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HomeMy WebLinkAboutNC0023884_Wasteload Allocation_19940520NPDES WASTE LOAD ALLOCATION PERMIT NO.: NC0023884 PERMITTEE NAME: FACILITY NAME: City of Salisbury Grants Creek Wastewater Treatment Plant Facility Status: Existing Permit Status: Renewal Major Minor Pipe No.: 001 Design Capacity: 7.50 MGD Domestic (% of Flow): Industrial (% of Flow): 78 % 22 % Comments: Pretreatment info requested. Percent industrial flow is based on permitted flow and SIU flows reported in application. RECEIVING STREAM: Grants Creek Class: C Sub -Basin: 03-07-04 Reference USGS Quad: E 17 NW (please attach) County: Rowan Regional Office: Mooresville Regional Office Previous Exp. Date: 12/31/90 Treatment Plant Class: Class IV Classification changes within three miles: none L�c0.s Requested by: -eh i"+owc Date: 4/14/93 Prepared by: � Date: 3 11 Reviewed by: i , a.tr Date: Modeler Date Rec. I # 6AJ rS 9 s o 2 Drainage Area (mi ) 1--5- 9 Avg. Streamflow (cfs): 7Q10 (cfs) Winter 7Q10 (cfs) //. 5-1 30Q2 (cfs) 167-15- Toxicity Limits: IWC , % Acut me Instream Monitoring: K - 1!5.& P Parameters l e , 77G,� Co �, �U�r, �YI`/,_�VHi , /Uvk Upstream Location`,95 r}- &,bore occAal( Downstream '' Locatioabore S1je.7cP- i✓wrPw,-f4l1 hl—/- 0 dw1e,JA, -., s:/* z mom - of ,.-«. fs ('„eeK. Effluent Characteristics Summer Winter BOD5 (mg/1) i ✓, NH3-N (mg/1) l D.O. (mom) .5— S' TSS (mg/1) 41) F. Col. V100 ml) pH (SU)'- `I �- p�fra�i ems, dad wcni R rc a tle 7 Comments: Alelyrrn2 - Cam, Zh , T , ur a •n�nfynuna�taceKf D/r�.� -ni 5Z '��<.lc L�c�N; Sr`a�c -a• vtu 14- ✓ rxc��al be re�caleer. Laa� wo. 062 kv- FACT SHEET FOR WASTELOAD ALLOCATION Request # 7410 Facility Name: City of Salisbury WWTP N C DEPT. OF H&ALTIL NPDES No.: NCO023884 RONM N'rI RESOURGES Type of Waste: Domestic/ Industrial &NATURAL Facility Status: Existing APR 25 jqu Permit Status: Renewal Receiving Stream: Stream Classification: Grants Creek C ��t 0 {�ViSIDtI OfEI E AE6 ONAI Subbasin: 03-07-04 t140RESVIL County: Rowan Stream Characteristic: Regional Office: Mooresvillw USGS # Requestor: Charles Lowe Date: Date of Request: 9/28/92 Drainage Area (mi2): 65.8 Topo Quad: E17NW Summer 7Q10 (cfs): 5.8 Winter 7Q10 (cfs): 12.4 Average Flow (cfs): 79 30Q2 (cfs): IWC (%): 67 Wasteload Allocation Summary (approach taken, corresponaence wltn region. gra. erc. There were no observed DO violations instream during the summer of 1992. However, the plant has acheived better than permitted limits. Instream violations occured in 1991. Facility is working to alleviate sludge build-up in the plant which has caused mercury violations. Facility failed toxicity tests in Dec 1992. In a 1989-1990 survey of High Rock lake, Grants Creek was ranked second among tributaries for nutrient impairment. There is little available dilution (1.5:1) for wastewater. In addition, the creek below the WWTP is very slow moving so there is ample retention time for algal growth. Algal blooms are frequent below the WWTP. Upon completion of a nutrient management plan for High Rock Lake, nutrient limits may be required. Relocation of the discharge to the Yadkin River is recommended in order to allow for expansion of the WWTP and to provide better assimilation of the wastewater. Special Schedule Requirements and additional comments frfrom Prepared by: -0 -- Dater tsy Johnson Reviewed by � ^ , ���� Instream Assessment: �. (�Lt Date: �D Regional Supervisor:�G- 'D /2 /?IS Date: Permits & Engineering: Date: 9 RETURN TO TECHNICAL SERVICES BY: iY i 1994 - fLo - /. -Z lw�/ Kaio WLA plaj j r CONVENTIONAL PARAMETERS Existing Limits: Wasteflow (MGD): BOD5 (mg/1): NH3N (mg/1): DO (mg/1): TSS (mg/1): Fecal Col. (/100 ml): pH (SU): Residual Chlorine (µg/1) Oil & Grease (mg/1): TP (mg/1): IN (mg/1): Recommended Limits: Wasteflow (MGD): BOD5 (mg/1): NH3N (mg/1): DO (mg/1): TSS (mg/1): Fecal Col. V100 ml): pH (SU): Residual Chlorine (µg/1) Oil & Grease (mg/1): TP (mg/1): TN (mg/1): Monthly Average Summer Winter 7.5 7.5 15 30 6 12 5 5 30 30 200 200 6-9 6-9 monitor monitor monitor I monitor monitor I monitor Grants Creek Monthly Average Rummer Winter 7.5 7.5 15 30 6 12 5 5 30 30 200 200 6-9 6-9 monitor monitor monitor monitor monitor monitor A nutrient management plan for High Rock Lake is currently being developed which may require nutrient controls at this facility.:V- 15 /14(( A T7Prant-not reliCQkd to `adelnl 4,e. twMex�-/,m,6 cell &- 51ottz-oP fhe-ad. X5 TOXICS/METALS Type of Toxicity Test: Chronic, quarterly Existing Limit: 67% Recommended Limit: 67% (Grants Creek) Monitoring Schedule: Mar, Jun, Sep, Dec Existing Limits Cadmium (ug/1): Chromium (ug/1): Copper (ug/1): Nickel (ug/1): Lead (ug/1): Zinc (ug/1): Cyanide (ug/1): Aluminum (ug/1): Fluoride (mg/1): Mercury (ug/1): Chlorides (mg/1): Toluene (ug/1): TDS (mg/1): Silver (ug/1): 7.5 mgd Daily max WO or EL monitor 75 W monitor monitor 37 W monitor monitor monitor 2.7 W 0.018 W monitor monitor monitor monitor Recommended Limits 7.5 mgd Dailv max WO or EL Cadmium (ug/1): Cyanide (ug/1): Mercury (ug/1): Chromium (ug/1): Nickel (ug/1): Lead (ug/1): Aluminum (ug/1): Copper (ug/1): Zinc (ug/1): Iron (ug/1): TDS (mg/1): Silver (ug/1): Toxics were reevaluated based on observed DMR data and new EPA methods. Limits are required for cadmium, cyanide, and mercury based on observed and predicted exceedances of the water quality allowable levels. Chromium, nickel, lead, and aluminum will -be monitored through the long-term monitoring plan. The observed and predicted values are lower than the allowable levels with the exception of aluminum which greatly exceeds the allowable but which has no state standard. Monthly monitoring is recommended for copper, zinc, iron, and silver due to high levels observed in the effluent. , Limits Changes Due To: Change in 7Q10 data Change in stream classification Relocation of discharge Change in wasteflow New pretreatment information Failing toxicity test Other (onsite toxicity study, interaction, etc.) Parameter(s) Affected toxics, new method _x_ Parameter(s) are water quality limited. For some parameters, the available load capacity of the immediate receiving water will be consumed. This may affect future water quality based effluent limitations for additional dischargers within this portion of the watershed. X' No parameters are water quality limited, but this discharge may affect future allocations. INSTREAM MONITORING REQUIREMENTS Grants Creek discharge Upstream Location: 25 feet above the outfall Downstream Location: 1. above the. Spencer WWTP outfall 2. at the mouth of Grants Creek Parameters: Temp, DO, Fecal, Cond Special instream monitoring locations or monitoring frequencies: at downstream site 2: June -Sept. (1/wk), TP, PO4, TKN, NH3-N, NOx MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS Adequacy of Existing Treatment Has the facility demonstrated the ability to meet the proposed new limits with existing treatment facilities? Yes No If no, which parameters cannot be met? Would a "phasing in" of the new limits be appropriate? Yes No If yes, please provide a schedule (and basis for that schedule) with the regional office recommendations: If no, why not? Special Instructions or Conditions :m �5 Cu✓iea��l y toofA�n 00_ a- n�dfn� model of M h f�cxk (cam,, u '� Ct�mjae&)vu of 4he model a cj acfapbi2 of nine. lnanayzn&� 64QWe,5 A3 p�mrf mmy b� reo�d IDDinclude- adned 11m,45, Wasteload sent to EPA? (Major) (Y or N) (If yes, then attach schematic, toxics spreadsheet, copy of model, or, if not modeled, then old assumptions that were made, and description of how it fits into basinwide plan) Additional Information attached? (Y or N) If yes, explain with attachments. Facility Name 1aysuz, -e �& Permit # 13 k '`f Pipe # Oct! CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in: 1.) The North Carolina Ceriodaphnia chronic effluent bioassay procedure (North Carolina Chronic Bioassay Procedure _ Revised *September 1989) or subsequent versions. The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is 6 7 % (defined as treatment two in the North Carolina procedure document). The permit holder shall perform r r monitoring using this procedure to establish compliance with the permit condition. The first test will be performed after thirty days from the effective date of this permit during the months of My . J L. Sr-iP, T>Ec . Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly. in the months specified above. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. 7Q10 _57 Jt' cfs Permitted Flow 7. S MGD IWC ; G 7 % % Basin & Sub -basin 63 - 07- D Y Receiving Stream G',-an!!Sj County Flo&w,✓ Recommended by: Date 4113V QCL PlF Version 9191 COMMENTS ON PROPOSED WL n FOR cp L T !c�PTJRY ' c GRANT CREEK WWTP The staff of this Office has had an opportunity to review the attached WLA Approval For d the following owi g comments are _ a_ a:h__. ..__ r _m an•_. __ n� _ offered. Substantial documentation exists regarding the level of Wn found in both High Rock rake and its tributaries. As stated in the management recommendations for High pock Lake, impairment is consistent throughout the lake with violation of turbidity, chlorophyll -a and a documented proliferation of algae blooms. Additional nutrient loading from point Sources is expected, to only exacerbate the blooms:. This reservoir, being the -first on the Yadkin chain, also acts as a settling basin for the nutrient rich -sediments that are deposited from upstream nonpoint sources; a trend likely to continue unless Strict best management % practices are implemented, according to the management -l.an'for ,(,- High Rock, all new or expanding dischargers ,as roe I as =11 S existing major dischargers? should be required to construr't state-of-the-art nutrient removal technology to mPet limits of bc- J 0.5 mg! l TP and 4 mg; l TN. / T Rased on the above information, not requiring Salisbury to install nutrient removal_ technology would appear to be t=k __ a significant step backward In the protection of WQ within this reservoir. Having known for some time that nutrient removal is a major issue for point source dischargers in this basin, City officials are expecting nutrient limits to be placed in the Permit upon renewal. These limits will allow the City to gather support for passage of bonds needed to fund the construction of a new state-of-the-art TX?WTP complete with nutrient remn-1,7al technology. The rity's two existing TA?WTPs are antiquated and will require a significant expenditure to upgrade to meet current standards, not to mention future constraints that may be imposed. Therefore failure to incorporate nutrient limits into the Permit during this ,renewal period allows little i nre_nti ve for Sal i sburlr to pursue the abandonment of the existing facilities bse _ a L1,: .1L eP.t to the constriction of a new WWTP o,r7 upgrading the existing Wu?TPs, an option ,tie feel cure they do not want to consider For these reasons., we cannot concur with the WLA as submitted Note for Betsy Johnson From: Ruth Swanek on Wed, May 18, 1994 4:19 PM Subject: Salisbury To: Dave Goodrich Cc: Betsy Johnson; Coleen Sullins; Don Safrit I talked to MIke Parker today. He really wants nutrient limits in Salisbury's permit. He indicated that Town wants them to help them get bond money. He is going to call town and tell them limits will not be included and to send a letter requesting them if they really want them. He said that if limits are not included in permit, he would like to see a special cover letter written to facility to send out with permit. The letter should state that DEM is currently performing nutrient study on High Rock Lake, and that preliminary findings indicate that it is likely that Salisbury will receive nutrient limits and that there is a good. possibility that they will be state of the art. He also wants to let them know what type of time frame they will have to come into compliance with limits once strategy established (i.e. he stated 2 years from date strategy adopted; for NSW we have done 5 for many waterbodies). We should probably fax him a copy of the letter we will send out. Please let me know if you have any questions or need any help from our end. Thanks. Page: 1 April 15, 1994 ►JI 8 6 ►I�� P� TO: . Monica Swihart FROM: Betsy Johnson THROUGH: Steve Bevington Ruth Swanek SUBJECT: Salisbury Environmental Assessment The report discusses Grants Creek and Yadkin River but makes little reference to'Town Creek. The relocation is to eventually remove a discharge from Town Creek also. Discussion of current water quality in Town Creek and removal of the discharge should be included. As ususual for an environmental assessment for a discharge system this document has only one page about water quality impacts. There is a great deal of historical water quality information available on High Rock Lake. In addition, there is a recent High Rock Lake water quality report by Environmental Sciences. Data on Grants Creek and Town Creek are covered as well as the lake data. There is also quite a bit of self -monitoring data on Grants and Town Creek which should be summarized. The no -action alternative should inlcude a discussion of the age of the existing plants and be more specific about the existing compliance problems and parameters which may not be treated properly in the future, i.e., BOD, NH3, nutrients, DO... There should be amore complete discussion of the new wastewater treatment plant. What type of plant is it? What kind of removal efficiencies will it have? Though the new plant has not received permit limits yet, there should be a discussion of speculative limits. DEM provided a letter with speculative limits in February 1993. Speculative limits were provided for BOD5, NH3, and DO. Dechlorination or alternate disinfection will be required. Nutrient removal is recommended due to eutrophication in High Rock Lake. Chemical specific limits will be based on Salisbury's pretreatment program and final diffuser design. Modeling and design for the diffuser are currently in progress. There should be a short discussion of mitigation of acute impacts by discharging through a diffuser which will increase near field mixing. In addition, the facility will be required to conduct quarterly toxicity testing. This will likely be a chronic test at a percentage based on near field dilution. If you have any questions or comments, please call me at Ext. 508. State of North Carolina Department of Environment, Health and Natural Resources James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary Steven J. Levitas, Deputy Secretary Division of Environmental Management Water Quality Section P.O. Box 29535 Raleigh, N.C. 27626-0535 FAX:(919) 733-9919 FAX TO: I A i Vr FaIFAX NUMBER: ► 4VO 1 FROM: -f5i Sc-Dk-.sue PHONE: (919) 733-5083 NO. OF PAGES INCLUDING THIS SHEET: v � �i/01�0 Z 'of a's �� �� y A41Ivy l y . An Equal Opportunity Affirmative Action Employer FACT SHEET FOR WASTELOAD ALLOCATION Facility Name: NPDES No.: Type of Waste: Facility Status: Permit Status: Receiving Stream: Stream Classification: Subbasin: County: Regional Office: Requestor: Date of Request: Topo Quad: City of Salisbury WWTP NCO023884 Domestic/ Industrial Existing Renewal Grants Creek C 03-07-04 Rowan Mooresville Charles Lowe 9/28/92 E17NW Wasteload Allocation Summary Request # 7410 Stream Characteristic: USGS # Date: Drainage Area (mi2): 65.8 Summer 7Q10 (cfs): 5.8 Winter 7Q10 (cfs): 12.4 Average Flow (cfs): 79 30Q2 (cfs): IWC (%): 67 (approach taken. correspondence with region. EPA. etc.) There were no observed DO violations instream during the summer of 1992. However, the plant has acheived better than permitted limits. Instream violations occured in 1991. Facility is working to alleviate sludge build-up in the plant which has caused mercury violations. Facility failed toxicity tests in Dec 1992. In a 1989-1990 survey of High Rock lake, Grants Creek was ranked second among tributaries for nutrient impairment. There is little available dilution (1.5:1) for wastewater. In addition, the creek below the WWTP is very slow moving so there is ample retention time for algal growth. `tie VUf - n UPsv. aV% p� 0. ri���p�n�' vtncw�a�w--'�' �r�— 4-.�✓ I(�c� L-., Fes- Gw�--+.5 C^_'L' .-- VjW ­%( r -jai r c s -(.. �4„ro � r►�(N� �i� S Special Schedule Requirements and additional comments from Reviewers: Recommended by: (�r ' ` `� Date: g `� Betsy J o nson Reviewed by Instream Assessment: Regional Supervisor: Permits & Engineering: RETURN TO TECHNICAL SERVICES BY: Date: Date: Date: CONVENTIONAL PARAMETERS Wasteflow (MGD): BOD5 (mg/1): NH3N (mg/1): DO (mg/1): TSS (mg/1): Fecal Col. (/100 ml): pH (SU): Residual Chlorine (µg/1): Oil & Grease (mg/1): TP (mg/1): TN (mg/1): Wasteflow (MGD): BOD5 (mg/1): NH3N (mg/1): DO (mg/1): TSS (mg/1): Fecal Col. (/100 ml): pH (SU): Residual Chlorine (µg/1): Oil & Grease (mg/1): TP (mg/1): TN (mg/1): Monthly Average Summer Winter 7.5 7.5 15 30 6 12 5 5 30 30 200 200 6-9 6-9 monitor monitor monitor monitor monitor monitor Grants Creek Monthly Average Summer Winter 0® 11 11 Yadkin River -All Yadkin River u )ACOUHP. Theu our . A nutrient management plan for High Rock Lake is currently being developed—►jk i't L. ��I r� ��r;er►� ca,�k„o (� a� �— Type of Toxicity Test: Existing Limit: Recommended Limit: TOXICS/METALS Chronic, quarterly 67% 67% (Grants Creek) Monitoring Schedule: Mar, Jun, Sep, Dec Existing Limits 7.5 mgd Dailv max WO or EL Cadmium (ug/1): Chromium (ug/1): Copper (ug/1): Nickel (ug/1): Lead (ug/1): Zinc (ug/1): Cyanide (ug/1): Aluminum (ug/1): Fluoride (mg/1): Mercury(ug/1): Chlorides (mg/1): Toluene (ug/1): TDS (mg/1): Silver (ug/1): monitor 75 W monitor monitor 37 W monitor monitor monitor 23 W 0.01.8 W monitor monitor monitor monitor Recommended Limits 7.5 mgd Cadmium (ug/1): Cyanide (ug/1): Mercury (ug/1): Chromium (ug/1): Nickel (ug/1): Lead (ug/1): Aluminum (ug/1): Copper (ug/1): Zinc (ug/1): Iron (ug/1): TDS (mg/1): Silver (ug/1): Dailv max WO or EL 3 1 W 7.5 W 0.018 W monitor monitor monitor monitor monitor Toxics were reevaluated based on observed DMR data and new EPA methods. Limits are required for cadmium, cyanide, and mercury based on observed and predicted exceedances of the water quality allowable levels. Chromium, nickel, lead, and aluminum will be monitored through the long-term monitoring plan. The observed and,predicted values are lower than the allowable levels with the exception of aluminum which greatly exceeds the allowable but which has no state standard. Monthly monitoring is recommended for copper, zinc, iron, and silver due to high levels observed in the effluent. Limits Changes Due To: Change in 7Q10 data Change in stream classification Relocation of discharge Change in wasteflow New pretreatment information Failing toxicity test Other (onsite toxicity study, interaction, etc.) Parameter(s) Affected toxics, new method _x_ Parameter(s) are water quality limited. For some parameters, the available load capacity of the immediate receiving water will be consumed. This may affect future water quality based effluent limitations for additional dischargers within this portion of the watershed. No parameters are water quality limited, but this discharge may affect future allocations.' INSTREAM MONITORING REQUIREMENTS Grants Creek discharge Upstream Location: 25 feet above the outfall Downstream Location: 1. above the Spencer W ;TP outfall 2. at the mouth of Grants Creek Parameters: Temp, DO, Fecal, Cond Special instream monitoring locations or monitoring frequencies: at downstream site 2: June -Sept. (1/wk), TP, PO4, TKN, NH3-N, NOx MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS . Ad�uacy of Existing Treatment Has the facility demonstrated the ability to meet the proposed new limits with existing treatment facilities? Yes. No If no, which parameters cannot. be met? Would a "phasing in" of the new limits be appropriate? Yes . No If yes, please provide a schedule (and basis for that schedule) with the regional office recommendations: J If no, why not? IMMI-IMOMMMO MOM 1 Wasteload sent to EPA? (Major) (Y or N) (If yes, then attach schematic, toxics spreadsheet, copy of model, or, if not modeled, then old assumptions that were made, and description df how it fits into basinwide plan) Additional Information attached? (Y or N) If yes, explain with attachments. Facility Name Salisbury - Grants NPDES # 23884 Qw (MGD) 7.5 7010s (cfs) 5.8 IWC (%) 66.71 Recwing Stream Grants Creek Stream Class C -7. Ace�� - - S% I / 3Z Tn 4, INf',� e_ v, 3 TI, i7, P� Cr YvtU�`Jey� Ole4 Toxics Spreadsheet pb cu zn al cr ni hg fe ag CN cd 1 10 32 360 2.8 16 0.1 640 2.5 5 0.2 1 3.44 0.1 780 1 2.7 1 530 1 3.35 0.1 810 2.76 9 38 320 2.34 16 0.1 790 2.1 5 0.13 1 0.1 730 1 0.1 780 1 0.1 810 0.1 1 19 1 594 6.45 6 0.1 860 3 80 0.05 1 10.35 0.1 840 1 8.29 0.1 990 1 5.35 0.1 1030 1 4.81 0,1 72 1 34 39 480 4.9 5 0.1 420 2 40 381 1 6.4 0.1 440 1 8.8 0.1 1000 1 6.2 0.1 1000 0.1 1 16 28 340 3.2 3 0.1 525 5 5 0.1 5 0.1 350 3.5 0.1 409 1 0.1 380 0.1 0.5 20 33.4 432 3.5 5.1 0.1 480 4.2 5 0.2 0.5 0.1 390 2.6 0.1 450 0.5 0.1 420 0.5 450 1 22 44 500 11 6.1 0.39 1060 1.5 5 0.2 2.5 4.3 0.1 950 2.9 5 0.1 1040 0.5 4.7 0.1 1030 0.5 14 44 154 2.28 4 0.1 719 3.9 5 0.4 I DMR data only Toxics Spreadsheet 0.5 18 32 284 2.92 5 0.1 834 0.3 0.5 18 32 214 2.76 5 0.1 761 0.3 2.38 3.88 0.1 873 0.5 3.76 0.61 830 0.5 5.16 2.5 10 24.8 368 5 4 0.1 638 4 5 0.3 2.5 5 0.36 643 2.5 5 0.3 653 2.5 5 0.55 738 0.5 12 24 370 2.6 2 0.1 494 1.5 5 0.2 0.5 2.98 0.23 433 1.5 0.5 2.94 0.1 513 1.5 1.99 3.22 0.2 668 1.5 0.5 12 25 316 1.14 3 0.1 640 10 5 0.1 0.5 1.28 0.1 590 10 0.5 0.5 0.1 380 10 0.5 6.32 1.23 530 10 n 5 2.42 0.4 350 10 number samples 49 13 P4q4 13 39 13 50 48 18 11 13 max 5 34594 11 16 1.23 1060 10 80 381 standard 25 7 1 50 1 147 50 88 0.012 1 0.06 5 2 nh cu zn al cr ni ha fe as CN Cd std dev 0.98 6.49 10.70 113.46 2.29 4.35 0.22 231.34 3.46 22.86 101.47 mean 1.26 16.46 30.55 364.00 4.41 6.17 0.19 661.31 4.68 15.00 29.50 cv 0.78 0.39 0.35 0.31 0.52 0.70 1.20 0.35 0.74 1.52 3.44 mult. fact. 2 2 1.9 1 1.7 1.7 3.1 2.5 1 1.4 2.8 8 15 I `• Wi 4a . q 4 / . 1 S' Max. Pred. 1 10 1 68 1 83.6 1 1010 1 18.7 1 49.6 13,075 1 1484 1 28 1 640 1 5715 Allowable 37.5 10.5 74.9 220.3 74.9 131.9 0.0 1.5 0.1 7.5 3.0 C� LT - LIT pl"AV P lAAJ ekn 1 DMR data only