5.00 1 08/12/202217:24 WG1905934 Copper, Dissolved ND 5.00 1 08/02/202214:37 WG1903521 Iron 2260 100 1 08/12/202217:24 WG1905934 Iron,Dissolved ND 100 1 08/02/202214:37 WG1903521 Lead 3.45 2.00 1 08/12/202217:24 WG1905934 Lead,Dissolved ND 2.00 1 08/02/202214:37 WG1903521 Nickel ND 2.00 1 08/12/202217:24 WG1905934 Nickel, Dissolved ND 2.00 1 08/02/202214:37 WG1903521 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 6 of 20 MW-6 SAMPLE RESULTS - 03 Collected date/time: 07/27/22 14:55 L1519627 Gravimetric Analysis by Method 2540 C-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Dissolved Solids 86000 10000 1 08/03/202218:00 WG1905119 Wet Chemistry by Method 350.1 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Ammonia Nitrogen ND 250 1 08/03/202216:03 WG1904045 Wet Chemistry by Method 365.4 Result Qualifier RDL Analyte ug/I ug/I Phosphorus, Total ND 100 Wet Chemistry by Method 9056A Dilution Analysis Batch date / time 1 08/09/20221130 WG1907864 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Chloride 15000 1000 1 07/29/2022 04:25 WG1902443 Nitrate as (N) ND 100 1 07/29/2022 04:25 WG1902443 Sulfate 13100 5000 1 07/29/2022 04:25 WG1902443 Wet Chemistry by Method 9060A — FP - FC FS - Fn- - Rc F, [Al RC Result Qualifier Analyte ug/I TOC (Total Organic Carbon) 3070 B Metals (ICPMS) by Method 6020B RDL ug/I 1000 Dilution Analysis date / time 1 08/23/20221140 Batch WG1909545 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Chromium 3.97 2.00 1 08/12/202217:28 WG1905934 Chromium, Dissolved ND 2.00 1 08/02/202214:40 WG1903521 Copper ND 5.00 1 08/12/202217:28 WG1905934 Copper, Dissolved ND 5.00 1 08/02/202214:40 WG1903521 Iron 6180 100 1 08/12/202217:28 WG1905934 Iron,Dissolved ND 100 1 08/02/202214:40 WG1903521 Lead 2.34 2.00 1 08/12/202217:28 WG1905934 Lead,Dissolved ND 2.00 1 08/02/202214:40 WG1903521 Nickel ND 2.00 1 08/12/202217:28 WG1905934 Nickel, Dissolved ND 2.00 1 08/02/202214:40 WG1903521 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 7 of 20 MW-7 SAMPLE RESULTS - 04 Collected date/time: 07/27/22 16:10 L1519627 Gravimetric Analysis by Method 2540 C-2011 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Dissolved Solids 414000 10000 1 08/03/202218:00 WG1905119 Wet Chemistry by Method 350.1 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Ammonia Nitrogen ND 250 1 08/03/202216:05 WG1904045 Wet Chemistry by Method 365.4 Result Qualifier RDL Analyte ug/I ug/I Phosphorus, Total 438 100 Wet Chemistry by Method 9056A Dilution Analysis Batch date / time 1 08/09/20221131 WG1907864 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Chloride 112000 1000 1 07/29/2022 04:40 WG1902443 Nitrate as (N) ND 100 1 07/29/2022 04:40 WG1902443 Sulfate 122000 5000 1 07/29/2022 04:40 WG1902443 Wet Chemistry by Method 9060A — FP - FC FS - Fn- - Rc F, [Al RC Result Qualifier Analyte ug/I TOC (Total Organic Carbon) 16700 Metals (ICPMS) by Method 6020B RDL ug/I 1000 Dilution Analysis date / time 1 08/23/202212:03 Batch WG1909545 Result Qualifier RDL Dilution Analysis Batch Analyte ug/I ug/I date / time Chromium 7.74 2.00 1 08/12/202217:31 WG1905934 Chromium, Dissolved 2.96 2.00 1 08/02/202214:43 WG1903521 Copper ND 5.00 1 08/12/202217:31 WG1905934 Copper, Dissolved ND 5.00 1 08/02/202214:43 WG1903521 Iron 7070 100 1 08/12/202217:31 WG1905934 Iron,Dissolved 246 100 1 08/02/202214:43 WG1903521 Lead 3.60 2.00 1 08/12/202217:31 WG1905934 Lead,Dissolved ND 2.00 1 08/02/202214:43 WG1903521 Nickel 2.19 2.00 1 08/12/202217:31 WG1905934 Nickel, Dissolved ND 2.00 1 08/02/202214:43 WG1903521 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 3 of 20 WG1905119 Gravimetric Analysis by Method 2540 C-2011 Method Blank (MB) (MB) R3324096-1 03/03/22 13 00 MB Result Analyte ug/I Dissolved Solids U MB Qualifier MB MDL MB RDL ug/I ug/I 10000 10000 L1519361-01 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1519627-01,02,03,04 (OS) L1519361-01 03/03/22 13:00 • (DUP) R3324096-3 03/03/22 13 00 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I %_ Dissolved Solids 1100000 1130000 1 2.15 5 Laboratory Control Sample (LCS) (LCS) R3324096-2 03/03/22 13 00 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I Dissolved Solids 8800000 8200000 93.2 77.3-123 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 9 of 20 WG1904045 QUALITY CONTROL SUMMARY Wet Chemistry by Method 350.1 11519627-01,02,03,04 Method Blank (MB) (MB) R3322347-1 03/03/22 15:44 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Ammonia Nitrogen U 117 250 L1519468-02 Original Sample (OS) • Duplicate (DUP) (OS) L1519463-02 03/03/22 15:51 • (DUP) R3322347-5 03/03/22 15:53 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I %_ Ammonia Nitrogen ND ND 1 0.000 10 L1519732-03 Original Sample (OS) • Duplicate (DUP) (OS) L1519732-03 03/03/22 16:14 • (DUP) R3322347-7 03/03/22 16:15 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I Ammonia Nitrogen ND ND 1 0.000 10 Laboratory Control Sample (LCS) (LCS) R3322347-2 03/03/22 15:45 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I Ammonia Nitrogen 7500 7280 97.1 90.0-110 L1519732-02 Original Sample (OS) • Matrix Spike (MS) (OS) L1519732-02 03/03/22 16:11 • (MS) R3322347-6 03/03/22 16:12 Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier Analyte ug/I ug/I ug/I Ammonia Nitrogen 5000 ND 4890 97.7 1 90.0-110 L1517696-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1517696-01 03/03/22 16:42 • (MS) R3322347-8 03/03/22 16:44 • (MSD) R3322347-9 03/03/22 16:45 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I Ammonia Nitrogen 5000 ND 4760 4870 95.3 97.3 1 90.0-110 2.12 10 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 10 of 20 WG1907864 QUALITY CONTROL SUMMARY Wet Chemistry by Method 365.4 L1519627-01,02,03,04 Method Blank (MB) C p (MB) R3324133-1 03/09/22 1113 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I ITC] Phosphorus, Total U 35.0 100 FS L1519592-01 Original Sample (OS) • Duplicate (DUP) [�n] (OS) L1519592-01 03/09/22 11:16 • (DUP) R3324133-3 03/09/22 1117 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits F Analyte ug/I ug/I Phosphorus, Total 661 645 1 2.45 20 L1519592-02 Original Sample (OS) • Duplicate (DUP) GI (OS) L1519592-02 03/09/22 11:21 • (DUP) R3324133-6 03/09/22 1122 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits 1711 Analyte ug/I ug/I Phosphorus, Total 362 368 1 1.64 20 FSc Laboratory Control Sample (LCS) (LCS) R3824133-2 08/09/22 1114 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I Phosphorus, Total 3780 3380 89.4 Rec. Limits LCS Qualifier 83.2-116 L1519592-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1519592-01 03/09/22 11:16 • (MS) R3324133-4 03/09/22 1118 • (MSD) R3324133-5 03/09/22 1119 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I Phosphorus, Total 2500 661 2860 2710 88.0 82.0 1 90.0-110 J6 J6 5.39 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 11 of 20 WG1902443 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9056A 11519627-01,02,03,04 Method Blank (MB) (MB) R3820643-1 07/23/22 2342 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Chloride U 379 1000 Nitrate 52.2 J 48.0 100 Sulfate U 594 5000 L1518846-01 Original Sample (OS) • Duplicate (DUP) (OS) L1513346-01 07/29/22 00:26 • (DUP) R3320643-3 07/29/22 00:41 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I Chloride 55500 55400 1 0.127 15 Nitrate ND ND 1 1.59 15 Sulfate 5860 5850 1 0.249 15 L1519583-01 Original Sample (OS) • Duplicate (DUP) (OS) L1519533-01 07/29/22 05:39 • (DUP) R3320643-6 07/29/22 05:54 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I Chloride 2230 2190 1 1.56 15 Nitrate 1210 1200 1 0.348 15 Sulfate 5000 ND 1 0.390 15 Laboratory Control Sample (LCS) (LCS) R3820643-2 07/28/22 23:57 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I Chloride 40000 40400 101 Nitrate 8000 8020 100 Sulfate 40000 40500 101 Rec. Limits LCS Qualifier 80.0-120 80.0-120 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 12 of 20 WG1902443 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9056A 11519627-01,02,03,04 L1518846-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1513346-01 07/29/22 00:26 • (MS) R3320643-4 07/29/22 00:56 • (MSD) R3320643-5 07/29/22 0111 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I Chloride 50000 55500 106000 107000 101 104 1 80.0-120 1.22 15 Nitrate 5000 ND 5150 5310 102 105 1 80.0-120 2.91 15 Sulfate 50000 5860 58500 59900 105 108 1 80.0-120 2.45 15 L1519583-01 Original Sample (OS) • Matrix Spike (MS) (OS) L1519533-01 07/29/22 05:39 • (MS) R3320643-7 07/29/22 06:09 Spike Amount Original Result MS Result MS Rec. Analyte ug/I ug/I ug/I Chloride 50000 2230 53100 102 Nitrate 5000 1210 6230 100 Sulfate 50000 5000 55500 101 Dilution Rec. Limits MS Qualifier 1 80.0-120 1 80.0-120 1 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 13 of 20 -------------- WG1909545 Wet Chemistry by Method 9060A Method Blank (MB) (MB) R3329501-2 03/20/22 1108 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 369 J 102 1000 Method Blank (MB) (MB) R3329506-2 03/23/22 1120 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 220 J 102 1000 Method Blank (MB) (MB) R3831484-2 03/22/22 1622 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) U 102 1000 L1519185-04 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY 11519627-01,02,03,04 (OS) L1519135-04 03/22/22 16:54 • (DUP) R3331434-4 03/22/22 17:07 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I TOC (Total Organic Carbon) ND ND 1 0.000 20 Laboratory Control Sample (LCS) (LCS) R3829501-1 08/20/22 10:56 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I TOC (Total Organic Carbon) 75000 77800 104 85.0-115 Laboratory Control Sample (LCS) (LCS) R3829506-1 08/23/22 1106 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I TOC (Total Organic Carbon) 75000 83700 112 85.0-115 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 14 of 20 WG1909545 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9060A 11519627-01,02,03,04 Laboratory Control Sample (LCS) (LCS) R3331434-1 03/22/22 15:53 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I TOC (Total Organic Carbon) 75000 80800 108 85.0-115 L1519185-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1519135-01 03/20/22 13:02 • (MS) R3329501-3 03/20/22 13:25 • (MSD) R3329501-4 03/20/22 13:47 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte ug/I ug/I ug/I ug/I TOC (Total Organic Carbon) 50000 3630 56700 55000 106 103 L1519185-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) Dilution Rec. Limits MS Qualifier MSD Qualifier RPD 1 80.0-120 3.06 (OS) L1519135-02 03/20/22 14:02 • (MS) R3329501-5 03/20/22 14:25 • (MSD) R3329501-6 03/20/22 14:47 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I TOC (Total Organic Carbon) 50000 3840 58600 57800 110 108 1 80.0-120 1.46 RPD Limits 20 RPD Limits 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 15 of 20 WG1903521 Metals (ICPMS) by Method 6020B Method Blank (MB) (MB) R3321727-1 03/02/22 13:07 MB Result Analyte ug/I Chromium, Dissolved U Copper, Dissolved U Iron,Dissolved U Lead,Dissolved U Nickel, Dissolved U MB Qualifier MB MDL MB RDL ug/I ug/I 1.24 2.00 1.51 5.00 28.1 100 0.849 2.00 0.816 2.00 QUALITY CONTROL SUMMARY L1519627-01,02,03,04 Laboratory Control Sample (LCS) (LCS) R3821727-2 03/02/22 1310 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I Chromium, Dissolved 50.0 50.5 101 80.0-120 Copper, Dissolved 50.0 49.6 99.1 80.0-120 Iron,Dissolved 5000 5250 105 80.0-120 Lead,Dissolved 50.0 49.9 99.7 80.0-120 Nickel, Dissolved 50.0 50.0 99.9 80.0-120 L1519551-09 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1519551-09 03/02/22 13:13 • (MS) R3321727-4 03/02/22 13:20 • (MSD) R3321727-5 03/02/22 13:24 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I Chromium, Dissolved 50.0 ND 50.1 51.0 100 102 1 75.0-125 1.71 Copper, Dissolved 50.0 ND 49.2 48.7 98.3 97.5 1 75.0-125 0.855 Iron,Dissolved 5000 ND 5050 5110 99.5 101 1 75.0-125 1.15 Lead,Dissolved 50.0 ND 47.2 47.2 94.5 94.3 1 75.0-125 0.174 Nickel, Dissolved 50.0 ND 49.6 50.5 95.4 97.3 1 75.0-125 1.89 RPD Limits 20 20 20 20 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 16 of 20 WG1905934 Metals (ICPMS) by Method 6020B Method Blank (MB) (MB) R3325303-6 03/12/22 16:38 MB Result Analyte ug/I Chromium U Copper U Iron U Lead U Nickel U MB Qualifier MB MDL MB RDL ug/I ug/I 1.24 2.00 1.51 5.00 28.1 100 0.849 2.00 0.816 2.00 Laboratory Control Sample (LCS) (LCS) R3825808-7 08/12/22 16:42 Spike Amount LCS Result Analyte ug/I ug/I Chromium 50.0 48.4 Copper 50.0 47.9 Iron 5000 4930 Lead 50.0 47.7 Nickel 50.0 48.8 QUALITY CONTROL SUMMARY 11519627-01,02,03,04 LCS Rec. Rec. Limits LCS Qualifier 96.8 80.0-120 95.7 80.0-120 98.5 80.0-120 95.5 80.0-120 97.6 80.0-120 L1519896-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1519396-04 03/12/22 16:45 • (MS) R3325303-9 03/12/22 16:52 • (MSD) R3325303-10 03/12/22 16:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I Chromium 50.0 ND 49.9 50.6 99.8 101� 1 75.0-125 1.36 Copper 50.0 ND 49.6 49.1 93.4 92.3 1 75.0-125 1.17 Iron 5000 ND 5130 5190 101 103 1 75.0-125 1.14 Lead 50.0 ND 50.2 49.9 100 99.9 1 75.0-125 0.581 Nickel 50.0 ND 49.7 50.6 96.3 98.0 1 75.0-125 1.65 RPD Limits 20 20 20 20 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 17 of 20 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions u Fc Fss] MDL Method Detection Limit. ND Not detected at the Reporting Limit (or MDL where applicable). Fn RDL Reported Detection Limit. Rec. Recovery. Fr RPD Relative Percent Difference. SDG Sample Delivery Group. U Not detected at the Reporting Limit (or MDL where applicable). Fc Analyte The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. F These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. LEI Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe samples from the time of collection until delivery to the laboratory for analysis. This section ofyour report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description B The same analyte is found in the associated blank. J The identification ofthe analyte is acceptable, the reported value is an estimate. J6 The sample matrix interfered with the ability to make any accurate determination, spike value is low. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 13 of 20 ACCREDITATIONS & LOCATIONS Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 F Alabama 40660 Nebraska N E-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Fc Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TNO02 California 2932 New Mexico TN00003 Fss] Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 3 Fn Georgia NELAP North Carolina 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Fr Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 6 QC Kansas E-10277 Rhode Island LA000356 Kentucky' 6 KY90010 South Carolina 84004002 Kentucky 2 16 South Dakota n/a 7 C71 Louisiana A130792 Tennessee'" 2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texass LABO152 Maryland 324 Utah TN000032021-11 Massachusetts M-TNO03 Vermont VT2006 Michigan 9958 Virginia 110033 F Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A2 LA A2LA— ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2 LA — ISO 17025 5 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Frit Car Inc. 3522054 L1519627 03/30/22 13:49 19 of 20 Billing Information: Analysis / Container / Preservative Chain of Custody Page _ of Frit Car Inc. 012 US Hwy 17N Accounts Payable Pres chk PO Box 1340 *ESC New Bern, NC 28560 Brewton, AL 36427 L-A-B S C-1-E-N-C•E•5 12065 Leaanon Rd • � 11] Report to: Email To: Connie Pettis pettts(Rrltcar.com Mount Juliet. TN 17122 Phone. 615-759-58.58 Phone: 800-767-5859 rav 615-758-5859 ❑� i t Project Bridgeton Facility City/State ,L� 1jr Collected: Nri4 19') N Description J L # 5l P7 Phone:252-63$-2675 Client Project # Lab Project # Fax: 05`1 FRITINCNBNC-GW 41 a K099 lam.. 0. T Collected by (print): Site/Facility ID # P.O. # tq Li (A Acctnum: FRITINCNBNC eat D ` = i Z L Template:T171121 Collected by (signature): Rush? (Lab MUST Be Notified) Quote # Same Day Five Day Q LL �- Prelogin: Next Day 5 Day (Rad Only) Date Results Needed Z -0 Ci O TSR: Heather Wagner Immediately _Iwo Day 10 Day (RadOnly) No.? V ,� � PB: Packed on Ice N Y _-._. Three Day of C O L p rn y O M 2 O N ❑ U ❑ Sample ID Comp/Grab Matrix' Depth Date Time ntrs Shipped Via: U Remak; Sa mnlr Jr {lah nily) Gait, rw 121 111,0 5 1) d ILA Gw �7- I Li ISS5 J Fa G V 1 I I L ioo`J ' Matrix'Remarks: sample 1eCE :^.i Cr =CxiiSc CDC Seal Present/Ir.ta_t: N7 A—N SS -Soil AIR -Air F- Filter pH Temp_ GW - Groundwater B- Bioassay COC Signed/Accurate: Y —N �_Tt WW - Waste Water Flow Other Bottles arrive intact: _ Y Correct bottles used: y fJ aW - Drinking Water Samples returned via: 1 _ Sufficient volume sent: Y _N QT - Other _ UPS _ Fed Ex ,Lcourier _ Tracking # if Applicablz VOA Zero Headspace: N reservation Correct/Checked: � to Relinquished : {Signature) Date: Time Received by: (Signature) Trip Blank Received: Yes No 6n x, ��,� I L SoHCL eOH TBR Relinquished by: (Signature) Date: Time: Received by: (Signature) ; Temp:��'C Botttes Received If preservation required by Login: Date/Time 711712,z l7• .- 20 Relinquished by : (Signature) Date: Time: Receive r lab by: (Signature) Date: Time: T /1(� Hold: Condition`, NCF / 6/ 7